Methane Gestis

27/1/2015 Methane

http://gestisen.itrust.de/nxt/gateway.dll/gestis_en%2F010000.xml?f=templates&fn=print.htm&GLOBAL=G_&G_DIEXSL=GESTISPRINT.XSL 1/15

GESTISSubstanceDatabase

IDENTIFICATION

MethaneR50

ZVGNo: 10000CASNo: 74828ECNo: 2008127INDEXNo: 601001004

CHARACTERISATION

SUBSTANCEGROUPCODE

140110162000

Hydrocarbons,aliphatic,saturatedOrganicgases

STATEOFAGGREGATION

Thesubstanceisgaseous.

PROPERTIES

Colour: colourlessOdour: odourless

CHEMICALCHARACTERISATION

Extremelyflammablegas.Formsexplosivemixtureswithair.Onlyslightlysolubleinwater.Gasislighterthanair.

FORMULA

CH4

Methane

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Molarmass: 16,04g/molConversionfactor(gaseousphase)at1013mbarand20C:1ml/m= 0,667mg/m

PHYSICALANDCHEMICALPROPERTIES

TRIPLEPOINT

Temperature: 182,5CPressure: 0,117bar

MELTINGPOINT

Meltingpoint: 182,47C

BOILINGPOINT

BoilingPoint: 161,5C

CRITICALDATA

Crit.temperature: 82,6CCrit.pressure: 46,0barCrit.density: 0,162g/cm

DENSITY

VAPOURDENSITYunderstandardconditions(0C,1013mbar)Value: 0,7175kg/m

DENSITYOFLIQUIDPHASEATBOILINGPOINTValue: 0,4226kg/l

RELATIVEVAPOURDENSITYRatioofthedensitytodryairatthesametemperatureandpressureValue: 0,55

VAPOURDENSITYValue: 0,6709kg/mTemperature: 15Cat1bar

IGNITIONTEMPERATURE

Ignitiontemperature: 595CTemperatureclass: T1

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Minimumignitionenergy: 0,29mJMax.exper.safegap(MESG):

1,14mm

Explosiongroup: IIA

EXPLOSIONLIMITS

Lowerexplosionlimit:4,4vol.%29g/mUpperexplosionlimit:17vol.%113g/mMaximumexplosionpressure:8,1bar

SOLUBILITYINWATER

Concentration: 26ml/l

PARTITIONCOEFFICIENT(octanol/water)

logKow: 1,09RecommendedvalueofLOGKOWDatabank.

HAZARDOUSREACTIONS

Hazardouschemicalreactions:Riskofexplosionincontactwith:chlorinefluorinechlorinedioxidedifluorodioxidedifluorooxidedinitrogenoxideliquidoxygennitrogendioxidenitrogentrifluorideThesubstancecanreactdangerouslywith:strongoxidizingagentsacetylenebrominepentafluoridechlorinetrifluorideiodineheptafluorideThesubstanceformsanexplosivemixturewithair.

FURTHERINFORMATION

globalwarmingpotential:21ozonedepletionpotential:0

OCCUPATIONALHEALTHANDFIRSTAID

ROUTESOFEXPOSURE

MainRoutesofexposure:Themainintakepathwayformethane(M.)isviatherespiratorytract.[7748]

Respiratorytract:M.isabsorbedviathelungs.Incomparisonwithrats,pulmonaryabsorptioninhumansislessrapid,

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butthelargestproportionofthedoseretainedinhumansandanimalsisexhaledunchangedagain.[8089,454]

Skin:Uptakethroughtheskinseemstohavenotoxicologicalsignificance.[454]Basedonitsphysicochemicalproperties(gaswithpoorsolubilityinwater),M.isnotexpectedtopenetratetheskintoasignificantextent.[99999]

Gastrointestinaltract:SwallowingofM.couldonlybepossibleasarefrigeratedliquid,buteveninthiscaseabsorptioninthegastrointestinaltractisunlikelybecauseofitshighvolatility.[99999]

TOXICEFFECTS

Maintoxiceffects:Acute:Colddamage/frostbitefollowingcontactwithrefrigeratedliquidorexpandedgas[419]inhighconcentrationssuffocatingactionduetodisplacementofoxygen[454]Chronic:Nosubstancerelatedeffectsknown[99983]

Acutetoxicity:M.asagascausesnoirritationeithertotheskinnortotheeyesandairways.[7748]Nevertheless,contactwithrefrigeratedliquefiedgasorexpandesgasfromcompressedgascylinderscauseslocalundercoolingorfrostbite(symptoms:numbness,prickling,itching,inseverecasesburningsensation,stiffnessoftheaffectedarea,blistering,necrosis,gangrene).Followingcontactwithliquefiedgasorexpandedgas,theeyescanbedamagedseriouslyorevenirreversibly.[419]Withregardtosystemiceffects,M.isconsideredpracticallynontoxic.[7748]Itsmostsignificanteffectisthedisplacementofoxygenfromtherespiratoryairresultingathighconcentrations.140000ppm,(14%)causestheoxygencontentintherespiratoryairtodecreaseto18%.Atevenhigherconcentrations,theoxygenpartialpressureintherespiratoryairisfurtherreducedandtheorganismincreasinglysuffersfromoxygendeficiencydisplayingcentralnervoussymptoms,includingattentionandperformancedeficiencies.BymeansofaphysiologicallybasedmodelbasedonthesolubilitypropertiesofM.(partitioncoefficientair/oil:0.89),itwasestimatedthateffectsontheCNS(narcosis)causedbythesubstanceitselfisonlytobeexpectedatconcentrationsof300000ppmM.(30%)andabove.Basedontheserelations,M.isconsideredtobeasimpleasphyxiant.[7748,454]Inanimalexperiments,thelinebetweentheanesthetizingandthefataleffectofM.isverythin:concentrationsof87%M.ledtoanoxiceffectsformiceandnarcosisforcatswhile90%M.wasfatalforcatsandmiceduetorespiratoryarrest.[7748]Effectsforhumanswhichappearasaconsequenceofanoxygendeficiencyaregenerallyknown:reductionoftheoxygencontentto1216%increasesrespiratoryfrequencyandpulseandleadstoslightmuscleincoordinationat1014%O2emotionalupsetsandabnormalfatiguefromexertionanddisturbedrespirationwereobserved.Contentsbelow610%O2producenausea,vomiting,disturbedcoordination,collapseandpossibleunconsciousnessbelow6%O2:cramps,gasping,respiratoryarrestanddeath.Followingheavyphysicalexertion(includingincreasedneedofoxygenintheorganism)thecorrespondingsymptomsmayalreadyoccureveniftheoxygencontentintherespiratoryairhasnotyetbeenreducedtothereferredlevels.Temporarysevereoxygendeficiencyintheorganismcanadditionallyleadtodamageinvariousorgansincludingthebrainwhichmaynotbereversible.Someshortchainedhydrocarbongaseslikepropaneandbutane(frequentlyaccompanyinggasesofM.inmixtures)cancausethehearttobecomesensitizedtoadrenaline,which,especiallyunderstressfulconditions,mayresultincardiacarrest.Insituationsofoxygendeficiency,M.canpromotesuchaneffect.[419]

Chronictoxicity:TherearenofieldreportsondamagetohumansasaconsequenceofprolongedinhalationofM.[99983]HealthdamagingeffectsfromM.arealsonotexpected,providedthereisnodeficiencyofoxygen.[419]Inanexperimentonrats,amixtureof1volumeofoxygenand4volumesofM.wastoleratedlong

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termwithoutanyilleffects.[454]

Reproductivetoxicity,Mutagenicity,Carcinogenicity:Reproductivetoxicity:ThereisalackofstudiescarriedoutwithpuregradeM.[99983]Inatestonmicewhichinhaled58%fuelgas(containing85%M.andinadditionethane,butaneandpropane)duringtheirpregnancyforonehour,thefetesshowedchangesintheirbrains.[454]Mutagenicity:Nodataisavailable.[99983]Carcinogenicity:Dataisavailableneitherforhumansnorfromanimalexperiments.[99983]ThereisnosuspicionthatM.couldbecarcinogenic.[454]

BiotransformationandExcretion:ThemajorityofinhaledM.isexhaledunchanged.AsmallproportionreactstoformmethanolandfinallyCO2.[8089]

Annotation:Thisoccupationalhealthinformationwascompiledon14.09.2011.Itwillbeupdatedifnecessary.

FIRSTAID

Eyes:Followingcontactwiththeliquefiedorexpandedgas,rinsetheeyesonlyshortlyunderrunning(lukewarm)water.Donotpartlids,leavecontactlensesintheirplaceinitially.Donotattempttorewarm.Coverwithasteriledressing.Arrangemedicaltreatment.[419,99996]

Skin:Whilstprotectingyourself,relocatethecasualtyawayfromthesourceofdanger.Removecontaminatedclothingwhileprotectingyourself.Followingcontactwithliquefiedmethaneorexpandedgas,firstthawoffclothingfrozentothebodybyrinsingwithalotofcoldorlukewarmwaterandonlyafterthat,peelitoffcarefully.Alsorinseskinareaswhicharesuspectedtobefrozenfollowingcontaminationwithrefrigeratedmethane.Donotrubaffectedareasanddonotusedryheatbutcoverwithasteriledressing.Laythecasualtydowninaquietplaceandprotecthimagainsthypothermia.Arrangemedicaltreatment.[419]

Respiratorytract:Whilstprotectingyourselfremovethecasualtyfromthehazardousareaandtakehimtothefreshair.Laythecasualtydowninaquietplaceandprotecthimagainsthypothermia.Inthecaseofbreathingdifficultieshavethecasualtyinhaleoxygen.Arrangemedicaltreatment.Afterverymassiveinhalation,thefollowingmeasuresmaybecomenecessary:Ifthecasualtyisunconsciousbutbreathinglayhiminastablemanneronhisside.Inthecaseofcardiacarrest(lackofheartbeatorpulse)immediatelyapplyheartlungresuscitation.Theprotectionofthevitalfunctions(heartbeatandrespirationwithoutassistance)takespriorityovereveryotheractivity.Ifthecasualtyhasstoppedbreathinggivemouthtonoseresuscitation.Ifthisisnotpossibleusemouthtomouthresuscitation.Keephisrespiratorytractclear.[419]

Swallowing:Swallowingoftherefrigeratedliquidisunlikely.[419]Ifitneverthelesshashappened:Havethecasualtyslowlydrink12glassofwater.[454]FurthermeasuresasestablishedforRespiratorytract.Callaphysiciantothesiteoftheaccident.[99999]

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Informationforphysicians:Methanegasdoesnotirritateandisconsideredtobenontoxic,butitactsasanasphyxiantinveryhighconcentrationsduetothedisplacementofoxygen.Liquefiedgasorgasescapingfromcompressedgascylinderscancausecolddamage.[419]

Symptomsofacutepoisoning:Eyes:frostbiteduetoliquefiedorexpandedgasSkin:frostbiteduetoliquefiedorexpandedgas(numbness,prickling,itching,burning,stiffnessoftheaffectedarea,laterpossibleblistering,necrosis,gangrene)Inhalation:atconcentrationsabove140000ppm(14%)andhigher:anoxiceffects,intensifiedfollowingadditionalphysicalexertion:increasedrespiratoryfrequencyandpulse,muscleincoordination,emotionaldisturbances(euphoriaoranxiety),pronouncedsleepiness,difficultiesinbreathingfollowingextremehypoxia:nausea,vomiting,inabilitytomovefreely,collapse,unconsciousness,cramps,dangerofrespiratoryarrestfollowingsurvivalpossibleorgandamageasconsequencesofhypoxia,inparticularorganswithhighneedofoxygen(suchasCNSandheart),[419,454]possiblyalsofunctionaldisturbancesofthekidneys(asaconsequenceofrhabdomyolysis),[454]followingdirectinhalationofrefrigeratedaerosolfromcompressedgascylinders:dangerofreflectivecardiacarrestduetocoldirritationtothenervusvagus[99996]Ingestion:followingswallowingofrefrigeratedliquidpossiblecolddamageoracutecardiovascularreactions(seeabove).[99999]

Medicaladvice:Ifeyescomeintocontactwithliquefiedgasorexpandedgas,ophthalmologictreatmentisindicatedassoonasrinsinghasbeencompleted.Frostbiteontheskinorundercoolingasaconsequenceofextensivecontactcanbetreatedintheusualway.Followingmassiveinhalation,administerfreshairandoxygenassoonaspossible.Laythecasualtydowninaquietplaceandtreataccordingtosymptoms.[419,454]Afterverymassivecontact,measuresforcardiopulmonaryandcerebralresuscitationcanrapidlybecomenecessary.Althoughmethaneisnotknowntocausethehearttobemoresensitivetoadrenaline,cautionisadvisedwhencatecholaminesareadministered.[419,99999]FollowingmassiveexposureandineverycasewhendisturbancestotheCNSbecamenoticeablehospitalizationshouldbeconsideredinordertobeabletoidentifypossiblehypoxicdamage.[454]

Recommendations:Providethephysicianinformationaboutthesubstance/productandtreatmentalreadyadministered.[99999]

Annotation:Thisfirstaidinformationwascompiledon14.09.2011.Itwillbeupdatedifnecessary.

SAFEHANDLING

TECHNICALMEASURESHANDLING

Workplace:Provisionofverygoodventilationintheworkingarea.Installaceilingexhaust.Devicesfordetectingandreportingthepresenceofhazardousgasesshouldbepresent.

Equipment:Useonlyclosedapparatus.Ifdangerouspressurecanarisefromcontactwithheat,suitablesafetymeasuresandequipmentshouldbeprovided.Ifreleaseofthesubstancecannotbeprevented,thenitshouldbesuctionedoffatthepointofexit.Consideremissionlimitvalues,apurificationofwastegasesifnecessary.

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Labelcontainersandpipelinesclearly.Thereshouldbeashutoffforthelinesatasafedistance.Suitablematerials:Forcylindersandvalves:Allusualmaterials.Forseals:PolytetrafluoroethylenePTFE(Teflon)PolychlorotrifluoroethylenePCTFEPolyvinylidenefluoridePolyamidePAPolypropylenePPAcrylonitrilebutadienerubberNBRPolychloroprenerubberCRFluororubberFKM

Adviceonsaferhandling:Donotstorecylindersattheworkingarea.Donotforceopenvalve.Whenchangingbottles,alwaysinspecttheleakproofclosureofthefilledandemptybottles.Refillingortransferinstorageroomsisprohibited.Preventcylindersfromfallingover.Suckbackofwaterintothecontainermustbeprevented.Donotallowbackfeedintothecontainer.Priortofilling,ensurethatthecylindersarefreefromcontaminantsandhumidity.Thegashastobedrywhenfilled.Thatmeans,thedewpointhastobe

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Organicperoxidesandselfreactivesubstances.Combustibleandnoncombustibleacutelytoxicsubstancesofstorageclasses6.1Aand6.1B.Combustibletoxicorchronicallyactingsubstancesofstorageclass6.1C.Noncombustibletoxicorchronicallyactingsubstancesofstorageclass6.1D.Combustibleliquidsofstorageclass10.Undercertainconditionsthecollocatedstoragewiththefollowingsubstancesispermitted(FormoredetailsseeTRGS510):Aerosols(spraybottles).Ammoniumnitrateandpreparationscontainingammoniumnitrate.Combustiblecorrosivesubstancesofstorageclass8A.Combustiblesolidsofstorageclass11.ConsidertheregulationsofTRG280atcollocatedstorageofdifferentcompressedgases.Thesubstanceshouldnotbestoredwithsubstanceswithwhichhazardouschemicalreactionsarepossible.

TECHNICALMEASURESFIREANDEXPLOSIONPROTECTION

Technical,constructivemeasures:Substanceiscombustible.Firefightingequipmentmustbeavailable.Measuresrequiredbythe"ExplosionsschutzRichtlinie":Preventingtheformationofanexplosiveatmosphere(limitingandmonitoringtheconcentration,makinginert,sealing,ventilation,warningsystems,etc.)Preventingtheignitionofanexplosiveatmosphere(separationintozones,removalofsourcesofignition,explosionproofelectricalinstallation,grounding,etc.)Architecturalmeasurestolimittheeffectsofanexplosion(explosiveforceproofconstruction,releaseofexplosivepressure,explosionsuppression,etc.)Takeprecautionarymeasuresagainststaticdischarges.Earthallpartswhichcanbeelectricallycharged.Protectpartsofthesystemfromanywarmingifnecessary,providecoolingwithsprayedwater.Suitablemeasuresmustbeappliedtosealoffwastewatersystems,cableandpipeaccessways,etc.(e.g.:immersingandsandbeds).

Precautiononhandling:Thegasairmixtureisexplosive.Areawithexplosionrisk.Keepatadistancefromsourcesofignition(e.g.electricaldevices,openflames,heatsources,sparks).Observethesmokingprohibition!Absolutelynoweldingintheworkingarea.Onlyworkwithvesselsandlinesafterthesehavebeenthoroughlyrinsed.Displacementwithairisonlypermissibleunderstrictobservanceofspecialprotectivemeasures.Workdonewithfireoropenflameshouldonlybecarriedoutwithwrittenpermissioniftheriskoffireorexplosioncannotbecompletelyeliminated.Donotuseanytoolsthatcausesparks.Itmustbeavoidedthatgasesorvapourscanescapeintootherroomswheresourcesofignitionarepresent.

ORGANISATIONALMEASURES

Instructiononthehazardsandtheprotectivemeasuresusinginstructionmanual(TRGS555)arerequiredwithsignatureifjustmorethanoneminorhazardwasdetected.Instructionmustbeprovidedbeforeemploymentandthenataminimumofonceperannumthereafter.Instructionshouldincludeahintregardingthedangerofsuffocation.Anescapeandrescueplanmustbepreparedwhenthelocation,scale,anduseoftheworksitesodemand.Observetherestrictionsonjuvenileemploymentasdefinedinthe"Jugendarbeitsschutzgesetz".Onlyemployeesarepermittedtoentertheworkareas.Signpostingtothiseffectmustbedisplayed.

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PERSONALPROTECTION

Bodyprotection:Useprotectivebootswhilehandlinggascylinders.Wearflameproof,antistaticprotectiveclothing.

Respiratoryprotection:Inanemergency(e.g.:unintentionalreleaseofthesubstance)respiratoryprotectionmustbeworn.Considerthemaximumperiodforwear.Wearselfcontainedbreathingapparatus.Donotusefilterrespirator.

Eyeprotection:Sufficienteyeprotectionshouldbeworn.Whenhandlingcompressedgas,atleastglasseswithsideprotectionshouldbeworn.Whenhandlingliquidgas,chemicalsafetygogglesmustbeusedaswellasaprotectiveshield.

Handprotection:Wearleatherglovestopreventfrostbiteinjuriesfromrapidlyexpandinggaswhenhandlingpressurisedgasbottles.

Industrialhygiene:Avoidskincontactwiththeliquidphase:riskoffrostbite.Avoidinhalationofgas.Changeclothingthathasbeenincontactwithortakenupanyofthegasandairtheclothingfarfromanysourcesofignition.

DISPOSALCONSIDERATIONS

Compressedgascylinderscannormallybereturnedtothesupplier.Pressurisedcansarenonreturnableandmustbedisposedof.Donotemptypressurevesselstothepointofpressurecompensation.Markemptyvesselstoavoidconfusionwithfullones.

ACCIDENTALRELEASEMEASURES

Shutoffallsourcesofignition.Provideadequateventilation.Evacuatearea.Warnaffectedsurroundings.Wearrespiratoryprotection(seechapterPersonalProtection).Attempttostopthegasfromescaping.Otherwiseplaceleakybottlesunderasuctioningdeviceorputthemoutdoors.Usenonsparkingtools.Afterwardsventilatearea.Endangermentofwatert:Nohazardstosourcesofwateraretobefearedifreleasedintowater,drainage,sewer,ortheground.

FIREFIGHTINGMEASURES

Classesoffires:C gaseous,alsocompressedsubstances

Suitableextinguishingmedia:Water(spraynotsplash)DryextinguishingpowderCarbondioxideextinguisherwithgasnozzle

Instructions:

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Inthecaseoffireadvisefirefightersonthepresenceofgascylinders.Coolsurroundingcontainerswithwaterspray.Ifpossible,takecontaineroutofdangerouszone.Heatingcausesariseinpressure,riskofburstingandexplosion.Shutoffsourcesofignition.Onlyputoutfireifthegasflowcanbeinterrupted.Riskofexplosionfromgasaccumulationandbackfire.Useonlyexplosionprovedequipment.

Specialprotectiveequipment:Wearselfcontainedbreathingapparatus.

REGULATIONS

Classification:Flammablegases,Category1H220Gasesunderpressure,compressedgasH280

SignalWord: "Danger"

HazardStatementHphrases:H220:Extremelyflammablegas.H280:Containsgasunderpressuremayexplodeifheated.

PrecautionaryStatementPphrases:P210:Keepawayfromheat,hotsurfaces,sparks,openflamesandothersourcesofignition.Nosmoking.P377:Leakinggasfire:Donotextinguish,unlessleakcanbestoppedsafely.P381:Eliminateallignitionsourcesifsafetodoso.P403:Storeinawellventilatedplace.

Manufacturer'sspecificationbyAirLiquide

Reference:01401

ThesubstanceislistedinappendixVI,table3.1ofCLPregulation.Thegivenclassificationcandeviatefromthelistedclassification,sincethisclassificationistobecomplementedconcerningmissingordivergentdangerclassesandcategoriesfortherespectivesubstance.

Reference:99999

OLDCLASSIFICATION

F+R12

F+Extremelyflammable

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Riskphrases(Rphrases):R12 Extremelyflammable

EUclassificationaccordingtoGHSregulation,appendixVI,table3.2

Reference: 07500

COLOURCODINGOFGASCYLINDERS

Shouldercolour:Red(flammablegases)

WORKPLACELABELLINGACCORDINGTOGERMANASRA1.3

Prohibitionlabel:

Noopenflamefire,openignitionsourcesandsmokingprohibited

Noadmittanceforunauthorizedpersons

Warninglabel:

Cautiongascylinder

Cautionexplosiveatmosphere

Preceptlabel:

Usesafetygoggles

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Wearsafetyshoes

GERMANWATERHAZARDCLASS

SubstanceNo: 1343nonhazardoustowatersClassificationaccordingtotheAdministrativeRegulationofSubstancesHazardoustoWater(VwVwS)

TECHNICALINSTRUCTIONSONAIRQUALITYCONTROL(TALUFT)

Chapter5.2.5OrganicSubstances,exceptdusts.Thefollowingvalues,specifiedasoverallcarbon,areinallnotallowedtobeexceededinexhaustgas:Massflow: 0,50kg/hrorMassconc.: 50mg/mAtoldunitswithanannualmassflowtill1,5Mg/a,specifiedastotalcarbon,theemissionsinexhaustgasarenotallowedtoexceed1,5kg/h.

TRANSPORTREGULATIONS

UNNumber:1971Shippingname:Methane,compressedorNaturalgas,compressed,withahighmethanecontentHazardIdentificationNumber:23Class:2.1(FlammableGases)PackingGroup:DangerLabel:2.1

Tunnelrestrictions:Transportsintanks:passageforbiddenthroughtunnelsofcategoryB,C,DandE.Othertransports:passageforbiddenthroughtunnelsofcategoryDandE.

UNNumber:1972Shippingname:Methane,refrigerated,liquidHazardIdentificationNumber:223Class:2.1(FlammableGases)PackingGroup:DangerLabel:2.1

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Tunnelrestrictions:Transportsintanks:passageforbiddenthroughtunnelsofcategoryB,C,DandE.Othertransports:passageforbiddenthroughtunnelsofcategoryDandE.

GERMANORDINANCEOFFAILURE

Datastillrefertotheoldhazardclassification,becausethisOrdinancehasnotyetbeenconvertedtoGHS.

AnnexI,No: 11Thresholdforoperatingrangeto1sec.1Record1: 50000kgRecord2: 200000kgScope:extremelyflammable,liquifiedgases(includingliquidgas)andnaturalgas

Pleasenote:WiththeuseoftheadditionruleofStrfallVappendix1No.5(c,d,e)thesubstanceistobeassignedtooneorseveralgroupsofappendix1No.5(c,d,e),accordingtoitshazardclassifications.Forthecalculationoftheriskquotientforthissubstancetheabovementionedthresholdvalueistobeused.

RESTRICTIONSOFUSE/BANSOFUSE

DirectivesonSafetyinSchool(BGR/GUVSR2003)Activitybanforpupilstillgrade4(form)inclusive.SubstancelisttoGUVSR2004(asof11.2010)Specialsubstitutecheckrequired(substanceswithCMR,T+,E,andCwithR35).SubstancelisttoGUVSR2004(asof11.2010)

FURTHERREGULATIONS

TRGS200EinstufungundKennzeichnungvonStoffen,ZubereitungenundErzeugnissenAusgabeOktober2011

TRGS201EinstufungundKennzeichnungbeiTtigkeitenmitGefahrstoffenAusgabeOktober2011

TRGS400GefhrdungsbeurteilungfrTtigkeitenmitGefahrstoffenAusgabeDezember2010gendertundergnztSeptember2012

TRGS555BetriebsanweisungundInformationderBeschftigtenAusgabeJanuar2013

TRGS600SubstitutionAusgabeAugust2008

TRGS407TtigkeitenmitGasenGefhrdungsbeurteilungAusgabeJuni2013,berichtigtDezember2013

TRGS725/TRBS3145OrtsbeweglicheDruckgasbehlterFllen,Bereithalten,innerbetrieblicheBefrderung,EntleerenAusgabeJuni2013

TRGS726/TRBS3146OrtsfesteDruckanlagenfrGaseAusgabeApril2014

TRGS510

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LagerungvonGefahrstoffeninortsbeweglichenBehlternAusgabeJanuar2013,gendertundergnztNovember2014

TRGS500SchutzmanahmenAusgabeJanuar2008,ergnztMai2008

TRGS800BrandschutzmanahmenAusgabeDezember2010

LINKS

InternationalLimitValues

REFERENCES

Reference:00001IFA:ErfassungsundPflegehandbuchderGESTISStoffdatenbank(nichtffentlich)DataacquisitionandmaintenancemanualoftheGESTISsubstancedatabase(notpublicly)

Reference:00240E.Brandes,W.Mller"SicherheitstechnischeKenngren"Band1"BrennbareFlssigkeitenundGase"("Safetyrelatedcharacteristics"Vol.1"Combustibleliquidsandgases"),WirtschaftsverlagNW,VerlagfrneueWissenschaftGmbH,Bremerhaven,2003

Reference:002601x1derGase.PhysikalischeDatenfrWissenschaftundPraxis.Herausgeber:AIRLIQUIDEDeutschlandGmbH,Dsseldorf,1.Auflage2005

Reference:00419CHEMINFODatenbankrecherche(CHEMpendium)ab2001

Reference:00447DatenbankCHEMSAFE,Version2.6(2010),DECHEMAPTBBAM

Reference:00448DatenbankCHEMSAFE,Version2.7(2011),DECHEMAPTBBAM

Reference:00454HazardousSubstancesDataBank(HSDB)

Reference:01400Sicherheitsdatenblatt(MaterialSafetyDataSheet),AirLiquide

Reference:01401GHSSicherheitsdatenblatt(GHSMaterialSafetyDataSheet),AirLiquide

Reference:02070LOGKOWDatabank,compiledbyDr.JamesSangster,SangsterResearchLaboratories,Montreal,Canada,distributedbyTechnicalDatabaseServices(TDS),NewYork

Reference:05000KhnBirettGruppenmerkbltter

Reference:05097KhnBirettMerkbltter:97.Ergnzungslieferung03/97

Reference:05240TRGS407"TtigkeitenmitGasenGefhrdungsbeurteilung"AusgabeJuni2013,berichtigt

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Dezember2013

Reference:05300TRGS510"LagerungvonGefahrstoffeninortsbeweglichenBehltern"AusgabeJanuar2013,gendertundergnztNovember2014

Reference:06002L.Roth,U.Weller"GefhrlicheChemischeReaktionen"LoseblattsammlungmitErgnzungslieferungen("Dangerouschemicalreactions"looseleafcollectionwithsupplementdeliveries),ecomedVerlag

Reference:06501DINEN3781"KlteanlagenundWrmepumpen"AusgabeJuni2008mitBerichtigungJanuar2010

Reference:07500Verordnung(EG)Nr.1272/2008desEuropischenParlamentsunddesRatesvom16.Dezember2008berdieEinstufung,KennzeichnungundVerpackungvonStoffenundGemischen,zurnderungundAufhebungderRichtlinien67/548/EWGund1999/45/EGundzurnderungderVerordnung(EG)Nr.1907/2006(EGGHSVerordnung)

Reference:07584AllgemeineVerwaltungsvorschriftzurnderungderVerwaltungsvorschriftwassergefhrdendeStoffeVwVwSvom27.Juli2005BundesanzeigerJahrgang57,Nr.142a,vom30.Juli2005

Reference:07635AUERDATA98undBGR/GUVR190"EinsatzvonAtemschutzgerten"Ausgabe11/2009

Reference:07748AmericanConferenceofGovernmentalIndustrialHygienists"DocumentationofthethresholdlimitvaluesandbiologicalexposureindicesLoseblattsammlungmitErgnzungslieferungen

Reference:07902ADR2013EuropischesbereinkommenberdieinternationaleBefrderunggefhrlicherGteraufderStrae(ADR)

Reference:08089BinghamE.,CohrssenB.,PowellC.H.(edts.)"PattysToxicology"fithedition,JohnWiley&Sons,NewYork2001

Reference:99983LiteraturlistenStandardwerke,erweitert(Bibliographicalreferencestandardworks,extended)

Reference:99996ProjektgebundeneLiteraturlisteNr.2(ProjectrelatedbibliographicalreferenceNo2)

Reference:99999AngabedesBearbeiters(Indicationoftheeditor)

Thissubstancedatasheetwascreatedwithgreatestcare.Neverthelessnoliabilityirrespectiveoflegalbasiscanbeaccepted.

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