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Nobuhiro Matsumoto - Sumitomo Metal Mining Co - A problem and the prospects of HPAL
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Transcript of Nobuhiro Matsumoto - Sumitomo Metal Mining Co - A problem and the prospects of HPAL
NC
Philippine
Saprolite
Hyuga Smelter
Fe-Ni
21kT-Ni/A
PI Vale
others
CBNC THPAL
Nickel Matte MS
Harima DivNiihama Ni Refinery
E-Ni
65kTt-Ni/A
NiSO46H2O
11kT-Ni/A
Capital: US$ 487 M (Line1:180 + Line2:307)
Product: Mixed Sulfide (Ni : 55 - 58% , Co : 4 - 5%)
Capacity: 24,000Ni-t/year,1,700Co-t/year
Technology
Operation
Mixed Sulfide
Ore & Limestone
Share: 10% Share: 18%
Share: 18%Share: 54%
Technology
Operation
Laterite Ore Supply
Mixed Sulfide
SHARE 15%
SHARE 62.5%
SHARE 22.5%
Capital: US$ 1,590 M
Product: Mixed Sulfide (Ni : 56 - 58% , Co : 5 - 6%)
Capacity: 30,000Ni-t/year,2,650Co-t/year
0.0
5.0
10.0
15.0
20.0
25.0
30.0
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014
CBNC THPAL
YEAR
Ni P
rod
ucti
on
/ K
T
Nickel Ore
Ore-Prep.
H2SO4, Steam
H2S
Mixed Sulfide(NiS/CoS)
Final
Neutralization
Tailings Dam
Leach Residue
Limestone
CCD
Neutralization
HPAL
Zinc Removal
Sulphurization
Barren Liquor
Pre-Neutralization
High Quality for Production of E-Ni
Selective Sulfurization of Zinc
High Nickel Recovery
Prevention of Scale Formation
*MS Reactors
*PAL Autoclave
Controllability of Heat Recovery System
Utilization of Low Grade Nickel Ore
0
0.01
0.02
0.03
0.04
0 20 40 60 80 100
Temperature(℃ )
Zn
Co
nc.(
g/L
)5.0
5.1
5.2
5.3
5.4
Ni
Co
nc.(
g/L
)Zn(g/l)
Ni(g/l)
ZnS = Zn2+ + S2- : 7 × 10-26
CoS = Co2+ + S2- : 7 × 10-22
NiS = Ni2+ + S2- : 7 × 10-21
Successful Removal of Zn
Low Temperature < 60 ℃Homogeneous Reaction
Ni loss in Zn ppt < 1% (CBNC)
Energy Conservation
High Recovery of Nickel
High Partial Pressure of H2S
Prevention of Scale Formation
Operation Temperature (℃) Pressure (kPaG)
Moa Bay 120 1000
Murrin Murrin 95 100
CBNC 80 270
THPAL 70 350
Cost Saving Reduce Construction Cost for Tailings Dam
Hematite Production
Dry Stacking System
Long Life of Maintenance Parts
Chromite Recovery
Technological Advantage Recovery of Bi-ProductC
Scandium Recovery
Generation of Tailing Residue : 120-150m3/T-Ni
⇒ Hematite Production from Leach Residue
2007:Collaboration with Japanese Steel Mill
Capability of Chromium <0.01% for Blast Furnace
Application of Reduction Furnace
Utilization of Hematite for Stainless Mill
Element (%) Fe Si Al S Cr
Steel Mill 56-63 <2.7 <1.4 <0.1 <0.01
Stainless Mill >56 <2.6 1.3 - -
Leach Residue 33.3 2.8 1.5 NA 1.5
Hematite Residue 62.4 1.7 1.1 1.4 1.2
Chromite Promote Erosion of Facility Materials
⇒ Chromite Production from Feed Ore
Apply Gravity Separator
such as Cyclone, Density separator and Spiral
Presence of Scandium in Laterite Ni Detection of Trace Amount of Sc in Nonoc MS
Intensive Investigation of Sc Recovery in 2005
Scandium MarketDemand: 10-15 Ton in the World
Usage: SOFC, AL-Sc Alloy
Price: 1,500 - 2,000 USD/Kg Sc2O3
SMM produce 100kT/Year of Nickel, will expand
to 150kT/Year in the future
Our HPAL operation succeeds in the Philippines
We have to dilute fixed cost to gain further
profits, such as CAPEX of Tailings Dam
We will begin production of by-product to secure
competitiveness and superiority