PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits....

43
L^ ...-^" BALSAM ENVIRONMENTAL CONSULTANTS, INC. Superf«Biiiid Records Ceastier SITE: t M r r ^ - t o ^<3 BREAK: OTHER: ^f?^ f n - ^ MEMORANDUM SDMS DocID 469107 TO: File FROM: Stefan C. Sokol > ^ ' ' Mindi F. Jacobs \P DATE: November 21, 1989 SUBJECT: Mottolo Site - Balsam Project 6185/814 Phase I Ground Water, Surface Water, and Sediment Sampling Data Validation - Inorganics Analyses The four data packages under evaluation consisted of 48 aqueous samples and nine sediment samples from the Mottolo Site which were analyzed by Cambridge Analytical Associates (CAA) for the Hazardous Substance List (HSL) inorganic parameters including cyanide. The analyses were performed in accordance with the U.S. Environmental Protection Agency (EPA) Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganics Analyses. A validation of the data was performed using criteria established in the Mottolo Project Operations Plan (POP) and the EPA document, "Laboratory Data Validation, Functional Guidelines for Evaluating Inorganics Analyses", dated July 1988 and subsequently referred to as "guidelines" in this memorandum. The parameters evaluated in review of the data package included: 0 integrity and completeness of the data package, 0 holding times, 0 initial and continuing calibrations, 0 laboratory blank samples 0 ICP interference check sample, 0 laboratory control sample, duplicate sample analysis, 0

Transcript of PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits....

Page 1: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

L^ - BALSAM ENVIRONMENTAL CONSULTANTS INC

SuperflaquoBiiiid Records Ceastier SITE tMrr^- to lt3

BREAK OTHER ^f^ f n - ^

MEMORANDUM

SDMS DocID 469107 TO File

FROM Stefan C Sokol gt ^

Mindi F Jacobs P

DATE November 21 1989

SUBJECT Mottolo Site shy Balsam Project 6185814 Phase I Ground Water Surface Water and Sediment Sampling Data Validation - Inorganics Analyses

The four data packages under evaluation consisted of 48 aqueous samples and

nine sediment samples from the Mottolo Site which were analyzed by Cambridge

Analytical Associates (CAA) for the Hazardous Substance List (HSL) inorganic

parameters including cyanide The analyses were performed in accordance with

the US Environmental Protection Agency (EPA) Contract Laboratory Program

(CLP) Statement of Work (SOW) for Inorganics Analyses A validation of the

data was performed using criteria established in the Mottolo Project Operations

Plan (POP) and the EPA document Laboratory Data Validation Functional

Guidelines for Evaluating Inorganics Analyses dated July 1988 and

subsequently referred to as guidelines in this memorandum The parameters

evaluated in review of the data package included

0 integrity and completeness of the data package

0 holding times

0 initial and continuing calibrations

0 laboratory blank samples

0 ICP interference check sample

0 laboratory control sample

duplicate sample analysis 0

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 2

0 field duplicates

0 matrix spike sample

0 furnace atomic absorption Quality Control and

0 ICP serial dilution

INTEGRITY AND COMPLETENESS OF THE DATA PACKAGE

Inorganics data were reported by CAA in four discrete data packages and were

evaluated accordingly in this review The data packages are referred to by the

following work orders No 8904288 No 8904286 No 8904271 and

No 8904324

The case narrative by CAA noted poor reproducibility for laboratory duplicate

analyses of cyanide in sample SD-Sl-001 however the sample was not

reanalyzed by CAA until well after the holding time was past Data for both

analyses were reported separately Review of the data packages indicated that

sufficient data were present to perform the data assessment summarized in this

memorandum

HOLDING TIMES

Holding times were assessed in terms of the SOW and the Mottolo POP criteria

The maximum acceptable holding time specified in the POP from sample

collection to analysis was 14 days for cyanide analyses and 28 days for mercury

analyses The same holding times were established in the SOW but were based

upon aqueous matrices and measurement of time from the date of sample

receipt at the laboratory to the date of analysis Other HSL inorganics must be

analyzed within 6 months from sample collection or from sample receipt to

analysis according to the POP and SOW respectively

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Balsam Project 6185814 November 21 1989 Page 3

Cyanide analyses for the nine sediment samples exceeded the POP holding time

criteria with analyses performed 32 days after sample collection Holding times

for cyanide analyses in sediment matrices were based upon holding times in

aqueous matrices in which cyanide stability is highly dependent on pH Based

upon conversations with the analytical laboratory it was judged that cyanide

would be more stable in a sediment matrix and that substantial degradation

within this time frame would be unlikely Detected cyanide concentrations for

samples of this matrix were qualified as approximate (J) Holding times for

cyanide analyses of the aqueous samples ranged from six to eight days from

sample collection and were v^dthin the maximum allowable holding time

Mercury analyses for the nine sediment samples were performed 33 days after

sample collection and exceeded the holding time criteria by five days No

actions will be taken with regard to these samples since mercury was not

detected Mercury analyses for aqueous samples were performed from 8 to

25 days after sample collection and were within the maximum allowable holding

time

Holding times for the other inorganic parameters in sediment and aqueous

matrices ranged from 4 to 47 days from sample collection to analysis and were

within the six month holding time limit

INITIAL AND CONTINUING CALIBRATIONS

In accordance with the guidelines a check was made to determine whether the

instruments used to analyze metals were calibrated daily and each time they

were set up The schedule of blank and standard samples used to develop

analytical performance curves for mercury cyanide inductively coupled plasma

(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of

the guidelines Results for calibration standards (Form II) must be within

percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115

percent for cyanide and 90 to 110 percent for other analytes

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Balsam Project 6185814 November 21 1989 Page 4

Initial calibration was performed at the beginning of sample analysis and

continuing calibrations were performed as required during the analysis runs

Analyses were found to have the required number of blanks and standards

Calibrations met the specified R windows

LABORATORY BLANK SAMPLES

Calibration blank and preparation blank data (Form III) were reviewed to

determine the existence and magnitude of possible laboratory contamination

problems The guidelines indicate that sample detection limits should be raised

to five times the concentration detected in any associated blank sample Sample

results greater than the instrument detection limit (IDL) but less than the

adjusted detection limit should be qualified as not detected and the adjusted

detection limit reported and qualified (UJ) Sample results greater than the

adjusted detection limit should not be qualified and the original detection limit

should be reported These criteria were applied to raw data for sediment

samples since raw data for aqueous blank samples and solid matrices are

presented in the same relative units

A total of 16 analytes were identified as blank contaminants in the four data

packages Raw data for the highest contaminant concentrations detected for the

blank sample within each data package are presented in Table I along vdth

action values representing five times the positive contaminant concentrations

Samples with reported analyte concentrations less than these action values were

reported as not detected with the original concentration reported as the adjusted

analytical detection limit and qualified (UJ) Sample concentrations greater

than these action values were accepted (A) Blank actions were not necessary

for samples in which blank sample contaminants were not detected

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 5

Analytes for some blank samples were reported by the laboratory as negative

concentrations Negative concentrations that have an absolute value greater

than the IDL may adversely affect quantitation for these analytes The most

negative concentrations are reported in Table I Associated sample results were

qualified as approximate (J) and the detection limits were qualified (UJ) for

samples in which the analytes were not detected

ICP INTERFERENCE CHECK SAMPLE

The ICP check sample (ICS) data were reviewed to assess the analytical

correction factors used during an ICP analysis run The guidelines require that

an ICS be run at the beginning and end of each analysis run or at least two

times during each 8-hour shift Results of the ICS analysis (Form IV) must be

v^dthin + 20 of control limits Calculations from raw data should be verified

In the review of the ICS data sheet recovery data were found to be wdthin

control limits and no data qualification actions were necessary An ICS was

analyzed at the beginning and end of each analysis run and in some instances

exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS

recoveries were recalculated from raw data and laboratory results were

confirmed for aluminum barium beryllium calcium cobalt chromium copper

iron magnesium manganese nickel potassium selenium silver vanadium and

zinc

LABORATORY CONTROL SAMPLE

In accordance with the guidelines laboratory control sample (LCS) results were

reviewed to determine whether the percent recovery (R) fell within the

specified control limits Control limits in aqueous matrices are specified as 80 to

120 percent for each analyte except antimony and silver for which control limits

are not established Control limits for solid matrices are specified for analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

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No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

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The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

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Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

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Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

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P P F P P P P P P P P F P P CV P P F P P F P P

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oao alaquo-6o

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ltroo ^OOddO

Qoo ] r oo s-oc

u M w U ( i u

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tt R wp

u U R ] ^ tJ ws^

pound U A tA A Ashy

ltltoc M

55 00 Oi

S i ^6 fffe oo

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lOOft

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3oodu ^bull(Jp u

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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

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ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

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bull Soo LL l QO

Q O UshyLL

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M ^ amp

jpoundkSE

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l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

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Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 2: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 2

0 field duplicates

0 matrix spike sample

0 furnace atomic absorption Quality Control and

0 ICP serial dilution

INTEGRITY AND COMPLETENESS OF THE DATA PACKAGE

Inorganics data were reported by CAA in four discrete data packages and were

evaluated accordingly in this review The data packages are referred to by the

following work orders No 8904288 No 8904286 No 8904271 and

No 8904324

The case narrative by CAA noted poor reproducibility for laboratory duplicate

analyses of cyanide in sample SD-Sl-001 however the sample was not

reanalyzed by CAA until well after the holding time was past Data for both

analyses were reported separately Review of the data packages indicated that

sufficient data were present to perform the data assessment summarized in this

memorandum

HOLDING TIMES

Holding times were assessed in terms of the SOW and the Mottolo POP criteria

The maximum acceptable holding time specified in the POP from sample

collection to analysis was 14 days for cyanide analyses and 28 days for mercury

analyses The same holding times were established in the SOW but were based

upon aqueous matrices and measurement of time from the date of sample

receipt at the laboratory to the date of analysis Other HSL inorganics must be

analyzed within 6 months from sample collection or from sample receipt to

analysis according to the POP and SOW respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 3

Cyanide analyses for the nine sediment samples exceeded the POP holding time

criteria with analyses performed 32 days after sample collection Holding times

for cyanide analyses in sediment matrices were based upon holding times in

aqueous matrices in which cyanide stability is highly dependent on pH Based

upon conversations with the analytical laboratory it was judged that cyanide

would be more stable in a sediment matrix and that substantial degradation

within this time frame would be unlikely Detected cyanide concentrations for

samples of this matrix were qualified as approximate (J) Holding times for

cyanide analyses of the aqueous samples ranged from six to eight days from

sample collection and were v^dthin the maximum allowable holding time

Mercury analyses for the nine sediment samples were performed 33 days after

sample collection and exceeded the holding time criteria by five days No

actions will be taken with regard to these samples since mercury was not

detected Mercury analyses for aqueous samples were performed from 8 to

25 days after sample collection and were within the maximum allowable holding

time

Holding times for the other inorganic parameters in sediment and aqueous

matrices ranged from 4 to 47 days from sample collection to analysis and were

within the six month holding time limit

INITIAL AND CONTINUING CALIBRATIONS

In accordance with the guidelines a check was made to determine whether the

instruments used to analyze metals were calibrated daily and each time they

were set up The schedule of blank and standard samples used to develop

analytical performance curves for mercury cyanide inductively coupled plasma

(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of

the guidelines Results for calibration standards (Form II) must be within

percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115

percent for cyanide and 90 to 110 percent for other analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 4

Initial calibration was performed at the beginning of sample analysis and

continuing calibrations were performed as required during the analysis runs

Analyses were found to have the required number of blanks and standards

Calibrations met the specified R windows

LABORATORY BLANK SAMPLES

Calibration blank and preparation blank data (Form III) were reviewed to

determine the existence and magnitude of possible laboratory contamination

problems The guidelines indicate that sample detection limits should be raised

to five times the concentration detected in any associated blank sample Sample

results greater than the instrument detection limit (IDL) but less than the

adjusted detection limit should be qualified as not detected and the adjusted

detection limit reported and qualified (UJ) Sample results greater than the

adjusted detection limit should not be qualified and the original detection limit

should be reported These criteria were applied to raw data for sediment

samples since raw data for aqueous blank samples and solid matrices are

presented in the same relative units

A total of 16 analytes were identified as blank contaminants in the four data

packages Raw data for the highest contaminant concentrations detected for the

blank sample within each data package are presented in Table I along vdth

action values representing five times the positive contaminant concentrations

Samples with reported analyte concentrations less than these action values were

reported as not detected with the original concentration reported as the adjusted

analytical detection limit and qualified (UJ) Sample concentrations greater

than these action values were accepted (A) Blank actions were not necessary

for samples in which blank sample contaminants were not detected

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 5

Analytes for some blank samples were reported by the laboratory as negative

concentrations Negative concentrations that have an absolute value greater

than the IDL may adversely affect quantitation for these analytes The most

negative concentrations are reported in Table I Associated sample results were

qualified as approximate (J) and the detection limits were qualified (UJ) for

samples in which the analytes were not detected

ICP INTERFERENCE CHECK SAMPLE

The ICP check sample (ICS) data were reviewed to assess the analytical

correction factors used during an ICP analysis run The guidelines require that

an ICS be run at the beginning and end of each analysis run or at least two

times during each 8-hour shift Results of the ICS analysis (Form IV) must be

v^dthin + 20 of control limits Calculations from raw data should be verified

In the review of the ICS data sheet recovery data were found to be wdthin

control limits and no data qualification actions were necessary An ICS was

analyzed at the beginning and end of each analysis run and in some instances

exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS

recoveries were recalculated from raw data and laboratory results were

confirmed for aluminum barium beryllium calcium cobalt chromium copper

iron magnesium manganese nickel potassium selenium silver vanadium and

zinc

LABORATORY CONTROL SAMPLE

In accordance with the guidelines laboratory control sample (LCS) results were

reviewed to determine whether the percent recovery (R) fell within the

specified control limits Control limits in aqueous matrices are specified as 80 to

120 percent for each analyte except antimony and silver for which control limits

are not established Control limits for solid matrices are specified for analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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p p

r P p p p p p p p p F P P CV P P F P P F P P

cfrraquo c LABORATORY QUALIFIERS

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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P P F P P P P P P P P F P P CV P P F P P F P P

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

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E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 3: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 3

Cyanide analyses for the nine sediment samples exceeded the POP holding time

criteria with analyses performed 32 days after sample collection Holding times

for cyanide analyses in sediment matrices were based upon holding times in

aqueous matrices in which cyanide stability is highly dependent on pH Based

upon conversations with the analytical laboratory it was judged that cyanide

would be more stable in a sediment matrix and that substantial degradation

within this time frame would be unlikely Detected cyanide concentrations for

samples of this matrix were qualified as approximate (J) Holding times for

cyanide analyses of the aqueous samples ranged from six to eight days from

sample collection and were v^dthin the maximum allowable holding time

Mercury analyses for the nine sediment samples were performed 33 days after

sample collection and exceeded the holding time criteria by five days No

actions will be taken with regard to these samples since mercury was not

detected Mercury analyses for aqueous samples were performed from 8 to

25 days after sample collection and were within the maximum allowable holding

time

Holding times for the other inorganic parameters in sediment and aqueous

matrices ranged from 4 to 47 days from sample collection to analysis and were

within the six month holding time limit

INITIAL AND CONTINUING CALIBRATIONS

In accordance with the guidelines a check was made to determine whether the

instruments used to analyze metals were calibrated daily and each time they

were set up The schedule of blank and standard samples used to develop

analytical performance curves for mercury cyanide inductively coupled plasma

(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of

the guidelines Results for calibration standards (Form II) must be within

percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115

percent for cyanide and 90 to 110 percent for other analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 4

Initial calibration was performed at the beginning of sample analysis and

continuing calibrations were performed as required during the analysis runs

Analyses were found to have the required number of blanks and standards

Calibrations met the specified R windows

LABORATORY BLANK SAMPLES

Calibration blank and preparation blank data (Form III) were reviewed to

determine the existence and magnitude of possible laboratory contamination

problems The guidelines indicate that sample detection limits should be raised

to five times the concentration detected in any associated blank sample Sample

results greater than the instrument detection limit (IDL) but less than the

adjusted detection limit should be qualified as not detected and the adjusted

detection limit reported and qualified (UJ) Sample results greater than the

adjusted detection limit should not be qualified and the original detection limit

should be reported These criteria were applied to raw data for sediment

samples since raw data for aqueous blank samples and solid matrices are

presented in the same relative units

A total of 16 analytes were identified as blank contaminants in the four data

packages Raw data for the highest contaminant concentrations detected for the

blank sample within each data package are presented in Table I along vdth

action values representing five times the positive contaminant concentrations

Samples with reported analyte concentrations less than these action values were

reported as not detected with the original concentration reported as the adjusted

analytical detection limit and qualified (UJ) Sample concentrations greater

than these action values were accepted (A) Blank actions were not necessary

for samples in which blank sample contaminants were not detected

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 5

Analytes for some blank samples were reported by the laboratory as negative

concentrations Negative concentrations that have an absolute value greater

than the IDL may adversely affect quantitation for these analytes The most

negative concentrations are reported in Table I Associated sample results were

qualified as approximate (J) and the detection limits were qualified (UJ) for

samples in which the analytes were not detected

ICP INTERFERENCE CHECK SAMPLE

The ICP check sample (ICS) data were reviewed to assess the analytical

correction factors used during an ICP analysis run The guidelines require that

an ICS be run at the beginning and end of each analysis run or at least two

times during each 8-hour shift Results of the ICS analysis (Form IV) must be

v^dthin + 20 of control limits Calculations from raw data should be verified

In the review of the ICS data sheet recovery data were found to be wdthin

control limits and no data qualification actions were necessary An ICS was

analyzed at the beginning and end of each analysis run and in some instances

exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS

recoveries were recalculated from raw data and laboratory results were

confirmed for aluminum barium beryllium calcium cobalt chromium copper

iron magnesium manganese nickel potassium selenium silver vanadium and

zinc

LABORATORY CONTROL SAMPLE

In accordance with the guidelines laboratory control sample (LCS) results were

reviewed to determine whether the percent recovery (R) fell within the

specified control limits Control limits in aqueous matrices are specified as 80 to

120 percent for each analyte except antimony and silver for which control limits

are not established Control limits for solid matrices are specified for analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

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5 0 O G2JD

a r o c VraquofiT5pOn

gtoo s oo

h^^opoo Vdo

lS-on l ^ o o lOOO

u egtU u U

iiishyfi u

KUu u u

uIALA

a I lLlt

UJ

U)

icJ E

N pound hJ

^ ^

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

O

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3SOO IOO 100

lOT^bOCtC i n on 5O0C

^oc 5ffeoc

oOO

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as on laogfxy

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Qotgt l ^ o o llt^ 0 0 OiOO

u u M u U U

U

u i

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u u R U

U M T T

lA

ugt

^

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A

fl-^od LI on 0 0 0

bull=^5-0C loc IOO

Qr^nto on IfiOO a^c ltac

^Oinr^n Ofcd

oHnor JltJ^laquo

0 A 6

4gt3roo r^rtSood

I OA fTOO

^afeoeo I40O

Soo ^ i ^ O

)CgtOD

u M u l i tx A

i A u R

It M 4 Ai t^

6

n _L1

uJ

t o f

(0 V ^ A A 7

5 5 0 0 if00 Jloo

bullzsoD l-oo IOO

imoooA loop

3 O 0 Soo

3 S iOe i

IZSOoo Siesoo

copyao J 5- Ofl

I3 i 0r tlaquo Joo

Sraquoo( n 0000

Hioo

u a u l i

u u

u p uft u ft

laquoJ

u bullR t lgtlaquo

^

U l ^ o d U ffOO U ld ocL

W

E

hJ

A W

Ashy

5-5- OC l OO

W-SS-oo bullraquogts oo

oo too

tgtgt0000 oofl

copypoundlaquo 5 0 0

J9r06firtr) 3 f i f t

bullSlriOrtC MltJW00C

oao alaquo-6o

^ l ^0 66 IOO

ltroo ^OOddO

Qoo ] r oo s-oc

u M w U ( i u

u Li l

tt R wp

u U R ] ^ tJ ws^

pound U A tA A Ashy

ltltoc M

55 00 Oi

S i ^6 fffe oo

oo i)OOrtO0

lOOft

L u

R (i D IJ

3oodu ^bull(Jp u

^r-SEi R ^ 0 0

HlhOOo 333 oo

(33C 0 5 0 0

J ^ O O d O A 60 ^-ao

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in fl

u M

R Llt

Vcdu 1^00 22S) lopo

(gtl

^

A ^

N FMJJ

N

1

3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

S2^3QAJ0pound1 i yg f f t

ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

y5Oegt 3 = i ^ (A W

^ B IOO L L

pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

EE ^iSe

ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 4: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 4

Initial calibration was performed at the beginning of sample analysis and

continuing calibrations were performed as required during the analysis runs

Analyses were found to have the required number of blanks and standards

Calibrations met the specified R windows

LABORATORY BLANK SAMPLES

Calibration blank and preparation blank data (Form III) were reviewed to

determine the existence and magnitude of possible laboratory contamination

problems The guidelines indicate that sample detection limits should be raised

to five times the concentration detected in any associated blank sample Sample

results greater than the instrument detection limit (IDL) but less than the

adjusted detection limit should be qualified as not detected and the adjusted

detection limit reported and qualified (UJ) Sample results greater than the

adjusted detection limit should not be qualified and the original detection limit

should be reported These criteria were applied to raw data for sediment

samples since raw data for aqueous blank samples and solid matrices are

presented in the same relative units

A total of 16 analytes were identified as blank contaminants in the four data

packages Raw data for the highest contaminant concentrations detected for the

blank sample within each data package are presented in Table I along vdth

action values representing five times the positive contaminant concentrations

Samples with reported analyte concentrations less than these action values were

reported as not detected with the original concentration reported as the adjusted

analytical detection limit and qualified (UJ) Sample concentrations greater

than these action values were accepted (A) Blank actions were not necessary

for samples in which blank sample contaminants were not detected

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 5

Analytes for some blank samples were reported by the laboratory as negative

concentrations Negative concentrations that have an absolute value greater

than the IDL may adversely affect quantitation for these analytes The most

negative concentrations are reported in Table I Associated sample results were

qualified as approximate (J) and the detection limits were qualified (UJ) for

samples in which the analytes were not detected

ICP INTERFERENCE CHECK SAMPLE

The ICP check sample (ICS) data were reviewed to assess the analytical

correction factors used during an ICP analysis run The guidelines require that

an ICS be run at the beginning and end of each analysis run or at least two

times during each 8-hour shift Results of the ICS analysis (Form IV) must be

v^dthin + 20 of control limits Calculations from raw data should be verified

In the review of the ICS data sheet recovery data were found to be wdthin

control limits and no data qualification actions were necessary An ICS was

analyzed at the beginning and end of each analysis run and in some instances

exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS

recoveries were recalculated from raw data and laboratory results were

confirmed for aluminum barium beryllium calcium cobalt chromium copper

iron magnesium manganese nickel potassium selenium silver vanadium and

zinc

LABORATORY CONTROL SAMPLE

In accordance with the guidelines laboratory control sample (LCS) results were

reviewed to determine whether the percent recovery (R) fell within the

specified control limits Control limits in aqueous matrices are specified as 80 to

120 percent for each analyte except antimony and silver for which control limits

are not established Control limits for solid matrices are specified for analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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p p

r P p p p p p p p p F P P CV P P F P P F P P

cfrraquo c LABORATORY QUALIFIERS

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

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P P F P P P P P P P P F P P CV P P F P P F P P

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

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3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

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E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 5: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 5

Analytes for some blank samples were reported by the laboratory as negative

concentrations Negative concentrations that have an absolute value greater

than the IDL may adversely affect quantitation for these analytes The most

negative concentrations are reported in Table I Associated sample results were

qualified as approximate (J) and the detection limits were qualified (UJ) for

samples in which the analytes were not detected

ICP INTERFERENCE CHECK SAMPLE

The ICP check sample (ICS) data were reviewed to assess the analytical

correction factors used during an ICP analysis run The guidelines require that

an ICS be run at the beginning and end of each analysis run or at least two

times during each 8-hour shift Results of the ICS analysis (Form IV) must be

v^dthin + 20 of control limits Calculations from raw data should be verified

In the review of the ICS data sheet recovery data were found to be wdthin

control limits and no data qualification actions were necessary An ICS was

analyzed at the beginning and end of each analysis run and in some instances

exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS

recoveries were recalculated from raw data and laboratory results were

confirmed for aluminum barium beryllium calcium cobalt chromium copper

iron magnesium manganese nickel potassium selenium silver vanadium and

zinc

LABORATORY CONTROL SAMPLE

In accordance with the guidelines laboratory control sample (LCS) results were

reviewed to determine whether the percent recovery (R) fell within the

specified control limits Control limits in aqueous matrices are specified as 80 to

120 percent for each analyte except antimony and silver for which control limits

are not established Control limits for solid matrices are specified for analytes

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

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3 0 0 0 4 Soo

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l i S O R 5^00 Pi h J

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J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

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pound ^ pound ^ g-^ gg bull g gg

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l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

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pound J E L

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g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

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i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

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JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

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IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

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A ^ g i i ^M a ^ t g g g

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

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O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

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J u^

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bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 6: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 6

including antimony and silver on the Form VII data sheets Laboratory

calculation of R should be verified from the raw data

Silver was the only analyte with recoveries outside the specified control limits

In data package No 8904288 which contained the sediment sample analysis

the reported silver recovery of 6 percent was far below the acceptable range

Silver results in data package No 8904288 were reported as less than the

instrument detection limit (IDL) and were qualified as approximate (UJ) This

low silver recovery will be discussed further in the summary Raw data and

reported results were spot checked for transcription errors none were noted

The R for the LCS was recalculated from raw data for over 40 percent of the

analytes reported in the four data packages and the reported results were

confirmed

DUPLICATE SAMPLE ANALYSIS

Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)

to provide an indication of laboratory precision The guidelines establish control

limits of + 35 relative percent difference (RPD) for sediment samples and

+ 20 percent for aqueous sample concentration values greater than five times

the CRDL Control limits for sample concentration values less than five times

the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for

aqueous samples A check of the laboratory RPD calculation should also be

performed according to the guidelines

Duplicate sample comparative results were unacceptable for some analytes in

each of the four data packages The laboratory appropriately flagged these

analytes in several cases as indicated with a below Additional analytes

with unacceptable results were also identified during the data package review

Analytes with unacceptable comparative results included aluminum () arsenic

chromium () manganese () selenium vanadium zinc () and cyanide () in

data package No 8904288 antimony cobalt () nickel and lead in data package

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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p p

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

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E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

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bullJ^^SSL JJL

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f f g g g u u

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f^

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 7: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 7

No 8904271 cobalt lead and zinc () in data package No 8904286 and

antimony and chromium () in data package No 8904324 Reported data for

analytes with unacceptable comparative results in samples associated with a

specific data package were qualified as approximate (J) Laboratory calculations

of RPD were recalculated for each analyte and reported results were confirmed

It should be noted that the laboratory performed a cyanide reanalysis for sample

SD-Sl-001 because of poor duplicate RPDs Although the sample holding time

had passed the reanalysis concentration was only slightly lower than in the

reported initial analysis and duplicate RPDs were acceptable This suggested

that the original cyanide result was acceptable despite the anomalous RPD The

reanalysis confirmed the results of the initial analysis therefore initial analysis

data for sample SD-Sl-001 was reported in the validated data tables

FIELD DUPLICATES

Field duplicates were submitted and analyzed as a measure of field and

laboratory precision Duplicate results were assessed in terms of general

comparability although specific review criteria and actions are not established in

the guidelines The RPD criteria used for assessing inorganic laboratory

duplicate samples were also used to compare data for sets of field duplicates

The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had

comparable results for analytes where RPD calculations were possible The only

significant differences between analyte concentrations were for sodium zinc and

cyanide and these analjd^es were previously qualified due to other factors

identified in the quality control review Therefore no additional data

qualification actions were taken

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

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P P F P P P P P P P P F P P CV P P F P P F P P

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

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PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

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LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 8: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 8

The aqueous field duplicates included the follovnng sets of samples

GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and

SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the

+ 20 percent RPD criterion applied to laboratory duplicate samples indicating

that precision was acceptable

MATRIX SPIKE SAMPLE

The results of matrix spike sample analyses (Form V) were reviewed to assess

potential sample matrix effects Spike recoveries (R) must be vdthin the limits

of 75 to 125 percent of the individual spike concentrations according to the

guidelines unless the sample concentration exceeds the spike concentration by a

factor of four or more The spike recovery should also be recalculated from raw

data to assess laboratory reporting

Matrix spike recoveries were outside the specified windows for antimony

chromium manganese and silver in data package No 8904288 silver thallium

and zinc in data package No 8904286 cadmium silver and zinc in data

package No 8904271 and silver in data package No 8904324 Results for

analytes detected at concentrations greater than the instrument detection limit

(IDL) and with R greater than 125 percent or less than 75 percent were

qualified as approximate (J) Results for non-detected analytes were accepted

(A) if the R exceeded 125 percent however the corresponding detection limits

were qualified as approximate (UJ) if the R was less than 75 percent

Reported recoveries for the anal3^es discussed above and specific actions applied

to samples associated with the affected data packages are presented in Table II

FURNACE ATOMIC ABSORPTION QUALITY CONTROL

Furnace AA quality control (QC) data were reviewed to assess precision and

accuracy of the individual analytical results for lead arsenic selenium and

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

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PAGE _5 of IP

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y5Oegt 3 = i ^ (A W

^ B IOO L L

pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

EE ^iSe

ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 9: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 9

thallium which were the only HSL inorganic parameters analyzed by furnace AA

techniques In accordance with the guidelines samples must be reanalyzed once

if initial duplicate injections result in a percent relative standard deviation

(RSD) in excess of + 20 percent In addition spike recoveries must be in the

range from 85 to 115 percent and samples requiring the Method of Standard

Addition (MSA) should have correlation coefficients greater than 0995

Results for duplicate injections were found to be within the range of

+ 20 percent RSD in each of the four data packages Spike recoveries were

found to be beyond the acceptable range for analytes presented in Table III

Because sample absorbances for each affected sample were less than 50 percent

of the post digestion spike absorbance results for these analytes greater than

the IDL were qualified as approximate (J) and the detection limits for

undetected analytes were qualified as approximate (UJ) The Method of

Standard Addition (MSA) was performed for lead on samples SD-Sl-001

SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation

coefficient was less than 0995 for sample GW-MW16D-027 and the lead result

for this sample was qualified as approximate (J)

ICP SERIAL DILUTION

This parameter was evaluated to assess whether physical or chemical matrix

interferences may have affected sample results The guidelines state that

results of the serial dilutions must agree within a 10 percent difference (D) of

the original results (Form IX) The D should also be recalculated from raw

data

The D between initial results and serial dilution results were checked

Analytes met the D criterion with the exception of magnesium and sodium in

data package No 8904286 and manganese in data package No 8904288 which

were appropriately flagged with an E by the laboratory This flag signified

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

p p

r P p p p p p p p p F P P CV P P F P P F P P

cfrraquo c LABORATORY QUALIFIERS

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^ ^

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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LABORATORY QUALIFIERS

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oao alaquo-6o

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ltroo ^OOddO

Qoo ] r oo s-oc

u M w U ( i u

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u U R ] ^ tJ ws^

pound U A tA A Ashy

ltltoc M

55 00 Oi

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lOOft

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3oodu ^bull(Jp u

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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

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n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

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bull Soo LL l QO

Q O UshyLL

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jpoundkSE

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l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

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Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 10: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 10

that the concentrations were estimated due to interferences noted during the

dilution analyses Results for the three analytes were qualified as approximate

(J) for each sample in the corresponding data packages The D for analytes

outside criteria were recalculated from raw data and reported laboratory results

were confirmed The D of other analytes were recalculated from data on the

Form IX data sheet and laboratory calculations were found to be correct

SUMMARY

The most noteworthy analytical problems concerned sediment samples Holding

times were not met for cyanide and mercury analyses based upon POP criteria

and matrix interferences resulted in some very poor recoveries The LCS

recovery in the sediment matrix was poor for the silver analysis However

given that the MSMSD recovery for silver was close to acceptable limits the

LCS results were considered insufficient to qualify the data as rejected (R) and

instead the detection limits were reported as approximate (UJ) Duplicate

recoveries were also in some instances very poor resulting in the reanalysis of

cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis

was comparable to that of the original analysis the original data were judged as

representative of the sample and qualified as approximate (J) Laboratory blank

contamination resulted in the adjustment of detection limits for a total of

10 analytes

Data qualifications for analytes in the aqueous samples were not as extensive

and were largely the result of laboratory blank contamination and recoveries

outside of specifications in the matrix spike and duplicate analyses Detection

limits were adjusted for a total of 15 analytes in response to blank

contamination Reported negative concentration values for blank samples also

required data qualification action Furnace AA QC and the ICP serial dilution

data in some cases were not within control limits Unvalidated laboratory data

and validated data are provided in Tables IV and V respectively

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

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l^afgte ^v-7n

l 60 J00

Q-i^aooo f i 0 6 bullS f ih KOO

oyoo b f ) ^ O t )

H m o t c a S7Vlt9 A r t

n l U i plaquor6f

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u IJ ugt

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bulls-oo l i O O I OO

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1 4 0 0 s yo

3 f ) lt 0 M l i jlter

o n o fps-en

S(J4o rraquo l o n

Soo ^9raquoex60 ^ t j oo

s-oa is - oo l o o o

(J f l II-

A6 11 u

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LI

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^ u A J j J

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Xiiro i c o n

5 0 O G2JD

a r o c VraquofiT5pOn

gtoo s oo

h^^opoo Vdo

lS-on l ^ o o lOOO

u egtU u U

iiishyfi u

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uIALA

a I lLlt

UJ

U)

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N pound hJ

^ ^

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

O

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3SOO IOO 100

lOT^bOCtC i n on 5O0C

^oc 5ffeoc

oOO

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as on laogfxy

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lA

ugt

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A

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bull=^5-0C loc IOO

Qr^nto on IfiOO a^c ltac

^Oinr^n Ofcd

oHnor JltJ^laquo

0 A 6

4gt3roo r^rtSood

I OA fTOO

^afeoeo I40O

Soo ^ i ^ O

)CgtOD

u M u l i tx A

i A u R

It M 4 Ai t^

6

n _L1

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t o f

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5 5 0 0 if00 Jloo

bullzsoD l-oo IOO

imoooA loop

3 O 0 Soo

3 S iOe i

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copyao J 5- Ofl

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Hioo

u a u l i

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laquoJ

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^

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oo too

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copypoundlaquo 5 0 0

J9r06firtr) 3 f i f t

bullSlriOrtC MltJW00C

oao alaquo-6o

^ l ^0 66 IOO

ltroo ^OOddO

Qoo ] r oo s-oc

u M w U ( i u

u Li l

tt R wp

u U R ] ^ tJ ws^

pound U A tA A Ashy

ltltoc M

55 00 Oi

S i ^6 fffe oo

oo i)OOrtO0

lOOft

L u

R (i D IJ

3oodu ^bull(Jp u

^r-SEi R ^ 0 0

HlhOOo 333 oo

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^

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N FMJJ

N

1

3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

S2^3QAJ0pound1 i yg f f t

ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

y5Oegt 3 = i ^ (A W

^ B IOO L L

pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

EE ^iSe

ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 11: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 11

Data in this package were found to generally meet the Data Quality Objectives

(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions

Phase I report In these references specific data quality requirements for the

Mottolo site were outlined The review of consistency with DQOs focused on the

following areas contaminants of concern analytical methods detection limits

and data precision accuracy and completeness It should be noted that the

DQO criteria presented in the Scoping of Response Actions Phase I report were

for volatile organic compounds Similar criteria obtained from DQO guidance

documents were used to assess data for inorganic parameters

The contaminants of concern in this data package were the HSL inorganic

compounds and cyanide Analyses were performed by CAA using CLP protocols

and methodology presented in the SOW in accordance with the DQOs

According to the DQOs the Contract Required Detection Limits (CRDLs) defined

in the SOW were to be utilized as the analytical detection limits The detection

limits achieved were adjusted for some analytes based upon the quality control

review but the adjustments were consistent with the criteria presented in the

validation guidelines It should also be noted that the CLP SOW acknowledges

that detection limits are highly dependent on matrix effects and may require

adjustment

Data precision and accuracy were addressed during the validation review process

of samples in the four data packages Laboratory precision and accuracy were

assessed in terms of spike recovery performance Most MSMSD recoveries

found to be unacceptable were just beyond the windows presented in the

validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)

for analysis of these spiked samples were comparable to historical CLP

laboratory values presented in the EPA data quality objectives guidance

MSMSD recoveries for manganese and silver in one data package each were

further outside the windows and were not comparable to historical CLP values

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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LABORATORY QUALIFIERS

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S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

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R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

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pound ^ pound ^ g-^ gg bull g gg

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f f lP JLVff f tOg A

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g y o J L 35 1 go J

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SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

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f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

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i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

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jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

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3^5^ fgtP f57W

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 12: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Balsam Project 6185814 November 21 1989 Page 12

The objective for data completeness stated in the Scoping of Response Actions

Phase I report was to obtain a minimum of 85 valid data This objective was

achieved in this data package as nearly 100 of the data were judged to be

valid

tb2161

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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LABORATORY QUALIFIERS

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S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

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R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

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pound ^ pound ^ g-^ gg bull g gg

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f f lP JLVff f tOg A

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g y o J L 35 1 go J

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SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

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f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

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i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

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jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

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3^5^ fgtP f57W

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 13: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

Resul ts

Blank Contaminants

Aluminum

Antimony

Calcium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Nickel

Potassium

Selenium

Silver

Sodium

Vanadium

Zinc

TABLE I

BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^

Da ta Package^

No 8904288 No 8904286 No 8904271

15263(76)

46(23)

-790

- - 476(238)

127(64) - 149(74)

294(148) 762(381) 708(354)

- - 22(11)

931(466) - 1860(930)

53(27) - 111(56)

258(129) -350 355(178)

2567(1284) -2430 3525 (1763)

15(8) 15(8) -

72(36) 79(40) 55(28)

-760 3485(1743) 2915(1458)

- - 242 (121)

_ - 197(99)

No 8904324

56(28)

-

55(28)

294(147)

-

845 (423)

53(27)

268(134)

1471(736)

10(5)

-70

3378(1689)

-

-

NOTES

1 Action values represent the raw sample results multiplied by five

2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)

Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes

Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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LABORATORY QUALIFIERS

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

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R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

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bullJ^^SSL JJL

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 14: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE n

MATRIX SPIKE ACTIONS

Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL

No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J

No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J

No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J

No 8904324 Silver 716 UJ

NOTES

A = Accept data as reported by laboratory

J = Data qualified as approximate as a result of quality control review

UJ = Detection limit qualified as approximate as a result of quality control review

IDL = Instrument detection limit

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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H K~ e

u u s u 14 N

^ u A J j J

u u N i f shyu

gt1I006 Q0O S 9 0

6 Soo I O O I OO

l ( ^ V 0 O 0 0 10 DO 9gtt^n

V 0 0 lObCrs

Xiiro i c o n

5 0 O G2JD

a r o c VraquofiT5pOn

gtoo s oo

h^^opoo Vdo

lS-on l ^ o o lOOO

u egtU u U

iiishyfi u

KUu u u

uIALA

a I lLlt

UJ

U)

icJ E

N pound hJ

^ ^

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

O

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3SOO IOO 100

lOT^bOCtC i n on 5O0C

^oc 5ffeoc

oOO

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as on laogfxy

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Qotgt l ^ o o llt^ 0 0 OiOO

u u M u U U

U

u i

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u u R U

U M T T

lA

ugt

^

y AJW

A

fl-^od LI on 0 0 0

bull=^5-0C loc IOO

Qr^nto on IfiOO a^c ltac

^Oinr^n Ofcd

oHnor JltJ^laquo

0 A 6

4gt3roo r^rtSood

I OA fTOO

^afeoeo I40O

Soo ^ i ^ O

)CgtOD

u M u l i tx A

i A u R

It M 4 Ai t^

6

n _L1

uJ

t o f

(0 V ^ A A 7

5 5 0 0 if00 Jloo

bullzsoD l-oo IOO

imoooA loop

3 O 0 Soo

3 S iOe i

IZSOoo Siesoo

copyao J 5- Ofl

I3 i 0r tlaquo Joo

Sraquoo( n 0000

Hioo

u a u l i

u u

u p uft u ft

laquoJ

u bullR t lgtlaquo

^

U l ^ o d U ffOO U ld ocL

W

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A W

Ashy

5-5- OC l OO

W-SS-oo bullraquogts oo

oo too

tgtgt0000 oofl

copypoundlaquo 5 0 0

J9r06firtr) 3 f i f t

bullSlriOrtC MltJW00C

oao alaquo-6o

^ l ^0 66 IOO

ltroo ^OOddO

Qoo ] r oo s-oc

u M w U ( i u

u Li l

tt R wp

u U R ] ^ tJ ws^

pound U A tA A Ashy

ltltoc M

55 00 Oi

S i ^6 fffe oo

oo i)OOrtO0

lOOft

L u

R (i D IJ

3oodu ^bull(Jp u

^r-SEi R ^ 0 0

HlhOOo 333 oo

(33C 0 5 0 0

J ^ O O d O A 60 ^-ao

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in fl

u M

R Llt

Vcdu 1^00 22S) lopo

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^

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N FMJJ

N

1

3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

S2^3QAJ0pound1 i yg f f t

ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

y5Oegt 3 = i ^ (A W

^ B IOO L L

pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

EE ^iSe

ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 15: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium

GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X

GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X

GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X

GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X

GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X

GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X

November 21 1989 Balsam Project 61852161

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

mdash n^TL-6(0-M OflOR-605 r r ) r L - ( ^ i i ) - M t ^ A s ITtTL -6gttJ3shy jyi^pS^aaa mTi - f eoshy VgtOii^r rOJO

__ 1 nrr^a-nci)nD-ajM

Inorganic Elements bullmU^

bull

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

p p

r P p p p p p p p p F P P CV P P F P P F P P

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u u s u 14 N

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6 Soo I O O I OO

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V 0 0 lObCrs

Xiiro i c o n

5 0 O G2JD

a r o c VraquofiT5pOn

gtoo s oo

h^^opoo Vdo

lS-on l ^ o o lOOO

u egtU u U

iiishyfi u

KUu u u

uIALA

a I lLlt

UJ

U)

icJ E

N pound hJ

^ ^

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

O

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S = Reported value was determined by the Method of Standard Addition (MSA)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

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l i S O R 5^00 Pi h J

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J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

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SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

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f r pQ BH U lampL 2Q0 4L

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bdquo g t g z y g g

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SMJSQ 7raquo0 t0g

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3 P V A ( X - a g g raquo j t t _ i L

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3^5^ fgtP f57W

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LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 16: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

BALSAM ENVIRONMENTAL CONSULTANTS INC

TABLE III (Continued)

FURNACE ATOMIC ABSORPTION QC ACTIONS

Analytes Outside Cr i te r ia

Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium

GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X

GW-DUP-041 X X X GW-DUP-042 X X

SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X

SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X

SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X

SD-S9-004 X SD-DUP-009 X

NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected

November 21 1989 Balsam Project 61852161

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

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N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

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Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

S2^3QAJ0pound1 i yg f f t

ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

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^ B IOO L L

pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

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ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 17: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME

PROJECT NUMBER

PAGE _ of ^

Sample Locat ion Sample Number

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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r

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cfrraquo c LABORATORY QUALIFIERS

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N = Spiked sample recovery not within control limits

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= Duplicate analysis was not within control limits

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

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U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 18: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)

^ j o H ^ ^ ^ PROJECT NAME

PROJECT NUMBER

PAGE ^ o i lyt

Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP

1 -OLJI1

Inorganic Elements

Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA

P P F P P P P P P P P F P P CV P P F P P F P P

(U

LABORATORY QUALIFIERS

O

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3SOO IOO 100

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1

3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

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ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

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pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

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IOO u W S-eo

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55oo

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bull Soo LL l QO

Q O UshyLL

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M ^ amp

jpoundkSE

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3Z 5 cn -E 0 0 s M-^shy

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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

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i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

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u M

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JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 19: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)

^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^

PAGE _5 of IP

Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO

Inorganic Elements

Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI

MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^

^i4Sltgt-oo k hJ

M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

65oo rHs 4^qiTic 3^-qg LL

LL

g^7Pft poundL goc LL 3floru S L C L LL

6ooo cgfOQ

S2^3QAJ0pound1 i yg f f t

ggC-Lt bull bullfaff 0 0 ti b S b C C

n^IyZS SIM ^gftrxo ^bull^-yenshy

Noo L N W-OQ ^vQO (j A^ orod L4

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pound(1 tL aH^o66o

IgiOf) s Sooe LL

gpoundpound LL 3^r00 22s E 5AZ

id^naoi mg s ^ jampiSfi

9S(gto LL 3 Q pgHOtWA

IOO u W S-eo

^apofi u ^ 0 0 V T N

^bulloo XL 7 5 ^ urjy^ ooa Mshy

55oo

2bull 0 0 i ^ LL

bull Soo LL l QO

Q O UshyLL

^ SL 35 iCCQ i ^

M ^ amp

jpoundkSE

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ay-Ofi UshyLL ^^gpoc

l i Q O EL 5-PQ U ll

3Z 5 cn -E 0 0 s M-^shy

J S L M J t jroo 1 0 0 0 LL

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 20: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h

PAGE _ ^ of ^

Sample Location Sample Number

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C

LABORATORY QUALIFIERS

bull

l ^ l f l i ) m )ilaquors - ^ r

Seuroob u 5-0C ft w Qoo u

^f0O u 0 0 u 0 0 u

h2aoai noo ^

3 0 0 0 4 Soo

blt4co lt J 8 0 w

ISWOft s E i ^ ^ f i r

0 3 0 Mp^frs (J gtISDOO ^

l i S O R 5^00 Pi h J

bull^aoQfv^ bull F 1

J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J

R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S Reported value was determined by the Melhod of Standard Addition (MSA)

- Duplicate analysis was not within control limits

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 21: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

^0i3Z^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)

4rouydugtatir PROJECT NUMBER C f l f 0 f ^

PAGE s c)f f x gt

Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2

Inorganic Elements

Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo

LABORAIORY QOALIFIERS

Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (USA)

= Duplicate analysis was not within control limits y y

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 22: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^

Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H

Inorganic Elements

Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS

fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N bull- Spiked sajple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bullJ K P f dv^iT^

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 23: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER

PAGE ^ of ^

Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^

Inorganic Elements

Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS

0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

- Ouplicate analysis was not wittyn control limits bdquo

Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 24: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^

PAGE _g_ of [(f

Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio

Inorganic Elements

Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa

2232pound 7 mdash HQQ ZOO

^ t P O O

AL bull r

2 raquo o e o i t ^ e 3 g e g _fcL

pound ^ pound ^ g-^ gg bull g gg

^g OO plusmn ^ ^ O

g g o LL r og

l 3 i Q Q Q A g g K

f f lP JLVff f tOg A

LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A

pound J E L

^ i gt o tOO

M ^ U LJ

ggg JL a p g p

JL ^ t W yshy

Jt3poundeupoundiamp t t c

JUL Mij6upound6

Z P g Jl llaquo2 fvaraquogo s i f g

g y o J L 35 1 go J

IS lQQd S o LL

SraquoPff unr t ^ te oO Vtgltgt iL

bullJ^^SSL JJL

^ IZ

raquo bull raquo raquo

f r pQ BH U lampL 2Q0 4L

3flaquoltgtltgt g g

l i _

A^pound U Wt2OD0

JpoundxUL A

-90 06 U Xufipound i L

i lt f ^ 00 tA S-Z^2fi

7g57 ^ f i g

bdquo g t g z y g g

I I

jpound10iJSeL APg 5_SI

SMJSQ 7raquo0 t0g

u M

igtgg t S t P Q Z7VP o gQ is

JIMM 10 0 U h) Zdo JUL

I S E S A o g n o p u

3 P V A ( X - a g g raquo j t t _ i L

^ ^ 2 pound

3^5^ fgtP f57W

y i o o Q i i o W P O

g tt g f g g

Ik t o 9 P ^

iS r-VM

SS^Tfi graquo ltro^ IL

jSxpound2 J L

i t lP g g o _feL

z z-fog JLQtL U U) JL f ig U

arg^ g e

^

l C O 3 t i g As

IL g r g g I H i 1L_

Li2flL i L

f f g g g u u

zuraquo^o g f g g

ygtog laquo_ S h l O p O

A ^ g i i ^M a ^ t g g g

f^

vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L

LABORATORY QUALIFIERS

p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S bull- Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits bdquo

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 25: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q

PAGE ^ of ^

Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf

Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI

g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH

Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO

u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s

Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS

Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 26: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

0

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -

PAGE I0_ of pound

Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh

Inorganic Elements

Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium

IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO

Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P

irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL

Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-

bull ^

intor) LL LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U - Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sample recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 27: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER

PAGE of ^

Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^

Inorganic Elements

Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL

t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a

Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL

P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO

LABORATORY QUALIFIERS

= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S - Reported value was determined by the Method of Standard Addition (MSA)

= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 28: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H

PAGE R of ^

Sample Location Sample Number VATUampltP-YA^^^S-0-2)

bull

Inorganic Elements

Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy

^ 0 O

ioo i O G

s^^ao l o a o o

^ pound lt f f O O O C O O

3 ^ 0 0 I ^ ^ 0 0

3 f S Q SLea

V4 00 Too 0 Z 0

Z S O i S 3 o a

O O

soo Z ^ c o 0 0

^ D O S O Q i o o o o o

u - I A UJ

A lA U ^ U A

u ^ ^

bull u bull ^

Uu Af^ u 1 A J

Ip i u u

J u^

V

bull bull 1

bull

J

LABORATORY W I F I E R S

3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= nniiratp anilv5is was not within control limits A I

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 29: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^

pprv PROJECT NUMBER CgtlS J E

PAGE J2 )0 i IJpound

Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2

Inorganic Elements

Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^

MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^

Jis iRrOUALf LABORATORY^QUALIFIERS

R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)

CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected

E = Reported value is estimated because of the presence of interference

N = Spiked sasple recovery not within control l imits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 30: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^

PAGE ^ of lppound

Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor

Inorganic Elements

Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o

utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO

Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS

R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)

U = Analyte was analyzed for but not detected

E - Reported value is estimated because of the presence of interference

N = Spiked saaple recovery not within control limits

S = Reported value was determined by the Method of Standard Addition (MSA)

= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 31: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V

VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005

Inorganic

-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull

Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)

Cyanide (lOOU) (10OU) (1000) (100U) (10OU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 8

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 32: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V (Continued)

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS

Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010

Inorganic

Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)

Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)

DATA QUALIFIERS

- shy Not detected J - Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 33: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

HH7S GW-MW7S-011

MW7D GW-HW7D-012 GW-HW8S-013

MW9S 6W-HK9S-015

HW9D GH-HW9D-016

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc

3410

391

14500

(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)

3710 (550U) - (40U)

52J (20U) - (350U) - (lOU) - (lOUJ)

18800J (700U) - (lOOU)

379J (300U) - (50U) - (381UJ)

28J (20U) - (700U) - (50U) - (020U) - (250UJ)

48800J (1450U) - (lOU) - (50UJ)

68800J (60GU) - (40U) - (150U) - (150UJ)

--

168 ---

7900 ---

1520 -

2350 2670 --

5000 --

5150 ---

(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)

487 ----

28J 1540J -

373J --

36J 861J 225 -

126J 709J --

3360J ---

(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)

194 -----1920 ---

862 --

108 -----

3720 ---

(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)

Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)

DATA QUALIFIERS

- shy Not detected J = Data approximated as a result of quality control review

(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R shy Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 34: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185

HSL INORGANIC ANALYSES (Concentrat ions in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021

Inorganic

Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)

Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

rage 4 Ol 8

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 35: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V (Continued)

VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)

Balsam Project 8185

MOTTOLO RIFS RAYMOND NH

Sample Location Sample Number

Inorganic

MW13D GW-MW13D-022

HW13D GW-DUP-038 Duplicate

HW14 S GH-HW14S-023

HW14D GW-MW14D-024

HW15S GH-KW15S-025

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

_

-

26 ---

24400 -----

4080 838 --

2960 --

4880 --

IIOJ

(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)

_

-

26 ---

24100 -----

3810 726 --

3050 --

4940 --

178J

(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)

-

-

47 ---

17500 ---

546 -

2980 612 --

3750 --

8410

--

(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)

-

-

23 ---

25100 -----

3460 632 --

4130 --

8210 ---

(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)

-

50J ----

6220J ----

28J 1540J 1450 --

3150J --

(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)

32000J (600U) ---

(40U) (15OU) (150UJ)

Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)

DATA QUALIFIERS

- shy Not detected J shy Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 5 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 36: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028

Inorganic

Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)

Cyanide (1000) (1000) (1000)

DATA QUALIFIERS

- ^ Not detected J = Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

MW18S HW18D GW-HW18S-029 GH-HW180-030

- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)

114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)

30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)

1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)

1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)

11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)

(10OU) (1000)

Page 6 of 8

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 37: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)

HOTTOLO RIFS RAYHOND NH

Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042

Duplic ate Duplicate Inorganic

Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)

Cyanide (1000) (1000) (1000) (lOOU) (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 7 of 8

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 38: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V (Continued )

VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035

Inorganic

-

Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)

Aluminum 202 (5500) (5500)

- bull

Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)

Cyanide - (10OU) - (1000)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 8 Oi 8

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 39: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V ( C o n t i n u e d )

Balsam Project 8185

HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009

Ouplicate Inorganic

Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy

Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)

Cyanide (1000) (1000) (1000) (1000) (lOOU)

DATA QUALIFIERS

- = Not detected J - Data approximated as a result of quality control review

(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 1 of 3

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 40: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

- -

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)

MOTTOLO RIFS RAYMOND NH

cSample Location S5 S8 V 7 S 3 S^

Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004

Inorganic

Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)

Cyanide (1000) (1000) (1000) (1000) (1000)

DATA QUALIFIERS

- - Not detected J - Data approximated as a result of quality control review

(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 2 of 3

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 41: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE V ( C o n t i n u e d )

VALIDATED DATA - PHASE HSL INORGANIC ANALYSES

I SURFACE WATER SAMPLING (Concentrations in PPB)

- Balsam Project 6185

HOTTOLO RIFS RAYHOND NH

Sample Location Sample Number

SIO sw-silO-010

Inorganic

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

129 -----

13100 12 OJ --

546 -

1970 268

--

5610 --

3720 --

215

(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)

Cyanide shy (1000)

DATA QUALIFIERS

- -- Not detected J - Data approximated as a result of quality control review

(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

NOTE

Samples were filtered in the field using a 045 micron filter

Page 3 of 3

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 42: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

T A B L E V ( C o n t i n u e d )

VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)

MOTTOLO RIFS RAYHOND NH

Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005

Inorganic

Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)

Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)

Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)

DATA QUALIFIERS

- -shy Not detected J - Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review

R - Data rejected as a result of quality control review

Page 1 of 2

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2

Page 43: PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits. Calculations from raw data should be verified. In the review of the ICS data sheet, recovery

TABLE IV (Continued)

VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)

Balsam Project 6185

MOTTOLO RIFS RAYMOND NH

Saaple Location Sample Number

Inorganic

S5 SD-DUP-009 Duplicate

S6 SD-S6-006

S9 SD-S9-004

SIO SO-SlO-008

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc

1230J 14J 19J ---

297 ---

1480 26 308 161J -----

949J --

60J

(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)

2050J -

13J 198 --

807 ---1900 47 367 530J -----

896J --

157J

(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)

8120J -

42J ---

388 63J --

6130 121 624 301J -----

106J -

65J 199J

(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)

7220J -

807J 448 -

30 8980 -

732 -

69900 269 1030

(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)

11800J (500) -- ---

261J -

334J 158J

(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)

Cyanide 70J (170) - (19U) 41J (190) 86J (59U)

DATA QUALIFIERS

- = Not detected J = Data approximated as a result of quality control review

(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review

R = Data rejected as a result of quality control review

Page 2 of 2