Magnasoft* CJS Textile Enhancer - Latro Kimya of Textile Silicone Softeners Increased Benefit to...
Transcript of Magnasoft* CJS Textile Enhancer - Latro Kimya of Textile Silicone Softeners Increased Benefit to...
Magnasoft* CJS Textile Enhancer
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 2
Evolution of Textile Silicone Softeners
Increased Benefit to Consumers
Overall Perform
ance
PendantAmino Silicones
PendantAmino Polyethers
Linear[AB]n Textile Enhancers
x y
NH
H2N
R = CH3, OH, OCH3
RSi
OSi
OSi
OSi
R
y z
*Si
OSi
RNH
R'O
OO
R'NH
R*
x n"A" "B"
Textile mills require products and processes that are forgiving and that deliver benefits easily felt by
consumers
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 3
A new product that further enriches Momentive’s prestigious line of Textile Enhancers such as Magnasoft SRS and DerMa NT Textile Enhancer
Nearly 100% actives patented [AB]n linear silicone copolymer
Easily emulsified using a simple mixer generally available in the industry
Not only hydrophilic, but can help provide luxurious softness with smooth, silky and dry feel for virtually all types of cellulosic fabric
Can help provide natural cotton-like touch to cotton knits and sheeting
Wider pH tolerance at elevated temperatures and good stability to shearing; can be considered for use in very demanding conditions for textile finishing
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Magnasoft* CJS Textile Enhancer
A New Prestigious Textile Softener with Multiple Functionality
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 4
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Typical Physical Properties -Magnasoft* CJS Textile Enhancer
0.99 gr/cm-3Density at 25°C
Typical Value
20,000 cpsViscosity at 25°C
79°CFlash point
Clear to Hazy Yellow LiquidAppearance
The data values for typical physical properties should not be used as specifications, which are available by contacting Momentive Performance Materials
Magnasoft CJS Textile Enhancer as
received
70% actives emulsion of Magnasoft CJS Textile
Enhancer
10% actives emulsion of Magnasoft CJS Textile
Enhancer
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Smooth, silky, rich and in-depth softness with dry/cool feel on virtually all types of cellulosic fabrics
Can help provide natural cotton-like touch on cotton knits and sheeting
Hydrophilic: can help water & perspiration be rapidly absorbed with minimal impact on the hydrophilic nature of cotton
Excellent exhaustibility and affinity towards cellulosic fibers: unique and unusually powerful softness effect at low use levels
Nearly 100% silicone actives, hence potentially economical
Readily emulsified to generate emulsions that generally possess high shear and pH stability (acidic and alkaline)
Virtually no fabric yellowing and no color shade change
May be compatible with textile finishing auxiliaries
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Key Features & Typical Benefits -Magnasoft* CJS Textile Enhancer
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 6
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Performance Positioning -Magnasoft* CJS Textile Enhancer
0
2
4
6
8
10Softness
Smoothness
Fabric Whiteness
Hydrophilicity
Shear Stability
Alkali Stability
Color Migration
Emulsification
Magnasoft CJS Textile Enhancer Amino Silicone Fluid
Benchmark A Benchmark B
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
Hydrophilic Magnasoft* Textile Enhancers
Very GoodVery GoodExcellentVery GoodAlkaline Stability
90%85%67%100%(AB)n Silicone %
Magnasoft SilQ Textile Enhancer
Magnasoft DerMa NT Textile Enhancer
Magnasoft JSS Textile Enhancer
Magnasoft CJS Textile Enhancer
Brushed cotton fabrics, Terry towels, Cotton knits
Cotton knits & yarns, Viscose, Towels, Denim
Enzyme treated cotton knits, Viscose rayon, Tencel
Cotton sheets & wovens, Cotton/ Spandex blends, Tencel
Typical Target Fabrics
Limp, DrapeSoft, VoluminousDry, smoothSilky, smoothHand feel
1~3 sec5~10 sec3~8 sec9~15 secWater Absorption
8~10 cycles8~10 cycles3~5 cycles3~5 cyclesWash Durability of Softness
Easy with emulsifiers
Easy with emulsifiersNo need to emulsify
Easy with emulsifiers
Emulsifiability
Very GoodGoodExcellent GoodShear Stability
GoodVery GoodModerateGoodStretch Recovery
Typical Data. Actual data may vary.
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Softness & Smoothness -Magnasoft* CJS Textile Enhancer
Cotton Woven
Cotton Knit
0.0586
0.0538
0.0425
0.0456
0.0664
0.0436
0.0437
0.0296
0.0324
0.0377
(B+2HB)/2
4.34.20.159Magnasoft CJS Textile Enhancer (10% dilution)
4.44.4N/AMagnasoft CJS Textile Enhancer (10% dilution)
0.169
0.161
0.157
0.186
N/A
N/A
N/A
N/A
MIU
KES value
4.14.0Benchmark A
Hand Panel
4.0
4.4
2.5
4.2
4.1
4.4
2.5
Smoothness
4.2Benchmark B
4.3Amino Micro-emulsion
2.5Control – Cotton Woven Untreated
4.1Benchmark B
4.1Benchmark A
4.4Amino Micro-emulsion
2.5Control – Cotton Knit Untreated
Softness
Note: Test results. Actual results may vary.
Superior Softness & Smoothness to Benchmarks on Cotton Fabrics
*Magnasoft is a trademark of Momentive Performance Materials Inc.
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What is KES value ?
KES (Kawabata Evaluation System) is a test equipment to measure softness and smoothness.
Treated fabrics are subjected to a KES evaluation. The instrument eliminates the subjective human factor by delivering numerical values for softness and smoothness.
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Fabric Whiteness -Magnasoft* CJS Textile Enhancer
63.8466.77Control – Cotton Woven
Cotton Woven
55.0964.15Amino Micro-emulsion
64.8466.94Magnasoft CJS Textile Enhancer
(10% dilution)
Cotton Knit
Whiteness (CIE)
67.56
67.15
77.05
76.83
75.74
76.04
77.19
Dry at 130°°°°C
75.67Magnasoft CJS Textile Enhancer
(10% dilution)
65.13Benchmark A
75.17Benchmark B
63.89Benchmark B
75.68Benchmark A
72.50Amino Micro-emulsion
76.94Control – Cotton Knit
Curing at 170 °°°°C X 2 min
Note: Test results. Actual results may vary.
The Lower the Values, the Higher the Fabric Yellowing
*Magnasoft is a trademark of Momentive Performance Materials Inc.
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
Hydrophilicity – Magnasoft* CJS Textile Enhancer
Moderate Hydrophilicity to Optimize the Softness & Smoothness
Cotton Woven by Water Drop Test (Sec)
4.92
4.69
> 60
9.03
1.26
Dry at 130°°°°C
15.1811.6112.00Magnasoft CJS Textile Enhancer (10% dilution)
4.73
5.10
> 60
1.44
Curing at 170°°°°C X 1 min
Hydrophilicity after 24 hrsaging of the treated fabric
Hydrophilicity after 5 days aging of the treated fabric
6.42
10.05
> 60
1.20
Curing at 170°°°°C X 1 min
6.26Benchmark B
8.58Benchmark A
> 60Amino Micro-emulsion
1.17Control – Cotton Knit
Dry at 130°°°°C
* The hydrophilicity of Magnasoft CJS Textile Enhancer can be improved by adding 1~2% Magnasoft TLC Hydrophilic Textile Softener to 10% actives emulsion of Magnasoft CJS Textile Enhancer
Note: Test results. Actual results may vary.
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
Shear & Electrolyte Stability -Magnasoft* CJS Textile Enhancer
No oiling; Translucent appearanceMagnasoft CJS Textile Enhancer (10% dilution)
Significant oiling on surfaceAmino Micro-emulsion
No oiling; Translucent appearanceBenchmark A
No oiling but gel particles deposited on beaker wallBenchmark B
Electrolyte Stability in 10~40 g/lt MgCl2.6H2O at & 50℃℃℃℃ for 5 days
Shear Stability at 50℃℃℃℃, pH10, 1000rpm for 30 min
Stable but becomes translucent
Stable
Unstable
Stable
Observation Results
Benchmark B
Benchmark A
Amino Micro-emulsion
Magnasoft CJS Textile Enhancer (10% dilution)
Product
Magnasoft CJS Textile Enhancer
Amino Micro-emulsion Benchmark BNote: Test results. Actual results may vary.
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
Stability at Various Bath pH & Temperatures
Bath pHBath Temperature
Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃
Significant OilingHazy, No oilingHaze, No oilingClear, No oiling50℃
Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃
Haze, No oilingClear, No oilingClear, No oilingClear, No oiling50℃
Oiling on surfaceOiling on surfaceNo oilingNo oiling30℃
Significant oiling on surface
Significant oiling on surface
OilingNo oiling50℃
Clear, No oilingClear, No oilingClear, No oilingClear, No oiling30℃Magnasoft* CJS Textile Enhancer
(10% dilution)Hazy, No oilingHazy, No oilingClear, No oilingClear, No oiling50℃
Benchmark B
Benchmark A
Amino Micro-emulsion
Product
80℃
80℃
80℃
80℃ Hazy, OilingHazy, OilingClear, No oilingClear, No oiling
Hazy, No oilingHazy, No oilingClear, No oilingClear, No oiling
Oiling
Oiling
7
Much Oiling
Much oiling on surface
10
Clear, No oiling
Gelling
4
Significant Oiling
Much oiling on surface
12
Magnasoft CJS Textile Enhancer: Excellent Stability in Most Conditions
Note: Test results. Actual results may vary.
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
Easy Emulsification -Magnasoft* CJS Textile Enhancer
--0.1Sodium Acetate
6.06.084.2Water
-11.761.7Tridecyl Alcohol 12 Ethoxylate
10.010.01.5Butyl Carbitol
Per manufacturer’s label
0.2
-
2.3
10.0
-2.24Tridecyl Alcohol 6 Ethoxylate
10% Actives Formulation
70% Actives FormulationMaterial
-
14.0
70.0
B
Biocide
-Acetic Acid
-Tridecyl Alcohol 10 Ethoxylate
70.0Magnasoft CJS Textile Enhancer
A
Note: Test results. Actual results may vary.
Product formulations are included as illustrative examples only. Momentive makes no representation or warranty of any kind with respect to such formulations, including, without limitation, concerning the efficacy or safety of any product manufactured using such formulations.
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 15
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Easy Emulsification -Magnasoft* CJS Textile Enhancer
Procedure for 70% actives emulsion formulation
- Charge Magnasoft CJS Textile Enhancer, emulsifiers & butyl carbitol. Mix well until fully homogeneous.
- Slowly add the water solution to silicone/ emulsifiers blend while mixing. Avoid stirring at high speed to prevent foaming.
Procedure for 10% actives emulsion formulation
- Charge Magnasoft CJS Textile Enhancer, emulsifiers & butyl carbitol. Mix well until fully homogeneous.
- Dissolve acetic acid and sodium acetate in water.
- Slowly add the water solution to silicone/ emulsifiers blend while mixing. Avoid stirring at high speed to prevent foaming.
Note: Test results. Actual results may vary.
Product formulations are included as illustrative examples only. Momentive makes no representation or warranty of any kind with respect to such formulations, including, without limitation, concerning the efficacy or safety of any product manufactured using such formulations.
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
A Sample Emulsification for More Hydrophilicity -Magnasoft* CJS Textile Enhancer
NoteWeight %Material
8.0Initial Water
73.0Final Water
TDE-10 emulsifier3.0Tridecyl Alcohol 10 Ethoxylate
Per manufacturer’s label
4.0
2.0
10.0
Magnasoft TLC Hydrophilic Textile Softener
TDE-5 emulsifier
Biocide
Tridecyl Alcohol 5 Ethoxylate
Magnasoft CJS Textile Enhancer
Note: Test results. Actual results may vary.
Product formulations are included as illustrative examples only. Momentive makes no representation or warranty of any kind with respect to such formulations, including, without limitation, concerning the efficacy or safety of any product manufactured using such formulations.
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 17
*Magnasoft is a trademark of Momentive Performance Materials Inc.
A Sample Emulsification for More Hydrophilicity -Magnasoft* CJS Textile Enhancer
Procedure for the sample emulsification
- Charge Magnasoft CJS Textile Enhancer, Magnasoft TLC Hydrophilic Textile Softener, TDE-5 and TDE-10 into a mixer.
- Start stirring at 500 rpm for 5 minutes.
- Add initial water and keep stirring at 500~800 rpm until fully homogeneous and translucent.
- Slowly add the final water while stirring at 500 rpm.
- Stop stirring and wait until the foam collapses.
- A clear micro-emulsion may be obtained.
Note: Test results. Actual results may vary.
Product formulations are included as illustrative examples only. Momentive makes no representation or warranty of any kind with respect to such formulations, including, without limitation, concerning the efficacy or safety of any product manufactured using such formulations.
Copyright 2009 Momentive Performance Materials Inc. All rights reserved. 18
*Magnasoft is a trademark of Momentive Performance Materials Inc.
Potential Applications -Magnasoft* CJS Textile Enhancer
Cotton sheets & woven
Cotton/Spandex blended knits & woven
Cotton knits bio-polished
Tencel and its blends
Surface smoothness with silky & full hand
Good shear stability & compatibility withelectrolytes
Moderate hydrophilicity to absorb water& perspiration
MagnasoftCJS TextileEnhancer
Target F
abrics
Functio
nality
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*Magnasoft is a trademark of Momentive Performance Materials Inc.
You‘ll feel Magnasoft* Textile
Enhancers
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*Magnasoft is a trademark of Momentive Performance Materials Inc.Momentive, M-design logo and “The Science behind the solutions” are trademarks of Momentive Performance Materials Inc.
Technical subject matter in this publication is described and protected by one or more of the following U.S. Patents and their foreign counterparts and/or patent applications: U.S. Patent Nos. 5,807,956 and 5,981,681. Other U.S. and foreign patents and/or patent applications not listed covering the subject matter may be relevant.