Mércia F. M. Bettini - Ph.D. Flavor Tec Aromas de Frutas ... PM PDF... · ICBC – INTERNATIONAL...
Transcript of Mércia F. M. Bettini - Ph.D. Flavor Tec Aromas de Frutas ... PM PDF... · ICBC – INTERNATIONAL...
ICBC – INTERNATIONAL CITRUS & BEVERAGE CONFERENCE
September, 2015
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Mércia F. M. Bettini - Ph.D.
Flavor Tec – Aromas de Frutas Ltda
Brazil
•
A – Citrus Production/ commercial
data in the last 10 years
Concentrated juice (FCOJ)
Essential peel oil (CPOO), essence oil or
oil phase (OP)
Water Phase (WP), D-Limonene (DL)
and citrus pellets (CPP).
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GLC profiles for citrus oils obtained by
Vaccum Fractionated Distillation
Tables and Flow Charts
B – Technical Data
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Source: CitrusBr 4
CROP
Total Production
of FCOJ 66º Brix
(mtons x 1000)
Industrial yields
included pulp
wash (Boxes/ ton
FCOJ)
Processed
Fruit
(mtons
x 1000)
Boxes of fruit
x 1000
2005/2006 1.161 226,42 10.725.244 262.873
2006/2007 1.357 232,69 12.883.021 315.760
2007/2008 1.377 228,49 12.836.934 314.630
2008/2009 1.141 252,88 11.772.272 288.536
2009/2010 1.009 262,52 10.807.213 264.882
2010/2011 1.044 240,58 10.247.553 251.165
2011/2012 1.500 265,36 16.240.032 398.040
2012/2013 1.445 263,54 15.537.264 380.851
2013/2014 851 282,00 9.792.000 239.982
2014/2015 1.128 240,50 10.073.120 271.284
2015/2016 889 280,15 10.158.792 249.053
AVG 252,28
MAX 1.500 282,00
MIN 851 226,42
Table 1 - FCOJ - Industrial Yields and Production Quantities
1 box = 40.8 Kg
5 Source: CitrusBr
Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available 6
CROP
Cold Pressed
orange Oil
(CPOO)
D-Limonene
(D-L)
Oil Phase
(OP)
Water
Phase (WP)
Citrus Pellets
(CPP)
2005/2006 29.972,00 19.870,00 2.083,00 6.253,10 1.238.320,30
2006/2007 35.536,60 23.051,30 2.839,00 8.580,50 1.375.028,10
2007/2008 33.528,20 24.263,10 2.442,00 9.916,50 1.387.279,30
2008/2009 31.900,40 22.962,70 2.057,60 5.872,10 1.221.663,50
2009/2010 26.227,20 18.303,30 1.559,90 4.721,80 1.045.352,30
2010/2011 24.104,80 16.400,30 1.841,60 6.959,50 1.037.981,30
2011/2012 40.863,70 27.890,20 2.979,50 10.179,30 1.604.877,20
2012/2013 27.041,50 18.628,80 1.613,40 6.545,58 1.137.502,40
*2013/2014 21.744,00 19.992,00 1.248,00 5.328,00 1.524.000,00
*2014/2015 23.549,90 24.200,30 1.626,00 9.519,50 1.138.200,00
*2015/2016 22.310,40 19.646,10 1.095,60 7.619,40 1.120.500,00
MAX 40.863,70 27.890,20 2.979,50 10.179,30 1.604.877,20
MIN 21.744,00 16.400,30 1.095,60 4.721,80 1.037.981,30
Table 2 - By Products - Production Quantities
Orange By Products (mtons)
Source: CitrusBr/ MBAgro (related to crops
2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available
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CROP
Total production
of CPOO
(mtons )
Industrial Yields
(g/box)
2005/2006 29,972.0 114.05
2006/2007 35,536.6 112.51
2007/2008 33,528.2 106.54
2008/2009 31,900.4 110.60
2009/2010 26,227.2 99.02
2010/2011 24,104.8 96.01
2011/2012 40,863.7 102.65
2012/2013 27,041.5 89.65
*2013/2014 21,744.0 90.60
*2014/2015 23,549.9 86.90
*2015/2016 22,310.4 89.60
Table 2.1 - CPOO
Production Quantities X Industrial yields
CROP
Total production
of O.P.
(mtons)
Industrial Yields
(g/box)
2005/2006 2,083.0 7.93
2006/2007 2,839.0 8.99
2007/2008 2,442.0 7.76
2008/2009 2,057.6 7.13
2009/2010 1,559.9 5.89
2010/2011 1,841.6 7.34
2011/2012 2,979.5 7.48
2012/2013 1,613.4 5.35
*2013/2014 1,248.0 5.20
*2014/2015 1,626.0 6.00
*2015/2016 1,095.6 4.40
Table 2.2 - Oil Phase (OP)
Production Quantities X Industrial yields
CROP
Total
production
of D L.
(mtons)
Industrial
Yields
(g/box)
2005/2006 19,870.0 75.61
2006/2007 23,051.3 72.98
2007/2008 24,263.1 77.10
2008/2009 22,962.7 79.61
2009/2010 18,303.3 69.10
2010/2011 16,400.3 65.32
2011/2012 27,890.2 70.06
2012/2013 18,628.8 61.76
*2013/2014 19,992.0 83.30
*2014/2015 24,200.3 89.30
*2015/2016 19,646.1 78.90
Table 2.3 - D-Limonene (D-L)
Production Quantities X Industrial yields
Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available 8
Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available 9
Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available 10
Source: CitrusBr/ MBAgro (related to crops 2005/2006 up to 2012/2013)
( * ) Estimated data - real data not available
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25.46 % 25.15%
5.89% 7.74 %
3.46 % 2.15 %
3.64 %
US
A
NE
TH
ER
LA
ND
S
UK
GE
RM
AN
Y
IND
IA
SP
AIN
CH
INA
Fig 5 - Exportation data of CPOO in 2014 (Jan to Dec)
Source: http://aliceweb.mdic.gov.br/
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14 Source: http://aliceweb.mdic.gov.br/
15 Source: http://aliceweb.mdic.gov.br/
16 Source: http://aliceweb.mdic.gov.br/
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0
1
2
3
4
5
6
7
8
92005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
US
$/K
g
Fig 9 - Market Price of Orange Oil
Citrus Oils Processing at Flavor Tec
by Vacuum Fractional Distillation
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Flavor Tec – Line Products
1 – Citrus Distillation Area:
• Citrus Aromas (FTNF)
• Folded Citrus Oils (5F, 10F, 20F)
• Folded Orange Essence Oils (5F, 10F)
• Citrus Terpenes
•Special Flavour Fractions
• Special formulations as required by the customers
2 – Juices Area:
• Fruttini - Natural Sweetened Concentrated Juices
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Fractional Distillation Industrial
Plant at Flavor Tec
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Fig. 10 - Original Orange Oil Phase
Fig. 11 - 10 Folded Orange Oil Phase, concentrated by
vacuum distillation
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CHROMATOGRAPHIC PROFILES
Fig 12 - Special light fraction of orange
oil phase by V.D.
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TABLE 6- Orange Oil Phase (O.P.) -
GLC data (mg/l)
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24
0
2
4
6
8
10
12
to
tal ald
eh
yd
es
(%)
Total yield = 7.20%
FIG 13 – LEMON / LIME OILS - TOTAL ALDEHYDES (%) X SPECIAL FRACTIONS
Lemon Lime
25
0
1
2
3
4
5
6
7
8
9
To
tal ald
eh
yd
es (
%)
Total yield = 4 - 5 %
FIG 14 – MANDARINE / CRAVO OILS - TOTAL ALDEHYDES (%) X SPECIAL FRACTIONS
Mandarine Cravo
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0
5
10
15
20
25
30
35
40
45
Cit
ral
(are
a %
)
FIG 15 – LEMON / LIME - CITRAL (AREA %) BY GLC
Lemon Lime
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YieldArea % GLC
(Citral)
Total
Aldehydes
%
YieldArea % GLC
(Citral)Total
Aldehydes %
Essential oil - 4.23 2.5 - 2.51 3.6
Fraction 1 1.44 8.72 7 1.44 37.37 7
Fraction 2 1.44 17.8 7.5 1.44 36.91 7.1
Fraction 3 1.44 42.76 7.89 1.44 28.85 7.5
Fraction 4 1.44 40.15 8.5 1.44 17.34 8
Fraction 5 1.44 30.41 10 1.44 6.2 10
Total Yield 7.2 - - 7.2 - -
Total area % GLC (Citral) - 28.85 - - 25.84 -
Total aldehydes % (Tritation) - - 8.20 - - 7.90
Lemon Lime
TABLE 07 - LEMON X LIME - ANALYTICAL DATA
Products
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Yield
Area % GLC
(Dimethyl
Antranilate)
Aldehydes % Yield Aldehydes %
Essential oil - 0.25 0.86 - 0.75
Fraction 1 1 0.47 6.5 1 6
Fraction 2 1 0.5 7 1 6.5
Fraction 3 1 0.55 7.2 1 7
Fraction 4 1 0.92 8 1 8
Fraction 5 1 1.20 8.5 - -
Total Yield 5 - - 4 -
% area total GLC (Dimethyl
Antranilate) - 0.73 - - -
Total aldehydes % - - 7.44 - 6.88
Products
Mandarine Cravo
TABLE 8 - MANDARINE X CRAVO ANALYTICAL DATA
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Fig. 17 – Lemon – Original Essential Oil
and Concetrated Fractions
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Fig. 18 – Lime – Original Essential Oil
and Concentrated Fractions
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Fig. 19 – Tangerines – Original Essential
Oils - Mandarine and Cravo
Prediction
•Brazilian crop 2015 / 2016
- 250 MM boxes for processing
- FCOJ – 890,000 mtons
- CPOO – 27,000 mtons
- O.P. – 1,930 mtons
- D-L – 18,300 mtons
- WP – 6,700 mtons
- CPP – 1,066,700 mtons
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• Fractional Distillation
-Efficient process if conducted correctly
-FTNF – Wide acceptance by sensory
evaluations as by the legislations
- The challenge – to develop and produce more
and more natural flavors.
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THANK YOU!!!
Dr Mércia F M Bettini
www.flavortec.com.br
Email: [email protected]
Phone: ++55 17 3572 1000
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