POLYMER FILM EVAPORATION TECHNOLOGY · MVRE PLANT (3 X 500 M3/D) COPPER CABLE MANUFACTURING FROM...
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POLYMER FILM EVAPORATION TECHNOLOGY
Transcript of POLYMER FILM EVAPORATION TECHNOLOGY · MVRE PLANT (3 X 500 M3/D) COPPER CABLE MANUFACTURING FROM...
POLYMER FILM EVAPORATION
TECHNOLOGY
3 = high separation 2 = moderate 1 = low separation
Note! pH may change rating considerably
Pollutant to remove
Dissolved substances
Cati
on
s (
e.g
. h
eavy m
eta
ls)
M
onovale
nt
ions
M
ultiv
ale
nt
ions
C
om
ple
xed ions
An
ion
s
M
onovale
nt
(e.g
. chlo
ride)
M
ultiv
ale
nt
(e.g
. S
O4
2- )
A
mm
oniu
m
Org
an
ic c
om
po
un
ds
C
arb
ohydra
tes
P
rote
ins
A
lcohols
S
olv
ents
(e.g
. hydro
carb
ons)
P
igm
ents
P
esticid
es
C
OD
in g
enera
l
Technology
Adsorption (e.g. activated carbon) 1 1 1 1 1 1 1 3 3 3 1
Ion exchange 3 3 3 3 2
Chemical precipitation 1 2 3 2 2 1
Membrane technologies
Ultrafiltration (UF) 2 1 1
Nanofiltration (NF) 2 3 2 2 3 2 3 2
Reverse osmosis (RO) 3 3 3 3 3 1 3 3 1 3 3 3
Electrodialysis 3 3 3 3 3 3
Evaporation 3 3 3 3 3 2 3 3 3 3 3
Distillation 3 3 3
Flotation 1 1 2 2 2 1 1
Air/steam stripping 3 2 3 2
Electrical methods
Electrolyse 3 3 3
Electro coagulation 1 3 3 2 2 2 2
Biological treatment 1 1 2 1 1 2 3 3 3 1 2 1 2
Methods have often to be combined for zero discharge operation or to meet discharge limits
APPLICABILITY OF DIFFRENT WATER TREATMENT TECHNOLOGIES
EVAPORATION – NATURE’S PURIFICATION METHOD
PROCESS
PRETREATMENT EVAPORATION RE –USE
OR DISPOSAL
CONCENTRATE
WASTE WATER CLEAN WATER
MAKE UP WATER
ZERO DISCHARGE SYSTEM BY EVAPORATION
SINGLE EFFECT EVAPORATION
Specific Steam Consumption =
1.1
Vapour
Steam
Primary Condensate
Feed
Concentrate
Cooling Water
Condensate
1.1
1.0
CONDENSER
4-EFFECT MULTI-EFFECT EVAPORATION
Concentrate
Condensate
Vapour Steam Vapour
Waste Heat
Feed
Cooling
Water CONDENSER
Vapour Vapour Vapour
Primary Condensate
Specific Steam Consumption = 0.28
Vapor
Feed
Concentrate
Condensate
COMPRESSOR
Compressed Vapor
DT Steam consumption ~ 0
Cooling water cons. ~ 0
P = C x MF x DT P = Fan Power Use (kW) C = Constant (2,5…3) MF = Vapor mass flow (ton/h) DT = Temp. difference (°C)
MECHANICAL VAPOR RECOMPRESSION EVAPORATION
ENERGY USE IN EVAPORATION
0
2
4
6
8
10
12
14
16
0
0.2
0.4
0.6
0.8
1
1.2
PowerSteam
Steam ton/ton
Electricity,
kWh/ton
ARVIND ENVISOL INTRODUCES
NEW EVAPORATION
TECHNOLOGY
USING LOW COST POLYMERIC FILM AS HEAT TRANSFER MEDIA
10
POLYMERIC FILM EVAPORATION TECHNOLOGY
Low cost Evaporative surface
o large heat transfer surface
o small temperature difference
o low energy use - typically 8 to 14
kWh per m3 of purified water
Efficient production of
polymeric heat exchanger
elements by new machine
(1,5 million m2/year)
11
0
500
1000
1500
2000
2500
3000
00,20,40,60,811,2
Wall thickness, mm
Heat
tran
sfe
r co
eff
icie
nt,
U W
/m2oC
SS 316 PE
OVERALL HEAT TRANSFER COEFFICIENT AS FUNCTION OF WALL THICKNESS
Uniform distribution of Liquid on the Surface of Polymeric Heat Exchanger
LIQUID DISTRIBUTION ON POLYMERIC HEAT EXCHANGER
POLYMERIC EVAPORATIVE HEAT EXCHANGER CASSETTE
50 elements
Surface area 200 m2
Total weight 50 kg
OPERATION PRINCIPLE
TYPICAL EVAPORATOR LAY OUT (14 CASSETTES)
LARGE DIAMETER UNIT (3.8 mtr.)
CONTAINER SIZE EVAPORATOR (10 CASSETTES)
SMALL DIAMETER UNIT (2.4 mtr.)
INTERNAL ARRANGEMENT OF CASSETTES
MVR-FAN (HEART OF SYSTEM)
OPEX COMPARISON OF POLYMER MVR WITH CONVENTIONAL MEE & MVR
Energy consumption (el = 6 rp/kWh, steam 1 rp/kg) rp/m3 clean water New technology MVR (12 kWh/m3 + 10 kg/m3) 82
Conventional MVR (25 kWh/m3 + 20 kg/m3) 170 Conventional ME 1 stage (2 kWh/m3 +1100 kg/m3) 1112
Conventional ME 4 stage (3 kWh/m3 + 280 kg/m3) 298
COST COMPARISION OF SOME HEAT EXCHANGE MATERIALS
Material Relative cost/m2
AISI 316 51 x 1,0 mm tube (50 EUR/m2) 1 254 SMO 51 x 1,25 mm tube 2.5 654 SMO 51 x 1,25 mm tube 4.9 Sanicro 28 51 x 1,8 mm tube 5.7 Hastelloy C276 51 x 1,0 mm tube 13 Titanium 50,8 x 0,9 mm tube 13 Polyolefin film 40 my (0,3 EUR/m2) 0.006 High tech plastic film 0.06
TYPICAL APPLICATION AREAS
Textile industry Steel and metal industry Mining industry Pulp & Paper Food and feed industry Landfill leachate Groundwater remediation Seawater desalination Chemical industry Electronic industry Power plants Pharma industry
MVRE PLANT (3 X 500 M3/D)
COPPER CABLE MANUFACTURING FROM COPPER EFFLUENT 350 M3/D
Condensate
Concentrate
Copper
Electrolyse
Sulfuric acid H2SO4
Evaporator
Pickling basin
H 2 SO 4 Surface active agent
Copper cable
Passivation Rinsing counter current
