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Transcript of NEW FRONTIERS SEMINAR: Closing The Loop: Conserving Resources Through Sustainable Design and...
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Closing the Loop:Conserving resources through
sustainable design and chemistryMike PittsChemistry Innovation
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
content
• Chemistry and Industry (who uses it?)• Chemistry and Sustainability (issues?)• Chemistry and Sustainable Design
(examples)• Sustainable Design Guide
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Chemistry-Using Industries
Source: 2009 R&D Scoreboard of Top 850 UK Companies - published by BIS
Chemical Manufacture
Process Technology
Product Development
Application &Formulation Skills
£113 bn
£226 bn
£523 bn
CUIs contributetowards £270 bn GVA
to the UK
Chemistry
Engineering
Biotechnology
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Chemists and Sustainability
Green Chemistry: Theory & Practice, Anastas & Warner, 1998
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
RSC Roadmap
Sustainable Designis a RSC Roadmap‘Top Ten’ Challenge
www.rsc.org/roadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
For every tonne of household wastethat we throw away, there's a further 5
tonnes of materials that have beenused in the manufacturing of the
products consumed
Don't throw anything away. There is no 'away' - Shell advert
90% of all products are waste within 6 months of purchase
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Oil
•• The world consumes 84 million barrels of oil a day.The world consumes 84 million barrels of oil a day.•• We consume two barrels of oil for every barrelWe consume two barrels of oil for every barrel
discovered.discovered.•• It took us 125 years to use the first trillion barrels of oil.It took us 125 years to use the first trillion barrels of oil.
WeWe’’ll use the next trillion in 30.ll use the next trillion in 30.•• The world has been finding less oil than itThe world has been finding less oil than it’’s been usings been using
for twenty years now.for twenty years now.•• In 20 years the world will consume 40% more oil than itIn 20 years the world will consume 40% more oil than it
does today.does today.•• The oil and gas weThe oil and gas we’’ve been finding is coming fromve been finding is coming from
places that are tough to reach.places that are tough to reach.•• Peak oil production passed?Peak oil production passed?
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Renewable Chemicals
“natural”, “naturederived”, “renewable”etc.do not equate with“less impact onenvironment”
Need to consider:scale, energyintensity, competingland requirements ,etc.
Source: JLS Consulting
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Water
by 2020 we will need 17% moreby 2020 we will need 17% morewater than is currently availablewater than is currently available
‘‘water is the oil of the 21st centurywater is the oil of the 21st century’’Dow CEO Andrew LiverisDow CEO Andrew Liveris
‘embedded’water
content (litres)1 pair of shoes 1 cotton T-shirt 1 hamburger 1 glass of milk 1 cup of coffee 1 microchip (2 g)
80004100240020014032
Source: World Council, UNESCO, DEFRA
about how much adishwasher uses
in a year
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Endangered Elements
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
• As much gold in 1 tonneof computer scrap as in17 tonnes of gold ore
• Concentration ofplatinum in the dust onthe streets ofBirmingham is higherthan in the ore it camefrom
• More copper above theground in use that left inviable supplies
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Sustainable Design
Reducing the overall environmental impact, whilstmaintaining or improving economic, technical andsocial performance
A shift in thinking: from unit operation to whole system from plant/product to whole life cycle from process and product to service
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
From unitoperation towhole system
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Development of a Green Route toViagra™
ProblemSildenafil citrate development route was inefficientand used large amounts of toxic materials.
Technical SolutionNew, convergent route was designed with a cleancyclisation as the final step, eliminating purification processes.
Benefits nine-fold increase in yield organic waste reduced 15 fold aqueous waste reduced 5 fold highly volatile solvents eliminated toxic metal steps avoided no reaction step involved an extraction reduced energy and waste disposal costs
source: Sustainable Technologies Roadmap
New Route – lower yield but less resource demand
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Whole system thinking
source: Sustainable Technologies Roadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
From plant/productto whole life cycle
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Product Life-Cycle
materials
manufacture
distribution & retail
disposal
use of product
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Lifecycle Analysis
for each pint of milk:
Source: DEFRA
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Improved Efficiency
70
80
90
100
110
120
130
140
150
160
1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
Year
Re
lati
ve
In
de
x (
19
90
= 1
00
)
Greenhouse Gas Emissions
Energy Consumption
Production
source: CEFIC/European Environment Agency
EU Chemicals Industry (incl. pharma)
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Low-Carbon Solutions
For every unit of GHG emitted directlyand indirectly by the chemical industry,this industry enabled 2-3 units ofemission savings via the products andtechnologies provided to other industriesand consumers.
Under 2030 scenarios, this could reach4:1
The most significant savings came from:marine antifoulingcoatingssynthetic textilesautomotive plasticslow-temperaturedetergentsplastics used in piping
insulating foamsagrochemicalslightingplasticpackagingengineefficiency
Source: www.icca-chem.org
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Design for lifecycle
source: Sustainable Technologies Roadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
From process andproduct toservice
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Closed-loop business models
Key materials• scarce elements• recyclable polymers• all metals
Managing Molecules Service Models
sunlight
Globalresources
Deliveredbenefit
Focus on• delivered benefits• customer service• efficient delivery
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Closed-loop business models
Key materials• scarce elements• recyclable polymers• all metals
Separationtechnologie
s
Globalresources
Deliveredbenefit
Chemicalmanageme
nt
‘Chemicalleasing’
Consumertakeback
Design forrecycling
Design forreuse
renewables
Intelligentdesign
Consumereducation
Near netshapemanuf
Customised
products
Reducedresourceintensity
Efficientprocessdesign
Managing Molecules Service Models
Focus on• delivered benefits• customer service• efficient delivery
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Design for recycle and re‑use(closed-loop)
source: Sustainable Technologies Roadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Design for service
source: Sustainable Technologies Roadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Sustainable Design Guide
Shows chemistry-usingorganisations how to buildsustainable thinking intotheir innovation processes
A collection of best practicewith a process for how todo it
Linked supporting resources
www.chemistryinnovation.co.uk/sdg
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Workbook Content
www.chemistryinnovation.co.uk/sdg
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Supporting Information
www.chemistryinnovation.co.uk/sdg
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
Roadmap website
www.chemistryinnovation.co.uk/stroadmap
www.chemistryinnovation.co.uk/stroadmap
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Knowledge Transfer NetworksAccelerating business innovation;a Technology Strategy Boardprogramme
‘Today's problems cannot be solved if we still think theway we thought when we created them’ - Albert Einstein
www.chemistryinnovation.co.uk/stroadmapwww.chemistryinnovation.co.uk/sdg
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Closing the Loop
Ian Holmes
C-Tech Innovation
Environmental Sustainability KTN
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Starter for 10
• What has;
• 20 different types of fastener
• Complex mixture of 25 or more chemical compounds
• Is the fastest growing source of waste in the EU
• Has no current commercial recycling or recovery process?
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Average TV screen Size is now 32”
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Liquid Crystal Displays
• Electronic items containing LCDs has been identified as one of thefastest growing sources of waste in the EU, increasing by 16-28%every five years (and predictions are expected to be conservative).
• The future volumes per year of LCD TVs in WEEE for the UK alone,have been estimated at around;
Predicted Disposal Statistics for LCD Telev isions in the UK
Year 2004 2005 2006 2007 2008 2009 2010 Total
Units(1000) 39 39 74 109 134 305 770 1,470
Mass(MT) 1,050 1,050 1,650 2,250 3,125 5,500 10,900 25,525
Avg Unit Mass kg/Unit 27 27 22 21 23 18 14
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Reflated
Project Objectives
• Development of semi automated methods for LC glass panel disassembly,
• Guidelines for integration of LCD recycling with general WEEE reprocessing,
• Active disassembly designs for LCD displays (both casings and LC panels) andother electronics,
• Development of a process for recovery of the LC, Indium and glass from LC displays,
• The re-use of the recovered materials
• The development of new applications for recovered materials as well as direct re-use.
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The REFLATED process aimed to recover maximum value from LCD waste . Based on thismaterial offsetting virgin production, savings may be achieved. LCA and economic analysisindicated, a saving of 960kg of CO2 emissions and cost saving of £1,500 per tonne may beachieved if materials are recovered rather than land filled.
LiquidCry stal
Glass
Dismantle
Indium
WasteStream
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Project Goals
• Recovery of metals already in short supply
• Recovery of liquid crystal material
• Development of disassembly techniques for LCD containing equipment
• Recycling of high quality glass
• Development of new markets for liquid crystals.
• Diversion of waste LCDs from landfill (up to 10,000 tonnes of waste/year inthe UK )
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LCD what’s inside?
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Anticipated Challenges
• Separation of screens from housing
• Extraction of liquid crystals from displays
• Recovery of Indium from ITO coated glass
• Markets for recovered materials
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Disassembly of housing
• Myriad of designs and configurations
• Automated dismantling not feasibly• Number of tool changes required for screws• Large variation in sizes 10” – 42”• Cutting not feasible due to;
• Presence of backlights containing mercury• Most displays not labelled to show Hg present• Current Hg recovery systems not suited to CCFLs
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Treatment of Panel
• No standard Panel within a display model• Different manufacturer• Different LCs used
• Film removal• Varity of adhesives used• Varied between same model of display• Responded differently to solvents / removal processes
• Identification of display type• Twisted Nematic (TN) [including STN, TFT-TN];• In-Plane Switching (IPS)• Vertically-Aligned Nematic (VAN).
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Display Type
In-Plane Switching (IPS) Vertically Aligned Nematic (VAN) Twisted Nematic (TN)
OFF OFF OFFON ON ON
Electric field
Backlight Backlight Backlight
Electric field
CommonElectrode
PixelElectrode
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Display Type
• The mode of action determines the nature of the liquid crystal mixture used in eachdisplay type.
• TN and IPS technologies require liquid crystal mixtures with positive dielectric, +Δε,VAN technology requires materials with negative dielectric, -Δε.
• If the LC recovered is to be used in electronically activated applications care must betaken not to mix TN and IPS LCD panels with VAN LCD panels.
• The type of screen is hard to identify and will present a significant problem in therecycling process if the intention is to recover and reuse the LC.
• In addition it is believed that some additional compounds are added for “confusion”
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Glass Recovery
Thought to be lowest value material, but highest volume in wastestream.
• Original concept was that glass could be recycled into new displays• Logistics – manufactured in far east, to expensive to transport• Quality issues- very high specification for display glass
• Conventional recycling• Not suitable due to chemical properties and high melting temperature
• Possible route into insulation manufacture
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Disassembly
• Manual process opted for• Faster and safer than an automated process• Best practice guidelines and training course developed
• Design and development of Active Disassembly fastenings
Thermal-Probe Release Screws
Thermally Reversible Polymers
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Polariser Removal
• A host of solvents were tried
• Ethanol, Methanol, DCM
• Banana Oil! - Isoamyl acetate
• Orange juice / citric acid
• No perfect all rounder.
• Resorted to peeling films form whole screens• Not safe or practical for damaged screens
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Liquid Crystal Recovery
Ideal was the use of super-critical CO2
• Not practical on larger scale at present
• 2 stage process1. “conventional” solvent removal from screens2. “Clean up” with super critical CO2
Data base complied of “common” LC components in order to see if therewere any “key stone” compounds to target for recovery
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Process
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Markets
• Liquid Crystal compounds-• Virgin material - $15 - $30/g• Recycled material – no market
• Deployment of recovered LC in other applications is still underinvestigation.
• Glass• Virgin material – high
• Indium – although rumoured to be in short supply current marketprice is dropping!• Not economically viable to recover at current price.
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Recommendations
• Labelling• Identification of screen types• Identification of backlight types• Mark plastics by resin type
• Design for disassembly• Use fewer screws• Use uniform screws• Or adopt active disassembly fasteners• Developed “removable” adhesives• Make lamps easier to remove
• Develop Market for recovered products
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Outputs
• Technology and knowledge to recover liquid crystal and Indium• Not currently economically viable
• Best practice guide and training course on manual handling anddismantling of LCD panels
• Possible route for LCD glass reuse• Would be significant reduction in waste to landfill
• New “active disassembly” fastening and construction prodcuts
• Recommendations to WRAP on recycling of LCDs
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WEEE Recovery:Japan September 2005
BatteriesMay 2006
WEEE Recovery:Europe June 2006
Product LightweightingApril 2007
Life Cycle AssessmentAugust 2007
BioplasticsOctober 2007
Useful Reports
Retail WasteDecember 2007
Materials SecurityMarch 2008
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Design for recyclingRoger Morton Director, Axion
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Closed loop recycling
• A bit about Axion• Some practical examples of the issues
– Coat hangers– Game console– Milk bottles– Vinyl flooring– Carpets
• Actions for designers
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The Axion Group
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Axion Consulting• Develops and evaluates novel resource recovery
and manufacturing processes• Tests and operates innovative recyclable
collection systems• Business planning and financial analysis• Carbon footprinting for the industrial sector• Wide range of private and public sector clients• 31 staff - 20 chemical engineers, chemists &
environmental scientists
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Axion Polymers• Leading UK re-processor of
plastics from WEEE and otherpost consumer waste
• High quality Axpoly® 100%recycled plastic compounds forinjection moulding & extrusion
• Produced to ISO9001 qualitystandards
• First UK polymer to achieveCarbon Footprint label
• 30 staff, running on 3 shifts
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Axion Polymers
Polymer recycling factory 40,000sq.ft.Salford, Manchester
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Axion Polymers’ Process
INPUT WASTE M
ATERIAL
REMO
VE NON-PLASTICS
WASTE
POLYMER SEPARATION
METALS
COM
POUND & BLEND
USERSPECIFICPRODUCT
20+ separation steps in full process
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Axion Polymers
Polymerproductfromextruder
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The Full Story :-Primary Fridge Treatment -
Shredded Plastic
Plastic Recycling, At Axion Polymers,
Manchester UK
Injection MouldingWhite Goods Part
Washing Machine Manufacturer
Waste white goods
New white goods
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Axion Polymers
Washingmachinecomponentmade fromAxpoly
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Axpoly PS13 – Closed Loop
garment hangershred – complex mix
We convert the shredto produce Axpoly PS13 for resale back into garment hangers
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Why China?
• “Demand is Huge”• OEM brands made there already• Axion has scrap material sources in UK• Labour & operating costs lower• ʻWork withʼ not ʻCompete againstʼ• Opportunity to ʻstretch the loopʼ....
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Extended closed-loop – retailgarment hanger
• Success proven in UK – hanger-to-hanger• Major volume is moulded in China• Export to Chinese compounding partner• Sell local resin to Chinese hanger moulder• Hangers exported back to UK / USA
Traceable – Quality – Price
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SONY PlayStation 3 Recycling
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a
PS3 casing disassembled
Foam
PC
MetalRubber
Stickers
ABS
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Pellets from a 99%-1% blendof PS3 casing and foam
Plastic strand after removing onlymetal from the PS3 casings
Pellets after removing all non-PCcomponents from PS3 casings
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HDPE milk bottle design forrecycling
• Supports UK dairy andretail industry CourtauldCommitment
• Maximise theavailability and qualityof food grade recycledHDPE for closed looprecycling
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HDPE recycling flowsheet
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HDPE bottle categories
A B CEasy torecycle withgood yield inclosed loopusing existingtechnology
Tricky torecyclebutachievablewithreducedyield
Notsuitablefor closedlooprecycling
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Recycling PVC flooring
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UK Collectable Flooring Tonnage
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What do we accept?
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How is the PVC recycled?
• Off cuts back intoproduction of newflooring includingsafety
• Uplifted flooring toroad cone bases etc
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Collection logistics
Material collected bymanufacturers using:BackloadsDiversion of vehiclesConsolidation at:
waste transfer stationsdistributors
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Environmental tradeoff
Maximise resourceefficiency
Use recycled polymer• Oil-based raw material
re-used• Legacy additives
appear in new products
Eliminate persistentchemicals
Use virgin polymer &modern additives
• No chemical impact• Carbon impact of virgin
polymer 10 x recycledPVC
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Carpet recycling
UK carpet waste tonnes/yr
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Half UK carpet waste is PP
Wide range ofconstructions:
• Tufted, looped, tiled• PP, jute, polyester,
nylon scrim• Rubber, bitumen,
PVC backed
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PP carpet identification
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Recovery to polymer
Shredding Feed extruderExtrusion
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Trial results
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Trial resultsPhysical properties
testUnits
Recycledcarpet
Virgin PP used forinjection moulding
MFI (at 230°C, 2.16kg) 19.5 12
Tensile strength MPa 17 32Impact strength kJ/m2 3.96 3.5
Elongation @ Yield % 7.3 10
Elongation @ Break % 15
Density g/cm3 1.09 0.905
Ash % 17 0
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Actions for designers• Consider end of life right from the start• Work with the supply chain to keep end of
life product out of general waste• Treat end of life product as a resource• Use carbon footprint to guide design choices
•Talk to the recyclers!
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