Pigment preparations for polyvinyl chloride (PVC) · 4 Pigment preparations for polyvinyl chloride...

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Pigment preparations for polyvinyl chloride (PVC) Product selection guide

Transcript of Pigment preparations for polyvinyl chloride (PVC) · 4 Pigment preparations for polyvinyl chloride...

Page 1: Pigment preparations for polyvinyl chloride (PVC) · 4 Pigment preparations for polyvinyl chloride (PVC)Explanation of data Pigment preparations for polyvinyl chloride (PVC) Explanation

Pigment preparations for polyvinyl chloride (PVC)Product selection guide

Page 2: Pigment preparations for polyvinyl chloride (PVC) · 4 Pigment preparations for polyvinyl chloride (PVC)Explanation of data Pigment preparations for polyvinyl chloride (PVC) Explanation

3Pigment preparations for polyvinyl chloride (PVC)A palette of solutions

Pigment preparations for polyvinyl chloride (PVC)2 Packaging everyday life

With our Colors & Effects brand, BASF offers a comprehensive range of solutions for

intense colors in your plastics. Specially designed for the easy processing of PVC, our

pigment preparations improve polymer operations – resulting in reliable performance,

improved working conditions, fast processing and the effi cient use of working capital.

A palette of solutions for better performance

Pigment preparations for polyvinyl chloride (PVC) are only one part of the broad palette of BASF’s coloring solutions.To receive the full overview of our palette for colors and effects, please contact your BASF representative.

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Pigment preparations for polyvinyl chloride (PVC)4 5Pigment preparations for polyvinyl chloride (PVC)Explanation of data Explanation of data

Color shades

All organic pigment shades shown here are based on a full shade concentration of 0.2% powder pigment; with the exception of violets, where 0.1% powder pigment was used. In the white reductions, the illustrations are based on the relevant powder pigment concentration to achieve 1/3 ISD based on 5% TiO2.

Inorganic pigment shades are based on a full shade concentration of 2% powder pigment and a ratio of 1:4 for white reductions.

Hot light fastness* (PVC-p)

Exposure was carried out at 600 kJ/m2 in accordance with ASTM SAE J2412 (previously ASTM SAE J1885).

Color changes were assessed using the ISO 105-A02 grayscale (GS) with GS 5 denoting no change and GS 1 denoting the lowest hot light fastness.

Pigment content

The average pigment concentration [%] in the relevant pigment preparation is a nominal value. This value is intended only as a guideline. In practice, the specifications for the pigment preparations are set to achieve the correct color appearance and color strength.

Weather resistance* (PVC-p)

Weather resistance was determined using xenon light exposure tests in accordance with the equivalent test methods ASTM G155, ISO 4892-2, or the internal test method WOM 119/50.

The PVC-p samples were exposed for up to 5,000 hours.

Color changes were assessed using the ISO 105-A02 grayscale (GS) with GS 5 denoting no change and GS 1 denoting the lowest weather resistance.

Bulk density

Bulk density was determined by the weight of a product sample that can be contained in a vessel of specified volume and is expressed as kg/l. Assessment was in accordance with ISO/R 787-11.

Light fastness (PVC-p)

Light fastness was determined using xenon lamp exposure tests in accordance with the equivalent test methods ISO 4892-2 or ISO 105-B02.

The samples were assessed against the 1–8 Blue Wool Scale as described in ISO 105-B02 with Blue Wool 8 denoting the highest light fastness.

Migration (PVC-p)

Migration resistance was determined in accordance with DIN 53775 by way of direct contact between the colored test sheet and a white, flexible PVC contact sheet.

Staining of the contact sheet was assessed using the ISO 105-A03 grayscale (GS) with GS 5 denoting no migration and steps 1 to 5 being subdivided.

Application performance

A selection of performance data for the most important properties in PVC (Ba/Zn-stabilized, flexible PVC) is presented here. All data given is for the corresponding base pigment, unless otherwise stated. Pigment concentrations used are those based on powder pigments.

Organic pigments: Full shade (FS): 0.1% White reduction (WR): 0.2% + 2% TiO2 (ratio 1:10)

Inorganic pigments: Full shade (FS): 1% White reduction (WR): 1% + 4% TiO2 (ratio 1:4)

Explanation of data

* Hot light fastness and weather resistance ratings below GS 3 are not included in this pattern card. Products with a low performance are not recommended for these applications.

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7Pigment preparations for polyvinyl chloride (PVC)Our pigment preparations are designed to make your life easier

Pigment preparations for polyvinyl chloride (PVC)6 Packaging everyday life

Pigment preparations for PVC enable excellent scale-up from lab to production,

shorter change-over times between different colors and a signifi cantly reduced need

for reworking production batches.

Our pigment preparations are designed to make your life easier

Micranyl® Q

The Micranyl® Q range is based on organic and inorganic pigments dispersed in a phthalate-free, vinyl carrier system. Micranyl® products are specifi cally recommended for mass coloration of fl exible and semi-rigid polyvinyl chloride fi lms and may also be used for PVC extrusion and injection-molding applications. Due to their conformity to anti-fogging requirements, Micranyl® Q products are suitable for automotive applications.

Key portfolio

Microlith® KP

The Microlith® KP range consists of specially prepared pigment preparations, mainly based on high-performance organic pigments as well as titanium dioxide and carbon black at a concentration of between 40% and 70%. These pigments are fi nely pre-dispersed in a vinyl copolymer resin, which leads to greatly enhanced coloristic properties. Therefore, Microlith® KP products can be used in all applications that require utmost pigment dispersion levels, extreme transparency, and dichroism-free colorations, such as stretched calendared rigid PVC fi lm, lamination and decoration fi lms, blown rigid PVC fi lm and bottles.

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Pigment preparations for polyvinyl chloride (PVC)8 9Pigment preparations for polyvinyl chloride (PVC)Micranyl® Q Micranyl® Q

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Micranyl® Yellow 1025 Q C.I. Pigment Yellow 17** Diarylide

0 1 - 4.7 7–8 7 - - - - 40 0.6

Micranyl® Yellow 1070-20 Q C.I. Pigment Yellow 168 Monoazo salt

0 1 - 5 7–8 7 - - - - 20 0.7

Micranyl® Yellow 1210 Q C.I. Pigment Yellow 93 Disazo condensation

0 1 - 5 8 7–8 5 5 4 3–4 40 0.6

Micranyl® Yellow 1500 Q C.I. Pigment Yellow 95 Disazo condensation

0 1 - 5 8 7–8 4–5 4–5 3–4 - 45 0.6

Micranyl® Yellow 1740 Q C.I. Pigment Yellow 83** Diarylide

0 1 - 5 8 7–8 5 3–4 - - 40 0.6

Micranyl® Yellow 1760 Q C.I. Pigment Yellow 191:1 Monoazo salt

0 1 - 5 8 7 4–5 3–4 - - 30 0.6

Micranyl® Yellow 2070 Q C.I. Pigment Yellow 110 Isoindolinone

0 1 - 5 8 8 4–5 4–5 4–5 4–5 50 0.6

Micranyl® Orange 2430 Q C.I. Pigment Orange 82 Mixed Metal Oxide

0 1 - 5 8 8 5 5 5 5 65 0.8

Micranyl® Yellow 2565 Q C.I. Pigment Yellow 42 Iron oxide

0 1 - 5 7–8 7–8 5 5 - - 50 1.0

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.** At temperatures above 200 °C diarylide pigments may decompose. Users are advised to follow the recommendations of ETAD information No. 2.

Micranyl® Q0 Limited suitability 1 Recommended

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Pigment preparations for polyvinyl chloride (PVC)10 11Pigment preparations for polyvinyl chloride (PVC)Micranyl® Q Micranyl® Q

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Micranyl® Brown 2650 Q C.I. Pigment Red 101 Iron oxide

0 1 - 5 8 8 5 5 - - 45 0.9

Micranyl® Brown 2915 Q C.I. Pigment Red 101 Iron oxide

0 1 - 5 8 8 - - - - 15 0.7

Micranyl® Orange 2960 Q C.I. Pigment Orange 64 Benzimidazolone

0 1 - 5 7–8 7–8 4–5 3–4 - - 45 0.7

Micranyl® Scarlet 3540 Q C.I. Pigment Red 166 Disazo condensation

0 1 - 5 8 7 5 4–5 3–4 - 40 0.7

Micranyl® Red 3580 Q C.I. Pigment Red 149 Perylene

0 1 - 5 8 7 5 3–4 4 - 30 0.6

Micranyl® Red 3840 Q C.I. Pigment Red 254 Diketopyrrolopyrrole (DPP)

0 1 - 5 8 7–8 4–5 4–5 5 3–4 45 0.7

Micranyl® Red 3890 Q C.I. Pigment Red 144 Disazo condensation

0 1 - 5 8 7–8 5 5 3–4 - 45 0.7

Micranyl® Red 4035-20 Q C.I. Pigment Red 221 Disazo condensation

0 1 - 5 7–8 6–7 5 3 - - 20 0.6

Micranyl® Red 4111 Q C.I. Pigment Violet 19 Quinacridone

0 1 - 5 8 7–8 4–5 4–5 4 - 40 0.6

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.

Micranyl® Q0 Limited suitability 1 Recommended

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Pigment preparations for polyvinyl chloride (PVC)12 13Pigment preparations for polyvinyl chloride (PVC)Micranyl® Q Micranyl® Q

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Micranyl® Red 4170 Q C.I. Pigment Red 48:2** BONA (Ca)

0 1 - 5 7 6 - - - - 40 0.7

Micranyl® Rubine 4270 Q C.I. Pigment Red 57:1** BONA (Ca)

0 1 - 5 6 4 - - - - 45 0.6

Micranyl® Violet 5350 Q C.I. Pigment Violet 19 Quinacridone

0 1 - 5 7–8 7 4–5 4 4 3 40 0.6

Micranyl® Violet 5700-20 Q C.I. Pigment Violet 37 Dioxazine

0 1 - 5 7–8 6–7 4–5 - 3–4 - 20 0.6

Micranyl® Violet 5800-20 Q C.I. Pigment Violet 23 Dioxazine

0 1 - 4 7–8 7-8 4–5 3 4-5 - 20 0.6

Micranyl® Blue 6250 Q C.I. Pigment Blue 29 Ultramarine blue

0 1 - 5 8 8 5 5 5 5 50 0.7

Micranyl® Blue 6255 Q C.I. Pigment Blue 29 Ultramarine blue

0 1 - 5 8 8 5 5 5 5 50 0.7

Micranyl® Blue 6911 Q C.I. Pigment Blue 15:1 Cu-phthalocyanine

0 1 - 5 8 7 4–5 4–5 4–5 4 40 0.7

Micranyl® Blue 7090 Q C.I. Pigment Blue 15:3 Cu-phthalocyanine

0 1 - 5 8 8 4–5 5 4–5 4–5 55 0.7

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.** Products with this C.I. number may vary in color and resistance properties in different polymer systems.

Micranyl® Q0 Limited suitability 1 Recommended

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Pigment preparations for polyvinyl chloride (PVC)14 15Pigment preparations for polyvinyl chloride (PVC)Micranyl® Q Micranyl® Q

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Micranyl® Green 8750 Q C.I. Pigment Green 7 Cu-phthalocyanine

0 1 - 5 8 8 5 5 5 4–5 50 0.7

Micranyl® White 0022 Q C.I. Pigment White 6 Titanium dioxide

0 1 - 5 8 8 5 5 5 5 70 1.2

Micranyl® White 0027 Q C.I. Pigment White 6 Titanium dioxide

0 1 - 5 8 8 5 5 5 5 70 1.2

Micranyl® Black 0055 Q C.I. Pigment Black 7 Carbon black

0 1 - 5 8 8 5 5 5 5 30 0.7

Micranyl® Black 0068 Q C.I. Pigment Black 7 Carbon black

0 1 - 5 8 8 5 5 5 5 30 0.6

Micranyl® Black 0069 Q C.I. Pigment Black 7 Carbon black

0 1 - 5 8 8 5 5 5 5 30 0.6

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.

Micranyl® Q0 Limited suitability 1 Recommended

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Pigment preparations for polyvinyl chloride (PVC)16 17Pigment preparations for polyvinyl chloride (PVC)Microlith® KP Microlith® KP

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Microlith® Yellow 0961 KP C.I. Pigment Yellow 138 Quinophtalone

1 0 - 4–5 7–8 7–8 5 4–5 - - 60 0.7

Microlith® Yellow 0990 KP C.I. Pigment Yellow 128 Disazo condensation

1 0 - 5 8 7–8 5 4–5 4–5 4 55 0.6

Microlith® Yellow 1210 KP C.I. Pigment Yellow 93 Disazo condensation

1 0 - 5 8 7–8 5 5 4 3–4 40 0.5

Microlith® Yellow 1740 KP C.I. Pigment Yellow 83** Diarylide

1 0 - 5 8 7–8 5 3–4 - - 50 0.7

Microlith® Yellow 2060 KP C.I. Pigment Yellow 110 Isoindolinone

1 0 - 5 8 8 4–5 4–5 4–5 4–5 50 0.7

Microlith® Brown 3001 KP C.I. Pigment Brown 23 Disazo condensation

1 0 - 5 8 7–8 5 4–5 4 - 45 0.6

Microlith® Scarlet 3540 KP C.I. Pigment Red 166 Disazo condensation

1 0 - 5 8 7 5 4–5 3–4 - 45 0.6

Microlith® Red 3840 KP C.I. Pigment Red 254 Diketopyrrolopyrrole (DPP)

1 0 - 5 8 7–8 4–5 4–5 5 3–4 45 0.6

Microlith® Red 3890 KP C.I. Pigment Red 144 Disazo condensation

1 0 - 5 8 7–8 5 5 3–4 - 40 0.5

Microlith® Pink 4430 KP C.I. Pigment Red 122 Quinacridone

1 0 - 5 8 8 5 5 4–5 4–5 45 0.7

Microlith® Magenta 4535 KP C.I. Pigment Red 202 Quinacridone

1 0 - 5 8 7–8 5 4–5 4–5 4 65 0.7

Microlith® KP0 Limited suitability 1 Recommended

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.** At temperatures above 200 °C diarylide pigments may decompose. Users are advised to follow the recommendations of ETAD information No. 2.

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Pigment preparations for polyvinyl chloride (PVC)18 Pigment preparations for polyvinyl chloride (PVC) 19Microlith® KP Microlith® KP

ProductFull shade (FS)

White reduction (WR)

Applications Application performance in PVC-p Physical properties

PVC-u PVC-p Plastisol Migration FS* Light FS* Light WR*Hot light (600 kJ) FS*

Hot light (600 kJ) WR*

Weather (5,000 h) FS*

Weather (5,000 h) WR*

Pigment content

Bulk density

Microlith® Violet 5700 KP C.I. Pigment Violet 37 Dioxazine

1 0 - 5 7–8 6–7 4–5 - 3–4 - 45 0.5

Microlith® Blue 6480 KP C.I. Pigment Blue 60 Indanthrone

1 0 - 5 7–8 8 4 3–4 3–4 - 50 0.6

Microlith® Blue 7080 KP C.I. Pigment Blue 15:3 Cu-phthalocyanine

1 0 - 5 8 8 4–5 4–5 4–5 4–5 50 0.6

Microlith® Green 8750 KP C.I. Pigment Green 7 Cu-phthalocyanine

1 0 - 5 8 8 5 5 5 4–5 50 0.7

Microlith® White 0022 KP C.I. Pigment White 6 Titanium dioxide

1 0 - 5 8 8 5 5 5 5 70 1.2

Microlith® Black 0066 KP C.I. Pigment Black 7 Carbon black

1 0 - 5 8 8 5 5 5 5 50 0.7

Microlith® KP0 Limited suitability 1 Recommended

The color shade is indicative. The actual shade in use depends on the formulation and may vary. * All data is based on the testing concentration as mentioned on page 4 under “Application performance”.

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Contact

BASF Colors & Effects

Pigments for plasticsG-EDP

[email protected]

Visit our website: www.colors-effects.basf.com

The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings, photographs, data, proportions, weights etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our products to ensure that any proprietary rights and existing laws and legislation are observed. When handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed.

® = Registered trademark of BASF SE