Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious...

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Secondary Alcohol Ethoxylate Alkyloxypolyethyleneoxyethanol C12-14-H25-29-O(C2-H4-O)xH Polyethylene Glycol Ethers WZ5600000 84133-50-6 T1261 Not available. CALL (310) 516-8000 SPECTRUM LABORATORY PRODUCTS INC. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 1 2 0 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment Section 1. Chemical Product and Company Identification Common Name/ Trade Name Catalog Number(s). CAS# RTECS CI# Manufacturer Synonym Chemical Name Chemical Family IN CASE OF EMERGENCY CHEMTREC (24hr) 800-424-9300 Chemical Formula Supplier See Section 15. Commercial Name(s) TSCA TSCA 8(b) inventory: Secondary alcohol ethoxylate; Polyethylene Glycol 2 1 0 Health Hazard Fire Hazard Reactivity Page Number: 1 ORAL (LD50): Acute: 2380 mg/kg [Rat]. >412 mg/kg [Rat] DERMAL (LD50): Acute: 2000 mg/kg [Rabbit]. >14000 mg/kg [Rat] 1) Secondary alcohol ethoxylate 84133-50-6 >97 2) Polyethylene Glycol 25322-68-3 <3.0 Toxicological Data on Ingredients Name Section 2.Composition and Information on Ingredients Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight CAS # Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Continued on Next Page SD ESSENTIALS 1100 N.W. 9TH WAY BATTLE GROUND, WA 98604 Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Tergitol 15-S-3 Surfactant Tergitol 15-S-9 Surfactant Tergikleen record cleaning concentrate A Product Of:

Transcript of Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious...

Page 1: Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious Inhalation Ingestion Serious Ingestion Not available. May be combustible at high temperature.

Secondary Alcohol Ethoxylate

Alkyloxypolyethyleneoxyethanol

C12-14-H25-29-O(C2-H4-O)xH

Polyethylene Glycol Ethers

WZ5600000

84133-50-6

T1261

Not available.

CALL (310) 516-8000

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

12 0

Material Safety Data SheetNFPA HMIS Personal Protective Equipment

Section 1. Chemical Product and Company Identification

Common Name/Trade Name

CatalogNumber(s).

CAS#

RTECS

CI#

Manufacturer

Synonym

Chemical Name

Chemical Family

IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300

Chemical Formula

Supplier

See Section 15.

Commercial Name(s)

TSCA T S C A 8 ( b ) i n v e n t o r y :S e c o n d a r y a l c o h o lethoxylate; PolyethyleneGlycol

210

Health Hazard

Fire Hazard

Reactivity

Page Number: 1

ORAL (LD50): Acute: 2380 mg/kg [Rat]. >412 mg/kg [Rat] DERMAL (LD50): Acute: 2000 mg/kg [Rabbit]. >14000 mg/kg [Rat]

1) Secondary alcohol ethoxylate 84133-50-6 >972) Polyethylene Glycol 25322-68-3 <3.0

Toxicological Dataon Ingredients

Name

Section 2.Composition and Information on IngredientsExposure Limits

TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #

Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant, permeator), ofingestion, of inhalation.

CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.Repeated or prolonged exposure is not known to aggravate medical condition.

Section 3. Hazards IdentificationPotential Acute Health Effects

Potential Chronic HealthEffects

Continued on Next Page

SD ESSENTIALS1100 N.W. 9TH WAYBATTLE GROUND, WA 98604

Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant

Tergitol 15-S-9 Surfactant

Tergitol 15-S-3 SurfactantTergitol 15-S-9 Surfactant

Tergikleen record cleaning concentrate

A Product Of:

Page 2: Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious Inhalation Ingestion Serious Ingestion Not available. May be combustible at high temperature.

Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 2

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention ifsymptoms appear.

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water forat least 15 minutes. Cold water may be used. Get medical attention.

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient.Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughlyclean shoes before reuse. Get medical attention.

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediatemedical attention.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.

Not available.

Not available.

Section 4. First Aid MeasuresEye Contact

Skin Contact

Serious Skin Contact

Inhalation

Serious Inhalation

Ingestion

Serious Ingestion

Not available.

May be combustible at high temperature.

These products are carbon oxides (CO, CO2).

CLOSED CUP: 193°C (379.4°F). (Pensky-Martens.) OPE N CUP: 243°C (469.4°F) (Cleveland.).

Not available.

SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Slightly flammable to flammable in presence of open flames and sparks, of heat.Non-flammable in presence of shocks.

Not available.

Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.

Not available.

Section 5. Fire and Explosion DataFlammability of the Product

Auto-Ignition Temperature

Flash Points

Flammable Limits

Products of Combustion

Fire Hazards in Presence ofVarious Substances

Explosion Hazards in Presenceof Various Substances

Fire Fighting Mediaand Instructions

Special Remarks onFire Hazards

Special Remarks on ExplosionHazards

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposalcontainer. Finish cleaning by spreading water on the contaminated surface and dispose of according to localand regional authority requirements.

Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 6. Accidental Release MeasuresSmall Spill

Large Spill

Keep container tightly closed. Keep container in a cool, well-ventilated area.

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do notingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficientventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizingagents, acids, alkalis.

Section 7. Handling and StoragePrecautions

Storage

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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 3

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors belowtheir respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to thework-station location.

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should beused to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult aspecialist BEFORE handling this product.

Polyethylene Glycol:TWA: 10 (mg/m3) from AIHA [United States] Inhalation

Consult local authorities for acceptable exposure limits.

Section 8. Exposure Controls/Personal ProtectionEngineering Controls

Personal Protection

Personal Protection in Case ofa Large Spill

Exposure Limits

Decomposes >250°C (482°F)

Liquid.

Not available.

7.1 [Neutral.]

Pour point: 9°C (48.2°F)

1.006 (Water = 1)

>1 (Air = 1)

<0 kPa (@ 20°C)

Not available.

Not available.

See solubility in water.

Easily soluble in cold water, hot water. Completely soluble, but some compositions may form gels.

Not available.

Not available.

596 g/mole (approximate)

Mild (Slight.)

Not available.

Colorless. Clear

Section 9. Physical and Chemical PropertiesPhysical state and appearance Odor

Taste

ColorMolecular Weight

pH (1% soln/water)

Boiling Point

Melting Point

Critical Temperature

Specific Gravity

Vapor Pressure

Vapor Density

Volatility

Odor Threshold

Water/Oil Dist. Coeff.

Ionicity (in Water)

Dispersion Properties

Solubility

The product is stable.

Not available.

Reactive with oxidizing agents, acids, alkalis.

Not available.

Normally unreactive. However, avoid strong bases at high temperatures, strong acids, strong oxidizingagents, and materials reactive with hydroxyl compounds.

Not available.

Excess heat, incompatible materials

Section 10. Stability and Reactivity DataStability

Instability Temperature

Conditions of Instability

Incompatibility with varioussubstances

Corrosivity

Special Remarks onReactivity

Special Remarks onCorrosivity

Polymerization Will not occur.

Continued on Next Page

Page 4: Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious Inhalation Ingestion Serious Ingestion Not available. May be combustible at high temperature.

Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 4

Absorbed through skin. Dermal contact. Eye contact.

Acute oral toxicity (LD50): 2380 mg/kg [Rat]. >412 mg/kg [Rat]Acute dermal toxicity (LD50): 2000 mg/kg [Rabbit]. >14000 mg/kg [Rat]

Hazardous in case of eye contact (irritant)Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Not available.

Not available

Acute Potential Health Effects:Skin: May cause mild to moderate skin irritation with redness and itching. May cause drying , and flaking ofthe skin.Eyes: Causes moderate to severe eye irritation and conjunctivitis. Corneal injury may occur.Inhalation: May cause respiratory tract irritation. Short-term harmful health effects are not expected fromvapor generated at ambient (room) temperature do to low volatility. Vapor from heated material may causerespiratory tract irritation. Excess exposure may cause lung injuryIngestion: May cause irritation of the digestive tract (mouth, throat, esophagus, and stomach) with pain ordiscomfort in the abdomen, nausea, vomiting, diarrhea, salivation,Chronic Potential Health Effects:Skin: Repeated or prolonged skin contact is unlikely to result in absorption of harmful amounts.Medical Conditions Aggravated by Exposure: Skin contact may aggravate an existing dermatitis

Not available.

Section 11. Toxicological InformationRoutes of Entry

Toxicity to Animals

Chronic Effects on Humans

Other Toxic Effects onHumans

Special Remarks onToxicity to Animals

Special Remarks onChronic Effects on Humans

Special Remarks on otherToxic Effects on Humans

Ecotoxicity in water (LC50): 4.1 mg/l 48 hours [Daphnia (daphnia)]. 7.3 mg/l 48 hours [Daphnia (daphnia)].3.2 mg/l 96 hours [Fish (Fathead minnow)]. 3.6 mg/l 96 hours [Fish (Fathead minnow)].

Not available.

Possibly hazardous short term degradation products are not likely. However, long term degradation productsmay arise.

The products of degradation are less toxic than the product itself.

Not available.

Section 12. Ecological InformationEcotoxicity

BOD5 and COD

Products of Biodegradation

Toxicity of the Productsof Biodegradation

Special Remarks on theProducts of Biodegradation

Section 13. Disposal ConsiderationsWaste Disposal Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

DOT Classification Not a DOT controlled material (United States).

Not applicable.

Not applicable.

Section 14. Transport Information

Identification

DOT (Pictograms)

Special Provisions forTransport

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Page 5: Material Safety Data Sheet - SD Pickups · ki nCo tac Serious Skin Contact Inh al tion Serious Inhalation Ingestion Serious Ingestion Not available. May be combustible at high temperature.

Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 5

Not available.

01

2210h

Not controlled under WHMIS (Canada). However, it might be classified as WHMISClass D-2B: Material causing other toxic effects (TOXIC).

R36/38- Irritating to eyes and skin.

Section 15. Other Regulatory Information and Pictograms

Other Regulations

Other Classifications WHMIS (Canada)

DSCL (EEC)

HMIS (U.S.A.) Health Hazard

Fire Hazard

Reactivity

National Fire ProtectionAssociation (U.S.A.)

Personal Protection

Health

Flammability

Reactivity

Specific hazard

WHMIS (Canada)(Pictograms)

DSCL (Europe)(Pictograms)

TDG (Canada)(Pictograms)

ADR (Europe)(Pictograms)

Protective Equipment

Vapor respirator. Be sure to use anapproved/certified respirator orequivalent.

Lab coat.

Splash goggles.

Gloves.

Federal and StateRegulations

TSCA 8(b) inventory: Secondary alcohol ethyoxylate; Polyethylene GlycolMinnesota: Polyethylene Glycol

CaliforniaProposition 65Warnings

California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause cancer which would require a warning under the statute: No products were found.California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause birth defects which would require a warning under the statute: No products were found.

S26- In case of contact with eyes, rinseimmediately with plenty of water and seekmedical advice.S37- Wear suitable gloves.

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Tergitol 15-S-9 Surfactant / Tergitol 15-S-3 Surfactant Page Number: 6

Major Uses: Hight performance cleaners and detergents; Hard surface cleaners; Prewash spotters; Paper andtextile processing; Paints adn coatings; Agrochemicals; Oil field chemicals

Not available.

CALL (310) 516-8000

All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop propermethods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.

Notice to Reader

Verified by Sonia Owen.Printed 7/17/2012.

Validated by Sonia Owen on 7/17/2012.

Other SpecialConsiderations

References

Section 16. Other InformationMSDS Code T3124