MED PART I OPTIMIZING ENERGY EFFICIENCY AND HEAT … · 10.1 Purpose of heating process water 10.2...
Transcript of MED PART I OPTIMIZING ENERGY EFFICIENCY AND HEAT … · 10.1 Purpose of heating process water 10.2...
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 1
MED PART I
OPTIMIZING ENERGY EFFICIENCY AND HEAT RECOVERY
DRYING SECTION
Model improving Energy efficiency Drying process (MED)
FdG/6th November 2009/Version: V3 Copyright FdG ©2009 All rights reserved.
ROYAL VNP
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 2
Preface
By far the largest share of energy use in a paper mill is in the drying sections.
Figures from the Dutch paper industry show that 84% of the steam consumption and
about 50% of the total energy consumption in paper production is in the drying
sections. About 87% of the energy used in these drying sections is in the form of
steam, 8,5% in the form of electricity and 4,5 % is directly used fuel (mainly gas).
The total amount of product water evaporated in the Dutch paper and board mills is
3.800.000 m3 per year. The heat consumption is between 3050 and 7000 MJ/m3
product water evaporation; this is about 400.000.000 m3 natural gas equivalent per
year.
This handout presents an overview of the possibilities to optimize the energy efficiency
and heat recovery of the drying sections in paper and board mills.
For better understanding the energy efficiency of drying processes basic knowledge
about psychrometrics and thermodynamics will be presented first.
Next the principles of drying are pointed out as well as the theoretical background
behind the energy consumption of water evaporation. This is explained with help of the
Mollier chart.
Then several possibilities to optimize the energy efficiency of the drying sections and
the heat recovery are discussed; it will be shown that:
- At higher temperatures energy consumption decreases and quality of heat in
exhaust air for heat recovery (HRC) improves
- The higher the temperature the less the energy consumption decreases
- The higher the temperature the more the quality of heat in exhaust air improves
- At higher temperatures the heat for process water, spray water and
space-heating can (almost) be covered by HRC (no fresh steam!!)
To assess the optimal process conditions and the energy saving possibilities belonging
to these conditions often extensive and time-consuming calculations are required.
To prevent this the MED-software is developed. MED is an abbreviation for Model
improving Energy efficiency Drying process.
MED calculates, for the whole product range (g/m2), the current and optimal conditions,
the possibilities for heat recovery and the energy savings.
This handout provides also the necessary knowledge for understanding MED.
Royal VNP
Postbus 731
2130AS Hoofddorp
www.vnp-online.nl
T 020 6543055
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 3
Table of contents MED part I
PART I FUNDAMENTALS OF DRYING
1 PSYCHROMETRICS
1.1 Introduction
1.2 Thermo physical properties of humid air
1.3 Relation between pressure, temperature and vapor content
2 THERMO-DYNAMICS
2.1 Introduction
2.2 Gas laws
2.3 Relation between mass, amount of substance and volume
2.4 Calculation mass flow from volume flow and temperature
2.5 Pitot-tube for measuring volume flows
2.6 Calculation enthalpy of humid air
3 FORMULA LIBRARY FOR DRYING PROCESSES
3.1 Overview formulas
3.2 Method of working humid air
3.3 Method of working combustion gas
4 MOLLIER CHART
4.1 Introduction
4.2 Explanation Mollier chart
PART II THERMAL PAPER AND BOARD DRYING
5 DRYING PRINCIPLES
5.1 Product water removal
5.2 Thermal drying
5.3 Drying periods and rates
5.4 Air systems
5.5 Supply air
5.6 Dryer hoods
5.7 Zero pressure level
5.8 Exhaust air
6 ENERGY CONSUMPTION DRYERS
6.1 System boundary heat consumption drying section
6.2 Heat and mass balance drying section
6.3 Heat consumption per kg evaporated product water
6.4 Relationship between exhaust air temperature and heat consumption
PART III HEAT RECOVERY
7 IMPROVING QUALITY OF HEAT IN EXHAUST AIR
7.1 Increasing the exhaust air temperature
7.2 Explanation heat recovery process in Mollier chart
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7.3 Improving heat recovery potential multi-cylinder dryers
7.4 Improving heat recovery potential yankee-cylinder dryers
7.5 Demonstration energy-efficiency and heat recovery potential dryers
8 SELECTION OF HEAT EXCHANGERS
8.1 Design and selection
8.2 Indicative k-values for heat-exchangers
9 HEATING SUPPLY AIR
9.1 Purpose heating supply air
9.2 Temperature efficiency air-air heat exchangers
9.3 Calculating heat consumption supply air
10 PROCESSWATER HEATING
10.1 Purpose of heating process water
10.2 Increase dry solids content after press section
10.3 Spontaneous water evaporation process water
10.4 Calculating heat consumption process water
10.5 Simplified diagram for process water
11 SPRAYWATER HEATING
11.1 Purpose of heating spray water
11.2 Calculating heat consumption spray water
12 SPACEHEATING
12.1 Heat losses buildings
12.2 Degree-days and base-temperature
12.3 Capacity heat exchangers steam and heat recovery
12.4 Heat consumption heat exchangers and heat recovery
13. DRYING PROCESS AND HEATRECOVERY IN MOLLIER CHART
13.1 Introduction
13.2 Reference and optimal situation
13.3 Power consumption fans
PART IV UTILITIES FOR DRYING
14 FANS, PUMPS AND COMPRESSORS
14.1 Introduction
14.2 Power consumption pumps
14.3 Power consumption fans
15 ENERGY CONVERSION
15.1 Introduction
15.2 Heat recovery in energy conversions 15.3 Heat savings and electricity production
ANNEXES A COMBUSTION PROCESSES
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A1 INTRODUCTION
A2 COMBUSTION EQUATION
A2.1 Components in natural gas
A2.2 Genereal combustion equation
A2.3 Combustion G-gas
B ENERGY CONVERSION
B1 INTRODUCTION
B1.1 Configuration energy conversion
B1.2 Thermal efficiency
B2 GASTURBINES
B2.1 Principle
B2.2 Types of gas-turbines
B2.3 Gas-turbine cycle
B2.4 Gas-turbine efficiency
B3 STEAMTURBINES
B3.1 Principle
B3.2 Types of steam-turbines
B3.3 Steam-turbine cycle
B3.4 Steam-turbine efficiency
B4 STEAMBOILERS
B4.1 Steam-boiler plant
B4.2 Types of steam-boilers
B4.3 Exhaust heat steam-boiler
B4.4 Efficiency steam-boilers
B5 COMBINED HEAT POWER (CHP)
B5.1 Combined heat power plant
B5.2 Combined cycle plant
C CENTRIFUGAL FANS AND PUMPS
C1 Types of centrifugal fans and compressors
C2 Power consumption centrifugal fans and compressors
C3 Relation between pressure and required power
C4 Electricity consumption supply, exhaust and circulation fans
C5 Types of pumps
C6 Head pressure
C7 Power consumption pumps
C8 Pump and system characteristic
D TABLES AND UNITS
D1 Steamtable
D2 Units
D3 Relation between θ, θdew, pvapour and wvapour
D4 Average heat capacities
D5 Mollier charts
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1. PSYCHROMETRICS
1.1 Introduction
Psychrometrics or psychrometry is the science of moist air properties and processes.
Psychrometrics describes the physical and thermodynamic properties of gas-vapor
mixtures.
Though the principles of psychrometry apply to any physical system consisting of gas-
vapor mixtures, we consider only mixtures of water vapor and dry air. These
components will be named hereafter vapor and air.
At atmospheric circumstances the mixture consists of a non-condensing component
(air) and a condensing component (vapor); the ratio between these components
depends on the circumstances of the drying process.
In this chapter we will explain how the thermo physical properties of these components
can be determined.
1.2 Thermo physical properties of humid air
There are seven physical properties of humid air applied in drying processes.
As, without elaborate study, the relation between these properties is very hard to
understand these properties are discussed in the next chapters in detail.
In this chapter we will confine to a definition of these properties:
Dry-bulb-temperature (θ in oC)
The dry bulb temperature of an air sample is determined by an ordinary thermometer,
the thermometer’s bulb being dry. The dry-bulb temperature will hereafter be indicated
as temperature.
Wet-bulb-temperature (θwet-bulb in oC)
In order to understand the concept of wet bulb temperature for air – water vapor
mixtures, it is necessary to understand two processes:
- 1st process: large amount of water is contacting an air flow (temperature air after is
lower and humidity is higher; water becomes adiabatic saturation temperature; see
fig.1)
In a well-insulated chamber entering air contacts a spray of circulating liquid water.
The air leaving the chamber is at a higher humidity and lower temperature than the
air that enters.
The evaporation of water into the air results in saturation of the air by converting
part of the enthalpy (sensible heat) of the entering air into latent heat for vaporizing
water.
Or in other words: increase in latent heat = decrease in sensible heat.
Exchange of heat between the air and the water with no loss across the chamber
walls is defined as adiabatic saturation.
The temperature of the water being circulated reaches a steady-state temperature
called adiabatic saturation temperature (θsat).
This θsat is attained when a large amount of water continuously contacts the entering
air in an adiabatic chamber.
The enthalpy balance over the chamber for 1 kg air can be expressed as follows:
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(wvapor– w”vapor) * hRo = (cp av. air+ cp av.vapor* wvapor) * (θ –θ”) (1)
Where:
θ = temperature of the air before the insulated chamber in °C
θ” = temperature of the air after the insulated chamber in °C
wvapor = absolute humidity supply air in kg water per kg dry gas (kg/kg)
w”vapor= absolute humidity exhaust air in kg water per kg dry gas (kg/kg)
cp av.air = average humid heat or specific heat of dry air (= 1,01 kJ/(kg.°C))
cp av.vapor = average humid heat or specific heat of water vapor (= 1,84 kJ/(kg.°C))
hRo = latent heat of vaporization of water (= 2501,6 kJ/kg).
Adiabatic chamber
Supply air Exhaust air
θ, wvapour θ", w"vapour
Make-up water
Fig. 1. Adiabatic saturation of a gas in an insulated chamber.
- 2nd process: small amount of water is contacting a large air flow (temperature and
humidity air after is same as before; water becomes adiabatic saturation
temperature; wet-bulb-thermometer process):
When a small amount of water is exposed to a continuous stream of entering gas
under adiabatic conditions, the water temperature decreases to a steady-state non
equilibrium temperature. As the amount of liquid is small and the air flow is big, the
temperature and humidity of the air are not modified, as is the case in the first
process, adiabatic saturation. Rather, the cooling effect of evaporating water into gas
decreases the temperature of the remaining water to what is known as the wet bulb
temperature (Twet).
For an accurate wet-bulb thermometer, “the wet-bulb temperature” and “the adiabatic
saturation temperature” are approximately equal for air-water vapor mixtures at
atmospheric temperature and pressure. In literature the wet-bulb temperature is often
indicated as “thermodynamic wet-bulb temperature”.
The thermodynamic wet-bulb temperature is the minimum temperature which may be
achieved by purely evaporative cooling of a water-wetted ventilated surface.
For a given parcel air at a known pressure and dry-bulb temperature, the
thermodynamic wet-bulb temperature corresponds to unique values of relative
humidity, dew point temperature and other properties.
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The wet-bulb-temperature is the same as the dry-bulb-temperature when the air
sample is saturated with water. For air that is less than saturated (<100 % relative
humidity), the wet-bulb temperature is lower than the dry-bulb temperature; and the
dew point temperature is less than the wet-bulb temperature.
In the paper drying process sensible heat from the drying air is converted into latent
heat in the vapor from the paper web. As long as the surface of the paper web is wet by
surface-moist or macro-capillary-moist the wet surface will obtain the wet bulb
temperature.
Cooling of the human body through perspiration is inhibited as the wet-bulb
temperature (and relative humidity) of the surrounding air increases in summer.
It is the thermodynamic wet-bulb temperature that is plotted on psychrometric charts.
In practice, this is the reading of a thermometer whose sensing bulb is covered with a
wet sock evaporating into a rapid stream of the sample air.
Isenthalpic, adiabatic or isothermal ? Isenthalpic process An isenthalpic process is a process that proceeds without any change in enthalpy. A process will be isenthalpic if there is:
- no transfer of heat to or from the surroundings, - no work done on or by the surroundings, and - no change in the kinetic energy of the fluid. In an isenthalpic process: h1 = h2
The throttling process (for instance in pressure reducing valves) is a good example of an isenthalpic process. Adiabatic process
An adiabatic process is a process in which no heat is transferred. This can happen: - if the process happens so quickly that there is no time to transfer heat, or - if the system is very well insulated from its surroundings.
In an adiabatic process: Q = 0
Adiabatic heating occurs in a diesel engine. During the compression stroke adiabatic heating will elevate the temperature sufficiently to ignite the fuel. Another example of an adiabatic process is the drying process in a closed chamber without any heat exchange to the surroundings. An adiabatic process that is reversible is also called an isentropic process. Additionally, an adiabatic process that is irreversible and extracts no work is in an isenthalpic
process. Isothermal process An opposite extreme of the adiabatic process is the isothermal process. This process allows heat transfer with the surroundings, causing the temperature to remain constant.
Dew point temperature (θdew in oC)
The dew point is the temperature to which a given parcel of moist air must be cooled,
at constant barometric pressure, to condense the water vapor in the air into water. The
point indicates, independent of temperature, the mole fraction of water vapor in the air,
and therefore determines the specific humidity (NL: absolute vochtigheid) of the air.
The dew point is a saturation point.
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The dew point is associated with relative humidity. A high relative humidity indicates
that the dew point is closer to the current air temperature. Relative humidity of 100%
indicates that the dew point is equal to the current temperature (and the air is
maximally saturated with water). When the dew point stays constant and temperature
increases, relative humidity will decrease.
Relative humidity (φ in -)
For a given parcel of air (=per unit volume) the relative humidity (φ) is the ratio of the
actual mass of the water vapor in the air to the (maximum) mass of the water vapor in
this parcel of air at the same temperature when the air is saturated with water vapor
(the saturation vapor pressure).
The ratio of the actual mass of water vapor and the maximum mass of water vapor is
the same as the actual partial vapor pressure and the maximum vapor pressure.
Absolute humidity (wvapor in g vapor / kg dry air or simply g/kg)
The absolute humidity is also known as specific humidity, moisture content, mixing
ratio, or humidity ratio (NL: absolute vochtigheid).
It is the proportion of mass of water vapor per unit mass of dry air at the given
conditions (θ, θwet-bulb ,θdew , φ etc.).
Specific enthalpy (h in kJ/kg dry air or simply kJ/kg)
The specific enthalpy , also called heat content per unit mass, is the sum of the internal
(heat) energy of the moist air in question, including the heat of the air and water vapor
within. In the approximation of ideal gases, lines of constant enthalpy are about parallel
to lines of constant θwet-bulb .
Specific volume (v in m3/kg dry air or simply m3/kg)
The specific volume, also called inverse density, is the volume per unit mass of the air
sample.
1.3 Relation between pressure, temperature and vapor content
When air is saturated with vapor, the relative humidity (φ) is 100% and the
temperature (θ), the dewpoint (θdew) and wet-bulb temperature (θwet-bulb) are the same.
Saturated air: φ = 100%; θ = θdew = θwet-bulb (2)
Furthermore there is an empirical relation between the dew point (θdew), the partial
vapor pressure (pvapor) and the specific humidity (wvapor).
This empiric relation is shown in table 1.
The atmospheric pressure (po) consists of two partial pressures: the partial pressure of
the dry air (pair) and the partial pressure of the water vapor in the air (pvapor):
po = pair + pvapor (see paragraph 2.1: gas laws).
The relation between the saturated partial pressure p”vapor and θ is shown in the
equations (3a) and (3b) and explained in box 1:
"θ237,3
"θx17,27exp.x0,611p
"
D
(3a)
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In chapter 2 (about thermo-dynamics) it will be shown that the partial vapor pressure
(pvapor) is a very important humid air condition.
For most calculations in the dryer section pvapor must be known.
Table 1 Empirical relations between θ, θdew, pvapor and wvapor
Dew
poin
t
Absolu
te
hum
idity
Part
ial vapor
pre
ssure
Rela
tive
hum
idity
Tem
pera
ture
Wet
bulb
tem
pera
ture
Enth
alp
y
Dew
poin
t
Absolu
te
hum
idity
Part
ial vapor
pre
ssure
Rela
tive
hum
idity
Tem
pera
ture
Wet
bulb
tem
pera
ture
Enth
alp
y
θdew wvapor pvapor φ θ θwet.bulb h θdew wvapor pvapor φ θ θwet.bulb h
°C g/kg kPa % °C °C J/g °C g/kg kPa % °C °C J/g
1,0 4,1 0,7 100 1,0 1,0 11 51,0 92,6 13,0 100 51,0 51,0 2922,0 4,4 0,7 100 2,0 2,0 13 52,0 98,0 13,6 100 52,0 52,0 3073,0 4,8 0,8 100 3,0 3,0 15 53,0 103,7 14,3 100 53,0 53,0 3234,0 5,1 0,8 100 4,0 4,0 17 54,0 109,8 15,0 100 54,0 54,0 3405,0 5,5 0,9 100 5,0 5,0 19 55,0 116,1 15,7 100 55,0 55,0 3586,0 5,9 0,9 100 6,0 6,0 21 56,0 123,0 16,5 100 56,0 56,0 3777,0 6,3 1,0 100 7,0 7,0 23 57,0 130,2 17,3 100 57,0 57,0 3978,0 6,7 1,1 100 8,0 8,0 25 58,0 137,9 18,2 100 58,0 58,0 4189,0 7,2 1,1 100 9,0 9,0 27 59,0 146,0 19,0 100 59,0 59,0 441
10,0 7,7 1,2 100 10,0 10,0 30 60,0 154,7 19,9 100 60,0 60,0 46511,0 8,3 1,3 100 11,0 11,0 32 61,0 163,9 20,9 100 61,0 61,0 49012,0 8,8 1,4 100 12,0 12,0 34 62,0 173,8 21,8 100 62,0 62,0 51713,0 9,5 1,5 100 13,0 13,0 37 63,0 184,3 22,9 100 63,0 63,0 54614,0 10,1 1,6 100 14,0 14,0 40 64,0 195,4 23,9 100 64,0 64,0 57615,0 10,8 1,7 100 15,0 15,0 42 65,0 207,3 25,0 100 65,0 65,0 60916,0 11,5 1,8 100 16,0 16,0 45 66,0 220,2 26,2 100 66,0 66,0 64417,0 12,3 1,9 100 17,0 17,0 48 67,0 234,0 27,3 100 67,0 67,0 68218,0 13,1 2,1 100 18,0 18,0 51 68,0 248,7 28,6 100 68,0 68,0 72219,0 14,0 2,2 100 19,0 19,0 55 69,0 264,4 29,8 100 69,0 69,0 76520,0 14,9 2,3 100 20,0 20,0 58 70,0 281,5 31,2 100 70,0 70,0 81121,0 15,9 2,5 100 21,0 21,0 62 71,0 299,8 32,5 100 71,0 71,0 86122,0 16,9 2,6 100 22,0 22,0 65 72,0 319,7 34,0 100 72,0 72,0 91523,0 18,0 2,8 100 23,0 23,0 69 73,0 341,3 35,4 100 73,0 73,0 97324,0 19,1 3,0 100 24,0 24,0 73 74,0 364,7 37,0 100 74,0 74,0 1.03725,0 20,3 3,2 100 25,0 25,0 77 75,0 390,2 38,6 100 75,0 75,0 1.10626,0 21,6 3,4 100 26,0 26,0 81 76,0 417,9 40,2 100 76,0 76,0 1.18127,0 23,0 3,6 100 27,0 27,0 86 77,0 448,2 41,9 100 77,0 77,0 1.26228,0 24,4 3,8 100 28,0 28,0 91 78,0 480,5 43,7 100 78,0 78,0 1.35029,0 26,0 4,0 100 29,0 29,0 96 79,0 518,6 45,5 100 79,0 79,0 1.45230,0 27,6 4,2 100 30,0 30,0 101 80,0 559,3 47,4 100 80,0 80,0 1.56231,0 29,3 4,5 100 31,0 31,0 106 81,0 604,7 49,3 100 81,0 81,0 1.68532,0 31,1 4,8 100 32,0 32,0 112 82,0 655,7 51,4 100 82,0 82,0 1.82233,0 32,9 5,0 100 33,0 33,0 118 83,0 713,2 53,4 100 83,0 83,0 1.97734,0 35,0 5,3 100 34,0 34,0 124 84,0 777,8 55,6 100 84,0 84,0 2.15135,0 37,1 5,6 100 35,0 35,0 130 85,0 852,4 57,8 100 85,0 85,0 2.35236,0 39,3 5,9 100 36,0 36,0 137 86,0 937,7 60,1 100 86,0 86,0 2.58137,0 41,7 6,3 100 37,0 37,0 144 87,0 1.036,4 62,5 100 87,0 87,0 2.84638,0 44,1 6,6 100 38,0 38,0 152 88,0 1.152,4 65,0 100 88,0 88,0 3.15839,0 46,8 7,0 100 39,0 39,0 160 89,0 1.290,7 67,5 100 89,0 89,0 3.53040,0 49,5 7,4 100 40,0 40,0 168 90,0 1.458,7 70,1 100 90,0 90,0 3.98241,0 52,5 7,8 100 41,0 41,0 177 91,0 1.665,9 72,8 100 91,0 91,0 4.53842,0 55,6 8,2 100 42,0 42,0 186 92,0 1.927,2 75,6 100 92,0 92,0 5.24043,0 58,8 8,6 100 43,0 43,0 195 93,0 2.268,3 78,5 100 93,0 93,0 6.15744,0 62,3 9,5 100 44,0 44,0 205 94,0 2.731,7 81,5 100 94,0 94,0 7.40145,0 65,9 9,6 100 45,0 45,0 216 95,0 3.396,1 84,6 100 95,0 95,0 9.18546,0 69,8 10,1 100 46,0 46,0 227 96,0 4.426,7 87,7 100 96,0 96,0 11.95347,0 73,9 10,6 100 47,0 47,0 239 97,0 6.248,4 91,0 100 97,0 97,0 16.84448,0 78,1 11,2 100 48,0 48,0 251 98,0 10.303,1 94,3 100 98,0 98,0 27.73149,0 82,7 11,7 100 49,0 49,0 264 99,0 27.145,9 97,8 100 99,0 99,0 72.95350,0 87,5 12,3 100 50,0 50,0 277 100,0 - 101,4 100 100,0 100,0 -
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 11
and
ln (1,639 x "
Dp ) = "3,237
"27,17
x (3b)
Box 1 Relation pressure, temperature and vapor content
60 isotherm p"vapour
θ"
50 Vapour
40
30
20
Water
10
7
0
1 5 10 15 20
Vapour pressure kPa
Tem
pera
ture
oC
Formula for the relation between the saturated vapor pressure (p”vapor) and the
saturated temperature (θ”); valid for temperatures between 0 and 100 oC:
"θ237,3
"θx17,27exp.x0,611p
"
vapor
(3a)
ln (1,639 x "
vaporp ) = "3,237
"27,17
x (3b)
Question 1:
What happens when vapor (pvapor = 1 kPa, θ =60 oC), in a parcel void of air, is
compressed ?
Answer:
When water vapor is compressed slowly (isothermal process) the rise of the pressure
will be limited. At a certain pressure the vapor will start to condense. Further
isothermal compression will result in more condensation of vapor till all vapor is
condensed.
The pressure stays constant during the condensation process. This socalled
saturated pressure depends on the temperature of the system
Question 2:
How much vapor can be absorbed in air when at atmospheric pressure the
temperature is more than 100 oC ?
Question 3:
The temperature of the humid air is 70 oC and the partial vapor pressure is 20 kPA.
What is the dew point temperature ?
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2 THERMO-DYNAMICS
2.1 Introduction
Thermodynamics is the study of the conversion of energy into work and heat and its
relation to variables such as temperature, volume and pressure. Historically, thermo-
dynamics developed out of need to increase the efficiency of early steam engines.
In our calculations thermodynamic processes are defined as systems that move from
state 1 to state 2, where the state number is denoted by subscript.
The relationships between the pressure, volume and temperature of a sample of gas are
set down in gas laws.
2.2 Gas laws
The early gas laws were developed at the end of the eighteenth century, when
scientists began to realize that relationships between the pressure, volume and
temperature of a sample of gas could be obtained which could be applied to all gases.
Gases behave in a similar way over a wide variety of conditions because to a good
approximation they all have molecules which are widely spaced.
The earlier gas laws (Boyle, Gay-Lussac etc) are now considered as special cases of the
Ideal gas equation or General gas law.
For all gas laws the basic assumption is that the gas is an “ideal gas”. This means that
both molecular size and intermolecular attractions are neglected.
The ideal gas law is most accurate for mono atomic gases at high temperatures and low
pressures. The neglect of molecular size becomes less important for larger volumes,
i.e., for lower pressures. The relative importance of intermolecular attractions
diminishes with increasing temperatures.
Boyle’s law
Boyle’s Law shows that for an ideal process at constant temperature the product of
pressure and volume is always constant.
p.V =constant (5)
Where:
p = the pressure of the gas, N/m2
V = the volume of the gas, m3
The product is: N/m2 x m3 = Nm = J
When air is compressed and the conditions before compression are p1,V1 and after p2,V2
the equation will be:
p1 x V1 = p2 x V2
In case of compression this equation is only correct when during compression heat is
removed because the temperature should be constant.
Gay-Lussac’s law
Gay-Lussac’s Law shows that for an ideal process at constant volume the quotient of
pressure and absolute temperature is always constant.
p/T =constant (6)
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Where:
p = the pressure of the gas, N/m2
T = absolute temperature, K
Note: 0 oC = 273 K; 20 oC = (20 +273) K
Avogadro’s Law
Avogadro’s Law states that the volume occupied by an ideal gas is proportional to the
amount of moles (or molecules) present in the container.
This gives rise to the molar volume of a gas, which at standard conditions for
temperature and pressure is 22,4 m3.
Note: standard conditions for temperature and pressure are 273 K (= 0 oC) and
101,325 kPa (=101.325 Pa = 1,01325 bar = 1 atm.)
Dalton’s Law
Dalton’s Law states that the the pressure of a mixture of gases simply is the sum of the
partial pressures of the individual components.
Dalton’s Law is as follows:
ptotal = p1 + p2 + p3 + ……. Pn (7)
Where:
ptotal = total pressure of the gas mixture
p…. = partial pressure of each component in the mixture
For drying processes at standard pressure conditions Dalton’s Law is as follows:
po = pair + pvapor
Where:
po = 101,325 kPa (“standard” total pressure of the atmosphere)
pair = partial pressure of the dry air component in the mixture
pvapor = partial pressure of the water vapor component in the mixture
Dalton’s law is not exactly followed by real gases. Those deviations are considerably
large at high pressures. In such conditions, the volume occupied by the molecules can
become significant compared to the free space between them.
Combined and ideal gas laws
The combined gas law or general gas equation (NL: Algemene gaswet) is formed by the
combination of the laws of Boyle, Gay-Lussac and Avogadro.
The law shows that the state of an amount of gas is determined by its pressure, volume
and temperature.
The modern form of the equation is:
p.V = n.R.T (kPa.m3=(kN/m2).m3=kNm=kJ) (8)
Where:
p = the absolute pressure of the gas, in kPa
V = the volume of the gas, in m3
n = amount of substance in kmol
R = the universal gas law constant of 8,3145 m3·kPa/(kmol·K)
T = the absolute temperature of the gas, in K
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 14
This law has the following important consequences:
- If temperature and pressure are kept constant, then the volume of the gas is
directly proportional to the number of molecules of gas.
- If the temperature and volume remain constant, then the pressure of the gas
changes is directly proportional to the number of molecules of gas present.
- If the number of gas molecules and the temperature remain constant, then the
pressure is inversely proportional to the volume.
- If the temperature changes and the number of gas molecules are kept constant,
then either pressure or volume (or both) will change in direct proportion to the
temperature.
The law is the equation of state of a hypothetical ideal gas.
It is a good approximation to the behaviour of many gases under many conditions,
although it has several limitations.
As the amount of substance could be given in mass instead of moles, sometimes an
alternative form of the ideal gas law is useful:
m = n x M (9)
Where:
m = mass in kg
n = number of moles
M = molar mass in kg/kmol
2.3 Relation between mass, amount of substance and volume
This relation is shown in box 2.
In box 3 an exercise for this relation is depicted.
2.4 Calculation mass flow from volume flow and temperature
During field measurements usually volume flows and temperatures are laid down.
In box 4 is shown how, with help of the gas laws, the mass of these flows is calculated.
To calculate the mass of humid air the vapor content of the flow should be known.
Calculations for determining the vapor content of a flow are shown in chapter 3.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 15
Box 2 Relation between mass, amount of substance and volume
Name Symbol Unit Explanation
Mass m kg
Amount of substance n kmol
Volume V m3
Normal volume Vo m3o p = 101,325 kPa; θ = 0 oC
Molar volume VM m3o VM = 22,4 m3
o
Molar mass M kg/kmol See explanation
Pressure p kPa 100 kPa = 1 bar
Normal pressure po kPa po = 101,325 kPa
Temperature θ oC
Temperature T K T = (θ + 273) K
Density ρ kg/m3o ρ = M/VM
Universal gas constant R kJ/(kmol.K) R = 8,3145 kJ/(kmol.K)
see explanation
Explanation:
Molar mass
Molar mass = atomic or molecular weight x molar mass constant
Molar mass constant = 1 kg/kmol
Atomic weight: H=1, C=12, N=14, O=16
Molar mass:
Water vapor H2O: M = (2 x1 +16) x 1 = 18 kg/kmol (= 22,4 m3o)
Carbon-di-oxide CO2: M = (12 + 2 x 16) x 1 = 44 kg/kmol (= 22,4 m3o)
Nitrogen N2: M = (2 x 14) x 1 = 28 kg/kmol (= 22,4 m3o)
Oxigen O2: M = (2 x 16) x 1 = 32 kg/kmol (= 22,4 m3o)
Example: 1 kmol O2 = 22,4 m3o = 32 kg; ρ = (32/22,4=) 1,43 kg/m3
o
Universal gas constant
Calculated for 1 kmol gas:
po = standard pressure (= 101,325 kPa);
VM = molar volume (= 22,4 m3
o /kmol);
To = 273,15 K (= 0oC);
R = universal gas constant.
R = po x VM / To (kJ/(kmol.K) (12a)
(kPa x m3o/kmol/K = kN/m2 x m3/kmol/K = kN.m/(kmol.K)= kJ/(kmol.K)
R = (101,325 x 22,4) / 273,15 = 8,3145 kJ/(kmol.K) (12b)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 16
Box 2 Relation between mass, amount of substance and volume
Name Symbol Unit Explanation
Mass m kg
Amount of substance n kmol
Volume V m3
Normal volume Vo m3o p = 101,325 kPa, θ = 0 oC
Molar volume VM m3o VM = 22,4 m3
o
Molar mass M kg/kmol See explanation
Pressure p kPA 100 kPa = 1 bar
Normal pressure po kPa po = 101,325 kPa
Temperature θ oC
Temperature T K T = (θ + 273) K
Density ρ kg/m3o ρ = M/VM
Universal gas constant R kJ/(kmol·
K)
R =8,3145 kJ/(kmol·K)
See explanation
Explanation:
Molar mass
Molar mass = atomic or molecular weight x molar mass constant
Molar mass constant = 1 kg/kmol
Atomic weight: H=1, C=12, N=14, O=16
Molar mass:
Water vapor H2O: M = (2 x1 +16) x 1 = 18 kg/kmol (= 22,4 m3o)
Carbon-di-oxide CO2: M = (12 + 2 x 16) x 1 = 44 kg/kmol (= 22,4 m3o)
Nitrogen N2: M = (2 x 14) x 1 = 28 kg/kmol (= 22,4 m3o)
Oxigen O2: M = (2 x 16) x 1 = 32 kg/kmol (= 22,4 m3o)
Example: 1 kmol O2 = 22,4 m3o = 32 kg; ρ = (32/22,4=) 1,43 kg/m3
o
Universal gas constant
Calculated for 1 kmol gas:
po = standard pressure (= 101,325 kPa);
VM = molar volume (= 22,4 m3
o /kmol);
To = 273,15 K (= 0oC);
R = universal gas constant.
R = po x VM / To (kJ/(kmol.K) (12a)
(kPa x m3o/kmol/K = kN/m2 x m3/kmol/K = kN.m/(kmol.K)= kJ/(kmol.K)
R = (101,325 x 22,4) / 273,15 = 8,3145 kJ/(kmol.K) (12b)
Box 3 Exercise 1: Relation between mass, amount substance & volume
Given:
In box 2 the relation between mass, amount of substance and volume is shown.
Question:
Complete the table in this box and answer the questions.
Answer:
Gas M(kg/kmol) VM(m3o / kmol) ρ(kg/m3
o)
Water vapor H20
Air
(79%N2&21% O2)
Methane CH4
Propane C3H8
Butane
C4H10
2x1+16 = 18
0,79x2x14+0,21x
2x16 = 28,84
1x12+4x1 = 16
3x12+8x1 = 44
4x12+10x1 = 58
22,4
22,4
22,4
22,4
22,4
18/22,4=0,804
28,84:22,4=1,2875
16:22,4 = 0,714
44:22,4 = 1,964
58:22,4 = 2,589
The combustion equation for methane (CH4) and oxygen (O2) is:
1 CH4 + 2 O2 1 CO2 + 2H2O
How many kg water vapor will be formed during combustion of 1 m3o methane and
how much combustion air is required ?
1 kmolCH4 + 2 kmol O2 1 kmol CO2 + 2 kmol H2O
22,4m3CH4+44,8m3O2 22,4m3CO2+44,8m3H2O
16 kg CH4+64 kg O2 44 kg CO2+36 kg H2O
Vapor formed during the combustion of 1 m3o methane:
36kg H2O:22,4m3CH4=1,61kgH2O/m3CH4
Air required for the combustion of 1 m3o methane:
2m3O2/m3CH4x
zuurstofm
luchtm3
3
21,0
1= 9,52m3 air/m3CH4
Why is it not allowed to park your LPG-car in a “closed” building ?
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 17
Box 4 Calculation mass flows from volume flow and temp
(1) Universal gas constant for 1 kmol gas:
K).kJ/(kmol8,314273,15
22,4x101,325
T
V.pR
o
mo (12)
(2) General gas law (amount of substance = n kmol gas):
kJ/KT
V.pR.n (8)
(3) Mass m (kg) of n (kmol) with molar mass M (kg/kmol):
m = n . M. (9)
(4) Formula (2) substituted in formula (3):
kg/sT
V.p
R
Mm (13a)
(5) Air flow with atmospheric conditions: only V and T should be measured
kg/sT
V. 101,325
8,314
29m (13b)
(6) Dalton:
po = pG + pD kPa (7)
For drying processes:
po = atmospheric pressure (101,235 kPa)
pair = partial pressure non-condensable components (dry air)
pvapor = partial pressure condensable components (water vapor)
(7) Mass vapor flow (mvapor):
T
V.p
8,314
18m
vapour
vapour (13c)
(8) Mass dry air flow (mair):
T
V.p
8,314
28,84m air
air (13d)
The question is how to calculate pvapor en pair
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 18
2.5 Pitot-tube for measurering volume flows
A pitot tube is a pressure meter that measures head according Bernoulli ‘s law:
h = v2 / 2g
Where:
h = head in m
v = gas velocity in m/s
g = gravity (9,81 m/s2)
The pitot-tube measures ∆p over the connections:
∆p (N/m2) = ρ (kg/m3) x g (m/s2) x h (m)
Where:
∆p = pressure difference over the connections in N/m2
ρ = specific density in kg/m3
Note: unit Newton (N) is kg.m/s2
Substitution of (formule 1) in (formule 2):
v = (2 * ∆p / ρ) )^0,5
Substitution of formule 19 from table 3:
v =(2*∆p/((28,84*pdry air+18*pvapor)/(8,314*(273,15+θdry bulb))))^0,5 (17)
2.6 Calculation enthalpy of humid air
In thermodynamics the enthalpy (denoted as H, or specific enthalpy denoted as h) is
a thermodynamic property used to calculate the heat transfer during a process taking
place under constant pressure (isobaric process).
Enthalpy H is an arbitrary concept but the enthalpy change ΔH is more useful because it
is equal to the change in the internal energy of the system, plus the work that the
system has done on its surroundings.
The specific enthalpy may be defined by:
h = u + p.V (10)
Where:
h = specific enthalpy (kJ/kg)
u = internal energy (kJ/kg)
p = pressure (kPa)
V = volume in (m3)
For gasses h = 0 when the temperature (θ) of that gas is 0 oC.
Humid air is a mixture of dry air and water vapor.
The enthalpy of humid air includes the enthalpy of the dry air (= sensible heat) and
the enthalpy of the vapor in the air (= latent heat)
Specific enthalpy of humid air is defined as the total enthalpy of the mixture of dry air
and vapor per kg dry air:
h = cp av.airx θ + wvapor x (hRo+cp av.vapor x θ) (kJ/kg (dry!) air) (11)
Where:
h = specific enthalpy of humid air (kJ/kg dry air)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 19
cp av.air = average specific heat of dry air (kJ/(kg.oC); see table 2
θ = temperature (oC)
wvapor = absolute humidity supply air in kg water per kg dry gas (kg/kg)
hRo = heat of evaporation (= 2501,6 kJ/kg)
cp av.vapor = average specific heat of vapor (kJ/(kg.oC); see table 2
We distinguish specific heat capacity at constant pressure (cp) and average specific heat
capacity at constant pressure (cp av). Both are heat capacities for constant pressures.
The specific heat capacity at constant pressure (cp) is not a fixed constant and varies
somewhat depending on the temperature. For air, for instance, this “true” specific heat
capacity is 1,01 at 0 oC and about 1,30 at 2000 oC.
To simplify calculations the average specific heat capacity (cp av) is introduced.
By definition cp av represents the average quantity of heat needed to raise 1 kg of gas
through 1 oC in the range between 0 and θ oC. For air, for instance, this average
specific heat capacity is 1,01 at 0 oC and about 1,16 for the temperature range 0 –
2000 oC.
In box 5 is shown how the enthalpy of humid air is calculated. Also some average
specific heat capacities of some gasses are graphically shown.
Table 2 Average specific heat
'Cp.av. in kJ/(kg.oC) of components in air or flue gas
temp
range °CCO2 Ar O2 N2 H2O Dry air
0 0,819 0,519 0,917 1,041 1,83 1,006
0 - 100 0,870 0,519 0,923 1,041 1,84 1,009
0 - 200 0,915 0,519 0,935 1,045 1,87 1,012
0 - 300 0,953 0,519 0,950 1,048 1,89 1,019
0 - 400 0,989 0,519 0,964 1,055 1,92 1,028
0 - 500 1,021 0,519 0,978 1,065 1,95 1,038
0 - 600 1,046 0,519 0,993 1,075 1,98 1,048
0 - 700 1,072 0,519 1,005 1,087 2,01 1,061
0 - 800 1,092 0,519 1,017 1,098 2,04 1,071
0 - 900 1,112 0,519 1,029 1,109 2,07 1,080
0 - 1000 1,129 0,519 1,037 1,118 2,11 1,090
0 - 1100 1,144 0,519 1,045 1,129 2,14 1,100
0 - 1200 1,158 0,519 1,052 1,139 2,17 1,109
0 - 1300 1,170 0,519 1,060 1,145 2,20 1,118
0 - 1400 1,181 0,519 1,066 1,152 2,23 1,125
0 - 1500 1,192 0,519 1,072 1,160 2,26 1,132
0 - 1600 1,203 0,519 1,078 1,168 2,29 1,139
0 - 1800 1,219 0,519 1,090 1,182 2,34 1,153
0 - 2000 1,234 0,519 1,101 1,192 2,39 1,162
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 20
Box 5 Calculation enthalpy of humid air
Average specific heat gasses and water vapor
(H2O*=water vapor as ideal gas en H2O** water vapor is nota n ideal gas)
Dry gas (sensible heat) Water vapor (latent heat)
Average specific heat dry gas in kJ/(kg.K)
absolute humidity in kg water per kg dry gas (kg/kg)
Heat of evaporation water at 0oC (=2501,6 kJ/kg)
Average specific heat water vapor
h = cp av.air . θ + wvapor . (hRo + cp av.vapor . θ ) kJ/kg (dry) gas (11)
Avera
ge s
pecific
heat
dry
gas in kJ/
(kg.K
)
Temperature θ in oC
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 21
3 FORMULA LIBRARY FOR DRYING PROCESSES
3.1 Overview formulas
In box 6 formulas for relative and absolute humidity are derived from the definitions
and formulas in the chapters psychrometrics and thermodynamics.
In table 3 a “Formula library for calculating physical properties of drying air” is depicted.
The formulas are derived from the formulas in chapter 2 and 3. The polynom formulas,
derived from table 1, are not depicted in the table.
As an example the formula for deriving θdew from wvapor shows as follows: θdew=ALS(W(vapor)>4427;1,3169*LN(W(vapor))+85,626;ALS(W(vapor)>1928;4,4688* LN(W(vapor))+ 58,565;ALS(W(vapor)>1153;7,4765*LN(W(vapor))+35,491;ALS(W(vapor)>605;10,644*LN(W(vapor))+13,081;ALS(W(vapor)>265;14,287*LN(W(vapor))-10,328; ALS(W(vapor)> 155; 0,00000000000137* W(vapor)^6-0,0000000019017* W(vapor)^5+ 0,00000109041874* W(vapor)^4-0,00032957623934* W(vapor)^3 +0,05507945136945* W(vapor)^2-4,70562681251105* W(vapor)+215,243754649645; ALS(W(vapor)>38; -0,00000000000476* W(vapor)^6 + 0,0000000033553* W(vapor)^5 - 0,00000099856273* W(vapor)^4 + 0,00016432944202* W(vapor)^3 – 0,01669988421594* W(vapor)^2 + 1,18909495672254* W(vapor) + 7,17981604351348;-0,00000011228793*W(vapor)^6 + 0,00001583312096* W(vapor)^5 – 0,00091311105523* W(vapor)^4 + 0,02800484300993* W(vapor)^3 – 0,50553648368732* W(vapor)^2 + 6,14499909516863* W(vapor) – 17,3718810425193)))))))
3.2 Method of working humid air
In table 4 the method of working for calculating air conditions and mixing flows is shown.
Table 4 Method of working calculating humid air conditions and mixing flow
a b c d e f g h i j k l m n o p q r s t u v w
Calculating flow Formulas for calculations air with watervapour
- h b/Ф A ∆p k v V po θdew θdry bulb wvapour h φ pvapour"θwet bulb pdry air mdry air mvapour mwet air H cpm dry air cpm vapour
- m m m2 Pa - m/s m3/s kPa oC oC g/kg kJ/kg % kPa °C kPa kg/s kg/s kg/s kJ/s kJ/(kg.K)kJ/(kg.K)
Step 1: dimensions of the ducts, air velocities, dry- and wet-blub temperatures are measured are measured
1 1,68 3,92 3,14 101,3 47 31,4 1,01 1,84
2 0,66 0,66 2,15 101,3 128 63,4 1,01 1,84
Step 2: copy the corresponding formulas from the library and paste them at the right place
1 1,68 3,92 6,59 3,14 20,7 101,3 26,7 47 22 106 32,3 3,5 31,4 97,8 21,9 0,49 22,4 2312 1,01 1,84
2 0,66 0,66 0,44 2,15 1,00 2,30 1,00 101,3 58,8 128 143 521 7,2 18,9 63,4 82,5 0,7 0,1 0,8 372 1,01 1,84
Step 3: flows 1 and 2 are mixed; flow 3 is sum mdry air, sum mvapour and sum H
1 21,9 0,5 2312
2 0,7 0,1 372
3 22,6 0,6 2684
Step 4: calculate h = H/mdry air and wvapour = mvapour*1000/mdry air
1
2
3 26,1 119 22,6 0,6 2684
Step 5: copy the corresponding formulas from the library and paste them at the right place
1
2 *3 101,3 29,1 50,6 26,1 119 31,7 4,02 33,4 97,3 22,6 0,6 23,2 2684 1,01 1,84
Values in white cells are input data !!; * The validity of the formula for wet bulb temperature is limited, check mollierdiagram
Specific
heat
vapour
Mass f
low
dry a
ir
Mass f
low
vapour
Mass f
low
wet
air
Enth
alp
y
Specific
heat
dry a
ir
Enth
alp
y
Rela
tive h
um
idity
Partial vap.
Pressure
Wet
bulb
tem
peratu
re
*
Partial dry a
ir
pressure
Flo
w n
um
ber
Hig
ht
duct
Wid
th/dia
met
er d
uct
Cross-section
duct
pressure-
diffe
rence
pitot-
tube
calibr.-
facto
r
pitot-
tube
gas-velo
city
Volu
me f
low
Tota
l
pressure
Dew
poin
t
Dry b
ulb
tem
peratu
re
Absolu
te
hum
idity
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 22
3.3 Method of working combustion gas
In table 4 of chapter 3 the method of working for calculating air conditions and mixing
flows is shown.
These flows are a mixture of only two components: dry air and vapor. Although dry air
consists mainly of two components, N2 and O2, its composition will not change. In
drying processes only the amount of vapor (H2O) per kg dry air will change.
In fact the calculations for humid air only relate to the components dry air and vapor.
Only these components need to be considered in calculations on drying processes.
Calculations on combustion processes are more complicated: CH4 + 2O2 -- 2H2O + CO2
This means that during combustion the chemical reactions will change the composition
of the gas; the amount of O2 will decrease and the amounts of O2 and H2O will increase.
For calculations in drying processes when combustion products are involved four
components need to be considered: N2, O2, H2O and CO2.
In annex A the method of working for combustion gases is explained.
Box 6 Formulas for relative and absolute humidity
Relative humidity (φ in -)
For a given parcel of air the relative humidity (φ) is the ratio of the actual mass of the
water vapor in the air (mvapor in kg) to the (maximum) mass of the water vapor
(m”vapor in kg) in the same parcel of air at the same temperature when the air is
saturated with water vapor.
Note that relatve humidity is per unit volume.
In “Papermaking Part 2, Drying” the relative humidity is defined per unit mass as φ =
mvapor / mdry air; this is not correct.
φ = (mvapor / m”vapor) x 100 % (14)
With formula (13c) can be derived :
φ = (pvapor / p”vapor) x 100 % (15)
When θ is measured p”vapor can be laid down with formula (3a),
When φ is measured pvapor can be calculated.
Absolute humidity
The absolute humidity is also known as specific humidity, moisture content, mixing
ratio, or humidity ratio.
Absolute humidity is the proportion of mass of water vapor per unit mass of dry air
(wvapor in kg/kg (dry!) air) at the given conditions (θ, θwet-bulb ,θdew , φ etc.).
wvapor = (mvapor / mdry air) kg vapor/kg dry air (16)
Formula (17) is derived from formulas (13c), (13d) and (15)
wvapor = ''
vapouro
''
vapour
dryair
vapour
pp
p
M
M
kg vapor / kg drygas (17)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 23
a b c d e f g h i j k l m n o p q r s t u v w
Calculating flow Formulas for calculations air with watervapour
= value to be calculated from and
Values in white cells are input data !!
Validity formula wet bulb temp. is limited, check mollierdiagram
- h b/Ф A ∆p k v V po θdew θdry bulb wvapour h φ pvapour"
θwet bulb pdry air mdry airmvapour mwet air H cpm dry air cpm vapour Mdry air=28,84 kg/kmol; Mvapour=18,0 kg/kmol; T= 273,15 K (=0oC); R=8,314 kJ/(kmol.K)
- m m m2 Pa - m/s m3/s kPa oC oC g/kg kJ/kg % kPa °C kPa kg/s kg/s kg/s kJ/s kJ/(kg.K)kJ/(kg.K)
1 58,43 18,51 θdew = ln((1,639*pvapour)*(237,3+θdew)/17,27)
2 58,42 141,3 θdew (kPa) = polynom based on wvapour
3 58,42 79,9 141,3 455 θ = (h - 0,001*wvapour*(2501,6+1,85*θ))/1,01
4 θsupply air out = 0,01*ηθ*(θexhaust air in-θsupply air in) +θsupply air in
5 58,42 139,6 wvapour(g/kg)=1000*(18/28,84)*((0,611*exp(1)^((17,27*θdew))))/(237,3+θdew))/(101,325-(0,611*exp((17,27*θdew))))/(237,3+θdew))))))
6 151,4 455 air is saturated with vapour !! wvapour(g/kg)= polynom based on h when air is saturated with vapour
7 80,0 141,3 455 h (J/g) = 1,01*θ + 0,001*wvapour*(2501,6+1,85*θ)
8 58,42 80,0 39,0 φ (%) = ((0,611*exp(1)^((17,27*θdew)/(237,3+θdew)) )) / (((0,611*exp(1)^(17,27*θ)/(237,3+θ)))))*100
9 58,42 18,52 pvapour'" (kPa) = 0,611*exp(1)^((17,27*θdew)/(237,3+θdew))
10 141,3 18,71 pvapour '" (kPa) = wvapour *(101,325-pvapour)/0,624; condition: pvapour < 0,5*po (in this example po = 101,325 kPa)
11 455 19,57 air saturated with vapour !! pvapour "(kPa) = polynoom based on h when air is saturated with vapour
12 58,42 18,51 pvapour "(kPa) = polynom based on θdew
13 58,42 141,3 18,52 pvapour "(kPa) = polynom based on wvapour
14 58,62 80,0 18,67 60,14 pvapour (kPa) = 0,611*exp(1)^((17,27*θ)/(237,3+θ))
15 58,62 80,0 141,2 455 18,67 60,14 θwetbulb = ((0,00066*101,325)*θ+(4098*pvapour/(θdew +237,3)^2*θdew))/((0,00066*101,325)+4098*pvapour/(θdew+237,3)^2)
16 58,62 80,0 141,2 455 18,67 60,00 pvapour (kPa) = 0,611*exp(1)^((17,27*θwet bulb/(237,3+θwet bulb) - 101,325*(θ(dry bulb) - θwet bulb)*0,000660*(1+0,00115*θwet bulb)
17 58,62 80,0 141,3 455 18,67 60,00 pvapour (kPa) = 0,6112*exp(1)^((17,67*θwet bulb/(243,5+θwet bulb) - 101,325*(θ(dry bulb) - θwet bulb)*0,000660*(1+0,00115*θwet bulb)
18 58,62 80,0 141,3 455 39,3 18,67 60,00 θdew = ln((1,639*(0,6112*exp(1)^((17,67*θwet bulb/(243,5+θwet bulb) - 101,325*(θ(dry bulb) - θwet bulb)*0,000660*(1+0,00115*θwet bulb)))*(237,3+θdew)/17,27)
19 3,00 1,00 3,00 15,0 1,00 5,69 17,07 101,3 58,62 80,0 141,3 455 39,3 18,70 60,00 82,6 ## 1,96 15,8 6305 1,010 1,840 mdry air = (28,84/8,314)*((pdry air*V)/(273,15+θ(dry bulb));mvapour = (18/8,314)*((pvapour*V)/(273,15+θ(dry bulb))
20 101,3 58,62 80,0 141,3 455 39,3 18,70 60,00 82,6 ## 1,96 15,8 6305 1,010 1,840
21 3,00 1,00 3,00 15,0 1,00 5,69 17,07 101,3 80,0 18,67 60,00 82,7 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
22 3,00 1,00 3,00 15,0 1,00 0,54 101,3 58,62 80,0 18,70 82,6 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
23 3,00 1,00 3,00 3,00 9,00 101,3 58,62 80,0 141,3 455 39,3 18,70 60,00 82,6 7,3 1,03 8,3 3323 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
24 3,00 1,00 3,00 3,00 9,00 101,3 58,62 80,0 141,2 455 39,3 18,70 60,14 82,6 7,3 1,03 8,3 3323 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
Different volume flows to be combined to one common flow
25a 3,00 1,00 3,0 15,0 1,00 5,69 17,07 101,3 58,62 80,0 141,3 455 39,3 18,70 60,00 82,6 13,9 1,96 15,8 6305 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
25b 1,00 0,8 15,0 1,00 5,69 4,47 101,3 58,42 80,0 139,6 451 39,0 18,52 59,96 82,8 3,6 0,51 4,1 1640 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
25c 3,00 1,00 3,0 15,0 1,00 5,69 17,07 101,3 58,62 80,0 141,3 455 39,3 18,70 60,00 82,6 13,9 1,96 15,8 6305 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
25d 3,00 1,00 3,0 15,0 1,00 5,69 17,07 101,3 58,42 80,0 139,6 451 39,0 18,52 59,96 82,8 13,9 1,94 15,8 6256 1,010 1,840 v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k (formule 5)
25 58,58 80,0 140,6 453 39,3 18,64 60,10 45,2 6,4 51,6 20505 1,010 1,840 Calculate Σ mdry air, mvapour and H; subsequently h and wvapour; for remaining values use common formula's.
Enth
alp
y
Rela
tive h
um
idity
Partial vap.
Pressure
Wet
bulb
tem
peratu
re
*
Partial dry a
ir
pressure
Mass f
low
dry a
ir
Mass f
low
vapour
Mass f
low
wet
air
Enth
alp
y
Specific
heat
dry a
ir
Specific
heat
vapour
Absolu
te
hum
idity
Form
ula
num
ber
Channel
heig
ht
Channel
wid
th/ d
iam
.
press.d
iffe
r.
pitot
tube
drukverschil
pitotb
uis
kalibr.-
facto
r
pitotb
uis
velo
city
(m
ole
ntj
e)
Volu
me f
low
Tota
l
pressure
Dew
poin
t
Dry b
ulb
tem
peratu
re
Table 3 Formula library for calculating physical properties of drying air
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 24
4 MOLLIER CHART
4.1 Introduction
To understand the relation between the properties of humid air in processes,
psychro-metric charts are developed.
The versatility of the psychrometric chart lies in the fact that by knowing three
independent properties of some humid air (one of which is the barometric pressure),
the other properties can be determined. Changes in state, such as when two air
streams mix, can be modeled easily.
The most welkwown psychrometric chart is the Mollier diagram. The barometric air
pressure for the diagram described will be 101,325 kPa.
To determine the thermophysical properties of a mixture at least two of the six
independent properties must be known (θ, θwet-bulb, θdew, φ, h and v).
4.2 Explanation Mollier chart
The Mollier chart is explained in eight steps in box 7.1 u/i 7.8.
For each step the applied formulas from table 3 are depicted in the box concerned.
Exercise 2 is depicted in box 7.6.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 25
6,1 absolute humidity 136 (wvapour in g/kg dryair) 144
Mollier chart: h and wvapour
The Mollier-chart is a roadmap for humid air with total pressure 101,325 kPa
Humid air = 1 kg dry air + vapour
x-axis = absolute humidity of humid air (wvapour in g vapour / kg dry air)
y-axis = enthalpy of humid air (h in kJ / kg dry air)
Vapour means that the relative humidity φ =< 100 %
(increasing the vapour content when φ =100 % will result in condensation of vapour)
So one of the borders will be the constant line for φ =< 100 %
Box 7.1. Mollier chart for humid air (h and wvapour)
Ab
s.h
um
idit
y
Ab
so
lute
hu
mid
ity
(w
vap
ou
rin
g
/k
g d
ry a
ir)
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 26
1,2 2,5 (pvap in kPa) partial vapour pressure
430 °C
408 °C
59 °C
58 °C
21 °C
i1
10 °C
7,7 16 absolute humidity 138 (wvapour in g/kg dryair) 146
Mollier chart: pvapour and θdew
For air saturated with water vapour there are empirical relations between θdew, wvapour, & pvapour
From the table some values from these relations are depicted in the Mollier-chart
The values can also be calculated by the following formula's:
wvapour(g/kg) =1000*(18/28,84)*((0,611*exp(1)^((17,27*θdew))))/(237,3+θdew))/
(101,325-(0,611*exp((17,27*θdew))))/(237,3+θdew))))))
pvapour" (kPa) = 0,611*exp(1)^((17,27*θdew)/(237,3+θdew))
θdew = ln((1,639*pvapour)*(237,3+θdew)/17,27)
Box 7.2. Mollier chart for humid air (pvapour and θdew)
18,2 19,0
The total pressure (po) of the humid air is the sum of the partial pressure of dry air (pdry air) and the
partial pressure of the vapour (pvapour); po = pdry air + pvapour (kPa)
The partial pressure of the vapour (pvapour) depends on the amount of vapour in the humid air
(wvapour) and the latter depends on the temperature at saturation (θdew) of the humid air.
Temperature
Ab
s.h
um
idit
y
(g
/kg
dry
air
)
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
Pa
rtia
l va
po
ur
pre
ssu
re (
kP
a)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 27
1,2 2,5 (pvap in kPa) partial vapour pressure
430 °C
408 °C
Heat capacity J/(g.K)
temp
rang
vapo
ur
dry
air
0 1,83 1,01
0 - 100 1,84 1,01
0 - 200 1,87 1,01
0 - 300 1,89 1,02
0 - 400 1,92 1,03
0 - 500 1,95 1,04
0 - 600 1,98 1,05
0 - 700 2,01 1,06
0 - 800 2,04 1,07
80 °C 0 - 900 2,07 1,08
0 - 1000 2,11 1,09
59 °C A 0 - 1100 2,14 1,10 B
C D 0 - 1200 2,17 1,11
58 °C 0 - 1300 2,20 1,12
21 °C 0 - 1400 2,23 1,13
0 - 1500 2,26 1,13
0 - 1600 2,29 1,14
0 - 1800 2,34 1,15
10 °C 0 - 2000 2,39 1,16
7,7 16 absolute humidity 138 (wvapour in g/kg dryair) 146
Mollier chart: θ and φ
The temp.(θ) can be derived from the relation between enthalpy (h), abs.humidity (wvapour) and temp.(θ):
h (J/g) = cp av.dry air (J/(g.K)) * θ (oC)+ 0,001 * wvapour (g/kg) * (hRo (J/g) + cp av.vapour * θ)
cp av. = average heat capacity (see insert)
R = heat of evaporation; for watervapour compared to 0 oC: R = 2501,6 J/g
The rel. humidity (φ) in A is the actual mvapour divided by the maximum mvapour at the same temperature:
mvapour =mass of vapour present in a space
m"vapour =maximum possible mass of vapour present in the same space at the same temperature
φ = mvapour /m"vapour * 100 %
When V = volume-flow (m3/s) and T = absolute temperature (K):
mvapour = (18/8,314)*pvapour * V/T (kg/s); also:
φ = pvapour /p"vapour * 100 %
Example: In point A θdry bulb=59 oC, pvapour=2,5 kPA; max. mass at 59 oC is at B: p"vapour=19,0 kPa
φ = 2,5/19,0 *100% = 13,2 %
Box 7.3. Mollier chart for humid air (θ and φ)
18,2 19,0
Temperature
Temperature
Temperature
Temperature
Ab
so
lute
hu
mid
ity
(g
/k
g d
ry a
ir)
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
Pa
rtia
l va
po
ur
pre
ssu
re (
kP
a)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 28
1 (pvap in kPa) 18 partial vapour pressure 19 20
430 °Ci4
408 °C
i3
80 °C A
59 °C u5=60,5oC
58 °Cθwetbulb in A
21 °C
10 °C
i1= 6,1 absolute humidity u4=136 (wvapour in g/kg dryair) u2= 144
Mollier chart: θwet bulb and difference with θdew
pvapour (and subsequently φ) can be calculated from:
pvapour (kPa) = 0,611*exp(1)^((17,27*θwet bulb/(237,3+θwet bulb) - 101,325*(θ(dry bulb) - θwet bulb)*0,000660*(1+0,00115*θwet bulb)
Note: in point A the wet bulb temperature is 60,5 oC and the dew point is 59 oC
Box 7.4. Mollier chart for humid air ( θwet bulb and difference with θdew)
Temperature
Ab
so
lute
hu
mid
ity (
w v
ap
ou
r) =
1
44
g/
kg
Temperature
Temperature
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
The (thermodynamic) wet-bulb temperature (θwetbulb) is the temperature a volume of air
will have if cooled adiabatically to saturation by evaporation of water into it, all latent
heat being supplied by the volume of air.
Wet-bulb temperature is measured using a thermometer that has its bulb wrapped in
cloth, called a sock, that is kept wet with water.
When φ <100%, water evaporates from the bulb which cools the bulb below ambient
temperature.
Compare: the temperature of drying air that passes over wet paper web in a dryer and
becomes saturated is the wet-bulb temperature.
De
w p
oin
t in
A
(θ
de
w)
= 5
9 o
C
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 29
1 (pvap in kPa) 18 partial vapour pressure 19 20
430 °Ci4
408 °C
i3
80 °C A
59 °C u5=60,5oC
58 °Cθwetbulb in A
21 °C
10 °C
i1= 6,1 absolute humidity u4=136 (wvapour in g/kg dryair) u2= 144
Mollier chart: density ρ in kg/m3; not depicted in this chart
ρ is an indication for the air-duct-dimensions and is used for pitot-tube calculations
A pitot tube measures the head (h); with (h in m) the air velocity (v in m/s) can be calculated.
h (m) = v2 (m/s) / 2g (m/s2) (1)
The pressure difference (∆p) between the connections on the pitot tube is measured:
∆p (N/m2) = ρ (kg/m3) x g (m/s2) x h (m) (2) (Attention: unit newton (N) = kg.m/s2 )
v (m/s) = (2 * ∆p (Pa) / ρ (kg/m3) )^0,5 (3)
ρ (kg/m3) = mwet (kg) / V (m3) (4)
v (m/s) = (2 * ∆p (Pa) / (mwet/V) (kg/m3) )^0,5 *k
mwet = mdry air + mvapour
mdry air = (28,84/8,314)*((pdry air*V)/(273,15+θ(dry bulb));
mvapour = (18/8,314)*((pvapour*V)/(273,15+θ(dry bulb))
v (m/s) = (2 * ∆p (Pa) / ((28,84*pdry air + 18*pvapour)/(8,314*(273,15+θdry bulb))))^0,5 * k
k= calibration factor
Box 7.5. Mollier chart for humid air ( density ρ in kg/m3 of humid air)
Temperature
Ab
so
lute
hu
mid
ity (
w v
ap
ou
r) =
1
44
g/
kg
Temperature
Temperature
Ab
s.h
um
idit
y
Ab
s.h
um
idit
y
De
w p
oin
t in
A
(θ
dew
) =
59
oC
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 30
1 (pvap in kPa) 18 partial vapour pressure 19 20
430 °C
408 °C
80 °C A
59 °C θwet bulb A
58 °Cθdew A=59
oC 60,5
oC
21 °C
B10 °C
6,1 absolute humidity 136 (wvapour in g/kg dryair) 144
Mollier chart: draw the following processes in the Mollier chart !
1) Air with conditions as depicted in B is heated in a steamheater
2) Air with conditions as depicted in B is heated in a natural gas heater
3) How is the drying process depicted in the Mollier chart
4) Air with conditions as depicted in A is cooled in the heatrecovery
5) Supply- and exhaust air conditions of a dryer are B and A; what is the heat consumption
Box 7.6. Mollier chart for humid air ( processes in the Mollier chart)
Dewpoint A
Temperature A
Pa
rtia
l va
po
ur
pre
ssu
re in
A 1
9 k
Pa
Ab
so
lute
hu
mid
ity i
n A
14
4 g
/k
g d
ry a
ir
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 31
1 (pvap in kPa) 18 partial vapour pressure 19 20
430 °C i4
408 °C i3
80 °C u1
59 °C u2 θwet bulb u1
u3 θdew u1=59oC 60,5
oC
58 °C u4
21 °C i2 Real process in multi cylinder dryer
(isothermal, adiabatic or isenthalpic ?)
10 °C i1
6,1 absolute humidity 136 (wvapour in g/kg dryair) 144
Moisture increase per kg dry air: ∆w = wu1-wi1 = 138 g moisture / kg dry air
Required air per kg PWE: 1000 g : ∆w g/kg = 7,2 kg air / kg PWE
Cons.with HRC supplyair: 7,2 x (hi3 - hi2) = 2920 kJ/kg PWE
Mollier chart: heat input process water
(1 kg PWE * 4,2 kJ/(kg.oC) * 40oC) kJ/kg PWE : ((1000/(143-6)) kg air/kg PWE = 23 kJ/kg
Box 7.7. Mollier chart for humid air (heat input process water)
"Real process in multi cylinder dryer":
From i1 till i4 air is heated by cylinders and (pocket ventilation)air heaters from 10oC to "430"oC.
This pocket ventilation air is preheated (i1-i2) by heat recovery from the exhaust air (u1-u3).
It is assumed that during heating the moisture content of the air will not change:
the process follows the line of constant moisture content wvap (= 6,1 g moisture/kg).
In realty the process will be as depicted on the insert on the Mollier chart
"Heat contribution process water"
The entalpie in the Mollier chart is based on 0oC
As the process-water temperature is higher than 0oC between i3-i4 no heating is required.
When the process water temperature is f.i. 40 oC the heat between i3 and i4 can be calculated as follows:
Dewpoint u1A
Temperature u1
Pa
rtia
l va
po
ur
pre
ssu
re in
u1
19
kP
a
Ab
s.h
um
idit
y i
n u
1 1
44
g/
kg
dry
air
He
ati
ng
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 32
1 (pvap in kPa) 18 partial vapour pressure 19 20
430 °C i4
PWE = productwater evaporation
θwb = wet bulbtemperature exhaust air
408 °C i3 φ = relative humidity (%)
ŋθ = temp.-efficiency air heatexchanger
ŋθ = 15 %
80 °C u1 Exhaust air
59 °C u2 θwet bulb u1
u3 60,5oC
58 °C u4
21 °C i2
Supply air
10 °C i1
6,1 absolute humidity 136 (wvapour in g/kg dryair) 144
Moisture increase per kg dry air: ∆w = wu1-wi1 = 138 g moisture / kg dry air
Required air per kg PWE: 1000 g : ∆w g/kg = 7,2 kg air / kg PWE
Cons.with HRC supplyair: 7,2 x (hi3 - hi2) = 2920 kJ/kg PWE
HRC when cooling exhaust air till 58 oC is 12 % of heat consumption
Consumption dryer - savings processwater is 2564 kJ/kg PWE
Mollier chart: heat recovery
Temperature-efficiency:
ŋθ = (θi2 -θi1) /(θu1 - θi1) ***
ŋθ = temperature efficiency of the heat exchanger
θ = temperature (oC)
*** Heat capacity of the exhaust air flow => supply air flow
Box 7.8. Mollier chart for humid air (heat recovery)
Temperature efficiency values are supplied by the supplier of the equipment and are employed to
calculate the amount of heat transferred in air to air heat recovery equipment
Dewpoint u1A
Temperature u1
Pa
rtia
l va
po
ur
pre
ssu
re in
u1
19
kP
a
Ab
s.h
um
idit
y i
n u
1 1
44
g/
kg
dry
air
He
ati
ng
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 33
5 DRYING PRINCIPLES
5.1 Product water removal
After the stock preparation the stock flow enters the head box of the paper machine
with a consistency between about 0,2 and 1,3 %. After drainage on the wire or forming
section the web consistency increases to 15 till 26 %. After the press section
consistency is called dry solids content (ds). The dry solids contents after the press
section is between 40 and 55 %.
After the press section the web enters the drying section where the remaining water
thermally is removed till the dry solids content is between 91 and 95 %.
The product water removed in the drying section is:
PWE = (100/dsin – 100/dsout) x Pbone-dry (kg water/s or ton water/h) (18)
Where:
PWE = product water evaporation in kg/s or ton/h
dsin = dry solids content of the web entering the drying section in %
dsout = dry solids content of the paper or board leaving the drying section in %
P bone-dry = the mass of the product dried in the drying section in kgbone-dry /s or ton/h
Some dryers consist of a pre-dryer and an after-dryer; in between is a size-press, a
coater or a glue-machine for applying respectively starch, coating or glues:
Starch
In the case of starch, typically, size press additions involve re-wetting the pre-dried
paper on flooded rollers with a starch solution so as to soak the starch into the paper.
Once soaked, the treated paper is dried again, thereby providing paper of increased
strength. In the production of paper for corrugated board from recovered paper,
approximately 3,5% of the end weight of the product is starch. Currently, starch is
typically added in a solution with only 8% dry matter content. This means that for every
100.000 ton of paper produced, 3500 ton of starch is added in a solution of 40.250 ton
of water, that needs to be evaporated in the after-dryer section.
Coating
Coatings can constitute a large share of the total end weight of the paper (more than
30%). Coatings are added to the paper in much higher consistency than starch, typical
values are between 60 and 70 % dry matter content. This means that for every
100.000 ton of paper produced, 30.000 ton of coating is added in a solution of 14.118
ton of water.
Glues
Glues are used to laminate board with a layer of paper. The amount of paper added to
the board can be a large share of the total end weight of the product, but the glue is
only about 1,5% of the final board mass (without paper additions). Glue is typically
added to the board in a solution of 30% dry matter content. This means that for every
100.000 ton of board produced, 1500 ton of glue is added in a solution of 3500 ton of
water.
In all cases the product is rewetted after the pre-dryer.
In table 5 is shown the increase in productwater evaporation (PWE) in the after-dryer at
different additive solutions.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 34
When, for instance, the consistency of the starch-solution for the size-press is
increased from 8 till 12 % (see column e in table 5) the PWE in the after-dryer will
decrease from 9,5 till 6,0 ton/h (see column i).
Table 5 Waterevaporation in after-dryer at different additives solutions *
a b c d e f g h i j
Input
pre
-dry
er
Dry
solids c
onte
nt
befo
re p
re-d
ryer
Dry
solids c
onte
nt
aft
er
pre
-dry
er
Pro
duct
wate
r evap-
ora
tion p
re-d
ryer
Additiv
es s
olu
tion
(to s
ize p
ress o
r
coate
r)
Input
aft
er-
dry
er
(fib
res +
additiv
es)
Dry
solids c
onte
nt
befo
re a
fter-
dry
er
Dry
solids c
onte
nt
aft
er
aft
er-
dry
er
Pro
duct
wate
r evap-
ora
tion a
fter-
dry
er
Pro
duct
wate
r evap-
ora
ted in p
re-
dry
ers
I&
II a
nd
aft
er-
dry
er
Pdryer dsin dsout PWE - Pdryer dsin dsout PWE PWE
t bone
dry/h% %
t PWE
/h
%-bone
dry
t bone
dry/h% %
t PWE
/h
t PWE
/h
22,2 46,3 95,0 24,6 8,0 23,1 68,3 95,0 9,5 34,1
22,2 46,3 95,0 24,6 12,0 23,1 76,1 95,0 6,0 30,7
22,2 46,3 95,0 24,6 20,0 23,1 83,7 95,0 3,3 27,9
22,2 46,3 95,0 24,6 30,0 23,1 88,1 95,0 1,9 26,5
22,2 46,3 95,0 24,6 40,0 23,1 90,5 95,0 1,2 25,8
22,2 46,3 95,0 24,6 60,0 23,1 93,0 95,0 0,5 25,1
22,2 46,3 95,0 24,6 90,0 23,1 94,8 95,0 0,0 24,7
22,2 46,3 95,0 24,6 20,3 23,1 83,9 95,0 3,2 27,8 ‘* Final product 90 g airdry/m2, ds=95%; product to after-dryer (0,95*90=) 85,5 g bone-dry/m2; additives = 3,6% bone-dry; product to pre-dryer ((100-3,6)/100)*85,5 = 82,4 g bone-dry/m2
5.2 Thermal drying
Drying methods
In the Netherlands are three types of thermal drying methods:
- Multi-cylinder drying for paper and boards
- Yankee cylinder drying for tissues
- Infrared drying for drying after surface sizing and coating
The temperatures in these dryers are up to 100 oC for multi-cylinder dryers, 400 oC for
yankee-dryers and 900 oC for infrared dryers.
In thermal drying of a product, we can distinguish 3 steps:
- the separation of the liquid from the product,
- the transition of the liquid from a fluid to a gaseous phase and
- the removal of the produced vapor.
The manner and temperature at which these steps occur largely determine the energy-
efficiency of the drying process.
For the removal of the produced vapor convective type drying and boiling type drying
are distinguished.
Convective type drying
(Translation: DE: verdunsten, NL: verstrooien)
During convective drying the vapor is removed by a (molecular) diffusion process.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 35
Molecular diffusion, often called simply diffusion, is a net transport of molecules from a
region of higher concentration to one of lower concentration by random molecular
motion. The result of diffusion during convective drying processes is a gradual mixing of
water vapor and dry air molecules. Basically diffusion is the movement of molecules
from an area of high concentration to a lower area.
In the multi-cylinder dryers in the paper industry, heat transfer is mainly conductive
(from the cylinder wall) and for a neglectable part convective (from the heated pocket
air).
Vapor transfer is convective.
The evaporated water diffuses in the air surrounding the cylinders. This air needs to be
replaced all the time in order to maintain a difference in vapor concentration between
the vapor at the surface of the paper web and the vapor in the air. The difference in
vapor concentration is proportional to the water vapor pressure at the paper web
surface and the partial water vapor pressure in the air, which also determines the speed
of diffusion. The speed of diffusion decreases towards zero if the moisture content of
the product would be in balance with the relative moisture content of the surrounding
air.
The Stefan equation expresses evaporation from the web surface to the surrounding
air:
mevaporation = β x R/(Mvapor x T) x (pwebsurface – pvapor) (19)
Where :
mevaporation = drying rate
β = mass transfer coefficient
R = universal gas constant = 8,3145 kJ/(kmol.K)
Mvapor = molar mass water vapor = 18 kg/kmol
T = temperature in K
pwebsurface = partial vapor pressure on the web surface in kPa
pvapor = partial vapor pressure of the vapor in the surrounding air in kPa
As long as the surface of the paper web is wet by surface-moist or macro-capillary-
moist, the wet surface will obtain the wet bulb temperature (θwet-bulb). In this case the
partial vapor pressure on the web surface (pwebsurface) is derived from this wet bulb
temperature (θwet-bulb).
An important feature of the diffusion process is:
Convective type drying : pvapor < po (19a)
Where :
po = atmospheric pressure (101,325 kPa)
During convective type drying air transports the vapor from the dryer to outside.
Boiling type drying
During boiling type drying under atmospheric conditions the temperature of the water
vapor is higher than 100 oC. This results in:
Boiling type drying : pvapor => po (19b)
There is no longer diffusion the vapor flows free in the surrounding air like the boiling
process in a singing teakettle.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 36
No air is needed to transport the vapor from the dryer to outside; the vapor just flows
freely to the surrounding air.
Examples of drying processes with boiling type drying air:
- generally processes with temperatures > 100 oC
- infrared dryers
- yankee dryers
- vacuum dryers
5.3 Drying periods and rates
As shown in the example in figure 2a, the drying process has typically three phases:
- the heat up period
- the constant rate period
- and the falling rate period
During the heat up period the temperature of the web increases tot the the level of
adiabatic saturation. The length of this period is typically 4 to 6 heated cylinders.
During the constant rate period the temperature of the web is typically 65 – 75 oC.
As long as there the surface is saturated with moist during this period, the temperature
of the surface of the web will be theoretically the wet bulb temperature. Due to
conductive heat transfer it will be somewhat higher.
The heat transfer rate from the cylinder to the web determines the rate of
evaporation.
The constant rate period ends when all free water has been removed from the voids
between the fibers. Moisture content is then critical moisture content.
0,50 g/g
70oC
55oC
40oC
15 kg/(m2.h)
0,05 g/g
Temperature
Drying rate
Time
Heat up period Falling rate periodConstant rate period
Figure 2a Drying periods (typical values)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 37
The falling rate period starts at the critical moisture content. The uniform water film
has disappeared and the web is partly dry. The evaporating surface is decreasing;
this results in more resistance between the web and the cylinder. As a result the
heat conductivity decreases and the temperature of the web starts to rise.
The values for drying rate depuicted in figure 1 are typically for multi cylinder
dryers. Drying rates in Yankees are much higher. In figure 2b indicative average
drying rates for multi-cylinder and yankee dryers are shown.
28
22
Multi-cylinder dryers
14
12
120 200
Steam temperature oC
170
140
Air impingement dryers
(Yankee hood etc)
Jet speed > 100 m/s
25
120 500
Jet temperature oC
Dry
ing r
ate
kg/(
m2.h
)D
ryin
g r
ate
kg/(
m2.h
)
Fig. 2b Indicative drying rates for multi-cylinder and yankee dryers
(values for illustration only; not for calculations)
Drying rates decrease considerably when dryness of paper increases. The average
drying rate reflects the average evaporation from wet to dry.
5.4 Air systems
The dryer section ventilation sytem consists essentially of the following parts:
- Supply air system (including distribution elements, pocket ventilators, blow boxes,
air knives, impulse blowing sytems etc)
- Hood and basement enclosures
- Exhaust air sytems
- Heat recovery equipment
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 38
5.5 Supply air
Some decades ago the supply air to the drying section was primarily distributed through
the basement. Now the aim is to provide as much dry air as close as possible to the
web to promote evaporation. To obtain this correct distribution of the the supply air is
necessary. Correct distribution will improve both drying rate and sheet uniformity.
The air humidity (wvapor) close to the sheet, which has a fixed relation with the partial
vapor pressure (pvapor), should be at a reasonable level to create sufficient driving force
for evaporation.
The driving force (pwebsurface – pvapor) can be derived from formula (19):
mevaporation = β x R/(Mvapor x T) x (pwebsurface – pvapor) .
The supply air is distributed mainly by blow boxes. Pocket ventilation is one of the
concepts to improve the drying rate and sheet uniformity. The supply air provided by
pocket ventilation to areas where evaporation occurs should be as dry as possible.
A suitable supply air temperature is 90 – 95 oC. Testing showed that higher
temperatures resulted in only negligible increase in evaporation rates while specific heat
consumption increased.
In multi-cylinder dryers the web is heated by conductive heat transfer from the steam
heated cylinders. The heat transfer from the pocket air is negligible.
In yankee dryers, however, air speeds of more than 100 m/s are often maintained. In
this case the heat transfer has an impingement character and will be considerably.
To restrict cold and moist air from the press section from entering the hood and to
restrict hot humid drying air from the hood entering the machine room sometimes
air knives are build in the hood.
5.6 Dryer hoods
The removal of the produced vapor in the drying section of paper mills can be done in
three ways:
No real hood
This means that the ceiling of the production location functions as a hood. In order to
avoid condensation (droplets) the production space is ventilated.
Because of labor conditions, the temperature in summer can not be above 30-40 ºC and
the relative humidity will be below 75 %.
In winter the incoming air should be heated till about 25 oC.
Because of low drying temperatures, the amount of drying air to be removed is high.
This results in poor energy efficiencies.
Open hood
This means that a hood is placed about 2 meters above the machine floor. The incoming
air is first pre-heated by the exhaust air. The temperature of the exhaust air is about
45-50 ºC. By installing an open hood the exhaust air temperature can be raised without
increasing the hall temperature.
Because of low drying temperatures, energy efficiency is better but still poor.
Labor conditions were improved by these hoods.
Closed hood
Here the drying sections of the paper machine are completely separated from the
production space. The ventilation air can be controlled and is supplied to those places
where evaporation is highest. Because of high drying temperatures, energy efficiency is
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 39
much better than in the former two options. We distinguish low, medium and high
humidity hoods.
Table 6 shows typical operating values for the different types of closed hoods for
multicylinder and yankee dryers.
The webtemperature at entering the dryer is in all cases supposed to be 35 oC.
Table 6 Typical operating values for different hood concepts
Multi cylinder dryer Yankee-dryer
Unit
Open hood
Low humidit closed hood
Medium humidit closed hood
High humidity
closed hood
Medium humiditclosed hood
High humidit closed hood
Exhaust air:
θ
φ
θdew
wvapor
kg air / kg PWE
oC
% oC
g/kg
kg/kg
55,0
40,0
37,1
41
28,3
80,0
33,0
54,9
114
9,2
85,0
38,0
62,2
174
6,0
90,0
38,0
66,6
225
4,6
320
0,12
53,8
107
9,9
320
0,54
88,6
1215
0,8
Supply air
wvapor
θ before HRC
ŋ θ HRC
θ after HRC
θ after HE steam
msupply/mexhaust
g/kg oC
% oC oC
%
7
10
-
-
-
-
7
10
50
45
95
60
7
10
55
51
95
75
7
10
60
54
95
90
7
10
50
165
-
80
7
10
60
196
-
90
Heat consumption
Without HRC supply air
With HRC supply air
Savings (in relation to
(preceding column)
J/gPWE
J/gPWE
%
3757
-
0
3161
2832
24,6
2967
2716
4,1
2894
2688
1,0
6069
4506
0
3205
3048
32
Heatrecovery
θ before HRC
θ after HRC
Recovery rate
oC oC
%
-
-
-
80
60
7
85
60
18
90
60
36
320
60
51
320
60
93
Note that, when medium humidity hoods of multi-cylinder dryers are replaced by
high humidity hoods, the heat savings will only be 1%. But at the same time, after
cooling the exhaust air till 60 oC, the the heat-recovery rate (= recovered heat / heat
consumption), increases from 18 to 36 % !!
Conclusion: by increasing the temperature of the exhaust air, not only the energy use
in the drying section decreases, also particularly the heat recovery potential increases
with increasing temperatures.
Other advantages of high humidity hoods are smaller air ducts and heat recovery
equipment.
There will also be savings on electricity consumption.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 40
5.7 Zero pressure level
In dryer enclosures, where air temperature and humidity or both are higher than
outside, a difference in density will exist between the air in the enclosure and the air
outside.
The value for this density (ρ in kg/m3) can be derived from the formulas:
ρ = mwet / V ( kg/m3) (21)
Where:
ρ = density of the humid air in kg/m3
mwet = mair + mvapor for volume V m3
mair and mvapor can be derived from:
T
V.p
8,314
18m
vapour
vapour (13c)
T
V.p
8,314
29m
air
air (13d)
The difference in densities causes the so-called chimney effect. Air of low density in the
upper parts of the enclosure tries to escape while air of higher density tries to enter
through the lower parts of the enclosure.
The upper part of the enclosure has a slight excess pressure while in the lower part
there is a slight under pressure compared to the outside. The level where the in- and
outside pressures are equal is the zero pressure level.
This level can be adjusted by balancing the amounts of supply and exhaust air. More
supply air will result in a falling zero level; more exhaust air will result in a rising zero
level.
The zero level is adjusted to where the largest openings are; these are the sheet
entrance and exit openings.
5.8 Exhaust air
To remove the exhaust air in a controlled way from the hood the air passes a false
ceiling or a plenum which is provided with slide dampers along the length of the
machine.
To compensate different evaporation rates these slide dampers can be separately
adjusted.
Normally adjustment is only performed at start-up of the machine after rebuild of the
dryer section.
A better solution to control the humidity of the exhaust air is installing speed controlled
supply and exhaust air fans.
Especially in dryers for a wide product range the exhaust air conditions will vary
depending on the product weight and machine speed. In this case installing speed
controlled fans will result in substantial heat savings.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 41
6 ENERGY CONSUMPTION DRYERS
6.1 System boundary heat consumption drying section
Figure 3 shows a block diagram for defining the borderline for heat consumption of the
dryer section. The depicted situation is just an example for explaining what belongs and
what belongs not to the heat consumption of the dryer.
Example of calculating heat consumption:
- Enthalpy steam supply + 5510 MJ
- Condensate to heat-exchanger processwater - 495 MJ
- Flash steam to steambox - 321 MJ
- Condensate to steamboiler - 416 MJ
- Heat consumption drying section + 4278 MJ
The heat consumption is caused by:
- Heat consumption dryer section I + 1939 MJ
- Heat consumption dryer section II + 1939 MJ
- Heating river water + 387 MJ
- Flash on condensate tank dryer + 13 MJ
- Heat consumption drying section + 4278 MJ
Boundary balance heat consumption drying-sections
Dryer-section I
Dryer-section II
Flashtank
Condensor
steam2000 kg5500 MJ6 bar,159 oC
condensate930 kg, 670 J/g +
blowthrough steam70 kg, 2755 J/g
6 bar,159 oC
condensate930 kg, 670 J/g +
blowthrough steam70 kg, 2755 J/g
6 bar,159 oC Flashtank
condensate882 kg, 561 J/g
3 bar,133 oC
HP Flash steam118 kg, 2723 J/g
3 bar,133 oC
Flashtank
condensate828 kg, 429 J/g 1,1 bar,103 oC
LP Flash steam172 kg, 2678 J/g
1,1 bar,103 oC
cooling waterto river
∆Q= 387 MJ
consumptiondrying section I
Q= 1939 MJ
consumptiondrying section II
Q= 1939 MJ
steam
1000kg2755 J/g
6 bar,159 oC
steam
1000kg2755 J/g
6 bar,159 oC
condensate172 kg, 429 J/g 1,1 bar,103 oC
Condensatetank
flash losscondens.tank1,0 bar,100 oC
∆Q= 13 MJ
condensate to boiler995 kg, 418 J/g, 1,0 bar, 100 oC,
416 MJ
condensate to heat exchanger
space-heating495 MJ
HP Flash steamto steam-boxes
321 MJ
Heat supply to drying sectionsSteam to drying section I 2755 MJSteam to drying section II 2755 MJ +Steam to drying sections 5510 MJ
Heat consumption drying sectionsDrying section I 2755 MJDrying section II 2755 MJ Cooling water from river 387 MJ Flash steam condensate tank 13 MJ +Total heat consumption 4278 MJ
Heat delivery to other consumersHeat-exchanger space-heating 495 MJSteamboxes 321 MJ Condensate to boiler 416 MJ +Total delivery other consumers 1232
Figure 3 Defining system boundary heat consumption drying section
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 42
Expressing the heat consumption in tons steam does not give the right information for
heat consumption. Example from practice:
Example heat consumption expressed in ton steam:
Mill A: Steam supply to drying section 1 ton (10 bar, 190 oC, >> h= 2806 MJ/ton) Condensate to boilerhouse 1 ton ( 1 bar, 95 oC, >> h= 399 MJ/ton)
Heat consumption 0 ton ∆h= 2407 MJ/ton
Mill B: Steam supply to drying section 1 ton (10 bar, 190 oC, >> h= 2806 MJ/ton) Condensate to boilerhouse 1 ton ( 8 bar, 170 oC, >> h= 720 MJ/ton)
Heat consumption 0 ton ∆h = 2086 MJ/ton
Though the steam supply is in both cases 1 ton; the “steam consumption” is 0 ton and
the heat consumption in mill A is 15% higher than in mill B.
6.2 Heat and mass balance drying section
In figure 4 an example of a heat and mass balance of drying section is shown. In this
figure also the symbols and units applied in the following chapters are explained.
Heat and mass transfer
Drying section
Paper web in
θpr.in
mpr.in = m.pr.ds. in + mpr.H2O.in
Supply airheater
Product WaterEvaporationθevap; PWE= m.pr.H2O. in - mpr.H2O.out
Paper web out
θpr.out
mpr.out = m.pr.ds. out + mpr.H2O.out
Exhaust air
θexh. ; θdew.exh.; θwet-b.exh.; φexh.;mair.exh.; mvapour.exh.; wvapour.exh.; hexh
Supply air
θsupply; θdew.supply.; θwet-b.supply;
φsupply;mair.supply; mvapour.supply; wvapour.supply; hsupply
Infiltration air
Exfiltration air
Steam supply
Hsteam
Condensate Hcond.
Heat lossesRadiation & convection,
f lash, condensor, leaks
Symbols:
θ = temperature in oC
θdew. = dew point in oC
θwet-b.= wet-bulb temp.in oC
φ = relative humidity
mair = mass dry air in kg
mvapour = mass vapour in kg
wvapour = absolute humidity
in g vapour/ kg dry air
H = enthalpy in kJ
h = specific enthalpy in kJ/kg
PWE = product water evaporation
mpr.= mass wet product m.pr.ds.= mass dry product
mpr.H2O = mass water in product
Figure 4 Heat and mass balance drying section
On the basis of this figure the heat consumption of the in- and outgoing flows for a
typical contemporary drying section are calculated in table 7.
The heat consumption for the average drying section can be roughly divided as follows:
a) Heating of the paper web (2%)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 43
dry material & final moisture
b) Evaporating water (75 %)
- heating of water
- water evaporation
- superheating vapor
- heat of sorption
c) Heating of the supply air (19%)
- heating supply air including vapor
- heating of the air infiltrating in the enclosure of the dryer
d) Convective and radiation heat losses (2%)
e) Other losses (2 %)
- flash steam, leaks, vacuum pumps etc.
The depicted percentages are typical values (state of the art about 1995); the situation
in the mill can be different. In the next chapters energy use for a), d) and e) is not
taken into account. This means that about 94% of the heat consumption of the dryer is
covered.
For multi-cylinder dryers the heat consumption is covered by the difference of
enthalpies of steam supply and condensate:
In general, the heat needed for drying paper is dependent on:
a) the amount of water that needs to be removed in the drying sections
b) the efficiency of water evaporation
c) the amount of heat that is recovered from the exhaust air
6.3 Heat consumption per kg evaporated product water
In box 7.1 u/i 7.8 the Mollier chart is explained.
In box 7.6 an example is given for calculating the heat consumption for evaporating 1
kg product water (MJ/kg PWE).
In excercise 3 you will make this calculations yourself.
A summary of the formulas based on the Mollier chart will be given.
There is no infiltration and exfiltration air so:
mdrying = msupply = mexh
Where:
mdrying = mass drying air in kg/s
msupply = mass supply air in kg/s
mexh = mass exhaust air in kg/s
Main heat consumers dryer section (enthalpies):
- Exhaust air - supply air = 94 %
- Paper web out - paper web in = 2 %
- Heat and other losses = 4 %
- Steam - condensate = 100 %
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 44
Table 7. Calculation heat consumption drying section without heatrecovery (see fig. 4 for mass en heat balance)
Nr Heat consumer Formula Typical values closed hoods kJ/kgPWE *
1
1a
1b
Heating product (mpr.in)
from θPr.in tot θPr.out
- dry matter
- final moisture
QPr.ds=mPr.ds . cPr. (θPr.out–θPr.in)
QPr.H2O.out=mPr.H2O.out.cW.(θPr.out– θPr.in)
θPr.in = 45oC, θPr.out = 80oC, cPr = 1,34 J/(g.K),
cW = 4,2 J/(g.K), mPr.H2O.out= mPr.ds.(1/ds-1);ds=0,93
50
10
2
2a
2b
2c
2d
Productwater evaporation (PWE) at θevap
- heating productwater from θPr.i to θevap
- evaporating productwater at θevap
- superheating vapor from θevap to θexh
- bound water (hS)
QHW = PWE . cW . (θevap – θPr.in)
QEW = PWE . (hRO – 2,4. θevap)
QSV = PWE .cvapor . (θexh- θevap)
QBW = PWE. hS
PWE = m Pr.H2O.in – mPr.H2O.out , cvapor = 1,8 J/(g.K),
hRo = 2502 J/(g.K), θevap = 80oC, θexh = 85oC
150
2310
10
0-20
3
3a
3b
Heating supply air
- heating supply air from θsupply to θexh
- heating vapor supp.air (θsupply to θexh)
Qsa = mair.supply . cair . (θexh – θsupply)
Qsv=mair.supply.wvapor.cvapor.(θexh– θsupply)
cair = 1,01 J/(g.K), θsupply = 10oC
wvapor.supply = 0,010 kg vapor/kg (dry) supply air
384
4
4
4a
4b
Heating infiltration air and air for heating
machine room (in winter)
- heating infiltration air from θinfiltr to θexh
- heating room air from θsupply to θroom
Qinf.air = mair.infiltr . cair . (θexh – θinfiltr)
Qroom.air=mair.room . cair . (θroom – θsupply)
θroom = 20oC (average machine room temperature)
mair.infiltr = depends on air balance
mair.room= about 25 kg air for each kg PWE
Year average θsupply = 10oC and year average θroom
during heating season is 16oC
100
150
5
5a
Radiation and convection losses
to surroundings
Qrad.conv = Σ (.A.Δθ)
= 0,3 – 0,5 W/m2. oC, A(m2), θ(oC)
40
6
6a
Other losses
(flash, condensor, leaks etc)
0,3 – 0,5 W/m2 oC
45
7
Total (excl. machine room)
3110
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 45
The amount of drying air for 1 kg (= 1000 g) product water evaporation is:
mdryingPWE =(1000 gPWE/kgPWE)/(wvapor.exh- wvapor.supply) kg air/kgPWE (22)
Where:
mdryingPWE = kg drying air/ kg PWE
wvapor.exh = absolute humidity g vapor / kg (dry) air
wvapor.supply = absolute humidity g vapor / kg (dry) air
When the temperature of the process water is 0 oC (θ=0 > h=0), the heat consumption
for 1 kg (= 1000 g) product water evaporation is:
QPWE,0o
C = mdryingPWE x (hexh - hsupply) kJ / kg PWE (23)
Where:
mdryingPWE = kg drying air/ kg PWE
h.exh = enthalpy of the exhaust air in kJ / kg (dry) air
hsupply = enthalpy of the supply air in kJ / kg (dry) air
Remark: the drying process is an adiabatic process; when θ = 0 oC the adiabatic line in
the Mollier chart is the same as the isenthalpic line.
When the temperature of the process water is θ oC, the enthalpy of the process water
will be:
Hprocess.θo
C = cw x θ process kJ / kg PWE (24)
Where:
Hprocess.θoC = enthalpy of the processwater in kJ / kg PWE
cw = specific heat water (=4,2) kJ/(kg.K)
θprocess = temperature process water oC
In the Mollier chart specific enthalpy (h) and abspolute humidity (wvapor) are always per
kg drying air:
∆hprocess.θo
C = Hprocess.θo
C / mdryingPWE kJ / kg (dry) air (25)
When the temperature of the process water is θ oC (θ >0 oC »»» h >0 kJ/kg), the heat
consumption for 1 kg (= 1000 g) product water evaporation is:
QPWE,θo
C = mdryingPWE x {(hexh - hsupply) - ∆hprocess.θo
C } kJ / kg PWE (26)
Where:
mdryingPWE = kg drying air/ kg PWE
h.exh = enthalpy of the exhaust air in kJ / kg (dry) air
hsupply = enthalpy of the supply air in kJ / kg (dry) air
6.4 Relationship between exhaust air temperature and heat consumption
In order to define the optimal drying conditions (i.e. with lowest heat consumption) the
relation between the temperature of the exhaust air and the heat consumption per kg
water evaporation is calculated with help of the formulas in the previous chapters. This
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 46
relation is shown in figure 5. Also different dew point temperatures, relative humidities
and drying air temperatures are indicated. The conditions of the supply (outside) air for
this figure are set at 10°C and 80% relative humidity.
Figure 5 Indicative heat consumption ideal dryer
(values for illustration only, not for calculations;
Based on “Trockner und Trocknungsverfahren, Kast, 1956)
The figure shows that from a point of view of heat consumption optimal exhaust air
conditions are: temperature 100 oC and relative humidity (φ) 100%.
This point, however, is located on the pure vapor line where moisture content of the air
is 100% and drying will be impossible. In order to keep the drying process at sufficient
speed, the relative humidity of the air should be around 40%. If the line of 40%
moisture content is followed, it can be seen that the energy use per kg evaporated
water decreases with increasing temperature. This may seem contradictory since higher
temperatures demand a higher energy use. However, the capacity of air to hold
moisture increases exponentially with increasing temperatures, meaning that much less
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 47
air is needed to evaporate a kg of water. Therefore, although the temperature
increases, the amount of air that needs to be heated decreases which results in a
decrease in total energy consumption. Given the above, in theory, the optimal drying
condition would be a relative moisture content of around 40% with as high temperature
as possible (i.e. just above the pure vapor line).
Apart from the process constraint (i.e. φ is about 40 %) there is also a construction
limitation. Current best available dryers have dew points of maximum 70°C while many
paper mills with closed hoods have dryers with operating dew points only around 55°C
or even lower. A transition from a dew point of 55°C to a dew point of 70° C would decrease energy use per kg of water evaporation with more than 8%.
The relative humidity in the pockets of the drying section are mostly between 50 and
60% (see figure 6).
As a result of short circuit flows the relative humidity of the exhaust air is considerably
lower. Typical differences between these values vary in practice from 10 till 30%. As
these differences have a high impact on the heat consumption of the dryer, the 10%-
value may be considered as good practice and the 30%-value as bad practice.
Figure 6 Example of relative humidity in pockets of cylinder dryers
Conditions for optimizing exhaust air conditions and heat consumption:
- process constraint:
relative humidity drying air (φ)
(φ lays down the “drying rate”)
- construction constraint:
dew point in the hood (θdew)
(θdew lays down the vapor content of the exhaust air)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 48
The relation between the exhaust air conditions temperature and dewpoint and the heat
consumption are shown in table 8 for relative humidities in exhaust air of 20% and
40%.
The table shows that for a given relative humidity of the exhaust air the heat
consumption will decrease at higher temperatures.
Table 8 Relative humidity and temperature exhaust air and heat consumption
φ= 20% φ= 40%
Dew
poin
t
Tem
pera
ture
Absolu
te
hum
idity
Heat
consum
ption
Savin
gs
Dew
poin
t
Tem
pera
ture
Absolu
te
hum
idity
Heat
consum
ption
Savin
gs
oC oC g/kg kJ oC oC g/kg kJ
24,1 54 19 6.069 36,2 54 39 3.952
28,9 60 26 5.233 14% 41,5 60 53 3.692 7%
33,7 66 34 4.669 46,8 66 72 3.490
38,5 72 45 4.262 52,0 72 97 3.330
42,5 77 57 4.000 56,4 77 124 3.222
47,2 83 74 3.752 61,6 83 168 3.115
52,0 89 97 3.556 5% 66,8 89 229 3.027 3%
56,7 95 126 3.399 72,1 95 317 2.956
61,4 101 165 3.271 77,2 101 450 2.897
66,0 107 218 3.166 82,4 107 669 2.848
70,7 113 290 3.080 87,6 113 1.084 2.807
Exhaust air conditions I Exhaust air conditions II
However at higher temperatures the decrease will be less than at lower temperatures.
The table shows that for a relative humidity of the exhaust air of 20%:
- Increasing the temperature 6 oC from 54 till 60 oC will decrease consumption 14 %
- Increasing the temperature 6 oC from 83 till 89 oC will decrease consumption 5 %
For exhaust air with a relative hunisity of 40% these values are only 7 and 3%.
Example good practice:
Relative humidity between cylinders = 50%
Relative humidity in exhaust pipe = 40%
Difference = 10%
Example bad practice:
Relative humidity between cylinders = 50%
Relative humidity in exhaust pipe = 30%
Difference = 20%
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 49
See also “Demonstration drying temperatures, relative humidity and energy
consumption” of the excel file “Demonstration” of MED for a demonstration of the
influence of the actual and optimal drying temperature and relative humidity on the
energy consumption.
Statements:
- At higher temperatures heat consumption decreases
(and quality of heat in exhaust air for heat recovery (HRC) improves)
- The higher the temperature the less the energy consumption decreases
(However the more the quality of the exhaust air improves)
- The higher the relative humidity the less the energy consumption decreases
(However the more the quality of the exhaust air improves)
- The higher the temperature the more the quality of heat in exhaust
air improves
- At higher temperatures the heat for process water, spray water and space-
heating can (almost) be covered by HRC (no fresh steam!!)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 50
Exercise 3 (page 1). Relation heat consumption and exhaust air temperature
Givens: Ideal dryer: there are no heatlosses to the surroundings and no leakages.
The dryer is shown in figure 4 and below.
Product (P):
Temperature product in θPr.in = 0oC
Temperature product out θPr.out = θexh
Mass dry product = 0 kg
Product water evaporation =mpr.H2O.in–mpr.H2O.out=1kg
Supply air (supply):
Temperature θsupply = 10oC
Relative humidity φsupply = 80%
Mass dry air mair.supply = ? kg
Absolute humidity (g vapor/kg dry air) wvapor.supply = ? g/kg
Specific enthalpy (air + vapor/kg dry air) hsupply = ? kJ/kg
Exhaust air (exh):
Temperature ………………………………….……………………… θu =see questions
relative humidity …………………………………………….. φu =see questions
Heat of evaporation, evaporation-temperature and specific heat:
Heat of evaporation at 0oC hRo =2.501,6 kJ/kg
Evaporation-temperature θevap = θexh
Heat of evaporation at θexh oC see steam table in annex
Specific heat water cwater = 4,2 kJ/kg . K.
Specific heat vapor cvapor = 1,8 kJ/kg . K.
Specific heat dry solids product cPr.ds = 1,34 kJ/kg. K.
Specific heat dry air cair = 1,01 kJ/kg . K.
Ideal dryer Supply airheater
Product WaterEvaporationθevap; PWE = m.pr.H2O. in - mpr.H2O.out
Paper web out
θpr.out
mpr.out = m.pr.ds. out + mpr.H2O.out
Exhaust air
θexh. ; θdew.exh.; θwet-b.exh.; φexh.;mair.exh.; mvapour.exh.; wvapour.exh.; hexh
Supply air
θsupply; θdew.supply.; θwet-b.supply;
φsupply;mair.supply; mvapour.supply; wvapour.supply; hsupply
Steam supply
Hsteam
Condensate
Hcond.
Heat consumption Q = Hsteam - H cond
Paper web in
θpr.in
mpr.in = m.pr.ds. in + mpr.H2O.in
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 51
Exercise 3 (page 2). Relation heat consumption and exhaust temperature
Questions :
a) Along which constant line in the Mollier chart is the drying process ?
b) Calculate heat consumption if φexh = 20% at θexh = 40, 60, 80 and 95oC.
Write the results in the table on page 3 of this exercise.
c) Ditto if φ = 50%
d) Ditto if φ = 80%
e) Determine the dewpoint at the exhaust air conditions.
f) Draw the results on page 4 of this exercise.
g) At question c) you calculated the heat consumption (Q) for the evaporation of 1
kg water when φexh = 50% and θexh = 40, 60, 80 and 95oC on the basis of the
difference of the enthalpy of the exhaust and supply air.
This consumption can be divided in four parts and after that it can also be
calculated for each part:
- Heating air (Qair.supply)
- Heating vapor in the air (Qvapor.supply)
- Evaporating the product water (QPWE.evap)
- Heating the product water (QPWE.water)
Calculate the consumption for each part and total (Qtotal).
Write the result in the table on page 3 of this exercise.
Compare the results with those you calculated before with the Mollier chart.
Answers :
a) Heat for the vapor in the supply air may be neglected.
Note that the temperature of the ingoing product water is 00C,
In this case the drying process is along the constant line for …………… .
b) u/i f)
The table on page 3 of this exercise can be completed as follows:
- wvapor.supplyi, hsupply, wvapor.exh, hexh and θdew.exh ; see Mollier-chart
- mexh =1 kg PWE : (wvapor.exh – wvapor.supply) kg vapor/kg dry air (=kg air/kg PWE)
- Q = mexh . (hexh – hsupply) kJ/kg PWE.
g) Calculating the heat consumption for each part:
given are φexh = 50% and θexh = 40, 60, 80 and 95oC; calculate p”vapor from: (θ
= θ”)
p”vapor = 0,611 x exp. (17,27 x θ”) : (237,3 + θ”) ;
Calculate wvapor.exh from: (Mvapor = 2x1+16=18 kg; Mair =
0,21x2x16+0,79x2x14=28,84 kg)
wvapor =
vapouro
vapour
air
vapour
pp
p
M
M
kg vapor/kg (dry) air
msupply= mexh = 1 kg PWE : (wvapor.exh – wvapor.supply) kg (dry) air/kg PWE
Qair.supply = msupply . cair . (θexh – θsupply) kJ/kg PWE
Qvapor.supply= msupply .wvapor.supply .cvapor . (θexh - θsupply) kJ/kg PWE
QPWE.evap = hRo – 2,4 . θu * kJ/kg PWE
QPWE.water = cWater . (θexh – 0) kJ/kg PWE
Qtotal = Qair.supply + Qvapor.suppl + QPWE.evap + QPWE.water kJ/kg PWE
Remarks:
* Approximating formula; see also steamtable
∆hair.supply = cair . (θexh - θsupply) kJ/kg (dry) air
∆hair.vapor = cvapor . (θexh - θsupply) kJ/kg vapor
∆hsupply.total = cair.(θexh-θsupply)+ wvapor.supply .(θexh-θsupply) kJ/kg (dry) air
∆hPWE.water = cWater . (θexh – 0) kJ/kg PWE
∆hPWE.evap = hRo – 2,4 . θu kJ/kg PWE ∆hPWE.total = cWater . (θexh – 0) + (hRo – 2,4 . θu) kJ/kg PWE
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 52
Exercise 3 (page 3) Relation heat consumption and exhaust temperature
Results calculations heat consumption for 1 kg product water (PWE)
Supply air (θsupply = 10oC; φsupply = 80%)
Temperature θsupply oC
Relative humidity φsupply %
Absolute humidity wvapor.supply g/kg
Enthalpy hsupply kJ/kg
10
80
6
25
10
80
6
25
10
80
6
25
10
80
6
25
Exhaust air ( φexh = 20%)
Temperature θexh oC
Absolute humidity wvapor.exh g/kg
Mass mex kg/kgPWE
Enthalpy hexh kJ/kg
Heat consumption Q kJ/kg H2O
Dew point θdew.exh oC
40
9
333
64
13.00
13
60
26
50
128
5.150
29
80
69
15,9
260
3.736
46
95
133
7,9
450
3.357
57,5
Exhaust air ( φexh = 50%)
Temperature θexh oC
Absolute humidity wvapor.exh g/kg
Mass mexh kg/kgPWE
Enthalpy hexh kJ/kg
Heat consumption Q kJ/kg H2O
Dew point θdew.exh oC
40
24
56
101
4.222
27,6
60
68
16,1
238
3.435
45,8
80
190
5,43
584
3.038
63,8
95
446
2,27
1.289
2.873
77,2
Heating supply air Q kJ/kg H2O
Heating vapor in supply air.Q kJ/kg H2O
Evaporating product water.Q kJ/kg H2O
Heating product water. Q kJ/kg H2O
Total. Q kJ/kg H2O
1.683
18
2.406
168
4.275
815
9
2.358
252
3.433
384
4
2.310
336
3.034
195
2
2.274
399
2.870
Exhaust air ( φexh = 80%)
Temperature θexh oC
Absolute humidity wvapor.exh g/kg
Mass mexh kg/kgPWE
Enthalpy hexh kJ/kg
Heat consumption Q kJ/kg H2O
Dew point θdew.exh oC
40
38,5
31
139
3.508
35,9
60
116
9,1
364
3.082
55,3
80
372
2,73
1.066
2.844
74,6
95
1.250
0,80
3.444
2.748
89,1
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 53
Exercise 3 (page 4) Relation heat consumption and exhaust air temperature
Heat consumption in kJ / kg PWE
12.000
11.000
10.000
9.000
8.000
7.000
6.000
5.000
4.000
3.000
2.000
30 40 50 60 70 80 90 100
Temperature exhaust air °C
Results calculations heat consumption in kJ / kg PWE
40%
%
80%
50%
0%
%
20%
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 54
7 IMPROVING QUALITY OF HEAT IN EXHAUST AIR
7.1 Increasing the exhaust air temperature
By increasing the temperature of the exhaust air, not only the heat consumption in the
drying section decreases, also the heat recovery potential increases with increasing
temperatures.
When the exhaust air temperature is increased and the relative humidity of this exhaust
air is not changed we may assume that the drying rate will not change.
Table 8 showed that when the exhaust temperature and the relative humidity in the
current situation are already rather high the heat savings will be small.
In this chapter we shall demonstrate that, though the heat savings will be small in
these cases, the quality of the exhaust heat will improve sharply and as a result of this
the heat recovery potential rises sharply.
In this chapter we shall demonstrate the increase of the heat recovery potential as well
for multi-cylinder dryers as for yankeedryers.
Hence we will discuss the possibilities to apply the recovered heat for:
- Pre-heating supply air
- Heating process water (head box water)
- Heating spray water (cleaning wires, felts etc)
- Space heating machine room
- Space heating other spaces
In exercise 6 in chapter 13 you can calculate the heat recovery potential in your
current situation and the exhaust heat quality improvement in your optimal situation.
7.2 Explanation heat recovery process in Mollier chart
In figures 7MC(R), 7MC(O) 7YC(R) and 7YC(O) Mollier-charts for heat recovery
processes for exhaust air from multi-cylinder and yankee dryers are depicted.
“MC” indicates multi cylinder, YC yankee cylinder, R is reference situation and O is
optimal situation.
These processes are described in paragraphs 7.3 and 7.4.
In this paragraph we shall give an explanation; the values in this explanation refer to
figure 7MC(R).
i1 – i4 = Heating drying air
Drying air is heated from 10oC to “430”oC. This happens mainly indirect by the cylinders
via the web (conductive) and direct by heating air for pocket ventilation. Air for pocket
ventilation is preheated (i1-i2) by heat recovery from the exhaust air (u1-u3). It is
assumed that during heating the moisture content of the air will not change. This
means that the heating process follows the line of constant moisture content wvap ( 6,1
g moisture/kg is the moisture content of the supply air). As a result of the heat in the
process-water the temperature of this water will be higher than 0oC; this means that
between i3-i4 no heating is required. When the process water temperature is for
instance 40 oC the distance between i3 and i4 can be calculated as follows:
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 55
(1 kg PWE * 4,2 kJ/(kg.oC) * 40oC) kJ/kg PWE : ((1000/(144-6)) kg air/kg PWE = 23
kJ/kg
In realty the process in multi-cylinder dryers will not reach a temperature of 430 oC.
The real process will be as depicted below. The heating-line i1-i4 is is supposed to be
the sum of all blue lines (in the same way the drying-line i4-u1 is supposed to be the
sum of all red lines). In this way a process that looks isothermal can be split up in a
combination of many small processes of constant moisture en constant enthalpy.
Real process in multi cylinder dryer
(isothermal, adiabatic or isenthalpic ?)
i4-u1 = Drying
Though the drying process is an adiabatic process, it is assumed to be isenthalpic so it
will follow the line of constant enthalpy. This is only about correct when the
temperature of the product is 0 oC; as we corrected already before for this temperature
the final result will be correct. During drying the temperature of the air decreases
(sensible heat) and at the same time the moisture content of the air increases (latent
heat). The sum of sensible heat and latent heat does not change; this means that the
enthalpy stays constant during the drying process. In u1 the temperature of the
exhaust air is 80oC, the dew point 59 oC, the enthalpy 463 kJ/kg and the relative humidity φ =40%.
u1-u3 = Heat recovery (HRC) from exhaust air (u1-u3) to supply air (i1-i2).
Assuming supply air (i1) is 10 oC, exhaust air (u1) is 80 oC and temperature efficiency
of the heat exchanger is 45%. The preheating of the supply air (i1-i2) can be calculated
as follows: 0,45 x (80-10) = 31,5 oC and θi2 = 31,5+10=41,5 oC.
The Mollier-chart shows that 32,2 kJ/kg is transferred from the exhaust air to the
supply air.
u3-u4 = Heat recovery (HRC) from exhaust air to process- & spraying water
Heat transfer between u3 and u4 is about (431–414=) 17,2 kJ/kg exhaust air.
Heat recover capacity
The amount of heat transferred between u1 and u4 per 1 kg product-water-evaporation
(PWE) is:
(1000 g PWE : (144-6)g PWE/kg air) * (463-414) kJ/kg air = 357 MJ/t PWE.
This is 12% of the energy consumption.
7.3 Improving heat recovery potential multi-cylinder dryers
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 56
In figures 7MCc and 7MCo the reference and optimal situation for the heat recovery
potentials are depicted in Mollier charts.
In both situations the temperature of the supply air is 10 oC and the relative humidity is
80%.
The realative humidity of the exhaust air is in both cases 40%; so we may assume that
the drying rate will stay about the same. In the reference situation the exhaust air
temperature is 80 oC and in the optimal situation this temperature is 92,6 oC.c The dew
point under these circumstances will be respectively 59 oC and 70 oC.
In both situations the temperature efficiency of the heat-exchanger for pre-heating the
supply air is 45% (see chapter 8 for explanation).
The fuelprice is in both situations 45,50 €/MWh and the steamboiler efficiency is 90%
In both situations the exhaust air is cooled down in the heat recovery till 58 oC; below
this temperature there are no applications for further heat recovery available.
Comparing the heat recovery potentials for both situations shows that there is a big
difference in heat recovery capacity. In case all exhaust heat with a temperature above
58 oC can be utilised for heat recovery (HRC) the amount of recovered heat in the
current and optimal situation will be respectively 12 and 56% of the heat consumption.
7.4 Improving heat recovery potential yankee-cylinder dryers
In figures 7YCc and 7YCo the reference and optimal situation for the heat recovery
potentials are depicted in Mollier charts.
In both situations the temperature of the supply air is 10 oC and the relative humidity is
80%.
The relative humidity of the exhaust air is in the current situation 0,20% and in the
optimal situation 1,00%; so we may assume that the drying rate will stay about the
same. In the current situation the exhaust air temperature is 300 oC and in the optimal
situation this temperature is also 300 oC. The dew point under these circumstances will
be respectively 58,8 oC and 88,3 oC.
In the reference situation the temperature efficiency of the heat-exchanger for pre-
heating the supply air is 30% and in the optimal situation 60%. (see chapter 9 for
explanation).
The fuel price is in both situations 45,50 €/MWh and the steam boiler efficiency is 90%
In both situations the exhaust air is cooled down in the heat recovery till 58 oC; below
this temperature there are no applications for further heat recovery available.
Comparing the heat recovery potentials for both situations show that there is a big
difference in heat recovery capacity. In case all exhaust heat with a temperature above
58 oC can be utilised for heat recovery (HRC) the amount of recovered heat in the
current and optimal situation will be respectively 47 and 95% of the heat consumption.
7.5 Demonstration energy-efficiency and heat recovery potential
The excel file “Demonstration” of the MED-program contains a demonstration program
for simulating multi-cylinder dryers and yankee-dryers.
For instance fill in:
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 57
“Demo MC(R)”: for exhaust air from dryer 83 oC and 40%, for exhaust air after HRC 60
oC, for process water temperature 40 oC and for the temperature efficiency of the
supply air heat recovery 50%
“Demo MC(O)”: for exhaust air from dryer 89 oC and 40%, for exhaust air after HRC 60
oC, for process water temperature 40 oC and for the temperature efficiency of the
supply air heat recovery 50%
The figures show that energy consumption is reduced from 2717 to 2678 J/g PWE
(PWE = Product Water Evaporation).
In case all exhaust heat with a temperature above 60 oC can be utilised for heat
recovery (HRC) the amount of recovered heat in the actual and future situation will be
respectively 15 and 38 % of the energy consumption.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 58
1,0 18,2 partial vapour pressure (pvap in kPa) 19,0 20,4
430 °C i4
PWE = productwater evaporation
θwb = wet bulbtemperature exhaust air
φ = relative humidity (%)
ŋθ = temp.-efficiency air heatexchanger
ŋθ = 45% 15
408 °C i3 23
40
440437
463
Exhaust air
80 °C U1
U2 u5 θwb=
59,0 °C 60,5
u3
40,0 431 3
2,2
58,0 °C u4
80
41,5 °C i2
100
57,7
414 17,2
49
357
Supply air i1
10 °C
25,5 32,2
12
6,1 136 absolute humidity (wvap in g/kg air) 144
=i1 =u4 =u2
(Fuelprice 45,50 €/MWh)
Moisture increase per kg dry air: ∆w = wu1-wi1 = 138 g moisture / kg air (ŋst.boiler 90 % )
Required air per kg PWE: 1000 g : ∆w g/kg = 7,23 kg air / kg PWE
Cons.with HRC supplyair: 7,23 x (hi3 - hi2) = 2765 kJ/kg PWE Cost: 38,83 €/ t PWE
HRC when cooling exhaust air till 58 °C is 12 % of heat consumption
Consumption dryer - savings processwater = 2409 kJ/kg PWE Cost: 33,82 €/"t PWE"
Dewpoint exhaust air
Temperature exhaust air
Figure 7MC(R) Example of the reference Multi Cylinder drying
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 59
1,2 18,2 partial vapour pressure (pvap in kPa) 31,1 32,7
787 °C i4
PWE = productwater evaporation
θwb = wet bulbtemperature exhaust air
φ = relative humidity (%)
ŋθ = temp.-efficiency air heatexchanger
ŋθ = 45%
727 °C i3 63
55
772801
835
Exhaust air
92,6 °C u1
u2 u5 θwb=
70,0 °C 71,0
u3
40797 3
8
58,0 °C u4
80
47,2 °C i2
100
63
414
383
421
1551
Supply air (i1)
10,0 °C
25,5 38 56
6,1 136 absolute humidity (wvap in g /kg air) 278
i1 u4 u2
(Fuelprice 45,5 €/MWh)
Moisture increase per kg dry air: ∆w = wu1-wi1 = 271 g moisture / kg air (ŋst.boiler 90 % )
Required air per kg PWE: 1000 g : ∆w g/kg = 3,68 kg air / kg PWE
Cons. with HRC supplyair: 3,68 x (hi3 - hi2) = 2612 kJ/kg PWE Cost: 35,94 €/ t PWE
HRC when cooling exh. air till 58,0 °C is 56 % of heat consumption
Consumption dryer - savings processwater = 1061 kJ/kg PWE Cost: 14,60 €/"t PWE"
Dewpoint exhaust air
Temperature exhaust air
Figure 7MC(O) Example of the optmal Multi Cylinder drying process
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 60
1,0 18,2 partial vapour pressure (pvap in kPa) 18,9 40,0
694 °C i4
PWE = productwater evaporation
θwb = wet bulbtemperature exhaust air
φ = relative humidity (%)
ŋθ = temp.-efficiency air heatexchanger
ŋθ = 30% 15
672 °C i3 23
40
716432
739
Exhaust air
300 °C U1
U2 u5 θwb=
58,8 °C 75,8
u3
0,2
0650 8
8,8
58,0 °C u4
80
97 °C i2
100
114,4
414 236
325
2377
Supply air i1
10 °C
25,5 88,8
47
6,1 136 absolute humidity (wvap in g/kg air) 143
=i1 =u4 =u2
(Fuelprice 45,50 €/MWh)
Moisture increase per kg dry air: ∆w = wu1-wi1 = 137 g moisture / kg air (ŋst.boiler 90 % )
Required air per kg PWE: 1000 g : ∆w g/kg = 7,32 kg air / kg PWE
Cons.with HRC supplyair: 7,32 x (hi3 - hi2) = 4403 kJ/kg PWE Cost: 61,83 €/ t PWE
HRC when cooling exhaust air till 58 °C is 47 % of heat consumption
Consumption dryer - savings processwater = 2026 kJ/kg PWE Cost: 28,46 €/"t PWE"
Dewpoint exhaust air
Temperature exhaust air
Figure 7YC(R) Example of the reference Yankee Cylinder drying process
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 61
1,2 18,2 partial vapour pressure (pvap in kPa) 65,9 81,1
3.694 °C i4
PWE = productwater evaporation
θwb = wet bulbtemperature exhaust air
φ = relative humidity (%)
ŋθ = temp.-efficiency air heatexchanger
ŋθ = 60%
3.507 °C i3 195
40
3.669
3.195
3.864
Exhaust air
300 °C u1
u2 u5 θwb=
88,3 °C 93,7
u3
1
3.686 178
58,0 °C u4
80
184 °C i2
100
203
414
3.2
72
3.4
50
2974
Supply air (i1)
10,0 °C
25,5 178
95
6,1 136 absolute humidity (wvap in g /kg air) 1166
i1 u4 u2
(Fuelprice 45,5 €/MWh)
Moisture increase per kg dry air: ∆w = wu1-wi1 = 1160 g moisture / kg air (ŋst.boiler 90 % )
Required air per kg PWE: 1000 g : ∆w g/kg = 0,86 kg air / kg PWE
Cons. with HRC supplyair: 0,86 x (hi3 - hi2) = 2988 kJ/kg PWE Cost: 41,12 €/ t PWE
HRC when cooling exh. air till 58,0 °C is 95 % of heat consumption
Consumption dryer - savings processwater = 14 kJ/kg PWE Cost: 0,19 €/"t PWE"
Dewpoint exhaust air
Temperature exhaust air
Figure 7YC(O) Example of the optimal Yankee Cylinder drying process
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 62
8 SELECTION OF HEAT EXCHANGERS
8.1 Design and selection
Sequence and design of heat exchangers should be determined in consultation with
the designer of this equipment. Special attention should be paid to anti fouling
measures.
Figure 8 (example from file “Calculations” MED) shows possible configurations of the
heat exchangers in the heat recovery.
Exhaust heat can be applied, for instance, as follows:
- preheating supply air (air for pocket ventilation)
- keeping process water at the desired temperature without applying fresh steam
- heating spray-water for cleaning wires and felts; if necessary in combination with
the exhaust gasses of the steam-boilers
- heating the machine room by the glycol-system;
Selection heat exchangers:
- closed heat exchanger
- open heat exchanger
- half open heat exchanger
Criterion for “low temperature” applications of heat exchangers:
- counter-current flow or counter-current/cross flow
- temperature difference between “water in” and “air out”
- temperature-efficiency air/air heat exchangers
Selection of heat exchangers
“Direct contact” heat exchangers, like scrubbers, perform very good heat transfer and
are also preferred from a point of view of investments. The absorption of air in the
process water may be a disadvantage.
High quality exhaust heat means that the vapor content is high. This results in
condensing heat exchangers which have even higher heat transfer coefficients.
In direct counter-current flow heat exchangers the temperature of the outgoing water
flow may reach the temperature of the outgoing exhaust air.
8.2 Indicative k-values for heat-exchangers
Indicative k-values for the total heat transfer in W/(m2.K) are as follows:
- air/air typical value: 8 ( 5 - 35)
- water/air typical value: 12 (10 - 70)
- steam/air typical value: 14 (10 - 80)
- water/water typical value: 325 (300 - 1200)
- steam/water typical value: 1050 (1000-4000)
(= steam-condenser with thin cupper pipes)
- exhaust gas boiler (15-50)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 63
Heat consumption in GJt or MJt mdry.air mvapor θ θdew Q
Steam Cyl.+HE I&II 29,5 GJt / h 24,5 1,5 44 44 5,0
Steam Cyl.+HE I&II 8,2 MW
Prod.w.evap.(PWE) 10,8 t PWE / h HRC IV 40,0 °C 100 m3/h
Net consumption 2721 MJ / t PWE glycol
Heat consumption in ton steam/h 33,9 °C HE V 65 °C
Steam pressure 4,9 bar ∆Q=-0,68 MW ∆Q= 3,46 MW 2,778
Steam temperature 160,0 oC Steam/glycol
Steam enthalpy 2770 kJ / kg 24,5 1,3 41 41 4,3
Condens.pressure 1,0 bar kg/s kg/s °C °C MW
Condens.temperature 89,8 oC
Condens. enthalpy 377 kJ/kg HRC III 13 °C 120 m3/h
Ton steam / hour 12,3 t / h spraywater
Ton steam / t PWE 1,14 t / t PWE 49,3 °C HE IV 50 °C
∆Q= 5,08 MW ∆Q= 0,10 MW
Gas 0,27 €/m3o ŋboiler 100 % Steam/sprayw.
Heatcosts 8,45 €/GJt 24,5 3,1 56,3 56,3 9,4
Dryers
Gross consumption 25,68 €/t PWE HRC II 45,0 °C 2403 m3/h
HRC for supply air 2,70 €/t PWE processwater
Net consumption 22,98 €/t PWE 45,0 °C HE III 45,5 °C
Processwater ∆Q= 0,00 MW ∆Q= 1,32 MW
Gross consumption 3,7 €/t PWE Steam/processw.
HRC in dryer 0,00 €/t PWE 24,5 3,07 56,3 56,3 9,4
Net consumption 3,7 €/t PWE
Spraywater
Gross consumption 14,52 €/t PWE
HRC in dryer 14,25 €/t PWE
Net consumption 0,27 €/t PWE Supply air mdry.air mvapor θ θdew Q
Spaceheating machine hall 24,5 0,1 10 6,0 0,6
Gross consumption 2,58 €/t PWE HRC I kg/s kg/s °C °C MW
HRC in dryer -1,77 €/t PWE supply air
Net consumption 4,35 €/t PWE ∆Q= 0,96 MW
Spaceheating other
Gross consumption 2,65 €/t PWE 24,5 0,1 48,5 6,0 1,6
HRC in boilerhouse 2,64 €/t PWE
Net consumption 0,01 €/t PWE HE II
Total net consumption Condens./air HRC = heat recovery
Gross 49,14 €/t PWE HE I HE = heat exchanger
HRC 17,82 €/t PWE Steam/air PWE=ProductWaterEvap
Net 31,31 €/t PWE ∆Q= 1,2 MW
24,5 0,1 95 6,0 2,7
24,5 3,15 80 57 10,3
Exfiltration air Infiltration air 0,0 0,0 10 6,0 -
95,0 5,8 112
24,5 3,15 80 57 10,3 24,5 0,1 95,0 6,0 2,7
Paper in (temp. 45 oC) PM1 Pre-dryer PWE= 3,01 kg/s
v 1.000 m/min dm 66,6 %
width 5,00 m
bonedry 54,9 g/m2 Condensate out
bonedry 16,47 t/h Steam cylinders in
dry-m. 46,3 % ∆Q= 7,0 MW
dry a
ir
vapor
tem
peratu
re
dew
poin
t
heat
Ex
ha
ust
air
Figure 8 Configuration heat recovery for exhaust air drying section
(from file “Calculations MED”)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 64
9 HEATING SUPPLY AIR
9.1 Purpose heating supply air
An option to recover the heat of the exhaust air is to pre-heat the supply air of the
drying section first and subsequently heat the process water, spray-water and glycol for
space heating.
As already stated in paragraph 5.5 correct distribution of the the supply air is
necessary. Correct distribution will improve both drying rate and sheet uniformity.
In multi-cylinder dryers the web is heated by conductive heat transfer from the steam
heated cylinders. Pocket ventilation is one of the concepts to improve the drying rate
and sheet uniformity. Because air velocities are low the convective heat transfer from
the pocket air is negligible.
A suitable supply air temperature is 90 – 95 oC; about the exhaust air temperature.
Testing showed only negligible increase in evaporation rates while specific heat
consumption increased.
In yankee dryers, however, air speeds of more than 100 m/s are often maintained. In
this case the heat transfer has an impingement character and will be considerably.
Figure 2b shows that at 500 oC and air velocities of more than 100 m/s drying rates of
up to 150 kg/(m2.h) are possible.
Pre-heating supply air with exhaust air is already common practice. For economic
reasons the temperature efficiencies of the heat exchangers are seldom higher than
60%.
9.2 Temperature-efficiency air-air heat exchangers
The efficiency of heat recovery from the exhaust air to preheat the incoming air
depends on the efficiency of the (air-air) heat exchanger.
Temperature efficiency values are employed to calculate the amount of heat transferred
in air to air heat recovery equipment.
For definition temperature efficiency see figure 9.
9.3 Calculating heat consumption supply air
In table 9 is shown how the heat recovery from the exhaust air and the additional
steam heating is calculated.
The data in the white cells are obtained from field measurements:
- Mass supply air to heatrecovery HRC I as percentage of the drying air mass (column b) - Mass exhaust air to heatrecovery HRC I as percentage of the drying air mass (column l)
- Temperatures and dewpoints supply air and exhaust air for the whole product range
- Temperature efficiency of the heat exchanger
- Temperature supply air after steamheater
The data in the coloured cells are calculated with the formulas from the formula library
in table 3.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 65
Figure 9 Temperature efficiency heat exchanger
Table 9 Calculations heatrecovery and steam heating supply air
a b c d e f g h i j k l m n o p q r s t u v w x y
Supply air after HRC I Exhaust air after HRC I
Mass s
upply
air
to
HR
C in %
of
mdry
Supply
air
consum
ption
Dew
poin
t
Tem
pera
ture
Abs.
hum
idity
Enth
alp
y
Dew
poin
t
Tem
pera
ture
Abs.
hum
idity
Enth
alp
y
Mass e
xh.
Air
to
HR
C in %
of
mdry
Exhaust
air
consum
ption
Dew
poin
t
Tem
pera
ture
Abs.
hum
idity
Enth
alp
y
Dew
poin
t
Tem
pera
ture
Abs.
hum
idity
Enth
alp
y
Tem
p.e
ffic
iency
heat
exchanger
Heat
reception in
heat
recovery
HR
C I
Tem
p.
aft
er
ste
am
-heate
r
Heat
reception in
ste
am
heat
exchanger
%msupply ∆mi2 θdew θ wvapour h θdew θ wvapour h % mexh ∆mu3 θdew θ wvapour h θdew θ wvapour h ηθ ∆hiI θi3 ∆HHE
% kg/s oC oC g/kg J/g oC oC g/kg J/g % kg/s oC oC g/kg J/g oC oC g/kg J/g % MW °C MW
60 80 26,6 6,7 10,0 6,1 25 6,7 46,0 6,1 62,3 90 29,9 52,0 82,0 97 340 52,0 54,5 97 307 50 0,98 95 1,33
80 80 33,2 6,7 10,0 6,1 25 6,7 46,5 6,1 62,8 90 37,4 53,0 83,0 103 356 53,0 55,3 103 323 50 1,24 95 1,65
90 80 32,4 6,7 10,0 6,1 25 6,7 47,0 6,1 63,3 90 36,5 54,0 84,0 109 373 54,0 56,2 109 340 50 1,23 95 1,59
100 80 30,5 6,7 10,0 6,1 25 6,7 47,5 6,1 63,8 90 34,3 55,0 85,0 115 391 55,0 57,1 115 357 50 1,17 95 1,48
110 80 28,7 6,7 10,0 6,1 25 6,7 48,0 6,1 64,3 90 32,3 56,0 86,0 122 410 56,0 58,0 122 376 50 1,11 95 1,38
120 80 27,0 6,7 10,0 6,1 25 6,7 48,5 6,1 64,8 90 30,4 57,0 87,0 129 431 57,0 58,9 129 396 50 1,06 95 1,28
130 80 25,3 6,7 10,0 6,1 25 6,7 49,0 6,1 65,3 90 28,5 58,0 88,0 136 452 58,0 59,9 136 417 50 1,01 95 1,19
91,8 80 29,2 6,7 10,0 6,1 25 6,7 47,3 6,1 63,6 90 32,8 54,8 84,7 113 386 54,8 56,8 113 353 50 1,11 95 1,42
Exhaust air
Pro
duct
code
Heat recovery supply air
g air
dry
/m2
Supply air before HRC I
Supply air
Exhaust air before HRC I
ηθ = temperature efficiency of the heat exchanger
m = mass (kg)
h = enthalpy of the humid air (kJ/kg dry air)
wvapor = moisture content (g/kg dry air)
θ = temperature (oC)
c = specific heat (kJ/(kg.oC))
When: mexh . cexh < msupply . csupply
supply1exh1exh
supply1supply2supplysupply
.c.m
c.m
exh
(27)
When: mexh . cexh => msupply . csupply
supply1exh1
supply1supply2
supply1exh1supplysupply
supply1supply2supplysupply
)(.c.m
)(c.m
(28)
Exhaust air in (heat delivery)
mexh, θexh1, wvapor.exh1,
hexh1, cexh
Exhaust air out
mexh, θexh2, wvapor.exh2,
hexh2, cexh
Supply air in (heat reception)
msupply, θsupply1, wvapor.supply1, hsupply1, csupply
Supply air out
msupply, θsupply2, wvapor.supply2,
hsupply2, csupply
Heat
exchan
ger air - air
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 66
10 PROCESSWATER HEATING
10.1 Purpose of heating processwater
The purpose of heating processwater is to obtain a higher dry matter content of the
web after the press section. This will decrease the amount of water to be evaporated in
the drying section and also result in a lower heat consumption in the drying section.
Further heating process water will improve the runnability in many mills.
There are many advantages and disadvantages:
Advantages
- Steam savings due to higher dry matter content after press section in some cases
- Lower specific energy consumption for pulping and vacuum
- Improved felt- and wire cleaning
- Decreased “picking” on cylinders dryer
- Lower biological activity in process water circulation loop (θ >50 oC; to prevent
legionella pneumophila θ >55 oC)
- Lower specific water consumption
Disadvantages
- Higher temperatures waste water and higher pipe temperatures
- In case of direct contact heat exchangers (=scrubbers): after-scrubbing necessary,
extra maintenance demisters, air in process water
- Heat losses by spontaneous water-evaporation in wire and press section
10.2 Increase dry solids content after press section
The most important advantage is the increase of the dry solids content of the web after
the press section.
Heating the process water will lower energy use since an increased process water
temperature results in a lower viscosity of this water. The lower viscosity leads to
increased drain velocity in the wire and press section which results in some mills in a
higher dry solids content after the press section.
Calculations show that for each percent increase in the dry solids content, the amount
of water to be evaporated decreases with 4%. As a rule of thumb, a temperature
increase of 10°C yields an increase of approximately 1% in dry solids content of the
web after the press section (Cutshall and Hudspeth, 1987) However the precise
increase depends on several conditions (Patterson and Iwasama, 1999, Szikla, 1992
and Maloney et al., 1998).
See example in exercise 4.
The following assumptions based on several of the above mentioned sources:
- Process-water from 40 oC to 50 oC, increase d.s. 1,5%, (steam saving 6 %)
- Process-water from 50 oC to 60 oC, increase d.s. 1,3%, (steam saving 5,2%)
- Process-water from 60 oC to 70 oC, increase d.s. 1,1%, (steam saving 4,4%)
- Process-water from 70 oC to 80 oC, increase d.s. 0,9%, (steam saving 3,6%)
After the stock preparation the stock flow enters the headbox of the papermachine with
a consistency between about 0,2 and 1,3 %. After drainage on the wire or forming
section the web consistency increases tot 15 till 26 %. After the press section
consistency is called dry solids content (ds). The dry solids contents after the press
section is between 40 and 55 %.
After the press section the web enters the drying section where the remaining water
thermally is removed till the dry solids content is between 91 and 95 %.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 67
10.3 Spontaneous water evaporation process water
The most important disadvantage of process water heating is the sharp increase of the
spontaneous water evaporation in the wire and press section.
This heat loss should be compensated in order to keep the process water at a constant
high temperature.
The spontaneous water evaporation is a linear function of the saturated partial vapor
pressure and the relation between both follows from the formula:
pvap = 0,611 exp ((17,27 x θ”)/(237,3 + θ”) (29)
Figure 10 depicts an example of spontaneous water evaporation (Qevap.wire) for different
process water temperatures.
Exercise 4 Example heat savings after increasing ds-contents after press section
The product water removed in the drying section can be calculated with formula
(18):
PWE = (100/dsin – 100/dsout) x Pbone-dry (kg water/s or ton water/h)
Given:
dsout = 92% (dry solids content of the paper leaving the drying section)
P bone-dry = 1 ton/h (mass of the product dried in the drying section)
dsin 50 oC = 48,0% (dry solids content of the web entering the drying section θ=50 oC)
dsin 60 oC = 49,3% (dry solids content of the web entering the drying section θ=60 oC)
Question:
Calculate PWE (product water evaporation in ton/h) at dsin 50 oC=48,0% and dsin 60
oC=49,3%
Answer:
PWE at dsin 50 oC=48,0% = (100/48,0 – 92/100) x 1 = 0,996 t PWE/h
PWE at dsin 60 oC=49,3% = (100/49,3 – 92/100) x 1 = 0,945 t PWE/h
A ds- increase of 1,3% results in a PWE-decrease of 5,1% this results in a heat
saving of (5,1/1,3=) about 4% per 1% ds increase in the press section.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 68
Figure 10 Indication spontaneous water evaporation in wire & press section
10.4 Calculating heat consumption processwater
In order to maintain a constant process water temperature, the energy losses need to
be compensated. In table 10 is shown how the heat recovery from the exhaust air and
the additional steam heating is calculated.
The data in the white cells are obtained from field measurements.
The data in the coloured cells in columns t u/i ae are calculated with the formulas from
the formula library in table 3.
The other data are calculated as follows:
∆Hgross = Wweb.width x Qevap.wire x 0,001 x (hRo-2,4xθ) /3600 (s/h) (30a)
∆Hint.pump = mprocess x 0,001 x ∆Hpump
∆Hint.refiner= Pdryer x 0,001 x ∆Hrefiner (30b)
∆Hnet = ∆Hgross - ∆Hint.pump - ∆Hint.refiner
θin(gross) = {∆Hgross x 3600(s/h) + mprocess x 4,2 x θout }/{mprocess x 4,2} (30c)
θin(net) = {∆Hnet x 3600(s/h) + mprocess x 4,2 x θout }/{mprocess x 4,2 } (30d)
Stock temperature oC
Sponta
neous w
ate
r evapora
tion o
n w
ire &
pre
ss
section in k
g w
ate
r /
(h .
m w
eb w
idth
)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 69
Where:
- Wweb.width = paper web width in m (column c)
- Qevap.wire = spontaneous water evaporation in wire & press section in kg/(h.m)
- θ = temperature process water after wire in oC; column n
- hRo = heat of evaporation (kJ/kg evaporated water); see steam table
- mprocess = process water flow in m3/h (column g)
- Pdryer = wire production in tbone.dry/h (column b)
- dsheadbox = % dry solids content in head box (column d)
- R = % retention on wire section (column e)
- f = - multiply factor for calculating process water (column f)
- ∆Hrefiner = electricity consumption refiners based on ton bone dry wire production
in kWh/tonbone.dry production (column j)
- ∆Hpump = electricity consumption head box pumps based on process water flow
in kWh/m3 process water (column k)
- θout = temperature processwater after wire section in oC (column n)
- ∆Hgross = heat losses on wire section caused by spontaneous water
evaporation in MW (column i)
- ∆Hint.pump = heat delivery by electricity consumption head box pumps based
on process water flow in MW (column m); is part of total consumption
- ∆Hint.refiner = heat delivery by electricity consumption refiners based on ton bone dry
wire production in MW (column l); is part of total consumption
- ∆Hnet = net heat losses in wire & press section to be compensated by
heatrecovery or steam heating in MW (column n)
- θin(gross) = (virtual) temperature processwater before wire section
calculated on base of gross heat loss in oC (column p)
- θin(net) = real temperature processwater before wire section
calculated on base of net heat loss in oC (column q)
When there is a lot of refiner heat the process water temperature may rise above the
desired temperature of θout = 50oC. When the temperature becomes for instance 60 oC
the increase in the spontaneous water evaporation can be calculated from the formula
(29) by calculating pvap at 50 and 60 oC : pvap.50oC and pvap60oC.
Formula (29): pvap = 0,611 exp ((17,27 x θ”)/(237,3 + θ”)
When the spontaneous water evaporation at 50 oC is 1000 kg/((h.m) it will be at 60
oC: Qevap.wire.60oC = Qevap.wire.50oC x (pvap.60oC : pvap50oC)
Heat calculations can be simplified by applying the following specific units:
Amount process water expressed in kg process water per kg PWE:
mprocess.water/PWE = mprocess.water / PWE ton process water/ton PWE
Amount spray water expressed in kg spray water per kg PWE:
msrray.water/PWE = mspray.water / PWE ton spray water/ton PWE
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 70
Table 10 Calculations heatrecovery and steam heating process water (MED)
a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae ad
50 oC is 1.000kg/(h
.m)D
ry solids content
in head box
Retentio
n
Multip
ly-factor for
calc
. processw
ater
Process w
ater
(head box w
ater)
Water evap. in
w
ire &
press sectio
n (kg/(h.m
wir
e w
idth)
Gross lo
ss by spontane-
ous w
ater evaporatio
n
in w
ire &
press sectio
n
Ele
ctr.cons. refin
ers per
ton bone dry dryer in
Ele
ctr.cons. pum
ps per
ton processw
ater
Internal heat productio
n
processw
. by refin
ers
Internal heat productio
n
in processw
. by pum
ps
Net lo
ss by spontaneous
water evaporatio
n in
wir
e &
press sectio
n
Tem
perature after w
ire
Tem
perature before
wir
e (based on ∆
Hgross )
Tem
p.before w
ire(based
on ∆
Hnet i.s.o. ∆
Hgross)
Processw
.expr. in
g
pro
cess w
ater
/g PW
E
Part of m
process c
overed
by steam
Part of m
process c
overed
by h
eatrec. d
ryer
Mass exh. air
to H
RC
II
in %
of m
dry
Exhaust air
consum
ptio
n
Dew
poin
t
Tem
perature
Absolu
te hum
idity
Enthalp
y
Dew
poin
t
Tem
perature
Absolu
te hum
idity
Enthalp
y
Heat receptio
n in
heat
recovery H
RC
II
Heat receptio
n in
steam
heat exchanger
- PdryerWweb
ds(hb) R f mproc WWE ∆Hgross ∆Hrefin ∆Hpump ∆Hint.refiners ∆Hint.pump ∆Hnet θout θin θin mproc - -%
mexh
∆mu4 θdew θ wvapour h θdew θ wvapour h ∆HHRCII ∆Hsteam
g air
dry
/m2
t
bone
dry/h
m % % - m3/hkg/
(h.m)MW
kWh
/tbonedr
kWh/
tproc.w.
MW MW MW oC oC oCg/g
PWE
0/100
%
0/100
%% kg/s °C °C g/kg J/g °C °C g/kg J/g MW MW
1.000 50,0
60 16,5 5,00 0,70 83,0 1,05 2.958 1.000 3,29 90 0,07 1,48 0,21 1,60 50,0 50,95 50,46 132 100 0 90 69,9 50,2 58,5 88 289 50,2 58,6 88 289 0,00 1,60
80 22,0 5,00 0,75 84,0 1,05 3.636 1.000 3,29 90 0,07 1,98 0,25 1,06 50,0 50,78 50,25 122 100 0 90 86,1 51,2 57,0 93 301 51,2 57,0 93 301 0,00 1,06
90 22,9 5,00 0,80 85,0 1,05 3.503 1.000 3,29 90 0,07 2,06 0,25 0,98 50,0 50,80 50,24 113 100 0 90 85,1 52,2 57,7 99 316 52,2 57,7 99 316 0,00 0,98
100 22,9 5,00 0,85 86,0 1,05 3.267 1.000 3,29 90 0,07 2,06 0,23 0,99 50,0 50,86 50,26 106 100 0 90 79,1 53,2 58,5 105 332 53,2 58,5 105 332 0,00 0,99
110 23,0 5,00 0,90 87,0 1,05 3.052 1.000 3,29 90 0,07 2,07 0,21 1,01 50,0 50,92 50,28 99 100 0 90 75,1 54,2 59,2 111 349 54,2 59,2 111 349 0,00 1,01
120 23,1 5,00 0,95 88,0 1,05 2.871 1.000 3,29 90 0,07 2,08 0,20 1,01 50,0 50,98 50,30 93 100 0 90 70,0 55,2 60,0 117 367 55,2 60,0 117 367 0,00 1,01
130 23,0 5,00 1,00 89,0 1,05 2.691 1.000 3,29 90 0,07 2,07 0,19 1,03 50,0 51,05 50,33 88 100 0 90 67,0 56,0 60,7 123 381 56,0 60,7 123 381 0,00 1,03
91,8 21,6 5,00 0,830 85,83 1,05 3.155 1.000 3,29 90 0,07 1,94 0,22 1,12 50,0 50,89 50,31 108 100 0 90 76,3 52,9 58,6 103 328 52,9 58,6 103 328 0,00 1,12
Paper w
eb w
idth
Quantity processwaterLosses in wire-&press-section
(evaporation loss at
Heat sources for
processwater
Exhaust air
(from HRC I pre-& after dryers)
Exhaust air (to HRC III
pre-& after dryers)
Heat rec.
proc. water
Product code
Input dryer
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 71
Heating headbox water 1289 m3/h
On the processwater side all heatexchangers HRC II are connected in parallel
The processwater flow is proportional to the waterevaporation in each drying section
1289
mwater4= 358 kg/s mwater5= 358 kg/s
dilution θwater4= 55,0 oC HRC II θwater5= 57,0 oC Att. temperature headboxwater out
Steamconsumption 0,00 MW water Hwater4= 82,7 MW 2,95 Hwater5= 85,6 MW Maximum θwater5 = about 60,6 oC
p(bar) = 4,85 temp. (oC) =160 tank Check with designer heat exchanger
steam (J/g) = 2770 cond.(J/g)= 237
Steamconsumption 0,00 t/h Exhaust air MW Exhaust air
363 kg stock/s mG= 20,5 kg/s mG= 20,5 kg/s
1074 kg water/s θ= 60,7 oC θ= 65,6 oC
251 MW θdew out= 60,7 oC θdew in= 65,6 oC
55,7 oC
mbone dry 1= 4,15 kg stock/s Spontaneous waterevaporation
mwater 1= 111,0 kg water/s 1,9 kg water/s
Refiner dry matter 1= 3,60 % dm Headbox pump (incl. refiners) wire- 4,42 MW
θ1= 55,0 oC 1,47 MW section Retention: press-
Hwater1= 25,6 MW Thin stock 2578 m3/h head 83 % section To dryer-section
Thick stock fwater 1= 26,78 5,05 mbone dry 2= 5,05 kg stock/s box mbo.dry3= 3,99 kg stock/s
716 kg water/s mwater 2= 716,0 kg water/s mwater 3= 4,7 kg water/s
0,7 % dm dry matter 2 = 0,70 % dm dry s. 3 = 46 % dm
55,7 oC θ2= 56,5 oC θ3= 55,0oC
mbone dry 5= 0,90 kg stock/s 168 MW Hwater2= 169,8 MW Hwater3= 1,08 MW
mwater 5= 605,0 kg water/s
dry matter 5 = 0,149 % dm
θ5= 55,0 oC
Hwater5= 139,8 MW
fwater 5= 670,84
mbone dry 6= 0,16 kg stock/s mbone dry 4= 1,06 kg stock/s
mwater 6= 104,5 kg water/s mwater 4= 709,5 kg water/s
dry matter 6 = 0,15 % dm dry matter 4 = 0,15 % dm
θ6= 55,0 oC θ4= 55,0 oC
Hwater6= 24,1 MW Hwater4= 163,9 MW
To thick stock preparation
Inputdata 376,0339 Inputdata Inputdata
Final productweight 90 g a.d./m2 Dry matter input drying section 46,0 % Exhaust air HE in & out in out
Basisweight 86 g b.d./m2 Dry matter output drying section 97 % Dry mass exhaust air 20,5 20,5 kg/s
Input drying section 14,4 t b.d./h Evaporation in wire &press section 1.350 kg/(h.m) Temperature exhaust air (θ) 65,6 60,7 oC
Input drying section 4,0 kg b.d./s Wire width (WW) 5,00 m Dew point exhaust air (θdew) 65,6 60,7 oC
Dry matter content thick stock 3,60 % Evaporation heat (EH) 2.357 kJ/kg Heattransfer in heatexchanger HE 2,95 MW
Dry matter content thin stock 0,70 % Powercons. headbox pump and refiners 1,47 MW Mass head box water 716,0 kg/s
Retention wire section 83 % Temperature processwater after wire 55 oC Mass HRCwater/mass head box water *** 0,500 -
Multiply-factor for calc. processwater 1,05 - Steam consumption heating processwater 0,00 MW θdew in (exh.air) - θwater5 out HE=minimal 5,0 oC
Maximum mass water to heat-exchanger 716 kg/s Steampressure and steamtemperature 4,85 160 oC *** Evaporation in wire- & press-section also changes
Figure 11 Simplified diagram for process water (MED)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 72
10.5 Simplified diagram for process water loop
Figure 11 shows a simplified diagram for the process water loop of the paper machine.
There are two reasons why there is always an excess of water present in the paper
machine loop. First, the paper machine loop is continuously fed with fresh water, used for
spraying and cleaning wires and felts. Secondly, the incoming water content of the stock
is higher than the water content in the sheet after the press section.
This excess water is sent as make-up water to the stock preparation, thus following the
counter current principle.
By replacing the input values in the white cells of figure 11 heat and electricity savings
can be simulated:
- Keeping the refreshing by spray water as low as possible (for instance < 5 m3 per ton
wire production). In chapter 11 the heating of spray water will be discussed.
- By replacing the 1,0%-value in the white cell in figure 11 by 3,6% the amount of
excess water that is sent back to the stock preparation will reduce from 1640 m3/ to
376 m3/h.
- Keeping the dry matter content of the thin stock as high as possible. By replacing the
0,7%-value in the white cell in figure 11 by 1,2% the amount of head box water in
the machine loop will reduce from 2578 m3/ to 1496 m3/h.
- Keeping the multiplier f = “mass HRC water / mass head box water” as low as
possible:
f = 1,00 > mass HRC water = 2578 m3/h; water is heated from 55,0 to 56,0 oC
f = 0,50 > mass HRC water = 1289 m3/h; water is heated from 55,0 to 57,0 oC
f = 0,25 > mass HRC water = 644 m3/h; water is heated from 55,0 to 58,9 oC
At lower water flows temperature differences increase; this is less favorable for the
efficiency of the heating process.
Electricity savings will be discussed in chapter 14.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 73
11 SPRAYWATER HEATING
11.1 Purpose of heating spray water
Spray water is used for cleaning wires, felts etc. For good cleaning results the
temperature of the spray water should be at least equal to the temperature of the
process water.
Further heating of the spray water will improve the runnability.
A second function of the spray water is refreshment of the machine water loop.
11.2 Calculating heat consumption spray water
Because most fresh water is first used for cooling purposes the temperature will be 5 till
10 oC higher than the source and will be about 22 oC.
In table 11 is shown how the heat recovery from the exhaust air and the additional
steam heating is calculated.
The data in the white cells are obtained from field measurements.
The data in the coloured cells in columns “t” u/i “ae” are calculated with the formulas
from the formula library in table 3.
The temperature difference between the dew point of the exhaust air and the spray
water after the heat exchanger is set at 7 oC.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 74
Table 11 Calculations heatrecovery and steam heating spray water (MED)
a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab
Spraywater; θ=55,0oC; ∆θ exh. HRC & spr.water =7,0
oC
From HRC dryers
- mspray θin θout Qspray - θin θout - θin θout - θin θout
%
mexh
∆mu4 θdew θ wvapour h θdew θ wvapour h mw2 QsprayHRC Qspray BH Qspray ST
- m3/h oC oC MW on/off oC oC on/off oC oC on/off oC oC % kg/s °C °C g/kg J/g °C °C g/kg J/gg w/g
PWEMW MW MW
60 130 22 55,0 5,01 on 22,0 42,3 off 42,3 42,3 on 42,3 55,0 90 69,9 50,2 58,6 88 289 47,4 47,2 75 243 5,79 3,26 0,00 1,74
80 130 22 55,0 5,01 on 22,0 43,9 off 43,9 43,9 on 43,9 55,0 90 86,1 51,2 57,0 93 301 48,8 48,7 82 261 4,36 3,41 0,00 1,59
90 130 22 55,0 5,01 on 22,0 45,0 off 45,0 45,0 on 45,0 55,0 90 85,1 52,2 57,7 99 316 49,8 49,7 86 274 4,20 3,57 0,00 1,44
100 130 22 55,0 5,01 on 22,0 45,9 off 45,9 45,9 on 45,9 55,0 90 79,1 53,2 58,5 105 332 50,6 50,4 90 285 4,20 3,72 0,00 1,29
110 130 22 55,0 5,01 on 22,0 46,9 off 46,9 46,9 on 46,9 55,0 90 75,1 54,2 59,2 111 349 51,4 51,3 95 297 4,21 3,87 0,00 1,14
120 130 22 55,0 5,01 on 22,0 47,8 off 47,8 47,8 on 47,8 55,0 90 70,0 55,2 60,0 117 367 52,2 52,0 99 309 4,21 4,02 0,00 0,99
130 130 22 55,0 5,01 on 22,0 48,6 off 48,6 48,6 on 48,6 55,0 90 67,0 56,0 60,7 123 381 52,8 52,7 103 320 4,23 4,15 0,00 0,86
92 130,0 22,0 55,0 5,01 on 22,0 45,5 off 45,5 45,5 on 45,5 55,0 90 76,3 52,9 58,6 103 328 50,2 50,0 88 280 4,46 3,67 0,00 1,34
Heat covered
by boilerhouse
Mass w
ater to H
RC
III
Heat sources spraywater
Heat covered
by steam
Dew
poin
t
Tem
perature
Absolu
te hum
idity
Enthalp
y
Exhaust air
(to HRC IV pre-& after dryers)
Heat covered
by H
RC
III dryer
Mass exh. air
to H
RC
III
in %
of m
dry
Exhaust air
consum
ptio
n
Exhaust air
(from HRC II pre-& after dryers)
Tem
p. after steam
heater
(H
E IV
in
fig
.1-S
um
m)
Dew
poin
t
Tem
perature
Absolu
te hum
idity
Enthalp
y
Tem
p. sprayw
ater after H
RC
III (fig
.1-S
um
m)
Heat recovery from
H
R
boilerhouse [o
n] or [o
ff]
Tem
p. before H
E3 in
boilerhouse (see fig
.3.1H
)
Tem
p. after H
E3 in
boilerhouse
(see fig
.3.1H
)
Heatin
g by steam
[o
n] or [o
ff]
Tem
p. before steam
heater
(H
E IV
in
fig
.1-S
um
m)
Code
Required heat spraywater From HR boilerhouse From steam
Sprayw
ater quantity
(cle
anin
g w
ire and felts)
Tem
perature sprayw
ater
before heatin
g
Tem
perature sprayw
ater
after heatin
g
Requir
ed heat for
heatin
g sprayw
ater
Heat rec. H
RC
III dryin
g
sectio
ns [o
n] or [o
ff]
Tem
p. sprayw
ater before H
RC
III (fig
.1-S
um
m)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 75
12 SPACEHEATING MACHINE ROOM AND OTHER SPACES
12.1 Heat losses buildings
The amount of heat required to maintain the desired conditions in a building depends
on the required amount of ventilation, the insulation of the building and the outside air
temperature. The amount of ventilation depends on the desired conditions in the
machine room or other building. The insulation depends on the thermal resistance (R-
value) or the reciprocal overall heat transfer coefficient (U-value).
The R-value is a measure of thermal resistance of a building construction:
R = ∆T / qarea m²·K/W (31)
Where:
R = thermal resistance of a construction (building) in m²·K/W
∆T = the temperature difference over the construction
qarea = heat flow per unit area in W/m2
The bigger the number, the better the building insulation's effectiveness.
The U-value, more correctly called the overall heat transfer coefficient, is the reciprocal
of the R-value:
U = 1 /R W/(m²·K) (32)
Increasing the thickness of an insulating layer increases the thermal resistance.
Perfect wall insulation only eliminates conduction through the insulation but leaves
unaffected the conductive heat loss through such materials as glass windows as well as
heat losses from air exchange.
12.2 Degree days (Dgd) and base temperature
Degree-days
Unlike heating process water or spray water, there is no “fixed” temperature difference
for calculating heat consumption for space heating.
During the space heating season, the outside temperature varies in the Netherlands,
between about + 20 oC and -10 oC.
This means, when space heating starts at an outside temperature of 20 oC, the
temperature difference might be between (20-20=) 0 oC and (20 - - 10=) 30 oC.
To simplify calculations a measure of heating or cooling was introduced: degree day
(Dgd).
Distinction is made between “heating degree days” (Dgdheating) and “cooling degree
days” (Dgdcooling).
Dgdheating reflect the demand for energy needed to heat a building or home. Dgd’s are
derived from daily temperature observations. The heating requirements for a given
building are considered to be directly proportional to the number of Dgd’s.
The cooling degree day' (Dgdcooling), reflects the amount of energy used to cool a
building.
A zero degree-day is when both heating and cooling consumption is at a minimum.
Totalized degree days for a certain period may be used to monitor the heating costs of
buildings.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 76
Table 12 Calculations space heating machine room
a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab
Spaceheating: Room PM 1 θgly.out.HRC IV -θdew.before.HRC IV = 7,0oC Glycol heating machine room
Heatrec. [on] or [off] on 2
Base temperature θbase 20oC 3
Degree-days at θbase 2399 dgd/a 4
HR temperature θHR oC 5
Degree-days at θHR dgd/a 6
Lowest temp. outdoor θlow -10oC 7
Degree-days at θlow 0 dgd/a 8
Required heat per Dgd q 8,0 GJ/dgd 9
Req. heating cap. (Pgly.max) 2,78 MW 10
Temp. glycol before heating 35oC 11
Temp. glycol after heating 60 oC 12
Glycolwater flow 100 m3/h 13 PUnet θdew mglycol θinθgly.outH
RC
θout.b.houseθout.ste.h. Pgly.max Pgly.HR Pgly.steam θbase θHRC θlow - θHRC θHRC θHRC q Qglycol Qgly HRC Qgly steam
∆ θglyco & θexhaus t air / flue 7,0oC 14 h/a °C m3/h
oC oC oC oC MW MW MW oC oC oC dgd/a dgd/a dgd/a dgd/aGJ/dgd GJ/a GJ/a GJ/a
Av. cap. HRC/HE (Pgly.HR) MW 15
Av. cap. steam-h. (Pgly.steam) MW 16 60 1100 45,7 100 35,0 38,7 38,7 60,0 2,78 0,41 2,37 20 15,6 -10,0 455 2281 1511 286 8,0 3641 1349 2292
Degree-days at Pgly.max- dgd/a 17 80 900 48,1 100 35,0 41,1 41,1 60,0 2,78 0,68 2,10 20 12,7 -10,0 372 1569 1039 161 8,0 2979 1689 1290
Degree-days at Pgly.HR - dgd/a 18 90 850 49,1 100 35,0 42,1 42,1 60,0 2,78 0,79 1,99 20 11,5 -10,0 352 1287 852 125 8,0 2813 1814 999
Heatdelivery HRC/HE 12.339 GJ/a 19 100 800 49,9 100 35,0 42,9 42,9 60,0 2,78 0,87 1,91 20 10,6 -10,0 331 1094 725 100 8,0 2648 1848 800
20 110 750 50,7 100 35,0 43,7 43,7 60,0 2,78 0,96 1,81 20 9,6 -10,0 310 901 597 77 8,0 2482 1865 617
Heat delivery steam-heater 6.857 GJ/a 21 120 700 51,4 100 35,0 44,4 44,4 60,0 2,78 1,05 1,73 20 8,7 -10,0 290 738 488 59 8,0 2317 1845 472
22 130 700 52,1 100 35,0 45,1 45,1 60,0 2,78 1,12 1,65 20 7,9 -10,0 290 608 402 49 8,0 2317 1928 388
Total heat consumption 19.196 GJ/a 23 20 8,0
24 92 5800 49,2 100 35,0 42,2 42,2 60,0 2,78 0,81 1,97 20 11,3 -10,0 2399 - 1295 857 8,0 19196 12339 6857
Heat
covere
d b
y H
RC
IV
dry
er
Required heating
capacity
Outdoor
temperaturesDegree days (Dgd)
Dew
poin
t exhaust
air
befo
re H
RC
IV
Gly
colw
ate
r flow
(heating m
achin
e h
all)
Tem
pera
ture
gly
colw
ate
r
befo
re h
eating
Tota
l re
quir
ed c
apacity (
HR
C
IV,
HE b
oilerh
.&ste
am
heate
r)
Req.
heat
per
degre
e-d
ay
Degre
e-d
ays a
t θ
HR
C
(wit
h c
orr
. fo
r pro
d.
days
)
Degre
e-d
ays a
t θ
HR
C
(wit
h c
orr
. fo
r pro
d.
ho
urs
)
θH
R is low
est
tem
p.
heatr
ec.
is s
uff
icie
nt;
here
aft
er
addit.
ste
am
heating is r
equir
ed
Low
est
tem
pera
ture
outs
ide
Degre
e-d
ays a
t θ
HR
C
(without
corr
. fo
r pro
d.
hours
)
Heat consumptionMass flow and temp. glycol
Pro
duction h
ours
PM
(=re
el pro
duction)
Depends
product
Depends
product
Code
Heat
covere
d b
y s
team
Tem
p.
gly
col aft
er
ste
am
heate
r
Base t
em
pera
ture
Degre
e-d
ays a
t θbase f
or
the w
hole
pro
duct
range
Tem
pera
ture
gly
colw
ate
r
aft
er
HR
C I
V (
fig.1
H-S
um
m)
Capacity c
overe
d
by H
RC
IV
dry
er
Real to
tal heatc
onsum
ption
(fro
m H
RC
IV
, boilerh
ouse &
ste
am
heate
r)
Tem
p.
gly
col aft
er
boilerh
ouse (
HE3 in f
ig.3
H)
Capacity c
overe
d
by s
team
g air
dry
/m2
Maximum required heating capacity (Pgly.max; table 12 cell d10)
Pgly.max =(θbase - θlow)oC x q GJ/Dgd x1000 MJ/GJ/(24h x 3600s/h) MW (33)Pgly.max =(20 – (-10))oC x 8,0 GJ/Dgd x1000 MJ/GJ/(24h x 3600s/h) =2,78 MW
Available heating capacity heat recovery dryer (Pgly.HR; table 12 cell d15) Pgly.HR1=(θbase - θHR)oC x q GJ/Dgd x 1000 MJ/GJ/(24h x 3600s/h) MW (34)
Pgly.HR1=(20 - θHR)oC x 8 GJ/Dgd x 1000 MJ/GJ/(24h x 3600s/h)= 0,09x(20-θHR)MW
θHR is the lowest temp. HRC is sufficient; hereafter additional steam heating is required
How to calculate θHR ??θHR depends on the heat that can be extracted economically from the exhaust air:
minimum ∆ between θdew.exhaust.air and θglycol.after.HRC (45,7 – 7=) 38,7 oC (cell l16).
Heat extracted by the glycol water from the exhaust air heat:Pgly.HR2 =(θgly.outHRC-θgly.inHRC )oC x mgly m
3/h x (1/3600) x sh MJ/(oC.m3) MW
Pgly.HR2 = (38,7-35)oC x 100 m3/h x(1h/3600s) x 4,0 MJ/(oC.m3) = 0,41 MWBecause Pgly.HR2 =Pgly.HR1 temperature θHR (=15,6oC) can be calculated
Additional heating capacity steam heater (Pgly.steam; table 12 cell d16 > q16)
Pgly.steam=(θgly.outSteam- θgly.outHRC)oC x mgly m3/h x(1/3600)x sh MJ/(oC.m3) MW
Pgly.steam=(60 – 38,7) x 100 x (1/3600) x 4 = 2,37 MW
Degree days (Dgd; table 12 cells d4, d8 etc)Base temperature θbase = 20oC (cell r16), based on 8760 h/a > 3624 Dgd.
Dgd during production (5800/8760) x 3624 Dgd = 2399 Dgd
60 g air.dry/m2: 1100 h/a (cell h16) > Dgd=(1100/5800) x 2399 = 455 Dgd (cell u16).At θHRC= 15,6oC (cell s16) there 2281 Dgd / 365 d (cell v16)
Total production hours: (5800/8760) x 2281 Dgd = 1511 Dgd (cell w16)60 g air.dry/m2 > 1100h/a(cell h16) > Dgd=(1100/5800)x1511= 286 Dgd (cell x16)
Heat delivery HRC IV and heat consumption steam heater
Q = d Dgd/a x q GJ/DgdQglycol = (455 – 0) Dgd x 8 GJ/Dgd = 3641 GJ/a
Qgly.HRC = (455 – 286) Dgd x 8 GJ/Dgd = 1349 GJ/aQglysteam = (286 – 0) Dgd x 8 GJ/Dgd = 2292 GJ
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 77
30 oC 1330 Dgd 1833 Dgd
(30--10)x45,8=
Heatdelivery sun, motors, people etc.
1 day
20oC (20--10)x45,8=
20oC=θbase 455 Dgd 1375 Dgd
Dgd=1 day x (20-16)oC= 4 Dgd
Pgly.HR Heat delivery by heat recovery
0,41 16oC Actual heat delivery (168 Dgd x 8 GJ/Dgd =) 1.349 GJ/a
MW * Available heat delivery (204 Dgd x 8 GJ/Dgd =) 1.631 GJ/a
"HRC-SURFACE"= Max. Dgd HRC= Capacity utilization factor (f) = actual heat delivery : available heat delivery
Pgly.max Actual Dgd HRC= (1375-1171=) Capacity utilization factor (f) = 0,83
2,78 (455-286=)168 Dgd 204 Dgd
MW
15,6 oC = θHR 286 Dgd 1171 Dgd
(15,6--10)x45,8=)
"STEAM-SURFACE" Heat delivery by steam heaters
Pgly.s team Actual Dgd steam = Max. Dgd steam= Actual heat delivery (286 Dgd x 8 GJ/Dgd =) 2.292 GJ/a
2,37 (=286-0=) 286 Dgd (1171-0=) Available heat delivery (1171 Dgd x 8 GJ/Dgd =) 9.369 GJ/a
MW * 1171 Dgd Capacity utilization factor (f) = actual heat delivery : available heat delivery
Capacity utilization factor (f) = 0,24
-10 oC = θlow 0 Dgd 0 Dgd
1-jul 1-feb 30-jun
Days = production hours / 24 (= 1100/24=) 45,8 d/a
(Total surface = (30 -(-10))oC x 45,8 d/a = 1.833 Dgd)
* Pgly.max = (θbase - θlow) oC x (q) GJ/dgd x 1000 MJ/GJ / (24 x3600) s/d = ….MW* Pgly.HR = (θbase - θHR) oC x (q) GJ/dgd x 1000 MJ/GJ / (24 x3600) s/d = ….MW
* Pgly.steam = (θHR - θlow) oC x (q) GJ/dgd x 1000 MJ/GJ / (24 x3600) s/d = ….MW
Heat consumption q = 8,0 GJ/Dgd
Example for product 60 g air dry / m2; degree-days and capacities heat exchangers, heat recovery & heat consumption
Figure 12 Calculations space heating machine room
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 78
Base-temperature
Dgd’s are defined relative to a base temperature.
The base-temperature is the outdoor temperature above which a building needs no
heating.
For historical reasons Dgd’s are often made available with base temperatures of 18°C
or 15°C. These base temperatures are approximately appropriate for a good proportion
of buildings. For machine rooms and other buildings in paper mills, however, these
base-temperatures are often not appropriate for the following reasons:
- The temperature the building is heated to is deviating from normal
- Large heat and moist production by production equipment
- Heavy insulation of the building
- Solar radiation
- The amount of wind outside
- Individuals' opinions about what constitutes a comfortable indoor temperature.
An approximation method for calculating Dgd is to take the average temperature on
any given day, and subtract it from the base temperature. If the value is less than or
equal to zero, that day has zero Dgd. But if the value is positive, that number
represents the number of Dgd on that day.
Dgd can be added over periods of time to provide a rough estimate of seasonal heating
requirements. In the course of a year, for example, the number of Dgd for Amsterdam
is around 3000 whereas that for a place in Alaska is over 18.000. Thus, one can say
that, for a given building, six times the energy would be required to heat the building in
Alaska.
Example:
For a typical Amsterdam winter day (= 24h), the temperature is during 8 hours 2 oC,
during 12 hours 6 oC and during the other 4 hours 8 oC.
The average temperature during this day (= 24 hours) is ((8x2+12x6+4x8)/24=) 5 oC.
When the base temperature is 18 oC the number of degree-days (Dgd) for that day is
18- 5 = 8 Dgd. A month of thirty similar days might accumulate Dgd (=30x8=) 240
Dgd.
A year (including summer average temperatures above 18 oC) might accumulate an
annual Dgd = 3200.
12.3 Capacities heat exchangers steam and heat recovery
On the basis of the examples depicted in table 12 and figure 12 the method of working
for calculating the required capacity for steam heaters and heat recovery equipment
will be demonstrated. As far as the product range is involved the example will be based
on 60 g air dry / m2 (table 12 cell g16).
Maximum required heating capacity (Pgly.max; table 12 cell d10)
Pgly.max=(θbase- θlow)oC * q GJ/Dgd *1000 MJ/GJ/(24h*3600s/h) MW (33)
[ table 12: d10 = (d3 – d7) x d9 x 1000 /(24 x 3600) ]
Pgly.max =(20 – (-10))oC x 8,0 GJ/Dgd x1000 MJ/GJ/(24h x 3600s/h) =2,78 MW
Available heating capacity heat recovery dryer (Pgly.HR; table 12 cell d15)
Pgly.HR1=(θbase-θHR)oC * q GJ/Dgd * 1000 MJ/GJ/(24h * 3600s/h) MW (34)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 79
[ table 12: d15 = (d3 – d5) x d9 x 1000 /(24 x 3600) ]
Pgly.HR1=(20 - θHR)oC x 8 GJ/Dgd x 1000 MJ/GJ/(24h x 3600s/h)= 0,09x(20-θHR)MW
θHR is the lowest temperature the heatrecovery is sufficient; hereafter additional steam
heating is required.
The question is how to calculate θHR;
To do this we need to know how much heat can be recovered in HRC IV.
This differs for each product. As an example the method of working will be explained for
the weight 60 g air dry / m2.
The heat recover capacity depends on the amount of heat that can be extracted
economically from the exhaust air. Economically means that there should be a
minimum temperature difference between the (dew point) temperature of the exhaust
air before HRC IV (=45,7 oC, cell i16) and the temperature of the glycol after HRC IV. In
the example this temperature is set at 7 oC (cell n1) which results in a glycol
temperature after HRC IV of (45,7 – 7=) 38,7 oC (cell l16).
Now the heat extracted by the glycol water from the exhaust air heat can be calculated:
Pgly.HR2 =(θgly.outHRC-θgly.inHRC )oC*mgly m
3/h*(1/3600)*sh MJ/(oC.m3) MW (35)
[ table 12: p16 = (l16 – k16) x j16 x 4,0 MJ/(oC.m3) ] Pgly.HR2 = (38,7-35)oC x 100 m3/h x(1h/3600s) x 4,0 MJ/(oC.m3) = 0,41 MW
sh = specific heat (for 10% glycol solution 4,0 MJ/(oC.m3))
Because Pgly.HR2 =Pgly.HR1 temperature θHR (=15,6oC) can be calculated with formula
(34).
Additional heating capacity steam heater (Pgly.steam; table 12 cell d16 > q16)
Pgly.steam=(θgly.outSteam- θgly.outHRC)oC*mgly m
3/h*(1/3600)*sh MJ/(oC.m3) MW (36)
[ table 12: q16 = (n16 – l16) x j16 x (1/3600) x 4,0 ) ]
Pgly.steam=(60 – 38,7) x 100 x (1/3600) x 4 = 2,37 MW
12.4 Heat consumption heat exchangers and heat recovery
On the basis of the examples depicted in table 12 and figure 12 the method of working
for calculating degree-days and the heat consumption will be demonstrated. As far as
the product range is involved the example will be based on 60 g air dry / m2 (table 12
cell h16).
Degree days (Dgd; table 12 cells d4, d8 etc)
Are calculated in MED and/or can be obtained from www.kwa.nl:
At base temperature θbase = 20oC (cell r16) there are, based on 365 d/a (=8760 h/a),
3624 Dgd.
Though there are 8760 hours in a calendar year, there are only 5800 h/a for production
(cell h24); the difference between calendar and production hours are left aside in our
calculations.
This result in (5800/8760) x 3624 Dgd = 2399 Dgd (cell u24)for the whole product
range.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 80
For the weight 60 g air dry / m2 the number of production hours is 1100 h/a (cell h16);
the number of degree days is: (1100/5800) x 2399 = 455 Dgd (cell u16).
At the lowest temperature heat recovery is still sufficient for heating θHRC= 15,6oC (cell
s16) there 2281 Dgd / 365 d (cell v16)
For total production hours there are: (5800/8760) x 2281 Dgd = 1511 Dgd (cell
w16)for the whole product range.
For the weight 60 g air dry / m2 the number of production hours is 1100 h/a (cell h16);
the number of degree days is: (1100/5800) x 1511 = 286 Dgd (cell x16).
Heat delivery HRC IV and heat consumption steam heater
Q = d Dgd/a x q GJ/Dgd (37)
Where:
Q = Heat delivery or heat consumption in GJ/a
d = degree days in Dgd/a
q = heat consumption in GJ/Dgd
Total heat consumption for space heating machine room:
Qglycol = (455 – 0) Dgd x 8 GJ/Dgd = 3641 GJ/a
Total heat delivered by heat recovery HRC IV:
Qgly.HRC = (455 – 286) Dgd x 8 GJ/Dgd = 1349 GJ/a
Total heat consumption for space heating machine room:
Qglysteam = (286 – 0) Dgd x 8 GJ/Dgd = 2292 GJ/a
How to calculate the heat consumption per degree day
See figure 12.
Base temperature = 20 oC
Average outdoor temperature during 24 hours (=1 day) = 16 oC
Number of degree days = (20 – 16)oC x 1 day = 4 Dgd
Heat consumption during that day = 200 m3o natural gas x 31,65 MJ/m3
o= 6330 MJ/d
Heat consumption per degree day = 6330 MJ/d : 4 Dgd/d = 1582 MJ/Dgd
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 81
13 DRYING PROCESS AND HEATRECOVERY IN MOLLIER CHART
13.1 Introduction
In chapter 7 was shown how by increasing the temperature of the exhaust air, not only
the heat consumption in the drying section decreases, but also the heat recovery
potential.
It was demonstrated that when the exhaust temperature and the relative humidity are
already rather high the heat savings are small, but the quality of the exhaust heat will
improve sharply and as a result of this the heat recovery potential rises sharply.
When the exhaust air temperature is increased and the relative humidity of this exhaust
air is not changed we may assume that the drying rate will not change.
In chapters 8 u/i 12 possibilities and constraints for applying recovered heat for pre-
heating supply air, heating process water, heating spray water and heating glycol for
space heating
were discussed.
In this chapter the knowledge we gained will be applied on a case from practice.
13.2 Reference and optimal situation
Introduction
In exercise 6 two situations are compared.
The first situation, the reference situation, is an example for calculations to be carried
out in the optimal situation.
The exercise should be carried out in the tables and pictures on next pages.
For this task make use of the Mollier-chart 300oC, 190 g/kg; this chart is included as an
attachment (note: unit for h is Wh/kg).
Specify the entire process in the Mollier-chart.
Specify how the efficiency of the dryer can be increased.
Explain in a callout how far the process water can be heated in the heat recovery if no
additional steam injection is applied.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 82
Exercise 5 & 6 (page 1)
Comparing reference and optimal situation
Given:
See MED-tables 1.1 u/i 1.3 and MED-table 4 on next pages.
Question:
Calculate the values in the yellow cells in tables 1.1 u/i 1.3
Remark: the letters above the columns are the same as in the tables of MED IV
Answer:
PRODUCTION
Input drying section:
Reference situation:
Pdryer = 91,6 g bone.dry/m2 x 1200 m/min x 5m x 10-6x 60min/h = 33,0 t bone.dry/h
Optimal situation:
Pdryer = 91,6 g bone.dry/m2 x1200 m/min x 5m x 10-6x 60min/h = 33,0 t bone.dry/h
Product water evaporation:
PWE = (100/dsin – 100/dsout) x Pbone-dry kg water/s or ton water/h (formula 18)
Reference situation:
PWE = (100/50 – 100/95) x 33,0 = 31,2 ton water/h
Optimal situation:
PWE = (100/50 – 100/95) x 33,0 = 31,2 ton water/h
PROCESWATER (= HEAD BOX WATER)
Process water (head box water):
Reference situation:
mprocess = (33,0 t bone.dry/h / (85,0/100)) x ((100-0,80)/0,80) x 1,00 = 4810 t/h
Optimal situation:
mprocess = (33,0 t bone.dry/h / (85,0/100)) x ((100-0,80)/0,80) x 1,00 = 4810 t/h
For calculating heat losses in the wire and press section the following symbols are
used:
Wweb.width = paper web width in m
Qevap.wire = spontaneous water evaporation in wire & press section in kg/(h.m)
hRo = heat of evaporation (kJ/kg evaporated water); see steam table
mprocess = process water flow in m3/h
Pdryer = wire production in tbone.dry/h
dsheadbox = % dry solids content in head box
R = % retention on wire section
f = multiply factor for calculating process water
θout = temperature process water after wire section in oC
∆Hint.pump = heat delivery by electricity consumption head box pumps based on
process water flow in MW
∆Hint.refiner = heat delivery by electricity consumption refiners based on
ton bone dry wire production in MW
∆Hnet = net heat losses in wire & press section to be compensated by
heat recovery or steam heating in MW
θin = temperature process water before wire section in oC
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 83
MED: Table 1.1 Calculations Product Water Evaporation (PWE) for different paper grades
b c d e f g h i j k l m n o p q r s t u v
Production Spraywater ∆θ between exh. HRC & spr.water = 7,0oC
Required heat spraywater HR sources heating sprayw.
- PUnet vnom Wweb Pdryer dsin dsuit PWE mspray θin θout Pspray Qspray Scos t θin θout θout mproces PsprayHRC Pspray STScos t add.
g bd
/m2 h/a m/min m t bd/h % %t PWE
/hm3/h oC oC MW GJ/a €/a oC oC oC
g/g
PWEMW MW €/a
Reference situation
91,6 7.000 1.200 5,00 33,0 50,0 95,0 31,2 100,0 20,0 55,0 4,08 102.900 874.169 20,0 49,3 55,0 3,20 3,42 0,66 142.216
Optimal situation
91,6 7.000 1.200 5,00 33,0 50,0 95,0 31,2 100,0 20,0 55,0 4,08 102.900 874.169 20,0 52,6 55,0 3,20 3,81 0,27 58.742
MED: Table 1.2 Required heat from Heat ReCovery (HRC) and/or (additional) steam for heating processwater
b c d e f g h i j k l m n o p q r s t u v
Quantity processwater Heat losses in wire-&press-section HR sources processwater
Pro
duct
to d
ryin
g-s
ection
Dry
solids c
onte
nt
in h
ead b
ox
Rete
ntion
Multip
ly-f
acto
r fo
r
calc
ula
ting p
rocessw
ate
r
Pro
cess w
ate
r
(head b
ox w
ate
r)
Wate
r evapora
tion in
wir
e &
pre
ss s
ection
Gro
ss loss w
ate
r
evapora
tion in w
ire a
ns
pre
ss s
ection
Ele
ctr
.cons.
refiners
per
t
bone d
ry d
ryer
in
Ele
ctr
.consum
ption p
um
ps
per
ton p
rocessw
ate
r
Inte
rnal heat
pro
duction in
pro
cessw
ate
r by r
efiners
Inte
rnal heat
pro
duction in
pro
cessw
ate
r by p
um
ps
Net
loss w
ate
r evap.
in
wir
e a
ns p
ress s
ection
Tem
pera
ture
aft
er
wir
e
Tem
pera
ture
befo
re w
ire
(based o
n ∆
Hgro
ss )
Tem
p.
befo
re w
ire (
based
on ∆
Hnet i.s
.o.
∆H
gro
ss)
Net
loss (
=ste
am
) w
ate
r
evap.
wir
e &
pre
ss s
ection
Cost
ste
am
if
no H
RC
Part
of
mpro
cess covere
d
by s
team
Part
of
mpro
cess covere
d b
y
heatr
ecovery
dry
ers
(HRC)
Pro
cessw
.expre
ssed in
g p
rocessw
ate
r/g P
WE
Part
of
mpro
cess covere
d
by h
eat
recovery
(H
RC)
- ds(hb) R f mpro. WWE ∆Hgros ∆Hrefi ∆Hpu ∆Hint.refiners ∆Hint.pump ∆Hnet θout θin θin ∆Hnet Scos t - - mproces mproHRC
g bd
/m2% % - t/h
kg/
(h.m)MW
kWh
/tbd
kWh/
tpr.w
MW MW MW oC oC oC GJ/a €/a0/100
%
0/100
%
g/g
PWE
g/g
PWE
Reference situation
91,6 0,80 85,0 1,00 4.810 1.400 4,58 5 0,07 0,16 0,34 4,08 55,0 55,82 55,73 102.878 873.984 100 0 154 0
Optimal situation
91,6 0,80 85,0 1,00 4.810 1.400 4,58 5 0,07 0,16 0,34 4,08 55,0 55,82 55,73 102.878 873.984 0 100 154 154
MED: Table 1.3 Heating spraywater and supply air and exhaust air conditions drying section
b c d e f g h i j k l m n o p q r s t u v
Energy costs
Net heating value (NHV)31,65 31,65 MJ/m3o
Electricity price 0,085 0,085 €/kWh
CO2-emiss.rights 22,00 22,00 €/t CO2
Gas.price(commodity) 0,30 0,30 €/m3o
Gas.price(transport) 0,01 0,01 €/m3o
CO2-emiss.rights 0,04 0,04 €/m3o
Natural gas price 0,35 0,35 €/m3o
Adjustm.gasprice*1) 76,9 76,9 %
Adjusted gas price 0,27 0,27 €/m3o
Steam - feedwater 2.543 2.543 MJ/t
- θdew θ wvapor h pvapor ηθ θsupply msuppl θdew θ wvapor h pvapor mexh Efficiency boiler 100 100 %
g bd
/m2oC oC g/kg J/g kPa % oC % oC oC g/kg J/g kPa %
Reference situation
91,6 6,0 10,0 6 25 0,9 55,0 95 100 57,0 80,0 129 422 17,3 100
Optimal situation
91,6 6,0 10,0 6 25 0,9 55,0 95 100 66,0 90,0 218 671 25,9 100,0
Explanation: White cells are givens; yellow cells are to be calculated.
*1) adjustment gas price due to
electr.production loss in steamturbine
Tem
pera
ture
supply
air
aft
er
ste
am
heat
exchanger
mass s
upply
air
/
mass d
ryin
g a
ir
Dew
poin
t exhaust
air
Tem
pera
ture
exhaust
air
Absolu
te h
um
idity e
xhaust
air
Spra
yw
ate
r expr.
in g
spra
yw
./g P
WE
Requir
.heat
covere
d b
y
HR
C I
II d
ryer
Requi.heat
covere
d b
y
ste
am
Additio
nal ste
am
costs
Pro
duct
to d
ryin
g-s
ection
Drying-section Refer
ence
Opti
malUnits
Supply air Exhaust air
Dew
poin
t supply
air
Tem
pera
ture
supply
air
Abs.
hum
idity s
upply
air
Enth
alp
y s
upply
air
Part
ial vapour
pre
ssure
supply
air
Tem
pera
ture
eff
iecie
ncy
heat
exchanger
supply
- /
exh.
air
Enth
alp
y e
xhaust
air
Part
ial vapour
pre
ssure
exhaust
air
mass e
xhaust
air
/
mass d
ryin
g a
ir
Product Production & water evap. (PWE) Temperatures
Pro
duct
to d
ryin
g-
section
Pro
d.
hours
PM
(=
reel
pro
duction)
Machin
e s
peed
Paper
web w
idth
Input
dry
er
(fib
res o
nly
)
Dry
solids c
onte
nt
befo
re d
ryer
Dry
solids c
onte
nt
aft
er
dry
ing-s
ection
Pro
duct
wate
r evap-
ora
tion in d
ryer
Spra
yw
. Q
uantity
(c
leanin
g w
ire &
felts)
Tem
p.
spra
yw
ate
r
befo
re h
eating
Tem
p.
spra
yw
ate
r
aft
er
heating
Requir
ed h
eat
for
heating s
pra
yw
ate
r
Requir
ed h
eat
for
heating s
pra
yw
ate
r
Cost
ste
am
if
no H
RC
III
for
heating s
pra
yw
.
Tem
p.
spra
yw
ate
r
befo
re H
RCII
I
Tem
p.
spra
yw
ate
r
aft
er
HRC I
II
Tem
p.
spra
yw
ate
r
aft
er
ste
am
heate
r
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 84
Exercise 6 (page 2)
Gross heat loss by spontaneous water evaporation in wire and press section:
∆Hgross = Wweb.width x Qevap.wire x 0,001 x (hRo-2,4xθ) /3600 (s/h) MW (formula 30a)
Reference situation:
Spontaneous water evaporation:
θout = 55 oC >> 1400 kg/(h.m), derived from figure 10.
∆Hgross = 5 m x 1400 kg/(h.m) x 0,001 t/kg x (2501,6-2,66x55)/3600s/h= 4,58 MW
Optimal situation:
Spontaneous water evaporation: θout = 55 oC >>
pvap.55oC(1) = 0,611 exp ((17,27 x 55)/(237,3 + 55) = 15,75 kPa(1) (formula 24)
pvap.55oC(2) = 0,611 exp ((17,27 x 55)/(237,3 + 55) = 15,75 kPa(2) (formula 24)
When the spontaneous water evaporation at 55oC(1) is 1400 kg/((h.m) it will be at
55oC(2):
Qevap.wire.55oC(2) = Qevap.wire.55oC(1) x (pvap.55oC(2) : pvap55oC(1)) (formula 29)
Qevap.wire.55oC = 1400 x (15,75/15,75) = 1400 kg/(h.m)
∆Hgross =5 m x 1400 kg/(h.m) x 0,001t/kg x (2501,6-2,66x55)/3600s/h=4,58 MW
Heat delivery by electricity consumption head box pumps (∆Hint.pump ):
∆Hint.pump = mprocess x 0,001 x ∆Hpump MW
Reference situation:
∆Hint.pump = 4810 t proc.w./h x 0,001 MW/kW x 0,07 kWh/tproc.water = 0,34 MW
Optimal situation:
∆Hint.pump = 4810 t proc.w./h x 0,001 MW/kW x 0,07 kWh/tproc.water = 0,34 MW
Electricity consumption refiners based on ton bone dry wire production (∆Hrefiner ):
∆Hint.refiner= Pdryer x 0,001 x ∆Hrefiner MW (formula 30b)
Reference situation:
∆Hint.refiner= 33,0 t bone.dry/h x 0,001 MW/kW x 5 kWh/ t bone.dry = 0,16 MW
Optimal situation:
∆Hint.refiner= 33,0 t bone.dry/h x 0,001 MW/kW x 5 kWh/ t bone.dry = 0,16 MW
Net heat losses in wire & press section to be compensated by HRC or steam heating
∆Hnet = ∆Hgross - ∆Hint.pump - ∆Hint.refiner
Reference situation:
∆Hnet = 4,58 – 0,34 – 0,16 = 4,08 MW
Optimal situation:
∆Hnet = 4,58 – 0,34 – 0,16 = 4,08 MW
Virtual temperature process water before wire section calculated on base of gross
heat loss in wire and press section (θin(gross) ):
θin(gross) ={∆Hgross x3600(s/h)+mprocess x 4,2 x θout}/{mprocess x 4,2}oC (formula 30c)
Reference situation:
θin(gross) = {4,58 x 3600 + 4810 x 4,2 x 55 }/{4810 x 4,2} = 55,82 oC
Optimal situation:
θin(gross) = {4,58 x 3600 + 4810 x 4,2 x 55 }/{4810 x 4,2} = 55,82 oC
Real temperature process water before wire section calculated on base of net heat
loss:
θin(net) ={∆Hnet x3600 (s/h)xmprocessx4,2 x θout }/{mprocessx 4,2 }oC (formula 30d)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 85
Exercise 6 (page 3)
Reference situation:
θin(net) = {4,08 x 3600 + 4810 x 4,2 x 55 }/{4810 x 4,2} = 55,73 oC
Optimal situation:
θin(net) = {4,08 x 3600 + 4810 x 4,2 x 55 }/{4810 x 4,2} = 55,73 oC
Amount process water expressed in kg process water per kg PWE:
mprocess.water/PWE = mprocess.water / PWE ton process water/ton PWE
Reference situation:
mprocess.water/PWE = 4810 t/h / 31,2 t/h = 154 g process water/ g PWE
Optimal situation:
mprocess.water/PWE = 4810 t/h / 31,2 t/h = 154 g process water/ g PWE
Net heat loss (= additional steam consumption) by spontaneous water evaporation in
wire and press section:
∆Hnet.GJ/a = ∆Hnet.MW x 3600 s/h x PUnet h/a x 0,001 GJ/MJ GJ/a
Reference situation:
∆Hnet.GJ/a = 4,08 MW x 3600 s/h x 7000 h/a x 0,001 GJ/MJ = 102.878 GJ/a
Optimal situation:
∆Hnet.GJ/a = 4,08 MW x 3600 s/h x 7000 h/a x 0,001 GJ/MJ = 102.878 GJ/a
Cost steam for compensating net heat loss if no HRC is available:
Scost = [{∆Hnet.MW x 3600 s/h x PUnet h/a x (100/ŋboiler)} / Hi MJ/m3o] x sgas €/ m3
o
Reference situation:
Scost = [{4,08 x 3600 x 7000 x (100/100)} / 31,65] x 0,27 = 102.878 €/a
Optimal situation:
Scost = [{4,08 x 3600 x 7000 x (100/100)} / 31,65] x 0,27 = 102.878 €/a
For more accurate calculations:
The process water is heated by steam injection:
Steampressure 6 bar, saturated; hsteam = 2.755 MJ/t (see steam table)
Steam injection is live steam, this means the condensate is lost at θprocess.water and is
substituted by make-up water of 10 oC.
Heat for producing 1 ton steam: h∆steam = 2755 – 10 x 4,2 = 2713 MJ
msteam = ∆Hnet.GJ/a x 1000 MJ/GJ / h∆steam ;
Reference situation:msteam =102.878/a x 1000MJ/GJ / 2713 MJ=87.920 t steam /a
Optimal situation:msteam =102.878GJ/a x 1000MJ/GJ / 2713 MJ=87.920 steam /a
SPRAY-WATER
Heat consumption spray water:
The required heat for heating spray water (Pspray):
Pspray = mspray m3/h x (1/3600) h/s x (θout – θin)
oC x 4,2 MJ/(m3.oC)
Reference situation:
Pspray = 100 m3/h x (1/3600) h/s x (50 – 20) oC x 4,2 MJ/(m3.oC) = 4,08 MW
Optimal situation:
Pspray = 100 m3/h x (1/3600) h/s x (56 – 20) oC x 4,2 MJ/(m3.oC) = 4,08 MW
Note:
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 86
Exercise 6 (page 4)
The temperature difference between the spray water coming from the HRC and the dew
point of the exhaust air to the HRC is set at 7 oC. This temperature difference
determines to a large extent the investment for the heat exchanger.
For method for calculating consumption per year and steam costs see process water.
DRYING SECTION
In the calculations the processes move from (for instance) state 1 to state 2, where the
state number is denoted by subscript; the applied subscripts are shown in MED: figure
2 on pages 89 and 90 .
The yellow marked formulas are applied in the answers:
pvapor (kPa) = 0,611*exp(1)^((17,27*θdew)/(237,3+θdew)) (3a)
wvapor = (Mvapour/Mdry.air) * (((p”vapour / ((po/φ) – p”vapour))) (17)
Substitute formula (3a) in formula (17); note: if θ = θdew then φ =100 %
wvapor (g/kg) = 1000 * (18/28,84) * ((0,611*exp(1)^((17,27*θdew))))/(237,3+θdew)) /
(101,325-(0,611*exp((17,27*θdew))))/(237,3+θdew)))))) (17der)
φ (%) = (pvapour / p”vapour) * 100 % (15)
Substitute (3a) in (15) and see definition in box 6 on page 23 and box 1 on page 11:
φ (%) = ((0,611*exp(1)^((17,27*θdew)/(237,3+θdew)) )) /
(((0,611*exp(1)^(17,27*θ)/(237,3+θ))))) * 100 (15)
h = cp av.air . θ + wvapour . (hRo + cp av.vapour . θ ) kJ/kg (dry) gas (11)
For cp av.air . and cp av.vapour see table 2 on page 20; hRo = 2501,6 kJ/kg
ln (1,639 * p”vapour) = (17,27 * θ”) / (237,3 + θ”) (3b)
When the dew point belonging to the temperature θ is θdew:
θdew = ln((1,639*pvapour)*(237,3+θdew)/17,27) (3bder)
θwet.bulb = ((0,00066*101,325)*R12+(4098*V12/(Q12+237,3)^2*Q12))/((0,00066*101,325)+
4098*V12/(Q12+237,3)^2) (table 3) Note: Results of the wet bulb calculation should always be checked !!!
Supply air conditions drying section
Given: θDi1 = 6 oC and θi1 = 10 oC;
Reference situation:
pDi1 = 0,611 * 2,71828 ^ (17,27*6)/(237,3+6) = 0,935 kPa
wi1 = 1000 * (18/28,84) * ((0,611*exp(1)^((17,27*6))))/(237,3+6)) /
(101,325-(0,611*exp((17,27*6))))/(237,3+6)))))) = 5,81 g/kg
φi1 = ((0,611*exp(1)^((17,27*6)/(237,3+6)) )) /
(((0,611*exp(1)^(17,27*10)/(237,3+10))))) * 100 = 76,15 %
hi1 =1,009 * 10 + 5,81 * (2501,6 + 1,84 * 10 ) = 24,8 kJ/kg (dry) gas θwet.bulb = 8,05 oC
Optimal situation:
pDi1 = 0,935 kPa
wwi1 = 5,81 g/kg
φi1 = 76,15 %
hi1 = 24,73 kJ/kg (dry) gas
θnbi1 = 8,05 oC
Exhaust air conditions drying section
Reference situation:
Given: θdu1 = 57 oC and θu1 = 80 oC;
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 87
MED: Table 4 Calculations energy consumption in the reference and optimal situation
A C D G H I J K L Q R S T U V AA AB AC AD AE AM AV
Supply air Exhaust air after drying section Consumption between i1 & u1
Dew
poin
t
Tem
pera
ture
Absolu
te h
um
idity
Enth
alp
y
Rela
tive h
um
idity
Part
ial vapour
pre
ssure
Dew
poin
t
Tem
pera
ture
Absolu
te h
um
idity
Enth
alp
y
Rela
tive h
um
idity
Part
ial vapour
pre
ssure
Dry
ing a
ir c
ons.
(g a
ir/g
PW
E)
Dry
ing a
ir c
ons.
(kg a
ir /
s)
Mois
ture
reception
(g m
ois
ture
/g P
WE)
Heat
consum
ption
(J h
eat
/g P
WE)
Heat
consum
ption
(MW
)
- PUnet PWE θdi1 θi1 wi1 hi1 φi1 pDi1 θdu1 θu1 wu1 hu1 φu1 pD1 mair/PWE mair/s ∆wvapour∆hPWE ∆hs hu2 ∆hu2
g bd
/m2h/a
gPWE/
s°C °C g/kg J/g % kPa °C °C g/kg J/g % kPa
g/g
PWEkg/s
g/g
PWE
J/g
PWEMW J/g
J/g
PWE
91,6 7.000 8.676 6,0 10,0 5,8 24,8 76,4 0,9 57,0 80,0 129 422 36,4 17,3 8,14 70,58 1,000 2.999 26,02 393 234
91,6 7.000 8.676 6,0 10,0 5,8 24,8 76,4 0,9 66,0 90,0 218 671 37,1 25,9 4,72 40,97 1,000 2.822 24,48 637 161
BU BV BW BX BY BZ CA CF CG CH CI CJ CN CO CP CQ CR CS CT CU CZ DA DB DC DD
Exhaust air after HRC I, this is in u3 Heat deliv. between u1 & u3 Supply air after HRC I Heat recept. between i1 & i2
Mass s
upply
air
aft
er
HRCI
in %
of
mu
Dew
poin
t
aft
er
HRC I
Tem
pera
ture
aft
er
HRC I
Absolu
te h
um
idity
aft
er
HRC I
Enth
alp
y
aft
er
HRC I
Rela
tive h
um
idity
aft
er
HRC I
Part
. vapour
pre
ss.
aft
er
HRC I
Dry
ing a
ir c
ons.
(g a
ir/g
PW
E)
Dry
ing a
ir
consum
ption
Mois
ture
delivery
(g m
ois
ture
/g P
WE)
Heat
delivery
(J h
eat/
g P
WE)
Heat
delivery
(MW
)
Tem
p.
eff
icie
ncy
heat-
exchanger
Mass s
upply
-air
to H
RC in %
of
mu
Dew
poin
t
aft
er
HRC I
Tem
pera
ture
aft
er
HRC I
Absolu
te h
um
idity
aft
er
HRC I
Enth
alp
y
aft
er
HRC I
Rela
tive h
um
idity
aft
er
HRC I
Part
ial vap.
pre
ss.
aft
er
HRC I
Supply
air
cons.
(g s
upply
air
/gPW
E)
Supply
air
cons.
(kg s
upply
air
/s)
Mois
ture
reception
(g m
ois
ture
/g P
WE)
Heat
reception
(J h
eat
/g P
WE)
Heat
reception
(MW
)
%mu θdu3 θu3 wu3 hu3 φu3 pDu3 ∆mu3 ∆mu3 ∆wu3 ∆huI ∆huI ηθ i%mu θdi2 θi2 wi2 hi2 φ i2 pDi2 ∆mi2 ∆mi2 ∆wi2 ∆hiI ∆hiI
% °C °C g/kg J/g % kPag/g
PWEkg/s
g/g
PWE
J/g
PWEMW % % °C °C g/kg J/g % kPa
g/g
PWEkg/s
g/g
PWE
J/g
PWEMW
100 56,3 56,3 125 382 100 16,7 8,14 70,6 0,03 320 2,77 55 100 6,0 48,5 5,8 64,1 8,2 0,936 8,1 70,6 0,00 320 2,77
100 65,6 65,6 214 626 100 25,6 4,72 41,0 0,02 212 1,84 55 100 6,0 54,0 5,8 69,7 6,2 0,936 4,7 41,0 0,00 212 1,84
6th 7th 9th 8th 5th 4th 1st 2nd 3rd
DS DT DU DV DW DX DY ED EE EF EG EH EL EM EN EO EP EQ
Exhaust air after HRC II, this is in u3' Heat deliv. between u3&u3' Heat reception between u3 & u3'
Mass s
upply
air
aft
er
HRCII
in %
of
mu
Dew
poin
t
aft
er
HRC I
I
Tem
p.
aft
er
HRC I
I
Absolu
te h
um
idity
aft
er
HRC I
I
Enth
alp
y a
fter
HRC I
I
Rela
tive h
um
idity
aft
er
HRC I
I
Part
. vap.
pre
ss.
aft
er
HRC I
I
Dry
ing a
ir c
ons.
(g a
ir/g
PW
E)
Dry
ing a
ir c
ons.
(kg a
ir/s
)
Mois
ture
delivery
(g m
ois
t./g
PW
E)
Heat
delivery
(J h
eat/
g P
WE)
Heat
delivery
(MW
)
Mass w
ate
r to
HRC I
I
Mass w
ate
r to
HRC I
I
Tem
p.
befo
re
HRC I
I
Tem
p.
aft
er
HRC I
I
Heat
reception
in H
RC I
I
Heat
reception
in H
RC I
I
% mu θdu3 ' θu3 ' wu3 ' hu3 ' φu3 ' pD3 ' ∆mu3 ' ∆mu3 ' ∆wu3 ' ∆huII ∆huII mw1 mw1 θwi1 θwu1 ∆hwII ∆hwII
% °C °C g/kg J/g % kPag/g
PWEkg/s
g/g
PWE
J/g
PWEMW
g
w/gkg/s °C °C
J/g
PWEMW
100 56,3 56,3 125 382 100 16,7 8,14 70,6 0,00 0 0,00 0 0 55,0 55,7 0 0,00
100 62,4 62,4 177 527 100 22,2 4,72 41,0 0,17 471 4,08 154 1.336 55,0 55,7 471 4,08
6th 7th 9th 8th 5th 4th 3rd
ET EU EV EW EX EY EZ FE FF FG FH FI FM FN FO FP FQ FR
Exhaust air after HRC III, this is in u3'' Heat delivery between u3' & u3''Heat reception between u3' & u3''
Mass s
upply
air
aft
er
HRC I
II in %
of
mu
Dew
poin
t
aft
er
HRC I
II
Tem
pera
ture
aft
er
HRC I
II
Abs.
hum
idity
aft
er
HRC I
II
Enth
alp
y
aft
er
HRC I
II
Rela
tive h
um
idity
aft
er
HRC I
II
Part
ial vapour
pre
ss.
aft
er
HRC I
II
Dry
ing a
ir c
ons.
(g a
ir/g
PW
E)
Dry
ing a
ir c
ons.
(kg a
ir/s
)
Mois
ture
delivery
(g m
ois
ture
/g P
WE)
Heat
delivery
(J h
eat/
g P
WE)
Heat
delivery
(MW
)
Mass w
ate
r
to H
RC I
II
Mass w
ate
r
to H
RC I
II
Tem
pera
ture
befo
re H
RC I
II
Tem
pera
ture
aft
er
HRC I
II
Heat
reception
in H
RC I
II
Heat
reception
in H
RC I
II
%mu θdu3 '' θu3 '' wu3 '' hu3 '' φu3 '' pDu3 '' mu3 '' mu3 '' ∆wu3 '' ∆huIII ∆huIII mw2 mw2 θwi2 θwu2 ∆hwIII ∆hwIII
% °C °C g/kg J/g % kPag/g
PWEkg/s
g/g
PWE
J/g
PWEMW
g w/g
PWEkg/s °C °C
J/g
PWEMW
100 53,7 53,7 108 334 100 14,8 8,14 70,6 0,14 394 3,42 3,20 27,8 20,0 49,3 394 3,42
100 58,7 58,7 144 434 100 18,8 4,72 41,0 0,16 439 3,81 3,20 27,8 20,0 52,6 439 3,81
6th 7th 9th 8th 5th 4th 3rd
FU FV FW FX FY FZ GA GF GG GH GI GJ GN GO GP GQ GR GS
Exhaust air after HRC IV, this is in u4 Heat del. between u3'' & u4' Heat reception between u3'' & u4
Mass s
upply
air
aft
er
HRCIV
in %
of
mu
Dew
poin
t aft
er
HRC
IV
Tem
pera
ture
aft
er
HRC I
V
Abs.
hum
idity a
fter
HRC I
V
Enth
alp
y a
fter
HRC
IV
Rela
tive h
um
idity
aft
er
HRC I
V
Part
ial vapour
pre
ss.
aft
er
HRC I
V
Dry
ing a
ir
consum
ption
Dry
ing a
ir
consum
ption
Mois
ture
delivery
(g m
ois
ture
/g P
WE)
Heat
delivery
(J h
eat/
g P
WE)
Heat
delivery
(MW
)
Mass w
ate
r to
HRC
IV
Mass w
ate
r to
HRC
IV
Tem
pera
ture
befo
re
HRC I
V
Tem
pera
ture
aft
er
HRC I
V
Heat
reception in
HRC I
V
Heat
reception in
HRC I
V
% mu θdu4 θu4 wu4 hu4 φu4 pDu4 mu4 mu4 ∆wu4 ∆huIV ∆hu IV mw3 mw3 θwi3 θwu3 ∆hwIV ∆hwIV
% °C °C g/kg J/g % kPag/g
PWEkg/s
g/g
PWE
J/g
PWEMW
g w/g
PWEkg/s °C °C
J/g
PWEMW
100 52,3 52,3 100 311 100 13,8 8,14 70,6 0,07 187 1,62 4,00 34,7 35,0 46,7 187 1,62
100 56,0 56,0 123 377 100 16,5 4,72 41,0 0,10 268 2,32 4,00 34,7 35,0 51,7 268 2,32
6th 7th 9th 8th 5th 4th 3rd
Code
Pro
duction h
ours
PM
(=re
el pro
duction)
Enth
alp
y e
xh.a
ir
when θ
= θ
dew
HRC I (pre-heating supply air)
HRC II (heating process water)
HRC III (heating spraywater)
HRC IV (heating glycol)
Pro
ductw
ate
r
evapora
tion
Heat
delivery
betw
een θ
& θ
dew
Drying section
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 88
0,9 13,8 (pD) partial vapour pressure (kPa) 17,3 18,8
391 °C i4
364 °C i3 28
584 °C i3
393
422
393
temperature (θ in oC)
382 Exhaust air (u1)
80 °C U1
U2 θnb=
57,0 °C 58,8
56 °C
u3' u3
56,3 °C
36 u3''
53,7 °C382 3
9 u3'' 58,7 °C
52,3 °C u4
76 0
88
49 °C i2
100 334 100
64,164,1
311 48
901
Supply air 23
10 °C i1
24,8 39 88
30
5,8 100 absolute humidity (wD in g/kg air) 125,2 128,7
=i1 =u4 u3 =u2
Moisture increase per kg dry air: ∆w = wu1-wi1 = 123 g moisture / kg air
Required air per kg PWE: 1000 g : ∆w g/kg = 8,14 kg air / kg PWE
Consumpt. without HRC: 8,14 x (hi3 - hi1) = 2999 kJ/kg PWE
HRC when cooling exhaustair till 52,3 °C is 30 % of heat consumption
Attention: for HRC is a minimal temperature difference required between both flows !!!!!
"% of mu" = mass percentage of the exhaust air from the dryer
Heat receiving flow Heat delivering flow Heat recovery
heating of quantity unit from oC to oC cooling of % of mufrom oC to oC path J/g PWE GJ/a €/a
HRC I supply air 100 % of mu 10,0 48,5 exhaust air 100 80,0 56,3 u1 - u3 320 69.900 593.826
HRC II processwater 4.810 m3/h 55,0 55,7 exhaust air 100 56,3 56,3 u3 - u3' 0 0 0
HRC III spraywater 100 m3/h 20,0 49,3 exhaust air 100 56,3 53,7 u3' - u3'' 394 86.159 731.952
Share HRC in heating process water 0% Share steam in heating process water 100% u1 - u3'' 901 156.060 1.325.778
Share HRC in heating spray water 84% Share steam in heating spray water % 16%
Heat consumption
Heat consumption without HRC (process water is 0 oC) = g air/g PWE x (hi4 - hi1) J / g air = i1 - i4 3.230 706.210 5.999.483
Heat consump. without HRC (process water is 55,7oC) = g air/g PWE x (hi3 - hi1) J / g air = i1 - i3 2.999 655.705 5.570.429
Heat consumpt. incl. HRC I (process water is 55,7oC) = g air/g PWV x (hi3-hi2eq) J/g lucht = i2 - i3 2.679 585.805 4.976.603
Heat consump.incl. HRC I,II&III (processw. is 55,7 oC) = g air/g PWE*((hi3-hi1)-0,01mu(hu1-hu3''))J/g air=i - u 2.285 499.646 4.244.651
MED: Figure 2 Results reference process (exh. air: 80,0 °C; rh = 36 %)
(p
D) p
arti
al va
po
ur p
re
ssu
re
(k
Pa
)
(w
D) a
bso
lute
hu
mid
ity
g/
kg
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 89
0,9 16,5 partial vapour pressure (pD in kPa) 25,9 27,7
631 °C i4
584 °C i3 49
622
671
637
Exhaust air (u1)626 Exhaust air (u1)
90 °C temperature U1
U2 θnb=
66,0 °C 67,3
66 °C 62,4 °C u3 45
u3'
u3''
53,7 °C 37 u3'' 58,7 °C 527 J/g
56,0 °C u4
76434 1
00
238
54 °C i2 %mu=
100100
69,769,7
377 93
1389
Supply air 57
10 °C i1 J/g HRC III
25 4
5
238
49
5,8 (w) 123 absolute humidity (wD in g/kg air) 213,7 217,6
=i1 =u4 u3 =u2
Moisture increase per kg dry air: ∆w = wu1-wi1 = 212 g moisture / kg air
Required air per kg PWE: 1000 g: ∆w g/kg = 4,72 kg air / kg PWE
Consumpt. without HRC 4,72 x (hi3 - hi1) = 2822 kJ/kg PWE
HRC when cooling exhaustair till 56,0 °C is 49 % of heat consumption
Attention: for HRC is a minimal temperature difference required between both flows !!!!!
"% of mu" = mass percentage of the exhaust air from the dryer
Heat receiving flow Heat delivering flow Heat recovery
heating of quantity unit from oC to oC cooling of % of mu from oC to oC path J/g PWE GJ/a €/a
HRC I supply air 100 % of mu 10,0 54,0 exhaust air 100 90,0 65,6 u1 - u3 212 46.373 393.956
HRC II processwater 4.810 m3/h 55,0 55,7 exhaust air 100 65,6 62,4 u3 - u3' 471 102.878 873.984
HRC III spraywater 100 m3/h 20,0 52,6 exhaust air 100 62,4 58,7 u3' - u3'' 439 95.985 815.427
Aandeel WTW in opwarmen proceswater % 100% Aandeel stoom in opwarmen proceswater % 0% u1 - u3'' 1.389 245.237 2.083.367
Aandeel WTW in opwarmen sproeiwater % 93% Aandeel stoom in opwarmen sproeiwater % 7%
Heat consumption
Heat consumption without HRC (process water is 0 oC) = g air/g PWE x (hi4 - hi1) J / g air = i1 - i4 3.053 667.458 5.670.268
Heat consump.without HRC (process water is 55,7 oC) = g air/g PWE x (hi3 - hi1) J / g air = i1 - i3 2.822 616.953 5.241.214
Heat consumpt. incl. HRC I (processwater is 55,7 oC) = g air/g PWV x (hi3-hi2eq) J/g lucht = i2 - i3 2.610 570.580 4.847.257
Heat consump.incl.HRC I,II&III (processw. is 55,7 oC) = g air/g PWE*((hi3-hi1)-0,01mu(hu1-hu3''))J/g air= i - u 1.700 371.716 3.157.847
MED: Figure 2 Results optimal process (exh. air: 90,0 °C; rh = 37 %)
pa
rti
al va
po
ur p
re
ssu
re
(p
D i
n k
Pa
)
(w
D) a
bso
lute
hu
mid
ity (
g/
kg
)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 90
Exercise 6 (page 5)
pDu1 = 0,611 * 2,71828 ^ (17,27*57)/(237,3+57) = 17,3 kPa
wu1 = 1000 * (18/28,84) * ((0,611*exp(1)^((17,27*57))))/(237,3+57)) /
(101,325-(0,611*exp((17,27*57))))/(237,3+57)))))) = 129 g/kg
φu1 = ((0,611*exp(1)^((17,27*57)/(237,3+57)) )) /
(((0,611*exp(1)^(17,27*80)/(237,3+80))))) * 100 = 36,4 %
hu1 =1,009 * 80 + 5,81 * (2501,6 + 1,84 * 80 ) = 422 kJ/kg (dry) gas
θnbu1 = 58,8 oC
Optimal situation:
Given: θDu1 = 66 oC and θu1 = 90 oC;
pDu1 = 25,9 kPa
wu1 = 218 g/kg
φu1 = 37,1 %
hu1 = 671 kJ/kg (dry) gas
θnbu1 = 67,28 oC
Consumption drying section
The yellow marked formulas are applied in the answers:
Drying air consumption:
mair/PWE =1000 /(wvap.exh. –wvap.supp.) g air/g PWE
m.air/s = (PWE) g PWE/s * (mair) g air/g PWE * 0,001 kg/s
Moisture reception:
∆wvapour= mair/PWE * (wvap.exh – wvap.supp) * 0,001 g/g PWE
Heat consumption without heat recovery air/air:
∆hPWE = mair/PWE * (hi3 – hi1) J/g PWE; for hi3 and hi1 see Fig.2-Mol
∆hsec = (PWE) g PWE/s * ∆hPWE * 0,000001 MW
Reference situation:
Drying air consumption:
mair/PWE = ∆mu = 1000 /(128,7 – 5,8) = 8,14 g air/g PWE
mair/s = mu = 8676 * 8,14 * 0,001 = 70,58 kg/s
Moisture reception:
∆wvapour= ∆wu = 8,14 * (128,7 – 5,8) * 0,001 = 1,000 g/g PWE
Heat consumption without heat recovery air/air:
∆hPWE = ∆hu = 8,14 * (393 – 24,8) = 2999 J/g PWE; for hi3 and hi1 see Fig.2-Mol
Remark: exhaust air h = 422 J/g (see page 4) and process-water is 55 oC (see page 2); heat already in process-water per g drying air: 55oC * 4,2 J/(oC.g) / 8,14 g air/g PWE = 28,4 J/g air; this means that the air should be heated till 422 – 28,4 = 393 J/g air
∆hsec =hu = 8676 * 2999 * 0,000001 = 26,02 MW
Optimal situation:
Drying air consumption:
mair/PWE =∆mu = 1000 /(218 – 5,8) = 4,72 g air/g PWE
mair/s = mu = 8676 * 4,72 * 0,001 = 40,97 kg/s
Moisture reception:
∆wvapour=∆wu = 4,72 * (218 – 5,8) * 0,001 = 1,000 g/g PWE
Heat consumption without heat recovery air/air:
∆hPWE = ∆hu = 4,72 * (622 – 24,8) = 2822 J/g PWE; for hi3 and hi1 see Fig.2-Mol
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 91
Exercise 6 (page 6)
Remark:
exhaust air h = 671 J/g (see page 5) and process-water is 55 oC (see page 2); heat already in process-water per g drying air: 55oC * 4,2J/(oC.g) / 4,72 g air/g PWE = 48,9 J/g air; this means that the air should be heated till 671 – 49 = 622 J/g air
∆hsec = hu = 8676 * 2822 * 0,000001 = 24,48 MW
Calculating exhaust air temperatures (θu3, θu3’, θu3” and θu4) after respectively HRC I,
II, III and IV:
The temperature after each HRC depends on the amount of heat-exchange (∆hu) in
J/g PWE or in MW:
Reference situation:
HRC I: heat-exchange exhaust air – supply air:
1st : ŋθ = (θi2 - θi1) / (θu1 - θi1) * 100% (see figure 9 in chapter 9.3)
θi2 = 55 * 0,01 * (80 – 10) + 10 = 48,5 oC
2nd: h = cp av.air . θ + wvapour . (hRo + cp av.vapour . θ ) kJ/kg (dry) gas
hi2 = 1,01*48,5 + 0,001*5,8*(2501,6 + 1,84*48,5) = 64,1 J/g
3rd: ∆hiI = ∆mi2 (g air/g PWE)* (hi2 – hi1) (J/g air) (= J/g PWE)
∆hiI = 8,14 * (64,2 – 24,8) = 320 J/g PWE
∆hiI = (PWE) g PWE/s * (∆hiI) J/g PWE * 0,000001 MW
∆hiI = 8676 g PWE/s * 320 J/g PWE * 0,000001 = 2,77 MW
4th: Heat reception = heat delivery; ∆hiI = ∆huI
The enthalpy of the exhaust air after HRC I (hu3) is the enthalpy of the
exhaust air after the dryer (hu1) minus ∆huI
For calculating the temperature of the exhaust air after HRC I it is necessary
to know whether this temperature (θu3) is above or below the dewpoint
(θdu2); to do this we can also check if hu3’ is above or below hu2.
First the partial vapour pressure pDu3 should be calculated:
5th: pDu3 = if (hu3 => hu2; pd1; if (hu3>3158; …………(multi-stage polynomial)
pDu3 = 16,7 kPa
After pDu3 is calculated the dew-point θdu3 can be calculated:
6th: θdu3 = ((ln (1,639 * pDu3)*(237,3 + θdu3)) / 17,27)
θdu3 = ((ln (1,639 * 16,7)*(237,3 + θdu3)) / 17,27) = 56,3 oC
7th: θu3 = if (hu3 <= hu2; θdu3; wu3*0,001*(2501,6+1,84*θu3) / 1,01
θu3 = 56,3 oC
8th: hu3 = hu1 - ∆huI / ∆mu3
hu3 = 422 – 320 / 8,14 = 382 J/g
9th: wu3 = if (hu3 => hu2; wu1; if (hu3>3979; …………(multi-stage polynomial)
wu3 = 125,2 g vapour/kg dry air
HRC II: heat-exchange exhaust air – process water:
1st : θwi1= 55,0 oC ( temperature process water before HRC II)
2nd: θwu1= 55,7 oC (temperature process water after HRC II)
3rd u/ i 9th: see HRC I
HRC III: heat-exchange exhaust air – spray water:
1st : θwi2 = 20,0 oC ( temperature spray water before HRC III)
2nd: θwu2= 49,3 oC (temperature spray water after HRC III)
3rd u/ i 9th: see HRC II
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 92
Exercise 6 (page 7)
HRC IV: heat-exchange exhaust air – glycol:
1st : θwi3 = 35,0 oC ( temperature glycol before HRC IV)
2nd: θwu3 = 46,7 oC (temperature glycol after HRC IV)
3rd u/ i 9th: see HRC II
Optimal situation:
HRC I: heat-exchange exhaust air – supply air:
1st : θi2 = 54,0 oC
2nd: hi2 = 69,7 J/g
3rd: ∆hiI = 212 J/g PWE
∆hiI = 1,84 MW
4th: ∆hiI = ∆huI = 212 J/g PWE
5th: pDu3 = 22,2 kPa
6th: θdu3 = 62,4 oC
7th: θu3 = 62,4 oC
8th: hu3 = 527 J/g
9th: wu3 = 177 g vapour/kg dry air
Remark: difference temperatures exhaust air and water (or glycol)
Reference situation:
Heating spray water in HRC III:
θdu3’ = 56,3 oC (dew point after HRC II; see: MED table 4 column DT)
∆θ = 7,0 oC (temp.diff. exhaust HRC II and spray-water out;MED table1.1, col.r)
θwu2 = 49,3 oC (temp. spray-water after HRC III; see: MED table 4 column FP)
Heating glycol in HRC IV:
θdu3” = 53,7 oC (dew point after HRC III; see: MED table 4 column EU)
∆θ = 7,0 oC (temp.diff. exhaust HRC III and glycol out; MED table 12 cell 14)
θwu3 = 52,6 oC (temp. glycol after HRC IV; see: MED table 4 column GQ)
Optimal situation:
Heating spray water in HRC III:
θdu3’ = 62,4 oC (dew point after HRC II; see: MED table 4 column DT)
∆θ = 7,0 oC (temp.diff. exhaust HRC II and spray-water out;MED table1.1, col.r)
θwu2 = 55,7 oC (temp. spray-water after HRC III; see: MED table 4 column FP)
Heating glycol in HRC IV:
θdu3” = 58,7 oC (dew point after HRC III; see: MED table 4 column EU)
∆θ = 7,0 oC (temp.diff. exhaust HRC III and glycol out; MED table 12 cell 14)
θwu3 = 51,7 oC (temp. glycol after HRC IV; see: MED table 4 column GQ)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 93
PART IV UTILITIES FOR DRYING
14 FANS, PUMPS AND COMPRESSORS
14.1 Introduction
In Annex C an elaborate description is given for calculating electricity consumption for
fans, compressors an pumps.
Here only a summary of this annex will be depicted.
14.2 Power consumption pumps
Total head pumps
Head is a concept that relates the energy in a fluid to the height of an equivalent static
column of that fluid. Head is expressed in m of height.
The static head of a pump is the maximum height (pressure) it can deliver. The
capability of the pump can be read from its Q-H curve (flow vs. height).
Head is equal to the fluid's energy per unit weight.
Head is useful in specifying centrifugal pumps because their pumping characteristics
tend to be independent of the fluid's density.
There are four types of head used to calculate the total head in and out of a pump:
elevation, pressure, velocity and resistance head. The equation is shown in formula (39)
in box 1.
With formula (40) height can be converted in kPa (=kN/m2) and, as the difference
between pressure gauges on the discharge and suction side of the pump is equal to the
total head, formula (42) can be derived from formula’s (39) and (41).
The resistance loss in pipes and tubes due to friction depends on the flow velocity, pipe
or duct length, pipe or duct diameter, and a friction factor based on the roughness of
the pipe or duct, and whether the flow us turbulent or laminar – the Reynolds Number
of the flow. The resistance loss is divided in major loss due to friction and minor loss
due to change of velocity in bends, valves and similar. The latter are also expressed in
equivalent friction losses.
The resistance loss in a tube or duct due to friction can be expressed as:
ploss.resistance = λ* (l / dh) * (½ * ρ * vpipe2 ) (44)
Where:
ploss.resistance = pressure loss (kPa)
λ = friction coefficient
l = length of duct or pipe (m)
dh = hydraulic diameter (m)
vpipe = flow velocity in pipe or duct (m/s)
For an existing pump system λ, l, and dh are constant (Cpipe):
Cpipe = λ* (l / dh) (45)
Substituting formula (44) in (45):
ploss.resistance = Cpipe * (½ * ρ * vpipe2 ) (46)
Power consumption pumps
The power required to drive a pump is defined by formula (43) in box 1.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 94
Box 1 Head and required power pumps
Explanation symbols and units
p = pressure in N/m2 (=Pa)
(1 bar = 105N/m2; 1 kN = 1 kg.m/s2)
ρ = fluid density in kg/m3
(ρwater = 1000 kg/m3)
g = acceleration due to gravity
(g = 9,81 m/s2)
Pinput = required input power in kW
H = energy head added to the flow in m
Q = flow rate in m3/s or m3/h
ŋpump = total efficiency pump (as decimal)
ŋmotor = efficiency electric motor (as decimal)
Total head (Htot in m):
Htot = (h1 – h2) + resistance
2
2
2
121 H2g
vv
gρ
p p
(39)
Elevation head pressure head velocity head resistance head
Static head (independent of flow) Dynamic head (depending on flow)
Resistance head is friction loss in pipes, ducts, bends etc.
Conversion of pressure (p in N/m2) in head (m):
p (N/m2) = ρ (kg/m3) x g (m/s2) x h (m) (40)
(Note: N = kg.m/s2)
Difference between outlet and inlet pressure pump (= pman):
pman = poutlet – pinlet (41)
Total head (pman = ρ.g.Htot = poutlet – pinlet in kN/m2)
pman = ρ.g.Hgeo + (p1 – p2) + ½ . ρ . )v(v2
2
2
1 + Cpipe .(½. ρ. vpipe2) (42)
Required power electric motor when Q in m3 water/s and p in kPa
Pinput =)ηx(η
}kPa)p(px /s{(Q)m
pompmotor
inletoutlet
3 kW (43)
h1
h2
v2
v1
p1
p2
poutlet
outle
pintlet
outle
Hg
eo =
h
1 -
h2
pressure gauges are on the same height level
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 95
Pump efficiency (ηpump) is defined as the ratio of the power imparted on the fluid by the
pump in relation to the power supplied to drive the pump.
Efficiency is a function of the discharge and therefore also operating head; this
means its value is not fixed for a given pump. One important part of system design
involves matching the pipeline headloss-flow characteristic with the appropriate pump
which will operate at or close to the point of maximum efficiency.
Pump efficiencies tend to decline over time due to wear.
The energy usage is determined by multiplying the power requirement by the length of
time the pump is operating.
Pinput =)ηx(η
}kPa)p(px /s{(Q)m
pompmotor
inletoutlet
3 kW (43)
In this formula poutlet – pinlet is the pressure difference between the discharge and
suction gauge on the pump; we will call this difference “manometric head’’:
pman = poutlet – pinlet (41)
This head is equal to the total head (pman = ρ.g.Htot = poutlet – pinlet in kN/m2):
pman = ρ.g.Hgeo + (p1 – p2) + ½ . ρ . )v(v2
2
2
1 + Cpipe .(½. ρ. vpipe2) (42)
14.3 Power consumption fans
Power consumption centrifugal fans and compressors
In thermo dynamics two compression processes are distinguished: isothermal
compression and isentropic compression.
Isothermal compression assumes that the compressed gas remains at a constant
temperature throughout the compression process. This is only possible when during
compression heat is removed. Compressors that utilize inter-stage cooling between
compression stages come closest to achieving isothermal compression.
Isentropic compression assumes that no heat is removed from the gas during the
compression, and all supplied work is added to the internal energy of the gas, resulting
in increases of temperature and pressure. Theoretical temperature rise is:
Toutlet = Tinlet x (poutlet/pinlet)(k-1)/k
(47)
Where:
Toutlet = outlet temperature in K
Tintlet = inlet temperature in K
poutlet = outlet pressure in kPa
pinlet = inlet pressure in kPa
k = cp/cv, (= ratio of specific heats, approximately 1,4 for air and 1,3 for water vapor)
Isentropic (also called adiabatic) compression is more closely real life.
Isothermal compression takes less work than isentropic (adiabatic) compression:
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 96
Pisentropic=)ηx(η
}1)p
p{(x
1k
kx (kPa)px /s)V(m
compressormotor
k
1k
inlet
outlet
inlet
3
kW (48)
Pisothermic= Wk)ηx(η
p
p lnx (kPa) px /s)(mV
compressormotor
inlet
outlet
inlet
3
(49)
Where:
pinlet = inlet pressure in kPa
poutlet = outlet pressure in kPa
ηmotor = efficiency electric motor in decimal
ηcompr. = efficiency compressor or fan in decimal
V = flow rate in m3/s (at inlet pressure)
Pisentropic = required power for isentropic compression in kW
Pisothermic = required power for isothermic compression in kW
k = cp/cv, (= ratio of specific heats, appr. 1,4 for air and 1,3 for water vapor)
Total head fans
For fans also four kinds of head can be distinguished.
There are however important differences between the transport fluids:
- the density of water in pumps is 1000 kg/m3 and for air in fans this is about 1,3
kg/m3 at standard conditions (0 oC and 101,325 kPa)
- water is incompressible and air is compressible
In box 1 is derived that for pumps the required power: P(kW)= Q (m3/s) x pman (kPa).
In this formula the required power for liquid pumps depends on the difference between
the inlet and outlet pressure pman is:
pman = poutlet – pinlet (41)
pman = ρ.g.Hgeo + (pa – pe) + ½ρ. )v(v 2
e
2
a + Cpipe .(½. ρ. vpipe2) (42)
pman =elevation head + pressure head + velocity head + resistance head
The required power for gas compressors and fans for air depends on the pressure ratio:
“pman” = pinlet x (k/(k-1)) x (((poutlet/pinlet)^((k-1)/k))-1)
(51)
When the suction and discharge pipes of the fans are at the same level (Hgeo=0) and
the air velocities are also the same (va = ve) then the elevation head (ρ.g.Hgeo) and the
velocity head (½ρ. )v(v 2
e
2
a ) can be neglected. In these cases the power consumption
depends on the pressure head and the resistance head.
In yankee hoods pressure head is a result of the pressure drop in the plenum where air
velocities of more than 100 m/s are created. Also blow boxes in multi-cylinder dryers
may
need pressure head.
Resistance head
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 97
The pressure loss ducts due to friction depends on the flow velocity, pipe or duct length,
pipe or duct diameter, and a friction factor based on the roughness of the pipe or duct,
and whether the flow is turbulent or laminar – the Reynolds Number of the flow-.
The pressure loss in a tube or duct due to friction can be calculated with formula’s (44,
45 & 46).
Electrticity consumption supply, exhaust and circulation fans
When optimizing the energy efficiency of drying processes very often the dew point of
the exhaust air in the optimal situation will be higher than in the reference situation.
When this happens the amount of air will decrease and the absolute vapour content of
this air (g vapour / kg dry air) will increase. This may result in substantial electricity
savings for supply and exhaust air fans of the dryer.
Usually the electricity consumption in the reference situation is known.
In table C1 of Annex C the formula’s for centrifugal fans are applied on supply air,
exhaust air and circulation fans for multi cylinder and yankee dryers for as well the
reference as the optimal situation.
The known data of the reference situation are applied to try to predict the electric
consumption in the optimal situation.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 98
15 ENERGY CONVERSION
15.1 Introduction
In Annex B an elaborate description is given for equipment, heat recovery possibilities
and efficiencies of the energy conversion. In Annex A the method of working is
described when combustion processes are involved.
Calculations on unit operations with combustion processes are very extensive and to
make the right choice for heat recovery extensive calculations are necessary.
Software for these calculations is provided in MED II and IV. In the next chapter a
sample of these calculations will be shown.
15.2 Heat recovery in the energy conversion
Additional heat recovery for auxiliary processes, such as heating spray water for
cleaning wires, can be obtained from the rest heat of the energy conversion.
As an example the configuration of two of these conversions with heat recovery is
shown in figures 13 and 14.
In figure 13 spray water (spw) is heated by boiler feed water (bfw) in heat exchanger
(HE3). The heat exchange is 5,04 MW. As a result the bfw is cooled down 33,3 oC
(from 105 oC to 71,7 oC). As a result the flue gasses will normally also be cooled 33,3 oC (from 99 oC to 65,7 oC) in the economizer. For economic reasons however there
should be a minimum temperature difference between the flue and the bfw of 15 oC.
The saving is only 1,97 MW.
In figure 14 spray water (spw) is heated by flue gasses (flue) in heat exchanger (HE3).
As a result the flue is cooled down 37 oC (from 107 oC to 70 oC). The heat exchange is
5,04 MW. The saving is also 5,04 MW.
Although the investment for water-water heat exchangers are lower than those for
water-gas heat exchangers, the latter gives better results. Generally high air factors in
th foregoing combustion process will give better results.
In table 13, with help of MED-software some situations are calculated and compared.
Table 13 Comparison heat recovery from feed water and flue gas
a b c d e f g h i j k l m n o
1 Configuration Consumption and production Heat recovery Savings
2
3
4
5
6
7 - - -oC oC MW MW MW MW MW MW MW MW MW MW
8
8 SBno heat
recovery1,15 150 92,28 0 0 85,9 5,04 0 0 5,04 97,32 0
9 SBboiler feed
water1,15 117 96,14 0 0 85,9 5,04 5,04 0 0 96,14 1,18
10 SB flue gas 1,15 150 55 92,28 0 0 85,9 5,04 0 5,04 0 92,28 5,04
11 SBno heat
recovery1,84 103 92,24 0 0 85,9 5,04 0 0 5,04 97,28 0
12 SBboiler feed
water1,84 89* 95,27 0 0 85,9 5,04 5,04 0 0 96,62 0,66
13 SB flue gas 1,84 101 46 92,24 0 0 85,9 5,04 0 5,04 0 92,24 5,04
14 GT+SB+STno heat
recovery1,84 137 158,39 42,13 12,8 85,9 5,04 0 0 5,04 163,43 0
15 GT+SB+STboiler feed
water1,84 104 159,84 42,13 12,8 85,9 5,04 5,04 0 0 159,84 3,59
16 GT+SB+ST flue gas 1,84 101 52 158,39 42,13 12,8 85,9 5,04 0 5,04 0 158,39 5,04
16 GT+SB+STno heat
recovery2,65 101 158,39 42,13 12,8 85,9 5,04 0 0 5,04 163,43 0
18 GT+SB+STboiler feed
water2,65 86,7* 161,46 42,13 12,8 85,9 5,04 5,04 0 0 161,46 1,97
19 GT+SB+ST flue gas 2,65 101 70 158,39 42,13 12,8 85,9 5,04 0 5,04 0 158,39 5,04
** Heating spraywater: 40 kg/s from 25 oC to 55 oC (= 5,04 MW) * Correction due to: θflue => θboilerfeedwater + 15 oC
*** SB = steam boiler; GT = gasturbine + generator; ST = steam turbine + generator
energ
y c
onvers
ion
***
tem
p.
flue a
fter
heat
exchanger
spra
y w
ate
r
heat
recovery
fro
m
air
facto
r
ste
am
pro
duction
ste
am
boiler
Savin
gs
tem
p.
flue a
fter
boiler
gas c
onsum
ption
energ
y c
onvers
ion
(SB
+G
T+
cofiri
ng)
ele
ctr
icity
pro
duction g
as
tubin
e
ele
ctr
icity
pro
duction g
as
tubin
e
gas c
onsum
ption
heating s
pra
y w
ate
r
requir
ed h
eat
for
spra
y w
ate
r **
heat
recovery
fro
m
boiler
feed w
ate
r
heat
recovery
fro
m
flue b
oiler
tota
l gas
consum
ption
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 99
15.3 Heat savings and electricity production
Heat savings on the drying section may result in less steam supply to the steam-
turbine. If the amount of steam is below design specifications the flow in the turbine will
not be optimal and there will be more internal losses. This results in an increase of the
entropy of the outlet steam (=”back pressure” steam). Figure B7 of annex B shows
that, at a certain back pressure, this will result in an increase in enthalpy and
temperature. As a result the enthalpy drop and thus the electricity production shall
decrease. To calculate cost savings an adjusted gas-price is applied. See table 14.
Note that there is no energy loss: the sum of the enthalpy drop in the steam turbine
and the steam to the production processes shall not change.
Table 14 Calculating steam and gas-consumption and adjustment gas-price
REFERENCE SITUATION OPTIMAL SITUATION Difference
Net production hours 7.000 h/a Net production hours 7.000 h/a 0 h/a
Steam consumption production process according to MPI-Pems Steam consumption production process according to MPI-Pems
Heat delivery steam (=steam - condensate) 2,392 GJ/t Heat delivery steam (=steam - condensate) 2,392 GJ/t
Consumer GJt/a MW ton/a ton/h Consumer GJt/a MW ton/a ton/h
Processwater heating 24.947 0,99 10.428 1,5 Processwater heating 0- 0,00- 0- 0,0- 24.947 GJt/a
Spraywater heating 2.449 0,10 1.023 0,1 Spraywater heating 145 0,01 61 0,0 2.304 GJt/a
Spaceheating mach.hall 1.368 0,05 572 0,1 Spaceheating mach.hall 876 0,03 366 0,1 493 GJt/a
Pre-dryer (H2O-evap.) 247.902 9,84 103.620 14,8 Pre-dryer (H2O-evap.) 219.915 8,73 91.921 13,1 27.988 GJt/a
Pre-dryer (losses) 22.807 0,91 9.533 1,4 Pre-dryer (losses) 14.294 0,57 5.975 0,9 8.513 GJt/a
Spaceheating other 114 0,00 48 0,0 Spaceheating other 118 0,00 49 0,0 -4 GJt/a
Other 10.000 0,40 4.180 0,6 Other 10.000 0,40 4.180 0,6 0 GJt/a
Balance 42 0,00 17 0,0 Balance 77 0,00 32 0,0 -36 GJt/a
Cons. energy conversion319.449 12,68 133.525 19,1 Cons. energy conversion255.245 10,13 106.689 15,2 64.205 GJt/a
Steam to and from steamturbine Steam to and from steamturbine
Pressure steam before steamturbine 81 bar Pressure steam before steamturbine 81 bar 0 bar
Temp. steam before steamturbine 510 oC Temperature steam before steamturbine 510 oC 0 oC
Steam pressure after steam turbine 5 bar Steam pressure after steam turbine 5 bar 0 bar
Temp. steam after steamturbine 220 oC Temperature steam after steamturbine 225 oC -5 oC
Unit prices natural gas and electricity Unit prices natural gas and electricity
Total natural gas 0,35 €/m3o Total natural gas 0,35 €/m3o 0,00 €/m3o
Yield electricity 85 €/MWh Yield electricity 85 €/MWh 0 €/MWh
Consumption natural gas and yield electricity Consumption natural gas and yield electricity
Gas consumption gasturbine 2.196 m30/h Gas consumption gasturbine 2.196 m30/h 0 m30/h
Gas cons. cofiring flue-gas boiler 590 m30/h Gas consumption cofiring flue-gas boiler 230 m30/h 360 m30/h
Total gas consumption 2.786 m30/h Total gas consumption 2.426 m30/h 360 m30/h
Total gas consumption 19.502.000 m30/a Total gas consumption 16.982.000 m30/a 2.520.000 m30/a
Total cost natural gas 6.814.678 €/a Total cost natural gas 5.934.102 €/a 880.576 €/a
Electricity production gasturbine 5,78 MW Electricity production gasturbine 5,78 MW 0,00 MW
Electricity production steamturbine 2,56 MW Electricity production steamturbine 2,00 MW 0,56 MW
Total electricity production 8,34 MW Total electricity production 7,78 MW 0,56 MW
Total electricity production 58.396 MWh/a Total electricity production 54.454 MWh/a 3.943 MWh/a
Yield electricity 4.963.694 €/a Yield electricity 4.628.556 €/a 335.138 €/a
Balance natural gas and electricity 1.850.984 €/a Balance natural gas and electricity 1.305.545 €/a 545.438 €/a
Adjustment gasprice in % in case of production loss electricity due to heat savings
Adjustment gasprice in €/GJt 8,50 €/GJt 8,50 €/GJt
Adjustment gasprice in €/m3o 0,27 €/m3o 0,27 €/m3o
Adjustment gasprice in % 76,95 % 76,95 %
a b c d e f g h i j k l m n
Explanation:
(1) Steam savings (m10) 64.205 GJt/a (5) Adjusted gasprice (m28) 8,50 €/GJt
(2) Total savings natural gas (m21) 880.576 €/a (6) 1 GJt = (1000/31,65=) 31,6 m3o/GJt
(3) Total yield electricity (m26) 335.138- €/a (7) Adjusted gasprice (m29) 0,27 €/m3o
(4) Total net savings (m27) 545.438 €/a (8) Adjusted gasprice (m30) 76,9 %
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 100
φ mdry mvapor θ θdew Q Gas- ŋ gear & generator 95 % Loss 2,11 MJ/s mdry mvapor θ θdew Q
Comb. air 80 147,0 0,89 10 6,74 3,75 tur- dry mass H2O temp. dewtemp
bine ŋ shaft-gasturbine 30 % Electricity 42,13 MW kg/s kg/s oC oC MJ/s
Natural gas mdry mvapor θ θdew Q mdry mvapor θ θdew Q
4,000 m30/s 3,33 5,610 - - 140,4 Oxygen in dry flue gas15,11 % O2 3,37 = λ 144,7 6,50 500 38,5 99,94 Symbols used in figures:
126,71 MW kg/s kg/soC oC MJ/s mdry = dry mass gas (flue, air etc)
Natural gas mdry mvapor θ θdew Q mvapor = vapour
1,097 m30/s Co-firing 0,9 1,539 683 42,3 38,5 m = total mass gas (=mG +mW)
34,75 MW kg/s kg/s oC oC MJ/s θ = temperature
161,46 MW (total gas) θdew = dewpoint
mdry mvapor θ θdew Q Q = enthalpy or heat
Flue losses Without HE2/3 144,1 8,04 99,0 42,3 36,0 Specific heat water 4,20 J/(g.K)
% O2 = 13,46 With HE2/3 144,1 8,05 86,7 42,3 34,1
λ = 2,65 Difference 0,0 0 33,3 0,0 1,97
kg/s kg/s oC oC MJ/s
Correction exhaust gas temperature= 21 oC Steam
(∆Qflue =< ∆Qboiler.feed.water; θflue - θb.feedw =>15oC) boiler
Spraywater 25,0 oC 40,0 kg/s 4,20 MW ŋexhaust
70,0 Losses 0,64 kJ/s
Spraywater 55,0 oC 40,0 kg/s 9,24 MW % ŋgear&gen 95 %
∆=
5,04 ŋco-firing
MW 90,2 Steam
36,0 kg/s HE3 36,0 kg/s % tur-
Deaerator: ∆θ= 10oC; >10oC 441 kJ/kg 441,0 kJ/kg ŋtotal bine Electricity 12,8 MW
105 oC 105 oC 75,4 27,0 kg/s
15,89 MW 15,89 MW % 500 oC
Make-up water 4,2 kg/s ∆= 36,0 kg/s 36,0 kg/s 91,6 MW
(incl. injection water) 12 oC 0,00 De- 441 kJ/kg 301,2 kJ/kg 104,39 Steam
50 kJ/kg Con- 35,1 kg/s MW 35,1 kg/s aer 36,0 kg/s 105,0oC 71,7
oC MW 33,7 5,0 bar 220oC
0,21 MW den- 89,4oC 89,4
oC ator 105oC 15,89 MW 10,85 MW steam 500 27,0 kg/s 2898 kJ/kg
kg make-up water/ sate- 376 kJ/kg HE2 376 kJ/kg 441 kJ/kg 33,7 kg/s 80 78,2 MW
kg steam to process = tank 13,18 MW 13,18 MW 15,9 MW ∆HE3 5,04 MW 71,7oC 3398
12 % ∆θ= 33,3 oC 301 kJ/kg 114,5
10,15 MW
6,7 kg/s Bypass steam
30,9 kg/s 0,96 kg/s 500oC
100oC Steam 184 oC 80 bar
420 kJ/kg to de-aerator 4,85 bar Cooling water 3398 kJ/kg Bypass / total =
12,97 MW Pro- 2824 kJ/kg 2,33 kg/s 22,9 MW 20 %
duction steam to process 2,72 MW 71,7 oC
30,9 kg/s Condens to boilerhouse proces 35,1 kg/s 36,0 kg/s 301 kJ/kg
100 oC 184oC 184
oC 0,70 MW
420 kJ/kg 4,85 bar 4,85 bar Steam
12,97 MW 2824 kJ/kg 2824 kJ/kg cooler 33,7 kg/s
∆MW= 99,1 MW 101,8 MW 2998 kJ/kg
4,2 kg/s 85,9 101,1 MW Nett production hours 7.218 h/a
100oC Condensate losses Check pinch &approach temperatures steamboiler !! Gas(all in) price (GHV=) 35,10 MJ/m3
o) 0,25 €/m3o
420 kJ/kg Check temperature differences and other results Extra HRC from flue gasses steamboiler GJt/a
1,77 MW Minimum ∆θ fluegas boilerout & boilerfeedwater is approx. 20 oC Gross cost heating spraywater in HE 3 €/a
Boiler efficiencies are based on gross heating values (GHV) Extra HRC from flue gasses steamboiler €/a
All costs and savings are based on co-firing Net cost heating spraywater in HE 3 €/a
Figure 13 Gasturbine + exhaust gas boiler with cofiring + steamturbine + heatrecovery from boiler feed water
51.256
1.033.997
404.681
629.316
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 101
Waterinjection GT (for extra G-gas, electricity and heat see chart) 0 kg/m3o 0,00 kg/s mG mW θ θd Q
105,0 oC dry mass H2O temp. dewtemp
Loss 2,11 MJ/s 441,0 kJ/kg kg/s kg/s oC oC MJ/s
φ in % mG mW θ θd MW ŋ gear & generator 95 % 0,00 MW
Comb. air 80 144,4 0,88 10 6,74 3,69 Gas- Symbols used in figures:
kg/s kg/s oC oC MJ/s tur- Electricity 42,13 MW mG = dry mass gas (flue, air etc)
bine ŋ shaft-gasturbine 30 % mW = vapour
Natural gas mG mW θ θd MW mG mW θ θd MW Steam m = total mass gas (=mG +mW)
4,000 m30/s 3,33 5,610 - - 140,4 15,00 % O2 3,311 = λ 142,1 6,49 509 38,8 99,87 boiler θ = temperature
126,71 MW kg/s kg/s oC oC MJ/s θd = dewpoint
Q = enthalpy or heat
Specific heat water 4,20 J/(g.K)
Natural gas mG mW θ θd MW
1,000 m30/s Co-firing 0,83 1,403 678 42,3 35,1
31,68 MW kg/s kg/s oC oC MJ/s
158,39 MW (total gas)
Flue losses mG mW θ θd MW ∆MW= mG mW θ θd MW
% O2 = 13,47 141,5 7,89 70,0 42,3 30,55 5,04 141,5 7,89 100,7 42,3 35,59 Losses 0,6 kJ/s
λ = 2,65 ŋexhaus t ŋgear&gen 95 %
∆mW= 50,2
0,000 % Steam Electricity 12,8 MW
m3 H2O/h 26,9 kg/s tur-
Spraywater 40,00 kg/s (total spraywater = 40,0 kg/s; see also fig ….) ŋco-firing 500 oC bine 26,9 kg/s
25,0 oC 4,20 MW HE3 90,2 91,4 kW 220 oC
% Steam 5 bar
Spraywater 40,00 kg/s 2898 kJ/kg
55,0 oC 9,24 MW ŋtotal 77,9 MW
73,6
%
Make-up water 4,2 kg/s Con- De- 99,4
(incl. injection water) 12 oC den- aer MW
50 kJ/kg 35,1 kg/s ator 36,1 kg/s 33,6 kg/s steam 33,6 6,7 kg/s Bypass steam to process
0,00 MW 89,4 oC 105 oC 105 oC 500 500 oC
sate- 376 kJ/kg 441 kJ/kg 441 kJ/kg 80 80 bar
Condensate 30,9 kg/s tank 13,2 MW 15,9 MW 14,8 MW 3398 3398 kJ/kg Bypass/total= 20 %
100 oC 114,2 22,8 MW
420 kJ/kg
0,00 MW 0,96 kg/s 2,46 kg/s
Steam to de-aerator 184 oC Cooling water 105,0 oC
4,85 bar 441 kJ/kg
2824 kJ/kg 1,09 MW
2,72 MW
Pro-
duction 36,1 kg/s
Condensate to boilerhouse 30,9 kg/s proces 35,1 kg/s 184 oC
100 oC 420 kJ/kg 12,98 MW 184 oC Steam to process 4,85 bar Steam 33,6 kg/s
4,85 bar 2824 kJ/kg cooler 2998 kJ/kg
Condens. losses (incl.conversion) 4,2 kg/s 2824 kJ/kg 101,9 MW 100,8 MW
100 oC 420 kJ/kg 1,77 MW ∆MW= 99,1 MW Check pinch &approach temperatures steamboiler !!
85,9 Check temperature differences and other results Nett production hours 7.218 h/a
kg make-up water / kg steam to process12 % Minimum ∆θ de-aerator out & in is 10 oC Gas(all in) price (GHV=) 35,10 MJ/m3o) 0,25 €/m3
o
Make-up water for compensation production losses Minimum ∆θ fluegas boilerout & boilerfeedwater is approx. 20 oC Extra HRC from flue gasses steamboiler GJt/a
4,2 kg/s 12 oC 50,4 kJ/kg 0,21 MW Boiler efficiencies are based on gross heating values (GHV) Gross cost heating spraywater in HE 3 €/a
All costs and savings are based on additional firing Extra HRC from flue gasses steamboiler €/a
Figure 14 Gasturbine + exhaust gas boiler with cofiring + steamturbine + heatrecovery in flue Net cost heating spraywater in HE 3 - €/a
130.963
1.033.997
1.033.997
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 102
ANNEX A COMBUSTION PROCESSES
For more information about “Combustion processes see handout “Themadag
verbetering energie-efficiency processen met (vochtige) verbrandingsgassen” published by Royal VNP on 20th august 2006.
A1 INTRODUCTION
In chapter 3 “Formula library for drying processes” an overview of formulas for
calculations on humid air for drying processes is given.
In table 4 of chapter 3 the method of working for calculating air conditions and mixing
flows is shown.
These flows are a mixture of only two components: dry air and vapor. Although dry air
consists mainly of two components, N2 and O2, its composition will not change. In
drying processes only the amount of vapor (H2O) per kg dry air will change.
In fact the calculations for humid air only relate to the components dry air and vapor.
Only these components need to be considered in calculations on drying processes.
Calculations on combustion processes are more complicated: CH4 + 2O2 -- 2H2O + CO2
This means that during combustion the chemical reactions will change the composition
of the gas; the amount of O2 will decrease and the amounts of O2 and H2O will increase.
For calculations in drying processes when combustion products are involved four
components need to be considered: N2, O2, H2O and CO2.
A2 COMBUSTION EQUATION
A2.1 Components in natural gas
In table A1 the some components and some of het properties that may be in natural
gas are shown.
In the last column the composition of “Groningen” natural gas (G-gas) is shown; the
caloric values for G-gas are: GHV = 35,17 MJ/m30 and NHV = 31,67 MJ/m3
0.
A2.2 General combustion equation
Stoichiometric combustion
Stoichiometric is the ideal combustion process where fuel is burned completely with no
excess of air..
Process heating equipment is rarely run that way. Combustion in boilers and process
equipment usually incorporates a modest amount of excess air to burn the fuel
completely. This amount is about 4% for boilers and about 200 till 300 % for gas-
turbines.
An insufficient amount of combustion air may result in unburned fuel, soot, smoke, and
carbon monoxide exhausts from the boiler. This results in heat transfer surface fouling,
pollution, lower combustion efficiency, flame instability and a potential for explosion. To
avoid inefficient and unsafe conditions boilers normally operate at an excess air level.
The chemical equation for stoichiometric combustion of methane (CH4) with oxygen can
be expressed as:
CH4 + 2*O2 --> CO2 + 2*H2O
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 103
Table A1 Components, molar mass, -volume and caloric values natural gas
Air contains 21% O2 and 79% N2 :
CH4 + 2*(O2 + (0,79/0,21)N2) --> CO2 + 2*H2O + 2*(0,79/0,21)N2
Air factor
If more air is supplied some of the air will not be involved in the reaction.
The additional air is termed excess air, when air factor λ=2 the theoretical air is 200%
and the excess air is 100%.
The chemical equation for methane burned with excess air can be expressed as:
CH4 + 2*λ(O2 + (0,79/0,21)N2) --> CO2 + 2H2O + 2*λ(0,79/0,21)N2
General combustion equation
s
O2L
222
O2L
nm HLx
λ)
4
n(mO)
4
n(mOH
2
nm.COL
x
λ)
4
n(mHC
(A1)
component
formula molar
mass
(M)
kg/kmol
molar
volume
(VM)
m3o/kmol
Hs =
Gross Caloric
Value
(GHV)
Hi =
Net Caloric
Value
(NHV)
Compo-
sition
“Gron-
ingen”
gas
MJ/kmol MJ/m30 MJ/kmol MJ/m3
0 %
methane
ethene
ethane
propene
propane
1-butane
butane
dimethylpropane
hydrogen sulphide
methanol
carbon monoxide
carbon dioxide
hydrogen
nitrogen
oxygen
water vapor
CH4
C2H4
C2H6
C3H6
C3H8
C4H8
C4H10
C5H12
H2S
CH3OH
CO
CO2
H2
N2
O2
H2O
16,04
28,05
30,07
42,08
44,10
56,11
58,12
72,15
34,08
32,04
28,01
44,01
2,02
28,01
32,00
18,01
22,36
22,24
22,19
21,99
21,93
21,61
21,52
21,29
22,19
21,08
22,40
22,25
22,44
22,40
22,40
21,63
890
1411
1560
2058
2220
2717
2877
3517
563
764
283
-
286
-
-
-
39,82
63,43
70,30
93,61
101,23
125,77
133,69
165,20
25,36
36,25
12,63
-
12,74
-
-
-
802
1323
1428
1926
2044
2541
2657
3253
519
676
283
-
242
-
-
-
35,88
59,48
64,35
87,61
93,21
117,62
123,47
152,80
23,38
32,07
12,63
-
10,78
-
-
-
81,29
2,87
0,38
0,15
0,04
0,89
14,32
0,01
Fuel Combustion air
Combustion products
Consumed oxygen
Combustion air
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 104
Where:
m = the number of C-atoms
n = the number of H-atoms
λ = the air factor
xO2L = mole fraction oxygen in air; xO2L = 0,21
xN2L = mole fraction nitrogen in air; xN2L = 0,79
L = 1 mole combustion air; L = xO2L + xN2L; L = 0,79 N2 + 0,21 O2
Hs = Gross heating value (GHV); for G-gas Hs= 35,17 MJ/m30
Hi = Net heating value (NHV); for G-gas Hi = 31,65 MJ/m30
Mole fraction x (also called amount fraction) expresses the composition of a mixture.
The mole fraction of each component i is defined as its amount of substance ni divided
by the total amount of substance in the system, n.
Usually fuel consists of more than one component. In this case the combustion equation
should be applied to each component and subsequently the results have to be
multiplied by the mole fraction of each component. In table A2 this is shown for the
usual components in natural gas.
By applying formulas (A1), (A2) and (A3) calculations are strongly simplified.
Caloric values (ISO 6976)
Gross caloric value (GHV; Hs):
The amount of heat evolved by the complete combustion of a unit volume of gas
(normally V= 1 m30 at 0 oC and 101,325 kPa) with air at a constant pressure of
101,325 kPa and a constant temperature TH (normally 25 oC) when the combustion
products have once more cooled to the starting conditions and whereby the water
produced by combustion is assumed to be completely condensed.
Net caloric value (NHV; Hi):
The amount of heat evolved by the complete combustion of a unit volume of gas
(normally V= 1 m30 at 0 oC and 101,325 kPa) with air at a constant pressure of
101,325 kPa and a constant temperature TH (normally 25 oC) when the combustion
products have once more cooled to the starting conditions and whereby the water
produced by combustion is assumed to remain as vapor.
A2.3 Combustion Gronings natural gas (G-gas)
To simplify calculations the formulas for G-gas are derived from table A1 and A2.
If not otherwise specified all values are calculated for 1 m30 G-gas (1 m3
0 =1 m3 at 0 oC
and 101,325 kPa)
Fuel
For composition G-gas see table A1.
MB = 18,637 kg/kmol G-gas
VMB = 22,363 m3/kmol G-gas
VGB = amount G-gas in 3
om
mB = 0,827 kg/3
om
cpmB = 1,8 kJ/kg.K (heat capacity)
hB = 36 kJ/kg (specific enthalpy at 20oC)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 105
Table A2 Combustion equation for natural gas
xcl . (CH4 + 2
LLO
xx
2
1 CO2 + 2 H2O – 2 O2 + 2 LLO
xx
2
+ 0 + 0 )
xc2 . (C2H6 + 3,5
LLO
xx
2
2 CO2 + 3 H2O – 3,5 O2 + 3,5 LLO
xx
2
+ 0 + 0 )
xc3 . (C3H8 + 5
LLO
xx
2
3 CO2 + 4 H2O – 5 O2 + 5 LLO
xx
2
+ 0 + 0 )
xc4 . (C4H10 + 6,5
LLO
xx
2
4 CO2 + 5 H2O – 6,5 O2 + 6,5 LLO
xx
2
+ 0 + 0 )
xc5 . (C5H12 + 8
LLO
xx
2
5 CO2 + 6 H2O – 8 O2 + 8 LLO
xx
2
+ 0 + 0 )
xCO2B . (CO2 + 0 0 + 0 - 0 + 0 + CO2 + 0 )
xN2B . (N2 + 0 0 + 0 - 0 + 0 + N2 + 0 )
xH2OB . (H2O+ 0 0 + 0 - 0 + 0 + 0 + H2O)
_____________+_________+
___+_____+_________+______________+_____+_____+
(xCB+xNB+xH2OB)+ A
LLO
xx
2
B + C - A + A LLO
xx
2
+ xNB + xH2OB
fuel combustion air chem. chem. comb. combustion air non (see table 1) (see formula (A1)) CO2 H2O O2 (see formula (A1) combustibles Explanation:
xcl = mole fraction CH4 in fuel xc2 = mole fraction C2H6 in fuel xc3 = mole fraction C3H8 in fuel xc4 = mole fraction C4H10 in fuel
xc5 = mole fraction C5H12 in fuel xCO2B = mole fraction CO2 in fuel xN2B = mole fraction N2 in fuel
xH2OB = mole fraction H2O-vapor in fuel xCB = xcl + xc2 + xc3 + xc4 + xc5l xNB = xCO2B + xN2B xO2L = mole fraction O2 in combustion air; xO2L = 0,21 xN2L = mole fraction N2 in combustion air; xN2L = 0,79
XL = combustion air; XL= xO2L + xN2L λ = air factor A = 2 xcl + 3,5 xc2 + 5 xc3 + 6,5 xc4 + 8 xc5
(A2)
B = xcl + 2 xc2 + 3 xc3 + 4 xc4 + 5 xc5
(A3)
C = 2 xcl + 3 xc2 + 4 xc3 + 5 xc4 + 6 xc5
(A4)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 106
HB = 29,8 kJ/3
om (enthalpy per 3
om at 20oC)
Hi = 31. 650 kJ/3
om (Net Heating Value)
Hs = 35.170 kJ/3
om (Gross Heating Value)
Combustion air:
Composition : xN2L= 0,7809 ; xO2L= 0,2095 ; xArL= 0,0093 ; xCO2L= 0,0003
Assumption : rel.humidity φ=50% and θ=20oC (w=6,2 g H2O/kg dry air).
Molar mass combustion air:
ML = 29,18 kg/kmol dry air (=molar mass wet air)
MGL = 29,00 kg/kmol dry air (=molar mass dry air)
MDL = 18 kg/kmol vapor (=molar mass vapor)
Volume combustion air for 1 m30 G-gas:
VL = 8,465.λ m3 wet combustion air
VGL = 8,381.λ m3 dry combustion air
VDL = 0,084.λ m3 vapor in combustion air
mL = 10,918.λ kg wet combustion air
mGL = 10,850.λ kg dry combustion air
mDL = 0,067.λ kg vapor in combustion air
A = 1,76 m3 O2 (=required oxygen)
wDL = 0,0062 kg vapor/kg dry combustion air
pDL = 1,003 kPa (partial vapor pressure in air)
θdL = 7oC dew point vapor in air
cpmD = 1,80 kJ/kg K (average specific heat vapor)
cpmGL = 1,01 kJ/kg K (average specific heat dry air)
hL = 36,6 kJ/kg (specific enthalpy air at 20oC)
HL = 397,1 .λ. kJ (enthalpy combustion air at 20oC)
Flue gas from G-gas
Molar mass flue gas:
MV= (30,61.λ+1,84) : (λ-0,086) kg/kmol dry flue gas (=molar mass wet flue gas)
MGV= (29,00.λ-1,53) : (λ-0,086) kg/kmol dry flue gas (=molar mass dry flue gas)
MDV= 18 kg/kmol vapor (=molar mass vapor)
Volume flue gas from 1 m30 G-gas:
VV= 8,465.λ + 1,02 m30 wet flue gas
VGV= 8,381.λ – 0,72 m30 dry flue gas
VDV= 0,084.λ + 1,74 m30 vapor in flue gas
Mass flue gas from 1 m30 G-gas:
mV= 10,91.λ + 0,83 kg wet flue gas
mGV= 10,84.λ – 0,57 kg dry flue gas
mDV= 0,07 λ + 1,40 kg vapor in flue gas
Mole fraction O2 (xO2) in dry flue gas and air factor (λ ):
xO2= (λ-1) : (4,776.λ-0,407)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 107
λ = (1-0,407.xO2) : (1-4,776.xO2)
Vapor per kg dry flue gas:
wDV= (0,07.λ+1,40) : (10,84.λ-0,57) kg H2O/kg dry flue gas
Partial pressure vapor:
pvapor= (1,01.λ+20,83) : (λ+0,12) kPa
Dew point temperature flue gas:
θdV=(234: (((17,1 : ln (pDV : 0,61))-1)) oC
If flue gases are cooled below the dewpoint, for instance θ”, then p”vapor can be
calculated with formula (3a) and subsequently w”DV with formula (13). The amount
condensed vapor is: Δ wDV = mGV. (wDV-w”DV) kg.
Enthalpy flue gas:
HV= 35.200 + 397,1.λ kJ/ m30 G-gas (=HB+HL+HS)
hV= (35.200 + 397.1.λ) : (10,84.λ-0,57) kJ/kg dry flue gas
(hV = 3450 kJ/kg when λ=1 and 660 kJ/kg when λ=5)
Heat capacity:
Cpm= see table 2.
A2.4 Calculations combustion processes Yankee
Figure A1.1 and A1.2 are examples of MED calculations on yankee dryers.
In figure A1 2 the oxygen in the combustion air to the gas-turbine is consumed in three
steps: first in the gas-turbine, then in the yankee hood and finally for co-firing in the
flue gas boiler.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 108
mG 2,1 kg/s Gasconsumption = 1668 m30/h mG 1,90 kg/s mG 1,9 kg/s mG 11,4 kg/s
mW 0,03 kg/s MJ/t PWE (based on GHV & steam from co-firing) mW 0,027 kg/s mW 3,32 kg/s mW 0,49 kg/s
θ 10oC MJ/t PWE (based on NHV & steam from co-firing) θ 10,0
oC θ 262oC θ 51
oC
θd 6,0oC θd 6,0
oC θd 91,3oC θd 37,7
oC
P 0,05 MW 100% 90% P 0,05 MW P 10,2 MW P 1,9 MW
Combustion and infiltration (supply) air Combustion air
Infiltration air= 10% P 0,01 MW ŋθ= 55% Spraywater
θ 169oC HE 0,31 MW Q= 39 m3/h 13
oC HE
Combustion and infiltration (supply) air P 0,36 MW P 1,6 MW 48oC
mG 2,1 kg/s mG 1,9 kg/s
mW 0,03 kg/s mG rec 40,3 kg/s mW 3,32 kg/s
θ 153oC Recirculation multiplier: mW 69,93 kg/s θ 300
oC
θd 6oC mG rec / mG exh = 20 θ 300
oC θd 91,3oC mG 11,4 kg/s
P 0,36 MW θd 91,3oC P 10,5 MW mW 0,49 kg/s
PWE = Product Water Evaporation P 221 MW θ 180oC
Nat.gas (co-firing 2) R1= 2955 kJ/kg Exfiltration 5% θd 37,7oC
Q 604 m30/h mG 42 kg/s PWE= 3,25 kg H2O/s mG 42,3 kg/s P 3,5 MW ŋcofiring GHV =
Q 0,17 m30/s mW 70,2 kg/s Yankee θin = 35
oC mW 73,42 kg/s 90 %
GHV 35,10 MJ/m3o mG 2,0 kg/s θ 292
oC hood θout = 300oC θ 300
oC mG exh 2,0 kg/s ŋflue-gas GHV =
P 5,9 MW mW 0,25 kg/s θd 90,9oC Q= 9599 kJ/s θd 91,3
oC mW 3,50 kg/s Steam 2842 J/g 54 %
θ 1912oC P 227 MW P 232,1 MW θ 300
oC 17 bar 220oC
θd 56,2oC θd 91,3
oC
P 6,3 MW P 11,1 MW P= 4,52 MW
Natural gas O2 3,0 % w= 1736 g/kg P= GJt
Q 1000 m30/h λ 1,15 - h= 5488 kJ/kg 1,8 kg/s 6,6 t/h
Q 0,28 m30/s
GHV 35,10 MJ/m3o Heat by steam Feedwater 376 J/g
P 9,75 MW 90oC 1,0 bar
50 % * Attention:
Combustion air 4800 kJ/s O2 % based on dry flue gas = Steamboiler
θ 15oC O2 % based on wet flue gas = mG 11,4 kg/s
r.h. 60 % mW 0,49 kg/s
θd 7,3oC mbone dry=10,0 t/h mbone dry=10 t/h θ 528
oC
P 0,36 MW dsin 45 % dsuit 95 % θd 37,7oC
Flue-gas P 8,0 MW
ŋ shaft-gasturbine 27,0 % mG 11,4 kg/s O2 15,5 % *
ŋ gear & generator 95,1 % mW 0,46 kg/s λ 3,59 -
θ 485oC
Natural gas (co-firing 1) 2,63 MW Gross heating value (GHV) 35,10 MJ/m3o θd 36,8
oC
Q 64 m30/h Net heating value (NHV) 31,68 MJ/m3
o P 7,4 MW
Q 0,02 m30/s Loss0,13 MW ŋs teamboiler cofiring based onNHV = 100 % O2 15,8 %
GHV 35,10 MJ/m3o λ 3,82 -
P 0,62 MW
Figure A1.1 Separated direct utilisation natural gas in gasturbine and in Yankee hood in future situation
mG 11,3 kg/s
Consumption = m30/h mW 3,94 kg/s
Savings = θ 100oC
recirculation θd 73,5oC
mG rec 227 kg/s P 11,7 MW
Recirculation multiplier: mW 76,8 kg/s 11,7
mG 11,3 kg/s mG rec / mG exh = 20 θ 310oC Spraywater
mW 0,59 kg/s θd 73,1oC Q= 39,2 m3/h 13
oC HE
θ 686oC P 308 MW P 1,6 MW 48
oC
θd 41,1oC
P 10,60 MW
10,6
PWE = Product Water Evaporation mG 11,3 kg/s
Natural gas (co-firing 1) R1= 2955 kJ/kg mW 3,94 kg/s
Q= 333 m30/h mG 238 kg/s PWE= 3,25 kg H2O/s mG 238 kg/s θ 180
oC
Q= 0,09 m30/s mW 77,4 kg/s Yankee θin = 35
oC mW 80,7 kg/s θd 73,5oC
GHV 35,10 MJ/m3o θ 323
oC hood θout = 310oC θ 310
oC P 13,3 MW ŋcofiring GHV =
P= 3,25 MW θd 72,5oC Q= 9599 kJ/s θd 73,1
oC 90 %
P 319 MW P 323 MW "ŋflue-gas GHV="
Natural gas Steam 2842 J/g 31 %
Q= 1000 m30/h 17 bar 220
oC
Q= 0,28 m30/s Fluegas
GHV 35,10 MJ/m3o mG 11,4 kg/s P= 4,52 MW
P= 9,75 MW mW 0,46 kg/s P= GJt
θ 480oC Heat by steam 1,8 kg/s 6,6 t/h
Combustion air θd 36,8oC
θ 15oC P 7,35 MW 50 % Feedwater 376 J/g
r.h. 60 % O2 15,8 % 4.800 kJ/s 90oC 1,0 bar
θd 7,3oC λ 3,816 -
P= 0,36 MW Steamboiler
mG exh 11,3 kg/s mG 11,3 kg/s
mbone dry=10,0 t/h mbone dry=10 t/h mW 3,84 kg/s mW 3,94 kg/s
dsin 45 % dsuit 95 % θ 310oC θ 421
oC
θd 73,1oC θd 73,5
oC
ŋ shaft-gasturbine 27,0 % P 15,4 MW P 17,9 MW
2,63 ŋ gear & generator 95,1 % O2 14,0 % O2 12,7 % *
Natural gas (co-firing 2) MW λ 2,86 - λ 2,41 -
Q= 252 m30/h Gross heating value (GHV)= 35,10 MJ/m3
o * Attention:
Q= 0,07 m30/s Net heating value (NHV)= 31,68 MJ/m3
o O2 % based on dry flue gas = 12,7 %
GHV 35,10 MJ/m3o Loss 0,1 MW ŋs teamboiler cofiring based onNHV = 100 % O2 % based on wet flue gas = 8,2 %
P= 2,46 MW
Figure A1.2 Direct utilisation exhaust heat gasturbine in Yankee hood in future situation
15,5%
14,5%
1585
131.947
5%
131.947
3450
3113
Burner
Yankee-
cylinder
Gas-turbine
Gene-rator
Bur-ner
Burner
Yankee-
cylinder
Gas-turbine
Gene-rator
Bur-ner
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 109
ANNEX B ENERGY CONVERSION
For more information about “Energy Conversion” see handout “Themadag verbetering
energie-efficiency energie conversies” published by Royal VNP on 18th august 2006.
B1 INTRODUCTION
B1.1 Configuration energy conversion
In the Dutch paper and board mills three kinds of energy conversion are distinguished:
- Gas turbine + steam boiler with or without cofiring + back pressure steam turbine
with or without condensing part
- Gas turbine + (flue gas) steam boiler with or without cofiring
- Steam boiler
The configuration of these conversions is shown in figure B1. Normally the heat
exchangers HE1, HE2 and HE3n will not be installed at the same time.
ENERGY CONVERSION
Combustion air Gas- Loss
tur-
bine Electricity
Natural gas Flue gas
Natural gas Co-firing
Flue losses Flue gas
HE1
Process water in Steam
boiler
Process water out
Process water in
Process water out Losses
Steam
HE2 tur-
Boiler feed water steam bine Electricity
Steam
Make-up water
De-
Con- HE3 aer
den- ator
sate-
tank
Bypass steam
PRODUCTION PROCESSES
Steam Cooling water
Condens to boilerhouse to de-aerator
Pro- Steam
duction
proces steam to process Steam
cooler
Condensate losses
Figure B1 Configuration energy conversion
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 110
B1.2 Thermal efficiency
Thermal efficiency (ŋth) is a dimensionless performance measure of a thermal device.
It can be defined as follows:
Thermal efficiency = the extent to which a resource is used in a thermal device for the
intended purpose.
Examples thermal devices:
- gas-turbines
- steam-turbines
- steam-boilers
- heat-exchangers
- energy conversion
Examples of resources:
- fuel (for gas-turbines, steam-boilers etc)
- steam (for steam-turbines, heat-exchangers etc)
- exhaust heat (heat recovery equipment, heat exchangers)
Examples of intended purposes:
- steam boiler: transform boiler feed water into steam
- gas-turbine-generator set: (conversion of fuel heat in electricity)
- steam-turbine-generator: (conversion of (enthalpy drop) steam in electricity)
Example of an energy conversion process in a gas fired steam power plant:
1. Chemical energy in the gas (=resource) is converted to thermal energy
2. Thermal energy converted to kinetic energy in steam
3. Kinetic energy converted to mechanical energy in the turbine
4. Mechanical energy of the turbine converted to electrical energy (=intended purpose)
Thermal efficiency can best be described as the ratio between “What you attained in the
conversion process” and “What you had to pay fot that”.
Examples:
In a steam boiler steam is generated from boiler-feed water by heat from fuel:
- “What you attained in the conversion process” = m kg boiler-feed water with
enthalpy hb.f.w. (kJ/kg) converted into steam with enthalpy hsteam (kJ/kg).
- “What you had to pay fot that”= the heat content of the fuel.
thatfor pay to had youWhat
process conversion the in attained youWhat
th ` (B1)
B1.3 Energy monitoring and targeting
Definition
Energy monitoring and targeting is primarily a management technique that uses energy
information as a basis to eliminate waste, reduce and control current level of energy
use and improve the existing operating procedures.
It builds on the principle “you can’t manage what you don’t measure”. It essentially
combines the principles of energy use and statistics.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 111
While, monitoring is essentially aimed at establishing the existing pattern of energy
consumption, targeting is the identification of energy consumption level which is
desirable as a management goal to work towards energy conservation.
Monitoring and Targeting is a management technique in which all plant and building
utilities such as fuel, steam, compressed air, water, effluent, and electricity are
managed as controllable resources in the same way that raw materials, finished product
inventory, building occupancy, personnel and capital are managed.
It involves a systematic, disciplined division of the facility into Energy Cost Centers.
The utilities used in each centre are closely monitored, and the energy used is
compared with production volume or any other suitable measure of operation.
Once this information is available on a regular basis, targets can be set, variances can
be spotted and interpreted, and remedial actions can be taken and implemented.
2 GAS TURBINES
B2.1 Principle
A gas turbine is a rotary engine that extracts energy from a flow of combustion gas. It
has an upstream compressor coupled to a downstream turbine, and a combustion
chamber in-between.
Energy is added to the gas stream in the combustor, where air is mixed with fuel and
ignited. Combustion increases the temperature, velocity and volume of the gas flow.
This is directed through a nozzle over the turbine's blades, spinning the turbine and
powering the compressor. In figure B2 is a single shaft and a double shaft machine
depicted.
In Dutch paper and board mills gas turbines are applied in Combined Heat and Power
(CHP) plants for co-generation of power and steam. In these plants the exhaust heat of
the gas turbine is recovered in flue gas steam boilers. To make the plant more flexible
the boiler is provided with cofiring.
B2.2 Types of gas turbines
Aeroderivatives and jet engines
Airbreathing jet engines are gas turbines optimized to produce thrust from the exhaust
gases, or from ducted fans connected to the gas turbines.
Aeroderivatives are also used in electrical power generation due to their ability to
startup, shut down, and handle load changes more quickly than industrial machines.
The GE LM2500 and LM6000 are two common models of this type of machine.
Single shaft turbojet engine (GE type J85)
(axial-flow from left to right: compressor, combustion chambers and turbine)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 112
Industrial gas turbines for electrical generation
Industrial gas turbines differ from aeroderivative in that the frames, bearings, and
blading is of heavier construction. They can be particularly efficient—up to 60%—when
waste heat from the gas turbine is recovered by a heat recovery steam generator to
power a conventional steam turbine in a combined cycle configuration.
They can also be run in a cogeneration configuration: the exhaust is used for steam
production in a flue gas boiler. A cogeneration configuration can be over 90% efficient.
The turbines are provided with a reduction gear box to obtain a speed of 3,000 rpm to
match the AC power grid frequency.
As a general rule, the smaller the engine the higher the rotation rate of the shaft(s)
needs to be to maintain top speed. Turbine blade top speed determines the maximum
pressure that can be gained,this produces the maximum power possible independent of
the size of the engine. Jet engines operate around 10,000 rpm and micro turbines
around 100,000 rpm.
Gas generator
Combustionchamber
Combus-
tion air
Compres
-sed air
Air com-
pressorGas
turbine
Natural
gas
Hot
gasses
Exhaust
gasses
Gener-
ator
Single shaft gasturbine and electr. generator (pmc = constant); power down >>>>> air factor up >>>>>>> efficiency down
Combustionchamber
Combus-
tion air
Compres
-sed air
Air com-
pressor
Pow
er
tur
bine
Natural
gas
Hot
gasses
Exhaust
gasses
Double shaft gasturbine for pumps & electr. generator (pmc = variable);HP-rotor + nozzles + LP-rotor (= power turbine)
Figure B2 Single and double shaft gas turbine
To match the AC power grid frequency gasturbines always have a fixed speed of 3,000
rpm after the gear box. For efficiency reasons the load should normally always be 100
%. At lower loads the compressed amount of air will stay the same resulting in an
increase of the air factor. Higher air factors will decrease the efficiency of the
gasturbine.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 113
B2.3 Gas turbine cycle
Gas turbines are described thermodynamically by the Brayton cycle, in which air is
compressed isentropically, combustion occurs at constant pressure, and expansion over
the turbine occurs isentropically back to the starting pressure. The process is shown in
a p-V-diagram in figure B3.
In practice, friction and turbulence cause:
- non-isentropic compression: for a given overall pressure ratio, the compressor
delivery temperature is higher than ideal.
- non-isentropic expansion: although the turbine temperature drop necessary to
drive the compressor is unaffected, the associated pressure ratio is greater, which
decreases the expansion available to provide useful work.
- pressure losses in the air intake, combustor and exhaust: reduces the expansion
available to provide useful work.
B2.4 Gas turbine efficiency
When transforming thermal energy into mechanical energy, the thermal efficiency of a
heat engine is the percentage of heat energy that is transformed into work:
ŋth = Wout / Win = 1 – (Qout / Qin) (B3)
The second law of thermodynamics puts a fundamental limit on the thermal efficiency of
heat engines (gas- and steam- tubines): even an ideal frictionless engine cannot
convert 100% of its input heat into work. The limiting factors are the temperature at
which the heat enters the engine (Tin in K; for gasturbines called TIT) and the
temperature of the environment into which the engine exhausts its waste heat To in K):
ŋth.carnot = (Tin - To) / Tin (B4)
Where:
ŋth.carnot = the highest achievable thermal efficiency
Tin = turbine inlet temperature (called: TIT) in K
To = the ambient temperature where the turbine is located in K
This limiting value is called the Carnot cycle efficiency because it is the efficiency of an
unattainable ideal reversible engine cycle called the Carnot cycle.
When, for instance, TIT is 1450 oC and the ambient temperature is 20 oC the carnot-
efficiency is 83 %. In practice this will be only about 46%, 37 %-points short of the
Carnot value.
Since To is fixed by the environment, the only way to increase the efficiency of an
engine is to increase Tin, the operating temperature of the engine. For this reason the
operating temperatures of engines have increased greatly over the long term.
As with all cyclic heat engines, higher combustion temperature means greater
efficiency. The limiting factor is the ability of the materials that make up the engine to
withstand heat and pressure. Considerable engineering goes into keeping the turbine
parts cool.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 114
Q1
1 – 2 isentrop
p 2 3 2 – 3 isobar
3 – 4 isentrop
4 – 1 isobar
tip loss
Otto & Diesel process
1 4
Q2
V p-V-diagram Brayton process
ηth = thisfor fuel from dtransformeheat
gasturbine in energy mechanical in dtransformeheat
ηth =1
2
1
21
Q
Q1
Q
=1-
)T(T.cm
)T(T.cm
23p
14p
= 1 -
1T
T.T
1
41 :
1T
T.T
2
32
1
2k
1-k
1
2
T
T
p
p
(a)
4
3k
1-k
4
3
T
T
p
p
(b)
(a) and (b) gives:4
3
1
2
p
p
p
p (= ) so : T2 :T1 = T3 : T4 of: T4 : T1 = T3 : T2
(T4 – T1) : (T3 – T2) = T1: T2 = T4 : T3
ηth = 1 - 2
1
T
T of ηth = 1 –
3
4
T
T of ηth = 1 -
k
1-k
1
Figure B3 Thermal efficiency Brayton process
An important property of a gasturbine is the pressure ratio (α); the relation between α
and Tin for the carnot efficiency is shown in figure B3.
η= 1 -
k
1-k
1
α= 15 η= 53,9% α= 24 η= 59,7% (B5)
In practice the efficiencies will be only about 2/3 of these values.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 115
B3 STEAM TURBINES
B3.1 Principle
A steam turbine is a mechanical device that extracts thermal energy from pressurized
steam, and converts it into rotary motion.
The steam turbine is a form of heat engine that derives much of its improvement in
thermodynamic efficiency through the use of multiple stages in the expansion of the
steam, which results in a closer approach to the ideal reversible process.
B3.2 Types of steam turbines
Depending on the steam supply and exhaust conditions the following types are
distinguished:
- Backpressure or noncondensing turbines
These turbines are most widely used for process steam applications in paper and
board plants. The exhaust pressure is controlled by a regulating valve to suit the
needs of the process.
- Condensing turbines
In paper and board mills these turbines are applied in combination with
backpressure turbines. The combination makes it possible to respond on fluctuations
on the steam demand. When for instance there is a paper web broke the load of the
condensing turbine will be increased by the dropped demand of the paper machine.
The vapor content of the exhaust steam of these turbines is typically 95% at a
pressure of about 0,05 bar in the condenser.
- Reheat turbines
These are used almost exclusively in electrical power plants. In a reheat turbine,
steam flow exits from a high pressure section of the turbine and is returned to the
boiler where additional superheat is added. The steam then goes back into an
intermediate pressure section of the turbine and continues its expansion.
- Extracting type turbines
These are common in paper and board mills. In an extracting type turbine, steam is
released from various stages of the turbine, and used for process needs.
The interior of a turbine comprises several sets of blades, or “buckets” as they are more
commonly referred to. One set of stationary blades is connected to the casing and one
set of rotating blades is connected to the shaft. The sets intermesh with certain
minimum clearances, with the size and configuration of sets varying to efficiently exploit
the expansion of steam at each stage.
To maximize turbine efficiency the steam is expanded in a number of stages. These
stages are characterized by how the energy is extracted from them. Depending on the
way how the energy is extracted from the stages the following types are distinguished:
- Impulse turbines
- Reaction turbines
The difference between both turbines is shown in figure B4.
Most steam turbines use a mixture of the reaction and impulse designs: each stage
behaves as either one or the other, but the overall turbine uses both. Typically, higher
pressure sections are impulse type and lower pressure stages are reaction type.
The turbines used for electric power generation are most often directly coupled to their
generators. As the generators must rotate at constant synchronous speeds according to
the frequency of the electric power system, the most common speeds are 3000 rpm for
50 Hz systems.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 116
Figure B4 Difference between an impulse and a reaction turbine (Wikipedia)
B3.3 Steam turbine cycle
Steam turbines are described thermodynamically by the Rankine cycle.
The process is shown in the flowchart in figure B7 and in a p-V-diagram in figure B5:
- Water is pumped to high pressure (5-1)
- High pressure water is heated in a boiler at constant pressure and becomes
saturated steam (1-2)
- The saturated steam is heated in a superheater at constant pressure and becomes
superheated steam (2-3)
- Super heated steam expands in the steam turbine generating power; the
temperature and pressure of the steam decrease and at the end some condensation
may occur. The process shown in figure B5 is for an ideal steam turbine. An ideal
steam turbine is considered to be an isentropic process in which the entropy of the
steam entering the turbine is equal to the entropy of the steam leaving the turbine.
No steam turbine is truly “isentropic”; the entropy will increase during the process.
Typical isentropic efficiencies are ranging from 20%-90% based on the application
of the turbine.
- The wet steam (about 5% moisture) is condensed in the condenser at a constant
pressure and becomes water (4-5). The pressure and temperature of the condenser
is fixed by the temperature of the cooling coils as the fluid is undergoing a phase-
change.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 117
Q1
p1 1. 1'. 2. 3.
p2
5. 4.
Q2
V1 V2
water wet steam superheated steam
saturated water saturated steamProcess:
1-2-3 isobararic3-4 isentropic
4-5 isobaric5-1 isochoric
pre
ssure
volume
The thermo dynamic efficiency is defined as:
ηth = 1
21
Q
Where:
Q1 = heat supplied in boiler (including super heater)
= h3 – h1
Q2 = heat removed in condensor
= h4 – h5
W = work delivered by isentropic expansion
= Q1 – Q2
Also:
ηth = )H(h
)h(h)h(h
13
5413
The difference between h5 and h1, the work required by the pump, is only about 1%
and can be neglected:
ηth = 13
43
hh
hh
(B6)
or in words:
ηth = steam by suppliedheat
expansion isentropic during drop enthalpy (B7)
Figure B5 Thermodynamic efficiency Rankine process
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 118
B3.4 Steam turbine efficiency
As already described for gasturbines in chapter B2.4 there is a a fundamental limit on
the thermal efficiency for heat engines.
The limiting factors for steam turbines are the temperature of the steam that enters the
turbine and the temperature of the steam after the turbine. The latter depends on the
cooling in the condenser.
As with all cyclic heat engines higher supply steam temperature means greater
efficiency. The limiting factor is the ability of the materials that make up the engine to
withstand heat and pressure.
Higher supply steam temperatures result in higher enthalpies (h3) of this steam.
For efficiency reasons steam boilers for steam-turbines need to be provided with
superheaters.
To gain a clear insight in the possibilities of improving the efficiency of a steamturbine
a, so called, Mollier h,s diagram (h=enthalpy and s=entropy) can be applied. An
example of this diagram, also called Mollier chart for steam, is shown in figure B6. For
calculations charts on A2-size are commercially available.
Figure B6 Mollier chart for steam
In figure B7 the Rankine process is shown in the h-s-diagram.
Efficiencies can be easily defined by this diagram:
Isentropic Efficiency
The isentropic efficiency for an expansion process is defined as:
ŋisentropic = (B6)
real enthalpy drop after real expansion . enthalpy drop after isentropic expansion
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 119
ŋisentropic = (B7)
The difference between numerator and denominator are the internal losses in the
turbine.
Rankine efficiency
The Rankine efficiency is defined as:
ŋRankine = (B8)
ŋRankine = (B9)
The difference between numerator and denominator is the Rankine loss in the turbine.
Thermal efficiency
The thermal efficiency is defined as:
ŋThermal = (B10)
ŋThermal = (B11)
The difference between numerator and denominator is the condenser loss, this is the
sum of the Rankine loss and the internal losses in the turbine.
h3
h4"
h4
h1
s1 s2
isotherm (superheated steam)enthalpy superheated steam
enthalpy condensate
enth
alp
y
enthalpy steam after turbine
entropy
internal losses
condenser lossRankine loss
enthalpy steam after ideal turbine
Figure B7 Efficiencies steamturbine in h-s-digram
h3 - h4” . h3 - h4
enthalpy drop after isentropic expansion enthalpy drop after condenser
h3 - h4 . h3 - h1
enthalpy drop after real expansion enthalpy drop after condenser
h3 - h4” .
h3 - h1
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 120
Exercise B1: Steam turbine processes in h-s- diagram
Given:
Steam supplyvoer steam turbine 80 bar 590 oC.
The process steam is extracted at 15 bar, the temperature shows to be 408oC.
(in order to make this steam usable for the process, the steam should be cooled first to
around 220oC)
Questions:
(a) What is the isentropic efficiencyrate of return (ηisent)?
What part of the enthalpy of the steam supply is used for electricity generation
(Δhhelectr), and what is then the enthalpy after the process (hproces)?
Calculate the electricity production (E) when the efficiency of the gear box and
the generator (ηgear) is together 96%.
(b) As (a) when the steam is extracted at 3,5 bar and 270oC.
(c) As (a) when all steam is discharged in the condenser, this steam has a pressure
of 0,05 bar and contains 5% moisture.
(d) What is in the efficiency of the electricity generation in case (c) (ηE) when the
steam in the condenser is cooled to 50oC, the boiler efficiency is 97%.
Answer h3 = 3615 J/g
3265 J/g
3010 J/g
h4"
2435 J/g
h4
h1 210 J/g
s1 s2
590 oC
enthalpy condensate
enth
alp
y
enthalpy steam after turbine
entropy
condenser lossRankine loss
408 oC
270 oC
50 oC
Answer
ηisent
(%)
Δhhelectr
(kJ/kg)
hproces
(kJ/kg)
ηE
(%)
E
(Wh/kg)
(a)
(b)
(c)
66
70
80
350
605
1180
3265
3010
n.v.t.
96
96
96
93,4
161,3
314,7
(d) (1180 x 0,96) : ((3615 – 50 x 4,2) : 0,97) = 32,3 %
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 121
B4 STEAM BOILERS
B4.1 Steamboiler plant
In figure B8 the main components of a steam-boiler and the auxiliary equipment in the
boiler-house are depicted in a block diagram.
A steam-boiler always consists of an evaporator and combustion equipment.
Additionally the boiler may be provided with an economizer, a super-heater and an air
pre-heater. The boiler feed-water is treated and de-aerated.
BOILER HOUSE STEAM
BOILER
Boiler feed water
Make-up water
Con- De-
HE3 aer
den- ator
sate-
tank
Pro-
duction Steam Cooling water
Condens to boilerhouse proces to de-aerator
Steam
steam to process
cooler
Condensate lossesBurner
Super heater
Evaporator
Economizer
Air pre-heater
Fuel
CombustionairFlue
Figure B8 Boilerhouse equipment
The main components are:
De-aerator
De-aerator is a device that is used for the removal of air and other dissolved gases from
the boiler feed water. In particular, dissolved oxygen in boiler feed water will cause
serious corrosion damage in steam systems by attaching to the walls of metal piping
and other metallic equipment and forming oxides (rust). It also combines with any
dissolved carbon dioxide to form carbonic acid that causes further corrosion.
Air pre-heater
An air pre-heater a device designed to heat for example combustion air. The purpose of
the air pre-heater is to recover the heat from the boiler flue gas which increases the
thermal efficiency of the boiler by reducing the useful heat lost in the flue gas.
Economizers
Economizers are devices, fitted in a boiler chimney, which use the waste heat in the flue
gases from the boiler to preheat the cold boiler feed water.
Superheater
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 122
A superheater is a device used to convert saturated steam into dry steam used for
power generation or processes. There are three types of superheaters namely: radiant,
convection, and separately fired.
A radiant superheater is placed directly in the combustion chamber.
A convection superheater is located in the path of the hot gases.
A separately fired superheater is totally separated from the boiler.
Heat exchanger HE3 (see figure B8)
In the de-aerator the boiler feed-water is heated to minimal 105 oC. As the temperature
difference between the flue after the economizer and this feed-water is in practice
about 15 oC the temperature of the flue will be at least 120 oC. When the water in the
condensate tank is at least 10 oC colder than 105 oC heat can be transferred by HE3
from after the de-aerator to before the de-aerator. This will result in lower steam
consumption of the de-aerator and lower feed water temperature to the economizer and
thus in lower flue temperatures.
B4.2 Types of steamboilers
Depending on the fluid that through the pipes two types of boilers are distinguished:
fire-tube boilers and water-tube boilers.
Fire-tube boilers
In this type of boiler, the gases of combustion pass through tubes that are surrounded
by water. Figure B9 illustrates a cutaway view of a fire-tube boiler.
Figure B9 Fire-tube boiler (source: dieselduck.com)
The heat energy from the gases passes through the sides of the tubes by thermal
conduction, heating the water and ultimately creating steam.
Water-tube boilers
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 123
In this type of boiler, the water circulates through tubes that are heated externally by
fire. Water-tube boilers operate on the principle of forced or natural water circulation.
Figure B10 illustrates a cross section view of a water-tube boiler with natural
circulation of the water. These boilers consist basically of a steam drum and a water
drum connected by a bank of generating tubes. The two drums are also connected by a
row of water tubes, which forms a water-cooled sidewall opposite the tube bank.
Figure B10 Water-tube boiler with natural circulation (Source: tpub.com)
Figure B11 shows the principle of forced circulation.
Water tube boilers are used for high-pressure boilers in power stations.
The small water content in these boilers result in rapid response to load change
The flexible design possibilities make easy control of the temperature of the
superheated steam possible.
B4.3 Exhaust heat steam boiler
Flue gas steam boilers (also called: waste heat or exhaust heat boilers) are an
important component in combined heat power (CHP) plants.
In flue gas boilers heat from the hot exhaust gas stream from the gas-turbine is
recovered. The steam can be used in production processes or used to drive a steam
turbine.
Flue gas boilers consist of three major components: the evaporator, superheater
and economizer. Super heaters are necessary when the flue gas boiler delivers steam to
a steam-turbine.
Flue gas boilers can be categorized by number of ways such as direction of exhaust
gases flow or number of pressure levels.
Based on the flow of exhaust gases, they are categorized into vertical and horizontal
types. In horizontal types exhaust gas flows horizontally over vertical tubes whereas in
vertical types exhaust gas flow vertically over horizontal tubes.
Based on pressure levels, they can be categorized into single pressure and multi
pressure. Single pressure boilers have only one steam drum and steam is generated at
single pressure level whereas multi pressure boilers employ two or more steam drums.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 124
Because of the relatively low temperature of the gas turbine exhaust, compared to the
burner flame in a conventional boiler, a much greater boiler heat transfer area is
required for a given heat load.
Figure B11 Water-tube boiler with forced circulation (Source:Spirax)
B4.4 Efficiency Steam boiler
Total steam-boiler efficiency
The total steam boiler efficiency (ŋsteamboiler) indicates the overall efficiency of the boiler
inclusive flue gas losses, radiation and convection losses and boiler blow down losses.
The total steam boiler efficiency (ŋsteamboiler) is also known as “fuel to fluid efficiency”.
The total steam boiler efficiency (ŋsteamboiler) is defined as follows.
Attained in the conversion process: generating steam from boiler feedwater
Paid for this: fuel
LHV.V
)hh(.m
naturalgas
waterboilerfeedsteamsteam
rsteamboile
Where:
msteam = mass steam produced from boiler feed water in kg/s (or ton/h)
hsteam = enthalpy steam in kJ/kg (or MJ/ton)
hboilerfeedwater = enthalpy boiler feed water in kJ/kg (or MJ/ton)
Vnatural gas= natural gas consumption in m30/s (or m3
o/h)
LHV = lower heating value natural gas in MJ/m30 (G-gas = 31,65 MJ/m3
0)
Losses steam boiler conversion process (= numerator – denominator):
- Flue loss
Heat from gas-turbine
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 125
This is the difference (hflue) between the enthalpies of the flue gas and the
combustion air. A measure for the ratio flue loss (∆hflue) and the fuelconsumption
(hfuel) is the combustion efficiency (ŋcomb):
ŋcomb = (hfuel - hflue) / hfuel
- Convection and radiation losses
The external surface of an operating steam boiler is hotter than its surroundings
and therefore loses heat by both radiation and convection.
The radiation and convection loss is proportional to the external surface area.
- Boiler blow down
Steam boilers should be blown down daily to maintain recommended dissolved
solids levels and to remove sludge and sediment.
Co-firing efficiency
Temperature limits at the gas turbine inlet force the turbine to use excess air, above
the optimal stoichiometric ratio to burn the fuel.
The flue gases of the gas-turbine contain between about 12 and 15 % oxygen. Co-firing
makes use of this oxygen and no extra combustion air is required. This means that the
mass exhaust gas will not increase. If the exhaust gas temperature also does not
increase then the flue losses will stay the same. Normally the exhaust gas temperature
does not increase. Even more often this temperature will decrease; this is caused by
the increased feed water flow that will cool the exhaust gas further.
In practice co-firing efficiencies are between 97 and 105 %.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 126
B5 COMBINED HEAT AND POWER PLANTS (CHP)
B5.1 Combined heat and power (CHP) plant
Figure B12 shows a CHP plant in paper and board mills which is composed of a gas-
turbine and a flue gas boiler.
COMBINED HEAT POWER
Combustion air Gas- Loss
tur-
bine Electricity
Natural gas Flue gas
Natural gas Co-firing
Flue losses Flue gas
HE1
Process water in Steam
boiler
Process water out
Boiler feed water steam
Make-up water
De-
Con- HE3 aer
den- ator
sate-
tank
PRODUCTION PROCESSES
Steam Cooling water
Condens to boilerhouse to de-aerator
Pro- Steam
duction
proces steam to process Steam
cooler
Condensate losses
Figure B12 Combined Heat Power plant
The hot exhaust gases from a gas turbine (approximately 500- 550 °C) are led through
a flue gas boiler, where saturated steam is generated and used in the production
processes.
The turndown ratio of these plants is poor, because of the need for the turbine to rotate
at a speed synchronized to the electrical frequency. This means that, without special
provisions like “Inlet Guide Vanes”, these plants run at full-load, providing the base load
of steam to the production processes.
When the load of the turbine is turned down the fuel supply will also be turned down
however the speed stays constant. This means that the amount of combustion air also
stays constant which results in high air factors and bad efficiencies.
In these plants the ratio of the steam and electricity production is fixed. Electricity that
can not be used on the site is exported to the national grid. For a flexible steam supply
often co-firing is installed on the waste heat boiler; the advantage of cofiring is that
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 127
efficiencies between about 95 and 105 % are obtained.
B5.2 Combined cycle plant (CCP)
A combined cycle employs more than one thermodynamic cycle. Gas turbines are only
able to use a portion of the energy their fuel generates.
Combining two or more "cycles" such as the Brayton cycle and Rankine cycle results in
improved overall efficiency.
In a combined cycle power plant a gas turbine generator generates electricity and the
waste heat is used to make steam to generate additional electricity via a steam turbine.
As a rule, in order to achieve high efficiency, the temperature difference between the
input and output heat levels should be as high as possible (see Carnot efficiency).
By combining both gas and steam cycles, high input temperatures and low output
temperatures can be achieved. The efficiency of the cycles add, because they are
powered by the same fuel source. So, a combined cycle plant has a thermodynamic
STEAMBOILER
Combus.chamber
Combus-
tion air
Compres
-sed air
Air com-
pressorGas
turbine
Natural
gas
Hot
gasses
Exhaust
gasses
Gener-
ator
Burnerco-firing
Super heater
Evaporator
Economizer
Flue gasses
Conden
-sing
turbine
Conden
sate
Back pr.
turbine
Natural
gas
Condensor
Boiler feed watertreatment
plant
HP
steamLP
steam
PRODUCTION PROCESSES
1.
4.3.
3.
2.
1".
5".
4". 5.
5.
4".
Figure B13 Combined Cycle plant with steam extraction from BP-turbine
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 128
cycle that operates between the gas-turbine's high firing temperature and the waste
heat temperature from the condensers of the steam cycle. This large range means that
the Carnot efficiency of the cycle is high. The actual efficiency, while lower than this is
still higher than that of either plant on its own.
The CCP can, like other CHP plants, be designed with co-firing (also called:
supplementary firing) of fuel after the gas turbine in order to increase the quantity or
temperature of the steam generated. Co-firing lets the plant respond to fluctuations of
electrical load.
The relatively low temperatures of the flue gas from the gas-turbine may require
additional heating to bring the steam up to the specification required for the steam
turbines.
A CCP plant in paper and board mills is composed of a gas-turbine, a flue gas boiler and
a back pressure steam-turbine and sometimes, additional, a condensing steam-turbine.
The process steam is extracted from the back pressure steam-turbine. The principle is
shown in figure B13.
The superheated steam is directed to steam turbines which drive the generator or, after
being cooled to about 15 oC above the saturation temperature, to the production
process.
The combined-cycle system includes single-shaft and multi-shaft configurations.
The single-shaft system depicted in figure B13 consists of one gas turbine, one steam
turbine, one generator and one flue gas boiler with co-firing. The key advantage of this
single-shaft arrangement is its operating simplicity with higher reliability than multi-
shaft blocks. Further operational flexibility is provided with a steam turbine which can
be disconnected for start up or for simple cycle operation of the gas turbine.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 129
ANNEX C: CENTRIFUGAL FANS AND PUMPS
For more information about “Centrifugal fans and pumps” see handout “Themadag
verbetering energie-efficiency pompen, compressoren en vacuumsystemen” published
by Royal VNP on 1st august 2006.
CENTRIFUGAL FANS AND COMPRESSORS
C1 Types of centrifugal fans and compressors
Compressors and fans are similar to pumps, both increase the pressure on a fluid and
both can transport the fluid through a pipe. As gases are compressible, the compressor
also reduces the volume of a gas. Liquids are incompressible, so the main action of a pump is to pressurize and transport liquids.
One of the most common types of compressors is the centrifugal compressor.
Centrifugal compressors use a rotating disk or impeller in a shaped housing to force the
gas to the rim of the impeller, increasing the velocity of the gas. A diffuser (divergent
duct) section converts the velocity energy to pressure energy. Compressors with
multiple staging can achieve high output pressures.
A centrifugal fan is depicted in figure C1.
Figure C1: Components of a centrifugal fan (from Wikipedia)
The fan drive determines the speed of the fan wheel. When the fan drive is provided
with an electronic variable-speed control better overall energy efficiency at reduced
speeds may be obtained. This is important when the weights (g/m2) in the product
range produced on a machine differ.
See also Box C2 “Pump- and system characteristic and control pump capacity”.
Fan dampers, to control gas flow into and out of the centrifugal fan, may be installed on
the inlet side or on the outlet side of the fan, or both. Inlet dampers reduce fan energy
usage.
C2 Power consumption centrifugal fans and compressors
In thermo dynamics two compression processes are distinguished: isothermal
compression and isentropic compression.
Although neither of them model the real world exactly, each can be useful for analysis.
Isothermal compression
This model assumes that the compressed gas remains at a constant temperature
throughout the compression process. In this cycle internal energy is removed from the
system as heat at the same rate that it is added by the mechanical work of
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 130
compression. Compressors that utilize inter-stage cooling between compression stages
come closest to achieving isothermal compression.
Isentropic compression
This model assumes that no energy (heat) is transferred to or from the gas during the
compression, and all supplied work is added to the internal energy of the gas, resulting
in increases of temperature and pressure. Theoretical temperature rise is:
Toutlet = Tinlet x (poutlet/pinlet)(k-1)/k (C1)
Where:
Toutlet = outlet temperature in K
Tintlet = inlet temperature in K
poutlet = outlet pressure in kPa
pinlet = inlet pressure in kPa
k = cp/cv, (= ratio of specific heats, approximately 1,4 for air and 1,3 for water vapor)
Isentropic (also called adiabatic) compression is more closely real life.
In practice there will always be a certain amount of heat flow out of the compressed
gas.
Power consumption centrifugal fans and compressors
Isothermal compression takes less work than isentropic (adiabatic) compression:
Pisentropic=)ηx(η
}1)p
p{(x
1k
kx (kPa)px /s)V(m
compressormotor
k
1k
inlet
outlet
inlet
3
kW (C2)
Pisothermic= Wk)ηx(η
p
p lnx (kPa) px /s)(mV
compressormotor
inlet
outlet
inlet
3
(C3)
Where:
pinlet = inlet pressure in kPa
poutlet = outlet pressure in kPa
ηmotor = efficiency electric motor in decimal
ηcompr. = efficiency compressor or fan in decimal
V = flow rate in m3/s (at inlet pressure)
Pisentropic = required power for isentropic compression in kW
Pisothermic = required power for isothermic compression in kW
k = cp/cv, (= ratio of specific heats, appr. 1,4 for air and 1,3 for water vapor)
The efficiency of multi-stage compressors can be increased by cooling the compressed
gas between stages; this makes the compression less isentropic (adiabatic) and more
isothermal.
C3 Relation between pressure and required power
When optimizing the energy efficiency of drying processes very often the dew point of
the exhaust air in the optimal situation will be higher than in the reference situation.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 131
When this happens the amount of air will decrease and the absolute vapour content of
this air (g vapour / kg dry air) will increase. This may result in substantial electricity
savings for supply and exhaust air fans of the dryer.
Usually the electricity consumption in the reference situation is known. Hereafter will be
explained how the electricity consumption in the optimal situation can be calculated.
The power consumption of the centrifugal fan in case of isentropic compression:
Pisentropic=)ηx(η
}1)p
p{(x
1k
kx (kPa)px /s)V(m
compressormotor
k
1k
inlet
outlet
inlet
3
kW (C2)
Conversion of pressure (p in kPa= kN/m2) in head (m); see box C1:
p = ρ (kg/m3) x g (m/s2) x H (m) kPa (C4)
Where:
p = pressure in kPa; (1 bar = 105 N/m2 = 105 Pa; 1 N = 1 kg.m/s2)
ρ = fluid density in kg/m3; (ρwater = 1000 kg/m3; ρair = about 1,3 kg/m3)
g = acceleration due to gravity; (g = 9,81 m/s2)
H = head in m
The density of water is 1000 kg/m3, for air this is 1,29 kg/m3 at standard conditions (0 oC en 101,325 kPa).
At higher than standard elevation (sea level) and higher than standard temperature, air
density is lower than standard density. At higher temperatures the centrifugal fan will
create less pressure and will require less power. As the density of air is, compared to
water, very low the elevation head for air will also be low.
Note that a centrifugal fan is a constant volume device that will move the same volume
of air at two different temperatures.
The density ρ of the wet exhaust air depends on the vapour content:
ρwet.air = mwet .air / V (C5)
mwet .air = mdry.air + mvapour (C6)
Where :
mwet.air = mass wet air in kg/s
mdry.air = mass dry air in kg/s
mvapour = mass vapour in air in kg/s
V = flow rate in m3/s
The mass of the dry air and the mass of the vapour can be derived from:
mdry.air = (28,84/8,314) x (pdry.air x V /T) (13c)
mvapour = (18/8,314) x (pvapour x V /T) (13d)
Substitute formula (13c) and (13d) in formula (C6) :
ρ = {(28,84/8,314) x (pdry.air x V /T) + (18/8,314) x (pvapour x V /T)} / V
ρwet.air= (28,84 x pdry air+ 18,00 x pvapor)/(8,314 x (273,15 + θdry bulb)) (C7)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 132
C4 Electrticity consumption supply, exhaust and circulation fans
In table C1 the formula’s for centrifugal fans are applied on supply air, exhaust air and
circulation fans for multi cylinder and yankee dryers for as well the reference as the
optimal situation.
The known data of the reference situation are applied to try to predict the electric
consumption in the optimal situation.
Total head
In box C1 is derived that for pumps the required power: P(kW)= Q (m3/s) x pman (kPa).
In this formula the required power for liquid pumps depends on the difference between the inlet and outlet pressure pman is:
pman = poutlet – pinlet (C17)
pman = ρ.g.Hgeo + (pa – pe) + ½ρ. )v(v 2
e
2
a + Cpipe .(½. ρ. vpipe2) (C18)
pman =elevation head + pressure head + velocity head + resistance head
The required power for gas compressors and fans for air depends on the pressure ratio:
“pman” = pinlet x (k/(k-1)) x (((poutlet/pinlet)^((k-1)/k))-1) (C9)
When the suction and discharge pipes of the fans are at the same level (Hgeo=0) and
the air velocities are also the same (va = ve) then the elevation head (ρ.g.Hgeo) and the
velocity head (½ρ. )v(v 2
e
2
a ) can be neglected. In these cases the power consumption
depends on the pressure head and the resistance head.
In yankee hoods pressure head is a result of the pressure drop in the plenum where air
velocities of more than 100 m/s are created. Also blow boxes in multi-cylinder dryers
may need pressure head.
Resistance head
In table C1 is assumed that there are only “other” and resistance losses due to friction.
The pressure loss in pipes and tubes due to friction depends on the flow velocity, pipe
or duct length, pipe or duct diameter, and a friction factor based on the roughness of
the pipe or duct, and whether the flow is turbulent or laminar – the Reynolds Number of
the flow-. The pressure loss in a tube or duct due to friction can be expressed as:
ploss.resistance = λ * (l / dh) * (½ * ρ * v2 ) (C10)
Where:
ploss.friction = pressure loss due to friction in ducts (Pa)
λ = friction coefficient
l = length of duct (m)
dh = hydraulic diameter (m)
vpipe = flow velocity in the duct (m/s)
For an existing ventilation system λ, l, and dh are, within certain limits, constant (Cpipe):
Cpipe = λ* (l / dh) (C11)
Substituting formula (C11) in (C10):
ploss.resistance = Cduct * (½ * ρ * vduct2 ) (C12)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 133
Table C1 Electricity consumption supply, exhaust and recirculation fans dryers (rough estimation)
a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah
Requir
ed
power
Dryin
g a
ir (
*3)
Dew
poin
t (*1)
Tem
peratu
re (
*1)
Absolu
te h
um
idity (
*2)
Enth
alp
y (
*2)
Rel.hum
idity(*2)
Partial vapour p
ressure
(*2)
Abs.
hum
. supply
air
(*2)
Product
wate
r e
vap.
(*3)
Inle
t pressure
(*1) (
*14)
Partial pressure
dry a
ir (
*4)
Density h
um
id a
ir (
*5)
Volu
me f
low
(*6)
Tem
peratu
re (
*7)
Partial vapour p
ressure
(*8)
Outlet
pressure (
*1)
(*15)
Partial pressure d
ry a
ir
(*9)
Dryin
g a
ir (
*10)
Density h
um
id a
ir (
*5)
Volu
me f
low
(*6)
Tota
l pressure losses
(*18)
Ele
vation,
pressure &
velo
city loss
Ele
vation,
pressure &
velo
city loss (
*19:r)
Resis
tance loss (
fric
tion
in d
ucts
etc
) (
*20)
Cross s
ectional area
duct
(*1)
Air
velo
city in d
ucts
etc
(*21)
Eff
icie
ncy e
lectr
ic m
oto
r
(*1;16)
Eff
icie
ncy c
om
pressor
(*1;17)
Requir
ed p
ow
er (
*11)
- - - mdry.air θdew θ wvap.out h φ pvapor wvap.in PWE pinlet pdry.air ρwet.air V θ pvapor poutlet pdry.air mdry.air ρwet.air V ∆ptot ∆pother ∆pother ∆pl.res. A v ŋmotor ŋcompres Pisentr
- - - kg/s °C °C g/kg kJ/kg % kPa g/kg kg/s kPa kPa kg/m3 m3/s °C kPa kPa kPa kg/s kg/m3 m3/s kPa % kPa kPa m2 m/s - - kW
Reference situation1 exhaust 52,9 57,0 80 128,7 422 36,4 17,3 - 6,5 101,3 84,0 0,93 56,8 83,6 18,0 105,0 87,0 52,9 0,96 55,4 3,7 60,0 2,2 1,5 3,86 14,4 0,95 0,85 255
2 supply 52,9 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 43,2 12,6 1,0 103,6 102,6 52,9 1,25 42,3 3,3 60,0 2,0 1,3 3,86 10,9 0,95 0,85 175
3 exhaust 52,9 57,0 80 128,7 422 36,4 17,3 - 6,5 101,3 84,0 0,93 56,8 83,6 18,0 105,0 87,0 52,9 0,96 55,4 3,7 60,0 2,2 1,5 3,86 14,4 0,95 0,85 255
4 supply 52,9 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 43,2 12,6 1,0 103,6 102,6 52,9 1,25 42,3 3,3 60,0 2,0 1,3 3,86 10,9 0,95 0,85 175
5 exhaust 52,9 57,0 80 128,7 422 36,4 17,3 - 6,5 101,3 84,0 0,93 56,8 83,6 18,0 105,0 87,0 52,9 0,96 55,4 3,7 60,0 2,2 1,5 3,86 14,4 0,95 0,85 255
6 supply 52,9 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 43,2 12,6 1,0 103,6 102,6 52,9 1,25 42,3 3,3 60,0 2,0 1,3 3,86 10,9 0,95 0,85 175
7 recirculation20,0 57,0 80 128,7 422 36,4 17,3 128,7 0,0 100,3 83,0 0,92 21,7 84,5 18,1 104,8 86,7 20,0 0,95 21,0 4,5 60,0 2,7 1,8 0,20 105,2 0,95 0,85 119
Optimal situation1 exhaust 30,7 66,0 90 217,6 671 37,1 26,2 - 6,5 101,3 75,1 0,87 35,1 92,8 26,9 104,1 77,2 30,7 0,89 34,5 2,7 80,6 2,2 0,5 3,86 8,9 0,95 0,85 118
2 supply 30,7 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 25,1 11,9 1,0 102,7 101,7 30,7 1,25 24,6 2,4 81,6 2,0 0,4 3,86 6,4 0,95 0,85 75
3 exhaust 30,7 66,0 90 217,6 671 37,1 26,2 - 6,5 101,3 75,1 0,87 35,1 92,8 26,9 104,1 77,2 30,7 0,89 34,5 2,7 80,6 2,2 0,5 3,86 8,9 0,95 0,85 118
4 supply 30,7 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 25,1 11,9 1,0 102,7 101,7 30,7 1,25 24,6 2,4 81,6 2,0 0,4 3,86 6,4 0,95 0,85 75
5 exhaust 30,7 66,0 90 217,6 671 37,1 26,2 - 6,5 101,3 75,1 0,87 35,1 92,8 26,9 104,1 77,2 30,7 0,89 34,5 2,7 80,6 2,2 0,5 3,86 8,9 0,95 0,85 118
6 supply 30,7 7,0 10 6,2 26 81,6 1,0 6,2 0,0 100,3 99,3 1,22 25,1 11,9 1,0 102,7 101,7 30,7 1,25 24,6 2,4 81,6 2,0 0,4 3,86 6,4 0,95 0,85 75
7 recirculation18,8 66,0 90 217,6 671 37,1 26,2 - - 100,3 74,1 0,86 21,7 94,5 27,3 104,7 77,4 18,8 0,89 21,1 4,4 61,5 2,7 1,7 0,20 105,3 0,95 0,85 116
Explanation ((*…r) = reference situation; (*…o) = optimal situation; (*…r+o) = both)): (*18:r+o) ∆ptot = poutlet - pinlet
(*1:r+o) White cells: data measured or calculated elsewhere (MED) (*11:r+o) Pisentr. = V x pinlet x (k/(k-1)) x (((poutlet/pinlet)^((k-1)/k))-1) / (ŋmotorXŋcompressor) ∆ptot = ∆pelevation + ∆ppressure + ∆pvelocity+ ∆presistance
(*2:r+o) Calculated with formula's from "Formula library" (*5:r+o) ρwet.air= (28,84 x pdry air+ 18,00 x pvapor)/(8,314 x (273,15 + θdry bulb)) ∆pother = ∆pelevation + ∆ppressure + ∆pvelocity
(*3:r) PWE = mdry.air x 0,001 x (wvap.out - wvap.in) (*6:r+o) V = mdry.air / ρwet.air (*19:r) ∆pother = % x ∆ptot (= rough estimation)
(*3:o) mdry.air = PWE / ((0,001 x (wvap.out - wvap.in)) (*7:r+o) Toutlet = Tinlet x (poutlet/pinlet) ^ ((k-1)/k) (*19:o) ∆pother(o) = ∆pother(r)
(*3:o) cell l3ref= cel l3opt (PWEoptmal.sit = PWEreference.sit.) (*8:r+o) pvapour = poutlet - pdry.air (*20:r) ∆pl.res = ∆ptot -∆pother
(*3:o) cell l5ref= cel l5opt (PWEoptmal.sit = PWEreference.sit.) (*15:o) poulet = pinlet + ∆ploss.friction + ∆pother (*20:o) ∆p(o)l.res = ((ρ(r).v(r)2)/(ρ(o).v(o)2)) x ∆p(r)l.res
(*3:o) cell p7ref= cel p7opt (Voptmal.sit = Vreference.sit.);(vimpingement) (*9:r+o) pdry.air.outlet = (poutlet/oinlet) * pdry.air.inlet (*21:r+o) v = V/A
(*14:o) pinlet.optmal.sit = pinlet.reference.sit. (*10:r+o) mdry.air.outlet = mdry.air.inlet (*16:o) ŋmotor.optimal.sit. = ŋmotor.reference.sit.
(*4:r+o) pdry.air = pinlet - pvapor; (*20:r) C duct can be derived from ploss.friction = C duct * ρwet.air * v2 (*17:o) ŋcompressor.optimal.sit. = ŋcompressor.reference.sit.
multi
cyl.
yan-
kee
cyl.
other
multi
cyl.
yan-
kee
cyl.
Fan n
um
ber
Multi cylinder o
r y
ankee d
ryer
Exhaust,
supply
or c
ircula
tion
air
Inlet fan (suction) Outlet fan (discharge)
other
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 134
Exercise 1C One stage compression
Given:
Q = 1 m3 air, pinlet = 0,85 bar , poutlet = 8,5 bar, ηmotor x η compressor = 0,60
Question:
Calculate Pisentropic and Pisothermic in Wh.
Calculate the savings when isothermic in stead of isentropic compression is applied.
Answer:
Apply formula’s (C2) and (C3); 0,85 bar = 85 kPa, 8,5 bar = 850 kPa):
Pop(isentr.)= Wk461 0,60
11,4
11,4
)85
850(x
11,4
1,4x kPa85x /s
31m
Pop(isoth.) = kW k 326 0,60
85
850 lnx kPa85x /s1m
3
Savings: (461-326)/461= 29%
Exercise 2C Two stage compression with and without intermediate cooling
Given
Two stage compression with and without intermediate cooling:
Q = 1 m3 air, pinlet.stage1 = 0,85 bar =(85 kPa) , poutlet = 8,5 bar (= 850 kPa),
poutlet.stage2 = 8,5 bar (=850 kPa), θinlet.stage1= 10oC; ηmotor x η compressor = 0,60.
Stage 1 is rootsblower, compression ratio= 2, intermediate cooler: θinlet.stage2 = 10oC,
Stage 2 is screw compressor, compression ratio = 5.
Question:
Calculate Pisentropic in kW for roots-blower, screw-compressor and total with and without
intermediate cooling.
Calculate savings in relation to one stage compression.
What can you tell about the capacity of the compressor ?
Answer:
Two stage compression without intermediate cooling:
P Isentropic.stage1 = Wk108 0,60
1)85
170(x
11,4
1,4xkPa85x /sm 1 1,4
11,4
3
Apply Poisson I for calculatig Vafter.stage1 :
pinlet x Vkinlet = poutlet x Vk
outlet
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 135
Vafter.stage1 : 0,85 x 1 = 1,7 x Vkafter.stage1; Vafter.stage1 = 0,61 m3
P(isentopic.stage 2= kW 353 0,60
1170
850x
1-1,4
1,4x kPa 170x /s0,61m
1,4
11,4
3
Pisentr.tot = (108 + 353=) 461 kW; also the same as in one stage compression (see
exercise 1C.
Two stage compression with intermediate cooling:
Pisentropc.stage1 = 108 kW
For calculation Θafter.stage1 apply Poisson II:
;170
85
θ
10273 ;
p
p
T
T
1,4
11,4
e1after.stag
k
1k
outlet
inlet
outlet
inlet
Θafter.stage1 = 72oC
Vafter.stage1 = 0,61 m3
For calculation Vbefore.stage2: 10293
V
72273
0,61;
T
V
T
V ge2before.sta
2
2
1
1
Vbefore.stage2 = 0,50 m3
Pisentropicstage2 = Wk289 0,60
1170
850x
1-1,4
1,4x kPa 170x m 0,50
1,4
11,4
3
Pisentropic.tot = (108 + 289=) 397 kW
Savings in relation to one stage compression: ((461-397)/461=)14% (maximum
feasible 29%)
When normally two screw compressors are running, one can be replaced by a
rootsblower.
PUMPS
C5 Types of pumps
Pumps fall into two major groups: positive displacement pumps and rotodynamic
pumps. Their names describe the method for moving a fluid.
Positive displacement pumps
Positive displacement pumps are "constant flow machines". Positive displacement
pumps will produce the same flow at a given speed. A positive displacement pump must
not be operated against a closed valve on the discharge side of the pump because it
might burst the discharge line.
Roto- dynamic pumps
The most common roto-dynamic pump is the centrifugal pump.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 136
In roto-dynamic pumps kinetic energy is added to the fluid by increasing the flow
velocity. This increase in kinetic energy is converted to a gain in potential energy
(pressure) when the velocity is reduced prior to or as the flow exits the pump into the
discharge pipe. These pumps can operate under closed valve conditions.
This pump uses a rotating impeller to increase the pressure and flow-rate of a fluid.
A centrifugal pump containing two or more impellers is called a multistage centrifugal
pump. The advantages to using a multistage centrifugal pump or a single stage pump
include production of a higher pressure head, and to discharge a larger quantity of liquid.
C6 Head pressure
Total head
Head is a concept that relates the energy in a fluid to the height of an equivalent static
column of that fluid. Head is expressed in m of height.
The static head of a pump is the maximum height (pressure) it can deliver. The
capability of the pump can be read from its Q-H curve (flow vs. height).
Head is equal to the fluid's energy per unit weight.
Head is useful in specifying centrifugal pumps because their pumping characteristics
tend to be independent of the fluid's density.
There are four types of head used to calculate the total head in and out of a pump:
elevation, pressure, velocity and resistance head. The equation is shown in formula (15)
in box 1.
With formula (16) height can be converted in kPa (=kN/m2) and, as the difference
between pressure gauges on the discharge and suction side of the pump is equal to the
total head, formula (18) can be derived from formula’s (15) and (17).
Resistance head
The resistance loss in pipes and tubes due to friction depends on the flow velocity, pipe
or duct length, pipe or duct diameter, and a friction factor based on the roughness of
the pipe or duct, and whether the flow us turbulent or laminar – the Reynolds Number
of the flow. The resistance loss is divided in major loss due to friction and minor loss
due to change of velocity in bends, valves and similar. The latter are also expressed in
equivalent friction losses.
The resistance loss in a tube or duct due to friction can be expressed as:
ploss.resistance = λ* (l / dh) * (½ * ρ * vpipe2 ) (C12)
Where:
ploss.resistance = pressure loss (kPa)
λ = friction coefficient
l = length of duct or pipe (m)
dh = hydraulic diameter (m)
vpipe = flow velocity in pipe or duct (m/s)
For an existing pump system λ, l, and dh are constant (Cpipe):
Cpipe = λ* (l / dh) (C13)
Substituting formula (C13) in (C14):
ploss.resistance = Cpipe * (½ * ρ * vpipe2 ) (C14)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 137
Box 1C. Head and required power pumps
Explanation symbols and units
p = pressure in N/m2 (=Pa)
(1 bar = 105N/m2; 1 kN = 1 kg.m/s2)
ρ = fluid density in kg/m3
(ρwater = 1000 kg/m3)
g = acceleration due to gravity
(g = 9,81 m/s2)
Pinput = required input power in kW
H = energy head added to the flow in m
Q = flow rate in m3/s or m3/h
ŋpump = total efficiency pump (as decimal)
ŋmotor = efficiency electric motor (as decimal)
Total head (Htot in m):
Htot = (h1 – h2) + resistance
2
2
2
121 H2g
vv
gρ
p p
(C15)
Elevation head pressure head velocity head resistance head
Static head (independent of flow) Dynamic head (depending on flow)
Resistance head is friction loss in pipes, ducts, bends etc.
Conversion of pressure (p in N/m2) in head (m):
p (N/m2) = ρ (kg/m3) x g (m/s2) x h (m) (C16)
(Note: N = kg.m/s2)
Difference between outlet and inlet pressure pump (= pman):
pman = poutlet – pinlet (C17)
Total head (pman = ρ.g.Htot = poutlet – pinlet in kN/m2)
pman = ρ.g.Hgeo + (p1 – p2) + ½ . ρ . )v(v2
2
2
1 + Cpipe .(½. ρ. vpipe2) (C18)
Required power electric motor when Q in m3 water/s and p in kPa
Pinput =)ηx(η
}kPa)p(px /s{(Q)m
pompmotor
inletoutlet
3 kW C19)
h1
h2
v2
v1
p1
p2
poutlet
outle
pintlet
outle
Hg
eo =
h
1 -
h2
pressure gauges are on the same height level
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 138
C7 Power consumption pumps
The power required to drive a pump is defined by formula (C19) in box C1.
Units check: kg/m3 x m/s2 x m x m3/s = (kg.m/ s2) x m / s = kNm/s =kJ/s = kW
Pump efficiency (ηpump) is defined as the ratio of the power imparted on the fluid by the pump
in relation to the power supplied to drive the pump.
Efficiency is a function of the discharge and therefore also operating head; this means its
value is not fixed for a given pump. One important part of system design involves matching
the pipeline headloss-flow characteristic with the appropriate pump which will operate at or
close to the point of maximum efficiency.
Pump efficiencies tend to decline over time due to wear.
The energy usage is determined by multiplying the power requirement by the length of time the
pump is operating.
C8 Pump- and system characteristics
In box 1 is shown that the total pump head is the sum of the static head and the dynamic
head. The static head is independent of the liquid flow while the dynamic head depends on it.
The relation between the heads and the liquid flow is shown in the pump characteristic (H/Q) and
system characteristic (HA/Q) in figure 2.
Figure 2 Pump (H/Q) and system (HA/Q) characteristics
The crossing of the characteristics is the working point. In the example in figure 2 at this
point Q = 160 m3/h, H = 50 m, P = 28 kW and η = 73%.
Pump capacity can be controlled by throttling valve in the discharge op the pump or by
variable speed drive.
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 139
In box 2 the differences are shown. Throttling causes pressure drop across the valve and
will result in considerable losses.
Box 2 Pump- and system characteristic and control pump capacity
a) throttling b) variable speed control
Control pump capacity:
a) throttling
- system characteristic changes
- throttling loss = Δ h
b) variable speed control
- pump characteristic changes
- no loss
- relation between Q, H and P when n (speed in rpm) changes:
Qx = (nx/n) * Q (C19)
Hx = (nx/n)2 * Q (C20)
Px = (nx/n)3 * Q (C21)
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 140
Excercise C3 Head and required power head box pumps
Given:
Head box pumppumps suspension from cleaners to wire section
Velocity from head box to wire = 20 m/s (=velocity wire).
Recirculation from head box = 10%
Pressure on liquid surface on suction side pump = 1,2 bar
Pressure on liquid surface on discharge side pump = 1 bar (=barmetric prssure).
Elevation head liquid levels = 2 m.
Friction losses in pipes = 15 m.
Mass flow = 3.701.064 ton bone dry per year
Consistence = 0,93 %.
Question:
Calculate with formula (16) total, elevation, pressure, velocity and resistance head.
Convert m in bar
Calculate the yearly consumption in MWh and in euro’s (ŋmotor= 80%, ŋpump=95%and
1MWh costs € 65)
Answer:
H=2m+ (1,0–1,2)x105N/m2:(1000kg/m3x9,8m/s2) +(202-02)m2/s2:(2x9,8m/s2)+15 m
H = + 2 m - 2,04 m + 20,41 m + 15 m = 35,37 m
Pman = 1000 kg/m3 x 9,8 m/s2 x 35,37 m = 346.626 N/m2 (= 3,47 bar)
Pop(man)={(1,1x3.701.064):0,0093}m3x3,47barx(1:36.000)MWh/bar:(0,80X0,95)=55.50
2 MWh
K = 55.502 MWh x 65 €/MWh = € 3.608.802
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 141
ANNEX D: TABLES AND UNITS
D1 STEAM TABLE: PROPERTIES OF STEAM AT VARYING PRESSURES AND TEMPERATURES
Absolute pressure (kPa, kN/m2)
Temperature (oC)
Specific Volume (m3/kg)
Density - ρ - (kg/m3)
Specific Enthalpy of Specific Entropy of Steam - s - (kJ/kgK)
Liquid - hl - (kJ/kg)
Evaporation - he - (kJ/kg)
Steam - hs - (kJ/kg)
0.8 3.8 160 0.00626 15.8 2493 2509 9.058
2.0 17.5 67.0 0.0149 73.5 2460 2534 8.725
5.0 32.9 28.2 0.0354 137.8 2424 2562 8.396
10.0 45.8 14.7 0.0682 191.8 2393 2585 8.151
20.0 60.1 7.65 0.131 251.5 2358 2610 7.909
28 67.5 5.58 0.179 282.7 2340 2623 7.793
35 72.7 4.53 0.221 304.3 2327 2632 7.717
45 78.7 3.58 0.279 329.6 2312 2642 7.631
55 83.7 2.96 0.338 350.6 2299 2650 7.562
65 88.0 2.53 0.395 368.6 2288 2657 7.506
75 91.8 2.22 0.450 384.5 2279 2663 7.457
85 95.2 1.97 0.507 398.6 2270 2668 7.415
95 98.2 1.78 0.563 411.5 2262 2673 7.377
100 99.6 1.69 0.590 417.5 2258 2675 7.360
101.3 100 1.67 0.598 419.1 2257 2676 7.355
110 102.3 1.55 0.646 428.8 2251 2680 7.328
130 107.1 1.33 0.755 449.2 2238 2687 7.271
150 111.4 1.16 0.863 467.1 2226 2698 7.223
170 115.2 1.03 0.970 483.2 2216 2699 7.181
190 118.6 0.929 1.08 497.8 2206 2704 7.144
220 123.3 0.810 1.23 517.6 2193 2711 7.095
260 128.7 0.693 1.44 540.9 2177 2718 7.039
280 131.2 0.646 1.55 551.4 2170 2722 7.014
320 135.8 0.570 1.75 570.9 2157 2728 6.969
360 139.9 0.510 1.96 588.5 2144 2733 6.930
400 143.1 0.462 2.16 604.7 2133 2738 6.894
440 147.1 0.423 2.36 619.6 2122 2742 6.862
480 150.3 0.389 2.57 633.5 2112 2746 6.833
500 151.8 0.375 2.67 640.1 2107 2748 6.819
550 155.5 0.342 2.92 655.8 2096 2752 6.787
600 158.8 0.315 3.175 670.4 2085 2756 6.758
650 162.0 0.292 3.425 684.1 2075 2759 6.730
700 165.0 0.273 3.66 697.1 2065 2762 6.705
750 167.8 0.255 3.915 709.3 2056 2765 6.682
800 170.4 0.240 4.16 720.9 2047 2768 6.660
850 172.9 0.229 4.41 732.0 2038 2770 6.639
900 175.4 0.215 4.65 742.6 2030 2772 6.619
950 177.7 0.204 4.90 752.8 2021 2774 6.601
1000 179.9 0.194 5.15 762.6 2014 2776 6.583
1050 182.0 0.186 5.39 772 2006 2778 6.566
1150 186.0 0.170 5.89 790 1991 2781 6.534
1250 189.8 0.157 6.38 807 1977 2784 6.505
1300 191.6 0.151 6.62 815 1971 2785 6.491
1500 198.3 0.132 7.59 845 1945 2790 6.441
1600 201.4 0.124 8.03 859 1933 2792 6.418
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 142
D2 UNITS Unit
(SI) unit
Explanation
Name
Symbol
Name
Symbol *
temperature mass force pressure work power amount substance molar volume molaire massa density Gross Heating Value Net Heating Value Normal volume
θ
m F p p A P n
Vm
M ρ
Hs
Hi
Vo
kelvin gram newton (N) pascal (bar) joule watt mol - - -
GHV NHV -
K
g
kg.m/s2
Pa (bar)
J
W
mol
m3/kmol
kg/kmol
kg/m3
MJ/ 3om
MJ/ 3om
m3
o
273 K = 0oC Mass (m) of a body is the constant ratio between the force (F) and acceleration (a) caused by the force on the body: m (kg) = F (N) : a (m/s2); F = m x a (kg . m/s2) The force of gravity (G) that gives an body with a mass (m) of 1 kg an acceleration (g) of 1 m/s2 is 1 Newton A body with a mass of m kg has a weight of: G = m x g N ; g = 9,8 m/s2 (gravity) 1 Pa = 1 N/m2 1 bar = 105 Pa Convert pressure in m height: p (N/m2) = h (m) x ρ (kg/m3) x g (m/s2) 1 J = 1 N . m 1 W = 1 J/s For gas at 273 K and 101,325 kPa: Vm = 22,4 m3/kmol N = 14, O = 16, C = 12, H = 1, S = 32; bijv.: CO2: (1 x 12 + 2 x 16 =) 44 kg/kmol. ρ = M : Vm
G-gas Hs = 35,17 MJ/ 3om
G-gas Hi = 31,65 MJ/ 3om
V(…) = V (0oC; 101,325kPa)
Pre-fix: P = 1015, T = 1012. G = 109, M = 106, k = 103, - = 100, m = 10-3, μ = 10-6, n = 10-9
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 143
D3 EMPIRICAL RELATIONS BETWEEN θ, θdew, pvapor AND wvapor
Dew
poin
t
Absolu
te
hum
idity
Part
ial vapor
pre
ssure
Rela
tive
hum
idity
Tem
pera
ture
Wet
bulb
tem
pera
ture
Enth
alp
y
Dew
poin
t
Absolu
te
hum
idity
Part
ial vapor
pre
ssure
Rela
tive
hum
idity
Tem
pera
ture
Wet
bulb
tem
pera
ture
Enth
alp
y
θdew wvapor pvapor φ θ θwet.bulb h θdew wvapor pvapor φ θ θwet.bulb h
°C g/kg kPa % °C °C J/g °C g/kg kPa % °C °C J/g
1,0 4,1 0,7 100 1,0 1,0 11 51,0 92,6 13,0 100 51,0 51,0 2922,0 4,4 0,7 100 2,0 2,0 13 52,0 98,0 13,6 100 52,0 52,0 3073,0 4,8 0,8 100 3,0 3,0 15 53,0 103,7 14,3 100 53,0 53,0 3234,0 5,1 0,8 100 4,0 4,0 17 54,0 109,8 15,0 100 54,0 54,0 3405,0 5,5 0,9 100 5,0 5,0 19 55,0 116,1 15,7 100 55,0 55,0 3586,0 5,9 0,9 100 6,0 6,0 21 56,0 123,0 16,5 100 56,0 56,0 3777,0 6,3 1,0 100 7,0 7,0 23 57,0 130,2 17,3 100 57,0 57,0 3978,0 6,7 1,1 100 8,0 8,0 25 58,0 137,9 18,2 100 58,0 58,0 4189,0 7,2 1,1 100 9,0 9,0 27 59,0 146,0 19,0 100 59,0 59,0 441
10,0 7,7 1,2 100 10,0 10,0 30 60,0 154,7 19,9 100 60,0 60,0 46511,0 8,3 1,3 100 11,0 11,0 32 61,0 163,9 20,9 100 61,0 61,0 49012,0 8,8 1,4 100 12,0 12,0 34 62,0 173,8 21,8 100 62,0 62,0 51713,0 9,5 1,5 100 13,0 13,0 37 63,0 184,3 22,9 100 63,0 63,0 54614,0 10,1 1,6 100 14,0 14,0 40 64,0 195,4 23,9 100 64,0 64,0 57615,0 10,8 1,7 100 15,0 15,0 42 65,0 207,3 25,0 100 65,0 65,0 60916,0 11,5 1,8 100 16,0 16,0 45 66,0 220,2 26,2 100 66,0 66,0 64417,0 12,3 1,9 100 17,0 17,0 48 67,0 234,0 27,3 100 67,0 67,0 68218,0 13,1 2,1 100 18,0 18,0 51 68,0 248,7 28,6 100 68,0 68,0 72219,0 14,0 2,2 100 19,0 19,0 55 69,0 264,4 29,8 100 69,0 69,0 76520,0 14,9 2,3 100 20,0 20,0 58 70,0 281,5 31,2 100 70,0 70,0 81121,0 15,9 2,5 100 21,0 21,0 62 71,0 299,8 32,5 100 71,0 71,0 86122,0 16,9 2,6 100 22,0 22,0 65 72,0 319,7 34,0 100 72,0 72,0 91523,0 18,0 2,8 100 23,0 23,0 69 73,0 341,3 35,4 100 73,0 73,0 97324,0 19,1 3,0 100 24,0 24,0 73 74,0 364,7 37,0 100 74,0 74,0 1.03725,0 20,3 3,2 100 25,0 25,0 77 75,0 390,2 38,6 100 75,0 75,0 1.10626,0 21,6 3,4 100 26,0 26,0 81 76,0 417,9 40,2 100 76,0 76,0 1.18127,0 23,0 3,6 100 27,0 27,0 86 77,0 448,2 41,9 100 77,0 77,0 1.26228,0 24,4 3,8 100 28,0 28,0 91 78,0 480,5 43,7 100 78,0 78,0 1.35029,0 26,0 4,0 100 29,0 29,0 96 79,0 518,6 45,5 100 79,0 79,0 1.45230,0 27,6 4,2 100 30,0 30,0 101 80,0 559,3 47,4 100 80,0 80,0 1.56231,0 29,3 4,5 100 31,0 31,0 106 81,0 604,7 49,3 100 81,0 81,0 1.68532,0 31,1 4,8 100 32,0 32,0 112 82,0 655,7 51,4 100 82,0 82,0 1.82233,0 32,9 5,0 100 33,0 33,0 118 83,0 713,2 53,4 100 83,0 83,0 1.97734,0 35,0 5,3 100 34,0 34,0 124 84,0 777,8 55,6 100 84,0 84,0 2.15135,0 37,1 5,6 100 35,0 35,0 130 85,0 852,4 57,8 100 85,0 85,0 2.35236,0 39,3 5,9 100 36,0 36,0 137 86,0 937,7 60,1 100 86,0 86,0 2.58137,0 41,7 6,3 100 37,0 37,0 144 87,0 1.036,4 62,5 100 87,0 87,0 2.84638,0 44,1 6,6 100 38,0 38,0 152 88,0 1.152,4 65,0 100 88,0 88,0 3.15839,0 46,8 7,0 100 39,0 39,0 160 89,0 1.290,7 67,5 100 89,0 89,0 3.53040,0 49,5 7,4 100 40,0 40,0 168 90,0 1.458,7 70,1 100 90,0 90,0 3.98241,0 52,5 7,8 100 41,0 41,0 177 91,0 1.665,9 72,8 100 91,0 91,0 4.53842,0 55,6 8,2 100 42,0 42,0 186 92,0 1.927,2 75,6 100 92,0 92,0 5.24043,0 58,8 8,6 100 43,0 43,0 195 93,0 2.268,3 78,5 100 93,0 93,0 6.15744,0 62,3 9,5 100 44,0 44,0 205 94,0 2.731,7 81,5 100 94,0 94,0 7.40145,0 65,9 9,6 100 45,0 45,0 216 95,0 3.396,1 84,6 100 95,0 95,0 9.18546,0 69,8 10,1 100 46,0 46,0 227 96,0 4.426,7 87,7 100 96,0 96,0 11.95347,0 73,9 10,6 100 47,0 47,0 239 97,0 6.248,4 91,0 100 97,0 97,0 16.84448,0 78,1 11,2 100 48,0 48,0 251 98,0 10.303,1 94,3 100 98,0 98,0 27.73149,0 82,7 11,7 100 49,0 49,0 264 99,0 27.145,9 97,8 100 99,0 99,0 72.95350,0 87,5 12,3 100 50,0 50,0 277 100,0 - 101,4 100 100,0 100,0 -
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 144
D4 AVERAGE SPECIFIC HEAT
'Cp.av. in kJ/(kg.oC) of components in air or flue gas
temp
range °CCO2 Ar O2 N2 H2O Dry air
0 0,819 0,519 0,917 1,041 1,83 1,006
0 - 100 0,870 0,519 0,923 1,041 1,84 1,009
0 - 200 0,915 0,519 0,935 1,045 1,87 1,012
0 - 300 0,953 0,519 0,950 1,048 1,89 1,019
0 - 400 0,989 0,519 0,964 1,055 1,92 1,028
0 - 500 1,021 0,519 0,978 1,065 1,95 1,038
0 - 600 1,046 0,519 0,993 1,075 1,98 1,048
0 - 700 1,072 0,519 1,005 1,087 2,01 1,061
0 - 800 1,092 0,519 1,017 1,098 2,04 1,071
0 - 900 1,112 0,519 1,029 1,109 2,07 1,080
0 - 1000 1,129 0,519 1,037 1,118 2,11 1,090
0 - 1100 1,144 0,519 1,045 1,129 2,14 1,100
0 - 1200 1,158 0,519 1,052 1,139 2,17 1,109
0 - 1300 1,170 0,519 1,060 1,145 2,20 1,118
0 - 1400 1,181 0,519 1,066 1,152 2,23 1,125
0 - 1500 1,192 0,519 1,072 1,160 2,26 1,132
0 - 1600 1,203 0,519 1,078 1,168 2,29 1,139
0 - 1800 1,219 0,519 1,090 1,182 2,34 1,153
0 - 2000 1,234 0,519 1,101 1,192 2,39 1,162
ENERGIETRANSITIE P1/MED I/DRYING/FdG/V3/06-11-2009/PAGE 145
D5 MOLLIER CHARTS FOR HUMID AIR