Propyzamide Warning SPECIMEN DATE...Add 375 ml KERB FLO to 625 ml of water in the spray bottle....

P990474421709

Registered by: Dow AgroSciences LimitedCPC2 Capital Park, Fulbourn, Cambridge, CB21 5XE Telephone: +44(0)1462 457272Fax : +44(0)1462 42660524 Hour Emergency telephone number:+44(0)1553 761251For Technical Enquiries Call: +44 (0) 800 6898899

H

® Trademark of the Dow Chemical Company ("Dow") or an affiliated company of Dow

Distributed by:

T.P.WHELEHAN Son & Co. LtdSuite 12 Bunkilla Plaza,

Bracetown Business Park,Clonee, Meath

+353 1 83 422 33e-mail: [email protected]

Kerb

FLO

HERBICIDE

®

A residual herbicide for the control of a wide range of weeds

in WINTER OILSEED RAPE and several other AGRICULTURAL and

HORTICULTURAL crops and in FORESTRY and AMENITY situations.

A suspension concentrate containing 400 g/litre (35.3% w/w) propyzamide.

FOR USE ONLY AS AN AGRICULTURAL/

HORTICULTURAL/FORESTRY HERBICIDE

TRIPLE RINSE CONTAINER, PUNCTURE AND INVERT TO DRY AT TIME OF USE

Product Identifier according to Art.18 of Reg. (EC) No 1272/2008 [CLP]: Kerb® Flo, Propyzamide

WarningSuspected of Causing Cancer.Very Toxic to aquatic life with long lasting effects. Do not handle until all safety precautions have been read and understood.Wear protective gloves/protective clothing/eye protection/face protection.IF exposed or concerned: Get medical advice/attentionCollect spillage.Dispose of contents/container to a licensed hazardous waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste.Contains 2-Naphthalenesulfonic acid, 6-hydroxy-, polymer with formaldehyde and methylphenol, sodium salt and 1,2-benzisothiazolin-3-one. May produce an allergic reaction.To avoid risks to human health and the environment, comply with the instructions for use.

PCS No. 02830

SHAKE WELL BEFORE USE

READ DIRECTIONS FOR USE ON ENCLOSED LEAFLET

PROTECT FROM FROST

5 Litres

130mm14

0mm

EU 4634Package MID : 99047442 1709

Trade Name : KERB FLO

Country : IRELAND

Size : 130x140MM

Artwork Type : 5L LABEL - FLAT

Specification : EU 4634

Standardisation Level :

COLOUR REFERENCES

Number of Colours used:

1

Printer : EMEA - CCL LABEL ITALY

EMEA - MOZZANICA (F447-F470)Packing Location :

4

Ticket No : 594767A01/502260

Date : 06-OCT-17

Proof Cycle No : 1

BlackYellowMagentaCyan

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.

WARNINGTake care to avoid local overdosing.

Do not make more than one application of KERB FLO within 9 months to the same area of land.

IMPORTANT INFORMATION.

FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY/ HERBICIDE

Crops/situations Maximum Individual Dose

(litres product/hectare)

Maximum Number of Treatments

Latest Time of Application

Oilseed rape (winter) 2.1 One per crop Before 1st February in year of harvest

Field bean (winter) 2.1 One per crop Before 1st February in year of harvest

Pome fruit, top/cane fruit (see other specifi c restrictions)

4.25 One per year Before 1st February in year of harvest

Strawberry (outdoor use only) 3.5 One per year Before 1st January in year of harvest

Lucerne 1.75 One per crop Before 1st February in year of harvest

Lettuce (outdoor use only ) 3.5 One per crop Six weeks before harvest

Rhubarb (outdoor use only) 4.25 One per year Before the 1st of January in year of harvest

Forest, forest nursery and woody ornamentals

4.25 One per year -

Christmas trees 3.75 One per year -

Other Specifi c Restrictions:Use in pome and top/cane fruit is restricted to application to apple, blackberry, blackcurrant, gooseberry, loganberry, pear, plum, raspberry, redcurrant

This product may only be applied to edible crops except lettuce between 1st October and the specifi ed latest time of application.

Do not harvest crops for human or animal consumption for at least 6 weeks after last application.READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

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SOIL TYPESKERB FLO can be used on all soil types with the following exceptions:1. Do not use on soils containing more than 10% organic matter.2. Do not use on strawberries or winter field beans grown in certain soil types. See Crop Recommendation tables.

SOIL AND WEATHER CONDITIONSKERB FLO requires moisture for root uptake. Best residual action is obtained in moist soils of fine tilth.

KERB FLO can be applied under frosty conditions but should not be used where run-off from the soil surface is likely.

Best results are achieved when growth of weeds (especially black-grass and volunteer cereals) is slow, but transpiration continues. In mild autumns/winters, emerged weeds may take longer to be controlled, the residual activity of KERB FLO will be shortened and overall control may be reduced.

The efficiency of KERB FLO may be reduced in organic soils and in the presence of excessive surface organic debris, burnt straw, ash, or ploughed-up turf.

In winter field beans ensure a firm seedbed before spraying.

RESISTANCE

Strains of some annual grasses (e.g. black-grass, wild oats, Italian ryegrass) have developed resistance to herbicides which may lead to poor control. A strategy for preventing and managing such resistance should be adopted. Guidelines have been produced and are available from your local Teagasc/independent advisor.

CROP INFORMATIONNote: Specific application information for each crop is contained in the Crop Recommendation Tables that follow. In the recommendation tables which follow:S = Susceptible MS = Moderately susceptible MR = Moderately resistant R = Resistant

WINTER OILSEED RAPEKERB FLO can be applied after the use of a specific graminicide applied in accordance with the manufacturer’s recommendations.

FORESTRY, FOREST NURSERY, OUTDOOR WOODY ORNAMENTALSKERB FLO is recommended for use on the following species: Alder, Beech, Southern Beech, Birch, Douglas Fir, Grand Fir, Noble Fir, Horse Chestnut, Larch, Lawson Cypress, Oak, Bishop Pine, Corsican Pine, Lodgepole Pine, Monterey Pine, Scots Pine, Poplar, Norway Spruce, Sycamore, Sitka Spruce, Western Hemlock, Wild Cherry.

KERB FLO is recommended for use on the following species which have been planted out not later than the previous spring: Berberis darwinii, Buddleia davidii, Chamaecyparis spp (False Cypress), Cotoneaster spp, Crataegus spp (Hawthorns), Fagus sylvatica (Beech), Forsythia x intermedia, Ilex aquifolium (Holly), Larix decidua (Larch), Philadelphus spp (Mock Orange), Picea spp (Spruces), Pinus spp (Pines), Prunus gladulosa, Quercus spp (Oak), Rosa spp (Roses including Rose rootstocks), Spiraea x bumalda `Froebelii’, Syringa vulgaris (Lilac), Taxus baccata (Yew), Thuja orientalis `Rosedalis’.

Kerb Flo may be used in the production of Christmas trees.

SOIL TEXTURE (85 System)Textural Group Textural classSands Coarse sand, sand, fine sand, loamy coarse sandVery Light Soils Loamy sand, loamy fine sand, coarse sandy loamLight Soils Sandy loam, fine sandy loam, sandy silt loam, silt loam (85)Medium Soils Sandy clay loam, clay loam, silty clay loamHeavy Soils Sandy clay, clay, silty clay


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FRUIT CROPSSee Crop Recommendation Tables.

MISCELLANEOUS, INCLUDING LETTUCESee Crop Recommendation Tables.

PROCESSED CROPSNo taints have been detected in tests with treated field crops. Consult your processor before use.

WATER VOLUMESWinter oil seed rape, winter field beans, lucerne: Apply KERB FLO in 200 to 1000 litres of water per hectare.

Pome fruit, top and cane fruit [apple, blackcurrant, redcurrant, gooseberry, raspberry, loganberry, blackberry, pear, plum], forestry, forest nursery, outdoor woody ornamentals, Christmas trees, lettuce (outdoor), rhubarb (outdoor), strawberry (outdoor): Apply KERB FLO in 400 to 1000 litres of water per hectare.

Ensure good ground cover.

APPLICATION EQUIPMENTDo not apply through broadcast air-assisted sprayers.

All crops: Application may be made through a ground crop sprayer.

Forestry, forest nursery, outdoor woody ornamental, Christmas trees :KERB FLO may also be applied with a knapsack sprayer or the Micron Herbi CDA sprayer.

Knapsack applications: Add half the required amount of water to the knapsack. Shake the KERB FLO container vigorously and add the required amount to the knapsack, agitate the knapsack until the KERB FLO is fully dispersed. Top up the knapsack with the rest of the water and spray immediately, do not allow the mixture to stand.

Micro Herbi Application: Fit the Micron Herbi with the orange nozzle and the 0.19 inch OD breather tube. Any other size could result in uneven application. Add 375 ml KERB FLO to 625 ml of water in the spray bottle. Shake thoroughly to ensure all the product is in suspension. Then add 5 ml of an approved wetting agent and shake gently to ensure an even mixture.The Herbi applies a 1.2 metre band. To apply the recommended rate of KERB FLO, the operator should cover 10 metres in approximately 13 seconds with sprayer held at approximately 45° to the horizontal. Under very cold conditions (near 0°C) flow is improved by holding the sprayer head at 50° to the horizontal.

Where crosswinds occur allow for drift by moving the Herbi head to the windward side of the tree row.

3 litres of KERB FLO is sufficient to make 8 litres of suspension, which will treat 6,660 metres of tree line.


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CROP RECOMMENDATION TABLESS = Susceptible MS = Moderately susceptible MR = Moderately resistant R = Resistant

Crop Rate of Use Weed Species Stage of Weed Growth Time of Year Timing Stage of Crop

Soil Type(Soil Texture (85 System)

Germinating Up to 2 leaf

Established

Winter oilseed rape

2.1 litres/ha

Annualmeadow-grass,barren brome, volunteer cereals, wild-oat

S S S

1st

st October to

31 January

As soon as possible after 3rd true leaf stage.

Crop selectivity is by depth protection. Factors which cause shallow rootingmay reduce crop selectivity

All soils with less than 10% organic matter

Common chickweed S S S1

Black-grass S S MS2

Black-bindweed,black nightshade, fat-hen, knotgrass, redshank, small nettle, speedwells

S S MR

Field forget-me-not MS MS RCleavers MS MR R

1.25 litres/ha - Use this rate only where a specific graminicidehas controlled volunteercereals and grass weeds and chickweed is not a problem

Annualmeadow-grass,volunteer cereals, wild-oat

S S S

Black-bindweed,black nightshade, common chickweed, fat-hen, knotgrass, redshank, small nettle

S S R

Speedwells S R R

Winter field beans 2.1 litres/ha

Annualmeadow-grass,barren brome, common chickweed, volunteer cereals, wild-oat

S S S

1 October to 31 January

Within 7 days after drilling but before crop emerges

Use only on medium or heavy soils with less than 10% organic matter

Black-grass S S MSBlack-bindweed,black nightshade, fat-hen, knotgrass, redshank, small nettle, speedwells

S S MR

Cleavers MS MR R

st

st


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Germinating Up to 2 leaf Established

Pome frut, top/cane fruit [apple, blackcurrant blackberry, gooseberry, loganberry, pear, plum, raspberry, redcurrant], rhubarb (outdoor),

2.1 litres/ha

Black-grass S S MS

Rhubarb:1st October to 31st December

Other crops:1st October to 31st January

Established crops planted for at least 1 season


Annual meadow-grass, barren brome, common chickweed, volunteer cereals, wild-oat

S S S

Black-bindweed, black nightshade, fat-hen, knotgrass, redshank, small nettle, speedwells

S S MR

4.25 litres/ha

Annual meadow-grass, barren brome, black-grass, common chickweed, volunteer cereals, wild-oat

S S S

Common couch3 and other perennial grasses S S S


S S MS

Cleavers S S RCommon fumitory, shepherd’s-purse MS MS R

Creeping buttercup, broad-leaved dock, sheep’s sorrel

S MS MS

Field horsetail MS MS MS


Soil Type

(Soil Texture (85 System)

Strawberry (outdoor)

2.1 litres/ha

Black-grass S S MS

Strawberry:

1st October to 31st December

Strawberry:

Established crops planted for at least 1 year.

Strawberry:

Use only on heavy soils with less than 10% organic matter

Annual meadow-grass, barren brome, common chickweed, volunteer cereals, wild-oat

S S S

Black-bindweed, black nightshade, fat-hen, knotgrass, redshank, small nettle, speedwells§

S S MR

Strawberry:

(not matted row crops) 3.5 litres/ha

Common couch3 and other perennial grasses S S S

Cleavers S S RCommon fumitory, shepherd’s-purse MS MS R


S MS MS

Field horsetail MS MS MS§Controlled at the rate of 2.1litres/Ha except for established weeds which are MS at the higher rate of 3.5litres/Ha


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Crop type Rate of Use Weed Species Stage of Weed Growth Time of Year Timing Stage of

CropGerminating Up to 2 leaf Established

Lucerne 1.75 litres/ha

Black-grass S S MS

1st October to 31st January

Established crops grown for at least 1 season. Not less than 7 days after last cut.


Annualmeadow-grass, barren brome, commonchickweed, volunteer cereals, wild-oat

S S S


S S MR

Cleavers MS MR R

Lettuce (outdoor use only)

2.75-3.5litres/ha. Underdry soil conditionsor warm weather use 3.5 litres/ha and irrigateor incorporate

Annualmeadow-grass, barren brome, black-grass, commonchickweed, volunteer cereals, wild-oat

S S S

Any time up to 6 weeks before harvest

Before or after drilling


S S MS

Cleavers, common fumitory, shepherd’s-purse

MS MS R



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Crop Rate of use Weed species Stage of Weed Growth Time of Year Timing Stage of Crop

Soil Type (Soil Texture (85 System))

Germinating Up to 2 leaf Established

Christmas trees 3.75 litres/ha

Common bent, common couch, sweet vernal grass, tufted hair-grass, Yorkshire-fog and other perennial grasses

S S S


Forests:Any stage including

pre-planting

Nurseries:Treat no earlier than 1 month after transplanting

Forests:Any stage includingpre-planting

Nurseries:Treat no earlier than 1 month aftertransplanting

Mineral Soils(Surface water gleys, brown earths and sands). Use between 1st October and 31st December. (See also Time of Year).Peat Soils(Peaty gleys and peat soils with a depth of organic matter greater than 10 cm). Use between 1st October and 31st December (See also Time of Year).

Creeping soft-grass S S MSCock’s foot S S MRField horsetail MS MS MSSedges MS MS MSFoxglove, willowherbs

R R R

Forestry, forest nursery and outdoor woody ornamentals (see list of species under CROP INFORMATION),

2.1 litres/ha

Annual meadow-grass, barren brome, black-grass, common chickweed, volunteer cereals, wild-oat

S S S


Established crops planted for at least 1 season


Black-bindweed, black nightshade, fat-hen, knotgrass, redshank, small nettle, speedwells¥

S S MR

4.25 litres/ha

Common couch and other perennial grasses

S S S


S S MS

Cleavers S S RCommon fumitory, shepherd’s-purse

MS MS R


S MS MS

Field horsetail MS MS MS

¥Controlled at the rate of 2.1litres/Ha except for established weeds which are MS at the higher rate of 4.25 litres/Ha


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NOTES FOR CROP RECOMMENTATION TABLESa) Chickweed control may be reduced where it is well established (over 10 cm in diameter)b) CONTROL OF BLACKGRASS IN WINTER OILSEED RAPE: Established (well tillered) black grass is moderately susceptible: Where populations of black grass and/or

volunteer cereals exceed 50/m2 KERB FLO should be applied in a tank mix with an approved graminicide in accordance with the manufacturers recommendations, or following an effective approved graminicide to ensure optimum weed control.

Deeper germinating black grass within the soil profile could reduce product efficacy. Where partial resistance (R or RR) to the partner graminicide is known to exist the dose of KERB FLO may be

increased to 2.1 litres/ha. This may also be done if applications are made early in the season, under warm conditions and an increase in the duration of residual control is required (see Soil and Weather Conditions above).

Where high levels of resistance (RRR) to the partner graminicide occurs there is no advantage of adding this graminicide to KERB FLO for black grass control, and KERB FLO even at 2.1 litres/ha will not give acceptable levels of established black grass control in these circumstances.

R = 1* RR = 2*/3* RRR = 4*/5*

c) For heavy infestation of common couch a repeat application may be required the following winter. Avoid deep burying of rhizomes when preparing land prior to KERB FLO treatment.

Crop type Weed type Rate of Use

Weed Species Stage of Weed Growth Time of Year

Timing Stage of

CropGerminating Up to 2 leaf Established

All listed crops

Annual and perennial All rates

Common poppy, gallant soldier, groundsel, mayweed, scarlet pimpernel

R R R

Any time Any stage All soilsClover, dandelion, field bindweed, ragwort, thistle

R R R



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*Treated land must be mouldboard ploughed to a depth of 15 cm prior to drilling a following cereal, grass or any other crop not listed above.

Please consult Dow AgroSciences if a treated crop fails because of bad growing conditions.

MIXINGAdd half the required volume of water to the spray tank and begin agitation. Shake the container vigorously and add the recommended quantity of KERB FLO through the filter basket. When container becomes empty, wash out with water and add the washings through the filter basket. Rinse through the filter basket and add the rest of the water. Continue agitation while topping up the tank and whilst spraying.

Spray immediately: do not allow the mixture to stand.

Thoroughly wash all spraying equipment with water immediately after use.

COMPATIBILITYFor the latest advice on tank mixes please contact Dow AgroSciences or your distributor.

TRADEMARKSKERB is a trademark of Dow AgroSciences LLC.

Dow AgroSciences Conditions of SupplyAll goods supplied by us are of high grade and we believe them to be suitable but, as we cannot exercise control over their storage, handling, mixing or use, or the weather conditions before, during or after application which may affect the performance of the goods, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded. No responsibility will be accepted by us or re-sellers for any failure in performance, damage or injury whatsoever arising from their storage, handling, application or use. These conditions cannot be varied by our staff or agents whether or not they supervise or assist in the use of such goods.

FOLLOWING CROPS

The number of weeks which must elapse between the last application of KERB FLO and drilling or planting of the following crop is shown in the table below:Following crops Rate of KERB FLO applied to

previous cropDate KERB FLO applied to previous crop

1st April – 31st July 1st August – 31st MarchLettuce 1.75-4.25 litres/ha 0 weeks 0 weeksField beans, broad beans, peas, chicory, radish, clover, lucerne 1.75-4.25 litres/ha 5 weeks 10 weeks

Brassicas, leeks, onions , parsley, parsnips, celery, oilseed rape, strawberries

1.75-4.25 litres/ha 10 weeks25 weeks or plant/sow

after 15th June whichever occurs sooner

Cereals and grasses4 1.75-2.1 litres/ha 30 weeks2.75-4.25 litres/ha 40 weeks

40 weeks40 weeks

Any other crop4 2.75-4.25 litres/ha 20 weeks 40 weeks


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Safety Data SheetThis Safety Data Sheet does not form part of the approved product label.

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING1.1 Product identifierProduct name: Kerb Flo 400 Herbicide

1.2 Relevant identified uses of the substance or mixture and uses advised againstIdentified uses: Plant Protection Product

1.3 Details of the supplier of the safety data sheetCOMPANY IDENTIFICATIONDOW AGROSCIENCES LIMITEDLATCHMORE COURTBRAND STREETHITCHINEnglandSG5 1NHUNITED KINGDOM

Customer Information Number: [email protected]

1.4 EMERGENCY TELEPHONE NUMBER24-Hour Emergency Contact: 00 31 115 694 982Local Emergency Contact: 00 31 115 694 982

SECTION 2. HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008:Carcinogenicity - Category 2 - H351Chronic aquatic toxicity - Category 1 - H410For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008:

Hazard pictograms

Signal word: WARNING


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Hazard statementsH351 Suspected of causing cancer.H410 Very toxic to aquatic life with long lasting effects.Precautionary statementsP202 Do not handle until all safety precautions have been read and understood.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P308 + P311 IF exposed or concerned: Call a POISON CENTRE or doctor/ physician.P391 Collect spillage.P501 Dispose of contents/container to a licensed waste disposal contractor or collection site except for

empty clean triple rinsed containers which can be disposed of as non-hazardous waste.Supplemental informationEUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Contains propyzamide (ISO)

2.3 Other hazardsNo data available

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS3.2 Mixtures

This product is a mixture.

CASRN / EC-No. /

Index-No.

REACH Registration Number Concentration Component

Classification:REGULATION (EC) No 1272/2008

CASRN23950-58-5

EC-No.245-951-4Index-No.

616-055-00-4

_ 35.1% propyzamide (ISO) Carc. - 2 - H351Aquatic Acute - 1 - H400Aquatic Chronic - 1 - H410

CASRN107-21-1EC-No.

203-473-3Index-No.

603-027-00-1

01-2119456816-28 < 5.0 % Ethanediol; ethylene glycol

Acute Tox. - 4 - H302STOT RE - 2 - H373

If present in this product, any not classified components disclosed above for which no country specific OEL value(s) is(are) indicated under Section 8, are being disclosed as voluntarily disclosed components.For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4. FIRST AID MEASURES4.1 Description of first aid measuresGeneral advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: No emergency medical treatment necessary.

Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. Suitable emergency safety shower facility should be available in work area.


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Eye contact: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control centre or doctor for treatment advice. Suitable emergency eye wash facility should be available in work area.

Ingestion: No emergency medical treatment necessary.

4.2 Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.

4.3 Indication of any immediate medical attention and special treatment neededNotes to physician: No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Have the Safety Data Sheet, and if available, the product container or label with you when calling a poison control centre or doctor, or going for treatment.

SECTION 5. FIREFIGHTING MEASURES5.1 Extinguishing mediaSuitable extinguishing media: To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam.

Unsuitable extinguishing media: No data available

5.2 Special hazards arising from the substance or mixtureHazardous combustion products: Under fire conditions some components of this product may decompose. The smoke may contain unidentified toxic and/or irritating compounds. Combustion products may include and are not limited to: Nitrogen oxides. Hydrogen chloride. Carbon monoxide. Carbon dioxide.

Unusual Fire and Explosion Hazards: This material will not burn until the water has evaporated. Residue can burn.

5.3 Advice for firefightersFire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. To extinguish combustible residues of this product use water fog, carbon dioxide, dry chemical or foam. Contain fire water run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the “Accidental Release Measures” and the “Ecological Information” sections of this (M)SDS.

Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance.

SECTION 6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures: Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

6.2 Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

6.3 Methods and materials for containment and cleaning up: Contain spilled material if possible. Small spills: Absorb with materials such as: Clay. Dirt. Sand. Sweep up. Collect in suitable and properly labeled containers. Large spills: Contact Dow AgroSciences for clean-up assistance. See Section 13, Disposal Considerations, for additional information.

6.4 Reference to other sections: References to other sections, if applicable, have been provided in the previous sub-sections.


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SECTION 7. HANDLING AND STORAGE7.1 Precautions for safe handling: Keep out of reach of children. Do not swallow. Avoid contact with eyes, skin, and clothing. Avoid breathing vapour or mist. Wash thoroughly after handling. Use with adequate ventilation. Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION.

7.2 Conditions for safe storage, including any incompatibilities: Store in a dry place. Store in original container. Keep container tightly closed when not in use. Do not store near food, foodstuffs, drugs or potable water supplies.

7.3 Specific end use(s): Refer to product label.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parametersExposure limits are listed below, if they exist.

Component Regulation Type of listing Value/NotationEthanediol; ethylene glycol ACGIH C Aerosol only 100 mg/m3

Dow IHG TWA 50 mg/m3 Dow IHG STEL 100 mg/m3

2000/39/EC TWA 52 mg/m3 20 ppm2000/39/EC STEL 104 mg/m3 40 ppm2000/39/EC TWA Absorbed via skin2000/39/EC STEL Absorbed via skin

IE OEL OELV - 8 hrs (TWA) particles 10 mg/m3 IE OEL OELV - 15 min (STEL) Vapour 104 mg/m3 40 ppmIE OEL OELV - 8 hrs (TWA) Vapour 52 mg/m3 20 ppmIE OEL OELV - 8 hrs (TWA) Absorbed via skinIE OEL OELV - 15 min (STEL) Absorbed via skinIE OEL OELV - 8 hrs (TWA) Absorbed via skin

RECOMMENDATIONS IN THIS SECTION ARE FOR MANUFACTURING, COMMERCIAL BLENDING AND PACKAGING WORKERS. APPLICATORS AND HANDLERS SHOULD SEE THE PRODUCT LABEL FOR PROPER PERSONAL PROTECTIVE EQUIPMENT AND CLOTHING.8.2 Exposure controlsEngineering controls: Use local exhaust ventilation, or other engineering controls to maintain airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, general ventilation should be sufficient for most operations.

Individual protection measuresEye/face protection: Use safety glasses (with side shields). Safety glasses (with side shields) should be consistent with EN 166 or equivalent. Skin protection

Hand protection: Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate (“EVAL”). Examples of acceptable glove barrier materials include: Natural rubber (“latex”). Neoprene. Nitrile/butadiene rubber (“nitrile” or “NBR”). Polyvinyl chloride (“PVC” or “vinyl”). Viton. When prolonged or frequently repeated contact may occur, a glove with a protection class of 4 or higher (breakthrough time greater than 120 minutes according to EN 374) is recommended.


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When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended. NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Respiratory protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or discomfort have been experienced, or where indicated by your risk assessment process. For most conditions no respiratory protection should be needed; however, if discomfort is experienced, use an approved air-purifying respirator. Use the following CE approved air-purifying respirator: Organic vapour cartridge with a particulate pre-filter, type AP2.

Environmental exposure controlsSee SECTION 7: Handling and storage and SECTION 13: Disposal considerations for measures to prevent excessive environmental exposure during use and waste disposal.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesAppearance

Physical state Liquid. Colour Tan

Odour Mild Odour Threshold No test data available pH 7.91 1% pH Electrode (1% aqueous suspension)Melting point/range Not applicableFreezing point -20 °C Boiling point (760 mmHg) No test data availableFlash point closed cup > 100 °C Closed Cup Evaporation Rate (Butyl Acetate = 1) No test data availableFlammability (solid, gas) Not ApplicableLower explosion limit No test data available Upper explosion limit No test data available Vapour Pressure No test data availableRelative Vapour Density (air = 1) No test data available Relative Density (water = 1) No test data available Water solubility No test data available Partition coefficient: n-octanol/water No data availableAuto-ignition temperature > 400 °C Decomposition temperature No test data available Dynamic Viscosity No test data availableKinematic Viscosity No data availableExplosive properties No Oxidizing properties No, No significant increase (>5C) in temperature.


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9.2 Other informationLiquid Density 1.133 g/cm3 at 20 °C Digital density meter Molecular weight No data availableSurface tension 61.5 mN/m at25 °C EC Method A5

NOTE: The physical data presented above are typical values and should not be construed as a specification.

SECTION 10. STABILITY AND REACTIVITY10.1 Reactivity: No dangerous reaction known under conditions of normal use.

10.2 Chemical stability: Thermally stable at typical use temperatures.

10.3 Possibility of hazardous reactions: Polymerization will not occur.

10.4 Conditions to avoid: Some components of this product can decompose at elevated temperatures.

10.5 Incompatible materials: Avoid contact with: Strong oxidizers.

10.6 Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Hydrogen chloride. Nitrogen oxides.

SECTION 11. TOXICOLOGICAL INFORMATIONToxicological information appears in this section when such data is available.

11.1 Information on toxicological effectsAcute toxicity

Acute oral toxicityVery low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.

As product: LD50, Rat, female, > 5,000 mg/kg

Acute dermal toxicityProlonged skin contact is unlikely to result in absorption of harmful amounts.

As product: LD50, Rat, male and female, > 5,000 mg/kg

Acute inhalation toxicityNo adverse effects are anticipated from inhalation. Based on the available data, respiratory irritation was not observed.

As product: LC50, Rat, male and female, 4 Hour, Aerosol, > 5.19 mg/l

Skin corrosion/irritationBrief contact may cause slight skin irritation with local redness.

Serious eye damage/eye irritation

Corneal injury is unlikely.May cause slight temporary eye irritation.

SensitizationDid not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:No relevant data found.


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Specific Target Organ Systemic Toxicity (Single Exposure)Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Specific Target Organ Systemic Toxicity (Repeated Exposure)For the active ingredient(s):In animals, effects have been reported on the following organs:Adrenal gland.Kidney.Liver.Ovaries.Pancreas.Thyroid.

For the minor component(s):Observations in humans include:Nystagmus (involuntary eye movement).In animals, effects have been reported on the following organs:Kidney.Liver.

CarcinogenicityFor the active ingredient(s): Has caused cancer in laboratory animals.

TeratogenicityFor the active ingredient(s): Has been toxic to the foetus in laboratory animals at doses toxic to the mother. Did not cause birth defects in laboratory animals.

Based on animal studies, ingestion of very large amounts of ethylene glycol appears to be the major and possibly only route of exposure to produce birth defects. Exposures by inhalation or skin contact, the primary routes of occupational exposure, had minimal effect on the fetus, in animal studies.

Reproductive toxicityFor the active ingredient(s): In laboratory animal studies, effects on reproduction have been seen only at doses that produced significant toxicity to the parent animals.

Ingestion of large amounts of ethylene glycol has been shown to interfere with reproduction in animals.

MutagenicityFor the active ingredient(s): In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.

Aspiration HazardBased on available information, aspiration hazard could not be determined.

SECTION 12. ECOLOGICAL INFORMATIONEcotoxicological information appears in this section when such data is available.

12.1 ToxicityAcute toxicity to fishMaterial is harmful to aquatic organisms (LC50/EC50/IC50 between 10 and 100 mg/L in the most sensitive species).

LC50, Oncorhynchus mykiss (rainbow trout), flow-through test, 96 Hour, 53.6 mg/l, OECD Test Guideline 203

Acute toxicity to aquatic invertebratesEC50, Daphnia magna (Water flea), flow-through test, 48 Hour, > 99.2 mg/l, OECD Test Guideline 202


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Acute toxicity to algae/aquatic plantsErC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate inhibition, 10.4 mg/l

Toxicity to bacteriaNOEC, activated sludge, Respiration inhibition, 3 Hour, > 100 mg/l

Toxicity to Above Ground Organismsoral LD50, Apis mellifera (bees), 48 Hour, mortality, > 100µg/bee

contact LD50, Apis mellifera (bees), 48 Hour, mortality, > 100µg/bee

Toxicity to soil-dwelling organismsLC50, Eisenia fetida (earthworms), 14 d, > 10,000 mg/kg

NOEC, Eisenia fetida (earthworms), 28 d, 92.2 mg/kg

12.2 Persistence and degradability

propyzamide (ISO)Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen). No data available Stability in Water (1/2-life)Hydrolysis, pH 5 - 9, Stable

Ethanediol; ethylene glycolBiodegradability: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). 10-day Window: Pass Biodegradation: 90 - 100 % Exposure time: 10 d Method: OECD Test Guideline 301A or Equivalent 10-day Window: Not applicable Biodegradation: 90 % Exposure time: 1 d Method: OECD Test Guideline 302B or Equivalent

12.3 Bioaccumulative potential

propyzamide (ISO)Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 3 Bioconcentration factor (BCF): 49 Lepomis macrochirus (Bluegill sunfish)

Ethanediol; ethylene glycolBioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): -1.36 Measured

12.4 Mobility in soil

propyzamide (ISO)Potential for mobility in soil is low (Koc between 500 and 2000).Partition coefficient(Koc): 840 Measured

Ethanediol; ethylene glycolGiven its very low Henry’s constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process.Potential for mobility in soil is very high (Koc between 0 and 50).Partition coefficient(Koc): 1 Estimated.


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12.5 Results of PBT and vPvB assessment

propyzamide (ISO)This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

Ethanediol; ethylene glycolThis substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

12.6 Other adverse effects

propyzamide (ISO)This substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

Ethanediol; ethylene glycolThis substance is not in Annex I of Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

SECTION 13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methodsIf wastes and/or containers cannot be disposed of according to the product label directions, disposal of this material must be in accordance with your local or area regulatory authorities. This information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. If the material as supplied becomes a waste, follow all applicable regional, national and local laws.

The definitive assignment of this material to the appropriate EWC group and thus its proper EWC code will depend on the use that is made of this material. Contact the authorized waste disposal services.

SECTION 14. TRANSPORT INFORMATIONClassification for ROAD and Rail transport (ADR/RID):14.1 UN number UN 308214.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(Propyzamide)14.3 Class 914.4 Packing group III14.5 Environmental hazards Propyzamide14.6 Special precautions for user Hazard Identification Number: 90

Classification for SEA transport (IMO-IMDG):14.1 UN number UN 308214.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.(Propyzamide)14.3 Class 914.4 Packing group III14.5 Environmental hazards Propyzamide14.6 Special precautions for user EmS: F-A, S-F14.7 Transport in bulk according to

Annex I or II of MARPOL 73/78 and the IBC or IGC Code

Consult IMO regulations before transporting ocean bulk


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Classification for AIR transport (IATA/ICAO):14.1 UN number UN 308214.2 Proper shipping name Environmentally hazardous substance, liquid, n.o.s.(Propyzamide)14.3 Class 914.4 Packing group III14.5 Environmental hazards Not applicable14.6 Special precautions for user No data available.

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.

SECTION 15. REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACh Regulation (EC) No 1907/2006This product contains only components that have been either pre-registered, registered, are exempt from registration or are regarded as registered according to Regulation (EC) No. 1907/2006 (REACH)., The aforementioned indications of the REACH registration status are provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. It is the buyer´s/user´s responsibility to ensure that his/her understanding of the regulatory status of this product is correct.

Seveso II - Directive 96/82/EC and its amendments:Listed in Regulation: Directive 96/82/EC does not apply

Other regulationsRegistration Number: PCS No. 02830

15.2 Chemical Safety AssessmentFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.

SECTION 16. OTHER INFORMATIONFull text of H-Statements referred to under sections 2 and 3.H302 Harmful if swallowed.H351 Suspected of causing cancer.H373 May cause damage to organs through prolonged or repeated exposure if swallowed.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) No 1272/2008Carc. - 2 - H351 - Calculation methodAquatic Chronic - 1 - H410 - Calculation method

RevisionIdentification Number: 101189906 / A293 DAS Code: GF-1197Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.


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Legend2000/39/EC Europe. Commission Directive 2000/39/EC establishing a first list of indicative

occupational exposure limit valuesAbsorbed via skin Absorbed via skinACGIH USA. ACGIH Threshold Limit Values (TLV)C Ceiling limitDow IHG Dow Industrial Hygiene GuidelineIE OEL Ireland. List of Chemical Agents and Occupational Exposure Limit Values - Schedule 1OELV - 15 min (STEL) Occupational exposure limit value (15-minute reference period)OELV - 8 hrs (TWA) Occupational exposure limit value (8-hour reference period)STEL Short term exposure limitTWA Time weighted average

Information Source and ReferencesThis SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company.

DOW AGROSCIENCES LIMITED urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.


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H

A residual herbicide for the control of a wide range of weeds in WINTER OILSEED RAPE and several other AGRICULTURAL, HORTICULTURAL and in FORESTRY and AMENITY situations.A suspension concentrate containing 400 g/litre (35.3% w/w) propyzamide.

SAFETY PRECAUTIONSEngineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment:WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE PROTECTIVE GLOVES when handling the concentrate or contaminated surfaces.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) when applying by vehicle-mounted or trailed equipment.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES AND RUBBER BOOTS when applying by hand-held equipment.WASH HANDS AND EXPOSED SKIN before meals and after work.

Environmental protection:Do not contaminate water with the product or its container.Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.Do not contaminate ponds, waterways or ditches with chemical or used container.Storage and disposal:STORE IN ORIGINAL CONTAINER, tightly closed, in a safe place.EMPTY CONTAINER COMPLETELY and dispose of safely.Do not re-use container for any other purpose.

READ DIRECTION FOR USE ON ATTACHED LEAFLET.SHAKE WELL BEFORE USEPROTECT FROM FROST

FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY HERBICIDE

5 Litres®Trademark of the Dow Chemical Company ("Dow") or an affiliated company of Dow

T.P.WHELEHAN Son and Company LtdSuite 12 Bunkilla Plaza,Bracetown Business Park,Clonee, Co Meath+353 1 83 422 33

Distributed by:

PROVID

ING

TRAC

EABILITY WITH

PATENTED

TECHNOLOGY

TRIPLE RINSE CONTAINER, PUNCTURE AND INVERT TO DRY AT TIME OF USERegistered by:Dow AgroSciences LimitedLatchmore Court, Brand Street, Hitchin, Hertfordshire. SG5 1NH.Telephone: +44(0)1462 457272Fax: +44(0)1462 42660524 Hour Emergency Telephone Number: +44 (0) 1553 761 251

IMPORTANT INFORMATION.FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/FORESTRY/ HERBICIDECrops/Situations: Oilseed rape (winter), field bean

(winter), Pome fruit, top/cane fruit (see full details in the Important Information Area on the attached leaflet), strawberry (outdoor use only), lettuce (outdoor use only), lucerne, rhubarb (outdoor use only), forest, forest nursery, outdoor woody ornamentals, Christmas trees

Maximum Individual Dose: }Maximum Number of Treatments: } Full details are given in the Important Information Latest Time of Application: } Area on the attached leafletOther Specific Restrictions: }This product may only be applied to edible crops except lettuce between 1st October and the specified latest time of application.Do not harvest crops for human or animal consumption for at least 6 weeks after last application.READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

PROFESSIONAL USE ONLY

Kerb®

FLO

HERBICIDE


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Propyzamide Warning SPECIMEN DATE...Add 375 ml KERB FLO to 625 ml of water in the spray bottle....

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