Minerals and Rocks What is a mineral? What is a mineral? –naturally occurring, inorganic, solid...
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Minerals and RocksMinerals and Rocks What is a mineral?What is a mineral?
– naturally occurring, inorganic, solid element or compound naturally occurring, inorganic, solid element or compound with a definite chemical composition and a regular internal with a definite chemical composition and a regular internal crystal structurecrystal structure
What is rock?What is rock?– solid, cohesive, aggregate of one or more mineralssolid, cohesive, aggregate of one or more minerals– Each rock type has a characteristic mixture of mineralsEach rock type has a characteristic mixture of minerals
What is an Ore?What is an Ore?– Rock with large concentration of a particular maineral to Rock with large concentration of a particular maineral to
make it profitablemake it profitable– High and low grade oresHigh and low grade ores
» NON- Metalic MineralNON- Metalic Mineral Sand, gravel, limestoneSand, gravel, limestone
» MetalicMetalic Aluminum, Steel, manganese, cobalt, chromium, Copper, GoldAluminum, Steel, manganese, cobalt, chromium, Copper, Gold
Types of Mining:
• Surface Mining: Scoop ore off surface or earth. • cheap. • safe for miners. • large environmental destruction.
• Underground Mining: Use of shafts to reach deeply buried ores. • expensive. • hazardous for miners. • less environmental damage.
Mining: Extract Ore from GroundMining: Extract Ore from Ground
Strip MiningStrip Mining strip-mining: scoop off rock
overburden, and then scoop off ore material.
• Economics of strip mining depend on stripping ratio
• Large land area can be involved, especially for coal and bauxite.
Results of Mining utube
Surface MiningSurface Mining open pit mining:
• circular hole in ground, with ramp circling down along sides, allows deeper ore to be reached.
Video of Pit mining for gold
Gold in QuartzGold in Quartz
A large quartz boulder with a lot of visible gold. A large quartz boulder with a lot of visible gold. Usually, the gold is much finer and hard to see.Usually, the gold is much finer and hard to see.
Placer DepositionPlacer Deposition
Panning for Panning for gold in a gold in a placer placer depositdeposit
Aeolian PlacersAeolian Placers
The "diamond crawl" in a The "diamond crawl" in a deflation basin, Diamond deflation basin, Diamond Area No 1, NamibiaArea No 1, Namibia
Diamond concentrations Diamond concentrations were increased by wind were increased by wind erosionerosion
CassiteriteCassiterite tin oxide ore mineral, SnO2. It is generally tin oxide ore mineral, SnO2. It is generally
opaque but is translucent in thin crystals. Its opaque but is translucent in thin crystals. Its luster and multiple crystal faces produce a luster and multiple crystal faces produce a desirable gem. Cassiterite has been the chief desirable gem. Cassiterite has been the chief tin ore throughout ancient history and tin ore throughout ancient history and remains the most important source of tin remains the most important source of tin today today
TinSoldiers
Non-Non-renewable renewable Mineral Mineral
Resource Resource Depletion Depletion
CurvesCurves
Source: Miller, G. Tyler, Living In The Environment. (2000) Wadsworth Publishing. New York.
EnergyEnergy Chapters 15 -18Chapters 15 -18
Living in the EnvironmentLiving in the Environment, 16, 16thth Edition, Miller Edition, MillerAdvanced Placement Environmental ScienceAdvanced Placement Environmental Science
La Canada High SchoolLa Canada High School
Dr. E A. Friedland andDr. E A. Friedland and
With a few links and additions by Ms. WilkinsWith a few links and additions by Ms. Wilkins
1. Energy Resources1. Energy Resources
2. Oil2. Oil
3. Natural Gas3. Natural Gas
4. Coal4. Coal
5. Nuclear Energy5. Nuclear Energy
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Energy SourcesEnergy Sources Modern society requires large quantities of energy that Modern society requires large quantities of energy that
are generated from the earth’s natural resources.are generated from the earth’s natural resources.
Primary Energy Resources:Primary Energy Resources: The fossil fuels(oil, gas, The fossil fuels(oil, gas, and coal), nuclear energy, falling water, geothermal, and and coal), nuclear energy, falling water, geothermal, and solar energy.solar energy.
Secondary Energy ResourcesSecondary Energy Resources: Those sources which : Those sources which are derived from primary resources such as electricity, are derived from primary resources such as electricity, fuels from coal, (synthetic natural gas and synthetic fuels from coal, (synthetic natural gas and synthetic gasoline), as well as alcohol fuels.gasoline), as well as alcohol fuels.
www.lander.edu/rlayland/Chem%20103/chap_12.ppt
Energy resources removed from the earth’s crust include: oil, natural gas, coal, and uranium
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
"We are surrounded with people who think that what we have been doing for one fortieth of the [last] second can go on indefinitely. They are considered normal, but they are stark raving mad.”David Brower as quoted by John McPhee in Encounters With The Archdruid.
Nonrenewable Nonrenewable EnergyEnergy
Chapters 15Chapters 15 Living in the EnvironmentLiving in the Environment, 15, 15thth Edition, Miller Edition, Miller
Advanced Placement Environmental ScienceAdvanced Placement Environmental ScienceLa Canada High SchoolLa Canada High School
Dr. EDr. E
With a few links and additions by Ms. WilkinsWith a few links and additions by Ms. Wilkins
Problems with Fossil Problems with Fossil FuelsFuels
Fossil fuels are nonrenewable resourcesFossil fuels are nonrenewable resources– At projected consumption rates, natural gas At projected consumption rates, natural gas
and petroleum will be depleted before the end and petroleum will be depleted before the end of the 21st centuryof the 21st century
Impurities in fossil fuels are a major source Impurities in fossil fuels are a major source of pollutionof pollution
Burning fossil fuels produce large amounts Burning fossil fuels produce large amounts of COof CO22, which contributes to global , which contributes to global
warmingwarmingwww.lander.edu/rlayland/Chem%20103/chap_12.ppt
1. Energy Resources 1. Energy Resources
2. Oil2. Oil3. Natural Gas3. Natural Gas
4. Coal4. Coal
5. Nuclear Energy5. Nuclear Energy
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
OilOil Deposits of crude oil often are trapped within Deposits of crude oil often are trapped within
the earth's crust and can be extracted by drilling the earth's crust and can be extracted by drilling a wella well
Fossil fuel, produced by the decomposition of Fossil fuel, produced by the decomposition of deeply buried organic matter from plants & deeply buried organic matter from plants & animalsanimals
Crude oil: complex liquid mixture of Crude oil: complex liquid mixture of hydrocarbons, with small amounts of S, O, N hydrocarbons, with small amounts of S, O, N impuritiesimpurities
How Oil Drilling WorksHow Oil Drilling Works by Craig C. Freudenrich, Ph.D. by Craig C. Freudenrich, Ph.D.
Sources of OilSources of Oil•Organization of Petroleum Exporting Countries (OPEC) -- 13 countries have 67% world reserves:
• Algeria, Ecuador, Gabon, Indonesia, Iran, Iraq, Kuwait, Libya, Nigeria, Qatar, Saudi Arabia, United Arab Emirates, & Venezuela
•Other important producers: Alaska, Siberia, & Mexico.
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Oil in U.S.Oil in U.S.•2.3% of world reserves
•uses nearly 30% of world reserves;
•65% for transportation;
•increasing dependence on imports. www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Low oil prices have stimulated economic growth, they have discouraged / prevented improvements in energy efficiency and alternative technologies favoring renewable resources.
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
• Burning any fossil fuel releases carbon dioxide into the atmosphere and thus promotes global warming.
• Comparison of CO2 emitted by fossil fuels and nuclear power.
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
OilOil Crude oil is transported to a Crude oil is transported to a
refinery where distillation produces refinery where distillation produces petrochemicalspetrochemicals– How Oil Refining WorksHow Oil Refining Works
by Craig C. by Craig C.
Freudenrich, Ph.D.Freudenrich, Ph.D.
1. Energy Resources 1. Energy Resources
2. Oil2. Oil
3. Natural Gas3. Natural Gas4. Coal4. Coal
5. Nuclear Energy5. Nuclear Energy
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Natural Gas - Fossil Natural Gas - Fossil FuelFuel
• Mixture •50–90% Methane (CH4)
•Ethane (C2H6)
•Propane (C3H8)
•Butane (C4H10)
•Hydrogen sulfide (H2S)www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Sources of Natural Sources of Natural GasGas
•Russia & Kazakhstan - almost 40% of world's supply.
•Iran (15%), Qatar (5%), Saudi Arabia (4%), Algeria (4%), United States (3%), Nigeria (3%), Venezuela (3%);
•90–95% of natural gas in U.S. domestic (~411,000 km = 255,000 miles of pipeline).
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Natural GasNatural Gas Experts predict increased use of natural gas Experts predict increased use of natural gas
during this centuryduring this century
Natural GasNatural Gas When a natural gas field is tapped, propane When a natural gas field is tapped, propane
and butane are liquefied and removed as and butane are liquefied and removed as liquefied petroleum gas (LPG) liquefied petroleum gas (LPG)
The rest of the gas (mostly methane) is The rest of the gas (mostly methane) is dried, cleaned, and pumped into pressurized dried, cleaned, and pumped into pressurized pipelines for distributionpipelines for distribution
Liquefied natural gas (LNG) can be shipped Liquefied natural gas (LNG) can be shipped in refrigerated tanker shipsin refrigerated tanker ships
1. Energy Resources 1. Energy Resources
2. Oil2. Oil
3. Natural Gas3. Natural Gas
4. Coal4. Coal5. Nuclear Energy5. Nuclear Energy
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Coal: Supply and Coal: Supply and DemandDemand
Coal exists in many forms therefore a chemical Coal exists in many forms therefore a chemical formula cannot be written for it.formula cannot be written for it.
Coalification: After plants died they Coalification: After plants died they underwent chemical decay to form a product underwent chemical decay to form a product known as peatknown as peat– Over many years, thick peat layers formed. Over many years, thick peat layers formed. – Peat is converted to coal by geological events such Peat is converted to coal by geological events such
as land subsidence which subject the peat to great as land subsidence which subject the peat to great pressures and temperatures.pressures and temperatures.
www.lander.edu/rlayland/Chem%20103/chap_12.ppt
Ranks of CoalRanks of Coal Lignite: A brownish-black coal of low quality (i.e., Lignite: A brownish-black coal of low quality (i.e.,
low heat content per unit) with high inherent moisture low heat content per unit) with high inherent moisture and volatile matter. Energy content is lower 4000 and volatile matter. Energy content is lower 4000
BTU/lb.BTU/lb. Subbituminous: Black lignite, is dull black and Subbituminous: Black lignite, is dull black and
generally contains 20 to 30 percent moisture Energy generally contains 20 to 30 percent moisture Energy
content is 8,300 BTU/lb.content is 8,300 BTU/lb. Bituminous: most common coal is dense and black Bituminous: most common coal is dense and black
(often with well-defined bands of bright and dull (often with well-defined bands of bright and dull material). Its moisture content usually is less than 20 material). Its moisture content usually is less than 20 percent. Energy content about 10,500 Btu / lb.percent. Energy content about 10,500 Btu / lb.
Anthracite :A hard, black lustrous coal, often referred Anthracite :A hard, black lustrous coal, often referred to as hard coal, containing a high percentage of fixed to as hard coal, containing a high percentage of fixed carbon and a low percentage of volatile matter. carbon and a low percentage of volatile matter. Energy content of about 14,000 Btu/lb.Energy content of about 14,000 Btu/lb.
www.uvawise.edu/philosophy/Hist%20295/ Powerpoint%5CCoal.ppt
Main Coal DepositsMain Coal Deposits
BituminousBituminous
AnthraciteAnthracite
SubbituminousSubbituminous
LigniteLignite
www.lander.edu/rlayland/Chem%20103/chap_12.ppt
Advantages and DisadvantagesAdvantages and Disadvantages
Pros•Most abundant fossil fuel•Major U.S. reserves•300 yrs. at current consumption rates•High net energy yield
Cons•Dirtiest fuel, highest carbon dioxide•Major environmental degradation•Major threat to health © Brooks/Cole Publishing Company / ITP
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Coal Producing Electricity Producing Electricity
with Coalwith Coal Coal gasification Coal gasification Synthetic Synthetic natural gas (SNG)natural gas (SNG)
Coal liquefaction Coal liquefaction Liquid Liquid fuelsfuels
DisadvantageDisadvantage– CostlyCostly– High environmental impactHigh environmental impact
Sulfur in CoalSulfur in Coal When coal is burned, sulfur is released When coal is burned, sulfur is released
primarily as sulfur dioxide (SOprimarily as sulfur dioxide (SO22 - serious - serious
pollutant)pollutant)
– Coal Cleaning - Methods of removing sulfur Coal Cleaning - Methods of removing sulfur from coal include cleaning, solvent refining, from coal include cleaning, solvent refining, gasification, and liquefaction Scrubbers are used gasification, and liquefaction Scrubbers are used to trap SOto trap SO22 when coal is burned when coal is burned
– Two chief forms of sulfur is inorganic (FeSTwo chief forms of sulfur is inorganic (FeS22 or or
CaSOCaSO44) and organic (Sulfur bound to Carbon)) and organic (Sulfur bound to Carbon)www.lander.edu/rlayland/Chem%20103/chap_12.ppt
Acid Mine Acid Mine DrainageDrainage
The impact of The impact of mine drainage mine drainage on a lake after on a lake after
receiving receiving effluent from effluent from
an abandoned an abandoned tailings tailings
impoundment impoundment for over 50 for over 50
yearsyears
Relatively fresh tailings in an Relatively fresh tailings in an impoundment. impoundment.
The same tailings impoundment The same tailings impoundment after 7 years of sulfide after 7 years of sulfide
oxidation. The white spots in oxidation. The white spots in Figures A and B are gulls. Figures A and B are gulls.
http://www.earth.uwaterloo.ca/services/whaton/s06_amd.html
Mine Mine effluent effluent
discharging discharging from the from the
bottom of a bottom of a waste rock waste rock
pilepile
Shoreline Shoreline of a pond of a pond receiving receiving
AMD AMD showing showing massive massive
accumulatiaccumulation of iron on of iron
hydroxides hydroxides on the on the pond pond
bottom bottom
Groundwater flow Groundwater flow through a tailings through a tailings impoundment and impoundment and
discharging into lakes or discharging into lakes or streams. streams.
1. Energy Resources 1. Energy Resources
2. Oil2. Oil
3. Natural Gas3. Natural Gas
4. Coal4. Coal
5. Nuclear Energy5. Nuclear Energy
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Nuclear EnergyNuclear Energy In a conventional nuclear In a conventional nuclear
power plantpower plant– a controlled nuclear fission a controlled nuclear fission
chain reaction chain reaction – heats waterheats water– produce high-pressure steam produce high-pressure steam – that turns turbines that turns turbines – generates electricity. generates electricity.
Nuclear EnergyNuclear EnergyControlled Fission Chain Reaction
neutrons split the nuclei of atoms such as of Uranium or Plutonium
release energy (heat)
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
• Radioactive decay continues until the the original isotope is changed into a stable isotope that is not radioactive
• Radioactivity: Nuclear changes in which unstable (radioactive) isotopes emit particles & energy
RadioactivityRadioactivity
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
• Types• Alpha particles consist of 2 protons and 2 neutrons,
and therefore are positively charged• Beta particles are negatively charged (electrons)• Gamma rays have no mass or charge, but are a form
of electromagnetic radiation (similar to X-rays)
• Sources of natural radiation• Soil• Rocks• Air• Water• Cosmic rays
RadioactivityRadioactivity
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
The time needed for one-half of the nuclei in a radioisotope to decay and emit their radiation to form a different isotope
Half-time emitted Uranium 235 710 million yrs alpha, gammaPlutonium 239 24.000 yrs alpha, gamma
During operation, nuclear power plants produce radioactive wastes, including some that remain dangerous for tens of thousands of years
Half-LifeHalf-Life
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Diagram of Radioactive Diagram of Radioactive DecayDecay
cstl-cst.semo.edu/bornstein/BS105/ Energy%20Use%20-%203.ppt
• Genetic damages: from mutations that alter genes
• Genetic defects can become apparent in the next generation
• Somatic damages: to tissue, such as burns, miscarriages & cancers
Effects of RadiationEffects of Radiation
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
1. Low-level radiation (Gives of low amount of radiation)• Sources: nuclear power plants, hospitals &
universities• 1940 – 1970 most was dumped into the ocean• Today deposit into landfills
2. High-level radiation (Gives of large amount of radiation)• Fuel rods from nuclear power plants• Half-time of Plutonium 239 is 24000 years• No agreement about a safe method of storage
Radioactive WasteRadioactive Waste
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Radioactive WasteRadioactive Waste1. Bury it deep underground.
• Problems: i.e. earthquake, groundwater…2. Shoot it into space or into the sun.
• Problems: costs, accident would affect large area.3. Bury it under the Antarctic ice sheet.
• Problems: long-term stability of ice is not known, global warming
4. Most likely plan for the US• Bury it into Yucca Mountain in desert of Nevada • Cost of over $ 50 billion• 160 miles from Las Vegas• Transportation across the country via train & truck
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Reprocess Nuclear FuelReprocess Nuclear Fuel During the operation of a nuclear During the operation of a nuclear
reactor the uranium runs outreactor the uranium runs out Accumulating fission products Accumulating fission products
hinder the proper function of a hinder the proper function of a nuclear reactornuclear reactor
Fuel needs to be (partly) renewed Fuel needs to be (partly) renewed every yearevery year
www.geology.fau.edu/course_info/fall02/ EVR3019/Nuclear_Waste.ppt
Nuclear EnergyNuclear Energy Concerns about the safety, Concerns about the safety,
cost, and liability have cost, and liability have slowed the growth of the slowed the growth of the nuclear power industrynuclear power industry
Accidents at Chernobyl and Accidents at Chernobyl and Three Mile Island showed Three Mile Island showed that a partial or complete that a partial or complete meltdown is possiblemeltdown is possible
Nuclear Power Plants in Nuclear Power Plants in U.S.U.S.
cstl-cst.semo.edu/bornstein/BS105/ Energy%20Use%20-%203.ppt
Three Mile IslandThree Mile Island•March 29, 1979, a reactor near Harrisburg, PA lost coolant water because of mechanical and human errors and suffered a partial meltdown
•50,000 people evacuated & another 50,000 fled area
•Unknown amounts of radioactive materials released
•Partial cleanup & damages cost $1.2 billion
•Released radiation increased cancer rates.
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt
ChernobylChernobyl• April 26, 1986, reactor explosion (Ukraine) flung radioactive debris into atmosphere
• Health ministry reported 3,576 deaths
• Green Peace estimates32,000 deaths;
• About 400,000 people were forced to leave their homes
• ~160,000 sq km (62,00 sq mi) contaminated
• > Half million people exposed to dangerous levels of radioactivity
• Cost of incident > $358 billionwww.bio.miami.edu/beck/esc101/Chapter14&15.ppt
Use of Nuclear Use of Nuclear EnergyEnergy• U.S. phasing out
• Some countries (France, Japan) investing increasingly
• U.S. currently ~7% of energy nuclear• No new U.S. power plants ordered since 1978• 40% of 105 commercial nuclear power expected
to be retired by 2015 and all by 2030• North Korea is getting new plants from the US• France 78% energy nuclear
www.bio.miami.edu/beck/esc101/Chapter14&15.ppt