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    Performance and emission characteristics of a turbocharged

    spark-ignition hydrogen-enriched compressed natural gas

    engine under wide open throttle operating conditions

    Fanhua Ma*, Mingyue Wang, Long Jiang, Jiao Deng, Renzhe Chen, Nashay Naeve,Shuli Zhao

    State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, PR China

    a r t i c l e i n f o

    Article history:

    Received 16 July 2010

    Received in revised form

    13 August 2010

    Accepted 13 August 2010

    Available online 17 September 2010

    Keywords:

    Wide open throttle

    Combustion

    Emission

    a b s t r a c t

    This paper investigates the effect of various hydrogen ratios in HCNG (hydrogen-enriched

    compressed natural gas) fuels on performance and emission characteristics at wide open

    throttle operating conditions using a turbocharged spark-ignition natural gas engine. The

    experimental data was taken at hydrogen fractions of 0%, 30% and 55% by volume and was

    conducted under different excess air ratio (l) at MBT operating conditions. It is found that

    under various l, the addition of hydrogen can significantly reduce CO, CH4 emissions and

    the NOx emission remain at an acceptable level when ignition timing is optimized. Using

    the same excess air ratio, as more hydrogen is added the power, exhaust temperatures and

    max cylinder pressure decrease slowly until the mixtures lower heating value remains

    unchanged with the hydrogen enrichment, then they rise gradually. In addition, the early

    flame development period and the flame propagation duration are both shorter, and the

    indicated thermal efficiency and maximum heat release rate both increase with more

    hydrogen addition.

    2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

    1. Introduction

    Recently, environmental protection and energy conservation

    have been increasingly concerned worldwide, more and more

    attention in the auto industry has been shifted to the use of

    alternative fuels. Among all these potential fuels, hydrogen isconsidered to be the most desirable alternative fuel used in

    vehicle engines [1]. Hydrogen has many advantages, such as it

    can be obtained from electrolysis of water and the electricity

    used can be generated by solar energy, which means

    hydrogen is a kind of real renewable energy, or an ideal energy

    carrier [2].

    However, there are many potential problems in hydrogens

    production, storage and distribution if hydrogen is used as

    energy. At present, hydrogen is limited used as additive to

    other fuels, and HCNG (hydrogen-enriched compressed

    natural gas) has been regarded as the most potential energy to

    take the place of engine oil in a short time [3]. HCNG, also

    called Hythane (themixtures of H2 and CNG), is the alternative

    gas fuel which blends the H2 and CNG (compressed naturalgas) at a given ratio. The research and development of HCNG

    engine can be treated as the transitional technological means

    to the wide use of hydrogen energy. In addition, HCNG vehi-

    cles commercialization can be beneficial to the hydrogen

    energys infrastructure.

    Some thermal and chemical properties of hydrogen and

    methane, which is the main component of natural gas, are

    compared in Table 1 [4]. As can be seen, hydrogen has a wider

    * Corresponding author. Tel./fax: 86 10 62785946.E-mail address: [email protected] (F. Ma).

    A v a i l a b l e a t w w w . s c i e n c e d i r e c t . c o m

    j o u r n a l h o m e p a g e : w w w . e l s e v i e r . c o m / l o c a t e / h e

    i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 3 5 ( 2 0 1 0 ) 1 2 5 0 2 e1 2 5 0 9

    0360-3199/$ e see front matter 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

    doi:10.1016/j.ijhydene.2010.08.053

    mailto:[email protected]://www.sciencedirect.com/http://www.elsevier.com/locate/hehttp://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://dx.doi.org/10.1016/j.ijhydene.2010.08.053http://www.elsevier.com/locate/hehttp://www.sciencedirect.com/mailto:[email protected]
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    flammable mixture range, lower ignition energy and much

    faster burning speed, all of which are helpful to improveengines lean burn capability; and CNG reserves are abundant

    and result in relatively low emissions compared with tradi-

    tional gasoline and diesel in combustion engines. HCNG fuel

    possesses advantages of both H2 and CNG. We can attribute

    HCNG engine remarkable combustion speed to the hydrogen

    contribution. Addition of hydrogen increases burning velocity

    of HCNG [5]. Therefore, it is a potential alternative fuel to

    vehicle engines.

    An engines performance during WOT (wide open throttle)

    conditions directly indicates the engines maximum power

    performance includingthe vehiclesmaximumspeed, maximum

    acceleration andgrade abilityetc [6].Hence,thereisalwaysmuch

    attention paid to the engines WOT parameters.This paper specifically deals with the engines performance

    and emission characteristics in a turbocharged spark-ignition

    (SI) natural gas engine at WOT operating conditions under

    various operating conditions including different spark timing,

    excess air ratio (l), with different fuel: CNG, 30% HCNG, 55%

    HCNG, percentages of hydrogen are measured on a per

    volume scale.

    2. Previous work

    Over the past several years, there has been extensive researchrelated to hydrogen-enriched fuels, of which some focuses on

    the influence of the hydrogen addition on the engines overall

    performance. This research includes the engines power,

    efficiency, and combustion, emission performance under

    various engine speeds, excess air ratios, ignition timings andMAP(Manifold Absolute Pressure) including medium load, low

    load and even idle conditions.

    Ma et al. carried out a series of experiments to research the

    port-injection HCNG engines combustion and emission

    characteristics under various ignition timings. They found

    that the combustion duration and ignition delay are both

    reduced linearly with the addition of hydrogen, and the NOx,

    CO and THC (total hydro-carbon emissions) emissions all

    descend with the increase of spark advance angle, and ascend

    as the MAP increases [7].

    Wang et al. investigated the combustion behavior of

    a direct injection engine operating on various fractions of

    NGe

    hydrogen blends [8]. The results showed that the brakeeffective thermal efficiency increased with the increase of

    hydrogen fraction at low and medium engine loads. The rapid

    combustion duration decreased, the heat release rate and

    exhaust NOx increased with the increase of hydrogen fraction

    in the blends. Their study suggested that the optimum

    hydrogen volumetric fraction in NGehydrogen blends is

    around 20% to get compromise in both engine performance

    and emissions.

    Collier et al. pointed out that the engine application which

    could achieve the greatest advantage from HCNG was heavy-

    duty engine [9]. They achieved a major reduction in NOxemission in a Daewoo heavy-duty engine fuelled with HCNG

    containing 30% hydrogen at all power levels while kept COand THC in the same range of a conventional CNG engine.

    Table 1 e Comparison of hydrogen and methane [4].

    Fuel characteristics Hydrogen(H2)

    Methane(CH4)

    Equivalence ratio ignition lower

    limit in NTP air

    0.1 0.53

    Mass lower heating value(kJ/kg) 119,930 50,000

    Density of gas NTP(kg/m3

    ) 0.083764 0.65119Volumetric lower heating value at

    NTP (kJ/m3)

    10,046 32,573

    Stoichiometric air-to-fuel ratio 34.20 17.19

    Volumetric fraction of fuel in air,

    l 1

    0.290 0.095

    Volumetric lower heating value in

    air l 1

    2913 3088

    Burning speed in NTP air(cm/s) 265e325 37e45

    Flame temperature in air(K) 2318 2148

    NTP denotes normal temperature (293.15K) and pressure (1 atm).

    Table 2 e Engine specifications.

    Item Value

    Engine make DONGFENG MOTOR CO., LTD,

    China

    Engine type in-line 6 cylinders,

    spark ignition

    Aspiration method Turbocharged intercooledCompression ratio 10

    Bore (mm) 105

    Stroke (mm) 120

    Displacement Volume(L) 6.234

    Rated power/speed 154 kW/2800 rpm

    Maximum torque/speed 620 Nm/1600 rpm

    Full-load minimum fuel

    consumption rate

    198 g/kW h

    Table 3 e Measurement instruments specifications.

    Instruments Range Sensitivity Linearity

    Cylinder pressure sensor (Kistler6117B) 0e20 Mpa 16.8 pC/bar 0.6% FSO

    Charge Amplifier (Kistler5011B) 10e9.99 105 (10V FS) 0,01e9.99 104 pC/M.U.;

    0,01e9.99 104 mV/M.U.

    0.05% FS

    Crank angle generator (Kistler2613B) 1w2.0 104 r/min 0.1e6 e

    Mass air flow meter (ToCeil20N100114LI) 0w1000 Nm3/h 1% 0.24%

    Alicat Mass CNG flow meter 0.5(S)CCM_1500(S)LPM 0.4% e

    Alicat Mass hydrogen flow meter 0.5(S)CCM_1500(S)LPM

    0.4%e

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    Through the experiments aimed at optimizing the intake

    system for HCNG application, they found that the homoge-

    neousness of fueleair mixture was very important to NOxemission.

    Bauer and Forest reported a test conducted on a single

    cylinder cooperative fuel research engine operating on

    mixtures of hydrogen in methane of 0%, 20%, 40% and

    60% by volume. [4] Each fuel was tested at the speeds of

    700 and 900 rpm, full and part loads, and equivalence

    ratios from stoichiometric to the partial burn limit. The

    experiment results showed that hydrogen enrichment

    reduced the value of spark advance for best torque anddecreased power due to a reduction in volumetric lower

    heating value. Furthermore, their experiment got an

    unusual result which is rarely found in others research-

    esdengines thermal efficiency drops as hydrogen frac-

    tion increases.

    Marie Bysveen studied the engines emission and

    performance with different mixtures including: pure CNG,

    and 29% H2 by volume in CNG. For each mixture, four engine

    speeds were investigated and the engines performance was

    tested under full-load conditions. The lean limit for the pure

    CNG tested in the engine is approximately l 1.8 and the

    lean limit for the HCNG is even leaner. The efficiency for

    HCNG is greater than that of CNG for the same l, and thedifference in break thermal efficiency between HCNG and

    CNG for the same l increases with increasing excess air

    ratio [10].

    However, very few studies involved various operating

    conditions including different spark timing, excess air

    ratio (l) with CNG to high hydrogen ratio HCNG fuel under

    WOT operating conditions in a turbocharged spark-igni-

    tion natural gas engine. Considering that the WOT

    performance is very important to actual road conditions,

    the purpose of this research is to study the engines

    combu sti on a nd e mi ss io n p erf or man ce at W OT

    conditions.

    3. Experimental apparatus and test method

    The experiments were carried out on a six-cylinder, single

    point injection, SI NG engine (see Table 2 for

    specifications).

    Fig. 1 e Schematic of the fuel supply system.

    Table 4 e Test engine specifications.

    Item Value

    Engine Speed 1200 rpm

    Hydrogen fraction by volume 0%, 30%, 55%

    Intake manifold absolute pressure Wide Open Throttle

    Spark timing

    Excess air ratio

    MBT

    1.0 to lean burn limit

    0.0 0.2 0.4 0.6 0.8 1.0

    1.4

    1.6

    1.8

    2.0

    2.2

    2.4

    2.6

    2.8

    3.0

    3.23

    Jk/eulavgnitaehrewoLerutniM

    m(

    3)

    1-

    Enriched hydrogen ration /vol%

    =1

    =1.2

    =1.4

    =1.5

    =1.6

    =1.8

    =2.0

    =2.2

    10

    Fig. 2 e Mixture lower heating value at various hydrogen

    enrichments.

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    4.2. In-cylinder pressure data and combustion

    parameters

    Fig. 5 shows in-cylinder pressure curve under various l with

    different fuel: pure CNG, 30%HCNG, 55%HCNG. From Fig. 6(a)

    we can see, as the mixture is leaner, the max in-cylinder

    pressure is smaller. Fig. 6(bed) shows further the position of

    the max in-cylinder pressure is later before the l 1.5. On the

    other hand, when l> 1.5,the max in-cylinder pressure is more

    near the TDC.

    Fig. 6 illustrate heat release rate under various l withdifferent fuels. We can safely make a conclusion from the

    figure: as l raise, the max heat release rate decreases gradu-

    ally. While under the same l, hydrogen-enriched improves the

    max heat release rate since more hydrogen-enriched can

    expand the lean burn limit and improve the combustion

    performance.

    In this paper, we define the early flame development period

    as the crank angles (CA) from ignition to 10% cumulative heat

    release, and flame propagation duration as crank angles (CA)

    from 10% to 90% cumulative heat release. Fig. 7(a) implies the

    early flame development period relation with l. As the mixture

    becomes leaner, the early flame development period is longer,

    which means lean mixture goes against with the flame cores

    formation and rapid development [16]. Besides, hydrogen

    enrichment shortens the early flame development period since

    the combustion speed is faster and in-cylinder temperature

    increases, which is good for the flame propagation.

    Fig. 7(b) shows the relation between the flame propagation

    duration and l. Its variation tendency is similar to the early

    flame development period. The increment of l leads the

    flame development period longer. In addition, hydrogen

    enrichment shortens the flame development period. Quad-

    ers research implies that the engines flame development

    period is almost the same on the lean burn limit conditionswith different fuels [17]. From this, at the same l, the fuel of

    shortest flame development period is best at lean burn.

    Hydrogen enrichment can expand the mixture fuels lean

    burn limit and enable the engine work at bigger l, which is

    good for improving the engine efficiency and emission

    performance.

    Fig.8 shows the variation of COVimep versus excess air ratio

    with three different fuels. It is found that a high hydrogen

    ratio can significantly extend the lean burn limit. Quaders

    research has shown that no matter what type of fuel used, the

    combustion duration remains nearly the same when the

    engine reaches its lean limit. This is to say although

    combustion duration will be prolonged as the engine is

    a

    b

    c

    d

    Fig. 5 e (a) Max cylinder pressure versus excess air ratio. (b) In-cylinder pressure for CNG. (c) In-cylinder pressure for 30%

    hydrogen volumetric ratio. (d) In-cylinder pressure for 55% hydrogen volumetric ratio.

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    decreases at first and then increase as l increases. This

    appearance is suitable for fuel of any hydrogen enrichment.

    The decrease of CO emission is due to the increase of oxygen

    content in the mixture which is beneficial for the reduction of

    CO. The increase of CO is also because of the unstable

    combustion which includes some incomplete oxidation that

    produces CO. It is also obvious that the minimum value of CO

    emission occurs at a larger l as more hydrogen is enriched.This is because hydrogen enrichment expands the lean burn

    limit.

    5. Conclusion

    The study presented is an experimental study aimed at

    investigating the effect of various hydrogen ratios of HCNG

    fuel on performance and emission characteristics under WOT

    operating conditions using a turbocharged spark ignited

    natural gas engine. The experimental data was taken for

    hydrogen fractions of 0%, 30% and 55% by volume and wasconducted under various operating conditions including

    different spark timings and excess air ratios (l).

    The following main conclusions were drawn from this

    study:

    1. Using the same fuel mixture, as l increases the engines

    torque, power, MAP and exhaust temperature gradually

    decrease. While using the same excess air ratio, as more

    hydrogen is added, the mixtures lower heating value

    decreases, resulting in a decrease in power output and

    a reduction in exhaust temperature, the turbo become less

    efficient, the MAP appears to similarly decrease. Further-

    more, due to hydrogens rapid combustion velocity theangle of maximum power becomes more advanced.

    2. The maximum in-cylinder pressure decreases as l

    increases. When hydrogen is added without holding the

    mixtures lower heating value constant, the position of max

    in-cylinder pressure occurs later as l is increased; however

    when the mixtures lower heating value is held constant,

    the position moves closer to TDC.

    3. Using various fuel mixtures, the maximum heat release

    rate reduces as l increases. Hydrogen enrichment can also

    enhance the maximum heat release rate.

    4. Using the same fuel mixture, as l increases both the early

    flame development period and flame propagation duration

    are extended. While holding l constant, increased

    a

    b

    Fig. 7 e (a) Spark to 10% MFB burn duration versus excess

    air ratio. (b) 10%e90% MFB burn duration versus excess air

    ratio.

    Fig. 8e

    COVimep versus excess air ratio.

    Fig. 9 e Indicated thermal efficiency versus excess air ratio.

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