RbLi(NH2)2, a Rubidium Amido Lithiate Investigated by X-Ray and Neutron Diffraction.
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2002 structure structure (solids and liquids) D 2000 44 - 010 RbLi(NH 2 ) 2 , a Rubidium Amido Lithiate Investigated by X-Ray and Neutron Diffraction. — The title compound and the fully deuterated analogue are synthesized by the reaction of RbNH 2 /RbND 2 and Li metal in supercritical NH 3 /ND 3 (autoclave, 470 K, 220 MPa, 41 d). As revealed by single crystal XRD and powder neutron diffraction, RbLi(NH 2 ) 2 crystallizes in the orthorhombic space group Pnma with Z = 4. The structure is an orthorhombically distorted variant of the ThCr 2 Si 2 type structure with an ordered half occupation by Li of the tetrahedral sites of puckered 4 4 nets of amide ions. The compound contains an unexpected hydrogen bonding system between crystallographic different amide ions. — (JACOBS, HERBERT; BOHGER, PATRICK; KOCKELMANN, WINFRIED; Z. Anorg. Allg. Chem. 628 (2002) 8, 1794-1798; Lehrstuhl Anorg. Chem., Univ. Dortmund, D-44221 Dortmund, Germany; EN) 1
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Transcript of RbLi(NH2)2, a Rubidium Amido Lithiate Investigated by X-Ray and Neutron Diffraction.
2002 structure
structure (solids and liquids)D 2000
44 - 010RbLi(NH2)2, a Rubidium Amido Lithiate Investigated by X-Ray andNeutron Diffraction. — The title compound and the fully deuteratedanalogue are synthesized by the reaction of RbNH2/RbND2 and Li metal insupercritical NH3/ND3 (autoclave, 470 K, 220 MPa, 41 d). As revealed bysingle crystal XRD and powder neutron diffraction, RbLi(NH2)2 crystallizesin the orthorhombic space group Pnma with Z = 4. The structure is anorthorhombically distorted variant of the ThCr2Si2 type structure with anordered half occupation by Li of the tetrahedral sites of puckered 44 nets ofamide ions. The compound contains an unexpected hydrogen bonding systembetween crystallographic different amide ions. — (JACOBS, HERBERT;BOHGER, PATRICK; KOCKELMANN, WINFRIED; Z. Anorg. Allg. Chem.628 (2002) 8, 1794-1798; Lehrstuhl Anorg. Chem., Univ. Dortmund, D-44221Dortmund, Germany; EN)
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