NITED STATES ENVIRONMENTAL PROTk YION AGENCYJun 01, 2011 · penetration to aid in sugar...

- \NITED STATES ENVIRONMENTAL PROTk_ YION AGENCY

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYWASHINGTON, D.C. 20460

OFFICE OF CHEMICAL SAFETYAND POLLUTION PREVENTION

Maria Pilar HerreroRegulatory Affairs ManagerValent BioSciences Corporation870 Technology WayLibertyville, EL 60048

Subject: ProGibb 40%EPA Registration No. 73 049-1Label Amendment to add new uses for coffee, banana/plantain, pineapple, wheat, barley and oatsDecision #: 445603Application Dated: February 14, 2011

Dear Ms. Herrero:

The amendment referred to above, submitted in connection with registration under FIFRA section3(c)(5), is acceptable provided that you:

1. Submit and/or cite all data required for registration/reregistration of your product under FIFRA section3(c)(5) when the Agency requires all registrants of similar products to submit such data.

2. Submit three (3) copies of your final printed labeling before you release the product for shipment. Finalprinted labeling means the label or labeling of the product when distributed or sold. Clearly legiblereproductions or photo reductions will be accepted for unusual labels, such as those silk-screened directlyonto glass or metal containers or large bags or drum labels.

If these conditions are not complied withj the registration will be subject to cancellation in accordancewith FIFRA section 6(b). Your release for shipment of the product bearing the amended labeling constitutesacceptance of these conditions.

Should you have any questions, you may contact Ms. Menyon Adams directly at 703.347.8496 or viaemail at adams.menvoni@,epa.gov.

Sincerely,

^esticides BranchBiopesticic es^and Pollutic nPrevention Division (75 1 P)

EPA Form 1320-1A (1/90) Printed on Recycled Paper OFFICIAL FILE COPY

* U.S. Government Printing Office: 2005 206-899 fmanl

MASTER LABEL

Primary Product name: ProGibb 40% Plant Growth Regulator, Water SolubleGranule.

Sublabel I: ProGibb 40%, Plant Growth Regulator, Water Soluble Granule;For agricultural use on grapes, citrus, blueberry, banana/plantain, pineapple, coffee, sourand sweet cherries, pecan, celery, lettuce for seed, artichoke, carrot, cucumber, pepper,rhubarb, spinach, mustard greens, collard greens, turnip, strawberry, watercress and thestonefruit group. Also rice, hops, dry bean, wheat and cotton.

Sublabel II: RyzUp Smartgrass, Plant Growth Regulator;For agricultural use on Pastures and commercial use on Sod and Turf, Wheat, Barley andOats.

For Organic Production

Active IngredientGibberellin A3 40.0% w/wOther Ingredients 60.0% w/wTotal 100.0% w/w

Contains a total of 128 g of Gibberellic Acid in 320 g of product.

KEEP OUT OF REACH OF CHILDREN

CAUTION

EPA Registration No. 73049-1EPA Establishment No.

Valent BioSciences Corporation870 Technology Way, Suite 100Libertyville, IL 60048

Net Contents: 2.5g satchels, 80 or 320 g bottles Lot No.This container will treat acre at the maximum use rate, as directed for use on

ACCEPTED

Under the FederaHfcsectlcide, Fulwlcldeand Rodentfcjdt Act. as ame^ed/for 'i*! Pf stfclde registered under

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SUB-LABEL I

ProGibb® 40% Plant Growth RegulatorWater Soluble Granule

For agricultural use on grapes, citrus, blueberry, banana/plantain, pineapple, sour andsweet cherries, pecan, celery, lettuce for seed, artichoke, carrot, cucumber, pepper,rhubarb, spinach, mustard greens, collard greens, turnip, strawberry, watercress and thestonefruit group, melon, coffee, sugar cane. Also rice, hops, dry bean, wheat and cotton.

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PROGIBB®40%Plant Growth RegulatorWater Soluble Granule





CAUTION

See inside booklet for Precautionary Statements.


Valent BioSciences Corporation870 Technology Way, Suite 100Libertyville, IL 600481-847-968-4700

Net Contents: 2.5g, 80 g and 320 g Lot No.:

This container will treat acre at the maximum use rate, as directed for use on

FIRST AIDIf in eyes

If on skin or clothing

• Hold eye open and rinse slowly and gently with water for 15-20minutes.

• Remove contact lenses, if present, after the first 5 minutes, thencontinue rinsing eye.

• Call a poison control center or doctor for treatment advice.• Take off contaminated clothing.• Rinse skin immediately with plenty of water for 15-20 minutes.• Call a poison control center or doctor for treatment advice.

HOT LINE NUMBERHave the product container or label with you when calling a poison control center or doctor, or goingfor treatment. You may also call toll-free 1-800-892-0099 (24 hours) for emergency medical treatmentand/or transport emergency information. For all other information, call 1-800-6- Valent.

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PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS & DOMESTIC ANIMALS

Caution: Causes moderate eye irritation. Harmful if absorbed through skin. Avoidcontact with skin, eyes or clothing. Wash thoroughly with soap and water afterhandling. Remove and wash contaminated clothing before reuse.

Personal Protective Equipment (PPE)Applicators and other handlers must wear:

• Long-sleeved shirt and long pants.• Waterproof gloves.• Shoes plus socks.

Follow the manufacturer's instructions for cleaning/maintaining PPE. If no suchinstructions for washables, use detergent and hot water. Keep and wash PPE separatelyfrom other laundry.

User Safety Recommendations

Users should:• Wash hands before eating, drinking, chewing gum, using tobacco or using the

toilet• Remove clothing/PPE immediately if pesticide gets inside. Then wash

thoroughly and put on clean clothing.• Remove PPE immediately after handling this product. Wash the outside of

gloves before removing. As soon as possible, wash thoroughly and changeinto clean clothing.

ENVIRONMENTAL HAZARDSFor terrestrial uses: Do not apply directly to water, or to areas where surface water ispresent or to intertidal areas below the mean high water mark. Do not contaminate waterwhen cleaning or disposing of equipment washwaters or rinsate.Do not use treated seed for food, feed, or oil purposes. Exposed treated seed may behazardous to birds and other wildlife. Treat only those seeds needed for immediate useand planting. Do not store excess treated seed beyond planting time. Dispose of allexcess treated seed and seed packaging by burial away from bodies of water.

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DIRECTIONS FOR USEIt is a violation of Federal law to use this product in a manner inconsistent with itslabeling. Do not apply this product in a way that will contact workers or other persons,either directly or through drift. Only protected handlers may be in the area duringapplication. For any requirements specific to your State or Tribe, consult the State orTribe agency responsible for pesticide regulation.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worker ProtectionStandard, 40 CFR Part 170. This Standard contains requirements for the protection ofagricultural workers on farms, forests, nurseries, and greenhouses, and handlers ofagricultural pesticides. It contains requirements for training, decontamination, notification,and emergency assistance. It also contains specific instructions and exceptions pertaining tothe statements on this label about personal protective equipment (PPE), and restricted-entryinterval. The requirements in this box only apply to uses of this product that are covered bythe Worker Protection Standard.

Do not enter or allow worker entry into treated areas during the restricted entry interval(REI) of 4 hours unless wearing appropriate PPE.

PPE required for early entry to treated areas that is permitted under the Worker ProtectionStandard and that involves contact with anything that has beentreated, such as plants, soil, or water is:

• Coveralls.• Waterproof gloves.• Shoes plus socks.

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GENERAL DIRECTIONS FOR USE

Use only as directed. Read the label thoroughly and make sure it is understood beforemaking applications. Keep out of reach of children.

Application Instructions:

•ProGibb 40% water soluble granule contains gibberellic acid which is an extremelypotent plant growth regulator; when applying plant growth regulators, deviations from thelabel directions in the rates, timings, water volumes, or the adoption of untested spraymixes, results in undesirable effects. Always consult the local Valent representative inyour area for the spray regimen best suited to your conditions.

• Do not apply to plants under pest, nutritional, or water stress.

• When a range of rates is indicated, use the concentration and spray volume indicated bythe local Valent representative.

• For optimum effectiveness, thorough spray coverage of the target area must beachieved. Prepare solution concentrations by mixing the required amount of product withwater in a clean, empty spray tank. Discard any unused spray material at the end of eachday following local, state or federal law.

• For most efficacious results, the water pH is best at 7.0, and always below 8.5.

• Applications made under slow drying conditions (cool to warm temperatures, mediumto high relative humidity, and no wind) will increase absorption of the active ingredientby the plant, thus optimizing effectiveness. Night-time applications are encouraged whenday-time conditions are not conducive to slow drying conditions.

• Product persistence: Re-apply if significant rain occurs within 2 hours of application.

• Compatibility: When considering tank mixing with other products, use the followingcompatibility jar test before mixing a whole tank.

Start with a clear glass or plastic quart jar. Add water from the same water source thatwill be used for the larger tank mix. Add the pesticides in correct proportions. Mixthoroughly and let stand for a minimum 15 minutes. Heat, separation, gelling, are allsigns of incompatibility. Before using any mixes that pass the jar tests for compatibility,it is imperative to test the mixture on a designated area as it may result either inphytotoxicity or ineffectiveness. For further information, consult your local Valentrepresentative.

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• For aerial applications spray volumes must be greater than 2 gallons per acre (10gallons per acre for tree crops).

• No preharvest interval is required for this product.

SPRAY GUIDELINES FOR GRAPE

For all grapes, application by ground sprayer gives the most efficacious coverage. Applyas a concentrate or dilute spray in sufficient water volume to ensure complete coverage ofall flower clusters or berries. For cultivar specific spray rates and timings, seeaccompanying tables.

SEEDLESS TABLE GRAPE

CLUSTER STRETCH SPRAYS - SEEDLESS TABLE GRAPEOBJECTIVE/BENEFIT

For cluster elongation and looser clusterforms. To reduce costs of thinning,allow better air circulation to aid in thecontrol of bunch rot, and increase lightpenetration to aid in sugar development.

CROP/ CULTIVARPerlette SeedlessFlame Seedless

Thompson SeedlessRaisin

Other Seedless Grapes

APPLICATION TIMINGMake one to three applications before bloomwhen flower clusters are 2 to 7 inches long.

GRAMSA.I./Acre

8-248-248-248-24

GramsProduct/Acre

20-6020-6020-6020-60

OuncesProduct/Acre

0.7- 2.2 oz0.7- 2.2 oz0.7- 2.2 oz0.7 - 2.2 oz

No indications are available at this time.

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BERRY THINNING SPRAYS - SEEDLESS TABLE GRAPEOBJECTIVE/BENEFIT

For decreased berry set, reduced hand-thinning costs, and hastened maturity.

CROP/ CULTIVAR

Flame SeedlessThompson Seedless

RaisinOther Seedless Grapes

APPLICATION TIMINGMake one to four applications during bloom.Make only 1 -2 applications for "Other SeedlessGrapes." When the bloom period is extended,subsequent sprays are to be made 1 to 7 daysafter the first application.

GRAMSA.I./Acre

3-168-203-12

0.5 - 12

GramsProduct/Acre

7.5-4020-507.5-301.3-30

OuncesProduct/Acre0.3- 1.4oz0.7-1.8oz0.3 - 1.1 oz0.1 - 1.1 oz

NOTE: At the high end of the prescribed range of rates and number of applications,expect significantly more thinning in young vines or vines with high vigor. For "OtherSeedless Grapes" use caution as some of the new cultivars are very responsive and over-thin easily. Consult the Valent representative or local specialist before thinning cultivarswith which there is no familiarity.

BUMP SPRAY - SEEDLESS TABLE GRAPEOBJECTIVE/BENEFIT

To help initiate the beginning of theberry growth period.

CROP/ CULTIVAR

Thompson Seedless

APPLICATION TIMINGMake one application during the periodbetween the last thinning spray and the firstsizing spray.

GRAMSA.I./Acre

16-24

GramsProduct/Acre

40-60

OuncesProduct/Acre

1.4-2.2oz

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BERRY SIZING SPRAYS - SEEDLESS TABLE GRAPEOBJECTIVE/BENEFITFor larger berries and larger clusterswhen used in conjunction withestablished girdling and thinningpractices.

CROP/CULTIVAR

Perlette SeedlessFlame SeedlessThompsonSeedlessRaisinOther SeedlessGrapes

TARGETBERRY

DIAMETER*4-5 mm6-9 mm

3-5 mm3-5 mm

3-14 mm

APPLICATION TIMINGMake one to four applications beginning when theaverage berry size reaches "target" diameter (Seebelow). Timing of the subsequent sprays will bedictated by experience in the vineyard andtemperatures occurring between sprays. Spraysmade after 15-20 days from the first sizing sprayare less effective.

GRAMSA.I./Acre

32 - 12820 - 128

32 - 128

4-20

8-60

GramsProduct/Acre

80-32050-320

80-320

10-50

20- 150

OuncesProduct/Acre

2.9-11.5oz1. 8-11.5 oz

2.8-11.5oz

0.4-1.8oz

0.7- 5.4 oz

Target average berry diameter for the first application.NOTE: In some growing regions and for some cultivars, the higher amounts ofgibberellic acid indicated will reduce fruitfulness (cluster counts) the following year. Atthe high end of the prescribed range of rates and number of applications, a delay in berryskin color development, sugar accumulation and overall maturation has been observed.Consult the Valent representative or local specialist before sizing cultivars with whichthere is no familiarity.

BERRY SIZING CLUSTER DIP - SEEDLESS TABLE GRAPEOBJECTIVE/BENEFIT

To increase berry size.

CROP/ CULTIVAR

Seedless Grapes

APPLICATION TIMINGApply 20 - 50 ppm GA3 solution as a dip or direct spray tothe cluster when berries reach 12-15 mm.

Rate Per 5 Gallons Treatment Solution

PPMAI

20-50

Grams Product

1-2.5

Ounces Product

0.1-0.25Note: To prepare dip solution, add 1 - 2.5 gram ProGibb 40% for every 5 gallons ofsolution needed. Consult the Valent representative or local specialist before sizingcultivars with which there is no familiarity.

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BERRY SIZING SPRAYS - SEEDED TABLE GRAPEOBJECTIVE/BENEFIT

To increase berry size in listedcultivars; and also to reduce berryshrivel in Emperor.

CROP/CULTIVAR

EmperorRed GlobeCalmeriaChristmas RoseRogueQueens

BERRYDIAMETER

(mm)*

12-1612-1812-1612-1612-1612-15

APPLICATION TIMINGMake one application during the indicated berrydiameter range to the entire vine.

Rate

GRAMSA.I./Acre

20

GramsProduct / Acre

50

OuncesProduct /

Acre

1.8

*Predominant average berry diameter for this application.NOTE: Whole vine applications have been known to reduce fruitfulness (cluster counts)the following year. Consult the Valent representative or local specialist before sizingcultivars with which there is no familiarity.

BERRY SIZING CLUSTER DIPS - SEEDED TABLE GRAPEOBJECTIVE/BENEFIT

To increase berry size in listedcultivars; and also to reduce berryshrivel in Emperor.

CROP/CULTIVAR

EmperorRed GlobeCalmeriaChristmas RoseRogueQueens

Other SeededGrapes

BERRYDIAMETER

(mm)*12- 1612- 1812- 1612- 1612-1612- 15

2-3 weeksafter bloom

or whenshatter is

completed

APPLICATION TIMING

Make one 20 - 50 ppm application during theindicted berry diameter range. Make the applicationas a direct spray or dip to the cluster.

Rate Per 5 Gallons Treatment Solution

PPMAI

20-50

Grams Product

1-2.5

Ounces Product

0.1-0.25

^Predominant average berry diameter for this application.NOTE: To prepare a 50 ppm GAS solution, add 1 gram A.I. for every 5 gallons of dipsolution needed. Consult the Valent representative or local specialist before sizingcultivars with which there is no familiarity.

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BERRY SIZING SPRAYS - BLACK CORINTHOBJECTIVE/BENEFIT

To increase berry size.

CROP/ CULTIVAR

Black Corinth (Zante Currant)

APPLICATION TIMINGMake one application 3-5 days after full bloom,but before shatter begins.

GRAMS A.I./Acre

1 - 12

GramsProduct /

Acre2.5-30

OuncesProduct /

Acre0.1 - 1.1

SPRAY GUIDELINES FOR CITRUS

For citrus, apply in sprays of sufficient water volume to ensure thorough fruit wetting. Inmost cases, this application will cause some drop of oldest (most mature) leaves; thisdrop of older leaves is inconsequential. However, application to trees of low vigor orunder stress (pest, nutritional, or water, etc) causes severeleaf and/or fruit drop. Do not apply in white wash sprays in which lime or other causticmaterial has produced a high pH in the spray tank. Applications of copper fungicidesand/or oils within three weeks (before or after) the ProGibb 40% application often resultsin significant leaf drop and fruit drop.

CITRUS: FIELD APPLICATIONS

CITRUS - INCREASE FRUIT SETCROP/

VARIETYOBJECTIVE/

BENEFITUSE RATE / ACRE

APPLICATIONTIMING

NavelOrangeAmbersweetOrange*

*(Not for usein California)

To enhance fruit setand yield.

15 -25 GRAMS A.I

37.5 - 62.5 gramsproduct

1.4-2.3 ouncesproduct

Make a single dilute spraybetween mid Decemberand late January usingsufficient spray volume foradequate coverage of treecanopy

NOTE: Many blocks of Ambersweet and Navel orange in Florida tend to flower very heavily,yet set poor crops. In these blocks, it appears that tree resources are wasted by heavyflowering, compromising the trees' ability to set fruit, support early fruit growth, and carryfruit to harvest. Productivity of heavily blooming blocks is often increased by reducing flowerformation.

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CITRUS - INCREASE FRUIT SETCROP/

VARIETY

ClementineMandarin

TangerinesandMandarinHybrids

(Orlando,Robinson,Minneola,Sunburst, andothers)

(Not for usein California)

Grapefruit


OBJECTIVE/BENEFIT

To increase fruit setand yield

To increase fruit setand yield.

To enhance fruit set,size and yield

USE RATE/ACRE

1 - 40 GRAMS A.I

2.5 - 150 gramsproduct


8 - 30 GRAMS A.I

20 - 75 grams product

0.7 — 2.7 ouncesproduct

8 - 30 GRAMS A.I

20 - 75 grams product

0.7 -2.7 ouncesproduct

APPLICATIONTIMING

Make one to twoapplications from earlybloom up to 4 weeks afterpetal fall. Use a dilutespray with sufficient sprayvolume for adequatecoverage of tree canopy.Typically 1 - 8 grams a.i.is diluted per 100 gallonsspray solution. Allow aminimum of three daysbetween sprays.

Make one to twoapplications during thebloom period. Apply as adilute spray.

Make a single applicationinDecember - January. Applyin125-175 gallons of waterper acre.

.2/S

NOTE: The rate and number of applications depends upon amount of desired fruit set.Generally, more fruit will be set by 2 applications, earlier applications, higher rates, andclimactic conditions more favorable to set. Differential responses to the PGR across citruscultivars also interact with the above factors to affect the degree of fruit set achieved.Reductions in final fruit size are known to occur as a result of excessive fruit set. Increases inmature leaf drop occur in trees under stress.

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CITRUS - REDUCE FRUIT DROP

CROP/VARIETY

Star RubyGrapefruit

(Not for useinCalifornia)

OBJECTIVE/BENEFIT

To reduce early-season smallfruit drop of StarRuby Varietytherebyincreasingyields.

USE RATE / ACRE

25 - 35 GRAMS A.I


2.3 - 3.2 ouncesproduct

APPLICATION TIMING

Make a single diluteapplication during the bloomperiod.

NOTE: Results vary from season to season depending on environmental conditions.Maintain a well-balanced fertilization and watering program.

CITRUS - DELAY RIND AGING

CROP/VARIETY

Navel andother orangecultivars(exceptValencia)

OBJECTIVE/BENEFIT

To delay rindaging, reducephysiologicaldisorders (e.g.,rind staining,water spotting,sticky or tackysurface,oleocellosis),and produce amore orderlyharvesting .pattern

USE RATE /ACRE

16 - 48 GRAMSA.I

40- 120 gramsproduct


APPLICATION TIMING

Make one or two applicationsas a concentrate or dilutespray.

Early application: sprayapproximately 2 weeks priorto color break (typicallyAUG. -NOV.). This timingcauses the greatest delay inrind aging and produces thefirmest rind possible.

AND/OR

Late application: oneapplication after marketablecolor (typically OCT. -DEC.). This late spray hasbeen known to cause re-greening.

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CITRUS - DELAY RIND AGINGCROP/

VARIETY

ValenciaOrange

OBJECTIVE/BENEFIT

To reduce rindcreasing and todelay rind agingand softening

USE RATE /ACRE

40 - 80 GRAMSA.I

100 -300 gramsproduct


APPLICATION TIMING

Make a single application as aconcentrate or dilute spray inAugust to October to targetcrop of young fruit.

NOTE:• Do not apply the early spray to groves that will be harvested early, as fruit

coloring will be delayed. Do not apply from January through July, as productionis often reduced the following year.

• Slower color development is to be expected in the target crop. Increased re-greening of mature fruit has been known to occur. After marketable color isachieved, treatment effects are reduced the longer treated fruit remain on the tree.

TangerineHybrids(Orlando,Robinson,Minneola,Sunburst, andothers)

To delaydisordersassociated withrind aging,puffiness, andsoftening, andto increase peelstrength, oftangerinehybrids

20 - 40 GRAMSA.I



Make one spray applicationtwo weeks prior to colorbreak. Apply as a dilute spray.

NOTE: Do not apply if early harvest is planned. Do not apply after coloring as pre-harvest rind staining and re-greening has been known to occur. Application duringcoloring sometimes causes variation in rind color development.

Grapefruit

(Not for use inCalifornia)

To delaydisordersassociatedwithrind aging(e.g.,puffiness,softening, andorangecoloration),prevent

16-48 GRAMS Make one or two dilute sprayA.I applications in sufficient

volume to ensure coverage. Do40 — 120 grams not exceed 20 ppm a.i. (8

product grams a.i. /100 gallons) inspray solution.

1.4-4.3 ouncesproduct EARLY: Make application two

weeks prior to color break.Apply as a dilute spray (AUG.- SEPT).

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CITRUS - DELAY RIND AGINGCROP/

VARIETYOBJECTIVE/

BENEFITpreharvestdrop ofmature fruit,increase peelstrength,reduce waterloss duringstorage, andproduce amore orderlyharvestingpattern.

USE RATE /ACRE APPLICATION TIMING

AND/OR

LATE: Make application aftermarketable color hasdeveloped (OCT - DEC).

NOTE: Do not spray groves that will be harvested early, as fruit coloring will bedelayed. Treated fruit will re-green if allowed to remain on the tree for extended periods.Do not use concentrate sprays. Results vary from season to season depending onenvironmental conditions. For maximum effect on rind firmest and delay in rind aging,make applications before color change.

Lemon/ Lime To decreaserind aging,yellowing,and theamount ofsmall ripefruit, and toproduce amoredesirableproductionpatternrelative tomarketdemand.

10 - 32 GRAMSA.I

25 - 80 gramsproduct

0.9 -2. 9 ouncesproduct

Make a single applicationwhen target crop is 1/2 to fullsize, but still green.

NOTE: When applied two years in a row, an even larger difference in harvest pattern andmaturity have been known to occur.

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CITRUS - INCREASE JUICE YIELDCROP/

VARIETY

Processingoranges

OBJECTIVE/BENEFIT

To increase juiceextraction yieldin late-harvestedprocessingoranges.

USE RATE /ACRE

20 GRAMS A.I

50 grams product

1.8 ounces product

APPLICATION TIMING

Make a single application atfruit color break in sufficientvolume to ensure completecoverage of the fruits.

SPRAY GUIDELINES FOR TEMPERATE FRUIT CROPS

For temperate fruit crops, apply in sprays of sufficient water volumes to ensure thoroughfruit wetting. Application to plants or trees of low vigor or under stress (pest, nutritional,or water, etc) causes severe leaf and/or fruit drop. Applications of copper fungicidesand/or oils within three weeks (before or after) theProGibb 40% application often results in significant leaf drop and fruit drop.

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TEMPERATE FRUIT CROPS: FIELD APPLICATIONS

TEMPERATE FRUIT CROPS - FRUITSET

CROP/VARIETY

HighbushBlueberry :

Coville, Jersey,Stanley,Earliblue,Weymouth,Walcott,Berkeley,Blueray,Bluecrop,1316A,Concord, andothers


RabbiteyeBlueberry:

Aliceblue,Beckyblue,Bonita,Brightwell,Climax, Delite,Tiftblue,Woodward andothers.


OBJECTIVE/BENEFIT

To improve fruitset.

To improve fruitset.

USE RATE/ACRE

40 - 80 GRAMSA.I


3.6 — 7.2 ouncesproduct

40 - 80 GRAMSA.I



APPLICATION TIMING

Make a single application of80 grams a.i. per acre in 40 to100 gallons of water. Theapplication should be made atfull bloom (when 75% of theflowers are fully open).

OR

Make two applications of 40grams a.i. per acre in 40 to100 gallons of water. Makethe first application at fullbloom, and the secondapplication within 10-14 daysof the first spray.

For Weymouth, applicationcan be delayed up to twoweeks after bloom to increasesize of "shot" berries.

Make a single application of40 to 80 grams a.i. in 40 -to-100 gallons of water per acrewhen most of the flowers areelongated but not yet open(Bloom Stage 5).

OR

Make two to four applications10-to-14 days apart starting atbloom Stage 5. Spray 20 to 40grams in 40 to 100 gallons ofwater per acre per application.

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TEMPERATE FRUIT CROPS - FRUITSET

CROP/VARIETY

Melon


OBJECTIVE/BENEFIT

To stimulate fruitset during periodsof cooltemperatures

USE RATE/ACRE

1 - 4 GRAMS A.I

2.5-10 gramsproduct


APPLICATION TIMING

Make application just prior tobloom. For cantaloupes andwatermelons two additionalapplications should be madeat intervals of 10-to-14 days.

NOTE:• For maximum benefits, vines must be in good condition, except for reduced rate ofgrowth due to cool temperatures.

TEMPERATE FRUIT CROPS - SPUR FORMATIONCROP/

VARIETY

Sour Cherry


OBJECTIVE/BENEFIT

To maintain andextend high fruitingcapacity of sourcherry trees bypromoting spurformation andreducing theoccurrence of"blind" nodes. Spurformation isapparent the yearafter application.Therefore, changesin shoot, spur, andflower productionwill not be evidentuntil two or threeyears after programinitiation.

USE RATE/ACRE

4 - 18 GRAMSA.I

1 0 - 45 gramsproduct

0.4- 1.6 ouncesproduct

APPLICATION TIMING

Apply one spray 14-to-28days after bloom. Optimumtiming is defined as that stagewhen 3-to-5 terminal leaveshave fully expanded, or, atleast l-to-3 inches of terminalshoot extension has occurred.Use 4 — 1 8 grams a.i. per acre,depending on tree age andvigor (See Table below).Apply as a dilute spray insufficient water to ensurethorough wetting, or as aconcentrate spray ensuringuniform coverage.

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NOTE:• Applications must be applied annually to ensure spur development and

subsequent yield improvement year after year.

• Rates are based on expected normal tree vigor at various ages. Adjust rateaccording to tree vigor. If trees are vigorous, use lowest recommended rates.Lowest rates should also be used on trees that have been heavily pruned orhedged. Use higher rates for trees low in vigor and weak in shoot and spurproduction. Excessive application rates will increase vegetative growth at theexpense of fruit production the following year.

• Applications will not improve growth of trees under stress conditions, such asnutritional, moisture, or pest. Best results will be obtained when combined withgood cultural practices.

APPLICATION RATES FOR SOUR CHERRY TREES BY AGE

TREE AGE(YEARS)

6-1011-1516-20

20 + years

GRAMSA.I./ACRE

4 - 68-1010-1414-18

GRAMSPRODUCT/ ACRE

10-1520-2525-3535-45

OUNCESPRODUCT/ ACRE

0.4-0.50.7-0.90.9-1.31.3-1.6

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TEMPERATE FRUIT CROPS - FRUIT QUALITYCROP/

VARIETYOBJECTIVE/

BENEFITUSE RATE/

ACREAPPLICATION TIMING

Sweet Cherry To produce larger,brighter colored,firmer fruit.

16 - 48 GRAMSA.I



Apply a single spray whenthe fruit is translucent greento straw colored. Usesufficient water volume toensure thorough wetting.

Sweet Cherryin cultivarswith unevenmaturity


To produce larger,brighter colored,firmer fruit

16 - 48 GRAMSA.I



Make 2 applications. Apply1/3 to 1/2 of the totaldesired amount when themajority of the fruit istranslucent green, Apply theremaining material3-7 days later, when themajority of the fruit is strawcolored.

NOTE:• Color development and harvest date is often slightly delayed.• Use higher rates with heavier crop loads.

Stone FruitGroup

To increase fruitfirmness andimprove fruitquality in theseason ofapplication

16 - 32 GRAMSA.I


IA-2.9 ouncesproduct

Apply as a single spray oneto 4 weeks prior to thebeginning of the harvestperiod. Use sufficient waterto achieve completecoverage of fruits andfoliage.

NOTE:• This application has been known to cause reduction in flower counts the year

following the application, particularly if it is made during the months of Maythrough July.

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TEMPERATE FRUIT CROPS - FRUIT QUALITYCROP/

VARIETY

Stone Fruit:Italian Prune


OBJECTIVE/BENEFIT

To reduce internalbrowning,improve quality,and increase size.

USE RATE/ACRE

16-48 GRAMSA.I



APPLICATION TIMING

Make a single applicationfour to five weeks beforeexpected harvest. Apply insufficient water volume toensure thorough wetting.

NOTE:• Color development and harvest may be slightly delayed. May reduce bloom the

following season.

TEMPERATE FRUIT CROPS - NON BEARING USESCROP/

VARIETYPecan

OBJECTIVE/BENEFIT

To extend leafretention andenhanced thecanopy duringlate season inpecan;maintaining greenfoliage later in theseason willimprove returnbloom and fruitset in nextseason's crop.

USE RATE/ACRE

10 GRAMS A.I

25 g rams product

APPLICATION TIMING

Make four applications attwo week intervalsbeginning in late Augustand continuing until mid-October.Apply in 50-100 gals, totalvolume per acre.

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TEMPERATE FRUIT CROPS - NON BEARING USESCROP/

VARIETY

Non BearingStone Fruit


Non BearingBlueberry


OBJECTIVE/BENEFIT

To reduceflowering andfruiting in youngstone fruit trees inorder to minimizethe competitiveeffect of earlyfruiting on treedevelopment.

To reduceflowering andfruiting in youngblueberry plants inorder to minimizethe competitiveeffect of earlyfruiting on plantdevelopment.

USE RATE/ACRE

20 - 80 GRAMSA.I



20 - 80 GRAMSA.I



APPLICATION TIMING

Make a single applicationduring the period of flowerbud initiation for thefollowing year. Usesufficient water to achievegood coverage of thecanopy.

Make one to fourapplications during theperiod of flower budinitiation for the followingyear. Use sufficient water toachieve good coverage ofthe canopy.

NOTE:Do not spray plants/trees in their first year. Treat in the second season for reduction offlowering in the third season, and again in the third season if flower reduction andfruiting is desired in the fourth season. Treat only plants/trees that are in goodphysiological condition. Discontinue treatment the year before desired harvest. Consultwith the Valent representative or local horticulturist for timings and rates for specificcultivars in your area.

Strawberry


To increase runnerproduction ofmother plants.

15 - 25 GRAMSA.I



Make a single application tomother plants 10 — 30 daysafter planting. Plants shouldhave 1-6 leaves at spraying.Apply 100 gallonsspray /acre to point of run-off.

NOTE:Not for use on fruiting plants. Treatments have not always been effective on plantings setout after mid-May. Response varies with cultivar and location. Consult your Valentrepresentative or local horticulturist for specific recommendations.

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SPRAY GUIDELINES FOR TROPICAL FRUIT CROPS

TROPICAL FRUIT CROPS - FIELD USES

CROP/VARIETY

OBJECTIVE/BENEFIT

USE RATE /ACRE

APPLICATION TIMING

Pineapple(Not for usein California)

To improve fruitsize.

125-250 GRAMSA.I.

312.5 -625 gramsproduct


Apply after flowering. Make 2applications at 3-5 weeksintervals. Direct sprays to thefruit. Use sufficient water toachieve adequate coverage.

To improveuniformity of fruitmaturity andenhance harvestefficiency.

12-24 Grams a.i..

30-60 gramsproduct


Make the first application a fewdays after planting when plantsare established. Repeatapplications at 3-4 weeksintervals.

To maintain thequality of thecrown (greenness,turgidity), delaydesiccation,discoloration, andbrowing, andimprove overallappearance duringtransit, storageand shelf life.

Apply at the rate of250 - 500 ppm as aspray directed tothe crown

Apply after harvest and priorto packing. Make sure allleaves are thoroughly coveredwith the spray withoutexcessive runoff.

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TROPICAL FRUIT CROPS - FIELD USESCROP/

VARIETYOBJECTIVE/

BENEFITUSE RATE /

ACRE APPLICATION TIMING

Coffee(Not for usein California)

To induce flowerbud break fromlatent dormancyinto developingflowers andcherry set

10 to 40 Grams A.I.

25 to 100 gramsproduct

0.9 - 3.6 oz product

Applied in sufficient watervolume to assure totalcoverage of developing budsalong all laterals (arrangenozzles for coverage frombottom up as well as topdown of laterals and leaves)Multiple applications at 3 to7 day frequency may berequired over a period of 10to 14 daysUse a non-ionic surfactant at0.05% v/v.

TROPICAL CROPS - FIELD USESCROP/

VARIETYSugarcane(Not foruse inCalifornia)

OBJECTIVE/BENEFIT

To maintain yieldsin older plantings,increase bio-massand stimulategrowth beforeharvest of cane inolder productionfields (>3 years)

USE RATE /ACRE

1.0-2.0 Grams a.i.2.5 - 5 Grams

product

0.1 -0.2 oz product

APPLICATION TIMING

Apply at 1st to 5th internodestage to ratoon crop in at least20 gal/A. Addition of non-ionic surfactant may increaseactivity

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CROP/Variety

Banana

(Not foruse inCalifornia)

OBJECTIVE /BENEFIT

ESTABLISHEDPLANTINGS;To stimulate plantgrowth and toreduce the effectsof stresses causedby insect, disease oradverse weather.These applicationsmay help improvefruit size, qualityand overall yields.

NEWPLANTINGS:To stimulate earlygrowth in newplantings, increaseplant vigor and

DOSE RATE

AERIAL FOLIARSPRAY:Apply 6 to 20 grams a.i.per acre per spray.

GROUND FOLIARSPRAY:Apply 6 to 20 grams a.i.per acre per spray..

FOLIAR PLANTSPRAYS:Add 1 gram a.i. pergallon of waterequivalent.

APPLICATIONTIMING

Make applications at 1to 3 weeks frequencythroughout the year.Use higher dose ratesand shorter sprayfrequency prior to andduring the periods ofintense stress. Usesufficient water volumeto achieve adequatecanopy coverage. Tankmixing with thestandard pesticidetreatments applied byair is permissible.

Direct applications todeveloping daughterplants and pre-bloomedmother plants. Makeapplications every 1 to3 weeks throughout theyear as needed. Usehigher dose rates andshorter spray frequencyduring periods ofintense stress. Usesufficient water volumeto achieve adequatecanopy coverage Tankmixing with standardpesticides ispermissible.

Make 2 to 3 foliarapplications, beginningwith the 1st applicationtiming at 3-5 weeksafter planting, followedby a 2nd and 3rd

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acceleratedevelopment toflowering.

BUNCH SPRAYS:To stimulate bunchfruit development,improving fruit sizeand quality andoverall yields.

FOLIAR BUNCHSPRAY:Add 1 to 2 grams a.i. pergallon of water.

PSEUDOSTEMINJECTIONS:Add 2.0 to 5.0 grams a.i.per gallon of water.

application at 2 to 3week frequency. Usesufficient spray watervolume to achieveadequate canopycoverage.

Make applicationsimmediately after floralbunch emergence whenhands and fingers areexposed through bunchbagging program. Usesufficient water volumeto achieve adequatecanopy coverage Tankmixing with standardpesticides ispermissible. Add NP-7surfactant at 0.05% v/vto enhance coverageand uptake.

Utilize a 5 ml volumeper injection. Make 2 to4 injections from the14th through 23 trueleaves stage of plantgrowth. Make the firstinjection beginning atthe 14th to 15th trueleaves measured fromthe 10th Filiform leafdevelopment

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CROP/CULTIVAR

Plantain

(Not for usein California

OBJECTIVE /BENEFIT

ESTABLISHEDPLANTINGS:To stimulate plantgrowth and toreduce the effectsof stresses causedby insect, diseaseor adverseweather. Theseapplications mayhelp improve fruitsize, quality andoverall yields.

NEWPLANTINGS:To stimulate earlygrowth in newplantings,increase plantvigor andacceleratedevelopment toflowering.

DOSE RATE

GROUND FOLIARSPRAY:Apply 6 to 20 grams a.i.per acre per spray..

FOLIAR PLANTSPRAYS:Add 1 gram a.i. pergallon of waterequivalent.

APPLICATIONTIMING

Direct applications todeveloping daughterplants and pre-bloomedmother plants. Makeapplications every 1 to3 weeks throughout theyear as needed. Usehigher dose rates andshorter spray frequencyduring periods ofintense stress. Usesufficient water volumeto achieve adequatecanopy coverage Tankmixing with standardpesticides ispermissible.

Make 2 to 3 foliarapplications, beginningwith the 1st applicationtiming at 3-5 weeksafter planting, followedby a 2nd and 3rd

application at 2 to 3week frequency. Usesufficient spray watervolume to achieveadequate canopycoverage.

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SPRAY GUIDELINES FOR VEGETABLE CROPS

For vegetable crops, apply in sprays of sufficient water volumes to ensure thorough fruitwetting. Foliage of treated plants occasionally and temporarily appears lighter green incolor due to accelerated growth rates following application. Application to plants of lowvigor or under stress (pest, nutritional, or water, etc) causes severe leaf yellowing, poorperformance and/ or undesirable effects. Tank-mixing with surfactants, fertilizers, and/orother pesticides should not be done unless compatibility and phytotoxicity testing is donefirst using appropriate methods.

VEGETABLE CROPSCROP/

VARIETY

Artichoke

Carrots

Fresh andProcessing

OBJECTIVE/BENEFIT

To acceleratematurity and shiftharvest to anearlier date

To delay leafsenescence.

Maintainingvigorous foliagehas been shownto help reduce theincidence ofinfection byAlternaria dauci.

USE RATE/ACRE

10 -20 GRAMSA.I



1 - 6 GRAMS A.I

2.5-15 gramsproduct


APPLICATION TIMING

For perennials: apply one tothree applications at budinitiation stage.

For annuals: apply one to fourapplications at 2-week intervals,beginning at the fourth true leaf.

Use sufficient water volume toensure thorough wetting of theentire plant (leaves, stems andbuds).

Make the first application 4 -6weeks after emergence usingcommercial ground or aerialequipment with sprayconcentrations of 20-30 ppm. Insevere disease situations or coolweather a second spray 14 dayslater is sometimes required toachieve the desired amount offoliar recovery. Do not applymore than twice per crop.

NOTE: • Dilutions of greater concentration can increase the risk of excessive top growth,particularly with a second application.

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VARIETY

Celery

OBJECTIVE/BENEFIT

To increase plantheight and yieldand to overcomestress due to coldweatherconditions orsaline soils, andobtain earliermaturity.

USE RATE/ACRE

2.5 - 10 GRAMSA.I



APPLICATION TIMING

Make a single application one tofour weeks prior to harvest. Use25-to-50 gallons of water peracre by ground application or 5-to-10 gallons of water per acrefor aerial application (except inCalifornia). Use lowerconcentrations if applying 3-to-4 weeks before harvest andhigher concentrations within 1-to-2 weeks before harvest.

NOTE: Do not apply by air in California. Do not apply earlier than 4 weeks beforeharvest as bolting has been known to occur.

Cucumber


To stimulate fruitset during periodsof cooltemperatures.

1 - 4 GRAMS A.I

2.5 — 10 gramsproduct


Make one application prior tobloom followed by twoadditional applications atintervals of 10-to-14 days. It isacceptable to use up to fourapplications. Use sufficientwater volume for thoroughcoverage of exposed foliage.

NOTE: For maximum benefits, vines must be in good condition, except for reduced rateof growth due to cool temperatures.

Lettuce forSeed

Pepper


To obtainuniform boltingand increase seedproduction

To increase fruitset and promoteearly season fruitgrowth

1 - 4 GRAMS A.I

2.5-10 gramsproduct


1 - 3 GRAMS A.I



Apply one to four applicationsat two-week intervals,beginning at the fourth true leaf.Use sufficient water volume toensure thorough wetting.

Apply one to two sprays of 25to 50 gallons per acre at weeklyintervals during the floweringperiod.

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5//S3


VARIETYOBJECTIVE/

BENEFITUSE RATE/

ACREAPPLICATION TIMING

NOTE: This use is best for areas with short growing seasons, or when low temperaturesslow plant growth. The high rate is most efficacious for areas and/or varieties with

_r_>ollination and/or fruit set problems.

Pepper


To increase fruitsize and yield

NOTE: The high rate is best for

Rhubarb To breakdormancy onplants receivinginsufficientchilling and toincrease market-able yield offorced rhubarb.

1 - 3 GRAMS A.I



Apply in 25-to-50 gallons ofwater per acre at the beginningof the picking period.

plants with heavy fruit loads.

10 - 20 GRAMSA.I


0.9- 1.8 ouncesproduct

1) When the rest period is notcompletely broken, make asingle application of 2 fluidounces (60 ml) of a solutioncontaining 20 grams a.i. in 10gallons of water to each cleanedcrown.

2) When the rest period isbroken by cold weather, apply 2fluid ounces (60 ml) of asolution containing 1 0 gramsa.i. in 10 gallons of water toeach cleaned crown.

NOTE: • Keep forcing house temperatures at 40 - 50F for 24 hours after application. Ifhouse is warmer than 50F, cover crowns with plastic. Temperatures above 50F loweryields and cause poor stalk color.

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VARIETY

Spinach,Mustardgreens,Collardgreens andTurnipgreens.


OBJECTIVE/BENEFIT

To facilitateharvest, increaseyield andimprove qualityof fall and over-winter crops.

USE RATE/ACRE

4 - 10 GRAMS A.I

10-25 gramsproduct


APPLICATION TIMING

Apply a single spray 10-to-18days before each anticipatedharvest on fall or over-wintercrops, ideally when daytimetemperatures are 40° F-to-70° Fand during early morning hourswhen dew is present on crop.

When applied to promotegrowth of second cutting, waituntil some regrowth has startedbefore spraying.

Maximum benefit is obtainedwhen below normaltemperatures prevail followingapplication and growth wouldbe otherwise slowed inuntreated crops.

NOTE: • Since the promotion of bolting has been known to occur, do not apply after themid-winter period or if temperatures are expected to exceed 75 F within several days ofapplication. Do not apply on spring plantings.

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TEMPERATE FIELD CROPS - SEED TREATMENTCROP/

VARIETY

Rice (semi-dwarf andtall varieties)

OBJECTIVE/BENEFIT

To promotegermination,emergence andstand uniformity.

USE RATE / 100 LBSEED

0.5 -2.1 GRAMSA.I



APPLICATION TIMING

For every 100 Ibs rice seedto be treated, mix thedesired amount of productinto 8 — 20 fl ounces ofwater to form treatmentsolution.

Note:• Do not apply product prior to a 24 hour presoak or to water used for the presoak.• Do not exceed 2.1 grams a.i./lOO Ibs of seed

CROP/VARIETY

Rice

OBJECTIVE/BENEFIT

To promote earlyseason plant vigorand more uniformseedling growthprior topermanent floodestablishment.

USE RATE/ACRE

1-3 GRAMS A.I

2.5 — 7.5 gramsproduct


APPLICATION TIMING

Make one to two applicationsat the 1-2 and/or 4-5 leafstages of growth.

TEMPERATE FIELD CROPS - FIELD USES

NOTE:Early flooding reduces the additional flushing costs associated with a delay inestablishing the permanent flood, reduce weed infestations and the number ofherbicide applications, and/or promote earlier and more uniform grain maturity.Do not apply prior to the 2-to-3 leaf stage if gibberellin seed treatment is used.Timing and dosage are to be based upon environmental conditions, tank mixcombinations with herbicides, and preferred permanent flood practice in relationto rice leaf stage.Do not apply when rice is subjected to drought stress conditions.

Rice(Not for usein California)

To promote mainculm and tillerpanicle extensionresulting inimproved

3 - 8 GRAMS A.I

7.5-20 gramsproduct

Make a single applicationbetween split-boot and 100%panicle heading.

Heading applications to the

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f

Rice (HybridSeedProduction)(Not for usein California)

Cotton

Dry Bean

pollination andseed yield.

To promote mainculm and tillerpanicle extensionresulting inimprovedpollination andseed yield.

Promote earlyseason growthand increaseseedling vigor.

Promotes earlyseason growth,increasedseedling vigor,and increasedplant heightallowing forimprovedharvestingefficiency.


20-100 GRAMSA.I



1 - 6 GRAMS A.I

2.5-15 gramsproduct

0.1 -0.5 ouncesproducts

1 - 6 GRAMS A.I


0.1 - 0.5 ouncesproducts

first crop also has beenobserved to accelerate re-growth of second crop rice.

Make 1-5 applications atregular intervals during theheading period to promotemain culm and tiller panicleextension.

Apply 1 - 2 applications as afoliar broadcast spray duringthe 3 to 7 leaf/node stage. Ifapplying as a banded sprayreduce rates accordingly.Complete coverage of leaftissue is essential.

Use higher rates whentemperatures will likelyaverage 75°F or less duringthe 14 days followingapplication(s).

Apply 1-2 applications as afoliar broadcast spray duringthe 3 to 7 leaf/node stage. Ifapplying as a banded sprayreduce rates accordingly.Complete coverage of leaftissue is essential.

Use higher rates whentemperatures will likelyaverage 75°F or less duringthe 14 days followingapplication(s).

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NOTE:Do not apply plants that are under drought stress. If plants are under continuousstress, delay the application until the stress is alleviated and the plants arebeginning to recover.Applying more often than necessary to achieve the desired height results inexcessive vegetative growth.Avoid drift or accidental application to other crops.

Hops

Seeded andseedlessFuggle hopsand similarvarietiesadapted tothe North-westernstates.

To increase fruitset and yield.

4 - 6 GRAMS A.I

10-15 gramsproduct


Make a single application in100-150 gallons of water peracre when vine growth is 5-8feet in length.

Note: Do not apply RyzUp to plants that are under drought stress. Applications duringstem elongation may increase lodging. Avoid drift or accidental application to othercrops.

Wheat seedtreatment (Not forUse in California)

To promotegermination,emergence, andplant establishment,particularly for seedwith dormancyproblems that areplanted under coolsoil conditions.

0.1 -0.27 oz productin 8-20 fl oz water /lOOlbseed.(1.0 to 3.0 grams a.i.or 2.5-7.5 gramsproduct in 23 7-5 91ml / 45 kg seed.

Do not exceed 0.27oz. Product 7100 Ibseed.

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SPRAY GUIDELINES FOR WATERCRESS:

WatercressCROP/

VARIETY

Watercress

OBJECTIVE/BENEFIT

1) To enhancegrowth in adverseweatherconditions;

2) To help plantsresume growthafter insect anddisease attacks;

3) To increaseroot free stemlength during lowlight/short dayconditions.

USE RATE/ACRE

15 -25 GRAMSA.I

37.5 -62.5 gramsproduct


APPLICATION TIMING

Make one or two applicationsper acre per crop 3 to 7 daysbefore harvest. Use 50-100gallons of water per acre.

PROGIBB 40% CONVERSIONS

ProGibb 40% contains 1.0 gram of active ingredient per 2.5 grams (0.09 oz) of product.

To convert from Grams AI to Grams Product - Multiply grams AI x 2.5(i.e. 32 g a.i. x 2.5 = 80g ProGibb 40%)

To convert from Grams AI to Dry Ounces Product - Multiply grams AI x 0.09(i.e. 32 g a.i. x 0.09 = 2.9 oz ProGibb 40%)

ProGibb 40%05-12-11

Page 3 5 of 52

CONVERSION TABLE (for the 320 g size)

Grams of ActiveIngredient

245681015203040506080100128

Grams of ProGibb 40%

510

12.5152025

37.55075100125150200250320

Ounces of ProGibb40%0.20.40.50.60.70.91.41.82.73.64.55.47.29.011.5

Grams of ProGibb 40% WSG for given ppm's of Gibberellic Acid at DifferentWater Volumes.

Gallonsof

Water75100125150200250300400500600750

Desired parts

4

1.522.53455.57.59.51114

5

34568101115192328

6

4.567.5911141723283443

8

6891115192330384557

jer million (ppm) gibberellic acid

10

7.510121419242838475771

15

11141821283543577185106

20

141924283847577695113142

30

21283543577185113142170213

40

283847577695113151189227284

50

3547597195118142189236284

Note: The numbers inside the table are the grams of ProGibb 40% WSG needed to obtain thedesired ppm's for each gallonage.

Example:To make 250 gallons of a 40 ppm gibberellic acid solution, dissolve 95 grams of ProGibb 40%WSG in 250 gallons of water (see shaded area).

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CONVERSION TABLE (for the 80 g size)ProGibb 40% contains approximately 10 grams of active ingredient per 25 grams ofproduct.


245681015203040506080


510

12.5152025

37.55075100125150200

Ounces of ProGibb40%0.20.40.50.60.70.91.41.82.73.64.55.47.2

(Alternate for 80 g packaging)

Gallonsof

Water75100125150200

parts per million (p4

3.04.05.06.08/0

5

3.85.06.37.510.0

6

4.56.07.59.012.0

8

6.08.010.012.016.0

10

7.510.012.515.020.0

pm) gibberellic acid15

11.315.018.822.530.0

20

15.020.025.030.040.0

30

22.530.037.545.060.0

40

30.040.050.060.080.0

50

38506375

Note: The numbers inside the table are the grams of ProGibb 40% WSG needed to obtain thedesired ppm's for each gallonage.

Example:To make 200 gallons of a 40 ppm gibberellic acid solution, dissolve 80 grams of ProGibb 40%WSG in 200 gallons of water (see shaded area).

DIRECTIONS FOR CHEMIGATIONFill the supply tank with the desired amount of water. Then add the amount of ProGibb40% required in order to achieve the final solution rate recommended for the specificcrop to be treated. Agitate the mixture of ProGibb 4% frequently during the chemigationperiod to assure a uniform distribution throughout the system.Apply ProGibb 4% continuously for the duration of the water application but do notexceed recommended rates and volumes as outlined on the product label.

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CHEMIGATION PRECAUTIONSApply this product only through the following systems: Overhead sprinklers such asimpact, micro-sprinklers, or booms. Do not apply this product through any other type ofirrigation system. Crop injury or lack of effectiveness can result from nonuniformdistribution of treated water. If you have any questions about calibration, you shouldcontact State Extension Service specialists, equipment manufacturers or other experts. Donot connect an irrigation system (including greenhouse systems) used for pesticideapplication to a public water system unless the pesticide label prescribed safety devicesfor public water systems are in place. A person knowledgeable of the chemigation systemand responsible for its operation or under the supervision of the responsible person, shallshut the system down and make necessary adjustments should the need arise. Prior toapplication ensure that the chemigation system meets the following requirements:

• The system must contain a functional check valve, vacuum relief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent watersource contamination from backflow.

• The pesticide injection pipeline must contain a functional, automatic, quickclosing check valve to prevent the flow of fluid back toward the injection pump.

• The pesticide injection pipeline must also contain a functional, normally closed,solenoid-operated valve located on the intake side of the injection pump andconnected to the system interlock to prevent fluid from being withdrawn from thesupply tank when the irrigation system is either automatically or manually shutdown.

• The system must contain functional interlocking controls to automatically shut offthe pesticide injection pump when the water pump motor stops.

• The irrigation line or water pump must include a functional pressure switch,which will stop the water pump motor when the water pressure decreases to thepoint where pesticide distribution is adversely affected.

• Systems must use a metering pump, such as a positive displacement injectionpump (e.g. diaphragm pump) effectively designed and constructed of materialsthat are compatible with pesticides and capable of being fitted with a systeminterlock.

In addition to the above use rates and recommendations, the following precautions mustbe observed when using this product in any type of irrigation system.

CHEMIGATION SYSTEMS CONNECTED TO PUBLIC WATER SYSTEMSPublic water system means a system for the provision to the public of piped water forhuman consumption if such system has at least 15 service connections or regularly servesan average of at least 25 individuals daily at least 60 days of the year. Chemigationsystems connected to public water systems must contain a functional, reduced pressure

ProGibb40% Page 38 of 5205-12-11

(

zone, backflow preventer (RPZ) or the functional equivalent in the water supply lineupstream from the point of pesticide introduction. As an option to the RPZ, the waterfrom the public water systems should be discharged into a reservoir tank prior topesticide introduction. There shall be a complete physical break (air gap) between theoutlet end of the fill pipe and the top or overflow rim of the reservoir tank of at leasttwice the inside diameter of the fill pipe. The pesticide injection pipeline must contain afunctional, automatic, quick closing check valve to prevent the flow of fluid back towardthe injection pump. The pesticide injection pipeline must also contain a functional,normally closed, solenoid-operated valve located on the intake side of the injection pumpand connected to the system interlock to prevent fluid from being withdrawn from thesupply tank when the irrigation system is either automatically or manually shut down.The system must contain functional interlocking controls to automatically shut off thepesticide injection pump when the water pump motor stops, or in cases where there is nowater pump, when the water pressure decreases to the point where the pesticidedistribution is adversely affected.

Systems must use a metering pump, such as a positive displacement injection pump (e.g.diaphragm pump) effectively designed and constructed of materials that are compatiblewith pesticides and capable of being fitted with a system interlock.

ProGibb 40% Page 39 of 5205-12-11

STORAGE AND DISPOSALDo not contaminate water, food or feed by storage or disposal.

Pesticide StorageKeep containers tightly closed when not in use.

Pesticide DisposalWastes resulting from the use of this product must be disposed of on site or at anapproved waste disposal facility.

Container Disposal: ( 80 or 320 g bottles)Nonrefillable container. Do not reuse or refill this container. Triple rinse (or equivalent)promptly after emptying. Triple rinse as follows: Empty remaining contents intoapplication equipment or mix tank. Fill container % full with water and recap. Shake 10seconds. Pour rinsate into application equipment or mix tank or store rinsate for later useor disposal. Drain for 10 seconds after flow begins to drip. Repeat this procedure twomore times. Then offer for recycling or dispose of in a sanitary landfill, or incineration,if allowed by state and local authorities by burning. If burned, stay out of smoke.

(2.5 g sachets)Nonrefillable container. Do not reuse or refill this container. Offer for reconditioning ifappropriate or dispose of in a sanitary landfill, or incineration, if allowed by state andlocal authorities by burning. If burned, stay out of smoke.

Warranty and Disclaimer Statement:To the fullest extent permitted by law, seller makes no warranty, express or implied, ofmerchantability, fitness or otherwise concerning use of this product other than asindicated on the label. User assumes all risks of use, storage or handling not in strictaccordance with accompanying directions.

@2011

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SUB-LABEL II

RyzUp Smartgrass™PLANT GROWTH REGULATOR

Water Soluble Granule

For agricultural use on Pastures, Wheat, Barley and Oats,and commercial use on Sod and Turf.

ProGibb40% Page 41 of 5205-12-11.

f r

RyzUp Smartgrass™Plant Growth RegulatorWater Soluble Granule





CAUTION

See inside booklet for Precautionary Statements.


Valent BioSciences Corporation870 Technology Way, Suite 100Libertyville, IL 600481-847-968-4700

Net Contents: 320 g Lot No.:

This container will treat acre at the maximum use rate, as directed for use on

FIRST AIDIf in eyes

If on skin or clothing

• Hold eye open and rinse slowly and gently with water for 15-20minutes.

• Remove contact lenses, if present, after the first 5 minutes, thencontinue rinsing eye.

• Call a poison control center or doctor for treatment advice.• Take off contaminated clothing.• Rinse skin immediately with plenty of water for 15-20 minutes.• Call a poison control center or doctor for treatment advice.

HOT LINE NUMBERHave the product container or label with you when calling a poison control center or doctor, or goingfor treatment. You may also call toll-free 1-800-892-0099 (24 hours) for emergency medical treatmentand/or transport emergency information. For all other information, call 1-800-6-Valent.

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PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS & DOMESTIC ANIMALS

Caution: Causes moderate eye irritation. Harmful if absorbed through skin. Avoidcontact with skin, eyes or clothing. Wash thoroughly with soap and water afterhandling. Remove and wash contaminated clothing before reuse.

Personal Protective Equipment (PPE)Applicators and other handlers must wear:

• Long-sleeved shirt and long pants.• Waterproof gloves.• Shoes plus socks.

Follow the manufacturer's instructions for cleaning/maintaining PPE. If no suchinstructions for washables, use detergent and hot water. Keep and wash PPE separatelyfrom other laundry.

User Safety Recommendations

Users should:• Wash hands before eating, drinking, chewing gum, using tobacco or using the

toilet• Remove clothing/PPE immediately if pesticide gets inside. Then wash

thoroughly and put on clean clothing.• Remove PPE immediately after handling this product. Wash the outside of

gloves before removing. As soon as possible, wash thoroughly and changeinto clean clothing.

ENVIRONMENTAL HAZARDSFor terrestrial uses: Do not apply directly to water, or to areas where surface water ispresent or to intertidal areas below the mean high water mark. Do not contaminate waterwhen cleaning or disposing of equipment washwaters or rinsate.Do not use treated seed for food, feed, or oil purposes. Exposed treated seed may behazardous to birds and other wildlife. Treat only those seeds needed for immediate useand planting. Do not store excess treated seed beyond planting time. Dispose of allexcess treated seed and seed packaging by burial away from bodies of water.

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DIRECTIONS FOR USEIt is a violation of Federal law to use this product in a manner inconsistent with itslabeling. Do not apply this product in a way that will contact workers or other persons,either directly or through drift. Only protected handlers may be in the area duringapplication. For any requirements specific to your State or Tribe, consult the State orTribe agency responsible for pesticide regulation.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worker ProtectionStandard, 40 CFR Part 170. This Standard contains requirements for the protection ofagricultural workers on farms, forests, nurseries, and greenhouses, and handlers ofagricultural pesticides. It contains requirements for training, decontamination, notification,and emergency assistance. It also contains specific instructions and exceptions pertaining tothe statements on this label about personal protective equipment (PPE), and restricted-entryinterval. The requirements in this box only apply to uses of this product that are covered bythe Worker Protection Standard.

Do not enter or allow worker entry into treated areas during the restricted entry interval(REI) of 4 hours unless wearing appropriate PPE.

PPE required for early entry to treated areas that is permitted under the Worker ProtectionStandard and that involves contact with anything that has beentreated, such as plants, soil, or water is:

• Coveralls.• Waterproof gloves.• Shoes plus socks.


( (

GENERAL DIRECTIONS FOR USE

Use only as directed. Read the label thoroughly and make sure it is understood beforemaking applications. Keep out of reach of children.

Application Instructions:

• Ryzup Smartgrass water soluble granule contains gibberellic acid which is an extremelypotent plant growth regulator; when applying plant growth regulators, deviations from thelabel directions in the rates, timings, water volumes, or the adoption of untested spraymixes, results in undesirable effects. Always consult the local Valent representative inyour area for the spray regimen best suited to your conditions.

• Do not apply to plants under pest, nutritional, or water stress.

• When a range of rates is indicated, use the concentration and spray volume indicatedlocally by the local Valent representative.

• For optimum effectiveness, thorough spray coverage of the target area must beachieved. Prepare solution concentrations by mixing the required amount of product withwater in a clean, empty spray tank. Discard any unused spray material at the end of eachday following local, state or federal law.

• For most efficacious results, the water pH is best at 7.0, and always below 8.5.

• Applications made under slow drying conditions (cool to warm temperatures, mediumto high relative humidity, and no wind) will increase absorption of the active ingredientby the plant, thus optimizing effectiveness. Night-time applications are encouraged whenday-time conditions are not conducive to slow drying conditions.

• Product persistence: Re-apply if significant rain occurs within 2 hours of application.

• Compatibility: When considering tank mixing with other products, use the followingcompatibility jar test before mixing a whole tank.

Start with a clear glass or plastic quart jar. Add water from the same water source thatwill be used for the larger tank mix. Add the pesticides in correct proportions. Mixthoroughly and let stand for a minimum 15 minutes. Heat, separation, gelling, are allsigns of incompatibility. Before using any mixes that pass the jar tests for compatibility,it is imperative to test the mixture on a designated area as it may result either inphytotoxicity or ineffectiveness. For further information, consult your local Valentrepresentative.

• For aerial applications spray volumes must be greater than 2 gallons per acre (10gallons per acre for tree crops).

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1 No preharvest interval is required for this product.

SPRAY GUIDELINES

Apply in sprays of sufficient water volumes to ensure thorough wetting. Foliage oftreated plants occasionally and temporarily appears lighter green in color due toaccelerated growth rates following application. Application to plants of low vigor orunder stress (pest, nutritional, or water, etc) causes severe leaf yellowing, poorperformance and/ or undesirable effects. Tank-mixing with surfactants, fertilizers, and/orother pesticides should not be done unless compatibility and phytotoxicity testing is donefirst using appropriate methods.

PASTURESCROP/

VARIETYOBJECTIVE/

BENEFITUSE RATE/


Pasture Grass To stimulate drymatter productionwhen cool seasonsoil conditionslimit naturalpasture growthrates.

3-11 GRAMS A.I

7.5 -27.5 gramsproduct


Apply 1 to 6 applicationsevery 3 to 4 weeks from lateautumn to early spring.

Allow at least 1 - 5 days aftergrazing before treating.Moisture levels and fertilitymust be adequate for grassgrowth prior to application.

NOTE:Do not apply to pastures that are not at least 1 year old..When natural pasture grass growth is very rapid, grass may not respond withadditional growth.Do not apply when pasture grass is subjected to drought stress conditions.Foliage occasionally and temporarily appears lighter green in color due toaccelerated growth rates following application.

On youngwheat, barleyand oat plants(Not for usein California)

Promote growthand standestablishment

3 to 6 GRAMS a.i.

8 to 17 GRAMS ofproduct

0.3 to 0.6 ozproduct

As a foliar application duringtillering but before stemelongation.Use higher rates (within theindicated range) whentemperatures will likelyaverage 75°F or less duringthe 14 days followingapplication.

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PASTURESCROP/

VARIETYOBJECTIVE/

BENEFITUSE RATE/


NOTE:• Maintain adequate moisture and proper fertilization programs as required for the

local area.• Keep applications of the high rate at least two weeks apart.

Sod and Turf Uses:

CROP/VARIETY

Bermudagrass

Tifdwarf,Tifgreen

Bermudagrass

(Tifdwarf,Tifgreen, andothercultivars)

OBJECTIVE/BENEFIT

To maintain orenhance regrowthBermudagrassduring summermonths.

To initiate ormaintain growthand prevent colorchange duringperiods of coldstress and lightfrosts.

USE RATE/ACRE

1-3 GRAMS A.I



10-25 GRAMS A.I

25 - 62.5 gramsproduct

0.9 -2. 3 ounceproduct

APPLICATION TIMING

Under hot conditions, applyl-to-3 grams a.i./acre weeklyin 25-to- 100 gallons ofwater/acre.

Under cool conditions, apply10 grams a.i./acre weekly or25 grams a.i./acre biweekly in25-to- 100 gallons ofwater/acre.

NOTE:• Maintain adequate moisture and proper fertilization programs as required for the

local area.• Keep applications of the high rate at least two weeks apart.• Do not use on dormant grass• Discontinue treatments if thinning is observed.

More frequent mowing is occasionally necessary.

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CONVERSION TABLE (for the 320 g size)

Ryzup Smartgrass contains approximately 10 grams of active ingredient per 25 grams ofproduct.


245681015203040506080100128


510

12.5152025

37.55075100125150200250320

Ounces of ProGibb40%0.20.40.50.60.70.91.41.82.73.64.55.47.29.011.5

Grams of ProGibb 40% WSG for given ppm's of Gibberellic Acid at DifferentWater Volumes.

Gallonsof

Water75100125150200

&-2SJM300400500600750

Desired parts

4

1.52

2.534

5.57.59.51114

5

34568

^fg^1115192328

6

4.56

7.5911

i^fti!1723283443

8

6891115

i®Sfl2330384557

per million (ppm) gibberellic acid

10

7.510121419

§124̂2838475771

15

1114182128

f.tS^a «(•"--"• :pfe,i3.3Lvi,'-:,

43577185106

20

1419242838

'&_-:4S*ft577695113142

30

2128354357

•&:-<7^ .,85113142170213

40i> t*

~l2*f3847-57-76'

';S9̂113151189227284

50

3547597195118142189236284

Note: The numbers inside the table are the grams of RyzUp Smartgrass™ WSG needed toobtain the desired ppm's for each gallonage.

Example:To make 250 gallons of a 40 ppm gibberellic acid solution, dissolve 95 grams of RyzUpSmartgrass™ WSG in 250 gallons of water (see shaded area).

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CONVERSION TABLE (for the 80 g size)ProGibb 40% contains approximately 10 grams of active ingredient per 25 grams ofproduct.


245681015203040506080


5 .10

12.5152025

37.55075100125150200

Ounces of ProGibb40%0.20.40.50.60.70.91.41.82.73.64.55.4

.7.2

(Alternate for 80 g packaging)

Gallonsof

Water75100125150

parts per million (p4

3.04.05.06.0

5

3.85.06.37.5

-JV.M, i«au-jS «<&&&•

6

4.56.07.59.0

•f J£r;t'-nv*>' **"$&!

8

6.08.0

10.012.0

10

7.510.012.515.0

pm) gibberellic acid15

11.315.018.822.5

20

15.020.025.030.0

30

22.530.037.545.0

jK^**Mjtel!$ 50

38506375

Note: The numbers inside the table are the grams of RyzUp Smartgrass™ WSG needed to obtainthe desired ppm's for each gallonage.

Example:To make 200 gallons of a 40 ppm gibberellic acid solution, dissolve 80 grams of RyzUpSmartgrass™ WSG in 200 gallons of water (see shaded area).

DIRECTIONS FOR CHEMIGATIONFill the supply tank with the desired amount of water. Then add the amount of RyzupSmartgrass required in order to achieve the final solution rate recommended for thespecific crop to be treated. Agitate the mixture of of Ryzup Smartgrass frequently duringthe chemigation period to assure a uniform distribution throughout the system.Apply of RyzUp Smartgrass continuously for the duration of the water application but donot exceed recommended rates and volumes as outlined on the product label.

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CHEMIGATION PRECAUTIONSApply this product only through the following systems: Overhead sprinklers such asimpact, micro-sprinklers, or booms. Do not apply this product through any other type ofirrigation system. Crop injury or lack of effectiveness can result from nonuniformdistribution of treated water. If you have any questions about calibration, you shouldcontact State Extension Service specialists, equipment manufacturers or other experts. Donot connect an irrigation system (including greenhouse systems) used for pesticideapplication to a public water system unless the pesticide label prescribed safety devicesfor public water systems are in place. A person knowledgeable of the chemigation systemand responsible for its operation or under the supervision of the responsible person, shallshut the system down and make necessary adjustments should the need arise. Prior toapplication ensure that the chemigation system meets the following requirements:

• The system must contain a functional check valve, vacuum relief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent watersource contamination from backflow.

• The pesticide injection pipeline must contain a functional, automatic, quickclosing check valve to prevent the flow of fluid back toward the injection pump.

• The pesticide injection pipeline must also contain a functional, normally closed,solenoid-operated valve located on the intake side of the injection pump andconnected to the system interlock to prevent fluid from being withdrawn from thesupply tank when the irrigation system is either automatically or manually shutdown.

• The system must contain functional interlocking controls to automatically shut offthe pesticide injection pump when the water pump motor stops.

• The irrigation line or water pump must include a functional pressure switch,which will stop the water pump motor when the water pressure decreases to thepoint where pesticide distribution is adversely affected.

• Systems must use a metering pump, such as a positive displacement injectionpump (e.g. diaphragm pump) effectively designed and constructed of materialsthat are compatible with pesticides and capable of being fitted with a systeminterlock.

In addition to the above use rates and recommendations, the following precautions mustbe observed when using this product in any type of irrigation system.

CHEMIGATION SYSTEMS CONNECTED TO PUBLIC WATER SYSTEMSPublic water system means a system for the provision to the public of piped water forhuman consumption if such system has at least 1 5 service connections or regularly servesan average of at least 25 individuals daily at least 60 days of the year. Chemigationsystems connected to public water systems must contain a functional, reduced pressure


zone, backflow preventer (RPZ) or the functional equivalent in the water supply lineupstream from the point of pesticide introduction. As an option to the RPZ, the waterfrom the public water systems should be discharged into a reservoir tank prior topesticide introduction. There shall be a complete physical break (air gap) between theoutlet end of the fill pipe and the top or overflow rim of the reservoir tank of at leasttwice the inside diameter of the fill pipe. The pesticide injection pipeline must contain afunctional, automatic, quick closing check valve to prevent the flow of fluid back towardthe injection pump. The pesticide injection pipeline must also contain a functional,normally closed, solenoid-operated valve located on the intake side of the injection pumpand connected to the system interlock to prevent fluid from being withdrawn from thesupply tank when the irrigation system is either automatically or manually shut down.The system must contain functional interlocking controls to automatically shut off thepesticide injection pump when the water pump motor stops, or in cases where there is nowater pump, when the water pressure decreases to the point where the pesticidedistribution is adversely affected.

Systems must use a metering pump, such as a positive displacement injection pump (e.g.diaphragm pump) effectively designed and constructed of materials that are compatiblewith pesticides and capable of being fitted with a system interlock.

STORAGE AND DISPOSALDo not contaminate water, food or feed by storage or disposal.

Pesticide StorageKeep containers tightly closed when not in use.

Pesticide DisposalWastes resulting from the use of this product must be disposed of on site or at anapproved waste disposal facility.

Container DisposalNonrefillable container. Do not reuse or refill this container. Triple rinse (or equivalent)promptly after emptying. Triple rinse as follows: Empty remaining contents intoapplication equipment or mix tank. Fill container 1A full with water and recap. Shake 10seconds. Pour rinsate into application equipment or mix tank or store rinsate for later useor disposal. Drain for 10 seconds after flow begins to drip. Repeat this procedure twomore times. Then offer for recycling or dispose of in a sanitary landfill, or incineration,if allowed by state and local authorities by burning. If burned, stay out of smoke.


WARRANTY AND DISCLAIMER STATEMENTTo the fullest extent permitted by law, seller makes no warranty, express or implied, ofmerchantability, fitness or otherwise concerning use of this product other than asindicated on the label. User assumes all risks of use, storage or handling not in strictaccordance with accompanying directions.

RyzUp Smartgrass is a registered trademark of Valent BioSciences Corporation.Products That Work, From People Who Care is a trademark of Valent U.S.A.Corporation.© 2011 Valent BioSciences CorporationRegistered by:Valent BioSciences Corporation870 Technology Way, Suite 100Libertyville, IL 6004804-XXXX/RXDistributed by Valent U.S. A. Corporation.

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NITED STATES ENVIRONMENTAL PROTk YION AGENCYJun 01, 2011 · penetration to aid in sugar...

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