Mixed Chloride Indicator Powder 24-9808 v2 1 1 1 8-Oct-2010 Us-English-local on Apr-27-2013

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MIXED CHLORIDE INDICATOR POWDER Chemwatch Material Safety Data Sheet Oct-8-2010 CHEMWATCH 24-9808 X!293SP Version No:2.1.1.1 Page 1 of 10 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME MIXED CHLORIDE INDICATOR POWDER STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. NFPA FLAMMABILITY 1 HEALTH HAZARD 2 INSTABILITY 0 SUPPLIER Company: Drew Marine Address: 100 South Jefferson Road Whippany, NJ 07981 United States of America Telephone: 973 526- 5700. Emergency Tel:The numbers below are for EMERGENCY USE ONLY. Use the corporate number above for all other calls. Emergency Tel:CHEMWATCH: From within the US and CANADA: 1 877- 715- 9305 OR call + 613 9573 3112. From outside the US and Canada: + 800 2436 2255 ( +800 CHEMCALL) or +613 9573 3112 PRODUCT USE Used according to manufacturer's directions. Section 2 - HAZARDS IDENTIFICATION HAZARD RATINGS Flammability Toxicity Body Contact Reactivity Chronic SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 CANADIAN WHMIS SYMBOLS continued...

description

MSDS

Transcript of Mixed Chloride Indicator Powder 24-9808 v2 1 1 1 8-Oct-2010 Us-English-local on Apr-27-2013

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

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Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAMEMIXED CHLORIDE INDICATOR POWDER

STATEMENT OF HAZARDOUS NATURECONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200.

NFPA

FLAMMABILITY1HEALTH HAZARD2 INSTABILITY0

SUPPLIERCompany: Drew MarineAddress:100 South Jefferson RoadWhippany, NJ 07981United States of AmericaTelephone: 973 526- 5700.Emergency Tel:The numbers below are for EMERGENCY USE ONLY. Use the corporate number above for allother calls.Emergency Tel:CHEMWATCH: From within the US and CANADA: 1 877- 715- 9305 OR call + 613 9573 3112.From outside the US and Canada: + 800 2436 2255 ( +800 CHEMCALL) or +613 9573 3112

PRODUCT USEUsed according to manufacturer's directions.

Section 2 - HAZARDS IDENTIFICATION

HAZARD RATINGS

Flammability Toxicity

Body Contact Reactivity

Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

CANADIAN WHMIS SYMBOLS

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

Page 2 of 10Section 2 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

RISKHarmful if swallowed.Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED■ Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may befatal or may produce serious damage to the health of the individual.

EYE■ This material can cause eye irritation and damage in some persons.

SKIN■ This material can cause inflammation of the skin oncontact in some persons.■ The material may accentuate any pre-existing dermatitis condition.■ Open cuts, abraded or irritated skin should not be exposed to this material.■ Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

INHALED■ The material can cause respiratory irritation in some persons.The body's response to such irritation can cause further lung damage.■ Inhalation of dusts, generated by the material during the course of normal handling, may be damaging to the health of theindividual.■ Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incurfurther disability if excessive concentrations of particulate are inhaled.

CHRONIC HEALTH EFFECTSLong-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Phenylhydrazines are capable of exerting haemolytic effects following a haemoglobin-catalysed metabolic conversion. Thishaemolytic effect is a consequence of the formation of free radicals in which phenylhydrazine undergoes oxidation to a phenyldiazinyl radical intermediate and subsequent conversion to a phenyl radical (and nitrogen, N2).Oxygen activation (generation of a superoxide) occurs during one of the reactions of this metabolic sequence. Superoxide is astrong base and can therefore attract protons from a variety of compounds; it is also a potent reducing agent which can reducetransition metal ions (such as Fe3+ and Cu+) to their reduced form Superoxide may also act as a nucleophile and may readily reactwith a number of electrophilic agents. Finally superoxide may initiate oxidation reactions, for example, of molecules such asascorbic acid or epinephrine (adrenaline) following hydrogen abstraction due to its basicity.Under certain conditions the rate of formation of reactive oxygen species may exceed the capacity of the bodies auto-oxidativedefence mechanisms and, as a result, result in "oxidative stress'". Oxidative stress appears to be involved in some biologicalprocesses such as aging and inflammation reactions and is thought to play a role in the pathogenesis of several diseases,including acute pancreatitis, post-ischaemic syndrome,tumour formation, atherosclerosis and diabetic angiopathy.Free radicals can react with specific cellular molecules including low molecular weight biomolecules such as neurotransmittersand co-enzymes and, as a consequence, inactivate them. macromolecules and cellular membranes are particularly vulnerable to freeradical damage with the resultant loss of physiological function and cell death Depolymerisation of polysaccharides (such ashyaluronic acid) may result in inflammation of the joints.Free radicals have a high affinity for sulfur containing amino-acids and therefore many proteins. The may bind covalently tothese proteins leading to loss, of biological function such as catalysis exhibited by enzymes. Covalent binding may also resultin allergic reactions when the modified protein is recognised, by the bodies immune system, as "foreign" Free radicals are alsocapable of causing proteins to cross-link to yield larger aggregates.Free radicals are also able to react with the nucleic acids of DNA which may affect cell division or cell death Oxidativemodifications of DNA may result in tumour initiation.Lipids containing several double bonds (such as polyunsaturated fatty acids and cholesterol) are also subject to damage. In thecase of membrane phospholipids, such "peroxidation" results in impairment of cellular and/ or subcellular membranes which mayproduce cell death. Transition metal ions may also play an important role in lipid peroxidation after free radical-induced changeof valency . Fe3+/Fe2+, copper and mercury ions, as well as vanadate and chromate ions seem to initiate this process and mayeven exacerbate it by producing secondary radicals when the phospholipid is modified.Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis; caused by particles lessthan 0.5 micron penetrating and remaining in the lung.

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

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Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %diphenylcarbazone 538-62-5 >60bromophenol blue 115-39-9 5-10sulfamic acid 5329-14-6 5-10Note: Manufacturer has supplied full ingredientinformation to allow CHEMWATCH assessment.

Section 4 - FIRST AID MEASURES

SWALLOWED• IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.• Where Medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise:• For advice, contact a Poisons Information Center or a doctor.• Urgent hospital treatment is likely to be needed.

EYE■ If this product comes in contact with the eyes:• Wash out immediately with fresh running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.• If pain persists or recurs seek medical attention.• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN■ If skin contact occurs:• Immediately remove all contaminated clothing, including footwear• Flush skin and hair with running water (and soap if available).• Seek medical attention in event of irritation.

INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIANTreat symptomatically.In poisonings involving hydrazine:Correction of early hypoglycaemia, with large parenteral doses of pyridoxine appears to suppress convulsions and other

neurological effects.In man, hydrazine-induced hyperexcitability and coma may respond to massive doses of pyridoxine but there is no evidence thatliver necrosis or damage can be prevented or corrected by this antidote.GOSSELIN, SMITH & HODGE: Clinical Toxicology of Commercial Products, 5 th Ed.

Section 5 - FIRE FIGHTING MEASURES

Vapour Pressure (mmHg): Not AvailableUpper Explosive Limit (%): Not AvailableSpecific Gravity (water=1): Not AvailableLower Explosive Limit (%): Not Available

EXTINGUISHING MEDIA• Water spray or fog.• Foam.• Dry chemical powder.• BCF (where regulations permit).

FIRE FIGHTING• Alert Emergency Responders and tell them location and nature of hazard.• Wear breathing apparatus plus protective gloves.

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

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• Prevent, by any means available, spillage from entering drains or water course.• Use water delivered as a fine spray to control fire and cool adjacent area.When any large container (including road and rail tankers) is involved in a fire,consider evacuation by 100 metres in all directions.

GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS• Combustible solid which burns but propagates flame with difficulty.• Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture

with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the finegrinding of the solid are a particular hazard; accumulations of fine dust may burn rapidly and fiercely if ignited.

• Dry dust can be charged electrostatically by turbulence, pneumatic transport, pouring, in exhaust ducts and during transport.• Build-up of electrostatic charge may be prevented by bonding and grounding.Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), otherpyrolysis products typical of burning organic material.

FIRE INCOMPATIBILITY■ Avoid contamination with oxidizing agents i.e. nitrates, oxidizing acids,chlorine bleaches, pool chlorine etc. as ignition mayresult.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS• Remove all ignition sources.• Clean up all spills immediately.• Avoid contact with skin and eyes.• Control personal contact with the substance, by using protective equipment.• Use dry clean up procedures and avoid generating dust.• Place in a suitable, labelled container for waste disposal.Environmental hazard - contain spillage.

MAJOR SPILLSEnvironmental hazard - contain spillage.Moderate hazard.• CAUTION: Advise personnel in area.• Alert Emergency Responders and tell them location and nature of hazard.• Control personal contact by wearing protective clothing.• Prevent, by any means available, spillage from entering drains or water courses.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING• Avoid all personal contact, including inhalation.• Wear protective clothing when risk of exposure occurs.• Use in a well-ventilated area.• Prevent concentration in hollows and sumps.• Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including secondary explosions)• Minimise airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces, sparks, and flame.• Establish good housekeeping practices.• Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds.• Use continuous suction at points of dust generation to capture and minimise the accumulation of dusts. Particular attention should be given to overhead and hidden horizontal surfaces to minimise the probability of a "secondary" explosion. According to NFPA Standard 654, dust layers 1/32 in.(0.8 mm) thick can be sufficient to warrant immediate cleaning of the area.• Do not use air hoses for cleaning.• Minimise dry sweeping to avoid generation of dust clouds. Vacuum dust-accumulating surfaces and remove to a chemical disposal area. Vacuums with explosion-proof motors should be used.• Control sources of static electricity. Dusts or their packages may accumulate static charges, and static discharge can be a source of ignition.• Solids handling systems must be designed in accordance with applicable standards (e.g. NFPA including 654 and 77) and other national guidance.• Do not empty directly into flammable solvents or in the presence of flammable vapors.• The operator, the packaging container and all equipment must be grounded with electrical bonding and grounding systems. Plastic bags and plastics cannot be grounded, and antistatic bags do not completely protect against development of static charges.

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Empty containers may contain residual dust which has the potential to accumulate following settling. Such dusts may explode in the presence of an appropriate ignition source.• Do NOT cut, drill, grind or weld such containers.• In addition ensure such activity is not performed near full, partially empty or empty containers without appropriate workplace safety authorisation or permit.

RECOMMENDED STORAGE METHODS• Lined metal can, Lined metal pail/drum• Plastic pail• Polyliner drum• Packing as recommended by manufacturer.Glass container.

STORAGE REQUIREMENTS■ Observe manufacturer's storing and handling recommendations.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLSThe following materials had no OELs on our records• bromophenol blue: CAS:115- 39- 9• sulfamic acid: CAS:5329- 14- 6

MATERIAL DATABROMOPHENOL BLUE:DIPHENYLCARBAZONE:SULFAMIC ACID:

It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there isevidence of health effects at airborne concentrations encountered in the workplace.

At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animalexperiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible andoccupational exposure must be kept to a minimum.

NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.

DIPHENYLCARBAZONE:SULFAMIC ACID:

Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historicallyoccupational exposure standards for these irritants have been based on observation of workers' responses to various airborneconcentrations. Present day expectations require that nearly every individual should be protected against even minor sensoryirritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasionanimal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additionalapproach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been toassign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight ofevidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission(Germany) uses a five-category system based on intensive odour, local irritation, and elimination half-life. However this systemis being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL);this is more closely allied to that of the USA.

OSHA (USA) concluded that exposure to sensory irritants can:• cause inflammation• cause increased susceptibility to other irritants and infectious agents• lead to permanent injury or dysfunction• permit greater absorption of hazardous substances and• acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure.

MIXED CHLORIDE INDICATOR POWDER:Not available

PERSONAL PROTECTION

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

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RESPIRATOR•Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

EYE• Safety glasses with side shields.• Chemical goggles.• Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them. DO NOT wear contact

lenses.

HANDS/FEET■ The selection of the suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves andhas to be observed when making a final choice.Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:• frequency and duration of contact,• chemical resistance of glove material,• glove thickness and• dexteritySelect gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).• When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time

greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.• When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes

according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.• Contaminated gloves should be replaced.Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids,where abrasive particles are not present.• polychloroprene• nitrile rubber• butyl rubber• fluorocaoutchouc• polyvinyl chlorideGloves should be examined for wear and/ or degradation constantly.

OTHER• Overalls.• P.V.C. apron.• Barrier cream.• Skin cleansing cream.• Eye wash unit.

ENGINEERING CONTROLS• Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively

large, a certain proportion will be powdered by mutual friction.• Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the workplace.• If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be

considered. Such protection might consist of:(a): particle dust respirators, if necessary, combined with an absorption cartridge;(b): filter respirators with absorption cartridge or canister of the right type;(c): fresh-air hoods or masks• Build-up of electrostatic charge on the dust particle, may be prevented by bonding and grounding.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL PROPERTIESMixes with water.

State Divided Solid Molecular Weight Not ApplicableMelting Range (°F) Not Available Viscosity Not AvailableBoiling Range (°F) Not Available Solubility in water (g/L) MiscibleFlash Point (°F) Not Available pH (1% solution) Not AvailableDecomposition Temp (°F) Not Available pH (as supplied) Not Available

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MIXED CHLORIDE INDICATOR POWDERChemwatch Material Safety Data SheetOct-8-2010 CHEMWATCH 24-9808X!293SP Version No:2.1.1.1

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Autoignition Temp (°F) Not Available Vapour Pressure (mmHg) Not AvailableUpper Explosive Limit (%) Not Available Specific Gravity (water=1) Not AvailableLower Explosive Limit (%) Not Available Relative Vapor Density Not Available

(air=1)Volatile Component (%vol) Not Available Evaporation Rate Not Available

APPEARANCEOrange odourless powder; mixes with water.

Section 10 - CHEMICAL STABILITY

CONDITIONS CONTRIBUTING TO INSTABILITY• Presence of incompatible materials.• Product is considered stable.• Hazardous polymerization will not occur.

STORAGE INCOMPATIBILITY■ Sulfamic acid:• reacts violently with chlorine, nitric acid, fuming nitric acid, strong bases, chlorine, hypochlorous acid, strong oxidising agents, sulfides, cyanides or when heated with nitrates, nitrites• is strongly acidic in aqueous solution• hydrolyses to ammonium bisulfate at elevated temperatures• is incompatible with alkylene oxides, aliphatic amines, alkanolamines, amides, ammonia, epichlorohydrin, organic anhydrides, isocyanates, metal nitrates/ nitrites, oxidisers, vinyl acetate, common metals and their alloys, water

Contact with metals may result in the evolution of hydrogen (H2) which can form explosive mixtures in air.Avoid reaction with oxidizing agents.

For incompatible materials - refer to Section 7 - Handling and Storage.

Section 11 - TOXICOLOGICAL INFORMATION

MIXED CHLORIDE INDICATOR POWDER

TOXICITY AND IRRITATION■ Not available. Refer to individual constituents.

CARCINOGENbromophenol blue US Environmental Defense Reference(s) P65- MC

Scorecard SuspectedCarcinogens

Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.This material and its container must be disposed of as hazardous waste.Avoid release to the environment.Refer to special instructions/ safety data sheets.

EcotoxicityIngredient Persistence: Persistence: Air Bioaccumulation Mobility

Water/Soildiphenylcarbazone HIGH No Data LOW MED

Availablebromophenol blue HIGH No Data LOW LOW

Available

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sulfamic acid HIGH No Data LOW HIGHAvailable

Section 13 - DISPOSAL CONSIDERATIONS

Disposal InstructionsAll waste must be handled in accordance with local, state and federal regulations.¦ Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked.A Hierarchy of Controls seems to be common - the user should investigate:• Reduction• Reuse• Recycling• Disposal (if all else fails)This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Shelf life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be appropriate. In most instances the supplier of the material should be consulted.DO NOT allow wash water from cleaning equipment to enter drains. Collect all wash water for treatment before disposal.• Recycle wherever possible.• Consult manufacturer for recycling options or consult Waste Management Authority for disposal if no suitable treatment or disposal facility can be identified.• Dispose of by: Burial in a licensed land-fill or Incineration in a licensed apparatus (after admixture with suitable combustible material)• Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

Section 14 - TRANSPORTATION INFORMATION

DOT:Symbols: G Hazard class or Division: 9Identification Numbers: UN3077 PG: IIILabel Codes: 9 Special provisions: 8, 146,

335, A112,B54, IB8,IP3, N20,T1, TP33

Packaging: Exceptions: 155 Packaging: Non- bulk: 213Packaging: Exceptions: 155 Quantity limitations: No limit

Passenger aircraft/rail:Quantity Limitations: Cargo No limit Vessel stowage: Location: Aaircraft only:Name:Environmentally hazardous substance, solid, n.o.s

Air Transport IATA:ICAO/IATA Class: 9 ICAO/IATA Subrisk: NoneUN/ID Number: 3077 Packing Group: IIISpecial provisions: A97Cargo OnlyPacking Instructions: 956 Maximum Qty/Pack: 400 kgPassenger and Cargo Passenger and CargoPacking Instructions: 956 Maximum Qty/Pack: 400 kgPassenger and Cargo Limited Quantity Passenger and Cargo Limited QuantityPacking Instructions: Y956 Maximum Qty/Pack: 30 kg G

Shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(contains bromophenol blue)

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Maritime Transport IMDG:IMDG Class: 9 IMDG Subrisk: NoneUN Number: 3077 Packing Group: IIIEMS Number: F-A,S-F Special provisions: 274 335Limited Quantities: 5 kg Marine Pollutant: YesShipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(contains bromophenol blue)

Section 15 - REGULATORY INFORMATION

REGULATIONS

Regulations for ingredients

diphenylcarbazone (CAS: 538-62-5) is found on the following regulatory lists;"Canada - Alberta Ambient Air Quality Guidelines", "Canada - Alberta Ambient Air Quality Objectives", "Canada - British Columbia Occupational Exposure Limits", "Canada - Nova Scotia Occupational Exposure Limits", "Canada - Ontario Occupational Exposure Limits", "Canada - Prince Edward Island Occupational Exposure Limits", "Canada - Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada Domestic Substances List (DSL)", "Canada National Pollutant Release Inventory (NPRI)", "FisherTransport Information", "Sigma-AldrichTransport Information", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - Michigan Exposure Limits for Air Contaminants", "US - Oregon Permissible Exposure Limits (Z-1)", "US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants", "US - Washington Permissible exposure limits of air contaminants", "US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US ACGIH Threshold Limit Values (TLV)", "US Clean Air Act (CAA) National Ambient Air Quality Standards (NAAQS)", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

bromophenol blue (CAS: 115-39-9) is found on the following regulatory lists;"Acros Transport Information", "Canada - Alberta Ambient Air Quality Guidelines", "Canada - Alberta Ambient Air Quality Objectives", "Canada - British Columbia Occupational Exposure Limits", "Canada - Ontario Occupational Exposure Limits", "Canada - Quebec Permissible Exposure Values for Airborne Contaminants (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Bioaccumulative to the environment (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Inherently Toxic to the Environment (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Inherently Toxic to the Environment (French)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that are Persistent, Bioaccumulative, and Inherently Toxic to the Environment (PBiT) (English)", "Canada CEPA Environmental Registry Substance Lists - List of substances on the DSL that meet the ecological criteria for categorization (English)", "Canada Domestic Substances List (DSL)", "Canada National Pollutant Release Inventory (NPRI)", "Sigma-AldrichTransport Information", "US - California Air Toxics ""Hot Spots"" List (Assembly Bill 2588) Substances for Which Emissions Must Be Quantified", "US - California Permissible Exposure Limits for Chemical Contaminants", "US - Maine Chemicals of Concern List", "US - Michigan Exposure Limits for Air Contaminants", "US - Oregon Permissible Exposure Limits (Z-1)", "US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants", "US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants", "US Clean Air Act (CAA) National Ambient Air Quality Standards (NAAQS)", "US DOE Temporary Emergency Exposure Limits (TEELs)", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

sulfamic acid (CAS: 5329-14-6) is found on the following regulatory lists;"Canada Domestic Substances List (DSL)", "Canada Ingredient Disclosure List (SOR/88-64)", "Canada Toxicological Index Service - Workplace Hazardous Materials Information System - WHMIS (English)", "FisherTransport Information", "International Council of Chemical Associations (ICCA) - High Production Volume List", "OECD List of High Production Volume (HPV) Chemicals", "Sigma-AldrichTransport Information", "US - New Jersey Right to Know - Special Health Hazard Substance List (SHHSL): Corrosives", "US - New Jersey Right to Know Hazardous Substances (English)", "US American Cleaning Institute Cleaning Product Ingredient Inventory", "US DOE Temporary Emergency Exposure Limits (TEELs)", "US FDA CFSAN GRAS Substances evaluated by the Select Committee on GRAS Substances (SCOGS)", "US FDA Everything Added to Food in the United States (EAFUS)", "US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory"

No data for MIXED MIXED CHLORIDE INDICATOR POWDER (CW: 24-9808)

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Section 16 - OTHER INFORMATION

Denmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codesdiphenylcarbazone 538- 62- 5 N; R50■ Classification of the mixture and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

■ For detailed advice on Personal Protective Equipment, refer to the following U.S. Regulations and Standards:OSHA Standards - 29 CFR:1910.132 - Personal Protective Equipment - General requirements1910.133 - Eye and face protection1910.134 - Respiratory Protection1910.136 - Occupational foot protection1910.138 - Hand ProtectionEye and face protection - ANSI Z87.1Foot protection - ANSI Z41Respirators must be NIOSH approved.

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Issue Date: Oct-8-2010Print Date: Apr-28-2013