Prest WM Abridged) Envirotech 17.3

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    Hands on Training in Appropriate

    Instrumentation and Techniquesfor Ambient Air Quality Monitoring.New Delhi, March 17, 2012

    Presentation on

    Waste Minimisation &Zero Discharge

    by

    Dr. Dilip B. Boralkar

    Former Member SecretaryMaharashtra Pollution Control Board, Mumbai

    www.boralkar.com

    Organised by

    M/s Envirotech Insruments Pvt. Ltd., New Delhi

    http://www.boralkar.com/http://www.boralkar.com/http://www.boralkar.com/
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    Introduction The waste minimization can be phrased differently:

    Waste reduction or waste strength reduction;

    Application of clean technologies or green technologies

    Pollution prevention;

    Environment-friendly technologies (LNWT)

    The preference, naturally, will be reflected in the following order:

    No waste generation at all

    If waste is generated, it is recycled Residual wastes reduction v/w and in toxicity by treatment

    Disposal of treated residues should be so smooth that it does not

    adversely affect the recipient body (for example, discharge of

    treated effluent through an out fall diffuser).

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    WM Program: Critical StepsApproach of out of site, out of mind to be changed

    WM program to aim

    Waste Quantity

    Waste Toxicity

    Recovery

    ExpenditurePotential Risk

    SavingRaw Material cost

    SavingWaste Disposal

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    Preparation of WM Program:

    Waste Audit : Characterize waste streams

    Emission inventory : Quantification of release

    Fugitive loss control

    Good operating practice (GOP)

    Good maintenance practice (GMP)

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    WM Techniques

    Technology selected depends on nature of waste andtype of contaminants such as :

    Contaminants Type Break-up

    1. Organic Organic liquids, soils, sludge sediments Petroleum contaminated soils, sludge sediments Solvent contaminated soils, sludge sediments Rubber goods, tyre, belts, polymers, etc.

    2. Inorganic Metal containing solutions Metal containing soils, sludge sediments Slag, bottom ashes, fly ash, foundry sands Batteries, mercury containing materials, etc.

    3. Misc. Chemical tanks, demolition debris, transformers, ballasts,etc.

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    Waste Recycling Technologies : a.Wastes containing organics

    Waste type Possible recycling technology

    Organic solvent & petroleum product Distillation, energy recovery, decanting

    Soils-sludge-sediments, solvent/ petroleumcontaminated or organic sledges

    Energy recovery, decanting, thermaldesorption, solvent extraction

    VOCs In-situ vacuum extraction,

    Non-aqueous phase liquids (O & G) Pump and recover

    Dissolved organics Freeze- crystallization

    Propellant & explosives Energy recovery, extraction, reuse

    Lead acid battery cases Energy recovery and/or reuse

    Rubber goods (tyres, belts) Energy recovery, size reduction, reuse

    Liquid monomers Distillation, energy recovery

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    Waste Recycling Technologies : b. Wastes containing inorganics

    Waste type Possible recycling technologyMetal containingsolutions

    Crystallization, precipitation, ion-exchange, RO, evaporation,cementation, electrowinning

    Metal containingsoil, sludge,sediment, slag

    Chemical leaching, solidification,vitrification,

    Abrasive blasting

    material, foundrysand

    Use as raw material for cement,

    vetrification

    Lead acid & Ni-Cdbatteries

    Chemical leaching, pyro-metallurgical processing, physical

    separation

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    Waste Recycling Technologies : c. Miscellaneous waste

    Waste type Possible recycling technology

    Scrap chemicaltanks, pipes

    Decontamination anddisassembly

    Non-metalstructures anddemolition debris

    Separation and disassembly, useas construction material

    Wood debris Energy recovery

    Transformer &ballast

    PCB flush and treat, metalrecovery

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    Recycling Technologies

    Distillation

    Energy recovery (general)

    Energy recovery (cementkiln)

    Thermal desorption

    Solvent extraction

    Freeze crystallization Chemolysis

    Thermolysis

    Chemical precipitation

    Ion Exchange

    Liquid ion exchange (LIX)

    Reverse Osmosis (RO)

    Diffusion dialysis (DD)

    Electrolysis (ED)

    Evaporation

    Cement raw materials

    Physical separation

    Adsorption

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    Implementation of WM ProgramA. Training

    B. Raw material control

    C. Managing utilities Boiler performance

    A/F ratio Flue gas analysis Temperature O&M

    Combustion in oil fired boiler Energy Pumps Fans Air compressors

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    Implementation of WM Program

    D. Hardware & Machinery

    Efficiency

    Mechanical separation

    Equipment modificationsE. Process Modification

    Reactors

    Effectiveness of catalysts

    Heat exchangers : cause of waste due to reduced efficiency Distillation columns : cause of waste due to reduced

    efficiency

    D. Catalyst : Hastens reaction, increased conversion,reduced waste

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    Pollution of rivers due to sewage disposal:

    Need for Zero DischargeThe dumping and discharge of untreated or

    partially treated sewage and industrial waste

    waters into the rivers is the principal causeof the slow death of these rivers.

    The rivers systems are biologically dead.

    People living on river banks suffer fromseveral ailments caused by microorganismspenetrating the food chain through suchcontaminated water sources.

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    Continued

    In order to bring the river back to life, weneed to impose more stringent standards for

    the treatment and discharge of domesticsewage and industrial effluent

    It is now achievable with newly available,

    cost-effective, not-so-space intensive andenvironmentally sound technologies.

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    Past Experience

    A BOD of 30 mg/litre is nationalstandard for the disposal of treatedsewage or trade effluent into surface

    water streams.The limit, though high, is not stringent

    enough and it does not includeremoval of nitrogen and phosphorous

    which are responsible foreutrophication of our water bodies.

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    continued

    In fact, the efforts of 38 years of theimplementation of the Water

    (Prevention and Control of Pollution)Act, 1974 and 25 years of theimplementation of the Environment

    (Protection) Act, 1986 have not yieldedresults of even minimum satisfactionlevel.

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    Technologies

    In the last few years several welcome technologicaldevelopments have taken place which ifimplemented would bring the rivers back to life.

    The new technologies which include theSequential Batch Reactor (SBR), Moving Bed BioReactor (MBBR), Membrane Bio Reactor (MBR),Up-flow Anaerobic Sludge Blanket (UASB)

    technology etc. are more efficient and more costeffective.

    They require less space and save local municipalcorporations huge costs on land requirements.

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    continued

    They can deliver 4 to 5 times better resultsas compared with those of conventionaltechnologies that were set up based on the

    30 BOD standard: they can achieve anaverage of BOD 5mg/L for treated sewagewith maximum being

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    Policy

    Policy interventions are required toseize the initiative and momentumfor river conservation gathered not

    only at the government level butalso in public forums.

    We have in the past decades ofdevelopment taken away the life ofthe rivers.

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    continued

    We are solely responsible forreversing that situation.

    If we do not do that in theimmediate future, especially when

    we now have the technology, thecoming generation will neverforgive us.

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    Thanks very much!

    For more information visit:

    www.boralkar.com