Plasticizers for today and for the future
Transcript of Plasticizers for today and for the future
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Plasticizers for today and for the future PVC Formulation 2014, Dusselsdorf
Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions
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Table of Contents
Introduction of the company Perstorp in PVC industry
Plasticizers
– Investment – Emoltene™ 100 (DPHP, C10) – Pevalen™ (Polyolester plasticizer)
Summary
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Perstorp in brief World leader in several sectors of the specialty chemicals market
Pioneer in formalin chemistry, plastics and surface materials
Perstorp was formed in 1881, over 130 years of winning formulas
Since December 2005 controlled by PAI partners, a leading European private equity company
Annual turnover of more than 10 billion SEK in 2012
About 1,500 employees in 22 countries
Production plants in Europe, Asia and North America
Sales offices in all major markets
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Perstorp in the PVC industry
Fully integrated plasticizer producer based on the west coast of Sweden since 1980’s
Perstorp exited the DOP business in 2012 Storage facilities in UK, Belgium, Germany and Portugal to serve
entire Europe Focus on European market and sustainable growth Member of ECPI, VinylPlus and founding member of PlasticiserPlus
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Perstorp believes in plasticizers
Perstorp is making its largest investment in history
Based on our own technology and backwardly integrated in raw materials
It will be on stream in Q1 2015
Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM
This investment will increase the production by 150 000 MT
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EmolteneTM 100 PevalenTM Investment for a more
sustainable future
Versatile general PVC plasticizer
Established C10 (DPHP) GP plasticizer
Excellent versatility and flexibility
Expands lifespan of end products
High technical performance, with good outdoor properties
High performance polyol ester plasticizer
Highly efficient in providing softness
Easy to process and use
Low volatility ensuring no VOC and consistent properties
New capacity for Valeraldehyde and its derivatives
Strengthen our production platform
Fully integrated and secure supply chain
Ability to offer competitive and safe products
Innovative plasticizer for sensitive applications
Flexible, versatile & safe
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Emoltene™ 100 and Pevalen™ focus on different markets
Emoltene™ 100 - Durable applications
– Wire and cables – Films & sheets e.g. roofing membranes,
swimming pool liners, automotive foils – Coated fabrics; e.g. tarpaulins – Automotive interiors
Pevalen™ - Sensitive applications
– Coated fabrics; e.g. table cloths, protective clothing
– Films & sheets; e.g. office materials, furniture foils
– Flooring – Plastisols; e.g. wallpaper, toys – Moulded parts; e.g. grips
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Key segments where Emoltene™ 100 is preferable
CABLES & WIRES AUTOMOTIVE INTERIOR
Low volatility and high UV resistance with C10 plasticizer
Well accepted for PVC cables
at all major users
Low volatility/migration of C10 plasticizers secures long life span required
Plasticized PVC not easy substituted for this industry due to the advantage PVC has vs. other polymers
FILM AND SHEETS
Low volatility of C10 plasticizers secures long life span required
Plasticized PVC good UV stability and outdoor resistance
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Volatility
-25
-20
-15
-10
-5
0DPHP DINP DOP
Wei
ght
Cha
nge,
%
Emoltene™ 100 (DPHP) has low volatility Emoltene™ 100 (DPHP) makes the product durable
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Fogging
Emoltene™ 100 (DPHP) has lower fogging Emoltene™ 100 (DPHP) is suitable for car interiors
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Migration to plastics ABS PC PS Acrylic TOTM Polymeric Polymeric Polymeric
DPHP TOTM TOTM TOTM
DOTP DPHP DOTP DPHP DEHP DINP DINP DINCH
DINCH DINCH DPHP DINP
DINP DOTP DEHP DOTP
Polymeric DEHP DINCH DEHP
DOA ATBC DOA DOA
ATBC DOA ATBC ATBC
Benzoate Benzoate Benzoate Benzoate
Source: www.filmandsheet.com, www2.teknorapex.com/PVC-Plasticizer-Migration
Emoltene™ 100 (DPHP) has low migration Emoltene™ 100 (DPHP) contributes with high permanency
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Water absorption
0,29
0,3
0,31
0,32
0,33
0,34
0,35
0,36
DPHP DINP DOP
Wei
ght
Cha
nge,
%
Emoltene™ 100 (DPHP) has low water absorption Emoltene™ 100 (DPHP) suitable for outdoor applications
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Pevalen™
A versatile general purpose plasticizer that is equal to or in some cases better than standard phthalate plasticizers
Perstorp is increasing capacity and will meet customer demand. Perstorp will by 2015 be fully integrated in raw materials.
At this time, Pevalen™ will be commercially competitive to other high volume plasticizers
The chemistry is well established and proven
Process for food contact approval underway
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Easy storage
Pevalen™ has low viscosity even at temperatures below 0 °C Pevalen™ does not need to be heated during storage
0
0,5
1
1,5
2
2,5
-20 0 20 40 60 80
Vis
cosi
ty P
as
Temperature °C
Viscosity
Emoltene 100
DOTP
DOP
DINP
Dinch
Pevalen™
DINCH
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Processing – top of the class
Pevalen™ has short dry blend time Pevalen™ gives fast processing
00:00
03:00
06:00
09:00
12:00
15:00
DINCH DINP DOP DOTP Pevalen™
Tim
e (
mm
/ss)
Dry blend time
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Unique product performance
79
80
81
82
83
84
85
86
87
88
0 5 10 15 20 25
Har
dnes
s (S
hore
A)
Volatility (% lost)
Effciency
DINCH
DINP
DOP
DOTP
Pevalen™
Pevalen™ has a unique combination of low volatility and high plasticizing efficiency
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Migration to rubber
Pevalen™ has lower or equal migration to rubber
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Migration to plastics
Pevalen™ has comparable migration to plastics Pevalen™ high compatibility to PVC is also shown here it has
a tendency to migrate more to non-plasticized PVC
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Durability
Pevalen™ has very good resistance to chemicals Pevalen™ has same performance as other plasticizers on oil
-5,0
0,0
5,0
10,0
15,0
20,0
25,0
30,0
Heptane Hexane Olive Oil
Wei
ght
loss
%
Extraction chemicals and oil
DINCH
DINP
DOP
Pevalen™
DOTP
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Durability
Pevalen™ has same or better resistance to water solution as other plasticizers
-0,6
-0,5
-0,4
-0,3
-0,2
-0,1
0,01 %Soap 1% NaOH
Wei
ght
loss
%
Extraction water solutions
DINCH
DINP
DOP
Pevalen™
DOTP
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Summary Plasticizers Emoltene™ 100 – well-established HMW phthalate plasticizer
– Available in high volumes – Highly competitive production platform – Valued for low water absorption, low volatility and migration – Reflected in improved durability, good outdoor resistance and long life span
Pevalen™ – an innovative polyol ester plasticizer
– High performance polyol ester plasticizer – Highly efficient in providing softness – Easy to process and use – Low volatility and migration ensuring no VOC and consistent properties
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Thank You for your attention!
Anders Magnusson Application Specialist [email protected] Perstorp Group