Pep Set Al5995 Catalyst

8/9/2019 Pep Set Al5995 Catalyst

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Revision Date: 23.03.2011

SAFETY DATA SHEET Print Date: 02.04.2012

PEP SETAL5995CATALYST

Trademark, ASK Chemicals, registered in

various countries

362028

MSDS Number: R0550104

Version: 1.0

Conforms to EU Regulation 1907/2006/EC as amended. - GENVAR_GB

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

ASK Chemicals GmbH

Reisholzstrae 16-18D-40721 Hilden

Germany

[email protected]

Emergency telephone number

+1-800-274-5263/+1-606-329-5701 , or contact yourlocal emergency telephone number at 112

Product Information

+49 (0)211 711-030, or contact your local CSR contact

person

Product name PEP SETAL5995 CATALYST

Trademark, ASK Chemicals, registered in various countries

Product code 362028

Product Use Description Foundry - Catalyst.

2. HAZARDS IDENTIFICATION

Hazard Summary

Toxic

Corrosive

Harmful

Dangerous for the environment

Risks Flammable.

May impair fertility., May cause harm to the unborn child.

Toxic: danger of serious damage to health by prolonged exposure if

swallowed., Toxic by inhalation and in contact with skin.

Causes burns.

Harmful if swallowed.

Possible risk of irreversible effects.

Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.


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3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Components CAS-No. EINECS-No. Concentration Symbol(s) R-phrase(s)

Cyclohexyldimethylamin

e

98-94-2 202-715-5 >=80 - =10 -


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Hazardous combustion products

carbon dioxide and carbon monoxide, stannic oxide fumes, toxic fumes, Hydrocarbons

Thermal decomposition

no data available

Precautions for fire-fighting

Do not allow run-off from fire fighting to enter drains or water courses. Keep containers and

surroundings cool with water spray. Prevent fire extinguishing water from contaminating surface water or

the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of inaccordance with local regulations. For safety reasons in case of fire, cans should be stored separately in

closed containments.

Personal protective equipment

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Persons not wearing protective equipment should be excluded from area of spill until clean-up has

been completed. Ensure adequate ventilation. Pay attention to the spreading of gases especially at ground

level (heavier than air) and to the direction of the wind. Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth,

diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations

(see section 13). Keep in suitable, closed containers for disposal.

Other information

Comply with all applicable federal, state, and local regulations.

7. HANDLING AND STORAGE

Handling

Do not breathe vapours or spray mist. Avoid exposure - obtain special instructions before use. Avoid

contact with skin and eyes. For personal protection see section 8. Provide sufficient air exchange and/or

exhaust in work rooms. Avoid exceeding of the given occupational exposure limits (see section 8). Smoking,eating and drinking should be prohibited in the application area. Ensure all equipment is electrically

grounded before beginning transfer operations.Take measures to prevent the build up of electrostatic


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charge. Mixture may charge electrostatically: always use earthing leads when transferring from one

container to another. Keep product and empty container away from heat and sources of ignition. No sparking

tools should be used. Avoid formation of aerosol.

Storage

Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.

Containers which are opened must be carefully resealed and kept upright to prevent leakage. Stable under

recommended storage conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Dibutyltin dilaurate (CAS 77-58-7 )EH40 WEL time weighted average 0.1 mg/m3

EH40 WEL Short term exposure limit 0.2 mg/m3

General advice

These recommendations provide general guidance for handling this product. Personal protective

equipment should be selected for individual applications and should consider factors which affect exposure

potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the

responsibility of the employer to follow regulatory guidelines established by local authorities.Keep away

from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash

stations and safety showers are close to the workstation location. Wash hands and face before breaks and

immediately after handling the product.

Exposure controlsProvide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below

level of overexposure (from known, suspected or apparent adverse effects).

Eye protection

Tightly fitting safety goggles

Skin and body protection

Wear as appropriate:

Safety shoes

impervious clothing

Flame-resistant clothing

Discard contaminated shoes.

Wear resistant gloves such as:butyl-rubber

Nitrile rubber


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Respiratory protectionWhen workers are facing concentrations above the exposure limit they must use appropriate certified

respirators.

In the case of vapour formation use a respirator with an approved filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid

Form no data available

Colour yellow

Odour amine-like

Boiling point/boiling range (>)158.00 C

Melting point/range no data available

Sublimation point no data available

pH no data available

Flash point 51.00 C, Pensky Martens closed cup

Ignition temperature no data availableEvaporation rate (


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Stability

Stable under recommended storage conditions.

Conditions to avoid

Exposure to light. Heat, flames and sparks.

Incompatible products

Reducing agents, strong bases, Strong oxidizing agents, UV light.

Hazardous decomposition productscarbon dioxide and carbon monoxide, stannic oxide fumes, Hydrocarbons

Hazardous reactions

Hazardous polymerisation does not occur. Vapours may form explosive mixture with air.

11. TOXICOLOGICAL INFORMATION

Exposure routes

Skin contact, Eye Contact, Ingestion, Skin Absorption

Eye contact

May cause irreversible eye damage.

Skin contact

Causes skin burns.

Ingestion

Harmful if swallowed.

InhalationToxic by inhalation.

Aggravated Medical Condition

Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to

this material: Skin, lung (for example, asthma-like conditions), Liver

Symptoms

Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of

the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation

(nose, throat, airways), Cough, Lung irritation, Headache, Shortness of breath

Target Organs


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Overexposure to this material (or its components) has been suggested as a cause of the following

effects in laboratory animals:

Acute oral toxicity

Cyclohexyldimethylamine(98-94-2 ) : no data available

Dibutyltin dilaurate(77-58-7 ) : LD 50 Rat: 175 mg/kg

Acute inhalation toxicity


Dibutyltin dilaurate(77-58-7 ) : LC 50 Mouse: 150 mg/m3, 2 h

Acute dermal toxicity


Dibutyltin dilaurate(77-58-7 ) : LD 50 Rabbit: > 2 g/kg

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability)

BiodegradabilityCyclohexyldimethylamine(98-94-2 ) : no data available

Dibutyltin dilaurate(77-58-7 ) : 23 % Exposure time: 39 d Not readily biodegradable.

Physico-chemical removabilityCyclohexyldimethylamine(98-94-2 ) : no data available

Dibutyltin dilaurate(77-58-7 ) : no data available

Bioaccumulation : The bioaccumulation potential cannot be determined.

Ecotoxicity effects

Toxicity to fish


Dibutyltin dilaurate(77-58-7 ) : 48 h LC 50 Leuciscus idus (Golden orfe): 2.000 mg/l

Mortality

96 h LC 50 Danio rerio (zebra fish): 2.000 mg/l

Toxicity to daphnia and other aquatic invertebrates.


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Dibutyltin dilaurate(77-58-7 ) : 24 h EC 50 Water flea (Daphnia magna): 0.660 mg/l ;

Intoxication

Toxicity to algaeCyclohexyldimethylamine (98-94-2 ) : no data available

Dibutyltin dilaurate (77-58-7 ) : no data available

Toxicity to bacteriaCyclohexyldimethylamine(98-94-2 ) : no data available

Dibutyltin dilaurate(77-58-7 ) : no data available

13. DISPOSAL CONSIDERATIONS

Waste disposal methods

Dispose of in accordance with the European Directives on waste and hazardous waste. Do notcontaminate ponds, waterways or ditches with chemical or used container. Container hazardous when

empty. Dispose of in accordance with local regulations.

Empty packaging

Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an

approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use

a cutting torch on, the empty drum.

European Waste Catalogue

The Waste code should be assigned in discussion between the user and the waste disposal

company.

14. TRANSPORT INFORMATION

REGULATION

ID

NUMBER

PROPER SHIPPING

NAME

*HAZARD

CLASS

SUBSIDIARY

HAZARDS

PACKING

GROUP

MARINE

POLLUTANT /

LTD. QTY.

ADR


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UN 1992 FLAMMABLE LIQUID,

TOXIC, N.O.S.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III

ADNR


TOXIC, N.O.S.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III

RID


TOXIC, N.O.S.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III

INTERNATIONAL MARITIME DANGEROUS GOODS

UN 1992 FLAMMABLE LIQUID,TOXIC, N.O.S.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III MARINEPOLLUTANT:(DI

BUTYLTIN

DILAURATE)

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

UN 1992 Flammable liquid, toxic,

n.o.s.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER

UN 1992 Flammable liquid, toxic,

n.o.s.

(DIMETHYLCYCLOHEXY

LAMINE, DIBUTYLTIN

DILAURATE)

3 (6.1) III

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific

exceptions that can be applied. Consult shipping documents for descriptions that are specific to the

shipment.


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15. REGULATORY INFORMATION

Hazard symbols

Toxic Dangerous for the environment

R-phrase(s)R60 May impair fertility.

R61 May cause harm to the unborn child.

R22 Also harmful if swallowed.

R23/24 Also toxic by inhalation and in contact with skin.

R48/25 Also toxic: danger of serious damage to health by prolonged exposure if swallowed.

R10 Flammable.

R34 Causes burns.

R68 Possible risk of irreversible effects.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

S-phrase(s)

S53 Avoid exposure - obtain special instructions before use.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical

advice.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S38 In case of insufficient ventilation, wear suitable respiratory equipment.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the

label where possible).

S51 Use only in well-ventilated areas.

Special labelling of certain mixtures1999/45/EC Restricted to professional users.

Contains

Cyclohexyldimethylamine 98-94-2

Dibutyltin dilaurate 77-58-7

Notification status

US. Toxic Substances Control Act y (positive listing)

Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing)Canada. Canadian Environmental Protection Act (CEPA).

Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)

y (positive listing)

Japan. Kashin-Hou Law List y (positive listing)


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Korea. Toxic Chemical Control Law (TCCL) List y (positive listing)

Philippines. The Toxic Substances and Hazardous and Nuclear

Waste Control Act


China. Inventory of Existing Chemical Substances y (positive listing)

New Zealand. Inventory of Chemicals (NZIoC), as published by

ERMA New Zealand


16. OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3

R22 Harmful if swallowed.

R34 Causes burns.

R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.

R23/24 Toxic by inhalation and in contact with skin.

R60 May impair fertility.

R61 May cause harm to the unborn child.

R68 Possible risk of irreversible effects.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

R10 Flammable.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

R36/38 Irritating to eyes and skin.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

The information accumulated herein is believed to be accurate but is not warranted to be whether originating

with the company or not. Recipients are advised to confirm in advance of need that the information is

current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's

Environmental Health and Safety Department (+31 10 497 5000).

Pep Set Al5995 Catalyst

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