Properties Data Bank
-
Upload
imran-azman -
Category
Documents
-
view
213 -
download
0
Transcript of Properties Data Bank
-
8/19/2019 Properties Data Bank
1/14
Properties Data Bank
• Heat Capacities of Inorganic and Organic Liquid
• Heat Capacities of Inorganic and Organic Compounds in Ideal Gas State
• Heat of Vaporization of Inorganic and Organic Compounds
• Standard Heat of Formation of Inorganic and Organic Compounds
• Saturation Pressure of Inorganic and Organic Compounds
• Molecular Weigt of Inorganic and Organic Compounds
!e properties data of
• Heat Capacities of Inorganic and Organic Compounds in Ideal Gas State
• Heat of Vaporization of Inorganic and Organic Compounds
• Molecular Weigt of Inorganic and Organic Compounds
"ere o#tained from Perr$%s Cemical &ngineers% Hand#oo'( Se)ent &dition *+,
!e properties data of
• Heat Capacities of Inorganic and Organic Liquid
-
8/19/2019 Properties Data Bank
2/14
• Heat Capacities of Inorganic and Organic Liquid
Assumptions
1. 0ata of i3C4H+5 "as represented #$ /3Met$lpropane
/. 0ata of C4H6 "as represented #$ cis3/37utene
2. 0ata of i3C8H+/ "as represented #$ /3Met$l#utane4. 0ata of C8H+5 "as represented #$ +3Pentene
8. 0ata of i3C9H+4 "as represented #$ /3Met$lpentane9. 0ata of C9H+/ "as represented #$ +3He:ene
;. 0ata of i3C;H+9 "as represented #$ /(2(30imet$lpentane6. 0ata of i3C6H+6 "as represented #$ /(2(23!rimet$lpentane
-
8/19/2019 Properties Data Bank
3/14
Heat Capacities of Inorganic and Organic Liquid
Component A B C D
CO/ 32.265/ 8./;55 3/.2/;
-
8/19/2019 Properties Data Bank
4/14
Component A B C D
n3C6H+6 6./;29&>5+ +.2542&>55 32.6/84&352 4.9485/ ;.;99+&35+ 3/.2//4&352 2.+954&359
=$lene C6H+5 ;.55+ 6.5485&35+ 3/.+668&352 /.859+&359&t$l7enzene C6H+5 +.5/++&>5/ 8.8
-
8/19/2019 Properties Data Bank
5/14
Heat Capacities of Inorganic and Organic Compounds in the Ideal as !tate
Component C1 C" C# C$ C%
CO/ /.54 2.4845&>54 +.4/65&>52 /.9455&>54 866.5555
?/ /.54 6.9+55&>52 +.;5+9&>52 +.5555&>5/ 52 6.52 ++952 2.568+&>52 6.4955&>52 +826./555
H/ /.;9/5&>54 52 /.4995&>52 2.;955&>52 89;.9555
CH2OCH2 6.9/+5&>54 /.88+5&>58 +.84+2&>52 +.42;5&>58 3966.54 654 ;.54 52 ;.2//5&>54 ;8/.6;55
C/H4 2.2265&>54 54 ;45.6555
C2H6 8.+54 +.58 +.9/98&>52 +.+965&>58 ;/2.9555
C2H9 4.2254 +.8/55&>58 +.4/85&>52 ;.6955&>54 9/2.54 /.4255&>58 +.9255&>52 +.8522&>58 ;25.4/55
i3C4H+5 9.8454 /.4;;9&>58 +.86;5&>52 +.8;85&>58 3;59.58 +.9/58 ;254 2.5++5&>58 +.985/&>52 +.658 ;4;.9555
i3C8H+/ ;.4955&>54 2./985&>58 +.8485&>52 +.58 999.;555
C8H+5 ;.854 /.88/8&>58 +.86/5&>52 +.9995&>58 ;+2.5555
C$clo3C8H+5 4.+955&>54 2.5+45&>58 +.49+;&>52 +.6558 3996.6555
n3C9H+4 +.5445&>58 2.8/25&>58 +.952 /.2958 ;9+.9555
i3C9H+4 54 2.65+5&>58 +.95/5&>52 /.4825&>58 3958 +.8;4/&>52 /.52/5&>58 ;+8.5555
7enzene C9H9 4.44/5&>54 /.2/58&>58 +.452 +.;/+2&>58 39;6.+855
C$clo3C9H+/ 4.2/55&>54 2.;285&>58 +.+52 +.9285&>58 3825.+555
n3C;H+9 +./5+8&>58 4.55+5&>58 +.9;99&>52 /.;455&>58 ;89.4555
i3C;H+9 6.8445&>54 4.8;;/&>58 +.8+6+&>52 /.58 94+.5+55
!oluene C;H6 8.6+45&>54 /.6925&>58 +.4459&>52 +.658 3985.4255
-
8/19/2019 Properties Data Bank
6/14
&quation@ Cp ABmol DE
(C 5
T )/ cosh (
C 5
T )¿2
(C 3
T )/ sinh (
C 3
T )¿2+C 4 ¿
C 1+C 2¿
Component C1 C" C# C$ C%
n3C6H+6 +.2884&>58 4.42+5&>58 +.9289&>52 2.5845&>58 ;49.4555
i3C6H+6 54 8.45/5&>58 +.82+5&>52 2.458 9258 39;8.54 2.258 3;5/.5555
n3C58 4.58 +.9446&>52 2.4;55&>58 ;452 /.258 9;6.2555
+3/343!rimet$l37enzene
C58 2.62+4&>58 +.85+5&>52 /.258 9;6.2555
+32383!rimet$l37enzene
C58 +.9+4+&>52 2.;6/5&>58 ;4/.5555
i3C+5H// 3 3 3 3 3
?aptalene
C+5H6
9.6585&>54 2.8458 +.4/9/&>52 /.858 985.+555
0urene +3/34383!etramet$l3
7enzene C+5H+4
+.2+69&>58 4.2529&>58 +.;;24&>52 2./8;5&>58 6++.58 4.2529&>58 +.;;24&>52 2./8;5&>58 6++.58 4.2529&>58 +.;;24&>52 2./8;5&>58 6++.
-
8/19/2019 Properties Data Bank
7/14
n3C++H/4 +.
-
8/19/2019 Properties Data Bank
8/14
Heat of &apori'ation of Inorganic and Organic Compounds
&quation@ H)ap AB'molE AC+EA+3!rE*C/>AC2EA!rE>AC4EA!rEA!rE,
( !r!!c
Component C1 C" C# C$ (c
CO/ /+;25555 5.26/5 35.422< 5.4//+ 254./+
?/ ;4
-
8/19/2019 Properties Data Bank
9/14
Component C1 C" C# C$ (c
n3C6H+6 88+65555 5.264; 5.5555 5.5555 896.;5
i3C6H+6 4
-
8/19/2019 Properties Data Bank
10/14
!tandard Heat of )ormation of Inorganic and Organic Compounds
Table x: Heat of #ormation of Inorganic and Organic Compounds
-
8/19/2019 Properties Data Bank
11/14
!aturation Pressure of Inorganic and Organic Compounds
Component *Hf+",-
/k0mol2
Component *Hf+",-
/k0mol2
CO/ 32.5/ n3C6H+6 3/.5665&>5/
?/ 5.5555&>55 i3C6H+6 3/.+685&>5/
H/O 3/.4+65&>5/ =$lene C6H+5 +.;255&>5+CO 3+.+585&>5/ &t$l7enzene C6H+5 /.55 n3C5/ i3C5+ +3/343!rimet$l37enzene C5+
C/H9 36.2655&>5+ +32383!rimet$l37enzene C5+
C/H4 8./855&>5+ n3C+5H// 3/.45/
C2H6 3+.54;5&>5/ i3C+5H// 3
C2H9 +.5+ ?aptalene C+5H6 +.8595&>5/
n3C4H+5 3+./965&>5/ 0urene +3/34383!etramet$l37enzene C+5H+4 34.4895&>5+
i3C4H+5 3+.2855&>5/ Iso0urene +3/32383!etramet$l37enzene C+5H+4 34.4;55&>5+C4H6 3;.4555&>55 Prenitene +3/32343!etramet$l37enzene C+5H+4 34.+655&>5+
n3C8H+/ 3+.4965&>5/ n3C++H/4 3/.;542&>5/
i3C8H+/ 3+.82;5&>5/
C8H+5 3/.+255&>5+
C$clo3C8H+5 3;.;+55&>5+
n3C9H+4 3+.995/
i3C9H+4 3+.82;5&>5/
C9H+/ 34./555&>5+
7enzene C9H9 6./5+
C$clo3C9H+/ 3+./245&>5/
n3C;H+9 3+.6;65&>5/
i3C;H+9 3+.5/
!oluene C;H6 8.5/55&>5+
-
8/19/2019 Properties Data Bank
12/14
Component A B C D 3 )
CO/ +22.9/55 34;28.5555 5.5555 3/+./9;5 5.545< +.5555
?/ 28.4++2 3
-
8/19/2019 Properties Data Bank
13/14
n3C6H+6 69.
-
8/19/2019 Properties Data Bank
14/14
4olecular 5eight of Inorganic and Organic Compounds
Table x: %olecular &eight of Inorganic and Organic Compounds
Component 45 /gmol2 Component 45 /gmol2
CO/ 44.5+55 n3C6H+6 ++4./2+5
?/ /6.5+45 i3C6H+6 ++4./2+5
H/O +6.5+85 =$lene C6H+5 +59.+9;5
CO /6.5+55 &t$l7enzene C6H+5 +59.+9;5H/ /.5+95 n3C