Mid Atlantic Presented To: Equipment

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Presented To: Mid Atlantic Equipment Management Association

Transcript of Mid Atlantic Presented To: Equipment

Presented To:Mid Atlantic Equipment Management Association

MeetingAgendaMeetingAgenda

• Interduction

• Coolants Training•Evolution•Properties• HD Extended Life Coolants

•How they work

• Interduction

• Coolants Training•Evolution•Properties• HD Extended Life Coolants

•How they work

The Evolution of AntifreezeThe Evolution of Antifreeze

Problem:1. Engines need cooling

2. Water freezes during winter

3. Summer boil over

4. Cooling system corrosion

5. Inhibitor Depletion/ Maintenance

Solution:Radiator with water

Add Methanol to the radiator

Ethylene Glycol

Corrosion Inhibitors

Change antifreeze, add SCAs (H/D) or use Extended Life Coolants

Antifreeze / CoolantAntifreeze / Coolant

Inhibitors-(5%)

Glycol-(47.5%) Glycol Provides Boil-Over And Freeze Point Protection

Water-(47.5%) Water Transfers Heat

Inhibitors Protect Metals From Rust And Corrosion

100

0

Ethylene Glycol Concentration, Wt %

33% Glycol = FreezingProtection -20°C

Tem

pera

ture

, °C

Tem

pera

ture

, °F

-20

-40

-60

-800 20 40 60 80

-90

-60

-30

0

30

Max. Protectionat Eutectic, -68°C

Freeze Protection Typically - Ethylene Glycol + Water

Chemical Definitions

Two Inhibitor Classes: Organic and InorganicOrganic Compounds‐

Chemicals which contain carbon atoms

Inorganic Compounds‐Chemical Compounds which do not contain carbon atoms

• Silicate, Borate, Nitrate, Phosphate, Nitrite• Fast Film Forming--Short Lived, Drop-out concerns• Requires Addition of Supplemental Coolant Additive (SCA) when

used in Heavy Duty Applications

• Silicate, Borate, Nitrite• Fast Film Forming– Short Lived, Fewer Drop-out Concerns• SCA Pre-Charged for Heavy-Duty Applications

Coolant Technology Definitions

Conventional: Inorganic ObsoleteConventional: Inorganic Obsolete

Fully Formulated: Inorganic DINISHING IN USEFully Formulated: Inorganic DINISHING IN USE

The Old Technology

THE PROBLEM: Fully Formulated Coolants

Poor Coolant Or Poor Maintenance Contributes To More Than 40% Of All Heavy Duty Engine Failures

Fully Formulated Coolant/SCA Systems

0

20

40

60

80

100

120

0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

Glycol Content

Freq

uenc

y

Shaded Area RepresentsDesired Glycol Range Of

40% to 60%.

Glycol & Inhibitor Frequency Distribution

Glycol Concentrations

• To little Glycol the inhibitor levels are too low for protection in Conventional Coolants

• To Much Glycol leads to:– Over Heating – Formation of Acids

• High Acid concentration leads to corrosion

• Part failures

Daylight PlateCalibration

ScrewFocus

Adjustment

Main PrismAssembly

RubberGrip

Eyepiece

Step 1: Place 2 To 3 Drops Of Coolant Under The Daylight Plate.  After 30 Seconds, Go To Step 2.

Step 2:Looking Through The Eyepiece, Read Freeze Point For EG Or PG Base Coolant.

Refractometer Best Practice for Freeze Point Adjustment

Refractometer Best Practice for Freeze Point Adjustment

Fully Formulated Coolant/SCA Systems

020406080

100120

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5

SCA Units

Freq

uenc

y

Shaded Area RepresentsDesired SCA Range Of

1.0 to 1.5 Units.

Why Is Maintaining SCA Levels Such A Problem?

Why Is Maintaining SCA Levels Such A Problem?

• Inorganic Inhibitors Deplete

• Topping Off With Conventional Antifreeze Dilutes SCA Levels

• Topping Off With Water Dilutes SCA Levels

• The addition of too many SCA’s

Max

Min

Ideal

Over Treated

Under Treated

Results of Poor System Maintenance

CAVITATION CORROSION SCALE “GREEN GOO”

Seals In Heat1/16” 40%

Seals In Heat1/16” 40%

Destroys Cooling System

Metals/Parts

Destroys Cooling System

Metals/Parts

Or Wet Sleeve Cylinder Liner

Pitting

Or Wet Sleeve Cylinder Liner

Pitting

Phosphate And Silicate Dropout

Phosphate And Silicate Dropout

HD OEM Transition to Extended Life Technology

• Europeans1990’s

• Japanese1990’s

• G.M. & Caterpillar 1995

• Paccar 2001

• All HD OEM’s offer 2002

• ALL HD OEM’s FF 2010

• Europeans1990’s

• Japanese1990’s

• G.M. & Caterpillar 1995

• Paccar 2001

• All HD OEM’s offer 2002

• ALL HD OEM’s FF 2010

No Major OEMs Use Conventional Green Coolant or Fully Formulated

As Standard Initial Fill

No Major OEMs Use Conventional Green Coolant or Fully Formulated

As Standard Initial Fill

OEM DateOEM Date

Questions ???

Heavy-Duty Coolant SolutionsHeavy-Duty Coolant Solutions

The Solution

Recommended Best Practice

Extended Life Coolants

• Organic Acids, in Combination with one or more Conventional Inhibitors

• Fast and Slow Film Forming– Longer lasting than Conventional, Shorter lasting than OAT. Potential Drop-out Issues

• Organic Acids- No Silicates, Phosphates, Nitrates, or Borates• Slower Film Forming—Longer lasting, No Drop-out concerns

Coolant Technology Definitions

Organic Acid Technology: Organic BESTOrganic Acid Technology: Organic BEST

Hybrid Organic Acid Technology (HOAT): Organic + Inorganic BetterHybrid Organic Acid Technology (HOAT): Organic + Inorganic Better

Current Technology

Global Evolution of Heavy-Duty Coolant

Conventional

Fully Formulated

Extended Life

Fully Formulated

Why Use Extended Life Coolants

• Superior inhibitor Performance– More Robust Inhibitors with Stands Higher

Dilution

– Slow Inhibitor Depletion

– Improved Component Life

– Improved Heat Transfer

– Excellent Rust & Corrosion Protection

– Excellent Hot Surface Protection

CathodicCathodicArea

ConventionalCoolant

METAL

AnodicSite e-e-

e-

Protective Layer:Insoluble Metal-Inhibitor Salts

Q

CarboxylateCoolant

METAL

AnodicSite Cathodic

Area

e-e -

e -

H+

H+H2

Inh

Q Q Q

InhInh

Protection Mechanism

Extended LifeExtended Life

Differences: Extended Life VS Conventional

23

ConventionalExtended Life

Slow Inhibitor DepletionCorrosion Inhibitor Depletion Rates

Organic Inhibitors Deplete at a Much Slower Rate Than Inorganic Inhibitors

Improved Component Life Wet Sleeve Liner Protection

A Sleeve Inserted In Diesel Engine Blocks To:

• Improve Heat Transfer

• Improve Serviceability Of Heavy Duty Engines

One of the most common and costly cooling system repairs is the perforation

of wet sleeve cylinder liners.

What Causes Cavitation OrWet Sleeve Liner Cavitation?

When the piston moves down it creates force on the Thrust and Anti Thrust side. This moves the Liner out and it snaps back creating an Implosion of bubbles.

What Is Causes Cavitation OrWet Sleeve Liner Cavitation?

Thrust on Liner

In Untreated Systems,

Imploding Bubbles

Bore Through The Steel

Liners

Preventing Wet Sleeve Liner Cavitation

Preventing Wet Sleeve Liner Cavitation

In Treated Systems, Imploding Bubbles Are Blocked By Inhibitors Inorganic inhibitors are

destroyed in this process and must be replaced (Nitrite Depletion)

Organic Inhibitors are not used up in this process

Improved Component Life

• No Silicates to plate out on surfaces

• No Phosphates to drop out and form Scale

• No borates which can be aggressive to Aluminum

Improved Heat Transfer

• No Silicates to Form a Heat Barrier

• No Phosphates to help in the formation of Scale another Heat Barrier

CarboxylateCoolant

METAL

AnodicSite Cathodic

Area

e-e -

e -

H+

H+H2

Inh

Q Q Q

InhInh

Heat Transfer Rate (at 2 gpm Flow Rate)

31

2.8

3

3.2

3.4

0 25 50 75 100 125 150 175 200Time, Hours

Hea

t Tra

nsfe

r Rat

e, k

W

Carboxylate-basedSilicate-based

8 % Difference

Excellent Rust & Corrosion and Hot Surface Protection

• Carboxylate corrosion protection mechanism provides superior protection in high heat and coolant dilution situations

CarboxylateCoolant

METAL

AnodicSite Cathodic

Area

e-e -

e -

H+

H+H2

Inh

Q Q Q

InhInh

•Water is Clear & Ethylene Glycol is Clear. Coolants Can Be Dyed Any Color.

• All Coolant Are Compatible – However Performance Is Impacted !!

• Conventional Coolants & Some ELC = Conventional Coolant

• ELC + More Than 25% Conventional Coolant = Conventional Coolant

• Treat Both Above As Conventional Coolant OK

• If You Treat ELC With More Than 25% Dilution With Water Or Conventional Coolants As ELC You Could Have A FAILURE.

Color, Compatibility, Or Mixing

Color, Compatibility, Or Mixing

•ELC Are Long Chain Hydrocarbons - Soaps -They Will Clean The System Up!

•Changing Or Mixing Old Conventional Systems With ELC Can Uncover Leaks & CreatePremature Water Pump Failure.

• We Recommend Maintaining The Same Technology Which Is In The Vehicle.

ELC Conventional

Conversion From Conventional Systems to Extended Life Coolant

• Maintain vehicles on Fully Formulated until sold– Continue to add SCA’a

– Could use ELC as top up

• Maintain all new vehicles on ELC

Conversion From Conventional Systems to Extended Life Coolant

• Flush and Fill– Flush with water

– Remove Charged SCA filter

– Replace with Blank Filter

– Drain all water

– Fill with Extended Life Coolant 50/50

– Adjust Freeze Point if needed

– Identify with new Product Sticker

Maintaining The Cooling System

1. Use only ELC 50/50 Pre-Diluted coolant when topping-off the cooling system.

2. If Extended Life Coolant is not available, top-off the cooling system with water. If freeze protection is not needed then Adjust freeze point when Concentrate ELC when available.

3. Maintain between a 45% to 60% coolant and a 55% to 40% water mix

4. Do not add Supplemental Coolant Additives (SCAs) to the cooling system or use chemically charged filters.

5. After conversion, You are good to go One Million Miles

Water Pump Failure

– Check your coolant by holding a sample in a clear vessel up to the light.

– If you see floating particles

Change your Coolant

Why Extended Life Coolants

• Saves you Money $$$$$$$$$$$$$

– Eliminates the Cost of SCA’s

– Reduces down time for Maintenance

– 25% Dilution with out loss of performance

Cooling System Maintenance CostCooling System Maintenance Cost

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Green FullyFormulated ELC Line 4

0

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Green FullyFormulated ELC Line 4

Cost

Questions ???

Thank You

Ron Moser

[email protected]

Phone 361-230-3011