Molecular Orbitals.ppt

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Molecular Molecular Orbitals Orbitals An approach to bonding in which An approach to bonding in which orbitals encompass the entire orbitals encompass the entire molecule, rather than being molecule, rather than being localized between atoms. localized between atoms.

Transcript of Molecular Orbitals.ppt

Page 1: Molecular Orbitals.ppt

Molecular Molecular OrbitalsOrbitals

An approach to bonding in An approach to bonding in which orbitals encompass the which orbitals encompass the entire molecule, rather than entire molecule, rather than

being localized between being localized between atoms.atoms.

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Molecular OrbitalsMolecular OrbitalsMolecular orbitals result from Molecular orbitals result from

the combination of atomic orbitals. the combination of atomic orbitals. Since orbitals are wave Since orbitals are wave

functions, they can combine either functions, they can combine either constructively (forming a bonding constructively (forming a bonding molecular orbital), or destructively molecular orbital), or destructively (forming an antibonding molecular (forming an antibonding molecular orbital).orbital).

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Molecular OrbitalsMolecular OrbitalsMolecular orbitals form when Molecular orbitals form when

atomic orbitals with similar energies atomic orbitals with similar energies and proper symmetry can overlap.and proper symmetry can overlap.

Atomic orbitals with differing Atomic orbitals with differing energies or the wrong spatial energies or the wrong spatial orientation (orthogonal) do not orientation (orthogonal) do not combine, and are called combine, and are called non-bondingnon-bonding orbitals.orbitals.

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Need for MO TheoryNeed for MO TheoryValence bond theory fails to Valence bond theory fails to

explain the bonding in many simple explain the bonding in many simple molecules. molecules.

The oxygen molecule has a bond The oxygen molecule has a bond length and strength consistent with length and strength consistent with a double bond, and it contains two a double bond, and it contains two unpaired electrons.unpaired electrons.

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Need for MO TheoryNeed for MO TheoryValence bond theory predicts Valence bond theory predicts

the double bond, but not the the double bond, but not the paramagnetism of oxygen.paramagnetism of oxygen.

O=OO=O:

::

:

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Need for MO TheoryNeed for MO TheoryResonance is another example of the Resonance is another example of the limitations of valence bond theory. limitations of valence bond theory. Bond lengths and strengths are Bond lengths and strengths are intermediate between single, double intermediate between single, double or triple bonds. or triple bonds. Molecular orbital theory is often a Molecular orbital theory is often a better approach to use with better approach to use with molecules that have extended molecules that have extended ππ systems.systems.

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Molecular Orbital TheoryMolecular Orbital TheoryIn order to simplify things, we’ll In order to simplify things, we’ll

consider the interaction of the consider the interaction of the orbitals containing valence electrons orbitals containing valence electrons to create molecular orbitals.to create molecular orbitals.

The wave functions of hydrogen The wave functions of hydrogen atom A and hydrogen atom B can atom A and hydrogen atom B can interact either constructively or interact either constructively or destructively.destructively.

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Molecular Orbital TheoryMolecular Orbital TheoryConstructively:Constructively:

ΨΨ((σσ)) or or ΨΨ++ = ( = (1/√2 ) 1/√2 ) [[φφ(1s(1saa) ) + + φφ(1s(1sbb) ) ]]

Destructively:Destructively:ΨΨ((σσ*)*) or or ΨΨ-- = ( = (1/√2 ) 1/√2 ) [[φφ(1s(1saa) ) - - φφ(1s(1sbb) ) ]]

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Molecular Orbital TheoryMolecular Orbital TheoryThe bonding The bonding

orbital results in orbital results in increased electron increased electron density between density between the two nuclei, and the two nuclei, and is of lower energy is of lower energy than the two than the two separate atomic separate atomic orbitals.orbitals.

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Molecular Orbital TheoryMolecular Orbital TheoryThe The

antibonding orbital antibonding orbital results in a node results in a node between the two between the two nuclei, and is of nuclei, and is of greater energy greater energy than the two than the two separate atomic separate atomic orbitals.orbitals.

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Molecular Orbital TheoryMolecular Orbital TheoryThe result is an The result is an energy level diagram energy level diagram with the bonding with the bonding orbital occupied by a orbital occupied by a pair of electrons. The pair of electrons. The filling of the lower filling of the lower molecular orbital molecular orbital indicates that the indicates that the molecule is stable molecule is stable compared to the two compared to the two individual atoms.individual atoms.

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Molecular Orbital TheoryMolecular Orbital Theory

The bonding The bonding orbital is orbital is sometimes given sometimes given the notation the notation σσgg, , where the where the gg stands stands for for geradegerade, or , or symmetric with symmetric with respect to a center respect to a center of inversion. of inversion.

+

+

-

The signs on the molecular orbitals indicate the sign of the wave function, not ionic charge.

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Molecular Orbital TheoryMolecular Orbital Theory

The anti-bonding The anti-bonding orbital is orbital is sometimes given sometimes given the notation the notation σσuu, , where the where the u u stands stands for for ungeradeungerade, or , or asymmetric with asymmetric with respect to a center respect to a center of inversion. of inversion.

+

+

-

The signs on the molecular orbitals indicate the sign of the wave function, not ionic charge.

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Rules for Combining Rules for Combining Atomic OrbitalsAtomic Orbitals

1.1. The number of molecular orbitals = The number of molecular orbitals = the number of atomic orbitals the number of atomic orbitals combined.combined.

2.2. The strength of the bond depends The strength of the bond depends upon the degree of orbital overlap.upon the degree of orbital overlap.

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Experimental EvidenceExperimental EvidencePhotoelectron spectroscopy (PES) is a Photoelectron spectroscopy (PES) is a technique in which a beam of technique in which a beam of ultraviolet light with an energy of 21 ultraviolet light with an energy of 21 eV is used to irradiate molecules. eV is used to irradiate molecules. The energy is high enough to eject The energy is high enough to eject electrons. The kinetic energy of the electrons. The kinetic energy of the emitted electrons is measured, and emitted electrons is measured, and used to determine the energy level of used to determine the energy level of the electron.the electron.

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Experimental EvidenceExperimental EvidenceThe technique The technique allows for the allows for the measurement of measurement of specific ionization specific ionization energies (I). Each energies (I). Each ionization energy ionization energy represents the represents the removal of an removal of an electron from a electron from a specific molecular specific molecular orbital.orbital.

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Experimental EvidenceExperimental EvidenceElectrons in Electrons in lower energy lower energy levels require levels require more energy to more energy to be removed, and be removed, and are ejected with are ejected with less kinetic less kinetic energy. energy.

hhννoo = I + E = I + Ekinetickinetic

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Period 2 Diatomic Period 2 Diatomic MoleculesMolecules

For the second period, assume that, For the second period, assume that, due to a better energy match, due to a better energy match, ss orbitals combine with orbitals combine with ss orbitals, and orbitals, and pp orbitals combine with orbitals combine with pp orbitals. orbitals.The symmetry of The symmetry of pp orbitals permits orbitals permits end-on-end overlap along the bond end-on-end overlap along the bond axis, or side-by-side overlap around, axis, or side-by-side overlap around, but not along, the internuclear axis.but not along, the internuclear axis.

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MOs using MOs using pp orbitals orbitals

With the With the xx axis as the bond axis, the p axis as the bond axis, the pxx orbitals may combine constructively or orbitals may combine constructively or destructively. The result is a destructively. The result is a σσ bonding bonding orbital and a orbital and a σσ anti-bonding orbital. anti-bonding orbital.

+

++ -

--

-

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MOs using MOs using pp orbitals orbitals

The designation The designation σσ indicates symmetric indicates symmetric electron density around the internuclear electron density around the internuclear ((xx) axis. The + and – signs indicate the ) axis. The + and – signs indicate the sign of the wave function, and not sign of the wave function, and not electrical charges.electrical charges.

+

++ -

--

-

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MOs using MOs using pp orbitals orbitals

Some texts will use the Some texts will use the symmetry designations of symmetry designations of gg (gerade) (gerade) or or uu (ungerade) instead of indicating (ungerade) instead of indicating bonding or anti-bonding. bonding or anti-bonding.

+

++ -

--

-

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MOs using MOs using pp orbitals orbitals

For these orbitals, the bonding For these orbitals, the bonding orbital is orbital is geradegerade, or symmetric , or symmetric around the bond axis.around the bond axis.

+

++ -

--

-

σg

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MOs using MOs using pp orbitals orbitals

For these orbitals, the anti-bonding For these orbitals, the anti-bonding orbital is asymmetric about the bond orbital is asymmetric about the bond axis, and is designated as axis, and is designated as σσuu. Note that . Note that the designations of the designations of uu or or gg do notdo not correlate with bonding or anti-bonding.correlate with bonding or anti-bonding.

+

++ -

--

-

σg

σu

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ππ Molecular Orbitals Molecular Orbitals

The orbital overlap side-by-side is less than The orbital overlap side-by-side is less than that of overlap along the bond axis (end-on-that of overlap along the bond axis (end-on-end). As a result, the bonding orbital will be end). As a result, the bonding orbital will be higher in energy than the previous example.higher in energy than the previous example.

side-by-side overlap

++

+

--

-

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ππ Molecular Orbitals Molecular Orbitals

ππ orbitals are asymmetric with respect orbitals are asymmetric with respect to the bond axis. There is electron to the bond axis. There is electron density surrounding the bond axis, with density surrounding the bond axis, with a node along the internuclear axis.a node along the internuclear axis.

side-by-side overlap

++

+

--

-

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ππ Molecular Orbitals Molecular Orbitals

Some texts use the subscripts Some texts use the subscripts gg and and uu instead of bonding and anti-bonding. In this instead of bonding and anti-bonding. In this example, the bonding orbital is ungerade, or example, the bonding orbital is ungerade, or asymmetric about a center of symmetry.asymmetric about a center of symmetry.

side-by-side overlap

++

+

--

-πu

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ππ Molecular Orbitals Molecular Orbitals

The anti-bonding orbital is The anti-bonding orbital is geradegerade, or symmetric about a center , or symmetric about a center of symmetry.of symmetry.

side-by-side overlap

++

+

--

-πu

πg

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Molecular Orbital Molecular Orbital DiagramDiagram

This is a molecular This is a molecular orbital energy level orbital energy level diagram for the diagram for the pp orbitals. Note that orbitals. Note that the the σσ bonding bonding orbital is lowest in orbital is lowest in energy due to the energy due to the greater overlap greater overlap end-on-end.end-on-end.

2p 2p

σg

πu

πg

σu

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Molecular Orbital Molecular Orbital DiagramDiagram

The The alternate alternate notation is notation is provided on the provided on the right side of the right side of the energy level energy level diagram.diagram.

2p 2p

σg

πu

πg

σu

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Molecular Orbital Molecular Orbital DiagramsDiagrams

1.1. Electrons preferentially occupy molecular Electrons preferentially occupy molecular orbitals that are lower in energy.orbitals that are lower in energy.

2.2. Molecular orbitals may be empty, or Molecular orbitals may be empty, or contain one or two electrons.contain one or two electrons.

3.3. If two electrons occupy the same If two electrons occupy the same molecular orbital, they must be spin molecular orbital, they must be spin paired.paired.

4.4. When occupying degenerate molecular When occupying degenerate molecular orbitals, electrons occupy separate orbitals orbitals, electrons occupy separate orbitals with parallel spins before pairing.with parallel spins before pairing.

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Molecular Orbital Molecular Orbital DiagramsDiagrams

Although molecular orbitals Although molecular orbitals form from inner (core) electrons as form from inner (core) electrons as well as valence electrons, many well as valence electrons, many molecular orbital diagrams include molecular orbital diagrams include only the valence level.only the valence level.

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Molecular Orbital Molecular Orbital DiagramsDiagrams

For OFor O22, , there will be there will be a total of 12 a total of 12 valence valence electrons that electrons that must be must be placed in the placed in the diagram.diagram.

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Molecular Orbital Molecular Orbital DiagramsDiagrams

For OFor O22, , there will be there will be a total of 12 a total of 12 valence valence electrons that electrons that must be must be placed in the placed in the diagram.diagram.

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Molecular Orbital Molecular Orbital DiagramsDiagrams

For OFor O22, , there will be there will be a total of 12 a total of 12 valence valence electrons that electrons that must be must be placed in the placed in the diagram.diagram.

2p 2p

2s 2s

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MO Diagram for OMO Diagram for O22

2p 2p

2s 2sσg

σ*u

σg

πu

π*g

σ*u The molecular orbital diagram for oxygen shows two unpaired electrons, consistent with experimental data.

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Bond OrderBond OrderBond order is an indicator of the bond Bond order is an indicator of the bond strength and length. A bond order of strength and length. A bond order of 1 is equivalent to a single bond. 1 is equivalent to a single bond. Fractional bond orders are possible.Fractional bond orders are possible.

The bond order of the molecule =The bond order of the molecule =(# e(# e-- in bonding orbtls) in bonding orbtls) - - (# e(# e-- in anti- in anti-bonding orbtls)bonding orbtls) 22 22

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MO Diagram for OMO Diagram for O22

2p 2p

2s 2sσg

σ*u

σg

πu

π*g

σ*uThe bond order of O2 is:

8-4 = 2 2

This is consistent with a double bond.

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MO Diagram for OMO Diagram for O22

2p 2p

2s 2sσg

σ*u

σg

πu

π*g

σ*uThis energy level diagram works well for atoms in which the 2s and 2p levels are fairly far apart. These are the elements at the right of the table: O, F and Ne.

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Experimental EvidenceExperimental EvidenceOxygen is paramagnetic, consistent with Oxygen is paramagnetic, consistent with having two unpaired electrons. In addition, having two unpaired electrons. In addition, photoelectron spectroscopyphotoelectron spectroscopy (PES) can be (PES) can be used for determining orbital energies in used for determining orbital energies in molecules. The molecule is bombarded with molecules. The molecule is bombarded with UV or X-rays to remove an electron from the UV or X-rays to remove an electron from the molecule. The kinetic energy of the emitted molecule. The kinetic energy of the emitted electron is measured and subtracted from electron is measured and subtracted from the incident radiation to determine the the incident radiation to determine the binding energy of the electron.binding energy of the electron.

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Photoelectron Photoelectron SpectroscopySpectroscopy

The result is a spectrum of The result is a spectrum of absorptions which are correlated to the absorptions which are correlated to the molecular orbitals of the molecule. In molecular orbitals of the molecule. In addition, electrons ejected from bonding addition, electrons ejected from bonding orbitals show more vibrational energy orbitals show more vibrational energy levels than electrons emitted from anti-levels than electrons emitted from anti-bonding or non-bonding orbitals.bonding or non-bonding orbitals.

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MO diagram for Li MO diagram for Li through Nthrough N

The elements on the left side of The elements on the left side of period 2 have a fairly small energy period 2 have a fairly small energy gap between the 2s and 2p orbitals. gap between the 2s and 2p orbitals. As a result, interaction between s As a result, interaction between s and p orbitals is possible. This can and p orbitals is possible. This can be viewed in different ways. be viewed in different ways.

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MO diagram for Li MO diagram for Li through Nthrough N

In some approaches, the s orbital on In some approaches, the s orbital on one atom interacts with the p orbital on one atom interacts with the p orbital on another. The interaction can be another. The interaction can be constructive or destructive.constructive or destructive.

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MO diagram for Li MO diagram for Li through Nthrough N

In another approach, the s and p In another approach, the s and p orbitals on the orbitals on the samesame atom interact in atom interact in what is called what is called orbital mixingorbital mixing. .

Either approach yields the same Either approach yields the same result. The result. The σσ bonding and anti- bonding and anti-bonding orbitals are raised in energy bonding orbitals are raised in energy due to the interaction with a due to the interaction with a pp orbital.orbital.

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MO diagram for Li MO diagram for Li through Nthrough N

σg

σg

σ*u

σ*u

πu

π*g

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MO diagram for NMO diagram for N22

σg

σg

σ*u

σ*u

πu

π*g

N2 has 10 valence electrons.

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Experimental EvidenceExperimental EvidenceThe photoelectronic The photoelectronic spectrum of spectrum of nitrogen is nitrogen is consistent with a consistent with a molecular orbital molecular orbital approach. approach. Electrons emitted Electrons emitted from bonding from bonding orbitals show orbitals show vibrational vibrational excitations.excitations.

σg

πu

σ*u

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Experimental EvidenceExperimental Evidence

σg

πu

σ*uσg

σg

σ*u

σ*u

πu

π*g

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Heteronuclear Diatomic Heteronuclear Diatomic MoleculesMolecules

The more electronegative atom will The more electronegative atom will have orbitals of lower energy, and have orbitals of lower energy, and therefore contribute more to the therefore contribute more to the bonding orbitals.bonding orbitals.The less electronegative atom has The less electronegative atom has orbitals of higher energy, and orbitals of higher energy, and contributes more to the anti-bonding contributes more to the anti-bonding orbitals.orbitals.

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Rules for Combining Rules for Combining Atomic OrbitalsAtomic Orbitals

For heteronuclear molecules:For heteronuclear molecules:

1. The bonding orbital(s) will reside 1. The bonding orbital(s) will reside predominantly on the atom of lower predominantly on the atom of lower orbital energy (the more orbital energy (the more electronegative atom).electronegative atom).

2. The anti-bonding orbital(s) will reside 2. The anti-bonding orbital(s) will reside predominantly on the atom with greater predominantly on the atom with greater orbital energy (the less electronegative orbital energy (the less electronegative atom).atom).

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HFHFThe 2s and 2pThe 2s and 2pxx orbitals orbitals on fluorine interact on fluorine interact with the 1s orbital on with the 1s orbital on hydrogen. hydrogen. The pThe pyy and p and pzz orbitals orbitals on fluorine lack proper on fluorine lack proper symmetry to interact symmetry to interact with hydrogen, and with hydrogen, and remain as non-bonding remain as non-bonding orbitals.orbitals.

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HFHFThe anti-bonding The anti-bonding orbital resides orbital resides primarily on the less primarily on the less electronegative atom electronegative atom (H).(H).Note that the Note that the subscripts subscripts gg and and uu are are not used, as the not used, as the molecule no longer molecule no longer has a center of has a center of symmetry.symmetry.

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Carbon monoxideCarbon monoxideIn carbon In carbon

monoxide, the monoxide, the bonding orbitals bonding orbitals reside more on reside more on the oxygen atom, the oxygen atom, and the anti-and the anti-bonding orbitals bonding orbitals reside more on reside more on the carbon atom. the carbon atom.

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Carbon monoxideCarbon monoxideCO is a highly CO is a highly reactive molecule reactive molecule with transition with transition metals. Reactivity metals. Reactivity typically arises from typically arises from the the hhighest ighest ooccupied ccupied mmolecular olecular oorbital (HOMO), rbital (HOMO), when donating when donating electrons.electrons.

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Carbon monoxideCarbon monoxideWhen When

acting as an acting as an electron pair electron pair acceptor, the acceptor, the llowest owest uunoccupied noccupied mmolecular olecular oorbital (LUMO), rbital (LUMO), is significant.is significant.

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Carbon monoxideCarbon monoxideWhen When

acting as an acting as an electron pair electron pair donor, the donor, the hhighest ighest ooccupied ccupied mmolecular olecular oorbital (HOMO), rbital (HOMO), is significant.is significant.

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The highest occupied molecular orbital of CO is a molecular orbital which puts significant electron density on the carbon atom.

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The lowest unoccupied molecular orbital of CO is the π* orbitals. The lobes of the LUMO are larger on the carbon atom than on the oxygen atom.

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CO as a LigandCO as a LigandCarbon monoxide is known as a Carbon monoxide is known as a

σσ donor and a donor and a ππ acceptor ligand. It acceptor ligand. It donates electrons from its HOMO to donates electrons from its HOMO to form a sigma bond with the metal.form a sigma bond with the metal.

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CO as a LigandCO as a LigandCarbon monoxide accepts Carbon monoxide accepts

electrons from filled electrons from filled dd orbitals on orbitals on the metal into its antibonding the metal into its antibonding (LUMO) orbital.(LUMO) orbital.

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CO as a LigandCO as a Ligand

This phenomenon is called This phenomenon is called back bondingback bonding. . The increased electron density in the The increased electron density in the antibonding orbitals of CO causes an antibonding orbitals of CO causes an increase in the C-O bond length and a increase in the C-O bond length and a decrease in its stretching frequency.decrease in its stretching frequency.

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MOs for Larger MOs for Larger MoleculesMolecules

Group theory is usually used to develop Group theory is usually used to develop molecular orbital diagrams and drawings molecular orbital diagrams and drawings of more complicated molecules. When a of more complicated molecules. When a central atom is bonded to several atoms central atom is bonded to several atoms of the same element (Hof the same element (H22O, BFO, BF33, or PtCl, or PtCl44

2-2-], ], group theory can be used to analyze the group theory can be used to analyze the symmetry of the orbitals of the non-symmetry of the orbitals of the non-central atoms, and then combine them central atoms, and then combine them with the appropriate orbitals of the with the appropriate orbitals of the central atom.central atom.

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MOs for Larger MOs for Larger MoleculesMolecules

The orbitals of the non-central The orbitals of the non-central atoms are called atoms are called group orbitalsgroup orbitals. In . In considering a simple example, Hconsidering a simple example, H22O, O, we obtain group orbitals using the we obtain group orbitals using the two two 1s1s orbitals on the hydrogen orbitals on the hydrogen atoms.atoms.

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The characters for the The characters for the group orbitals is obtained group orbitals is obtained by considering each by considering each hydrogen as a spherical hydrogen as a spherical 1s1s orbital. They remain orbital. They remain in position for identity, in position for identity, are exchanged during are exchanged during rotation, remain in place rotation, remain in place for σfor σxzxz (the molecular (the molecular plane), and are plane), and are exchanged for σexchanged for σyzyz..

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Group Orbitals of WaterGroup Orbitals of WaterΓΓredred and its irreducible and its irreducible representations are:representations are:

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Group Orbitals of WaterGroup Orbitals of WaterThe AThe A11 representation has both representation has both 1s1s orbitals with positive wave orbitals with positive wave functions: Hfunctions: Haa+H+Hbb..

The BThe B11 representations is H representations is Haa+H+Hbb..

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Group Orbitals of WaterGroup Orbitals of WaterThese group orbitals are combined These group orbitals are combined with orbitals on oxygen that have with orbitals on oxygen that have the same symmetry.the same symmetry.

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Group Orbitals of WaterGroup Orbitals of Water

The 2s and 2pz orbital on oxygen have A1 symmetry, the 2px orbital has B1 symmetry, and the 2py has B2 symmetry.

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Molecular Orbitals of Molecular Orbitals of WaterWater

Since the Since the 2p2pyy orbital on oxygen orbital on oxygen doesn’t match the symmetry of the doesn’t match the symmetry of the group orbitals of hydrogen, it will group orbitals of hydrogen, it will remain non-bonding. The other remain non-bonding. The other orbitals on oxygen will combine with orbitals on oxygen will combine with the appropriate group orbitals to the appropriate group orbitals to form bonding and antibonding form bonding and antibonding molecular orbitals.molecular orbitals.

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MOs for Larger MOs for Larger MoleculesMolecules

Group theory is usually used to Group theory is usually used to develop molecular orbital diagrams develop molecular orbital diagrams and drawings of more complicated and drawings of more complicated molecules. A simplified example will molecules. A simplified example will be shown for the be shown for the ππ bonding of bonding of benzene.benzene.

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ππ Bonding of Benzene Bonding of BenzeneBenzene belongs to point group Benzene belongs to point group

DD6h6h. In determining the orbital . In determining the orbital combinations for combinations for ππ bonding, we need bonding, we need to obtain to obtain ГГππ by looking only at the p by looking only at the pzz orbitals on each carbon atom.orbitals on each carbon atom.We need only

consider those orbitals on carbon atoms that remain in place for a given symmetry operation.

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ππ Bonding of Benzene Bonding of Benzene

DD6h6h EE 2C2C66

2C2C33

CC22

3C3C′′22

3C3C″″22

ii 22SS33

22SS66

σσhh

3 3 σσdd

3 3 σσvv

ГГππ

{z axis

C′2C″2

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ππ Bonding of Benzene Bonding of Benzene

DD6h6h EE 2C2C66

2C2C33

CC22

3C3C′′22

3C3C″″22

ii 22SS33

22SS66

σσhh

3 3 σσdd

3 3 σσvv

ГГππ 66 00 00 00 -2-2 00 00 00 00 -6-6 00 22

{z axis

C′2C″2

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ππ Bonding of Benzene Bonding of Benzene

DD6h6h EE 2C2C66

2C2C33

CC22

3C3C′′22

3C3C″″22

ii 22SS33

22SS66

σσhh

3 3 σσdd

3 3 σσvv

ГГππ 66 00 00 00 -2-2 00 00 00 00 -6-6 00 22

{z axis

C′2C″2

This reduces to: B2g + E1g + A2u + E2u

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ππ Bonding of Benzene Bonding of BenzeneГπ: B2g + E1g + A2u + E2u

Group theory can be used to draw Group theory can be used to draw each of the each of the ππ molecular orbitals. molecular orbitals. Molecular orbitals with fewer nodes Molecular orbitals with fewer nodes are lower in energy (more bonding), are lower in energy (more bonding), and those with more nodes are higher and those with more nodes are higher in energy (more antibonding).in energy (more antibonding).

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ππ Bonding of Benzene Bonding of BenzeneГπ: B2g + E1g + A2u + E2u

A2u fully bonding and lowest in energy

E1g degenerate bonding orbitals with one node

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ππ Bonding of Benzene Bonding of BenzeneГπ: B2g + E1g + A2u + E2u

E2u degenerate largely anti-bonding orbitals with two nodesB2g fully anti-

bonding orbital with three nodes

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ππ Bonding of Benzene Bonding of Benzene

A2u

E1g

E2u

B2g

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Molecular Orbitals of Molecular Orbitals of ComplexesComplexes

Group theory is also used to construct Group theory is also used to construct molecular orbital diagrams for the molecular orbital diagrams for the complexes of metal atoms or ions. The complexes of metal atoms or ions. The symmetry combinations of the atomic symmetry combinations of the atomic orbitals on the ligands are determined, orbitals on the ligands are determined, and then “matched” with appropriate and then “matched” with appropriate atomic orbitals on the central metal. atomic orbitals on the central metal. Both Both σσ and and ππ bonding between the bonding between the metal and ligands can be considered.metal and ligands can be considered.