Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj...

15
Quality parameters of wheat. Quality parameters of wheat. Bi Bi o- o- ethanol ethanol versus versus bread bread ? ? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University of West Hungary, Faculty of Agricultural and Food Sciences, Mosonmagyaróvár 2 Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnava, 917 01 Trnava, SK. 3 UIS Ungarn Laboratories, Mosonmagyaróvár 6th ALPS-ADRIA SCIENTIFIC WORKSHOP 30 April - 5 May, 2007 Obervellach, Austria ENVIRONMENTAL CONSEQUENCES OF SUSTAINABILITY

description

6 H 2 O + 6 CO 2 C 6 H 12 O 6 (C 6 H 10 O 5 )n + n H 2 OnC 6 H 12 O 6 C 6 H 12 O 6 2CH 3 – CH 2 – OH + 2CO 2 h amilase CH 3 CH 3 C – OH + HO – CH 2 – CH 3 = CH 3 C – O – CH 2 – CH 3 CH 3 ETBE

Transcript of Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj...

Page 1: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Quality parameters of wheat.Quality parameters of wheat.

BiBio-o-ethanol ethanol versusversus breadbread??

Pál SZAKÁL1 – Rezső SCHMIDT1 – Juraj LESNY2 – Renátó KALOCSAI3 – Margit BARKÓCZI1

1 University of West Hungary, Faculty of Agricultural and Food Sciences, Mosonmagyaróvár

2 Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnava, 917 01 Trnava, SK.

3 UIS Ungarn Laboratories, Mosonmagyaróvár

6th ALPS-ADRIA SCIENTIFIC WORKSHOP

30 April - 5 May, 2007 Obervellach, Austria

ENVIRONMENTAL CONSEQUENCES OF SUSTAINABILITY

Page 2: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Decrease of fossil energy carriers

Bio-ethanol is a potential replacement of oil and natural gas

The increasing importance of high-starch content plants (Wheat, maize)

Bio-ethanol, bio polymers, dextrin, starch syrup, D-glucose, etc.

EU’s cereal production 285 million tons; Hungary’s cereal production 6 million tons

1 l bio-ethanol appr. 3.1 kg wheat, 2.8 kg maize. (Maize germ)

Page 3: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

6 H2O + 6 CO2 C6H12O6

(C6H10O5)n + n H2O nC6H12O6

C6H12O6 2CH3 – CH2 – OH + 2CO2

h

amilase

CH3 CH3

CH3 C – OH + HO – CH2 – CH3 = CH3 C – O – CH2 – CH3

CH3 CH3 ETBE

Page 4: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Why to use bio-ethanol?

1. Environmental reasons. Glasshaouse effects, climate change.

2. Ceasing the dependance on crude oil.

Page 5: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

STARCH

GLUCOSE

ALCOHOL

Starch, cellulose, inulinSaccharose containing materials (sugar beet, sorghum, etc.)

Decomposition of starch (cooking with thermo stabile -amylase;Hydrolysis (gluco-amilase)

Fermentation

The production of bio-ethanol

Page 6: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.
Page 7: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Plant Yield Transformation efficiency

%

Ethanol yield

tha-1 totalmillion t

lt-1 lha-1

Sugar beet

38.0 143.0 35 95 4300

Wheat 3.5 82 24 356 1200

Maize 4.5 49 32 387 2100

Potato 10.3 0.1 82 110 3050

Sugarcane

57.0 187 31 67 5300

The alcohol production potential of different plants

Page 8: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Aim: to increase the starch content of wheat for increasing bio- ethanol yield

STARCH RAW PROTEIN,GLUTEN

Page 9: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Material and methods

Treatment: manganese carbohydrate

Plant: winter wheat

Phenological phase: booting

Way of application: foliar

Soil type: Danube alluvial, Darnózseli, Hungary

Experiment: 10 m2 plots, 4 repetitions, randomised block design

Doses: 0.05, 0.1, 0.3, 0.5 kgha-1 Mn

Page 10: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

pH KA CaCO3 Humus%

AL-solublemgkg-1

Mgmgkg-1

EDTA-solublemgkg-1

H2O KCl P2O5 K2O Na Zn Cu Mn Fe

7.7 7.3 42 5.1 2.1 228 205 51 58 1.2 0.9 18 19.7

Soil analysis results. Darnózseli 2005.

Page 11: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

There was not any significant yield increase due to the treatments (LSD5% = 0.57).

The effect of the treatments on the yield

4,7

5 4,9

4,7

4,6

4,4

4,5

4,6

4,7

4,8

4,9

5

Yiel

d t/h

a

Dosekg/ha

0 0,05 0,1 0,3 0,5

The Mn-complexes increased the yield generally, the highest yield was measured at the 0.05 kgha-1 dose, at the higher doses the yield decreased.

The lowest yield was measured at 0.5 kgha-1 Mn dose, the value was lower than that of the control.

Page 12: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Raw protein content

13,2

12,612,7

12,9

13,1

12,312,412,512,612,712,812,913

13,113,2

Raw

pro

tein

%

Dosekg/ha

0 0,05 0,1 0,3 0,5

The manganese treatments decreased the protein content. We measured the lowest protein content at the Mn-dose of 0.05 kgha-1. The Mn-doses higher than this increased the protein content a little, but it was still lower than the protein content of the control.

Page 13: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Starch content

57

58,2

58,7 58,7

57,8

56

56,5

57

57,5

58

58,5

59

Star

ch %

Dosekg/ha

0 0,05 0,1 0,3 0,5

As a result of the treatments the starch content increased and at the 0.1 and 0.3 kgha-1 Mn-saccharose treatment the increase of the starch content was significant

(LSD5% = 1.5).

Page 14: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Conclusions

The lower doses of Mn-saccharose increased the yield.

The 0.05 kgha-1 increased the yield the most, but it still was not significant.

At the same time at this dose we measured the lowest (12.63 m%) raw protein content.

Due to the raising Mn-doses the starch content increased, compared to the control. This increase was significant in the case of the Mn-dose of 0.1 kgha-1 and 0,3

kgha-1.

Page 15: Quality parameters of wheat. Bio-ethanol versus bread? Pál SZAKÁL 1 – Rezső SCHMIDT 1 – Juraj LESNY 2 – Renátó KALOCSAI 3 – Margit BARKÓCZI 1 1 University.

Thank you for your attention!