OChem 4 (1:11:12)
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Transcript of OChem 4 (1:11:12)
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8/11/2019 OChem 4 (1:11:12)
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Page 1.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
Introduction
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Page 2.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
review organic acidity
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Page 3.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
acidity summary
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Page 4.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
carbonyl reactivity - tautomerization
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Page 5.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
carbonyl reactivity - nucleophilicity of enolates
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Page 6.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
carbonyl reactivity - electrophilicity
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Page 7.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - general mechanism
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Page 8.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - hydride reductions
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Page 9.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - organometallic reagents
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Page 10.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - acetal reaction
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Page 11.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - acetal mechanism
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Page 12.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
acetal/hemiacetal structure
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Page 13.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
acetal identification problems
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Page 14.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
original carbonyl compounds
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Page 15.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - imine formation
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Page 16.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - aldol reaction
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Page 17.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
how many enolates?
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Page 18.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
relative acidities of alpha protons
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Page 19.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
kinetic vs. thermodynamic enolates
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Page 20.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
reactivity and resonance structures
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Page 21.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic additions - Michael addition
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Page 22.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P9 text
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Page 23.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P9 Q1&2
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Page 24.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P9 Q3
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Page 26.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P9 Q5
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Page 28.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 text
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Page 29.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 Q1&2
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Page 30.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 Q3
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Page 31.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 Q4
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Page 32.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 Q5
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Page 33.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P10 Q6
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Page 34.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
carboxylic acids
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Page 35.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
COOH acid derivatives - synthesis from COOH
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Page 36.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
COOH acid derivatives - relative reactivities and LGs
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Page 37.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
nucleophilic addition-eliminations
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Page 38.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
COOH acid derivatives - ester formation overall
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Page 39.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ester mechanism
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Page 40.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
COOH acid derivatives - saponification
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Page 41.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
COOH acid derivatives - predict the product
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Page 42.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 text
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Page 43.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q1
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Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q2
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Page 45.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q3
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Page 46.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q4
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Page 47.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q5
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Page 48.
Elluminate Live! - MCAT119EARLY-O CHEM 4 Jan 11, 2012 12:06:44 PM
ICC P11 Q6
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