MONTHLY MONITORING REPORT JULY 2016 · 317 E. Main Street Ventura, CA 93001 Tel: (805) 585-2110...

317 E. Main Street Ventura, CA 93001

Tel: (805) 585-2110 Fax: (805) 585-2111

MONTHLY MONITORING REPORT JULY 2016

DATE: September 16, 2016 (revised Jan 4, 2017 to correct groundwater gradient to southeasterly - see Section 2.0, 3rd line).

PREPARED FOR: Rose Marie Caraway, Remedial Project Manager/Environmental Scientist U.S. Environmental Protection Agency, Region 9 75 Hawthorne Street, SFD 7-2 San Francisco, California 94105

PREPARED BY: Max Ramos, E.I.T., Staff Environmental Engineer, OTIE Lindsey Larsen, Environmental Scientist, OTIE John Wingate, P.E., Project Manager, OTIE

RE: July 2016 Plant Influent and Effluent Sampling Results for the Pemaco Superfund Site Treatment Plant, Maywood, California

1.0 INTRODUCTION The United States Environmental Protection Agency (U.S. EPA) is currently implementing the Long-Term Response Action (LTRA) at the Pemaco Superfund Site in Maywood, California. Oneida Total Integrated Enterprises, LLC. (OTIE) performs monthly monitoring work for the U.S. EPA under contract by the United States Army Corps of Engineers (USACE), Los Angeles District Contract Number W912PL 16-C-0016.

OTIE prepared this Report to summarize the results of monthly influent and effluent water and vapor sampling performed on July 20, 2016 at the Pemaco Superfund Site Treatment Plant (Plant).

The influent and effluent water samples (SP-201 and SP-209, respectively), and influent and effluent vapor samples (SP-104 and SP-106, respectively) were analyzed for volatile organic compounds (VOCs) and 1,4-dioxane. Samples were analyzed in accordance with the Final Sampling and Analysis Plan, (Field Sampling Plan and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial Action (OTIE, 2015).

Monthly water and vapor sampling is performed to demonstrate compliance with Los Angeles County Sanitation District (LACSD) limits and South Coast Air Quality Management District (SCAQMD) guidance; confirm liquid phase granular activated carbon (LGAC) and vapor phase granular activated carbon (VGAC) effectiveness; and summarize data trends necessary for evaluation of remedial progress. The metric for “mass removal” is evaluated in the Quarterly Operations and Maintenance Report.

The groundwater treatment system (GTS) and vapor treatment system (VTS) achieved operational uptimes of approximately 34% and 3%, respectively, during July 2016. The VTS and GTS were not operated July 1 through July 18, and July 1 through July 20, respectively, to simulate “static” conditions

Oneida Total Integrated Enterprises of 11

SEMS-RM DOCID # 1163860

Monthly Monitoring Report July 2016 Plant Influent and Effluent Sampling Results Pemaco Superfund Site, Maywood, California

for the July semiannual groundwater monitoring event. Additional treatment system shutdowns occurred as follows:

• The VTS was not operated for a portion of July 19 through July 25 due to a failure of chillerRC-201 during high ambient temperatures;

• The VTS was not operated from July 26 to July 31 while awaiting the arrival of a replacementcompressor oil pump for RC-201.

Additional operational details are available in the most recent Operations Summary and the July weekly Quality Control Reports located on the Pemaco SharePoint website. Plant operational details will be summarized in the 2016 Third Quarter Operation and Maintenance Report.

2.0 ‘A’ ZONE GROUNDWATER LEVEL GAUGING Groundwater elevations and analytical data suggest an off-site contaminant source is located northwest of Maywood Riverfront Park, with significant trichloroethene (TCE) concentrations in the Exposition Aquifer ‘A’ Zone (OTIE, 2016a). Groundwater extraction from the ‘A’ Zone may promote a southeasterly migration of contaminants from northwest of the Park toward the former electrical resistive heating (ERH) area. In order to protect the ERH remedy area and discourage potential migration of the off-site source, the ‘A’ Zone wells were shut down on April 28, 2016 following stakeholder discussion and U.S. EPA approval. Groundwater levels in the ‘A’ Zone will be gauged monthly to monitor gradient changes while the ‘A’ Zone extraction wells remain inactive.

The July 8, 2016 ‘A’ Zone groundwater gauging event was the third groundwater level monitoring task performed since shutdown of ‘A’ Zone extraction wells in April 2016. Groundwater elevation data for the July 2016 gauging event is provided in Attachment 1. July 2016 groundwater elevations are compared to the most recent groundwater elevation data from the December 2015 semiannual groundwater monitoring event. ‘A’ Zone groundwater elevation changes at individual well locations include both increases and decreases compared to December 2015 values. The ‘A’ Zone groundwater elevation changes over time are shown in the hydrograph presented in Figure 1 (after text). Groundwater elevations in many ‘A’ Zone wells increased between the June 2016 gauging event and the July 2016 gauging event, however, evaluation of the overall ‘A’ Zone groundwater elevation trends requires additional data. Elevation trends will be included in future monthly monitoring reports following sufficient rounds of monthly gauging.

3.0 PLANT WATER SAMPLING RESULTS Influent and effluent water grab samples were collected on July 20, 2016 and the detected analytical results are summarized in Table 1. The laboratory analysis was performed by Eurofins CalScience, Inc. The laboratory reports containing the full list of analytical results for VOCs and 1,4-dioxane in sample SP-201 and SP-209 are provided in Attachment 2.

The Exposition Zone groundwater extraction wells were not active on the date of sample collection. The July 2016 influent sample results represent a composite of flow from the following active wells screened in the Perched Zone:

• Perched Zone (dual-phase extraction [DPE]): PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05,PD-06, and PD-07.



Table 1 Monthly Summary of Detected VOCs in Influent / Effluent Water Samples

Analyte Method

Sample Locations Sample ID

Sample Date

SP-201 (Influent) SP-201-20160720

7/20/2016 Results

SP-209 (Effluent) SP-209-20160720

7/20/2016 Results SSRL Unit

1,1-Dichloroethane SW8260B 5 μg/L <0.28 1.2**

1,4-Dioxane (P-Dioxane) SW8260SIM 1* μg/L <18 5.3

1,2,4-Trimethylbenzene SW8260B NC μg/L 0.39 J <0.36

Chloroform SW8260B 80 μg/L <0.46 0.96 J**

cis-1,2-Dichloroethene SW8260B 6 μg/L <0.48 5.1**

Ethylbenzene SW8260B 300 μg/L 2.4 <0.14

n-Butylbenzene SW8260B NC μg/L 1.1 <0.23

n-Propylbenzene SW8260B NC μg/L 0.75 J <0.17

Naphthalene SW8260B 6.2 μg/L 6.2 <5.0

sec-Butylbenzene SW8260B NC μg/L 0.70 J <0.25

Trichloroethene SW8260B 5 μg/L 3.0 <0.37

Vinyl Chloride SW8260B 0.5 μg/L <0.30 0.32 J**

Notes: 1. * - Indicates value is a "California Notification Level" which is less than the SSRL of 3.0, listed in the ROD (U.S. EPA, 2005). 2. ** - Indicates effluent sample concentration was higher than influent concentration as a result of preferential desorption. 3. Bold indicates a sample detection. 4. ID = identification; SSRL = site-specific remediation level; μg/L = micrograms per liter; < = indicates compound was not

detected above the method detection limit. 5. Effluent water quality complied with the LACSD permit limit of 1,000 μg/L for total VOCs. 6. The high 1,4-dioxane detection limit for the month of July 2016 was due to a necessary sample dilution performed by

Eurofins CalScience.

3.1 PROCESS WATER INFLUENT (SP-201) DISCUSSION The following VOCs are associated with groundwater plumes being monitored as part of the semiannual groundwater monitoring program. Analytical results for samples collected during the July 2016 event for these VOCs are summarized below:

• Cis-1,2-dichloroethene (cis-1,2-DCE) was not detected for the month of July. The non-detection of cis-1,2-DCE in the influent water sample is lower than the normal concentration range (Figure 2). The lower cis-1,2-DCE concentration demonstrates a difference between the normal plant influent process water from Perched and Exposition extraction wells, and the plant influent during the July monitoring event, which represents plant process water from Perched Zone extraction wells only. The Perched Zone generally exhibits a lower concentration of VOCs in groundwater than Exposition Aquifer groundwater (OTIE, 2016b). Additionally, treatment system processes associated with the Perched Zone extraction wells, such as high vacuum and processing through the condensate sumps, encourages volatilization of VOCs prior to the process water influent sample port.

• TCE was detected at a concentration of 3 μg/L, the lowest concentration observed during 2016 (Figure 3). The low TCE concentration in process water influent is attributed to differing VOC



concentrations in normal plant process water and in process water from Perched Zone extraction wells only, as described above for the cis-1,2-DCE concentration.

• 1,4-Dioxane was not detected for the month of July (Figure 4). The non-detection of 1,4-dioxanein the plant influent sample is attributed to a high detection limit caused by laboratory sampledilution, which was required due to the presence of hydrocarbons. Hydrocarbon concentrationsin the plant influent likely originated from well PD-04, which was that, entered the plant uponreactivation on July 19. The OTIE sampling team observed approximately 18 inches of floatingfree product in PD-04 during the July semiannual sampling event. Analytical results from thesample collected at well PD-04 show detections of benzene compounds and naphthalene,consistent with the compounds detected in the July process water influent sample (OTIE,2016b). The treatment system is removing the free product, as evidenced by the absence ofmeasured free product during “dynamic” (pumping, per standard operations) monitoringevents.



Figure 2 Historical Concentrations of cis-1,2-Dichloroethene in Influent Water

Figure 3 Historical Concentrations of Trichloroethene in Influent Water

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Figure 4 Historical Concentrations of 1,4-Dioxane in Influent Water

Notes for Figures 2, 3, and 4: 1. Data collected over a 24 month period beginning in August 2014. Concentration values reflected on the figure represent

samples collected during monthly monitoring events. 2. Values that were below the laboratory detection limit are expressed as concentrations of zero. 3. Plant influent water was not analyzed in November 2015. 4. The trend line represents a linear regression of 23 data points from samples collected during monthly monitoring events.

The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected.

3.2 PROCESS WATER EFFLUENT (SP-209) DISCUSSION The water effluent quality satisfied the LACSD permit limit for total VOCs of 1,000 μg/L. VOC concentrations in plant effluent were below their respective SSRLs, with the exception of 1,4-dioxane (5.1 μg/L), which has a low LGAC adsorptive capacity.

The LGAC performance is satisfactory because the LACSD permit limits were satisfied and filter vessels continue to operate with acceptable head loss.

4.0 PLANT VAPOR SAMPLING RESULTS The influent and effluent vapor samples were collected in 1-liter SUMMA® canisters on July 20, 2016. The analytical results for this event are summarized in Table 2. The laboratory analysis was performed by ALS Environmental and the laboratory report is provided as Attachment 3. The July 2016 influent vapor sample represents a composite of concentrations from active DPE wells (PB-01, PB-02, PB-03, PB-05, PC-06, PD-04, PD-05, PD-06, and PD-07), all screened in the Perched Zone.

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Table 2 Summary of Detected VOCs in Influent and Effluent Vapor Samples

Analyte

Sample Location Sample ID

Sample Date

SP-104 (Influent) SP-104-20160720

7/20/2016 Result

SP-106 (Effluent) SP-106-20160720

7/20/2016 Result Method Unit

2-Butanone TO15 μg/m3 <70 3.7 J*

2-Propanol TO15 μg/m3 <140 4.2 J*

Acetone TO15 μg/m3 <260 43*

Acrolein TO15 μg/m3 <57 0.64 J*

Chloromethane TO15 μg/m3 <50 1.2 J*

Cumene TO15 μg/m3 450 <0.54

Cyclohexane TO15 μg/m3 350 <1.0

Dichlorodifluoromethane TO15 μg/m3 <57 5.1*

Ethanol TO15 μg/m3 <270 22*

Ethylbenzene TO15 μg/m3 5000 <0.57

Isopropylbenzene TO15 μg/m3 450 <0.54

N-Heptane TO15 μg/m3 160 J <0.61

N-Hexane TO15 μg/m3 440 0.87 J

N-Propylbenzene TO15 μg/m3 1200 <0.57

Tetrachloroethene TO15 μg/m3 54 J 0.95 J

Tetrahydrofuran TO15 μg/m3 <67 0.80 J*

Toluene TO15 μg/m3 <57 0.66 J*

Trichloroethene TO15 μg/m3 300 <0.50

Vinyl chloride TO15 μg/m3 <57 6.2*

Notes: 1. * - Indicates a compound detected in effluent sample and not in influent sample as a result of higher detection limits for

influent analysis. 2. Bold indicates sample detection. 3. ID = identification; J = estimated value; μg/m3 = micrograms per cubic meter; < = indicates compound was not detected

above the method detection limits. 4. A complete listing of analytes is found in the laboratory report (Attachment 3).

4.1 PROCESS VAPOR INFLUENT (SP-204) DISCUSSION Influent vapor concentrations over the previous 24 months are presented in Figure 5. The sum of VOCs detected in plant vapor influent shows a decreasing trend. The trend is influenced by the high VOC concentrations detected during the months of January and February 2015. This concentration spike was associated with prolonged shutdown of the VTS system from December 4, 2014 to January 16, 2015 to facilitate removal of the Flameless Thermal Oxidizer. Influent vapor VOC concentrations since the June 2015 sampling event have been consistent with influent vapor VOC concentrations prior to the VTS shutdown. Slightly elevated influent concentrations observed in the July 2016 sample are attributed to concentrations of benzene compounds, likely associated with free product entering the treatment plant from well PD-04 (Figure 5).



The COCs with highest concentrations in the vapor influent were: Ethylbenzene (5000 μg/m3), N-Propylbenzene (1200 μg/m3), Cumene (450 μg/m3), Isopropylbenzene (450 μg/m3), n-Hexane (440 μg/m3) and Cyclohexane (350 μg/m3).

Figure 5 Historical Influent VOC Concentrations in Vapor

Notes: 1. Monthly data collected over a 24 month period beginning in August 2014. Concentration values reflected on the figure

represent samples collected during monthly monitoring events. 2. Plant influent vapor was not analyzed in November 2015. 3. The trend line represents a linear regression of 23 data points from samples collected during monthly monitoring events.

The trend line is a best-fit representation of the data and serves as a forecasting tool; it is not intended to represent the mean value of all samples collected.

4.2 PROCESS VAPOR EFFLUENT (SP-208) DISCUSSION Plant air effluent is not formally permitted but does comply with SCAQMD permit guidance for human health risk assessment. Tier 2 Screening Risk Assessment for the Pemaco Site was conducted using risk assessment methods prescribed in the 2015 SCAQMD Risk Assessment Procedures1 (SCAQMD, 2015). A

1 The Pemaco Final Remedial Design Report (TN&A, 2006) indicated that the VTS will meet the substantive requirements of the SCAQMD Risk Assessment Procedures for Rules 1401 and 212, Version 7.0 (SCAQMD, 2005). Monthly plant vapor effluent monitoring is evaluated according to the June 2015 updated SCAQMD Risk Assessment Procedures for Rules 1401, 1401.1 and 212, Version 8.0 (SCAQMD, 2015) in order to document that continued operation of the VTS is protective of human health.

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Historical Influent VOC Concentrations



Tier 2 Screening Risk Assessment Report based on the 2015 SCAQMD procedures for July is included in Attachment 4 and demonstrates plant vapor emission compliance with the 2015 SCAQMD permit guidance. The Tier 2 Screening Risk Assessment Report was generated using the SCAQMD Risk Tool (V1.02) Microsoft excel spreadsheet distributed on the SCAQMD website (SCAQMD, 2016).

A summary of the results from the Tier 2 Air Screening Risk Assessment is presented in Table 3. The maximum incremental cancer risk (MICR) associated with potential exposure to toxic air contaminants (TACs) is roughly two (for resident) and three (for worker) orders of magnitude less than the U.S. EPA acceptable cancer risk of “one in a million” (1 x 10-6) for residential and worker receptors, respectively. Calculated non-cancer hazard indices (chronic hazard index [HIc], acute hazard index [HIa], and 8-hour chronic hazard index [HI8]) associated with potential exposure to TACs are less than the established limit of one.

Table 3 Summary of Tier 2 Screening Risk Assessment Health Risk Values Maximum Individual Cancer Risk (MICR)

Chronic Hazard Index (HIc)

Acute Hazard Index (HIa)

8-Hour Chronic Hazard Index (HI8)

Receptor1 Resident Worker Resident Worker Resident Worker Resident Worker

Maximum Health Risk Value 1.35E-08 5.45E-09 2.15E-05 1.05E-04 2.33E-05 6.73E-05 1.08E-05 5.23E-05

Notes: 1. Health risk values are calculated for residential receptors at a distance of 75 meters from the plant vapor effluent stack

and for commercial (worker) receptors at a distance of 25 meters from the plant vapor effluent stack. 2. Health risk values were calculated with the SCAQMD Risk Tool (V1.02) (SCAQMD, 2016) using analytical data from the July

20, 2016 vapor effluent sample. The full Tier 2 Screening Risk Assessment Report is provided in Attachment 4.

Destruction removal efficiency (DRE) is typically calculated to evaluate the performance of the VGAC and the vapor conditioning package. The DRE equals the mass difference between the influent and effluent divided by the total mass in the influent. The sum of VOCs detected in the influent was 8404 μg/m3; the sum of VOCs detected in the effluent was 89 μg/m3. The resulting DRE of 99% for July 2016 is above average and consistent with the previous month (98%), representing a return to typical operational values following the May 10, 2016 VGAC changeout.

5.0 CONCLUSIONS • During the month of June, the GTS achieved an uptime of 34% and the VTS achieved an uptime

of 3%. Extended shutdowns were required to accommodate the July 2016 semiannualgroundwater monitoring event and during repair of the chiller RC-201.

• July ‘A’ Zone groundwater elevation measurements were collected approximately three monthsfollowing shutdown of the ‘A’ Zone groundwater extraction wells. Elevation trends will beevaluated following additional rounds of monthly gauging.

• Results of the July 2016 plant water and vapor sampling conducted on July 20, 2016 confirmedcompliance with LACSD permit limits and 2015 SCAQMD permit guidance.

• The July 2016 plant water influent sample represented process water from Perched Zoneextraction wells only. Low concentrations of VOCs detected in the July influent water sample areattributed to lower VOC concentrations in Perched Zone groundwater and potentialvolatilization of VOCs during plant processing of Perched Zone influent water. Plant influent



water concentrations of naphthalene and benzene compounds are indicative of the extraction (and dilution) of the observed free product in well PD-04.

• Concentrations of VOCs in influent vapor samples were slightly elevated compared to recentmonthly sampling results, likely caused by rebound following shutdown of the VTS toaccommodate the July 2016 semiannual groundwater monitoring event.

• The LGAC performance is satisfactory because the LACSD permit limits were satisfied and filtervessels continue to operate with acceptable head loss.

• Vapor effluent VOC concentrations and DRE values remain satisfactory following changeout ofthe VGAC on May 10, 2016.

6.0 REFERENCES Earth Tech, Inc. 2007. SCAQMD – Tier 2 Toxic Air Contaminant Emissions Modeling, Pemaco Superfund

Site, 5050 East Slauson Avenue, Maywood, California. February.

Oneida Total Integrated Enterprises (OTIE). 2015. Final Sampling and Analysis Plan (Field Sampling Plan and Quality Assurance Project Plan), Long-Term Response Action for the Pemaco Remedial Action. September.

_____. 2016a. Draft Semiannual Groundwater Monitoring Report, December 2015 Monitoring Event for the Pemaco Superfund Site Treatment Plant, Maywood, California. April.

_____. 2016b (under production). Draft Semiannual Groundwater Monitoring Report, July 2016 Monitoring Event for the Pemaco Superfund Site Treatment Plant, Maywood, California

South Coast Air Quality Management District (SCAQMD). 2005. Risk Assessment Procedures for Rules 1401 and 212 Version 7.0, Permit Application Package “L” Rules 1401 and 212 Version 7.0. July 1.

_____. 2015. Risk Assessment Procedures for Rules 1401, 1401.1 and 212. Version 8.0. June 5.

_____. 2016. Rule 1401 Risk Assessment Program, Risk Tool (V1.02), Version 8.0 & Attachment M, Revision March 2016. Available online at http://www.aqmd.gov/home/permits/risk-assessment. Accessed 4 April 2016.

United States Environmental Protection Agency (U.S. EPA). 2005. Record of Decision, Pemaco Maywood Superfund Site, Maywood, California. EPA ID: CAD980737092. January 13.

FIGURES (AFTER TEXT) Figure 1 Exposition ‘A’ Zone Hydrograph

ATTACHMENTS Attachment 1 July 2016 ‘A’ Zone Groundwater Gauging Results


http://www.aqmd.gov/home/permits/risk-assessment


Attachment 2 Lab Report from Eurofins CalScience, Inc. – SP-201 VOC & 1,4-dioxane analysis; SP-209 VOC & 1,4-dioxane analysis

Attachment 3 Lab Report from ALS Environmental

Attachment 4 Tier 2 Screening Risk Assessment Report (Version 8.0 & Attachment M, Revision March 2016) – Risk Tool (V1.02)


FIGURE 1Exposition 'A' Zone Hydrograph

Oneida Total Integrated Enterprises Page 1 of 1

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Figure 1Exposition 'A' Zone Hydrograph

Pemaco Superfund Site, Maywood, California

DA‐01DA‐02DA‐03DA‐04DA‐05DA‐06DA‐07DA‐08DA‐09DA‐10DA‐11DA‐12MW‐01‐80MW‐03‐70MW‐04‐75MW‐07‐75MW‐08‐70MW‐09‐70MW‐10‐75MW‐12‐70MW‐14‐80MW‐19‐70MW‐20‐70MW‐21‐80MW‐22‐75MW‐26‐75MW‐27‐70MW‐36‐80MW‐37‐80MW‐38‐80RW‐01‐70Dry

'A' Zone extraction wells shut down (4/28/2016)

ATTACHMENT 1 June 2016 'A' Zone Groundwater Gauging Results

Attachment 1July 2016 'A' Zone Groundwater Gauging ResultsPemaco Superfund Site, Maywood, California

Depth to Water (ft btoc)

Groundwater Elevation (ft amsl)

Depth to Water (ft btoc)

Groundwater Elevation (ft amsl)

1 MW‐01‐80 Monitoring 59 ‐ 79 75.48 73.08 75.33 73.23 0.152 MW‐03‐70 Monitoring 60 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐3 MW‐04‐75 Monitoring 65 ‐ 75 70.75 75.32 69.67 76.40 1.084 MW‐07‐75 Monitoring 65 ‐ 75 64.11 75.21 63.3 76.02 0.815 MW‐08‐70 Monitoring 63 ‐ 68 * ‐‐ * ‐‐ ‐‐6 MW‐09‐70 Monitoring 65 ‐ 70 * ‐‐ * ‐‐ ‐‐7 MW‐10‐75 Monitoring 68 ‐ 73 67.73 72.89 * ‐‐ ‐‐8 MW‐12‐70 Monitoring 65 ‐ 70 * ‐‐ * ‐‐ ‐‐9 MW‐14‐80 Monitoring 76 ‐ 81 75.67 73.88 74.8 74.75 0.87

10 MW‐19‐70 Monitoring 62 ‐ 67 Dry ‐‐ Dry ‐‐ ‐‐11 MW‐20‐70 Monitoring 63 ‐ 68 Dry ‐‐ Dry ‐‐ ‐‐12 MW‐21‐80 Monitoring 68 ‐ 78 74.16 74.23 73.88 74.51 0.2813 MW‐22‐75 Monitoring 69 ‐ 74 Dry ‐‐ Dry ‐‐ ‐‐14 MW‐26‐75 Monitoring 65 ‐ 75 * ‐‐ 72.8 73.30 ‐‐15 MW‐27‐70 Monitoring 60 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐16 RW‐01‐70 Monitoring 55 ‐ 70 Dry ‐‐ Dry ‐‐ ‐‐17 WW‐MW‐30A Monitoring 61 ‐ 66 NM ‐‐ NM ‐‐ ‐‐18 MW‐36‐80 Monitoring 67.5 ‐ 77.5 69.15 74.83 69.33 74.65 ‐0.1819 MW‐37‐80 Monitoring 68 ‐ 78 69.83 72.61 69.62 72.82 0.2120 MW‐38‐80 Monitoring 67.5 ‐ 77.5 69.51 73.02 69.58 72.95 ‐0.0721 DA‐01 Extraction 61 ‐ 76 68.11 72.60 68.60 72.11 ‐0.4922 DA‐02 Extraction 72 ‐ 82 67.48 71.22 65.93 72.77 1.5523 DA‐03 Extraction 74 ‐ 84 67.85 71.07 65.79 73.13 2.0624 DA‐04 Extraction 56 ‐ 66 Dry ‐‐ Dry ‐‐ ‐‐25 DA‐05 Extraction 68 ‐ 78 * ‐‐ 67.37 73.94 ‐‐26 DA‐06 Extraction 60 ‐ 70 Dry ‐‐ 68.3 72.23 ‐‐27 DA‐07 Extraction 61 ‐ 71 Dry ‐‐ Dry ‐‐ ‐‐28 DA‐08 Extraction 65 ‐ 75 * ‐‐ 65.32 75.31 ‐‐29 DA‐09 Extraction 66 ‐ 76 Dry ‐‐ Dry ‐‐ ‐‐20 DA‐10 Extraction 66 ‐ 76 Dry ‐‐ Dry ‐‐ ‐‐21 DA‐11 Extraction 64 ‐ 74 NM ‐‐ Dry ‐‐ ‐‐32 DA‐12 Extraction 66 ‐ 76 65.58 78.04 67.4 76.22 ‐1.82

Notes:1) Gauging data from the December 2015 semiannual groundwater monitoring event under dynamic (pumping) conditions.

3) "*" indicates the water level could not be determined due to the presence of an in‐well pump.

Acronyms: amsl = above mean sea level; btoc = below top of casing; ft = feet; NM = not measured; "‐‐" = not available.

Change in GW Elevation

2) Gauging data from July 8, 2016 collected during the July 2016 Semiannual groundwater monitoring event under static (non‐pumping) conditions.'A' Zone groundwater extraction wells were shut down on April 28,2016.

Well ID Well Type

December 4, 20151

Screen Interval (ft btoc)

July 8, 20162

OTIE Page 1 of 1

ATTACHMENT 2 Lab Report from Eurofins CalScience, Inc.

WORK ORDER NUMBER: 16-07-1384

Analytical Report ForClient: OTIE

Client Project Name: Pemaco - MonthlyAttention: Orval Osborne

317 East Main StreetVentura, CA 93001-2624

Approved for release on by:Virendra PatelProject Manager

AIR SOIL WATER MARINE CHEMISTRY

Eurofins Calscience, Inc. (Calscience) certifies that the test results provided in this report meet all NELAC requirements for parameters for which accreditation isrequired or available. Any exceptions to NELAC requirements are noted in the case narrative. The original report of subcontracted analyses, if any, is attached tothis report. The results in this report are limited to the sample(s) tested and any reproduction thereof must be made in its entirety. The client or recipient of thisreport is specifically prohibited from making material changes to said report and, to the extent that such changes are made, Calscience is not responsible, legally orotherwise. The client or recipient agrees to indemnify Calscience for any defense to any litigation which may arise.

08/04/2016

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7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Client Project Name: Pemaco - Monthly

Work Order Number: 16-07-1384

1 Work Order Narrative. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2 Sample Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

3 Detections Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

4 Client Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64.1 EPA 8260 SIM 1,4-Dioxane (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64.2 EPA 8260B Volatile Organics (Aqueous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

5 Quality Control Sample Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135.1 MS/MSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135.2 LCS/LCSD. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

6 Sample Analysis Summary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

7 Glossary of Terms and Qualifiers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

8 Chain-of-Custody/Sample Receipt Form. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

Page 2 of 19

Condition Upon Receipt: Samples were received under Chain-of-Custody (COC) on 07/20/16. They were assigned to Work Order 16-07-1384. Unless otherwise noted on the Sample Receiving forms all samples were received in good condition and within the

recommended EPA temperature criteria for the methods noted on the COC. The COC and Sample Receiving Documents are

integral elements of the analytical report and are presented at the back of the report. Holding Times: All samples were analyzed within prescribed holding times (HT) and/or in accordance with the Calscience Sample Acceptance

Policy unless otherwise noted in the analytical report and/or comprehensive case narrative, if required. Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15

minutes (40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being

received outside of the stated holding time unless received at the laboratory within 15 minutes of the collection time. Quality Control: All quality control parameters (QC) were within established control limits except where noted in the QC summary forms or

described further within this report. Subcontractor Information: Unless otherwise noted below (or on the subcontract form), no samples were subcontracted. Additional Comments: Air - Sorbent-extracted air methods (EPA TO-4A, EPA TO-10, EPA TO-13A, EPA TO-17): Analytical results are converted from

mass/sample basis to mass/volume basis using client-supplied air volumes. Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC

results are always reported on a wet weight basis.

Work Order Narrative


Work Order: 16-07-1384 Page 1 of 1

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Sample Identification Lab Number Collection Date and Time Number ofContainers

Matrix

SP-201-20160720 16-07-1384-1 07/20/16 12:00 10 Aqueous

SP-209-20160720 16-07-1384-2 07/20/16 11:30 10 Aqueous

Sample Summary


Client: OTIE

317 East Main Street

Ventura, CA 93001-2624

Work Order: 16-07-1384

Project Name: Pemaco - Monthly

PO Number: 2014166

Date/TimeReceived:

07/20/16 18:30

Number ofContainers:

20

Attn: Orval Osborne

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Subcontracted analyses, if any, are not included in this summary.

SP-201-20160720 (16-07-1384-1)

n-Butylbenzene 1.1 1.0 ug/L EPA 8260B EPA 5030C

sec-Butylbenzene 0.70 J 0.25* ug/L EPA 8260B EPA 5030C

Ethylbenzene 2.4 1.0 ug/L EPA 8260B EPA 5030C

Naphthalene 6.2 J 5.0* ug/L EPA 8260B EPA 5030C

n-Propylbenzene 0.75 J 0.17* ug/L EPA 8260B EPA 5030C

Trichloroethene 3.0 1.0 ug/L EPA 8260B EPA 5030C

1,2,4-Trimethylbenzene 0.39 J 0.36* ug/L EPA 8260B EPA 5030C

SP-209-20160720 (16-07-1384-2)

1,4-Dioxane 5.3 1.0 ug/L EPA 8260 SIM EPA 5030C

Chloroform 0.96 J 0.46* ug/L EPA 8260B EPA 5030C

1,1-Dichloroethane 1.2 1.0 ug/L EPA 8260B EPA 5030C

c-1,2-Dichloroethene 5.1 1.0 ug/L EPA 8260B EPA 5030C

Vinyl Chloride 0.32 J 0.30* ug/L EPA 8260B EPA 5030C

Detections Summary


Client: OTIE





Received: 07/20/16

Attn: Orval Osborne Page 1 of 1

Client SampleID

Analyte Result Qualifiers RL Units Method Extraction

* MDL is shown

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Client Sample Number Lab SampleNumber

Date/TimeCollected

Matrix Instrument DatePrepared

Date/TimeAnalyzed

QC Batch ID

SP-201-20160720 16-07-1384-1-H 07/20/1612:00

Aqueous GC/MS M 08/03/16 08/03/1612:58

160803L027

Comment(s): - The reporting limit is elevated resulting from matrix interference.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

1,4-Dioxane ND 50 18 50.0

Surrogate Rec. (%) Control Limits Qualifiers

1,4-Dichlorobutane 109 80-120

SP-209-20160720 16-07-1384-2-H 07/20/1611:30

Aqueous GC/MS M 08/03/16 08/03/1612:28

160803L027

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.


1,4-Dioxane 5.3 1.0 0.35 1.00



Method Blank 099-16-536-99 N/A Aqueous GC/MS M 08/03/16 08/03/1611:00

160803L027



1,4-Dioxane ND 1.0 0.35 1.00



Analytical Report


OTIE



Date Received: 07/20/16


Preparation: EPA 5030C

Method: EPA 8260 SIM

Units: ug/L

Project: Pemaco - Monthly Page 1 of 1

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-201-20160720 16-07-1384-1-A 07/20/1612:00

Aqueous GC/MS CC 07/21/16 07/22/1610:48

160721L036



Acetone ND 20 10 1.00

Benzene ND 0.50 0.14 1.00

Bromobenzene ND 1.0 0.30 1.00

Bromochloromethane ND 1.0 0.48 1.00

Bromodichloromethane ND 1.0 0.21 1.00

Bromoform ND 1.0 0.50 1.00

Bromomethane ND 10 3.9 1.00

2-Butanone ND 10 4.4 1.00

n-Butylbenzene 1.1 1.0 0.23 1.00

sec-Butylbenzene 0.70 1.0 0.25 1.00 J

tert-Butylbenzene ND 1.0 0.28 1.00

Carbon Disulfide ND 10 4.1 1.00

Carbon Tetrachloride ND 0.50 0.23 1.00

Chlorobenzene ND 1.0 0.17 1.00

Chloroethane ND 5.0 2.3 1.00

Chloroform ND 1.0 0.46 1.00

Chloromethane ND 10 3.5 1.00

2-Chlorotoluene ND 1.0 0.24 1.00


Dibromochloromethane ND 1.0 0.25 1.00

1,2-Dibromo-3-Chloropropane ND 5.0 1.2 1.00

1,2-Dibromoethane ND 1.0 0.36 1.00

Dibromomethane ND 1.0 0.46 1.00

1,2-Dichlorobenzene ND 1.0 0.46 1.00



Dichlorodifluoromethane ND 1.0 0.46 1.00

1,1-Dichloroethane ND 1.0 0.28 1.00


1,1-Dichloroethene ND 1.0 0.43 1.00

c-1,2-Dichloroethene ND 1.0 0.48 1.00

t-1,2-Dichloroethene ND 1.0 0.37 1.00

1,2-Dichloropropane ND 1.0 0.42 1.00


Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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1,1-Dichloropropene ND 1.0 0.46 1.00

c-1,3-Dichloropropene ND 0.50 0.25 1.00

t-1,3-Dichloropropene ND 0.50 0.25 1.00

Ethylbenzene 2.4 1.0 0.14 1.00

2-Hexanone ND 10 4.2 1.00

Isopropylbenzene ND 1.0 0.58 1.00

p-Isopropyltoluene ND 1.0 0.16 1.00

Methylene Chloride ND 10 3.8 1.00

4-Methyl-2-Pentanone ND 10 4.4 1.00

Naphthalene 6.2 10 5.0 1.00 J

n-Propylbenzene 0.75 1.0 0.17 1.00 J

Styrene ND 1.0 0.17 1.00

1,1,1,2-Tetrachloroethane ND 1.0 0.40 1.00


Tetrachloroethene ND 1.0 0.39 1.00

Toluene ND 1.0 0.24 1.00

1,2,3-Trichlorobenzene ND 1.0 0.51 1.00


1,1,1-Trichloroethane ND 1.0 0.30 1.00

1,1,2-Trichloro-1,2,2-Trifluoroethane ND 10 3.9 1.00


Trichloroethene 3.0 1.0 0.37 1.00

Trichlorofluoromethane ND 10 3.3 1.00

1,2,3-Trichloropropane ND 5.0 0.64 1.00

1,2,4-Trimethylbenzene 0.39 1.0 0.36 1.00 J

1,3,5-Trimethylbenzene ND 1.0 0.28 1.00

Vinyl Acetate ND 10 5.6 1.00

Vinyl Chloride ND 0.50 0.30 1.00

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00

Methyl-t-Butyl Ether (MTBE) ND 1.0 0.31 1.00


1,4-Bromofluorobenzene 101 80-120

Dibromofluoromethane 112 78-126

1,2-Dichloroethane-d4 111 75-135

Toluene-d8 101 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

SP-209-20160720 16-07-1384-2-A 07/20/1611:30

Aqueous GC/MS CC 07/21/16 07/22/1611:21

160721L036




Benzene ND 0.50 0.14 1.00







n-Butylbenzene ND 1.0 0.23 1.00

sec-Butylbenzene ND 1.0 0.25 1.00






Chloroform 0.96 1.0 0.46 1.00 J












1,1-Dichloroethane 1.2 1.0 0.28 1.00



c-1,2-Dichloroethene 5.1 1.0 0.48 1.00




Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Ethylbenzene ND 1.0 0.14 1.00






Naphthalene ND 10 5.0 1.00

n-Propylbenzene ND 1.0 0.17 1.00

Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00






Trichloroethene ND 1.0 0.37 1.00






Vinyl Chloride 0.32 0.50 0.30 1.00 J

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 98 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Date/TimeCollected


Date/TimeAnalyzed

QC Batch ID

Method Blank 099-14-001-20929 N/A Aqueous GC/MS CC 07/21/16 07/22/1606:38

160721L036




Benzene ND 0.50 0.14 1.00







n-Butylbenzene ND 1.0 0.23 1.00

sec-Butylbenzene ND 1.0 0.25 1.00






Chloroform ND 1.0 0.46 1.00















c-1,2-Dichloroethene ND 1.0 0.48 1.00




Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Ethylbenzene ND 1.0 0.14 1.00






Naphthalene ND 10 5.0 1.00

n-Propylbenzene ND 1.0 0.17 1.00

Styrene ND 1.0 0.17 1.00




Toluene ND 1.0 0.24 1.00

1,2,3-Trichlorobenzene 0.73 1.0 0.51 1.00 J

1,2,4-Trichlorobenzene 0.61 1.0 0.50 1.00 J




Trichloroethene ND 1.0 0.37 1.00






Vinyl Chloride ND 0.50 0.30 1.00

p/m-Xylene ND 1.0 0.30 1.00

o-Xylene ND 1.0 0.23 1.00






Toluene-d8 97 80-120

Analytical Report


OTIE






Method: EPA 8260B

Units: ug/L



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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed MS/MSD Batch Number

16-07-1757-2 Sample Aqueous GC/MS M 08/03/16 08/03/16 11:30 160803S012

16-07-1757-2 Matrix Spike Aqueous GC/MS M 08/03/16 08/03/16 14:55 160803S012

16-07-1757-2 Matrix Spike Duplicate Aqueous GC/MS M 08/03/16 08/03/16 15:25 160803S012

Parameter SampleConc.

SpikeAdded

MSConc.

MS%Rec.

MSDConc.

MSD%Rec.

%Rec. CL RPD RPD CL Qualifiers

1,4-Dioxane ND 100.0 94.82 95 94.30 94 80-120 1 0-20

Quality Control - Spike/Spike Duplicate


OTIE








RPD: Relative Percent Difference. CL: Control Limits

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Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS Batch Number

099-16-536-99 LCS Aqueous GC/MS M 08/03/16 08/03/16 09:51 160803L027

Parameter Spike Added Conc. Recovered LCS %Rec. %Rec. CL Qualifiers

1,4-Dioxane 20.00 17.15 86 80-120

Quality Control - LCS


OTIE









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Total number of LCS compounds: 14

Total number of ME compounds: 0

Total number of ME compounds allowed: 1

LCS ME CL validation result: Pass

Quality Control Sample ID Type Matrix Instrument Date Prepared Date Analyzed LCS/LCSD Batch Number

099-14-001-20929 LCS Aqueous GC/MS CC 07/21/16 07/22/16 05:06 160721L036

099-14-001-20929 LCSD Aqueous GC/MS CC 07/21/16 07/22/16 05:36 160721L036

Parameter SpikeAdded

LCS Conc. LCS%Rec.

LCSDConc.

LCSD%Rec.

%Rec. CL ME CL RPD RPD CL Qualifiers

Benzene 50.00 50.16 100 49.71 99 80-120 73-127 1 0-20

Carbon Tetrachloride 50.00 47.96 96 46.66 93 67-139 55-151 3 0-20

Chlorobenzene 50.00 50.84 102 49.90 100 78-120 71-127 2 0-20

1,2-Dibromoethane 50.00 52.75 105 52.03 104 80-120 73-127 1 0-20

1,2-Dichlorobenzene 50.00 50.74 101 50.19 100 63-129 52-140 1 0-20

1,2-Dichloroethane 50.00 44.06 88 43.21 86 70-130 60-140 2 0-20

1,1-Dichloroethene 50.00 50.54 101 50.18 100 66-126 56-136 1 0-20

Ethylbenzene 50.00 52.28 105 52.18 104 80-123 73-130 0 0-20

Toluene 50.00 49.78 100 49.64 99 80-120 73-127 0 0-20

Trichloroethene 50.00 53.12 106 53.54 107 80-122 73-129 1 0-20

Vinyl Chloride 50.00 44.26 89 43.84 88 70-130 60-140 1 0-20

p/m-Xylene 100.0 107.6 108 106.3 106 75-123 67-131 1 0-20

o-Xylene 50.00 54.17 108 53.59 107 74-122 66-130 1 0-20

Methyl-t-Butyl Ether (MTBE) 50.00 50.91 102 51.53 103 69-129 59-139 1 0-20

Quality Control - LCS/LCSD


OTIE






Method: EPA 8260B



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Method Extraction Chemist ID Instrument Analytical Location

EPA 8260 SIM EPA 5030C 486 GC/MS M 2

EPA 8260B EPA 5030C 1042 GC/MS CC 2

Sample Analysis Summary Report



Location 2: 7445 Lampson Avenue, Garden Grove, CA 92841

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Qualifiers Definition

* See applicable analysis comment.

< Less than the indicated value.

> Greater than the indicated value.

1 Surrogate compound recovery was out of control due to a required sample dilution. Therefore, the sample data was reported without furtherclarification.

2 Surrogate compound recovery was out of control due to matrix interference. The associated method blank surrogate spike compound wasin control and, therefore, the sample data was reported without further clarification.

3 Recovery of the Matrix Spike (MS) or Matrix Spike Duplicate (MSD) compound was out of control due to suspected matrix interference. Theassociated LCS recovery was in control.

4 The MS/MSD RPD was out of control due to suspected matrix interference.

5 The PDS/PDSD or PES/PESD associated with this batch of samples was out of control due to suspected matrix interference.

6 Surrogate recovery below the acceptance limit.

7 Surrogate recovery above the acceptance limit.

B Analyte was present in the associated method blank.

BU Sample analyzed after holding time expired.

BV Sample received after holding time expired.

CI See case narrative.

E Concentration exceeds the calibration range.

ET Sample was extracted past end of recommended max. holding time.

HD The chromatographic pattern was inconsistent with the profile of the reference fuel standard.

HDH The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but heavier hydrocarbonswere also present (or detected).

HDL The sample chromatographic pattern for TPH matches the chromatographic pattern of the specified standard but lighter hydrocarbons werealso present (or detected).

J Analyte was detected at a concentration below the reporting limit and above the laboratory method detection limit. Reported value isestimated.

JA Analyte positively identified but quantitation is an estimate.

ME LCS Recovery Percentage is within Marginal Exceedance (ME) Control Limit range (+/- 4 SD from the mean).

ND Parameter not detected at the indicated reporting limit.

Q Spike recovery and RPD control limits do not apply resulting from the parameter concentration in the sample exceeding the spikeconcentration by a factor of four or greater.

SG The sample extract was subjected to Silica Gel treatment prior to analysis.

X % Recovery and/or RPD out-of-range.

Z Analyte presence was not confirmed by second column or GC/MS analysis.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC results arereported on a wet weight basis.

Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15 minutes(40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being received outside of thestated holding time unless received at the laboratory within 15 minutes of the collection time.

A calculated total result (Example: Total Pesticides) is the summation of each component concentration and/or, if "J" flags are reported,estimated concentration. Component concentrations showing not detected (ND) are summed into the calculated total result as zeroconcentrations.

Glossary of Terms and Qualifiers



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Page 18 of 19

Chain of Custody

~

Report To:

Contact: Orval Osborne Company: OTIE fQIJ~ Address: 317 East Main Street Ventura, CA 93001

~-"T.~ OTIE

Phone: (805) 585-4313 Fax: (805)585-2111

317 East Ma in Street Ventura, CA 93001

E-Mail: [email protected]

Phone: (805) 585-2110 Fax: (805) 585-2111

Sampler Name: Brian Hendron


Project Location: 5973 S. District o,.,,, - r-" Qn?7n

Lab PM: Virendra Patel, Ca1Science 714-895-5494

Signature;..-,i1 l.. __ .• - .. -· ~n~-c .. - ;I~

Project ~umber: 2014166

Date Requested Standard TAT

kal:!orat9ry MS Client Sample ID

Sampling ID MSD Date Time

SP-201-20160720 7/20/16 12:00

SP-209-20160720 7/20/16 11 :30

.

: •· .

..

' 1

II

RELINQ ,1!51;LED BY~ L p COMPANY I,\ '\._ 'H./Jli Olif\t/J~ __

M t X

w w

G r a b

X

X

0 r.o N e (,)

~

X

X

DATE TIME

~-ai ~ -~ CJ? r:io .J-~ ,_..~

X

X

REUN< 1,1: IRED~ l ~ COMPANY ... ... .. 67oL01.b . .. I 5-, o

Bill To:

Contact: -------------

Company: -------------

Address --··18;.0J• 138I --~ Phone:-------------

Fax: --------------

PO#: _____ _ Quote: _____ _

ct;cl, COMPANY

-------·-· eci '--:J

WW = Wastewater W =Water S =Soil

Matrix Key SE = Sediment SO=Solid OS = Drum Solid DL = Drum Liquid L = Leachate WI =Wipe

Container Key 1. Plastic 2. VOAVial 3, sterile Plastic

Preservative Key ~ ~TS: OTIE-specific EDDs needed 1. HCI, Coolto4' .4 ioxane: 1 UQ/L RL 2. H2S04, Cool to 4' I/ 3. HN03, Cool to 4'

SL = Sludge MS = Miscellaneous OL =Oil A .=Air O = ____ _

4. Amber Glass 5. Widemouth Glass 6, Other

4. NaOH, Cool to 4' 5. NaOH/Zn Acetate, Cool t 4' 6, Cool to 4'

7. None

..

Shaded Areas For Internal Use Only 1 of 1

Lab Lot#

:

Pa9ij~9e.:$~~Jt;1c.f > · .. · .. S .•. •a ....•.•. ·.•.•v·.m··-·.·· .. • .. •e·.P.: .. :s'.f ....• e.:.' .•... • •... ··s .. 'NS.•·· .. ·.0e ...... · •. · .. a .. • .. 1 .. ea. :i · .. i/ .Yes '<ihilci>·'

.. · .. ,-.,,,. .. .·

Additional Analyses I Remarks

Field grab pH reading at 1130 = 7.44

VTS system is on, GTS is off

TIME

18.?Jo

Date Received

.

Courier: Hand DelivereO

Bill of Lading:

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Page 19 of 19. ' ' . : ;

-;~: eurofins WORK ORDER NUMBER:J16-07- 13 <64. Caisc .i enc.e

SAMPLE RECEIPT CHECKLIST COOLER _ I _OF_,_ !

DA1TE: 07 / a_o / 2016 CLIENT: -------------------TEMPERATURE: (Criteria: 0.0°C - 6.0°C, not frozen except sediment/tissue)

Thermometer ID: SC1B (CF: 0.0°C); Temperature (w/o CF): J. q 0 c (w/ CF): J. .C\ °C;¥9lank D Sample

D Sample(s) outside temperature criteria (PM/APM contacted by: )

D Sample(s) outside temperature criteria but received on ice/chilled on same day of sampling '

D Sample(s) received at ambient temperature; placed on ice for transport by courier

Ambient Temperature: D Air D Filter ' Checked by: G( I I

CUSTODY SEAL: ! :

Cooler D Present and Intact D Present but Not Intact _)2:('Not Present D NIA ; Checked by:

Checked by: Sample(s) D Present and Intact D Present but Not Intact .%Not Present D N/A I

' ; ;

SAMPLE CONDITION: (

:

Chain-of-Custody (COC) document(s) received with samples .. . ... .. ......... ... ... ... . ... .. ... . ... ..... . .. ; -r COC document(s) received complete .... ..... ... .. . ...... .. ...... ... .... .. . ...... ... ... .... .. ... ... ..... .. .. .. .. . :.J.

D Sampling date D Sampling time O Matrix ,~mber of containers · i

D No analysis requested D Not relinquished D No relinquished date D No relinquished tim~

Sampler's name indicated on COC .. ....... ... .... . ....... .. ...... .... .... .. .. .... ... ... .. . .. ..... .. . .. ... .. . ..... ,. !.

Sample container label(s) consistent with COC .. .... .. . .... .. ... .. .. .. ....... .. .. . ....... ........ ....... .. ... .. '. ./ .

Sample container(s) intact and in good condition .. .... .... .. . ... . . .... ... ..... .... .. ...... . .... .. .... .. .. ... .. '. l Proper containers for analyses requested ... ... .. .. ... .. .... .. .. . .. . ... ... .... .. ... . .... ..... . .. ... . . ... .. . .... . .

Sufficient volume/mass for analyses requested ... ..... . ..... . .... ....... . ...... .. .. ... .... .. .. .. . ... . .... . .... . '.

Samples received within holding time ....... ...... .... ..... .. ..... .... ..... .. ...... . ... . .. . ... ..... . .. ..... .. .... .. . .. ·. ;

Aqueous samples for certain analyses received within 15-minute holding time ; !

Yes

er' D

D pH D Residual Chlorine D Dissolved Sulfide D Dissolved Oxygen . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . D

Proper preservation chemical(s) noted on COC and/or sample container ..... .. .. .... .... ... . .. .. .. .... .. { A . Unpreserved aqueous sample(s) received for certain analyses

D Volatile Organics D Total Metals O Dissolved Metals

. i :

· l Container(s) for certain analysis free of headspace .... .. ... .. ... ..... .. .. .... .......... .. ... .. .. .. ..... . ..... . ... )Zf

~olatile Organics D Dissolved Gases (RSK-175) D Dissolved Oxygen (SM 4500) · i . D Carbon Dioxide (SM 4500) D Ferrous Iron (SM 3500) D Hydrogen Sulfide (Hach) ,

;

Tedlar™ bag(s) free of condensation : .

.. .. ....... . ... .. . . ...... . . ... .. ... . ... .... .. ... . .. . ... . ... ...... . .. . ... .. . ... .... 0

No

D

~

D

D

D

D

D

0

D

D

0

D

61 J

\Or]

NIA

D

D

D

D

D

D

0

D

D

D

~ CONTAINER TYPE: Q (Trip Blank Lot Num~er: _______ )

Aqueous: D VOA JZ) ~h D VOAna2 D 100PJ D 100PJna2 D 125AGB O 125AGBh D 12~AGBp D 125PB

D 125P8znna D 250AGB O 250CGB O 250CGBs D 250PB O 250PBn D 500AGB D 500Ac'.3J D SOOAGJs I

0500PB D1AGB D1AGBna2 01AGBs 01PB D1PBna D D O · : D __ _ : '

Solid: D 4ozCGJ D 8ozCGJ D 16ozCGJ D Sleeve(__) D Encores®(__) D TerraCore~® (__) D __ _

Air: D Tedlar™ D Canister D Sorbent Tube D PUF D Other Matrix ( ): !o D ---Container: A :a Amber, B :a: Bottle. C = Clear, E = Envelope, G :a Glass, J = Jar, P = Plastic, and Z :a Ziploc/R~sealable Bag

Preservative: b = buffered. f = filtered. h :a HCI, n = HN03, na :a NaOH, na2 = Na2S20 3, p :a H, P04, Labe/ed/Checked by: \ Ol I s = H2S04, u :a ultra-pure, znna = Zn(CH3C02)2 + NaOH I Reviewed by: G~ ·

2015-04-10 Revision

t

ATTACHMENT 3Lab Report from ALS Environmental

2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com

R I G H T S O L U T I O N S | R I G H T P A R T N E R

LABORATORY REPORT

August 9, 2016

Orval Osborne Oneida Total Integrated Enterprises (OTIE) 317 E. Main St. Ventura, CA 93001

RE: Pemaco-Plant Vapor Monitoring

Dear Orval:

Enclosed are the results of the samples submitted to our laboratory on July 20, 2016. For your reference, these analyses have been assigned our service request number P1603624.

All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein.

If you have any questions, please call me at (805) 526-7161.

Respectfully submitted,

ALS | Environmental

Kelly Horiuchi Laboratory Director

1 of 100

http://www.alsglobal.com/


kelly.horiuchi

Kelly



Client: Oneida Total Integrated Enterprises (OTIE) Service Request No: P1603624 Project: Pemaco-Plant Vapor Monitoring _______________________________________________________________________________

CASE NARRATIVE

The samples were received intact under chain of custody on July 20, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt.

Volatile Organic Compound Analysis

The samples were analyzed for volatile organic compounds in accordance with EPA Method TO-15 from the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), January, 1999. This procedure is described in laboratory SOP VOA-TO15. The analytical system was comprised of a gas chromatograph / mass spectrometer (GC/MS) interfaced to a whole-air preconcentrator. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP, LLC accreditation. Any analytes flagged with an X are not included on the NELAP or DoD-ELAP accreditation.

The containers were cleaned, prior to sampling, down to the method reporting limit (MRL) reported for this project. Please note, projects which require reporting below the MRL could have results between the MRL and method detection limit (MDL) that are biased high. _____________________________________________________________________________________

The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report.

Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory.

2 of 100




ALS Environmental – Simi Valley

CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS

Agency Web Site Number

AIHA-LAP, LLC http://www.aihaaccreditedlabs.org 101661

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694

PJLA (DoD ELAP)

http://www.pjlabs.com/search-accredited-labs 65818

(Testing) Florida DOH (NELAP)

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020

Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

2014025

Minnesota DOH (NELAP)

http://www.health.state.mn.us/accreditation 977273

New Jersey DEP (NELAP)

http://www.nj.gov/dep/oqa/ CA009

New York DOH (NELAP)

http://www.wadsworth.org/labcert/elap/elap.html 11221

Oregon PHD (NELAP)

http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx

4068-003

Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307

(Registration) Texas CEQ (NELAP)

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413-

16-7 Utah DOH (NELAP)

http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201

6-6

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946

Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website.

Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification.

3 of 100


http://www.aihaaccreditedlabs.org/

http://www.azdhs.gov/lab/license/env.htm

http://www.pjlabs.com/search-accredited-labs

http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp-services/labcert/labcert.htm

http://www.health.state.mn.us/accreditation

http://www.nj.gov/dep/oqa/

http://www.wadsworth.org/labcert/elap/elap.html



http://www.depweb.state.pa.us/labs

http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html

http://www.health.utah.gov/lab/labimp/certification/index.html

http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html


P1603624_Detail Summary_1608021442_RG.xls - DETAIL SUMMARY

Client: Oneida Total Integrated Enterprises (OTIE) Service Request: P1603624Project ID: Pemaco-Plant Vapor Monitoring

Date Received: 7/20/2016Time Received: 11:10

Client Sample ID Lab Code MatrixDate

CollectedTime

CollectedContainer

IDPi1

(psig)Pf1

(psig)

SP-106-20160720 P1603624-001 Air 7/20/2016 09:50 1BV06769 -0.18 6.12 XSP-104-20160720 P1603624-002 Air 7/20/2016 10:00 1BV06767 0.15 5.15 X

ALS ENVIRONMENTAL

DETAIL SUMMARY REPORT

TO-1

5 - V

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Can

s

4 of 100

5 o

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0

ALS Environmental 265S Pa rte Center Olive, &ilt9 A

Simi Volley. CA 9305.S

TEL: (80&) 626•7181 , FAX: (805) 526-7220

LA80RA TORY cuon\ OTIE

ADDRESS:

317 E. Main Street Ventura CA 93001

IE.1.: '"'"· '

"

.

f _r,//..1\ ,t ~\:I CHAIN OF CUSTODY RECORD

.,\\If DATE: 7/20/2016 \\

PAGB: ___ ..a1 ___ 0F

. ' P.O.NO.: •··

Pemaco • Plant Vapor Monitorina 2014166 PROJECT CONTACT: ·. ~~ltooor Orval O&borne SAUF\.ER(S). l'SIGtU\.TURE) Bri~n Hendron COEL T LOG CODE ,ll(>,llaERR~IP.r ···;·· ,:,:;: ::~~ ~ 6,,,~11.. DD DD tr¥:~}'' :.;.:.:.;.:.:<:.

805.585.4313 805.585.2111 .. oosbometa>otie.oom . ... ·····················•·····. TURl>lf\ROUHQTf,...

0SAMEDAY 024HR n 48HR 072HR D ~DAYS @,lODAYS ., REQ,l)ESTED ANALYSIS SPECIAL Af:411RE:.\FIIT'&(AOOmo11A.l COSTS~i\YAPF\. Y) .. ·,

D D D ' Sl>l::CIAL IN$TRUCTIONS ! . • -. .

Please repon EDDs in both ppmv and mglm3 l'.' " SP-108 started at -29.92 ...

SP-104 started at -29.93 g ll ·:~;,: SAMPUNO ..,.m, ..

;'11,\l~i $AMPLE 10 Fi•ld Point Ntme ""''· " i\,'l)I~'( DATE llME X 0 > CONTAJNl:R TYPE

::·r . ..,

J\ \ SP-106-20160720 V•PO•~P-106 07/20/16 9:50 air 1 X Bottle 1BV06769

:• · ,'•j SP-'104·20160720 ~

Va nor SP .. 104 07/20/16 10:00 air 1 X Bottle 1BV06787

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I ·~5.S S), . ..rt:-,/ ?f2o/11c, /() J. C)/") Rel-·00$ .. : (Sigoaw••> Rec>),'\lsd by: ($lgnst1Jre) Ost&: Time:

Te.S.5> Ou.-vA, ./ -. ~ -,, ?..0 - If 11!}6 Rs1riqu1sMO ov: CSi)l•u,e> Reoefllsd by: (SlgnstlJ~ .. ~ O&ls: 1lrt1e: .

/'

8/9/16 9:03 AMP1603624_Oneida Total Integrated Enterprises (OTIE)_Pemaco-Plant Vapor Monitoring.xls - Page 1 of 1

ALS EnvironmentalSample Acceptance Check Form

Client: Oneida Total Integrated Enterprises (OTIE) Work order: P1603624Project: Pemaco-Plant Vapor MonitoringSample(s) received on: 7/20/16 Date opened: 7/20/16 by: KKELPE

Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of

compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A

1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to?

8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)? Sealing Lid?

Were signature and date included? Were seals intact?

9 Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?

10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact?

Are dual bed badges separated and individually capped and intact?

Lab Sample ID Container Required Received Adjusted VOA HeadspaceDescription pH * pH pH (Presence/Absence) Comments

1.0 L Bottle-Vac™1.0 L Bottle-Vac™

RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4)

Explain any discrepancies: (include lab sample ID numbers):

Do containers have appropriate preservation, according to method/SOP or Client specified information?

Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it?

Receipt / Preservation

P1603624-001.01P1603624-002.01

6 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - Sample

ALS ENVIRONMENTAL

RESULTS OF ANALYSISPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)SP-106-20160720 ALS Project ID: P1603624

ALS Sample ID: P1603624-001

Test Code: EPA TO-15 Modified Date Collected: 7/20/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Date Received: 7/20/16Analyst: Simon Cao Date Analyzed: 7/22/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes: Container ID: 1BV06769

Initial Pressure (psig): -0.18 Final Pressure (psig): 6.12

Canister Dilution Factor: 1.43

CAS # Compound MRL MDL MRL MDL Dataµg/m³ µg/m³ ppbV ppbV Qualifier

115-07-1 Propene ND 1.8 0.50 ND 1.0 0.2975-71-8 Dichlorodifluoromethane (CFC 12) 5.1 1.8 0.61 1.0 0.36 0.1274-87-3 Chloromethane 1.2 1.8 0.54 0.57 0.87 0.26 J

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 1.8 0.68 ND 0.26 0.097

75-01-4 Vinyl Chloride 6.2 1.8 0.61 2.4 0.70 0.24106-99-0 1,3-Butadiene ND 1.8 0.79 ND 0.81 0.3674-83-9 Bromomethane ND 1.8 0.68 ND 0.46 0.1775-00-3 Chloroethane ND 1.8 0.61 ND 0.68 0.2364-17-5 Ethanol 22 18 2.9 12 9.5 1.575-05-8 Acetonitrile ND 1.8 0.64 ND 1.1 0.38107-02-8 Acrolein 0.64 7.2 0.61 0.28 3.1 0.27 J67-64-1 Acetone 43 18 2.8 18 7.5 1.2 B75-69-4 Trichlorofluoromethane ND 1.8 0.61 ND 0.32 0.1167-63-0 2-Propanol (Isopropyl Alcohol) 4.2 18 1.5 1.7 7.3 0.61 J107-13-1 Acrylonitrile ND 1.8 0.61 ND 0.82 0.2875-35-4 1,1-Dichloroethene ND 1.8 0.61 ND 0.45 0.1575-09-2 Methylene Chloride ND 1.8 0.61 ND 0.51 0.18107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 1.8 0.57 ND 0.57 0.1876-13-1 Trichlorotrifluoroethane ND 1.8 0.61 ND 0.23 0.07975-15-0 Carbon Disulfide ND 18 0.54 ND 5.7 0.17156-60-5 trans-1,2-Dichloroethene ND 1.8 0.68 ND 0.45 0.1775-34-3 1,1-Dichloroethane ND 1.8 0.57 ND 0.44 0.141634-04-4 Methyl tert-Butyl Ether ND 1.8 0.61 ND 0.50 0.17108-05-4 Vinyl Acetate ND 18 2.3 ND 5.1 0.6678-93-3 2-Butanone (MEK) 3.7 18 0.75 1.3 6.1 0.25 J

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL.B = Analyte detected in both the sample and associated method blank.

Client Sample ID:Client Project ID:

ResultppbV

Resultµg/m³

Pemaco-Plant Vapor Monitoring

7 of 100


ALS ENVIRONMENTAL




Test Code: EPA TO-15 Modified Date Collected: 7/20/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Date Received: 7/20/16Analyst: Simon Cao Date Analyzed: 7/22/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.40 Liter(s)Test Notes:Container ID: 1BV06769




156-59-2 cis-1,2-Dichloroethene ND 1.8 0.57 ND 0.45 0.14141-78-6 Ethyl Acetate ND 3.6 1.3 ND 0.99 0.35110-54-3 n-Hexane 0.87 1.8 0.54 0.25 0.51 0.15 J67-66-3 Chloroform ND 1.8 0.61 ND 0.37 0.12109-99-9 Tetrahydrofuran (THF) 0.80 1.8 0.72 0.27 0.61 0.24 J107-06-2 1,2-Dichloroethane ND 1.8 0.57 ND 0.44 0.1471-55-6 1,1,1-Trichloroethane ND 1.8 0.61 ND 0.33 0.1171-43-2 Benzene ND 1.8 0.57 ND 0.56 0.1856-23-5 Carbon Tetrachloride ND 1.8 0.54 ND 0.28 0.085110-82-7 Cyclohexane ND 3.6 1.0 ND 1.0 0.3078-87-5 1,2-Dichloropropane ND 1.8 0.57 ND 0.39 0.1275-27-4 Bromodichloromethane ND 1.8 0.54 ND 0.27 0.08079-01-6 Trichloroethene ND 1.8 0.50 ND 0.33 0.093123-91-1 1,4-Dioxane ND 1.8 0.57 ND 0.50 0.1680-62-6 Methyl Methacrylate ND 3.6 1.1 ND 0.87 0.27142-82-5 n-Heptane ND 1.8 0.61 ND 0.44 0.1510061-01-5 cis-1,3-Dichloropropene ND 1.8 0.50 ND 0.39 0.11108-10-1 4-Methyl-2-pentanone ND 1.8 0.57 ND 0.44 0.1410061-02-6 trans-1,3-Dichloropropene ND 1.8 0.57 ND 0.39 0.1379-00-5 1,1,2-Trichloroethane ND 1.8 0.57 ND 0.33 0.10108-88-3 Toluene 0.66 1.8 0.61 0.18 0.47 0.16 J591-78-6 2-Hexanone ND 1.8 0.57 ND 0.44 0.14124-48-1 Dibromochloromethane ND 1.8 0.57 ND 0.21 0.067106-93-4 1,2-Dibromoethane ND 1.8 0.57 ND 0.23 0.074123-86-4 n-Butyl Acetate ND 1.8 0.57 ND 0.38 0.12

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL.


Resultµg/m³

Result


ppbV

8 of 100


ALS ENVIRONMENTAL







MRL MDL MRL MDL Data CAS # Compound µg/m³ µg/m³ ppbV ppbV Qualifier

111-65-9 n-Octane ND 1.8 0.64 ND 0.38 0.14127-18-4 Tetrachloroethene 0.95 1.8 0.50 0.14 0.26 0.074 J108-90-7 Chlorobenzene ND 1.8 0.57 ND 0.39 0.12100-41-4 Ethylbenzene ND 1.8 0.57 ND 0.41 0.13179601-23-1 m,p-Xylenes ND 3.6 1.1 ND 0.82 0.2575-25-2 Bromoform ND 1.8 0.54 ND 0.17 0.052100-42-5 Styrene ND 1.8 0.54 ND 0.42 0.1395-47-6 o-Xylene ND 1.8 0.54 ND 0.41 0.12111-84-2 n-Nonane ND 1.8 0.54 ND 0.34 0.1079-34-5 1,1,2,2-Tetrachloroethane ND 1.8 0.54 ND 0.26 0.07898-82-8 Cumene ND 1.8 0.54 ND 0.36 0.1180-56-8 alpha-Pinene ND 1.8 0.50 ND 0.32 0.090103-65-1 n-Propylbenzene ND 1.8 0.57 ND 0.36 0.12622-96-8 4-Ethyltoluene ND 1.8 0.57 ND 0.36 0.12108-67-8 1,3,5-Trimethylbenzene ND 1.8 0.57 ND 0.36 0.1295-63-6 1,2,4-Trimethylbenzene ND 1.8 0.54 ND 0.36 0.11100-44-7 Benzyl Chloride ND 1.8 0.39 ND 0.35 0.076541-73-1 1,3-Dichlorobenzene ND 1.8 0.54 ND 0.30 0.089106-46-7 1,4-Dichlorobenzene ND 1.8 0.50 ND 0.30 0.08395-50-1 1,2-Dichlorobenzene ND 1.8 0.54 ND 0.30 0.0895989-27-5 d-Limonene ND 1.8 0.50 ND 0.32 0.09096-12-8 1,2-Dibromo-3-chloropropane ND 1.8 0.35 ND 0.19 0.037120-82-1 1,2,4-Trichlorobenzene ND 1.8 0.57 ND 0.24 0.07791-20-3 Naphthalene ND 1.8 0.64 ND 0.34 0.1287-68-3 Hexachlorobutadiene ND 1.8 0.50 ND 0.17 0.047


ResultResultµg/m³

Client Project ID:

ppbV

Client Sample ID:Pemaco-Plant Vapor Monitoring

9 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - Sample (2)

ALS ENVIRONMENTAL




Test Code: EPA TO-15 Modified Date Collected: 7/20/16Instrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Date Received: 7/20/16Analyst: Simon Cao Date Analyzed: 7/22/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 0.0040 Liter(s)Test Notes:Container ID: 1BV06767

Initial Pressure (psig): 0.15 Final Pressure (psig): 5.15



115-07-1 Propene ND 170 47 ND 97 2775-71-8 Dichlorodifluoromethane (CFC 12) ND 170 57 ND 34 1274-87-3 Chloromethane ND 170 50 ND 81 24

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 170 64 ND 24 9.1

75-01-4 Vinyl Chloride ND 170 57 ND 66 22106-99-0 1,3-Butadiene ND 170 74 ND 76 3374-83-9 Bromomethane ND 170 64 ND 43 1675-00-3 Chloroethane ND 170 57 ND 64 2264-17-5 Ethanol ND 1,700 270 ND 890 14075-05-8 Acetonitrile ND 170 60 ND 100 36107-02-8 Acrolein ND 670 57 ND 290 2567-64-1 Acetone ND 1,700 260 ND 710 11075-69-4 Trichlorofluoromethane ND 170 57 ND 30 1067-63-0 2-Propanol (Isopropyl Alcohol) ND 1,700 140 ND 680 57107-13-1 Acrylonitrile ND 170 57 ND 77 2675-35-4 1,1-Dichloroethene ND 170 57 ND 42 1475-09-2 Methylene Chloride ND 170 57 ND 48 16107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 170 54 ND 54 1776-13-1 Trichlorotrifluoroethane ND 170 57 ND 22 7.475-15-0 Carbon Disulfide ND 1,700 50 ND 540 16156-60-5 trans-1,2-Dichloroethene ND 170 64 ND 42 1675-34-3 1,1-Dichloroethane ND 170 54 ND 41 131634-04-4 Methyl tert-Butyl Ether ND 170 57 ND 46 16108-05-4 Vinyl Acetate ND 1,700 220 ND 480 6278-93-3 2-Butanone (MEK) ND 1,700 70 ND 570 24

ND = Compound was analyzed for, but not detected above the laboratory detection limit.MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method.

ResultppbV

Resultµg/m³

Client Sample ID:Client Project ID: Pemaco-Plant Vapor Monitoring

10 of 100


ALS ENVIRONMENTAL








156-59-2 cis-1,2-Dichloroethene ND 170 54 ND 42 14141-78-6 Ethyl Acetate ND 340 120 ND 93 33110-54-3 n-Hexane 440 170 50 130 48 1467-66-3 Chloroform ND 170 57 ND 34 12109-99-9 Tetrahydrofuran (THF) ND 170 67 ND 57 23107-06-2 1,2-Dichloroethane ND 170 54 ND 41 1371-55-6 1,1,1-Trichloroethane ND 170 57 ND 31 1071-43-2 Benzene ND 170 54 ND 52 1756-23-5 Carbon Tetrachloride ND 170 50 ND 27 8.0110-82-7 Cyclohexane 350 340 97 100 97 2878-87-5 1,2-Dichloropropane ND 170 54 ND 36 1275-27-4 Bromodichloromethane ND 170 50 ND 25 7.579-01-6 Trichloroethene 300 170 47 56 31 8.7123-91-1 1,4-Dioxane ND 170 54 ND 46 1580-62-6 Methyl Methacrylate ND 340 100 ND 82 25142-82-5 n-Heptane 160 170 57 39 41 14 J10061-01-5 cis-1,3-Dichloropropene ND 170 47 ND 37 10108-10-1 4-Methyl-2-pentanone ND 170 54 ND 41 1310061-02-6 trans-1,3-Dichloropropene ND 170 54 ND 37 1279-00-5 1,1,2-Trichloroethane ND 170 54 ND 31 9.8108-88-3 Toluene ND 170 57 ND 44 15591-78-6 2-Hexanone ND 170 54 ND 41 13124-48-1 Dibromochloromethane ND 170 54 ND 20 6.3106-93-4 1,2-Dibromoethane ND 170 54 ND 22 7.0123-86-4 n-Butyl Acetate ND 170 54 ND 35 11


ppbVResultµg/m³

Result


11 of 100


ALS ENVIRONMENTAL








111-65-9 n-Octane ND 170 60 ND 36 13127-18-4 Tetrachloroethene 54 170 47 8.0 25 6.9 J108-90-7 Chlorobenzene ND 170 54 ND 36 12100-41-4 Ethylbenzene 5,000 170 54 1,200 39 12179601-23-1 m,p-Xylenes ND 340 100 ND 77 2375-25-2 Bromoform ND 170 50 ND 16 4.9100-42-5 Styrene ND 170 50 ND 39 1295-47-6 o-Xylene ND 170 50 ND 39 12111-84-2 n-Nonane ND 170 50 ND 32 9.679-34-5 1,1,2,2-Tetrachloroethane ND 170 50 ND 24 7.398-82-8 Cumene 450 170 50 92 34 1080-56-8 alpha-Pinene ND 170 47 ND 30 8.4103-65-1 n-Propylbenzene 1,200 170 54 240 34 11622-96-8 4-Ethyltoluene ND 170 54 ND 34 11108-67-8 1,3,5-Trimethylbenzene ND 170 54 ND 34 1195-63-6 1,2,4-Trimethylbenzene ND 170 50 ND 34 10100-44-7 Benzyl Chloride ND 170 37 ND 32 7.1541-73-1 1,3-Dichlorobenzene ND 170 50 ND 28 8.4106-46-7 1,4-Dichlorobenzene ND 170 47 ND 28 7.895-50-1 1,2-Dichlorobenzene ND 170 50 ND 28 8.45989-27-5 d-Limonene ND 170 47 ND 30 8.496-12-8 1,2-Dibromo-3-chloropropane ND 170 33 ND 17 3.4120-82-1 1,2,4-Trichlorobenzene ND 170 54 ND 23 7.291-20-3 Naphthalene ND 170 60 ND 32 1287-68-3 Hexachlorobutadiene ND 170 47 ND 16 4.4


µg/m³

Client Project ID:

ppbV

Client Sample ID:

ResultResult


12 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - MBlank

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE)Method Blank ALS Project ID: P1603624

ALS Sample ID: P160722-MB

Test Code: EPA TO-15 Modified Date Collected: NAInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Date Received: NAAnalyst: Simon Cao Date Analyzed: 7/22/16Sample Type: 1.0 L Bottle-Vac™ Volume(s) Analyzed: 1.00 Liter(s)Test Notes:



115-07-1 Propene ND 0.50 0.14 ND 0.29 0.08175-71-8 Dichlorodifluoromethane (CFC 12) ND 0.50 0.17 ND 0.10 0.03474-87-3 Chloromethane ND 0.50 0.15 ND 0.24 0.073

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) ND 0.50 0.19 ND 0.072 0.027

75-01-4 Vinyl Chloride ND 0.50 0.17 ND 0.20 0.067106-99-0 1,3-Butadiene ND 0.50 0.22 ND 0.23 0.09974-83-9 Bromomethane ND 0.50 0.19 ND 0.13 0.04975-00-3 Chloroethane ND 0.50 0.17 ND 0.19 0.06464-17-5 Ethanol ND 5.0 0.80 ND 2.7 0.4275-05-8 Acetonitrile ND 0.50 0.18 ND 0.30 0.11107-02-8 Acrolein ND 2.0 0.17 ND 0.87 0.07467-64-1 Acetone 1.0 5.0 0.77 0.42 2.1 0.32 J75-69-4 Trichlorofluoromethane ND 0.50 0.17 ND 0.089 0.03067-63-0 2-Propanol (Isopropyl Alcohol) ND 5.0 0.42 ND 2.0 0.17107-13-1 Acrylonitrile ND 0.50 0.17 ND 0.23 0.07875-35-4 1,1-Dichloroethene ND 0.50 0.17 ND 0.13 0.04375-09-2 Methylene Chloride ND 0.50 0.17 ND 0.14 0.049107-05-1 3-Chloro-1-propene (Allyl Chloride) ND 0.50 0.16 ND 0.16 0.05176-13-1 Trichlorotrifluoroethane ND 0.50 0.17 ND 0.065 0.02275-15-0 Carbon Disulfide ND 5.0 0.15 ND 1.6 0.048156-60-5 trans-1,2-Dichloroethene ND 0.50 0.19 ND 0.13 0.04875-34-3 1,1-Dichloroethane ND 0.50 0.16 ND 0.12 0.0401634-04-4 Methyl tert-Butyl Ether ND 0.50 0.17 ND 0.14 0.047108-05-4 Vinyl Acetate ND 5.0 0.65 ND 1.4 0.1878-93-3 2-Butanone (MEK) ND 5.0 0.21 ND 1.7 0.071


ResultppbV

Resultµg/m³


13 of 100


ALS ENVIRONMENTAL







156-59-2 cis-1,2-Dichloroethene ND 0.50 0.16 ND 0.13 0.040141-78-6 Ethyl Acetate ND 1.0 0.35 ND 0.28 0.097110-54-3 n-Hexane ND 0.50 0.15 ND 0.14 0.04367-66-3 Chloroform ND 0.50 0.17 ND 0.10 0.035109-99-9 Tetrahydrofuran (THF) ND 0.50 0.20 ND 0.17 0.068107-06-2 1,2-Dichloroethane ND 0.50 0.16 ND 0.12 0.04071-55-6 1,1,1-Trichloroethane ND 0.50 0.17 ND 0.092 0.03171-43-2 Benzene ND 0.50 0.16 ND 0.16 0.05056-23-5 Carbon Tetrachloride ND 0.50 0.15 ND 0.080 0.024110-82-7 Cyclohexane ND 1.0 0.29 ND 0.29 0.08478-87-5 1,2-Dichloropropane ND 0.50 0.16 ND 0.11 0.03575-27-4 Bromodichloromethane ND 0.50 0.15 ND 0.075 0.02279-01-6 Trichloroethene ND 0.50 0.14 ND 0.093 0.026123-91-1 1,4-Dioxane ND 0.50 0.16 ND 0.14 0.04480-62-6 Methyl Methacrylate ND 1.0 0.31 ND 0.24 0.076142-82-5 n-Heptane ND 0.50 0.17 ND 0.12 0.04110061-01-5 cis-1,3-Dichloropropene ND 0.50 0.14 ND 0.11 0.031108-10-1 4-Methyl-2-pentanone ND 0.50 0.16 ND 0.12 0.03910061-02-6 trans-1,3-Dichloropropene ND 0.50 0.16 ND 0.11 0.03579-00-5 1,1,2-Trichloroethane ND 0.50 0.16 ND 0.092 0.029108-88-3 Toluene ND 0.50 0.17 ND 0.13 0.045591-78-6 2-Hexanone ND 0.50 0.16 ND 0.12 0.039124-48-1 Dibromochloromethane ND 0.50 0.16 ND 0.059 0.019106-93-4 1,2-Dibromoethane ND 0.50 0.16 ND 0.065 0.021123-86-4 n-Butyl Acetate ND 0.50 0.16 ND 0.11 0.034


ResultppbV


Resultµg/m³


14 of 100


ALS ENVIRONMENTAL







111-65-9 n-Octane ND 0.50 0.18 ND 0.11 0.039127-18-4 Tetrachloroethene ND 0.50 0.14 ND 0.074 0.021108-90-7 Chlorobenzene ND 0.50 0.16 ND 0.11 0.035100-41-4 Ethylbenzene ND 0.50 0.16 ND 0.12 0.037179601-23-1 m,p-Xylenes ND 1.0 0.30 ND 0.23 0.06975-25-2 Bromoform ND 0.50 0.15 ND 0.048 0.015100-42-5 Styrene ND 0.50 0.15 ND 0.12 0.03595-47-6 o-Xylene ND 0.50 0.15 ND 0.12 0.035111-84-2 n-Nonane ND 0.50 0.15 ND 0.095 0.02979-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.15 ND 0.073 0.02298-82-8 Cumene ND 0.50 0.15 ND 0.10 0.03180-56-8 alpha-Pinene ND 0.50 0.14 ND 0.090 0.025103-65-1 n-Propylbenzene ND 0.50 0.16 ND 0.10 0.033622-96-8 4-Ethyltoluene ND 0.50 0.16 ND 0.10 0.033108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ND 0.10 0.03395-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ND 0.10 0.031100-44-7 Benzyl Chloride ND 0.50 0.11 ND 0.097 0.021541-73-1 1,3-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.025106-46-7 1,4-Dichlorobenzene ND 0.50 0.14 ND 0.083 0.02395-50-1 1,2-Dichlorobenzene ND 0.50 0.15 ND 0.083 0.0255989-27-5 d-Limonene ND 0.50 0.14 ND 0.090 0.02596-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.099 ND 0.052 0.010120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.16 ND 0.067 0.02291-20-3 Naphthalene ND 0.50 0.18 ND 0.095 0.03487-68-3 Hexachlorobutadiene ND 0.50 0.14 ND 0.047 0.013


ppbV


Resultµg/m³


Result

15 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - Surrogates

ALS ENVIRONMENTAL

SURROGATE SPIKE RECOVERY RESULTSPage 1 of 1

Client: Oneida Total Integrated Enterprises (OTIE)ALS Project ID: P1603624

Test Code: EPA TO-15 ModifiedInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Date(s) Collected: 7/20/16Analyst: Simon Cao Date(s) Received: 7/20/16Sample Type: 1.0 L Bottle-Vac™(s) Date(s) Analyzed: 7/22/16Test Notes:

Client Sample ID ALS Sample ID Acceptance DataLimits Qualifier

P160722-MB 70-130 P160722-LCS 70-130 P1603624-001 70-130 P1603624-002 70-130

Surrogate percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly from the on-column percent recovery.

PercentToluene-d81,2-Dichloroethane-d4


Percent

Lab Control Sample 10910383106107

Recovered86

Bromofluorobenzene

Client Project ID:

SP-106-20160720SP-104-20160720

RecoveredRecoveredPercent

Method Blank

8081 115

112101119

16 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - LCS

ALS ENVIRONMENTAL

LABORATORY CONTROL SAMPLE SUMMARYPage 1 of 3

Client: Oneida Total Integrated Enterprises (OTIE)Lab Control Sample ALS Project ID: P1603624

ALS Sample ID: P160722-LCS


CAS # Compound DataQualifier

115-07-1 Propene 98 49-13175-71-8 Dichlorodifluoromethane (CFC 12) 96 65-11774-87-3 Chloromethane 101 48-132

76-14-2 1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC 114) 110 65-122

75-01-4 Vinyl Chloride 101 65-128106-99-0 1,3-Butadiene 115 62-14374-83-9 Bromomethane 107 65-13075-00-3 Chloroethane 110 69-12664-17-5 Ethanol 107 57-12675-05-8 Acetonitrile 94 51-134107-02-8 Acrolein 102 55-14667-64-1 Acetone 104 57-12075-69-4 Trichlorofluoromethane 88 59-13967-63-0 2-Propanol (Isopropyl Alcohol) 103 59-129107-13-1 Acrylonitrile 102 64-13675-35-4 1,1-Dichloroethene 113 72-12375-09-2 Methylene Chloride 115 63-117107-05-1 3-Chloro-1-propene (Allyl Chloride) 106 50-14176-13-1 Trichlorotrifluoroethane 111 68-11875-15-0 Carbon Disulfide 101 55-143156-60-5 trans-1,2-Dichloroethene 116 69-12975-34-3 1,1-Dichloroethane 101 66-1221634-04-4 Methyl tert-Butyl Ether 102 55-128108-05-4 Vinyl Acetate 116 66-14078-93-3 2-Butanone (MEK) 108 62-127

Laboratory Control Sample percent recovery is verified and accepted based on the on-column result.Reported results are shown in concentration units and as a result of the calculation, may vary slightly.

255218 231

1,040

212216

213244

1210

214220

Result

210

222

216

245

212216 245

220

201


200

202

204200

196188


200

ALSAcceptanceSpike Amount

Limits

206

193180

% Recoveryµg/m³ µg/m³

202237

224

212

217200998

2201070

430

214 2191,080216

1120190

418

237220

210

17 of 100


ALS ENVIRONMENTAL





CAS # Compound Data Qualifier

156-59-2 cis-1,2-Dichloroethene 106 65-125141-78-6 Ethyl Acetate 110 64-132110-54-3 n-Hexane 102 58-12667-66-3 Chloroform 100 68-117109-99-9 Tetrahydrofuran (THF) 104 64-123107-06-2 1,2-Dichloroethane 98 63-12471-55-6 1,1,1-Trichloroethane 101 68-12071-43-2 Benzene 100 61-11056-23-5 Carbon Tetrachloride 103 65-137110-82-7 Cyclohexane 110 68-12278-87-5 1,2-Dichloropropane 106 67-12275-27-4 Bromodichloromethane 106 71-12479-01-6 Trichloroethene 106 71-121123-91-1 1,4-Dioxane 118 67-12280-62-6 Methyl Methacrylate 114 76-130142-82-5 n-Heptane 109 67-12510061-01-5 cis-1,3-Dichloropropene 109 73-131108-10-1 4-Methyl-2-pentanone 105 66-13210061-02-6 trans-1,3-Dichloropropene 113 76-13579-00-5 1,1,2-Trichloroethane 115 73-121108-88-3 Toluene 101 67-117591-78-6 2-Hexanone 100 59-128124-48-1 Dibromochloromethane 115 73-132106-93-4 1,2-Dibromoethane 121 73-128123-86-4 n-Butyl Acetate 112 61-136


212

220209214

468

210226

229

482

216248

236

218

230

210

235226208

224

230

226

424216

224

422

254

229

226

230

218

238232220

216

220220

AcceptanceLimits

% RecoveryResult

471

µg/m³231

428

Client Sample ID:

218

Client Project ID:

µg/m³Spike Amount


ALS

216210

263

249221220

218252

212 217

18 of 100


ALS ENVIRONMENTAL





CAS # Compound DataQualifier

111-65-9 n-Octane 109 67-124127-18-4 Tetrachloroethene 118 65-126108-90-7 Chlorobenzene 114 68-120100-41-4 Ethylbenzene 114 69-123179601-23-1 m,p-Xylenes 113 67-12575-25-2 Bromoform 116 68-153100-42-5 Styrene 123 68-13295-47-6 o-Xylene 112 67-124111-84-2 n-Nonane 107 60-13079-34-5 1,1,2,2-Tetrachloroethane 127 72-12898-82-8 Cumene 114 67-12480-56-8 alpha-Pinene 118 67-129103-65-1 n-Propylbenzene 118 67-125622-96-8 4-Ethyltoluene 125 66-128108-67-8 1,3,5-Trimethylbenzene 113 65-12595-63-6 1,2,4-Trimethylbenzene 98 62-134100-44-7 Benzyl Chloride 110 74-145541-73-1 1,3-Dichlorobenzene 115 63-133106-46-7 1,4-Dichlorobenzene 124 62-12995-50-1 1,2-Dichlorobenzene 129 62-1345989-27-5 d-Limonene 122 66-13796-12-8 1,2-Dibromo-3-chloropropane 128 71-147120-82-1 1,2,4-Trichlorobenzene 118 60-14591-20-3 Naphthalene 118 56-15887-68-3 Hexachlorobutadiene 117 56-139


Client Sample ID:

204214

µg/m³Spike Amount

Client Project ID:

Resultµg/m³

ALSAcceptance

Limits% Recovery

220

210

228222

210

485

238202229

204235219267237

208

214

249

240

208

273

212 250

210

269257

256280

210218230

230218

268

265

272

284

251218

220

220263257


428

242218

241213

228

19 of 100

TO15SCAN.XLS - 75 Compounds - PageNo.:P1603624_TO15_1608011003_SC.xls - ISS

ALS ENVIRONMENTAL


Client: Oneida Total Integrated Enterprises (OTIE) ALS Project ID: P1603624Pemaco-Plant Vapor Monitoring

Internal Standard Area and RT Summary

Test Code: EPA TO-15 ModifiedInstrument ID: Tekmar AUTOCAN/Agilent 5973inert/6890N/MS9 Lab File ID: 07221610.DAnalyst: Simon Cao Date Analyzed: 7/22/16Sample Type: 1.0 L Bottle-Vac™(s) Time Analyzed: 11:44

Test Notes:

IS1 (BCM) IS2 (DFB) IS3 (CBZ)AREA # RT # AREA # RT # AREA # RT #

24 Hour Standard 127729 8.90 582249 10.87 214712 15.22 Upper Limit 178821 9.23 815149 11.20 300597 15.55 Lower Limit 76637 8.57 349349 10.54 128827 14.89

Client Sample ID01 Method Blank 122721 8.89 565804 10.87 209200 15.2202 Lab Control Sample 148134 8.92 680456 10.89 261806 15.2303 SP-104-20160720 141372 8.89 702019 10.87 242763 15.2304 SP-106-20160720 164734 8.89 743055 10.87 293558 15.2205060708091011121314151617181920

IS1 (BCM) = BromochloromethaneIS2 (DFB) = 1,4-DifluorobenzeneIS3 (CBZ) = Chlorobenzene-d5

AREA UPPER LIMIT = 140% of internal standard areaAREA LOWER LIMIT = 60% of internal standard areaRT UPPER LIMIT = 0.33 minutes of internal standard RTRT LOWER LIMIT = 0.33 minutes of internal standard RT

# Column used to flag values outside QC limits with an I.I = Internal standard not within the specified limits.

Client Project ID:

20 of 100

Quantitation Report (QT Reviewed)

Data File: I:\MS09\Data\2016_07\22\07221624.D Acq On : 22 Jul 2016 21:12 Operator: SC Sample : P1603624-001 (400mL) Misc : S29-07211602 ALS Vial : 10 Sample Multiplier: 1

Quant Time: Jul 25 10:41:01 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M

Internal Standards R.T. QIon Response Conc Units Dev(Min) --------------------------------------------------------------------------

1) Bromochloromethane (IS1) 8.89 130 164734 12.500 ng -0.0437) 1,4-Difluorobenzene (IS2) 10.87 114 743055 12.500 ng -0.0356) Chlorobenzene-d5 (IS3) 15.22 82 293558 12.500 ng 0.00

System Monitoring Compounds33) 1,2-Dichloroethane-d4(... 9.67 65 187814 10.033 ng -0.04

Spiked Amount 12.500 Range 70 - 130 Recovery = 80.24% 57) Toluene-d8 (SS2) 13.31 98 775360 12.681 ng -0.01

Spiked Amount 12.500 Range 70 - 130 Recovery = 101.44% 73) Bromofluorobenzene (SS3) 16.84 174 260516 14.012 ng 0.00

Spiked Amount 12.500 Range 70 - 130 Recovery = 112.08%

Target Compounds Qvalue2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 3.84 85 65771 1.437 ng 1004) Chloromethane 4.01 50 10877 0.329 ng 985) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D.6) Vinyl Chloride 4.29 62 54020 1.748 ng 997) 1,3-Butadiene 0.00 54 0 N.D. d 8) Bromomethane 0.00 94 0 N.D.9) Chloroethane 0.00 64 0 N.D.10) Ethanol 5.14 45 91782 6.102 ng 10011) Acetonitrile 0.00 41 0 N.D. d 12) Acrolein 5.49 56 2155 0.180 ng 9613) Acetone 5.61 58 179130 12.038 ng # 7814) Trichlorofluoromethane 5.81 101 525 N.D.15) 2-Propanol (Isopropanol) 5.94 45 59418 1.175 ng 9816) Acrylonitrile 6.17 53 47 N.D.17) 1,1-Dichloroethene 0.00 96 0 N.D.18) 2-Methyl-2-Propanol (t... 0.00 59 0 N.D. d 19) Methylene Chloride 6.62 84 1842 0.097 ng 9620) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. d 21) Trichlorotrifluoroethane 0.00 151 0 N.D.22) Carbon Disulfide 6.91 76 10895 0.147 ng 9923) trans-1,2-Dichloroethene 0.00 61 0 N.D.24) 1,1-Dichloroethane 0.00 63 0 N.D.25) Methyl tert-Butyl Ether 0.00 73 0 N.D. d 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 8.29 72 14014 1.046 ng # 7928) cis-1,2-Dichloroethene 0.00 61 0 N.D.29) Diisopropyl Ether 0.00 87 0 N.D.30) Ethyl Acetate 0.00 61 0 N.D.31) n-Hexane 8.98 57 8219 0.244 ng 9132) Chloroform 0.00 83 0 N.D.34) Tetrahydrofuran (THF) 9.47 72 2997 0.224 ng 9735) Ethyl tert-Butyl Ether 0.00 87 0 N.D.36) 1,2-Dichloroethane 0.00 62 0 N.D.38) 1,1,1-Trichloroethane 0.00 97 0 N.D.39) Isopropyl Acetate 0.00 61 0 N.D.40) 1-Butanol 0.00 56 0 N.D. d 41) Benzene 10.51 78 11411 0.142 ng 9742) Carbon Tetrachloride 0.00 117 0 N.D.43) Cyclohexane 10.79 84 467 N.D.44) tert-Amyl Methyl Ether 0.00 73 0 N.D.45) 1,2-Dichloropropane 0.00 63 0 N.D.46) Bromodichloromethane 0.00 83 0 N.D.47) Trichloroethene 11.57 130 2838 0.122 ng 9848) 1,4-Dioxane 0.00 88 0 N.D.49) 2,2,4-Trimethylpentane... 11.63 57 3744 N.D.

R9061416.M Mon Jul 25 10:42:57 2016 Page: 1

21 of 100

simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221624.D Acq On : 22 Jul 2016 21:12 Operator: SC Sample : P1603624-001 (400mL) Misc : S29-07211602 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jul 25 10:41:01 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 11.90 71 923 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 12.49 58 576 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 13.42 91 15887 0.186 ng 99 59) 2-Hexanone 13.69 43 4955 0.124 ng 95 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 14.33 43 1180 N.D. 63) n-Octane 14.45 57 854 N.D. 64) Tetrachloroethene 14.57 166 6600 0.267 ng 94 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 15.68 91 3126 N.D. 67) m- & p-Xylenes 15.86 91 9224 0.127 ng 91 68) Bromoform 0.00 173 0 N.D. 69) Styrene 16.26 104 1406 N.D. 70) o-Xylene 16.37 91 3891 N.D. 71) n-Nonane 16.61 43 1513 N.D. 72) 1,1,2,2-Tetrachloroethane 16.39 83 1570 N.D. 74) Cumene 16.99 105 11849 0.123 ng 99 75) alpha-Pinene 17.40 93 824 N.D. 76) n-Propylbenzene 17.52 91 2404 N.D. 77) 3-Ethyltoluene 17.63 105 6445 N.D. 78) 4-Ethyltoluene 17.68 105 3297 N.D. 79) 1,3,5-Trimethylbenzene 17.75 105 3329 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. d 81) 2-Ethyltoluene 17.95 105 2609 N.D. 82) 1,2,4-Trimethylbenzene 18.19 105 9807 0.128 ng 89 83) n-Decane 18.31 57 2839 N.D. 84) Benzyl Chloride 18.18 91 1005 N.D. 85) 1,3-Dichlorobenzene 18.42 146 692 N.D. 86) 1,4-Dichlorobenzene 18.42 146 692 N.D. 87) sec-Butylbenzene 18.64 105 2143 N.D. 88) 4-Isopropyltoluene (p-... 18.65 119 1296 N.D. 89) 1,2,3-Trimethylbenzene 18.64 105 2143 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 18.80 68 1121 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 20.71 128 5048 N.D. 96) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 18.16 119 4327 N.D. 100) n-Butylbenzene 19.08 91 1935 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Mon Jul 25 10:42:57 2016 Page: 2

22 of 100




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

1050000

1100000

1150000

1200000

1250000

1300000

1350000

1400000

Time-->

Abundance TIC: 07221624.D\data.ms

1,2,

4-Tr

imet

hylb

enze

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),S

m- &

p-X

ylen

es,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

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Tric

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1,4-

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(IS2)

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Dic

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S1),S

Tetra

hydr

ofur

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HF)

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n-H

exan

e,T

Brom

ochl

orom

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ne (I

S1),I

R

2-Bu

tano

ne (M

EK),T

Car

bon

Dis

ulfid

e,T

Met

hyle

ne C

hlor

ide,

T

2-Pr

opan

ol (I

sopr

opan

ol),T

Acet

one,

TAc

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in,T

Etha

nol,TVi

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TC

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ne (C

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2),T

R9061416.M Mon Jul 25 10:42:58 2016 Page: 3

23 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221624.D Acq On : 22 Jul 2016 21:12 Operator: SC Sample : P1603624-001 (400mL) Misc : S29-07211602 ALS Vial : 10 Sample Multiplier: 1 Quant Time: Jul 25 10:41:01 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 164734 12.500 ng -0.04 37) 1,4-Difluorobenzene (IS2) 10.87 114 743055 12.500 ng -0.03 56) Chlorobenzene-d5 (IS3) 15.22 82 293558 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.67 65 187814 10.033 ng -0.04 Spiked Amount 12.500 Range 70 - 130 Recovery = 80.24% 57) Toluene-d8 (SS2) 13.31 98 775360 12.681 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.44% 73) Bromofluorobenzene (SS3) 16.84 174 260516 14.012 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 112.08% Target Compounds Qvalue 3) Dichlorodifluoromethan... 3.84 85 65771 1.437 ng 100 4) Chloromethane 4.01 50 10877 0.329 ng 98 6) Vinyl Chloride 4.29 62 54020 1.748 ng 99 10) Ethanol 5.14 45 91782 6.102 ng 100 12) Acrolein 5.49 56 2155 0.180 ng 96 13) Acetone 5.61 58 179130 12.038 ng # 78 15) 2-Propanol (Isopropanol) 5.94 45 59418 1.175 ng 98 19) Methylene Chloride 6.62 84 1842 0.097 ng 96 22) Carbon Disulfide 6.91 76 10895 0.147 ng 99 27) 2-Butanone (MEK) 8.29 72 14014 1.046 ng # 79 31) n-Hexane 8.98 57 8219 0.244 ng 91 34) Tetrahydrofuran (THF) 9.47 72 2997 0.224 ng 97 41) Benzene 10.51 78 11411 0.142 ng 97 47) Trichloroethene 11.57 130 2838 0.122 ng 98 58) Toluene 13.42 91 15887 0.186 ng 99 59) 2-Hexanone 13.69 43 4955 0.124 ng 95 64) Tetrachloroethene 14.57 166 6600 0.267 ng 94 67) m- & p-Xylenes 15.86 91 9224 0.127 ng 91 74) Cumene 16.99 105 11849 0.123 ng 99 82) 1,2,4-Trimethylbenzene 18.19 105 9807 0.128 ng 89 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Mon Jul 25 10:41:24 2016 Page: 1

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simon.cao

Simon




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

1050000

1100000

1150000

1200000

1250000

1300000

1350000

1400000

Time-->


1,2,

4-Tr

imet

hylb

enze

ne,T

Cum

ene,

TBr

omof

luor

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(SS3

),S

m- &

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Chl

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TTo

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Tolu

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S2),S

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ene,

T

1,4-

Difl

uoro

benz

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(IS2)

,IRBe

nzen

e,T

1,2-

Dic

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d4(S

S1),S

Tetra

hydr

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n-H

exan

e,T

Brom

ochl

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ne (I

S1),I

R

2-Bu

tano

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Car

bon

Dis

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e,T

Met

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ne C

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ide,

T

2-Pr

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sopr

opan

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Acet

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TAc

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nol,TVi

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R9061416.M Mon Jul 25 10:41:24 2016 Page: 2

25 of 100

#3Dichlorodifluoromethane (CFC 12)Concen: 1.44 ng RT: 3.84 min Scan# 83Delta R.T. 0.055 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 85 Resp: 65771Ion Ratio Lower Upper 85 100 87 32.6 12.5 52.5 101 8.8 0.0 29.2 103 5.6 0.0 25.8

Ref

Raw

Sub

20 30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->

Abundance Scan 71 (3.771 min): 06141627.D\data.ms (-63) (-)85

50 10135 66 12274

20 30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->

Abundance Scan 83 (3.837 min): 07221624.D\data.ms29

4385

10166

20 30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


4385

10166

3.70 3.75 3.80 3.85 3.900

10000

20000

Time-->

Abundance 3.837

#4ChloromethaneConcen: 0.33 ng RT: 4.01 min Scan# 115Delta R.T. 0.027 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 50 Resp: 10877Ion Ratio Lower Upper 50 100 52 31.9 13.1 53.1

Ref

Raw

Sub

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


35 46 8529 39

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->

Abundance Scan 115 (4.012 min): 07221624.D\data.ms29 50

44 6539

8535 81

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


6532

858136

3.95 4.00 4.05 4.100

1000

2000

3000

4000

5000

Time-->

Abundance 4.012

07221624.D R9061416.M Mon Jul 25 10:41:25 2016 Page 3

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#6Vinyl ChlorideConcen: 1.75 ng RT: 4.29 min Scan# 166Delta R.T. 0.027 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


35 47 59 6531 39 50

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


322944

35 47 5938 5041 65

20 25 30 35 40 45 50 55 60 65 700

50

m/z-->


31

4435 5947

4.20 4.30 4.400

10000

20000

30000

Time-->

Abundance 4.292

#10EthanolConcen: 6.10 ng RT: 5.14 min Scan# 326Delta R.T. -0.114 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 47

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 47

30 32 34 36 38 40 42 44 46 48 50 52 54 560

50

m/z-->


4341 47

5.00 5.20 5.40 5.600

5000

10000

15000

20000

Time-->

Abundance 5.140

07221624.D R9061416.M Mon Jul 25 10:41:25 2016 Page 4

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#12AcroleinConcen: 0.18 ng RT: 5.49 min Scan# 394Delta R.T. -0.021 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


5337 39 42 44 58

30 35 40 45 50 55 60 650

50

m/z-->


4440

30 35 40 45 50 55 60 650

50

m/z-->


41

5.45 5.50 5.550

200

400

600

800

Time-->

Abundance 5.491

#13AcetoneConcen: 12.04 ng RT: 5.61 min Scan# 418Delta R.T. -0.057 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 58 Resp: 179130Ion Ratio Lower Upper 58 100 43 254.9 268.8 328.8#

Ref

Raw

Sub

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 6045 5254

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 45 52 55

30 35 40 45 50 55 60 650

50

m/z-->


58

3937 41 45 52 55

5.50 5.60 5.70 5.800

50000

100000

150000

Time-->

Abundance

5.615

07221624.D R9061416.M Mon Jul 25 10:41:26 2016 Page 5

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#152-Propanol (Isopropanol)Concen: 1.17 ng RT: 5.94 min Scan# 482Delta R.T. -0.072 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 750

50

m/z-->


41 5938 53

30 35 40 45 50 55 60 65 70 750

50

m/z-->


4239 55 59 70

30 35 40 45 50 55 60 65 70 750

50

m/z-->


41 55 59 7038

5.80 6.00 6.200

5000

10000

Time-->

Abundance 5.945

#19Methylene ChlorideConcen: 0.10 ng RT: 6.62 min Scan# 613Delta R.T. -0.047 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->

Abundance Scan 618 (6.646 min): 06141627.D\data.ms (-601) (-)49 84

59

41 883538 5545 70 74

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


4941 84

25 30 35 40 45 50 55 60 65 70 75 80 85 90 950

50

m/z-->


4941 84

6.55 6.60 6.650

200

400

600

800

1000

Time-->

Abundance

6.620

07221624.D R9061416.M Mon Jul 25 10:41:26 2016 Page 6

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#22Carbon DisulfideConcen: 0.15 ng RT: 6.91 min Scan# 669Delta R.T. -0.005 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


44101 1518564 121 13235

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


44

30 40 50 60 70 80 90 100 110 120 130 140 150 1600

50

m/z-->


44

6.85 6.90 6.95 7.000

1000

2000

3000

4000

Time-->

Abundance 6.909

#272-Butanone (MEK)Concen: 1.05 ng RT: 8.29 min Scan# 937Delta R.T. -0.021 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 72 Resp: 14014Ion Ratio Lower Upper 72 100 43 332.1 360.9 400.9#

Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


7257

53

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

5740 7551

30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

575140

8.20 8.30 8.400

5000

10000

15000

Time-->

Abundance

8.291

07221624.D R9061416.M Mon Jul 25 10:41:26 2016 Page 7

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#31n-HexaneConcen: 0.24 ng RT: 8.98 min Scan# 1071Delta R.T. -0.016 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 57 Resp: 8219Ion Ratio Lower Upper 57 100 56 58.3 40.8 61.2 86 13.9 11.7 17.5

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


578770

10133

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


13071 8695

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


43

13071 8695

8.90 8.95 9.00 9.050

1000

2000

3000

Time-->

Abundance 8.982

#34Tetrahydrofuran (THF)Concen: 0.22 ng RT: 9.47 min Scan# 1165Delta R.T. 0.021 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

6945 5335 5749

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

25 30 35 40 45 50 55 60 65 70 75 800

50

m/z-->


72

39

9.40 9.45 9.500

500

1000

1500

2000

2500

Time-->

Abundance

9.467

07221624.D R9061416.M Mon Jul 25 10:41:27 2016 Page 8

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#41BenzeneConcen: 0.14 ng RT: 10.51 min Scan# 1368Delta R.T. -0.020 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


51746337 48

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


5641 5244 7438 8463

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


5643 5239 74 8463

10.45 10.50 10.55 10.600

1000

2000

3000

4000

5000

Time-->

Abundance10.514

#47TrichloroetheneConcen: 0.12 ng RT: 11.57 min Scan# 1572Delta R.T. -0.026 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion:130 Resp: 2838Ion Ratio Lower Upper130 100132 94.2 76.3 116.3

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


95

4060 70

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


95

41 60 70

11.50 11.55 11.600

500

1000

Time-->

Abundance11.565

07221624.D R9061416.M Mon Jul 25 10:41:27 2016 Page 9

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#58TolueneConcen: 0.19 ng RT: 13.42 min Scan# 1931Delta R.T. -0.010 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


6539 5145 8574

30 40 50 60 70 80 90 1000

50

m/z-->


65 9843 51 8557

30 40 50 60 70 80 90 1000

50

m/z-->


65 98514539 8557

13.40 13.500

2000

4000

6000

Time-->

Abundance13.417

#592-HexanoneConcen: 0.12 ng RT: 13.69 min Scan# 1984Delta R.T. 0.015 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


58

100857150 77 916537

30 40 50 60 70 80 90 1000

50

m/z-->


58

85 100

30 40 50 60 70 80 90 1000

50

m/z-->


58

85

13.65 13.70 13.750

500

1000

1500

2000

2500

Time-->

Abundance13.690

07221624.D R9061416.M Mon Jul 25 10:41:27 2016 Page 10

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#64TetrachloroetheneConcen: 0.27 ng RT: 14.57 min Scan# 2155Delta R.T. -0.005 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

94

47 59 8235 11970

40 60 80 100 120 140 1600

50

m/z-->


129

9440

8259

40 60 80 100 120 140 1600

50

m/z-->


129

94

47 59 8235

14.50 14.55 14.600

1000

2000

3000

Time-->

Abundance14.572

#67m- & p-XylenesConcen: 0.13 ng RT: 15.86 min Scan# 2405Delta R.T. -0.021 minLab File: 07221624.DAcq: 22 Jul 2016 21:12

Tgt Ion: 91 Resp: 9224Ion Ratio Lower Upper 91 100106 56.0 29.9 69.9

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


106

775139 65 84 98

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


106

40 7751 65 117

30 40 50 60 70 80 90 100 110 1200

50

m/z-->


106

775139 65

15.80 15.900

1000

2000

3000

Time-->

Abundance15.861

07221624.D R9061416.M Mon Jul 25 10:41:28 2016 Page 11

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#74CumeneConcen: 0.12 ng RT: 16.99 min Scan# 2623Delta R.T. -0.011 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

40 60 80 100 120 140 160 1800

50

m/z-->


1207751 9139 63 174

40 60 80 100 120 140 160 1800

50

m/z-->


1207740 51 9165 174

40 60 80 100 120 140 160 1800

50

m/z-->


1207751 9139 65 174

16.95 17.00 17.050

2000

4000

6000

Time-->

Abundance16.985

#821,2,4-TrimethylbenzeneConcen: 0.13 ng RT: 18.19 min Scan# 2857Delta R.T. -0.005 minLab File: 07221624.DAcq: 22 Jul 2016 21:12


Ref

Raw

Sub

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


77 13441

58 281

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


105

40 79 133 191 24957

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


105

249191133735639

18.10 18.15 18.20 18.250

1000

2000

3000

4000

5000

Time-->

Abundance18.192

07221624.D R9061416.M Mon Jul 25 10:41:28 2016 Page 12

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Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221617.D Acq On : 22 Jul 2016 17:13 Operator: SC Sample : P1603624-002 (4.0mL) Misc : S29-07211602 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jul 25 10:35:00 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 141372 12.500 ng -0.05 37) 1,4-Difluorobenzene (IS2) 10.87 114 702019 12.500 ng -0.03 56) Chlorobenzene-d5 (IS3) 15.23 82 242763 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.67 65 163035 10.148 ng -0.04 Spiked Amount 12.500 Range 70 - 130 Recovery = 81.20% 57) Toluene-d8 (SS2) 13.31 98 726986 14.378 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 115.04% 73) Bromofluorobenzene (SS3) 16.84 174 228945 14.891 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 119.12% Target Compounds Qvalue 2) Propene 0.00 42 0 N.D. d 3) Dichlorodifluoromethan... 3.79 85 755 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 4.14 135 401 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. d 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.21 45 964 N.D. 11) Acetonitrile 0.00 41 0 N.D. 12) Acrolein 0.00 56 0 N.D. d 13) Acetone 0.00 58 0 N.D. d 14) Trichlorofluoromethane 5.80 101 535 N.D. 15) 2-Propanol (Isopropanol) 5.99 45 2011 N.D. 16) Acrylonitrile 0.00 53 0 N.D. d 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 6.40 59 50 N.D. 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 6.93 76 2310 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 7.85 63 615 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 8.34 72 513 N.D. 28) cis-1,2-Dichloroethene 8.73 61 1385 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 8.99 57 38021 1.315 ng 99 32) Chloroform 9.03 83 941 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 10.52 56 525 N.D. 41) Benzene 10.51 78 11536 0.152 ng 99 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 10.80 84 29216 1.030 ng 93 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 11.46 63 994 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. d 47) Trichloroethene 11.58 130 19873 0.902 ng 99 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D. d

R9061416.M Mon Jul 25 10:36:30 2016 Page: 1

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Simon


Data File: I:\MS09\Data\2016_07\22\07221617.D Acq On : 22 Jul 2016 17:13 Operator: SC Sample : P1603624-002 (4.0mL) Misc : S29-07211602 ALS Vial : 1 Sample Multiplier: 1



50) Methyl Methacrylate 0.00 100 0 N.D. d 51) n-Heptane 11.90 71 8824 0.483 ng 9652) cis-1,3-Dichloropropene 0.00 75 0 N.D.53) 4-Methyl-2-pentanone 0.00 58 0 N.D. d 54) trans-1,3-Dichloropropene 0.00 75 0 N.D.55) 1,1,2-Trichloroethane 0.00 97 0 N.D. d 58) Toluene 13.42 91 4813 N.D.59) 2-Hexanone 0.00 43 0 N.D. d 60) Dibromochloromethane 0.00 129 0 N.D.61) 1,2-Dibromoethane 0.00 107 0 N.D.62) n-Butyl Acetate 0.00 43 0 N.D. d 63) n-Octane 0.00 57 0 N.D. d 64) Tetrachloroethene 14.57 166 3305 0.162 ng 9865) Chlorobenzene 0.00 112 0 N.D. d 66) Ethylbenzene 15.68 91 1109728 14.942 ng 9867) m- & p-Xylenes 0.00 91 0 N.D. d 68) Bromoform 0.00 173 0 N.D.69) Styrene 16.27 104 1196 N.D.70) o-Xylene 16.37 91 5331 N.D.71) n-Nonane 0.00 43 0 N.D. d 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. d 74) Cumene 16.99 105 106862 1.345 ng 9975) alpha-Pinene 0.00 93 0 N.D. d 76) n-Propylbenzene 17.52 91 338786 3.572 ng 9777) 3-Ethyltoluene 17.64 105 2093 N.D.78) 4-Ethyltoluene 17.67 105 2972 N.D.79) 1,3,5-Trimethylbenzene 17.76 105 5637 N.D.80) alpha-Methylstyrene 0.00 118 0 N.D. d 81) 2-Ethyltoluene 0.00 105 0 N.D. d 82) 1,2,4-Trimethylbenzene 0.00 105 0 N.D. d 83) n-Decane 0.00 57 0 N.D. d 84) Benzyl Chloride 0.00 91 0 N.D. d 85) 1,3-Dichlorobenzene 18.41 146 440 N.D.86) 1,4-Dichlorobenzene 18.41 146 440 N.D.87) sec-Butylbenzene 0.00 105 0 N.D. d 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. d 89) 1,2,3-Trimethylbenzene 0.00 105 0 N.D. d 90) 1,2-Dichlorobenzene 0.00 146 0 N.D.91) d-Limonene 0.00 68 0 N.D. d 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D.93) n-Undecane 0.00 57 0 N.D. d 94) 1,2,4-Trichlorobenzene 20.60 180 510 N.D.95) Naphthalene 20.71 128 11559 0.126 ng 5996) n-Dodecane 0.00 57 0 N.D. d 97) Hexachlorobutadiene 0.00 225 0 N.D.98) Cyclohexanone 0.00 55 0 N.D. d 99) tert-Butylbenzene 0.00 119 0 N.D. d

100) n-Butylbenzene 0.00 91 0 N.D. d --------------------------------------------------------------------------

(#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Mon Jul 25 10:36:30 2016 Page: 2

37 of 100




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

Time-->


Nap

htha

lene

,T

n-Pr

opyl

benz

ene,

TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),S

Ethy

lben

zene

,T

Chl

orob

enze

ne-d

5 (IS

3),IR

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chlo

roet

hene

,T

Tolu

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S2),S

n-H

epta

ne,T

Tric

hlor

oeth

ene,

T

1,4-

Difl

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benz

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(IS2)

,IRC

yclo

hexa

ne,T

Benz

ene,

T

1,2-

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Brom

ochl

orom

etha

ne (I

S1),I

R

R9061416.M Mon Jul 25 10:36:31 2016 Page: 3

38 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221617.D Acq On : 22 Jul 2016 17:13 Operator: SC Sample : P1603624-002 (4.0mL) Misc : S29-07211602 ALS Vial : 1 Sample Multiplier: 1 Quant Time: Jul 25 10:35:00 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 141372 12.500 ng -0.05 37) 1,4-Difluorobenzene (IS2) 10.87 114 702019 12.500 ng -0.03 56) Chlorobenzene-d5 (IS3) 15.23 82 242763 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.67 65 163035 10.148 ng -0.04 Spiked Amount 12.500 Range 70 - 130 Recovery = 81.20% 57) Toluene-d8 (SS2) 13.31 98 726986 14.378 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 115.04% 73) Bromofluorobenzene (SS3) 16.84 174 228945 14.891 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 119.12% Target Compounds Qvalue 31) n-Hexane 8.99 57 38021 1.315 ng 99 41) Benzene 10.51 78 11536 0.152 ng 99 43) Cyclohexane 10.80 84 29216 1.030 ng 93 47) Trichloroethene 11.58 130 19873 0.902 ng 99 51) n-Heptane 11.90 71 8824 0.483 ng 96 64) Tetrachloroethene 14.57 166 3305 0.162 ng 98 66) Ethylbenzene 15.68 91 1109728 14.942 ng 98 74) Cumene 16.99 105 106862 1.345 ng 99 76) n-Propylbenzene 17.52 91 338786 3.572 ng 97 95) Naphthalene 20.71 128 11559 0.126 ng 59 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Mon Jul 25 10:35:48 2016 Page: 1

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simon.cao

Simon




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

Time-->


Nap

htha

lene

,T

n-Pr

opyl

benz

ene,

TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),S

Ethy

lben

zene

,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,T

Tolu

ene-

d8 (S

S2),S

n-H

epta

ne,T

Tric

hlor

oeth

ene,

T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Benz

ene,

T

1,2-

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S1),S

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e,T

Brom

ochl

orom

etha

ne (I

S1),I

R

R9061416.M Mon Jul 25 10:35:49 2016 Page: 2

40 of 100

#31n-HexaneConcen: 1.32 ng RT: 8.99 min Scan# 1072Delta R.T. -0.011 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


578770

10133

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


43

86 13071 95

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


43

86 13071 95

8.90 8.95 9.00 9.050

5000

10000

15000

Time-->

Abundance 8.987

#41BenzeneConcen: 0.15 ng RT: 10.51 min Scan# 1368Delta R.T. -0.021 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


51746337 48

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5239 5644 7463

30 35 40 45 50 55 60 65 70 75 80 850

50

m/z-->


5239 5644 7463

10.45 10.50 10.55 10.600

1000

2000

3000

4000

5000

Time-->

Abundance10.513

07221617.D R9061416.M Mon Jul 25 10:35:49 2016 Page 3

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#43CyclohexaneConcen: 1.03 ng RT: 10.80 min Scan# 1423Delta R.T. -0.016 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


41

69

535038 77 8163 7444 66

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


41

69

5350 6638 77 8144

30 35 40 45 50 55 60 65 70 75 80 85 900

50

m/z-->


41

69

53 66 77 8138 50

10.70 10.75 10.80 10.850

5000

10000

Time-->

Abundance10.797

#47TrichloroetheneConcen: 0.90 ng RT: 11.58 min Scan# 1574Delta R.T. -0.015 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


60

35 47 8270

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


56 70

4183

114

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


56 70

4183

114

11.50 11.600

2000

4000

6000

8000

Time-->

Abundance11.576

07221617.D R9061416.M Mon Jul 25 10:35:50 2016 Page 4

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#51n-HeptaneConcen: 0.48 ng RT: 11.90 min Scan# 1637Delta R.T. -0.005 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

30 40 50 60 70 80 90 1000

50

m/z-->


7157

1008550 796337

30 40 50 60 70 80 90 1000

50

m/z-->


57 71

10081

30 40 50 60 70 80 90 1000

50

m/z-->


100

8153

11.85 11.90 11.950

1000

2000

3000

4000

Time-->

Abundance11.901

#64TetrachloroetheneConcen: 0.16 ng RT: 14.57 min Scan# 2155Delta R.T. -0.005 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


129

94

47 59 8235 11970

40 60 80 100 120 140 1600

50

m/z-->


56

41

12697 111 166

40 60 80 100 120 140 1600

50

m/z-->


56

126111 16643 94

14.50 14.55 14.600

500

1000

1500

Time-->

Abundance14.572

07221617.D R9061416.M Mon Jul 25 10:35:50 2016 Page 5

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#66EthylbenzeneConcen: 14.94 ng RT: 15.68 min Scan# 2369Delta R.T. -0.006 minLab File: 07221617.DAcq: 22 Jul 2016 17:13

Tgt Ion: 91 Resp: 1109728Ion Ratio Lower Upper 91 100106 33.1 12.0 52.0

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

51 776539 84 98 119

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

55 70 7739 8463 98 126117

30 40 50 60 70 80 90 100 110 120 1300

50

m/z-->


106

51 7765 988438 124

15.60 15.700

100000

200000

300000

400000

500000

Time-->

Abundance15.675

#74CumeneConcen: 1.35 ng RT: 16.99 min Scan# 2624Delta R.T. -0.006 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

40 60 80 100 120 140 1600

50

m/z-->


1207751 9139 63 174

40 60 80 100 120 140 1600

50

m/z-->


43

71 9785111 142121 174

40 60 80 100 120 140 1600

50

m/z-->


43

71 85 97120 142 174107

16.90 17.00 17.100

20000

40000

60000

Time-->

Abundance16.990

07221617.D R9061416.M Mon Jul 25 10:35:51 2016 Page 6

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#76n-PropylbenzeneConcen: 3.57 ng RT: 17.52 min Scan# 2727Delta R.T. -0.006 minLab File: 07221617.DAcq: 22 Jul 2016 17:13

Tgt Ion: 91 Resp: 338786Ion Ratio Lower Upper 91 100120 23.2 3.2 43.2 65 12.9 0.0 29.4

Ref

Raw

Sub

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


12065 7839 51 105

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


5569

4112011183

14099

30 40 50 60 70 80 90 100 110 120 130 1400

50

m/z-->


1201117865 10338 13950

17.40 17.50 17.600

50000

100000

150000

Time-->

Abundance17.521

#95NaphthaleneConcen: 0.13 ng RT: 20.71 min Scan# 3346Delta R.T. 0.005 minLab File: 07221617.DAcq: 22 Jul 2016 17:13


Ref

Raw

Sub

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


10251 75 147 207

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


81109

146 166 207 281

40 60 80 100 120 140 160 180 200 220 240 260 2800

50

m/z-->


14616567 93 281207

20.70 20.800

1000

2000

3000

4000

Time-->

Abundance20.713

07221617.D R9061416.M Mon Jul 25 10:35:51 2016 Page 7

45 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221612.D Acq On : 22 Jul 2016 13:55 Operator: SC Sample : MB R9072216_1000mL Misc : S29-07211602 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Jul 22 14:20:55 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 122721 12.500 ng -0.04 37) 1,4-Difluorobenzene (IS2) 10.87 114 565804 12.500 ng -0.03 56) Chlorobenzene-d5 (IS3) 15.22 82 209200 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.67 65 149469 10.718 ng -0.04 Spiked Amount 12.500 Range 70 - 130 Recovery = 85.76% 57) Toluene-d8 (SS2) 13.31 98 580954 13.333 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 106.64% 73) Bromofluorobenzene (SS3) 16.84 174 174969 13.206 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 105.68% Target Compounds Qvalue 2) Propene 3.73 42 679 N.D. 3) Dichlorodifluoromethan... 0.00 85 0 N.D. 4) Chloromethane 0.00 50 0 N.D. 5) 1,2-Dichloro-1,1,2,2-t... 0.00 135 0 N.D. 6) Vinyl Chloride 0.00 62 0 N.D. 7) 1,3-Butadiene 0.00 54 0 N.D. 8) Bromomethane 0.00 94 0 N.D. 9) Chloroethane 0.00 64 0 N.D. 10) Ethanol 5.23 45 524 N.D. 11) Acetonitrile 5.51 41 50 N.D. 12) Acrolein 5.55 56 737 N.D. 13) Acetone 5.66 58 11066 0.998 ng # 68 14) Trichlorofluoromethane 0.00 101 0 N.D. 15) 2-Propanol (Isopropanol) 6.01 45 706 N.D. 16) Acrylonitrile 0.00 53 0 N.D. 17) 1,1-Dichloroethene 0.00 96 0 N.D. 18) 2-Methyl-2-Propanol (t... 6.69 59 47 N.D. 19) Methylene Chloride 0.00 84 0 N.D. 20) 3-Chloro-1-propene (Al... 0.00 41 0 N.D. 21) Trichlorotrifluoroethane 0.00 151 0 N.D. 22) Carbon Disulfide 6.95 76 1203 N.D. 23) trans-1,2-Dichloroethene 0.00 61 0 N.D. 24) 1,1-Dichloroethane 0.00 63 0 N.D. 25) Methyl tert-Butyl Ether 0.00 73 0 N.D. 26) Vinyl Acetate 0.00 86 0 N.D. d 27) 2-Butanone (MEK) 8.34 72 1018 0.102 ng # 42 28) cis-1,2-Dichloroethene 0.00 61 0 N.D. 29) Diisopropyl Ether 0.00 87 0 N.D. 30) Ethyl Acetate 0.00 61 0 N.D. 31) n-Hexane 0.00 57 0 N.D. 32) Chloroform 0.00 83 0 N.D. 34) Tetrahydrofuran (THF) 0.00 72 0 N.D. 35) Ethyl tert-Butyl Ether 0.00 87 0 N.D. 36) 1,2-Dichloroethane 0.00 62 0 N.D. 38) 1,1,1-Trichloroethane 0.00 97 0 N.D. 39) Isopropyl Acetate 0.00 61 0 N.D. 40) 1-Butanol 10.52 56 704 N.D. 41) Benzene 10.51 78 3633 N.D. 42) Carbon Tetrachloride 0.00 117 0 N.D. 43) Cyclohexane 10.85 84 403 N.D. 44) tert-Amyl Methyl Ether 0.00 73 0 N.D. 45) 1,2-Dichloropropane 0.00 63 0 N.D. 46) Bromodichloromethane 0.00 83 0 N.D. 47) Trichloroethene 0.00 130 0 N.D. 48) 1,4-Dioxane 0.00 88 0 N.D. 49) 2,2,4-Trimethylpentane... 0.00 57 0 N.D.

R9061416.M Fri Jul 22 14:21:09 2016 Page: 1

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simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_07\22\07221612.D Acq On : 22 Jul 2016 13:55 Operator: SC Sample : MB R9072216_1000mL Misc : S29-07211602 ALS Vial : 2 Sample Multiplier: 1 Quant Time: Jul 22 14:20:55 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 0.00 71 0 N.D. 52) cis-1,3-Dichloropropene 0.00 75 0 N.D. 53) 4-Methyl-2-pentanone 0.00 58 0 N.D. 54) trans-1,3-Dichloropropene 0.00 75 0 N.D. 55) 1,1,2-Trichloroethane 0.00 97 0 N.D. 58) Toluene 13.42 91 1570 N.D. 59) 2-Hexanone 0.00 43 0 N.D. 60) Dibromochloromethane 0.00 129 0 N.D. 61) 1,2-Dibromoethane 0.00 107 0 N.D. 62) n-Butyl Acetate 0.00 43 0 N.D. 63) n-Octane 0.00 57 0 N.D. 64) Tetrachloroethene 0.00 166 0 N.D. 65) Chlorobenzene 0.00 112 0 N.D. 66) Ethylbenzene 0.00 91 0 N.D. 67) m- & p-Xylenes 0.00 91 0 N.D. 68) Bromoform 0.00 173 0 N.D. 69) Styrene 0.00 104 0 N.D. 70) o-Xylene 0.00 91 0 N.D. 71) n-Nonane 0.00 43 0 N.D. 72) 1,1,2,2-Tetrachloroethane 0.00 83 0 N.D. 74) Cumene 0.00 105 0 N.D. 75) alpha-Pinene 0.00 93 0 N.D. 76) n-Propylbenzene 0.00 91 0 N.D. 77) 3-Ethyltoluene 17.71 105 514 N.D. 78) 4-Ethyltoluene 17.71 105 514 N.D. 79) 1,3,5-Trimethylbenzene 17.78 105 501 N.D. 80) alpha-Methylstyrene 0.00 118 0 N.D. 81) 2-Ethyltoluene 17.78 105 501 N.D. 82) 1,2,4-Trimethylbenzene 0.00 105 0 N.D. 83) n-Decane 0.00 57 0 N.D. 84) Benzyl Chloride 0.00 91 0 N.D. 85) 1,3-Dichlorobenzene 0.00 146 0 N.D. 86) 1,4-Dichlorobenzene 0.00 146 0 N.D. 87) sec-Butylbenzene 0.00 105 0 N.D. 88) 4-Isopropyltoluene (p-... 0.00 119 0 N.D. 89) 1,2,3-Trimethylbenzene 0.00 105 0 N.D. 90) 1,2-Dichlorobenzene 0.00 146 0 N.D. 91) d-Limonene 0.00 68 0 N.D. 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 0.00 57 0 N.D. 94) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 95) Naphthalene 0.00 128 0 N.D. 96) n-Dodecane 0.00 57 0 N.D. 97) Hexachlorobutadiene 0.00 225 0 N.D. 98) Cyclohexanone 0.00 55 0 N.D. 99) tert-Butylbenzene 0.00 119 0 N.D. 100) n-Butylbenzene 0.00 91 0 N.D. -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Fri Jul 22 14:21:09 2016 Page: 2

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Data File: I:\MS09\Data\2016_07\22\07221612.D Acq On : 22 Jul 2016 13:55 Operator: SC Sample : MB R9072216_1000mL Misc : S29-07211602 ALS Vial : 2 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

Time-->


Brom

oflu

orob

enze

ne (S

S3),S

Chl

orob

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3),IR

Tolu

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Difl

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Acet

one,

T

R9061416.M Fri Jul 22 14:21:10 2016 Page: 3

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Quantitation Report (Not Reviewed) Data File: I:\MS09\Data\2016_07\22\07221616.D Acq On : 22 Jul 2016 16:10 Operator: SC Sample : LCS R9072216_25ng Misc : S29-07211602/S29-07221602 (8/20) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Jul 22 16:36:06 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.92 130 148134 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.89 114 680456 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 15.23 82 261806 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.70 65 174342 10.357 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 82.88% 57) Toluene-d8 (SS2) 13.32 98 702764 12.888 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 103.12% 73) Bromofluorobenzene (SS3) 16.84 174 225488 13.599 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 108.80% Target Compounds Qvalue 2) Propene 3.67 42 456436 24.180 ng 98 3) Dichlorodifluoromethan... 3.78 85 926083 22.504 ng 100 4) Chloromethane 3.98 50 746467 25.098 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.14 135 587288 27.994 ng 100 6) Vinyl Chloride 4.25 62 700595 25.214 ng 99 7) 1,3-Butadiene 4.43 54 557745 29.584 ng 97 8) Bromomethane 4.73 94 469309 27.131 ng 100 9) Chloroethane 4.94 64 368627 27.542 ng 99 10) Ethanol 5.21 45 1805263 133.466 ng 100 11) Acetonitrile 5.38 41 862952 24.944 ng 99 12) Acrolein 5.50 56 295720 27.418 ng 98 13) Acetone 5.65 58 1869259 139.697 ng 86 14) Trichlorofluoromethane 5.80 101 797909 23.726 ng 99 15) 2-Propanol (Isopropanol) 5.98 45 2445192 53.752 ng 98 16) Acrylonitrile 6.17 53 652045 26.964 ng 99 17) 1,1-Dichloroethene 6.49 96 522732 30.584 ng 89 18) 2-Methyl-2-Propanol (t... 6.62 59 2512131 56.438 ng 98 19) Methylene Chloride 6.65 84 541350 31.863 ng 92 20) 3-Chloro-1-propene (Al... 6.77 41 683176 28.835 ng 94 21) Trichlorotrifluoroethane 6.95 151 474644 30.633 ng 95 22) Carbon Disulfide 6.91 76 1769350 26.589 ng 100 23) trans-1,2-Dichloroethene 7.67 61 697186 30.519 ng 93 24) 1,1-Dichloroethane 7.88 63 883971 26.776 ng 99 25) Methyl tert-Butyl Ether 7.94 73 1480586 27.473 ng 99 26) Vinyl Acetate 8.06 86 587643 151.017 ng # 78 27) 2-Butanone (MEK) 8.30 72 357004 29.620 ng # 88 28) cis-1,2-Dichloroethene 8.76 61 677933 28.876 ng 92 29) Diisopropyl Ether 8.99 87 433820 27.532 ng # 83 30) Ethyl Acetate 9.00 61 385320 58.867 ng 97 31) n-Hexane 8.99 57 822230 27.145 ng 99 32) Chloroform 9.06 83 877688 27.984 ng 100 34) Tetrahydrofuran (THF) 9.44 72 344778 28.609 ng 93 35) Ethyl tert-Butyl Ether 9.54 87 613730 28.752 ng 93 36) 1,2-Dichloroethane 9.81 62 577393 26.178 ng 100 38) 1,1,1-Trichloroethane 10.07 97 747736 26.443 ng 99 39) Isopropyl Acetate 10.44 61 652733 63.335 ng # 87 40) 1-Butanol 10.46 56 1063035 64.738 ng 94 41) Benzene 10.53 78 2077198 28.225 ng 100 42) Carbon Tetrachloride 10.68 117 669216 29.463 ng 100 43) Cyclohexane 10.80 84 1606559 58.452 ng 95 44) tert-Amyl Methyl Ether 11.13 73 1439018 28.151 ng 98 45) 1,2-Dichloropropane 11.34 63 526172 28.719 ng 100 46) Bromodichloromethane 11.52 83 705225 28.770 ng 100 47) Trichloroethene 11.58 130 610182 28.583 ng 99 48) 1,4-Dioxane 11.55 88 449936 31.047 ng 95 49) 2,2,4-Trimethylpentane... 11.64 57 2121360 26.774 ng 96

R9061416.M Mon Jul 25 09:10:23 2016 Page: 1

49 of 100

simon.cao

Simon

Quantitation Report (Not Reviewed) Data File: I:\MS09\Data\2016_07\22\07221616.D Acq On : 22 Jul 2016 16:10 Operator: SC Sample : LCS R9072216_25ng Misc : S29-07211602/S29-07221602 (8/20) ALS Vial : 2 Sample Multiplier: 1 Quant Time: Jul 22 16:36:06 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.77 100 439376 60.232 ng 94 51) n-Heptane 11.90 71 519608 29.318 ng 98 52) cis-1,3-Dichloropropene 12.43 75 810931 28.289 ng 100 53) 4-Methyl-2-pentanone 12.46 58 487158 28.963 ng 95 54) trans-1,3-Dichloropropene 12.95 75 729612 29.710 ng 100 55) 1,1,2-Trichloroethane 13.12 97 544464 31.173 ng 99 58) Toluene 13.42 91 2108256 27.619 ng 99 59) 2-Hexanone 13.66 43 977024 27.465 ng 95 60) Dibromochloromethane 13.83 129 610578 31.791 ng 99 61) 1,2-Dibromoethane 14.08 107 631161 32.832 ng 100 62) n-Butyl Acetate 14.31 43 1227189 31.452 ng 97 63) n-Octane 14.44 57 434276 28.658 ng 94 64) Tetrachloroethene 14.57 166 657113 29.812 ng 99 65) Chlorobenzene 15.27 112 1517722 31.343 ng 100 66) Ethylbenzene 15.68 91 2495610 31.159 ng 98 67) m- & p-Xylenes 15.87 91 3929475 60.629 ng 97 68) Bromoform 15.92 173 583514 33.083 ng 100 69) Styrene 16.25 104 1628629 34.151 ng 98 70) o-Xylene 16.37 91 1976152 29.428 ng 97 71) n-Nonane 16.61 43 958434 27.390 ng 95 72) 1,1,2,2-Tetrachloroethane 16.34 83 984472 33.333 ng 99 74) Cumene 16.99 105 2540562 29.655 ng 98 75) alpha-Pinene 17.40 93 1295316 31.258 ng 96 76) n-Propylbenzene 17.52 91 3063142 29.945 ng 98 77) 3-Ethyltoluene 17.63 105 2498429 31.555 ng 95 78) 4-Ethyltoluene 17.68 105 2573789 33.450 ng 99 79) 1,3,5-Trimethylbenzene 17.75 105 2106061 30.226 ng 97 80) alpha-Methylstyrene 17.91 118 1198202 32.325 ng 98 81) 2-Ethyltoluene 17.95 105 2283410 28.150 ng 98 82) 1,2,4-Trimethylbenzene 18.19 105 1818428 26.587 ng 98 83) n-Decane 18.31 57 908860 24.428 ng 96 84) Benzyl Chloride 18.32 91 1629055 30.067 ng 97 85) 1,3-Dichlorobenzene 18.34 146 1217723 32.903 ng 100 86) 1,4-Dichlorobenzene 18.41 146 1230295 32.146 ng 100 87) sec-Butylbenzene 18.48 105 2665220 29.279 ng 98 88) 4-Isopropyltoluene (p-... 18.64 119 2549597 29.599 ng 98 89) 1,2,3-Trimethylbenzene 18.64 105 2152722 30.007 ng 97 90) 1,2-Dichlorobenzene 18.77 146 1307014 35.463 ng 100 91) d-Limonene 18.80 68 837133 31.963 ng 97 92) 1,2-Dibromo-3-Chloropr... 19.23 157 489533 34.955 ng 88 93) n-Undecane 19.65 57 1140920 29.407 ng 98 94) 1,2,4-Trichlorobenzene 20.59 180 1013625 33.960 ng 100 95) Naphthalene 20.70 128 3179510 32.170 ng 100 96) n-Dodecane 20.74 57 1140630 30.437 ng 97 97) Hexachlorobutadiene 21.07 225 588145 33.565 ng 100 98) Cyclohexanone 16.01 55 702704 30.063 ng 95 99) tert-Butylbenzene 18.19 119 1768116 26.177 ng 99 100) n-Butylbenzene 19.08 91 2342517 34.136 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Mon Jul 25 09:10:23 2016 Page: 2

50 of 100

Quantitation Report (Not Reviewed)

Data File: I:\MS09\Data\2016_07\22\07221616.D Acq On : 22 Jul 2016 16:10 Operator: SC Sample : LCS R9072216_25ng Misc : S29-07211602/S29-07221602 (8/20) ALS Vial : 2 Sample Multiplier: 1


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R9061416.M Mon Jul 25 09:10:24 2016 Page: 3

51 of 100

Response Factor Report MS09

Method Path : I:\MS09\Methods\ Method File : R9061416.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Wed Jun 15 09:50:01 2016 Response Via : Initial Calibration

Calibration Files 0.08=06141621.D 0.10=06141622.D 0.20=06141623.D 0.40=06141624.D 1.0 =06141625.D 5.0 =06141626.D 25 =06141627.D 50 =06141628.D 100 =06141629.D

Compound 0.08 0.10 0.20 0.40 1.0 5.0 25 50 100 Avg %RSD --------------------------------------------------------------------------------------------

1) IR Bromochloromethane... ----------------ISTD--------------------- 2) T Propene 1.637 1.700 1.419 1.628 1.493 1.566 1.782 1.595 1.515 1.593 6.92 3) T Dichlorodifluo... 3.757 3.681 3.154 3.397 3.283 3.449 3.870 3.463 3.198 3.473 7.21 4) T Chloromethane 2.683 2.412 2.220 2.511 2.443 2.536 2.942 2.602 2.240 2.510 8.87 5) T 1,2-Dichloro-1... 1.707 1.786 1.500 1.753 1.713 1.767 2.028 1.895 1.784 1.770 8.07 6) T Vinyl Chloride 2.348 2.231 1.916 2.310 2.229 2.392 2.741 2.545 2.391 2.345 9.69 7) T 1,3-Butadiene 1.282 1.401 1.267 1.491 1.526 1.575 2.033 1.922 1.821 1.591 17.34 8) T Bromomethane 1.401 1.286 1.286 1.363 1.432 1.465 1.728 1.632 1.544 1.460 10.35 9) T Chloroethane 1.064 0.906 1.043 1.266 1.138 1.092 1.328 1.243 1.084 1.129 11.56 10) T Ethanol 1.084 1.041 1.016 1.146 1.126 1.194 1.329 1.218 1.118 1.141 8.41 11) T Acetonitrile 2.831 2.747 2.872 3.221 3.005 2.840 2.919 5.81 12) T Acrolein 0.644 0.747 0.941 1.116 1.033 0.979 0.910 19.68 13) T Acetone 1.235 1.117 1.001 1.102 1.050 1.121 1.275 1.174 1.087 1.129 7.66 14) T Trichlorofluor... 3.005 2.849 2.590 2.891 2.712 2.812 3.104 2.864 2.713 2.838 5.51 15) T 2-Propanol (Is... 3.985 3.639 3.340 3.697 3.640 3.891 4.499 4.126 3.731 3.839 8.75 16) T Acrylonitrile 1.703 1.842 2.020 2.358 2.214 2.106 2.041 11.79 17) T 1,1-Dichloroet... 1.301 1.466 1.233 1.368 1.347 1.438 1.695 1.600 1.532 1.442 10.27 18) T 2-Methyl-2-Pro... 3.880 3.547 3.218 3.646 3.660 3.891 4.572 4.092 3.298 3.756 11.04 19) T Methylene Chlo... 1.429 1.167 1.127 1.325 1.402 1.516 1.732 1.637 1.570 1.434 14.25 20) T 3-Chloro-1-pro... 1.532 1.986 1.649 1.882 1.942 2.090 2.470 2.282 2.161 1.999 14.74 21) T Trichlorotrifl... 1.317 1.295 1.104 1.318 1.249 1.295 1.463 1.384 1.342 1.307 7.48 22) T Carbon Disulfide 5.438 4.562 4.991 4.830 5.139 5.794 6.905 6.610 6.267 5.615 14.74 23) T trans-1,2-Dich... 1.421 1.558 1.363 1.792 1.928 2.181 2.506 2.362 2.237 1.928 21.80 24) T 1,1-Dichloroet... 2.871 2.693 2.480 2.693 2.723 2.817 3.140 2.916 2.740 2.786 6.56 25) T Methyl tert-Bu... 4.824 4.444 3.711 4.446 4.188 4.563 5.235 4.907 4.612 4.548 9.62 26) T Vinyl Acetate 0.203 0.275 0.400 0.388 0.376 0.328 26.11 27) T 2-Butanone (MEK) 0.799 0.934 0.996 1.193 1.116 1.063 1.017 13.76 28) T cis-1,2-Dichlo... 2.022 1.752 1.581 1.876 1.905 2.032 2.378 2.202 2.082 1.981 11.98 29) T Diisopropyl Ether 1.513 1.194 1.233 1.426 1.336 1.276 1.330 9.13 30) T Ethyl Acetate 0.417 0.509 0.555 0.656 0.612 0.566 0.552 15.07 31) T n-Hexane 2.708 2.496 2.091 2.591 2.466 2.599 2.908 2.674 2.471 2.556 8.73 32) T Chloroform 2.666 2.681 2.340 2.504 2.563 2.630 3.013 2.782 2.640 2.647 7.02 33) S 1,2-Dichloroet... 1.439 1.440 1.437 1.451 1.424 1.442 1.440 1.376 1.335 1.420 2.73 34) T Tetrahydrofura... 0.864 0.998 0.959 1.023 1.151 1.089 1.035 1.017 9.03 35) T Ethyl tert-But... 1.945 1.541 1.500 1.774 1.682 1.766 2.106 1.989 1.908 1.801 11.36 36) T 1,2-Dichloroet... 1.767 1.834 1.527 1.861 1.829 1.904 2.179 1.990 1.861 1.861 9.34

37) IR 1,4-Difluorobenzen... ----------------ISTD---------------------38) T 1,1,1-Trichlor... 0.526 0.521 0.455 0.509 0.498 0.514 0.590 0.546 0.515 0.519 6.96 39) T Isopropyl Acetate 0.179 0.160 0.156 0.179 0.186 0.195 0.231 0.217 0.200 0.189 12.93 40) T 1-Butanol 0.190 0.238 0.280 0.322 0.385 0.361 0.336 0.302 23.03 41) T Benzene 1.496 1.558 1.250 1.361 1.216 1.263 1.419 1.339 1.266 1.352 8.76 42) T Carbon Tetrach... 0.403 0.374 0.343 0.396 0.409 0.422 0.501 0.468 0.441 0.417 11.46

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Method Path : I:\MS09\Methods\ Method File : R9061416.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS)43) T Cyclohexane 0.498 0.497 0.431 0.486 0.479 0.503 0.583 0.550 0.516 0.505 8.52 44) T tert-Amyl Meth... 0.957 0.889 0.791 0.887 0.876 0.928 1.103 1.040 0.979 0.939 9.99 45) T 1,2-Dichloropr... 0.333 0.337 0.282 0.321 0.339 0.333 0.384 0.360 0.340 0.337 8.17 46) T Bromodichlorom... 0.451 0.411 0.387 0.432 0.427 0.450 0.532 0.496 0.467 0.450 9.75 47) T Trichloroethene 0.426 0.390 0.359 0.382 0.364 0.378 0.432 0.409 0.390 0.392 6.52 48) T 1,4-Dioxane 0.206 0.241 0.259 0.312 0.297 0.282 0.266 14.66 49) T 2,2,4-Trimethy... 1.615 1.450 1.260 1.412 1.368 1.425 1.643 1.525 1.401 1.455 8.32 50) T Methyl Methacr... 0.092 0.122 0.130 0.160 0.153 0.146 0.134 18.70 51) T n-Heptane 0.300 0.313 0.288 0.312 0.315 0.321 0.383 0.359 0.339 0.326 9.21 52) T cis-1,3-Dichlo... 0.421 0.454 0.514 0.626 0.591 0.553 0.527 15.07 53) T 4-Methyl-2-pen... 0.249 0.279 0.303 0.364 0.342 0.317 0.309 13.55 54) T trans-1,3-Dich... 0.293 0.358 0.443 0.568 0.537 0.508 0.451 23.81 55) T 1,1,2-Trichlor... 0.273 0.269 0.268 0.321 0.324 0.329 0.389 0.368 0.347 0.321 13.70

56) IR Chlorobenzene-d5 (... ----------------ISTD---------------------57) S Toluene-d8 (SS2) 2.623 2.620 2.597 2.622 2.600 2.595 2.591 2.569 2.615 2.604 0.69 58) T Toluene 4.273 3.752 3.137 3.413 3.336 3.475 3.995 3.776 3.643 3.645 9.61 59) T 2-Hexanone 1.136 1.517 1.754 2.081 1.909 1.794 1.698 19.55 60) T Dibromochlorom... 0.741 0.798 0.777 0.840 0.876 0.956 1.142 1.077 1.046 0.917 15.73 61) T 1,2-Dibromoethane 0.650 0.785 0.853 0.923 1.117 1.063 1.034 0.918 18.24 62) T n-Butyl Acetate 1.073 1.633 1.950 2.345 2.156 2.020 1.863 24.33 63) T n-Octane 0.755 0.629 0.567 0.696 0.692 0.734 0.867 0.803 0.768 0.724 12.48 64) T Tetrachloroethene 1.084 1.050 0.862 1.023 0.961 1.013 1.200 1.147 1.130 1.052 9.77 65) T Chlorobenzene 2.468 2.310 2.034 2.138 2.143 2.239 2.620 2.477 2.378 2.312 8.25 66) T Ethylbenzene 4.079 3.463 3.004 3.412 3.600 3.850 4.576 4.307 4.125 3.824 13.00 67) T m- & p-Xylenes 3.222 2.844 2.467 2.733 2.909 3.129 3.691 3.485 3.370 3.094 12.63 68) T Bromoform 0.576 0.692 0.738 0.832 1.042 1.013 1.002 0.842 21.63 69) T Styrene 1.595 1.802 2.054 2.350 2.855 2.682 2.601 2.277 20.83 70) T o-Xylene 3.241 2.925 2.616 2.932 3.083 3.229 3.823 3.563 3.445 3.206 11.48 71) T n-Nonane 1.643 1.497 1.362 1.603 1.604 1.771 2.042 1.833 1.681 1.671 11.78 72) T 1,1,2,2-Tetrac... 0.968 1.085 1.075 1.163 1.406 1.563 1.917 1.781 1.732 1.410 25.03 73) S Bromofluoroben... 0.775 0.782 0.774 0.781 0.788 0.810 0.817 0.793 0.805 0.792 1.96 74) T Cumene 4.073 3.773 3.372 3.797 3.874 4.137 4.914 4.536 4.337 4.090 11.24 75) T alpha-Pinene 1.903 1.846 1.589 1.737 1.783 2.047 2.438 2.272 2.191 1.979 14.06 76) T n-Propylbenzene 4.853 4.008 3.892 4.314 4.749 5.153 6.100 5.593 5.294 4.884 15.04 77) T 3-Ethyltoluene 3.207 3.146 2.911 3.461 3.552 3.973 4.941 4.472 4.358 3.780 18.32 78) T 4-Ethyltoluene 3.236 3.077 3.053 3.210 3.616 3.919 4.565 4.306 4.081 3.674 15.43 79) T 1,3,5-Trimethy... 3.418 3.277 2.659 2.986 3.021 3.336 3.967 3.693 3.584 3.327 12.01 80) T alpha-Methylst... 1.189 1.448 1.615 1.864 2.211 2.062 2.000 1.770 20.71 81) T 2-Ethyltoluene 3.737 3.452 3.155 3.602 3.695 4.007 4.682 4.354 4.170 3.873 12.28 82) T 1,2,4-Trimethy... 2.769 2.874 2.520 2.946 3.088 3.410 4.177 3.885 3.721 3.266 17.22 83) T n-Decane 1.522 1.544 1.347 1.661 1.744 1.967 2.283 2.068 1.851 1.776 16.66 84) T Benzyl Chloride 1.116 1.685 2.407 3.563 3.401 3.350 2.587 39.45 85) T 1,3-Dichlorobe... 1.460 1.334 1.210 1.523 1.735 1.904 2.361 2.211 2.166 1.767 23.52 86) T 1,4-Dichlorobe... 1.422 1.584 1.335 1.463 1.763 1.995 2.417 2.261 2.206 1.827 22.15 87) T sec-Butylbenzene 4.042 3.854 3.456 4.031 4.124 4.586 5.403 4.932 4.689 4.346 13.88 88) T 4-Isopropyltol... 3.639 3.524 3.260 3.682 3.942 4.374 5.256 4.819 4.518 4.113 16.20 89) T 1,2,3-Trimethy... 3.117 2.926 2.688 3.093 3.196 3.577 4.337 4.027 3.867 3.425 16.19 90) T 1,2-Dichlorobe... 1.383 1.452 1.303 1.540 1.731 1.916 2.297 2.134 2.082 1.760 20.60 91) T d-Limonene 1.083 0.989 0.960 1.108 1.199 1.375 1.628 1.500 1.414 1.250 18.99 92) T 1,2-Dibromo-3-... 0.362 0.510 0.648 0.878 0.816 0.799 0.669 30.06 93) T n-Undecane 1.738 1.460 1.392 1.697 1.780 2.087 2.385 2.151 1.982 1.852 17.63 94) T 1,2,4-Trichlor... 0.868 1.166 1.407 1.776 1.677 1.656 1.425 24.67

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Method Path : I:\MS09\Methods\ Method File : R9061416.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS)95) T Naphthalene 2.569 3.877 4.846 6.093 5.622 5.307 4.719 27.46 96) T n-Dodecane 1.675 1.403 1.275 1.427 1.794 2.119 2.348 2.119 1.942 1.789 20.83 97) T Hexachlorobuta... 0.764 0.754 0.659 0.717 0.782 0.841 1.039 0.987 0.986 0.837 16.18 98) T Cyclohexanone 0.766 1.002 1.138 1.343 1.255 1.193 1.116 18.47 99) T tert-Butylbenzene 2.955 2.907 2.599 2.952 3.050 3.332 4.001 3.710 3.519 3.225 13.90 100) T n-Butylbenzene 2.724 2.537 2.399 2.768 3.231 3.723 4.367 3.974 3.764 3.276 21.57 ----------------------------------------------------------------------------(#) = Out of Range

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1ng/L Std. ID:4ng/L Std. ID: S29-06021605

20ng/L Std. ID: S29-06021603200ng/L Std. ID: S29-06021601

Dilution Factors: 5 50 250 1000 4 4 4 4 20 20 200 200 200

Source Std. Injection (L): 0.020 0.025 0.050 0.100 0.050 0.25 0.125 0.25 0.50Compounds mg/m3 200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ngPropene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Dichlorodifluoromethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Chloromethane 0.98 196 19.6 3.92 0.98 0.0784 0.098 0.196 0.392 0.98 4.90 24.50 49.0 98Freon-114 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Vinyl Chloride 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1001,3-Butadiene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 106Bromomethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Chloroethane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101Ethanol 5.06 1012 101.2 20.24 5.06 0.4048 0.506 1.012 2.024 5.06 25.30 126.50 253.0 506Acetonitrile 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102Acrolein 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Acetone 5.37 1074 107.4 21.48 5.37 0.4296 0.537 1.074 2.148 5.37 26.85 134.25 268.5 537Trichlorofluoromethane 0.99 198 19.8 3.96 0.99 0.0792 0.099 0.198 0.396 0.99 4.95 24.75 49.5 99Isopropanol 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209Acrylonitrile 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1031,1-Dichloroethene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107tert-Butanol 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209Methylene Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Allyl Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Trichlorotrifluoroethane 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Carbon Disulfide 0.98 196 19.6 3.92 0.98 0.0784 0.098 0.196 0.392 0.98 4.90 24.50 49.0 98trans-1,2-Dichloroethene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 1061,1-Dichloroethane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Methyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Vinyl Acetate 5.07 1014 101.4 20.28 5.07 0.4056 0.507 1.014 2.028 5.07 25.35 126.75 253.5 5072-Butanone 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107cis-1,2-Dichloroethene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Diisopropyl Ether 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Ethyl Acetate 2.12 424 42.4 8.48 2.12 0.1696 0.212 0.424 0.848 2.12 10.60 53.00 106.0 212n-Hexane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Chloroform 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Tetrahydrofuran 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102Ethyl tert-Butyl Ether 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,2-Dichloroethane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,1,1-Trichloroethane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Isopropyl Acetate 2.21 442 44.2 8.84 2.21 0.1768 0.221 0.442 0.884 2.21 11.05 55.25 110.5 2211-Butanol 2.26 452 45.2 9.04 2.26 0.1808 0.226 0.452 0.904 2.26 11.30 56.50 113.0 226Benzene 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111Carbon Tetrachloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Cyclohexane 2.09 418 41.8 8.36 2.09 0.1672 0.209 0.418 0.836 2.09 10.45 52.25 104.5 209tert-Amyl Methyl Ether 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichloropropane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Bromodichloromethane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Trichloroethene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1031,4-Dioxane 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108Isooctane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Methyl Methacrylate 2.08 416 41.6 8.32 2.08 0.1664 0.208 0.416 0.832 2.08 10.40 52.00 104.0 208n-Heptane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107cis-1,3-Dichloropropene 1.12 224 22.4 4.48 1.12 0.0896 0.112 0.224 0.448 1.12 5.60 28.00 56.0 112

Primary Source Standards Concentrations (Working & Initial Calibration)

Working STD Conc.(ng/L):

Primary Working Standards

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1ng/L Std. ID:4ng/L Std. ID: S29-06021605

20ng/L Std. ID: S29-06021603200ng/L Std. ID: S29-06021601

Dilution Factors: 5 50 250 1000 4 4 4 4 20 20 200 200 200

Source Std. Injection (L): 0.020 0.025 0.050 0.100 0.050 0.25 0.125 0.25 0.50Compounds mg/m3 200ng/L 20ng/L 4ng/L 1ng/L ICAL Points: 0.08ng 0.1ng 0.2ng 0.4ng 1ng 5ng 25ng 50ng 100ng

Primary Source Standards Concentrations (Working & Initial Calibration)

Working STD Conc.(ng/L):

Primary Working Standards

4-Methyl-2-pentanone 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108trans-1,3-Dichloropropene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 1071,1,2-Trichloroethane 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105Toluene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1052-Hexanone 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111Dibromochloromethane 1.10 220 22.0 4.40 1.10 0.0880 0.110 0.220 0.440 1.10 5.50 27.50 55.0 1101,2-Dibromoethane 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107n-Butyl Acetate 1.11 222 22.2 4.44 1.11 0.0888 0.111 0.222 0.444 1.11 5.55 27.75 55.5 111n-Octane 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Tetrachloroethene 0.99 198 19.8 3.96 0.99 0.0792 0.099 0.198 0.396 0.99 4.95 24.75 49.5 99Chlorobenzene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Ethylbenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105m-&p-Xylene 2.08 416 41.6 8.32 2.08 0.1664 0.208 0.416 0.832 2.08 10.40 52.00 104.0 208Bromoform 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Styrene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108o-Xylene 1.02 204 20.4 4.08 1.02 0.0816 0.102 0.204 0.408 1.02 5.10 25.50 51.0 102n-Nonane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 1011,1,2,2-Tetrachloroethane 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100Cumene 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101alpha-Pinene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103n-Propylbenzene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1003-Ethyltoluene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1044-Ethyltoluene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 1051,3,5-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104alpha-Methylstyrene 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 1032-Ethyltoluene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2,4-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104n-Decane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 101Benzyl Chloride 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 1081,3-Dichlorobenzene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 1081,4-Dichlorobenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105sec-Butylbenzene 1.06 212 21.2 4.24 1.06 0.0848 0.106 0.212 0.424 1.06 5.30 26.50 53.0 106p-Isopropyltoluene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 1001,2,3-Trimethylbenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dichlorobenzene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107d-Limonene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 1041,2-Dibromo-3-chloropropane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104n-Undecane 1.01 202 20.2 4.04 1.01 0.0808 0.101 0.202 0.404 1.01 5.05 25.25 50.5 1011,2,4-Trichlorobenzene 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Naphthalene 1.00 200 20.0 4.00 1.00 0.0800 0.100 0.200 0.400 1.00 5.00 25.00 50.0 100n-Dodecane 1.04 208 20.8 4.16 1.04 0.0832 0.104 0.208 0.416 1.04 5.20 26.00 52.0 104Hexachloro-1,3-butadiene 1.07 214 21.4 4.28 1.07 0.0856 0.107 0.214 0.428 1.07 5.35 26.75 53.5 107Methacrylonitrile 1.03 206 20.6 4.12 1.03 0.0824 0.103 0.206 0.412 1.03 5.15 25.75 51.5 103Cyclohexanone 1.12 224 22.4 4.48 1.12 0.0896 0.112 0.224 0.448 1.12 5.60 28.00 56.0 112tert-Butylbenzene 1.05 210 21.0 4.20 1.05 0.0840 0.105 0.210 0.420 1.05 5.25 26.25 52.5 105n-Butylbenzene 1.08 216 21.6 4.32 1.08 0.0864 0.108 0.216 0.432 1.08 5.40 27.00 54.0 108

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Calibration Status Report MS09

Method : I:\MS09\Methods\R9061416.M (RTE Integrator) Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration

# ID Conc ISTD Path\FileConc

-- ---- ---- ---- ------------------------------------------------- 1 0.08 0 13 I:\MS09\Data\2016_06\14\06141621.D 2 0.10 0 13 I:\MS09\Data\2016_06\14\06141622.D 3 0.20 0 13 I:\MS09\Data\2016_06\14\06141623.D 4 0.40 0 13 I:\MS09\Data\2016_06\14\06141624.D 5 1.0 1 13 I:\MS09\Data\2016_06\14\06141625.D 6 5.0 5 13 I:\MS09\Data\2016_06\14\06141626.D 7 25 26 13 I:\MS09\Data\2016_06\14\06141627.D 8 50 52 13 I:\MS09\Data\2016_06\14\06141628.D 9 100 103 13 I:\MS09\Data\2016_06\14\06141629.D

# ID Update Time Quant Time Acquisition Time -- -- -------------------- ----------------- --------------------- 1 0.08 Jun 15 09:47 2016 Jun 15 09:41 2016 14 Jun 2016 23:33 2 0.10 Jun 15 09:47 2016 Jun 15 09:37 2016 15 Jun 2016 00:07 3 0.20 Jun 15 09:47 2016 Jun 15 09:35 2016 15 Jun 2016 00:40 4 0.40 Jun 15 09:48 2016 Jun 15 09:34 2016 15 Jun 2016 1:14 5 1.0 Jun 15 09:48 2016 Jun 15 09:33 2016 15 Jun 2016 1:48 6 5.0 Jun 15 09:48 2016 Jun 15 09:31 2016 15 Jun 2016 2:22 7 25 Jun 15 09:49 2016 Jun 15 09:29 2016 15 Jun 2016 2:56 8 50 Jun 15 09:49 2016 Jun 15 09:44 2016 15 Jun 2016 3:30 9 100 Jun 15 09:50 2016 Jun 15 09:45 2016 15 Jun 2016 4:05

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Data File: I:\MS09\Data\2016_06\14\06141621.D Acq On : 14 Jun 2016 23:33 Operator: SC Sample : 0.08ng TO-15 ICAL STD Misc : S29-06141607/S29-06021605 (7/1) ALS Vial : 5 Sample Multiplier: 1

Quant Time: Jun 15 09:41:28 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M




Spiked Amount 12.500 Range 70 - 130 Recovery = 88.32% 57) Toluene-d8 (SS2) 13.31 98 537261 13.939 ng 0.00



Target Compounds Qvalue2) Propene 3.71 42 1199 0.071 ng # 833) Dichlorodifluoromethan... 3.81 85 2671 0.081 ng # 904) Chloromethane 4.01 50 1869 0.067 ng 945) 1,2-Dichloro-1,1,2,2-t... 4.16 135 1250 0.076 ng # 436) Vinyl Chloride 4.29 62 1669 0.071 ng 977) 1,3-Butadiene 4.46 54 966 0.081 ng # 768) Bromomethane 4.75 94 996 0.072 ng 939) Chloroethane 4.98 64 764 0.067 ng # 4210) Ethanol 5.18 45 3900 0.363 ng # 5511) Acetonitrile 5.40 41 118 0.004 ng # 112) Acrolein 5.54 56 97 0.011 ng # 5413) Acetone 5.66 58 4714 0.374 ng 9214) Trichlorofluoromethane 5.81 101 2115 0.080 ng 9415) 2-Propanol (Isopropanol) 5.99 45 5921 0.147 ng 7116) Acrylonitrile 6.20 53 51 0.002 ng # 817) 1,1-Dichloroethene 6.50 96 990 0.068 ng 9118) 2-Methyl-2-Propanol (t... 6.66 59 5765 0.145 ng 8719) Methylene Chloride 6.64 84 1097 0.060 ng 9120) 3-Chloro-1-propene (Al... 6.77 41 1176 0.052 ng # 3721) Trichlorotrifluoroethane 6.95 151 1011 0.082 ng 9822) Carbon Disulfide 6.93 76 3789 0.066 ng # 7423) trans-1,2-Dichloroethene 7.66 61 1071 0.050 ng 8924) 1,1-Dichloroethane 7.86 63 2123 0.073 ng # 4325) Methyl tert-Butyl Ether 7.97 73 3601 0.077 ng 9126) Vinyl Acetate 0.00 86 0 N.D.27) 2-Butanone (MEK) 8.33 72 445 0.045 ng # 2628) cis-1,2-Dichloroethene 8.73 61 1538 0.073 ng 8429) Diisopropyl Ether 9.00 87 985 0.077 ng # 8530) Ethyl Acetate 9.02 61 426 0.076 ng # 1231) n-Hexane 8.99 57 2002 0.073 ng # 9132) Chloroform 9.03 83 2028 0.078 ng 9334) Tetrahydrofuran (THF) 9.49 72 584 0.053 ng # 4535) Ethyl tert-Butyl Ether 9.54 87 1452 0.079 ng 9136) 1,2-Dichloroethane 9.78 62 1319 0.073 ng # 4238) 1,1,1-Trichloroethane 10.05 97 1808 0.089 ng 9539) Isopropyl Acetate 10.45 61 1321 0.150 ng 9740) 1-Butanol 10.51 56 1420 0.108 ng # 5241) Benzene 10.51 78 5540 0.089 ng 9542) Carbon Tetrachloride 10.67 117 1451 0.087 ng 9143) Cyclohexane 10.79 84 3472 0.158 ng 9244) tert-Amyl Methyl Ether 11.14 73 3323 0.080 ng 9345) 1,2-Dichloropropane 11.33 63 1166 0.079 ng 9146) Bromodichloromethane 11.51 83 1611 0.088 ng 8447) Trichloroethene 11.57 130 1463 0.099 ng 9148) 1,4-Dioxane 11.59 88 670 0.064 ng # 1949) 2,2,4-Trimethylpentane... 11.63 57 5551 0.085 ng 96

R9061416.M Wed Jun 15 09:43:13 2016 Page: 1

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simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141621.D Acq On : 14 Jun 2016 23:33 Operator: SC Sample : 0.08ng TO-15 ICAL STD Misc : S29-06141607/S29-06021605 (7/1) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Jun 15 09:41:28 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 0.00 100 0 N.D. 51) n-Heptane 11.90 71 1071 0.074 ng # 88 52) cis-1,3-Dichloropropene 12.43 75 623 0.030 ng # 42 53) 4-Methyl-2-pentanone 12.48 58 651 0.050 ng # 62 54) trans-1,3-Dichloropropene 12.98 75 591 0.031 ng # 43 55) 1,1,2-Trichloroethane 13.12 97 955 0.071 ng 97 58) Toluene 13.41 91 5881 0.106 ng 91 59) 2-Hexanone 13.74 43 938 0.036 ng # 22 60) Dibromochloromethane 13.83 129 1069 0.080 ng # 72 61) 1,2-Dibromoethane 14.11 107 782 0.059 ng 86 62) n-Butyl Acetate 14.34 43 409 0.014 ng # 41 63) n-Octane 14.44 57 1019 0.084 ng # 84 64) Tetrachloroethene 14.57 166 1407 0.098 ng 94 65) Chlorobenzene 15.28 112 3461 0.103 ng 97 66) Ethylbenzene 15.69 91 5613 0.096 ng 94 67) m- & p-Xylenes 15.87 91 8784 0.188 ng 95 68) Bromoform 15.94 173 963 0.085 ng # 28 69) Styrene 16.27 104 2385 0.071 ng 90 70) o-Xylene 16.37 91 4333 0.089 ng 92 71) n-Nonane 16.61 43 2175 0.077 ng 93 72) 1,1,2,2-Tetrachloroethane 16.35 83 1269 0.055 ng 97 74) Cumene 16.99 105 5392 0.089 ng 96 75) alpha-Pinene 17.40 93 2569 0.084 ng 98 76) n-Propylbenzene 17.53 91 6360 0.085 ng # 89 77) 3-Ethyltoluene 17.64 105 4372 0.075 ng 98 78) 4-Ethyltoluene 17.68 105 4453 0.080 ng 93 79) 1,3,5-Trimethylbenzene 17.75 105 4659 0.097 ng 91 80) alpha-Methylstyrene 17.93 118 1694 0.069 ng # 82 81) 2-Ethyltoluene 17.96 105 5094 0.090 ng 98 82) 1,2,4-Trimethylbenzene 18.20 105 3775 0.080 ng 95 83) n-Decane 18.32 57 2015 0.070 ng 89 84) Benzyl Chloride 18.35 91 886 0.021 ng # 55 85) 1,3-Dichlorobenzene 18.35 146 2066 0.083 ng 85 86) 1,4-Dichlorobenzene 18.43 146 1957 0.077 ng 96 87) sec-Butylbenzene 18.48 105 5616 0.088 ng 95 88) 4-Isopropyltoluene (p-... 18.65 119 4769 0.082 ng 99 89) 1,2,3-Trimethylbenzene 18.64 105 4249 0.087 ng 88 90) 1,2-Dichlorobenzene 18.78 146 1940 0.080 ng 97 91) d-Limonene 18.79 68 1476 0.075 ng 95 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 19.66 57 2301 0.082 ng 89 94) 1,2,4-Trichlorobenzene 20.61 180 884 0.046 ng # 68 95) Naphthalene 20.74 128 2148 0.033 ng # 71 96) n-Dodecane 20.75 57 2283 0.078 ng # 66 97) Hexachlorobutadiene 21.07 225 1072 0.103 ng 99 98) Cyclohexanone 16.05 55 971 0.060 ng # 59 99) tert-Butylbenzene 18.18 119 4066 0.088 ng 96 100) n-Butylbenzene 19.11 91 3856 0.078 ng 93 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:43:13 2016 Page: 2

59 of 100




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T

n-Bu

tylb

enze

ne,T

d-Li

mon

ene,

T1,

2-D

ichl

orob

enze

ne,T

4-Is

opro

pylto

luen

e (p

-Cym

ene)

,T1,

2,3-

Trim

ethy

lben

zene

,Tse

c-Bu

tylb

enze

ne,T

1,4-

Dic

hlor

oben

zene

,T1,

3-D

ichl

orob

enze

ne,T

Benz

yl C

hlor

ide,

Tn-

Dec

ane,

T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

2,2,

4-Tr

imet

hylp

enta

ne (I

sooc

tane

),T1,

4-D

ioxa

ne,T

Tric

hlor

oeth

ene,

TBr

omod

ichl

orom

etha

ne,T

1,2-

Dic

hlor

opro

pane

,Tte

rt-A

myl

Met

hyl E

ther

,T1,

4-D

ifluo

robe

nzen

e (IS

2),IR

Cyc

lohe

xane

,TC

arbo

n Te

trach

lorid

e,T

Benz

ene,

T1-

Buta

nol,T

Isop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T2-

Buta

none

(MEK

),TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:43:15 2016 Page: 3

60 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141622.D Acq On : 15 Jun 2016 00:07 Operator: SC Sample : 0.10ng TO-15 ICAL STD Misc : S29-06141607/S29-06021605 (7/1) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Jun 15 09:37:39 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 110431 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.87 114 516967 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 15.22 82 202049 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.67 65 159040 11.044 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 88.32% 57) Toluene-d8 (SS2) 13.31 98 529288 13.919 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 111.36% 73) Bromofluorobenzene (SS3) 16.84 174 157937 12.573 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.56% Target Compounds Qvalue 2) Propene 3.72 42 1547 0.093 ng 98 3) Dichlorodifluoromethan... 3.81 85 3252 0.099 ng # 92 4) Chloromethane 4.01 50 2088 0.076 ng 98 5) 1,2-Dichloro-1,1,2,2-t... 4.16 135 1625 0.100 ng 96 6) Vinyl Chloride 4.28 62 1971 0.085 ng 97 7) 1,3-Butadiene 4.46 54 1312 0.111 ng 92 8) Bromomethane 4.75 94 1136 0.082 ng 90 9) Chloroethane 4.96 64 808 0.072 ng # 42 10) Ethanol 5.17 45 4654 0.436 ng # 59 11) Acetonitrile 5.49 41 2275 0.075 ng # 1 12) Acrolein 5.53 56 152 0.017 ng # 16 13) Acetone 5.66 58 5301 0.423 ng 90 14) Trichlorofluoromethane 5.80 101 2492 0.095 ng 99 15) 2-Propanol (Isopropanol) 5.99 45 6719 0.167 ng 74 16) Acrylonitrile 6.19 53 106 0.005 ng # 58 17) 1,1-Dichloroethene 6.51 96 1386 0.096 ng 100 18) 2-Methyl-2-Propanol (t... 6.65 59 6550 0.166 ng 91 19) Methylene Chloride 6.63 84 1113 0.062 ng 94 20) 3-Chloro-1-propene (Al... 6.77 41 1895 0.084 ng 73 21) Trichlorotrifluoroethane 6.94 151 1236 0.100 ng 98 22) Carbon Disulfide 6.93 76 3950 0.069 ng # 74 23) trans-1,2-Dichloroethene 7.66 61 1459 0.069 ng 87 24) 1,1-Dichloroethane 7.85 63 2474 0.086 ng 94 25) Methyl tert-Butyl Ether 7.97 73 4122 0.088 ng 90 26) Vinyl Acetate 0.00 86 0 N.D. 27) 2-Butanone (MEK) 0.00 72 0 N.D. 28) cis-1,2-Dichloroethene 8.74 61 1656 0.080 ng # 51 29) Diisopropyl Ether 9.00 87 1136 0.090 ng # 89 30) Ethyl Acetate 9.01 61 520 0.093 ng # 12 31) n-Hexane 8.98 57 2293 0.084 ng # 87 32) Chloroform 9.03 83 2534 0.098 ng 98 34) Tetrahydrofuran (THF) 9.48 72 913 0.084 ng # 91 35) Ethyl tert-Butyl Ether 9.55 87 1429 0.078 ng 93 36) 1,2-Dichloroethane 9.79 62 1701 0.095 ng 84 38) 1,1,1-Trichloroethane 10.05 97 2218 0.111 ng 96 39) Isopropyl Acetate 10.46 61 1464 0.168 ng # 87 40) 1-Butanol 10.50 56 1850 0.141 ng # 74 41) Benzene 10.51 78 7153 0.116 ng 100 42) Carbon Tetrachloride 10.66 117 1669 0.101 ng 90 43) Cyclohexane 10.79 84 4298 0.197 ng 99 44) tert-Amyl Methyl Ether 11.14 73 3824 0.093 ng # 80 45) 1,2-Dichloropropane 11.33 63 1464 0.100 ng 88 46) Bromodichloromethane 11.52 83 1820 0.100 ng 98 47) Trichloroethene 11.58 130 1661 0.113 ng 98 48) 1,4-Dioxane 11.60 88 666 0.064 ng # 19 49) 2,2,4-Trimethylpentane... 11.63 57 6176 0.095 ng 93

R9061416.M Wed Jun 15 09:41:12 2016 Page: 1

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simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141622.D Acq On : 15 Jun 2016 00:07 Operator: SC Sample : 0.10ng TO-15 ICAL STD Misc : S29-06141607/S29-06021605 (7/1) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Jun 15 09:37:39 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.78 100 538 0.102 ng # 12 51) n-Heptane 11.89 71 1386 0.096 ng # 81 52) cis-1,3-Dichloropropene 12.44 75 1472 0.071 ng # 42 53) 4-Methyl-2-pentanone 12.48 58 829 0.064 ng # 44 54) trans-1,3-Dichloropropene 12.97 75 495 0.026 ng # 43 55) 1,1,2-Trichloroethane 13.13 97 1169 0.087 ng 94 58) Toluene 13.42 91 6368 0.116 ng 100 59) 2-Hexanone 13.72 43 457 0.018 ng # 22 60) Dibromochloromethane 13.83 129 1419 0.108 ng 83 61) 1,2-Dibromoethane 14.10 107 976 0.074 ng 98 62) n-Butyl Acetate 14.33 43 833 0.028 ng # 78 63) n-Octane 14.44 57 1047 0.087 ng # 93 64) Tetrachloroethene 14.57 166 1681 0.119 ng 86 65) Chlorobenzene 15.27 112 3995 0.120 ng 93 66) Ethylbenzene 15.68 91 5878 0.102 ng 93 67) m- & p-Xylenes 15.87 91 9561 0.207 ng 97 68) Bromoform 15.94 173 962 0.086 ng 100 69) Styrene 16.26 104 2627 0.079 ng 96 70) o-Xylene 16.37 91 4822 0.101 ng 95 71) n-Nonane 16.61 43 2444 0.088 ng 96 72) 1,1,2,2-Tetrachloroethane 16.35 83 1753 0.078 ng 88 74) Cumene 16.99 105 6159 0.103 ng 96 75) alpha-Pinene 17.40 93 3073 0.102 ng 98 76) n-Propylbenzene 17.53 91 6479 0.088 ng 96 77) 3-Ethyltoluene 17.63 105 5289 0.092 ng 100 78) 4-Ethyltoluene 17.68 105 5223 0.095 ng 99 79) 1,3,5-Trimethylbenzene 17.76 105 5509 0.116 ng 89 80) alpha-Methylstyrene 17.92 118 1966 0.081 ng 92 81) 2-Ethyltoluene 17.95 105 5803 0.104 ng 100 82) 1,2,4-Trimethylbenzene 18.19 105 4832 0.103 ng 92 83) n-Decane 18.31 57 2521 0.089 ng 82 84) Benzyl Chloride 18.35 91 1089 0.027 ng # 55 85) 1,3-Dichlorobenzene 18.35 146 2328 0.095 ng 93 86) 1,4-Dichlorobenzene 18.42 146 2688 0.107 ng 88 87) sec-Butylbenzene 18.48 105 6604 0.105 ng 98 88) 4-Isopropyltoluene (p-... 18.65 119 5696 0.099 ng 96 89) 1,2,3-Trimethylbenzene 18.64 105 4919 0.102 ng 96 90) 1,2-Dichlorobenzene 18.78 146 2512 0.105 ng 95 91) d-Limonene 18.80 68 1662 0.086 ng 96 92) 1,2-Dibromo-3-Chloropr... 0.00 157 0 N.D. 93) n-Undecane 19.66 57 2383 0.086 ng 86 94) 1,2,4-Trichlorobenzene 20.62 180 1131 0.059 ng # 74 95) Naphthalene 20.74 128 2755 0.043 ng # 71 96) n-Dodecane 20.75 57 2359 0.082 ng # 69 97) Hexachlorobutadiene 21.07 225 1304 0.127 ng 92 98) Cyclohexanone 16.04 55 1294 0.081 ng # 81 99) tert-Butylbenzene 18.19 119 4933 0.108 ng 96 100) n-Butylbenzene 19.10 91 4429 0.091 ng 92 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:41:12 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T

n-Bu

tylb

enze

ne,T

d-Li

mon

ene,

T1,

2-D

ichl

orob

enze

ne,T

4-Is

opro

pylto

luen

e (p

-Cym

ene)

,T1,

2,3-

Trim

ethy

lben

zene

,Tse

c-Bu

tylb

enze

ne,T

1,4-

Dic

hlor

oben

zene

,T1,

3-D

ichl

orob

enze

ne,T

Benz

yl C

hlor

ide,

Tn-

Dec

ane,

T1,

2,4-

Trim

ethy

lben

zene

,Tte

rt-Bu

tylb

enze

ne,T

2-Et

hylto

luen

e,T

alph

a-M

ethy

lsty

rene

,T1,

3,5-

Trim

ethy

lben

zene

,T4-

Ethy

ltolu

ene,

T3-

Ethy

ltolu

ene,

Tn-

Prop

ylbe

nzen

e,T

alph

a-Pi

nene

,TC

umen

e,T

Brom

oflu

orob

enze

ne (S

S3),S

n-N

onan

e,T

o-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

1,4-

Dio

xane

,TTr

ichl

oroe

then

e,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

Met

hyl t

ert-B

utyl

Eth

er,T

1,1-

Dic

hlor

oeth

ane,

Ttra

ns-1

,2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:41:12 2016 Page: 3

63 of 100










Target Compounds Qvalue2) Propene 3.72 42 2570 0.155 ng 933) Dichlorodifluoromethan... 3.81 85 5546 0.170 ng # 954) Chloromethane 4.01 50 3825 0.140 ng 945) 1,2-Dichloro-1,1,2,2-t... 4.16 135 2716 0.168 ng 976) Vinyl Chloride 4.28 62 3369 0.145 ng 957) 1,3-Butadiene 4.45 54 2362 0.201 ng 968) Bromomethane 4.75 94 2261 0.165 ng 929) Chloroethane 4.96 64 1853 0.165 ng 8510) Ethanol 5.18 45 9039 0.850 ng 8311) Acetonitrile 5.46 41 4429 0.147 ng # 2512) Acrolein 5.52 56 645 0.072 ng # 7013) Acetone 5.65 58 9452 0.758 ng 9714) Trichlorofluoromethane 5.81 101 4509 0.173 ng 9715) 2-Propanol (Isopropanol) 5.97 45 12273 0.307 ng 9916) Acrylonitrile 6.19 53 1465 0.070 ng # 817) 1,1-Dichloroethene 6.50 96 2320 0.161 ng 9218) 2-Methyl-2-Propanol (t... 6.65 59 11825 0.300 ng 9319) Methylene Chloride 6.63 84 2140 0.119 ng 8320) 3-Chloro-1-propene (Al... 6.76 41 3131 0.139 ng 8621) Trichlorotrifluoroethane 6.94 151 2097 0.171 ng 9622) Carbon Disulfide 6.93 76 8600 0.152 ng # 7423) trans-1,2-Dichloroethene 7.65 61 2541 0.120 ng 9624) 1,1-Dichloroethane 7.85 63 4536 0.158 ng 9625) Methyl tert-Butyl Ether 7.96 73 6852 0.147 ng 10026) Vinyl Acetate 8.06 86 987 0.309 ng # 2927) 2-Butanone (MEK) 8.33 72 1292 0.131 ng # 6028) cis-1,2-Dichloroethene 8.73 61 2974 0.143 ng 9729) Diisopropyl Ether 8.99 87 2271 0.180 ng # 7330) Ethyl Acetate 9.00 61 1190 0.213 ng 9931) n-Hexane 8.99 57 3824 0.141 ng # 9132) Chloroform 9.04 83 4402 0.170 ng 9434) Tetrahydrofuran (THF) 9.48 72 1550 0.143 ng 9335) Ethyl tert-Butyl Ether 9.54 87 2770 0.153 ng 9936) 1,2-Dichloroethane 9.79 62 2819 0.158 ng 9938) 1,1,1-Trichloroethane 10.05 97 3874 0.193 ng 9939) Isopropyl Acetate 10.46 61 2853 0.328 ng 9840) 1-Butanol 10.50 56 3545 0.271 ng # 7841) Benzene 10.51 78 11457 0.187 ng 9942) Carbon Tetrachloride 10.66 117 3056 0.186 ng 10043) Cyclohexane 10.80 84 7441 0.342 ng 9744) tert-Amyl Methyl Ether 11.13 73 6794 0.166 ng 9445) 1,2-Dichloropropane 11.33 63 2449 0.167 ng 9746) Bromodichloromethane 11.51 83 3418 0.188 ng 9047) Trichloroethene 11.58 130 3051 0.208 ng 9948) 1,4-Dioxane 11.58 88 1678 0.162 ng # 1949) 2,2,4-Trimethylpentane... 11.64 57 10721 0.166 ng 99

R9061416.M Wed Jun 15 09:37:01 2016 Page: 1

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Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141623.D Acq On : 15 Jun 2016 00:40 Operator: SC Sample : 0.20ng TO-15 ICAL STD Misc : S29-06141607/S29-06021605 (7/1) ALS Vial : 5 Sample Multiplier: 1 Quant Time: Jun 15 09:35:53 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.78 100 1462 0.277 ng 93 51) n-Heptane 11.90 71 2542 0.177 ng 90 52) cis-1,3-Dichloropropene 12.43 75 3167 0.152 ng 88 53) 4-Methyl-2-pentanone 12.48 58 1809 0.140 ng # 83 54) trans-1,3-Dichloropropene 12.97 75 1986 0.105 ng # 43 55) 1,1,2-Trichloroethane 13.12 97 2320 0.174 ng 95 58) Toluene 13.42 91 10702 0.195 ng 99 59) 2-Hexanone 13.71 43 2566 0.098 ng # 70 60) Dibromochloromethane 13.83 129 2777 0.210 ng 88 61) 1,2-Dibromoethane 14.10 107 2258 0.171 ng 93 62) n-Butyl Acetate 14.33 43 3260 0.109 ng # 79 63) n-Octane 14.44 57 1897 0.157 ng 87 64) Tetrachloroethene 14.58 166 2773 0.195 ng 96 65) Chlorobenzene 15.27 112 7072 0.212 ng 98 66) Ethylbenzene 15.68 91 10247 0.176 ng 99 67) m- & p-Xylenes 15.87 91 16672 0.359 ng 98 68) Bromoform 15.94 173 2002 0.179 ng 90 69) Styrene 16.25 104 5595 0.167 ng 99 70) o-Xylene 16.37 91 8667 0.180 ng 99 71) n-Nonane 16.61 43 4469 0.160 ng 92 72) 1,1,2,2-Tetrachloroethane 16.34 83 3493 0.154 ng 92 74) Cumene 16.99 105 11065 0.184 ng 99 75) alpha-Pinene 17.40 93 5317 0.175 ng 95 76) n-Propylbenzene 17.53 91 12645 0.170 ng 95 77) 3-Ethyltoluene 17.63 105 9834 0.170 ng 99 78) 4-Ethyltoluene 17.68 105 10414 0.188 ng 95 79) 1,3,5-Trimethylbenzene 17.76 105 8983 0.189 ng 97 80) alpha-Methylstyrene 17.92 118 3979 0.163 ng 96 81) 2-Ethyltoluene 17.95 105 10661 0.190 ng 97 82) 1,2,4-Trimethylbenzene 18.19 105 8513 0.181 ng 98 83) n-Decane 18.31 57 4420 0.156 ng 90 84) Benzyl Chloride 18.34 91 2693 0.066 ng # 55 85) 1,3-Dichlorobenzene 18.35 146 4246 0.173 ng 98 86) 1,4-Dichlorobenzene 18.42 146 4554 0.181 ng 99 87) sec-Butylbenzene 18.48 105 11900 0.189 ng 98 88) 4-Isopropyltoluene (p-... 18.65 119 10589 0.183 ng 97 89) 1,2,3-Trimethylbenzene 18.64 105 9081 0.188 ng 95 90) 1,2-Dichlorobenzene 18.78 146 4528 0.188 ng 94 91) d-Limonene 18.79 68 3242 0.166 ng 96 92) 1,2-Dibromo-3-Chloropr... 19.24 157 933 0.095 ng 84 93) n-Undecane 19.65 57 4568 0.163 ng 94 94) 1,2,4-Trichlorobenzene 20.61 180 2556 0.133 ng # 93 95) Naphthalene 20.73 128 6558 0.101 ng # 71 96) n-Dodecane 20.75 57 4309 0.149 ng 84 97) Hexachlorobutadiene 21.07 225 2292 0.223 ng 98 98) Cyclohexanone 16.03 55 2449 0.152 ng 90 99) tert-Butylbenzene 18.18 119 8865 0.192 ng 95 100) n-Butylbenzene 19.10 91 8417 0.171 ng 94 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:37:01 2016 Page: 2

65 of 100




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

1,4-

Dio

xane

,TTr

ichl

oroe

then

e,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T2-

Buta

none

(MEK

),TVi

nyl A

ceta

te,T

Met

hyl t

ert-B

utyl

Eth

er,T

1,1-

Dic

hlor

oeth

ane,

Ttra

ns-1

,2-D

ichl

oroe

then

e,T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:37:02 2016 Page: 3

66 of 100










Target Compounds Qvalue2) Propene 3.71 42 5163 0.354 ng 983) Dichlorodifluoromethan... 3.80 85 10462 0.367 ng 984) Chloromethane 4.00 50 7578 0.316 ng 975) 1,2-Dichloro-1,1,2,2-t... 4.16 135 5560 0.393 ng 996) Vinyl Chloride 4.28 62 7112 0.350 ng 987) 1,3-Butadiene 4.44 54 4867 0.474 ng 988) Bromomethane 4.74 94 4198 0.350 ng 979) Chloroethane 4.95 64 3937 0.400 ng 8810) Ethanol 5.15 45 17857 1.918 ng 9111) Acetonitrile 5.36 41 8891 0.337 ng 9212) Acrolein 5.51 56 2123 0.272 ng 8013) Acetone 5.64 58 18226 1.669 ng 9714) Trichlorofluoromethane 5.80 101 8813 0.385 ng 9815) 2-Propanol (Isopropanol) 5.94 45 23795 0.680 ng 9316) Acrylonitrile 6.16 53 5401 0.295 ng 10017) 1,1-Dichloroethene 6.50 96 4507 0.358 ng 9418) 2-Methyl-2-Propanol (t... 6.64 59 23468 0.681 ng 9719) Methylene Chloride 6.63 84 4405 0.280 ng 9620) 3-Chloro-1-propene (Al... 6.77 41 6259 0.318 ng 9221) Trichlorotrifluoroethane 6.94 151 4382 0.408 ng 9822) Carbon Disulfide 6.91 76 14577 0.293 ng 9823) trans-1,2-Dichloroethene 7.65 61 5849 0.316 ng 9124) 1,1-Dichloroethane 7.85 63 8625 0.344 ng 9625) Methyl tert-Butyl Ether 7.96 73 14376 0.353 ng 9726) Vinyl Acetate 8.05 86 2148 0.768 ng # 5327) 2-Butanone (MEK) 8.30 72 2632 0.305 ng # 6528) cis-1,2-Dichloroethene 8.73 61 6181 0.341 ng 9729) Diisopropyl Ether 8.99 87 5033 0.456 ng # 5330) Ethyl Acetate 8.99 61 2722 0.558 ng 8631) n-Hexane 8.98 57 8299 0.349 ng 9732) Chloroform 9.03 83 8250 0.365 ng 10034) Tetrahydrofuran (THF) 9.47 72 3134 0.330 ng 9135) Ethyl tert-Butyl Ether 9.54 87 5736 0.361 ng 9636) 1,2-Dichloroethane 9.78 62 6017 0.385 ng 9838) 1,1,1-Trichloroethane 10.05 97 7566 0.432 ng 9739) Isopropyl Acetate 10.45 61 5713 0.752 ng 9840) 1-Butanol 10.48 56 7768 0.681 ng # 3441) Benzene 10.51 78 21798 0.407 ng 9942) Carbon Tetrachloride 10.66 117 6175 0.431 ng 9943) Cyclohexane 10.79 84 14664 0.771 ng 9744) tert-Amyl Methyl Ether 11.13 73 13301 0.371 ng 9845) 1,2-Dichloropropane 11.33 63 4859 0.379 ng 9646) Bromodichloromethane 11.51 83 6671 0.420 ng 9947) Trichloroethene 11.58 130 5671 0.442 ng 9748) 1,4-Dioxane 11.57 88 3203 0.353 ng 9649) 2,2,4-Trimethylpentane... 11.64 57 20975 0.371 ng 98

R9061416.M Wed Jun 15 09:35:38 2016 Page: 1

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Simon





50) Methyl Methacrylate 11.78 100 2751 0.598 ng # 7651) n-Heptane 11.90 71 4816 0.383 ng 10052) cis-1,3-Dichloropropene 12.44 75 6797 0.375 ng 8953) 4-Methyl-2-pentanone 12.48 58 3876 0.344 ng 8954) trans-1,3-Dichloropropene 12.96 75 4530 0.273 ng 9155) 1,1,2-Trichloroethane 13.12 97 4867 0.417 ng 9358) Toluene 13.42 91 20365 0.424 ng 9959) 2-Hexanone 13.69 43 7168 0.314 ng 9460) Dibromochloromethane 13.83 129 5248 0.454 ng 9861) 1,2-Dibromoethane 14.09 107 4772 0.413 ng 9262) n-Butyl Acetate 14.32 43 6768 0.258 ng 9663) n-Octane 14.44 57 4076 0.386 ng 9664) Tetrachloroethene 14.57 166 5756 0.462 ng 9865) Chlorobenzene 15.27 112 13000 0.445 ng 9566) Ethylbenzene 15.68 91 20358 0.401 ng 10067) m- & p-Xylenes 15.87 91 32301 0.796 ng 9868) Bromoform 15.93 173 4206 0.430 ng 9469) Styrene 16.26 104 11058 0.377 ng 9870) o-Xylene 16.37 91 16993 0.404 ng 10071) n-Nonane 16.61 43 9202 0.376 ng 9372) 1,1,2,2-Tetrachloroethane 16.35 83 6606 0.333 ng 9574) Cumene 16.99 105 21790 0.414 ng 9875) alpha-Pinene 17.40 93 10168 0.383 ng 8076) n-Propylbenzene 17.53 91 24512 0.377 ng 9877) 3-Ethyltoluene 17.63 105 20454 0.405 ng 9678) 4-Ethyltoluene 17.68 105 19154 0.396 ng 9679) 1,3,5-Trimethylbenzene 17.75 105 17645 0.424 ng 9780) alpha-Methylstyrene 17.92 118 8472 0.396 ng 9381) 2-Ethyltoluene 17.95 105 21285 0.434 ng 9782) 1,2,4-Trimethylbenzene 18.19 105 17409 0.424 ng 9983) n-Decane 18.31 57 9534 0.384 ng 9684) Benzyl Chloride 18.33 91 6848 0.192 ng 8885) 1,3-Dichlorobenzene 18.35 146 9345 0.436 ng 9586) 1,4-Dichlorobenzene 18.42 146 8726 0.397 ng 9687) sec-Butylbenzene 18.48 105 24276 0.440 ng 9888) 4-Isopropyltoluene (p-... 18.64 119 20924 0.413 ng 9989) 1,2,3-Trimethylbenzene 18.64 105 18280 0.432 ng 9490) 1,2-Dichlorobenzene 18.77 146 9362 0.444 ng 9691) d-Limonene 18.80 68 6548 0.384 ng 9992) 1,2-Dibromo-3-Chloropr... 19.25 157 2139 0.250 ng 9093) n-Undecane 19.65 57 9740 0.398 ng 9594) 1,2,4-Trichlorobenzene 20.59 180 5129 0.306 ng 9595) Naphthalene 20.72 128 14596 0.257 ng 9696) n-Dodecane 20.74 57 8430 0.333 ng 9297) Hexachlorobutadiene 21.07 225 4360 0.485 ng 9898) Cyclohexanone 16.03 55 4876 0.346 ng 9799) tert-Butylbenzene 18.18 119 17610 0.437 ng 99

100) n-Butylbenzene 19.09 91 16987 0.395 ng 97 --------------------------------------------------------------------------


R9061416.M Wed Jun 15 09:35:38 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

Met

hyle

ne C

hlor

ide,

T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:35:39 2016 Page: 3

69 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141625.D Acq On : 15 Jun 2016 1:48 Operator: SC Sample : 1.0ng TO-15 ICAL STD Misc : S29-06141607/S29-06021603 (7/1) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Jun 15 09:33:15 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.89 130 110747 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.87 114 510746 12.500 ng -0.01 56) Chlorobenzene-d5 (IS3) 15.22 82 203032 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.68 65 157729 10.922 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 87.36% 57) Toluene-d8 (SS2) 13.31 98 527928 13.816 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.56% 73) Bromofluorobenzene (SS3) 16.84 174 159958 12.672 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 101.36% Target Compounds Qvalue 2) Propene 3.69 42 13629 0.813 ng 99 3) Dichlorodifluoromethan... 3.79 85 29086 0.887 ng 100 4) Chloromethane 3.99 50 21209 0.768 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.14 135 15631 0.959 ng 98 6) Vinyl Chloride 4.26 62 19744 0.844 ng 99 7) 1,3-Butadiene 4.43 54 14334 1.212 ng 98 8) Bromomethane 4.73 94 12690 0.918 ng 98 9) Chloroethane 4.94 64 10184 0.899 ng 98 10) Ethanol 5.14 45 50471 4.709 ng 99 11) Acetonitrile 5.36 41 24823 0.819 ng 82 12) Acrolein 5.49 56 7081 0.790 ng 97 13) Acetone 5.62 58 49950 3.976 ng 98 14) Trichlorofluoromethane 5.80 101 23785 0.904 ng 100 15) 2-Propanol (Isopropanol) 5.93 45 67396 1.674 ng 93 16) Acrylonitrile 6.15 53 16806 0.798 ng 96 17) 1,1-Dichloroethene 6.49 96 12766 0.881 ng 95 18) 2-Methyl-2-Propanol (t... 6.57 59 67768 1.708 ng 98 19) Methylene Chloride 6.62 84 13413 0.741 ng 98 20) 3-Chloro-1-propene (Al... 6.76 41 18584 0.822 ng 94 21) Trichlorotrifluoroethane 6.94 151 11951 0.968 ng 98 22) Carbon Disulfide 6.90 76 44618 0.780 ng 100 23) trans-1,2-Dichloroethene 7.64 61 18111 0.851 ng 96 24) 1,1-Dichloroethane 7.85 63 25090 0.869 ng 99 25) Methyl tert-Butyl Ether 7.95 73 38958 0.831 ng 100 26) Vinyl Acetate 8.04 86 9140 2.838 ng # 77 27) 2-Butanone (MEK) 8.29 72 8857 0.891 ng 94 28) cis-1,2-Dichloroethene 8.73 61 18064 0.865 ng 99 29) Diisopropyl Ether 8.98 87 11424 0.899 ng 99 30) Ethyl Acetate 8.98 61 9552 1.700 ng 96 31) n-Hexane 8.98 57 22725 0.830 ng 98 32) Chloroform 9.03 83 24301 0.933 ng 98 34) Tetrahydrofuran (THF) 9.45 72 8663 0.792 ng 95 35) Ethyl tert-Butyl Ether 9.53 87 15645 0.856 ng 98 36) 1,2-Dichloroethane 9.79 62 17012 0.946 ng 99 38) 1,1,1-Trichloroethane 10.05 97 20969 1.058 ng 98 39) Isopropyl Acetate 10.44 61 16796 1.952 ng 99 40) 1-Butanol 10.46 56 25833 1.997 ng 90 41) Benzene 10.51 78 55163 0.909 ng 100 42) Carbon Tetrachloride 10.66 117 18036 1.110 ng 99 43) Cyclohexane 10.79 84 40943 1.901 ng 99 44) tert-Amyl Methyl Ether 11.12 73 37245 0.917 ng 98 45) 1,2-Dichloropropane 11.33 63 14559 1.003 ng 99 46) Bromodichloromethane 11.51 83 18669 1.037 ng 97 47) Trichloroethene 11.57 130 15314 1.053 ng 97 48) 1,4-Dioxane 11.56 88 10653 1.036 ng 97 49) 2,2,4-Trimethylpentane... 11.64 57 57571 0.899 ng 98

R9061416.M Wed Jun 15 09:34:13 2016 Page: 1

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simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141625.D Acq On : 15 Jun 2016 1:48 Operator: SC Sample : 1.0ng TO-15 ICAL STD Misc : S29-06141607/S29-06021603 (7/1) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Jun 15 09:33:15 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.77 100 10407 1.995 ng 99 51) n-Heptane 11.90 71 13773 0.968 ng 100 52) cis-1,3-Dichloropropene 12.43 75 20769 1.010 ng 99 53) 4-Methyl-2-pentanone 12.47 58 12298 0.964 ng 96 54) trans-1,3-Dichloropropene 12.95 75 15661 0.833 ng 99 55) 1,1,2-Trichloroethane 13.12 97 13902 1.052 ng 99 58) Toluene 13.42 91 56892 1.035 ng 98 59) 2-Hexanone 13.67 43 27359 1.047 ng 98 60) Dibromochloromethane 13.82 129 15649 1.183 ng 97 61) 1,2-Dibromoethane 14.09 107 14821 1.123 ng 97 62) n-Butyl Acetate 14.32 43 29450 0.984 ng 98 63) n-Octane 14.44 57 11580 0.960 ng 96 64) Tetrachloroethene 14.57 166 15452 1.084 ng 96 65) Chlorobenzene 15.27 112 37251 1.116 ng 98 66) Ethylbenzene 15.68 91 61397 1.057 ng 98 67) m- & p-Xylenes 15.87 91 98274 2.118 ng 100 68) Bromoform 15.93 173 12834 1.148 ng 99 69) Styrene 16.25 104 36033 1.075 ng 99 70) o-Xylene 16.37 91 51084 1.061 ng 97 71) n-Nonane 16.61 43 26308 0.940 ng 99 72) 1,1,2,2-Tetrachloroethane 16.34 83 22845 1.007 ng 100 74) Cumene 16.99 105 63546 1.056 ng 100 75) alpha-Pinene 17.40 93 29835 0.983 ng 91 76) n-Propylbenzene 17.52 91 77131 1.039 ng 98 77) 3-Ethyltoluene 17.63 105 59999 1.039 ng 95 78) 4-Ethyltoluene 17.68 105 61662 1.115 ng 96 79) 1,3,5-Trimethylbenzene 17.75 105 51032 1.072 ng 98 80) alpha-Methylstyrene 17.92 118 27024 1.104 ng 100 81) 2-Ethyltoluene 17.95 105 62423 1.114 ng 100 82) 1,2,4-Trimethylbenzene 18.19 105 52171 1.111 ng 99 83) n-Decane 18.31 57 28605 1.007 ng 100 84) Benzyl Chloride 18.32 91 29557 0.723 ng 97 85) 1,3-Dichlorobenzene 18.34 146 30428 1.240 ng 97 86) 1,4-Dichlorobenzene 18.41 146 30067 1.197 ng 99 87) sec-Butylbenzene 18.47 105 70999 1.126 ng 99 88) 4-Isopropyltoluene (p-... 18.64 119 64034 1.105 ng 99 89) 1,2,3-Trimethylbenzene 18.64 105 53985 1.116 ng 100 90) 1,2-Dichlorobenzene 18.77 146 30078 1.248 ng 98 91) d-Limonene 18.80 68 20248 1.039 ng 98 92) 1,2-Dibromo-3-Chloropr... 19.24 157 8615 0.879 ng 92 93) n-Undecane 19.65 57 29200 1.044 ng 98 94) 1,2,4-Trichlorobenzene 20.59 180 19699 1.028 ng 99 95) Naphthalene 20.71 128 62976 0.971 ng 98 96) n-Dodecane 20.74 57 30312 1.046 ng 99 97) Hexachlorobutadiene 21.07 225 13584 1.321 ng 97 98) Cyclohexanone 16.02 55 18221 1.130 ng 98 99) tert-Butylbenzene 18.18 119 52016 1.130 ng 99 100) n-Butylbenzene 19.09 91 56683 1.153 ng 98 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:34:13 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

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hlor

oben

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Isop

ropy

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hylb

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sec-

Buty

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Buty

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Tal

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Met

hyls

tyre

ne,T

1,3,

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imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

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chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

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than

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rom

ochl

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ne,T

2-H

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one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

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than

e,T

trans

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-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

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hane

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2-D

ichl

orop

ropa

ne,T

tert-

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yl M

ethy

l Eth

er,T

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Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

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hlor

oeth

ane,

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ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,T

Chl

orof

orm

,Tn-

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ane,

TEt

hyl A

ceta

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opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

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hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

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loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

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lein

,TAc

eton

itrile

,TEt

hano

l,TC

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ane,

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omom

etha

ne,T

1,3-

Buta

dien

e,T

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l Chl

orid

e,T

1,2-

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hlor

o-1,

1,2,

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than

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orom

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ne,T

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hlor

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uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:34:14 2016 Page: 3

72 of 100










Target Compounds Qvalue2) Propene 3.67 42 63222 4.263 ng 1003) Dichlorodifluoromethan... 3.78 85 135177 4.659 ng 1004) Chloromethane 3.97 50 97404 3.987 ng 995) 1,2-Dichloro-1,1,2,2-t... 4.13 135 71326 4.947 ng 996) Vinyl Chloride 4.24 62 93733 4.532 ng 997) 1,3-Butadiene 4.42 54 65411 6.253 ng 968) Bromomethane 4.72 94 57409 4.696 ng 999) Chloroethane 4.93 64 43222 4.311 ng 9910) Ethanol 5.15 45 236754 24.971 ng 9911) Acetonitrile 5.35 41 114819 4.280 ng 9712) Acrolein 5.48 56 39475 4.976 ng 9913) Acetone 5.61 58 235898 21.223 ng 9714) Trichlorofluoromethane 5.78 101 109110 4.686 ng 10015) 2-Propanol (Isopropanol) 5.93 45 318717 8.948 ng 9716) Acrylonitrile 6.14 53 81548 4.377 ng 9917) 1,1-Dichloroethene 6.48 96 60306 4.703 ng 9818) 2-Methyl-2-Propanol (t... 6.57 59 318720 9.080 ng 10019) Methylene Chloride 6.62 84 64173 4.007 ng 10020) 3-Chloro-1-propene (Al... 6.75 41 88466 4.420 ng 9821) Trichlorotrifluoroethane 6.93 151 54826 5.017 ng 9922) Carbon Disulfide 6.89 76 222549 4.399 ng 9923) trans-1,2-Dichloroethene 7.64 61 90608 4.810 ng 9724) 1,1-Dichloroethane 7.86 63 114809 4.493 ng 9825) Methyl tert-Butyl Ether 7.93 73 187750 4.527 ng 9926) Vinyl Acetate 8.04 86 54571 19.155 ng # 8627) 2-Butanone (MEK) 8.28 72 41780 4.750 ng 9328) cis-1,2-Dichloroethene 8.73 61 85228 4.613 ng 10029) Diisopropyl Ether 8.98 87 52168 4.643 ng # 9330) Ethyl Acetate 8.98 61 46106 9.276 ng 9831) n-Hexane 8.98 57 105937 4.373 ng 9932) Chloroform 9.04 83 110296 4.787 ng 9934) Tetrahydrofuran (THF) 9.44 72 40901 4.226 ng 9735) Ethyl tert-Butyl Ether 9.53 87 72691 4.494 ng 9536) 1,2-Dichloroethane 9.79 62 78333 4.923 ng 10038) 1,1,1-Trichloroethane 10.05 97 97110 5.453 ng 9939) Isopropyl Acetate 10.44 61 79116 10.237 ng # 9340) 1-Butanol 10.45 56 133660 11.506 ng 9641) Benzene 10.51 78 257199 4.718 ng 9942) Carbon Tetrachloride 10.66 117 83565 5.725 ng 9843) Cyclohexane 10.79 84 193083 9.978 ng 10044) tert-Amyl Methyl Ether 11.12 73 177165 4.856 ng 9845) 1,2-Dichloropropane 11.33 63 64111 4.919 ng 10046) Bromodichloromethane 11.52 83 88275 5.460 ng 9947) Trichloroethene 11.57 130 71440 5.471 ng 9948) 1,4-Dioxane 11.55 88 51359 5.562 ng 10049) 2,2,4-Trimethylpentane... 11.64 57 269301 4.680 ng 100

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simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141626.D Acq On : 15 Jun 2016 2:22 Operator: SC Sample : 5.0ng TO-15 ICAL STD Misc : S29-06141607/S29-06021603 (7/1) ALS Vial : 6 Sample Multiplier: 1 Quant Time: Jun 15 09:31:59 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.77 100 49752 10.619 ng 97 51) n-Heptane 11.89 71 63072 4.933 ng 98 52) cis-1,3-Dichloropropene 12.43 75 105721 5.724 ng 98 53) 4-Methyl-2-pentanone 12.46 58 60085 5.242 ng 95 54) trans-1,3-Dichloropropene 12.94 75 86933 5.148 ng 99 55) 1,1,2-Trichloroethane 13.12 97 63389 5.341 ng 98 58) Toluene 13.42 91 264943 5.392 ng 99 59) 2-Hexanone 13.66 43 141338 6.051 ng 100 60) Dibromochloromethane 13.82 129 76371 6.458 ng 99 61) 1,2-Dibromoethane 14.08 107 71743 6.080 ng 100 62) n-Butyl Acetate 14.31 43 157180 5.872 ng 99 63) n-Octane 14.44 57 54888 5.089 ng 99 64) Tetrachloroethene 14.57 166 72857 5.717 ng 98 65) Chlorobenzene 15.27 112 173969 5.831 ng 99 66) Ethylbenzene 15.67 91 293570 5.652 ng 100 67) m- & p-Xylenes 15.87 91 472621 11.391 ng 99 68) Bromoform 15.93 173 64619 6.463 ng 99 69) Styrene 16.25 104 184309 6.152 ng 99 70) o-Xylene 16.36 91 239126 5.557 ng 100 71) n-Nonane 16.61 43 129907 5.190 ng 98 72) 1,1,2,2-Tetrachloroethane 16.34 83 113531 5.597 ng 100 74) Cumene 16.98 105 303420 5.642 ng 100 75) alpha-Pinene 17.40 93 153097 5.643 ng 96 76) n-Propylbenzene 17.52 91 374163 5.635 ng 99 77) 3-Ethyltoluene 17.63 105 300057 5.810 ng 100 78) 4-Ethyltoluene 17.67 105 298835 6.042 ng 100 79) 1,3,5-Trimethylbenzene 17.75 105 251955 5.920 ng 99 80) alpha-Methylstyrene 17.91 118 139403 6.369 ng 99 81) 2-Ethyltoluene 17.95 105 302638 6.039 ng 99 82) 1,2,4-Trimethylbenzene 18.19 105 257526 6.131 ng 100 83) n-Decane 18.31 57 144231 5.681 ng 98 84) Benzyl Chloride 18.32 91 188779 5.164 ng 99 85) 1,3-Dichlorobenzene 18.34 146 149333 6.809 ng 99 86) 1,4-Dichlorobenzene 18.41 146 152108 6.770 ng 99 87) sec-Butylbenzene 18.47 105 352975 6.259 ng 99 88) 4-Isopropyltoluene (p-... 18.64 119 317596 6.132 ng 99 89) 1,2,3-Trimethylbenzene 18.64 105 270129 6.244 ng 99 90) 1,2-Dichlorobenzene 18.77 146 148855 6.906 ng 98 91) d-Limonene 18.79 68 103804 5.956 ng 99 92) 1,2-Dibromo-3-Chloropr... 19.23 157 48906 5.581 ng 97 93) n-Undecane 19.65 57 153045 6.122 ng 97 94) 1,2,4-Trichlorobenzene 20.59 180 106250 6.200 ng 99 95) Naphthalene 20.70 128 351891 6.067 ng 99 96) n-Dodecane 20.74 57 160049 6.178 ng 99 97) Hexachlorobutadiene 21.07 225 65346 7.106 ng 100 98) Cyclohexanone 16.01 55 92561 6.418 ng 99 99) tert-Butylbenzene 18.18 119 254068 6.171 ng 98 100) n-Butylbenzene 19.08 91 291939 6.642 ng 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:33:00 2016 Page: 2

74 of 100




4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

200000

400000

600000

800000

1000000

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

3200000

3400000

3600000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,T

Cum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-

Xyle

ne,T

1,1,

2,2-

Tetra

chlo

roet

hane

,TSt

yren

e,T

Cyc

lohe

xano

ne,T

Brom

ofor

m,T

m- &

p-X

ylen

es,T

Ethy

lben

zene

,TC

hlor

oben

zene

,TC

hlor

oben

zene

-d5

(IS3)

,IR

Tetra

chlo

roet

hene

,Tn-

Oct

ane,

Tn-

Buty

l Ace

tate

,T1,

2-D

ibro

moe

than

e,T

Dib

rom

ochl

orom

etha

ne,T

2-H

exan

one,

TTo

luen

e,T

Tolu

ene-

d8 (S

S2),S

1,1,

2-Tr

ichl

oroe

than

e,T

trans

-1,3

-Dic

hlor

opro

pene

,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T1-Bu

tano

l,TIs

opro

pyl A

ceta

te,T

1,1,

1-Tr

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e-d4

(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

hydr

ofur

an (T

HF)

,TC

hlor

ofor

m,T

n-H

exan

e,T

Ethy

l Ace

tate

,TD

iisop

ropy

l Eth

er,T

Brom

ochl

orom

etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:33:01 2016 Page: 3

75 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141627.D Acq On : 15 Jun 2016 2:56 Operator: SC Sample : 25ng TO-15 ICAL STD Misc : S29-06141607/S29-06021601 (7/1) ALS Vial : 7 Sample Multiplier: 1 Quant Time: Jun 15 09:29:00 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Fri Apr 22 10:14:32 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.91 130 103722 12.500 ng -0.03 37) 1,4-Difluorobenzene (IS2) 10.88 114 480704 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 15.23 82 192657 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.69 65 149325 11.040 ng -0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 88.32% 57) Toluene-d8 (SS2) 13.32 98 499157 13.766 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 110.16% 73) Bromofluorobenzene (SS3) 16.84 174 157319 13.135 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 105.04% Target Compounds Qvalue 2) Propene 3.67 42 380744 24.252 ng 99 3) Dichlorodifluoromethan... 3.77 85 802868 26.140 ng 99 4) Chloromethane 3.97 50 597997 23.121 ng 99 5) 1,2-Dichloro-1,1,2,2-t... 4.13 135 433309 28.387 ng 100 6) Vinyl Chloride 4.24 62 568635 25.969 ng 100 7) 1,3-Butadiene 4.42 54 446948 40.359 ng 98 8) Bromomethane 4.72 94 358430 27.697 ng 99 9) Chloroethane 4.93 64 278211 26.212 ng 100 10) Ethanol 5.19 45 1394705 138.955 ng 100 11) Acetonitrile 5.37 41 681444 23.996 ng 99 12) Acrolein 5.49 56 247679 29.491 ng 98 13) Acetone 5.64 58 1420488 120.717 ng 93 14) Trichlorofluoromethane 5.79 101 637529 25.865 ng 99 15) 2-Propanol (Isopropanol) 5.97 45 1950765 51.736 ng 97 16) Acrylonitrile 6.16 53 503797 25.544 ng 99 17) 1,1-Dichloroethene 6.48 96 376168 27.709 ng 100 18) 2-Methyl-2-Propanol (t... 6.60 59 1982117 53.341 ng 100 19) Methylene Chloride 6.65 84 387936 22.880 ng 97 20) 3-Chloro-1-propene (Al... 6.76 41 553317 26.116 ng 99 21) Trichlorotrifluoroethane 6.94 151 327848 28.340 ng 99 22) Carbon Disulfide 6.90 76 1403768 26.208 ng 100 23) trans-1,2-Dichloroethene 7.66 61 550972 27.628 ng 98 24) 1,1-Dichloroethane 7.87 63 677371 25.042 ng 100 25) Methyl tert-Butyl Ether 7.94 73 1140218 25.969 ng 99 26) Vinyl Acetate 8.05 86 420806 139.528 ng 98 27) 2-Butanone (MEK) 8.29 72 264802 28.441 ng 100 28) cis-1,2-Dichloroethene 8.75 61 527826 26.985 ng 98 29) Diisopropyl Ether 8.99 87 319410 26.853 ng 98 30) Ethyl Acetate 8.99 61 288311 54.793 ng 95 31) n-Hexane 8.99 57 627322 24.463 ng 100 32) Chloroform 9.06 83 668748 27.416 ng 100 34) Tetrahydrofuran (THF) 9.44 72 243517 23.768 ng 98 35) Ethyl tert-Butyl Ether 9.53 87 458688 26.790 ng 99 36) 1,2-Dichloroethane 9.80 62 474619 28.174 ng 100 38) 1,1,1-Trichloroethane 10.06 97 584585 31.327 ng 99 39) Isopropyl Acetate 10.44 61 490523 60.577 ng 95 40) 1-Butanol 10.46 56 835906 68.673 ng 98 41) Benzene 10.52 78 1514700 26.517 ng 100 42) Carbon Tetrachloride 10.67 117 519812 33.990 ng 100 43) Cyclohexane 10.80 84 1171504 57.778 ng 98 44) tert-Amyl Methyl Ether 11.12 73 1103225 28.861 ng 100 45) 1,2-Dichloropropane 11.34 63 387951 28.410 ng 99 46) Bromodichloromethane 11.52 83 547056 32.292 ng 99 47) Trichloroethene 11.58 130 427657 31.255 ng 99 48) 1,4-Dioxane 11.55 88 323478 33.433 ng 98 49) 2,2,4-Trimethylpentane... 11.64 57 1627428 26.990 ng 99

R9061416.M Wed Jun 15 09:30:00 2016 Page: 1

76 of 100

simon.cao

Simon

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141627.D Acq On : 15 Jun 2016 2:56 Operator: SC Sample : 25ng TO-15 ICAL STD Misc : S29-06141607/S29-06021601 (7/1) ALS Vial : 7 Sample Multiplier: 1 Quant Time: Jun 15 09:29:00 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Fri Apr 22 10:14:32 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 50) Methyl Methacrylate 11.77 100 320244 65.235 ng 100 51) n-Heptane 11.90 71 394298 29.433 ng 99 52) cis-1,3-Dichloropropene 12.43 75 674440 34.848 ng 100 53) 4-Methyl-2-pentanone 12.46 58 378241 31.493 ng 99 54) trans-1,3-Dichloropropene 12.95 75 583910 33.002 ng 100 55) 1,1,2-Trichloroethane 13.12 97 392540 31.568 ng 99 58) Toluene 13.42 91 1616143 30.992 ng 100 59) 2-Hexanone 13.66 43 889924 35.899 ng 98 60) Dibromochloromethane 13.83 129 483947 38.558 ng 100 61) 1,2-Dibromoethane 14.08 107 460415 36.764 ng 100 62) n-Butyl Acetate 14.31 43 1002972 35.305 ng 99 63) n-Octane 14.44 57 344168 30.065 ng 99 64) Tetrachloroethene 14.57 166 457675 33.839 ng 100 65) Chlorobenzene 15.27 112 1080000 34.107 ng 100 66) Ethylbenzene 15.68 91 1851414 33.585 ng 100 67) m- & p-Xylenes 15.87 91 2957806 67.171 ng 99 68) Bromoform 15.93 173 429490 40.476 ng 100 69) Styrene 16.25 104 1188189 37.370 ng 100 70) o-Xylene 16.37 91 1502593 32.904 ng 100 71) n-Nonane 16.61 43 794675 29.918 ng 99 72) 1,1,2,2-Tetrachloroethane 16.34 83 738735 34.317 ng 99 74) Cumene 16.99 105 1912470 33.508 ng 100 75) alpha-Pinene 17.40 93 967751 33.609 ng 99 76) n-Propylbenzene 17.52 91 2350449 33.357 ng 100 77) 3-Ethyltoluene 17.63 105 1980140 36.128 ng 100 78) 4-Ethyltoluene 17.68 105 1846832 35.187 ng 100 79) 1,3,5-Trimethylbenzene 17.76 105 1589788 35.200 ng 100 80) alpha-Methylstyrene 17.92 118 877356 37.770 ng 100 81) 2-Ethyltoluene 17.95 105 1876379 35.280 ng 100 82) 1,2,4-Trimethylbenzene 18.19 105 1673640 37.546 ng 100 83) n-Decane 18.31 57 888468 32.972 ng 99 84) Benzyl Chloride 18.32 91 1482563 38.212 ng 100 85) 1,3-Dichlorobenzene 18.34 146 982708 42.218 ng 100 86) 1,4-Dichlorobenzene 18.41 146 977876 41.011 ng 100 87) sec-Butylbenzene 18.48 105 2206597 36.869 ng 100 88) 4-Isopropyltoluene (p-... 18.64 119 2025390 36.849 ng 100 89) 1,2,3-Trimethylbenzene 18.64 105 1737809 37.848 ng 99 90) 1,2-Dichlorobenzene 18.77 146 947023 41.397 ng 100 91) d-Limonene 18.79 68 652363 35.269 ng 99 92) 1,2-Dibromo-3-Chloropr... 19.23 157 351670 37.817 ng 98 93) n-Undecane 19.65 57 928188 34.986 ng 99 94) 1,2,4-Trichlorobenzene 20.59 180 711851 39.138 ng 100 95) Naphthalene 20.70 128 2347737 38.141 ng 100 96) n-Dodecane 20.74 57 941099 34.228 ng 99 97) Hexachlorobutadiene 21.07 225 428189 43.874 ng 100 98) Cyclohexanone 16.02 55 579457 37.858 ng 99 99) tert-Butylbenzene 18.19 119 1618633 37.042 ng 99 100) n-Butylbenzene 19.09 91 1817410 38.959 ng 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed

R9061416.M Wed Jun 15 09:30:00 2016 Page: 2

77 of 100


Data File: I:\MS09\Data\2016_06\14\06141627.D Acq On : 15 Jun 2016 2:56 Operator: SC Sample : 25ng TO-15 ICAL STD Misc : S29-06141607/S29-06021601 (7/1) ALS Vial : 7 Sample Multiplier: 1

Quant Time: Jun 15 09:29:00 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Fri Apr 22 10:14:32 2016 Response via : Initial Calibration DataAcq Meth:TO15.M

4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,T

Styr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IRTe

trach

loro

ethe

ne,T

n-O

ctan

e,T

n-Bu

tyl A

ceta

te,T

1,2-

Dib

rom

oeth

ane,

TD

ibro

moc

hlor

omet

hane

,T2-

Hex

anon

e,T

Tolu

ene,

TTo

luen

e-d8

(SS2

),S1,

1,2-

Tric

hlor

oeth

ane,

Ttra

ns-1

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ichl

orop

rope

ne,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBenz

ene,

T1-

Buta

nol,TI

sopr

opyl

Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,Tn-

Hex

ane,

TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acry

loni

trile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAcet

onitr

ile,T

Etha

nol,T

Chl

oroe

than

e,T

Brom

omet

hane

,T1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,TD

ichl

orod

ifluo

rom

etha

ne (C

FC 1

2),T

Prop

ene,

T

R9061416.M Wed Jun 15 09:30:03 2016 Page: 3

78 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141628.D Acq On : 15 Jun 2016 3:30 Operator: SC Sample : 50ng TO-15 ICAL STD Misc : S29-06141607/S29-06021601 (7/1) ALS Vial : 7 Sample Multiplier: 1 Quant Time: Jun 15 09:44:27 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.93 130 114550 12.500 ng 0.01 37) 1,4-Difluorobenzene (IS2) 10.89 114 528538 12.500 ng 0.00 56) Chlorobenzene-d5 (IS3) 15.23 82 210792 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.70 65 157662 10.555 ng 0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 84.40% 57) Toluene-d8 (SS2) 13.32 98 541612 13.652 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 109.20% 73) Bromofluorobenzene (SS3) 16.84 174 167237 12.761 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.08% Target Compounds Qvalue 2) Propene 3.67 42 752641 43.409 ng 100 3) Dichlorodifluoromethan... 3.78 85 1586835 46.782 ng 100 4) Chloromethane 3.98 50 1168248 40.900 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.14 135 894151 53.040 ng 100 6) Vinyl Chloride 4.25 62 1166073 48.220 ng 100 7) 1,3-Butadiene 4.43 54 933463 76.322 ng 99 8) Bromomethane 4.73 94 747683 52.314 ng 99 9) Chloroethane 4.94 64 575398 49.087 ng 100 10) Ethanol 5.22 45 2825067 254.856 ng 100 11) Acetonitrile 5.39 41 1404246 44.774 ng 100 12) Acrolein 5.50 56 506505 54.609 ng 98 13) Acetone 5.65 58 2888417 222.263 ng 96 14) Trichlorofluoromethane 5.80 101 1299076 47.723 ng 100 15) 2-Propanol (Isopropanol) 5.99 45 3951119 94.883 ng 99 16) Acrylonitrile 6.18 53 1045109 47.981 ng 100 17) 1,1-Dichloroethene 6.49 96 784530 52.326 ng 97 18) 2-Methyl-2-Propanol (t... 6.63 59 3919018 95.496 ng 99 19) Methylene Chloride 6.66 84 810217 43.268 ng 97 20) 3-Chloro-1-propene (Al... 6.77 41 1129165 48.258 ng 98 21) Trichlorotrifluoroethane 6.95 151 684671 53.590 ng 99 22) Carbon Disulfide 6.91 76 2967956 50.174 ng 100 23) trans-1,2-Dichloroethene 7.67 61 1147347 52.094 ng 99 24) 1,1-Dichloroethane 7.88 63 1389354 46.508 ng 100 25) Methyl tert-Butyl Ether 7.95 73 2360616 48.682 ng 99 26) Vinyl Acetate 8.07 86 901104 270.540 ng # 88 27) 2-Butanone (MEK) 8.30 72 547390 53.235 ng 97 28) cis-1,2-Dichloroethene 8.76 61 1079401 49.968 ng 99 29) Diisopropyl Ether 8.99 87 661068 50.322 ng # 92 30) Ethyl Acetate 9.00 61 594124 102.240 ng 97 31) n-Hexane 8.99 57 1274031 44.985 ng 100 32) Chloroform 9.07 83 1364090 50.636 ng 100 34) Tetrahydrofuran (THF) 9.44 72 509131 44.996 ng 97 35) Ethyl tert-Butyl Ether 9.54 87 956984 50.609 ng 98 36) 1,2-Dichloroethane 9.81 62 957548 51.468 ng 99 38) 1,1,1-Trichloroethane 10.07 97 1188901 57.946 ng 99 39) Isopropyl Acetate 10.45 61 1013428 113.826 ng 94 40) 1-Butanol 10.47 56 1724369 128.843 ng 98 41) Benzene 10.53 78 3141142 50.014 ng 100 42) Carbon Tetrachloride 10.68 117 1067798 63.503 ng 100 43) Cyclohexane 10.81 84 2429920 108.997 ng 99 44) tert-Amyl Methyl Ether 11.13 73 2287496 54.427 ng 99 45) 1,2-Dichloropropane 11.35 63 799160 53.227 ng 99 46) Bromodichloromethane 11.53 83 1122328 60.254 ng 100 47) Trichloroethene 11.59 130 891418 59.252 ng 100 48) 1,4-Dioxane 11.56 88 678796 63.807 ng 99 49) 2,2,4-Trimethylpentane... 11.65 57 3321780 50.104 ng 100

R9061416.M Wed Jun 15 09:45:23 2016 Page: 1

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simon.cao

Simon





50) Methyl Methacrylate 11.78 100 674190 124.906 ng 9851) n-Heptane 11.90 71 812226 55.143 ng 9952) cis-1,3-Dichloropropene 12.43 75 1400012 65.791 ng 10053) 4-Methyl-2-pentanone 12.47 58 779909 59.060 ng 9754) trans-1,3-Dichloropropene 12.95 75 1214014 62.406 ng 10055) 1,1,2-Trichloroethane 13.13 97 816644 59.731 ng 10058) Toluene 13.42 91 3343061 58.592 ng 10059) 2-Hexanone 13.67 43 1786631 65.871 ng 9860) Dibromochloromethane 13.83 129 998648 72.721 ng 10061) 1,2-Dibromoethane 14.09 107 959269 70.008 ng 10062) n-Butyl Acetate 14.31 43 2017840 64.919 ng 9963) n-Octane 14.44 57 697517 55.690 ng 9964) Tetrachloroethene 14.57 166 957194 64.683 ng 10065) Chlorobenzene 15.27 112 2234493 64.496 ng 10066) Ethylbenzene 15.68 91 3813056 63.219 ng 10067) m- & p-Xylenes 15.88 91 6112620 126.874 ng 10068) Bromoform 15.93 173 914265 78.750 ng 10069) Styrene 16.25 104 2441952 70.195 ng 10070) o-Xylene 16.37 91 3063899 61.322 ng 9971) n-Nonane 16.61 43 1560937 53.710 ng 9872) 1,1,2,2-Tetrachloroethane 16.34 83 1502017 63.771 ng 10074) Cumene 16.99 105 3862937 61.858 ng 9975) alpha-Pinene 17.40 93 1972920 62.622 ng 9976) n-Propylbenzene 17.52 91 4715981 61.171 ng 9977) 3-Ethyltoluene 17.63 105 3921632 65.395 ng 9978) 4-Ethyltoluene 17.68 105 3811986 66.379 ng 9979) 1,3,5-Trimethylbenzene 17.76 105 3238100 65.528 ng 10080) alpha-Methylstyrene 17.92 118 1790512 70.450 ng 9981) 2-Ethyltoluene 17.95 105 3818366 65.617 ng 10082) 1,2,4-Trimethylbenzene 18.19 105 3406568 69.846 ng 10083) n-Decane 18.31 57 1761280 59.740 ng 9984) Benzyl Chloride 18.32 91 3096644 72.947 ng 9985) 1,3-Dichlorobenzene 18.35 146 2013016 79.040 ng 10086) 1,4-Dichlorobenzene 18.41 146 2001882 76.733 ng 10087) sec-Butylbenzene 18.48 105 4407878 67.314 ng 10088) 4-Isopropyltoluene (p-... 18.65 119 4063262 67.565 ng 9989) 1,2,3-Trimethylbenzene 18.64 105 3530882 70.284 ng 10090) 1,2-Dichlorobenzene 18.77 146 1925001 76.907 ng 10091) d-Limonene 18.80 68 1315149 64.985 ng 9992) 1,2-Dibromo-3-Chloropr... 19.23 157 715666 70.339 ng 9993) n-Undecane 19.65 57 1831834 63.107 ng 9994) 1,2,4-Trichlorobenzene 20.59 180 1470977 73.917 ng 10095) Naphthalene 20.70 128 4739917 70.380 ng 10096) n-Dodecane 20.74 57 1857950 61.760 ng 9997) Hexachlorobutadiene 21.07 225 890844 83.426 ng 10098) Cyclohexanone 16.02 55 1184882 70.752 ng 9999) tert-Butylbenzene 18.19 119 3284570 68.700 ng 100



R9061416.M Wed Jun 15 09:45:23 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

7500000

8000000

8500000

9000000

9500000

1e+07

1.05e+07

1.1e+07

1.15e+07

1.2e+07

1.25e+07

1.3e+07

Time-->


Hex

achl

orob

utad

iene

,Tn-D

odec

ane,

TN

apht

hale

ne,T

1,2,

4-Tr

ichl

orob

enze

ne,T

n-U

ndec

ane,

T1,

2-D

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mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

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onen

e,T

1,2-

Dic

hlor

oben

zene

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ropy

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ene

(p-C

ymen

e),T

1,2,

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imet

hylb

enze

ne,T

sec-

Buty

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hlor

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nzyl

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Buty

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ltolu

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Tal

pha-

Met

hyls

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ne,T

1,3,

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imet

hylb

enze

ne,T

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luen

e,T

3-Et

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luen

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ene,

Tal

pha-

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ne,TC

umen

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Brom

oflu

orob

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ne (S

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n-N

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lene

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loro

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ne,T

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ene,

TC

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hexa

none

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omof

orm

,Tm

- & p

-Xyl

enes

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enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IR

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chlo

roet

hene

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Oct

ane,

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Buty

l Ace

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rom

ochl

orom

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ne,T

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TTo

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S2),S

1,1,

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ichl

oroe

than

e,T

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pene

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none

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s-1,

3-D

ichl

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rope

ne,T

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Met

hyl M

etha

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bon

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er,T

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l Ace

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ochl

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ne (I

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Rci

s-1,

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ichl

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then

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EK),T

Viny

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yl E

ther

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e (A

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lene

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ethy

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Buty

l Alc

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anol

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anol

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Buta

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FC 1

2),T

Prop

ene,

T

R9061416.M Wed Jun 15 09:45:24 2016 Page: 3

81 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141629.D Acq On : 15 Jun 2016 4:05 Operator: SC Sample : 100ng TO-15 ICAL STD Misc : S29-06141607/S29-06021601 (7/1) ALS Vial : 7 Sample Multiplier: 1 Quant Time: Jun 15 09:45:40 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:31:43 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.94 130 124238 12.500 ng 0.02 37) 1,4-Difluorobenzene (IS2) 10.90 114 578305 12.500 ng 0.02 56) Chlorobenzene-d5 (IS3) 15.23 82 224921 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.71 65 165871 10.238 ng 0.02 Spiked Amount 12.500 Range 70 - 130 Recovery = 81.92% 57) Toluene-d8 (SS2) 13.32 98 588119 13.893 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 111.12% 73) Bromofluorobenzene (SS3) 16.84 174 181096 12.951 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 103.60% Target Compounds Qvalue 2) Propene 3.68 42 1550926 82.476 ng 100 3) Dichlorodifluoromethan... 3.78 85 3178133 86.389 ng 100 4) Chloromethane 3.99 50 2182045 70.435 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.14 135 1826809 99.914 ng 100 6) Vinyl Chloride 4.26 62 2376897 90.625 ng 100 7) 1,3-Butadiene 4.44 54 1918924 144.662 ng 99 8) Bromomethane 4.74 94 1534712 99.008 ng 99 9) Chloroethane 4.95 64 1088604 85.626 ng 100 10) Ethanol 5.25 45 5623566 467.756 ng 100 11) Acetonitrile 5.41 41 2879526 84.654 ng 99 12) Acrolein 5.51 56 1041297 103.513 ng 90 13) Acetone 5.67 58 5800870 411.567 ng 93 14) Trichlorofluoromethane 5.81 101 2669926 90.435 ng 100 15) 2-Propanol (Isopropanol) 6.02 45 7749951 171.596 ng 99 16) Acrylonitrile 6.19 53 2156409 91.281 ng 100 17) 1,1-Dichloroethene 6.50 96 1629370 100.201 ng 96 18) 2-Methyl-2-Propanol (t... 6.65 59 6850299 153.908 ng 99 19) Methylene Chloride 6.67 84 1684790 82.957 ng 94 20) 3-Chloro-1-propene (Al... 6.78 41 2319790 91.411 ng 98 21) Trichlorotrifluoroethane 6.96 151 1440768 103.978 ng 100 22) Carbon Disulfide 6.91 76 6104042 95.144 ng 100 23) trans-1,2-Dichloroethene 7.67 61 2357218 98.681 ng 98 24) 1,1-Dichloroethane 7.89 63 2831833 87.402 ng 100 25) Methyl tert-Butyl Ether 7.95 73 4813119 91.519 ng 100 26) Vinyl Acetate 8.08 86 1892938 524.003 ng # 74 27) 2-Butanone (MEK) 8.31 72 1130840 101.400 ng 94 28) cis-1,2-Dichloroethene 8.77 61 2214510 94.521 ng 97 29) Diisopropyl Ether 9.00 87 1369982 96.154 ng # 79 30) Ethyl Acetate 9.01 61 1193418 189.354 ng 94 31) n-Hexane 9.00 57 2554468 83.163 ng 99 32) Chloroform 9.09 83 2807897 96.103 ng 100 34) Tetrahydrofuran (THF) 9.45 72 1048875 85.469 ng 96 35) Ethyl tert-Butyl Ether 9.55 87 1990890 97.077 ng 97 36) 1,2-Dichloroethane 9.82 62 1941681 96.226 ng 99 38) 1,1,1-Trichloroethane 10.08 97 2456241 109.412 ng 99 39) Isopropyl Acetate 10.46 61 2047317 210.161 ng # 90 40) 1-Butanol 10.49 56 3509502 239.660 ng 96 41) Benzene 10.53 78 6498986 94.574 ng 99 42) Carbon Tetrachloride 10.68 117 2205236 119.861 ng 100 43) Cyclohexane 10.81 84 4986876 204.441 ng 97 44) tert-Amyl Methyl Ether 11.14 73 4708853 102.398 ng 99 45) 1,2-Dichloropropane 11.35 63 1649616 100.416 ng 100 46) Bromodichloromethane 11.53 83 2310143 113.350 ng 100 47) Trichloroethene 11.59 130 1860793 113.043 ng 100 48) 1,4-Dioxane 11.56 88 1410696 121.194 ng 98 49) 2,2,4-Trimethylpentane... 11.65 57 6675977 92.031 ng 100

R9061416.M Wed Jun 15 09:46:38 2016 Page: 1

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Simon








R9061416.M Wed Jun 15 09:46:38 2016 Page: 2

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

1e+07

1.1e+07

1.2e+07

1.3e+07

1.4e+07

1.5e+07

1.6e+07

1.7e+07

1.8e+07

1.9e+07

2e+07

2.1e+07

2.2e+07

2.3e+07

2.4e+07

2.5e+07

2.6e+07

Time-->


Hex

achl

orob

utad

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Dod

ecan

e,T

Nap

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lene

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2,4-

Tric

hlor

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Buty

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Buty

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hylb

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Buty

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Tal

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Met

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Tal

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Non

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Tetra

chlo

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Cyc

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ne,T

Brom

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m,T

m- &

p-X

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es,T

Ethy

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Oct

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Buty

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ne,T

2-H

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one,

TTo

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Tolu

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trans

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hlor

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3-D

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Met

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l Eth

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Difl

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bon

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hlor

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ane,

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oroe

than

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(SS1

),SEt

hyl t

ert-B

utyl

Eth

er,T

Tetra

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an (T

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,TC

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m,T

Ethy

l Ace

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,TD

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ropy

l Eth

er,T

n-H

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Brom

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etha

ne (I

S1),I

Rci

s-1,

2-D

ichl

oroe

then

e,T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T

2-M

ethy

l-2-P

ropa

nol (

tert-

Buty

l Alc

ohol

,T1,

1-D

ichl

oroe

then

e,T

Acr

ylon

itrile

,T2-

Prop

anol

(Iso

prop

anol

),TTr

ichl

orof

luor

omet

hane

,TAc

eton

e,T

Acro

lein

,TAce

toni

trile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 09:46:38 2016 Page: 3

84 of 100

Quantitation Report (QT Reviewed) Data File: I:\MS09\Data\2016_06\14\06141631.D Acq On : 15 Jun 2016 5:12 Operator: SC Sample : 25ng TO-15 ICV STD Misc : S29-06141607/S29-05251604 (6/23) ALS Vial : 3 Sample Multiplier: 1 Quant Time: Jun 15 10:24:30 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane (IS1) 8.91 130 129912 12.500 ng -0.02 37) 1,4-Difluorobenzene (IS2) 10.88 114 597257 12.500 ng -0.02 56) Chlorobenzene-d5 (IS3) 15.23 82 233889 12.500 ng 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4(... 9.70 65 169305 11.468 ng -0.01 Spiked Amount 12.500 Range 70 - 130 Recovery = 91.76% 57) Toluene-d8 (SS2) 13.32 98 609158 12.504 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 100.00% 73) Bromofluorobenzene (SS3) 16.84 174 188933 12.754 ng 0.00 Spiked Amount 12.500 Range 70 - 130 Recovery = 102.00% Target Compounds Qvalue 2) Propene 3.67 42 389634 23.537 ng 99 3) Dichlorodifluoromethan... 3.78 85 766767 21.246 ng 100 4) Chloromethane 3.97 50 623511 23.905 ng 100 5) 1,2-Dichloro-1,1,2,2-t... 4.13 135 456780 24.827 ng 99 6) Vinyl Chloride 4.25 62 619422 25.420 ng 99 7) 1,3-Butadiene 4.42 54 460769 27.868 ng 99 8) Bromomethane 4.72 94 418744 27.603 ng 100 9) Chloroethane 4.94 64 306024 26.072 ng 100 10) Ethanol 5.20 45 1537912 129.649 ng 100 11) Acetonitrile 5.37 41 747410 24.635 ng 100 12) Acrolein 5.49 56 242859 25.675 ng 99 13) Acetone 5.64 58 1570564 133.838 ng 92 14) Trichlorofluoromethane 5.80 101 666322 22.592 ng 100 15) 2-Propanol (Isopropanol) 5.97 45 2109031 52.865 ng 99 16) Acrylonitrile 6.16 53 559124 26.364 ng 99 17) 1,1-Dichloroethene 6.48 96 423234 28.236 ng 95 18) 2-Methyl-2-Propanol (t... 6.60 59 2098913 53.768 ng 99 19) Methylene Chloride 6.65 84 439169 29.474 ng 95 20) 3-Chloro-1-propene (Al... 6.76 41 587642 28.282 ng 98 21) Trichlorotrifluoroethane 6.94 151 368672 27.131 ng 99 22) Carbon Disulfide 6.90 76 1444818 24.758 ng 99 23) trans-1,2-Dichloroethene 7.66 61 587533 29.326 ng 97 24) 1,1-Dichloroethane 7.88 63 743040 25.664 ng 100 25) Methyl tert-Butyl Ether 7.94 73 1270173 26.874 ng 100 26) Vinyl Acetate 8.06 86 483625 141.719 ng # 87 27) 2-Butanone (MEK) 8.29 72 295148 27.923 ng 94 28) cis-1,2-Dichloroethene 8.75 61 577340 28.040 ng 97 29) Diisopropyl Ether 8.99 87 355915 25.756 ng # 92 30) Ethyl Acetate 8.99 61 319963 55.739 ng 98 31) n-Hexane 8.99 57 693342 26.101 ng 100 32) Chloroform 9.06 83 734787 26.714 ng 100 34) Tetrahydrofuran (THF) 9.44 72 288569 27.303 ng 96 35) Ethyl tert-Butyl Ether 9.53 87 508934 27.187 ng 98 36) 1,2-Dichloroethane 9.80 62 503379 26.024 ng 100 38) 1,1,1-Trichloroethane 10.06 97 630329 25.396 ng 99 39) Isopropyl Acetate 10.44 61 549137 60.705 ng # 91 40) 1-Butanol 10.46 56 876258 60.797 ng 98 41) Benzene 10.52 78 1724105 26.691 ng 100 42) Carbon Tetrachloride 10.67 117 547065 27.441 ng 99 43) Cyclohexane 10.80 84 1309322 54.274 ng 98 44) tert-Amyl Methyl Ether 11.13 73 1215415 27.089 ng 99 45) 1,2-Dichloropropane 11.34 63 437552 27.209 ng 100 46) Bromodichloromethane 11.52 83 589672 27.407 ng 99 47) Trichloroethene 11.58 130 476264 25.417 ng 99 48) 1,4-Dioxane 11.55 88 373862 29.392 ng 97 49) 2,2,4-Trimethylpentane... 11.64 57 1790366 25.744 ng 99

R9061416.M Wed Jun 15 10:25:57 2016 Page: 1

85 of 100

simon.cao

Simon


Data File: I:\MS09\Data\2016_06\14\06141631.D Acq On : 15 Jun 2016 5:12 Operator: SC Sample : 25ng TO-15 ICV STD Misc : S29-06141607/S29-05251604 (6/23) ALS Vial : 3 Sample Multiplier: 1






R9061416.M Wed Jun 15 10:25:57 2016 Page: 2

86 of 100


Data File: I:\MS09\Data\2016_06\14\06141631.D Acq On : 15 Jun 2016 5:12 Operator: SC Sample : 25ng TO-15 ICV STD Misc : S29-06141607/S29-05251604 (6/23) ALS Vial : 3 Sample Multiplier: 1


4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

500000

1000000

1500000

2000000

2500000

3000000

3500000

4000000

4500000

5000000

5500000

6000000

6500000

7000000

Time-->


Hex

achl

orob

utad

iene

,Tn-

Dod

ecan

e,T

Nap

htha

lene

,T1,

2,4-

Tric

hlor

oben

zene

,T

n-U

ndec

ane,

T1,

2-D

ibro

mo-

3-C

hlor

opro

pane

,Tn-

Buty

lben

zene

,Td-

Lim

onen

e,T

1,2-

Dic

hlor

oben

zene

,T4-

Isop

ropy

ltolu

ene

(p-C

ymen

e),T

1,2,

3-Tr

imet

hylb

enze

ne,T

sec-

Buty

lben

zene

,T1,

4-D

ichl

orob

enze

ne,T

1,3-

Dic

hlor

oben

zene

,TBe

nzyl

Chl

orid

e,T

n-D

ecan

e,T

1,2,

4-Tr

imet

hylb

enze

ne,T

tert-

Buty

lben

zene

,T2-

Ethy

ltolu

ene,

Tal

pha-

Met

hyls

tyre

ne,T

1,3,

5-Tr

imet

hylb

enze

ne,T

4-Et

hylto

luen

e,T

3-Et

hylto

luen

e,T

n-Pr

opyl

benz

ene,

Tal

pha-

Pine

ne,TCum

ene,

TBr

omof

luor

oben

zene

(SS3

),Sn-

Non

ane,

To-Xy

lene

,T1,

1,2,

2-Te

trach

loro

etha

ne,TStyr

ene,

TC

yclo

hexa

none

,TBr

omof

orm

,Tm

- & p

-Xyl

enes

,TEt

hylb

enze

ne,T

Chl

orob

enze

ne,T

Chl

orob

enze

ne-d

5 (IS

3),IRTe

trach

loro

ethe

ne,T

n-O

ctan

e,T

n-Bu

tyl A

ceta

te,T

1,2-

Dib

rom

oeth

ane,

TD

ibro

moc

hlor

omet

hane

,T2-

Hex

anon

e,T

Tolu

ene,

TTo

luen

e-d8

(SS2

),S1,

1,2-

Tric

hlor

oeth

ane,

Ttra

ns-1

,3-D

ichl

orop

rope

ne,T

4-M

ethy

l-2-p

enta

none

,Tci

s-1,

3-D

ichl

orop

rope

ne,T

n-H

epta

ne,T

Met

hyl M

etha

cryl

ate,

T2,

2,4-

Trim

ethy

lpen

tane

(Iso

octa

ne),T

Tric

hlor

oeth

ene,

T1,

4-D

ioxa

ne,T

Brom

odic

hlor

omet

hane

,T1,

2-D

ichl

orop

ropa

ne,T

tert-

Am

yl M

ethy

l Eth

er,T

1,4-

Difl

uoro

benz

ene

(IS2)

,IRC

yclo

hexa

ne,T

Car

bon

Tetra

chlo

ride,

TBe

nzen

e,T

1-Bu

tano

l,TIsop

ropy

l Ace

tate

,T1,

1,1-

Tric

hlor

oeth

ane,

T1,

2-D

ichl

oroe

than

e,T

1,2-

Dic

hlor

oeth

ane-

d4(S

S1),S

Ethy

l ter

t-But

yl E

ther

,TTe

trahy

drof

uran

(TH

F),T

Chl

orof

orm

,TEt

hyl A

ceta

te,T

Diis

opro

pyl E

ther

,Tn-

Hex

ane,

TBr

omoc

hlor

omet

hane

(IS1

),IR

cis-

1,2-

Dic

hlor

oeth

ene,

T

2-Bu

tano

ne (M

EK),T

Viny

l Ace

tate

,TM

ethy

l ter

t-But

yl E

ther

,T1,

1-D

ichl

oroe

than

e,T

trans

-1,2

-Dic

hlor

oeth

ene,

T

Tric

hlor

otrif

luor

oeth

ane,

TC

arbo

n D

isul

fide,

T3-

Chl

oro-

1-pr

open

e (A

llyl C

hlor

ide)

,TM

ethy

lene

Chl

orid

e,T2-

Met

hyl-2

-Pro

pano

l (te

rt-Bu

tyl A

lcoh

ol,T

1,1-

Dic

hlor

oeth

ene,

TAc

rylo

nitri

le,T

2-Pr

opan

ol (I

sopr

opan

ol),T

Tric

hlor

oflu

orom

etha

ne,T

Acet

one,

TAc

role

in,TAc

eton

itrile

,TEt

hano

l,TC

hlor

oeth

ane,

TBr

omom

etha

ne,T

1,3-

Buta

dien

e,T

Viny

l Chl

orid

e,T

1,2-

Dic

hlor

o-1,

1,2,

2-te

traflu

oroe

than

e ,T

Chl

orom

etha

ne,T

Dic

hlor

odifl

uoro

met

hane

(CFC

12)

,TPr

open

e,T

R9061416.M Wed Jun 15 10:25:58 2016 Page: 3

87 of 100

of 2 I:\MS09\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 6/15/16 10:31 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 06141631.D Acq. Method File: TO15.MData File Path: I:\MS09\Data\2016_06\14\ Sample Name: 25ng TO-15 ICV STD

Operator: SC Misc Info: S29-06141607/S29-05251604 (Date Acquired: 6/15/16 5:12 Instrument Name: MS09

Compound Ret. Amt. Spike % Lower Upper * OR# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail2) Propene 3.67 23.5 24.50 96 70 130 *3) Dichlorodifluoromethane (CFC 12 3.78 21.2 23.50 90 70 130 *4) Chloromethane 3.97 23.9 25.00 96 70 130 *5) 1,2-Dichloro-1,1,2,2-tetrafluoroeth 4.13 24.8 25.50 97 70 130 *6) Vinyl Chloride 4.25 25.4 25.00 102 70 130 *7) 1,3-Butadiene 4.42 27.9 25.75 108 70 130 *8) Bromomethane 4.72 27.6 25.25 109 70 130 *9) Chloroethane 4.94 26.1 25.00 104 70 130 *

10) Ethanol 5.20 130 124.75 104 70 130 *11) Acetonitrile 5.37 24.6 26.50 93 70 130 *12) Acrolein 5.49 25.7 26.75 96 70 130 *13) Acetone 5.64 134 134.75 99 70 130 *14) Trichlorofluoromethane 5.80 22.6 27.00 84 70 130 *15) 2-Propanol (Isopropanol) 5.97 52.9 52.25 101 70 130 *16) Acrylonitrile 6.16 26.4 26.50 100 70 130 *17) 1,1-Dichloroethene 6.48 28.2 27.00 104 70 130 *18) 2-Methyl-2-Propanol (tert-Butyl Alco 6.60 53.8 50.00 108 70 130 *19) Methylene Chloride 6.65 29.5 27.75 106 70 130 *20) 3-Chloro-1-propene (Allyl Chlorid 6.76 28.3 27.25 104 70 130 *21) Trichlorotrifluoroethane 6.94 27.1 27.50 99 70 130 *22) Carbon Disulfide 6.90 24.8 26.25 94 70 130 *23) trans-1,2-Dichloroethene 7.66 29.3 26.25 112 70 130 *24) 1,1-Dichloroethane 7.88 25.7 26.50 97 70 130 *25) Methyl tert-Butyl Ether 7.94 26.9 27.00 100 70 130 *26) Vinyl Acetate 8.06 142 129.75 109 70 130 *27) 2-Butanone (MEK) 8.29 27.9 27.50 101 70 130 *28) cis-1,2-Dichloroethene 8.75 28.0 27.25 103 70 130 *29) Diisopropyl Ether 8.99 25.8 27.00 96 70 130 *30) Ethyl Acetate 8.99 55.7 53.50 104 70 130 *31) n-Hexane 8.99 26.1 26.50 98 70 130 *32) Chloroform 9.06 26.7 28.00 95 70 130 *34) Tetrahydrofuran (THF) 9.44 27.3 27.50 99 70 130 *35) Ethyl tert-Butyl Ether 9.53 27.2 26.75 102 70 130 *36) 1,2-Dichloroethane 9.80 26.0 26.75 97 70 130 *38) 1,1,1-Trichloroethane 10.06 25.4 26.25 97 70 130 *39) Isopropyl Acetate 10.44 60.7 57.25 106 70 130 *40) 1-Butanol 10.46 60.8 51.25 119 70 130 *41) Benzene 10.52 26.7 28.25 95 70 130 *42) Carbon Tetrachloride 10.67 27.4 28.75 95 70 130 *43) Cyclohexane 10.80 54.3 53.00 102 70 130 *44) tert-Amyl Methyl Ether 11.13 27.1 26.75 101 70 130 *45) 1,2-Dichloropropane 11.34 27.2 27.00 101 70 130 *46) Bromodichloromethane 11.52 27.4 27.25 101 70 130 *47) Trichloroethene 11.58 25.4 27.00 94 70 130 *48) 1,4-Dioxane 11.55 29.4 26.25 112 70 130 *49) 2,2,4-Trimethylpentane (Isooctane) 11.64 25.7 26.75 96 70 130 *

88 of 100

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of 2 I:\MS09\0-Instrument Info\0-Security Certificates\ICV_07141501_REV1.CRT 6/15/16 10:31 AM

INITIAL CALIBRATION VERIFICATION CHECK SHEET

Data File Name: 06141631.D Acq. Method File: TO15.MData File Path: I:\MS09\Data\2016_06\14\ Sample Name: 25ng TO-15 ICV STD

Operator: SC Misc Info: S29-06141607/S29-05251604 (Date Acquired: 6/15/16 5:12 Instrument Name: MS09

Compound Ret. Amt. Spike % Lower Upper * OR# Name Time (ng) Amt.(ng) Rec. Limit Limit Fail

50) Methyl Methacrylate 11.77 56.2 52.75 107 70 130 *51) n-Heptane 11.90 27.9 27.00 103 70 130 *52) cis-1,3-Dichloropropene 12.43 26.6 26.00 102 70 130 *53) 4-Methyl-2-pentanone 12.46 27.8 27.50 101 70 130 *54) trans-1,3-Dichloropropene 12.95 28.1 26.25 107 70 130 *55) 1,1,2-Trichloroethane 13.12 28.6 27.00 106 70 130 *58) Toluene 13.42 26.8 27.25 98 70 130 *59) 2-Hexanone 13.66 29.4 27.50 107 70 130 *60) Dibromochloromethane 13.83 30.1 27.50 109 70 130 *61) 1,2-Dibromoethane 14.08 29.5 27.25 108 70 130 *62) n-Butyl Acetate 14.31 30.3 28.25 107 70 130 *63) n-Octane 14.44 27.3 26.25 104 70 130 *64) Tetrachloroethene 14.57 25.9 25.25 103 70 130 *65) Chlorobenzene 15.27 27.8 27.50 101 70 130 *66) Ethylbenzene 15.68 28.8 27.25 106 70 130 *67) m- & p-Xylenes 15.87 56.3 53.50 105 70 130 *68) Bromoform 15.93 28.5 28.50 100 70 130 *69) Styrene 16.25 30.5 27.75 110 70 130 *70) o-Xylene 16.37 27.3 26.25 104 70 130 *71) n-Nonane 16.61 26.6 25.50 104 70 130 *72) 1,1,2,2-Tetrachloroethane 16.34 30.4 26.25 116 70 130 *74) Cumene 16.98 26.9 26.00 103 70 130 *75) alpha-Pinene 17.40 27.5 26.50 104 70 130 *76) n-Propylbenzene 17.52 27.4 25.50 107 70 130 *77) 3-Ethyltoluene 17.63 29.9 26.75 112 70 130 *78) 4-Ethyltoluene 17.68 28.9 26.75 108 70 130 *79) 1,3,5-Trimethylbenzene 17.76 27.6 26.75 103 70 130 *80) alpha-Methylstyrene 17.91 27.9 26.25 106 70 130 *81) 2-Ethyltoluene 17.95 27.7 26.75 104 70 130 *82) 1,2,4-Trimethylbenzene 18.19 29.2 27.25 107 70 130 *83) n-Decane 18.31 28.1 26.25 107 70 130 *84) Benzyl Chloride 18.32 31.4 27.50 114 70 130 *85) 1,3-Dichlorobenzene 18.34 32.2 28.50 113 70 130 *86) 1,4-Dichlorobenzene 18.41 30.7 26.00 118 70 130 *87) sec-Butylbenzene 18.48 28.7 27.25 105 70 130 *88) 4-Isopropyltoluene (p-Cymene) 18.64 28.1 26.00 108 70 130 *89) 1,2,3-Trimethylbenzene 18.64 28.9 26.50 109 70 130 *90) 1,2-Dichlorobenzene 18.77 30.8 27.50 112 70 130 *91) d-Limonene 18.79 28.8 26.25 110 70 130 *92) 1,2-Dibromo-3-Chloropropane 19.23 30.0 27.25 110 70 130 *93) n-Undecane 19.65 28.1 25.25 111 70 130 *94) 1,2,4-Trichlorobenzene 20.59 29.6 28.75 103 70 130 *95) Naphthalene 20.70 28.5 27.25 105 70 130 *96) n-Dodecane 20.74 29.8 27.25 109 70 130 *97) Hexachlorobutadiene 21.07 29.2 28.75 102 70 130 *98) Cyclohexanone 16.02 28.1 27.50 102 70 130 *99) tert-Butylbenzene 18.19 28.3 26.75 106 70 130 *

100) n-Butylbenzene 19.09 31.3 28.00 112 70 130 *

Bold = 75 Compound List* = Pass

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Evaluate Continuing Calibration Report Data File: I:\MS09\Data\2016_07\22\07221610.D Acq On : 22 Jul 2016 11:44 Operator: SC Sample : CCV R9072216_5.0ng Misc : S29-07211602/S29-07211608 (8/19) ALS Vial : 4 Sample Multiplier: 1 Quant Time: Jul 22 13:00:59 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 1 IR Bromochloromethane (IS1) 1.000 1.000 0.0 130 -0.04 2 T Propene 1.593 1.526 4.2 127 0.00 3 T Dichlorodifluoromethane (CF 3.473 3.336 3.9 126 0.00 4 T Chloromethane 2.510 2.522 -0.5 130 -0.02 5 T 1,2-Dichloro-1,1,2,2-tetraf 1.770 1.881 -6.3 139 -0.01 6 T Vinyl Chloride 2.345 2.329 0.7 127 -0.02 7 T 1,3-Butadiene 1.591 1.597 -0.4 132 -0.02 8 T Bromomethane 1.460 1.525 -4.5 136 -0.02 9 T Chloroethane 1.129 1.023 9.4 122 -0.02 10 T Ethanol 1.141 1.102 3.4 120 -0.09 11 T Acetonitrile 2.919 2.656 9.0 121 -0.06 12 T Acrolein 0.910 0.903 0.8 125 -0.03 13 T Acetone 1.129 1.088 3.6 127 -0.06 14 T Trichlorofluoromethane 2.838 2.705 4.7 125 -0.02 15 T 2-Propanol (Isopropanol) 3.839 3.561 7.2 119 -0.07 16 T Acrylonitrile 2.041 1.912 6.3 123 -0.05 17 T 1,1-Dichloroethene 1.442 1.508 -4.6 137 -0.02 18 T 2-Methyl-2-Propanol (tert-B 3.756 3.475 7.5 116 -0.06 19 T Methylene Chloride 1.434 1.503 -4.8 129 -0.04 20 T 3-Chloro-1-propene (Allyl C 1.999 1.924 3.8 120 -0.03 21 T Trichlorotrifluoroethane 1.307 1.372 -5.0 138 -0.02 22 T Carbon Disulfide 5.615 5.892 -4.9 133 -0.02 23 T trans-1,2-Dichloroethene 1.928 1.977 -2.5 118 -0.03 24 T 1,1-Dichloroethane 2.786 2.660 4.5 123 -0.04 25 T Methyl tert-Butyl Ether 4.548 4.285 5.8 122 -0.02 26 T Vinyl Acetate 0.328 0.288 12.2 137 -0.04 27 T 2-Butanone (MEK) 1.017 0.994 2.3 130 -0.03 28 T cis-1,2-Dichloroethene 1.981 1.906 3.8 122 -0.03 29 T Diisopropyl Ether 1.330 1.246 6.3 132 -0.02 30 T Ethyl Acetate 0.552 0.551 0.2 130 -0.03 31 T n-Hexane 2.556 2.474 3.2 124 -0.02 32 T Chloroform 2.647 2.544 3.9 126 -0.04 33 S 1,2-Dichloroethane-d4(SS1) 1.420 1.191 16.1 108 -0.03 34 T Tetrahydrofuran (THF) 1.017 0.983 3.3 125 -0.01 35 T Ethyl tert-Butyl Ether 1.801 1.773 1.6 131 -0.02 36 T 1,2-Dichloroethane 1.861 1.686 9.4 115 -0.03 37 IR 1,4-Difluorobenzene (IS2) 1.000 1.000 0.0 127 -0.03 38 T 1,1,1-Trichloroethane 0.519 0.494 4.8 122 -0.02 39 T Isopropyl Acetate 0.189 0.191 -1.1 124 -0.02 40 T 1-Butanol 0.302 0.302 0.0 119 -0.04 41 T Benzene 1.352 1.269 6.1 128 -0.02 42 T Carbon Tetrachloride 0.417 0.419 -0.5 126 -0.02 43 T Cyclohexane 0.505 0.520 -3.0 131 -0.02 44 T tert-Amyl Methyl Ether 0.939 0.902 3.9 123 -0.02 45 T 1,2-Dichloropropane 0.337 0.333 1.2 127 -0.02 46 T Bromodichloromethane 0.450 0.442 1.8 125 -0.02 47 T Trichloroethene 0.392 0.409 -4.3 137 -0.02 48 T 1,4-Dioxane 0.266 0.270 -1.5 132 -0.02 49 T 2,2,4-Trimethylpentane (Iso 1.455 1.381 5.1 123 -0.02 50 T Methyl Methacrylate 0.134 0.137 -2.2 133 -0.02 51 T n-Heptane 0.326 0.332 -1.8 131 -0.01 52 T cis-1,3-Dichloropropene 0.527 0.509 3.4 126 -0.01 53 T 4-Methyl-2-pentanone 0.309 0.298 3.6 125 -0.01 54 T trans-1,3-Dichloropropene 0.451 0.428 5.1 123 -0.01

R9061416.M Fri Jul 22 13:20:22 2016 Page: 1

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Evaluate Continuing Calibration Report Data File: I:\MS09\Data\2016_07\22\07221610.D Acq On : 22 Jul 2016 11:44 Operator: SC Sample : CCV R9072216_5.0ng Misc : S29-07211602/S29-07211608 (8/19) ALS Vial : 4 Sample Multiplier: 1 Quant Time: Jul 22 13:00:59 2016 Quant Method : I:\MS09\Methods\R9061416.M Quant Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) QLast Update : Wed Jun 15 09:50:01 2016 Response via : Initial Calibration DataAcq Meth:TO15.M Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.33min Max. RRF Dev : 30% Max. Rel. Area : 200% Compound AvgRF CCRF %Dev Area% Dev(min) ------------------------------------------------------------------------- 55 T 1,1,2-Trichloroethane 0.321 0.343 -6.9 132 -0.01 56 IR Chlorobenzene-d5 (IS3) 1.000 1.000 0.0 118 0.00 57 S Toluene-d8 (SS2) 2.604 2.750 -5.6 125 -0.01 58 T Toluene 3.645 3.804 -4.4 129 -0.01 59 T 2-Hexanone 1.698 1.702 -0.2 115 -0.01 60 T Dibromochloromethane 0.917 1.081 -17.9 134 0.00 61 T 1,2-Dibromoethane 0.918 1.036 -12.9 133 -0.02 62 T n-Butyl Acetate 1.863 1.871 -0.4 113 0.00 63 T n-Octane 0.724 0.765 -5.7 123 -0.02 64 T Tetrachloroethene 1.052 1.202 -14.3 140 -0.01 65 T Chlorobenzene 2.312 2.544 -10.0 134 0.00 66 T Ethylbenzene 3.824 4.172 -9.1 128 -0.01 67 T m- & p-Xylenes 3.094 3.335 -7.8 126 -0.02 68 T Bromoform 0.842 1.007 -19.6 143 -0.01 69 T Styrene 2.277 2.626 -15.3 132 -0.01 70 T o-Xylene 3.206 3.471 -8.3 127 -0.02 71 T n-Nonane 1.671 1.726 -3.3 115 -0.01 72 T 1,1,2,2-Tetrachloroethane 1.410 1.717 -21.8 130 -0.01 73 S Bromofluorobenzene (SS3) 0.792 0.867 -9.5 127 0.00 74 T Cumene 4.090 4.563 -11.6 130 -0.01 75 T alpha-Pinene 1.979 2.288 -15.6 132 0.00 76 T n-Propylbenzene 4.884 5.686 -16.4 131 0.00 77 T 3-Ethyltoluene 3.780 4.490 -18.8 134 -0.01 78 T 4-Ethyltoluene 3.674 4.377 -19.1 132 0.00 79 T 1,3,5-Trimethylbenzene 3.327 3.693 -11.0 131 -0.01 80 T alpha-Methylstyrene 1.770 2.154 -21.7 137 -0.01 81 T 2-Ethyltoluene 3.873 4.460 -15.2 132 -0.01 82 T 1,2,4-Trimethylbenzene 3.266 3.784 -15.9 131 -0.01 83 T n-Decane 1.776 2.040 -14.9 123 -0.01 84 T Benzyl Chloride 2.587 2.698 -4.3 133 -0.02 85 T 1,3-Dichlorobenzene 1.767 2.231 -26.3 139 -0.02 86 T 1,4-Dichlorobenzene 1.827 2.312 -26.5 137 -0.01 87 T sec-Butylbenzene 4.346 4.890 -12.5 126 -0.01 88 T 4-Isopropyltoluene (p-Cymen 4.113 4.332 -5.3 117 -0.01 89 T 1,2,3-Trimethylbenzene 3.425 3.455 -0.9 114 -0.01 90 T 1,2-Dichlorobenzene 1.760 2.008 -14.1 124 -0.01 91 T d-Limonene 1.250 1.297 -3.8 112 0.00 92 T 1,2-Dibromo-3-Chloropropane 0.669 0.715 -6.9 131 0.00 93 T n-Undecane 1.852 1.966 -6.2 111 0.00 94 T 1,2,4-Trichlorobenzene 1.425 1.601 -12.4 135 0.00 95 T Naphthalene 4.719 5.142 -9.0 125 0.00 96 T n-Dodecane 1.789 1.845 -3.1 103 0.00 97 T Hexachlorobutadiene 0.837 1.018 -21.6 143 0.00 98 T Cyclohexanone 1.116 1.110 0.5 115 -0.02 99 T tert-Butylbenzene 3.225 3.778 -17.1 134 -0.01 100 T n-Butylbenzene 3.276 3.658 -11.7 116 -0.01 -------------------------------------------------------------------------- (#) = Out of Range SPCC's out = 0 CCC's out = 0

R9061416.M Fri Jul 22 13:20:22 2016 Page: 2

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Data File: I:\MS09\Data\2016_07\22\07221610.D Acq On : 22 Jul 2016 11:44 Operator: SC Sample : CCV R9072216_5.0ng Misc : S29-07211602/S29-07211608 (8/19) ALS Vial : 4 Sample Multiplier: 1





Spiked Amount 12.500 Range 70 - 130 Recovery = 83.84% 57) Toluene-d8 (SS2) 13.31 98 590552 13.205 ng -0.01



Target Compounds Qvalue2) Propene 3.67 42 80317 4.935 ng 973) Dichlorodifluoromethan... 3.78 85 170440 4.803 ng 1004) Chloromethane 3.97 50 126288 4.924 ng 995) 1,2-Dichloro-1,1,2,2-t... 4.13 135 99010 5.473 ng 1006) Vinyl Chloride 4.25 62 118967 4.966 ng 997) 1,3-Butadiene 4.42 54 86483 5.320 ng 968) Bromomethane 4.72 94 77896 5.223 ng 999) Chloroethane 4.93 64 52767 4.572 ng 10010) Ethanol 5.16 45 285013 24.438 ng 9911) Acetonitrile 5.36 41 138400 4.640 ng 9912) Acrolein 5.49 56 49386 5.310 ng 9113) Acetone 5.61 58 298528 25.874 ng 8914) Trichlorofluoromethane 5.78 101 136807 4.718 ng 9815) 2-Propanol (Isopropanol) 5.94 45 380255 9.694 ng 9916) Acrylonitrile 6.14 53 100617 4.825 ng 10017) 1,1-Dichloroethene 6.48 96 82440 5.594 ng 9018) 2-Methyl-2-Propanol (t... 6.58 59 371110 9.669 ng 9919) Methylene Chloride 6.63 84 82954 5.663 ng 9320) 3-Chloro-1-propene (Al... 6.75 41 106175 5.197 ng 9721) Trichlorotrifluoroethane 6.93 151 75696 5.666 ng 9522) Carbon Disulfide 6.89 76 295022 5.142 ng 10023) trans-1,2-Dichloroethene 7.65 61 107083 5.436 ng 9324) 1,1-Dichloroethane 7.86 63 141323 4.965 ng 9925) Methyl tert-Butyl Ether 7.93 73 229898 4.947 ng 9926) Vinyl Acetate 8.04 86 74694 22.262 ng # 8427) 2-Butanone (MEK) 8.28 72 54351 5.230 ng # 8928) cis-1,2-Dichloroethene 8.74 61 104201 5.147 ng 9229) Diisopropyl Ether 8.98 87 68760 5.061 ng # 8530) Ethyl Acetate 8.98 61 59715 10.580 ng 10031) n-Hexane 8.98 57 131483 5.034 ng 9932) Chloroform 9.04 83 139077 5.143 ng 9934) Tetrahydrofuran (THF) 9.44 72 51233 4.930 ng 9335) Ethyl tert-Butyl Ether 9.53 87 95118 5.168 ng 9336) 1,2-Dichloroethane 9.79 62 90439 4.755 ng 10038) 1,1,1-Trichloroethane 10.06 97 118423 4.894 ng 9939) Isopropyl Acetate 10.44 61 98117 11.126 ng # 9340) 1-Butanol 10.45 56 159159 11.328 ng 9941) Benzene 10.51 78 328027 5.209 ng 9942) Carbon Tetrachloride 10.66 117 105468 5.427 ng 9943) Cyclohexane 10.79 84 252964 10.756 ng 9644) tert-Amyl Methyl Ether 11.12 73 218407 4.993 ng 9845) 1,2-Dichloropropane 11.33 63 81465 5.196 ng 10046) Bromodichloromethane 11.52 83 110125 5.250 ng 9947) Trichloroethene 11.57 130 98139 5.372 ng 9948) 1,4-Dioxane 11.54 88 67864 5.473 ng 9449) 2,2,4-Trimethylpentane... 11.64 57 331351 4.887 ng 96

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4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00 22.00 23.00 24.000

50000

100000

150000

200000

250000

300000

350000

400000

450000

500000

550000

600000

650000

700000

750000

800000

850000

900000

950000

1000000

1050000

1100000

1150000

1200000

1250000

Time-->


Hex

achl

orob

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,Tn-

Dod

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Nap

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2,4-

Tric

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R9061416.M Fri Jul 22 13:20:10 2016 Page: 3

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BFB

Data Path : I:\MS09\Data\2016_06\14\ Data File : 06141620.D Acq On : 14 Jun 2016 22:59 Operator : SC Sample : 12.5ng TO-15 BFB STD Misc : S29-06141607(AC00463) ALS Vial : 2 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS09\Methods\R9061416.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Wed Jun 15 09:31:43 2016

15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.600

100000

200000

300000

400000

500000

Time-->


25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

10000

20000

30000

40000

50000

60000

70000

m/z-->

Abundance Average of 16.830 to 16.841 min.: 06141620.D\data.ms (-)95

174

75

5069

8737 61 8156 14145 117 128104 155148 169

AutoFind: Scans 2593, 2594, 2595; Background Corrected with Scan 2585

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 16.2 | 12167 | PASS || 75 | 95 | 30 | 66 | 44.1 | 33131 | PASS || 95 | 95 | 100 | 100 | 100.0 | 75179 | PASS || 96 | 95 | 5 | 9 | 6.7 | 5045 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 93.8 | 70528 | PASS || 175 | 174 | 4 | 9 | 8.0 | 5616 | PASS || 176 | 174 | 93 | 101 | 99.6 | 70227 | PASS || 177 | 176 | 5 | 9 | 6.1 | 4316 | PASS |----------------------------------------------------------------------

R9061416.M Wed Jun 15 09:44:04 2016 Page: 1

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BFB

Data Path : I:\MS09\Data\2016_07\22\ Data File : 07221610.D Acq On : 22 Jul 2016 11:44 Operator : SC Sample : CCV R9072216_5.0ng Misc : S29-07211602/S29-07211608 (8/19) ALS Vial : 4 Sample Multiplier: 1

Integration File: LSCINT.P

Method : I:\MS09\Methods\R9061416.M Title : EPA TO-15 per SOP VOA-TO15 (CASS TO-15/GC-MS) Last Update : Wed Jun 15 09:50:01 2016

15.00 15.20 15.40 15.60 15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.600

200000

400000

600000

800000

1000000

1200000

1400000

1600000

Time-->


25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 1850

20000

40000

60000

80000

m/z-->

Abundance Average of 16.831 to 16.841 min.: 07221610.D\data.ms (-)17495

75

5069

876137 8156 14345 117104 128 155 161148

AutoFind: Scans 2593, 2594, 2595; Background Corrected with Scan 2584

| Target | Rel. to | Lower | Upper | Rel. | Raw | Result || Mass | Mass | Limit% | Limit% | Abn% | Abn | Pass/Fail |----------------------------------------------------------------------| 50 | 95 | 8 | 40 | 14.1 | 12995 | PASS || 75 | 95 | 30 | 66 | 41.2 | 37947 | PASS || 95 | 95 | 100 | 100 | 100.0 | 92080 | PASS || 96 | 95 | 5 | 9 | 6.5 | 6023 | PASS || 173 | 174 | 0.00 | 2 | 0.0 | 0 | PASS || 174 | 95 | 50 | 120 | 102.0 | 93888 | PASS || 175 | 174 | 4 | 9 | 7.6 | 7178 | PASS || 176 | 174 | 93 | 101 | 97.8 | 91819 | PASS || 177 | 176 | 5 | 9 | 6.2 | 5654 | PASS |----------------------------------------------------------------------

R9061416.M Fri Jul 22 13:20:37 2016 Page: 1

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Date/Time File Name Sample ID Misc Info Operator Vial Comment1 6/14/16 10:19 06141601.D System S29-05061601/S29-06021602 (7/1) SC 2

2 6/14/16 10:53 06141602.D CCV R9061416_5.0ng S29-05061601/S29-06021604 (7/1) SC 4 pass

3 6/14/16 11:27 06141603.D Blank (100mL) S29-05061601(AC00463) SC 2 pass

4 6/14/16 12:01 06141604.D MB R9061416_1000mL S29-05061601(AC00463) SC 2 pass



7 6/14/16 14:54 06141607.D ALS QC CAN (1000mL) AS00919 SC 8 pass

8 6/14/16 16:11 06141608.D Blank (100mL) S29-06141607(AC00463) SC 2

9 6/14/16 16:44 06141609.D 12.5ng TO-15 BFB STD S29-06141607(AC00463) SC 2

10 6/14/16 17:19 06141610.D 0.4ng AC&F ICAL STD S29-06141607/S29-06071604 (7/6) SC 13




14 6/14/16 19:35 06141614.D 25ng AC&F ICAL STD S29-06141607/S29-06071602 (7/6) SC 14



17 6/14/16 21:17 06141617.D Blank (100mL) S29-06141607(AC00463) SC 2

18 6/14/16 21:51 06141618.D 25ng AC&F ICV STD S29-06141607/S29-06071615 (7/6) SC 15

19 6/14/16 22:25 06141619.D 25ng AC&F ICV STD S29-06141607/S29-06071615 (7/6) SC 15

20 6/14/16 22:59 06141620.D 12.5ng TO-15 BFB STD S29-06141607(AC00463) SC 2

21 6/14/16 23:33 06141621.D 0.08ng TO-15 ICAL STD S29-06141607/S29-06021605 (7/1) SC 5






27 6/15/16 2:56 06141627.D 25ng TO-15 ICAL STD S29-06141607/S29-06021601 (7/1) SC 7



30 6/15/16 4:38 06141630.D Blank (100mL) S29-06141607(AC00463) SC 2

31 6/15/16 5:12 06141631.D 25ng TO-15 ICV STD S29-06141607/S29-05251604 (6/23) SC 3

32 6/15/16 5:46 06141632.D 25ng TO-15 ICV STD S29-06141607/S29-06131604 (7/12) SC 8 cf

33 6/15/16 6:20 06141633.D Blank (100mL) S29-06141607(AC00463) SC 2

34 6/15/16 6:54 06141634.D 12.5ng Methanol BFB STD S29-06141607(AC00463) SC 2

35 6/15/16 7:27 06141635.D 10ng Methanol ICAL STD S29-06141607/S29-05171603 (6/16) SC 9







42 6/15/16 11:23 06141642.D 100ng Methanol ICV STD S29-06141607/S29-05171605 (6/16) SC 11

43 6/15/16 11:57 06141643.D 100ng Methanol ICV STD S29-06141607/S29-05171605 (6/16) SC 11 cf

44

45 pass

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Date/Time File Name Sample ID Misc Info Operator Vial Comment1 7/22/16 5:40 07221601.D CCV R9072216_5.0ng S29-06141607/S29-06291603 (7/28) SC 2

2 7/22/16 6:14 07221602.D CCV Me9072216_100ng S29-06141607/S29-06291614 (7/28) SC 13

3 7/22/16 6:47 07221603.D MB R9072216_1000mL S29-06141607 SC 2

4 7/22/16 7:21 07221604.D LCS R9072216_25ng S29-06141607/S29-06231602 (7/22) SC 16

5 7/22/16 7:55 07221605.D LCSD R9072216_25ng S29-06141607/S29-06231602 (7/22) SC 16

6 7/22/16 8:29 07221606.D LCS Me9072216_100ng S29-06141607/S29-06291616 (7/28) SC 14

7 7/22/16 9:02 07221607.D LCSD Me9072216_100ng S29-06141607/S29-06291616 (7/28) SC 14

8 7/22/16 10:22 07221608.D Blank (100mL) S29-07211602 SC 2 new is/surr

9 7/22/16 11:10 07221609.D Blank (100mL) S29-07211602 SC 2

10 7/22/16 11:44 07221610.D CCV R9072216_5.0ng S29-07211602/S29-07211608 (8/19) SC 4 pass

11 7/22/16 13:21 07221611.D CCV Me9072216_100ng S29-07211602/S29-06291614 (7/28) SC 13 pass

12 7/22/16 13:55 07221612.D MB R9072216_1000mL S29-07211602 SC 2 pass

13 7/22/16 14:28 07221613.D LCS Me9072216_100ng S29-07211602/S29-06291616 (7/28) SC 14 pass

14 7/22/16 15:02 07221614.D LCSD Me9072216_100ng S29-07211602/S29-06291616 (7/28) SC 14 pass

15 7/22/16 15:36 07221615.D LCS R9072216_25ng S29-07211602/S29-07221602 (8/20) SC 2 cf

16 7/22/16 16:10 07221616.D LCS R9072216_25ng S29-07211602/S29-07221602 (8/20) SC 2 pass

17 7/22/16 17:13 07221617.D P1603624-002 (4.0mL) S29-07211602 SC 1

18 7/22/16 17:47 07221618.D P1603261-001 (1000mL) S29-07211602 SC 5

19 7/22/16 18:21 07221619.D P1603360-001 (1000mL) S29-07211602 SC 6

20 7/22/16 18:55 07221620.D P1603622-001 (30mL) S29-07211602 SC 7 is failed

21 7/22/16 19:29 07221621.D P1603623-001 (400mL) S29-07211602 SC 8

22 7/22/16 20:03 07221622.D P1603625-001 (50mL) S29-07211602 SC 9 is failed

23 7/22/16 20:37 07221623.D P1603625-001dup (50mL) S29-07211602 SC 9 pass

24 7/22/16 21:12 07221624.D P1603624-001 (400mL) S29-07211602 SC 10

25 7/22/16 21:46 07221625.D P1603434-001 0.4ng LOD S29-07211602/S29-07211608 (8/19) SC 4 Rerun

26 7/22/16 22:20 07221626.D P1603434-002 0.5ng LOQ S29-07211602/S29-07211608 (8/19) SC 4 Rerun




30 7/23/16 0:37 07221630.D LCSD R9072216_25ng S29-07211602/S29-07221602 (8/20) SC 2 pass

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ATTACHMENT 4Tier 2 Screening Risk Assessment Report

(Version 8.0 & Attachment M, Revision March 2016) - Risk Tool (V1.02)

TIER 2 SCREENING RISK ASSESSMENT REPORT(Version 8.0 & Attachment M, Revision Mar 2016 ) - RiskTool (V1.02)

A/N: 123456 Application deemed complete date: 4/1/2016Fac: emaco Superfund Site

2. Tier 2 Data

Equipment Type Other No T-BACTOperation Schedule 24 hours/day; 7 days/week; 52 weeks/yearStack Height 25 ftDistance - Residential 75 mDistance - Commercial 25 mMeteorological Station Pico Rivera

Dispersion Factors tables Point SourceFor Chronic X/Q Table 3For Acute X/Q max Table 6

Dilution Factors

ReceptorΧ/Q

(µg/m³)/(tons/yr)X/Qmax

(µg/m³)/(lbs/hr)Residential 5.234 175.963Commercial - Worker 25.453 507.650

Adjustment and Intake FactorsResidential Worker

Year of Exposure 30

Combined Exposure Factor (CEF) - Table 9.1 & 9.2

676.63 56.26

Worker Adjustment Factor (WAF) - Table 10 1 1.00

Tier 2 Report - SCAQMD 2015 Risk Calculator_July16

Page 1 of 11 8/10/2016

A/N: 123456 04/01/16

3. Rule 1401 Compound Data

CompoundR1 -

Uncontrolled (lbs/hr)

R2 - Controlled

(lbs/hr)

CP(mg/kg-day)¯¹

MPMICR

Resident

MP MICR

Worker

MPChronic Resident

MP Chronic Worker

RELChronic(µg/m³)

REL8-hr Chronic

(µg/m³)

RELAcute

(µg/m³)MWAF

1.00 1.00 1.00 1.00 1.00E+03 6.80E+04 15.70E-03 1.00 1.00 1.00 1.00 1

1.00 1.00 1.00 1.00 7.00E+01 17.20E-02 1.00 1.00 1.00 1.00 4.00E+02 14.00E-02 1.00 1.00 1.00 1.00 8.00E+02 12.70E-02 1.00 1.00 1.00 1.00 3.00E+03 3.00E+03 1

1.90E-06 1.90E-06 1.00 1.00 1.00 1.00 1.30E+04 13.29E-07 3.29E-07 1.00 1.00 1.00 1.00 3.50E-01 7.00E-01 2.50E+00 1

1.00E-01 1.00 1.00 1.00 1.00 3.00E+00 3.00E+00 2.70E+01 11.00 1.00 1.00 1.00 8.00E+02 6.20E+03 1

1.50E-01 1.00 1.00 1.00 1.00 4.00E+01 1.90E+03 11.90E-02 1.00 1.00 1.00 1.00 3.00E+02 1.50E+02 18.70E-03 1.00 1.00 1.00 1.00 2.00E+03 13.50E-03 1.00 1.00 1.00 1.00 4.00E+02 1.40E+04 1

4.48E-07 4.48E-07 1.00 1.00 1.00 1.00 7.00E+03 11.20E-01 1.00 1.00 1.00 1.00 9.00E+00 1

1.00 1.00 1.00 1.00 3.00E+03 11.00 1.00 1.00 1.00 9.00E+02 2.10E+04 1

4.89E-07 4.89E-07 2.10E-02 1.00 1.00 1.00 1.00 3.50E+01 2.00E+04 13.40E-07 3.40E-07 1.00 1.00 1.00 1.00 3.00E+02 3.70E+04 1

7.00E-03 1.00 1.00 1.00 1.00 6.00E+02 11.00 1.00 1.00 1.00 2.00E+02 1

3.19E-06 3.19E-06 2.70E-01 1.00 1.00 1.00 1.00 1.80E+05 11.00 1.00 1.00 1.00 7.00E+02 2.20E+04 11.00 1.00 1.00 1.00 7.00E+02 2.20E+04 1

2.16E-06 2.16E-06 1.00 1.00 1.00 1.00 7.00E+03 3.20E+03 1

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene

ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)

1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Application deemed complete date:


Page 2 of 11 8/10/2016

A/N: 123456 04/01/164. Emission Calculations

Compound R1 (lbs/hr) R2 (lbs/hr) R2 (lbs/yr) R2 (tons/yr)

1.90E-06 1.90E-06 1.66E-02 8.32E-063.29E-07 3.29E-07 2.88E-03 1.44E-06

4.48E-07 4.48E-07 3.91E-03 1.96E-06

4.89E-07 4.89E-07 4.27E-03 2.13E-063.40E-07 3.40E-07 2.97E-03 1.48E-06

3.19E-06 3.19E-06 2.79E-02 1.39E-05

2.16E-06 2.16E-06 1.89E-02 9.44E-06

Total 8.86E-06 8.86E-06 7.74E-02 3.87E-05

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalene

p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzeneCarbon Disulfide

Vinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Propylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl Acetate



Page 3 of 11 8/10/2016

TIER 2 RESULTS A/N: 123456 Application deemed complete date: 04/01/16

5a. MICRMICR Resident = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Resident * CEF Resident * MP Resident * 1e-6 * MWAFMICR Worker = CP (mg/(kg-day))^-1 * Q (ton/yr) * (X/Q) Worker * CEF Worker* MP Worker* WAF Worker* 1e-6 * MWAF

Compound Residential Commercial

NO

1.59E-10 6.42E-11

1.33E-08 5.39E-09

No Cancer Burden, MICR<1.0E-6

Total 1.35E-08 5.45E-09PASS PASS

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)

Carbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-Hexane

Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)AcroleinBenzene

5b. Cancer Burden Calculation? NO

Zone Impact Area (km²):Population (7000 person/km²):

X/Q for one-in-a-million (µg/m³)/(tons/yr):New Distance at which MICR is 1 in a million (m):

Cancer Burden:

Vinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

NaphthalenePropylene (Propene)

StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethylene

Carbon Disulfide


Page 4 of 11 8/10/2016

6. Hazard Index A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max * MWAF ]/ Acute RELHIC = [Q(ton/yr) * (X/Q) * MP * MWAF] / Chronic RELHIC 8-hr= [Q(ton/yr) * (X/Q) * WAF * MWAF] / 8-hr Chronic REL

Acute Chronic 8-hr Chronic Acute Pass/Fail

Chronic Pass/Fail

8-hr Chronic Pass/Fail

Alimentary system (liver) - AL 1.55E-06 Pass Pass PassBones and teeth - BN Pass Pass PassCardiovascular system - CV Pass Pass PassDevelopmental - DEV 4.66E-09 1.60E-07 Pass Pass PassEndocrine system - END Pass Pass PassEye 6.73E-05 Pass Pass PassHematopoietic system - HEM Pass Pass PassImmune system - IMM Pass Pass PassKidney - KID 1.59E-06 Pass Pass PassNervous system - NS 2.61E-08 1.33E-07 Pass Pass PassReproductive system - REP 4.66E-09 1.60E-07 Pass Pass PassRespiratory system - RES 6.73E-05 1.05E-04 5.23E-05 Pass Pass PassSkin Pass Pass Pass

Target Organs



Page 5 of 11 8/10/2016

A/N: 123456 04/01/166a. Hazard Index Acute - ResidentHIA = [Q(lb/hr) * (X/Q)max resident * MWAF] / Acute REL

HIA - ResidentialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 2.58E-08 2.58E-08Acrolein 2.32E-05 2.32E-05BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene) 4.30E-09 4.30E-09 4.30E-09Toluene 1.61E-09 1.61E-09 1.61E-09 1.61E-09 1.61E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 3.12E-09 3.12E-09 3.12E-09o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 1.19E-07 1.19E-07

Total 1.61E-09 2.33E-05 9.03E-09 1.61E-09 2.33E-05



Page 6 of 11 8/10/2016

6a. Hazard Index Acute - Worker A/N: 123456 04/01/16HIA = [Q(lb/hr) * (X/Q)max Worker * MWAF] / Acute REL

HIA - CommercialCompound AL CV DEV EYE HEM IMM NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone) 7.43E-08 7.43E-08Acrolein 6.69E-05 6.69E-05BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene) 1.24E-08 1.24E-08 1.24E-08Toluene 4.66E-09 4.66E-09 4.66E-09 4.66E-09 4.66E-09TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene) 9.00E-09 9.00E-09 9.00E-09o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 3.43E-07 3.43E-07

Total 4.66E-09 6.73E-05 2.61E-08 4.66E-09 6.73E-05



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A/N: 123456 04/01/166b. Hazard Index Chronic - ResidentHIC = [Q(ton/yr) * (X/Q) Resident * MP Chronic Resident * MWAF] / Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)Acrolein 2.15E-05BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-Hexane 1.46E-09NaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene) 3.19E-07 3.19E-07Toluene 2.59E-08 2.59E-08 2.59E-08 2.59E-08TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 7.06E-09 7.06E-09 7.06E-09

Total 3.19E-07 3.29E-08 3.26E-07 2.73E-08 3.29E-08 2.15E-05



Page 8 of 11 8/10/2016

A/N: 123456 04/01/166b. Hazard Index Chronic - WorkerHIC = [Q(ton/yr) * (X/Q) * MP Chronic Worker * MWAF] / Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)Acrolein 1.05E-04BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-Hexane 7.11E-09NaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene) 1.55E-06 1.55E-06Toluene 1.26E-07 1.26E-07 1.26E-07 1.26E-07TrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol) 3.43E-08 3.43E-08 3.43E-08

Total 1.55E-06 1.60E-07 1.59E-06 1.33E-07 1.60E-07 1.05E-04



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6c. 8-hour Hazard Index Chronic - Resident A/N: 123456 04/01/16HIC 8-hr = [Q(ton/yr) * (X/Q) Resident * WAF Resident * MWAF] / 8-hr Chronic REL

HIC - ResidentialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)Acrolein 1.08E-05BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Total 1.08E-05



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A/N: 123456 04/01/166c. 8-hour Hazard Index Chronic - Worker HIC 8-hr = [Q(ton/yr) * (X/Q) Worker * WAF Worker * MWAF] / 8-hr Chronic REL

HIC - CommercialCompound AL BN CV DEV END EYE HEM IMM KID NS REP RESP SKIN

Methyl Chloroform (1,1,1-Trichloroethane)1,1,-Dichloroethane (Ethylidene Dichloride)Vinylidene Chloride (1,1-Dichloroethylene)Ethylene Dichloride (1,2-Dichloroethane)p-Dichlorobenzene1,4-Dioxane (1,4-Diethylene Dioxide)Methyl Ethyl Ketone (2-Butanone)Acrolein 5.23E-05BenzeneCarbon DisulfideCarbon Tetrachloride (Tetrachloromethane)ChloroformEthyl BenzeneMethylene Chloride (Dichloromethane)n-HexaneNaphthalenePropylene (Propene)StyrenePerchloroethylene (Tetrachloroethylene)TolueneTrichloroethyleneVinyl AcetateVinyl Chloride (Chloroethylene)o-XyleneXylenes (Mixed Isomers)Isopropyl Alcohol (Isopropanol)

Total 5.23E-05



Page 11 of 11 8/10/2016

MONTHLY MONITORING REPORT JULY 2016 · 317 E. Main Street Ventura, CA 93001 Tel: (805) 585-2110...

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