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AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
1
ANSWERS, HINTS & SOLUTIONS
FULL TEST –I (Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS 1. A B C
2. B B B
3. D B A
4. D B C
5. A, D
A, C A, C
6. A, B, C, D
A, B, C A, C
7. B, C A, B, D A, C
8. A, C A, B, D C, D
9. A, B, C B, C A, C, D
1.
(A) → (p, q, r, s ) (B) → (q, r) (C) → (q, r) (D) → (p, q, r, s)
(A) → (r, s) (B) → (p, r) (C) → (r, t) (D) → (q)
(A) → (s, t) (B) → (p, q) (C) → (r) (D)→ (p, q, r, s, t)
2.
(A) → (r) (B) → (p) (C) → (q) (D) → (s)
(A) → (q, r, t) (B) → (s, t) (C) → (s, t) (D) → (p, r, t)
(A) → (q) (B) → (r) (C) → (q) (D)→ (p, q, r, s, t)
1. 8 5 4
2. 4 2 8
3. 9 2 3
4. 5 5 5
5. 3 8 3
6. 1 8 5
7. 5 6 3 8. 8 7 3
ALL
IND
IA T
ES
T S
ER
IES
FIITJEE JEE(Advanced)-2013
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2
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
2
PPhhyyssiiccss PART – I
SECTION – A 1. By conservation of momentum J = mV + 2 mV V= J/3m. 2. 0 + 2 × 1 + 3 × 1 = VB ∴ VB = 5 volt
4. S < 21 gt2
⇒ S < 2g. (due to Lenz’s Law). 6. The molar heat capacity has the general definition
1 QCn T
∆= ⋅
∆
where n = number of moles, ∆Q = heat absorbed by the gas and ∆T = rise in temperature of gas. It is possible to obtain almost any set of values for ∆Q and ∆T by proper selection of a process.
7.
12 102usin 2Tg 10
× ×θ= = = 1 sec.
30º 30º
30º30º
8. M'g T M'a− = …(i) T = Ma …(ii) M'g a(M M')= +
M'ga(M M')
=+
masin mgcosθ = θ a gcot= θ
T
R
Mg
M
M'ggcot(M M')
θ =+
cot M cot M' M'θ + θ =
McotM'(1 cot )
θ=
− θ
T = M a = M. g cot θ
MgTtan
=θ
.
masinθ
ma
mgsinθmgcosθ
θ
+ macosθ
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
3
9. RF 2 2 iBa= .
2iBa
2iBa
SECTION –C
1. P = β v2
2mdv .v vdt
= β
0
0
2v t
v 0
dv dtv m
β=∫ ∫
ln2 .tmβ
=
mln2t =β
4 2t 0.6930.693×
= ×
t = 8 seconds. 2. After 5 s, speed of detector = 50 – 10 × 5 = 0 and that of source = 0 + 10 × 5 = 50 m/s
and the source has fallen a distance 21 10 (5) 1252
= × × = m
and the detector has rises a distance 2150 5 10(5) 125
2= × − × = m
So, 300 0f ' 130300 50
− = − = 156 Hz.
Ground
O v=0
50 m/sS
3. 2GMgR
=
2G.2mg'4R
=
gg'2
=
F mg'sin= − ∝
mgF .sin22
= − θ
αθmg’
2R
mgsinαθ2R
mgcosα
As θ is much small
mgma .22
= − θ
a g.= − θ
xa g.2R
= −
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
4
g2R
∴ ω = f
2RT 2g
= π
32 6400 10T 2 3.14
10× ×
= ×
= 2 × 3 × 800 × 1.41 T = 6768 s. 4. AB = v dt sin θ …(i) (along the circular arc)
OA = ANsinθ
ds = r dθ given vdt sin θ = OA dθ
2a 3
dθθO
B
N
A
ANvdt sin .dsin
θ = θθ
avdt sin dsin
θ = θθ
2d v sindt aθ= θ
d 5dtθ= rad/s.
5. We have, 10.2 = W + Kmax, 1 …(i) and 10.2 Z2 = W + Kmax, 2 …(ii)
Also de Broglieh h
2mK−λ = =ρ
1 22 1
2 1
K2.3 K 5.25 K
Kλ
∴ = = ⇒ =λ
…(iii)
Also 10.2 Z2 = energy corresponding to longest wavelength of the Lyman series = 3 × 13.6 ⇒ Z = 2. ∴ From equations (i), (ii) and (iii) W = 3 eV. 6. Velocity of efflux v 2gy=
Range 2hx 2gyg
= ×
The velocity of the block must be dxdt
.
V
A
x
ay
h
bdx 2h 1 dyV 2gdt g dt2 y
∴ = = × ×
bh dyV .
dty= …(i)
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
5
Using equation of continuity
Ady a 2gydt
= …(ii)
equation (i) and (ii)
bh aV 2gyy A
= ×
baV 2ghA
= ×
12020
= × = 1 ms–1.
7. If there were no hole
0 2GMgR
=
decrease in g due to hole (absent mass)
( )
1 2 2GM / 8 GMg
2RR2
= =
effective g = g0 – g1
2GM2R
=
= 5.5 m/s2.
8. q qdq .Rd .d2 R 2
= θ = θπ π
dq qddiT 2 2
θω= =
π π
2qdi .d4ω
= θπ
θ
dθRdθ
2
03
di(Rsin )dB
2Rµ θ
=
2
02
0
sin qdB d2R 4
π µ θ ω = θ π ∫ ∫
0qB
16 Rµ ω
=π
φ = Bπa2
2 0qa .
16 Rµ ω
φ = ππ
2
0q a16R
µ ωφ =
d| |dtφ
ε =
2
0qa| |
16Rµ
ε = α .
= 8 volt
8i1
= = 8 A.
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
6
CChheemmiissttrryy PART – II
SECTION – A
1. Wsolute = 3 gms, Wsolvent = 50 gm = 75 – 25
OH
3 xW40 56− = + .
( )+= = ×
3 x40 56m 5 1000
47
X = 9 2. Major product is formed via E2. H anti to halogen will be eliminated. 3. nHx = nNaOH = 0.25 × VNaOH, pH = pKa = 5 (acid buffer)
a1 1pH 7 pK logC 92 2
= + + = 1logC 1 C 10−⇒ = − ⇒ =
NaOHNaOH
0.25VC V 40 ml60 V
= ⇒ =+
nHx = 10 mm = 0.82 gm
0.82% 100 80%
1.025= × =
4. Time required for equifractional change in a first order reaction is constant.
SECTION – C 1.
C
H
N H CH
O
P Q
2.
Co
Cl
NH3H N3
Cl–
(Fac) (Mer)
+
Cl
NH3
H N3
Co
Cl
Cl
NH3
H N3
NH3 Cl
Co
Cl
Cl
H N3
Cl
NH3H N3
3. ( )
( )
2 4 7 2 3 34
5 3 4
Na B O H O 2Na B OH 2H BO
1 mol 2 mol
NaOH H BO NaB OH
2 mol 2 mol
+ → +
+ →
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
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7
4. A = 2y1/3 nm. M = 6.023 × y × 4 amu
Density = m/a3 = 27
27
6.023 4 1.66 10 kg / m³8y 10
−
−
× × ××
40 5 kg / m³8
= =
5. Two double bonds capable exhibiting geometrical and one chiral carbon molecule asymmetric. 23 = 8
6. Pvmw 58.33 gmRT
= =
58.33% 100 77%
75= × =
7.
B – O – BO
O
O
O
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com
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MMaatthheemmaattiiccss PART – III
SECTION – A
1. PQ is a focal chord 21 a 2aQ , t tt
− = −
Normal drawn at P(t) meets the curve at Q 2t, t− −
∴ Normal drawn at 1Qt
−
meets the parabola again at R 12tt
+
21 1R a 2t , 2a 2t
t t
+ +
Equation of tangent at R is 21 1y 2t x a 2t
t t + = + +
….. (1)
Equation of focal chord PQ is ( ) ( )2t 1 y 2t x a− = − ….. (2) T is the point of intersection of line (1) and (2)
⇒ 22
a 1 2a 1T 4t , 4t3 3 tt − +
∴ Area of ∆ TQR = 328a 1t
3 t +
2. Let a point (3λ + 1, λ + 2, 2λ + 3) of the first line also lies on the second line. Then
3 1 3 2 1 2 3 21 2 3
λ + − λ + − λ + −= = ⇒ λ = 1
Hence the point of intersection P of the two lines is (4, 3, 5). Equation of plane perpendicular to OP where OP is (0, 0, 0) and passing through P is 4x + 3y + 5z = 50
3. For non triangle solution a b cb c a 0c a b
∆ = =
⇒ a + b + c = 0 ⇒ ‘1’ is a root of ax2 + bx + c = 0 4. Clearly we have
xy 2xdy ydx xdy ydx
e x+ −
=
⇒ xy yd(xy)e dx
− = ∫ ∫ ⇒ xyy e c
x−+ =
5. Let the roots of az3 + bz2 + cz + d = 0, z1 = x1, z2, z3 = x2 ± iy2
⇒ z1 + z2 + z3 = ba
−
⇒ ab > 0
Also z1 z2 z3 = ( )2 21 2 2
dx x ya
+ = −
⇒ ad > 0
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
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9
6. On solving we have 12
α = and 2 34
β = ⇒ 32
β = ±
∴ New roots are ω and ω2 which are roots of x3 – 1 = 0 or x2 + x + 1 = 0
7. Redefining the function, we get
2x 4x 8 ; x 15 5 5f(x)
2 x ; x [1, 2)x 2 ; x 2
− + <= − ∈
− ≥
We have R.H.L at x = 1 is = h 0lim 2 (1 h) 1→
− + =
L.H.L at x = 1 is = ( ) ( )2
h 0
1 h 4 1 h 8lim 15 5 5→
− −− + =
∴ f(x) is continuous at x = 1
Now
2x 4 ; x 15 5
f '(x) 1 ; 1 x 21 ; x 2
− <= − ≤ < ≥
R.H.D at x = 1 ⇒ –1
L.H.D at x = 1 ⇒ 25
−
∴ Not differentiable at x = 1 ⇒ Not differentiable at x = 2 8. Let a , b , c lie in the xy plane
Let ˆa i= , 1 3ˆ ˆb i j2 2
= − + and 1 3ˆ ˆc i j2 2
= − −
∴ 1 3 1 3ˆ ˆ ˆ ˆ ˆp q r a b c i i j i j2 2 2 2
+ + = λ + µ + ν = λ + µ − + + ν − −
= ( )2
232 2 4µ ν λ − − + µ − ν
= 2 2 2λ + µ + ν − λµ − λν − µν
= ( ) ( ) ( )2 2 21 1 1 1 4 32 2
λ − µ + µ − ν + ν − λ ≥ + + =
∴ p q r+ + can take a value equal to 3 and 2. 9. z2 + az + a2 = 0 ⇒ z = aω, aω2 (where ‘ω’ is non real root of unity) ⇒ locus of z is a pair of straight lines and arg (z) = arg(a) + arg(ω) or arg(a) + arg(ω2)
⇒ arg(z) = ± 32π also, |z| = |a||ω| or |a| |ω2| ⇒ |z| = |a|.
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
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10
SECTION – B
1. Clearly lines are 2x + y + 2 = 0 and x + 2y + 1 = 0 and third line is bx + y + 5 = 0 For four circles three lines must not be concurrent ⇒ b ≠ 5
For two circles exactly two lines should be parallel ⇒ 1b2
= and 2
For no circle three lines must be concurrent ⇒ b = 5 For infinite circles two lines must be identical ⇒ b ∈ φ
2. (A) Solving 22K Ky 03−
= > and 24K 2Kx 0
3−
= > ⇒ 1K , 22
∈
(B) Given ( )1g(x) ln cos x−= ; As 10 cos x x [ 1, 1]−≤ ≤ π ∀ − So domain of g(x) = [–1, 1]. Hence number of integers are two (i.e. –1 and 0) (C) Clearly, domain of expression = {–1, 1}. As x > 0 given So x = 1
Hence value of expression ( )201011 sin x 1−+ =
(D) Here x af(x)x b+
=+
….. (1)
and 1 a bxf (x)x 1
− −=
− ….. (2)
Given 1f(x) f (x)−= ⇒ x a a bxx b x 1+ −
=+ −
⇒ ( ) ( ) ( )2 21 b x b 1 x x 1 b 0+ + − − + = ∀ x ∈ Df Hence b = –1 and a ∈ R
SECTION – C
1. Using AM – GM inequality
(a + b)2 + (a + b + 4c)2 = (a + b)2 + (a + 2c + b + 2c)2 ≥ ( ) ( )2 22 ab 2 2ac 2 2bc+ +
= 4ab 8ac 8bc 16c ab+ + +
∴ ( ) ( ) ( ) ( )
2 2a b a b 4c 4ab 8ac 8bc 16c aba b c a b cabc abc
+ + + + + + ++ + ≥ ⋅ + +
= ( )4 8 8 16 a a b ba b c cc b a 2 2 2 2ab + + + + + + + + +
≥ 2 2
552 2 41 a b c8 5 5 100
2a b c 2
× =
2. Putting X = x + 1 and Z = z + 1 ∴ f(X) + f(Z) = f(X + Z)
∴ ( )h 0 h h 0
f(X h) f(X) f(X) f(h) f(X) f(h) f(0)f ' X lim lim limh h h→ →∞ →
+ − + − −= = =
= f′(0) = 4 ⇒ f′(X) = 4 ⇒ f(X) = 4X + c ∴ f(x) = 4x ⇒ f(2) = 8 3. Let f(θ) = ∏(tan θ – tan αi) – ( )( )itan tanθ − α∑
We have ( ) / 2f θ→−πθ → −∞ Again ( )1f 0α > , ( )3f 0α < and ( ) / 2f θ→πθ → ∞ ⇒ There will be 3 such values of ‘θ’
AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/13
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11
4. Let the equation be K(x – α)(x – β) = 0 ∴ Sum of coefficient = K(α – 1)(β – 1) is prime ⇒ K is 1 and α – 1 is 1 ⇒ One root is 2 and β – 1 is 2 Hence roots are 2 and 3. 5. Let 3t x= in I2
We have 1 1
2 t 1 t0 0
1 1 1 1I dt dt3 3e (2 t) e (1 t)−
= =− +∫ ∫
⇒ 1 t
12 1
20
I1 e 1I dt I 33e (1 t) 3e eI
= = ⇒ =+∫
6. Let 3, 4 and r be radii of the circles inscribed into the ∆’s ACD, BCD and ∆ABC respectively, we
get r AB c3 AC b= = ⇒ 3cb
r=
Similarly ∆ABC and ∆BCD are similar, we get r c4 a= ⇒ 4ca
r=
Now as 2 2 2c a b= +
⇒ 2 2
22 2
9c 16ccr r
= + ⇒ r = 5
7. Putting x = 2, 12
and – 1 successively
1f(2) f 32
+ =
….. (1)
( )1 3f f 12 2
+ − =
….. (2)
and f(–1) + f(2) = 0 ..... (3)
Solving, we get 3f(2)4
=
8. On solving we have 4 2A cos 1 cos 1= θ + − θ + = 2
2 1 7cos2 4
θ − +
⇒ 7A , 24 ∈