Regiochemical Aspects of the Platinum Oxide Catalyzed Hydrosilylation of Alkynes.

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2007 Organo-silicon compounds S 0060 Regiochemical Aspects of the Platinum Oxide Catalyzed Hydrosilylation of Alkynes. — The process is also successful for heteroaromatic substituents [cf. (XIII)]. In the case of terminal aromatic and aliphatic alkynes, the hydrosilylation is governed by steric and electronic factors. — (HAMZE, A.; PROVOT, O.; BRION, J.-D.; ALAMI*, M.; Synthesis 2007, 13, p2025-p2036; Lab. Chim. Therap., Fac. Pharm., BIOCIS, Univ. Paris-Sud, F-92296 Chatenay-Malabry, Fr.; Eng.) — Lindner 46- 144

Transcript of Regiochemical Aspects of the Platinum Oxide Catalyzed Hydrosilylation of Alkynes.

Page 1: Regiochemical Aspects of the Platinum Oxide Catalyzed Hydrosilylation of Alkynes.

2007

200746.fm Page 151 Monday, October 15, 2007 1:43 PM

Organo-silicon compoundsS 0060 Regiochemical Aspects of the Platinum Oxide Catalyzed Hydrosilylation of

Alkynes. — The process is also successful for heteroaromatic substituents [cf. (XIII)]. In the case of terminal aromatic and aliphatic alkynes, the hydrosilylation is governed by steric and electronic factors. — (HAMZE, A.; PROVOT, O.; BRION, J.-D.; ALAMI*, M.; Synthesis 2007, 13, p2025-p2036; Lab. Chim. Therap., Fac. Pharm., BIOCIS, Univ. Paris-Sud, F-92296 Chatenay-Malabry, Fr.; Eng.) — Lindner

46- 144