/'ISOS PAGE ONE

£UANTUM CHDlICAL CORPORATIONspirit(N(I/\ ~Y'r1DVer

USI Division

•.•.Arr-RIALSAFETY DATA SHEETSDA 40-2 190 PROOF

MSDS NO.ISSUE DATE:

13730212/28/89

WARN ING ! FI.AKHABLE. KEEP A'rfAY FROM HEAT,SPARKS, FLAME AND .ALL OTHER IGNITION SOURCES.VAPOR HAY FORM FL.AMXABLE MIXTURES 1(1ra AIR.MAY BE RARMFUL OR FATAL IF S'rlAI.J.,C)WED. Ma yirritate body tissues. Use with adequateventilation. Avoid breathing vapor. Do notget in eyes, on skin, or on clothing. Washthoroughly after handling.

EM.E.RGENCY NUMBERS:Quantum (713) 479-2873CHEMTREC (800) 424-9300

GENERAL INFORMATION:Quantum (513) 530-6917

SECTION I - IDENTIFICATION

PRODUCT: Specially Denatured Alcohol (SDA) 40-2 190 Proof

SYNONYMs: Denatured Alcohol; Denatured Ethanol

CHEMICAL FAMILY: AlcoholSECTION 11 - INGREDIENTS

COHPOSITION CAS RN. NOHINAL , PEL/TLV

Ethyl Alcohol 64-17-5 92.3 1000 ppm Flammable; Nervoussystem depressant

Water 7732-18-5 7.6 None None K."l0l0m

t-Butyl Alcohol 75-&5-0 0.1 PEL-TWA 100 ppm Flammcble; IrritantSTEL 150 ppm Narcotic

'rLV-TWA 100 ppmSTEL 150 ppm

Brucine Sulfate 4845-99-2 Less than0.1

None Poison

SECTION III - HEALTH INFORMATION

For Pure Ethyl AlcoholINHALATION: Exposure to over 1000 ppm may cause headache, drowsioess and

lassitude, loss of appetite, inability to concentrate and irritation of thethroat. No evidence of teratogenicity (birth defects) was noted followinginhalation exposure by pregnant rats of airbor.ne vapor concentrations of upto 16,000 ppm for 1 hours on days 1 through 19 of gestation. In the samestudy, pr€9nant rats exposed to 20,000 ppm showed severe narcosis; offspringof these rats did not show clear evidence of increased incidence ofabnormali.tles.

{::.3Uf.DATE: 12/28/89 1".50S PAGE T1(Q_...

1)51 MSDS !'lOo137302 SDA 40-2 190 PROOFSECTION III - HEALTH INFORMATION (CONTINUED)

INGESTION: .Can cause depression of central nervous system, nausea, vomiting,diarrhea.

Ingestion of alcoholic beverages by pregnant ••••omen is associated "'ith "fetalalcohol syndrome" in offspring. The International Agency for Research onCancer (IARe) has reported a relationship betweendrinklnq alcoholicbeverages and cancer of the oral cavity, pharynx, esophagus and liver.

EYE COH'l'AC'I': Liquid or vapor may cause irritation.

SKIN COHTAC'I': Hay cause irritation and defatting of skin on prolonged contact.

SEC'I'IONIV - OCCUPATIONAL EXPOSURE LIMITS

PEL (OSHA Permisible Exposure Limit) : Mixture. See SectionII

TLV (ACGIH Threshhold Limit Value): Mixture. See Section 11

SECT ION V - EMERGENCY FIRST AI D PROCEDURE.

FOR OVE.R£XPOSURE BY:

SWALLOWING: If victim is conscious and able to swallow, have victim drink wateror milk to dilute. Never give anything by mouth if victim is unconscious orhav ing convu Ls ions. CALL A PHYSICIAN OR POISON CONTROL CE.N1'ERDOQ:I)I.Al'El..Y.Induce vomiting only if advised by physician or Poison Control center.

INHALATION: Immediately remove victim to fresh air. If victim has stoppedbreathing give artificial respiration, preferably ~th-to-mouth. GETHEDlCAL ATTENTION IMXEDlAT'ELY.

CONTACT WITH EYES OR SKIN: I~ediately flush affected area with plenty of coolwater. Eyes should be flushed for at least 15 minutes. Remove and ~asbcontaminated clothing befcre reuse. GET MEDICAL ATTENTION IXXEDLATELY.

SECTION VI - PHYSICAL DATA

BOILING POIN1':KELTING POINT:VAPOR PRESSURE:SPECIFIC GRAVITY:VAPOR DENSITY (AIR:l):SOLUBILITY IN WATER:APPEARANCE MD COLOR:

17 3°F--173°F-44.6 mm Hg @ 68°F-0.8159 @ 60°F1. 59-CompleteClear and colorless

- for Pure Ethyl Alcohol

1SSUE DP.TE: 12/28/89 HSDS PAGE 'I'HRE.E

USI HSDS HO. 137302 SDA 40-2 190 PROOFSECil0H V-'" - FlRE. Nm EXPLOSION HAZARDS

FLASH POIHT: 60°F ASTM 0-56 (Tag Closed CUp)AUTO-IGNITION TEMPERATURE: 6SsoF-F1..A."{MABLELIMITS IH AIR, \ E':' VOL.

NFPA RATING: HEALTH ( 0 )(Does not apply to exposure

LOWER: 3.3-UPPER: 19-

::RE ( 3) REACTIVITY ( 0 ).hazards other than during a fire.)

FIRE FIGHTING PROCEDURES: (~te - Individuals should perform only those fire-fighting procedures for wi:ich they have been trained.) Use dry chemical;"alcohol" foam, or carbon dioxide; water may be ineffective, but water shouldbe used to keep fire-expcsed containers cool. If a leak or spill has notignited, use .••.ater spray 'todisperse the vapors and to protect personnelattempting to stop a leak. Water spray may be used to flush spills away fromexposures and to dilute s:ills to nonflammable mixtures (NPPA-49 1975).

UNUSUAL FIRE & EXPLOSION ~_~S: Firefighters should wear self-containedbreathing apparatus in the positive pressure mode with a full facepiece whenthere is a possibility of exposure to smoke, fumes or hazardous decompositionprooucts.

* for Pure Ethyl AlcoholSECTION VIII - REACTIVITY

STABILITY: Generally stableHAZAROOUS POLY}{E.RIZATION:~t liXelyCONDITIONS & HATERIALS TO ,WelD: Contact with acetyl chloride and a .••.ide range

of oxidizing agents may ~~2ct violently. •

P~ZARDOUS DECC~~SITICH PRC~~C:S: carbon monoxide can form on incompletecombustion.

SECT:~'" IX - E.XPLOYEE PROTECTIONCONTROL MEASURES: Handle ir. the presence of adequate ventilation.RESPIRATORY PROTECTION: Wh~=e exposure is likely to exceed acceptable criteria

use NIOSH/MSHA approved ~~spiratory protection equipment. Respirators shouldbe selected based on the :crm and concentration of contaminant In air and inaccordance with OSHA (29 CFR 1910.134).

PROTECTIVE CLOTHING: Wear <;loves and protective clothing which are imperviousto this product for the c.lration of anticipated exposure if there ispotential for skln conta~.

EYE PROTECTION: Wear safety glasses meeting the specifications of ANSIStandard Z87.1 where no contact wlth the eye is anticipated. Chemicalsafety goggles meeting the specifications of ANSI Standard Z81.1 should beworn whenever there 1s the possibility of ~plashin9 or other contact withthe eyes.

ISSUE. DATE.: 12/28/8~ ~SDS PAGE FOUR

USl MSDS HO. 137302 SDA 40-2 190 PROOFSECTION X - ENVIRONXE.N1'AL PROnC'l'IOH

EHVIRO~ENTAL PRECAUTIONS: Avoid uncontrolled releases of this material. Wherespills are possible, a comprehensive spill response plan should ~ developedand implemented.

SPILL OR LE'.AKPROCEDGRES: Wear appropriate respiratory protection andprotective clothing as described in Section IX. Contain spilled material.Transfer to secure containers. Where necessary, collect using absorbentmedia. In the event of an uncontrolled release of this material, the usershould determine if the release is reportable under applicable laws andrequlations. '

WASTE DISPOSAL: All recovered material should be packaged, LabaLed , transportedand disposed of or reclaimed in conformance with applicable laws and

. regulations and in conformance with good engineering practices.SECfIOH XI - REGUI...ATORY CONTROLS

DEPARTMENT OF TRANSPORTA'rIOH:

OOT CLASS IFICATI00 :DOT PROPER SHIPPING NAME:OTHER DOT INFORMATION:

Flammable LiquidDenatured AlcoholIdentification Ho. NA1986Emergency Response Gulde Ho. 26

OTHER REGiJL1>.TORY REQG I:REXE.NTS :

ATF Distilled Spirits ActThe use of denatured alcohol is controlled by regulations which are definedby the Bureau of ~cohol, Tobacco and Firearms in Title 27 Code of FederalRegulations.

Toxic Substance Control ActThis product is a mixture and each component is listed in the TSCA Inventoryof Chemical Substances.

SARA Title III Hazard catesories:(as defined in Sections 311/312, Title III of SARA)

Immediate/Acute HealthDelayed/Chronic HealthFire hazard