L1007652 IREL/02T PPE 4049091 04462014

Product registration number: MAPP 16450; PCS No. 04816.

QUILT XCEL is a suspo-emulsion formulation containing 141.4 g/l azoxystrobin and 122.4 g/l propiconazole.

For useful reduction of Eyespot (Kabatiella Zeae) and leaf blight (Helminthosporium spp) in maize for grain and forage.

The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. (UK only).

FOR PROFESSIONAL USE ONLYTo avoid risks to human health and the environment comply with the instructions for use.A suspo-emulsion containing 141.4 g/l azoxystrobin and 122.4 g/l propiconazole.

Warning.Harmful if swallowed.Causes serious eye irritation.Harmful if inhaled.Very toxic to aquatic life with long lasting effects.Keep out of reach of childrenAvoid breathing dust/fume/gas/mist/vapours/spray.Wear eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Call a POISON CENTRE or doctor/ physician if you feel unwell.If eye irritation persists: Get medical advice/ attention. Collect spillage.Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.Contains propiconazole. May produce an allergic reaction.

MAPP 16450 PCS No . 04816

In case of toxic or transport emergency ring +44 (0) 1484 538444 any time.

PROTECT FROM FROST. SHAKE WELL BEFORE USE.

© Syngenta AG, 2015

5 litresProduct names marked ® or ™ , the ALLIANCE FRAMEthe SYNGENTA Logo and the PURPOSE ICON are Trademarks of a Syngenta Group Company

This product label is compliant with the CPA Voluntary Initiative (VI) guidance. (UK only)

Authorisation Holder & UK Marketing Company Marketing CompanySyngenta UK LtdCPC4, Capital Park, Fulbourn, Cambridge, CB21 5XETel: +44 (0)1223 883400

Syngenta Ireland LimitedBlock 6, Cleaboy Business Park, Old Kilmeaden Road, WaterfordTel: (051) 377203

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L1007653 IREL/02T PPE 4049093 04462014

QUILT XCEL

SAFETY PRECAUTIONS(a) Operator protection (COSHH applies to the UK only).Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment:WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD when handling the concentrate.WEAR SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces.However, engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal or higher standard of protectionWASH CONCENTRATE from skin and eyes immediately.DO NOT BREATHE SPRAY.WASH SPLASHES from skin or eyes immediately.WASH HANDS AND EXPOSED SKIN before eating, drinking or smoking and after work.

(b) Environmental protection Do not contaminate water with product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.

(c) Storage and disposalKEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.DO NOT RE-USE CONTAINER for any purpose.RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of safely.

IMPORTANT INFORMATIONFOR USE ONLY AS AN AGRICULTURAL FUNGICIDE

For use on:

Crops Maximum individual dose (litre product/ha)

Maximum number of treatments (per crop)

Latest time of application

Maize for grain and forage

1 1Before BBCH 69 (end of flowering)

READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

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This leaflet is part of the approved Product Label.

DIRECTIONS FOR USE

IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be carefully read in order to obtain safe and successful use of this product.

GENERAL INFORMATIONQUILT XCEL contains the strobilurin fungicide azoxystrobin (Qol) and the triazole (DMI) propiconazole.

Azoxystrobin and other strobilurin analogues inhibit fungal respiration.

Propiconazole is a triazole (DMI) fungicide. Propiconazole is a systemic fungicide with protectant and curative properties.

QUILT XCEL shows good crop safety and is best used as a protectant treatment or in the earliest stages of disease development. RESTRICTIONSCertain apple varieties are highly sensitive to azoxystrobin. As a precaution QUILT XCEL should not be applied when there is a risk of spray drift onto neighbouring apple crops. Spray equipment used to apply QUILT XCEL to other crops should not be used to treat apples.

CROPS AND GROWING CONDITIONSFor use on maize for grain and forage. Apply QUILT XCEL under good growing conditions with adequate soil moisture. Avoid poor growing conditions which may give less reliable results.

DISEASE CONTROLLEDEyespot (Kabatiella Zeae) - USEFUL REDUCTIONLeaf blight (Helminthosporium spp.) - USEFUL REDUCTION

RATE OF USEApply QUILT XCEL at 1 Litre of product per hectare.

TIMINGThe onset, occurrence and severity of these diseases is difficult to predict. It is recommended to only treat sites that have a known history of disease when conditions are conducive for disease development and to consult with a specialist maize agronomist before application.

Always inspect crops to assess disease development immediately before spraying. QUILT XCEL should be applied in the earliest stages of disease development at any time from the beginning of stem elongation (BBCH 30) up until the end of flowering (BBCH 69). Only one application should be made to any one crop.

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APPLICATION

Spray QualityApply QUILT XCEL using a conventional fan nozzle producing a medium spray quality at as defined by the British Crop Protection Council. A spray pressure of 2-3 bars is recommended.

Spray VolumeQUILT XCEL is recommended to be applied in a water volume of 200-600 litres of water per hectare through conventional crop spraying equipment.

Mixing and SprayingMake sure the sprayer is set to give an even application at the correct volume.

Fill the spray tank with half the required volume of clean water and start agitation. Add the required amount of QUILT XCEL to the spray tank and continue agitatation whilst adding the rest of the water .

Agitate the mixture thoroughly before use and continue agitation during spraying. Thoroughly wash all spray equipment with water immediately after use.

Wash out containers thoroughly, preferably using an integrated pressure rinsing device, or manually rinse three times. Add washings to the sprayer at the time of filling. Complete filling to the required volume and continue to agitate throughout the spraying operation.

After SprayingDo not leave the spray liquid in the sprayer for long periods (such as during meal breaks or overnight).

Thoroughly wash out sprayer according to manufacturer’s guidelines and dispose of washings and clean containers according to DEFRA Code of Practice and local water authority guidelines.

RESISTANCE MANAGEMENT Do not apply in highly curative situations.You must not apply more than two foliar applications of Qol containing products to any maize crop.

In order to minimise the likelihood of the development and spread of resistance, the following guidelines should be followed:

1. Use a full dose rate and avoid using QUILT XCEL as a highly curative application.2. Useage of partly resistant varieties or other cultural means, including where appropriate other fungicides with a different mode of action can reduce the disease pressure and therefore the selection of resistant isolates

Further information on resistance management strategies is available from the FRAG website.

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COMPANY INFORMATIONSince the occurrence of resistance cannot be forecast, neither Syngenta UK Limited nor its distributors can accept responsiblity for any loss or damage to crops by the failure of QUILT XCEL to control resistant strains.

This product is to be used only in accordance with the recommendations and instructions given on the labels provided with this pack.

Product registration number: MAPP 16450; PCS No. 04816

QUILT XCEL is a suspo-emulsion formulation containing 141.4 g/l azoxystrobin and 122.4 g/l propiconazole.

For useful reduction of Eyespot (Kabatiella Zeae) and leaf blight (Helminthosporium spp) in maize for grain and forage.

FOR PROFESSIONAL USE ONLYTo avoid risks to human health and the environment comply with the instructions for use.A suspo-emulsion containing 141.4 g/l azoxystrobin and 122.4 g/l propiconazole.

Warning

Harmful if swallowed.Causes serious eye irritation.Harmful if inhaled.Very toxic to aquatic life with long lasting effects.

Keep out of reach of childrenAvoid breathing dust/fume/gas/mist/vapours/spray.Wear eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Call a POISON CENTRE or doctor/ physician if you feel unwell.If eye irritation persists: Get medical advice/ attention. Collect spillage.Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.

Contains propiconazole. May produce an allergic reaction.MAPP 16450; PCS No. 04816

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The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work (UK only).

Authorisation Holder & UK Marketing Company Marketing Company

Syngenta UK LimitedCPC 4, Capital Park, FulbournCambridge CB21 5XETel: +44 (0) 1223 883400

Syngenta Ireland Ltd., Block 6, Cleaboy Business Park, Old Kilmeaden Road, WaterfordTel: (051) 377203

In case of toxic or transport emergency ring +44(0)1484 538444 any time.

© Syngenta AG, 2015.

PROTECT FROM FROSTSHAKE WELL BEFORE USE

Product names marked ® or ™ , the ALLIANCE FRAMEthe SYNGENTA Logo and the PURPOSE ICON are Trademarks of a Syngenta Group Company

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Section 6 of the Health and Safety at Work ActAdditional Product Safety Information

(This section does not form part of the product label under the Plant Protection Products Regulations 1995.)

The product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‘Extension of Use’ approval or is otherwise permitted under the Plant Protection Products Regulations.

The information on this label is based on the best available information including data from test results.

Safety Data Sheet according to Regulation (EC) No. 1907/2006

Revision date 29/01/2014

replaces all previous editions

QUILT XCEL

1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY/ UNDERTAKING 1.1 Product IdentifierTradename QUILT XCELDesign Code A15909D

1.2 Relevant Identified Uses of the substance or mixture and uses advised against Use Fungicide

1.3 Details of the supplier of the safety data sheetCompany Syngenta UK Ltd CPC4, Capital Park, Fulbourn, Cambridge, CB21 5XE Phone (01223) 883400 Fax (01223) 882195 Website www.syngenta.co.uk

1.4 Emergency telephone number Emergency phone No. +44 (0) 1484 538444 (24h)

2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EU) 1272/2008 Acute toxicity (Oral) Category 4 H302 Eye irritation Category 2 H319 Acute toxicity (inhalation) Category 4 H332 Acute aquatic toxicity Category 1 H400 Chronic aquatic toxicity Category 1 H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

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Classification according to EU Directives 67/548/EEC or 1999/45/EC Xn Harmful N Dangerous for the environment R20/22 Harmful by inhalation and if swallowed R36/38 Irritating to eyes and skin R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 2.2 Label elements Labelling: Regulation (EC) No. 1272/2008

Hazard Pictograms

Signal Word Warning

Hazard Statements H302 Harmful if swallowed H319 Causes serious eye irritation H332 Harmful if inhaled H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements P102 Keep out of reach of children P261 Avoid breathing dust/fume/gas/mist/vapours/spray P280 Wear eye protection/face protection P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 Call a POISON CENTRE or doctor/physician if you feel unwell P337/P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.

Supplemental Information EUH401 To avoid risks to human health and the environment comply with the instructions for use.

Hazardous components which must be listed on the label:• propiconazole• azoxystrobin

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Labelling: EU Directives 67/548/EEC or 1999/45/EC

Symbol(s)

Harmful Dangerous for the environment

R-phrases R20/22 Harmful by inhalation and if swallowedR36/38 Irritating to eyes and skinR50/53 Very toxic to aquatic organisms, may cause long-term

adverse effects in the aquatic environment

S-phrases S2 Keep out of the reach of childrenS13 Keep away from food, drink and animal feedingstuffsS20/21 When using do not eat, drink or smokeS35 This material and its container must be disposed or in a

safe wayS36/37 Wear suitable protective clothing and glovesS57 Use appropriate container to avoid environmental

contamination

Special labelling of certain mixtures

To avoid risks to man and the environment, comply with the instructions for use Contains propiconazole: May produce an allergic reaction

Hazardous components which must be listed on the label:• propiconazole • azoxystrobin

2.3 Other hazards None known

DANGEROUS FOR THE ENVIRONMENT

HARMFUL

Xn N

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3. COMPOSITION / INFORMATION ON INGREDIENTS 3.2 Mixtures Hazardous Component(s)

Chemical Name CAS No. EC No. Registration Number

Classification (67/548/EEC)

Classification (REGULATION (EC) No. 1272/2008

Concentration

azoxystrobin 131860-33-8 T, N R23R50/53

Acute Tox.3; H331Aquatic Acute 1; H400Aquatic Chronic 1; H410

13.5% w/w

propiconazole 60207-90-1 262-104-4

Xn, N R22 R43 R50/53

Acute Tox.4; H302 Skin Sens. 1B; H317Aquatic Acute 1; H400Aquatic Chronic 1; H410

11.7% w/w

octan-1-ol 111-87-5 203-917-6 01-2119486978-10 -0 005

XiR36

Eye Irrit.2; H319Aquatic Chronic 3; H412

8-15% w/w

poly(oxy-1,2-eth anediyl), al-pha-[tris(1-phenylethyl)phenyl]-o mega-hydroxy-

99734-09-5 70559-25-0

R52/53 Aquatic Chronic 3; H412 1-5% w/w

poly(oxy-1,2-eth anediyl), al-pha-phosphono-ome-ga-[2,4,6-tris(1-p henylethyl)phenoxy]-

90093-37-1 114535-82-9 618-446-5

XiR36

Eye Irrit.2; H319 1-5% w/w

propane-1,2-diol 57-55-6200-338-0

- - 1-5% w/w

Substances for which there are Community workplace exposure limitsFor the full text of the R-phrases mentioned in this Section, see Section 16.For the full text of the H-statements mentioned in this Section, see Section 16.

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4. FIRST-AID MEASURES4.1 Description of first aid measures General advice: Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta emergency number, a poison control centre or physician, or going for treatment. Inhalation: Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or Poison Control Centre immediately. Skin contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting.

4.2 Most Important symptoms and effects, both acute and delayedSymptoms: No information available

4.3 Indication of any immediate medical attention and special treatment neededMedical advice: There is no specific antidote available. Treat symptomatically.

5. FIRE-FIGHTING MEASURES5.1 Extinguishing mediaExtinguishing media - small fires Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Extinguishing media - large fires Alcohol-resistant foam or water spray.Do not use a solid water stream as it may scatter and spread fire.

5.2 Special hazards arising from the substance or mixture As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. 5.3 Advice for fire-fighters Wear full protective clothing and self-contained breathing apparatus. Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.

6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency proceduresRefer to protective measures listed in sections 7 and 8. 6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. 6.3 Methods and materials for containment and cleaning upContain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). If the product contaminates rivers and lakes or drains inform respective authorities. 6.4 Reference to other sectionsRefer to protective measures listed in sections 7 and 8Refer to disposal considerations listed in section 13.

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7. HANDLING AND STORAGE7.1 Precautions for safe handling No special protective measures against fire required. Avoid contact with skin and eyes. When using, do not eat, drink or smoke. For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs.

7.3 Specific end uses Registered Crop Protection products: For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION8.1 Control parameters

Components Exposure limit(s) Type of exposure limit Source

azoxystrobin 2 mg/m³ 8 h TWA SYNGENTA

propiconazole 8 mg/m³ 8 h TWA SYNGENTA

propane-1,2-diol 10 mg/m³ (particulates) 150 ppm, 470 mg/m³ (Total (vapour & particulates))

8 h TWA 8 h TWA

UK HSE UK HSE

The following recommendations for exposure controls/personal protection are intended for the manufacture, formulation and packaging of the product.

8.2 Exposure controlsEngineering Measures Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mist or vapours are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice. Protective measures The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards. Respiratory protection A particulate filter respirator may be necessary until effective technical measures are installed. Protection provided by air-purifying respirators is limited. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection. Hand protection Chemical resistant gloves are not usually required. Select gloves based on the physical job requirements. Eye Protection Eye protection is not usually required. Follow any site specific eye protection policies.

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Skin and body protection Assess the exposure and select chemical resistant clothing based on the potential for contact and the permeation / penetration characteristics of the clothing material. Wash with soap and water after removing protective clothing. Decontaminate clothing before re-use, or use disposable equipment (suits, aprons, sleeves, boots, etc.). Wear as appropriate: impervious protective suit.

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical state: Liquid Form: FluidColour: Off-white to yellowOdour: Aromatic, strongOdour Threshold: No data availablepH: 5.0 – 9.0 at 1.0% w/v (25°C)Melting point/range: No data availableBoiling Point/Boiling Range: No data availableFlash-Point: > 101°CEvaporation rate: No data availableFlammability (solid, gas): No data availableLower explosion limit: No data availableUpper explosion limit: No data availableVapour pressure: No data availableRelative vapour density: No data availableDensity: 1.056 g/cm3 at 20°CSolubility in other solvents: No data availablePartition Coefficient No data availablen-octanol/water Auto-ignition temperature: 455°CThermal decomposition : No data availableViscosity, dynamic: 105 - 618 mPa.s at 20°C 59 - 184 mPa.s at 40°CViscosity, kinematic: No data availableExplosive Properties: Not explosiveOxidising properties: Not oxidising

9.2 Other InformationSurface tension: 29.6 mN/m at 20°C

10. STABILITY AND REACTIVITY

10.1 Reactivity : No information available10.2 Chemical stability : No information available10.3 Possibility of hazardous reactions : None known. Hazardous polymerisation does not occur. 10.4 Conditions to avoid : No information available10.5 Incompatible materials : No information available10.6 Hazardous decomposition products : Combustion or thermal decomposition will evolve toxic and irritant vapours.

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11. TOXICOLOGICAL INFORMATION

Acute Oral Toxicity: LD50 female rat, > 1.030 mg/kg The toxicological data has been taken from products of similar composition Acute inhalation toxicity: LC50 male and female rat, >2.56 mg/l, 4h The toxicological data has been taken from products of similar compositionAcute Dermal Toxicity: LC50 male and female rat, > 5000 mg/kg The toxicological data has been taken from products of similar compositionSkin corrosion/irritation: Rabbit: Moderately irritating. The toxicological data has been taken from products of similar compositionSerious eye damage/eye irritation: Rabbit: Severely irritating. The toxicological data has been taken from products of similar compositionRespiratory or skin sensitisation: Buehler test guinea pig: Not a skin sensitiser in animal tests.Germ cell mutagenicityAzoxystrobin, Propiconazole: Did not show mutagenic effects in animal experiments. Octan-1-ol: Not mutagenic in Ames Test.Carcinogenicity Azoxystrobin, Propiconazole: Did not show carcinogenic effects in animal experiments. Reproductive toxicity Azoxystrobin, Propiconazole: Did not show reproductive toxicity effects in animal experiments. Octan-1-ol: No toxicity to reproduction. STOT – repeated exposureAzoxystrobin, Propiconazole: No adverse effect has been observed in chronic toxicity tests.

12. ECOLOGICAL INFORMATION12.1 Toxicity Toxicity to fish: LC50 Oncorhynchus mykiss (rainbow trout), 1.8 mg/l , 96 h Toxicity to aquatic invertebrates: EC50 Daphnia magna (Water flea), 0.78 mg/l, 48 h Toxicity to aquatic plants: ErC50 Pseudokirchneriella supcapitata (green algae), 2.9 mg/l, 96h EbC50 Pseudokirchneriella supcapitata (green algae), 0.63 mg/l, 96h

12.2 Persistence and degradability Biodegradability Azoxystrobin, Propiconazole: Not readily biogradable.

Stability in waterAzoxystrobin: Degradation half life: 214 d. Stable in water.Propiconazole: Degradation half life: 28 - 64 d. Stable in water. Stability in soilAzoxystrobin: Degradation half life: 80 d. Not persistent in soil.Propiconazole: Degradation half life: 66 - 170 d. Not persistent in soil.

12.3 Bioaccumulative potential Azoxystrobin: Does not bioaccumulate. Propiconazole: Low to medium mobility in soil.

12.4 Mobility in soil Azoxystrobin: Low to very high mobility in soil Propiconazole: Low to medium mobility in soil.

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12.5 Results of PBT and vPvB assessment Azoxystrobin, Propiconazole, These substances are not considered to be persistent, bioaccumulating nor toxic (PBT). Octan-1-ol: These substances are not considered to be very persistent nor very bioaccumulating (vPvB). 12.6 Other adverse effects Other information: Classification of the product is based on the summation of the concentrations of classified components.

13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken for local recycling or waste disposal. Do not re-use empty containers.

14. TRANSPORT INFORMATION Land transport (ADR/RID)

14.1 UN Number : UN 3082

14.2 UN proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (AZOXYSTROBIN AND PROPICONAZOLE)

14.3 Transport hazard class(es) : 9

14.4 Packing Group ; lll

Labels : 9

14.5 Environmental hazards : Environmentally hazardous

Tunnel restriction code : E

Sea transport (IMDG)

14.1 UN Number : UN 3082

14.2 UN proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (AZOXYSTROBIN AND PROPICONAZOLE)

14.3 Transport hazard class(es) : 9

14.4 Packing Group ; lll

Labels : 9

14.5 Environmental hazards : Marine pollutant

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Air transport (IATA-DGR)

14.1 UN Number : UN 308214.2 UN proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (AZOXYSTROBIN AND PROPICONAZOLE)

14.3 Transport hazard class(es) : 914.4 Packing Group ; lll

Labels : 9

14.6 Special precautions for user : None

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulation/legislation specific for the substance or mixture

Hazard Pictogram

Signal Word Warning

Hazard Statements H302 Harmful if swallowed H319 Causes serious eye irritation H332 Harmful if inhaled H410 Very toxic to aquatic life with long lasting effects.

Precautions Statements P102 Keep out of reach of children P261 Avoid breathing dust/fume/gas/mist/vapours/spray P280 Wear eye protection/face protection P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 Call a POISON CENTRE or doctor/physician if you feel unwell P337/P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.

Supplemental Information EUH401 To avoid risks to human health and the environment comply with the instructions for use. Contains propiconazole: May produce an allergic reaction

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Hazardous components which must be listed on the label:• propiconazole• azoxystrobin 15.2 Chemical Safety Assessment A chemical safety assessment is not required for this substance.

16. OTHER INFORMATIONApproval number, MAPP 16450; PCS No. 04816.Use plant protection products safely. Always read the label and product information before use.Based upon SDS release dated 29/01/2014, version 4 with local amendment.

Full text of R phrases referred to under Section 2 and 3:R22 Harmful if swallowed.R23 Toxic by inhalation.R36 Irritating to eyes.R43 May cause sensitisation by skin contactR50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of H-statements referred to under sections 2 and 3:H302 Harmful if swallowed H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H331 Toxic if inhaled.H332 Harmful if inhaledH400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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2015-03-02 Quilt Xcel 5L Label Approved GR.pdf2015-03-02 Quilt Xcel 5L Leaflet Approved GR.pdf