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Recent developments affecting the supply-demand-balance
of acidspar: The buyers view
Dr. Oliver Rhode
LANXESS Deutschland GmbH
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Agenda
1
2
Introduction
Recent developments affecting the demand
Recent developments affecting the supply 3
FSA and other alternatives 4
Summary & Outlook 5
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LANXESS facts and figures
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LANXESS facts and figures
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LANXESS produces hydrofluoric acid in Leverkusen, Germany
Berlin
Frankfurt
Munich
Leverkusen
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Standard specification for acidspar
- Min. 97% CaF2.
- Max. 1% silica (SiO2).
- Max. 1% carbonate (CaCO3).
- Max. 10ppm arsenic.
- Max. 300ppm phosphorus.
- Max. 0.10% sulfur as sulfide or free sulfur.
- Restrictions on iron, lead and other metals.
- Restrictions on organics.
- Particle size: maximum 10% +150 microns,
60% -45 microns.
- Max. 10% water content as filter cake.
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The balance of supply and demand of acidspar is determined by various factors
Supply-Demand-
Balance
Factors affecting the supply
New projects (green-field, brown-field, met-spar upgrading).
Capacity expansion of existing producers.
Export-policy of China.
Factors affecting the demand
Development of the downstream markets (fluorocarbons, fluoro-polymers, AlF3).
Development of HF-market.
Alternatives to replace acidspar or downstream products.
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The domestic market in China is the trigger for the global supply-demand-balance
China has become the largest fluorochemical
production and consumption area.
Although the role of China has changed, it still
dominates the acidspar market.
As long as the domestic demand is strong,
there is no incentive for any producer to
switch to higher grade export material.
Several non-Chinese producers of acidspar
adopt the pricing scheme of Chinese acidspar
exports.
Supply-Demand-
Balance
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Agenda
1
2
Introduction
Recent developments affecting the demand
Recent developments affecting the supply 3
FSA and other alternatives 4
Summary & Outlook 5
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The average annual growth rate for acidspar is estimated at 1,5% per year
Non-Feedstock
Fluorocarbons
Aluminum
Fluoride
Feedstock
Fluorocarbons
Products Demand
• Refrigerants
• Foaming agents
• Aerosols
• steady • 35%
• PTFE
• PVDF
• PEEK
• FPE
• AAGR 2,5% • 15%
• AlF3 • AAGR 2% • 25%
• Uranium enrichment
• Stainless steel pickling
• Gasoline alkylation
• Electronics
• Glass etching
• AAGR 2% • 25%
Others
approx. % of
HF consumption*
Source: Roskill, SRI, own estimates *based on 2.1 mt HF produced in 2010
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Fluorine-based replacements for existing fluorocarbons affects acidspar demand
Environmental pressures are opposing the
application of some fluorochemical products.
Fluorine-based replacements for these
fluorocarbons affects the future acidspar
demand.
Replacement candidates are hydrofluoro-
olefins of the HFO-1234-type for use in
automotive air-conditioning systems and
aerosol applications.
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Production development of fluorocarbons and fluoropolymers in China
0
100
200
300
400
500
600
2002 2005 2008 2010
HCFC-22
HFC-134a
PTFE(HCFC-22)
other fluoro-polymers
kt
Source: CCR, SRI, own estimates
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China’s fluorochemical industry needs technological innovation
– China's fluorochemical industry has largest capacity in the world.
– Industry has developed by relying on resource advantage and simple
production technologies.
– Capacity of high-value-added fluorochemicals is very limited.
– Positioning at the low end of the industrial chain with no differentiation of
products.
– Research of high-end fluorochemical products is weak.
– Chinese government has issued policies to support the development
towards a high-tech industry.
Source: CCR
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China encourages the production of high-value fluorocarbons and fluoropolymers
Acidspar HF Fluorocarbons Fluoropolymers
Current Situation
restricting exports extreme overcapacity overcapacity (primary products)
overcapacity (primary products)
Future Situation
further restrictions (?) moderate overcapacity balanced capacity (shift to advanced products)
Apparent China Strategy
Safeguard domestic availability of (low cost) raw material
Emphasize use in domestic downstream production, reduction of overcapacity
Develop more capacity for domestic & export demand, focus on “high-end” fluorocarbons
Production Chain
Develop more capacity for domestic & export demand, focus on “high-end” fluoropolymers
balanced capacity (shift to advanced products)
Vertical integration
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Total production volume approx. 830 kt
Global production volume of aluminum fluoride in 2010
59%
16%
19%
6%
China
NAFTA
WE
ROW
Source: AIT, own estimates
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Total installed production capacity approx. 2.6 mt
Average plant utilization rate estimated at 80% = 2.1 mt HF produced
Global production capacities for hydrofluoric acid in 2010
54%
15%
11%
11%
9%
China
NAFTA
WE
ROW
CIS
Source: CCR, Roskill, SRI, own estimates
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Recent developments in the production of hydrofluoric acid in China 1/2
– HF production capacity has expanded rapidly.
– Today more than 50 HF producers.
– 2010: HF output approx. 940 kt, up 12% from 2009.
– Average plant utilization rate was 67%.
– Exports of HF accounted for 160 kt, up 48% from 2009.
– Largest export destination was Japan (46% of total HF exports),
followed by Taiwan (19%) and Korea (14%).
– HF producers mainly distributed in the southeast; they are now
beginning to move towards Inner Mongolia.
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Recent developments in the production of hydrofluoric acid in China 2/2
– Consumption will continue to grow at 6% to 7% annually and will reach 1.08
mt in 2015.
– Average plant utilization rate of will remain at 60% to 70%.
– February 2011 - "Access Conditions for Hydrogen Fluoride Industry":
– total HF capacity of any new producer should be at least 50 kt/a, and
– capacity of any new HF plant should be not less than 20 kt/a.
– April 2011 - "Guiding Catalogue for Restructuring of Fluorine Chemical
Industry“:
– construction of new HF plants should be restricted, and
– HF plants with a capacity of less than 5 kt/a should be eliminated.
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Agenda
1
2
Introduction
Recent developments affecting the demand
Recent developments affecting the supply 3
FSA and other alternatives 4
Summary & Outlook 5
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Production capacity of acidspar by country in 2010 according to standard specification
Spain 140 kt
South Africa 300 kt
Namibia 120 kt
Kenya 100 kt
Morocco 100 kt
Mongolia 140 kt
China 2.300 kt
CIS 220 kt
Mexico 500 kt
Germany 30 kt
Mexico 120 kt
Bulgaria 30 kt Mongolia 50 kt
China 500 kt
Source: Roskill, own estimates
out of
specification
within specification,
but captive
within specification,
not captive
3.260 kt
290 kt
1.100 kt
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Historic developments in the production of acidspar in China
– Early 1990s: China has become a major source of supply.
– Production elsewhere declined.
– Domestic demand has grown at an AAGR of 20% since 2000, compared to
less than 1% in Europe or North America.
– Since 2004: Chinese government introduced a number of policies which
reduced exports of acidspar.
– Lower export from China was not balanced by other producers.
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Recent developments in the production of acidspar in China
– April 2010 - "Notification on the 2010 Mining Quotas for Fluorite”:
– national total mining quota for fluorite ore is 11 mt in 2010.
– May 2010 - "Production Quotas of Fluorite for Every Province in 2010”
– national production quota for acidspar is 2.44 mt.
– The actual output of acidspar exceeded the quota.
– June 2010: fluorite resource tax increased from 3 RMB/t to 20 RMB/t.
– Reduction of the 2011 national total fluorite mining quota by 500 kt.
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361386
215
575
483
564
422
252280
301
193
173
0
100
200
300
400
500
600
700
2006 2007 2008 2009 2010 2011
150
200
250
300
350
400
450
500
Chinese annual exports of acidspar and average FOB-price
Volume
[kt] FOB-Price
[USD/t]
Jan.-Sep. Source: CCR
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Where can we source new acidspar supplies in the future?
Additional potential volume of acidspar of more than 1 mt
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Agenda
1
2
Introduction
Recent developments affecting the demand
Recent developments affecting the supply 3
FSA and other alternatives 4
Summary & Outlook 5
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Will flurosilicic acid contribute to the supply-demand-balance of acidspar?
– Main fluorine resources are fluorite, phosphate rock, apatite, cryolite,
sellaite, sodium fluoride and bastnaesite.
– Fluorite supplies around 92% of global fluorine demand.
– Phosphate rock contains up to 3.5% fluorine, and it accounts for more
than 90% of the world's fluorine reserves.
– One ton of wet-process phosphoric acid (WPA) can yield approximately
50 - 60kg flurosilicic acid (FSA).
– A potential 3.5 mt of equivalent acidspar would be available as by-product
FSA.
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Will flurosilicic acid contribute to the supply-demand-balance of acidspar?
– High capital and processing costs have militated against FSA as acidspar
replacement.
– First HF plant using FSA opened in China in April 2008.
– Approx. 300 kt of acidspar equivalent, in the form of FSA, is used in AlF3
manufacture.
– Around 150 - 200 kt of FSA are used in water fluoridation.
– Remainder is generally neutralised, discharged, ponded or pumped to sea.
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Neither FSA nor another raw material will replace acidspar in the next couple of years
– Increased utilisation of FSA is unlikely to progress significantly.
– China promotes the further development of HF-production from FSA.
– A few thousand tons per year of synthetic acidspar is recovered - primarily
from uranium enrichment, but also from gasoline alkylation and stainless
steel pickling.
– Aluminum smelting dross, borax, calcium chloride, iron oxides, manganese
ore, silica sand, and titanium dioxide have been used as substitutes for
acidspar fluxes.
– Neither FSA nor another raw material will replace acidspar in he next
couple of years.
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Agenda
1
2
Introduction
Recent developments affecting the demand
Recent developments affecting the supply 3
FSA and other alternatives 4
Summary & Outlook 5
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Uncertainty and turbulence in the markets
- Health of economies in Europe,
- United States debt,
- China dilemma: low inflation rate vs.
GDP growth.
The further development of the global
economy depends on these topics, and
consequently the development of the
fluorochemical industry.
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Will demand for acidspar outstrip supply in the next five years?
After the worldwide recession, acidspar
markets recovered in 2010, and continued to
grow in 2011.
Supply was tight in the middle of 2011, now
the situation changed, acidspar is readily
available.
Supply and demand are in balance – there is
no structural deficit of acidspar.
No significant acidspar supply-demand-gap is
expected in the next couple of years.
Supply-Demand-
Balance
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Non-Chinese
“Yes“
Chinese
“No“
Do you believe China will become a net importer of acidspar in the next five years?
Results of a recent non-representative
survey
We asked Chinese and non-Chinese
market participants:
“Do you believe China will become a net
importer of acidspar in the next five years?”
All Chinese answered “No”.
In contrast, the non-Chinese believe “Yes”.
Thank You
for Your Attention