msds

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Safety Data Sheet Material Name: TRINITRORESORCINOL SDS ID: OHS24320 Issue Date: 03/08/2010 Revision: 1.2000 Other Sections 02 03 04 05 06 07 08 09 10 11 11B 12 13 14 15 16 * * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *

Material Name: TRINITRORESORCINOL

ChemADVISOR, Inc. Stone Quarry Crossing 811 Camp Horne Road, Suite 220 Pittsburgh, PA 15237 E-mail: [email protected] MSDS is for reference use only; please contact manufacturer for emergency response information, routine product inquiries and orders. Chemical Family nitro, hydroxyls, aromatic Synonyms 2,4,6-TRINITRO-1,3-BENZENEDIOL; 2,4,6-TRINITRO-RESORCINOL; STYPHNIC ACID; 2,4,6TRINITRORESORCINOL; 2,4-DIHYDROXY-1,3,5-TRINITROBENZENE; 1,3-DIHYDROXY-2,4,6TRINITROBENZENE; 3-HYDROXY-2,4,6-TRINITROPHENOL; UN 0219 * * * Section 2 - HAZARDS IDENTIFICATION * * *

EMERGENCY OVERVIEW Color: yellow Physical Form: crystals Physical Hazards: May explode if exposed to shock, friction or heating. Flammable solid. POTENTIAL HEALTH EFFECTS Inhalation Short Term: irritation, nausea, vomiting, headache, dizziness, bluish skin color Long Term: kidney damage, liver damagehttp://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 1 of 10

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Skin Contact Short Term: irritation, nausea, vomiting, headache, dizziness, bluish skin color Long Term: kidney damage, liver damage Eye Contact Short Term: irritation Long Term: no information is available Ingestion Short Term: no information is available Long Term: no information is available * * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * * CAS 82-71-3 Component / EC# TRINITRORESORCINOL 201-436-6 Percent 100 Symbol(s) Xn E Risk Phrase(s) R:20/21/22-3-4

* * * Section 4 - FIRST AID MEASURES * * * Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eyes Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Ingestion If a large amount is swallowed, get medical attention.

* * * Section 5 - FIRE FIGHTING MEASURES * * * See Section 9 for Flammability Properties NFPA Ratings: Health: 1 Fire: 4 Reactivity: 3 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Flammable Properties Severe fire hazard. Severe explosion hazard. Flood with water. If no water is available, use dry chemical, halogenated extinguishing agents or earth.http://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 2 of 10

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Fire Fighting Measures Do not move containers which have been damaged or exposed to heat. Do not try to fight fire in cargo or storage areas. Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. For tank, rail car or tank truck, evacuation radius: 1600 meters (1 mile). Explosive. Do not try to fight fire in cargo or storage areas. Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Avoid inhalation of material or combustion by-products. Evacuation radius: 1600 meters (1 mile).

* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * * Occupational spill/release Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Remove sources of ignition. Evacuation radius: 800 meters (1/2 mile). Keep unnecessary people away, isolate hazard area and deny entry. * * * Section 7 - HANDLING AND STORAGE * * * Storage Procedures Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. Department of Treasury 27 CFR Subpart K. U.S. OSHA 29 CFR 1910.109 NFPA 495 Standard for Storage, Use and Handling of Explosives. * * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * * Component Exposure Limits ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components. Exposure Limits for Chemicals which may be generated during processing This material has no components listed. Ventilation Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosionresistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Clothing Wear appropriate chemical resistant clothing. Glove Recommendationshttp://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 3 of 10

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Wear appropriate chemical resistant gloves. Respiratory Protection Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positivepressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positivepressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressuredemand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. * * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * * Physical State: Solid Color: yellow Odor: Not Available Taste: sour taste Boiling Point: Not applicable Vapor Pressure: Not applicable Density: Not available Water Solubility: slightly soluble Molecular Weight: 245.12 Solvent Solubility Soluble: alcohol, ether Appearance: Not available Physical Form: crystals Odor Threshold: Not available Melting Point: 180 C Flash Point: explodes Vapor Density (air = 1): Not applicable Specific Gravity (water = 1): Not available Coeff. Water/Oil Dist: Not available Molecular Formula: C6-H3-N3-O8

* * * Section 10 - STABILITY AND REACTIVITY * * * Chemical Stability May explode if exposed to shock, friction or heating. Conditions to Avoid Avoid heat, flames, sparks and other sources of ignition. Incompatible Materialshttp://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 4 of 10

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oxidizing materials TRINITRORESORCINOL: OXIDIZERS (STRONG): Fire and explosion hazard. Hazardous Decomposition Products oxides of nitrogen

Thermal decomposition products: oxides of nitrogen. Possibility of Hazardous Reactions Will not polymerize. * * * Section 11 - TOXICOLOGICAL INFORMATION * * * Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and no selected endpoints have been identified. RTECS Acute Toxicity (selected) The components of this material have been reviewed and RTECS publishes no data as of the date on this document. Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA. RTECS Irritation The components of this material have been reviewed and RTECS publishes no data as of the date on this document. Inhalation - Acute Exposure TRINITRORESORCINOL: No data available. Dusts may be irritating. However, nitro compounds of aromatic hydrocarbons may cause nervous system depression, nausea, vomiting, irritation of nose and throat, sclerotic icterus, anemia, moderate cyanosis, fatigue, dizziness, headache, insomnia and weight loss. Dark colored urine may also be present. Inhalation - Chronic Exposure TRINITRORESORCINOL: No data available. However, nitro compounds of aromatic hydrocarbons may cause liver and kidney damage with production of acute yellow atrophy, toxic hepatitis and fatty degeneration of the kidneys. Skin Contact - Acute Exposure TRINITRORESORCINOL: No data available. Excessive contact with dusts may cause irritation. However, nitro compounds of aromatic hydrocarbons may be absorbed through the skin and cause systemic poisoning. Nausea, vomiting, nervous system depression, anemia, moderate cyanosis, fatigue, slight dizziness, headache, insomnia, weight loss and dark colored urine may occur. The exposed skin is often yellowishbrown and the hair yellowish-red.

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Skin Contact - Chronic Exposure TRINITRORESORCINOL: No data available. However, nitro compounds of aromatic hydrocarbons may cause liver and kidney damage with production of acute yellow atrophy, toxic hepatitis and fatty degeneration of the kidneys. Eye Contact - Acute Exposure TRINITRORESORCINOL: No data available. Dusts may cause irritation. Eye Contact - Chronic Exposure TRINITRORESORCINOL: No data available. Ingestion - Acute Exposure TRINITRORESORCINOL: No data available. Ingestion - Chronic Exposure TRINITRORESORCINOL: No data available. * * * Section 12 - ECOLOGICAL INFORMATION * * * Component Analysis - Aquatic Toxicity No LOLI ecotoxicity data are available for this product's components. * * * Section 13 - DISPOSAL CONSIDERATIONS * * * Disposal Methods Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D003. Dispose in accordance with all applicable regulations. Component Waste Numbers The U.S. EPA has not published waste numbers for this product's components. * * * Section 14 - TRANSPORT INFORMATION * * * US DOT Information Shipping Name: Trinitroresorcinol Hazard Class: 1.1D UN/NA #: UN0219 Packing Group: II Required Label(s): 1.1D TDG Information Shipping Name: Styphnic acid Hazard Class: 1.1D UN #: UN0219 Packing Group: II Required Label(s): 1.1D ADR Informationhttp://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 6 of 10

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Shipping Name: Trinitroresorcinol Hazard Class: 1 UN #: UN0219 Required Label(s): 1 ADR Tunnel Code Restrictions This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations. TRINITRORESORCINOL (82-71-3) Restriction(s): B1000C [UN0219, UN0394] RID Information Shipping Name: Trinitroresorcinol Hazard Class: 1 UN #: UN0219 Required Label(s): 1, (+15) IATA Information Shipping Name: Trinitroresorcinol Hazard Class: 1.1D UN #: UN0219 ICAO Information Shipping Name: Trinitroresorcinol Hazard Class: 1.1D UN #: UN0219 IMDG Information Shipping Name: Trinitroresorcinol Hazard Class: 1.1 D UN #: UN0219 * * * Section 15 - REGULATORY INFORMATION * * * U.S. Federal Regulations None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan. SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: No Chronic Health: No Fire: Yes Pressure: Yes Reactive: Yes U.S. State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI


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TRINITRORESORCINOL Not listed under California Proposition 65

82-71-3

No

No

No

Yes

No

No

EU Marking and Labelling EC-No. 201-436-6 Symbols Xn Harmful E Explosive Risk Phrases R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition. R4 Forms very sensitive explosive metallic compounds. Safety Phrases S2 Keep out of the reach of children. S35 This material and its container must be disposed of in a safe way. Component Analysis - Inventory Component CAS

US

CA

EU

AU

PH

JP

KR

CN

NZ

TRINITRORESORCINOL 82-71-3 Yes NSL EIN Yes No Yes No No No Globally Harmonized System of Classification and Labelling (GHS) The listed component(s) of this material have been checked for country-specific published classifications according to the Globally Harmonized System of Classification and Labelling (GHS). The results of the queries are displayed below. Please see the individual country listings, as additional interpretations or reference information may be available. For a reference list of H- or P-statements, please visit ChemADVISORs website at www.chemadvisor.com\sdsoncommand\ghs_H&Pphrases.html. Australia GHS Classifications No published information available. This material may be hazardous according to published criteria for classification. EU GHS Classifications Classifications below according to Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (CLP). TRINITRORESORCINOL (82-71-3) Explosives: Hazard_Category: Expl. 1.1 Hazard_Statement: H201 Acute ToxicityOral: Acute ToxicityDermal: Acute ToxicityInhalation: EU Labelling: Acute Tox. 4 Hazard_Statement: H302 (Minimum classification)

Acute Tox. 4 Hazard_Statement: H312 (Minimum classification)

Acute Tox. 4 Hazard_Statement: H332 (Minimum classification)

Pictogram: GHS01, GHS07 Signal_Word: Dgr Hazard_Statement: H201, H332, H312, H302Page 8 of 10


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Indonesia GHS Classifications No published information available. This material may be hazardous according to published criteria for classification. Japan GHS Classifications Classifications below published under Japan's Chemicals Classification Program according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). TRINITRORESORCINOL (82-71-3) Explosives: Category: Division 1.1 Symbol: Exploding bomb Signal: Danger Statement: Exploding, mass explosion hazard Hazards to Category: 3 Symbol: None Signal: None Statement: Harmful to aquatic the Aquatic life Environment: Category: 3 Symbol: None Signal: None Statement: Harmful to aquatic life with long lasting effects Korea GHS Classifications No published information available. This material may be hazardous according to published criteria for classification. New Zealand GHS Classifications No published information available. This material may be hazardous according to published criteria for classification. South Africa GHS Classifications Information below presented according to the South African Bureau of Standards (SANS 10234:2008 Globally Harmonized System (GHS) of Classification and Labelling of Chemicals). The information below identifies substances with recommended GHS classifications by CAS or RR numbers and chemical names; the data field contains the word ''Present'' along with any clarifying information in parenthesis. NOTE: Due to copyright laws on the standard, we are not able to publish the classification. Details about South Africa's implementation of GHS are available by ordering the Standard and its supplement through the South African Bureau of Standards website. TRINITRORESORCINOL (82-71-3) Listing: Present; Present (dry or wetted with =30% water or a mixture of water and alcohol, by mass) Taiwan GHS Classifications No published information available. This material may be hazardous according to published criteria for classification. * * * Section 16 - OTHER INFORMATION * * * Key / Legendhttp://www.chemadvisor.com/SymyxMSDS/ohsdoc.pl?OHSNUMBER=OHS24320&DOCTYPE=SUMMARY Page 9 of 10

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ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Communicty; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Farenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances; SARA - Superfund Amendments and Reauthorization Act; STEL Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States Full text of R phrases in Section 3 R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition. R4 Forms very sensitive explosive metallic compounds. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Other Information Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or any other warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental or consequential damages resulting from its use. Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property damage arising out of the use of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS MSDS IS TO BE UTILIZED SOLEY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Material Safety Data Sheet before handling product. Copyright Copyright 1984-2010 ChemADVISOR, Inc.


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