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One Stanton Street

Marinette, WI 54143-2542

Tele: 715-735-7411

DOCUMENT CONTROL NO.: 20160715 US10.11014 1

July 15, 2016

Mr. Michael J. Mikulka Senior Environmental Engineer Land & Chemicals Division US Environmental Protection Agency 77 West Jackson Blvd Chicago, IL 60604-3590 Subject: Quarterly Progress Report (April through June 2016) Administrative Order on Consent (February 26, 2009) Tyco Fire Products LP Stanton Street Facility Marinette, Wisconsin WID 006 125 215 Dear Mr. Mikulka:

Section VI, 21, b (Page 10) of the Administrative Order on Consent (AOC), dated February 26, 2009, requires Tyco Fire Products LP (Tyco) to submit quarterly progress reports to the U.S. Environmental Protection Agency (USEPA) Region 5 and the Wisconsin Department of Natural Resources (WDNR). The reports are required to document activities conducted as part of the Resource Conservation and Recovery Act (RCRA) Corrective Actions at the Tyco facility in Marinette, Wisconsin. The enclosed report covers the period from April 1, 2016 through June 30, 2016, and presents a brief description of the work completed to date, data collected, problems encountered, and schedule of activities as required by the February 2009 AOC.

Work Completed During this Reporting Period

Operation of the groundwater collection and treatment system (GWCTS) continued through the second quarter of 2016. A summary of the operational data is included as Attachment 1. The Discharge Monitoring Reports (DMRs) are included in Attachment 2.

The barrier wall groundwater monitoring (BWGM) sampling event was completed the week of May 2, 2016. Sample results are included Attachment 3.

Visual inspection of the Vertical Barrier Wall was completed on June 3, 2016 and the report is included in Attachment 4 of this report. Figure 1 shows the locations of the findings identified during this inspection.

Visual inspection of the on-site cover areas referenced in the 2009 AOC was completed on May 19, 2016. The findings are included in Attachment 5 of this report. Figure 2 shows the locations of the findings identified during this inspection.

The survey of the Vertical Barrier Wall was completed in the month of April. Results of this survey are under review and will be included in the 2016 annual BWGM report.

MR. MICHAEL J. MIKULKA JULY 15, 2016

2 DOCUMENT CONTROL NO.: 20160715 US10.11014

The first Phyto Plot Inspection was completed by Sand Creek Consultants on June 8, 2016. A write up of all work performed for the 2016 year will be given in the Phyto Plot End of Year Report submitted in the January 15, 2017 quarterly report.

Additional Activities

The extraction and management of impacted groundwater in the 8th Street slip and former Salt Vault areas of the site as part of the agreed upon pump down program began operations on June 23, 2016. Extraction is expected to continue until the target groundwater elevations in these areas are achieved. Through July 8, 2016, approximately 242,951 gallons had been extracted as part of this project. Tyco has requisitioned the assistance of engineering consultant AECOM to assist with a site assessment to evaluate the advantages and disadvantages of potential changes to surface water flow and the practicality of abandoning and/or sealing storm sewer lines. Tyco and AECOM have been working on this assessment throughout the second quarter. USEPA and WDNR conducted a site visit on June 27 and 28, 2016. The agencies inspected the operation of the pump down program, were provided a tour of the site, and were presented an overview of historical and on-going site activities related to the RCRA project.

Data Collected

Extraction and treatment volumes, analytical testing, and discharge quantity data are required as part of the Wisconsin Pollutant Discharge and Elimination System (WPDES) permits obtained from WDNR for operation of the GWCTS. The GWCTS operates under permit WPDES WI-0001040-07-0. Attachment 2 includes the monthly WPDES DMRs for March 2016 through May 2016 for the GWCTS. Additional data on the operation of the GWCTS is included in Attachment 1.

Groundwater elevation and samples were collected as part of the semi-annual barrier wall groundwater monitoring event. The analytical results are included in Attachment 3. Groundwater elevation data will be provided in the annual report.

In addition, groundwater level data recorded by installed transducers was downloaded on June 30 and July1, 2016 and are being evaluated. The site-wide data will be provided in the annual report. Graphs of transducer data for the wells in the former Salt Vault and 8th Street Slip are included in Attachment 6.

Problems Encountered

There were no new problems to report during this quarter of operation.

Schedule of Upcoming Activities

The following is a summary of activities to be conducted during the next reporting period.

Submit the quarterly progress report.


3

Complete the second inspection of the phyto plots (to be completed by Tyco personnel) to assess tree health (early in the third quarter).

Complete third inspection of the phyto plots (to be completed by arborist) to assess tree heath (late third quarter to early 4th quarter).

Address inspection findings for the Vertical Barrier Wall, Cover Areas, and Monitoring Wells.

Continue operation of pump down program in the former Salt Vault and 8th Street Slip.

Respond to USEPA comments regarding the findings of the Outfall Investigation.

List of Key Correspondence and Document Submittals

Table 1

Documents Submitted

Quarterly Progress Report (April to June 2016), Tyco Fire Products LP Facility, Marinette, Wisconsin

Description of Submittal Submitted To Date Submitted

Response to WDNR Questions Regarding Proposed

Dye Testing

WDNR April 15, 2016

Quarterly Progress Report

USEPA April 15, 2016

Extension Request – Response to Comments to EPA Review of Tyco

Outfall Investigation Report USEPA April 18, 2016

2015 Barrier Wall Groundwater

Monitoring Annual Report

USEPA June 22, 2016

Well Installation, Abandonment and Repair Field Activities, November 2

to December 2, 2015

USEPA June 28, 2016

Tyco Pump Down Program Work

Plan and HSERP USEPA June 10, 2016

High Capacity Well Application

WDNR May 23, 2016

Email Response to EPA Comments on Tyco Contractor Work Plan

USEPA June 16, 2016

Pump Down Program Commencement - Tyco Site - email

USEPA June 8, 2016


5

Attachments

1 GWCTS Operation 2 Monthly Discharge Monitoring Reports 3 Visual Inspection of the Vertical Barrier Wall 4 Visual Inspection of the On-site Cover Areas c: Kristin DuFresne, WDNR Jim Killian, WDNR Joe Janeczek, Tyco International Scott Stacy, Tyco Fire Products LP Larry Wilson, SimplexGrinnell, A Tyco International Company Jeff Danko, CH2M HILL Mariel Carter, Stephenson Public Library

Document Control No.: 662118.237T

DOCUMENT CONTROL NO.: 20160715 US10.11014

Attachment 1

GWCTS Operation Summary

1

M E M O R A N D U M

Groundwater Collection and Treatment System Operation SUBJECT: Groundwater Collection and Treatment System Operation for Tyco

Fire Products LP, Marinette, Wisconsin

DATE: July 14, 2016

Operation of the groundwater collection and treatment system (GWCTS) occurring from April 1, 2016 through June 30, 2016 is summarized below:

The GWCTS operated for 27 days in April, 26 days in May, and 28 days in June, for a total of 81 days. The plant did not operate during the Memorial Day Holiday.

Approximately 244,120 gallons of reject water was produced during system operations and subsequently disposed of offsite.

The precipitation recorded from the weather station in Marinette, Wisconsin was 10.87 inches. (http://www.ncdc.noaa.gov/cdo-web/datasets/GHCND/stations/GHCND:USC00475091/detail).

An estimated total of 1,071,396 gallons was discharged to the Menominee River as effluent under WPDES permit.

An estimated total of 1,532,351 gallons of groundwater were extracted (not including volumes extracted as part of the pump down program) from the site during the reporting period. Details of water volumes extracted from each area of the site and changes in water levels are shown in the Table 1 below.

Table 1 – Extraction Well Data Summary

Extraction Well Gallons Run Q2 2015 (4/01/2015-6/30/2015)

Gallons Run Q22016 (4/01/2014-6/30/2014)

EW-1 213,594 231,831

EW-2 40,475 48,249

EW-3 25,570 0

EW-4 28,795 23,286

EW-5 182,454 68,758

EW-6 513,662 683,732

EW-7 527,801 90,549

Total 1,532,351 1,146,405


Attachment 2

Discharge Monitoring Reports (DMRs) for the GWCTS


Attachment 3

BWGMP Semi-Annual Laboratory Sample Reports

ANALYTICAL REPORT

Job Number: 500-111319-1

Job Description: Barrier Wall Monitoring

For:Tyco Fire Protection Products

1 Stanton StMarinette, WI 54143

Attention: Mr. Ryan Suennen

_____________________________________________

Approved for release.Richard C WrightSenior Project Manager7/11/2016 1:09 PM

Richard C Wright, Senior Project Manager2417 Bond Street, University Park, IL, 60484

[email protected]/11/2016 Revision: 1

All questions regarding this test report should be directed to the TestAmerica Project Manager whose signature appearson this report. All pages of this report are integral parts of the analytical data. Therefore, this report should bereproduced only in its entirety.

Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable.

TestAmerica Laboratories, Inc.

TestAmerica Chicago 2417 Bond Street, University Park, IL 60484

Tel (708) 534-5200 Fax (708) 534-5211 www.testamericainc.com

07/11/2016Page 1 of 729

mailto:[email protected]://www.testamericainc.comhttp://

Table of ContentsCover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Report Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Executive Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Method / Analyst Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Sample Datasheets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

QC Data Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

Data Qualifiers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60

Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Met Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62

Met Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63

Met QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93Met ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93Met CRQL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99Met Blanks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101Met ICSA/ICSAB . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108Met MS/MSD/PDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114Met Dup/Trip . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118Met LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120Met Serial Dilution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122

07/11/2016Page 2 of 729

Table of ContentsMet MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124

Met IECF . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128

Met Linear Ranges . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139

Met Preparation Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141

Met Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143

Met Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150

Met Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 721

Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 725

Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 726

Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 729

07/11/2016Page 3 of 729

Job Narrative500-111319-1

Revised ReportErroneous B Flag for Arsenic on lab sample 20 was removed.

Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.

07/11/2016Page 4 of 729

SAMPLE SUMMARY

Client: Tyco Fire Protection Products Job Number: 500-111319-1

Client Sample IDLab Sample ID Client Matrix Sampled ReceivedDate/Time Date/Time

500-111319-1 MW021S Water 05/01/2016 0831 05/09/2016 1030

500-111319-2 MW021M Water 05/01/2016 0833 05/09/2016 1030

500-111319-3 MW040S Water 05/01/2016 1026 05/09/2016 1030

500-111319-4 MW040M Water 05/01/2016 1025 05/09/2016 1030

500-111319-5 MW040D Water 05/01/2016 1023 05/09/2016 1030

500-111319-6 MW040S/D Water 05/01/2016 1027 05/09/2016 1030

500-111319-7 MW064S Water 05/01/2016 1400 05/09/2016 1030

500-111319-8 MW064M Water 05/01/2016 1359 05/09/2016 1030

500-111319-9 MW064D Water 05/01/2016 1402 05/09/2016 1030

500-111319-10 MW101S Water 05/01/2016 0929 05/09/2016 1030

500-111319-11 MW101M Water 05/01/2016 0915 05/09/2016 1030

500-111319-12 MW102S Water 05/01/2016 1452 05/09/2016 1030

500-111319-13 MW102M Water 05/01/2016 1451 05/09/2016 1030

500-111319-14 MW102D Water 05/01/2016 1453 05/09/2016 1030

500-111319-15 MW102D/D Water 05/01/2016 1454 05/09/2016 1030

500-111319-16 MW105S Water 05/01/2016 1144 05/09/2016 1030

500-111319-17 MW105M Water 05/01/2016 1522 05/09/2016 1030

500-111319-18 MW105D Water 05/01/2016 1518 05/09/2016 1030

500-111319-19 MW041S Water 05/02/2016 1502 05/09/2016 1030

500-111319-19MS MW041S Water 05/02/2016 1502 05/09/2016 1030

500-111319-19MSD MW041S Water 05/02/2016 1502 05/09/2016 1030

500-111319-20 MW041M Water 05/02/2016 1459 05/09/2016 1030

500-111319-21 MW047S Water 05/02/2016 0952 05/09/2016 1030

500-111319-22 MW047M Water 05/02/2016 0956 05/09/2016 1030

500-111319-23 MW047D Water 05/02/2016 1008 05/09/2016 1030

500-111319-24 MW100S Water 05/02/2016 0904 05/09/2016 1030

500-111319-24MS MW100S Water 05/02/2016 0904 05/09/2016 1030

500-111319-24MSD MW100S Water 05/02/2016 0904 05/09/2016 1030

500-111319-25 MW100M Water 05/02/2016 0852 05/09/2016 1030

500-111319-26 MW100D Water 05/02/2016 0850 05/09/2016 1030

500-111319-27 MW103S Water 05/02/2016 1206 05/09/2016 1030

500-111319-28 MW103M Water 05/02/2016 1206 05/09/2016 1030

500-111319-29 MW104S Water 05/02/2016 1416 05/09/2016 1030

500-111319-30 MW104M Water 05/02/2016 1405 05/09/2016 1030

TestAmerica Chicago 07/11/2016Page 5 of 729

EXECUTIVE SUMMARY - Detections


Analyte ResultReporting Limit Units Method

Lab Sample ID Client Sample IDQualifier

500-111319-1 MW021S

Total Recoverable0.0050 mg/L 200.7 Rev 4.40.060Arsenic

500-111319-2 MW021M

Total Recoverable0.0050 mg/L 200.7 Rev 4.40.0048 JArsenic

500-111319-3 MW040S


500-111319-4 MW040M


500-111319-5 MW040D


500-111319-6 MW040S/D


500-111319-7 MW064S


500-111319-8 MW064M


500-111319-9 MW064D







500-111319-10 MW101S


500-111319-11 MW101M


500-111319-12 MW102S


500-111319-13 MW102M


500-111319-14 MW102D


500-111319-15 MW102D/D


500-111319-16 MW105S


500-111319-17 MW105M


500-111319-18 MW105D







500-111319-19 MW041S

Total Recoverable0.025 mg/L 200.7 Rev 4.422Arsenic

500-111319-20 MW041M

Total Recoverable2.5 mg/L 200.7 Rev 4.41400Arsenic

500-111319-21 MW047S


500-111319-22 MW047M


500-111319-23 MW047D


500-111319-24 MW100S


500-111319-25 MW100M


500-111319-26 MW100D


500-111319-27 MW103S







500-111319-28 MW103M


500-111319-29 MW104S


500-111319-30 MW104M



METHOD SUMMARY


Preparation MethodMethodLab LocationDescription

Matrix: Water

Metals (ICP) TAL CHI EPA 200.7 Rev 4.4

Preparation, Total Recoverable Metals TAL CHI EPA 200.7

Lab References:

TAL CHI = TestAmerica Chicago

Method References:

EPA = US Environmental Protection Agency


METHOD / ANALYST SUMMARY


Method Analyst Analyst ID

Jones, Paul PJ1EPA 200.7 Rev 4.4Lacy, Keith M KMLEPA 200.7 Rev 4.4

TestAmerica Chicago

07/11/2016Page 11 of 729

Analytical Data


Client Sample ID:

Lab Sample ID:

MW021S

Client Matrix:

500-111319-1

Water

Date Sampled: 05/01/2016 0831

Date Received: 05/09/2016 1030

200.7 Rev 4.4 Metals (ICP)-Total Recoverable

200.7 Rev 4.4 Instrument ID:

Lab File ID: P8051016AA.asc

Dilution: 1.0 Initial Weight/Volume: 50 mL

05/10/2016 1738 Final Weight/Volume: 25 mL

05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:

Analysis Batch: 500-334919

500-334709Prep Batch:

Analysis Method:

Prep Method:

Analyte Result (mg/L) Qualifier MDL RL

0.060 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW021M

Client Matrix:

500-111319-2

Water

Date Sampled: 05/01/2016 0833







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0048 J 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW040S

Client Matrix:

500-111319-3

Water

Date Sampled: 05/01/2016 1026







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.046 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW040M

Client Matrix:

500-111319-4

Water

Date Sampled: 05/01/2016 1025







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.25 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW040D

Client Matrix:

500-111319-5

Water

Date Sampled: 05/01/2016 1023







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.023 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW040S/D

Client Matrix:

500-111319-6

Water

Date Sampled: 05/01/2016 1027







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.047 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW064S

Client Matrix:

500-111319-7

Water

Date Sampled: 05/01/2016 1400







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.42 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW064M

Client Matrix:

500-111319-8

Water

Date Sampled: 05/01/2016 1359







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


6.3 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW064D

Client Matrix:

500-111319-9

Water

Date Sampled: 05/01/2016 1402







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.53 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW101S

Client Matrix:

500-111319-10

Water

Date Sampled: 05/01/2016 0929







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.22 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW101M

Client Matrix:

500-111319-11

Water

Date Sampled: 05/01/2016 0915







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0032 J 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW102S

Client Matrix:

500-111319-12

Water

Date Sampled: 05/01/2016 1452







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.075 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW102M

Client Matrix:

500-111319-13

Water

Date Sampled: 05/01/2016 1451







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0097 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW102D

Client Matrix:

500-111319-14

Water

Date Sampled: 05/01/2016 1453







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.19 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW102D/D

Client Matrix:

500-111319-15

Water

Date Sampled: 05/01/2016 1454







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.19 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW105S

Client Matrix:

500-111319-16

Water

Date Sampled: 05/01/2016 1144







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.29 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW105M

Client Matrix:

500-111319-17

Water

Date Sampled: 05/01/2016 1522







05/10/2016 0840

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0047 J 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW105D

Client Matrix:

500-111319-18

Water

Date Sampled: 05/01/2016 1518




Lab File ID: P8051216B.asc



05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0092 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW041S

Client Matrix:

500-111319-19

Water

Date Sampled: 05/02/2016 1502







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


22 0.0250.012Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW041M

Client Matrix:

500-111319-20

Water

Date Sampled: 05/02/2016 1459





Dilution: 500 Initial Weight/Volume: 50 mL


05/10/2016 0842

200.7

ICP6

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


1400 2.51.2Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW047S

Client Matrix:

500-111319-21

Water

Date Sampled: 05/02/2016 0952







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.097 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW047M

Client Matrix:

500-111319-22

Water

Date Sampled: 05/02/2016 0956







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


1.3 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW047D

Client Matrix:

500-111319-23

Water

Date Sampled: 05/02/2016 1008







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.26 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW100S

Client Matrix:

500-111319-24

Water

Date Sampled: 05/02/2016 0904







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.076 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW100M

Client Matrix:

500-111319-25

Water

Date Sampled: 05/02/2016 0852







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0043 J 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW100D

Client Matrix:

500-111319-26

Water

Date Sampled: 05/02/2016 0850







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.22 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW103S

Client Matrix:

500-111319-27

Water

Date Sampled: 05/02/2016 1206







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.048 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW103M

Client Matrix:

500-111319-28

Water

Date Sampled: 05/02/2016 1206







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.016 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW104S

Client Matrix:

500-111319-29

Water

Date Sampled: 05/02/2016 1416







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0063 0.00500.0025Arsenic


Analytical Data


Client Sample ID:

Lab Sample ID:

MW104M

Client Matrix:

500-111319-30

Water

Date Sampled: 05/02/2016 1405







05/10/2016 0842

200.7

ICP8

Analysis Date:

Prep Date:



Analysis Method:

Prep Method:


0.0050 0.00500.0025Arsenic


Quality Control Results

Job Number: 500-111319-1Client: Tyco Fire Protection Products

WaterClient Matrix:

1.0Dilution:

Lab Sample ID:

Method Blank - Batch: 500-334709

Instrument ID:

Lab File ID:

Initial Weight/Volume:

Final Weight/Volume:

P8051016AA.asc

50 mL

25 mLUnits: mg/L

Method: 200.7 Rev 4.4Preparation: 200.7Total Recoverable

ICP8MB 500-334709/1-A

Analysis Date: 05/10/2016 1609

Analysis Batch:

Prep Batch:

Leach Batch: N/A

500-334919

500-334709

Prep Date:

Leach Date:

05/10/2016 0840

N/A

Analyte RLMDLQualResult



WaterClient Matrix:

1.0Dilution:

Lab Sample ID:

Method Blank - Batch: 500-334710

Instrument ID:

Lab File ID:



P8051216B.asc

50 mL

25 mLUnits: mg/L


ICP8MB 500-334710/1-A


Analysis Batch:

Prep Batch:

Leach Batch: N/A

500-335323

500-334710

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analyte RLMDLQualResult



Dilution:

Dilution:

Water

5.0

5.0

Client Matrix:

Instrument ID:

Lab File ID:



Instrument ID:

Lab File ID:



Client Matrix: Water

P8051216B.asc

50 mL

25 mL

P8051216B.asc

50 mL

25 mL


ICP8

ICP8

500-111319-19

500-111319-19

MS Lab Sample ID:

MSD Lab Sample ID:

Matrix Spike/Matrix Spike Duplicate Recovery Report - Batch: 500-334710

05/12/2016 2033

N/A

Analysis Date:

Prep Date:

Leach Date:

Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Analysis Date:

Prep Date:

Leach Date:

05/12/2016 2038

05/10/2016 0842

N/A

Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

05/10/2016 0842

Analyte RPD LimitRPDLimit

% Rec.

MS MSD MS Qual MSD Qual

-2876 -2653 70 - 130 1 20 4 4Arsenic

Dilution:

Dilution:

Water

1.0

1.0

Client Matrix:

Instrument ID:

Lab File ID:



Instrument ID:

Lab File ID:



Client Matrix: Water

P8051216B.asc

50 mL

25 mL

P8051216B.asc

50 mL

25 mL


ICP8

ICP8

500-111319-24

500-111319-24

MS Lab Sample ID:

MSD Lab Sample ID:


05/12/2016 2125

N/A

Analysis Date:

Prep Date:

Leach Date:

Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Analysis Date:

Prep Date:

Leach Date:

05/12/2016 2129

05/10/2016 0842

N/A

Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

05/10/2016 0842

Analyte RPD LimitRPDLimit

% Rec.

MS MSD MS Qual MSD Qual

119 106 70 - 130 5 20Arsenic




Water

05/12/2016 2033 05/12/2016 2038

Dilution: Dilution:5.0 5.0

Client Matrix: Client Matrix: Water


Units: mg/L500-111319-19 500-111319-19MS Lab Sample ID: MSD Lab Sample ID:


Analysis Date:

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analysis Date:

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Amount

Sample

Analyte Result/Qual Amount Result/Qual Result/Qual

MS MSDMS Spike MSD Spike

22 0.0500 0.0500 20.8 20.94 4Arsenic

Water

05/12/2016 2125 05/12/2016 2129

Dilution: Dilution:1.0 1.0

Client Matrix: Client Matrix: Water


Units: mg/L500-111319-24 500-111319-24MS Lab Sample ID: MSD Lab Sample ID:


Analysis Date:

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analysis Date:

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Amount

Sample

Analyte Result/Qual Amount Result/Qual Result/Qual

MS MSDMS Spike MSD Spike

0.076 0.0500 0.0500 0.136 0.129Arsenic




mg/LUnits:

Water

Dilution: 25

Serial Dilution - Batch: 500-334710

Lab Sample ID:

Client Matrix:

Instrument ID:

Lab File ID:



P8051216B.asc

50 mL

25 mL


ICP8500-111319-19


Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analyte Sample Result/Qual Result Limit Qual%Diff

Arsenic 22 20.8 6.7 10

mg/LUnits:

Water

Dilution: 5.0

Duplicate - Batch: 500-334710

Lab Sample ID:

Client Matrix:

Instrument ID:

Lab File ID:



P8051216B.asc

50 mL

25 mL


ICP8500-111319-19


Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analyte QualLimitRPDResultSample Result/Qual

22.622 1 20Arsenic

mg/LUnits:

Water

Dilution: 5.0

Serial Dilution - Batch: 500-334710

Lab Sample ID:

Client Matrix:

Instrument ID:

Lab File ID:



P8051216B.asc

50 mL

25 mL


ICP8500-111319-24


Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analyte Sample Result/Qual Result Limit Qual%Diff

Arsenic 0.076 0.0764 NC 10




mg/LUnits:

Water

Dilution: 1.0

Duplicate - Batch: 500-334710

Lab Sample ID:

Client Matrix:

Instrument ID:

Lab File ID:



P8051216B.asc

50 mL

25 mL


ICP8500-111319-24


Analysis Batch:

Prep Batch:

Leach Batch:

500-335323

500-334710

N/A

Prep Date:

Leach Date:

05/10/2016 0842

N/A

Analyte QualLimitRPDResultSample Result/Qual

0.07480.076 2 20Arsenic


DATA REPORTING QUALIFIERS


Lab Section Qualifier Description

Metals

MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

4

Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

J




QC Association Summary

Lab Sample ID Client Sample ID Client Matrix Method Prep Batch

ReportBasis

Metals

Prep Batch: 500-334709Lab Control Sample Water 200.7LCS 500-334709/2-A RMethod Blank Water 200.7MB 500-334709/1-A R

WaterMW021S 200.7500-111319-1 RWaterMW021M 200.7500-111319-2 RWaterMW040S 200.7500-111319-3 RWaterMW040M 200.7500-111319-4 RWaterMW040D 200.7500-111319-5 RWaterMW040S/D 200.7500-111319-6 RWaterMW064S 200.7500-111319-7 RWaterMW064M 200.7500-111319-8 RWaterMW064D 200.7500-111319-9 RWaterMW101S 200.7500-111319-10 RWaterMW101M 200.7500-111319-11 RWaterMW102S 200.7500-111319-12 RWaterMW102M 200.7500-111319-13 RWaterMW102D 200.7500-111319-14 RWaterMW102D/D 200.7500-111319-15 RWaterMW105S 200.7500-111319-16 RWaterMW105M 200.7500-111319-17 R

Prep Batch: 500-334710Lab Control Sample Water 200.7LCS 500-334710/2-A RMethod Blank Water 200.7MB 500-334710/1-A R

WaterMW105D 200.7500-111319-18 RWaterMW041S 200.7500-111319-19 R

Duplicate Water 200.7500-111319-19DU RMatrix Spike Water 200.7500-111319-19MS RMatrix Spike Duplicate Water 200.7500-111319-19MSD R

WaterMW041M 200.7500-111319-20 RWaterMW047S 200.7500-111319-21 RWaterMW047M 200.7500-111319-22 RWaterMW047D 200.7500-111319-23 RWaterMW100S 200.7500-111319-24 R

Duplicate Water 200.7500-111319-24DU RMatrix Spike Water 200.7500-111319-24MS RMatrix Spike Duplicate Water 200.7500-111319-24MSD R

WaterMW100M 200.7500-111319-25 RWaterMW100D 200.7500-111319-26 RWaterMW103S 200.7500-111319-27 RWaterMW103M 200.7500-111319-28 RWaterMW104S 200.7500-111319-29 RWaterMW104M 200.7500-111319-30 R

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ReportBasis

Metals

Analysis Batch:500-334919Lab Control Sample Water 500-334709200.7 Rev 4.4LCS 500-334709/2-A RMethod Blank Water 500-334709200.7 Rev 4.4MB 500-334709/1-A R

Water 500-334709MW021S 200.7 Rev 4.4500-111319-1 RWater 500-334709MW021M 200.7 Rev 4.4500-111319-2 RWater 500-334709MW040S 200.7 Rev 4.4500-111319-3 RWater 500-334709MW040M 200.7 Rev 4.4500-111319-4 RWater 500-334709MW040D 200.7 Rev 4.4500-111319-5 RWater 500-334709MW040S/D 200.7 Rev 4.4500-111319-6 RWater 500-334709MW064S 200.7 Rev 4.4500-111319-7 RWater 500-334709MW064M 200.7 Rev 4.4500-111319-8 RWater 500-334709MW064D 200.7 Rev 4.4500-111319-9 RWater 500-334709MW101S 200.7 Rev 4.4500-111319-10 RWater 500-334709MW101M 200.7 Rev 4.4500-111319-11 RWater 500-334709MW102S 200.7 Rev 4.4500-111319-12 RWater 500-334709MW102M 200.7 Rev 4.4500-111319-13 RWater 500-334709MW102D 200.7 Rev 4.4500-111319-14 RWater 500-334709MW102D/D 200.7 Rev 4.4500-111319-15 RWater 500-334709MW105S 200.7 Rev 4.4500-111319-16 RWater 500-334709MW105M 200.7 Rev 4.4500-111319-17 R

Analysis Batch:500-335323Lab Control Sample Water 500-334710200.7 Rev 4.4LCS 500-334710/2-A RMethod Blank Water 500-334710200.7 Rev 4.4MB 500-334710/1-A R

Water 500-334710MW105D 200.7 Rev 4.4500-111319-18 RWater 500-334710MW041S 200.7 Rev 4.4500-111319-19 R

Duplicate Water 500-334710200.7 Rev 4.4500-111319-19DU RMatrix Spike Water 500-334710200.7 Rev 4.4500-111319-19MS RMatrix Spike Duplicate Water 500-334710200.7 Rev 4.4500-111319-19MSD R

Water 500-334710MW041M 200.7 Rev 4.4500-111319-20 RWater 500-334710MW047S 200.7 Rev 4.4500-111319-21 RWater 500-334710MW047M 200.7 Rev 4.4500-111319-22 RWater 500-334710MW047D 200.7 Rev 4.4500-111319-23 RWater 500-334710MW100S 200.7 Rev 4.4500-111319-24 R

Duplicate Water 500-334710200.7 Rev 4.4500-111319-24DU RMatrix Spike Water 500-334710200.7 Rev 4.4500-111319-24MS RMatrix Spike Duplicate Water 500-334710200.7 Rev 4.4500-111319-24MSD R

Water 500-334710MW100M 200.7 Rev 4.4500-111319-25 RWater 500-334710MW100D 200.7 Rev 4.4500-111319-26 RWater 500-334710MW103S 200.7 Rev 4.4500-111319-27 RWater 500-334710MW103M 200.7 Rev 4.4500-111319-28 RWater 500-334710MW104S 200.7 Rev 4.4500-111319-29 RWater 500-334710MW104M 200.7 Rev 4.4500-111319-30 R

Analysis Batch:500-335477Water 500-334710MW041M 200.7 Rev 4.4500-111319-20 R

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ReportBasis

Report Basis

R = Total Recoverable

TestAmerica Chicago

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Laboratory Chronicle

05/09/2016 10:30

Lab ID:

Method Bottle ID Run

Analysis Batch Prep Batch

Date Prepared / Analyzed Dil Lab Analyst

Client ID:

Sample Date/Time: Received Date/Time:05/01/2016 08:31

500-111319-1 MW021S

P:200.7 500-111319-A-1-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-1-A 500-334919 500-334709 05/10/2016 17:38 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-2 MW021M

P:200.7 500-111319-A-2-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-2-A 500-334919 500-334709 05/10/2016 17:42 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-3 MW040S

P:200.7 500-111319-A-3-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-3-A 500-334919 500-334709 05/10/2016 17:47 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-4 MW040M

P:200.7 500-111319-A-4-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-4-A 500-334919 500-334709 05/10/2016 17:51 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-5 MW040D

P:200.7 500-111319-A-5-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-5-A 500-334919 500-334709 05/10/2016 17:56 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-6 MW040S/D

P:200.7 500-111319-A-6-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-6-A 500-334919 500-334709 05/10/2016 18:02 PJ1TAL CHI1

A = Analytical Method P = Prep Method TestAmerica Chicago

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05/09/2016 10:30

Lab ID:




Client ID:


500-111319-7 MW064S

P:200.7 500-111319-A-7-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-7-A 500-334919 500-334709 05/10/2016 18:15 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-8 MW064M

P:200.7 500-111319-A-8-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-8-A 500-334919 500-334709 05/10/2016 18:19 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-9 MW064D

P:200.7 500-111319-A-9-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-9-A 500-334919 500-334709 05/10/2016 18:24 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-10 MW101S

P:200.7 500-111319-A-10-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-10-A 500-334919 500-334709 05/10/2016 18:30 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-11 MW101M

P:200.7 500-111319-A-11-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-11-A 500-334919 500-334709 05/10/2016 18:35 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-12 MW102S

P:200.7 500-111319-A-12-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-12-A 500-334919 500-334709 05/10/2016 18:39 PJ1TAL CHI1


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05/09/2016 10:30

Lab ID:




Client ID:


500-111319-13 MW102M

P:200.7 500-111319-A-13-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-13-A 500-334919 500-334709 05/10/2016 18:43 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-14 MW102D

P:200.7 500-111319-A-14-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-14-A 500-334919 500-334709 05/10/2016 18:47 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-15 MW102D/D

P:200.7 500-111319-A-15-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-15-A 500-334919 500-334709 05/10/2016 18:52 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-16 MW105S

P:200.7 500-111319-A-16-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-16-A 500-334919 500-334709 05/10/2016 18:56 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-17 MW105M

P:200.7 500-111319-A-17-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-17-A 500-334919 500-334709 05/10/2016 19:10 PJ1TAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-18 MW105D

P:200.7 500-111319-A-18-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-18-A 500-335323 500-334710 05/12/2016 20:13 KMLTAL CHI1


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05/09/2016 10:30

Lab ID:




Client ID:


500-111319-19 MW041S

P:200.7 500-111319-A-19-A ^5

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI5

A:200.7 Rev 4.4 500-111319-A-19-A ^5

500-335323 500-334710 05/12/2016 20:18 KMLTAL CHI5

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-19 MW041S

P:200.7 500-111319-A-19-C MS ^5

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI5

A:200.7 Rev 4.4 500-111319-A-19-C MS ^5

500-335323 500-334710 05/12/2016 20:33 KMLTAL CHI5

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-19 MW041S

P:200.7 500-111319-A-19-D MSD ^5

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI5

A:200.7 Rev 4.4 500-111319-A-19-D MSD ^5

500-335323 500-334710 05/12/2016 20:38 KMLTAL CHI5

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-19 DU MW041S

P:200.7 500-111319-A-19-B DU ^5

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI5

A:200.7 Rev 4.4 500-111319-A-19-B DU ^5

500-335323 500-334710 05/12/2016 20:28 KMLTAL CHI5

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-19 SD MW041S

P:200.7 500-111319-A-19-A SD ^25

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI25

A:200.7 Rev 4.4 500-111319-A-19-A SD ^25

500-335323 500-334710 05/12/2016 20:23 KMLTAL CHI25


07/11/2016Page 55 of 729




05/09/2016 10:30

Lab ID:




Client ID:


500-111319-20 MW041M

P:200.7 500-111319-A-20-A ^500

500-335477 500-334710 05/10/2016 08:42 JEFTAL CHI500

A:200.7 Rev 4.4 500-111319-A-20-A ^500

500-335477 500-334710 05/13/2016 23:17 KMLTAL CHI500

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-21 MW047S

P:200.7 500-111319-A-21-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-22 MW047M

P:200.7 500-111319-A-22-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-23 MW047D

P:200.7 500-111319-A-23-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-24 MW100S

P:200.7 500-111319-A-24-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1



07/11/2016Page 56 of 729




05/09/2016 10:30

Lab ID:




Client ID:


500-111319-24 MW100S

P:200.7 500-111319-A-24-C MS

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-24-C MS

500-335323 500-334710 05/12/2016 21:25 KMLTAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-24 MW100S

P:200.7 500-111319-A-24-D MSD

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-24-D MSD

500-335323 500-334710 05/12/2016 21:29 KMLTAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-24 DU MW100S

P:200.7 500-111319-A-24-B DU

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 500-111319-A-24-B DU

500-335323 500-334710 05/12/2016 21:20 KMLTAL CHI1

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-24 SD MW100S

P:200.7 500-111319-A-24-A SD ^5

500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI5

A:200.7 Rev 4.4 500-111319-A-24-A SD ^5

500-335323 500-334710 05/12/2016 21:16 KMLTAL CHI5

05/09/2016 10:30

Lab ID:




Client ID:


500-111319-25 MW100M

P:200.7 500-111319-A-25-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1



07/11/2016Page 57 of 729




05/09/2016 10:30

Lab ID:




Client ID:


500-111319-26 MW100D

P:200.7 500-111319-A-26-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-27 MW103S

P:200.7 500-111319-A-27-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-28 MW103M

P:200.7 500-111319-A-28-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-29 MW104S

P:200.7 500-111319-A-29-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


05/09/2016 10:30

Lab ID:




Client ID:


500-111319-30 MW104M

P:200.7 500-111319-A-30-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1


Lab ID:




Client ID:

Sample Date/Time: N/A Received Date/Time: N/A

MB N/A

P:200.7 MB 500-334709/1-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 MB 500-334709/1-A 500-334919 500-334709 05/10/2016 16:09 PJ1TAL CHI1

P:200.7 MB 500-334710/1-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 MB 500-334710/1-A 500-335323 500-334710 05/12/2016 20:04 KMLTAL CHI1


07/11/2016Page 58 of 729




Lab ID:




Client ID:

Sample Date/Time: N/A Received Date/Time: N/A

LCS N/A

P:200.7 LCS 500-334709/2-A 500-334919 500-334709 05/10/2016 08:40 JEFTAL CHI1

A:200.7 Rev 4.4 LCS 500-334709/2-A 500-334919 500-334709 05/10/2016 16:13 PJ1TAL CHI1

P:200.7 LCS 500-334710/2-A 500-335323 500-334710 05/10/2016 08:42 JEFTAL CHI1

A:200.7 Rev 4.4 LCS 500-334710/2-A 500-335323 500-334710 05/12/2016 20:08 KMLTAL CHI1

Lab References:TAL CHI = TestAmerica Chicago


07/11/2016Page 59 of 729

Certification SummaryClient: Tyco Fire Protection Products TestAmerica Job ID: 500-111319-1Project/Site: Barrier Wall Monitoring

Laboratory Authority Program EPA Region Certification ID

TestAmerica Chicago 2903State ProgramCalifornia 9

TestAmerica Chicago 939State ProgramGeorgia 4

TestAmerica Chicago N/AState ProgramGeorgia 4

TestAmerica Chicago N/AState ProgramHawaii 9

TestAmerica Chicago 100201NELAPIllinois 5

TestAmerica Chicago C-IL-02State ProgramIndiana 5

TestAmerica Chicago 82State ProgramIowa 7

TestAmerica Chicago E-10161NELAPKansas 7

TestAmerica Chicago 66State ProgramKentucky (UST) 4

TestAmerica Chicago KY90023State ProgramKentucky (WW) 4

TestAmerica Chicago N/AState ProgramMississippi 4

TestAmerica Chicago 12019NELAPNew York 2

TestAmerica Chicago 291State ProgramNorth Carolina (WW/SW) 4

TestAmerica Chicago R-194State ProgramNorth Dakota 8

TestAmerica Chicago 8908State ProgramOklahoma 6

TestAmerica Chicago 77001State ProgramSouth Carolina 4

TestAmerica Chicago P330-15-00038FederalUSDA

TestAmerica Chicago 999580010State ProgramWisconsin 5

TestAmerica Chicago 8TMS-QState ProgramWyoming 8

Accreditation may not be offered or required for all methods and analytes reported in this package. Please contact your project manager for the laboratory’s current list of certified methods and analytes.

TestAmerica Chicago07/11/2016Page 60 of 729

METALS

07/11/2016Page 61 of 729

COVER PAGE

Lab Name: Job Number:

Client Sample ID Lab Sample ID

METALS

Project: Barrier Wall Monitoring

SDG No.:

500-111319-1TestAmerica Chicago

500-111319-1 MW021S500-111319-2 MW021M500-111319-3 MW040S500-111319-4 MW040M500-111319-5 MW040D500-111319-6 MW040S/D500-111319-7 MW064S500-111319-8 MW064M500-111319-9 MW064D500-111319-10 MW101S500-111319-11 MW101M500-111319-12 MW102S500-111319-13 MW102M500-111319-14 MW102D500-111319-15 MW102D/D500-111319-16 MW105S500-111319-17 MW105M500-111319-18 MW105D500-111319-19 MW041S500-111319-20 MW041M500-111319-21 MW047S500-111319-22 MW047M500-111319-23 MW047D500-111319-24 MW100S500-111319-25 MW100M500-111319-26 MW100D500-111319-27 MW103S500-111319-28 MW103M500-111319-29 MW104S500-111319-30 MW104M

Comments:

07/11/2016Page 62 of 729

1A-ININORGANIC ANALYSIS DATA SHEET

Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:

Lab Sample ID: 500-111319-1

Date Received: 05/09/2016 10:30

500-111319-1

MW021S

Water 05/01/2016 08:31Date Sampled:

Reporting Basis: WET

METALS - TOTAL RECOVERABLE

TestAmerica Chicago

CAS No. Analyte CUnits Q MethodRL MDL DILResult

7440-38-2 Arsenic 0.060 mg/L0.0050 0.0025 1 200.7 Rev 4.4

FORM IA-IN 07/11/2016Page 63 of 729


Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW021M




TestAmerica Chicago


7440-38-2 Arsenic 0.0048 Jmg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW040S




TestAmerica Chicago


7440-38-2 Arsenic 0.046 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW040M




TestAmerica Chicago


7440-38-2 Arsenic 0.25 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW040D




TestAmerica Chicago


7440-38-2 Arsenic 0.023 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW040S/D




TestAmerica Chicago


7440-38-2 Arsenic 0.047 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW064S




TestAmerica Chicago


7440-38-2 Arsenic 0.42 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW064M




TestAmerica Chicago


7440-38-2 Arsenic 6.3 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:


Date Received: 05/09/2016 10:30

500-111319-1

MW064D




TestAmerica Chicago


7440-38-2 Arsenic 0.53 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:

Lab Sample ID: 500-111319-10

Date Received: 05/09/2016 10:30

500-111319-1

MW101S




TestAmerica Chicago


7440-38-2 Arsenic 0.22 mg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:

Lab Sample ID: 500-111319-11

Date Received: 05/09/2016 10:30

500-111319-1

MW101M




TestAmerica Chicago


7440-38-2 Arsenic 0.0032 Jmg/L0.0050 0.0025 1 200.7 Rev 4.4



Client Sample ID:

Lab Name: Job No.:

SDG ID.:

Matrix:

Lab Sample ID: 500-111319-12

Date Received: 05/09/2016 10:30

500-111319-1

MW102S




TestAmerica Chicago


7440-38-2 Arsenic 0.075 mg/L0.0050 0.0025 1 200.7 Rev 4.4


1A-ININORGANIC ANALYSIS DATA

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