Notio Sn presentation.pdf
Transcript of Notio Sn presentation.pdf
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New New Syndiotactic Syndiotactic Elastomer Elastomer with Crystallinewith Crystalline
Structure controlled inStructure controlled in NanoNano Order Order
Mitsui Chemicals, Inc.Mitsui Chemicals, Inc.Elastomer Elastomer Div.Div.
SELLER WARRANTS TO THE BESTOF ITS KNOWLEDGE THAT THE USEOR SALE OF NOTIO TMSN WILL NOTINFRINGE UPON ANY PATENTCOVERING THE PRODUCT ITSELF,BUT DOES NOT WARRANT AGAINSTINFRINGEMENT BY REASON OF THEUSE THEREOF IN COMBINATIONWITH ANY OTHER PRODUCTS OR INTHE OPERATION OF ANY PROCESS.
SNSN
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1.1. What is NotioWhat is Notio TMTM--SNSN ??
2.2. Adapting for Adapting for calenderingcalendering of Notioof NotioTMTM
--SNSN
3.3. Features of NotioFeatures of Notio TMTM--SN leather SN leather
ContentsContents
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2013.02.2013.02. 2525Structure of NotioStructure of Notio TM TM - - SN SN
1. What is Notio1. What is Notio TM TM - - SN? SN?
NotioNotio TM TM - - SN is aSN is a Syndiotactic Syndiotactic New OlefinNew Olefin Elastomer Elastomer withwithCrystalline/Amorphous Structure Controlled inCrystalline/Amorphous Structure Controlled in NanoNano Order Order
50nm50nm
crystalline blockscrystalline blocksheat resistanceheat resistanceresistance to Scratch and Abrasionresistance to Scratch and Abrasion
NanoNano network of network of crystallinecrystalline / /amorphousamorphous segmentssegmentsTransparency, Solubility, Resistance to Scratch and AbrasionTransparency, Solubility, Resistance to Scratch and Abrasion
AFM ImageAFM Image
amorphous chainamorphous chainrubber elasticity/flexibilityrubber elasticity/flexibilityhigh melt tensionhigh melt tensionresistance to Scratch and Abrasionresistance to Scratch and Abrasion
TEMTEM ImageImage10001000 nmnm
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densitydensity / /
Light WeightLight Weight
NotioNotio
PVCPVCPUPU
00
500500
10001000
15001500
TransparencyTransparency
Heat ResistanceHeat Resistance / /Elasticity BalanceElasticity Balance
GoodGoodElasticityElasticityPermanent set after 150%Permanent set after 150% ExtesionExtesion (%)(%)
4040 3030 2020 1010 00
6060
100100
140140
2020
T M A
T M A
( ( ) )
180180
NotioNotio TMTM
C2 basedC2 based elastmer elastmer SEBSSEBS
GoodGood
H
e a
t R e s
i s t a n c e
H
e a
t R e s
i s t a n c e
FlexibilityFlexibility
PP /PP / NotioNotio TMTM = 80 / 20wt%= 80 / 20wt%
TEMTEM ImageImage
Compatibility with PPCompatibility with PP
1 m
FeatureFeature s of Notios of Notio TM TM - - SN(1)SN(1)1. What is Notio1. What is Notio TM TM - - SN? SN?
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AbrasionAbrasion ResistanceResistance
Amount of Amount of Weight LossWeight Loss
GoodGood
NotioNotio --00
2020
4040
6060
8080
100100
PVCPVC
Taber Abrasion Wear testingTaber Abrasion Wear testingWeel;Weel; HH--3838 Load;9.8N(1kg)Load;9.8N(1kg) 770rpm,0rpm, 11000cycles000cycles
Scratch ResistanceScratch Resistance
NotioNotio TMTM--SNSN
Ethylene basedEthylene basedelastomer elastomer
EthyleneEthylene vinylacetatevinylacetatecopolymer copolymer
Frictional wear testFrictional wear test JIS L 0849 compliant,JIS L 0849 compliant,Load=Load= 10001000 gf, reciprocating times=10(33times/min.),gf, reciprocating times=10(33times/min.),rubbed by cotton duckrubbed by cotton duck
PU coatedPU coatedOlefin Leather Olefin Leather
1. What is Notio1. What is Notio TM TM - - SN? SN?
FeatureFeature s of Notios of Notio TM TM - - SN(2)SN(2)
NotioNotio TM TM - - SN has high abrasion resistance and scratchSN has high abrasion resistance and scratchresistance same as PU.resistance same as PU.
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2013.02.2013.02. 2525Physical properties of NotioPhysical properties of Notio TM TM - - SN SN
0mgmgWeight lossWeight lossAbrasion ResistanceAbrasion Resistance
3cmcmFalling Ball TestFalling Ball TestStressStress --AbsorbingAbsorbingPropertyProperty
8%%
ININ
--HazeHaze
Optical PropertyOptical Property
61%%@70@70 CC
25%%@23@23 CCCompression SetCompression Set
15%%Permanent SetPermanent Set34MPaMPa Young Modulus Young Modulus
>700%%Elongation of BreakElongation of Break
15MpaMpaTensile StrengthTensile Strength
Mechanical PropertiesMechanical Properties
116 CCSofteningSofteningTemperatureTemperatureThermal Property
Thermal Property84Shore A HardnessShore A Hardness
865Kg/m3Kg/m3DensityDensity
1.4g/10min.g/10min.@230@230 CCMFRMFR
Basic PropertiesBasic Properties
Notio TM
SN-0285UnitUnitConditionConditionItemItem
1. What is Notio1. What is Notio TM TM - - SN? SN?
The above figures are just representative value, but not specification values.
Low Low - - MFR and High abrasion resistance is features of NotioMFR and High abrasion resistance is features of Notio TM TM - - SN.SN.
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NotioNotio TMTM--SN PelletSN Pellet
Formability of NotioFormability of Notio TM TM - - SN SN 1. What is Notio1. What is Notio TM TM - - SN? SN?
NotioNotio TM TM - - SN is supplied as pellets and can be formed by SN is supplied as pellets and can be formed by
extrusion or extrusion or calendering calendering process. process.
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Soft SheetsSoft Sheets
Car InteriorsCar Interiors StationeryStationery
BagBag ShoeShoe ss
Applications Applications1. What is Notio1. What is Notio TM TM - - SN? SN?
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1. What is Notio1. What is Notio TM TM - - SN? SN?
Through this collaboration, HUNTING WORLDwanted to express strong will, as symbolized byRyo Ishikawas strong resolve and ardentpassion, as well as the attitude of doggedlypursuing a dream. The theme color is red acolor that Ryo Ishikawa also likes to wear canbe said to be the most appropriate color for representing this will. As for attitude, this hasbeen expressed using a single, straight line.The inner lining is a deep red base materialembossed with Ryo Ishikawas brand logo, aswell as an albatross and eagle motifs, two birdsthat are used as golf terms to indicate scores.The lineup includes five items: a messenger
bag, a tote bag, a small tote bag, a duffle bag,and a pouch. Everything from the design andstyle down to the smallest details has beendeveloped in collaboration with Ryo Ishikawa.
For the main material, these products useNOTIONOTIO SN leather SN leather , a new material thatbrings several Japanese technologies together.NOTIONOTIO SN leather SN leather is a revolutionary materialwith excellent heat resistance, wear resistance,and scratch resistance, but none of the harmfulsubstances that are often included in thematerials normally used for bag applications.But the best thing about this material is that it isextremely light. In fact, the material used inthese bags is 30% to 40% lighter than theplastics that are normally used, such as PVC(vinyl chloride).
http://www.honda.co.jp/FREEDSPIKE/
NotioNotioTMTM-- SN is usedSN is usedfor surface leather.for surface leather.
(1)Honda Freed Spike (2)Hunting world
http://www.itochu.co.jp/ja/news/2012/121114.html
Adaption examples Adaption examples
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1.1. What is NotioWhat is Notio TMTM--SNSN ??
2.2. Adapting for Adapting for calenderingcalendering of Notioof NotioTMTM
--SNSN
3.3. Features of NotioFeatures of Notio TMTM--SN leather SN leather
ContentsContents
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melting & mixingmelting & mixing
CalenderingCalendering
LaminatingLaminating
CoolingCoolingwindingwinding
less than 35less than 35(sheet temperature)(sheet temperature)
115115 130130(sheet temperature)(sheet temperature)
160160 1818 55
(resin temperature)(resin temperature)
160160 1818 55(resin temperature)(resin temperature)
TemperatureTemperature
more than 10m/min.more than 10m/min.
Mixing timeMixing time ;;less than 30min.less than 30min.
Line speedLine speed
More than the softeningMore than the softeningtemperaturetemperature
Temperature should be set toTemperature should be set tomore than the melting pointmore than the melting pointof the polymer of the polymer
PointsPointsProcessProcess
Calendering Calendering conditionsconditions2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN
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2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN
Formulation examples for leather Formulation examples for leather
ShoreShore --A HardnessA Hardness 90906060
T a
b e r
A b r a s i o n
R e s
i s t a n c e
T a
b e r
A b r a s i o n
R e s
i s t a n c e
goodgood
NotioNotio TMTM--SN/PPSN/PP
NotioNotio TMTM--SN/PESN/PE
NotioNotio TMTM--SN/PP and/or SN/PP and/or
Tafmer Tafmer TMTM
--PN, ML, etcPN, ML, etc
NotioNotio TMTM--SN/EVA and/or SN/EVA and/or Tafmer Tafmer TMTM / /
Tafmer Tafmer TMTM--PN, ML, etcPN, ML, etc
NotioNotio TMTM--SN and/or SN and/or
Tafmer Tafmer TMTM
--PN, ML, etcPN, ML, etc
Car interiorsCar interiors
Bag/CaseBag/CaseUltrasonic Welder Ultrasonic Welder
Nonslip goodsNonslip goods
Shoes / FurnitureShoes / Furniture
Building MaterialsBuilding MaterialsFlexing ResistanceFlexing Resistance
Heat ResistanceHeat Resistance
Scent FreeScent Free
StationaryStationary
We recommend the Notio TM-SN base compound as your request spec.
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2. Adapting for 2. Adapting for calendering calendering of Notioof Notio TM TM - - SN SN
Ruck
Embossing
FoamingWorkability
Physical
property
Calendering
Flex resistance
(with filler)(with filler)(with filler)Flame resistance
CH-18SN-0285
(55)(55) (84)Flexibility (Shore-A)
Abrasion resistance
Notio TM-SNbase compound
Notio TM-SNItems
Formulation examples for leather Formulation examples for leather
CH-18 is the softest formulation which we have already developed.
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1.1. What is NotioWhat is Notio TMTM--SNSN ??
2.2. Adapting for Adapting for calenderingcalendering of Notioof NotioTMTM
--SNSN
3.3. Features of NotioFeatures of Notio TMTM--SN leather SN leather
ContentsContents
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2013.02.2013.02. 2525Compared PVC leather Compared PVC leather to Notioto Notio TM TM - - SN leather SN leather
3. Features of 3. Features of NotioNotio - - SN leather SN leather
conditionitem
No changeNo changeCrackCrack-100,000times-10
206226NwrapTear strength
1238858Nweft
50,000times
50,000times
CS-10, 9.8N,60rpm, 1000times
445050mg23 Abrasion resistance
(weight loss)
0.50.5mmCloth
Flexion resistance
No changeNo change-23
1263788NwrapTensile Strength
170126Nweft
-10
Total 1.11.1mm
Thickness
-
unit
No changeNo change
Notio TM-SN leather LV leather Measurement
Especially, abrasion resistance and flexion resistanceEspecially, abrasion resistance and flexion resistancein low temperature of NotioTM in low temperature of NotioTM - - SN leather are better SN leather are better
than those of LV leather.than those of LV leather.
Cloth>Resin layer Cloth>Resin layer
(Depending on(Depending on
cloth properties)cloth properties)
The above figures are just representative value, but not specification values.
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2013.02.2013.02. 2525Compared P Compared P U U leather leather to Notioto Notio TM TM - - SN leather SN leather
Pictures aftertesting
26 mg18 mgAmount of weight loss
PU leather NotioTM-SN leather
Taber Abrasion Wear testingTaber Abrasion Wear testing :H22, 1kg, 60rpm, 200times
PUPUPUPUPUPUPUPU leatherleatherleatherleatherleatherleatherleatherleather NotioNotioNotioNotioNotioNotioNotioNotioTMTMTMTMTMTMTMTM-------- SNSNSNSNSNSNSNSN leatherleatherleatherleatherleatherleatherleatherleather
The above figures are just representative value, but not specification values.
Exposed clothExposed clothExposed clothExposed clothExposed clothExposed clothExposed clothExposed cloth
3. Features of 3. Features of NotioNotio - - SN leather SN leather
Abrasion resistance of Notio TM -SN leather is the same as PU.(PU leather has exposed cloth after test, but Notio TM -SN leather dont have it.)
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aromaticaromaticcompoundscompounds
halidehalide
solventsolventplasticizer plasticizer
useuse--freefree
--useusefreefree
useuse--freefree--useusefreefree
PU leather PU leather PVC leather PVC leather NotioNotio TMTM--SN leather SN leather
Environment safety Environment safety
NotioNotio TM TM - - SN leather doesSN leather does NOT NOT include plasticizers, phthalate, halide, and include plasticizers, phthalate, halide, and styrene, and it is lower environmental load than PVC and PU leat styrene, and it is lower environmental load than PVC and PU leat her her ..
3. Features of 3. Features of NotioNotio - - SN leather SN leather
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NGNGNGNGgoodgoodWater Water
(100degreeC,(100degreeC,
5min.)5min.)
NGNGNGNGgoodgoodalkalinealkalineaqueous sol.aqueous sol.
NGNGNGNGgoodgoodacidacidaqueous sol.aqueous sol.
NGNGNGNGgoodgoodNaphthaleneNaphthalene(Mothball)(Mothball)
PU leather PU leather PVC leather PVC leather NotioNotio TMTM--SN leather SN leather
Durability ; hydrolysis, SolventsDurability ; hydrolysis, Solvents3. Features of 3. Features of NotioNotio - - SN leather SN leather
NotioNotio TM TM - - SN leather is stable against hydrolysis and Solvents.SN leather is stable against hydrolysis and Solvents.
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**test conditiontest condition JIS ZJIS Z 29112911 --20102010appendix1 test of plasticappendix1 test of plastic methodmethod Durability ; FungusDurability ; Fungus
PVCPVCNotioNotio TMTM--SNSN
Judgment0 ;The growth of mold is not visible under the naked eye and the microscope either.1;The growth of mold is not visible under the naked eye, but visible under the microscope.2; The growth of mold is not visible under the naked eye, the area of the growth part is less than 25%
of the overall product of the sample.3; The growth of mold is not visible under the naked eye, The area of the growth part is less than 50%
of the overall product of the sample.4; The bacterial thread often grows. The area of the growth part is 50% or more of the overall product of the sample.5 ; The growth of the bacterial thread intensely covers the front side of the sample.
PUPU
Result: 1Result: 1 Result: 3Result: 3 Result: 4Result: 4
3. Features of 3. Features of NotioNotio - - SN leather SN leather
NotioNotio TM TM - - SN has strong Fungus Resistance.SN has strong Fungus Resistance.
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**test conditiontest condition JIS ZJIS Z 29112911 --20102010appendix1 test of plasticappendix1 test of plastic methodmethod Cold resistanceCold resistance
3. Features of 3. Features of NotioNotio - - SN leather SN leather
DroppingDroppingDroppingDroppingDroppingDroppingDroppingDropping
-------- 3030303030303030
Cold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testCold resistance testJIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772JIS K 6772
PVCPVCPVCPVCPVCPVCPVCPVC
NotioNotioNotioNotioNotioNotioNotioNotioTMTMTMTMTMTMTMTM-------- SN leatherSN leatherSN leatherSN leatherSN leatherSN leatherSN leatherSN leather
NotioNotio TM TM - - SN leather is superior to PVC leather in Cold resistance,SN leather is superior to PVC leather in Cold resistance,
and it is not broken at and it is not broken at - - 30 30 ..