Quimica y Productos Naturales

7/25/2019 Quimica y Productos Naturales

1/27

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+!

!"# %&"'()*"# +,*(&,-.# ./ -, 01', 2"3'1,/,45/, 01#16/ 21./78),

3-789 %:;1, ?

@A +*, B';0*( +* ,' C";;*0)D+*,'5";;*E)#1)D*#

F*4';5'0*(5" +* 6/(5*#1#9 G#5;.)5.;' 2 H;"41*+'+*# +* B"04.*#5"# 7;IJ(1)"#3(#K5.5" +* -./01)' 7;IJ(1)' 8*(*;',LB63B

3-789 %:;1, ?

# $%& '() *(' +,(-%./(' 01/%,1*2' 3

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

!" !"#$%&' $% &'" ()$'()" (&*+

+,-$./+ $% 0" (+123$'%)4' 5$0

&')/$3%+6 1$5)"'7$ $0 $%7&5)+ 5$

0"% 1+08(&0"%9

!"% 1+08(&0"% 5$:'$' 0" ;+31" *

0"% 23+2)$5"5$% 5$ 0" 1"7$3)"


2/27

3-789 %:;1, ?

# $%& '() *(' +,(-%./(' 01/%,1*2' 3!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

M*;N*,1.#9 ' )"01*(N"# +*, #D O3O9 4;"4"(*P

!"#$%&' )*+,-.*%&')"0" ,' 4';5* Q.* *#5.+1',"# )"04.*#5"# Q.* #* *().*(5;'( *( ,"#$%*/,'0/1D

!"#$%&' 2,-.*%&')"0" ,' 4';5* Q.* *#5.+1',"# )"04.*#5"# Q.* 4;"+.)*( ,"# 1/,/1 3%3+1D6"( #.#5'()1'# Q.* #",'0*(5* #* 4.*+*( #1(5*KN';)"( ,' 4';K)14')1R( +* .( #*; &1&"9 *#5' 1+*' #*)"(")* )"0" 3%4'0%1$+D

3-789 %:;1, ?

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

6/(5*#1# +* ,' .;*' S5676T

U;*+*;)V WXV,*;

4 52,62*7%' 8Y3 0.#5 5*,, 2". 5V'5 3 )'( 4;*4';* .;*'Z15V".5 ;*Q.1;1(I ' [1+(*2 "; '(10', 9 *15V*; 0'( "; +"I\

97) 2:;1,7/1*7':( '(;,2>7>2 ?1'/1 9:;< @5%.?)2,2).()/,A 1..7-2)/1*:2)/2 B%2 ?1;C1 1.D>7-1-2)67:ED.1 2) 2F/,1./(' .2*%*1,2' -2'G,(>7'/(' -2.&*%*1' >7>1'H

# $%& '() *(' +,(-%./(' 01/%,1*2' 3

I)(,


3/27

3-789 %:;1, ?

# $%& '() *(' +,(-%./(' 01/%,1*2' 3!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

!"#$%&' 2,-.*%&' *# *, *#5.+1" +* ,"# )"04.*#5"# :'#'+"#*( )';:"(" 5'(5" +* ";1I*( ('5.;', )"0" #1(5]K)"D

=>/*.#1# ?&@A/1), B(>C1), '. %&"'()*"# +,*(&,-.#

G( *, #D O3OP!' !"#$%&' 8/ 9,+8"&4+1 :'4",'0/1#.;I* )"0" *, *#5.+1" +*5"+"# ,"# )"04.*#5"# Q.* #"( #1(5*KN'+"# 4"; ,"# #*;*# &1&"#D

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

K2/1;(*7/(' +,7:1,7(' @57(B%C:7.1H

! L(:%)2' 1 /(-(' *(' '2,2' >7>('!! 9() G(*C:2,(' @;7(G(*C:2,('H L1,;(?7-,1/(' M +,(/2C)1'!! 9() %)(' .72)/('!


4/27

3-789 %:;1, ?

# $%& '() *(' +,(-%./(' 01/%,1*2' 3!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

!' !"#$%&' 8/ 9,+8"&4+1 :'4",'0/1

*#5.+1' ,'# 0",]).,'# +* ,' ('5.;',*N'P;+1


5/27

%36!%@3G^C7FGH_7F`BC76 %C _%!G6

NH OF/,1..7A) -2 '% P%2)/2 )1/%,1* @I)P%'7A)= '%;'/1).71' '(*%;*2' 2) 1


6/27

B;"0'5"I;'a' *( )",.0('

RH S,1..7()1:72)/( M G%,7T.1.7A) -2* 2F/,1./(

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

UH V2/2,:7)1.7A) O'/,%./%,1*! K&/(-(' O'G2./,('.AG7.('

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


7/27

WH X7GA/2'7' O'/,%./%,1*

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

^.*N 0"#)'+' B,'&"

CHO

%;:", +* ,' B'(*,'

B1('0',+*V1+"

!, "D#.#16/ E"& -"# %&"'()*"# +,*(&,-.#8 ;'1 D1@/&%'1


8/27

3-789 %:;1, ?

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

O) NWYZ [1'.( -2 \1:1 7)7.71 '% >71Q2 ?1.71 ]1 7)-71!

O%,(G1 ,2'/1;*2.2 *1' ,2*1.7()2' .(:2,.71*2' .() *(' G%2,/('7)-7(' -2'-2 *1 &G(.1 -2 *(' ^(:1)('!

O) N_`N *(' G(,/%17)7**7)1 '2 G,(-%.2 .(:( -2P2)'1 .()/,1 .72,/(' G1/A


9/27

3-789 %:;1, ?

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

N

N N

N

O

O

CH3

H3C

CH3

N

N N

H

N

O

O

CH3

H3C

HN

N N

N

O

O

CH3

CH3

C*"b,1(' C*":;"01('

G#K0.,'(5*#P B'e]9 5* 2 )')'"D6* '+01(1#5;'( *( e";0' +* 1(e.#1R( !%:#";)1R( ,*(5' &1' 1(5*#K(',

B'e*/('

@L?7)1H

L?7)1= I)-71= I)-()2'714P,7.1

@OD(G71H

4P,7.1= c1:17.1=4:&,7.1

@4:&,7.1H

dP,7.1 /,(G7.1*I)-()2'71= K1*1'71

fe;1)' SB",' (1K+'T %0'N"(1' SH'.,,1(1'T g"h'# +* )")'

+eLIK49Kd\IL49

G#4*)1',0*(5* .K,1N'+'# *( 6.+'0];1)' 2 %0];1)' B*(5;',

B"0" *#K0.,'(5*#9 4';' 4',1'; *, V'0:;*9 " 4';' 5;'#)*(+*; ' ," #":;*('5.;',

" #* .K,1N'( 4"; 4,')*;

6. .#" *#5J ;*#5;1(I1+" ' ,"# #')*;+"5*#

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


10/27

H!%^C%FG!%B7B%

7;1I1(';1' +* ,' %0'N"(1'9 );*)* *(5;* ,"# >i== 2 ?=== 0 +* ',5.;'D

Gc1#5*( i 4;"+.)*( )")'/('D %)5.',0*(5* #* ).,K&'( +"# *#4*)1*# 4';' ,' 4;"+.))1R( +* )")'/('D

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

B"(")1+' +*#+* *, 4*;/"+" ('N)' S#1I," d3T K,1N'+' 4"; ,"# 1()'# *( ;15"# ;*,1I1"#"#

#" ;*#5;1(I1+" ' ,"# )V'0'(*#

H1N';;" *(5;' *( B.N)" *( >ijjG, )"(#.0" +* ,' )")' #* *cK*(+* *(5;*,"# 1(+/I*('#

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


11/27

%(I*," @';1'(1 1(&*(5R *, d1(" @';1'(1 1( >k?jS :";+*'.c Z1(* Z15V )")'1(*TD

G, H'4' !*"( O333 +1" #. '4;":')1R(

!'# V"h'# +* ,' )")' #* .K,1N'( *( G.;"4' 1(e.#1"('+'#

Y^.*&' &1+'9 (.*&" &1I";D d1(" 5R(1)" 2 *#K0.,'(5*Q.* e";5',*)*9 ;*e;*#)' 2 ;*#5'.;' ,'# e.*;N'# &15',*#DH"; *c)*#" +* 5;':'h" " 4"; e'KI' a#1)' " 0*(5',9

('+' 1I.', ', d1(" @';1'(1 4"; #.# *e*)5"# :*(]b)"#91(0*+1'5"# 2 +.;'+*;"#D G#5' '#*&*;')1R( #* :'#' *('4"2"# *#);15"# +* 0J# +* l9=== *01(*(5*# 0]+1)"#2 4"; #. .#" )"(K(." 4"; 0J# +* j= 'm"# *(V"#415',*#9 1(#K5.)1"(*# 4n:,1)'# 2 ;*,1I1"#'# +* 5"+'#

4';5*#D\

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

G( %0];1)' S>o==T

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


12/27

H*0:*;5"( 'm'+1R )'e*1('9 )'(*,'9 (.*N0"#)'+' *5)D ', d1(" @';1'(1DH;"V1:1+" *( >kk?ppDD#* ;**04,'N' *, &1("

4"; h';':* +* 'Nn)'; 2 (')* ,' )")'L)",' qqqqqq

G( >o=r ,' B")' B",' +*h' +* )"(5*(*;+*b(1K&'0*(5* )")')/('

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

B")'/('6* '/#,' *( >k?=

G( >kkr9 sX,,*; +*0.*#5;' ,'*b)')1' +* ,' )")'/(' )"0"

'(',I]#1)" 2 '(*#5]#1)" ,")',

^"&")'/('S61(5]K)'T

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


13/27

O

O

Me

CHO

Me

OH

C;"41"(', U1;#'(5", S6J(+',"T

L?1)2* L1,(*7)1 X2,,2,1

L7/,()2*(*

C"([' 5;** Sd*(*N.*,' 2 ^1I*;1'T

B.0';1(' Sg*("T

^'5.;',*# 61(5]K)"#

%;"0'# 2 H*;e.0*#

R_

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

OMe

H

MeH

E$=,+F \%M ]1,(.?2

G$=', -,%1

6*);*)1R( :1,1'; +*, 1(5*#K(" +*, )')V',"5*D

%;"0' *cQ.1#15" ', +*#)"04"(*;#*D

% 4;1()141"# +*, #1I," Od333 )"01*(N' ,' )'N'0'#1&' +*, )')V',"5*D

%)5.',0*(5* #. )"0*;)1" *#5J 4;"V1:1+"D

G, 1(5*#K(" +*, )')V',"5* *# ,' n(1)'e.*(5* ('5.;', +*, J0:'; I;1#

Rf

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

G, J0:'; I;1#


14/27

OH

OH O

O

O

StTLG#),';*", %0:;"c

6',&1' *#),';*'

RZ

I-&)D.( 1* B%2 '2 1C'*1-2 *1 P%2)/2 )1/%,1*!

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

[O0O0J9

G( ,' 7+1#*' #* +*#);1:* )R0"`,1#*# :.#)':' .( &*(*("0";5', 4';' 104;*I('; ,'#

4.(5'# +* N1() +* #. ,'(N'9).'(+" #* *()"(5;R )"( ,'+1"#' %5*(*'

CRc1)"-2,7>1 -2 C"c1["( S5"c"( u ';)" 2 G?1,:1["(u &*(*("T d*(*(" 4';' v*)V'#

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


15/27

[O0O0J9

[2)2)(' %D*761-(' G1,1 .161, @.%;,7, *1 )2.2'7-1- ;E'7.1 -2 1*7:2)/1,'2H

B _%_G

G(;*+'+*;' &*(*("#' +* ,' ).*()' +*,%0'N"('# S65;2)V("# 5"c1e*;'T

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

U;'()1#)" +* 7;*,,'('

Y!"# 1(+1"# 0'5';"( ' "5;" +* (.*#5;"#)"04'm*;"#ppDD2 '.(Q.*9 ,' v*)V' (" 4*(*5;R (1

0*+1" +*+"9 )"0" 5*(/' &*(*(" #* ,,*&R #. ',0' )"((.*#5;" 6*m";\

Lg^4^O

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


16/27

Lg^4^O

BV';,*# W'5*;5"(S>k1, 2*

.%,1,2 1 I)krrT

F*5*;01(R Q.* *, ).;';* 4;"+.)/' ,'4';J,1#1# +* ,"# 0n#).,"# +*, 4*)V" 2 +*,':+"0*(9 +*:1+" ', :,"Q.*" +* ,'5;'(#01#1R( +* ,"# 104.,#"# (*;&1"#"#D

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

Lg^4^O

i%;(.%,1,7)1

O) NYU_ 2* V,! X1,(*- j7)< 2'/1;*2.7A *12'/,%./%,1 -2* .(:G()2)/2 :E' 1.D>( -2*

.%,1,2= 1* B%2 -2)(:7)A i%;(.%,1,7)1!O) NYWR '2 %D*76A= G(, G,7:2,1 >26= 2) .7,%2)D*1.7A)1'7'D-1b!2"C1./H, (/, /(.I, .&, ./ )1&(J>,

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


17/27

_").;"(1" %5;').;1"

_*,'h'(5*# 0.#).,';*# #1(5]K)"#

@*("# 4"5*(5*# Q.* ,' 5.:").;';1(' @*h"; ;*I.,')1R( +*, *e*)5"

O* -2'1,,(**( -2 *(' 1koji9 *#5;.)5.;'T

M,"Q.*'(5*# #1(5]K)"#

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


18/27

]7>71 2'G('1 -2* 2:G2,1-(, 4%


19/27

g2"#)2'0.# (1I*; !D

B;*)* *( 5"+' G.;"4'9 %#1' )*(5;', 2"))1+*(5', 2 %0];1)' +*, ^";5*D 6* ,')"(")* 4"4.,';0*(5* )"0" :*,*m"

(*I;" " V1*;:' ,")'D

G( 4.*:,"# 4;101K&"# #* .K,1N':' )"0"

'e;"+1#/')"9 #1*(+" *, 4;1()14', )"04"(*(5* +* ,"#zb,5;"# +* '0";\

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

G( +"#1# 5Rc1)'# )'.#' 1(#*(#1:1,1+'+ '(5*# +* .('0.*;5* 1(+",";'

G( G#4'm' #* .K,1NR *( *, #1I," O3O )"0" ;*0*+1" )"(5;'*, '#0' 2 "5;'# +",*()1'# ;*#41;'5";1'#

g2"#)1(' S*#)"4",'01('T

34;'5;"41.0 S%5;"&*(5T%(K'#0JK)" #1(5]K)"

`K,1N'+" :'h" )"(5;", 0]+1)" 4';' 5;'5'; ,"#z+*,/;1.0 5;*0*(#z9 *41,*4#1'9 1(#"0(1"9 5*;;";*#9:;"(Q.1K# '#0JK)'

3(+.)* .( #.*m" 4;"e.(+"D 3041+* *, ;*).*;+"

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


20/27

[O0O0J940IK4]O9

_'(' Y+';+" &*(*("#"\ S+*(+;":'K+'*T ,' 0J# &*(*("#'D

g':15' *( ,' #*,&' 2 '+&1*;5* +* #. 4*,1I;" )"( ,' )",";')1R( ,,'0'K&' +* #. ).*;4"D

6. 41*, K*(* 4*Q.*m"# 4";"# 4"; ,"# Q.* #*I;*I'( *, 0";5', &*(*(" S:'5;')"5"c1('T)"( *, Q.* +1#.'+* ' +*4;*+'+";*#9 )"0" ,'# #*;41*(5*#D

C1*(*( &*(*(" #.b)1*(5* *( #. ).*;4" )"0" 4';' 0'5'; ' >= V"0:;*# '+.,5"#D

C")';,' " 4;":';,' )'.#' *#4'#0"# 0.#).,';*# 2 4.*+* )'.#'; ,' 0.*;5* 4"; 4';")';+/')"

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

C*5;"+"5"c1(' S(*.;"5"c1('T

H*N I,":"

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


21/27

@';*' ;"h'

%,I' 01);"#)R41)'

s';*(1' :;*&1#

+2,7-7)7)1 @.1,(/2)(7-2H

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

M;*&*5"c1(' M

[O0O0J9

[2)2)(' )2%,(/AF7.('

6"( e'5',*# 4';' ,"# 4*)*# * 1(),.#" 4';' ,'# :',,*('#DH.*+*,,*I'; ', b(', +* ,' )'+*(' 5;Rb)'

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


22/27

@GF3B3^%6

C'c.# :;*&1e",1' SC*h"TG( >o?< *, `6F% ;*)",*)5';"( 0.*#5;'# +* )";5*N' +* C*h"9

4';' 1(),.1;,'# *( .( 4;"I;'0' +* 1(&*#KI')1R( 4';' ,':n#Q.*+' +* 'I*(5*# '(K)'()*;"#"#pDDDD{4"; Q.]|

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

@GF3B3^%6

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

!" $% &'())% *( $% +%$,%-. /'$,0

1(-%) *(-2),3( 2040 ($ 5(6( &%$0

1%780$2'-. '"% 8(9 8("2,*0. -(

-',2,*: ;04%"*0 '" ;( *( $%

20);(9% *($


23/27

!' *#5;.)5.;' +*, C'c", #* *#5':,*)1R *( >ol>

+,(;*2:1'847'*1:72)/( /2-7('(= -7l.7* M %) ;1Q( ,2)-7:72)/(! 4-2:E' 2* E,;(* :%2,2!

Um!``` E,;(*2' G,(-%.2) R_ j< -2 /1F(*! i,1/1:72)/( -2 NR!``` G1.72)/2'

U E,;(*2'nG1.72)/2

O)(,:2 2'P%2,6( '7)/&D.(

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

V,! j! L! 07.(*1(%

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


24/27

V,! ^! 4! X(*/()

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

C'c.# :'))'5'

j=== [I +* V"h'# 4;"+.)*( > [I +* M'))'K(' 333

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


25/27

g*01#/(5*#1# +* C'c",

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

3-789 %:;1, ?

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

+%;*7.7-1- o2)


26/27

{H"; Q.] ,"# #*;*# &1&"# #1(5*KN'( 4;"+.)5"# ('5.;',*#|

D14,"&4",'1H >+* /*+,$/$/*4/ 8%3/,1'1H ;' 1%14/$'IJ'&%K* /1 $"L 8%M&%0

_N

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

{H"; Q.] ,"# #*;*# &1&"# #1(5*KN'( 4;"+.)5"# ('5.;',*#|

% 0*+1'+"# +*, #D OO V':/' 1(e";0')1R( #":;*P D14,"&4",'1H >+* /*+,$/$/*4/ 8%3/,1'1H ;' 1%14/$'IJ'&%K* /1 $"L 8%M&%0 _.5'# 0*5':R,1)'# 4;1()14',*# H;"41*+'+*# +* ,'# *(N10'# 0*+1'+";'#

H;"41*+'+*# +* ,"# 4;"+.)5"# ('5.;',*#

G, 1(5*;]# *( ,"# 4;"+.)5"# ('5.;',*# );*)* ' 4';K; +*, +*#).:;101*(5" +* ,' 4*(1)1,1('D!" Q.* 1(5*;*#' *# #. .#" )"0" '(K:1RK)"9 0J# ',,J +* #. ;'NR( +* #*;D

_R

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+


27/27

_U

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

K&"C,#

G#E.)1,#

LA&C,)"#

9,+8"&4+1 :'4",'0/1N"/*4/ %*'-+4'=0/ 8/ &+*+&%$%/*4+ / %*1@%,'&%K*@',' 0' &+$@,/*1%K* 8/0 $"*8+ A"/ *+1 ,+8/'

0././"#

]( )1/%,1* 2'bbbbbbb)1/%,1*= )7 ;%2)( )7 :1*(

]1 B%C:7.1 2'bbb%)1 -7'.7G*7)1= )7 ;%2)1 )7 :1*1!]1 B%C:7.1 2' .()(.7:72)/( B%2= 2)/,2 (/,('= )('G2,:7/2 -2'.%;,7, M '7)/2D61, G,(-%./(' )1/%,1*2'

!"# %&'()*# +* ,' -./01)' 2 #. 304')5" *( ,' 6")1*+'+

Quimica y Productos Naturales

Documents

Transcript of Quimica y Productos Naturales