MATERIALS SCIENCEMATERIALS SCIENCE C4:...

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Natural Sciences Tripos Part II MATERIALS SCIENCE MATERIALS SCIENCE C4: Tensors Dr E. G. Bithell Michaelmas Term 2013 14 Name............................. College.......................... Michaelmas Term 2013-14 II

Transcript of MATERIALS SCIENCEMATERIALS SCIENCE C4:...

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Natural Sciences Tripos Part II

MATERIALS SCIENCEMATERIALS SCIENCE

C4: Tensors

Dr E. G. Bithell

Michaelmas Term 2013 14

Name............................. College..........................

Michaelmas Term 2013-14

II

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Contents

Reference list ....................................................................................................................... 3

Formulae .............................................................................................................................. 4

1 Introduction .................................................................................................................. 5

1.1 Reasons for using tensors ....................................................................................... 5

1.2 Material properties represented by tensors ............................................................. 7

1.3 Anisotropy and symmetry ........................................................................................ 8

2 Stress and Strain .......................................................................................................... 9

2.1 Failure modes of materials and structures ............................................................... 9

2.2 Choice of volume element and coordinate system .................................................10

2.3 Alternative notations ...............................................................................................12

2.4 Examples of stress tensors ....................................................................................13

2.5 Einstein summation convention ..............................................................................14

2.6 Transformation of axes ...........................................................................................17

2.7 Transformation of components ...............................................................................18

2.8 Transformation laws for tensors .............................................................................19

2.9 Resolution of stresses ............................................................................................20

2.10 Principal axes .........................................................................................................25

2.11 Definition of strain at a point ...................................................................................31

2.12 Physical meaning of eij ...........................................................................................32

2.13 Separating shape changes from volume changes ..................................................35

3 Experimental Study of Stresses and Strains .............................................................37

3.1 Strain gauges .........................................................................................................37

3.2 Photoelasticity ........................................................................................................41

3.3 Brittle coating methods ...........................................................................................44

3.4 X-ray diffraction ......................................................................................................46

3.5 Ultrasonics .............................................................................................................46

3.6 Optical interferometry .............................................................................................47

3.7 Residual Stresses ..................................................................................................47

3.8 Example of stress and strain analysis: elasticity in thin films ..................................48

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4 Other tensor properties ..............................................................................................51

4.1 The representation surface for second rank tensors ...............................................51

4.2 Optical properties ...................................................................................................52

4.3 Piezoelectricity .......................................................................................................53

4.4 Effects of crystal symmetry .....................................................................................54

4.5 Ferroelectricity ........................................................................................................54

4.6 Applications of piezoelectricity ................................................................................56

4.7 Pyroelectricity .........................................................................................................57

4.8 Electrostriction ........................................................................................................57

5 Elasticity ......................................................................................................................58

5.1 Elasticity in isotropic media ....................................................................................58

5.2 Elasticity in general anisotropic media ....................................................................62

5.3 Crystal Symmetry ...................................................................................................66

5.4 Elastic stress distributions ......................................................................................70

5.5 Elastic waves .........................................................................................................72

5.6 Saint-Venant’s principle ..........................................................................................75

5.7 Examples of stress distributions .............................................................................76

5.8 Dislocations ............................................................................................................80

Lecture Examples ...............................................................................................................84

Preparatory Questions .......................................................................................................87

Question Sheet 1 ................................................................................................................88

Question Sheet 2 ................................................................................................................89

Question Sheet 3 ................................................................................................................90

Past Tripos Questions .......................................................................................................91

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Reference list

Principal textbooks

Nye: Physical Properties of Crystals, chapters 1, 2, 5, 6 & 8 (Lj13b)

We use Nye's notation throughout.

Lovett: Tensor Properties of Crystals, all chapters (NbA 73b)

Less comprehensive than Nye, but the content corresponds closely to that of the course.

Kelly and Knowles: Crystallography and Crystal Defects, chapters 5, 6 & A6

(NbA99,a,b)

Tensors, stress and strain, piezoelectricity, elasticity

Newnham, Properties of Materials, chapters 1, 5, 8 – 13, 18, 25, 27 (AB200)

Tensors, stress and strain, physical properties

Supplementary textbooks

Cottrell: Mechanical Properties of Matter, chapters 4, 5 & 6 (Lj18a)

Elasticity, stress distributions, elastic waves

Dieter: Mechanical Metallurgy, chapters 1 & 2 (Kz1a,c,e)

Analysis of mechanical failures, stress and strain, elasticity

Gere & Goodno: Mechanics of Materials, chapters 1, 7, 8 & 9 (Ka110a,b)

Stress and strain distributions, engineering design

Holister: Experimental Stress Analysis, chapters 1, 2 & 4 (Ky2)

Strain gauges, photoelasticity

Knott: Fundamentals of Fracture Mechanics, chapters 1 & 2 (Ke45a)

Modes of failure, stress concentrations

Le May: Principles of Physical Metallurgy, chapters 1, 2 & 4 (Kz31b)

Stress and strain, criteria for failure, dislocations

Lovell, Avery and Vernon: Physical Properties of Materials, ch. 8 & 10 (AB59)

Pyroelectricity, piezoelectricity, ferroelectricity, electro-optics, non-linear optics

Wilson and Hawkes: Optoelectronics: An Introduction, chapter 3 (LcD7)

Electro-optic effect, non-linear optics

Wyatt and Dew-Hughes: Metals, Ceramics and Polymers, ch. 5 & 6 (Ab14b)

Tensile testing, yield point phenomena, elasticity

Web resources

DoITPoMS TLPs: Introduction to Anisotropy; Tensors; Dislocations

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Formulae

This is a list of formulae and equations appearing in the Tensors course which are sufficiently

fundamental to the subject area that you may be expected to derive them, or to reproduce

them from memory in order to carry out further derivations or calculations.

Einstein summation convention (example using two indices):

( )

Total, normal and shear stresses on a plane:

| | (

)

( )

Hydrostatic stress:

Dilatation:

Elasticity relationships (tensor notation):

Superposition of normal stresses in an isotropic medium:

( )

Important note

This course goes beyond the mathematics which can reasonably be done as a ‘pencil and

paper’ exercise, and you will also learn (in outline) the background to computational

approaches to tensor calculations. You should therefore be prepared to answer essay-type

questions on this course, as well as calculations, and be able to illustrate your answers with

appropriate mathematics in the same way as you would with diagrams. In these cases, key

equations will not normally be provided.

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1 Introduction

1.1 Reasons for using tensors

We are concerned with the quantitative description and analysis of the properties of

materials.

There are two reasons why we need tensors:

1.1.1 Anisotropy (matter tensors)

A materials property such as density is just a number – direction has no meaning. But

properties such as electrical conductivity:

can depend upon direction

are anisotropic

need tensors for a proper description

These are “matter tensors”:

the properties have a particular orientation with respect to the material

they must conform to the material's symmetry (Neumann’s Principle)

Anisotropy is most readily associated with single crystals but this is not necessarily the only

possibility.

1.1.2 External influences and stimuli (field tensors)

Even if a material is isotropic, its properties relate specific quantities i.e. cause → effect, for

example:

electric field → current (via conductivity)

stress → strain (via stiffness or compliance)

Field tensors:

can have any orientation with respect to the material

can exist in isotropic materials

need not conform to the symmetry of the material

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We have two particular areas of interest:

1.1.3 Crystal physics

This is concerned with the behaviour of solid state devices, for example:

optical properties (birefringence is a strong indicator for anisotropy)

optoelectronic devices

magneto-optic devices

elasto-optic devices

1.1.4 Elasticity

This is concerned with the analysis of stress and strain:

at the atomic level – relevant to dislocations and cracks

at the microscopic level – e.g. thin films and micro devices

at the macroscopic level – components and structures

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1.2 Material properties represented by tensors

Many materials properties can be described by matter tensors – properties which relate two

other quantities (see also the Tensors TLP).

Property Relating the quantities

Density Mass Volume

Heat capacity Temperature Energy

Pyroelectricty Polarisation Temperature change

Electrocaloric effect Entropy change Electric field

Electrical conductivity Current density Electric field

Thermal conductivity Heat flow Temperature gradient

Permittivity Dielectric displacement Electric field

Permeability Magnetic induction Magnetic field

Thermal expansion Strain Temperature change

Direct piezoelectric effect Polarisation Stress

Electro-optic effect Change in dielectric

permeability Electric field

Elastic compliance Strain Stress

Piezo-optical effect Change in dielectric

impermeability Stress

Electrostriction Strain 2 electric field components

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1.3 Anisotropy and symmetry

These material properties are matter tensors and must obey Neumann’s Principle:

The symmetry elements of a material property must include

the symmetry elements of the point group of the material

Our treatment will rely upon Neumann’s Principle. First we need to understand how to

classify the symmetry found in different types of macroscopic materials:

An isotropic material

o Has infinite symmetry (rotation axes/mirrors in all directions)

o Is found not only in a macroscopic continuum but in a real amorphous solid

composed of atoms

Lower symmetry

o Is clearly seen in single crystals

o Is described by the 32 point groups, none of which have infinite symmetry

Polycrystals

o Are macroscopically isotropic if crystal shape and orientation are random

o Otherwise have preferred orientation or texture → anisotropy

Amorphous solids

o These may be isotropic but we can induce anisotropy

e.g. by annealing under a tensile stress

The property may have greater symmetry than the material (depending upon the type of

property), so for example second rank tensors (optical properties, electrical conductivity) are

isotropic for cubic crystals but cubic crystals are not isotropic in general and this is apparent

in higher order tensor properties such as elasticity.

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2 Stress and Strain

2.1 Failure modes of materials and structures

There are three modes of mechanical failure:

elastic

plastic

brittle

Analysis of each of these requires a treatment of stress and strain.

2.1.1 Elastic deformation

This is recoverable - remove the load and the body returns to its original state. In our course

we will deal only with linear time-independent elasticity.

In fact the stress-strain relationship need not be linear (anelasticity), and the strain response

need not be immediate (viscoelasticity).

The ability to analyse elastic deformations is important in many cases, such as …

2.1.2 Plastic deformation

Permanent and irrecoverable

Strains may be large

Often the desired failure mode e.g. energy absorption on car impact, because it is

slower and more predictable than ...

2.1.3 Brittle failure

Catastrophic propagation of a crack, with very little or no macroscopic plastic

deformation

2.1.4 Complex stress states

In a general, complex stress state, we need to consider also:

shear stress

that the stress in a real object can be very complicated

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So we need to:

describe the stress at a point

be able to deal with a general (complicated) stress

This will require several force/area terms. To define stress at a point we need to:

take a volume element surrounding the point

measure the forces transmitted across the faces

resolve forces along the coordinate axes

shrink the volume to a point

force / unit area = stress

2.2 Choice of volume element and coordinate system

We can choose the one which is most convenient for the given problem. Usually this means

that the symmetry of the coordinate system will reflect the symmetry of the body and/or the

stress state, and will normally be either Cartesian or cylindrical polar coordinates.

2.2.1 Cartesian coordinates

use a right-handed coordinate system

define axes 1, 2, 3

the volume element is a cube

We visualise the components of the stress tensor acting on a cubic volume element:

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i corresponds to the direction in which the stress (or force) acts

j is used for the face (or its normal) on which the stress (or force) acts

e.g. 13 represents a force acting in the x1 direction on a face normal to the x3 direction. This

notation is a convention (and others exist).

This means that we can identify two kinds of stress:

normal: ij with i = j

shear ij with i ≠ j

There must be no net force on the cube, otherwise it would accelerate (linearly), so:

a) Stresses on equal and opposite faces of the cube are equal and opposite, and we only

need to consider three faces. This means that 9 quantities are sufficient to describe the

stress at a point, and we can write these as a 3x3 array:

[

]

b) We can simplify this further by considering rotational as well as linear acceleration. For

example, considering moments about the x axis, and only showing the relevant stresses, the

total moment must be zero, so

In general, σij = σji for all i,j so our 3x3 array is symmetrical and there are only 6 independent

quantities. This array of 9 numbers is a second rank tensor, so we have also demonstrated

that stress is a symmetrical second rank tensor.

[

]

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2.2.2 Cylindrical coordinates

These are useful in describing cylindrically symmetrical geometries (tubes, disclocations ...)

σzr = force in z direction on r face, and as before σzr = σrz etc.

2.3 Alternative notations

The notation used is a matter of convention and convenience: in particular the use of τ for

shear stresses is common, which gives equivalent quantities as:

Equivalent notations

Normal stresses

(e.g. stress parallel to x1 on face 1) σ11 σx

Shear stresses

(e.g. stress parallel to x2 on face 1) σ21 τxy

We will use the numerical suffix notation in this course because it allows us to keep to the

same conventions when considering tensors other those for elastic properties, and because

it allows us to use the simplifications offered by the Einstein summation convention. Other

courses may use other conventions and it is important that you become accustomed to these

differences, which are widespread in both textbooks and the research literature.

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2.4 Examples of stress tensors

2.4.1 Uniaxial tension

Choosing sensible axes, with one (x1) along the axis of the rod, σ11 = σ, and all other σij = 0:

[

]

(σ > 0 for tension)

2.4.2 Uniaxial compession

[

]

(σ < 0 for compression)

2.4.3 Hydrostatic compression

(e.g. under water)

This time there are no shear stresses:

[

] ( )

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2.4.4 Pure shear

σ12 = σ21 = τ and all other σij = 0, so we have:

[

]

2.5 Einstein summation convention

We will use electric field, current and conductivity as an example to illustrate a more

generally applicable notation convention.

If we apply an electric field, a current will flow. Both of these quantities are vectors, and they

are related by electrical conductivity:

electric field E = (E1, E2, E3) [units V m–1] potential gradient

current density J = (J1, J2, J3) [units A m–2] current density

For a general anisotropic material the relationship between J and E can be expressed as a

series of equations relating their components:

This describes the conductivity as a tensor of the second rank, writing the above equations

as:

[

] [

] [

]

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The components of the tensor are 11

, 12

, etc, and the number of suffices indicates the rank

of the tensor.

Like conductivity, many other materials properties can be described by matter tensors, and

these properties then relate two other quantities:

Rank Number of

components Property Relating the quantities (with rank)

0 1 Density Mass (0) Volume (0)

Heat capacity Temperature (0) Energy (0)

1 3 Pyroelectricty Polarisation (1)

Temperature change (0)

Electrocaloric effect Entropy change (0) Electric field (1)

2 9

Electrical conductivity Current density (1) Electric field (1)

Thermal conductivity Heat flow (1) Temperature gradient (1)

Permittivity Dielectric displacement (1)

Electric field (1)

Permeability Magnetic induction (1)

Magnetic field (1)

Thermal expansion Strain (2) Temperature change (0)

3 27

Direct piezoelectric effect

Polarisation (1) Stress (2)

Electro-optic effect Change in dielectric permeability (2)

Field (1)

4 81

Elastic compliance Strain (2) Stress (2)

Piezo-optical effect Change in dielectric impermeability (2)

Stress (2)

Electrostriction Strain (2) 2 electric field components (2 × 1)

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We can rewrite the previous equations for the tensor components as summations, so these

equations:

Become:

or:

( )

This last equation can be written in contracted form using the Einstein Summation

Convention:

( )

A suffix occurring twice in a product (j in this case) implies summation with respect to that

suffix and is called the dummy suffix.

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2.6 Transformation of axes

We need to go from ‘old’ axes (x1, x

2 and x

3) to ‘new’ axes (x

1', x

2' and x

3').

Axis x2', for example, makes angles

12,

22 and

23 with the x

1, x

2 and x

3 axes. We define

direction cosines, a21

= cos 21

, a22

= cos 22

, a23

= cos 23

etc, completely specifying the

angular relationships between the axes. The nine direction cosines form a transformation

matrix:

Old axes

x1 x2 x3

New

axe

s

x'1 a11 a12 a13

x'2 a21 a22 a23

x'3 a31 a32 a33

So we have:

x'2 = x1 cos θ21 + x2 cos θ22 + x3 cos θ23

and so on ...

If one of the axes is unchanged this reduces to a 2x2 matrix which should look familiar!

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2.7 Transformation of components

When different reference axes are chosen, the tensor components change but the material

property must be the same. We need to know how the components change.

Using our conductivity example again:

Old axes:

New axes:

Transforming J → J' one component at a time:

or:

which is the 'old' to 'new' transformation.

Similarly for the 'new' → 'old' transformation

and so on, i.e.

So we have:

New from old

Old from new

But we want to relate J' to E':

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and

and

Therefore:

But also

So:

This gives us the ‘new from old’ transformation, and similarly for the ‘old from new’

transformation:

2.8 Transformation laws for tensors

These laws are the basis for defining tensors of a given rank.

Transformation law

Rank of tensor New from old Old from new

0 (scalar) ' = = '

1 (vector) pi' = aijpj pi = ajipj'

2 Tij' = aikajlTkl Tij = akialjTkl'

3 Tijk' = ailajmaknTlmn Tijk = aliamjankTlmn'

4 Tijkl' = aimajnakoalpTmnop Tijkl = amianjaokaplTmnop'

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2.9 Resolution of stresses

Force is a vector and is easily resolved into its components on Cartesian axes:

Resolution of stresses is not as simple as resolution of forces because we have to take into

account the plane on which the forces act (i.e. whether it is a normal or a shear stress).

Consider a body in which the stress is homogeneous. Suppose we are interested in the

stress acting within that body on planes in a particular orientation.

We consider the action of a vector force P per unit area (or "stress") on a plane ABC whose

orientation is specified by its unit normal vector n. The vector n makes angles 1, 2,3 with

the axes x1, x2, x3, and the direction of n is defined by its direction cosines.

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λ1, λ2 and λ3 are also the components of the unit vector n.

In order to work out the stress on the plane ABC due to P, we can start by taking any

element which has ABC as one of its faces, and it is simplest to take the tetrahedron OABC.

In equilibrium the net force on this element must be zero: the force per unit area P acting on

face ABC can be resolved into its components P1, P2, P3 and each of these should be

balanced by the stress components acting on the other faces of the volume element OABC.

We write the area of triangle ABC as ΔABC (and other triangles similarly).

P is a force per unit area, so the force on ABC is:

( )

We can resolve P. ΔABC because it is a vector:

But P. ΔABC is balanced by the other forces acting on the other faces, and we can take

these one direction at a time. In the x1 direction we have:

This can be simplified by noting that the volume of the tetrahedron OABC is:

Volume

And:

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Therefore:

Likewise:

Now dividing through by ΔABC:

And similarly for P2 and P3:

This set of 9 numbers relates a vector P (with components P1, P2, P3) to a vector n (with

components λ1, λ2, λ3), and defines the σij as a second rank tensor relating force and plane

orientation:

Remembering that:

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2.9.1 Total, normal and shear stresses

The total stress acting on a plane ABC is:

| | (

)

We want to calculate the normal and shear stresses separately.

2.9.2 Normal stress

This is important in (for example) tensile fracture

We need Pn, the component of P normal to the plane

We resolve each Pi in the direction of n:

But:

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2.9.3 Shear stress

This matters for slip

We want Ps, the component of P lying in the plane

We know that:

And we have expressions for P and Pn, so we can find Ps from:

( )

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2.10 Principal axes

All symmetrical second rank tensors possess three orthogonal principal axes. “Diagonalising”

a tensor to write its components referred to these axes leads to a simplified form of the

tensor:

[

] [

]

2.10.1 Principal axes of the stress tensor

A principal axis of the tensor is one along which the resultant stress is purely a normal stress

There are no shear stresses in the plane perpendicular to a principal axis

So whatever the state of stress, however complicated, there is always a set of axes such that

the stresses on the cubic volume element are:

And the stress tensor is:

[

]

So:

This is a diagonal tensor

There are no shear stresses

By convention, a single suffix denotes a principal stress

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2.10.2 Diagonalisation of a tensor

We need to find the orientation of a plane normal n (specified by direction cosines λ1, λ2, λ3)

for which the total force per unit area P is parallel to the normal.

Let the magnitude of P be ξ, so:

But:

So:

( )

( )

( ) }

These three simultaneous equations have non-trivial solutions only if their determinant is

equal to zero:

|

|

This gives a single cubic equation in ξ – the “secular equation” – with three roots (values of ξ)

corresponding to the three principal stresses.

2.10.3 Orientation of the principal axes

We need to find λ1, λ2, λ3 for each principal axis.

Take each value of ξ and substitute it back into the 3 simultaneous equations

Check:

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Then we have:

[

]

where σ1, σ2, σ3 are the three values of ξ

By convention the principal axes are (nearly always!) labelled such that:

2.10.4 2D diagonalisation

In many cases diagonalisation is much easier because one of the principal axes is already

known. We then simply have to rotate about that axis – effectively diagonalising in 2D only.

If one principal axis as already known, the tensor to be diagonalised is:

[

]

Remembering that σ12 = σ21

The diagonalisation required is in two dimensions, not three, and is comparatively

straightforward. The determinant becomes:

|

|

Multiplying out to get the secular equation:

( ){( )( ) }

One solution is ξ = σ3 for the principal axis already known. The other principal stresses are

obtained by solving the remaining quadratic:

( )

( ) √( )

( )

( )

√(

)

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2.10.5 The Mohr circle construction

Tha above solutions can also be represented geometrically. We start with the same stress

tensor, and take σ11 > σ22:

[

]

We construct the circle using:

From which:

Points to note:

The x-axis represents normal stresses.

The y-axis represents shear stresses.

The circle is centred on the x-axis and intercepts it at the principal stresses (which are

on the x-axis because there is no shear).

The circle represents the stress state of the volume we are interested in. The

coordinates of the two ends of any diameter give the normal and shear components

of the stress tensor for one particular orientation of the axes.

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The angle of rotation of the diameter (= 2θ) is twice the angle of rotation of the axes in

real space (= θ). The sense of rotation is the same.

The same principal stresses could arise from different combinations of σ11, σ22 and θ,

and these would all correspond to different diameters DC of the same circle.

The procedure works for any second rank tensor (and thus also for strain).

2.10.6 Uses of the Mohr circle

To find principal axes and strains.

To find the maximum shear stress.

Knowing the stress tensor for one orientation, we can find the tensor for any other

orientation.

2.10.7 Representation of a 3D stress state

This can be done by plotting 3 Mohr circles on one diagram, with one circle for plane

perpendicular to a principal axis.

For example, consider again the pure shear case:

[

]

x1x2 plane

[

]

x1x3 plane

[

]

x2x3 plane

[

]

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Note that the maximum shear stress still occurs in the x1x2 plane at 45° to the principal axes

– also that this is one case where we commonly do not observe the σ1 > σ2 > σ3 convention!

2.10.8 Triaxial tension

This time we will specify σ1 > σ2 > σ3, and the stress tensor is then:

[

]

Note that although we can represent the stress state of a 3D system using Mohr circles when

we already know the principal axes, we cannot diagonalise a general 3D tensor using Mohr

circles.

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2.11 Definition of strain at a point

Starting in one dimension, imagine an extensible string:

And now extend it:

The strain in OP is:

And the strain at the origin is defined as:

(

)

Now we do the same in 3 dimensions. After deformation of a body, suppose that point

P (x1, x2, x3) has moved to P' (x'1, x'2, x'3) with displacements u1, u2, u3.

So:

If the ui are the same for all points, then we have a rigid body displacement i.e. zero strain.

For there to be a strain, the ui must vary through the body.

( )

In one dimension:

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So:

And in 3 dimensions:

Which can be written as:

The form of the summation convention defines eij as a second rank tensor.

2.12 Physical meaning of eij

𝜕

𝜕

𝜕

𝜕

𝜕

𝜕

These are simply the tensile strains along the axes x1, x2, x3. Note that the signs are the

same as for stress: positive in tension and negative in compression.

Now consider what would happen for deformation in the x1x2 plane of a rectangular block,

when:

( )

For small angles, very much exaggerated, this corresponds to:

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Given that:

𝜕

𝜕 ( )

𝜕

𝜕 ( )

Consider possible combinations of e12 and e21:

1. e12 = e21 is “pure shear”

2. e12 = – e21 is “pure rotation” (with no deformation)

3. e12 ≠ 0 and e12 = 0 is “simple shear”

Note the distinction between pure shear and simple shear.

In general e12 and e21 describe both shear and rotation together. Note that displacements for

which (e21 + e12) is constant produce the same shape change but different rotations.

We can separate the effects of shear and rotation by writing:

Or in general:

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Where:

( )

And:

( )

Note that εij is symmetric with respect to i and j, and is a measure of shape change, whereas

ωij is antisymmetric with respect to i and j and is a measure of rotation:

And:

( )

So ωij has only 3 independent tensor elements, giving 3 independent rotations – one about

each coordinate axis.

Note the form of the strain tensor written in terms of the shear strain angle in simple shear:

[

]

[

] [

]

From now on, “the strain tensor” will mean εij

In this way, both stress and strain can be written as symmetrical second rank tensors

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2.13 Separating shape changes from volume changes

2.13.1 Hydrostatic and deviatoric components of stress

We can separate out two components of stress:

1. Hydrostatic volume changes

2. Deviatoric shape changes

For example under compressive pressure the stress tensor is:

[

] where

And plotting this on a Mohr circle:

The Mohr circle is simply a point

The stress tensor is the same for any orientation of the tensor axes i.e. it is an

isotropic tensor

There is never any shear stress

So in general we can write:

[

] [

] [

( )

( )

( )]

i.e. the full stress tensor is the sum of the hydrostatic component (volume change) and the

deviatoric component (shape change).

The normal components of the stress exert a pressure on the volume element, and the

hydrostatic component of the stress is their average:

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The hydrostatic stress is also known as the mean stress.

Plastic flow of metals depends only on the deviatoric component of the stress tensor and not

on the hydrostatic component, because it occurs without volume change.

2.13.2 Dilatational and deviatoric components of strain

This is exactly analogous to the separation of the stress components.

In this case, for small strains we can also write the volume of the unit cube:

( )( )( )

Where Δ is known as the “dilatation”.

So:

[

]

[

]

[ (

)

(

)

(

)]

i.e. the full strain tensor is the sum of the dilatational component (volume change) and the

deviatoric component (shape change).

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3 Experimental Study of Stresses and Strains

3.1 Strain gauges

These are devices which exploit the change of electrical resistance resulting from strain.

Start with a long straight wire of length L, and stretch it to L +dL

The resistance R is given by:

[ ρ =resistivity, A = area of cross-section; r = radius of wire]

Take logarithms:

Differentiate:

If the elongation is elastic, then:

Experimentally we find:

[ C ≈ 1 for metals; V = volume = πLr2]

So we have:

[

]

And therefore:

( ) ( )

The exact proportionality depends on the material (via the constants C and ν), so we

introduce a “gauge factor”:

To measure the strain, we:

Fix the wire onto the object

Allow it to deform

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Measure the change in R

Calculate the corresponding strain

However the strains are usually small ( 1%) so dR/R is difficult to measure. But we want to

map out the stress distribution across an object, so we cannot just use a very long wire to

make the absolute value of ΔR bigger – we need to be able to measure the strain over a

small area.

We deal with this by folding the wire, which gives us a small actual gauge length (typically 1

– 10mm) but a large effective length, large R and a large, easily measured R.

Gauges are made from wire or – more commonly – from foil etched to give an

appropriate pattern

A common material is “constantan” (55Cu + 45Ni), which gives a good linear

response

Semiconductor strain gauges are also available with C 1 and gauge factors ≈ 100

In the simplest case, the strain gauge can be connected to a Wheatstone Bridge

circuit to measure R

3.1.1 Thermal effects on strain gauges

The resistivity ρ and the gauge factor k are both temperature-dependent, which can lead to

false strain readings

It is better to use thermally compensated gauges, in which the thermal expansion is matched

to common substrate materials

3.1.2 Analysis of strain gauge results

A strain gauge is sensitive only to strains parallel to its length i.e. to normal strains, and not

to shear strains

If we know the directions of the principal stresses, we can measure the strains directly

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For example, the principal axes may be fixed by the symmetry of the body and the loading

geometry. In this case they are known at A but not at B:

But if the principal axes are unknown, the standard method is to use a rosette – an array of

gauges – from which the strain in any direction can be calculated.

The direction of the principle strains can then be deduced from the three readings, for

example using a Mohr circle.

3.1.3 Example of a strain gauge calculation: a 60° rosette

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Suppose we measure normal strains (the shear strains are unknown from the gauges):

As a vector diagram this is:

But on the Mohr circle the angles are doubled (and note that this is an arbitrary orientation

with respect to the principal axes):

The centre of the circle is at a distance:

And we need the principal strains εx and εy:

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( )

( )

So:

3.2 Photoelasticity

This technique allows the strain field in a transparent model to be visualised using stress-

induced birefringence: when we take a suitable transparent, isotropic material and apply a

stress, it can become optically anisotropic.

In an optically anisotropic material, light propagates with two different velocities and two

perpendicular planes of polarisation, such that:

( )

Where n1 and n2 are the refractive indices and c is the “stress-optical coefficient”.

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3.2.1 Analysis of plane stress distributions using a plane polariscope

We imagine looking towards the polariser, through a sample which is a plate cut in the x1x2

plane of the stress tensor.

At a particular point, the incident wave will be:

This wave splits into two components parallel to σ1 and σ2:

( )

( )

The wave travels through a plate of thickness d, which shifts the phase of each wave by:

So on the exit side of the plate our two waves become:

( ) (

⁄ )

( ) (

⁄ )

There is now a phase difference between the two waves. The wave passing through the

analyser is the sum of the resolved components:

( ) (

⁄ ) (

⁄ )

(

) (

)

This is a travelling wave, with amplitude:

| | (

)

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We get extinction (zero amplitude) when:

σ1 or σ2 is parallel to either the polariser or the analyser, which gives:

This gives black fringes joining the places where the principal stresses are parallel to

the polariser and the analyser. These are isoclinic fringes and are independent of

wavelength.

The two waves are in phase with each other:

(

) ( )

Given:

We get:

( )

( )

And:

( )

C is the stress-optical coefficient; m comesfrom counting the fringes. We get

extinction when the optical path difference is a whole number of wavelengths. These

are isochromatic fringes and:

o Depend on wavelength

o Join points with the same value of (σ1 – σ2)

o Are black in monochromatic light

o Are coloured in white light

Isoclinics orientation of principal stresses

Isochromatics value of (σ1 – σ2)

3.2.2 3D stress analysis

For 3-dimensional stress analysis we can:

Apply a stress to a hot, 3D transparent model

Cool to ‘freeze in’ the birefringence

Remove the external stresses

Section and view slices in a plane polariscope

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3.2.3 Birefringent coatings

These can be applied to the surface of an object under stress

A reflection polariscope (still using cross polars) is needed

Possible coatings need to have high values of the stress-optical coefficient C, for

example:

o Glass

o Epoxy resin

o Polycarbonate

o Perspex (PMMA)

3.3 Brittle coating methods

These can be used to determine the stresses and strains in the surface of a body

We apply a thin coating of a brittle material with a well-defined fracture strain

If it is thin enough and well-bonded, we can assume that the strain in the coating is

equal to the strain in the surface to which it has been applied

The coating will crack under tensile strains

To a first approximation, cracks appear when:

σ1(specimen) = E(specimen) εcrit(coating)

A pattern of cracks develops, oriented perpendicular to the maximum tensile stress in

the surface

3.3.1 Tension in one dimension

In uniaxial tension we will see:

The orientation of the cracks gives the direction of σ1

The load at which the cracks appear gives the magnitude of σ1 at that load

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3.3.2 Tension in two dimensions

If σ1 > σ2 > 0 and both are increasing, then the first set of cracks will appear perpendicular to

σ1 and a second set will appear perpendicular to σ2.

If σ1 = σ2 >0 then the direction of the cracks is indeterminate, and a crazed surface results.

This is commonly seen in:

Dried mud

Old china

Surfaces of varnished oil paintings

In these cases the crazing is the result of differential expansion or contraction.

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Brittle coatings can also be applied deliberately as an analytical technique:

Coatings are 50 - 200μm thick

Applied as a spray of resin

The solvent evaporates and the resin cures on heating leaving a brittle coating

Ceramic coatings can also be used (these need firing to melt, but can then be used at

high temperatures)

3.3.3 Advantages

Simple to use on a real structure

Useful to determine the directions of the principal stresses

Can then apply strain gauges for accurate measurements

3.3.4 Problems

Ceramic coatings are needed for high temperature use

Failure strains need calibrating

3.4 X-ray diffraction

This technique allows measurements of changes in lattice parameter (and is

especially good for thin films)

X-rays are truly non-destructive and non-contact

Useful for residual surface strains

A back reflection method is commonly used

But there are drawbacks:

Inconvenient to set up

Small penetration depth (tens of microns)

Only measures surface strains

3.5 Ultrasonics

Wave velocity depends on modulus and density:

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The modulus and density both depend on stress and strain (given that Poisson’s ratio

≠ ½ for most materials)

The appropriate modulus depends on what type of wave is being used

But again there are drawbacks:

Real materials are non-linearly elastic

Interpretation is not straightforward

3.6 Optical interferometry

This includes both holography and laser speckle interferometry. In general optical methods

are attractive because they are intrinsically non-contact and very sensitive.

3.7 Residual Stresses

These are internal stresses which are not a result of external forces, and which must be

retained by interlocking (for example, a residual compressive stress cannot exist by itself and

must be balanced by a tensile stress somewhere).

There are three main origins of residual stresses in macroscopic bodies:

3.7.1 Thermal stresses due to differential expansion

Consider a plate which has been roll-bonded at high temperature and is then cooled to room

temperature. αth = 1210-6 K-1 for Fe and αth = 1.710-6 K-1 for Cu so they apportion the

thermal strain between the layers differently:

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If the sheet is not symmetric, the residual stresses will cause bending: when this can be

calibrated (e.g. a bimetallic strip) it can be used for temperature measurement.

3.7.2 Plastic flow

Consider bending a bar so that the surfaces (but only the surfaces) are stressed beyond their

elastic limit. The surface regions flow, so when the stress is released the bar will remain

slightly bent in order to accommodate the residual stresses:

This means that residual stresses can be found as a result of forming processes such as

shot peening (surface hardening) and machining.

3.7.3 Changes in volume

Residual stresses can also result from non-uniform or localised changes in volume, such as

occur in:

Phase transformation

Carburising and nitriding (in which interstitials cause a change in lattice parameter)

3.8 Example of stress and strain analysis: elasticity in thin films

This is important for:

Pottery glazes

Optical and other coatings

Electronic devices

etc …

In addition, devices are often multilayered e.g. GaAs/AlAs solid state lasers, W/C x-ray

mirrors.

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3.8.1 Stresses in thin films

There cannot be any forces on a free surface, so σ33 = 0 and σi3 = 0 and this is plane stress:

[

]

In almost all cases σ11 = σ22 ( = σ ) so we have isotropic biaxial tension (or compression).

These are now principal stresses, and we should expect to find both biaxial in-plane strains,

and a normal strain.

[

] [

]

The biaxial stress σ and the biaxial strain ε in the (x1,x2) plane of the film are related by:

( )

( )

The normal strain in the film can be determined (for example) by x-ray diffractometry, and

is given by:

( )

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Residual stresses of this type can arise from:

thermal stresses due to differential contraction between film and substrate

deposition stresses – a film which is bombarded with gas atoms or ions during

deposition will normally develop a compressive stress

epitaxial stresses – a single crystal film in a fixed orientation with respect to its

substrate can develop a strain as a result of the difference in lattice parameters

3.8.2 Epitaxy in multilayers

Consider a stack of alternate layers of (100) Cu and (100) Pd on a (100) NaCl substrate.

Would the interfaces remain coherent?

1. If the multilayer stack is coherent (i.e. there are no dislocations) there is a 7.6%

difference in lattice parameter but the lattices are forced to match.

For Cu: a = 3.6148Å

For Pd: a = 3.8908Å

So the Cu must be in tension and the Pd in compression, with equal and opposite

stresses for equal layer thicknesses.

2. If the stack is not coherent, there is no strain energy due to matching but a 2D

network of dislocations is needed at each interface.

So we have two scenarios:

For thin layers (d < dcrit) the interfaces will be fully coherent with no dislocations

For thick layers (d > dcrit) there will be few interfaces but these will contain dislocations

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4 Other tensor properties

4.1 The representation surface for second rank tensors

For second rank tensors there exists a simple geometrical representation which is useful, for

example, in deriving the magnitude of a material property in a given direction. Taking

electrical conductivity as an example, the property referred to its principal axes is:

[

]

The applied field E has components (λ1E, λ2E, λ3E).

The resulting current density J therefore has components (σ1λ1E, σ2λ2E, σ3λ3E).

Thus the component of J resolved parallel to E is:

( )

So the conductivity σ parallel to E is:

This conductivity can be represented by the surface:

Which will be an ellipsoid if all the coefficients are positive. A radius in a given direction

(λ1, λ2, λ3) will have length r and intersect the surface at a point (x1, x2, x3) given by:

With these coordinates:

In general for a second rank tensor property, the radius length in any direction is the

(property)–1/2 in that direction. For an applied vector quantity parallel to the radius (e.g. field),

the normal to the representation surface at the point where the radius intersects the surface

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is parallel to the resultant vector (e.g. current density). [For discussion of this radius-normal

property, see Nye p28]

The representation surface (or quadric) for a second rank tensor property,

shown in this case for conductivity

4.2 Optical properties

For an isotropic material the electric displacement D is related to the electric field strength E

by:

where κo is the permittivity of vacuum and K is the dielectric constant. The real refractive

index is (K)1/2.

For an anisotropic material, the electric displacement and field strength are not necessarily

parallel. Their vector components are related by:

Where Kij is the tensorial dielectric constant, and Bij is the relative dielectric impermeability.

On principal axes therefore, the real refractive index is n = (K)1/2 = (B)–1/2. The representation

surface for Bij is therefore a plot of refractive index – this is the optical indicatrix.

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4.3 Piezoelectricity

4.3.1 Direct piezoelectric effect

This is the name given to the situtation where we apply a stress to a crystal, which develops

(or changes) its electric moment as a result.

The effect is linear, i.e. moment ∝ stress and when the stress is reversed, so is the moment.

So we need to relate the polarisation vector Pi (moment per unit volume, a first rank tensor)

and the stress σij.

This requires a relationship of the form:

and similarly for P2 and P3.

In general we have:

where dijk is a third rank tensor composed of the 27 piezoelectric moduli.

dijk = dikj always, so we have only 18 independent coefficients.

4.3.2 Converse piezoelectric effect

In this case the crystal develops a strain in response to an applied electric field.

So:

dijk must have the same components as before, otherwise we can make a perpetual motion

machine!

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4.4 Effects of crystal symmetry

Consider a crystal with a centre of symmetry.

Apply a stress e.g. σ11 (and this is inherently centrosymmetric)

The result must also be centrosymmetric

So any resultant dipole will be cancelled by its opposite.

Thus centrosymmetric crystals (belonging to the 11 centrosymmetric point groups, out of 32)

cannot be piezoelectric.

But we can expect to make piezoelectric devices from non-centrosymmetric single crystals

e.g. quartz, point group 32.

We can also have piezoelectric polycrystals provided that:

The individual grains are piezoelectric

The polycrystal has texture (preferred orientation)

4.5 Ferroelectricity

Texturing of piezoelectric polycrystalline ceramics makes use of ferroelectric properties, as in

BaTiO3.

Below 120°C the Ti atom moves towards one of the oxygens in the coordinating octahedron.

This causes:

A cubic → tetragonal transformation on cooling

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Spontaneous polarisation

The direction of polarisationcan be influenced by cooling in an electric field (“poling”).

High T cubic BaTiO3 polycrystal

(no texture)

Cool in electric field E

Low T tetragonal BaTiO3 polycrystal

(with texture and a net dipole parallel to E)

Ferroelectricity is only possible in the 10 polar classes:

1, 2, m, mm2, 3, 3m, 4, 4mm, 6, 6mm

These are a subset of the piezoelectric classes, and the final direction of polarisation in a

single crystal will be a unique direction.

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4.6 Applications of piezoelectricity

These are generally as transducers, which convert a mechanical signal into an electrical

signal, e.g.:

Sonar (e.g. ultrasonic testing)

Microphones

Earphones

Resonators

Gas lighters

4.6.1 Scanning tunnelling microscope

[CC-SA from http://commons.wikimedia.org/wiki/File:ScanningTunnelingMicroscope_schematic.png]

The tip is scanned laterally and the height adjusted to maintain a constant tunnelling current,

with control to better than 1Å, and thus atomic resolution. The tip has to be moved laterally

with extreme precision, and this is achieved with piezoelectric transducers.

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4.7 Pyroelectricity

Ferroelectricity is the existence of a spontaneous polarisation. If this polarisation varies with

temperature then we have pyroelectricity, according to:

ΔT also causes a change in volume ΔV, which also contributes to ΔPi.

If V is held constant (i.e. ΔV=0) then ΔT causes primary pyroelectricity; if it varies, we also

measure secondary pyroelectricity. An experiment will normally measure the sum of both

primary and secondary effects.

Pyroelectric materials come from the same 10 polar classes as the ferroelectric materials.

They are primarily used for temperature measurement and the detection of infra-red

radiation. Examples include BaTiO3 (doped), and triglycerine sulphate (TGS).

4.8 Electrostriction

Magnetostriction is a more important and useful effect, but electrostriction is an example of a

second order effect which illustrates the treatment of non-linearity. Whereas centrosymmetric

crystals cannot show piezoelectricity, they can show electrostriction.

We start from converse piezoelectricity:

If the effect is non-linear we require an additional term:

( )

The first term ( ) is linear in applied field (if the field is reversed, the strain is reversed),

and there can be no effect if the crystal is centrosymmetric.

It can also be useful to write this expression as:

( )

Where the “correction term” γiljk El is a third rank tensor which represents electrostriction.

The effect is quadratic in applied field (if the field is reversed, the strain is the same) and it

can appear for centrosymmetric crystals.

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5 Elasticity

We need to relate two second rank tensors: stress σij and strain εij.

Each component of σ can in general depend upon all nine components of ε, so we need a

fourth rank tensor:

5.1 Elasticity in isotropic media

In the perfectly general case, Cijkl could have 81 coefficients, so first we will consider the

simpler case of isotropic materials include:

Polycrystalline materials and ceramics (if texture-free) – these are isotropic on a

macroscopic scale although individual crystallites or grains will not be

Amorphous materials (glasses and glassy polymers)

Anisotropy arises from:

Texture (e.g. rolled metals)

Structure (e.g. composite materials, single crystals, wood …)

But we can often assume isotropy as an approximation.

5.1.1 Isotropy

Isotropy has two important, simplifying consequences:

1. The strain depends only on the stress state in the material and not on the orientation

2. The principal axes of stress and strain coincide

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5.1.2 Linear elasticity theory

This makes the dual assumptions of linearity and superposition.

1. Linearity – Hooke’s Law

This assumes a linear relationship (proportionality) between stress and strain e.g.

E is a scalar: the “Modulus of Elasticity” or “Young’s Modulus” and is the same

in both tension and compression.

2. Superposition

Suppose a stress σA produces a strain εA and σB produces εB. Then:

( ) ( )

This is a consequence of linearity and holds only for small strains.

5.1.3 Poisson’s ratio

Consider again the rod in uniaxial tension:

But there is a lateral contraction in the x2x3 plane:

Experimentally we find:

Where ν is Poisson’s ratio, and is constant for any one material (note the sign convention).

Typically it takes values of 0.25 – 0.33 for most materials in the elastic range.

If there were no volume change, then:

This requires ν = 0.5, and is true for the elastic deformation of rubber (caused by coils

unwinding rather than bonds stretching).

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Note that ν does not have to be positive, and for example cork has a negative Poisson’s ratio

because of its cell structure, as does α-cristobalite. These are known as auxetic materials.

5.1.4 General expression for strain

Using superposition, we can see that each principal strain is the sum of a tensile extension

due to the parallel stress, and two lateral contractions due to the perpendicular stresses, for

example:

( )

And similarly:

( )

( )

There are no shear stresses in these expressions because the tensors are referred to their

principal axes.

Even for arbitrary cases we still have equivalent expressions:

( )

For simple shear, shear stresses are related to shear strains by τ = μγ:

Or equivalently (given that γ = 2εij):

( )

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μ is the “shear modulus” or “modulus of rigidity” (alternatively sometimes written as G).

5.1.5 Other elastic constants

In isotropic media there are just two independent elastic constants (we can specify any two),

and so there are algebraic relationships between them. For example, to describe volume

changes due to hydrostatic pressure:

Dilatation Δ is given by:

And hydrostatic stress σH by:

( )

K is the bulk modulus and β is the compressibility.

We can find relationships between E, ν, μ, K and β by algebraic manipulation. For example

we can add the three equations relating principal stresses and strains:

( )

( )

Which gives:

And so:

( )

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5.1.6 Lamé’s constants

We have expressions for strains given known stresses, but we also need expressions for

stresses given known strains. Manipulating the above equations gives:

( )

( )( )( )

If we define:

( )( )

Then we have:

We call μ and λ Lamé’s constants.

For shear stresses σ12 = 2με12 etc as before. μ and λ are often quoted as the two elastic

constants but the choice is arbitrary.

5.2 Elasticity in general anisotropic media

We want to relate the two second rank tensors stress (σij) and strain (εij). So we write:

∑ ∑

The Cijkl are the 81 stiffness coefficients.

We can also write the reverse:

∑ ∑

Where the Sijkl are the compliances.

Again there are 81 of them, forming a 4th rank tensor.

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C → stiffness constants (elastic constants, Young’s modulus etc)

S → compliances (elastic moduli)

Both σij and εij are symmetrical and only have 6 independent components., so for stiffness

and compliance the number of independent coefficients is reduced to 66 = 36

i.e. Cijkl = Cijlk = Cjikl = Cjilk

5.2.1 Matrix notation

We have:

independent stress components σ1 → σ6

independent strain components ε1 → ε6

We would like to be able to write expressions like:

( ∑

)

( ∑

)

However going from tensor to matrix notation is not straightforward and must be done

carefully. First we replace the stress notation like this:

[

] [

]

Note that the σ1 → σ6 are not principal stresses.

In order for our equation σi = Cijεj to work, we have to define ε6 = 2ε12 etc, so the 6 strain

terms become:

[

]

[

]

Note that this makes ε4 the simple shear angle γ23 (and similarly for ε5 and ε6).

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So we can now write:

( ∑

)

Where Cijkl → Cmn for all m,n (appropriately ordered) i.e. the stiffness constants are

unchanged.

The compliances are more complicated. To write:

We require:

[

] [

] [

]

So that:

Sijkl = Smn when m and n are 1,2,3

Sijkl = ½ Smn when either m or n are 4,5,6

Sijkl = ¼ Smn when both m and n are 4,5,6

Defiend in this way, we can now write:

( ∑

)

Note that the two arrays of numbers Cij and Sij are matrices but not tensors.

5.2.2 Elastic strain energy

Considering the elastic energy stored in a body allows us to simplify the equations further.

Consider a bar in uniaxial tension, and remember that the elastic strain energy stored in a

body must be equal to the work done by the external forces in deforming it:

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At one instant the bar is under a load F with strain ε. Suppose it elongates by dL, then the

work done is:

Where A is the cross-sectional area, and:

So the work done per unit volume is:

[Compare this with σ = Eε for uniaxial stress]

In the general case, and using matrix notation, the work done per unit volume will be:

If the deformation is isothermal and reversible, the work done per unit volume is also equal to

the increase in free energy dψ, and so:

Now we can differentiate twice, giving:

𝜕

𝜕 (𝜕

𝜕 )

Similarly, we can derive: 𝜕

𝜕 (𝜕

𝜕 )

But ψ is a function of the state of the body and defined by the strains, so the order of

differentiation must be immaterial, so:

𝜕

𝜕 (𝜕

𝜕 )

𝜕

𝜕 (𝜕

𝜕 )

And therefore:

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Similarly

In the same way as the 1D case, this gives us the strain energy per unit volume = ½Cijεiεj.

Since Cij = Cji, the 36 coefficients reduce to 21 independent coefficients for a perfectly

general anisotropic solid.

5.3 Crystal Symmetry

The 21 independent coefficients are all that we need to describe the properties of a crystal of

minimum symmetry (i.e. triclinic), but for higher symmetry the number of independent

coefficients is lower still.

5.3.1 The cubic system

We should choose axes which reflect the symmetry of the lattice, so in the cubic

system we choose the cube axes (i.e. x1 is parallel to [100], x2 is parallel to [010] and

x3 is parallel to [001]). For the most general result, we choose the least symmetric

cubic point group – 23. This point group has:

Diads parallel to <100>

Triads parallel to <111>

No mirror planes

No 4-fold axes

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The four triads require the three cube axes to be equivalent to each other, so:

(and similarly for the compliances)

The diads require all the remaining constants to be zero (see Nye p137/8 for a proof).

So for all cubic crystals there are only 3 independent elastic constants:

C11

C12

C44

(or S11, S12 and S44)

The stiffness matrix is therefore:

[ ]

So, for example:

And similarly for the other axes.

5.3.2 Deformation modes of a cubic crystal

Each independent elastic constant is associated with a fundamental mode of deformation.

For an isotropic material there are two modes: dilatation and shear.

The three independent constants in a cubic crystal require there to be three independent

modes of deformation

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a) Dilatation by hydrostatic stress

Under a hydrostatic pressure p:

Then there are two shear modes:

b) Shear on a cube face parallel to a cube axis

e.g. on the (010) plane in the [001] direction:

C44 is a shear modulus, which by convention we name μo.

c) Shear at 45° to a cube axis

e.g. on the (110) plane in the ̅ direction. In this case the shear modulus is:

( )

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So we can define an anisotropy factor:

( )

For an isotropic material:

And:

This explains why cubic crystals are not in general isotropic.

W Al Fe Cu Na

1.0 1.2 2.4 3.2 7.5

Structure bcc fcc bcc fcc bcc

5.3.3 The Cauchy Relation

Where atoms lie at centres of symmetry and where interatomic forces act entirely

along the line joining atom centres, then:

This is roughly true for ionic crystals (e.g. KCl, NaBr) but does not work for metals,

where bonding is not localised.

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5.4 Elastic stress distributions

Additional equations are needed to describe stresses or strains which vary through a body.

We need to take account of:

Stress equilibrium

Strain compatibility

The stress-strain relationship

5.4.1 Stress equilibrium

The net forces on an element must balance, but the stress may change across a volume

element.

For example in direction x1:

𝜕

𝜕 𝜕

𝜕 𝜕

𝜕

may not necessarily equal zero. However it can be shown that:

𝜕

𝜕

𝜕

𝜕

𝜕

𝜕

So we have three equations which (using the summation convention) can be written as:

𝜕

𝜕 [∑

]

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5.4.2 Strain compatibility

The displacements ui must vary smoothly through the body with no gaps and no

discontinuities, which means that the ui components must be single-valued, continuous

functions of xi.

This leads to six “compatibility relations”:

𝜕

𝜕 𝜕 (

𝜕

𝜕

𝜕

𝜕

𝜕

𝜕 ) ( )

And:

𝜕

𝜕

𝜕

𝜕

𝜕

𝜕 𝜕 ( )

5.4.3 Stress-strain relationship

For linear elasticity we have:

( )

which gives another six equations.

So in general we have 3 + 6 + 6 = 15 equations with 15 unknowns: six stress components,

six strain components and three displacements.

5.4.4 The Airy Stress Function

The mathematical treatment of the general condition is formidable unless it is simplified by

symmetry. For example, plane stress gives σ1 and σ2 ≠ 0 and σ3 = 0. In this case we can use

the Airy Stress Function χ. This is defined such that:

𝜕

𝜕

𝜕

𝜕

𝜕

𝜕 𝜕

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The Airy stress function allows all 15 equations to be combined into the single biharmonic

equation:

( )

5.4.5 Computational procedure

Solve the differential equation for appropriate boundary conditions to obtain χ. This

can be done analytically in some cases (such as holes)

Differentiate χ to obtain σij

Obtain the strains from the stresses using Sijkl

5.5 Elastic waves

These are important in analysing the dynamic response of materials and structures (for

example impact/explosive loading can give a very different fracture pattern from static

loading). They are also important in the measurement of mechanical properties at high strain

rates.

Ultrasonic waves in particular are used for:

Flaw detection (non-destructive testing)

Medical applications

Microstructure refinement during casting and welding

Piezoelectric transducers in scanning probe microscopes

We will consider only isotropic materials (because anisotropic behaviour is much more

complex).

5.5.1 Longitudinal waves in a rod

There is a uniform stress across the planar cross-section.

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The net force on an element is:

𝜕

𝜕

If the displacement of an element from its rest position is u, we can use:

( )

And:

𝜕

𝜕

To give:

𝜕

𝜕

𝜕

𝜕 ( )

This is a 1-dimensional wave equation for a longitudinal wave propagating with velocity vo,

where:

These are rod waves. Similarly, for pure shear we get torsion waves according to:

5.5.2 Waves in infinite media

In this case the relevant strain is ε1, and the relevant modulus is C11, so we get compression

waves with a velocity given by:

Similarly we get transverse waves (shear distortion waves) according to:

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In general for a bulk, isotropic material there will be two waves, corresponding to the two

independent deformation modes.

For a fluid, μ = 0 (there is no shear), so only longitudinal waves are possible.

5.5.3 Surface waves

Displacements perpendicular to a surface are Rayleigh waves. On the surface of the Earth,

these are responsible for causing earthquake damage.

( )√

( )

( )

So in general, vs < v2, so the Rayleigh (surface) waves arrive after the bulk waves, and also

lose least energy because they are propagating in only two dimensions instead of three.

Elastic wave velocities (ms-1)

Steel Aluminium Rubber

Rod waves vo 5190 5090 46

Bulk, longitudinal v1 5940 6320 1040

Bulk, shear v2 3220 3100 27

Surface vs 2980 2920 26

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5.6 Saint-Venant’s principle

Any geometrical discontinuity (holes, cracks, notches …) will create a non-uniform stress

distribution, but far away from the discontinuity the stresses will remain uniform. This is an

example of Saint-Venant’s principle in operation, which can be stated as:

The stress distribution in a body depends only locally

on discontinuities or on the method of loading

Or more formally:

If the forces acting on a small part of the surface of a body are replaced

by statically equivalent forces (i.e. same resultant and couple),

the stress state is negligibly changed at large distance.

For example, the stress in the middle of a plate does not depend upon the method of

gripping:

This is an important principle which is implicit in all mechanical testing.

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5.7 Examples of stress distributions

5.7.1 Holes in plates

In general, the solutions for the stresses are:

{

(

) }

(

)

{

(

) }

Examining the limiting cases illustrates how the stresses vary:

At r = ro, we have σrr = 0 and σrθ = 0 because there is no stress perpendicular to a free

surface. But σθθ = σ ( 1 – 2 cos 2θ), so

θ = 0 σθθ = – σ

θ = ±π/2 σθθ = 3σ

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So we have stress magnification (3σ) beside the hole, which can lead to crack propagation

and catastrophic failure and stress reversal (–σ) above and below the hole. In brittle

materials (e.g. masonry) this can lead to failure above and below holes where a compressive

stress is reversed to become tensile.

At θ = π/2 ( cos 2θ = – 1 ) and large r, the stress falls off as 1/r2. As r → ∞

which is as expected from Saint-Venant’s principle.

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5.7.2 Stresses at notches and cracks

[See Cottrell p145 for an approximate treatment of notches and Knott p29 for a more

sophisticated treatment]

We can use the results for a hole to get a rough idea of the effect of a notch.

If there are n holes in total, after the nth and last hole the stress is:

Suppose that the radii decrease by a factor of 10 from one hole to the next, with the largest

radius being a and the smallest ρ. Then:

(

)

Taking logs of the first equation we have:

(

)

(

)

Taking exponentials of both sides gives:

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This is a good order magnitude estimate – for comparison, the exact solution for the stress at

the edge of an elliptical hole is:

( √

)

Note also (and don’t confuse with) the result for a sharp crack:

5.7.3 General features of stress distributions around holes and notches

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The general features of the stress distribution ahead of a notch are similar to those ahead of

a hole. The tensile stress in the radial direction is important in understanding how cracks are

stopped in composite materials:

If the fibre/matrix interfaces are weak in tension, they can open up ahead of a crack resulting

in crack blunting and stopping.

5.8 Dislocations

5.8.1 Screw dislocations

For the volume element on the surface of the cylinder surrounding the core of the dislocation:

In a finite medium this causes a problem at the ends of the cylinder because the forces do

not balance. This causes an Eshelby twist along the length.

Consider an annular element of a rod of total length L:

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Shear stress

Area

Tangential force

Moment

Total torque ∫

Suppose that the torque T causes a twist φ, which is the same everywhere. For the annular

element:

Shear strain

Shear stress (

)

Tangential force (

)

Moment (

)

Total torque ∫ (

)

(

)

So for this dislocation:

(

)

which gives the Eshelby twist as :

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Note that this depends on b and R, but is independent of μ.

5.8.2 Edge dislocations

In this case the expressions for the stresses are:

( )

( )

This is plane strain, so:

( )

( )

Exploring the special cases:

⁄ ( )

( )

⁄ ( )

( )

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The region below the dislocation half plane is therefore a desirable site for solute atoms.

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Lecture Examples

Lectures 4 and 8 will be in Examples Class format, during which you will have the

opportunity to work through the following questions. These are closely based upon

the content of the immediately preceding lectures.

1. A single crystalline orthorhombic material has an electrical conductivity tensor ij:

[

]

when referred to its principal axes x1, x2, x3 which are parallel to the crystallographic axes x, y

and z. A thin plate is cut from the crystal according to ‘new’ axes x1', x2', x3', with x1' being

the normal to the plate and x2', x3' lying in the plate. The axes are such that x2' is parallel to

x2, and x1' lies between x1 and x3 at 30˚ to x1. Calculate 11'.

Electrodes are plated on to the faces of the thin plate and a potential gradient E (V m–1) is

applied to it. The electric field vector will be perpendicular to the plate faces. What are the

components of E, referred to the 'old' (principal) axes? Using the diagonalised tensor ij

calculate the current density vector (referred to the old axes).

2. The orientation of a vector (x1, x2, x3) can be described by nine direction cosines (aij)

relative to the co-ordinate axes. These direction cosines are not independent, and are related

as follows:

( )

( )

Why is this the case?

3. A body is subjected to principal stresses of magnitudes 5, –3 and 0 respectively along

the x1, x2, and x3 axes. Calculate the normal and shear stresses acting on a plane which is

perpendicular to the x1x2-plane and inclined at 55˚ to the x1x3-plane.

4. Almost all second rank tensors of interest, whether of the matter or field type, are

symmetrical, i.e. Tij = Tji. Tensors with Tij = –Tji are called antisymmetrical. Separate the

following tensors into symmetrical and antisymmetrical components.

[

] [

]

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If these tensors were describing general strains, what would be the significance of the

symmetrical and antisymmetrical components?

5. Separate the following stress tensors into hydrostatic and deviatoric components:

[

] [

] [

]

6. The strains measured by three strain gauges arranged in a 60˚ rosette on the surface

of a steel plate are 1.2 10–3, 2.0 10–3 and –1.0 10–3. Determine the orientation and

magnitude of the principal strains in the surface. What is the maximum shear strain?

7. A 45° strain gauge rosette attached to the surface of an aluminium alloy panel

measures the following strains:

εa = –0.0025; εb = 0.0020; εc = –0.0040

The orientation of the gauges is as shown:

a) What are the normal stresses in the a, b and c directions?

b) What are the principal stresses in the plane of the surface?

The Young’s modulus of the aluminium alloy is 70GPa and its Poisson’s ratio is 0.33

8. Derive the following relationships:

( )

( )

Using these relationships, show that the bulk modulus K is given by:

( )

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9. A body of an isotropic elastic material is subjected to principal stresses along the

axes x1, x2 and x3 of such magnitudes that the elongations along x2 and x3 are zero. In a

second experiment it is stressed along these same axes in such a way that the elongations

along x2 and x3 are equal and that along x1 is zero. Show that the effective modulus (stress-

strain ratio) along x1 in the first case is (1 – ) times that along x2 or x3 in the second case.

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Preparatory Questions

You should be able to complete these questions from your knowledge and understanding of

the IB Mechanical Properties course. You may need to review your notes from that course,

and the recap at the start of the Part II Tensors course will also be helpful. Start (and finish)

this sheet as soon as you can – you should not need help from your supervisor with these

questions!

1. Construct a Mohr circle diagram for each of the following stress states and deduce

the values of the principal stresses. Describe each stress state in words. Then diagonalise

each tensor using the secular equation and check that you obtain the same values of

principal stress.

[

] [

] [

]

2. Construct Mohr circles for the following stress tensors. Find the principal stresses

and the angle between the tensor axes and the principal axes. Then calculate the same

quantities from the secular equation.

[

] [

]

3. A cylindrical tube of diameter 80 mm and wall-thickness 2 mm is pressurised to

10 MPa above atmospheric pressure. It bears a tensile load of 12.5 kN and is subjected to a

torque of 1 kN m at its ends. What are the principal stresses in this system, and at what

angles to the tube axis do they occur?

Answers

1. (a) σ1 = 2; σ2 = 0; σ3 = 0

(b) σ1 = +1; σ2 = -1; σ3 = 0

(c) σ1 = 0; σ2 = 0; σ3 = -4

2. (a) √ √

(b) √ √

3. (a) MPa MPa

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Question Sheet 1

1. A three-dimensional state of stress is given by

11 = + 80 MPa 12 = + 20 MPa

22 = – 40 MPa 23 = + 30 MPa

33 = + 60 MPa 31 = – 50 MPa

Show that the total stress on a plane with direction cosines:

is 106.6 MN m–2 and that the normal and shear stresses on this plane are 79.5 MPa and

71.0 MPa respectively.

2. A three-dimensional state of strain is given by:

11 = 4 10–4 12 = 3 10–4

22 = –6 10–4 23 = –3 10–4

33 = 2 10–4 31 = –5 10–4

Show that the greatest axial strain is 9.27 10–4 and that there is no volume expansion.

3. Tests are made in combined tension and shear on molybdenum single crystals to

decide whether cleavage fracture is controlled by a critical value of the normal stress across

the most highly stressed {100} cleavage plane. One such experiment is made on a crystal

whose tensile axis lies along [123]. If the crystal fractures under a combination of a tensile

stress of 400 MPa and a shear stress, acting on the (123) plane in the [2–1 0] direction, of 300

MPa, which is the {100} plane with the highest normal stress, and what is the critical value of

this stress?

4. A transformation of axes should not, of course, affect the property of a material or a

stress state, but the description in terms of tensor components will be changed. Show,

however, that a symmetrical tensor (of the second rank) will always remain symmetrical on

transformation of the reference axes.

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Question Sheet 2

1. (From Tripos 1996, Qu. 11) A cylindrical strut 20 mm in diameter is made from a

titanium alloy. A strain gauge is fixed to the surface of the strut at an angle of 30˚ to the axis

of the strut. What strain is registered by the gauge when the strut is subjected to an axial

tensile load of 5 kN? An axial torque is then applied to the strut, producing an additional

surface shear strain of 5 10–5. The sense of the torque is such as to decrease the strain

registered by the gauge. What value of strain is recorded by the gauge under these

conditions?

[For the titanium alloy, Young’s modulus E = 120 GPa, Poisson’s ratio = 0.30]

2. Two strain gauges are arranged to measure the principal strains on the surface of a

thin-walled tube which is subject to a tensile load P and a torque T. When the tube is on the

point of yielding the tensile strain has just twice the magnitude of the compressive strain.

Show that at yield T = 0.56 Pr, where r is the radius of the tube. [Poisson's ratio = 1/3]

3. In the manufacture of a test circuit, a polycrystalline thin film of aluminium is

deposited on to a thick silicon substrate at 120˚C. Subsequently, the silicon wafer with

aluminium layer uppermost is mounted in an X-ray diffractometer (in the standard setting with

the normal to the wafer bisecting the angle between the incident and diffracted beams). At

room temperature (20˚C) the diffractometer trace has aluminium peaks showing a lattice

parameter decrease of 0.167%, compared to the unstressed state at 20˚C. Assuming that

the aluminium was stress-free during deposition, what is the thermal expansion coefficient of

aluminium?

[The thermal expansion coefficient for silicon is 7.6 10–6 K–1. Poisson’s ratio for aluminium

is 0.345.]

4. A thin multilayer of many alternating (100) GaAs layers 10 unit cells thick and (100)

AlAs layers 4 unit cells thick is deposited on to a thick (100) GaAs substrate.

(a) If all the interfaces are fully coherent, what are the diagonalised strain tensors

representing the states in the GaAs layers and in the AlAs layers?

(b) If the multilayer were to lose coherency with the substrate but to retain it between the

GaAs and AlAs layers, the net force in the multilayer would be zero, i.e. the tensile and

compressive forces in alternate layers would balance. In that case, what would be the strain

tensors?

(c) If all coherency were to be lost, what would be the tensors?

[The lattice parameter, a, for GaAs is 0.5563 nm and for AlAs is 0.5571 nm. Poisson's ratio

is 0.429 for both GaAs and AlAs. Assume that GaAs and AlAs have equal elastic moduli.]

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PART II MATERIALS SCIENCE C4: Tensors

EGB/MT13

Question Sheet 3

1. Poisson’s ratio for rubber is 0.5. Show that a bicycle inner tube can be inflated with

zero change in circumferential length. (A small length of tube can be treated as a thin-walled

cylinder.)

2. The stress distribution in a rotating circular disc is of practical importance in the

design of gas turbine engines. For a disc containing a central hole of radius a, the principal

stresses in the plane of the disc depend on its density , its angular velocity and its

maximum radius b as follows:

{

}

{

[

] }

For a disc containing a central hole of radius a = b/10, plot the variation of r and with r.

Assume that Poisson's ratio is 1/3. Where are the maximum radial and tangential stresses?

Compare the maximum value of tangential stress with the maximum value for a disc with no

hole (a = 0) and note the stress-concentrating effect of the hole.

If a rotating transparent disc of suitable material is viewed in a polariscope, isochromatic

fringes will be seen joining all points with the same value of (r – ). Sketch the

appearance of these fringes.

3. An infinitely long edge dislocation of Burgers vector b in an

elastically isotropic medium, with shear modulus μ and Poisson’s ratio

ν, gives rise to plane strain and, via the Airy stress function, the

following stress tensor components are found:

where r and θ are defined with respect to the dislocation in the figure, and:

( )

(continued overleaf)

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a) Determine

b) Determine the strain tensor

c) Derive an expression for the dilatation and determine at what angle this is a

maximum for r > 0

d) Using the Mohr circle construction or otherwise, determine expressions for the

principal strains

[from Tripos 2010 q2(b)]

Past Tripos Questions

This list covers those Part II Tripos questions set during the last five years which were

directly based upon the Tensors course. It does not include questions drawn from other

courses which nevertheless require a sound knowledge of tensors.

Whilst the content of the Tensors course itself has remained relatively constant over recent

years, there have been changes in the structure, content and examination of the Part II

course as a whole, and also in the coverage of tensor-related material in Parts IA and IB. All

of the questions on this list could be attempted by a student from the current Part II Class,

but slight changes in coverage mean that some of the problems may appear more difficult

(or, conversely, easier!) than when they were first set. This is particularly likely to be true for

questions older than these which you may find in bound collections of Tripos papers in

libraries.

2013 Paper II questions 4; 5

2012 Paper I questions 3; 4

2011 Paper I questions 3; 4

2010 Paper I questions 2; 3; 4

2009 Paper I questions 2; 3; 4