Q2. - apps.dtic.milq2. a portion of the original document contains fine detail which may make...

74
CLEARINGHOUSE FOR FEDERAL SCIENTIFIC AND TECHNICAL INFO,'MATION CFSTI DOCUMENT MANAGEMENT BRANCH 410.11 LIMITATIONS IN REPRODUCTION QUALITY ACCESSION #l (~o ICALt ý I . WE REGRET THAT LEGIBILITY OF THIS DOCUMENT IS IN PART UNSATISFACTORY. REPRODUCTION HAS BEEN MADE FROM BEST AVAILABLE COPY. Q2. A PORTION OF THE ORIGINAL DOCUMENT CONTAINS FINE DETAIL WHICH MAY MAKE READING OF PHOTOCOPY DIFFICULT. O3 3. THE ORIGINAL DOCUMENT CONTAINS COLOR, BUT DISTRIBUTION COPIES ARE AVAILABLE IN BLACK-AND-WHITE REPRODUCTION ONLY. [3 4. THE INITIAL DISTRIBUTION COPIES CONTAIN COLOR WHICH WILL BE SHOWN IN BLACK-AND-WHITE WHEN IT IS NECESSARY TO REPRINT. O 5. LIMITED SUPPLY ON HAND: WHEN EXHAUSTED, DOCUMENT WILL BE AVAILABLE IN MICROFICHE ONLY. rl 6. LIMITED SUPPLY ON HAND: WHEN EXHAUSTED DOCUMENT WILL NOT BE AVAILABLE. Q 1. DOCUMENT IS AVAILABLE IN MICROFICHE ONLY. O 8. DOCUMENT AVAILABLE ON LOAN FROM CFSTI ( TT DOCUMENTS ONLY). 09. TSL-7-I/IPROC4ESR

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CLEARINGHOUSE FOR FEDERAL SCIENTIFIC AND TECHNICAL INFO,'MATION CFSTIDOCUMENT MANAGEMENT BRANCH 410.11

LIMITATIONS IN REPRODUCTION QUALITY

ACCESSION #l (~o ICALt ý

I . WE REGRET THAT LEGIBILITY OF THIS DOCUMENT IS IN PARTUNSATISFACTORY. REPRODUCTION HAS BEEN MADE FROM BESTAVAILABLE COPY.

Q2. A PORTION OF THE ORIGINAL DOCUMENT CONTAINS FINE DETAILWHICH MAY MAKE READING OF PHOTOCOPY DIFFICULT.

O3 3. THE ORIGINAL DOCUMENT CONTAINS COLOR, BUT DISTRIBUTIONCOPIES ARE AVAILABLE IN BLACK-AND-WHITE REPRODUCTIONONLY.

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Q 1. DOCUMENT IS AVAILABLE IN MICROFICHE ONLY.

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AIR FGRCE SY4IOWEANaa L V=

-IO' ITR ACT A P'S"S fi1OI) .lt*PROJECT 7181: TAOK 7101

Data Shots

John T. lilek

DS.IV4/

October 1964

* s

-FICHE , ND4 I;xA 5

S.... . +-•

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AIR FORCE MATERIALS LASORATORYRESEARCH AND TECHNOLOGY DIVISIONAI R FORCE SYSTEMS COMMAND

CONTRACT AF 33(611S.1235PROJECT 7381: TASK 7381f)3

SULFUR HEXAFLUORIDE

Data Sheets

John T. Milek

DS-14O

October 1964

EPIC

HUGHIESI.,OSESASCRPCOMPANY

CUtV601 CITV CALIPOANSA

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DS-140

FOREWORD

This report was prepared by Hughes Aircraft Company under Contract No. AF 33

(615)-1235. The contract was initiated under Project No. 7381, Task No. 738103.

The work was administered under the direction of the Directorate of Materials

and Processes, Aeronautical Systems Division, with Mr. R.F. Klinger acting as

.Project Engineer.

The Electronic Properties Information Center has been established to collect,

index and abstract the literature on the electrical and electronic properties of

materials and to evaluate and compile the experimental data from that literature.

A modified coordinate index to the literature is machine-stored and printed for

manual use. The Center publishes summary reports, thesauri, glossaries, data

sheets and similar publications as sufficient information is eý.aluated and com-

piled. This report consists of the compiled data sheets on Sulfur Ilexafluoride.

Many persons have contributed to the program which this report represents.

The author wishes especially to acknowledge the contributions of the following:

J.W. Atwood, C.L. Blocher, D.L. Grigsby, D.H. Johnson, H.T. Johnson, T.J. Lyndon,

M.S. Neuberger, E. Schafer and C.A. Schill.

ii

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DS-140

ABSTRACT

A compilation of the electrical properties of Sulfur Hexafluoride, a

dielectric gas is presented. Electrical properties include corona, dielec-

tric constant, dissipation factor and dielectric strength. The latter property

data section is segregated into parameter effects as follows: pressure, gap

distance, temperature, electrode configurations and gas mixtures. Each

property is compiled over the widest possible range of parameters obtained in

a thorough search of the world's literature.

This report has been reviewed and is approved for publication.

HI hayne J~nso•'•He'aad

Electronic Prop es Information Center

#hn WAtwoodzrojerct Manager

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DS-140

TABLE OF CONTENTS

PageForeword . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iiAbstract . o . . . . . . . . . . . . . . . . . . . . . . 1 , . 0. . 0.

Introduction . . . . . . . . . . . a . * . . . . * . a a . . . . . . 1General Description •.• .... • .• • .• • • • *. ... . .a. . 3

Corona Effects . . . . o . . 0 . 0 0 0 a a 0 0 a 0 0 . 0 * 0 0 V 0 8

Dielectric Constant • & • • a • • • • 0 • • • * • . . . . . a a . . 16

Dielectric Strength(A) Relative Dielectric Strength . . . . o o . . a • . . . . . . 18

(B) Dielectric Strength vs Pressure(1) Sphere-to-Sphere Geometry . . . . . . . . . . . . . . . . 21(2) Sphere-to-Plane Geometry . . . . . . . . . . . . . . . . 24(3) Sphere-to-Rod Geometry * * . . . . . . . . . . . . * . . 26(4) Sphere-to-Point Geometry . . . . . . . . . . . . . . . . 27(5) Plane-to-Plane Geometry .. .e . . . . . .o . . . . . . . . 29(6) Plane-to-Rod Geometry o o .o. . . . .* . . . .* . . . . . . 31(7) Plane-to-Point Geometry . .. .. ... . . . . . . . . . 32(8) Rod-to-Rod Geometry * .a . . .* . . . . . . . . . . . . .s . 36(9) Miscellaneous Geometries .0. . . . . . . . . .0. . . . . 37(10) Gas Mixtures. . . .. . .. .. . . . . . . . . . . . . . 42

(C) Dielectric Strength vs Gap Spacing(1) Sphere-to-Sphere Geometry . . . . . . . . . . . . . . . . 45(2) Sphere-to-Plane Geometry. . .9. . . . . . . . . . . . . . 46(3) Sphere-to-Rod Geometry . . . . . . . . . . . . . . . . . 48(4) Sphere-to-Point Geometry . . . . . . . . . . . . . . . . 50(5) Plane-to-Plane Geometry . . ..... . . . . . . . . . . 51(6) Plane-to-Rod Geometry . . . . . . . . . . . . . . . . . . 52(7) Plane-to-Point Geometry . . . . . . . . . . . . . . . . . 54(8) Rod-to-Rod Geometry . . . . . . . . . . . . . . . . . . . 55(9) Coaxial Cylinder Geometry . . . . . . . . . . . . . . . . 56(10) Various Configurations . . . . . . . . . . . . . . . . * 57(11) Gas Mixtures o . • • a . • . • . . . . . . . . . . . . 59

(D) Dielectric Strength vs Temperature o . .o . . . .o . . . . 60

(E) Miscellaneous Breakdown Parameters • . . . • • . . . . . . . 61

Dissipation Factor . . . . . . . . . . . . . . . . . . . . . . . . . 63

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64Publications of the Electronic Properties Information Center . . . . 66

iv

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DS-140

I NTRODUCT ION

In June 1961, a pnogram was initiated under the direction of the Air Force to

collect, index and abstract the literature on the electrical and electronic pro-

perties of materials and to evaluate and compile the experimental data from that

literature. Placed at Hughes Aircraft Company in Culver City, California, the

program, now called the Electronic Properties Information Center, was originally

intended to cover ten major categories of materials: Semiconductors. Insulators,

Ceramics, Ferroelectrics, Metals, Ferrites, Ferromagnetics, Electroluminescent

Materials, Thermionic Emitters and Superconductors.

During the first year, studies were completed on the Semiconductor and Insu-

lator categories; and Ceramics was discontinued as a separate category and sub-

sumed under the other nine. Vocabulary studies have how been completed on all

categories, and retrospective documentation is virtually complete for Semiconduc-

tors and Insulators. A full index to the literature is maintained; and publica-

tions such as data sheets, summary reviews, glossaries and thesauri are issued

periodically. The use of the Center and these publications are available to any-

one wishing information within the scope of the Center's objectives. A full list

of publications to date appears at the end of this report.

This report contains data sheets on Sulfur }lexafluoride. The data sheets have

been compiled directly from the literature. Articles are allowed to accumulate

until it is judged that a sufficient number are available on one material for ade-

quate evaluation. The manual modified coordinate index is then used to retrieve

all literature on the material to be compiled. Bibliographies are checked to

make sure that valuable and relevant literature is not overlooked. Then the

assembled literature is given to the specialist doing the evaluation and compila-

tion.

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Evaluation is confirned to primary source data except when only secondary cita-

tions are available. If equally valid data are available from several sources, all

are given. Data are rejected when judged questionable because of faulty or dubiousz

measurements, unknown sample composition, or if more reliable data are available

from another source. Selection of data is based upon~that which is judged most

representative, precise, reliable and covers the widest range of variables. The

addition of new data to a previously evaluated property requires a reappraisal of

the reported value9. Older data may be deleted if the new data are judged more

accurate or representative.

After a thorough analysis and evaluation, the data are compiled into data sheets

which present it in its most optimum form. This will be, primarily, but not

limited to, curves or tabular form. Where possible, graphs are adapted directly

from the original sources. If this is not pessible, they are drawn from data

compiled from the articles. Where thought important, notes are entered with each

graph to help the user.

The references, from which the data are drawn, are shown by reference number below

each graph with the fuil bibliographic information at the end of the data sheets.

The bibliography is referred to and listed in the order of enti, into the Center

(accession number). This provides a quick cross reference ir-.o the index used

with the literature.

2

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~~E A,. ODITMOO.NO 9*€:AIR FORE 1TRI4JSLAJORATOIY EPI * MjHri0rj, RES EARCH AND TECHNOLOGY DIVISION EiAIR FORCE SYSTEMS COMMAND

___ o IB H

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER , HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORI DE

General Description

Sulfur Hexafluoride (SF 6 ) is a stable, non-toxic gaseous dielectric with

excellent electronegative behaviour or characteristics. Its structure is

:such that all six fluorine atoms are at the corners of a regular octahedron

with the sulfur atom at the center:

F

F

SS

In pure form SF 6 gas does not have any odor and is harmless; it does not

burn and is heat resistant up to 500 0 C depending on conditions. At 150 0 C, SF6

begins to undergo chemical decomposition and is initiated catalytically to var-

ious degrees by different metals. Possible decomposition products are SF 2 , SF4 ,

S2Flo and HF. It is insoluble in water and has a molecular weight of 146.06.

In the gaseous state, SF 6 follows the ideal gas laws fairly closely.

3

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AMI N=NAMDIAS LUMTOIY P ARESEARCH AND TECHNOLOGY DIVISION 0AIR FORCE SYSTEMS COMMAND

C IRMjER

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

Physical Properties

Melting point -50.8 0 C at 32.5 psia (-58°F to -68°F)

Sublimation temperature -63.8 0 C (-800 F)

Critical temperature 45.547 0.0030 C (113°F to 1290?)

Critical pressure 545.47 psia

Critical density 0.730 gm/cc

4J-

UR IIVAPOR

-iO0 -20 -10,0 0 100

Temperature oC

The density of sulfur hexafluoride overthe temperature range from -273 to 450 C.

0- S@o oo 400Pressure, psi

The pressure density relationfor sulfur hexafluoride.

[Ref. 16775]

4

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AIRFORCE NAmIAMsLAMoLDRoY EpicRESEAR:=H AND TECHNOLOGY DIVISION IAIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

Phsical Properties ,oo. .

CRITICALTEMPERATURE

200 -- - -

The vapor pressure-temperature relationfor sulfur hexafluoride. 1i0

U•,

40

0

(I)(I)

S•MELTING POINT - -

> 10

•SUBLIMATION POINT

CI

2-

-80 -60 -40 -20 0 20 40 60

Temperature 0 C0) 0.300I.. [Ref. 16775]bo

to SULFUR MEXAFLUORI D0.20

AIR4.'

_ _ _The specific heat of sulfur hexafluorider lC measured at constant volume.

44.r4

O4 100 200 300 400

Temperature °C

[Ref. 16775)5

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AIRFO~cKEAIUILSLADOBATOSYRESEARCH AND TECHNOLOGY DIVISION 4CAIR FORCE SYSTEMS COMMANDCN

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

Applications

SF 6 provides an outstanding insulating medium for a wide range of electrical

and electronic equipment and applications. It is remarkably inert and possesses

exceptional thermal stability, uniquc arc-quenching properties and high dielec-

tric strength. The gas has found dielectric applications in the following:

waveguides, x-ray apparatus, switch gear, cathode ray accelerators, television

filter plexers, audio equipment, airborne electronics, Van de Graaf machines,

transformers, radar duplexers and gap tubes. Sulfur Hexafluoride is being used

extensively as a means of obtaining high peak power performance in waveguide

systems.

In a recent review study at Pome Air Development Center of the available

microwave behavior of SF6 it was reported that power ratios (breakdown power

of SF6 over that of air at normal pressures with all other parameters constant)

of SF6 varied from a low of 3 to a high of 40 in the literature. The mechanisms

of these inconsistencies were discussed in terms of geonetric configuration,

contamination, localized hot spots, localized corona discharges, etc. (Ref. V.C.

Vannicola, "Sulfur Hexafluoride in hfigh-Power Microwave Systems", Rome Air

Development Center, Report no. RADC-TDR-62-443, Nlovember 1962. AD 289-954.)

Leeds and Friedrich (Engineers Digest, V. 13, p. 1073-1075, 1962) reviewed

recent developments in the use of SF 6 for circuit breakers. SF 6 had superior

arc extinquishing properties because it acted like an "electron sponge." This

has made possible its usage in a variety of different commercial switchgear

apparatus: plain breaks, self generzted gas flow by arc heating, gas flow by

puffer action and gas flow by opening blast valves between high and low pressure

reservoirs.

6

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AIRFfta IATERIMSIA RMMY EpicRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED GY ELECTRONIC PROPERTIES INFORMATION CENTER e HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

"Notes

Sulfur Hexafluoride is currently undergoing study and testing by the Elec-

trical Tests Subcommittee 11 of AST14 Committee D-27 on Electrical Insulating

Liquids and Gases. The Gaseous Dielectrics Section of the Subcommittee has

undertaken the development of a standard test cell for the evaluation of the

dielectric strength of SF6 and other gases. Round-robin tests have been con-

ducted and some results reported in the "Symposium on Electrical Insulating

Gases," ASTM-STP No. 346, 1963, Philadelphia, Pa., American Society for Testing

and Materials.

The EPIC method of dielectric strength data presentation has fallen in line

with the philosophy of ASTM Committee D-27 on Electrical Insulating Liquids and

Gases as expressed in M.L. Manning's article "Gaseou- Tnsulation: Its Importance

and Need for Test Methods," ASTM-STP No. 346, 1962. p. 3-23. The philosophy

involves the segregation of dielectric strength data by a) electrode geometry

effects, b) by pressure effects, c) gap distance effects, d) type of applied

voltage.

7

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RESEARCH AND TECHNOLOGY DIVISION EI 1 9n MZEf09

AIR FORCE SYSTEMS COMMAND :M Fn

PREPARED my ELECTRONIC PROPERTIES INFORMATION CENTER *HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SUMFP IfXALUOICE

CORONA EFFECTS

240 11

U200-VSA1M -4GP

0 0 2OON 3NT 4 5 6

12 -toshee

A-C spark-over and corona onset voltages of sulfur hexafluoride forindicated gaps between 1/16 inch hemisphere point and 6 inch diameterplane in 12 inch diameter steel tank as a function of pressure.

(Ref. 11302)

fE ~I ec toode

SFS PS.iive Broakdown

Absolute Pressure - Atmospheres

Sparkover and corona onset voltages of SF6 in a 12 in.diameter steel tank as a function of pressure at 250C.

[Ref. 10936)

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AIR~~ ~ ~ ~ FOCENTEh1ART0YNflO F)9m 70mRESEARCH AND TECHNOLOGY DIVISION I IAIR FORCE SYSTEMS COMMAND I C Xm rm

PREPARED mY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

m _--

SULFUR HEXAFLUOR IDE

CORONA ErFECTS140 ,

to 120 - WLPAUJ#(n U) fXAFLWNIDE100

f~41

4J'

U)060

Corona onset voltage of sulfur hexafluoride 0~ .1 00940"as a function of gas pressure. 0 40 - P"DIA.

20 -~ VOLTAGEGSpark breakdown voltage 00VLM

--- Corona onset voltage m0 20 40 60 80 100 120 140 160

Gas Pressure$ lb/in2 (abs. )

[Ref. 1655]

100

80TEST TS>NO.3 NO5 TEST

NO.

60

40 -. Corona onset and spark breakdown charac-/ teristics for sulfur hexafluoride.

201 --- Corona onset voltage0 40 so 120 .... Spark breakdown voltage

Pressure, lb/in2 (abs.)

[Ref. 1853]

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RESEARCH AND TECrHNOLOC.,Y DIVISION EPI

AIR FORCE SYSTEMS COMMAND

_jIC RMTE

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER H HUGHES AIRCRAFT COMPANY., CULVER CITY. CALIFORNIA

SULFRM HEXA RIDE

CORONA EFFECTS a

#"000WO

4.1 cn~ 3-- T m

Air-

0 0 1-

Pressure, atm

Breakdown voltage to corona voltage ratio as a function of pressure forsulfur hexafluoride and air under both positive and negative point polarity.

[Ref. 6140]

Corona Onset and Flashover Voltage in SF6 Gas, 3/4-Inch Diameter

Square-Cut Rod-to-Plane Electrodes

Full-Wave Tests (1 1/2 x 40 usec)

Corona Onset FlashoverVoltage, % Voltage, %

Pressure, Spacing, Point Point Point PointPsig* Inches Negative Positive Negative Positive

0 1 92 100 200 11015 1 125 128 254 145

0 6 85 100 324 16215 6 132 140 354 147

Note: For each spacing, the corona onset voltage at atmosphericpressure and positive point = 100%.

* Pounds per square inch gage.

[Ref. 6209J

10

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AI RFORCE KATWM s AILAbmTOrY *p0 I•70 0RESEARCH AND TECHNOLOGY DIVISIONAlR FORCE SYSTEMS COMMAND C

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

CORONA EFFECTS 240 (a)

Corona current/voltage characteristicsfor sulfur hexafluoride.

(a) 15 lb/in2 absolute (e)(b) 25 Wb/in 2 absolute(c) 30 lb/in2 absolute(d) 35 lb/in2 absolute (g)(e) 40 lb/in2 absolute u(f) 45 lb/in2 absolute(g) 50 lb/in 2 absolute 0O

Voltage, kv

[Ref. 1853)

I' ' I I I I

i 4- (a)

+o 00O94

S > 2- Corona onset voltage as a function ofgap spacing in point-plane corona test

o (corrected to 760 mm) using polonium a-

0. source. Radius is 0.060 mm.02 4 6

Gap Spacing, Millimeters (a) SF6 , point positive(b) SF6 , point negative

[RP, ef. 62091

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A N=c nIATEEW n.M M~~nY nn,, I Q) F•ORA••7ORRESEARCH AND TECHNOLOGY DIVISION Epic I MAIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SU"FU HEWAFLRIDE

CORONA EFFECTS

POSITIVE DCIREAKOOWN

0,

r4-

0*

.i-I-'

POITIVE DCCORONA

040 Mo 120 1" O 204MPressure, cm of Mercury

The corona breakdown relation for sulfur hexafluoride as affectedby pressure.

Electrodes - 1/2" square rodsTest Gap - 2 inches

E

[Ref. 16775]

12-. -.- '.

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AIR FORCE MATERIALS LABORATORY -'RESEARCH AND TECHNOLOGY DIVISION EPIC M 41ý CHAlR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

CORONA EFFECTS R cm

0 25 0.026 0.04 0,0051 OOO2SCorona extinction field (-)E as a cc I I I I I I -function of l//R where R is radius 60 COFECTED r,-

of wire in 1/4 inch or 1/2 inch co- ATM

axial cylinder. L O S

* Peek's datao 1/2 inch outer cylindero 1 inch outer cylinder olA 1/4 inch outer cylinder 0 2 4 6 s 1 ,2 14 1 a 20

AL (R cm)

[Ref. 6209]

140

w 120 '

60

2C/i

8 00

Positiv DCPositi(ve

soolt presureat: 5°¢

[Ref. 0010

SDry AIr> .04 60Pln

0-4goT

o 40

0 DC Coroc.; Inception Voltage

20Air SF6 { J0 20 40 60 80 100 120 140 160

Positive DC Bias, (kv)

Total breakdown voltage as a function of positive dc bias voltage, 2 atm.

absolute pressure at 250C.

[Ref. 10936113

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U ImR ESEA RC H A ND TECHNOLOGY DIVIION PIC

AIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER • HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORI DE

CORONA EFFTCTS

e/ ) (a) 20 lb/in2 absolute, SF 6 plus N2IX .../ -- (b) 30 lb/in2 absolute, SF6 plus 1N2

(c) 40 lb/in2 absolute, SF6 plus l2> _"(d) 50 lb/in2 absolute, SF6 plus N2

(e) 65 lb/in2 absolute, SF 6 plus N2

--- Corona onset voltageSpark breakdown voltage

o 40

Wo so No 240 320 AmG

Pressure, lb/in2 abs.

Corona onset and spark breakdown characteristics (Ref. 1853]for mixtures of sulfur hexafluoride and nitrogen.

240 ,

(a) Total pressure, 20 lb/in2 absolute * 1(b) Total pre.sure, 25 lb/in2 absolute 0(c) Total pressure, 30 lb/in2 absolute - (0)(d) Total pressure, 40 lb/in2 absolute 1(e) Total pressure, 45 lb/in2 absolutei ()(f) Total pressure, 50 lb/in2 absolute so(g) Total pressure, 55 lb/in2 absolute 1(h) Total pressure, 60 lb/in2 absolute )(M) Total pressure, 65 lb/in2 absolute (i)-(1) Total pressure, 70 ib/in 2 absolute L

O0 40 8o

Voltage, kv

Corona current/voltage characteristicsfor 20 lb/in2 sulfur hexafluoride plus

nitrogen.

[Ref. 1853]1l',

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AIR FORCE KTEIAISLA ORATORY P mgp -ýP10HRESEARCH AND TECH rOLOGY DIVISION Epi

AlIR FORCE SYSTEMS COMMANDC

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

CORONA EFFECTS 24O (0

I - (a) 1(C)Corona current as a function of voltage = 4

characteristics for 30 lb/in2 sulfur 4.

hexafluoride plus nitrogen. r.

2 0 ((a) Total pressure, 30 lb/in absolute(b) Total pressure, 35 lb/in2 absolute(c) Total pressure, 40 lb/in2 absolute o(2) Total pressure, 40 ib/in absolute 0(d) Total pressure, 45 lb/in 2 absolute(e) Total pressure, 50 lb/in2 absolute(f) Total pressure, 50 lb/in absolute 00(g) Total pressure, 50 lb/in2 absolute

Voltage, kv

[Ref. 1853)

2

. 1(b) Corona current as a function of voltage"0 Icharacteristics for 40 lb/in2 sulfur

160 (a ) hexafluoride plus nitrogen.

0 ~(4)-

(e)_;1(a) Total pressure, 40 WnabsoluteC-)(b) Total pressure, '45 lb/in2 absolute

Ca)

-(c) Total pressure, 50 lb/in2 absolute(d) Total pressure, 55 lb/in2 absolute

c -- -(e) Total pressure, 60 lb/in2 absolute( f) Total pressure, 65 lb/in2 absolute

Voltage, kv

(Ref. 1853]

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MR FMld NA IK S LAORTOY F< rRESEARCH AND TECHNOLOGY DIVISION .JlrAAIR FORCE SYSTEMS COMMAND

Lj 7 U'\j LiLLd

PREPARED SY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC CONSTANT

1.06 - - a

LO?_

1.06 ---

4 :

'U

o,• I.

U-,.'0

1.02 _,

DATA: 91RdSAUM £MARRYOT,NATKNAL BUREAUOF STANDARDS.

1.01

140iii op- s -_a_-- -_-

0 2 4 a a 10 12 14 16 a6 20 22

Pressure - Atmospheres

Dielectric constant of sulfur hexafluoride(25 0 C and 24,240 "Ic) as a function of gas pressure.

[Ref. 11266]

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SI

AIR FORCE IATERLA1S UMORTORY i AMYF1A 0sRESEARCH AND TECHNOLOGY DIVISION

AIR FORCE SYSTEMS COMMAND

C

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

"* SULFUR HEXAFLUORIDE

DIELECTRIC CO'STA!;T

Frequency Pressure Temperature Dielectric Constant Ref.

27.5 0 C 1.00191 JQ299760 mm Hg 19.40 C 1.0021 1181708 mm I g 27.5 0 C 1.00191 11266

(l0-500kc) - -50 0 C ± 1°C 1.81 ± 0.02 1508(liquid SF6 )

For other conditions of pressure and temperature the

following equation is cited in reference no. 11266.

C = 1 + 10- 6 E

where E = dielectric coefficient

For E 25*C = 2049 (limiting value = 0-1 atm.)0-1

For E 6 = 2026 (limiting value = 0 atm.:if gases were perfect)

For E-O00C = 2018 (limiting values at -80 0 C)

17

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All rN= UIAIZL30SATOY pPN P QPA TRESEARCH AND TECHNOLOGY DIVISION PCI MIMM COgAIR FORCE SYSTEMS COMMAND L EI I

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER @ HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

S U HEXAFLUOR IDE

DIELECTRIC STRENGT!i

(A) Relative Dielectric Strength

RelativeDielectric Strength Pressure Temperature

4.5 760 mm Hg -49.2 0C

[Ref. 11279]

Relative dielectric strength of sulfur hexafluoride (test madebetween tungsten rod and 1 inch diameter sphere spared 1-inch.)

Atmospheric Pressure and Room Temperature

Relative Dielectric Strength

Conditions 60 Cycles Positive Impulse Negative

Nonunifor•i field - 1" spacing ;f6 5 3.5 3.1

Uniform field- 1/4" spacing SF6 2 1.1

Looped Toroids - 2" spacing SF 6 1.85 2.4

[Ref. 11266]

. ! I It ! Relative impulse strength of sulfur4J lIJ 1 I hexafluoride and air at both 25 and

-T1 I I 1000 C as a function of pressure.P' 0 so Is 3 S 4

- 1 T-- - Electrodes 0.5 inch stainless steels•1sphere to 3 inch diameter plane.

, I 10 2 2 1 tRef. 11279)Pressure, lbs/sq in. gage

18• -• • • •• • • 'IIi I l lb l d~ • b -at ,-, , , .... .•. .

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AIR FORCE NAI!IAI IADOBATORY A [PEAT R,RESEARCH AND TECHNOLOGY DIVISION EI

AIR FORCE SYSTEMS COMMAND

C

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER *HUGHES AIRCRAFT COMPANY. CULVER CITY. CAL.IFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRENGTH

(A) Relative Dielectric Strenjzth

60-cycle relative strength of sulfur _

hexafluoride to dry air as a function b

of configuration and spacing of theelectrodes. Gases at 250C and atatmospheric pressure.

.5--

40

4- I'/Gap Spacing (inches)

I [Ref. 11279)4J +

4J4Cn/

Relative breakdown strength of mixtures.r4 of helium + sulfur hexafluoride.

41w

Percent SF FA I L- --A

go~ 00 0 40 s. 0Percet Ile[Ref. 1931]

19

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AR FM~ IAIUL&U UMMITIY p" PRESEARCH AND TECHNOLOGY DIV;SIONAIR FORCE SYSTEMS COMMAND

I C C ¶HTiR

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR EXAFLUORIDE

DIELECTRIC STR7IJGTll

(A) Relative Dielectric Strength

---------------------

$4 The ratio of the corona and breakdown

"q. •voltages for air and SF 6 as a functionof the testing conditions in a nonuni-

AWDOWNform. field.SPOSIIvI POINT

-I coe rsowao POSITIVE PCVI

NUATI/TVE[ POINT

[Ref. 16775j

a 4 4 0 10 it 1 i si

Pressure - Atmospheres

0-I

The changing relation of the impulsevoltage breakdown of SF6 and air asthe gas pressure of each is increased. -

Electrodes - point-to-plane

Test Gap - 1 1/2 inches ")Voltage Wave rorm - 1 1/2 x 40 microsec.Point Electrode Polarity - positive 0- -

Test Temperature - 270 C 40 I

0

0.5

00, S O to so0 40

Pressure, psig

(Ref. 16775]20

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AIR FORCE NMATRIL LADORATORY EPIC' -E rF)7RESLARCH AND TECHNOLOGY DIVISION J -, LJjAIR FORCE SYSTEMS COMMAND

I

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(1) Sphere-to-Sphere Geometry

>350.x./ ";300 '

250-

m. i -

Breakdown voltage between 5 cm diameter spheres I' d /for sulfur hexafluoride. o-4

> JINegative impulse r 150- /

- Power Frequency .o ,100o - ,

50- I

0 20 40 60 S0

Gas Pressure, lb/in2 (abs.)

(Ref. 1589)

S140

4- 120 - --

Electrodes - 1 inch spheresGap Distance - 1/4 inch

- - -- -Temperature - roomPressure - atmospheric

.9-4

- - The dielectric strength of sulfurr4 hexafluoricle gas measured by impulse

I I voltage in a uniform electrical field.

Pressure., psi

[2ef. 177r]21

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AMRMNAWWIN___Y P A~)E TR

RESEARCH N TECHNOLOGY DVSOAIR FORCE SYSTEMS COMMAND

I_ C MMTRE

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVk[R CITY. CALIFORNIA

SULFUR HEXAPLUORIDE

DIELECTRIC STREIGTH

(P) Dielectric Strength vs Pressure

(1) Sphere-to-Sphere Geometry

Breakdown data for sulfur hexafluoride (5-cm diameter spherical electrodes).

Breakdown Voltage, (kv)

Com- Absolute Power Negative Negative [Relative . Impulseound Pressure Frequency direct_ impulse [electric ratio

__ _ _ ___ _ __ _ _ _ _ __._ _ _ strength _ _ _ _ _ _

Sphere gap, cm

0.5 1.0 0.5 1.0 0.5 1.0 0,5 1.0 0.5 1.0

sr6 1 45.0 86.0 44.0 83.5 47.7 91.3 2.6 2.7 1.06 1.06

2 79.0 161,0 91.0 171.0 2,47 2.87 1.15 1.06

3 112.5 218.0 134.5 244.0 2.48 2.G8 1.19 1.12

4 143.5 268.0 175.0 309.0 2.47 2.53 1,22 1.15

[Ref. 1181)

2

22

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AIR FORCE NATERIAIS LAORTORY P. )PI V~ F1 LEc-1 RRESEARCH AND TECHNOLOGY DIVISION I

AIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric strength vs Pressure

(1) Sphere-to-Sphere Geometry 220

200-

ISO - SF -160 - -I

140 -/

120 -

.X 100

80

60

40Impulse dielectric strength voltages of$r 6 using two 1-inch diameter spheres. 20

0 15 30Gage Pressure, lbs/sq in.

(Ref. 4Z299]

90

80

70

0 60 -SFS50 -

4.'v-4 400o 30 ;0

0 4.P4I>4 20

60-cycle dielectric strength of SF60 -"tested between two 1-inch diameter

I i spheres spaced 1/4 inch and at a gage

0 15 30 pressure up to 30 psi.Gaý,e Pressure, lbs/sq in.

[Ref. 4299]

23

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RItSEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED DY ELECTRONIC PROPERTIES INFORMATION CENTER 9 HUOHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SU".R HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(2) Sphere-1to-Plane Geometr:,140 I I " I ' " I

'•-

60-cycle breakdown voltages of Sr6 100as a function of pressure. (Gas at S IF GAProom temperature.) Electrodes 0.5 s o0inch diameter spi ere to 3 inch dia- ometer plane. G0

•40"

X PLANE AT HIGH POTENTIAL

NICKEL PLATED BRASS SPHERE USED FOR THESE TESTSI . I I , I I I

0 5 10 15 20 25 30 35 40

Sage Pressure, lbs/sq in.

[Ref. 11279]

Io 0 A STEEL SF'-'/2 ' GAP

* SF6-I VZ'OAP6" 40-4J

Ito PLATED RASS SPHERE Impulse breakdown of SF at room temp-

erature as a function oi pressure.I00 Electrodes 0.5 inch sphere to 3 inch

diameter plane. Positive impulse waveso .1 1/2 by 40 microseconds.

I I I I I i I

* 0 5 10 15 20 25 30 35 401-4

Gage Pressure, lbs/sq in.

[Ref. 11279]

24

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AIR FORCE MATERIUl LABORTORY EIRESEARCH AND TECHNOLOGY DIVISION

AIR FORCE SVSTEMS COMMAND

C

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER • HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(i) Dielectric Strengmth vs Pressure

(2) Sphere-to-Plane Geometry * 1 1 1

,00 - x do,

*8060-cycle breakdown voltages ofsr 6at 1000 C as a function of 4 6_pressure. Electrodes 0.5 inch 0stainless steel sphere to 3 inchdiameter point. 40

020 PLANE AT HIGH POTENTIAL--r 2O

0 ~0 PLANE G3ROUNDEDLg

<0 5 10 15 20 25 30 35 40

Gage Pressure, Ibs/sq in.

[Ref. 11279]

4 .... s. .' GAP

S140

120 - SFb- 1/2" GAP

4-,1-4 10o00

Im~pulse breakdown voltages of tsrat 100 0 C as a function of pressure.

ra Electrodes 0.5 inch stainless steelS60 sphere to 3 inch diameter plane.

Positive impulse wave 1 1/2 by L0

40 microseconds.

S20 -

0 5 10 15 20 25 30 35 40

Gage Pressure, lbs/sq in.

25~ef. 1177]253

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Al F1 KAM W LUMIMTm P ii• 0•RESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

LdC M-YE

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER o HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HOAUORI DE

DIELECTRIC STRENGTH

(B) Dielectric St:,etgth vs Pressure

(3) Sphere-to-Rod Geometry240

200

ISo -sp -

>120

80

40

I I

0 15 30 45Gage Pressure, lbs/sq in.

Impulse dielectric strength of SF6 as a function of pressure. Positive-wave testsmade between tungsten rod and 1 inch diameter sphere spaced 1 inch.

(Ref. 4299J

130 1 I I i I

120 SF-

I10

*K0

90a

7060

0 5 10 15 20 25 30 35

Gage Pressure. lbs/sq in.

60-cycle dielectric strength of SF6 as a function of pressure. Tests made betweentungsten rod and 1 inch sphere spaced 1 inch.

[Ref. 42991

26

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___P ••0

AIR N=R NTMW [AAB TOI€YRESEARCH AND TECHNOLOGY DIVISION Ei

AIR FORCE SYSTEMS COMMAND c_

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC •TRENGTI!

(B) Die•.c -trength vs Pressure

(4) Sphere-to-Point Geometry Itoo - 20mm

I / /040~~4 - , -0 k

4I I

I ,/ , -Ito

Op /1I ,II3.IJ

- 20 Poi1 e sm~

o 20" 4000 O 2 40 60 S0

Gas Pressure, 1b3/sq in. (abs.)

o -- -[1ef. 1589]

BDielectric strenvth of a 2 inch gap-point

to 1 inch diaeseter sphere as a function of

pressurne.

so0

00. 20 400 60 50 00 110140 0 S

Pressure, Atm.

"[Ref. 15279]

27

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AI MIFOQ UAIII SIAIOAWTO Epc4 (PL910eRESEARCH AND TECHNOLOGY DIVISIONAI N FORCE SYSTEMS COMMAND

PREPARED NY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SUL .. U I HEXItUIDE

DIELECTRIC STRENGTH

(D) Dielectric Strength vs Pressure

(4) Sphere-to-Point Geometry

K)0160 1 i 1 'I

POWER >o'uIR140 FRWA-VJ Y 140- VOL4E"

2120 C 1O 20mm 151mmke 30mm

;too- 11j00 leso0- so • O .'

O 0

t6o 06 toI40 .m d ' 60o0-

E 20" " 20 5m, I I I '

0 20 40 60 80 100 ISO - __ 0 20 40 60 80 100

Gas Pressure, lbs/sq in. • 160- IMPULSE Gas Pressure, Tbs/sq in.(abs.) 140 (abs.)

120

4j 20mm

0> so - 20rMM

680 - 35MMl~3mm"

60 5mm

40

S20 - I I I0 20 40 60 80 t00

Gas Pressure, lbs/sq in.(abs.)

Breakdown voltage for sulfur hexafluoride with point-sphere electrodes.

-- Power frequency, positive d.c. and impulseNegative d.c. and impulsePositive d.c. and impulse with radium.

(Ref. 1181)28

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AIRI FORCE KAlEUAIS UAORTORY ETIC i KEPMM DRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER - HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTII

(B) Dielectric. trength vs Pressure

(5) Plane-to-Plane Geometry 140

S120 -

10080o

so41

4 600

o 40p0Dielectric strength of sulfur hexa- • 20fluoride as a function of pressure,3 inch diameter round-edged planc-to-plane, 1/2 inch spacing. 0 5 10 15 20 25 30 35 40

Gas Pressure, psig

[Ref. 10452]

1000

4J goo0

%d800

o 600o 1

V. I

3: 500-00

100 10 1 10-1

p1t (rn l~g - ')

Paschen curve for sulfur hexafluoride (gap 1 mm, parallel circularbrass plates, 4 inches in diameter and 1/4 inch thick with rounded

edges of 1/9 inch radius.)

L[P,cf. 16238]-21

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All FORCE NAThEAIM LDUATOY EpicRESEARCH AND TECHNOLOGY DIVISIONA ,R FORCE SYSTEMS COMMAND C

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRENGTH

(M) Dielectric qtrength vs Pressure

(5) Plane-to-Plane Geometry

4.,

-0 5 10 Is 20 25 30O

Gas Pressure, psig

The dielectric strength-pressure relation forsulfur hexafluoride gas, showing the effect of

gap distance.

Electrodes - 3" diameter, rounded edge planesTest temperature - roomGap Distance - inches as shown on each curve

[Ref. 16775]

30

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AIR FORCE MATERIALS LABORATORY EPI, E R- mCRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND c -

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER 9 HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIEIECTRIC STRENIGTH

(F) Dielectric 'trength vs Pressure

(6) Plane-tc:-Rod Geometry

140 I -

- 120

80 oSF*

6600

r 40

S20

I t I I I I I I I

0 5 10 15 20 25 30 35 40 45Gas Pressure, psig

Dielectric strength of sulfur hexafluoride as a function of pressure.1/4 inch square rod-to-plane, I inch spacing.

[Ref. 10452]

31

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AM MW NAU3AIS EAMY P 1TmmRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARIED Y ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUO I DE

DIZLECTRIC STPEI:TH

(0) Dielectric Strength vs "ressure

(7) .lane-to-"oint , eormetrv 100 .... T__._.

I

TstTest 1480 - - _ + f .. -1

Tern No,• Test NoS o.I6

Corona onset and spark-breakdown charac- .teristics for sulfur hexafluoride.0. ,

Corona onset voltage , ,- Spark-breakdown voltage > -rest..

0 40 so 1.0

Absolute ?ressure, lb/3q in.

140 1 I 1 1 1 I 1- [Rlef. 1C531

x4* 120 FAOLP/AV

4o1 300. I + :

p100

soolt P-sue bs n

4j 0W> SO o

c 0N Spark breakdown voltage of sulfur hexa-.-. , 40"

40 - DIA. fluoride a3 a function of pressure.0 0 DC 1

$4 20 VOLTAE eWA

, , I I I I .I I I

0 20 40 60 SO 100 120 140 160

Gas Pressure, lb/s'3 _n. (abs.) 4

["cf. 16551

32

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AIR FORCE MATERIUM LAORTORY EPIC Moj~7 [aRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND c [

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(7) Plane-to-Point Geometry

> 160 T

o' OC(6 OXIS

b40 120.

dc %

" I. (-pee

Gas pressure as a function of dielectric strength for POIO"'yJ Jd.c. and 60 cps a.c. voltage. Dielectric strength in- -4 M/

creases normally with pressure up to about 1 atm. Fur- 4J

thur increase in pressure produces a divergence from

the straight line until a maximum strength is reached a0)0ctwe ' e 6at about 2 atm. Increasing pressure beyond this point 2 4 6

results in a drop in strength, the minimum occurring Gas Pressure, Atm.at about 5 atm.

[Ref. 6140]and

[Ref. 16775]240 1 ' I " - 1 '

* SPARMOVER-SF-2' GAP* SPARXOVER-S- IGAP2 SVAKOVER-S)-b GAP

% T SPRK•0VER-sr.-ii GAP% 0 CORONA ONSET- SFg-

160 - I" GAP%

1 20

a.c. spark-over and corona onsetvoltages of sulfur hexafluoridefor indicated gaps between 1/16

40 inch hemisphere point and 6 inchSo diameter plane in 12 inch dia-

meter steel tank as a function of

0 2 3 4 5 6 7 pressure.

Pressure, Atmospheres

[Ref. 11302]

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RESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER 6 HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULM" HEFLORRIDE

DIELECTRIC STRENGTH

(B) Dielectric Strenth vs-Pressure

(7) Plane-to-Point Geometry

The effect of gas pressure on the voltage " 1necessary to cause a prebreakdown current ? --

of 20 micro amperes in sulfur hexafluoride o/gas at room temperature.

Gap distance - 3 mm (0.118 inches)Electrodes - point-to-plane - -

Electrode Point - positive polarity /

0 20 40 100

Pressure, psi

[Ref. 16775]

S/ ",

A9a ___ The effect of pressure on the dielec-=- tric strength of sulfur hexafluoride4 gas in a nonuniform (DC) electrical

field for selected gap distances..

4j 9U' Flectrodes - 1/16" point to 6" planeS1 Electrode Polarity - point electrode

___ _as shown0 C// ap Distance - as shown on curve

Pressure - Atmosphei,(Ref. 16775]

34

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AIR FORCE NATEIIAIS LABORATOY UI, P A ý)P[RESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTZMS COMMAND

DT C M

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER , HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STREN4GTH

(B) Dielectric Strength vs Pressure

(7) Plane-to-Point Geometry

.Ix 2u

.C6C

4-,I

V1 0

ILI

4A'

a)o

'.,,

01 2 3 4 5 6 7Pressure - Atmospheres

The effect of pressure on the 60 cycle breakdown ofsulfur hexafluoride gas at selected gap distances.

Electrodes - 1/16" point to 6" planeGap Distance - as shown on curve

[Ref. 16775]

35

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MAl = nAIU AIS ARATU r E c I m IP RH OIRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED SY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUOR I DE

DIELECTRIC STRENGTH

(9) Dielectric-Strenath__vs, .Pressure

(8) Rod-to-Rod Geomety 140 ,

120

100

~SSF

J 60-

Breakdown voltage, nonuniform field, 401/41" rod.

20

I ,, I ,

0 10 20 30 40

Pressure, psig

(Ref. 1860]

140

The impulse breakdown of sulfurhexafluoride gas as affected by

-S- pressure.

Electrodes - 1/2" square cut rods-a -Gap Distance - 2 inches

Voltage rorm - 1 1/2 x 40 microsec.V4 -Voltage Polarity - positive

4.'u

r4.,-I

4-0 -5"

0 3 DIN 200 F"Pressure, cm of lercury

[Ref. 16775]36

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AIRFORCE IATERWSLABORAT1ORY *RESEARCH AND TECHNOLOGY DIVISIONAR FORCE SYSTEMS COMMAND C

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVEW CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(9) Miscellaneous Geometries

140 I " I '

gSF*120 /

> 100 '

Power frequency flashover voltage of solid o0 A>0-7 A Iiinsulation in sulfur hexafluoride. Uniformr

tangential stress. 03 60 - SURFACEFLASHOVER--- Breakdown voltage in the absence of,4J 0 40 - BREAKDOWN -

solid insulation mVOLTAGE INSurface flashover THE ABSENCE

20 OF SOLIDINSULATION

0 20 40 60 80

Gas Pressure, lb/sq in. (abs.)

50 [Ref. 1589)

SPARKOVER IPOS. P01.IMPULEWITHSTAND J(CREST)

400

60-CYCLE CRESTSPARKOVER

3500

CYCLESWITHSTAND (RMS)+- too0 Impulse and 60 cycle sparkover and

withstand voltages of sulfur hexa-1OO fluoride using 2 inch gap spacing.

ExAFL.Xo1RIDE"Ii I I l

0 5 10 15 20

Gas Pressure, psig

[Ref. 4299]

37

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AIROBCEMATEUAISIADOATORY pT P MI)A 0mPES!ARCY. AND TECHMNOL(OGY DIVISION I apiAIR FORCE SYSTEMS COMMAND

PRIPARED MY ELECTRONIC PROPERTiEf. INFORMATION CgN'VER * MUN3HI9 AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR tEXAFLUORI DE

DIEILICTRIC STRENGTH

(3) Dielectric Strength vs Pressure

(9) Miiscellaneous Geometries 7

> 6

S Fer-40

Breakdown voltage as a function of >press,,re for SF6 (across a spark- 4

plug.)

10 20 25 30

Pressure in Inches, fig (abs.)

[Ref. 10489]

..- S - - ----0

3reikdown voltage of mixturesof sr6 and air as a functionof pressure abs. 60 cps a-ciapplied across a sparkplug.I - -

Fressure in Inches, } (abs,) [P.ef. 111021

39

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AWIt FORCE MATERUlIS LABORATORY EPIC /ARESEARCH AND 7"CHNOLOGY DIVISION

SIR FORCE SYSTEMS COMMAND

C

PREPARED Sy ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric, Strength vs..Pressure

(9) HIiscellaneous Geometries 6 --

C

ABC - occur in chronological order SF-6

A - initial breakdown onset voltageB - voltage necessary to extinguish

arc after 1 minute of continuousarcing in confined volume A

C - onset voltage for breakdown after CI minute continuous arcing inconfined volume, followed by X 4 I

extinguishing W

4.1AB,C - for dielectric gas as received -40from the manufacturer

X',B',d- for 50% dielectric gas and 50% 3air mixture

2 .

15 20 30

Pressure in Inches, I!g (abs.)

Breakdowr voltage, extinguish voltage asa function of pressure.

[Ref. 100021

3)

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AMRMXTM __Y c P AMPRA DH

RESEARCH AND TECHNOLOGY DIVISION

AIR FORCE SYSTEMS COMMAND

C ]9 dNi7H

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(9) Miscellaneous Geometries

o 0• ,4 .a

17' 4- 4-0-liiT M4i I ION"

A_ 0

0 Il41 1

r.I el 4 0 Wl& O4

Absolute Pressure (Atm.) Absolute Pressure (Atm.)

RG-49U Wlaveguide (plane-to-plane configuration, left) - frequency, 2773 mc;

cavity loaded Q9 159.5; PRF, 225 pps; pulse length, twc microseconds. SingleRidge-to-plane S-Band Configuration (right) - frequency, 2812 mc; cavity loaded

Q9 165; PR,,P 225 pps; pulse length, two microsecond,- ; c-,-css-section drawing not

to scale. Diffusion and ion pair recombination have ,-•',ci•sive effect on break-down phenomena. Both depend on e ltctrode configuration and spacing. Pressureand ionic nature of gas under test also affect results.

[Ref. 6221]

Ito

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AIR FORCE MATERIALS lABORATORY rT E,€ Ii uRESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND C

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER . HUGHES AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(9) Miscellaneous Geometries o

.'-

-iJo 0I ~~T I Al n 65l],•Ilil,•: •'-,J!!!IV '-- I- I l

1 --1 ,.

0 rAT + ii lal 4

SAbsolute Pressure .JL (Atm. )

"Absolute Pressure (Atm.) Absolute Pressure (Atm.)

"Iemisphere-to-Plane S-,and Configuration (left) - Frequency, 2757mc; cavity loaded Q. 131; PP., 225 pps; pulse length, two micro-seconds; cross-section drawing riot to scale. Center: Rounded-Point-to-Plane S-Band Configuration - frequency, 2752 mc; PRF,225 pps; pulse length, two microseconds; cross-section drawingnot to scale. Right: Single-Ridge-to-Plane L-Band Configura-tion - frequency, 1316.5 mc; cavity loaded Q, 222; Pnr, 360 pps;pulse length, six microseconds; cross-section drawing not toscale.

[Ref. F221]

'42

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AllI - - UM A IAORR9rEARCi AND TC14NOLOGY DIVISION I AAIR FORCE SYSTEMS COMMAND

PREPARED DY ELECTRONIC PR1OPIRTIESl INFORMATION CENTER H NUOMES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SU"UR HEE .LUORI DE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(10) Gas Mixtures

-NNW74

0o• so 30 0 wo 40 To so wom

Percent SF 6 by Volume

Effect of air on dielectric strength of: SF6.

al

(Ref. 11266]42

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E--9,E S07Ao 01

AIR FORCE MATERAU UAORATORY EIP CRZSEARCH AND TECHNOLOGY ]DIVISIONAIR FORCE SYSTEMS COMMAND

____III C

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER & HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(10) Gas Mixtures

The dielectric strength of sulfur hexa-

fluoride mixtures with nitrogen, tested to so -

in a uniform field. 4J

Electrodes - bright mild steel t !Test Gap - 1 mm . 7 A- ICISNE[S 9F6

The mixtures were obtained by adding 0 3-03ATMePNERE SFtnitrogen to an initial pressure of o 4W 6 6W0 No n0 O• 0osulfur hexafluoride as indicated. Pressure, psi

[Ref. 167751

bo . The dielectric strength of sulfur0 Peu p hexafluoride mixtures with air.

> 000ýElectrodes - bright mild steel.Ito Test Gap - 1 mmI

I4 - 7 ATMOSPERES SF Field Configuration - uniformtoC - 2- 3.5 ATMOSPNERES SFg

W 3. 0. ITOPHR I The mixtures were obtained by adding210 m 40 So go 700ow Wo air to an initial pressure of sulfurPressure, psi hexafluoride.

[Pef, 16775]

43

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AllU NUVTMLW TPACURION

RESEARCH AND TECHNOLOOY DIVISIONAIR FORCE SYSTEMS COMMAND

PREPARED MY ELECTRONIC PROPERTIES INFORMATION CENTER * HUONES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SU"FUR HOWAL=URI DE

DIELECTRIC STRENGTH

(B) Dielectric Strength vs Pressure

(10) Gas Mixtures .We

5

.4Breakdoiwn voltage as a function of pressure fordifferent percentages of sulfur hexafluoride PRETmixed in air (across a sparkplug.)

3 - 75

-XIi 2 5

0

Ii i .

1O 20 25 30

Pressure in Inches, Hg (abs.)

[Ref. 10489)

Corona onset and spark breakdowncharacteristics for mixtures of

- - - - - -sulfur hexafluoride and nitrogen.4.'0 40 Corona onset voltage

> &V----L---"- Spark breakdown voltage

SI 2 J - (a) 20 psi abs. Sr6 + N2

Pressure, lb/sq in. (abs.) (c) 30 psi abs., SF 6 + N2( 6 2

(d) 50 psi abs. SF 6 + N2(e) 65 psi abs., SF 6 + "T 2

[Ref. 1853]44

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AIR FORCE MATERALS lAORATORY EPI I 1SRESEARCH AND TECHNOLOGY DIVISION

AIR FORCE SYSTEMS COMMAND SC

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRE!GT'

(C) Dielectric Strength vs Gap Spacing

(1) Sphere-to-Sphere Geometry

Elecfroes Z-10n boums 80er*S10 oC~,$ W cps. job"..,o

Dielectric strength as a function of gap " 11

distance in a uniform field. Q + 6

a) W,

CZ: +-' 2-

0 10 20 30 40 50 60 70 50p 1 dp £Jistafce, -ils

"Sulfur I!exafluoride [Ref. 6140]Breakdown Voltage

Radio Frequency Power rrequencyGap

kv peak .. kv Leak

0.3 26.4 27.?0.4 34.) 36.10.5 44.3 45.0

[Ref. 1181]

12

. tSULFURHEXAFLUORIDO

bD The dielectric strength of sulfur

1 hexafluoride in a uniform field4J ras affected bv .ao distance.

4 Electrodes - 2 inch brass qheresqas Pressure - atmospheric

- _as Temperature - roomTest Voltage - 60 cycles

0 10 20 30 40 s0 60 70 Sý

Gap Distance, nils[Pef. 16775)

L45

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l l

AM Fm cEAmIA SLSAORATOIRESEARCH AND TRCHNOLO@Y DIVIIONAIR IORCe SYSTeMS COMMAND o CPREPAR0D SY ELECTRONIC PROPERTIES INPORMATION CENTER * HU0HI4 AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(2) Sphere-to-Plane Geometry 160 1 1 1 I 1 1 1

140

120

60 cycle breakdown voltages of SF 100 -as a function of configuration anaspacing of the electrodes (at 25 0 C V2" SPHERE-

and atmospheric pressure.) TO-PLANE

40 (20

0 0.25 Q50 0.75 1.00 1.25 1.50 1.75 2OO 2.25

Gap Spacing, inches

[Ref. 11279)70 I I I I .

ISO - 3A" DIAMETER SPHERE TO5 GROUNDED PLANE ELECTRODE

50

20- Rapidly applied 60 cycle voltageGAS :SF6 breakdown strength as a function

10 - PRESSURE I ATMOSPHERE of gap distance.TEMPERATURE 230 C I

J, - I I - I_ I 1 4

0 0.1 0.2 03 0.4 0,5 06 0.7 0.8

Gap Spacing, inches[Ref. 1625]

46

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AIR FORCE AMATRIL LABRATORYEPCRESEARCH / 4D TECHNOLOGY DIVISIONAR FORC_ SYSTEMS COMMAND C NH 725

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEDAFLUORIDE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spac' m,

(2) Sphere-to-Plane Geometry 70 1 1

60 - 63A" DIAMETER SPHERE TOGROUNDED PLANE ELECTRODE

50-

One-minute withstand 60 cycle 40 -

voltage strength as a function 0

of gap distance. r 30

S•~ 2020~S SF/S

GAS: SF*10 PRESSURE I ATMOSPHERE

TEMPERATURE: 230 CI I I i , I I

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Gap, inches

[Ref. 1625]I40

120

100

w e0SF660 GAS : SF6

a

> PRESSURE : I ATMOSPHERE-: TEMPERATURE : 23 0 C

40 3/4 INCH DIA BRASS SPHERETO SOLIDLY GROUNDEDPLANE ELECTRODE

20 FULL WAVE 1.5X4OMS -Tpulse voltage wit:1 t_ 1

POSITIVE POLARITY strength as 3 functioi, -

I I ap sac.n,.

0 025 0.50 0.75

Electro±Že Jpacing, inches

L4 7

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All FORCE NAERM ILA TOL4RnY =I",,,.,,,.R ,. AND, TECH,-NOLOGY DIVISI.ONo e p ic --+• • • •AIR FORCE SYSTEMS COMMAND

PREPAREr BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(3) Sphere-to-Rod Geometry 70 1 1 1 1 1 ,6 3/4" DIAMETER SPHERE TO

GROUNDED60 - 2,I" SQUARE ELECTRODE

50

Rapidly applied 60 cycle voltage 40breakdown strength as a function SF6

of gap spacing for SF6 .

30 -20 GAS: SF6

PRESSURE: I ATMOSPHERE10 - TEMPERATURE: 230 C

I I I I I I , I

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Gap, Inches

[Pef. 1625]

70

O 3/4" DIAMETER SPHEREG0 _ TO GROUNDED

1 • " SQUARE ELECTRODE

50

30

9ne-minute withstand 60 cyclevoltage strength as a function

20 of gap distance.

10 - GAS : SF.PRESSURE : I ATMOSPHERE E}

TEMPERATURE : 230 CI lI 1 1

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Gap, Inches [Ref. 1625]

i R

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AIR FORCE MATERIALS LABORATORY EPICRESEARCH AND TECHNOLOGY DIVISION 7IA:R FORCE SYSTEMS COMMAND C -

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER e HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORI DE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(3) Sphero-to-Pod GeometryI I I I

160 320 -

140 15 0bsx 120 230 2.20

100 o 2200/ / ibslbS80 0 160

0)>0160

o60 • 120

4L0 80

20 40

0 0.5 1.03 1.50 2.',0 0 0.5 1.00 1.50 2.00

q'pace in Inches Space in Inches

60 cycle dielectric strength of SF6 'Negative - impulse dielectric strengthgas. Tests made between tungsten rod of SF 6 . Tests made between tungsten rodand l" diameter sphere (grounded). and 1" diameter sphere (grounded).

320 -

280F

S200F 30ibs0

- 160

0 0.5 1.50 1.5 2.00

Space in Inch~es

Positive - impu1se dielectric stren~gth of SF6 . Thsts madebetween tungsten rod and 1" diameter sphere (g;rounded).

[Fef. U2q99]49

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AIRFORCE IATERI1W IABORATORY RII 7ý 7RESEARCI AND TECHNOLOGY DIVISIONAIR FORCE SYSTIEMS COMMANDc

PREPARED BY ELECTRONIC PROPERTIFS INFORMATION CENTER • HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRSNGTH

(C) Dielectric Strength vs lap "lpacing,

(4) Sphere-to-Point Geometry

140 1 " 1 "

120

100-

o POINT TOSPHERE

S60-

,> 40

20 FROM PAPER BY CAMLU"AND CHAPMAN

0 0.5 1.0 1.5 2.0 2.5

Electrode Spacing, Incheb

Dielectric strength of sulfur hexafluoride as a function ofelectrode spacing for point tc sphere configuration at atmos-pheric pressure and 25 0 C.

r•ef. 11279]

so

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AIR FORCE MATERIALS LABORATORY [picRESEARCH AND TECHNOLOGY DIVISION lj J - jAIR FORCE SYSTEMS COMMAND

CJ L_________________ II

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY CULVER CITY, CALIFORNIA

SULFUR HXALUORIDE

DIELECTRIC STRj;:TGTII

(C) Dielectric ',trc-n-ti vs Gap Spacing

(5) Plane-to-Plane Geometry 140

A40 120

120 - 100 SF6

100 r

>o:60

II4 40

o0 20

i I I *0 01 02 0S 04 05

0 0.5 1.0 1.5 2.0Gap, Inches Gap, Inches

Breakdown voltase, uniform ,rea.:'iown voltaý,•, uniforr,field, 3 " disks. iPositive ftcli, 3" disks.impulse 1.5 x 40 m cro-ec,.

[rPef. 1 ar,O]

160

>30PSI 201PS

ob 10 PSIThe dielectric 3trength-gap ,.s--2-___S_

tancc relation in sulfur hex~a- Sfluoride gas ais affected by the TMSHEIpressure applied. 0-. /A ER

",-4

Electrodes - 3" diameter, rounded so-edge plines -

Temperature - room2;-as Pressure - as shown on edc-o

curve.4IO3

Gap Distance, Incr.-, [Ref. ] V,77r,1

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All FORCE NATERIM L5IMDRTORY VUAtjRESEARCH AFOD TECHNOLOGY DIVISION PIMAIR FORCE SYSTEMS COMMAND .pC F4IM

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORI DE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(6) Plane-to-Rod Geometry , ..

4.15 m~ 45Atgg

Gap distance-strength relationship in a non-uniform electrical field as affected by pres- -

sure. Note that dielectric strength of the 4-1

gas under 5 psig pressure actually decreases 0Uas gap distance increases beyond 1 1/4 inches. u

C I

0 I23

Gap Distance, in.

[Ref. 6140]and

[Ref. 167751

70 ' ,

GROUNDED PLANE

IB ELECTRODE50

40

"Rapidly applied 60 cycle voltagebreakdown strength as a function

20 -of gap distance.

S~GAS : sr~s10 PRESSURE : I ATMOSPHERE -

TEMPERATURE - 230 C

t I I . . I I - I I

0 0.W 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Gap, Inches

[Re?. 1,;251

52

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AIR FORCE KATERIAlS LABORATORY ___ 0RESEARCH AND TECHNOLOGY DIVISION

AIR FORCE SYSTEMS COMMAND IC ¶

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEWAFLUORIDE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(6) Plane-to-Rod Geometry 70 1 " , - 1 "

60 - V2" SQUARERODTOGROUNDED PLANE

One-minute withstand 60 cycle C ELECTRODEvoltage strength as a function 50

of gap distance.40

50

S- , 2020S1 GAS: sF,

10 PRESSURE uI ATMOSPHERETEMPERATURE= 23 0 C

SI, I 1 I 1 I

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Gap, Inches

[Ref. 16251140 .

120SF

100

X 80

Go 6Breakdown voltage, nonuniform field,1/4" rod.

40

20P 1 I 1_,

0 0.5 1.0 1.5 20

Gap, Inches

[R!ef. 1860]

53

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AIR FO)RCE MATEIJAS LABORATORY 1 EPIC 4)RESEARCH AND TECHNOLOGY DIVISIONAI R FORCE SYSTEMS COMMAND Ill KMC 1-rr~PREPARED BY ELECTRONIC PRO.DERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY, CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap ,pacin,;

(7) Plane-to-Point Geometry 160 ____,_,_,_,_•_,_....

140

120

60 cycle breakdown voltages of ',F6 00 POINT-TO-PLANEfor point-to-plane configurationas a function of gap spacing.

.60

40

20

0 0.25 0.50 0.75 1.00 125 1.50 1.75 2.00 2.25Gap Spacing, Incnes

[Ref. 11279]

1404I I120

toe-- ,/t

a.c. sparkover voltage of SF6 as a4' SC function of electrode spacing between4 •a 1/16 inch hemisphere point and aa 6 inch diameter plane at 3 atmospheres

) I>40 -

I I

o05 050 0100

Gap Spacing, Inches

[Fef. 11302]

54

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AIR FORCE HATERIALS LAORATORY EiIRESEARCH AND TEQH-NOLOGY DIVISIONAIR FORCE SYSTEMS COMMANDc LYE? 3

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY CULVER CITY CALIFORNIA

SULFUR HEXAFLUORI DE

DIELECTRIC STRENGTH

(C) Dielectric Strength vs Gap Spacing

(8) Rod-to-Rod Geometry 70 1 "

b 1/2" SOUARE ROD TO GROUNDED60 4-= 1/2" SQUARE ELECTRODE

50

40 SF6Rapidly applied 60 cycle voltage _

breakdown strength as a function

of gap spacing. 30

SI ,20"GA SFg

10 PRESSURE I ATMOSPHERETEMPERATURE: 230C

0 0.1 0.2 0.3 0.4 0.5 0.6 0.? 0.8

Gap, rniches

[Ref. 1625]

70

• I1/2" SQUARE ROD TO GROUNDED

60 - I" SQUARE ELECTRODE

GAS: SFs

50 PRESSURE I ATMOSPHERETEMPERATURE: 23 0 C

40

One minute withstand 60 cycleS30 -strength as a function of gap

S. spacing.

x 20

10

0 0.1 0.2 Q3 04 0.5 0.6 0.7 0.8

Gap, Inches [Ref. 1625]

[Rf.165

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All FORCE KATEIWR~ UNATOLR13Y EPIC'IRESEARCH AND TECHNOLOGY DIVISION I[\AIR FORCE SYSTEMS COMMAND [ A 0ýoC 19

PREPARED MY ELECTRONIC PROPERTIE8 INFORMATION CENTER *HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXALUOR IDE

DIELECTRIC STRENGTH

(C) Dielt%...tric Strength vs Gap Spacing

(9) Coaxial Cylinder Geometry

0 s7 *AppM N\

a ad io 0 S 6 2IdS O 200 1 I 2345~ 200 2

1[Ref 1181N1

F4~~~~~ COOAICEPI

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AIR FORCE MATERIALS LABORATORY S wTcTjr2'i

RESEARCH AND TECHNOLOGY IVISIONCAIR FORCE SYSTEMS COMMAND

I J)I C rI:-

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER . HUGHES AIRCRAFT COMPANY. CULVER CITY CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STE1IGT

(C) Dielectric Strength vs Gap Saciri

(10) Various Configurations

240 ELECT O0o CO;FIGURATION> - PLANE TO PLANE

200 - - SPH4ERE TO PLANE

- 3- SPHERE TO PLANE

The effect of electrode configuration on the 6 "4- 4L RODToPLANEdielectric strength of sulfur hexaifluoride 5- POINT TO PLANEas a function of gap distance at atmospheric 4J 120 P T , LAN

pressure when tested under impulse conditions. u..•

-- 4

S 0.5 1.0 1.5 2.0 2.5 3.0 3.5

'ap Distance, Inches

[Ref. 15775]160

140 e .0

> 120L

4 -'IO4

4-J SC

•___The dielectric strength-gap distance4J 00 E.LECTRODE CONFIGVRATION relation for sulfur hexafluoride gois0 i - PLANE TO PLANE as a function of the electrode config-

2- SR uration measured at atmospheric pres-2-/ SPHERE TO PLANE

3. SPHERE TO0 PLANE ue

4- ROD TO PLANE Test teriDerature - 250 C

5- POINT TO PLANE Voltage '-lave Form - 1 1/2 x 400 0 1.0 1.5 2.0 2.5 3.0 3.5 -llcrosecon<Is

Gap Distance, Inches Polarity - positive

.r'ef. 16775]57

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AR FORCE MAT•OIAISL ABORAT0RYR('SEARCH AND TECHNOLOGY DIVI SIONEpcMr DFAP Z V0oAIR FJRCE SYSTEMS COMMAND

IC leHT M-

PREPARED mY ELECTRONIC PROPERTIES INFORMATION CENTER e HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STPENGTH

(C) Dielectric Strength vs Gap Spacing

(10) Various Configurations

N/

D / C IIIC /

,, I____/

~IGO

>~ ~~ 16 C/ 0j•140

The comiparative dielectric strength of . .

sulfur hexafluoride gas tested under dc E _____,0 IVand ac voltage at room temperature and 1pressure, 100

ac voltage - 60 cycles 4

dc polarity - pos'tive ,

I- POINT TO PLANE ELECTRODES

2- 1 SPHERE TO PLANE ELECTRODES

010 0O.S .0 1.$ 2.0

flap Distance, Inches

[Ref. 16775]

C) The effect of electrode configuration on

En the dielectric strength of sulfur hexa-u fluoride gas at atmospheric pressure.

S40 'o I- POINT TO PLANE ELECTRODES Test temperature - room-4 /'0r/ 2 SPERE TO PLANE ELECTRODES Test voltage - 60 cyclesr

Cl3- 3" PLANE TO PLANE ELECTROWES

0. 5 1.0 1.5 2.0

Gap Distance, Inches[ReF. 16775]

58

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AIR FORCE AMATRIl LABRATODRY EPIC pRRESEARCH AND TECHNOLOGY DIVISION F 5

IA R FORCE SYSTEMS COMMAND

PREPARED NY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUORIDE

DIELECTRIC STRL'IGTIT

(C) Dielectric Strength vs Gap Spacing

(II) Gas '.ixtures

ft 4

> 1

4-1 4

-- I " - I I ri i Iq

0 0." 0.6 0,11 0.1 O* 0.

Cap, Inches

Spark breakdown voltages for air, He, 112, SF6 andmixtures of lie + SF6 for 1 inch diameter hermispheres.(7h•.6 centimeters Hg{, 29.5 degrees centigrade, 60cycle voltage. )

[Ref. 19311

5-3

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MR FO E K 'AT hIw UI o oY Epic I EPIC&RESEARCH AND TECHNOLOGY DIVISIONAIR FtORCE SYSTEMS COMMAND J(F c AM 1M

PREPARED MY ELECTRONIC PROPERTiES INFORMATION CENTER e HUGHES AIRCRAFT COMPANY CULVER CITY CALIFORNA

SULFUR HEXAFLUOR IDE

AIIELECTRIC STRENGTH

(D) Dielectric Strength vs Temperature

0 100

00 8:Cý ý ý gap

U''I

40sr 6 2 gap

r4 2C ONI I

V 20 40 60 80 100 120 140 160E Temperature °C

Impulse breakdown voltages of sulfur hexafluoride atatmospheric pressure as a function of temperature.

100 [Ref. 11279]

so 0

FUR HINAFLL0RIOK

U,o

64j

00

Temperature 0 C

The dielectric strength-temperature relation for sul-fur hexafluoride tested at atmospheric pressure.

Electrodes - 1/2 inch sphere-to-plane *Gap Distance - 1/2 inchVoltage - 1 1/2 x 40 microsecond wave form

(Ref. 16775]

6i0

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"RESEARCH AND TECHNOLOGY DIVISION _IAIR FORCE SYSTEMS COMMAND

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER * HUGHES AIRCRAFT COMPANY. CULVER CITY. CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRENGTH

(E) Miscellaneous Breakdown Parameters

> 4 0 0 G v M v v I J 1 v1v 1 1 1 1 1 1 1 1 1vI 1 w i l l I ~ I f i rv

Breakdown voltage as a function of timeto breakdown for SF for 2 inch gap be-

6tween 2 inch diameter sharp-edged elec-trode and 6 inch diameter plane in 12inch steel tank at 78.5 cm mercury ab-solute and 25 0 C for positive polarity. 0___.____________________I___

0 I-4 1 10 we 03 100 es tooI MI.SE9COIQ 13ECOND

Time of Rise of Voltage toBreakdown Voltage, usec

(Ref. 62091

34

C...

Spark breakdown voltage for Sr 6 + H!e mixtures.4.--0 Parameter + gap between 1 inch diameter hemi-

0 spheres (74.6 cm Hg, 29.5 0 C).

S

m O• 410 m 010

Percent SF6

Percent He [Ref. 19311

(1

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AIR Fl~a NAUIWS IADOTOIYEI 2 ýY eA T0[RESEARCH AND TECHNOLOGY DIVISION D"jAIR FORCE SYSTEMS COMMAND C G

PREPARED MY EKLECTRONIC PROPERTIES INFORMATION CENTER * HUGHIS AIRCRAFT COMPANY, CULVER CITY. CALIFORNIA

SULFUR HEXAFLUOR IDE

DIELECTRIC STRE14GTl!

(1;) liscellaneous Breakdown Pirameters

< i

3.0

i.4J

impulse voltage breakdown of sulfur Fhexafluoride and air as the gas pres- .

sure of each is increased.,Q

-; 1.5 - -

-4.

electrodes - point-to-plane

test gap - 1 1/2 inches 0voltage v age bform -k d /2 x 4o su ecpoint electrode po lat positive

test temperature - 27 0C$0 6 O Is W0 2 30 36 40

Pressure, psig

(Ref. 16775]

,oc1 / so s6

50% SF~50% Ali

(VOLUME)-M Showing the interrupting capacity ofIO F sulfur hexafluoride gas, air and a501V mixture thereof at 2300 volts,

-0 -zero nower factor, using a three inchAIR /plain break switch.AIR 4

-0 0 6 9 120 150JIOr.ssure, ps ig

[Pe~f 16775]

r.a

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__ P AF0f97NAIR FORCEI ATEIIAISD•O Y E Pg.,R I P1_ cc ICI RESEARCH AND TECHNOLOGY DIVISIONAIR FORCE SYSTEMS COMMAND c I N T [

PREPARED BY ELECTRONIC PROPERTIES INFORMATION CENTER o HUGHES AIRCRAFT COMPANY. CULVER CITY, CALIFORNIA

SULFUR HEXAFLUORIDE

DISSIPATION FACTOR

Ref.

at 1 atm. pressure tan 6 =< 2 x 10-7 11266

at 21 atm. pressure tan 6 = <5 x 10-6 11266

at -50 ±10C (i0-50OKc) tan 6 =<0.001 1508(liquid SF 6 )

G-3

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DS-140

SILFUR HEXAFLLOR IDE RPflUECES

1181. HdiARDD, P.R. Insialatior Properties of Compressed Electromegative Oases.INST. OF ELECTRICAL ENG.,. PROC., v. 104 A, no. 14, Apr. 1947. p. 123-138.

1508. BMI9 D. Dielectric Constant of Liquid Sulftr Hexafluoride. J. OF CK04.PHYS., v. 31, no. 2, Aug. 1959. p. 572-573.

1589. HOWARD, P.R. Compressed Gases as Insulants in High-Voltage Equipments.ELECTRICAL TIWS,, v. 132, Oct. 31, 1957. p. 683-686.

1625. MANNIXp, M.L. Experience with the AIEE Subcomittee Test Cell for GaseousInsulation. AIEEM, TRANS., III, v. 78, Oct. 1959. p. 800-807.

1655. FOOPD, T.R. Positive Point-to-Plane Spark Breakdown of Compressed Gases.NATEME, v. 166, no. 4224, Oct. 21, 1950. p. 688-689.

1853. F001RD, T.R. Some Experitments on Positive Point-to-Plane Corona and SparkBreakd of Copressed Gases. INST. OF ELECTRICAL ENG., PROC., v. 100,Pt. 2, no. 78, Dec. 1953. p. 585-590.

1860. BL1DWKIIT, F.W. Properties of Octafluorocyclobutane, A Dielectric Gas.AIEZ, TRANS., I, v. 78, Mar. 1959. p. 63-66.

1931. CaCINME J.D. Som Electrical and Thermal Characteristics of Helium andSulfur Hexafluoride Mixtures. AIEE, TRANS., I, v. 74, no. 19, July 1955.p. 318-321.

4299. CAICILLI, 0. and J.J. CHAPMAN. Gaseous Insulation for High-V itage Apparatus.GEN. ELZC IC REV., v. 51, no. 2, Feb. 1948. p. 35-41.

6140. CLARK, F.M. The Newer Insulating Gases. MATERIALS IN DESIGN ENG., v. 53,no. 2, Feb. 1961. p. 95-99.

6209. NAFR, P.,9 et al. Factors Controlling Electric Strength of Gaseous In-sulation. AIM., TRANS., III-A, v. 78, Aug. 1959. p. 545-550.

6221. ANWYMWXS. Sulfur Hexafluoride Waveguide Dielectric Breakdown Curves.SPACE/AER5aLICS, v. 31, no. 5, May 1959. p. 138-139.

10002. RC3 AIR DEVELOPMEWQT CENTER. GRIFFISS AIR FORCE BASE. Low FrequencyBreakdown in Dielectric Gases, by VANNICOLA, V.C. Tech. Documentary Rept.no. RADC-TDR-62-585. Dec. 1962. Proj. No. 4506. ASTIA AD-296 319.

10452. CAMILLI, G., et. al. The Dielectric Behavior of Some Fluorogases and TheirMixtures. AIEE, TRANS., I, v. 74, Nov. 1955. p. 637-642.

10489. RONU AIR DEVELOI1!r CEWTER. GRIFFISS AIR FARCE BASE. Sulfur Hexafluoride inHigh-Power Microwve Systems, by VANNICOLA, V. Tech. Documentaxy Rept. No.RADC-IDR-62-443. Nov. 1962. ASTIA AD-289 854.

10956. BEAG, D. and C.N. Wa1UM. The Influence of Space-Charges on the Electric Break-down of Sulfur Hexafluoride. In 1956 ANNJAL REPT. OF THE COEF. 011 ELECTRICALIN lAI. Washington, D.C., Nat. Acad. of Sci.-Nat. Res. Council, 1957. Pub.512. p. 57-58.

64

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DS-140

11266. ALLIED CHE24. CORP. Sulfur Hexafluoride. Tech. Bull. TB-85602. 1955.

11279. CAMILLI, G., et al. Gaseous Insulation for High-Voltage Transformers. AIEE,TRANS., III, v. 71, Jan. 1952. p. 348-357.

11302. WORM, C.N. and T.W. DAKIN. Dielectric Breakdown of Sulphur Hexafluoride.ELEC1'ICAL ENG., v. 72, no. 7, July 1953. p. 624.

16238. NAT. AERONAUTICS AND SPACE ADMINISTRATION. On the Breakdown Voltages of SomeElectronegative Geses at Low Pressures. By, SCHREIER, S. NASA TN D-1761.June 1963.

16775. CLARK, F.M. Insulating Materials for Design and Engineering Practice.N.Y. Wiley, 1962. Selected Pages.

F) 5

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DS-140

P!MLICATIONS OF TIE ELECT'FO,'C PROPFTIES INFORMATIONr CENTER

DS-IO1 Cadmium Telluride - Data Sheets. M. Neuberger. June 1962.

DS-102 indiumL Phosph'de - Data Sheets. M. f;euberger. June 1962.

DS-103 Indium Telluride - Data Sheets. M. Neuberger. June 1962.

DS-104 M Wnesium Sulicide - Data Sheets. M. Neuberger. June 1962.

DS-1O'; Polyethylene Terephthalate - Data Sheets. J.T. Milek. June 1962.

DS-106 Polytetrafluoroctayvlene Plastics - Data Sheets, Emil Schafer. June 1962.

DS-107 Polytrifluorochloroethylene Plastics - Data Sheets. Emil Schafer. June 1962.

DS-108 Zinc Telluride - Data Sheets. M. Neuberger. June 1962.

DS-109 Indium Arsenide - Data Sheets. M. Neuberger. July 1962.

DS-11O Aluminum Ant-monide - Data Sheets. M. Neuberger. September 1962.

DS-111 Gallium Phospn!de - Data Sheets. M. Neuberger. September 1962.

DS-112 Gallium Antimonide - Data Sheets. M. Neuberger. October 1962.

DS-113 Lead Tellur'de - Data Sheets. M. Neuberger. October 1962.

DS-114 Magnesium Stannide - Data Sheets. M. Neuberger. hovember 1962.

DS-115 Gallium Arzenide - Data Sheets. M. ieuberger. December 1962.

DS-116 Lead Selenide - Data Sheets. M. iNeuberger. December 1962.

DS-117 ( No longer available - Superseded by DS-137. j

DS-118 ( No longer available - Superseded by DI-157. )

D6-119 ( No longer available - Super3eded by DS-10'. )

DS-120 ( No longer available - Superseded by DS-137. )

DS-121 Indium Antimonide - Data Sheets. M. Neuberger. February 1963.

DS-122 3teatite - Data Sheets. J..7. Milek. February 1963.

DS-12.5 Beryllium Oxide - Data Sheets. J.T. Milek. March 1963.

DS-124 Cadmium Sulfide - Summary Rev'ew and Data Sheets. M. Neuberger. April 196)

.66

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DC-140

DS-125 Magnesium Oxide - Data Sheets. j.T. Milek. June 1963.

DS-126 ( No longer available - Superseded by DE-137. )

DG-127 Silicone Rubber - Data Sheets. J.T. MIlek. June 1963.

!D3-128 Cordierite - Data Sheets. O.T. Milek. June 1963.

DC-129 Forsterite - Data Sheets. J.T. Milek. August 1963.

D6-130 Pyroceram - Data Sheets. J.T. Milek. August 1963.

DS-131 Germanium - Data Sheets. M. Neuberger. September 1963.

EC-132 Zinc Selenide - Data Sheets. M. Neuberger. September 1963.

D6-133 Zinc Oxide - Data Sheets. M. Neuberger. October 1963.

DU-134 Cadmium Selenide - Data Sheets. M. Neuberger. November 1963.

EC-135 Zinc Sulfide - Data Sheets. M. Neuberger and D.L. Grigsby. December 1963.

DS-136 Aluminum Oxide - Data Sheets. ,.T. Milek. i'rch 1964.

D)-137 Silicon - Data Sheets. M. Neuberger. Ma•y 1964.

DS-138 Borosilicate Glasses - Data Sheets. J.T. Milek. June 1964.

DS-139 Aluminosllleate Glasses - Data Sheets. J.T. Milek. July 1964.

D6-140 Sulfur Hexafluoride - Data Sheets. J.T. Mulek. October 1964.

OPHE REPORTS

5171.2/8 Information Retrieval Program. Electronic/Electrical Properties ofMaterials. First Tuarterly Progress Report. E.M. Wallace.October 10, 1962.

5171.2/17 Information Retrieval ?rogram Electronic/Electrical Properties ofMaterials. Second ;uarterly Progress Report. F.M. Wallace.january 15, 1962.

5171.2/32 Information TBetrieval Program. Electronic/Electrical Properties oft'terials. Third Quarterly 7rogress Report. E.M. Wallace.April 15, 1962.

P62-i0 .lectrical and Flectronic Properties of Materials Information andRetrieval Program. Final Report. H. Thayne Johnson, Emil Schaferand Everett M. Wallace. June 1962.

67

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M)-140

6-i Insulatlon Materala3 Descrlptor3 U3ed in the Ele.-trlcal and Electronic,roperties of Mterialr. InformtJic Retrieval Irogram. Fail Schafer..July '962.

S-2 Semiconductor Materials Descriptors Used in the Electrical and ElectronicProperties of Materials Inforwation Retrieval PrograM. Fall Schafer.September 2.962.

5171.2/75 Information Retrieval Pror. Plectronic/Electrical Properties ofMbteri&ls. Fourth -uarterly progress lReport. H.T. Johnson.September 15, 1962.

P63-15 Electrical and riectrcnic Properties of Materials Information RetrievalProgrum. H. Thayne Johnson, Donald L. Grigsby and Damn H. Johnson.April 1963.

P64-10 Electrical and Electrnl,- Properties of Materials Informstion RetrievalProgram. H. Thayne Johnson and Dant H. Johnson. April 1964.

G-3 A Survey Materials Report on Tetrafluoroethylene (TFE) Plastics.J. T. Milek. September 1964.

S-4 The Purpose and Functions of the Electronic Properties InformationCenter. H. Thayne Johnson. August '964. 9

68