REFERENCES from Barry Master’s talks. CALIBRATION Latt, Cheung, Blout, PNAS 1965 Energy Transfer....

REFERENCES from Barry Master’stalks

CALIBRATIONLatt, Cheung, Blout, PNAS 1965

Energy Transfer. A System with Relatively Fixed Donor-Acceptor Separation

Synthesize ‘bisteroid’Attach donor and acceptor to the hydroxyl groups

Fixed donor-acceptor separation of 20 Å

Validate 1/ r sixth power rate

2Barry R. Masters

CALIBRATIONL. Stryer and R. P. Haugland, PNAS 1967

Energy Transfer. A Spectroscopic Ruler

Synthesize oligomers of poly-L-proline N=1-12Attach donor and acceptor to ends of oligomersN= 5 to 12 rigid

Fixed donor-acceptor separation of 12-46 Å

3Barry R. Masters

Validate 1/ r sixth power rate

Failure of the Ideal Dipole Approximation (IDA)

Munoz-Losa, C. Curutchet, B. P. Krueger, L. R. Hartselll, B. Mennucci

Biophysical Journal 96, June 2009

Ideal dipole approximation is implicit in Förster equation; it fails when molecules are “too close”

IDA valid to 20 Å with free rotations of donor and acceptor

IDA valid to only 50 Å if molecular motions of donor and acceptor are restricted

4Barry R. Masters

Energy Transfer in Monolayer Assemblies

• Spectroscopy of monolayer assemblies, in: Physical Methods of

Chemistry, Editor, A. Weissberger, B. Rossiter, Chapter VII, 577-

702 (1972)

• Part I. Principles and applications,

• H. Kuhn,

• Part II Experimental Procedure,

• D. Möbius, H. Bücher

5Barry R. Masters

A Theory of Sensitized Luminescence in

Solids D.L. Dexter

The Journal of Chemical Physics, vol. 21, no. 5, 836

(1953)

• Förster theory of energy transfer involves allowed transitions

• Dexter theory includes energy transfer by forbidden transitions

• Dexter theory is applicable for inorganic systems, i.e. inorganic phosphors

6Barry R. Masters

Long-range resonance energy transfer in molecular systems

• G. D. Scholes, Annu. Rev. Phys. Chem. 54: 57-87 (2003)

• Review of Förster theory for donor-acceptor pairs

• Review of electronic coupling for singlet-singlet, triplet-triplet,

pairs

• Discusses Coulombic coupling as well as electronic coupling

between molecular aggregates (excitons)

• Review of medium, weak, and strong coupling in energy transfer

• Energy transfer in complex molecular assemblies

7Barry R. Masters

Responsible Conduct of Research

B. R. Masters, Responsible Conduct of Research 8

Professor Barry R. MastersVisiting Scientist

Department of Biological EngineeringMassachusetts Institute of Technology

Cambridge, Massachusetts

Resources and References


CSE’s White Paper on Promoting Integrity in Scientific Journal Publications, 2009 update

http://www.councilscienceeditors.org

Avoiding plagiarism, self-plagiarism, and other questionable writing practices: A guide to ethical writing, Miguel Roig, Ph.D.

NIH Office of Research Integrityhttp://ori.gov/education/products/plagiarism

Uniform Requirements for Manuscripts Submitted to Biomedical Journals: Writing and Editing for Biomedical Publication (Updated October 2008) Publication Ethics: Sponsorship, Authorship, and Accountability, International Committee of Medical Journal Editors,

http://www.icmje.org

http://www.councilscienceeditors.org/



http://ori.gov/education/products/plagiarism

http://www.icmje.org/

Books• Shamoo, A.E., Resnik, D. B. Responsible Conduct of Research,

Second Edition, New York, Oxford University Press, 2009. ISBN 978-0-19-536824-6

• Emanuel E. J., Grady, C., Crouch, R. A., Lie, R.K., Miller, F. G., Wendler, D. (Eds.)The Oxford Textbook of Clinical Research Ethics, New York, Oxford University Press, 2009. ISBN 978-0-19-516865-5

• Beauchamp T. L., Childress, J. F. Principles of Biomedical Ethics, Fifth Edition, New York, Oxford University Press, 2001 ISBN 0-19-514332-9

• Steinbock, B. (Ed.) The Oxford Handbook of Bioethics, New York, Oxford University Press, 2007.

ISBN: 978-0-19-927335-5B. R. Masters, Responsible Conduct of

Research 10

Books• Scientific Style and Format, The CSE Manual for Authors, Editors, and

Publishers. 7th ed. Council of Science Editors, Reston (VA): The Council and The Rockefeller Press, 2006

• Coghill, AM, Garson, LR, eds. The ACS Style Guide, Effective Communication of Scientific Information, 3rd ed. New York, Oxford University Press, 2006

Part 1. Scientific Communications: Ethics in Scientific Communication, Peer Review, Copyright Basics

AMA Manual of Style, A Guide for Authors and Editors, 10th ed. New York, Oxford University Press , 2007

Ethical and Legal Considerations: Authorship Responsibility, Acknowledgements, Conflicts of Interest, Financial Disclosures, Duplicate Publication, Scientific Misconduct, Conflicts of Interest, Intellectual Property, Ownership, Access, Rights and Management, Confidentiality. Protecting Research Participants'’ and Patients’ Rights in Scientific Publication


Books• The Chicago Manual of Style, the Essential Guide for Writers, Editors, and

Publishers, 15th ed. Chicago, the University of Chicago Press, 2003– Chapter 4, Rights and Permissions: Copyright Law and the Licensing of Rights, Author’s

Responsibilities, Publisher’s Responsibilities

• Publication Manual of the American Psychological Association, 5th ed. Washington, DC, American Psychological Association, 2001– Chapter 2, Expressing Ideas and Reducing Bias in Language– Appendix C: Ethical Standards for the Reporting and Publishing of Scientific Information

MLA Style Manual and Guide to Scholarly Publishing, 2nd ed. Gibaldi J, New York, The Modern Language Association of America, 1998

Chapter 2, Legal Issues in Scholarly Publishing (A. F. Abelman): Copyright, Contracts, Defamation, Right of Privacy


BOOKS

• Andrews, LB, Mehlman, MJ, Rothstein, MA Genetics: Ethics, Law and Policy, second

edition, St. Paul, Thompson/West (2006)

This book discusses genetics research, biobanks, research on human embryos, commercialization of genetic research, and medical applications of genetics, genetic testing, screening, counseling, gene therapy, pharmacogenetics, and enhancement; forensics, privacy and confidentiality


Colloquium on Advances in Linear and Nonlinear Optical Microscopy

Confocal Microscopy to Nonlinear Optical Microscopy: Principles, Instruments,

Applications and Limitations

Professor Barry R. MastersVisiting Scientist

Department of Biological EngineeringMassachusetts Institute of Technology


14Barry R. Masters Confocal and Multiphoton Microscopy

References

• Noninvasive Diagnostic Techniques in Ophthalmology, (Editor, Barry R. Masters), Springer Verlag, New York, 1990

• Medical Optical Tomography: Functional

Imaging and Monitoring, Section Editor: B.R. Masters, SPIE Optical Engineering Press, Section V. Functional Imaging and Monitoring (Section Editor: B.R. Masters), 1993


References• Selected Papers on Confocal Microscopy, (Editor, Barry R. Masters),

Milestone Series MS 131, SPIE Optical Engineering Press, Bellingham, WA, 1996

• Selected Papers on Optical Low-Coherence Reflectometry and

Tomography, (Editor, Barry R. Masters), Milestone Series MS 165, SPIE Optical Engineering Press, Bellingham, WA, 2000

• Selected Papers on Multiphoton Excitation Microscopy,

(Editor, Barry R. Masters), Milestone Series, MS175, SPIE Optical Engineering Press, Bellingham, WA, 2003


References• "Biomedical Optical Biopsy" Vol. 2. Classic Articles in Optics and

Photonics on CD-ROM Series, OSA, Editors, R. R. Alfano and B. R. Masters, Optical Society of America, Washington, DC, 2004

• Confocal Microscopy and Multiphoton Excitation Microscopy: The

Genesis of Live Cell Imaging. B.R. Masters, SPIE, Optical Engineering Press, Bellingham, WA, 2006.

• Handbook of Biomedical Nonlinear Optical Microscopy, (Barry R. Masters, Peter T. C. So, Eds.), Oxford University Press, 2008

• Super-Resolution Optical Microscopy, Barry R. Masters, Cambridge University Press, NY (in preparation).


Reproduced with permission from: C.V. Raman, A Pictorial Biography,S. Ramaseshan and C. Ramachandra Rao, Indian Academy of Sciences,Bangalore, India, 1988

21Barry R. Masters

C.V. Raman: Discovery of the Effect and Attribution

of Credit

Barry R. Masters, Department of Biological Engineering, Massachusetts Institute of Technology


22Barry R. Masters

• Background, Education, and Professional Life• How did Raman discover the Raman Effect?• Raman’s equipment and experimental setup• Raman’s interests, research methodology, and his

scientific style• Attribution of credit• Research on Light Scattering in the 1920’s

23Barry R. Masters

References and Resources• C.V. Raman, The Molecular Scattering of Light, Nobel Lecture in

Physics, Dec. 11, 1930

• Raman Research Institute, Bangalore, India, www.rrr.res.in• Indian Academy of Sciences, Bangalore, India

• S. Ramaseshan and C. R Rao, C. V Raman, A Pictorial Biography, Bangalore, India, Indian Academy of Sciences, (1988)

• The Collected Papers of C. V. Raman, six volumes, Bangalore, India, Indian Academy of Sciences, (1988)

• A. Smekal, On the quantum theory of dispersion, Die Naturwissenschaften, 11, 873-875, (1923).

• H. A. Kramers and W. Heisenberg, On the dispersion of radiation by atoms. Zeitschrift für Physik, 31, 681-708, (1925).

24Barry R. Masters

http://www.rrr.res.in/

R. H. Stuewer, The Compton effect: turning point in physicsScience History Publications, (1975)

D.L. Rousseau, P.F. Williams,Resonance Raman scattering of light from a diatomic moleculeThe Journal of chemical Physics, Vol. 64, No. 9, 3519-3537, (1976)

B. R. Masters, C. V. Raman and the Raman EffectOptics & Photonics News, March 2009, Vol. 20, No. 3, 40-45.

G. Venkataraman,Journey Into Light, Life and Science of C. V. RamanIndian Academy of Sciences, Indian National Science Academy, Bangalore, 1988

25Barry R. Masters

R. Singh, F. Riess,The 1930 Nobel Prize for Physics: A close decision?Notes & Records of the Royal Society, London, 55, 267-283 (2001)

Abha Sur, Aesthetics, Authority, and Control in an Indian Laboratory,The Raman-Born Controversy on Lattice DynamicsIsis, 90: 25-40 (1999).

C. L. Braun, S. N. SmirnovWhy is Water Blue?Journal of Chemical Education, 70(8), 612-614, (1993)

26Barry R. Masters

• Why is Water Blue?

• Braun and Smirnov (1993 ref.)• Blue color of water is due to selective absorption of red part of visible spectrum.• Absorbed photons promote transitions to high overtone and combination states of

nuclear vibrations in water molecule-highly excited vibrations.• Only example in nature of color of substance due to vibrational transitions, usually

due to electronic transitions.

• Question: why is a body of water, viewed in reflection blue?• Blue color is due to both reflected sky light and the absorption of red light due to

vibrational transitions in water molecules. The relative contribution of each to the blue color is highly dependent on the observation angle.

27Barry R. Masters

REFERENCES from Barry Master’s talks. CALIBRATION Latt, Cheung, Blout, PNAS 1965 Energy Transfer....

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