Stevenson.SECA meeting 07 - stevenson final.ppt [Read-Only] · Title: Microsoft PowerPoint -...
Transcript of Stevenson.SECA meeting 07 - stevenson final.ppt [Read-Only] · Title: Microsoft PowerPoint -...
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Update on SOFC Test Vehicle Development and Implementation
Update on SOFC Test Vehicle Development and Implementation
J.W. Stevenson, Y.S. Chou, X.D. Zhou, Z.G. Yang, G.G. Xia, K.P. Recknagle, B.J. Koeppel, M. Khaleel, and P. Singh
Pacific Northwest National LaboratoryRichland, WA 99352
August 8, 20078th Annual SECA WorkshopSan Antonio, TX
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Presentation OutlinePresentation OutlinePresentation Outline
Conclusions BackgroundObjectivesApproachTest Vehicle DesignImplementation: Vehicle Assembly & Test ResultsFuture WorkConclusionsAcknowledgements
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ConclusionsConclusionsConclusions
A stack test vehicle based on 50mm x 50mm cells (40mm x 40mm cathode) has been developed for use by PNNL and other SECA participants.Details of test vehicle components, including CAD files of the metal components, will be made available to interested SECA participants.First test is in progress (initiated 7/30/07):
800ºC with InDEC anode-supported cell, refractory glass seal, and Mn-Co spinel-coated SS441 stainless steel “interconnects”High OCV indicates effectiveness of sealsDegradation observed during isothermal testing at 0.7V at ~800 C
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BackgroundBackgroundBackgroundSECA Core Program Testing at Sub-stack Level
Materials CharacterizationXRD, SEM, EDS, TEM, XPS, TGA, DSC, PSA, dilatometry, electrical conductivity, single & dual atmosphere oxidation
Multiple Component TestsButton cell testingASR testing of interconnect/cathode contact/cathode structuresElectrical testing and leak testing of seal/interconnect and cell/seal/interconnect structures
Next Step: “Stack” Testing Advantage: Higher degree of relevance to SECA Industry Team cells/stacksChallenge:
Multiple components & phenomena, so results more difficult to interpret
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ObjectivesObjectivesObjectives
Develop SOFC stack test fixture on behalf of SECA Core Technology Program (CTP)Evaluate/validate new materials, fabrication processes, and design concepts under realistic stack conditions
Larger cell size (≥50mm x ≥50mm)Complete stack functionality (cell, seals, interconnects)Validate materials/concepts developed by PNNL and other SECA CTPparticipants
Make fixture design available to other SECA participants for implementation at their facilitiesFacilitate technology transfer from SECA CTP to SECA Industry Teams
Bridge the gap between small-scale CTP tests (e.g., button cells) and SECA industry team stacks
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ApproachApproachApproachDesign
Initial fixture design provided by LBNL, McCallister Technical Services, and Lane WilsonDesign modified by PNNL to incorporate glass seals, cell-in-frame design concepts
ImplementationParts
Cells purchased from H.C. Starck (InDEC) - 50 mm x 50 mm ASC3 anode-supported cells; LSM/YSZ cathode; ~$190 each
Other components (interconnects, cell frame, seals) fabricated at PNNL- 441 steel provided by Allegheny Technologies, Inc.
Assembly and testing at PNNLElectrochemical performance evaluation via I-V and EIS analysis Post-test analysis via optical microscopy, XRD, SEM, EDS, TEM, XPS, etcCompare stack results with results from tests on individual materials and sub-stack structures, as well as modeled results
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Initial DesignInitial DesignInitial Design
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Modeling of stack test fixtureModeling of stack test fixtureModeling of stack test fixture
• Thermal-Fluid-Electrochemical modeling analysis was performed for the 50 mm x 50 mm cell• Both serpentine and parallel rib configurations were evaluated• No pressure drop issues in either case (at 50 mm x 50 mm scale)•The analyses indicated that, in either case, stack would operate “isothermally”(<5 °C maximum temperature difference)
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Modified Design of Steel ComponentsModified Design of Steel ComponentsModified Design of Steel Components
CAD files will be fine-tuned and then made available to interested CTP participants
Cathode plate
Anode plate
Cell frame
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H.C.Starck “InDEC” CellsH.C.StarckH.C.Starck ““InDECInDEC”” CellsCells
40 mm x 40 mmCathode Dimensions
(+/- 0.2 mm)50 mm x 50 mm x 525-625 μm
Cell Dimensions
30-40 μmPorous 8YSZ/LSM –LSM Double Layer
Cathode
4-6 μmDense 8YSZElectrolyte
5-10 μmPorous NiO/YSZAnode
520-600 μmPorous NiO/YSZAnode support
Anode-supported Cells, “Type 3”
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H.C.Starck “InDEC” CellsH.C.StarckH.C.Starck ““InDECInDEC”” CellsCells
At 750ºC, 0.85 V * 325 mA/cm2 ≈ 275 mW/cm2
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Cell-in-FrameCellCell--inin--FrameFrame
1.5 mm thick, 441 steel
Cathode side is coated w/ Mn-Co Spinel
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Cathode PlateCathode PlateCathode Plate
4.5 mm thick 441 steel (coated with Mn-Co spinel)
Anode plate is similar, except has recess for Ni mesh
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Heat ExchangersHeat ExchangersHeat Exchangers
•Air & fuel heat exchangers fabricated from Inconel 600
•Cathode heat exchanger aluminized to minimize Cr volatility
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Stack Test AssemblyStack Test AssemblyStack Test Assembly
Cell-in-frameFuel heat exchanger
Air heat exchangerCathode plateAnode plate
4 Furnace T/C; 2 Stack T/C (fuel outlet; air outlet)
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Components of Initial TestComponents of Initial TestComponents of Initial Test
Perimeter Seals: Mica/Ag Hybrid Cell-to-Frame Seal: Refractory Glass
Anode plate: 441 Steel
Cathode plate: 441 Steel w/ Mn-Co Spinel Coating
Frame
Nickel Mesh
LSM-20 Contact Paste
Nickel Oxide Contact Paste
Stack Test Cross-Section: Not to Scale
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Results from Initial TestResults from Initial TestResults from Initial Test
0.0 0.1 0.2 0.3 0.4 0.5 0.6
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Area: 16 cm2
Temp: 809°CH2:H2O (450 sccm)Air (800 sccm)
Voltage Power Density
Current Density (A/cm2)
Volta
ge (V
)
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Pow
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ensi
ty (m
W/c
m2 )
• Cell-to-frame seal: Refractory glass, 950ºC
•Stack fabrication: 900ºC, 2 hours
•Stack operating temperature: ~800ºC
•High OCV indicates effective sealing
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Results from Initial Test: Power Density at 0.7 V
Results from Initial Test: Results from Initial Test: Power Density at 0.7 VPower Density at 0.7 V
0 50 100 150 200
0.0
0.1
0.2
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809ºC
SS441; YSO77x1; spinel; H-micax4 97%H2 450 sccm; air 900 sccm
Pow
er D
ensi
ty (W
/cm
2 )
Time (h)
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Future workFuture workFuture work
Complete first stack test; perform post-test analysisVariables to be evaluated in future experiments:
Seals: Refractory glass seals, “Soft” glass seals, composite glass seals, reactive air brazesCoatings: Mn-Co spinel, aluminization of interconnect/frame seal areas; NETL-Albany Ce treatmentAlloys: Alternative stainless steels, e.g., surface/bulk modified 441New cathodes & cathode contact MaterialsThermal Conditions: Isothermal, thermal cycling, imposed thermal gradients
Compare experimental results with sub-stack tests and modeled resultsExpand test capability (multiple test stands)Pursue development of multiple cell/larger cell stack test fixtures
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ConclusionsConclusionsConclusions
A stack test vehicle based on 50mm x 50mm cells (40mm x 40mm cathode) has been developed for use by PNNL and other SECA participants.Details of test vehicle components, including CAD files of the metal components, will be made available to interested SECA participants.First test is in progress (initiated 7/30/07):
800ºC with InDEC anode-supported cell, refractory glass seal, and Mn-Co spinel-coated SS441 stainless steel “interconnects”High OCV indicates effectiveness of sealsDegradation observed during isothermal testing at ~800 C
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AcknowledgementsAcknowledgements
The work summarized in this paper was funded under the U.S. Department of Energy’s Solid-State Energy Conversion Alliance (SECA) Core Technology Program.Initial fixture design provided by LBNL, Lane Wilson, and McCallister Technical ServicesJim Rakowski at Allegheny Technologies, Inc.Additional PNNL contributors: Gary Maupin, Jared Templeton, Joshua Templeton, Kerry Meinhardt, Kevin Simmons
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Results from Initial Test: Fuel Utilization
Results from Initial Test: Results from Initial Test: Fuel UtilizationFuel Utilization
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0.30
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0 5 10 15 20 25 30 35 40
Fuel Utilization (%)
Pow
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ensi
ty (W
/cm
2)