ppm (f1) 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 ppm (f1) 400 MHz H … · ppm (f1) 7.50 7.00 6.50 6.00...
Transcript of ppm (f1) 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 ppm (f1) 400 MHz H … · ppm (f1) 7.50 7.00 6.50 6.00...
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
1
ppm (f1)1.02.03.04.05.06.07.08.09.0
ppm (f1)3.904.004.104.204.304.404.504.604.70
CN
CN
BrBr
400 MHz 1H-NMR spectrum of compound 10.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
2
ppm (f1)50100150
134.814
133.786
132.796130.915129.168129.027127.561
125.212
113.628112.998
52.485
51.48450.72950.381
CN
CN
BrBr
100 MHz 13C-NMR spectrum of compound 10.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
3
ppm (f1)3.04.05.06.07.08.0
00 56 64
CHCl3
CH2Cl2
CN
CN
BrBr
400 MHz 1H-NMR spectrum of compound 11.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
4
ppm (f1)050100150
135.934
131.497129.333
125.210
113.763
53.165
47.674
CN
CN
BrBr
100 MHz 13C-NMR spectrum of compound 11.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
5
ppm (t1)2.03.04.05.06.07.08.0
1.00
1.10
CHCl3
CH2Cl2
CN
CN
BrBr
400 MHz 1H-NMR spectrum of compound 12. -----------------------------------------------------------------------------------------------------------------------
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
6
ppm (f1)050100150
133.558
132.497
128.638
127.372
112.740
52.134
47.167CN
CN
BrBr
100 MHz 13C-NMR spectrum of compound 12.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
7
ppm (t1)1.02.03.04.05.06.07.08.09.0
ppm (t1)7.1007.1507.2007.2507.3007.3507.400
ppm (t1)5.2005.2505.300
ppm (t1)3.9003.9504.000
CN
CN
Br
Br
400 MHz 1H-NMR spectrum of compound 62.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
8
ppm (f1)050100150200
138.913134.607133.678132.273131.041129.873127.274
123.672112.152111.824
61.44158.09853.076
43.549
CN
CN
Br
Br
100 MHz 13C-NMR spectrum of compound 62.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
9
ppm (f1)1.02.03.04.05.06.07.08.09.0
ppm (f1)7.107.207.307.407.507.607.70
ppm (f1)5.6505.700
ppm (f1)4.7004.7504.800
ppm (f1)3.7003.7503.8003.850
CN
CN
Br
Br
400 MHz 1H-NMR spectrum of compound 47.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
10
ppm (f1)050100150
136.411132.611132.563131.959
130.657129.596127.788127.327112.281111.231
53.47852.87450.50043.035
CN
CN
Br
Br
100 MHz 13C-NMR spectrum of compound 47.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
11
1.02.03.04.05.06.07.08.09.0
ppm (t1)7.107.207.307.407.507.60
ppm (t1)4.8504.900
ppm (t1)3.7503.8003.8503.9003.950
CN
CN
Br
Br
400 MHz 1H-NMR spectrum of compound 48.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
12
ppm (t1)50100150
137.703133.632
132.537131.751130.865
129.673
128.470126.355
111.273111.232
53.553
52.318
44.397
38.480
CN
CN
Br
Br
100 MHz 13C-NMR spectrum of compound 48.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
13
2.03.04.05.06.07.0
0 8 3 1 6 6 7
ppm (f1)4.004.505.005.50
6 6 7
CN
CN
Br
Br
400 MHz 1H-NMR spectrum of compound 63.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
14
ppm (f1)50100150
135.726134.055
133.102131.901
130.919
129.931126.752126.421
113.100111.889
59.897
57.92354.256
42.935
CN
CN
Br
Br
100 MHz 13C-NMR spectrum of compound 63.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
15
ppm (f1)2.03.04.05.06.07.08.09.010.0
ppm (f1)4.7504.8004.8504.900 ppm (f1)
4.18504.19004.19503.8800
Br
Br
CO2Me
CO2Me
400 MHz 1H-NMR spectrum of compound 8.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
16
ppm (t1)050100150200
166.642165.652
146.098
140.047136.991134.533
128.841124.684122.564
53.05752.74150.28847.664
45.793
42.209
ppm (t1)128.820128.830128.840128.850128.860128.870
128.841
Br
Br
CO2Me
CO2Me
100 MHz 13C-NMR spectrum of compound 8.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
17
ppm (f1)050100150200
166.609165.656
146.101
140.036137.072134.455128.837
124.710122.558
53.07152.74150.26347.675
45.82342.256
Br
Br
CO2Me
CO2Me
100 MHz 13C APT NMR spectrum of compound 8.
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Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
18
ppm (f1)4.004.505.005.506.006.507.007.50
ppm (f1)5.7205.7305.7405.7505.760
ppm (f1)4.8104.8204.830
ppm (f1)3.8003.850
Br
CO2Me
CO2Me
Br
400 MHz 1H-NMR spectrum of compound 45. ------------------------------------------------------------------------------------------------------------------------
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
19
ppm (f1)50100150
164.075163.288
147.036
139.272
135.861133.170
132.180129.248128.632128.146
53.30952.83352.65352.62552.612
45.851
Br
CO2Me
CO2Me
Br
100 MHz 13C-NMR spectrum of compound 45.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
20
ppm (f1)4.004.505.005.506.006.507.007.50
ppm (f1)4.905.005.105.205.305.40
ppm (f1)3.91503.92003.9250
ppm (f1)3.76003.76503.77003.7750
BrCO2Me
CO2Me
Br
400 MHz 1H-NMR spectrum of compound 46.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
21
ppm (f1)050100150200
163.737163.042
148.161
138.820135.001
133.571133.215129.324128.561128.346
52.95752.79952.57252.41846.400
41.397
BrCO2Me
CO2Me
Br
100 MHz 13C-NMR spectrum of compound 46.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
22
ppm (f1)1.02.03.04.05.06.07.08.09.0
ppm (f1)5.105.205.305.405.50
ppm (f1)3.7503.8003.8503.9003.9504.0004.050
BrCO2Me
CO2Me
Br
400 MHz 1H-NMR spectrum of compound 60.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
23
ppm (f1)050100150200
164.421163.536
149.099
137.835135.736133.395133.294129.455128.667
127.276
61.34656.906
55.41152.78652.67546.735
BrCO2Me
CO2Me
Br
100 MHz 13C-NMR spectrum of compound 60.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
24
ppm (f1)3.04.05.06.07.08.0
ppm (f1)3.904.004.104.204.304.404.504.604.704.80
Br
Br
CN
CN
400 MHz 1H-NMR spectrum of compound 9.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
25
ppm (t1)050100150
144.432
139.180
130.575130.141129.617125.033124.372
123.084
114.554113.978
50.28448.69243.526
39.146
Br
Br
CN
CN
100 MHz 13C-NMR spectrum of compound 9.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
1
Mass spectra of compound 10.
Mass spectra of compound 11.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
2
Mass spectra of compound 45.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
3
Mass spectra of compound 60.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
4
Mass spectra of compound 48.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
5
Mass spectra of compound 47.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
6
Mass spectra of compound 46.
Supplementary Material (ESI) for New Journal of Chemistry This journal is © The Royal Society of Chemistry and The Centre National de la Recherche Scientifique, 2009
7
Mass spectra of compound 9.