Magnetic Gold; Structure Dependent Ferromagnetism in Au4V
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Transcript of Magnetic Gold; Structure Dependent Ferromagnetism in Au4V
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Structure-dependent ferromagnetism in Au4V studied under high pressure
Investigations into Magnetic Gold
D. D. Jackson et al., PRB 74, 174401, 2006 This work was performed under the auspices of the U.S. Department of Energy by University of California, Lawrence Livermore National Laboratory under Contract W-7405-Eng-48.
Lawrence Livermore National LaboratoryUniversity of CaliforniaLivermore, CA 94550
Damon D Jackson
Chantel AracneSam T. Weir
Wei QiuJoel D. GriffithYogesh Vohra
University of Alabama at BirminghamDepartment of Physics
Birmingham, AL 35294
Jason Jeffries*
Brian Maple
University of California, San DiegoDepartment of PhysicsSan Diego, CA 92093
* Now at LLNL
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Overview
•Au1-xVx is a “Kondo” system
•resistance minimum due to magnetic impurity
•If prepared correctly, V crystallographically order to form Au4V
•FM at TC=43 K
•Applying pressure increases magnetic coupling
•TC increases
•Pressure also pushes Au4V back to Au-20%V
Magnetic Phase Diagram
Au4V Au - 20% V
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Electrical Resistivity
ofMetals
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Electrical Resistivity vs Temperature for Metals
•Behavior of ρ(T) depends on dominant electron scattering mechanism
•T due to phonons (T>θD)
•T5 due to phonons (T≈ θD)
•T2 due to electron-electron scattering (low temperatures)
•saturates to a constant due to impurities (low temperatures)
•Matthiessen’s Rule says that the various mechanisms can be summed up to get total temperature dependence
ρ(T)=ρ0+ρelectrons(T)+ρphonons(T)
ρ(T)=ρ0 + aT2 + bT5 + cT
Typical Metallic Behavior
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Good Metals with Magnetic Impurities
•improvement in sample quality lead to interesting new phenomena
•semiconductors
•upturn at low T with very small concentrations of magnetic impurities
•Magnetic impurity concentrations < 1% resulted in resistance minima at large temperatures (10-20 K)
Magnetic Impurities cause ρ(T)to increase at low T
Jun Kondo, Prog. Theor. Phys. 32, 37, 1964
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Kondo Effect
•Metals with dilute magnetic impurities exhibit the “Kondo Effect”
•depth of minimum (ρ(T=0) - ρ(Tmin)) proportional to impurity concentration
•Electrons get trapped by magnetic impurity
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Kondo Effect
Ziman, “Electrons and Phonons”
•Metals with dilute magnetic impurities exhibit the “Kondo Effect”
•depth of minimum (ρ(T=0) - ρ(Tmin)) proportional to impurity concentration
•Electrons get trapped by magnetic impurity
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Kondo Resistance
Kondo’s Theory of the Resistance Minima
•explained concentration dependence on Tmin
•log(T) behavior below Tmin
•Kondo temperature
‣Δρ(TK) / Δρ(0) ) = 0.8
‣energy scale, not minimum
Schilling, Adv. Phys. 28, 657, 1979
TK ≈ TF exp(-1/| J N(EF) | )
ρspin(T)=Δρ(T)=ρimp(T) - ρhost(T)
Jun Kondo, Prog. Theor. Phys. 32, 37, 1964
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Kondo Resistance
Kondo’s Theory of the Resistance Minima
•explained concentration dependence on Tmin
•log(T) behavior below Tmin
•Kondo temperature
‣Δρ(TK) / Δρ(0) ) = 0.8
‣energy scale, not minimum
Schilling, Adv. Phys. 28, 657, 1979
TK ≈ TF exp(-1/| J N(EF) | )
ρspin(T)=Δρ(T)=ρimp(T) - ρhost(T)
Jun Kondo, Prog. Theor. Phys. 32, 37, 1964
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Example ρ(T) for Various TK
Kondo’s Theory of the Resistance Minima
•explained concentration dependence on Tmin
•log(T) behavior below Tmin
•Kondo temperature
‣Δρ(TK) / Δρ(0) ) = 0.8
‣energy scale, not minimum
Schilling, Adv. Phys. 28, 657, 1979
TK ≈ TF exp(-1/| J N(EF) | )
ρspin(T)=Δρ(T)=ρimp(T) - ρhost(T)
Jun Kondo, Prog. Theor. Phys. 32, 37, 1964
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Kondo Resistance with Pressure
Kondo Under Pressure
•Exponential dependence on magnetic exchange parameter result in
•TK increase with Pressure
•due to:
•increase in |-J |
Schilling, Adv. Phys. 28, 657, 1979
TK ≈ TF exp(-1/| J N(EF) | )
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Magnetic Exchange with Pressure
Kondo Under Pressure
•Exponential dependence on magnetic exchange parameter result in
•TK increase with Pressure
•due to:
•increase in |-J |
Schilling, Adv. Phys. 28, 657, 1979
TK ≈ TF exp(-1/| J N(EF) | )
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Electrical Resistivity
ofAu-V Alloys
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Electrical Resistivity of Au-V Alloys
•Kume (JPSJ, 22, 1116, 1967) found “quite peculiar” electrical resistivity for Au-V alloys
•Creveling investigated Au-V alloys in depth (PR, 176, 614, 1968) and found
•V has a local moment for concentration ≤ 30%
Au-V Resistance Kondo Resistance
ρspin(T)=Δρ(T)=ρAu-V(T) - ρAu(T)
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Kondo Behavior in Au-V Alloys
•Creveling found V has a local moment in Au-V alloys for concentration ≤ 30%
•Jeffries investigated Au-V up to 10% and found Kondo behavior for x<1%
•Au-0.5%V has deep Kondo min.
•Measured for P≤2.8 GPa
•TK increases with pressure
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Kondo Behavior in Au-V Alloys
•Creveling found V has a local moment in Au-V alloys for concentration ≤ 30%
•Jeffries investigated Au-V up to 10% and found Kondo behavior for x<1%
•Au-0.5%V has deep Kondo min.
•Measured for P≤2.8 GPa
•TK increases with pressure
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Kondo Behavior in Au-V Alloys
•Creveling found V has a local moment in Au-V alloys for concentration ≤ 30%
•Jeffries investigated Au-V up to 10% and found Kondo behavior for x<1%
•Au-0.5%V has deep Kondo min.
•Measured for P≤2.8 GPa
•TK increases with pressure
dTK/dP ≈ 6.5 K/GPa
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Au-V Kondo Behavior Review
•Magnetic impurities in a non-magnetic host
•Resistance minimum
•Pressure increases the Kondo temperature
•TK increases for Au-V
•d TK/d P ≈ 6.5 K/GPa
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Ziman, “Electrons and Phonons”
Au-V Kondo Behavior Review
•Magnetic impurities in a non-magnetic host
•Resistance minimum
•Pressure increases the Kondo temperature
•TK increases for Au-V
•d TK/d P ≈ 6.5 K/GPa
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Schilling, Adv. Phys. 28, 657, 1979
Au-V Kondo Behavior Review
•Magnetic impurities in a non-magnetic host
•Resistance minimum
•Pressure increases the Kondo temperature
•TK increases for Au-V
•d TK/d P ≈ 6.5 K/GPa
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TK vs P for Au-0.5%V
Au-V Kondo Behavior Review
•Magnetic impurities in a non-magnetic host
•Resistance minimum
•Pressure increases the Kondo temperature
•TK increases for Au-V
•d TK/d P ≈ 6.5 K/GPa
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Au4V and its properties
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Discovery of Ferromagnetism in Ordered Au4V
•Creveling, Luo, and Knapp annealed Au-20%V at 500 C for a week
•V atoms become crystallographically ordered
•Au4V alloy is FM at TC=43 K
•Paramagnetic state shows Curie-Weiss behavior with p
eff=1.43 µ
B
•indicates local moment, S=½
L. Creveling et al., Phys Rev. Lett., 18, 851 (1967)
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Magnetization of Au4V
Discovery of Ferromagnetism in Ordered Au4V
•Creveling, Luo, and Knapp annealed Au-20%V at 500 C for a week
•V atoms become crystallographically ordered
•Au4V alloy is FM at TC=43 K
•Paramagnetic state shows Curie-Weiss behavior with p
eff=1.43 µ
B
•indicates local moment, S=½
L. Creveling et al., Phys Rev. Lett., 18, 851 (1967)
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Curie-Weiss behavior of Au4V
Discovery of Ferromagnetism in Ordered Au4V
•Creveling, Luo, and Knapp annealed Au-20%V at 500 C for a week
•V atoms become crystallographically ordered
•Au4V alloy is FM at TC=43 K
•Paramagnetic state shows Curie-Weiss behavior with p
eff=1.43 µ
B
•indicates local moment, S=½
L. Creveling et al., Phys Rev. Lett., 18, 851 (1967)
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Crystal Structure
• Vanadiums ordered in Au4V
•Space Group I4/m
•Body-centered tetragonal
•a=6.40 Å
•c=3.98 Å
• Gold crystal structure is the basis for Au-V alloys
• fcc (Fm-3m
)
• a=4.08 Å
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Crystal Structure
• Vanadiums ordered in Au4V
•Space Group I4/m
•Body-centered tetragonal
•a=6.40 Å
•c=3.98 Å
• Gold crystal structure is the basis for Au-V alloys
• fcc (Fm-3m
)
• a=4.08 Å
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X-Ray Analysis
•Qiu and Griffith from Vohra’s group at UAB performed XRD
•energy dispersive
•angle dispersive
•tetragonal peak intensities reduce with P
Angle Dispersive XRDEnergy Dispersive XRD
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EOS for Au4V
•Between 18 and 27 GPa, can be indexed to fcc gold structure
•Gold structure maintained during downloading
•3rd-order Birch-Murnaghan EOS gives:
•B0 = 207.11 GPa
•B0 ́= 3.62
Au4V EOS
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•typical sample size is 75 µm in diameter, 50 µm thick
•“Center-of-Earth” type pressures (360 GPa) are possible
•wonderful tool for optical measurements (x-ray, Raman)
Diamond Anvil Cell:The tool for ultra-high pressure research
DAC capabilities are limited for electrical transport,
magnetic properties, etc.
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Designer Diamond Anvils
•lithographically fabricated thin-film tungsten microprobes
•completely encased within epitaxial diamond
•embedded leads provide electrical insulation so that metal gaskets can still be used
•diamond-encapsulated probes remain functional to multi-Mbar pressures60-250 µm
4-12 µm
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•“3D” Lithography required for fabrication onto the non-flat surfaces
•projection lithography for the diamond flat
•laser pantography for the contact pads
•Tungsten probes have a width of 5-10 µm and 0.5 µm thick
Electrical Contact Pads
1st Step: Lithography onto Diamond Anvils
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•2% methane and 98% hydrogen gas mixture
•plasma generated by a 1.2 kW magnetron, operating at 2.45 GHz
•epitaxial diamond onto diamond substrates at a growth rate of about 10 µm/hr
2nd Step: Microwave Plasma Chemical Vapor Deposition
Yogesh Vohra, Univ. of Alabama, Birmingham
Plasma
Heated Substrate (1000 C)
Diamond Growth
H2
CH4
Microwave Power
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•a new single-crystal diamond anvil with diamond-embedded electrodes
3rd Step: Polishing
electrical contact pads
rate of diamond nucleation and growth on clean metal films is low
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•Lithographic Fabrication of Microprobes
•laser pantography (electrical pads) and projection lithography (diamond flat)
•linewidths down to 1 µm
•Epitaxial Diamond Deposition
•Univ. of Alabama CVD process
•diamond film is typically 10-50 µm thick
•Final Polishing and Completion
•microprobes are now completely encapsulated in diamond, except for the exposed ends.
Designer Diamond Anvil Fabrication
300 µm
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Broad Range of Techniques
300 µm
I
I
II
I
I
V
Heating element in operation at ≈10 GPa
ElectricalResistivity
Magnetic Susceptibility
InternalOhmicHeating
10 m
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M.B. Maple et al., Phys. Lett. A, 25, 121 (1967)
Electrical Resistance of Au4V
•In 1967, Maple et al. found a kink
in R(T) at TC
•We analyzed the same batch
of samples!
•Can use the kink to identify TC and track its pressure dependance
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Au4V Resistivity Under Pressure
•Kink broadens as pressure increases
• TC increases with pressure
•Why not use magnetic susceptibility?
•Chin et al. (1968) found M
sat(4.2K) quickly decreased
with increasing strain
•M(T,P) signal too small
G.Y. Chin et al., Solid State Comm., 6, 153 (1968)
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TC vs Pressure Phase Diagram
• Bridgeman (hydrostatic) and DAC (non-hydrostatic) results are consistent
•P≤18 GPa, dTC/dP = 2.7 K/GPa
•Above 18 GPa, indication of TC became washed out
•not possible to accurately pinpoint TC
•No indication of magnetic ordering during downloading
Magnetic Phase Diagram
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•Au-0.5%V exhibits the Kondo effect, indicating
•TK ↑ with pressure
•|JK| ↓ with volume
•Au4V is tetragonal with V ordered on the Au sites
•18 < P < 27 GPa, structure goes to fcc gold
•Au4V is FM with TC = 43 K
•TC ↑ with pressure (P<18 GPa)
Review of Experimental Results
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•Au-0.5%V exhibits the Kondo effect, indicating
•TK ↑ with pressure
•|JK| ↓ with volume
•Au4V is tetragonal with V ordered on the Au sites
•18 < P < 27 GPa, structure goes to fcc gold
•Au4V is FM with TC = 43 K
•TC ↑ with pressure (P<18 GPa)
Review of Experimental Results
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•Au-0.5%V exhibits the Kondo effect, indicating
•TK ↑ with pressure
•|JK| ↓ with volume
•Au4V is tetragonal with V ordered on the Au sites
•18 < P < 27 GPa, structure goes to fcc gold
•Au4V is FM with TC = 43 K
•TC ↑ with pressure (P<18 GPa)
Review of Experimental Results
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•Au-0.5%V exhibits the Kondo effect, indicating
•TK ↑ with pressure
•|JK| ↓ with volume
•Au4V is tetragonal with V ordered on the Au sites
•18 < P < 27 GPa, structure goes to fcc gold
•Au4V is FM with TC = 43 K
•TC ↑ with pressure (P<18 GPa)
Review of Experimental Results
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Theoretical Description of
Au4V Ferromagnetism
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Kondo Coupling ⇔ TC increase
•For free electron: N(EF) ∝V⅔
‣dlnN(EF)/dlnV = 2/3
•Data implies dln|JK|/dlnV
•Heisenberg interaction depends on local moment exchange
•Exchange mediated through indirect exchange
‣ℐ ∝ N(EF) JRKKY2
•Data implies dln|JRKKY|/dlnV
✓ ✓ ✓
≈ -1.8dlnTK/dlnV ≈ -7
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Kondo Coupling ⇔ TC increase
•For free electron: N(EF),∝V⅔
‣dlnN(EF)/dlnV = 2/3
•Data implies dln|JK|/dlnV
•Heisenberg interaction depends on local moment exchange
•Exchange mediated through indirect exchange
‣ℐ ∝ N(EF) JRKKY2
•Data implies dln|JRKKY|/dlnV
✓✓ ✓✓
≈ -1.8
≈ -5.3
dlnTK/dlnV ≈ -7
dlnTC/dlnV ≈ -9.9
??
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Structure and Magnetism
•Au4V has bct structure
•Au-20%V has fcc structure
•Broad transition between them
•and
•FM ordering not found in fcc
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Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
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Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
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Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 51: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/51.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 52: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/52.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 53: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/53.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 54: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/54.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 55: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/55.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 56: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/56.jpg)
Magnetic Nearest Neighbors
•Au4V has 2 magnetic nearest neighbors
•fcc gold has
•12 1st nearest neighbors
•6 2nd nearest neighbors
•Due to random arrangement of V in Au-20%V, there are, on average,
• 18✕0.2= 3.6 nearest V neighbors within the same distance
![Page 57: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/57.jpg)
dlnz/dlnV ≈ -7
Must Account for Structure Changes
dlnTK/dlnV ≈ -7 dlnTC/dlnV ≈ -9.9
dln|J|/dlnV ≈ -1.8 ℐ ∝ N(EF) J2
Au-0.5%V Au4V
![Page 58: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/58.jpg)
dln|J|/dlnV ≈ -1.8
dlnz/dlnV ≈ -7
Must Account for Structure Changes
dlnTC/dlnV ≈ -9.9
Au4V•Au4V has 2 magnetic nearest neighbors within a unit cell lattice spacing
•Au-20%V has on average 3.6 magnetic nearest neighbors (within same distance)
•Using derived pressure dependencies, one finds
• P(z=3.6) = 21 GPa
![Page 59: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/59.jpg)
Au4V Phase Diagram
Must Account for Structure Changes
•Au4V has 2 magnetic nearest neighbors within a unit cell lattice spacing
•Au-20%V has on average 3.6 magnetic nearest neighbors (within same distance)
•Using derived pressure dependencies, one finds
• P(z=3.6) = 21 GPa
![Page 60: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/60.jpg)
Structure- Dependent
Ferromagnetism in Au4V
![Page 61: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/61.jpg)
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
Au-.5%V Kondo Behavior
![Page 62: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/62.jpg)
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
Au-.5%V Kondo Behavior
![Page 63: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/63.jpg)
Structure-dependent ferromagnetism in Au4V studied under high pressure
TK vs P for Au-0.5%V
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
![Page 64: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/64.jpg)
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
Au4V Crystal Structure
![Page 65: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/65.jpg)
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
bct to fcc Transformation
![Page 66: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/66.jpg)
Magnetic Phase Diagram
Structure-dependent ferromagnetism in Au4V studied under high pressure
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
![Page 67: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/67.jpg)
Au4V Phase Diagram
Au4V Au
- 20
% V
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
![Page 68: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/68.jpg)
•Au1-xVx is a Kondo material for x<1%
•Increasing Pressure results in increasing Kondo exchange parameter
•With careful annealing, V order crystallographical in Au4V
•Pressure gradually transforms Au4V into disordered alloy
•Au4V is FM and TC increases with pressure due to |J| and V nn’s
•Intimate connection between structure and magnetism for Au4V
Structure-dependent ferromagnetism in Au4V studied under high pressure
Au4V Phase Diagram
Au4V Au
- 20
% V
![Page 69: Magnetic Gold; Structure Dependent Ferromagnetism in Au4V](https://reader035.fdocuments.us/reader035/viewer/2022062300/556e491cd8b42a2c658b4617/html5/thumbnails/69.jpg)