Magnetic Properties Scott Allen Physics Department University of Guelph of nanostructures.
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Transcript of Magnetic Properties Scott Allen Physics Department University of Guelph of nanostructures.
Magnetic Properties
Scott Allen
Physics Department
University of Guelph
of nanostructures
Outline
Domains
Ferromagnetism
Types of magnetism
nano impact on magnetism
terminology
references for further investigation
Types of Magnetism
paramagnetism
ferromagnetism
constituent atoms have magnetic dipole moments
moments are unaligned, but in the presence of an external magnetic field they do attempt to align
all atoms contribute positively to a spontaneous net alignment in the absence of an external magnetic field
ferrimagnetism
net alignment in the absence of an external magnetic field, with some moments opposing, found in ionic compounds such as oxides (antiferromagnetism – special case is which there is full antialignment)
Ferromagnetism
exchange field (BE)strong internal interaction tending to line up the moments in a parallel manner (paramagnetism to ferromagnetism)
Curie temperatureabove this temperature the spontaneous magnetization is lost due to thermal fluctuation
saturation magnetizationmaximum induced magnetic moment that can be obtained in an external magnetic field
separates disordered paramagnetic phase from the ordered ferromagnetic phase
Ferromagnetism
hysteresisferromagnets can have a memory of an applied field after it has been removed
http://hyperphysics.phy-astr.gsu.edu/hbase/solids/magperm.html#c1
Ferromagnetism
in some cases a material in bulk will have a remanence of nearly zero
but if the exchange interaction between the magnetic moments is so high, why wouldn’t the material always be magnetically saturated?
Domains
bulk materials are divided into domainseach domain is spontaneously magnetized to saturation, but from domain to domain the direction of magnetization can be different thus leading to net magnetizations well below saturation
http://hyperphysics.phy-astr.gsu.edu/hbase/solids/ferro.html#c4
domain formation
http://www.irm.umn.edu/hg2m/hg2m_d/hg2m_d.html
surface charges form creating demagnetizing field
magnetostatic energy decreases through creation of second domain
Domain walls
interfaces between domains having differing directions of magnetization
exchange energy acts to keep spins parallel
a thinner wall requires more energy to create and maintain as the change in spin direction must be more abrupt
anisotropy energy tends to keep spins aligned along certain crystallographic planes
a thinner wall is more energetically favorable
competition exists between anisotropy and exchange energy ( domain walls have a finite width ~ 100 nm) http://www.irm.umn.edu/hg2m/hg2m_d/hg2m_d.html
nano impact
nanoscale particles are so small that it is not energetically favorable to have more than one domain single domain regime (10 - 100 nm)
in this regime the direction of magnetization can only change through rotation (not domain growth or formation)
this rotation is energetically difficult and leads to high coercivities and remanence
as the particle size decreases within the single domain regime the “superparamagnetic limit” is reached
coercivity and remanence are zero
nano impact
super paramagnetism – a single domain particle that is magnetically saturated along a particular direction will overcome the anisotropy energy and reverse its direction if the particle is sufficiently small and the temperature is high enough (thermal energy is enough)
http://www.irm.umn.edu/hg2m/hg2m_d/hg2m_d.html
P. Moriarty, Rep. Prog. Phys. 64 (2001) 297
nano impact
with no applied field, and T > 0K, the superparamagnetic particles net moment will average to zero
in an applied field, there will be a net alignment of the magnetic moments
similar to paramagnetism, except it’s the alignment of domains (many atoms) as opposed to single atoms
http://www.irm.umn.edu/hg2m/hg2m_d/hg2m_d.html
nano impact taking it further
this brief discussion of superparamagnetism was considering ideal bulk-like behaviour
due to the high surface to volume ratio in nanoparticles, one finds that surface effects start to play a dominant role
R.H. Kodama, J. Magn. Magn. Mater. 200 (1999) 359.
a good starting point for a more in depth look is:
references
interactions between nanoparticles
M.F. Hansen, S.Morup, J. Magn. Magn. Mater. 184 (1998) 262.
I.M.L. Billas, A. Chatelain, W.A. de Heer, Science 265 (1994) 1682.
intrinsic nanoparticle properties
C.P. Bean, J. Appl. Phys. 26 (1955) 1381.
R.H. Kodama, J. Magn. Magn. Mater. 200 (1999) 359.
R.H. Kodama, Phys. Rev. B. 59 (1999) 6321.
S.A. Majetich, J.H. Scott, E.M. Kirkpatrick, K. Chowdary, K. Gallagher, M.E. McHenry, Nanostruct. Mater. 9 (1997) 291.
S.A. Majetich, Y. Jin, Science 284 (1999) 470.
magnetism
C. Kittel, “Introduction to Solid State Physics”, Wiley, (1986).