MATERIAL SAFETY DATA SHEET · Mr. Pink Auto Wash In accordance with directive 91/155/EC (Amended as...
Transcript of MATERIAL SAFETY DATA SHEET · Mr. Pink Auto Wash In accordance with directive 91/155/EC (Amended as...
#20919 Page 1 of 13 Issue date 28-Sept-2010
Material Safety Data Sheet
Mr. Pink Auto Wash
In accordance with directive 91/155/EC (Amended as 93/112/EC) Revision
Date10/5/12
Page 1 of 4
Section 1: Identification of the substance and manufacture
Product Name: Mr. Pink Auto Wash Product Use: Automotive Detailing
Manufacturer: Chemical Guys 3915 W. 102nd Street Inglewood, CA 90303
Telephone Number: 310.674.8135 FAX Number: 310.988.1061 E-mail: [email protected] Web:
www.ChemicalGuys.com
Section 2: Composition / Information on Ingredients
CAS # / EC # Percent Chemical Name Haz. Symbol / R Phrases 1310-73-2 / 215-185-5 <1% Sodium Hydroxide T, Xn / R45,R46, R65 61789-40-0/ 263-058-8 1-5% Cocamido Propyl Betaine Xi; R36/38 68585-34-2/ 209-553-4 1-5% Lauryl Ether Sulfate Xi; R36/38 27176-87-0/ 204-489-3 15-20% Dodecylbenzen Xi; R36/38 Proprietary Blend 0.3% Dye Xi; R36/38 Proprietary Blend 0.20% Fragrance Xi; R36/38
55-70% Water NA
* Self-Classified
Section 3: Hazard Identification
Route of Entry:
See Below
Target Organs: No Information
Inhalation: May cause mild irritation.
Skin Contact: May Cause mild irritation.
Eye Contact: May cause irritation.
Ingestion: May cause irritation to the mucous membranes.
HMIS II-ratins (scale 0-4): Health =1, Fire = 0, Reactivity = 0 HMIS Rating H1/FO/PHO NFPA – ratings (scale 0-4): Health = 1, Fire = 0, Reactivity = 0
Section 4: First Aid Measures
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Inhalation: If breathing is difficult or irritating, move to fresh air immediately. If symptoms persist, get medical attention. Skin Contact: Rinse area with soap and water. Seek medical attention if any redness or irritation persists. Eye Contact: Flush immediately with large amounts of clean water for a minimum of 15 minutes, lifting upper and lower lids
occasionally. Do not rub eyes. If any irritation persists, seek medical attention. Ingestion: If the person is conscious, give two glasses of water to dilute the ingested material. Small amounts that may have
accidentally entered the mouth should be rinsed out thoroughly with water. Seek medical attention immediately.
MSDS Material Safety Data sheet
Mr. Pink Auto Wash
In accordance with directive 91/155/EC (Amended as 93/112/EC) Revision
Date 10/5/12
Page 2 of 4
Section 5: Fire Fighting Measures
Flash Point: N/A
Flash Point Method: Closed Cup
Burning Rate: N/A
Auto Ignition Temperature: N/A
LEL: N/A
UEL: N/A
Flammability Classification:
Non – Flammable
Section 6: Accidental Release Measures
Contain large spills with dikes to prevent entry to waterways and sanitary sewers and transfer the material to
appropriate containers for reclamation or disposal. Absorb/trap remaining material or small spills with inert material
(dirt, sand, industrial absorbent) and then place in chemical waste containers. Flush residual spill area with large
amounts of water. Dispose of all clean up materials in accordance with all applicable federal, state, and local health
and environmental regulations.
Section 7: Handling and Storage
Handling Precautions: Wear proper Personal Protective Equipment when handling.
Storage Requirements: Do not store in direct sunlight. Keep away from children. Keep
containers tightly closed. PROCEDURE FOR HANDLING - Avoid contact with eyes. - Wash and dry hands after using. - Use good occupational work practices. - Avoid physical damage to containers. SUITABLE CONTAINER - Packaging as recommended by manufacturer. - Check all containers are clearly labeled and free from leaks. STORAGE REQUIREMENTS - Store in original containers. - Keep containers securely sealed.
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- No smoking, naked lights or ignition sources. - Store in a cool, dry, well-ventilated area.
Section 8: Exposure Controls / Personal Protection
Engineering Controls: No Hazard Protective Equipment: HMIS PP, A / Goggles Safety glasses or goggles recommended.
Exposure Guidelines/other: None
Section 9: Physical and Chemical Properties
Appearance: Pink Boiling Point: 212F
Physical state: Liquid Soap Freezing: approx. 32 F
Odor: Fresh Scent Solubility: Soluble in water
pH: 8 Spec. Grav. / Density: 8.5 lbs/gal.
Vapor Pressure: No available data
Vapor Density: No available data
MSDS Material Safety Data sheet
Mr. Pink Auto Wash
In accordance with directive 91/155/EC (Amended as 93/112/EC) Revision Date:
10/5/12
Page 3 of 4
Section 10: Stability and Reactivity
Stability: Yes Conditions to avoid: None Known Materials to avoid: Strong Oxidizers.
Hazardous Decomposition: Will not occur. Hazardous Polymerization: Will not occur.
Section 11: Toxicological Information
Component Information Additional Information: The product is not subject to classification according to the calculation
method of the General EC Classification Guidelines for Preparations as issued in the latest
version. When used and handled according to specifications, the product does not have any
harmful effects according to our experience and the information provided to us.
Section 12: Ecological Information
Ecotoxicity effects: This product has no known eco-toxicological effects.
Section 13: Disposal Consideration
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Dispose of in accordance with local, state, and federal regulations.
Section 14: Transportation Information
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA,
IMDG, DOT, DOT CLASS
DOT Class: Not Regulated DOT: Cleaning Compound IMDG: Not Regulated ADG7: Not Regulated IATA: Not Regulated
Because this is produced and shipped in several different container sizes as well as domestically and internationally,
please consult your transportation specialist for the proper shipping name and class.
Section 15: Regulatory Information
CHIP 3Compliance Xi - Irritant R 36 - Irritating to eyes. S1/2 – Keep locked up and out of the reach of children S25- Avoid contact with eyes. S39 - Wear eye/face protection. S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
MSDS Material Safety Data sheet
Mr. Pink Auto Wash
In accordance with directive 91/155/EC (Amended as 93/112/EC) Revision Date:
10/5/12
Page 4 of 4
Section 16: Other Information
The information contained herein is based on data considered to be accurate. However, the information is provided
without any warranty, Expressed or implied, regarding its correctness. The conditions or methods of handling,
storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising
out of or in any way connected with handling, storage, use or disposal of the product.
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Distributed by Reckitt Benckiser (Canada) Inc. 1680 Tech Avenue Unit #2 Mississauga, ON L4W 5S9
In Case of Emergency: 1-800-888-0192 Transportation
Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-
3887 space
.
2. Hazards Identification
space
Emergency Overview CAUTION
EYE IRRITANT. DO NOT get in eyes.
space
Potential short term health effects
Routes of exposure
Keep out of reach of children.
Eye, Skin contact, Inhalation, Ingestion.
space Eyes space Skin space Inhalation space Ingestion
space
Irritating to eyes.
None expected during normal conditions of use.
Not expected to be a skin sensitizer. None expected during normal conditions of use.
Harmful if swallowed. Ingestion could cause irritation of the mouth and throat.
Target organs Eyes. Respiratory system. Skin. space
Chronic effects The finished product is not expected to have chronic health effects.
space
Ingredient(s) CAS #
Percent
Citric acid 77-92-9
0.1 - 1
Sodium cumenesulfonate 28348-53-0 1 - 5
.
space
Product Name space Drying Agent
UPC CODES space Refer to section 16
CAS # space Mixture
Product Use space Rinse additive
LEGEND
HMIS/NFPA
Severe 4
Serious 3 Moderate 2
Slight 1 Minimal 0
0
2 0
Health / 2
Flammability 0
Physical Hazard 0 Personal Protection
B
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Poly(oxy-1,2-ethanediyl), tridecyl-hydroxy-branched 69011-36-5
15 - 40
Alcohols Alkoxylates Trade Secret 7 - 13
1,2-Propylene glycol 57-55-6 7 - 13 space
Extinguishing media
Suitable extinguishing media Treat for surrounding material. space
Unsuitable extinguishing media Not available space
Protection of firefighters Specific hazards arising from Not available
the chemical space
Protective equipment for Firefighters should wear full protective clothing including self contained breathing firefighers apparatus.
space
Hazardous combustion products May include and are not limited to: Oxides of carbon. space
Explosion data
Sensitivity to mechanical impact Not available space Sensitivity to static discharge Not available
. 5. Accidental Release Measures
space
Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not
touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak. space
Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements
or confined areas.
.
3. First Aid Measures
space
First aid procedures Eye contact
space
If in eyes, IMMEDIATELY rinse eyes with plenty of water. Remove any contact lenses
and continue rinsing eyes for at least 15 minutes. If irritation persists, get medical
attention immediately. Skin contact
space Inhalation space Ingestion
space
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
Move to fresh air. Immediate medical attention is not required. If symptoms persist, call a physician.
If swallowed, rinse mouth and drink a glass of water. Do not induce vomiting. Call a
Poison Control Centre or doctor IMMEDIATELY. Notes to physician
space Treat patient symptomatically. General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with
eyes and skin. Keep out of reach of children. .
space
4. Fire-fighting Measures Flammable properties Not flammable by WHMIS criteria.
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space
Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may be
absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers.
Prevent large spills from entering sewers or waterways. Contact emergency services and
supplier for advice. Never return spills in original containers for re-use. .
6. Handling and Storage space
Handling
space
EYE IRRITANT DO NOT get in eyes. Do not ingest. Wash hands immediately after use.
Use good industrial hygiene practices in handling this material. When using do not eat or drink.
Storage Keep out of reach of children. Keep in properly labelled containers.
Keep containers tightly closed in a cool, well-ventilated place. .
7. Exposure Controls / Personal Protection
space
Exposure limit values Ingredient(s)
Exposure limit values
1,2-Propylene glycol ACGIH-TLV
Not established
Alcohols Alkoxylates ACGIH-TLV
Not established
Citric acid ACGIH-TLV
TWA: 10 mg/m3
Poly(oxy-1,2-ethanediyl), tridecyl-hydroxy-branched ACGIH-TLV
Not established
Sodium cumenesulfonate ACGIH-TLV
Not established space
Engineering controls General ventilation normally adequate.
space
Personal protective equipment
Eye/Face protection Space
Tightly fitting safety goggles. Emergency responders should wear full eye and face protection.
Hand protection space Skin and body protection
space Respiratory protection
space General hygiene considerations
.
Impervious gloves. Emergency responders should wear impermeable gloves.
Usual safety precautions while handling the product will provide adequate protection against injury or irritation.
Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible.
Not normally required under normal use conditions. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid
inhalation of vapours generated by this product during a spill or other clean-up operations.
Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink.
Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact.
8.Physical and Chemical Properties space
Appearance Liquid
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space
Colour Blue
space
Form aqueous solution
space
Odour Characteristic
space
Odour threshold Not available
space
Physical state Liquid
space
pH 3.0 ± 0.2 (100%)
space
Freezing point Not available
space
Boiling point > 100 °C (> 212.00 °F)
space
Pour point Not available
space
Evaporation Rate Not available
space
Flash point > 100 °C (> 212.00 °F)
space
Auto-ignition temperature Not available
space
Flammability limits in air, lower, % by
volume space
Flammability Limits in Air, Upper, %
by Volume space
Not available
Not available
Vapour pressure Not available space
Vapour density Not available
space
Specific gravity 1.05 - 1.07 space
Hazardous decomposition products May include and are not limited to: Oxides of carbon. space
Possibility of hazardous reactions Hazardous polymerisation does not occur. .
10. Toxicological Information
space
Component analysis - LC50
Ingredient(s)
LC50
1,2-Propylene glycol Not available
Alcohols Alkoxylates Not available
Citric acid Not available
Poly(oxy-1,2-ethanediyl), tridecyl-hydroxy-branched Not available
Sodium cumenesulfonate Not available
Octanol/water coefficient Not available
.
space
9. Stability and Reactivity Chemical stability
space Stable under recommended storage conditions. Conditions to avoid
space DO NOT MIX WITH BLEACH or use in conjunction with other household products.
Extremes of temperature and direct sunlight. Incompatible materials
space Acids. Oxidizers.
#20919 Page 9 of 13 Issue date 28-Sept-2010
space
Component analysis - Oral LD50
Ingredient(s)
LD50
1,2-Propylene glycol 14800 mg/kg rabbit; 20000 mg/kg rat
Alcohols Alkoxylates Not available
Citric acid 5040 mg/kg mouse; 3000 mg/kg rat
Poly(oxy-1,2-ethanediyl), tridecyl-hydroxy-branched 1080 mg/kg rat
Sodium cumenesulfonate space
Effects of acute exposure
7000 mg/kg rat
Eye space Irritating to eyes.
Skin space
Inhalation space
Ingestion space
None expected during normal conditions of use.
Not expected to be a skin sensitizer. None expected during normal conditions of use.
Harmful if swallowed. Ingestion could cause irritation of the mouth and throat.
Sensitisation space The finished product is not expected to have chronic health
effects. Chronic effects
space The finished product is not expected to have chronic health
effects. Carcinogenicity
space The finished product is not expected to have chronic health
effects. Mutagenicity
space The finished product is not expected to have chronic health
effects. Reproductive effects
space The finished product is not expected to have chronic health
effects. Teratogenicity
space The finished product is not expected to have chronic health
effects. Synergistic Materials Not available
#20919 Page 10 of 13 Issue date 28-Sept-2010
. 11. Ecological Information
space
Ecotoxicity See below Ecotoxicity - Freshwater Algae - Acute Toxicity Data
1,2-Propylene glycol 57-55-6 96 Hr EC50 Pseudokirchneriella subcapitata: 19000 mg/L Sodium cumenesulfonate 28348-53-0 72 Hr EC50 Desmodesmus subspicatus: >1000 mg/L
Ecotoxicity - Freshwater Fish - Acute Toxicity Data
1,2-Propylene glycol 57-55-6 96 Hr LC50 Oncorhynchus mykiss: 51600 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: 41-
47 ml/L [static]; 96 Hr LC50 Pimephales promelas: 51400 mg/L [static]; 96 Hr LC50 Pimephales
promelas: 710 mg/L Citric acid 77-92-9 96 Hr LC50 Lepomis macrochirus: 1516 mg/L [static] Ecotoxicity - Water Flea - Acute Toxicity Data
1,2-Propylene glycol
Citric acid Sodium cumenesulfonate
space
57-55-6 24 Hr EC50 Daphnia magna: >10000 mg/L; 48 Hr EC50 Daphnia magna: >1000 mg/L [Static]
77-92-9 72 Hr EC50 Daphnia magna: 120 mg/L 28348-53-0 24 Hr EC50 Daphnia magna: >1000 mg/L
Environmental effects space Not available
Aquatic toxicity space Not available
Persistence and degradability space Not available
Bioaccumulation/accumulation space Not available
Partition coefficient space Not available
Mobility in environmental media space Not available
Chemical fate information space Not available
Other adverse effects Not available .
12. Disposal Considerations
space
Waste codes Not available
space
Disposal instructions Dispose in accordance with all applicable regulations.
space
Waste from residues / unused
products space
Not available
Contaminated packaging Not available .
13. Transport Information space
UN/ID N.o. Not applicable
U.S. Department of Transportation (DOT): Cla\ssification: Not regulated
#20919 Page 11 of 13 Issue date 28-Sept-2010
Proper shipping name
U.S. DOT Hazard
Class Subsidiary Risk
Packing group
Not applicable
Not applicable
Not applicable Not
applicable
DOT RQ (lbs) Not applicable ERG NO Not applicable
space
Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated
Proper shipping name Not applicable
Status Not applicable
Packing group Not applicable
IMDG (Marine Transport): Classification: Not regulated Proper shipping name Not applicable
Class Not applicable
Subsidiary Risk Not applicable
Packing group Not applicable
IMDG Page Not applicable
Marine pollutant Not applicable
EMS
Not applicable
MFAG
Not applicable
Maximum Quantity Not applicable
IATA/ICAO (Air): Classification: Not regulated
Proper shipping name Not applicable
Class Not applicable Subsidiary Risk:
Not applicable
Packing group Not applicable
Maximum Quantity Not applicable
#20919 Page 12 of 13 Issue date 28-Sept-2010
15.
Regulatory Information
space
Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
Product Registration: Product is compliant with CCCR regulatory guidelines; a specific registration is not
required for this product.
Canada - WHMIS - Ingredient Disclosure List
1,2-Propylene glycol 57-55-6 1 % Citric acid 77-92-9 1 %
space
WHMIS classification Exempt - Consumer product
space
Inventory Status Country(s) or region
Canada
Canada
Inventory Name
Domestic Substances List (DSL) Non-Domestic Substances List (NDSL)
On Inventory (Yes/No)*
Yes
No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
.
.
#20919 Page 13 of 13 Issue date 28-Sept-2010
14. Other Information
space
Disclaimer
space
This product should only be used as directed on the label and for the purpose intended.
To the best of our knowledge, the information contained herein is accurate. However,
neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All
materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist. Further information
space 51700-80535 - 200 mL - FINISH® - JET-DRY® Turbo Drying Agent - 0220148 51700-81748 - 500 mL - FINISH® - JET-DRY® Turbo Drying Agent - 0220148
Issue date space 28-Sept-2010
Effective Date space 15-Sept-2010
Expiry Date space 15-Sept-2013
Prepared by space Regulatory Department 800-333-3899
Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page
of the document.