PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits....
Transcript of PHASE 1 GROUND WATER, SURFACE WATER AND SEDIMENT … · v^dthin + 20% of control limits....
L^ - BALSAM ENVIRONMENTAL CONSULTANTS INC
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BREAK OTHER ^f^ f n - ^
MEMORANDUM
SDMS DocID 469107 TO File
FROM Stefan C Sokol gt ^
Mindi F Jacobs P
DATE November 21 1989
SUBJECT Mottolo Site shy Balsam Project 6185814 Phase I Ground Water Surface Water and Sediment Sampling Data Validation - Inorganics Analyses
The four data packages under evaluation consisted of 48 aqueous samples and
nine sediment samples from the Mottolo Site which were analyzed by Cambridge
Analytical Associates (CAA) for the Hazardous Substance List (HSL) inorganic
parameters including cyanide The analyses were performed in accordance with
the US Environmental Protection Agency (EPA) Contract Laboratory Program
(CLP) Statement of Work (SOW) for Inorganics Analyses A validation of the
data was performed using criteria established in the Mottolo Project Operations
Plan (POP) and the EPA document Laboratory Data Validation Functional
Guidelines for Evaluating Inorganics Analyses dated July 1988 and
subsequently referred to as guidelines in this memorandum The parameters
evaluated in review of the data package included
0 integrity and completeness of the data package
0 holding times
0 initial and continuing calibrations
0 laboratory blank samples
0 ICP interference check sample
0 laboratory control sample
duplicate sample analysis 0
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 2
0 field duplicates
0 matrix spike sample
0 furnace atomic absorption Quality Control and
0 ICP serial dilution
INTEGRITY AND COMPLETENESS OF THE DATA PACKAGE
Inorganics data were reported by CAA in four discrete data packages and were
evaluated accordingly in this review The data packages are referred to by the
following work orders No 8904288 No 8904286 No 8904271 and
No 8904324
The case narrative by CAA noted poor reproducibility for laboratory duplicate
analyses of cyanide in sample SD-Sl-001 however the sample was not
reanalyzed by CAA until well after the holding time was past Data for both
analyses were reported separately Review of the data packages indicated that
sufficient data were present to perform the data assessment summarized in this
memorandum
HOLDING TIMES
Holding times were assessed in terms of the SOW and the Mottolo POP criteria
The maximum acceptable holding time specified in the POP from sample
collection to analysis was 14 days for cyanide analyses and 28 days for mercury
analyses The same holding times were established in the SOW but were based
upon aqueous matrices and measurement of time from the date of sample
receipt at the laboratory to the date of analysis Other HSL inorganics must be
analyzed within 6 months from sample collection or from sample receipt to
analysis according to the POP and SOW respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 3
Cyanide analyses for the nine sediment samples exceeded the POP holding time
criteria with analyses performed 32 days after sample collection Holding times
for cyanide analyses in sediment matrices were based upon holding times in
aqueous matrices in which cyanide stability is highly dependent on pH Based
upon conversations with the analytical laboratory it was judged that cyanide
would be more stable in a sediment matrix and that substantial degradation
within this time frame would be unlikely Detected cyanide concentrations for
samples of this matrix were qualified as approximate (J) Holding times for
cyanide analyses of the aqueous samples ranged from six to eight days from
sample collection and were v^dthin the maximum allowable holding time
Mercury analyses for the nine sediment samples were performed 33 days after
sample collection and exceeded the holding time criteria by five days No
actions will be taken with regard to these samples since mercury was not
detected Mercury analyses for aqueous samples were performed from 8 to
25 days after sample collection and were within the maximum allowable holding
time
Holding times for the other inorganic parameters in sediment and aqueous
matrices ranged from 4 to 47 days from sample collection to analysis and were
within the six month holding time limit
INITIAL AND CONTINUING CALIBRATIONS
In accordance with the guidelines a check was made to determine whether the
instruments used to analyze metals were calibrated daily and each time they
were set up The schedule of blank and standard samples used to develop
analytical performance curves for mercury cyanide inductively coupled plasma
(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of
the guidelines Results for calibration standards (Form II) must be within
percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115
percent for cyanide and 90 to 110 percent for other analytes
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Balsam Project 6185814 November 21 1989 Page 4
Initial calibration was performed at the beginning of sample analysis and
continuing calibrations were performed as required during the analysis runs
Analyses were found to have the required number of blanks and standards
Calibrations met the specified R windows
LABORATORY BLANK SAMPLES
Calibration blank and preparation blank data (Form III) were reviewed to
determine the existence and magnitude of possible laboratory contamination
problems The guidelines indicate that sample detection limits should be raised
to five times the concentration detected in any associated blank sample Sample
results greater than the instrument detection limit (IDL) but less than the
adjusted detection limit should be qualified as not detected and the adjusted
detection limit reported and qualified (UJ) Sample results greater than the
adjusted detection limit should not be qualified and the original detection limit
should be reported These criteria were applied to raw data for sediment
samples since raw data for aqueous blank samples and solid matrices are
presented in the same relative units
A total of 16 analytes were identified as blank contaminants in the four data
packages Raw data for the highest contaminant concentrations detected for the
blank sample within each data package are presented in Table I along vdth
action values representing five times the positive contaminant concentrations
Samples with reported analyte concentrations less than these action values were
reported as not detected with the original concentration reported as the adjusted
analytical detection limit and qualified (UJ) Sample concentrations greater
than these action values were accepted (A) Blank actions were not necessary
for samples in which blank sample contaminants were not detected
BALSAM ENVIRONMENTAL CONSULTANTS INC
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Analytes for some blank samples were reported by the laboratory as negative
concentrations Negative concentrations that have an absolute value greater
than the IDL may adversely affect quantitation for these analytes The most
negative concentrations are reported in Table I Associated sample results were
qualified as approximate (J) and the detection limits were qualified (UJ) for
samples in which the analytes were not detected
ICP INTERFERENCE CHECK SAMPLE
The ICP check sample (ICS) data were reviewed to assess the analytical
correction factors used during an ICP analysis run The guidelines require that
an ICS be run at the beginning and end of each analysis run or at least two
times during each 8-hour shift Results of the ICS analysis (Form IV) must be
v^dthin + 20 of control limits Calculations from raw data should be verified
In the review of the ICS data sheet recovery data were found to be wdthin
control limits and no data qualification actions were necessary An ICS was
analyzed at the beginning and end of each analysis run and in some instances
exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS
recoveries were recalculated from raw data and laboratory results were
confirmed for aluminum barium beryllium calcium cobalt chromium copper
iron magnesium manganese nickel potassium selenium silver vanadium and
zinc
LABORATORY CONTROL SAMPLE
In accordance with the guidelines laboratory control sample (LCS) results were
reviewed to determine whether the percent recovery (R) fell within the
specified control limits Control limits in aqueous matrices are specified as 80 to
120 percent for each analyte except antimony and silver for which control limits
are not established Control limits for solid matrices are specified for analytes
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Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
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The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
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Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
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Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
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oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
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lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
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bull Soo LL l QO
Q O UshyLL
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M ^ amp
jpoundkSE
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l i Q O EL 5-PQ U ll
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J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
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2 raquo o e o i t ^ e 3 g e g _fcL
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^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
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pound J E L
^ i gt o tOO
M ^ U LJ
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Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
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3^5^ fgtP f57W
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g tt g f g g
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z z-fog JLQtL U U) JL f ig U
arg^ g e
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IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
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A ^ g i i ^M a ^ t g g g
f^
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LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 2
0 field duplicates
0 matrix spike sample
0 furnace atomic absorption Quality Control and
0 ICP serial dilution
INTEGRITY AND COMPLETENESS OF THE DATA PACKAGE
Inorganics data were reported by CAA in four discrete data packages and were
evaluated accordingly in this review The data packages are referred to by the
following work orders No 8904288 No 8904286 No 8904271 and
No 8904324
The case narrative by CAA noted poor reproducibility for laboratory duplicate
analyses of cyanide in sample SD-Sl-001 however the sample was not
reanalyzed by CAA until well after the holding time was past Data for both
analyses were reported separately Review of the data packages indicated that
sufficient data were present to perform the data assessment summarized in this
memorandum
HOLDING TIMES
Holding times were assessed in terms of the SOW and the Mottolo POP criteria
The maximum acceptable holding time specified in the POP from sample
collection to analysis was 14 days for cyanide analyses and 28 days for mercury
analyses The same holding times were established in the SOW but were based
upon aqueous matrices and measurement of time from the date of sample
receipt at the laboratory to the date of analysis Other HSL inorganics must be
analyzed within 6 months from sample collection or from sample receipt to
analysis according to the POP and SOW respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 3
Cyanide analyses for the nine sediment samples exceeded the POP holding time
criteria with analyses performed 32 days after sample collection Holding times
for cyanide analyses in sediment matrices were based upon holding times in
aqueous matrices in which cyanide stability is highly dependent on pH Based
upon conversations with the analytical laboratory it was judged that cyanide
would be more stable in a sediment matrix and that substantial degradation
within this time frame would be unlikely Detected cyanide concentrations for
samples of this matrix were qualified as approximate (J) Holding times for
cyanide analyses of the aqueous samples ranged from six to eight days from
sample collection and were v^dthin the maximum allowable holding time
Mercury analyses for the nine sediment samples were performed 33 days after
sample collection and exceeded the holding time criteria by five days No
actions will be taken with regard to these samples since mercury was not
detected Mercury analyses for aqueous samples were performed from 8 to
25 days after sample collection and were within the maximum allowable holding
time
Holding times for the other inorganic parameters in sediment and aqueous
matrices ranged from 4 to 47 days from sample collection to analysis and were
within the six month holding time limit
INITIAL AND CONTINUING CALIBRATIONS
In accordance with the guidelines a check was made to determine whether the
instruments used to analyze metals were calibrated daily and each time they
were set up The schedule of blank and standard samples used to develop
analytical performance curves for mercury cyanide inductively coupled plasma
(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of
the guidelines Results for calibration standards (Form II) must be within
percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115
percent for cyanide and 90 to 110 percent for other analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 4
Initial calibration was performed at the beginning of sample analysis and
continuing calibrations were performed as required during the analysis runs
Analyses were found to have the required number of blanks and standards
Calibrations met the specified R windows
LABORATORY BLANK SAMPLES
Calibration blank and preparation blank data (Form III) were reviewed to
determine the existence and magnitude of possible laboratory contamination
problems The guidelines indicate that sample detection limits should be raised
to five times the concentration detected in any associated blank sample Sample
results greater than the instrument detection limit (IDL) but less than the
adjusted detection limit should be qualified as not detected and the adjusted
detection limit reported and qualified (UJ) Sample results greater than the
adjusted detection limit should not be qualified and the original detection limit
should be reported These criteria were applied to raw data for sediment
samples since raw data for aqueous blank samples and solid matrices are
presented in the same relative units
A total of 16 analytes were identified as blank contaminants in the four data
packages Raw data for the highest contaminant concentrations detected for the
blank sample within each data package are presented in Table I along vdth
action values representing five times the positive contaminant concentrations
Samples with reported analyte concentrations less than these action values were
reported as not detected with the original concentration reported as the adjusted
analytical detection limit and qualified (UJ) Sample concentrations greater
than these action values were accepted (A) Blank actions were not necessary
for samples in which blank sample contaminants were not detected
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 5
Analytes for some blank samples were reported by the laboratory as negative
concentrations Negative concentrations that have an absolute value greater
than the IDL may adversely affect quantitation for these analytes The most
negative concentrations are reported in Table I Associated sample results were
qualified as approximate (J) and the detection limits were qualified (UJ) for
samples in which the analytes were not detected
ICP INTERFERENCE CHECK SAMPLE
The ICP check sample (ICS) data were reviewed to assess the analytical
correction factors used during an ICP analysis run The guidelines require that
an ICS be run at the beginning and end of each analysis run or at least two
times during each 8-hour shift Results of the ICS analysis (Form IV) must be
v^dthin + 20 of control limits Calculations from raw data should be verified
In the review of the ICS data sheet recovery data were found to be wdthin
control limits and no data qualification actions were necessary An ICS was
analyzed at the beginning and end of each analysis run and in some instances
exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS
recoveries were recalculated from raw data and laboratory results were
confirmed for aluminum barium beryllium calcium cobalt chromium copper
iron magnesium manganese nickel potassium selenium silver vanadium and
zinc
LABORATORY CONTROL SAMPLE
In accordance with the guidelines laboratory control sample (LCS) results were
reviewed to determine whether the percent recovery (R) fell within the
specified control limits Control limits in aqueous matrices are specified as 80 to
120 percent for each analyte except antimony and silver for which control limits
are not established Control limits for solid matrices are specified for analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
mdash n^TL-6(0-M OflOR-605 r r ) r L - ( ^ i i ) - M t ^ A s ITtTL -6gttJ3shy jyi^pS^aaa mTi - f eoshy VgtOii^r rOJO
__ 1 nrr^a-nci)nD-ajM
Inorganic Elements bullmU^
bull
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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^ ^
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U = Analyte was analyzed for but not detected
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N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
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1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 3
Cyanide analyses for the nine sediment samples exceeded the POP holding time
criteria with analyses performed 32 days after sample collection Holding times
for cyanide analyses in sediment matrices were based upon holding times in
aqueous matrices in which cyanide stability is highly dependent on pH Based
upon conversations with the analytical laboratory it was judged that cyanide
would be more stable in a sediment matrix and that substantial degradation
within this time frame would be unlikely Detected cyanide concentrations for
samples of this matrix were qualified as approximate (J) Holding times for
cyanide analyses of the aqueous samples ranged from six to eight days from
sample collection and were v^dthin the maximum allowable holding time
Mercury analyses for the nine sediment samples were performed 33 days after
sample collection and exceeded the holding time criteria by five days No
actions will be taken with regard to these samples since mercury was not
detected Mercury analyses for aqueous samples were performed from 8 to
25 days after sample collection and were within the maximum allowable holding
time
Holding times for the other inorganic parameters in sediment and aqueous
matrices ranged from 4 to 47 days from sample collection to analysis and were
within the six month holding time limit
INITIAL AND CONTINUING CALIBRATIONS
In accordance with the guidelines a check was made to determine whether the
instruments used to analyze metals were calibrated daily and each time they
were set up The schedule of blank and standard samples used to develop
analytical performance curves for mercury cyanide inductively coupled plasma
(ICP) and furnace atomic absorption (AA) analyses were assessed in terms of
the guidelines Results for calibration standards (Form II) must be within
percent recovery (R) windows of 80 to 120 percent for mercury 85 to 115
percent for cyanide and 90 to 110 percent for other analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 4
Initial calibration was performed at the beginning of sample analysis and
continuing calibrations were performed as required during the analysis runs
Analyses were found to have the required number of blanks and standards
Calibrations met the specified R windows
LABORATORY BLANK SAMPLES
Calibration blank and preparation blank data (Form III) were reviewed to
determine the existence and magnitude of possible laboratory contamination
problems The guidelines indicate that sample detection limits should be raised
to five times the concentration detected in any associated blank sample Sample
results greater than the instrument detection limit (IDL) but less than the
adjusted detection limit should be qualified as not detected and the adjusted
detection limit reported and qualified (UJ) Sample results greater than the
adjusted detection limit should not be qualified and the original detection limit
should be reported These criteria were applied to raw data for sediment
samples since raw data for aqueous blank samples and solid matrices are
presented in the same relative units
A total of 16 analytes were identified as blank contaminants in the four data
packages Raw data for the highest contaminant concentrations detected for the
blank sample within each data package are presented in Table I along vdth
action values representing five times the positive contaminant concentrations
Samples with reported analyte concentrations less than these action values were
reported as not detected with the original concentration reported as the adjusted
analytical detection limit and qualified (UJ) Sample concentrations greater
than these action values were accepted (A) Blank actions were not necessary
for samples in which blank sample contaminants were not detected
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 5
Analytes for some blank samples were reported by the laboratory as negative
concentrations Negative concentrations that have an absolute value greater
than the IDL may adversely affect quantitation for these analytes The most
negative concentrations are reported in Table I Associated sample results were
qualified as approximate (J) and the detection limits were qualified (UJ) for
samples in which the analytes were not detected
ICP INTERFERENCE CHECK SAMPLE
The ICP check sample (ICS) data were reviewed to assess the analytical
correction factors used during an ICP analysis run The guidelines require that
an ICS be run at the beginning and end of each analysis run or at least two
times during each 8-hour shift Results of the ICS analysis (Form IV) must be
v^dthin + 20 of control limits Calculations from raw data should be verified
In the review of the ICS data sheet recovery data were found to be wdthin
control limits and no data qualification actions were necessary An ICS was
analyzed at the beginning and end of each analysis run and in some instances
exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS
recoveries were recalculated from raw data and laboratory results were
confirmed for aluminum barium beryllium calcium cobalt chromium copper
iron magnesium manganese nickel potassium selenium silver vanadium and
zinc
LABORATORY CONTROL SAMPLE
In accordance with the guidelines laboratory control sample (LCS) results were
reviewed to determine whether the percent recovery (R) fell within the
specified control limits Control limits in aqueous matrices are specified as 80 to
120 percent for each analyte except antimony and silver for which control limits
are not established Control limits for solid matrices are specified for analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
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iiishyfi u
KUu u u
uIALA
a I lLlt
UJ
U)
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N pound hJ
^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
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3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
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as on laogfxy
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Qotgt l ^ o o llt^ 0 0 OiOO
u u M u U U
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u u R U
U M T T
lA
ugt
^
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A
fl-^od LI on 0 0 0
bull=^5-0C loc IOO
Qr^nto on IfiOO a^c ltac
^Oinr^n Ofcd
oHnor JltJ^laquo
0 A 6
4gt3roo r^rtSood
I OA fTOO
^afeoeo I40O
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)CgtOD
u M u l i tx A
i A u R
It M 4 Ai t^
6
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t o f
(0 V ^ A A 7
5 5 0 0 if00 Jloo
bullzsoD l-oo IOO
imoooA loop
3 O 0 Soo
3 S iOe i
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copyao J 5- Ofl
I3 i 0r tlaquo Joo
Sraquoo( n 0000
Hioo
u a u l i
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u p uft u ft
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u bullR t lgtlaquo
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U l ^ o d U ffOO U ld ocL
W
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5-5- OC l OO
W-SS-oo bullraquogts oo
oo too
tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
oo i)OOrtO0
lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
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^ B IOO L L
pound(1 tL aH^o66o
IgiOf) s Sooe LL
gpoundpound LL 3^r00 22s E 5AZ
id^naoi mg s ^ jampiSfi
9S(gto LL 3 Q pgHOtWA
IOO u W S-eo
^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 4
Initial calibration was performed at the beginning of sample analysis and
continuing calibrations were performed as required during the analysis runs
Analyses were found to have the required number of blanks and standards
Calibrations met the specified R windows
LABORATORY BLANK SAMPLES
Calibration blank and preparation blank data (Form III) were reviewed to
determine the existence and magnitude of possible laboratory contamination
problems The guidelines indicate that sample detection limits should be raised
to five times the concentration detected in any associated blank sample Sample
results greater than the instrument detection limit (IDL) but less than the
adjusted detection limit should be qualified as not detected and the adjusted
detection limit reported and qualified (UJ) Sample results greater than the
adjusted detection limit should not be qualified and the original detection limit
should be reported These criteria were applied to raw data for sediment
samples since raw data for aqueous blank samples and solid matrices are
presented in the same relative units
A total of 16 analytes were identified as blank contaminants in the four data
packages Raw data for the highest contaminant concentrations detected for the
blank sample within each data package are presented in Table I along vdth
action values representing five times the positive contaminant concentrations
Samples with reported analyte concentrations less than these action values were
reported as not detected with the original concentration reported as the adjusted
analytical detection limit and qualified (UJ) Sample concentrations greater
than these action values were accepted (A) Blank actions were not necessary
for samples in which blank sample contaminants were not detected
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 5
Analytes for some blank samples were reported by the laboratory as negative
concentrations Negative concentrations that have an absolute value greater
than the IDL may adversely affect quantitation for these analytes The most
negative concentrations are reported in Table I Associated sample results were
qualified as approximate (J) and the detection limits were qualified (UJ) for
samples in which the analytes were not detected
ICP INTERFERENCE CHECK SAMPLE
The ICP check sample (ICS) data were reviewed to assess the analytical
correction factors used during an ICP analysis run The guidelines require that
an ICS be run at the beginning and end of each analysis run or at least two
times during each 8-hour shift Results of the ICS analysis (Form IV) must be
v^dthin + 20 of control limits Calculations from raw data should be verified
In the review of the ICS data sheet recovery data were found to be wdthin
control limits and no data qualification actions were necessary An ICS was
analyzed at the beginning and end of each analysis run and in some instances
exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS
recoveries were recalculated from raw data and laboratory results were
confirmed for aluminum barium beryllium calcium cobalt chromium copper
iron magnesium manganese nickel potassium selenium silver vanadium and
zinc
LABORATORY CONTROL SAMPLE
In accordance with the guidelines laboratory control sample (LCS) results were
reviewed to determine whether the percent recovery (R) fell within the
specified control limits Control limits in aqueous matrices are specified as 80 to
120 percent for each analyte except antimony and silver for which control limits
are not established Control limits for solid matrices are specified for analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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__ 1 nrr^a-nci)nD-ajM
Inorganic Elements bullmU^
bull
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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U = Analyte was analyzed for but not detected
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N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
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1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
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h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 5
Analytes for some blank samples were reported by the laboratory as negative
concentrations Negative concentrations that have an absolute value greater
than the IDL may adversely affect quantitation for these analytes The most
negative concentrations are reported in Table I Associated sample results were
qualified as approximate (J) and the detection limits were qualified (UJ) for
samples in which the analytes were not detected
ICP INTERFERENCE CHECK SAMPLE
The ICP check sample (ICS) data were reviewed to assess the analytical
correction factors used during an ICP analysis run The guidelines require that
an ICS be run at the beginning and end of each analysis run or at least two
times during each 8-hour shift Results of the ICS analysis (Form IV) must be
v^dthin + 20 of control limits Calculations from raw data should be verified
In the review of the ICS data sheet recovery data were found to be wdthin
control limits and no data qualification actions were necessary An ICS was
analyzed at the beginning and end of each analysis run and in some instances
exceeded the minimum of two ICS analyses per 8-hour shift The reported IGS
recoveries were recalculated from raw data and laboratory results were
confirmed for aluminum barium beryllium calcium cobalt chromium copper
iron magnesium manganese nickel potassium selenium silver vanadium and
zinc
LABORATORY CONTROL SAMPLE
In accordance with the guidelines laboratory control sample (LCS) results were
reviewed to determine whether the percent recovery (R) fell within the
specified control limits Control limits in aqueous matrices are specified as 80 to
120 percent for each analyte except antimony and silver for which control limits
are not established Control limits for solid matrices are specified for analytes
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
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ltltoc M
55 00 Oi
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
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3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
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JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
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IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 6
including antimony and silver on the Form VII data sheets Laboratory
calculation of R should be verified from the raw data
Silver was the only analyte with recoveries outside the specified control limits
In data package No 8904288 which contained the sediment sample analysis
the reported silver recovery of 6 percent was far below the acceptable range
Silver results in data package No 8904288 were reported as less than the
instrument detection limit (IDL) and were qualified as approximate (UJ) This
low silver recovery will be discussed further in the summary Raw data and
reported results were spot checked for transcription errors none were noted
The R for the LCS was recalculated from raw data for over 40 percent of the
analytes reported in the four data packages and the reported results were
confirmed
DUPLICATE SAMPLE ANALYSIS
Laboratory duplicate sample analyses were reviewed for the analytes (Form VI)
to provide an indication of laboratory precision The guidelines establish control
limits of + 35 relative percent difference (RPD) for sediment samples and
+ 20 percent for aqueous sample concentration values greater than five times
the CRDL Control limits for sample concentration values less than five times
the CRDL are plusmn two times the CRDL for sediment samples and + the CRDL for
aqueous samples A check of the laboratory RPD calculation should also be
performed according to the guidelines
Duplicate sample comparative results were unacceptable for some analytes in
each of the four data packages The laboratory appropriately flagged these
analytes in several cases as indicated with a below Additional analytes
with unacceptable results were also identified during the data package review
Analytes with unacceptable comparative results included aluminum () arsenic
chromium () manganese () selenium vanadium zinc () and cyanide () in
data package No 8904288 antimony cobalt () nickel and lead in data package
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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Inorganic Elements bullmU^
bull
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
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55 00 Oi
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
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U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
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J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
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^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 7
No 8904271 cobalt lead and zinc () in data package No 8904286 and
antimony and chromium () in data package No 8904324 Reported data for
analytes with unacceptable comparative results in samples associated with a
specific data package were qualified as approximate (J) Laboratory calculations
of RPD were recalculated for each analyte and reported results were confirmed
It should be noted that the laboratory performed a cyanide reanalysis for sample
SD-Sl-001 because of poor duplicate RPDs Although the sample holding time
had passed the reanalysis concentration was only slightly lower than in the
reported initial analysis and duplicate RPDs were acceptable This suggested
that the original cyanide result was acceptable despite the anomalous RPD The
reanalysis confirmed the results of the initial analysis therefore initial analysis
data for sample SD-Sl-001 was reported in the validated data tables
FIELD DUPLICATES
Field duplicates were submitted and analyzed as a measure of field and
laboratory precision Duplicate results were assessed in terms of general
comparability although specific review criteria and actions are not established in
the guidelines The RPD criteria used for assessing inorganic laboratory
duplicate samples were also used to compare data for sets of field duplicates
The field dupHcates for the sediment matrix SD-S5-005 and SD-DUP-009 had
comparable results for analytes where RPD calculations were possible The only
significant differences between analyte concentrations were for sodium zinc and
cyanide and these analjd^es were previously qualified due to other factors
identified in the quality control review Therefore no additional data
qualification actions were taken
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
mdash n^TL-6(0-M OflOR-605 r r ) r L - ( ^ i i ) - M t ^ A s ITtTL -6gttJ3shy jyi^pS^aaa mTi - f eoshy VgtOii^r rOJO
__ 1 nrr^a-nci)nD-ajM
Inorganic Elements bullmU^
bull
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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U = Analyte was analyzed for but not detected
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N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
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TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
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R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 8
The aqueous field duplicates included the follovnng sets of samples
GW-OW2DR-033GW-DUP-042 GW-MW13D-022GW-DUP-038 and
SW-S2-002SW-DUP-011 Calculated RPDs were typically within or near the
+ 20 percent RPD criterion applied to laboratory duplicate samples indicating
that precision was acceptable
MATRIX SPIKE SAMPLE
The results of matrix spike sample analyses (Form V) were reviewed to assess
potential sample matrix effects Spike recoveries (R) must be vdthin the limits
of 75 to 125 percent of the individual spike concentrations according to the
guidelines unless the sample concentration exceeds the spike concentration by a
factor of four or more The spike recovery should also be recalculated from raw
data to assess laboratory reporting
Matrix spike recoveries were outside the specified windows for antimony
chromium manganese and silver in data package No 8904288 silver thallium
and zinc in data package No 8904286 cadmium silver and zinc in data
package No 8904271 and silver in data package No 8904324 Results for
analytes detected at concentrations greater than the instrument detection limit
(IDL) and with R greater than 125 percent or less than 75 percent were
qualified as approximate (J) Results for non-detected analytes were accepted
(A) if the R exceeded 125 percent however the corresponding detection limits
were qualified as approximate (UJ) if the R was less than 75 percent
Reported recoveries for the anal3^es discussed above and specific actions applied
to samples associated with the affected data packages are presented in Table II
FURNACE ATOMIC ABSORPTION QUALITY CONTROL
Furnace AA quality control (QC) data were reviewed to assess precision and
accuracy of the individual analytical results for lead arsenic selenium and
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
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^ j o H ^ ^ ^ PROJECT NAME
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PAGE _5 of IP
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^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 9
thallium which were the only HSL inorganic parameters analyzed by furnace AA
techniques In accordance with the guidelines samples must be reanalyzed once
if initial duplicate injections result in a percent relative standard deviation
(RSD) in excess of + 20 percent In addition spike recoveries must be in the
range from 85 to 115 percent and samples requiring the Method of Standard
Addition (MSA) should have correlation coefficients greater than 0995
Results for duplicate injections were found to be within the range of
+ 20 percent RSD in each of the four data packages Spike recoveries were
found to be beyond the acceptable range for analytes presented in Table III
Because sample absorbances for each affected sample were less than 50 percent
of the post digestion spike absorbance results for these analytes greater than
the IDL were qualified as approximate (J) and the detection limits for
undetected analytes were qualified as approximate (UJ) The Method of
Standard Addition (MSA) was performed for lead on samples SD-Sl-001
SD-SlO-008 GW-OW2DR-033 GW-MW16D-027 and SW-S8-008 The correlation
coefficient was less than 0995 for sample GW-MW16D-027 and the lead result
for this sample was qualified as approximate (J)
ICP SERIAL DILUTION
This parameter was evaluated to assess whether physical or chemical matrix
interferences may have affected sample results The guidelines state that
results of the serial dilutions must agree within a 10 percent difference (D) of
the original results (Form IX) The D should also be recalculated from raw
data
The D between initial results and serial dilution results were checked
Analytes met the D criterion with the exception of magnesium and sodium in
data package No 8904286 and manganese in data package No 8904288 which
were appropriately flagged with an E by the laboratory This flag signified
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
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ltltoc M
55 00 Oi
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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6ooo cgfOQ
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 10
that the concentrations were estimated due to interferences noted during the
dilution analyses Results for the three analytes were qualified as approximate
(J) for each sample in the corresponding data packages The D for analytes
outside criteria were recalculated from raw data and reported laboratory results
were confirmed The D of other analytes were recalculated from data on the
Form IX data sheet and laboratory calculations were found to be correct
SUMMARY
The most noteworthy analytical problems concerned sediment samples Holding
times were not met for cyanide and mercury analyses based upon POP criteria
and matrix interferences resulted in some very poor recoveries The LCS
recovery in the sediment matrix was poor for the silver analysis However
given that the MSMSD recovery for silver was close to acceptable limits the
LCS results were considered insufficient to qualify the data as rejected (R) and
instead the detection limits were reported as approximate (UJ) Duplicate
recoveries were also in some instances very poor resulting in the reanalysis of
cyanide in sample SD-Sl-001 Since the cyanide concentration in this reanalysis
was comparable to that of the original analysis the original data were judged as
representative of the sample and qualified as approximate (J) Laboratory blank
contamination resulted in the adjustment of detection limits for a total of
10 analytes
Data qualifications for analytes in the aqueous samples were not as extensive
and were largely the result of laboratory blank contamination and recoveries
outside of specifications in the matrix spike and duplicate analyses Detection
limits were adjusted for a total of 15 analytes in response to blank
contamination Reported negative concentration values for blank samples also
required data qualification action Furnace AA QC and the ICP serial dilution
data in some cases were not within control limits Unvalidated laboratory data
and validated data are provided in Tables IV and V respectively
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
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n l U i plaquor6f
Zoscdfi h o t
1 P 0 0 ^9 -7^
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R n w IJ
u
plusmnft e (A M A u H AJ y ^
U hJAJ u U W ^ u
^ ^ O f i i^nr ^ bull S n
bulls-oo l i O O I OO
J)a)ooor^ o n n ^oeo f o o
1 4 0 0 s yo
3 f ) lt 0 M l i jlter
o n o fps-en
S(J4o rraquo l o n
Soo ^9raquoex60 ^ t j oo
s-oa is - oo l o o o
(J f l II-
A6 11 u
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LI
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u u s u 14 N
^ u A J j J
u u N i f shyu
gt1I006 Q0O S 9 0
6 Soo I O O I OO
l ( ^ V 0 O 0 0 10 DO 9gtt^n
V 0 0 lObCrs
Xiiro i c o n
5 0 O G2JD
a r o c VraquofiT5pOn
gtoo s oo
h^^opoo Vdo
lS-on l ^ o o lOOO
u egtU u U
iiishyfi u
KUu u u
uIALA
a I lLlt
UJ
U)
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N pound hJ
^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
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3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
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as on laogfxy
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Qotgt l ^ o o llt^ 0 0 OiOO
u u M u U U
U
u i
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u u R U
U M T T
lA
ugt
^
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A
fl-^od LI on 0 0 0
bull=^5-0C loc IOO
Qr^nto on IfiOO a^c ltac
^Oinr^n Ofcd
oHnor JltJ^laquo
0 A 6
4gt3roo r^rtSood
I OA fTOO
^afeoeo I40O
Soo ^ i ^ O
)CgtOD
u M u l i tx A
i A u R
It M 4 Ai t^
6
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t o f
(0 V ^ A A 7
5 5 0 0 if00 Jloo
bullzsoD l-oo IOO
imoooA loop
3 O 0 Soo
3 S iOe i
IZSOoo Siesoo
copyao J 5- Ofl
I3 i 0r tlaquo Joo
Sraquoo( n 0000
Hioo
u a u l i
u u
u p uft u ft
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U l ^ o d U ffOO U ld ocL
W
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A W
Ashy
5-5- OC l OO
W-SS-oo bullraquogts oo
oo too
tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
oo i)OOrtO0
lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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^
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N FMJJ
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1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
y5Oegt 3 = i ^ (A W
^ B IOO L L
pound(1 tL aH^o66o
IgiOf) s Sooe LL
gpoundpound LL 3^r00 22s E 5AZ
id^naoi mg s ^ jampiSfi
9S(gto LL 3 Q pgHOtWA
IOO u W S-eo
^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 11
Data in this package were found to generally meet the Data Quality Objectives
(DQOs) set forth in the Mottolo POP and the Scoping Of Response Actions
Phase I report In these references specific data quality requirements for the
Mottolo site were outlined The review of consistency with DQOs focused on the
following areas contaminants of concern analytical methods detection limits
and data precision accuracy and completeness It should be noted that the
DQO criteria presented in the Scoping of Response Actions Phase I report were
for volatile organic compounds Similar criteria obtained from DQO guidance
documents were used to assess data for inorganic parameters
The contaminants of concern in this data package were the HSL inorganic
compounds and cyanide Analyses were performed by CAA using CLP protocols
and methodology presented in the SOW in accordance with the DQOs
According to the DQOs the Contract Required Detection Limits (CRDLs) defined
in the SOW were to be utilized as the analytical detection limits The detection
limits achieved were adjusted for some analytes based upon the quality control
review but the adjustments were consistent with the criteria presented in the
validation guidelines It should also be noted that the CLP SOW acknowledges
that detection limits are highly dependent on matrix effects and may require
adjustment
Data precision and accuracy were addressed during the validation review process
of samples in the four data packages Laboratory precision and accuracy were
assessed in terms of spike recovery performance Most MSMSD recoveries
found to be unacceptable were just beyond the windows presented in the
validation guidelines The precision (RSD) and accuracy ( Bias or 100-R)
for analysis of these spiked samples were comparable to historical CLP
laboratory values presented in the EPA data quality objectives guidance
MSMSD recoveries for manganese and silver in one data package each were
further outside the windows and were not comparable to historical CLP values
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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Inorganic Elements bullmU^
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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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u x
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Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
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3SOO IOO 100
lOT^bOCtC i n on 5O0C
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bullzsoD l-oo IOO
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ltltoc M
55 00 Oi
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
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Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Balsam Project 6185814 November 21 1989 Page 12
The objective for data completeness stated in the Scoping of Response Actions
Phase I report was to obtain a minimum of 85 valid data This objective was
achieved in this data package as nearly 100 of the data were judged to be
valid
tb2161
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
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E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
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Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
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LABORATORY QUALIFIERS
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U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
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R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
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JUL Mij6upound6
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g y o J L 35 1 go J
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SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
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3flaquoltgtltgt g g
l i _
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7g57 ^ f i g
bdquo g t g z y g g
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JIMM 10 0 U h) Zdo JUL
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3^5^ fgtP f57W
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g tt g f g g
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IL g r g g I H i 1L_
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f f g g g u u
zuraquo^o g f g g
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A ^ g i i ^M a ^ t g g g
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LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
Resul ts
Blank Contaminants
Aluminum
Antimony
Calcium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Vanadium
Zinc
TABLE I
BLANK SUMMARY In Solut ion (Action Values In Parentheses) ^
Da ta Package^
No 8904288 No 8904286 No 8904271
15263(76)
46(23)
-790
- - 476(238)
127(64) - 149(74)
294(148) 762(381) 708(354)
- - 22(11)
931(466) - 1860(930)
53(27) - 111(56)
258(129) -350 355(178)
2567(1284) -2430 3525 (1763)
15(8) 15(8) -
72(36) 79(40) 55(28)
-760 3485(1743) 2915(1458)
- - 242 (121)
_ - 197(99)
No 8904324
56(28)
-
55(28)
294(147)
-
845 (423)
53(27)
268(134)
1471(736)
10(5)
-70
3378(1689)
-
-
NOTES
1 Action values represent the raw sample results multiplied by five
2 Concentrations in samples associated with the data package which are less than the action values but greater than the IDL are considered not detected with the detection limit adjusted to the original analyte concentration and qualified (UJ) Concentrations greater than or equal to the action values are accepted (A)
Action values are not reported for samples with negative blank values greater than the IDL Detectable concentrations of analytes for samples in data packages associated with negative blank data are qualified as approximate (J) the detection limit is qualified (UJ) for non-detected analytes
Values associated with the sediment data package No 8904288 must be adjusted for percent solids and sample volume before blank actions are applied
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
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Qoo IKtPk S ^ 9 0 l o a n
u x
K U I-t
u U u
q^ pound
u f^ p U hJ
E U u
AJ shyM
Hhl^ i i oc A o n
-^s-eo I OO
ano i m n o t
i c a a 17i3rt
5-0O ty7^o
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fhf^O l i l L t n ^ P amp
Oo fTiOO
1^ ^ ( n f i o V d A
ylt d r t i ^ o o 1 0 0 0
Ui O )
u U uh U )
TT IA A
A
PA e-
u
p(J
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A fi^ AsW
u u A (A
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l^afgte ^v-7n
l 60 J00
Q-i^aooo f i 0 6 bullS f ih KOO
oyoo b f ) ^ O t )
H m o t c a S7Vlt9 A r t
n l U i plaquor6f
Zoscdfi h o t
1 P 0 0 ^9 -7^
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U hJAJ u U W ^ u
^ ^ O f i i^nr ^ bull S n
bulls-oo l i O O I OO
J)a)ooor^ o n n ^oeo f o o
1 4 0 0 s yo
3 f ) lt 0 M l i jlter
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S(J4o rraquo l o n
Soo ^9raquoex60 ^ t j oo
s-oa is - oo l o o o
(J f l II-
A6 11 u
I J u
LI
H K~ e
u u s u 14 N
^ u A J j J
u u N i f shyu
gt1I006 Q0O S 9 0
6 Soo I O O I OO
l ( ^ V 0 O 0 0 10 DO 9gtt^n
V 0 0 lObCrs
Xiiro i c o n
5 0 O G2JD
a r o c VraquofiT5pOn
gtoo s oo
h^^opoo Vdo
lS-on l ^ o o lOOO
u egtU u U
iiishyfi u
KUu u u
uIALA
a I lLlt
UJ
U)
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N pound hJ
^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
^ r 0 6 ^ t t 200
3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
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as on laogfxy
oo ^ 5 Oo ^ ) 3O f t 0
Qotgt l ^ o o llt^ 0 0 OiOO
u u M u U U
U
u i
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u u R U
U M T T
lA
ugt
^
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A
fl-^od LI on 0 0 0
bull=^5-0C loc IOO
Qr^nto on IfiOO a^c ltac
^Oinr^n Ofcd
oHnor JltJ^laquo
0 A 6
4gt3roo r^rtSood
I OA fTOO
^afeoeo I40O
Soo ^ i ^ O
)CgtOD
u M u l i tx A
i A u R
It M 4 Ai t^
6
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uJ
t o f
(0 V ^ A A 7
5 5 0 0 if00 Jloo
bullzsoD l-oo IOO
imoooA loop
3 O 0 Soo
3 S iOe i
IZSOoo Siesoo
copyao J 5- Ofl
I3 i 0r tlaquo Joo
Sraquoo( n 0000
Hioo
u a u l i
u u
u p uft u ft
laquoJ
u bullR t lgtlaquo
^
U l ^ o d U ffOO U ld ocL
W
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hJ
A W
Ashy
5-5- OC l OO
W-SS-oo bullraquogts oo
oo too
tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
oo i)OOrtO0
lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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Vcdu 1^00 22S) lopo
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^
A ^
N FMJJ
N
1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
y5Oegt 3 = i ^ (A W
^ B IOO L L
pound(1 tL aH^o66o
IgiOf) s Sooe LL
gpoundpound LL 3^r00 22s E 5AZ
id^naoi mg s ^ jampiSfi
9S(gto LL 3 Q pgHOtWA
IOO u W S-eo
^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE n
MATRIX SPIKE ACTIONS
Repor ted Data P e r c e n t Sample Resul ts Sample Resul ts P a c k a g e Analyte Recovery ltIDL gtIDL
No 8904288 Antimony 596 UJ J Chromium 693 UJ J Manganese 3698 A J Silver 628 UJ J
No 8904286 Silver 534 UJ J Thallium 1302 A J Zinc 731 UJ J
No 8904271 Cadmium 1269 A J Silver 728 UJ J Zinc 139amp A J
No 8904324 Silver 716 UJ
NOTES
A = Accept data as reported by laboratory
J = Data qualified as approximate as a result of quality control review
UJ = Detection limit qualified as approximate as a result of quality control review
IDL = Instrument detection limit
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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V 0 0 lObCrs
Xiiro i c o n
5 0 O G2JD
a r o c VraquofiT5pOn
gtoo s oo
h^^opoo Vdo
lS-on l ^ o o lOOO
u egtU u U
iiishyfi u
KUu u u
uIALA
a I lLlt
UJ
U)
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N pound hJ
^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
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3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
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as on laogfxy
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Qotgt l ^ o o llt^ 0 0 OiOO
u u M u U U
U
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u u R U
U M T T
lA
ugt
^
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A
fl-^od LI on 0 0 0
bull=^5-0C loc IOO
Qr^nto on IfiOO a^c ltac
^Oinr^n Ofcd
oHnor JltJ^laquo
0 A 6
4gt3roo r^rtSood
I OA fTOO
^afeoeo I40O
Soo ^ i ^ O
)CgtOD
u M u l i tx A
i A u R
It M 4 Ai t^
6
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uJ
t o f
(0 V ^ A A 7
5 5 0 0 if00 Jloo
bullzsoD l-oo IOO
imoooA loop
3 O 0 Soo
3 S iOe i
IZSOoo Siesoo
copyao J 5- Ofl
I3 i 0r tlaquo Joo
Sraquoo( n 0000
Hioo
u a u l i
u u
u p uft u ft
laquoJ
u bullR t lgtlaquo
^
U l ^ o d U ffOO U ld ocL
W
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A W
Ashy
5-5- OC l OO
W-SS-oo bullraquogts oo
oo too
tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
oo i)OOrtO0
lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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Vcdu 1^00 22S) lopo
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^
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N FMJJ
N
1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
y5Oegt 3 = i ^ (A W
^ B IOO L L
pound(1 tL aH^o66o
IgiOf) s Sooe LL
gpoundpound LL 3^r00 22s E 5AZ
id^naoi mg s ^ jampiSfi
9S(gto LL 3 Q pgHOtWA
IOO u W S-eo
^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Se len ium Thal l ium
GW-MO1-001 X X GW-M02S-002 X X GW-M03SR-004 X X X GW-M03DR-005 X X X GW-M04S-006 X X X
GW-M04D-007 X X GW-M05S-008 X X X GW-M05DR-009 X GW-M06-010 X X GW-MW7S-011 X X
GW-MW7D-012 X X X GW-MW8S-013 X X GW-MW9S-015 X X X GW-MW9D-016 X X GW-MWlOD-017 X X X
GW-MWllD-018 X GW-MW12S-019 X X X GW-MW12D-020 X X X GW-MW13S-021 X GW-MW13D-022 X X
GW-MW14S-023 X X GW-MW14D-024 X GW-MW15S-025 X X GW-MW15D-026 X X GW-MW16D-027 X X
GW-MW17D-028 X X X GW-MW18S-029 X X GW-MW18D-030 X GW-MW19D-031 X X GW-OW2SR-032 X X X
November 21 1989 Balsam Project 61852161
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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__ 1 nrr^a-nci)nD-ajM
Inorganic Elements bullmU^
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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
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V 0 0 lObCrs
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5 0 O G2JD
a r o c VraquofiT5pOn
gtoo s oo
h^^opoo Vdo
lS-on l ^ o o lOOO
u egtU u U
iiishyfi u
KUu u u
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a I lLlt
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N pound hJ
^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
^ r 0 6 ^ t t 200
3SOO IOO 100
lOT^bOCtC i n on 5O0C
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3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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6ooo cgfOQ
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
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Seuroob u 5-0C ft w Qoo u
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h2aoai noo ^
3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
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2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
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Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
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IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
BALSAM ENVIRONMENTAL CONSULTANTS INC
TABLE III (Continued)
FURNACE ATOMIC ABSORPTION QC ACTIONS
Analytes Outside Cr i te r ia
Sample N u m b e r Ant imony Arsenic Cadmium Lead Selenium Thal l ium
GW-OW2DR-033 X X GW-OW3R-034 X X GW-OW4SR-035 X X GW-OW4DR-036 GW-DUP-038 X X X
GW-DUP-041 X X X GW-DUP-042 X X
SW-Sl-001 X SW-S2-002 X SW-S3-003 X X X X X SW-S4-009 X X SW-S5-005 X X X
SW-S6-006 X X X X SW-S7-007 X X SW-S8-008 X X X SW-S9-004 X X SW-SlO-010 X X SW-DUP-011 X
SD-Sl-001 X X SD-S2-002 X SD-S3-003 X SD-S4-007 X SD-S6-006 X X
SD-S9-004 X SD-DUP-009 X
NOTE Results for analytes outside criteria should be qualified as approximate (J) if detected or the detection limits should be qualified (UJ) if not detected
November 21 1989 Balsam Project 61852161
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
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Inorganic Elements bullmU^
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Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
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cfrraquo c LABORATORY QUALIFIERS
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Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
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Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
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LABORATORY QUALIFIERS
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= Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
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M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
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^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
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^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
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pound J E L
^ i gt o tOO
M ^ U LJ
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Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
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3^5^ fgtP f57W
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g tt g f g g
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z z-fog JLQtL U U) JL f ig U
arg^ g e
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IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
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A ^ g i i ^M a ^ t g g g
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LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb) PROJECT NAME
PROJECT NUMBER
PAGE _ of ^
Sample Locat ion Sample Number
mdash n^TL-6(0-M OflOR-605 r r ) r L - ( ^ i i ) - M t ^ A s ITtTL -6gttJ3shy jyi^pS^aaa mTi - f eoshy VgtOii^r rOJO
__ 1 nrr^a-nci)nD-ajM
Inorganic Elements bullmU^
bull
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Other r u a r
p p
r P p p p p p p p p F P P CV P P F P P F P P
cfrraquo c LABORATORY QUALIFIERS
r^ro UOO
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^ ^
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference p- Fu^nace ^ ^
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
^ r 0 6 ^ t t 200
3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
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W-SS-oo bullraquogts oo
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tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
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^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
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pound U A tA A Ashy
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55 00 Oi
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3oodu ^bull(Jp u
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HlhOOo 333 oo
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1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
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gpoundpound LL 3^r00 22s E 5AZ
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^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
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bull Soo LL l QO
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS AQUEOUS RESULTS (ppb)
^ j o H ^ ^ ^ PROJECT NAME
PROJECT NUMBER
PAGE ^ o i lyt
Sample Location Sample Number I f ^ L - h O ^ l i ( j j i h o - o a i mrL-S^co-rvDl^ltho^ Df^L bU) mji^s-oaH rYTL-(S0)rraquo(0-^5-R ^TL-66d-lbCLP
1 -OLJI1
Inorganic Elements
Aluminum Antimony Arsenic Barium Beryll ium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium ManRanese Mercury Nickel Potassium Selenium Silver Sodium Thall ium Vanadium Zinc Othen CsJOA
P P F P P P P P P P P F P P CV P P F P P F P P
(U
LABORATORY QUALIFIERS
O
^ r 0 6 ^ t t 200
3SOO IOO 100
lOT^bOCtC i n on 5O0C
^oc 5ffeoc
oOO
isys^ S S J O egtoo
as on laogfxy
oo ^ 5 Oo ^ ) 3O f t 0
Qotgt l ^ o o llt^ 0 0 OiOO
u u M u U U
U
u i
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u u R U
U M T T
lA
ugt
^
y AJW
A
fl-^od LI on 0 0 0
bull=^5-0C loc IOO
Qr^nto on IfiOO a^c ltac
^Oinr^n Ofcd
oHnor JltJ^laquo
0 A 6
4gt3roo r^rtSood
I OA fTOO
^afeoeo I40O
Soo ^ i ^ O
)CgtOD
u M u l i tx A
i A u R
It M 4 Ai t^
6
n _L1
uJ
t o f
(0 V ^ A A 7
5 5 0 0 if00 Jloo
bullzsoD l-oo IOO
imoooA loop
3 O 0 Soo
3 S iOe i
IZSOoo Siesoo
copyao J 5- Ofl
I3 i 0r tlaquo Joo
Sraquoo( n 0000
Hioo
u a u l i
u u
u p uft u ft
laquoJ
u bullR t lgtlaquo
^
U l ^ o d U ffOO U ld ocL
W
E
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A W
Ashy
5-5- OC l OO
W-SS-oo bullraquogts oo
oo too
tgtgt0000 oofl
copypoundlaquo 5 0 0
J9r06firtr) 3 f i f t
bullSlriOrtC MltJW00C
oao alaquo-6o
^ l ^0 66 IOO
ltroo ^OOddO
Qoo ] r oo s-oc
u M w U ( i u
u Li l
tt R wp
u U R ] ^ tJ ws^
pound U A tA A Ashy
ltltoc M
55 00 Oi
S i ^6 fffe oo
oo i)OOrtO0
lOOft
L u
R (i D IJ
3oodu ^bull(Jp u
^r-SEi R ^ 0 0
HlhOOo 333 oo
(33C 0 5 0 0
J ^ O O d O A 60 ^-ao
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in fl
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R Llt
Vcdu 1^00 22S) lopo
(gtl
^
A ^
N FMJJ
N
1
3 shy Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
U3 Pos+- dP^^eA ipiKiL-^ra^ f^curiajL f^lt^ t^ c ru i oT cavJnrxgt
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
65oo rHs 4^qiTic 3^-qg LL
LL
g^7Pft poundL goc LL 3floru S L C L LL
6ooo cgfOQ
S2^3QAJ0pound1 i yg f f t
ggC-Lt bull bullfaff 0 0 ti b S b C C
n^IyZS SIM ^gftrxo ^bull^-yenshy
Noo L N W-OQ ^vQO (j A^ orod L4
y5Oegt 3 = i ^ (A W
^ B IOO L L
pound(1 tL aH^o66o
IgiOf) s Sooe LL
gpoundpound LL 3^r00 22s E 5AZ
id^naoi mg s ^ jampiSfi
9S(gto LL 3 Q pgHOtWA
IOO u W S-eo
^apofi u ^ 0 0 V T N
^bulloo XL 7 5 ^ urjy^ ooa Mshy
55oo
2bull 0 0 i ^ LL
bull Soo LL l QO
Q O UshyLL
^ SL 35 iCCQ i ^
M ^ amp
jpoundkSE
EE ^iSe
ay-Ofi UshyLL ^^gpoc
l i Q O EL 5-PQ U ll
3Z 5 cn -E 0 0 s M-^shy
J S L M J t jroo 1 0 0 0 LL
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mo^hin f R X I p ^ AQUEOUS RESULTS (ppb)
^ l o ^ Q ^ ^ PROJECT NUMBER (jOlS^lt^
PAGE _5 of IP
Sample Location Sample Number mrL-^-sfc- DQk mT--6fU-gtl)20ggtO-^ 3SZE6^5M25EM Yirz-6^-^o3Dg-oolt Wlt^-(V - Wfi-0BO
Inorganic Elements
Aluminum n^Tob yS^-op y mdash r Antimony HTOP [k w 91^ Arsenic g oo LL 52^ IA w Barium bullgt$bullbull go LL TO^f l B-Beryll ium ipoundQ LL uQC L L Cadmium L i ^ isc LL Calcium gysof i i ffe 5ampI
MM2gOCfi Chromium lOOC LL lampCgt0 LL Cobalt _3GiOO iL ^PiPO LL Copper f-OP L L bull SOC IA Iron Lead umdash _ fncgt ^L T I lt W Magnesium S g Manganese ^apltgto Mercury CV Or^O J ^ Pgo LL Nickel y-ltgtcgt LL gSiOQ Lt Potassium lOWbQO ja_ Selenium loo lgtt W 5 poundr2 IL Silver ^ - 0 0 S t f i f i U N Sodium j-ijff^rboof Thall ium u tsiyJ Hlo^
^i4Sltgt-oo k hJ
M^ Vanadium y oo M l ^ O Q Zinc 5 iOQ SZSSEI 5laquoggto Other Cya^idc 1 0 O P LL IOgtQO LL LABORAIORY QUALIFIERS
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
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LL
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
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h2aoai noo ^
3 0 0 0 4 Soo
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0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
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TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
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l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
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JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
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f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
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7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
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JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
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3^5^ fgtP f57W
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IL g r g g I H i 1L_
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f f g g g u u
zuraquo^o g f g g
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A ^ g i i ^M a ^ t g g g
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LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Mojloh R J j F S AQUEOUS RESULTS (ppb) sect-9oW9^^ PROJECT NUMBER ^ ^ S i ^ h
PAGE _ ^ of ^
Sample Location Sample Number
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryll ium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thall ium F Vanadium P Zinc P Other ( ^CkA(^f C
LABORATORY QUALIFIERS
bull
l ^ l f l i ) m )ilaquors - ^ r
Seuroob u 5-0C ft w Qoo u
^f0O u 0 0 u 0 0 u
h2aoai noo ^
3 0 0 0 4 Soo
blt4co lt J 8 0 w
ISWOft s E i ^ ^ f i r
0 3 0 Mp^frs (J gtISDOO ^
l i S O R 5^00 Pi h J
bull^aoQfv^ bull F 1
J)oo gtlaquo A bullSoe^ bull i l ^ i O C J V i ^ inors J
R = Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S Reported value was determined by the Melhod of Standard Addition (MSA)
- Duplicate analysis was not within control limits
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
^0i3Z^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME y J p - f k U C t j I ^ S firOjxesU-S RESULTS (ppb)
4rouydugtatir PROJECT NUMBER C f l f 0 f ^
PAGE s c)f f x gt
Sample Location ~ Q ^ 1 J 1 Sample Number n i r u 6 u ) - t o P ^ JQ^7^-lt^UiTJhefS^-to4 1i f i r L C u i M t lt i O o ^ yyirL-AtA) V 4 j Z gt - 0 laquo n i T t amp U i i l i ) Z S ^ - i 3 l 2
Inorganic Elements
Aluminum P 5 r oo IA ltisoc u sfao u jr^rM u bullTiT oo u Antimony P-P oo u iOO U Ul ^ oo U U J fSO B W foo u u) Arsenic F t ^ O O arvj B r t e u u ZOO laquo i f s o o Barium P e^o R n ^ o n tTOC u s s o c k t Z O O e Beryllium P oo t oo M t o u O O u oo u Cadmium J f f oo M w _ 1 oo u oo u oo t oo u u) Calcium P lOQtO aolto0ilaquo f t 9 o t c ^ C T J i M y f9 fOd 0 ffO Chromium P laquo ro bull ooc u Z ^ 9 0 it ^c oo ^ o o o u Cobalt P ^ f l O u s o 00 u 3 0 oo u s 7 l 9 d 0 u 30 oo LL CoDoer P bullKbSo ^ d o u Soo u f r raquo A t V ) A Iron P i o iooo t c ^ t t o Ht60 B ^ 3 9 i 9 0 efraquoraquoooe 3Lead F bull 2 0 0 o 2 C 0 u 9 1 0 B z oo u Zdo u j O Magnesium P r_8laquoTooe B 3r-ooec R f f lO 00 B f r o e c Ji Z 9 0 0 0 s Manganese P g^vgtM 1 ZOTf i 0 P O 9 ^ 0 0 0 14400 Mercury CV I O o t o u otfo o z e u o r o u Nickel P L o i o TJfPO M -zgVto A 2 lt 0 0 u bull2ltO0 tA Potassium P S - ^ S O M 3CIOOO M y - 9 0 0 0 o ^ o oo f t f ^ t t c o o sSelenium F o o v lO oo u oo u o o u OP K Silver P f f iC LI n ^ 0 0 t l N KOO U N ^ 0 0 U A Soo u ^ A Sodium P 3laquo00laquoo 1 ^-990 Ot raquo sttotgto B 3ltfpound0 OC A n ^ ^ o o o Thallium F i laquo o u u) tOO f t ifOO IA U) ^ 0 0 M W-eo uVanadium P fC (gtraquo A l i s 00 U ^ o o M ^roo tlt -lt 9 0 R Zinc P l^ f ^C 2 9 0 3 0 0 92JL bull39 o Other C W v lt A l C- foop u l o o o U o oo M AfOC IA o o o laquo
LABORAIORY QOALIFIERS
Q = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (USA)
= Duplicate analysis was not within control limits y y
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME fYlo j fo lo C l bullA(56x^lt5-S RESULTS (ppb) PROJECT NUMBER I f P f i ^ ^ ^ PACE of ^
Sample Location Sample Number y i T c C C ^ gt U ^ R - 0 3 H
Inorganic Elements
Aluminum P JoSoc Antimony P 4 ^ 0 0 A 14 Arsenic F y^Po R Barium P z^f oo Beryllium P oo ifCadmium P I OO HCalcium P J f ( 2 OO laquo bull Chromium P lt 9 0 raquo Cobalt P tA90 6G Copper P 2 O 0 a Iron P S 5 0 A Lead F 2 t o ^ Magnesium P 5 2 6 0 $ Manganese P ^ O O KMercury CV azo laquo Nickel P bull 2 ^ 0 0 IA Potassium P f ^ Z O 0 p C Selenium F TltB R UJ Silver P ^ 0 0 lA A Sodium P t f O O O O Thallium F VO5 fc-Vanadium P ^ o q tA Zinc P 3 f t f Other p a o M LABORATORY QUALIFIERS
fi bullbull Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (lOL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N bull- Spiked sajple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bullJ K P f dv^iT^
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME t QUL^-OUS RESULTS (ppb) SIU-plusmnILU i k i j -r PROJECT NUMBER
PAGE ^ of ^
Sample Location Sample Number MSnUSElWIM l l T C ^ W - S l - C ^ 5 2 OOZ h l ^ S C O ^ S ^ O O S n i 7 i r ^ t gt i gt y 0 c mr^-a^
Inorganic Elements
Aluminum 2jrqo ^ mdash 1110^ SLSD Antimony Ugt IA) 4 t o ^z I HxOO JLpoundiL kZJS poundM A IA U Arsenic iOggt 2egtCgt I L JU^tS JL Zbo A - g ^g Barium -757 ltgtP M- 3 S o a i L i i j ^ g g a ^ T bdquo Q Q aroo Beryllium P fQO M- o o ^ A g o IL AltVgt u A Q lt Cadmium J ^ L o t i L _ j i L J oraquo Mu um Calcium ( f t p o o gofg ide 2tltPt ^ J L 7 S ^ OPAL-K Chromium g-ltgtg ^ S K2 s ur9P 000 plusmnZ2l2e Cobalt 3 0 O O j A ^ O j O ^ U aSCL M 3CP6P i L JSBiM Copper rpc I L PSPM AL f t O g M ffOO S^pound^ Iron PS0C j j s i J i i i JP3ALSSL ZtJoo 3 i i ^ Lead u ZOO Z i S amp t OP u ugt g f l I L Magnesium fiJTgg fr0Q ^ ^ lt raquo ^ J A g Q i3_ Manganese zz^^ a p-cgt i e bo pound g ^ laquo 2 pound i ^ Mercury CV lt2ltgt i L g 2 g g 2 g R a g g g -g^ IL JM_Nickel z r 9 C jplusmn Z S f O f i ZfCC 3pound IM JLL OO Potassium W9^O00 ^ Z f g i g O ^ 6HCC9 JS- ^ z ^ a o p-az^op Selenium 5pound I L o o Id- LSSL amp Agg u w o o Silver t T T T Lpoundfi 1 K T segtP plusmn M ^ o o i L ^rpo Sodium Z T f O Q t ^ Z T O 0 t T ^ i iLM ZAOOOO 2 r f 0 0 e Thallium 0 0 i L JLSO IA u _LOO J L Vanadium I f T W I L jyyy it l i - m J L f P O ifltgtltgt I L Zinc -flt j L i ^ ZE 5 0 ^ 2 g 3VV^ Other ^ i U t i d e - (S- O O d a g t O lt ^gffO J L OOO I^OP u LABORATORY QUALIFIERS
0 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
- Ouplicate analysis was not wittyn control limits bdquo
Ul laquo P o i f QUlaquoiCjfac( cpitst f - e r bull f gt u r r c u i ^ ^ A is otd o T covsf-rol
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o f i v ^ K1 P^S ^QUe^uS RESULTS (ppb) r]AP^lM^ Lkffci^ PROJECT NUMBER d ^ l f S ^
PAGE _g_ of [(f
Sample Location Sample Number m i r S W ^ l r P O ^ f ^ f gt r y n T i - S W rytn-st^- ^ t digtraquo nt7irfgt f - 60^ I M T L S O ) s O egtio
Inorganic Elements
Aluminum Antimony 321 Arsenic Barium Beryllium Cadmium P F Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury CV Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc Other rHAnritf Pa
2232pound 7 mdash HQQ ZOO
^ t P O O
AL bull r
2 raquo o e o i t ^ e 3 g e g _fcL
pound ^ pound ^ g-^ gg bull g gg
^g OO plusmn ^ ^ O
g g o LL r og
l 3 i Q Q Q A g g K
f f lP JLVff f tOg A
LpoundpoundL t t fv i f V b p J L fr-^ j pound x i i A
pound J E L
^ i gt o tOO
M ^ U LJ
ggg JL a p g p
JL ^ t W yshy
Jt3poundeupoundiamp t t c
JUL Mij6upound6
Z P g Jl llaquo2 fvaraquogo s i f g
g y o J L 35 1 go J
IS lQQd S o LL
SraquoPff unr t ^ te oO Vtgltgt iL
bullJ^^SSL JJL
^ IZ
raquo bull raquo raquo
f r pQ BH U lampL 2Q0 4L
3flaquoltgtltgt g g
l i _
A^pound U Wt2OD0
JpoundxUL A
-90 06 U Xufipound i L
i lt f ^ 00 tA S-Z^2fi
7g57 ^ f i g
bdquo g t g z y g g
I I
jpound10iJSeL APg 5_SI
SMJSQ 7raquo0 t0g
u M
igtgg t S t P Q Z7VP o gQ is
JIMM 10 0 U h) Zdo JUL
I S E S A o g n o p u
3 P V A ( X - a g g raquo j t t _ i L
^ ^ 2 pound
3^5^ fgtP f57W
y i o o Q i i o W P O
g tt g f g g
Ik t o 9 P ^
iS r-VM
SS^Tfi graquo ltro^ IL
jSxpound2 J L
i t lP g g o _feL
z z-fog JLQtL U U) JL f ig U
arg^ g e
^
l C O 3 t i g As
IL g r g g I H i 1L_
Li2flL i L
f f g g g u u
zuraquo^o g f g g
ygtog laquo_ S h l O p O
A ^ g i i ^M a ^ t g g g
f^
vTgg i L ifCgtP AL amp A ^ g oraquoltgoi i L
LABORATORY QUALIFIERS
p i = Reported value is less than the Contract Required Detection Limit ^ (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S bull- Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits bdquo
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME Pi(jff[)ICj ^ X j P S AQUEOUS RESULTS (ppb) lo^iav PROJECT NUMBER ( ^ ^ 6 Q
PAGE ^ of ^
Sample Location Sample Number rrLj-9^- TCiQ ) bullgt Og l rrsTL-fali j- mujqs-(a^ mvL-feU7-lTOJTHHgtQ3^ i^u-^laquoni^^Cgt-oifc yyvrL-foio-pound ugtj sg-ojf
Inorganic Elements m^ Aluminum ^bully^ rrgt u oS oo U L WWOn bullSS iOo M^ U Antimony Tpy bull^ co Arsenic ISX SiifQPi t o i 2C i pound2 Mgin LL_LLL ilSI
g P O U 2 pound a ipoundl 2ai2C_L4 ^ - 7 ^ ^ 0 Barium r)00 U ^ bull lt OO L L i SOO i L bull^gop ^ gt V ^iA Beryllium gt 0 O i A bull j i a gtC)0 ^ 65 _ Q Q U Cadmium T F T ^ l^oo U lUi i i 0 0 uu i^u ocgt u N)u L J pound u lQO u -rouo Calcium P w i5tf 100 i l7yifrrop 332SI^ feH
Q7Qo^7r^ Chromium |lt0r7OU i Q 0 0 LL lOigQ H lOQn ^JSF 0gg U L Cobalt gt0 OPU jpound7^j2ia bull=^0)te it ^MQo 335 bullCpppc- P v T^ 00 a bull^1 g c LL s00 u bull ^ 10 B ltroc Iron P v G 61 Oo U S ^ ^ f l - O O ^^bullno U r (o(o90o Lead ^bullrregtg Q70 ^bullSP ^ J i i i i D 1 ^ ^gtvg Magnesium 3S2lQaB [59TrO 0 0 T^MbOiOo =^=rrOiOO fe Manganese P V tT-Q^tJ ( g l ^ i T ^ SSLLQI ( - 1 ^ ^ 0 0 ^ Mercury CV ^ ^o U Q r f l O 0 ^OJA a-^c e 0)40 Nickel P bull r^fT-POU 97 IP bull^fTfCO i3 I o Potassium P y A50-opi 370-tY) H I r OiOC 3lfc B ^t^(oOOQ oa Selenium ^OOU I O O i Q Q 1 0 0 LL ^il LL Silver ^L f^o u TQP J t ^ S00 u W Sodium P V S2 ^^ iQ^c 37-^Qi 00 ^ 5A90cf mSIS Thall ium M7Q0 pound ^ bull 0 0 iL SM E 0700 PiPfo HI Vanadium P l ^ Q Q U I rT tOP ilTiOO L L i^i SLQ Zinc ^ t 00 TT bull30 VO
u 7 ^ 5gt00 ^ M ^ lt^y 9 g B s
Other Cs in i r e_ CT 10 o o i A ) O i O Q iLOj LL 1^3 001 fe iQ- fSJ LL 0 0 0 LL LABORATORY QUALIFIERS
Q = Reported value is less than the Contract Required Detection Limit X^dxAC-^rliAei^A C W f S ^ c i ^ 9 f a 4 ^ w gt - t l t (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits ( = Pos^ ^ C j c t W spQ Arf ^^AK-vuxjui A-tV l i m J of co^^rroi
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
0
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME ^foffeo K T I F S AQUEOUS RESULTS (ppb) ^Qll PROJECT NUMBER pl S ^t -
PAGE I0_ of pound
Sample Location Sample Number mrL-6iud-m uyiSTgt-r^b mi-~^UP-( ^ lD0^Qn U^rL-6uJ-tf p gt ^ S - 0 ( tSTL-hu^r^lDnS-oi rmL-fyjij-idc^^mh
Inorganic Elements
Aluminum 55 oo L L (plb-qo 5 6 00 f^sectCO S S I O O LA Antimony M i t 0 VA UJ ( p i b O KUJ rai amp I 00 nzm HPQQ IA U) Arsenic J L J i 2 a ta-lto A C^ Ih l DO L L l a J i D Barium d ^ i OO LL =^ff-OQ bull^ OQ LL ^ S i O O LL r i ^ iOO LL Beryllium Upoundpound h o c ^LL pound 1 ^ j D i i Li iA 11 Cadmium i o r ) O Q Calcium iws-c^ gt^n issoooc -7^007(30 3M1O00 fe ^r)ltqt)^gt^ Chromium
IA MJ oo U (I(A i2a IA ^^A) DO inr (A gtVLO
Oi QO u (PQg LL DiQO LL i l iOa LL lt)fOC fcECobalt i^-^r ^oco iA k^Q 3i^D 3 5 1 3 G Copper I ATo B ^ bull ^ U_ ^|0C LL iTQO LL 6^) O-Iron 5Si p g ^OPO gS0lt3o ^ ^ bull ( ^ 0 i 7^r-00 Lead J-TP - ^ 7S-P
irf60 s 1 15Z sn Magnesium ^bfrngtQO B^-00 a i s y o b amp 5 n g ^ t ^ i ^ ^ Q n n KManganese l a l ^ f O O ^gt00 iA_ ^(g70(f J22 ygrocc Mercury CV rgtr-9o L L O^gQ O-PO II r i f l O LL ^ an Nickel ^ ^ LL Q ^ I O i^pTiOO M rgt^CgtCJ LL
Potassium -ampC)i no bull S - f y ^ r ^ bull^050100 Selenium 0 LL hPQ I oo 0 0 LL LL u lon J J L Silver lt 0 0 ^ i O Q UZK (TTr f7fCo fTCQ U M L L T J Sodium ^gWOiCVO lt5frggt fig l l l Q O O Thall ium ^ 0 0 m MTgg EJH 10 0 iTTcr ^ s oa Vanadium jir QO f ^w -TOP gtlt6( i ii i lt c o L i I f i i Q O Zinc ^ - o o T 9 3 0 O SE fTpQ fcs ^ 3 4 0 t T ^ ^ (TTT Other ( Npridlti iQiOO M- c go n iO-OQ n IQiOQ -Lt-
bull ^
intor) LL LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U - Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sample recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
HSL INORGANIC ANALYSIS TABLE IV PROJECT NAME Mothhy-^lt AQUEOUS RESULTS (ppb) 9c^9l PROJECT NUMBER
PAGE of ^
Sample Location Sample Number frr(-^ugt-(Y)t^^-D~cgtrgt7 m-L-6ilU^(Vhl9S-j)li mT-faigtroiA)i n-gy m x L - auL gtDUP-0^S- m-rL-r^ii-nvirM^^n-o-^
Inorganic Elements
Aluminum 65^00 5 6Ffi0o LL fT^Soo ^ ^ l O O fvSQP LL
t uAntimony T^ IO UiOO U IX) H^QQ ^ U) T ^ t JUJL C ^ 3 Q a
Arsenic ^7G S S_ fV iOP i L ^ ^feO P60 E Barium ^50C LL ^ ^ bull Q O LL 3 f o - ^ S S l O Q LL bull ^ euro 0 0 LL Beryll ium JX^ LI _ ^ 0 0 J i i L Lt 0 0 U rshyoa Cadmium LL OQ i JELL j i Q (A KJ(D U ^ )^3 Calcium I l l 06 Of) n^^OOd ^^qzxPicPc Q^^chioo Chromium in on ( 00 ^ lt ^ LL JCuPiC SZE gCgtg LL Cobalt J2poundbpound0 a(^ -gt 30L)0 u r^OiOC L Igppg TT-F rCopper QO LL ltiOO IA 3ff^ LL i^ pound 1 Iron ~ ^ T ^ R fegtV go St T t ^ Lead tm j pound l pound S2pound 2 ^ Magnesium Himuco B_ 2 2 ^ ^ l a i C o Manganese nt^iOD bullMM amp ^ g3 Sg Mercury CV i ^ ^ QQ^gLi LL Q ^ O L L Nickel pound ^ 5 Lsioa ^ ^ i Q O ^Ls Potassium ^7^Tgt0Q plusmn g a TO26 I ^ ( f f O m fa7Vafr E S ^)=lO00 Selenium LL lOO a lgt00 L G Q bull 0 0 L L Silver M S vrw I ijigtiOQ EL ^ 5 0 0 g A Sodium bullMk a JPLU^PQO ^ V ^ - f^rg-po a Thallium n-or Vi(0 H VTOO mn SSS uzm i in s iZZ ^ bull 0 0 LL_ZL Vanadium ^rfoo fTfOC 12 i2Q 5ltg LL Zinc -^QO s s Other ^2^ pound1 iQiQC) LL Ji^ I^m LL i n i O ( ^ u Jj2d2a LL Dr^Q LL
P 7op i h ^ ISZSa lilEI ^ o lt o X T Oil ( O QO
LABORATORY QUALIFIERS
= Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S - Reported value was determined by the Method of Standard Addition (MSA)
= Ouplicate analysis was not within control limits u 3 - ^oist- ltUe^e6+ltpoundi 6pfce-hrr p^^i^claquo bull (i t ^ S P o-f c^vvir^(
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS 8^6VA7 PROJECT NAME jOnp-lUy^ 1 -1 f ^ 6 A-ClupoundJgtu^ RESULTS (ppb) PROJECT NUMBER Q ^ I ^ H
PAGE R of ^
Sample Location Sample Number VATUampltP-YA^^^S-0-2)
bull
Inorganic Elements
Aluminum P Antimony P Arsenic F Barium P Beryllium P Cadmium P Calcium P Chromium P Cobalt P Copper P Iron P Lead F Magnesium P Manganese P Mercury CV Nickel P Potassium P Selenium F Silver P Sodium P Thallium F Vanadium P Zinc _ P Othert (Jd (u -Xt ltLshy
^ 0 O
ioo i O G
s^^ao l o a o o
^ pound lt f f O O O C O O
3 ^ 0 0 I ^ ^ 0 0
3 f S Q SLea
V4 00 Too 0 Z 0
Z S O i S 3 o a
O O
soo Z ^ c o 0 0
^ D O S O Q i o o o o o
u - I A UJ
A lA U ^ U A
u ^ ^
bull u bull ^
Uu Af^ u 1 A J
Ip i u u
J u^
V
bull bull 1
bull
J
LABORATORY W I F I E R S
3 - Reported value is less than the Contract Required Detection Limit (CRDL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= nniiratp anilv5is was not within control limits A I
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
1o^^^^ TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME M o j ^ o gyC^ ^E |gtlKlaquoJs i r RESULTS -fp^H- J ^
pprv PROJECT NUMBER CgtlS J E
PAGE J2 )0 i IJpound
Sample Location Sample Number nT^ Samp- Sgt^ P-lt^^ gt7V- ^ f i S O O t 0 0 2 kMrt S [ ~s r )CiJ h^ThSpoundgtz^ltgtC^ mn-$l S2
Inorganic Elements
Aluminum (-^iOPti 9 0 0 1 r2jraquooo 3 pound ^ 0 0 3 S ^ M Antimony ^ K bull y g SL MM s 731 tA N CP u Tpound AM s s Arsenic s t o TSe ^ 3 raquo ^72c Jd Barium ~ iso I L JtPlUSpound- 3ip SL 3 i f O ISM a Beryll ium Ctr SL 0 7 ^ JL PPWW MLL JL oP3r iA Cadmium P ^ T o-i-f IL P T-t U U JSUUi t bullSL J L 0 3 f Calcium ^gO JBu tHyeo ^ Y r 0 0 lt f o 00 i f o ^ P Q Chromium Z-^P JA AZJ t Z t P ^SZSE j ^ p U A i raquo WPTP A^ ^ o t t A Cobalt gOO L L r$t y^- fc 2 S 0 u -Ay 3 0 f S o Copper Z Z 0 plusmn Sr^TQ 3 4^0 Iron fiQPO y f^ ^raquo 3CfrGoo Lead gfrP sirp ^ 0 P JLpoundQ Magnesium 30 g g fi_ syyypp amp y- op zfs pa Mangafgtese yi ^ 0 0 MpoundJLpound Z pound pound i pound plusmn ITWl i raquo g g g y 3 TTJtT IZME Mercury CY O C O SJA JL MPJL pound L 13Nickel I L ^ _2LS2_ 0 2 poundgt ^ y p 4 i MPotassium yr gt JS Z 0 6 0 0 i i rr g^ z^t plusmn t gt33po s Selenium P ^ l B lJ O T raquo i lt poundraquo ^y5 offT amp A L Silver ^ ^ ^ A 7 j p i o plusmn M L 2 S M -JL Sodium ^ ga M plusmn ZSOZ o ^
MP^O Thallium ^ C A g jyL ^ ^ M ^ JJ - I raquo o Vanadium S ^k f^P _poundL poundpound iL ^ ^ ^ L Zinc P g g j amp J L i f i g g g ZpoundgttP 4F r o Othert ^ 0 0 3 ^ aro E I K Zlt^g^ z a U - ^
Jis iRrOUALf LABORATORY^QUALIFIERS
R = Reported value is less than the Contract Required Detection Limit A ^ r L - S b S l - O O f liia-rULttya i uA (CRDL) but greater than the instrument detection l imit (IDL)
CAjAfu^U gjf-^o n frv^mdashshyU = Analyte was analyzed for but not detected
E = Reported value is estimated because of the presence of interference
N = Spiked sasple recovery not within control l imits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control l imits u j - ^ o c f cUc-eoffeE^ S p f f e A T L r u j o t A ^ c A ^ I o u plusmn o f cM^Phrc
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV HSL INORGANIC ANALYSIS PROJECT NAME ^Ol4 i ^ J ^ ^ S ^CplKAI^T RESULTS ( j i p i ^ PROJECT NUMBER ^ ^ I f t ^
PAGE ^ of lppound
Sample Location Sample Number h r i amp t gt S ^ - O O S r r r i r s t ^ ^ L d A i ^h rL^ S l ^ t b t i nirpoundstgt-s0Oor
Inorganic Elements
Aluminum P Jfo o o H Z O S 3 0 0 ^zaoo ^ ^ 2 2 j O 0 t Antimony o tA )o u A f t o A J O O AJ ^ F u uArsenic F ^ o ^ 730 A i^Zd lt i O 9 0 Barium P 9ltfO ^ I P O = i 5T6 IA t i f O O uBeryllium P - o t t lt 9 3 t u M O f t t V S^ Cadmium ^ f - o t g uu laquo5laquoV u on-h tA J^OO M Calcium P 1 ^ 0 ^ 0 A 6^ iO A j i i t o o 7 64fyO0p Chromium P 2gp VL Nyen 3 laquo o u h 6 Z O A J M OL AJ4 bt^ t Cobalt P ^ o O Z O tplusmn ^ f o u^ ^kke Copper P y 20 3 ^ 0 S l u o A 2 J U o ampMIron P Hb r^o ltfoooo 6 S O O O amp ^ 9 0 0 Lead F ^ - I t O H J O s Magnesium P -z f t f ao A bullp^dLoo A ^ z v o o ^ oso oo A Manganese P n z oo A ) i t g 1^6Pd6 ^ AlMt c-TftA A O ^ A M f f 9 0 0 0 0 A l i f Mercury CV oz-i r - i 9 tA O t 0 u d V J raquo U Nickel P 9-)o
utplusmn j t 2 K- ^ u j i ^ ^ Potassium P AP amp ZO j k Jz4Sl5h R ^Lf^sTbo s i L4 OO
Selenium F 0 9 - t e i f tJt CAJ fff s ugt z o o Sliver P t o Us A J u AJ amp ^ U J J Soo iLK A Sodium P M A M L A O plusmnClOO A iko ^ T Thallium F o 1 Avo U I A J ysraquoD ix ^ bull O O L t Vanadium P JSrSTgt jR lt o u pound r 2 gt B t r f b ^o B Zinc P s ^ o ^ T a s r r o o tzo Othen G A ^ M I U f k P t i ^ f 0 u ^ J P M - ^ c ^ ^ r^^o LABORATORYC^ALIFIERS
R = Reported value is less than the Contract Required Detection Limit (CROL) but greater than the instrument detection limit (IDL)
U = Analyte was analyzed for but not detected
E - Reported value is estimated because of the presence of interference
N = Spiked saaple recovery not within control limits
S = Reported value was determined by the Method of Standard Addition (MSA)
= Duplicate analysis was not within control limits LJ z Po5^ cL^laquoJL Jj- ife- ff fv Fu uu HV Cs irudc t^ Cujvm
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V
VALIDATED DATA - PHASE I GROUND IJATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location KOI M02 S M02DR H03SR M03DR Sample Nugiber GK-HOl-001 GW-H02S-002 Glaquo-M02DR-0G3 GW-M03SR-004 6H-H03DR-005
Inorganic
-Aluminum - (55CU) (55OU) - (550U) - (55OU) - (550U) Antimony - (230UJ) - (40UJ) - (lOU) - (40UJ) - (40UJ) Arsenic - (20U) 192 (20U) 279 (20U) 433 (20U) 191 (20U) ampar]m - (3500) 377 (350U) 585 (3500) - (350U) 489 (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) CadiiiiuiB - (lOUJ) - (lOU) - (lOU) - (lOU) - (lOU) Calcium 2580 (700U) 27500J (70OU) 20800J (700U) 18300J (70OU) 24400J (700U) Chromium - (lOOU) - (10OU) - (lOOU) - (lOOU) - (10OU) Cobalt - (300U) 51J (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (50U) - (50U) - (50U) Iron - (250U) 10700 (250U) 1510 (250U) 18000 (250U) - (381UJ) Lead - (llOUJ) - (20U) (20U) 30J (20U) 27J (20U) - bull
Magnesium - (930UJ) IIIOJ (700U) 3860J (700U) 3130J (700U) 4270J (70CU) Hanganese - (50U) 3740 (50U) 839 (50U) 4440 (50U) 123 (50U) Mercury - (020U) - (020U) - (020U) - (020U) - (020U) Nickel - (250U) - (250UJ) - (250UJ) - (250UJ) - (25CUJ) Potassium - (1763UJ) 3020J (1450U) 2650J (1450U) 3160J (1450U) 2840J (1450U) Selenium - (lOU) - (lCU) - (80UJ) lOJ (LOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 2180 (600U) 9970J (60OU) 5120J (600U) 18000J (600U) 5630J (50OU) Thallium - (40U) - (40UJ) - (40U) - (40U) - (40U) Vanadium - (150U) - (150U) - (150U) - (15GU) - (150U) Zinc 515J (150U) - (150UJ) 578J (150U) - (150UJ) - (150UJ)
Cyanide (lOOU) (10OU) (1000) (100U) (10OU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 8
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V (Continued)
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS
Saaple Location H04S M04D M05S M05DR m Sample Number GW-M04S-006 GW-M04D-007 GW-M05S-008 Glaquo-KO50R-009 GW-H06-010
Inorganic
Aluminum - (550U) (550U) (550U) (550U) (550U) Antimony - (40UJ) - (40UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic 104 (20U) 27 (20U) - (20UJ) 33 (20U) 55 (20U) Barium - (350U) - (35OU) - (350U) 559 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Cadmium - (lOUJ) - (lOUJ) - (lOU) - (lOU) - (lOU) Calcium 6050 (700U) 17100 (700U) 8280 (70OU) 20500 (700U) 20100J (700U) Chromium - (lOOU) - (lOOU) 258 J (lOOU) - (10OU) - (lOOU) Cobalt - 238UJ) - (300U) - (300U) - (300U) - (300U) Copper - (50U) - (50U) - (5CU) - (50U) - (50U) Iron 3950 (250U) - (354UJ) - (147UJ) - (147UJ) 714 (250U) Lead - (llOUJ) - (llOUJ) 21 (20U) - (20U) 24J (20U) Magnesium 1340 (700U) 4030 (700U) 1520 (700U) 3700 (700U) 3040J (70OU) Hanganese 4250 (50U) 113 (50U) - (270UJ) 194 (50U) 145 (50U) Hercury - (020U) - (020U) 040 (020U) - (020U) - (020U) Nickel - (250U) - (250U) - (250U) - (250U) - (250UJ) Potassium 3050 (1450U) 3750 (1450U) 1730 (1450U) 3610 (1450U) 2440J (1450U) Selenium - (lOU) - (LOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) 649J (50U) - (50UJ) - (50UJ) - (50UJ) Sodium 7710 (600U) 6630 (600U) 3840 (600U) 4970 (600U) 6380J (600U) Thallium - (40U) - (40U) - (40UJ) - (40U) - (40UJ) Vanadium - (150U) - (150U) - (15OU) - (15OU) - (150U) Zinc - (150U) - (150U) 301 (150U) 277 (150U) - (150UJ)
Cyanide (lOOU) (lOOU) (10OU) (lOOU) (lOOU)
DATA QUALIFIERS
- shy Not detected J - Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
HH7S GW-MW7S-011
MW7D GW-HW7D-012 GW-HW8S-013
MW9S 6W-HK9S-015
HW9D GH-HW9D-016
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodiuiii Thallium Vanadium Zinc
3410
391
14500
(550U) (40UJ) (20U) (350U) (lOU) (lOUJ) (700U) (lOOU) (238UJ) (50U) (250U) (llOUJ) (930UJ) (50U) (020U) (250U) (1763UJ) (lOU) (50UJ) (600U) (40U) (15OU) (99UJ)
3710 (550U) - (40U)
52J (20U) - (350U) - (lOU) - (lOUJ)
18800J (700U) - (lOOU)
379J (300U) - (50U) - (381UJ)
28J (20U) - (700U) - (50U) - (020U) - (250UJ)
48800J (1450U) - (lOU) - (50UJ)
68800J (60GU) - (40U) - (150U) - (150UJ)
--
168 ---
7900 ---
1520 -
2350 2670 --
5000 --
5150 ---
(550U) (40U) (20U) (35OU) (lOU) (lOUJ) (700U) (10OU) (238UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (150U) (150U)
487 ----
28J 1540J -
373J --
36J 861J 225 -
126J 709J --
3360J ---
(550U) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (70OU) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150UJ)
194 -----1920 ---
862 --
108 -----
3720 ---
(55OU) (40UJ) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (238UJ) (50U) (25OU) (llOUJ) (930UJ) (50U) (020U) (178UJ) (1783UJ) (lOU) (50UJ) (600U) (40U) (121UJ) (99UJ)
Cyanide (lOOU) (10OU) (10OU) (10OU) (lOOU)
DATA QUALIFIERS
- shy Not detected J = Data approximated as a result of quality control review
(U) shy Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R shy Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam P r o j e c t 8185
HSL INORGANIC ANALYSES (Concentrat ions in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HWIOD HWllD KH12S HH12D MH13S Sample Number GW-MWlOO-017 GW-HWllD-018 6H-HH12S-019 GW-HW12D-020 GW-HW13S-021
Inorganic
Aluminum 876 (550U) - (550U) - (5500) - (550U) (550U) Antimony - (230UJ) - (280UJ) - (40UJ) - (40UJ) - (40UJ) Arsenic - (20UJ) - (20U) - (20U) 80 (20U) - (20U) Barium - (350U) - (350U) - (350U) 388 (350U) - (350U) Beryllium - (lOU) - (lOU) - (lOU) - (lCU) - (lOU) Cadmium - (lOUJ) - (lOU) - (lOUJ) - (lOUJ) - (lOU) Calcium 12500 (700U) 4620 (700U) 7480 (700U) 22500 (700U) 3690 (700U) Chroffliuiii - (lOOU) 46 OJ (lOOU) - (lOOU) - (lOOU) - (lOOU) Cobalt - (300U) - (300U) - (300U) - (300U) - (238UJ) Copper - (50U) - (280UJ) - (50U) - (50U) - (50U) Iron - (354UJ) 633 (25OU) - (354UJ) 384 (250U) - (354UJ) Lead - (llOUJ) - (20U) - (llOUJ) - (llOUJ) - (20U) Magnesium - (930UJ) 450 (700U) 1450 (700U) 3980 (70OU) - (930UJ) Hanganese - (50U) 110 (50U) 184 (50U) 829 (50U) - (50U) Hercury - (020U) - (020U) - (020U) - (020U) - (020U) bull Nickel - (250U) - (250U) - (178UJ) - (250U) - (178UJ) Potassium 5770 (1450U) 1050 (1450U) 2790 (1450U) 2900 (1450U) - (1763UJ) Selenium - (lOU) - (lOU) - (lOU) - (lOU) - (lOU) Silver - (50UJ) - (50UJ) - (50UJ) - (50UJ) - (50UJ) Sodium 6770 (600U) 3950 (600U) 7120 (600U) 4980 (600U) 2400 (600U) Thallium - (40UJ) - (40U) - (40UJ) - (40UJ) - (40U) Vanadium - (15OU) - (150U) - (150U) - (150U) - (150U) Zinc - (99UJ) 482 (150U) - (150U) - (99UJ) 181J (150U)
Cyanide (lOOU) (lOOU) (lOOU) (lOOU) (lOOU)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
rage 4 Ol 8
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V (Continued)
VALIDATED DATA shy PHASE I GROUND WATER SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPB)
Balsam Project 8185
MOTTOLO RIFS RAYMOND NH
Sample Location Sample Number
Inorganic
MW13D GW-MW13D-022
HW13D GW-DUP-038 Duplicate
HW14 S GH-HW14S-023
HW14D GW-MW14D-024
HW15S GH-KW15S-025
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
_
-
26 ---
24400 -----
4080 838 --
2960 --
4880 --
IIOJ
(550U) (230UJ) (20U) (35OU) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (700U) (50U) (020U) (250U) (1450U) (100) (50UJ) (600U) (40UJ) (150U) (150U)
_
-
26 ---
24100 -----
3810 726 --
3050 --
4940 --
178J
(550U) (40UJ) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (300U) (50U) (354UJ) (llOUJ) (70OU) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40UJ) (15OU) (150U)
-
-
47 ---
17500 ---
546 -
2980 612 --
3750 --
8410
--
(5500) (230UJ) (20U) (350U) (lOU) (lOUJ) (7000) (lOOU) (233UJ) (50U) (250U) (llOUJ) (700U) (50U) (020U) (178UJ) (1450U) (lOU) (50UJ) (600U) (40U) (150U) (99UJ)
-
-
23 ---
25100 -----
3460 632 --
4130 --
8210 ---
(550U) (40U) (20U) (3500) (lOU) (lOUJ) (700U) (lOOU) (3000) (50U) (250U) (llOUJ) (7000) (50U) (020U) (250U) (1450U) (lOU) (50UJ) (800U) (40U) (1500) (150U)
-
50J ----
6220J ----
28J 1540J 1450 --
3150J --
(550U) (40U) (20U) (350U) (lOU) (lOU) (700U) (lOOU) (300U) (50U) (381UJ) (20U) (700U) (50U) (020U) (250UJ) (1450U) (80UJ) (50UJ)
32000J (600U) ---
(40U) (15OU) (150UJ)
Cyanide - (10OU) - (10OU) - (10OU) - (1000) - (lOOU)
DATA QUALIFIERS
- shy Not detected J shy Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 5 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 6185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location HW15D HW16D KW17D Sample Number GW-HW15D-026 GW-HW18D-027 GK-HW170-028
Inorganic
Aluminum - (550U) - (550U) - (550U) Antimony - (40UJ) - (40UJ) - (40UJ) Arsenic ll (200) - 20U) - (20U) Barium - (350U) - (3500) - (3500) Beryllium - (lOU) - (lOU) - (100) Cadmium - (lOUJ) - (lOU) - (lOU) Calcium 19800 (700U) 10300J (700U) 207C0J (70GU) Chromium - (lOOU) - (lOOU) - (lOOU) Cobalt - (238UJ) - (3000) 327J (3000) Copper - (740UJ) - (50U) - (5GU) Iron 588 (2500) - (381UJ) 4010 (2500) Lead - (llOUJ) 80J (20U) 26J (20U) Magnesium 3880 (700U) 1240J (700U) 3040J (700U) Hanganese 125 (500) 221 (50U) 244 (50U) Hercury - (020U) - (020U) - (020U) Nickel - (178UJ) - (250UJ) - (250UJ) Potassium 4500 (1450U) 1200J (1450U) 3090J (14500) Selenium - (lOU) - (lOU) - (lOUJ) Silver - (50UJ) - (50UJ) - (50UJ) Sodium 7540 (600U) 8730J (6000) 726GJ (600U) Thallium - (40U) - (40UJ) - (40U) Vanadium - (150U) - (150U) - (150U) Zinc - (1500) - (150UJ) 152J (1500)
Cyanide (1000) (1000) (1000)
DATA QUALIFIERS
- ^ Not detected J = Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
MW18S HW18D GW-HW18S-029 GH-HW180-030
- (5500) - (55GU) - (400J) - (40UJ) - (20U) - (200) - (3500) - (350U) - (lOU) - (lOU) - (lOU) - (lGO)
114GGJ (700U) 178G0J (70GU) - (10OU) - (lOOU)
30IJ (3000) - (3000) - (500) - (50U) - (381UJ) - (381UJ) - (2GU) 22J (20U)
1320J (7000) 3990J (7000) 552 (50U) 406 (50U) - (0200) - (02GU) - (250UJ) - (25GUJ)
1360J (1450U) 9750J (14500) bull - (lOU) - (80UJ) - (500J) - (50UJ)
11700J (6000) 11600J (600U) - (400J) - (40U) - (1500) - (150U) - (150UJ) - (150UJ)
(10OU) (1000)
Page 6 of 8
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE I GROUND WATER SAMPLING Balsam Pro jec t 8185 HSL INORGANIC ANALYSES (Concentrat ions i n PPB)
HOTTOLO RIFS RAYHOND NH
Sample Location HW190 0W2SR 0W2SR 0W2DR 0W2DR Sample Number GW-MW19D-031 GW-OW2SR-032 GW-DUP-041 GW-OW2DR-033 GW-DUP-042
Duplic ate Duplicate Inorganic
Aluminum _ (550U) - (5500) - (5500) - (5500) - (5500) Antimony - (40UJ) - (40U) - (40UJ) - (40UJ) - (400) Arsenic 413 (200) 188 (20U) 187 (2GU) 528 (200) 524 (20U) Barium - (3500) 420 (3500) 409 (3500) 704 (3500) 688 (3500) Beryllium - (lOU) - (lOU) - (lOU) - (100) - (lOU) Cadmium - (lOU) - (lOUJ) - (lOUJ) - (lOU) - (lOU) Calcium 24700J (7000) IIGOO (7000) 11100 (700U) 44200J (700U) 39000J (700U) Chromium - (IGOU) - (1000) lOlJ (lOOU) - (1000) - (lOOU) Cobalt - (300U) - (300U) - (3000) - (3000) - (300U) Copper - (5GU) - (280UJ) 304 (500) - (500) - (500) Iron - (381UJ) 104000 (2500) 101000 (2500) - (3810J) - (381UJ) Lead - (20U) - (20UJ) - (200) 90J (20U) - (20UJ) Hagnesium 2620J (700U) 2810shy (7000) 2890 (7000) 4530J (7000) 4160J (7000) Hanganese 140 (50U) 8910 (500) 8930 (500) 230 (50U) 233 (500) Mercury - (020U) - (0200) 11 (0200) - (020U) - (020U) Nickel - (250UJ) - (25OU) - (134UJ) - (250UJ) - (250UJ) Potassium 1650J (1450U) 5840 (14500) 5650 (14500) 27800J (14500) 28800J (14500) Selenium - (lOOJ) - (lOU) - (lOOJ) - (lOU) - (800J) Silver - (500J) - (500J) - (500J) - (500J) - (500J) Sodium 51G0J (80OU) 33900 (6000) 34700 (6000) 48500J (600U) 51800J (6000) Thallium - (40U) - (40U) - (40UJ) - (400J) - (40UJ) Vanadium - (15GU) 357 (1500) 400 (1500) - (1500) - (150U) Zinc - (15GUJ) 391 (1500) 694 (150U) - (150UJ) 225J (150U)
Cyanide (1000) (1000) (1000) (lOOU) (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 7 of 8
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V (Continued )
VALIDATED DATA - PHASE I GROOND WATER SAMPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location 0W3R 0W4SR Sample Number GW-OW3R-034 GW-OW4SR-035
Inorganic
-
Antimony - (40UJ) - (40UJ) Arsenic 58 (20U) 978 (20U) Barium 251 (3500) 599 (3500) Beryllium - (lOU) - (lOU) Cadmium - (100) - (lOOJ) Calcium 41200 (7000) 12700 (7000) Chromium 157J (1000) - (1000) Cobalt - (3000) - (238UJ) Copper - (280UJ) - (7400J) Iron - (147UJ) 99500 (250U) Lead - (20U) - (1100J) Hagnesium - (423UJ) 3570 (7000) Hanganese - (500) 4630 (500) Hercury (0200) - (0200)
Aluminum 202 (5500) (5500)
- bull
Nickel - (2500) - (178UJ) Potassium 47200 (14500) 4060 (14500) Selenium - (50UJ) - (100) Silver - (500J) - (50UJ) Sodium 44100 (6000) 50200 (6000) Thallium - (400) - (400) Vanadium - (150U) - (121UJ) Zinc 339 (1500) - (99UJ)
Cyanide - (10OU) - (1000)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 8 Oi 8
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V ( C o n t i n u e d )
Balsam Project 8185
HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
Sample Location S 1 S2 c2 S3 c4 Sample Number SW-Sl-001 SW-S2-002 SW-DUP-011 SW-S3-003 SW-S4-009
Ouplicate Inorganic
Aluminum 815 (5500) 111 (5500) 104 (550U) 251 (5500) 233 (5500) Antimony - (40UJ) - (40UJ) - (280UJ) - (280UJ) - (40UJ) Arsenic - (200) - (200) - (200) - (200) - (20U) Barium - (3500) - (3500) - (3500) - (3500) - (350U) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOUJ) - (100) - (lOU) (lOOJ) - (lOOJ) bull shy
Calcium 1880 (700U) 2060 (7000) 2130 (7000) 2190 (700U) 1440 (700U) Chromium 139J (1000) 202J (1000) - (10OU) 185J (1000) - (1000) Cobalt - (300U) - (3000) - (3000) - (3000) - (300U) Copper - (500) - (500) - (500) - (500) - (500) Iron - (1470J) - (1470J) - (1470J) 268 (2500) 398 (2500) Lead - (200) - (20U) - (200) - (20UJ) - (20U) Hagnesium 558 (7000) 585 (7000) 626 (7000) - 595 (7000) 436 (7000) Hanganese - (2700J) - (270UJ) - (270UJ) 70 (50U) 386 (50U) Hercury - (0200) - (020U) - (020U) - (0200) - (020U) Nickel - (2500) - (250U) - (250U) - (2500) - (2500) Potassium 1290 (14500) 1640 (1450U) 1320 (14500) 1470 (14500) 927 (1450U) Selenium - (100) - (lOU) - (100) - (lOOJ) - (lOU) Silver - (500J) - (500J) - (500J) - (500J) - (50UJ) Sodium 2320 (6000) 2740 (600U) 2370 (600U) 2600 (60OU) 2890 (6000) Thallium - (400) - (400) - (40U) - (40UJ) - (40U) Vanadium - (1500) - (1500) - (150U) - (1500) - (1500) Zinc 229 (150U) 295 (1500) 277 (150U) 172 (150U) 344 (1500)
Cyanide (1000) (1000) (1000) (1000) (lOOU)
DATA QUALIFIERS
- = Not detected J - Data approximated as a result of quality control review
(0) - Instrument Detection Limit (OJ) - Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 1 of 3
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
- -
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SURFACE WATER SAHPLING Balsam Project 6185 HSL INORGANIC ANALYSES (Concentrations in PPB)
MOTTOLO RIFS RAYMOND NH
cSample Location S5 S8 V 7 S 3 S^
Sample Number SW-S5-005 SW-S6-008 SW-S7-007 SW-S8-008 SW-S9-004
Inorganic
Aluminum 189 (5500) 113 (5500) (550U) (5500) 5880 (5500) Antimony - (400J) - (400J) - (400J) - (40UJ) - (400J) Arsenic - (200) - (200) - (200) - (200) - (200J) Barium - (3500) - (3500) - (3500) - (3500) - (3500) Beryllium - (100) - (100) - (100) - (100) - (lOU) Cadmium - (lOOJ) - (lOUJ) - (100) - (lOUJ) - (lOU) Calcium 2170 (7000) 2130J (700U) 4340 (7000) 4210 (700U) 3040 (7000) Chromium 189J (1000) - (1000) 116J (1000) 157J (1000) - (1000) Cobalt - (3000) - (3000) - (3000) - (3000) - (3000) Copper - (500) - (500) - (500) - (500) - (2800J) Iron 223 (2500) - (3810J) bull - (147UJ) 197 (2500) 3650 (2500) Lead - (200) - (20U) - (200J) - (20U) 134 (200) Hagnesium 720 (7000) 586J (700U) 943 (7000) 805 (7000) 730 (700U) Hanganese 566 (500) 194 (50U) - (270UJ) - (270UJ) 1070 (500) Hercury - (020U) - (020U) - (0200) - (0200) - (0200) Nickel - (2500) - (2500J) - (2500) - (25OU) - (2500) Potassium 1360 (14500) 1040J (14500) 1530 (14500) 1520 (1450U) 1610 (14500) Selenium - (100) - (lOUJ) - (100) - (lOOJ) - 50UJ) Silver 871J (500) - (500J) - (500J) - (500J) - (50UJ) Sodium 2490 (6000) 2450J (6000) 9740 (600U) 9760 (6000) 5580 (6000) Thallium - (400J) - (400J) - (400) - (400) - (400) Vanadium - (1500) - (1500) - (1500) - (1500) - (1500) Zinc 167 (1500) - (150UJ) 281 (1500) 224 (1500) 219 (1500)
Cyanide (1000) (1000) (1000) (1000) (1000)
DATA QUALIFIERS
- - Not detected J - Data approximated as a result of quality control review
(U) - Instrument Detection Limit (UJ) = Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 2 of 3
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE V ( C o n t i n u e d )
VALIDATED DATA - PHASE HSL INORGANIC ANALYSES
I SURFACE WATER SAMPLING (Concentrations in PPB)
- Balsam Project 6185
HOTTOLO RIFS RAYHOND NH
Sample Location Sample Number
SIO sw-silO-010
Inorganic
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese bull Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
129 -----
13100 12 OJ --
546 -
1970 268
--
5610 --
3720 --
215
(5500) (400J) (20U) (3500) (lOU) (100) (7000) (1000) (300U) (500) (2500) (20UJ) (7000) (500) (0200) (2500) (14500) (100) (500J) (6000) (40U) (1500) (1500)
Cyanide shy (1000)
DATA QUALIFIERS
- -- Not detected J - Data approximated as a result of quality control review
(0) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
NOTE
Samples were filtered in the field using a 045 micron filter
Page 3 of 3
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
T A B L E V ( C o n t i n u e d )
VALIDATED DATA - PHASE I SEDIMENT SAMPLING Balsam Project 8185 HSL INORGANIC ANALYSES (Concentrations in PPM)
MOTTOLO RIFS RAYHOND NH
Sample Location SI S2 s3 S4 S5 Sample Number SD-Sl-001 SD-S2-002 SD-S3-003 SD-S4-007 S0-S5-005
Inorganic
Aluminum 1710J (97U) 1920J (1240) 3580J (1430) 3840J (131U) 1120J (99U) Antimony - (IIUJ) - (14UJ) - (16UJ) 18J (15U) - (IIOJ) Arsenic 14J (0550) 13 IJ (0710) 24J (0820) - (0750) 13J (057U) Barium 449 (970) 394 (1240) 316 (143U) 198 (1310) - (990) Beryllium - (0280) - (038U) - (0410) - (0380) - (0280) Cadmium - (0280J) - (0360) - (0410) - (038U) - (028U) Calcium 364 (1930) 545 (2490) 1910 (2870) 409 (262U) 240 (199U) Chromium - (280J) - (360J) - (41UJ) - (38UJ) - (28UJ) Cobalt - (830) - (1070) - (123U) - (113U) - (85U) Copper - (1800J) - (2300J) - (2600J) - (2400J) - (180UJ)
Iron 3970 (69U) 8340 (890) 3680 (1020) 5170 (940) 1430 (71U) Lead 56 (0550) 80 (0710) 40 (082U) 96 (0750) 43 (057U) Hagnesium 594 (1930) 479 (2490) 951 (287U) 285 (2620) 284 (199U) Hanganese 2010J (140) 706J (180) 334J (200) 545J (19U) 192J (14U) Hercury - (013U) (0160) - (0200) - (018U) - (0130) Nickel (69U) - (4600J) - (1020) - (94U) - (710) Potassium - (355UJ) - (4560J) - (5260J) - (482UJ) - (3850J) Selenium - (028UJ) - (28UJ) - (33UJ) - (300J) - (230J) Silver - (14UJ) - (18UJ) - (200J) - (19UJ) - (14UJ) Sodium 798J (166U) 119J (213U) 107J (2460) IIIJ (225U) 691J (170U) Thallium - (IIUJ) - (14U) - (160) - (15U) - (110) Vanadium - (410) - (530) - (61U) - (56U) 45J (43U) Zinc 237J (410) 229J (53U) 201J (810) 157J (56U) 182J (43U)
Cyanide 313J (160) - (22U) - (210) - (21U) - (16U)
DATA QUALIFIERS
- -shy Not detected J - Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) - Detection limit approximated as a result of quality control review
R - Data rejected as a result of quality control review
Page 1 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2
TABLE IV (Continued)
VALIDATED DATA - PHASE I SEDIMENT SAMPLING HSL INORGANIC ANALYSES (Concentrations in PPM)
Balsam Project 6185
MOTTOLO RIFS RAYMOND NH
Saaple Location Sample Number
Inorganic
S5 SD-DUP-009 Duplicate
S6 SD-S6-006
S9 SD-S9-004
SIO SO-SlO-008
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Hagnesium Hanganese Hercury Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
1230J 14J 19J ---
297 ---
1480 26 308 161J -----
949J --
60J
(93U) (110) (0540) (930) (0270) (0270) (1870) (27UJ) (800) (1700J) (870) (0540) (1870) (13U) (0130) (670) (3430J) (21UJ) (130J) (1600) (IIU) (400) (400)
2050J -
13J 198 --
807 ---1900 47 367 530J -----
896J --
157J
(1190) (140J) (0880) (1190) (0340) (034U) (237U) (34UJ) (102U) (2200J) (85U) (0680) (2370) (17U) (0170) (850) (4350J) (0340J) (170J) (2030) (140J) (510) (510)
8120J -
42J ---
388 63J --
6130 121 624 301J -----
106J -
65J 199J
(1150) (13UJ) (0680) (1150) (0330) (0330) (2300) (33U) (99U) (210UJ) (82U) (068U) 230U) (16U) 016U) (82U) (422UJ) (26UJ) (16UJ) (1970) (13U) (49U) (49U)
7220J -
807J 448 -
30 8980 -
732 -
69900 269 1030
(3460) (400J) (200) (3460) (0990) (0990) (6930) (99UJ) (297U) (6300J) (247U) (200) (8930)
11800J (500) -- ---
261J -
334J 158J
(0470) (1280J) (12710J) (790J) (500J) (5940) (400) (1480) (1480)
Cyanide 70J (170) - (19U) 41J (190) 86J (59U)
DATA QUALIFIERS
- = Not detected J = Data approximated as a result of quality control review
(U) = Instrument Detection Limit (UJ) shy Detection limit approximated as a result of quality control review
R = Data rejected as a result of quality control review
Page 2 of 2