Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

159
Lamiaceae Acinos arvensis (L.) Dandy Synonyms A. thymoides Moench; Calaminta acinos L. Family: Lamiaceae Aerial Part Essential oil, % dry wt: 0.1 [1] FAs: 18:1(3) [1] Sterols, % dry wt: 0.06 [2] Triterpenoic acids, % dry wt: Ursolic acid – 1.4 [1, 2] Terpenoids Phytol, % dry wt: 0.05 [2] Seed Oil (n-hexane) Iodine value, % J 2 : 246.2 (cald) [3] FAs Composition (GLC, 10% PEGA), mol %: 16:0 – 4.1; 18:0 – 1.1; 18:1 – 5.6; 18:2 – 13.2; 18:3 – 76.0 [3] Use: Ornamental plant [1]. Leaves are used as kitchen spice [1]. References 1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6, 10 [in Russian] 2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2), 247 (1976) [in Russian] 3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32 (1971) Acinos rotundifolius Pers. Synonyms A. graveolens (Benth.) Lind. Family: Lamiaceae Aerial Part Essential oil, % dry wt: 0.12–0.14 Composition of essential oil, %: a-Pinene + b-pinene – 25.0; camphene + terpinolene + menthone – 60.0 Activity: Bacteriostatic activity of essential oils. Use: Source of menthol. References 1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6, 10 [in Russian] Agastache foeniculum O. Kuntze. Family: Lamiaceae Seed Oil, % dry wt: 32.11 (China); 40.73 (Russia) Iodine value, % J 2 : 187.18–189.92 A.I. Glushenkova (ed.), Lipids, Lipophilic Components and Essential Oils from Plant Sources, DOI 10.1007/978-0-85729-323-7, # Springer Science+Business Media, LLC 2012

Transcript of Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Page 1: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae

Acinos arvensis (L.) Dandy

Synonyms

A. thymoides Moench; Calaminta acinos L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1 [1]

FAs: 18:1(3) [1]

Sterols, % dry wt: 0.06 [2]

Triterpenoic acids, % dry wt: Ursolic acid – 1.4 [1, 2]

Terpenoids

Phytol, % dry wt: 0.05 [2]

Seed

Oil (n-hexane)

Iodine value, % J2: 246.2 (cald) [3]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.1; 18:0 – 1.1; 18:1 – 5.6; 18:2 – 13.2; 18:3 –

76.0 [3]

Use: Ornamental plant [1].

Leaves are used as kitchen spice [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

10 [in Russian]

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32 (1971)

A.I. Glushenkova (ed.), Lipids, Lipophilic Components and EssentDOI 10.1007/978-0-85729-323-7, # Springer Science+Business M

Acinos rotundifolius Pers.

Synonyms

A. graveolens (Benth.) Lind.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.12–0.14

Composition of essential oil, %: a-Pinene +

b-pinene – 25.0; camphene + terpinolene +

menthone – 60.0

Activity: Bacteriostatic activity of essential oils.

Use: Source of menthol.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

10 [in Russian]

Agastache foeniculum O. Kuntze.

Family: Lamiaceae

Seed

Oil, % dry wt: 32.11 (China); 40.73 (Russia)

Iodine value, % J2: 187.18–189.92

ial Oils from Plant Sources,edia, LLC 2012

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Lamiaceae 390 Agastache nepetoides (L.) Kuntze.

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Agastache nepetoides (L.) Kuntze.

Family: Lamiaceae

Plant Material

Terpenoids

Composition, %: Germacrene D – 48.3;

caryophyllene – 18.4; trans-ocimene – 3.6

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton,

L.S. Gill, Phytochemistry 11, 2636 (1972)

Agastache rugosa (Fisch. et Mey.)O. Kuntze

Synonyms

Liphanthus rugosus Fisch. et Mey.

Family: Lamiaceae

Essential oil, % dry wt: 0.14–0.39 [1]

Components, %: a-Pinene, b-pinene, (+)-limonene,

p-cymol, octanone-3, octan-3-ol, octene-3-ol,

linalool, b-caryophyllene, a-elangene, b-elemene, b-humulene, b-farnesene, g-cadinene,d-cadinene, calamenene, methyl eugenol and

others [1]

Inflorescence

Essential oil, % dry wt: 1.5 [2]

Leaf

Essential oil, % dry wt: 2.5–3.05 [1, 2]; 0.65 [3]

Seed

Oil, % dry wt: 17.35–21.42 [1]; 33.0–33.7 [3]

Iodine value, % J2: 194.27–196.84 [1]

Stem

Essential oil, % dry wt: 0.45 [1]; 0.1 [2]

Components, %: Methylhavicol – 89.5; octanone –

3.04; a-limonene – 2.0; and others [2]

Activity: Sedative [1]

Use: As drug agent “huo hsiang” in China [1]. Leaves

may be used as aromatic plant material [1]. Essential

oil may be used in perfume and as flowering agent [1].

Herbal may be used as flavoring agent in food [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 10 [in Russian]

2. N.I. Suprunov, P.G. Gorov, Yu. A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 127

[in Russian]

3. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Agastache urticifolia (Benth.) O. Kuntze.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.4 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 32.0 [1]

n40D : 1.4745

Iodine value (Wijs), % J2: 186.0; 196.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.0; 18:0� 1.3; 18:1� 16.0; 18:2� 24.0; 18:3�55.0; others (3) � 0.9

IR

Use: As aromatic agent for food, perfume, and cos-

metic industry [2].

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 100 [in

Russian]

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Ajuga chamaepitys subsp. chia var. ciliata 391 Lamiaceae

Ajuga bombycina Boiss.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), %: 0.1 (from air dried

material, Turkey)

Composition of essential oil (GC/MS, CP Sil 5CB),

%: trans-2-Hexenal – 0.1; a-thujene – 3.9; a-pinene – 18.5; camphene – 0.4; verbenene –

0.1; sabinene –0.9; b-pinene – 28.2; 2-

amylphurane – 0.2; myrcene – 0.7; a-phellandrene – 0.3; p-cymene – 0.3; b-phellandrene + limonene – 6.9; (Z)-b-ocimene

– tr; (E)-b-ocimene – 0.1; g-terpinene – 0.1;

terpinolene – 0.7; nonanal + linalool – l0.7; b-thujone – 0.1; a-campholene aldehyde – 0.6; cis-limonene oxide – 0.1; trans-limonene oxide –

0.1; trans-pinocarveol – 1.5; trans-verbenol –

1.1; pinocarvone – 2.6; terpinen-4-ol – l–tr;

myrtenol – 2.1; myrtenol – 0.1; verbenone –

0.3; decanal – 0.1; dodecane – 0.1; thymol –

2.3; carvacrol – 5.8; tridecane – 0.1; a-copaene– 0.5; b-bourbonene – 1.7; b-cubebene – 0.5; b-caryophyllene – 0.5; (E)-geranyl acetone – 0.3;

guajene – 0.1; a-humulene – 0.1; g-muurolene –

0.1; germacrene D – 8.5; bicyclogermacrene –

1.4; b-bisabolene + g-cadinene – 0.1; d-cadinene– 0.2; germacrene B – 0.9; germacrene D-4-ol –

1.1; caryophyllene oxide – 0.4; a-cedrol – 0.2;

hexahydrofarnesyl acetone – 1.0; hexadecanoic

acid – 0.1

References

1. K.H.C. Baser, M. Kurkcuoglu, F.Z. Erdemgil, Chem. Nat.

Comp. 37(3), 242 (2001)

Ajuga chamaepitys

Family: Lamiaceae

Herb

Essential oil, % dry wt: tr [1]

Activity: Antibacterial activity [2].

Use: Diuretic and hemostatic agent [2].

References

1. N. Tanker, F. Ilisulu, M. Koyuncu, M. Coskun, Int. J. Crud

Drug Res. 24(4), 177 (1986); K.H.C. Baser, M. Kurkcuoglu,

F.Z. Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

11 [in Russian]

Ajuga chamaepitys subsp. chia var. chia

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.3 [1]

Components, %: b-Caryophyllene – 24.4

Herb

Essential oil, % dry wt: 0.046 [2]

Components, %: b-Pinene – 20.8; germacrene-D –

12.6

References

1. F. Mericli, A.H. Mericli, Y. Korkmas-Alp, P. Yilmaz, Acta

Farm Turcica 36(1), 177 (1994); K.H.C. Baser,

M. Kurkcuoglu, F.Z. Erdemgil, Chem. Nat. Comp. 37, 242

(2001)

2. K.H.C. Baser, F.Z. Erdemgil, T. Ozek, B. Demirci, J. Essen-

tial oil Res. 11, 203 (1999); K.H.C. Baser, M. Kurkcuoglu,

F.Z. Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

Ajuga chamaepitys subsp. chia var. ciliata

Family: Lamiaceae

Herb

Essential oil, % dry wt: 0.086

Components, %: Germacrene D – 14.6; b-pinene –14.0

References

1. K.H.C. Baser, Z. Erdemgil, T. Ozek, B. Demirci, J. Essential

oil Res. 11, 203 (1999); K.H.C. Baser, M. Kurkcuoglu, F.Z.

Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

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Lamiaceae 392 Ajuga chamaepitys subsp. cuneatifolia

Ajuga chamaepitys subsp. cuneatifolia

Family: Lamiaceae

Herb

Essential oil, % dry wt: 0.1–0.4

References

1. N. Tanker, F. Ilisulu, M. Koyuncu, M. Coskun, Int. J. Crud

Drug Res. 24(4), 177 (1986); K.H.C. Baser, M. Kurkcuoglu,

F.Z. Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

Ajuga chamaepitys subsp. laevigata

Family: Lamiaceae

Herb

Essential oil, % dry wt: 0.1–0.4

References

1. N. Tanker, F. Ilisulu, M. Koyuncu, M. Coskun, Int. J. Crud

Drug Res. 24(4), 177 (1986); K.H.C. Baser, M. Kurkcuoglu,

F.Z. Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

Ajuga chamaepitys subsp. mesogitana

Family: Lamiaceae

Herb

Essential oil, % dry wt: 0.1–0.4

References

1. N. Tanker, F. Ilisulu, M. Koyuncu, M. Coskun, Int. J. Crud

Drug Res. 24(4), 177 (1986); K.H.C. Baser, M. Kurkcuoglu,

F.Z. Erdemgil, Chem. Nat. Comp. 37, 242 (2001)

Ajuga chia (Poir.) Schreb.

Synonyms

Ajuga chamaepitys Auct.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.01 [1]

Triterpenoic acids: Ursolic acid [1]

Seed and Pericarp

Mass of 1,000, g: 1.7 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 21.0 [2]

n40D : 1.4705

Iodine value (Wijs), % J2: 147; 149 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.8; 18:0 – 2.4; 18:1 – 22.0; 18:2 – 58.0; 18:3 –

11.0; others (3) – 0.1

IR

Seed

Oil, % dry wt: 17.4 [1]

Iodine value, % J2: 131.2 (cald) [3]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.6; 18:0 – 1.6; 18:1 – 16.1; 18:2 – 55.7; 18:3 –

21.9 [3]

Activity: Anti-inflammatory and hemostatic activi-

ties [4].

Use: Ornamental plant [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

11 [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

4. I. E. Akopov, Krovoostanavlivayushchie rasteniya (Fan,

Tashkent, 1990), p. 267 [in Russian]

Ajuga genevensis L.

Family: Lamiaceae

Sterols, % dry wt: 0.08 [1]

Terpenoids

Phytol, % dry wt: 0.06 [1]

Activity: Anti-inflammatory, hemostatic, and anti-

malarial activities [2].

Use: Ornamental plant [2].

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Amaracus dictamnus Benth. 393 Lamiaceae

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

12 [in Russian]

Ajuga iva (Poir.) Schreb.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.4

Oil (petroleum ether, 30–60�C), % dry wt: 18.0

n40D : 1.4691

Iodine value (Wijs), % J2: 144.0; 144.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.2; 18:0 – 3.1; 18:1 – 24.0; 18:2 – 53.0; 18:3 –

12.0; others (5) – 0.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ajuga laxmanii (L.) Benth.

Family: Lamiaceae

Sterols, % dry wt: 0.06 [1]

Terpenoids

Phytol, % dry wt: 0.07 [1]

Use: As antimalarial, antitumor agent in folk

medicine [2].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

12 [in Russian]

Ajuga reptans L.

Family: Lamiaceae

Sterols, % dry wt: 0.07 [1]

Terpenoids

Phytol, % dry wt: 0.05 [1]

Leaf

Hexadeca-7,10,13-trienoic acid, % total lipids:

0.2% [2]

Use: As anti-inflammatory antiseptic hemostatic-

tumor agent in folk medicine. Leaves are used as

vegetables [3].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. G.R Jamieson, E.H. Reid, Phytochemistry 10(8), 1837 (1971)

3. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

13 [in Russian]

Amaracus akhdarensis (Ietswaart etBoulos) Brullo et Furnari

Synonyms

Origanum akhdarensis

Family: Lamiaceae

Aerial Part

Extract (acetone)

Components (CC): Hydrocarbons, fats, waxes,

triterpenes, and diterpenes

Triterpenoic acids, g (from 269 g aerial part):

Oleanolic and ursolic acids – 2.0

References

1. S. Passannanti, M. Paternostro, F. Piozzi, J. Nat. Prod. 47, 885

(1984)

Amaracus dictamnus Benth.

Synonyms

Origanum dictamnus L.

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Lamiaceae 394 Amaracus pampanini Brullo et Farnari

Family: Lamiaceae

Flower

Extract (acetone)Triterpenoids (CC), g (from 50 g flowers): Methyl 3b-

dihydro-olean-12-en-28-oate + methyl 3b, 21a-dihydroxy-urs-12-en-28-oate – 15.0; uvaol – 10.0

Triterpenoic acids: Oleanolic acid, ursolic acid

Leaves and Stems

Extract (acetone), g (from 800 g leaves and stems):

58.0

Triterpenoic acids (CC), g: Oleanolic acid + ursolic

acids – 3.0; methyl 3b-dihydro-olean-12-en-28-oate – 0.11; methyl 3b, 21a-dihydroxy-urs-12-en-28-oate – 0.024

Methyl 3b-dihydro-olean-12-en-28-oate

M.p, [a]D, MS, 13C NMR

Methyl 3b, 21a-dihydroxy-urs-12-en-28-oateM.p, [a]D, MS, 13C NMR

References

1. F. Piozzi, M. Paternostro, S. Passannanti, E. Gacs-Baitz, Phy-

tochemistry 25, 539 (1986)

Amaracus pampanini Brullo et Farnari

Family: Lamiaceae

Aerial Part

Extract (acetone)Components (CC): Hydrocarbons, fats, waxes,

triterpenes and diterpenes

Triterpenoic acids, g (from 269 g aerial part):

Oleanolic + ursolic acids – 2.0; uvaol – 0.05

References

1. S. Passannanti, M. Paternostro, F. Piozzi, J. Nat. Prod. 47, 885

(1984)

Amethystea caeruleae L.

Family: Lamiaceae

Seed

Mass of 1,000 seeds, g: 0.6

Oil, %: 23.0

n40D : 1.4764

Iodine value, % J2: 185; 187 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.3; 18:0 – 2.0; 18:1 – 13.0; 18:2 – 35.0; 18:3 –

44.0; others (5) – 0.8

IR: Usually (methyl esters)

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Anisomeles indica (L.) O. Kuntze.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4680

Iodine value (Wijs), % J2: 130.0; 134.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

10.0; 18:0 – 4.0; 18:1 – 16.0; 18:2 – 68.0 18:3 –

0.8; others (2) – 0.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Anisomeles ovata

Family: Lamiaceae

Seed

Moisture, %: 7.2

Oil (petroleum ether, 40–60�C), % dry wt: 19.0

n33D : 1.4769

Iodine value (Wijs), % J2: 130.0

Saponification value, mg KOH: 190.0

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Arischrada korolkowii (Regel et Schmalh.) Robed 395 Lamiaceae

FAs

Composition (GLC, 15% DEGS and 2% SE-30), %:

16:0 – 14.7; 18:0 – 3.0; 18:1 – 20.8; 18:2 – 61.5

References

1. S.K. Husain, M.U. Ahmad, S. Sinha, A.A. Ansari, S.M.

Osman, Fette, Seifen, Anstrichmittel 80(6), 225 (1978)

Arischrada bucharica M. Pop.

Family: Lamiaceae

Essential oil, % dry wt: 0.025–0.17

Aerial Part

Essential oil, % dry wt: 0.12–0.25

Flower

Essential oil, % dry wt: 0.045–0.8

Leaf

Essential oil, % dry wt: 0.14–0.25

Stem

Essential oil, % dry wt: 0.05

Use: The plant is of importance as a flavoring agent in

the food industry.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

14 [in Russian]

Arischrada dracocephaloides Boriss.

Family: Lamiaceae

Aerial part

Essential oil (hydrodistillation), % dry wt: 0.9–1.4 (at

flowering stage)

Acid value, mg KOH: 4.48

Ester value, mg KOH: 21.04

Ester value after acetylated, mg KOH: 59.07

Composition of essential oil (GLC), %: a-Pinene –4.9; camphene – 8.5; b-pinene – 5.0; a-terpinene– 31.5; limonene – 0.6; 1,8-cineole – 0.5; cam-

phor – 38.7; linalool – 2.3; borneol – 0.5; anethol

– 0.5; a-terpineol – 0.7; iso-eugenol – 0.5; euge-nol – 0.7; thymol – 0.6; unidentifieds – 4.5

Monoterpene hydrocarbons, %: 50.5

Oxygenated components, %: 15.0

References

1. S.A. Mamedova, Chem. Nat. Comp. 33, 593 (1997)

Arischrada korolkowii (Regel etSchmalh.) Robed

Synonyms

Salvia korolkowii Regel et Schmalh.; Schraderiakorolkowii Regel et Schmalh Robed.

Family: Lamiaceae

Aerial Part

Lipids (chloroform–methanol, 2:1 v/v), % dry wt: 7.27

[1]

Composition of lipids (CC), %: Hydrocarbons +

carotenes – 12.0; esters of alcohols + triterpenols

+ sterols – 11.5; TAG – 11.4; free FAs – 8.5;

alcohols + triterpenols + sterols + components of

essential oil – 11.2; triterpenoic acids – 0.5; GL –

31.0; PhL – 0.8; chlorophylls + pheophytenes +

unidentified components – 13.1 [1]

TAG

FAs (GLC, 15% Reoplex 400), %: 12:0 – 0.4; 14:0

– 4.2; 15:0 – 0.2; 15:1 – 0.8; 16:0 – 28.1; 16:1 –

tr; 17:0 – 0.8; 17:1 – 0.9; 18:0 – 8.0; 18:1 – 12.8;

18:2 – 22.0; 18:3 – 21.8; 20:0 – tr

Free FAs

Composition (GLC), %: 12:0 – 0.4; 14:0 – 0.9; 15:0

– 0.7; 15:1 – tr; 16:0 – 54.8; 16:1 – tr; 17:0 – 1.7;

17:1 – tr; 18:0 – 13.5; 18:1 – 16.6; 18:2 – 1.0;

18:3 – 1.9; 20:0 – 8.5

GL

FAs (GLC), %: 14:0 – 1.3; 16:0 – 51.9; 16:1 – tr;

17:0 – tr; 18:0 – 5.0; 18:1 – 19.5; 18:2 – 8.6; 18:3

– 13.7; 20:0 – tr

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Lamiaceae 396 Ballota acetabulosa Benth.

Essential oil (hydrodistillation), %: 1.1 (Chatkal

mountains of Uzbekistan) [2]

Composition of essential oil (GC/MS, HP-Innowax

FSC), %: Tricyclene – 0.1; a-pinene – 2.5; a-thujene – 0.2; camphene – 3.4; b-pinene – 2.3;

sabinene – 0.1; myrcene – 0.3; p-mentha-1,7(8)-

diene – tr; a-terpinene – tr; dehydro-1,8-cineole

– 0.2; limonene – 3.3; 1,8-cineole – 29.3; isomyl

alcohol – tr; g-terpinene – 0.1; p-cymene – 1.6;

terpinolene – tr; 6-methyl-5-hepten-2-one – tr; a,p-dimethylstyrene – 0.1; trans-sabinene hydrate

– 0.2; (E,Z)-2,4-heptadienal – tr; a-copaene – tr;

a-compholene aldehyde – tr; (E,E)-2,4-heptadienal – tr; camphor – 9.8; linalool – 0.1;

cis-sabinene hydrate – 0.2; trans-p-menth-2-en-

1-ol – 0.1; pinocarvone – 0.2; bornyl acetate –

7.7; terpinen-4-ol – 1.2; b-caryophyllene – 8.5;

4-terpinenyl acetate – 0.1; cis-p-menth-2-en-1-ol

– 0.1; myrtenal – 0.3; pulegone – 0.1; phenylace-

taldehyde – tr; trans-pinocarveol – 0.7; p-

mentha-1,5-dien-8-ol – tr; trans-p-mentha-2;8-

dien-1-ol – tr; d-terpineol – 1.4; trans-verbenol– 0.4; a-humulene – 0.4; a-terpineol – 2.4; bor-

neol – 5.6; verbenone – 0.1; trans-p-menth-2-en-

1;8-diol – 0.1; carvone – 0.1; cis-piperitol – 0.1;

g-cadinene – 0.1; cis-p-menth-2-en-1,8-diol –

0.1; myrtenol – 0.2; trans-carveol – 0.2; cis-

calamenene – 0.1; geraniol – tr; p-cymen-8-ol –

0.2; (E)-geranyl acetate – tr; cis-carveol – 0.1;

cis-p-mentha-1(7);8-diene-2-ol – tr; geranyl

butyrate – tr; cubebol-(E)-12-norcaryophyll-5-en-2-one – 0.1; isocaryophyllene oxide – tr;

caryophyllene oxide – 7.2; perilla alcohol – 0.3;

methyl eugenol – tr; salvial-4(14)-en-1-one – tr;

humulene epoxide 1 – 0.1; humulene epoxide 2 –

0.5; cubenol – tr; globulol – tr; cumin alcohol –

tr; spathulenol – 0.3; isothymol (2-isopropyl-4-

methylphenol) – 0.1; eugenol – tr; thymol – 0.2;

t-muurolol – tr; isocarvacrol (4-isopropyl-2-

meyhylphenol) – 0.4; carvacrol – 0.2; elemicin

– tr; a-eudesmol – 0.1; b-eudesmol–0.4; (2Z,6Z)-

farnesol – tr; caryophylla-2(12);6(13)-dien-5b-ol – 0.3; caryophylla-2(12),6(13)-dien-5a-ol –1.3; abietatriene – tr; hexadecanoic acid – 0.1;

caryophylla-2(12),6-dien-5a-ol – 0.8;

caryophylla-2(12),6-dien-5b-ol – 1.0

Activity: The essential oil has bactericidal

properties [3].

Tincture prepared from roots and leaves exhibited

antibacterial activity [4].

References

1. D.T. Asilbekova, Chem. Nat. Comp. 40, 597 (2004)

2. K.H.C. Baser, T. Ozek, H.R. Nuriddinov, B. Demirci, Chem.

Nat. Comp. 38(1), 51 (2002)

3. I.V. Rakhimova, N.Z. Alimkhadjaeva, Izuchenieantimikrobnykh svoystv chetyrekh vidov shalfeya (Naukova

Dumka, Kiev, 1973), p. 36 [in Russian]

4. N.Z. Alimkhadjaeva, Author’s Abstract of Candidate’s Dis-

sertation (Lvov, 1974), p. 17 [in Russian]

Ballota acetabulosa Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 38.0

n40D : 1.4675

Iodine value (Wijs), % J2: 114.0; 114.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

10.0; 18:0 – 4.0; 18:1 – 16.0; 18:2 – 68.0; 18:3 –

0.8; others (2) – 0.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ballota hispanica (L.) Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4

Oil (petroleum ether, 30–60�C), % dry wt: 37.0

n40D : 1.4676

Iodine value (Wijs), % J2: 112.0; 111.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.7; 18:0� 3.2; 18:1� 32.0; 18:2� 41.0; 18:3�0.8; others (6) � 1.6

IR

Page 9: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Betonica foliosa Rupr. 397 Lamiaceae

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ballota nigra L.

Family: Lamiaceae

Essential oil, % dry wt: 0.01

Seed

Oil

Iodine value, % J2: 158.0

FAs

Composition, %: 16:0 – 6.2; 18:0 – 1.4; 18:1 – 19.3;

18:2 – 70.8; 18:3 – 2.3

Activity: Antibacterial activity.

Use: Ornamental plant.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

14 [in Russian]

Ballota nigra L. ssp. ruderalis (Sw.) Briq.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.1

Oil (petroleum ether, 30–60�C), % dry wt: 35.0

n40D : 1.4688

Iodine value (Wijs), % J2: 120.0; 119.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.5; 18:0 � 2.8; 18:1 � 24.0 18:2–48.0; 18:3 �1.2; others (8) � 1.7

Allenic acid, %: 15.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Betonica alopecuros L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4

Oil (petroleum ether, 30–60�C), % dry wt: 26.0

n40D : 1.4689

Iodine value (Wijs), % J2: 127.0; 129.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.7; 18:0� 3.0; 18:1� 26.0; 18:2� 55.0; 18:3�1.7; others (6) � 0.3

Allenic acid, %: 8.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Betonica foliosa Rupr.

Synonyms

Stachys betonicaeflora Rupr.; S. betonicaefolia Rgl.

Family: Lamiaceae

Essential oil, % dry wt: 0.035–0.82 [1]

Aerial Part

Essential oil, % dry wt: 0.12–0.83 [1]

Seed

Oil, % dry wt: 42.0 [1]

Iodine value, mg KOH: 187.4 [1]

FAs

Composition (GLC, mol %, 10% PEGA): 16:0 –

1.2; 18:0 – 0.3; 18:1 – 23.5; 18:2 – 74.1; 18:3 –

0.9 [1, 2]

Activity: Extracts have sedative, hemostatic, hypo-

tensive, cardiotonic, expectorant properties [1]

Use: Ornamental and honey bearing plant [1]

Page 10: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 398 Betonica grandiflora Willd.

References

1. G. V. Novitzkaya, V. I. Krishtopa, Rast. Resursy. 7(1), 32

(1971), [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 15 [in Russian]

Betonica grandiflora Willd.

Family: Lamiaceae

Seed

Oil, % dry wt: 30.7 [1]

Iodine value, % J2: 105.6 [1]; 152.9 (cald) [2]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �5.6; 18:0� 1.3; 18:1� 25.8; 18:2� 65.4; 18:3�1.9 [2]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Betonica officinalis L.

Synonyms

B. bielorussica Kossko ex Klok.; B. brachyodontaKlok.; B. fusca Klok.; B. peraucta Klok.; B. vulgaris

Rota; Stachys betonica Benth.; S. officinalis (L.)

Trevis.

Family: Lamiaceae

Essential oil, % dry wt: 0.028–0.058 [1]

Sterols, % dry wt: 0.01 [2]

Terpenoids

Phytol, % dry wt: 0.02 [2]

Flower

Essential oil, %: 0.03–0.05 [2]

Seed

Mass of 1,000, g: 1.40 [3]

Oil, % dry wt: 42.0 [2, 3]; 19.0–42.0 [4]

d20: 0.9251 [3]

Acid value, mg KOH: 6.41 [3]; 5.8 [4]

Сolor: 0862/2 [3]

Iodine value, % J2: 132.0–153.0 [4]; 153.0–158.4

[2, 5]

Saponification value, mg KOH: 198.0 [4]

FAs

Composition (GLC), %: 16:0 – 3.6; 18:0 – 1.4;

18:1(9) – 17.3; 18:1(6) – 1.3; 18:2 – 69.3; 18:3

– 1.4; others – 5.8, (FFAP) [3]

16:0 – 4.7; 18:0 – 2.1; 18:1 – 20.9; 18:2 – 69.5; 18:3

– 2.8 (mol %, 10% PEGA) [2, 5]

Activity: Antibacterial and antifungal properties [2].

Use: Tincture is used as hypotensive, sedative, anti-

inflammatory, antituberculosis, and diuretic agent in

folk medicine [2].

Ornamental plant [2].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

16 [in Russian]

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

4. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

5. G.V. Novitzkaya, V.I. Krishtopa, Rastitel’nye Resursy 7(1),

32 (1971) [in Russian]

Brazoria scutellarioides Engelm andGray.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 36.0

n40D : 1.4707

Iodine value (Wijs), % J2: 134.0; 136.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.7; 18:0� 2.0; 18:1� 30.0; 18:2� 14.0; 18:3�27.0; others (6) � 1.6

Allenic acid, %: 19.0

IR

Page 11: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Calamintha nepeta (L.) Savi subsp. glandulosa (Req.) P.W. Ball. 399 Lamiaceae

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Calamintha clinopodium Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4765

Iodine value (Wijs), % J2: 205.0; 206.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.6; 18:0 � 2.6; 18:1 � 7.3; 18:2� 25.0; 18:3�60.0; others (6) � 0.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Calamintha nepeta (L.) Savi ssp.glandulosa (Req.) P. W.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation in a semimicro Likens-

Nickerson apparatus, France)

Сomposition (GLC and GC/MS, WCOT and

FSOT SE 52), %: a-Pinene � 0.3; sabinene �0.2; b-pinene � 0.3; myrcene � 0.8; octan-3-ol

� 1.3; a-terpinene � tr; limonene � 5.5; cis-b-ocimene � tr; trans-b-ocimene � tr; g-terpinene� 0.1; trans-sabine hydrate � 0.4; cis-sabine +

methone � 12.1; isomethone � 0.6; neomenthol

+ terpinen-4-ol � 4.1; menthol � 0.5; isomethol

+ a-terpineol� 0.1; pulegone� 68.0; piperitone

oxide� 1.1; menthyl acetate� 0.1; piperitenone

� 1.6; piperitenone oxide � 0.5;

b-caryophyllene � 0.2; germacrene-D � 0.7

References

1. H.L. De Pooter, P. Goetghebeur, N. Schamp, Phytochemistry

26(12), 3355 (1987)

Calamintha nepeta (L.) Savi ssp. nepeta

Family: Lamiaceae

Aerial Part

Essential oil (by hydrodistillation in a semimicro

Likens-Nickerson apparatus, France)

Composition (GLC and GC/MS, WCOT and FSOT

SE 52), %: a-Pinene � 0.2–0.6; sabinene � 0.1–

0.4; b-pinene � 0.2–0.8; myrcene � 0.3–0.9;

octan-3-ol � 0.1–0.2; a-terpinene � tr � 0.4;

limonene � 0.7–4.6; cis-b-ocimene � 0.1–0.8;

trans-b-ocimene � tr � 0.2; g-terpinene � 0.2–

0.9; trans-sabinene hydrate � 0.1–2.4;

terpinolene � tr � 0.2; cis-sabine hydrate � tr

� 0.1; menthone� 4.9–8.9; isomenthone� 0.2–

6.7; neomenthol + terpinen-4-ol� 1.5–5.4; men-

thol � 1.4–7.5; isomenthol + a-terpineol � 0.5–

0.9; pulegone � 11.5–33.2; piperitone oxide �8.4–17.0; isopiperitenone � 0.5–0.6;

neomenthyl acetate � 0.6–1.9; menthyl acetate

� 0.7–2.5; 4-hydroxypiperitone � 0.1–1.4;

isomenthyl acetate + piperitenone � 0.4–3.8;

piperitenone oxide � 5.9–37.8; b-caryophyllene� 1.4–6.2; a-humulene + b-farnesene� 0.2–0.6;

germacrene-D � 0.6–1.6; a-elemene � 0.1–0.6

References

1. H.L. De Pooter, P. Goetghebeur, N. Schamp, Phytochemistry

26(12), 3355 (1987)

Calamintha nepeta (L.) Savi subsp.glandulosa (Req.) P.W. Ball.

Family: Lamiaceae

Plant Material

The headspace (Steam distillation), % fresh wt: 0.1–

0.3 (from the top with leaves and flowers)

Page 12: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 400 Calamintha nepetoides Jord.

Composition (GC/MS, OV-1), %: Methyl 2-

methylbutanoate – 0.7; a-thujene – 1.2; a-pinene– 4.4; camphene – 0.6; sabinene – 3.5; b-pinene –2.7; myrcene – 1.9; a-phellandrene + octan-3-ol –

4.4; a-terpinene – 1.2; b-cymene – 0.7; 1,8-cineole

– 0.1; limonene – 15.3; g-terpinene – 2.3; trans-

sabinene hydrate – 1.2; terpinolene – 0.8; cis-sabinene hydrate – 1.0; dihydrocarvone – 0.6;

piperitone oxide – 25.4; dihydrocarvyl acetate 1

–3.4; dihydrocarvyl acetate 2 – 0.8; piperitenone

oxide –1.6; b-caryophyllene – 5.4; a-humulene –

0.7

Essential oilComposition (GC/MS, OV-1), %: a-Thujene – tr; a-

pinene –0.1-0.4; camphene – tr; sabinene – 0.1–

0.4; b-pinene – 0.1–0.4; myrcene – 0.2–0.5; a-phellandrene + octan-3-ol – 0.6–2.4; a-terpinene– tr; b-cymene – 0.1–0.5; 1;8-cineole – tr.; lim-

onene – 0.7–4.3; g-terpinene – 0.3–1.0; trans-sabinene hydrate – 0.6–1.7; terpinolene – tr –

0.3; cis-sabinene hydrate – 0.3–1.2; terpinen-4-

ol – 0.9–4.9; dihydrocarvone – tr – 0.5; a-terpineol – tr – 0.4; piperitone oxide – 30.7–

74.2; 4-hydroxypiperitone – 0.6–15.9;

dihydrocarvyl acetate 1 – 0.5–3.6; dihydrocarvyl

acetate 2 – tr – 0.9; piperitenone oxide – 5.2–

52.0; b-caryophyllene – 0.7–2.3; a-humulene –

tr – 0.1; germacrene-D – 0.1–1.2

References

1. H.L. De Poorter, L.F. De Buyck, N.M. Schamp, Phytochem-

istry 25, 691 (1986)

Calamintha nepetoides Jord.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 38.0

n40D : 1.4758

Iodine value (Wijs), % J2: 196.0; 204.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.5; 18:0� 2.3; 18:1� 13.0; 18:2� 20.0; 18:3�61.0; others (4) � 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Chaiturus marrubiastrum (L.) Reichb.

Family: Lamiaceae

Sterols, % dry wt: 0.05

Terpenoids

Phytol, % dry wt: 0.04

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

Cleonia lusitanica L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 24.0

n40D : 1.4756

Iodine value (Wijs), % J2: 195.0; 205.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.4; 18:0 � 2.3; 18:1 � 15.0; 18:2� 9.7; 18:3�67.0; others (6) – 1.1

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Clinopodium integerrimum Boriss.

Family: Lamiaceae

Essential oil, % dry wt: 0.24

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

19 [in Russian]

Page 13: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Coridothymus capitatus (L.) Reichenb. fil. 401 Lamiaceae

Clinopodium vulgare L.

Family: Lamiaceae

Herb

Extract (petrol), % dry wt: 2.0 [1]

Waxes, %: 0.44 [1]

FAs of waxes, %: 0.1 [1]

Composition (GLC, 20% Reoplex 400), %: 14:0 �1.37; 16:0� 30.0; 18:0� 3.39; 20:0� tr; 18:1�10.62; 18:2� 21.6; 18:3� 29.63; others� 2.4 [1]

n-Triacontane, %: 0.098 [1]

M. p.

Sterols, % dry wt: 0.07 [2]

a-SpinasterolM.p. (acetate, benzoate) [1]

Terpenoids

Phytol, % dry wt: 0.04 [2]

Triterpenoic acids, % dry wt: Ursolic acid –

1.40 [2]

Betulin

M.p. [1]

b-Amyrin [2]

Aerial Part

Essential oil, % dry wt: 0.09 [3]

FAs

Components: 12:0; 14:0; 16:0; 18:0; 20:0; 18:1;

18:1(3); 18:2; 18:3 [3]

Leaf

Triterpenoic acids, % dry wt: Ursolic acid – 1.6 [3]

Seed

Oil (hexane) [4]

Iodine value, % J2: 230.7 (cald) [4]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �3.7; 18:0 � 1.7; 18:1 � 7.2; 18:2� 25.3; 18:3�62.1 [4]

Activity: Ether extracts have antibacterial property

[3].

Use: As fodder grass [3].

References

1. B. Broda, M. Krolikowska, B. Kostka, Acta Polon. Pharm.

31(2), 213 (1974)

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

3. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

19 [in Russian]

4. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Collinsonia canadensis L.

Family: Lamiaceae

Plant Material

TerpenoidsComposition, %: Germacrene D – 46.0;

caryophyllene – 5.3; elemicin – 3.6; b-elemene –

3.3

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Coridothymus capitatus (L.) Reichenb. fil.

Synonyms

Thymus capitatus (L.) Hoffm and Link; Satureja

capitata L.

Family: Lamiaceae

Essential oil (steam distillation), % v/w: 0.6 (Fresh

plant material, wild, from Israel) [1]

Main components (GLC, 5% Carbowax 20 M and

6%OV 17; GC/MS on OV 1), %: a-Pinene – 2.9;camphene – 0.3; b-pinene – 0.3; sabinene – 0.2;

D3-carene – 0.1; myrcene – 3.0; a-terpinene – 3.2;limonene – 0.7; 1,8-cineole – 0.6; g-terpinene –

19.4; p-cymene – 6.0; camphor – tr; linalool – 1.0;

terpinene-4-ol – 0.8; caryophyllene – 5.0; borneol

– 1.2; thymol – 39.3; carvacrol – 12.7 [1]

Aerial Part

Essential oil (Plant when in flower, steam distillation,

2 h), %: 3.2 [2, 3]

Components: (GLC-MS, W WCOT SP-2100,

INCOS data system): a-Pinene, a-thujene,

Page 14: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 402 Coridothymus capitatus (L.) Reichenb. fil.

camphene, b-pinene, D3-carene, myrcene,

a-terpinene, limonene, b-phellandrene,cis-b-ocimene, g-terpinene, b-cymene,

terpinolene, 6-methyl-5-hepten-2-one, 3-

octanol, a,p-dimethylstyrene, 7-octen-4-ol,

unidentified, cis-linalool oxid, furanoid, a-gurjunene, linalool, pulegone, bornyl acetate

(1S-endo), caryophyllene, aromadendrene,

isodihydrocarvone, unidentified, unidentified

mixture of an alcohol and sesquiterpene,

dihydrocarvone, alloaromadendrene, trans-

pinocarveol, dihydrocarveol acetate, a-humulene, neral, a-terpineol, borneol (endo),carvenone, geranial, carvone, naphthalene, d-cadinene, bisabolene, cuminic aldehyde, nerol,

geraniol, p-cymen-8-ol, cis-6,10-dimethyl-5,9-

undecadien-2-one, carvacryl acetate, 4-methyl-

2-(1,1-dimethyl-ethyl)-phenol, unidentified, 1-

(1,4-dimethyl-3-cyclohexen-1-yl)-ethanone, ledol,

unidentified, 4-(1,1-dimethyl-ethyl)-phenol, euge-

nol, thymol, diethyl-phenol, carvacrol, 2-methoxy-

1,3,5-trimethyl–benzene [2]

Main components: Carvacrol, thymol, and their iso-

mers, as well as myrcene, a-terpinene, and

p-cymene [2]

Components (GC/MS, W WCOT SP 2100): 2.5-

Diethyltetrahydrofuran, hexyl acetate and

butylbenzene isomer, methyl hexyl ketone,

bornyl chloride, 1-propenyl-2-methyl-1,3-

cyclohexadiene, a-copaene, sesquiterpene,

isogeranial, sesquiterpene, 4,8-dimethyl-nona-

4,7-dien-2-one, hydrocinnamic aldehyde,

piperitenone, 2-methyl-4-phenyl-2-butyl ace-

tate, g-octalactone, 2-(3-pentyl)-phenol, a-calacorene, ledyl acetate, g-nonalactone and

ledol, g-undelactone, atisirene (at flowering

state) [3]

Bornyl chloride

MS [3]

1-Propenyl-2-methyl-1,3-cyclohexadiene

MS [3]

Mixture of g-octalactone, 2-(3-pentyl)-phenol, and

a-calacoreneMS [3]

Ledyl acetate

MS [3]

Mixture of g-nonalactone and ledol

MS [3]

Atisirene

MS [3]

Phenols, % of oil: 1,0 [4]

Components (MS), %: 5-Methyl-2,4-

diisopropylphenol – more than 90.0; methyl-

2,5-diisopropylphenol, 2,5 diisopropylphenol,

3-methyl-2,5-diisopropylphenol, 5-methyl-2,3-

diisopropylphenol, 3-methyl-2,4 diisopro-

pylphenol [4]

Flowering Herb

Components (GLC,3%OV17),%:Carvacrol<60 [5]

Monoterpene hydrocarbons: a-Thujene, a-pinene,camphene, b-pinene, myrcene, D3-carene, a-phellandrene, a-terpinene, limonene, b-phellandrene, p-cymene (high, 10–20%), g-terpinene, terpinolene [5]

Light oxygenated compounds: 1,8-Cineole, 3-

octanol, 1-octen-3-ol, p-menth-3-en-9-al,

octenyl acetate, fenchone, sabinene hydrate,

thujone, linalool (high, 10–20%), isogeranial,

camphor, cis-3-hexenyl pentanoate, 1-terpinen-4-ol, cis-dihydrocarvone, trans-dihydrocarvone,

d-terpineol, a-terpineol, bornyl acetate, borneol,2-undecanone, 1-terpinen-4-yl acetate [5]

Sesquiterpene hydrocarbons: Isocaryophyllene,

b-caryophyllene (high, 10–20%), trans-

a-bergamoten, aromadendrene, a-humulene,

allo-aromadendrene, g-muurolene, b-bisabolene[5]

Heavy oxygenated compounds: Neral, carvone,

carvenone geranial, b-terpinyl acetate, cis-3-

hexenyl trans-4-hexenoate, carvacryl acetate,

3-methyl-2,6-diisopropyl phenol, caryophyllene

oxide [5]

p-Menth-3-en-9-al

MS [5]

Isogeranial, cis-3-Hexenyl pentanoate

MS [5]

a-Terpineol

MS [5]

cis-3-Hexenyl trans-4-hexenoate

MS [5]

3-Methyl-2,6-diisopropyl phenol

MS, 1H NMR [5]

Seed and Pericarp

Mass of 1,000, g: 0.3 [6]

Page 15: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Dracocephalum bipinnatum Rupr. 403 Lamiaceae

Oil, %: 37 (petroleum ether, 30–60�C, in the Butt

apparatus) [6]

n40D : 1.4761 [6]

Iodine value (Wijs), % J2: 193; 191 (cald.) [6]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.4; 18:0 – 3.0; 18:1 – 12.0; 18:2 – 21.0; 18:3 –

55.0; others (5) – 2.3 [6]

Hydroxy acid (IR) [6]

References

1. V. Ravid, E. Putievsky, Planta Med. 49, 248 (1983)

2. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

3. V.P. Papageorgiou, N. Argyriadou, Planta Med. Suppl. 29

(1980)

4. J.M. Sendra, P. Cunat, Phytochemistry 19, 1513 (1980)

5. J.M. Sendra, P. Cunat, Phytochemistry 19, 89 (1980)

6. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Cyclotrichium leucotrichum (Stapf exRech. fil.) Leblebici

Family: Lamiaceae

Leaf

Essential oil (microdistillation)

Composition of essential oil (GC/MS, HP-Innowax

FSC), %: 3-Hexanone – 0.34; b-pinene – 0.55; 3-hexanol–0.29; limonene–4.13;1,8-cineole–9.26;

g-terpinene – 0.26; p-mentha-3,8-diene – 1.45; p-

cymene – 3.03; 6-methyl-5-hepten-2-one – 0.49; a-fenchone – 5.95; camphor – 11.92; neomethyl ace-

tate – 2.21; methyl acetate – 1.08; bornyl acetate –

0.54; neomenthol – 1.63; b-caryophyllene – 14.14;p-menth-3-en-8-ol – 11.44; octyl butyrate – 0.63;

pulegone – 0.31; a-humulene – 0.66; borneol –

1.53; bicyclogermacrene – 0.90; naphthalene –

3.86; b-cadinene – 0.84; (E)-b-damascenone –

1.35; p-cymen-8-ol – 0.79; (E)-geranyl acetone –

1.37; caryophyllene oxide – 1.41; 1-epi-cubenol –0.29; T-cadinol – 3.81; thymol – 0.76; carvacrol –

2.28; total – 89.5

References

1. K.H.C. Baser, B. Demirci, F. Demirci, N. Kirimer, I.C.

Hedge, Chem. Nat. Comp. 37, 336 (2001)

Cyclotrichium stamineum (Boriss. andHohen.) Manden. and Scheng.

Family: Lamiaceae

Leaf

Essential oil (by microdistillation)

Composition of essential oil (GC/MS, HP-Innowax

FSC), %: a-Pinene – 0.99; b-pinene – 5.52;

g-terpinene – 2.68; p-cymene – 5.25;

pinocamphone – 33.78; isopinocamphone –

13.67; terpinen-4-ol – 7.22; myrtenyl acetate –

9.11; borneol – 1.75; naphthalene – 7.36;

myrtenol – 3.35; carvacrol – 1.99; total – 92.67

References

1. K.H.C. Baser, B. Demirci, F. Demirci, N. Kirimer, I.C.

Hedge, Chem. Nat. Comp. 37, 336 (2001)

Dracocephalum austriacum L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum bipinnatum Rupr.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.02–0.12

Activity: Ethanol extract has hypotensive property.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

19 [in Russian]

Page 16: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 404 Dracocephalum botryoides Stev.

Dracocephalum botryoides Stev.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.6–0.64

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum diversifolium Rupr.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.0–0.63

Use: Recommended as sedative agent.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

16 [in Russian]

Dracocephalum foetidum Bunge

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.46–1.0

Activity: Essential oil has antibacterial and antifun-

gal activity.

Use: Fodder grass for camel.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6 20

[in Russian]

Dracocephalum fruticulosum Steph.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.18–0.32

Composition of essential oil, %: Limonene + 1,8-

cineol – 62.0; linalool � 8.0–11.0; trans-pinocamphone � 8.0–10.0; a-pinene, b-pinene,myrcene, carvon, a-terpeneol

Use: Fodder grass for camel.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

20 [in Russian]

Dracocephalum heterophyllum Benth.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.03–0.37

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum imberbe Bunge

Family: Lamiaceae

Flower

Essential oil, % dry wt: 1.0

Leaf

Essential oil, % dry wt: 0.25

Activity: Essential oil showed antibacterial

activity.

Page 17: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Dracocephalum kotschyi 405 Lamiaceae

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991) 6, 23

[in Russian]

Dracocephalum integrifolium Bunge

Family: Lamiaceae

Aerial part

Essential oil, % dry wt: 0.08–0.15 [1]

Seed

Moisture, %: 7.98 [2]

Oil (petroleum ether, 40–50�C), % dry wt: 3.72 [2]

Iodine value (Kaufmann), % J2: 156.2 [2]

IR, UV [2]

FAs

IR, UV [2]

Iodine value (Kaufmann), % J2: 161.4 [2]

Conjugated dienes, %: 0.21 [2]

Activity: Ethanol extract is hypotensive [2].

Ether extract and essential oil have antibacterial

property [2].

References

1. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 8, 23

(1972)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

20 [in Russian]

Dracocephalum kotschyi

Family: Lamiaceae

Aerial Part

Essential oilComposition, %: a-Pinene – 12.2; camphene – 0.2;

2,4 (10)-thujadiene – 0.2; sabinene – 3.0; b-pinene – 0.8; b-myrcene – 2.3; p-mentha-

1(7),8-diene – 0.8; a-terpinene – 0.2; p-cymene

– 1.0; limonene – 7.2; b-phellandrene – 3.9;

(Z)-b-ocimene – 8.6; (E)-b-ocimene – 0.8; g-terpinene – 0.6; trans-sabinene hydrate – 0.4;

cis-linalool oxide – 0.2; terpinolene – 0.8; cis-

sabinene hydrate – 0.4; linalool – 1.0; 1-octen-3-

yl acetate – 0.1; 6-camphenol – 1.2; trans-p-2-

menthen-1-ol – 0.1; cis-p-2-mentha-2,8-dien-1-

ol – 0.2; trans-limonene oxide – 0.3; neo-allo-

ocimene – 1.0; trans-verbenol – 1.4;

pinocarvone – 0.2; 3-thujanol – 0.8; terpinen-4-

ol – 2.0; myrtenal – 0.2; a-terpineol – 0.1;

verbenone – 0.3; trans-carveol – 0.5; cumine

aldehyde – 0.2; neral – 6.6; geraniol – 0.1;

geranial – 5.1; bornyl acetate – 0.7; methyl

geranate – 11.2; trans-neryl acetate – 0.2; (Z)-

b-damascenone – 0.2; geranyl acetate – 4.1; b-bourbonene – 0.5; b-elemene – 0.6; (E)-

caryophyllene – 0.5; a-humulene – 0.1; allo-

aromadendrene – 1.1; germacrene D – 5.7;

bicyclogermacrene – 0.7; germacrene A – 0.2;

d-cadinene – 0.3; spathulenol – 0.7;

caryophyllene oxide – 0.2; humulene epoxide II

– 0.2; 10-epi-g-eudesmol – 0.4; heptadecane –

0.1; (E,E)-farnesol – 0.5

Composition, %: a-Pinene – 15.0; camphene – 0.2;

2,4 (10)-thujadiene – 0.3; sabinene – 3.6; b-pinene – 0.9; b-myrcene – 2.5; p-mentha-

1(7),8-diene – 0.8; p-cymene – 0.6; limonene –

11.2; b-phellandrene – 1.6; (Z)-b-ocimene – 8.4;

(E)-b-ocimene – 0.8; g-terpinene – 0.2; trans-

sabinene hydrate – 0.4; cis-linalool oxide – 0.3;

terpinolene – 0.6; cis-sabinene hydrate – 0.4;

linalool – 0.7; 1-octen-3-yl acetate – 0.1; 6-

camphenol – 0.9; trans-p-2-menthen-1-ol – 0.1;

cis-p-2-mentha-2,8-dien-1-ol – 0.3; neo-allo-

ocimene – 1.0; trans-verbenol – 0.4;

pinocarvone – 0.2; 3-thujanol – 0.6; myrtenal –

0.2; a-terpineol – 0.2; verbenone – 1.2; trans-

carveol – 0.1; cumine aldehyde – 0.1; neral – 2.9;

geranial – 1.3; bornyl acetate – 0.8; perilla alco-

hol – 0.1; p-menth-1-en-9-ol – 0.2; methyl

geranate – 14.5; trans-neryl acetate – 0.3;

geranyl acetate – 4.7; b-bourbonene – 0.9; b-elemene – 0.8; (E)-caryophyllene – 0.7; a-humulene – 0.2; allo-aromadendrene – 1.9;

germacrene D – 7.0; bicyclogermacrene – 0.6;

germacrene A – 0.1; d-cadinene – 0.4;

spathulenol – 0.9; caryophyllene oxide – 0.2;

Page 18: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 406 Dracocephalum moldavica L.

humulene epoxide II – 0.3; 10-epi-g-eudesmol –

0.7; heptadecane – 0.1; (E,E)-farnesol – 0.5

References

1. H.R. Monsef-Esfahani, F. Karamkhani, B. Nickavar, K. Abdi,

M.A. Faramarzi, Chem. Nat. Comp. 43, 265 (2007)

Dracocephalum moldavica L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.013–0.9 [1]

Components of essential oil, %: Citral – 20.0–50.0;

geraniol – 20.0–50.0; and others [1]

Flower

Essential oil, % dry wt: 1.09–1.9 [1]

Components of essential oil, %: Geraniol – 8.8–

17.4; geranyl acetate – 3.9–57.7; citral – 25.3–

80.4 [1]

Herbal

Essential oil, % dry wt: 0.008–0.2 [2]

[a]D: 0.39–5.42 [2]

d: 0.8978–0.9483 [2]

n40D : 1.4760–1.4874 [2]

Acid value, mg KOH: 2.32–18.6 [2]

Ester value, mg KOH: 34.64–170.33 [2]

Ester value after acetylated, mg KOH: 194.2–

288.11 [2]

Components, %: Citral – 50.0; geraniol – 30.0; nerol

− 7.0; citronelol − 4.0; thymol − 0.2; and

others [2]

Leaf

Essential oil, % dry wt: 0.8 [1]

Components of essential oil, %: Geraniol – 9.0–

21.0; geranyl acetate – 3.9–41.4; citral – 37.0–

80.5 [1]

Seed

Mass of 1,000, g: 1.5 [3]

Oil (petroleum ether, 30–60˚C), % dry wt: 20.0–29.0

[3, 4]

n20D : 1.4747 [3]

Iodine value (Wijs), % J2: 145.0–209.0 (cald) [2, 3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.6; 18:0 – 2.6; 18:1 – 7.3; 18:2 – 16.0; 18:3 –

67.0; others (6) – 1.8 [3]

IR [3]

Activity: Extract has antibacterial property [1]

Use: The essential oils are important in perfume and

cosmetic [1]. The essential oils are search for citral and

geraniol [2]. Cultivated in European part of SSSR [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 10 [in Russian]

2. N. I. Suprunov, P.G. Gorov, Yu. A. Pankov, Efirno-maslichnye rasteniya Dalnogo Vostoka (Novosibirsk, 1972),

p. 137 [in Russian]

3. J. M. Hageman, F. R. Earle, I. A. Wolff, A. S. Barclay, Lipids

2, 371 (1967)

4. N. I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Dracocephalum multicauli Montbr. etAuch. ex Benth.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 227.1 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 – 3.9;

18:0 – 2.3; 18:1 – 9.8; 18:2 – 21.1; 18:3 – 62.8

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Page 19: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Dracocephalum origanoides Steph. 407 Lamiaceae

Dracocephalum multicolor Kom.

Family: Lamiaceae

Flower

Essential oil, % dry wt: 0.25

Leaf

Essential oil, % dry wt: 1.0

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 136 [in

Russian]

Dracocephalum nodulosum Rupr.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.23–0.54

Activity: Ethanol extract has hypotensive property.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

21 [in Russian]

Dracocephalum nutans L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.01–2.12 [1, 2]

n20D : 1.505 [2]

Components of essential oil, %: Citral – 50.0;

limonene – 13.0; and others [1]

Seed

Oil (hexane) [3]

Iodine value, % J2: 231.4 (cald)

FAs

Composition (GLC, 10% PEGA), mole %: 16:0 –

4.3; 18:0 – 1.2; 18:1 – 8.8; 18:2 – 21.1; 18:3 –

64.6 [3]

Activity: Extract has antibacterial property [1]

Use: The essential oil is important in perfume [1]. The

essential oil may be used in perfume and herbal as

spice [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, p. 10 [in Russian]

2. N. I. Suprunov, P.G. Gorov, Yu. A. Pankov, Efirno-maslichnye rasteniya Dalnogo Vostoka (Novosibirsk, 1972),

p. 136 [in Russian]

3. G. V. Novitzkaya, V. I. Krishtopa, Rast. resursy. 7(1), 32

(1971), [in Russian]

Dracocephalum oblongifolium Rgl.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.49–0.53

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum origanoides Steph.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.3–0.46

Activity: Essential oil showed antibacterial and anti-

fungal activity.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

16 [in Russian]

Page 20: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 408 Dracocephalum palmatum Steph.

Dracocephalum palmatum Steph.

Family: Lamiaceae

Aerial part

Essential oil, % dry wt: 1.3

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum parviflora

Synonyms

Moldavica parviflora

Family: Lamiaceae

Seed

(nutlets)

Mass of 1,000, g: 2.3

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D :1.4743

Iodine value (Wijs), % J2: 192.0; 195.0 (cald)

Saponification value, mg KOH: 303.0

FAs

Composition (GLC, 14% Butanediol succinate), %:

14:0 � 0.3; 16:0 � 5.8; 16:1 � 0.8; 18:0 � 2.6;

18:1� 7.8; 18: 2� 28.7; 18:3� 53.3; 20:0� 0.7

Conjugated FAs as C18 diene, %: 0.4

References

1. E.C.M. Coxworth, J. Am. Oil Chem. Soc. 42, 891 (1965)

Dracocephalum paulsenii Briq.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1–0.39

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum peregrinum L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.03–0.5 [1]

Components of essential oil, %: a-Fellandrene –

70.0 and others [1]

Seed

Oil (hexane) [2]

Iodine value, % J2: 229.7 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �3.0; 18:0 � 1.4; 18:1 � 8.3; 18:2� 27.2; 18:3�60.1

Activity: Extracts have hypotensive and antibacterial

property [1].

Essential oil showed antibacterial and antifungal activ-

ity [1].

Use: The essential oil is of importance in the perfume

and cosmetics industry [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

22 [in Russian]

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Dracocephalum pinnatum L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.34

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Page 21: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Elsholtzia patrini Garcke 409 Lamiaceae

Dracocephalum Ruyschiana L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1 [1]

Seed

Oil, % dry wt: 14.56 [2]

d2020: 0.9276 [2]

n20D : 1.4801 [2]

Acid value, mg KOH: 4.22 [2]

Iodine value, % J2: 176.4 [2]; 205.1 (cald) [3]

Saponification value, mg KOH: 185.5 [2]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �4.5; 18:0� 1.1; 18:1� 11.0; 18:2� 26.8; 18:3�56.5 [3]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

22 [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Dracocephalum scrobiculatum Rgl.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.03

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum stamineum Kar et Kir.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.12–0.4

Components of essential oil, %: Citral – 45.3;

geraniol – 22.0; geranyl acetate –13.35’others

Activity: Essential oil has sedative property.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

16 [in Russian]

Dracocephalum subcapitatum(O. Kuntze) Lipsky

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 1.38–3.3

Activity: Essential oils have antibacterial property.

Use: Essential oils may be used in perfume.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

23 [in Russian]

Dracocephalum thymiflorum L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.03–0.13

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991) 6, 23

[in Russian]

Elsholtzia patrini Garcke

Synonyms

E. cristata Willd.

Page 22: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 410 Elsholtzia pseudo – cristata Levl. et Vant.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1–0.23 (1), 0.61−2.17 (2) [1][a]D: 1.0

o (1), 0.62−1.02 (2) [1]

d:-1.0121–0.9960 (1); 1.0131−1.0182 (2) [1]

n20D : 1.5166–1.5086 (1); 1.5275−1.5320 (2) [1]

Acid value, mg KOH: 7.09−2.11 (1); 0.65−0.71(2) [1]

Ester value, mg KOH: 31.31−18.31 (1); 13.71

−16.93 (2) [1]

Ester value after acetylated, mg KOH: 18.53 −19.24 (2) [1]

Seed

Oil, %:38.84–42.10 [2]

d15: 0.9355 [2]

n20D : 1.4840 [2]

n25D : 1.4830 [2]

Acid value, mg KOH: 0.36 [2]

Iodine value, % J2: 175.4–208.6 [2]

Saponification value, mg KOH: 192.0–196.0 [2]

Seed and Pericarp

Mass of 1,000, g: 0.2 [3]

Oil (petroleum ether, 30–60˚C), % dry wt: 40.0 [3]

n40D : 1.4752 [3]

Iodine value (Wijs), % J2: 194.0; 200.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.9; 18:0 – 2.2; 18:1 – 10.0; 18:2 – 23.0; 18:3 –

58.0; others (2) –0.2 [3]

IR [3]

Use: The essential oil may be used in perfume and

food [1]

References

1. N.I. Suprunov, P.G. Gorov, Yu. A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 145 [in

Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Elsholtzia pseudo – cristata Levl. et Vant.

Family: Lamiaceae

Flower

Essential oil, % dry wt: 2.0

Leaf

Essential oil, % dry wt: 1.01

Root

Essential oil, % dry wt: 0.11

Stem

Essential oil, % dry wt: 0.25

Use: The essential oil may be used in perfume and

food.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 145 [in

Russian]

Elsholtzia splendens Nak.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 39.0

n40D : 1.4754

Iodine value (Wijs), % J2: 195.0; 201.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.6; 18:0 � 2.1; 18:1 � 9.1; 18:2� 28.0; 18:3�55.0; others (2) � 0.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 23: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Eremostachys moluccelloides Rgl. 411 Lamiaceae

Eremostachys hyssarica Rgl.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 11.4 [1]

TAG

Main components (Coleman), mol %: OLeL � 1.8;

OLeO � 2.8; OLL � 5.0; OLO � 8.4; PLO �1.8; OOLe� 2.8; LOL� 3.1; OOL� 20.8; POL

� 2.4; OOO � 35.0; POO � 8.2; OPO � 1.1;

others (10) � 4.6 [2]

Composition, %: SSU + USS � 0.2; USU � 2.0;

SUS� 0.6; UUS + SUU� 14.2; UUU� 83.0 [1]

FAs (GLC, 15% Reoplex 400), %: 16:0 – 6.1; 16:1

� 1.1; 18:0 � tr; 18:1 � 69.5; 18:2(9,12) +

18:2(5,6) � 19.3; 18:3 � 4.0 [1]

Free FAs

Composition (GLC), %: 14:0 � 0.2; 16:0 � 6.6;

16:1 � tr; 17:0 � 0.4; 18:0 � 2.1; 18:1 � 48.6;

18:2� 16.8; 18:3� 1.2; 20:0 � 9.5; 20:1 � 3.9;

unidentified 1 � 8.5; unidentified 2–1.5; 22:0 –

0.7 [3]

References

1. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

2. T.V. Khomova, (unpublished)

3. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Eremostachys laciniata (L.) Bunge

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 25.0

Oil (petroleum ether, 30–60�C), % dry wt: 12.0

n40D : 1.4849

Iodine value (Wijs), % J2: 89.0; 84.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.1; 18:0� 1.6; 18:1� 65.0; 18:2� 11.0; 18:3�0.2; others (7) � 4.8

Allenic acid, %: 11.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Eremostachys moluccelloides Rgl.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 22.3 [1]

d20: 0.9115 [2]

n20D : 1.4732 [2]

Acid value, mg KOH: 2.5 [2]

Iodine value (Wijs), % J2: 107.1 [2]

Saponification value, mg KOH: 185.9 [2]

Unsaponifiables, %: 2.2 [2]

FAs

n20D : 1.4652 [2]

Iodine value (Wijs), % J2: 122.5 [2]

UV, IR [2]

Composition (GLC, 17% PEGS), %: 16:0 � 2.1;

18:0 � 0.3; 18:1 � 70.8; 18:2 � 26.3;

unidentified � 0.5 [2]

5,6-Octadekadienoic acid (laballenic), % total FAs:

8.5 [2]

Ag+-TLC, IR

Trans-10, trans-12-Octadecadienoic acid, % total

FAs: 0.5 [3]

Ag+-TLC, UV, IR

9,10-Dibromoctadecanoic acid [4]

9,10,12,13-Tetrabromoctadecanoic acid [4]

Ag+-TLC, IR, 13C NMR

Composition of oil (CC), %: Hydrocarbons + car-

otenes + esters of sterols + high molecular

alkanols + pigments � 1.1; TAG � 89.6; free

FAs + DAG +MAG� 0.8; PhL� 1.4; sterols�7.2 [5]

TAG

Composition, %; SSU + USS – 0.2; USU � 0.3;

SUS� 0.7; UUS + SUU� 10.0; UUU� 87.9 [5]

FAs

Composition (GLC, 15% Reoplex 400), %: 16:0 �3.1; 16:1 � 0.5; 18:0 � 1.1; 18:1� 71.9; 18:2�22.8; 18:3 � 0.6 [5]

DAG

IR, 1H NMR, MS [5]

Page 24: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 412 Eremostachys speciosa Rupr.

FAs (GLC), %: 16:0 � 2.9; 16:1 � 0.5; 17:0 � 0.2;

18:0� 1.1; 18:1� 57.5; 18:2� 34.7; 18:3� 1.2

[5]

1,2-DAG

Main components, %: PP � 0.2; OP � 2.9; LP �1.9; PO� 2.1; OO� 35.8; LO� 23.5; PL� 1.2

OL � 19.6; LL � 12.8 [5]

1,3-DAG

Main components, %: PP � 0.1; OP � 2.0; LP �1.4; PO� 2.0; OO� 34.0; LO� 22.3; PL� 1.3;

OL � 22.3; LL � 14.6 [5]

MAG

FAs (GLC), %: 16:0 � 13.7; 18:0 � 9.7; 18:1 �51.2; 18:2 � 25.4 [5]

Hydrocarbons (MS): C27–C35 [2]

Alkanols (MS): C32�C34 [2]

b Carotene [2]

UV

Hydroxycarotenes 1 and 2 [2]

UV

3,30-dihydroxycarotene [2]UV

Oxocarotene [2]

UV, IR

Di-2-ethylhexylphtalate [3]

UV, MS

References

1. T.V. Khomova, Autor’s Abstract of Candidate’s Dissertation(Akad. A.S. Sadikov Institute of Bioorganic chemistry of the

Uzbek Academy of Sciences, Tashkent, 1985) [in Russian]

2. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 11, 340(1975)

3. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 11, 527(1975)

4. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 12, 645(1976)

5. T.V. Panekina, S.D. Gusakova, M.Y. Tabak, A.U. Umarov,

Chem. Nat. Comp. 14, 33 (1978)

Eremostachys speciosa Rupr.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 8.9

Oil (petroleum ether, 30–60�C), % dry wt: 21.0

n40D : 1.4667

Iodine value (Wijs), % J2: 87; 81 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.6; 18:0 � 2.2; 18:1 � 53.0; 18:2� 8.8; 18:3�0.9; others (9) � 7.7

Allenic acid, %: 22.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Eremostachys vicaryi Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 6.3

Oil (petroleum ether, 30–60�C), % dry wt: 19.0

n40D : 1.4665

Iodine value, (Wijs), % J2: 90.0; 84.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.4; 18:0� 4.2; 18:1� 59.0; 18:2� 12.0; 18:3�0.3; others (5) � 3.1

Allenic acid, %: 15.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Galeopsis bifida Boenn.

Family: Lamiaceae

Essential oil, % dry wt: 0.1 [1]

Seed

Oil (petroleum ether), % dry wt: 42.0 [2]

d20: 0.9228

n20D : 1.4784

Acid value, mg KOH: 2.0

Iodine value (Kauffmann), % J2: 157.94

Saponification value, mg KOH: 190.08

Unsaponifiables, %: 1.07

Page 25: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Galeopsis bifida Boenn. 413 Lamiaceae

FAs

d20: 0.9003 [2]

n20D : 1.4685 [2]

Iodine value (Kauffmann), % J2: 164.92 [2]

UV, IR [2]

Composition (GLC, 17% EGS), %: 16:0 � 1.8;

16:1(9) � tr; 17:0 � tr; 18:0 � 0.9; 18:1 �12.4; 18:2 + 18:2(5,6) � 50.6; 18:3 � 33.4;

20:1(11) � tr; others (1) � 0.9 [2]

Composition of oil (CC), %: Hydrocarbons + squa-

lene � 0.14; TAG � 90.1; epoxy-TAG � 1.63;

free FAs + oxo-TAG � 1.1; hydroxy-TAG �2.12; DAG + sterols � 1.98; polar acylglycerol

1 � 0.29; polar acylglycerol 2 � 0.51; polar

acylglycerol 3 � 0.29; polar acylglycerol 4 �0.50; polar acylglycerol 5 � 0.11; polar

acylglycerol 6 � 1.2 [2]

UV, IR, 1H NMR

Free FAs

Composition, %: 14:0 � 0.1; 15:0 � tr; 16:0 � 7.4;

16:1(9) � 0.3; 17:0 � tr; 18:0 � 2.3; 18:1 �23.7; 18:2 � 45.6; 18:2(5,6) � 6.0; 18:3 � 14.6;

20:1(11) � tr [2]

TAG

Main components (Coleman), mol %: POL � 1.0;

OOL � 4.2; OOLe � 2.4; LOL � 6.0; LOLe �6.6; LeOLe� 1.8; PLL� 2.2; PLLe� 1.2; OLO

� 1.7; OLL � 9.6; OLLe � 5.5; LLL � 13.6;

LLLe� 15.0; LeLLe� 4.1; OLeL� 3.4; OLeSt

� 1.2; OLeLe� 1.8; LLeLe� 4.7; LeLeL� 5.2;

LeLeLe � 1.4 [2]

FAs, %:15:0� tr; 16:0� 2.7; 16:1(9)� 0.1; 17:0�tr; 18:0 � 1.0; 18:1 � 20.2; 18:2 � 49.1;

18:2(5;6) � 2.4; 18:3 � 24.5; 20:1(11) � tr [2]

The Positional Distributions of FAs in TAG (stereo

specific analysis), mol %: [3]

Position of

TAG 16:0 18:0 18:1

18:2(5,6) +

18:2(9,12) 18:3

Sn-1,2,3 2.9 1.0 20.1 51.4 24.6

Sn-1 7.3 2.4 25.1 44.8 20.4

Sn-2 0.5 – 24.6 55.6 19.3

Sn-3 0.9 0.6 10.6 53.8 34.1

Epoxy-TAG, %: 1.65 [4]

CC, UV, IR, MS [4]1H NMR [2]

Usual FAs of epoxy-TAG (GLC, 15% Reoplex

400), %: 16:0 � 3.3; 18:0 � 1.7; 18:1 � 20.8;

18:2 � 57.6; 18:3 � 16.3 [4]Epoxy-FAs (GLC, 15% Reoplex 400 and 3% OV-

1), %: cis-10,11-Epoxy-16:1(7Z) � 1.2; cis-

13,14-epoxy-16:2(7Z,10Z) � 0.4; cis-9,10-epoxy-18:0 � 3.0; cis-9,10-epoxy-18:1(12Z) �2.0; cis-12,13-epoxy-18:1(9Z) � 29.3; cis-

12,13-epoxy-18:2(9Z,15Z) � 7.2; cis-15,16-epoxy-18:2(9Z,12Z) � 52.8; trans-15,16-

epoxy-18:2(9Z,12Z) � 0.1; cis-15,16-epoxy-

18:2(9Z,12E or 9E,12Z) � 1.8; cis-11,12-epoxy-20:1(14Z) � 0.5; cis-14,15-epoxy-

20:1(11Z) � 1.4; cis-17,18-epoxy-

20:2(11Z,14Z) � 1.6 [4]

(-) 12(R),13(S)-Epoxy-18:1(9Z)

½a�20D : �2.7�

[a]560: �2.7�; [a]520: �2.7�; [a]480: �3.3�; [a]440:�3.0�; [a]360: �3.0�; [a]335: �1.8�; [a]310: 0.0�;[a]300: +0.9�; [a]280: +5.4�; [a]270: +6.7� (97.3%,

C 6.67 mg/mL, hexane) [4]

(+) 15(S),16(R) Epoxy-18:2(9Z,12Z)

½a�20D : + 6.9�

[a]560: + 6.9�; [a]480 + 8.9�; [a]400 + 15.5�; [a]360 +25.7�; [a]335 + 35.4�; [a]300 + 48.6�; [a]280 +

79.5� (87.2%, C 5.83 mg/mL, hexane) [4]

The Positional Distributions of FAs in epoxy-TAGs

(stereo specific analysis), mol %:

Sn-1,2,3: 16:0 � 5.0; C18 � 62.0; epoxy-18:1 �11.7; epoxy-18:2 � 21.3

Sn-1: 16:0 � 13.3; C18 � 29.0; epoxy-18:1 �9.2; epoxy-18:2 � 48.5

Sn-2: 16:0 � 1.6; C18 � 78.1; epoxy-18:1 �14.5; epoxy-18:2 � 5.8

Sn-3: 16:0 � 0.1; C18 � 78.9; epoxy-18:1 �11.4; epoxy-18:2 � 9.6 [3]

Oxo-TAG (CC), %: 0.3 [5]

UV, IR [2]

IR, MS [5]

Oxo-FAs: 10-Oxo-18:0, 9-oxo-18:0, 12-oxo-18:1(9Z),

10-oxo-18:1(8), 9-oxo-18:1(10), 9-oxo-

18:2(10,12), 13-oxo-18:3(9,11,15), 12-oxo-

18:3(9,13,15) [5]

Usual FAs of oxo-TAG (%, GLC, 15%

Replex 400): 16:0 � 3.9; 16:1 � 0.2;

18:0 � 0.9; 18:1 � 22.8; 18:2 � 49.4; 18:3 �22.8 [5]

Hydroxy-TAG

UV, IR, 1H NMR [2]

Page 26: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 414 Galeopsis Ladanum L.

Hydroxy FAs

Main components (GLC, 15% Reoplex 400 and 3%

OV-1): 13-Hydroxy-18:2(9Z,11E), 9-hydroxy-

18:2(10E,12Z), 12-hydroxy-18:1(9Z),

9-hydroxy-18:1(12Z) [1], 13-hydroxy-

16:2(9Z,11E), 9-hydroxy-18:0, 16-hydroxy-

18:2(9Z,12Z), 15-hydroxy-18:2(9Z,12Z), 12-

hydroxy-18:2(9Z,13E), 10-hydroxy-

18:2(8E,12Z), 16-hydroxy-18:3(9Z,12Z,14E),

15-hydroxy-18:3(9Z,13Z,16E), 9-hydroxy-

18:3(10E,12Z,15Z), 17-hydroxy-20:2(11Z,14Z),

and others [6]

UV, IR, MS [6]

Activity: Toxic oil [7].

Tincture has hypotensive property [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

27 [in Russian]

2. S.D. Gusakova, I.I. Vinokurov, A.U. Umarov, Chem. Nat.

Comp. 17, 217 (1981)

3. T.V. Khomova, S.D. Gusakova, A.U. Umarov, Chem. Nat.

Comp. 19, 266 (1983)

4. D.T. Asilbekova, S.D. Gusakova, G.P. Moiseeva, A.I.

Glushenkova, Chem. Nat. Comp. 23, 186 (1987)

5. S.D. Gusakova, T.V. Khomova, Chem. Nat. Comp. 20, 266

(1984)

6. S.D. Gusakova, D.T. Asilbekova, Chem. Nat. Comp. 27, 655

(1992)

7. I.A. Gusinin, Toksikologiya yadovitikh rastenii(Sel’khozizdat, Moscow, 1962), p. 6 [in Russian]

Galeopsis Ladanum L.

Family: Lamiaceae

Seed

Oil, % dry wt: 39.4 � 40.4 � 45.9 [1]

d20: 0.9220

n20D : 1.4763

Acid value, mg KOH: 4.3

Iodine value, % J2: 135.0–154.9

Saponification value, mg KOH: 195.4

Activity: Toxic oil [2].

Use: Recommended as technical oil [2].

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

16 [in Russian]

Galeopsis speciosa Mill.

Family: Lamiaceae

Seed

Oil, %: 40.0–44.3 [1]

Acid value, mg KOH: 3.1

Iodine value, % J2: 148.0 – 153.0 � 157.0

Saponification value, mg KOH: 105.0

Activity: Toxic oil [2].

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

27 [in Russian]

Galeopsis tetrahit L.

Family: Lamiaceae

Essential oil, % dry wt: 0.05 [1]

Seed

(Nutlets)

Mass of 1,000, g: 1.6 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 30.0 [2];

40.0–50.0 [1]

n40D :1.4713 [2]

Iodine value (Wijs), % J2: 161.0; 158.0 (cald) [2];

131.19–150.0 [1]

Saponification value, mg KOH: 293.0

Unsaponifiables, %: 0.9

FAs

Composition (GLC, 14% Butanediol succinate), %:

16:0� 4.8; 18:0� 0.9; 18:1� 27.0; 18:2� 45.0;

18:3 � 22.1; 20:0 � 0.3 [2]

Page 27: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Glechoma hirsuta Waldst. et Kit. 415 Lamiaceae

18:1 � 38.53; 18:2 � 47.38; and dihydroxy-18:0,

tetrahydroxy-18:0 [1]

Conjugated acids as C18 diene, %: 0.7 [2]

Activity: Seed oil is toxic. Ether extract has

antibacterial activity [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

27 [in Russian]

2. E.C.M. Coxworth, J. Am. Oil Chem. Soc. 42, 891 (1965)

Galeopsis tetrahit L. var. parvifloraBenth.

Family: Lamiaceae

Seed

Oil, % dry wt: 40.0–50.1

d2020: 0.9368

n20D : 1.4794

Acid value, mg KOH: 2.3–4.0

Iodine value, % J2: 131.1 – 159.8 � 161.0

Saponification value, mg KOH: 194.2–195.4

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Glechoma hederacea L.

Family: Lamiaceae

Essential oil, % dry wt: 0.03–0.08 [1]

Sterols: b-Sitosterol [1]FAs: 16:0 [1]

Aerial Part

Essential oil, % dry wt: 0.03–0.29 [1]

Triterpenoic6 acids: 2a-Hydroxyursolic acid [1]

b-Carotene [1]

Leaf

Essential oil, % dry wt: 0.013–0.9 [1]

Composition of essential oil, %: Germacrene D –

13.9; cis-ocymene – 9.2; b-elemene – 8.9; 1,8-

cineol – 6.2; and others [1]

Triterpenoic acids, %: Ursolic acid – 0.45 [1]

b-Carotene [1]

Plant Material

TerpenoidsComposition, %: Germacrene D – 19.4; germacrene

B – 13.9; cis-ocimene – 9.2; b-elemene – 8.9;

1.8-cineol – 6.2; a-pinene – 3.7; myrcene – 3.4;

b-pinene – 2.9; 3-octanone – 2.7; ɛ-bulgarene –1.9; sabinene – 1.5; terpinen-4-ol – 1.3; 1-octen-

3-ol – 1.2; g-elemene – 1.1; a-terpinol – 1.1; b-bourbonene – 1.0; limonene – 0.9; ɛ-muurolene

– 0.9; a-codinol – 0.9; borneol – 0.9 [2]

Essential oil, % dry wt: 0.29 [3]

Activity: Ether and ethanol extracts have

antibacterial property [1]. Essential oil is antiseptic [1].

Use: The herbal may be use as spice [3]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 28 [in Russian]

2. B.M. Lawrence, J. W. Hogg, S.J. Terhune, J. K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

3. N.I. Suprunov, P.G. Gorov, Yu. A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 132 [in

Russian]

Glechoma hirsuta Waldst. et Kit.

Family: Lamiaceae

Sterols, % dry wt: 0.07 [1]

Triterpenoic acids, % dry wt: Ursolic acid � 0.63 [1]

Terpenoids

Phytol, % dry wt: 0.06 [1]

FAs: 18:1 (3) [2]

Page 28: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 416 Glechoma longituba (Nakai) Kuprian.

Use: The essential oil is of importance in the perfume

industry [2].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

28 [in Russian]

Glechoma longituba (Nakai) Kuprian.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.40

Use: The essential oil may be used in perfume and the

flowers and leaves may be used as spice.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 131 [in

Russian]

Hedeoma drummondii Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.2

Oil (petroleum ether, 30–60�C), % dry wt: 6.9

n40D : 1.4764

Iodine value (Wijs), % J2: 199.0; 209.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.5; 18:0 � 2.9; 18:1 � 6.4; 18:2� 20.0; 18:3�64.0; others (6) � 1.1

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Hymenocrater bituminosus Fisch. et Mey.

Family: Lamiaceae

Essential oil, % dry wt: 0.14–0.18

Components of essential oil, %: Citral � 224.0–

28.0 and others

Sterols: b-Sitosterol

Activity: Essential oil has antibacterial property.

Ether extract showed antifungal activity.

Use: Ornamental plant.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

29 [in Russian]

Hymenocrater incidentatus Boriss.

Family: Lamiaceae

Essential oil, % dry wt: 0.18–0.24

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

29 [in Russian]

Hyptis decurrens (Blanio). Epl.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.5

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4740

Iodine value (Wijs), % J2: 189.0; 196.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.6; 18:0 � 3.2; 18:1 � 8.2; 18:2� 31.0; 18:3�51.0; others (2) � 0.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 29: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Hyptis stellulata Benth. 417 Lamiaceae

Hyptis floribunda Briq.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.4

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4749

Iodine value (Wijs), % J2: 185.0; 195.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.5; 18:0� 2.5; 18:1� 12.0; 18:2� 24.0; 18:3�55.0; others (3) � tr

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Hyptis mutabilis (Rich). Briq.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), % dry wt: 30.0

n40D : 1.4757

Iodine value, (Wijs), % J2: 196.0; 201.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.8; 18:0 � 2.7; 18:1 � 8.3; 18:2� 23.0; 18:3�58.0; others (4) � 0.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Hyptis spicigera Jacq.

Synonyms

Hyptis spicigera L.

Family: Lamiaceae

Seed

Oil, % dry wt: 37.3–38.0 [1]

d20: 0.9436

Iodine value, % J2: 171.0–203.0

Saponification value, mg KOH: 203.0

Seed and Pericarp

Mass of 1,000, g: 0.6 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 19.0 [2]

n40D : 1.4757

Iodine value (Wijs), % J2: 201.0; 212.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.4; 18:0 � 2.1; 18:1 � 6.1; 18:2� 22.0; 18:3�64.0; others (1) � 0.1 [2]

IR

References

1. N.I. Sharapov, Oil Plants and the Process of OilFormation (AS USSR Press, Moskwa-Leningrad, 1959), p.

351

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Hyptis stellulata Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 22.0

n40D : 1.4750

Iodine value, (Wijs), % J2: 191.0; 201.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.2; 18:0 � 2.7; 18:1 � 7.7; 18:2� 24.0; 18:3�58.0; others (2) � tr

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 30: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 418 Hyptis suaveolens (L.) Poit.

Hyptis suaveolens (L.) Poit.

Family: Lamiaceae

Seed

Moisture, %: 9.0 [1]

Oil (petrol ether, 40–60�C), %: 12.4 [1]; 13.0 [2]

n33D : 1.4830 [1]

Iodine value %, J2: 146.0 [1]; 140.2 [2]

Saponification value, mg KOH: 216.0 [1]

FAs

Composition (GLC, 15% DEGS and 2% SE 30), %:

16:0� 15.3; 18:0� 2.1; 18:1� 6.0; 18:2� 76.6

[1]

Seed and Pericarp

Mass of 1,000, g: 7.4 [3]

Oil (petroleum ether, 30–60�C), %: 24.0 [3]

n40D : 1.4696

Iodine value (Wijs), % J2: 145.0; 146.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �8.1; 18:0 � 2.9; 18:1 � 8.5; 18:2� 79.0; 18:3�0.6; others (3) � 0.9 [3]

Saturated � 12.0; 18:1 � 6.0; 18:2 � 77.0; conju-

gated 18:3 � 0.2 [4]

IR [4]

Root

Sitosterol-b-D-glucoside [5]

Triterpenoic acids

Components: Ursolic acid and betulinic acid [5]

3b-Hydroxylup-12-en-28-oic acid [6]

½a�25D : +12.0 (pyridine)

M.p., IR, MS,,1H NMR

3b-Hydroxylup-20(29)-en-27 oic acid [6]

½a�25D : +31.0 (pyridine)

M.p., IR, MS, 1H NMR

Triterpenols

Components: a-Amyrin and b-amyrin [5]

Heptacosanone [5]

References

1. S.K. Husain, M.U. Ahmad, S. Sinha, A.A. Ansari, S.M.

Osman, Fette, Seifen, Anstrichmittel 80, 225 (1978)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

4. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

5. T.N. Misra, R.S. Singh, J. Upadhyay, Phytochemistry 22, 603

(1983)

6. T.N. Misra, R.S. Singh, J. Upadhyay, Phytochemistry 22,

2557 (1983)

Hyssopus ambiguous (Trautv.) Iljin

Family: Lamiaceae

Essential oil, % dry wt: 1.4

Triterpenoic acid: Ursolic acid – 0.49

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

31 [in Russian]

Hyssopus cretaceus Dubjan.

Family: Lamiaceae

Essential oil, % dry wt: 1.2

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

31 [in Russian]

Hyssopus cuspidatus Boriss.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 1.13

Components of essential oil, %: a-Terpeniol – 30.0;a-pinene + b pinene – 18.0; 1,8-cineol –13.0;

Page 31: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Hyssopus seravschanicus (Dubjan.) Pazij 419 Lamiaceae

trans-pinocamphone – 10.0; limonene – 7.0;

pinocamphone – 9.0; and others

Use: The essential oil is of importance in the perfume

and cosmetics industry.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

29 [in Russian]

Hyssopus officinalis L.

Family: Lamiaceae

Essential oil, % dry wt: 0.22–0.6 [1]

b-Sitosterol [1]

Aerial Part

Essential oil, % dry wt: 0.07–1.7 [1]

Components of essential oil, %: Pinocamphone –

12.18–69.1; b pinene – 16.1–22.87; camphene –

0.35–11.5 and others

Triterpenoic acids: Ursolic acid, oleanolic acid [1]

Leaf

Essential oil, % dry wt: 0.14–0.9 [1]

Seed

Mass of 1,000, g: 1.0 [2]; 1.10 [3]

Oil, % dry wt: 29.0 (petroleum ether, 30–60�C) [2];26.0 [3]; 24.2 (hexane) [4]; 9.0–11.0 [5]

d20: 0.9296 [3]

n40D : 1.4758 [2]

Acid value, mg KOH: 5.6 [3]

Color: 763.0 [3]

Iodine value, (Wijs), % J2: 197.0; 202.0 (cald) [2];

229.0 (cald) [4]

FAs

Composition (GLC): 16:0� 5.4; 18:0� 2.6; 18:1�12.0; 18:2 � 17.0; 18:3 � 62.0; others (7) � 1.1

(%, 20% LAC-2R 446) [2]

16:0 � 5.0; 18:0 � 1.0; 18:1(9) � 9.6; 18:1(6) �0.9; 18:2 � 17.5; 18:3 � 64.4 (%, FFAP) [3]

16:0 � 5.1; 18:0 � 1.4; 18:1 � 8.6; 18:2 � 21.4;

18:3 � 63.5 (mol %, 10% PEGA) [4]

IR [2]

TAG

Main components (Coleman), mol %: LeLeLe �24.7; LLeLe � 11.6; OLeLe � 9.8; LeLLe �8.8; LeOLe � 6.7; PLeLe � 5.8; LLLe � 4.2;

OLLe� 3.6; LOLe� 3.2; OOLe� 2.6; OLeL�2.4; PLLe� 2.4; LLeL� 1.4; POLe� 1.8; PLeL

� 1.6; PLeO � 1.2; others (15) – 7.2 [5]

Composition, %: SSU + USS � 0.2; USU � 0.9;

SUS� 0.7; UUS + SUU� 15.8; UUU� 83.0 [5]

FAs (GLC, 15% Reoplex 400), %: 16:0� 4.8; 16:1

� tr; 18:0 � 1.3; 18:1 � 13.9; 18:2 � 17.2; 18:3

� 62.8 [6]

Activity: Essential oil showed antibacterial activity

[1].

Use: The essential oil is of importance in the perfume

industry [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

30 [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

4. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

5. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

6. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Hyssopus seravschanicus (Dubjan.) Pazij

Synonyms

H. ferganensis Boriss.; H. tianschanicus Boriss.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.67–0.83

Components of essential oil, %: Pinocamphone –

23.0; sabinene – 16.34; d-limonene 13.75;

myrcene – 5.03 and others

Page 32: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 420 Isanthus brachiatus (L.) BSP.

Triterpenoic acids: Ursolic acid, oleanolic acid

Sterols: b-Sitosterol

Undeground Part

Triterpenoic acids: Ursolic acid, oleanolic acid

Sterols: b-Sitosterol

Activity: Essential oil showed antibacterial activity.

Use: Aerial part is used as herbal tea and spice. The

essential oil is of importance in the perfume industry.

References

1. Rastitel’nye Resursy SSSR(Nauka, St. Petersburg, 1991), 6, 30[in Russian]

Isanthus brachiatus (L.) BSP.

Family: Lamiaceae

Plant Material

Terpenoids

Composition, %: a-Pinene – 64.8; b-pinene – 13.6;

myrcene – 5.8; caryophyllene – 3.0; limonene –

2.0; a-humulene – 1.7; 1-octen-3-ol – 0.6; trans-

verbenol –.4; 1.8-cineol – 0.2; terpinen-4-ol –

0.2; a-terpineol – 0.2

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Lagochilus occultiflorus

Family: Lamiaceae

Seed

Moisture, %: 4.35

Oil (petroleum ether, 40–50�C), % dry wt: 30.25

d20: 0.9262

n40D : 1.4771

Acid value, mg KOH: 1.19

Iodine value (Kaufmann), % J2: 122.3

UV, IR

FAs

Iodine value, % J2: 128.2

Neutralization value, mg KOH: 200.61

Conjugated dienes, %: 1.75

UV, IR

Composition (GLC, 17% PEGS), %: 14:0 – tr; 16:0

– 3.69; 18:0 – 1.49; 18:1 – 24.04; 18:2 – 66.11;

20:1 (11Z) – 2.92; 20:2(9Z, 11E or 9 E,11Z) –

1.75

Allenic acid, % total FAs: 18:2 (5.6) – 12.0

TAG

Composition, %: SSS – 0.01; SSU + USS � 0.5;

USU � 4.49; SUS � 0.27; UUS + SUU � 9.48;

UUU � 85.25

FAs

References

1. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 23

(1972)

Lallemantia iberica Fisch. et Mey.

Family: Lamiaceae

Seed

Oil, %: 24.0–38.0

d20: 0.9336–0.9340

n20D : 1.4840

Iodine value, % J2: 162.0–203.04

Saponification value, mg KOH: 185.0–189.0

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Lallemantia peltata (L.) Fisch. et Mey.

Family: Lamiaceae

Seed

Oil, % dry wt: 20.5 [1]; 17.5 [2]

Iodine value, % J2: 147.0

Page 33: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamium moshatum Mill. 421 Lamiaceae

Components of oil (TLC): Hydrocarbons, steryl

esters, TAG, free FAs, DAG, MAG, sterols [2]

TAG

FAs (GLC), %: 16:0 � 4.5; 16:1 � 0.5; 18:0 � 2.0;

18:1 � 25.0; 18:2 � 68.0 [2]

Free FAs

Composition (GLC), %: 14:0 � 8.4; 16:0 � 9.4;

16:1� 5.0; 18:0� 4.1; 18:1� 13.5; 18:2� 49.4;

18:3 � 10.2 [2]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

2. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova,

A.U. Umarov, Chem. Nat. Comp. 17, 326 (1981)

Lamium album L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.04–0.46

Flower

Essential oil, % dry wt: 0.05

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

38 [in Russian]

Lamium amplexicaule L.

Family: Lamiaceae

Essential oil, % dry wt: 0.09 [1]

Aerial Part

Terpenoids

Phytol, % dry wt: 0.1 [1]

Seed and Pericarp

Mass of 1,000, g: 0.6 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 39.0 [2]

n40D : 1.4703 [2]

Iodine value (Wijs), % J2: 136; 134 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.7; 18:0 – 3.0; 18:1 – 36.0; 18:2 – 28.0; 18:3 –

11.0; others (4) – 1.4 [2]

Allenic and trans acids (IR) [2]

IR: 870; 1960 [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

39 [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lamium molecellifolium

Family: Lamiaceae

Leaves

Hexadeca-7,10,13-trienoic acid, %: 0.2

References

1. G.R. Jamieson, E.H. Reid, Phytochemistry 10, 1837 (1971)

Lamium moshatum Mill.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 7.0

Oil (petroleum ether, 30–60�C)n40D : 1.4670

Iodine value (Wijs), % J2: 114; 115 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.3; 18:0� 4.1; 18:1� 38.0; 18:2� 44.0; 18:3�26.0; others (7) � 1.1

Trans acid, %: 5.4

IR: 870

Page 34: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 422 Lamium purpureum

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lamium purpureum

Family: Lamiaceae

Seed

Allenic acid: 18:3 (5Z, 6E, 16Z)

References

1. P. Pohl, H. Wagner, Fette, Seifen, Anstrichmittel 74(9), 541

(1972)

Lamium purpureum L.

Family: Lamiaceae

Aerial Part

Sterols, %: b-Sitosterol, stigmasterol, campesterol [1]

Seed and Pericarp

Mass of 1,000, g: 1.0 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 39.0 [2]

n40D : 1.4706 [2]

Iodine value (Wijs), % J2: 140; 135 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �9.2; 18:0� 2.4; 18:1� 24.0; 18:2� 34.0; 18:3�12.0; others (7) � 3.1 [2]

Allenic acids (IR), %: 15.0 [2]

Trans acid, %: 14.0 [2]

IR [2]

Seed

Oil, %: 40.5 [1, 3]

FAs

Composition (GLC, 10% PEGA), mol %): 16:0 �12.5; 18:0 � 1.7; 18:1 � 25.7; 18:2 � 33.7;

18:3 � 26.3 [3]

16:0 � 11.0; 18:0 � 2.0; 18:1 � 25.0; 18:2 � 34.0;

18:3 + allenic acid � 28.0 [4]

(-) Octadeca-5,6-trans-16-trienoic acid, %: 16.0 [4]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

40 [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971) [in Russian]

4. K.L. Mikolajczak, M.F. Rogers, C.R. Smith, I.A. Wollf,

Biochem. J. 105, 1245 (1967)

Lavandula angustifolia Mill.

Family: Lamiaceae

Essential oil

Composition of essential oil (GC, SPBS; GC/MS),

%:Myrcene� 0.7; 1,8-cineole� 0.9; b-ocimene

� 1.8; linalool � 31.5; linalyl acetate � 43.6;

b-caryophyllene � 5.0; unidentified � 3.0

References

1. C. Ghelardini, N. Galeotti, G. Salvatore, G. Mazzanti, Planta

Med. 65, 700 (1999)

Lavandula dentata L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.2

Oil (petroleum ether, 30–60�C), % dry wt: 31.0

n40D : 1.4757

Iodine value (Wijs), % J2: 202; 205 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.6; 18:0 � 1.1; 18:1 � 8.8; 18:2 � 11; 18:3 �72; others (5) � 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 35: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lavandula latifolia Medic. 423 Lamiaceae

Lavandula gibsonii

Synonyms

L. perrottetii

Family: Lamiaceae

Whole Plant

Sitosterol (from 1 kg air dried whole plant: root, stem,

leaves, and flowers), g: 0.46

Methyl 3-acetoxy-16-methylheptadecanoate (from

1 kg), g: 0.55

3-Acetoxy-16-methylheptadecanoic acid

IR, MS, 1H NMR

Activity: Acetone extracts exhibit antifeedant,

antigonadal, ovipositor-deterrent, and repellent

properties against different insects.

References

1. S.A. Patwardhan, A.S. Gupta, Phytochemistry 22, 165 (1983)

Lavandula lanata Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.0

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4760

Iodine value (Wijs), % J2: 198; 207 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.6; 18:0� 2.1; 18:1� 10.0; 18:2� 16.0; 18:3�65.0; others (7) � 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lavandula latifolia

Family: Lamiaceae

Essential oil (steam distillation), % dry wt: 0.6

Composition of essential oil (GLC, 20% Apiezon

L and 20% Carbowax 20M), %: a-Pinene �4.21; camphene � 0.23; b-pinene � 0.84;

sabinene � 0.86; b-myrcene � 0.15; 1;8-cineole

� 33.65; p-cymene � 0.91; linaloyl oxide �0.53; a-gurjunene � 0.47; camphor � 5.31; lin-

alool� 26.34; caryophyllene� 1.39; d-cadinene� 0.98; trans-pinocarveol � 0.37; d-terpineol �1.02; a-terpineol � 1.71; borneol � 4.89; b-bisabolene � 0.40; myrthenol � 0.23; trans-a-bisabolene � 1.90; geraniol � 0.20; cis

calamanenes + trans-calamanenes � 0.29;

cymenol � 0.37; carveol � 0.35; b-farnesene� 0.03; caryophyllene oxide � 1.04; cuminyl

alcohol � 0.23; herniarn � 1.07; coumarin �9.04

Monoterpene hydrocarbons, %: 7.0

Sesquiterpene-hydrocarbons %: 7.3

Oxygenated monoterpenoids, %: 75.2

2-Terpineol

CC, Ag+-TLC, IR, MS, 1H NMR

References

1. I. De Pascual-T, E. Caballero, C. Caballero, G. Machin, Phy-

tochemistry 22, 1033 (1983)

Lavandula latifolia Medic.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.1

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4766

Iodine value (Wijs), % J2: 207; 213 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %:16:0 �4.9; 18:0 � 2.6; 18:1 � 9.2; 18:2 � 13; 18:3 �69; others (4) � 0.8

IR

Page 36: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 424 Lavandula officinalis L.

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lavandula officinalis L.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 18.3

Iodine value (Wijs), % J2: (cald)

TAG, %: 97.7

FAs from TAG

Composition (GLC, 15% Reoplex 400), %:14:0 �tr; 16:0 � 6.8; 16:1 � 0.5; 18:0 � 1.5; 18:1 �21.3; 18:2 � 21.9; 18:3 � 48.0

Free FAs

Composition (GLC, 15% Reoplex 400), %: 14:0 �0.5; 16:0 � 9.3; 16:1 � 1.1; 18:0 � 2.4; 18:1 �25.3; 18:2 � 18.6; 18:3 � 42.8

References

1. S.D. Gusakova, G.A. Stepanenko, D.T. Asilbekova, Y.M.

Murdokhaev, Rast. Resursy 19(4), 444 (1983)

Lavandula pendunculata Cav.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4770

Iodine value (Wijs), % J2: 207; 208 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.9; 18:0 � 1.7; 18:1 � 8.1; 18:2� 16.0; 18:3�66.0; others (5) � 3.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lavandula spica L.

Synonyms

L. vera DC.

Family: Lamiaceae

Seed

Oil, %: 29.77–30.0

d2020: 0.9344–0.9348

n20D : 1.4830–1.4835

Acid value, mg KOH: 4.22

Iodine value, % J2: 191.38; 192.4

Saponification value, mg KOH: 191.93

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 327 [in

Russian]

Lavandula stoechas L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4749

Iodine value (Wijs), % J2: 199, 209 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %:16:0 �5.6; 18:0 � 2.0; 18:1 � 8.8; 18:2� 18.0; 18:3�65.0; others � 0.8

IR: 792; 940

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 37: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Leonurus cardiaca L. 425 Lamiaceae

Lavandula vera L.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 20.0 [1]

Iodine value (Wijs), % J2: (cald) [1]

TAG

Main components (by Coleman), mol %: LeLeLe –

42.8; LLeLe – 6.6; OLeLe – 4.8; LeLLe – 12.5;

LeOLe – 11.6; PLeLe – 4.0; LLLe – 2.0; OLLe –

1.2; LOLe – 1.8; OOLe – 1.4; PLLe – 1.2; POLe –

1.2; LePLe – 4.7; others – 4.1 [2]

Composition, mol %: SUS – 0.1; SSU + USS – 0.6;

USU – 5.8; UUS + SUU – 7.2; UUU – 86.3

FAs of TAG

Composition (GLC, 15% Reoplex 400), %: 16:0 –

4.3; 16:1(9) – tr; 18:0 – 0.5; 18:1(9) – 8.6;

18:2(9,12) – 10.2; 18:3(9,12,15) – 76.4 [2]

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Leonotis nepetaefolia (L.) R. Br.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.0

Oil (petroleum ether, 30–60�C), % dry wt: 37.0

n40D : 1.4662

Iodine value (Wijs), % J2: 92; 87 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %:16:0 �11; 18:0� 5.5; 18:1� 47; 18:2� 19; 18:3� 0.6;

others (5) � 2.5

Allenic acid (IR), %: 15.0 [1]; 16.0 [2]

IR: 1960

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. M.O. Bagby, C.R. Smith, K.L. Mikolajczak, I. A. Wollf,

Biochemistry 1(4), 632 (1962)

Leontis nepetaefolia (R. Br.) Ait.

Family: Lamiaceae

Seed

Oil, %: 28.0

n20D : 1.4673

Iodine value, % J2: 82.5

Saponification value, mg KOH: 191.2

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347

Leonurus cardiaca L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.003–0.09 [1]

Leaf

Essential oil

Composition, %: Caryophyllene – 39.8; a-humulene – 34.8; a-pinene – 5.6; b-pinene –

0.5; linolool – 0.7; limonene – 0.4 [1]

Triterpenoic acids, % dry wt: Ursolic acid – 0.26 [1]

Seed

Oil, % dry wt: 14.9 [1, 2]

Iodine value, % J2: 167.7 [1, 3]

FAs

Composition (GLC, 10% PEGA), mole %: 16:0 –

4.3; 18:0 – 0.6; 18:1 – 16.8; 18:2 – 73.6; 18:3 –

4.7 [2]

Seed and Pericarp

Ash, %: 6.4 [4]

Mass of 1,000, g: 1.2 [3]; 0.4 [4]; 0.85 [5]

Oil (petroleum ether, 30−60˚C), % dry wt: 38.0 [3];

23.0 – 30.2 [4, 5, 6]

d20: 0.9387 [4]; 0.9230 [5]

n20D : 1.4694 [3]; 1.4689 [7]

Acid value, mg KOH: 2.75 [5]

Color: 3.2 [5]

Page 38: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 426 Leonurus glaucescens Bge.

Iodine value (Wijs), % J2: 126.0–203.0 [6]; 133.0

[7]; 130, 131 (cald) [3]; 167.7 (cald) [2]

Saponification value, mg KOH: 180.0 [7]

HBr uptake, as C18 epoxy acid, %: 0.5 [7]

IR [7]

FAs

Composition (GLC), %:16:0 – 4.6; 18:0 – 2.3; 18:1

– 21.0; 18:2 – 55.0; 18:3 – 3.6; others (8) –3.1

(20% LAC-2R 446) [3]; 16:0 – 4.7; 18:0 – 2.7;

18:1(9) – 19.6; 18:1(6) – 0.9; 18:2 – 58.9; 18:3 –

2.7; others – 10.1 (FFAP) [5]: Saturated – 6.0;

18:1 – 35.0; 18:2 – 53.0; 18:3 – 2.0 (20%

Apiezon L) [7]

Allenic acid (IR), %: 9.9 [3]

IR: 1960 [3]

Stem

Essential oil, % dry wt: 0.06 [1]

Plant material

Terpenoids

Composition, %: Caryophyllene – 39.8; a-humulene – 34.8; a-pinene – 5.6; linalool – 0.7;

b-pinene – 0.5; limonene – 0.4 [8]

Use: The plant is of importance as a flavoring agent

in food industry; the seed oil may be used as technical

oil [1]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, p. 40 [in Russian]

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

4. F.R. Earle, Q. Jones, Econ. Bot. 16(4) 221 (1962)

5. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Pol. 44(3), 161

(1998)

6. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

7. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Amer.

Oil Chem. Soc. 37, 440 (1960)

8. B.M. Lawrence, J. W. Hogg, S.J. Terhune, J. K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Leonurus glaucescens Bge.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 158.3 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.6; 18:0 – 2.2; 18:1 – 20.7; 18:2 – 70.1; 18:3 –

2.4

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Leonurus heterophyllus Sweet.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.02 (1), 0.04 (2)

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 132 [in

Russian]

Leonurus quinquelobatus Gilib.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 16.2 [1]:

Iodine value, % J2: 165.2 (cald) [2]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

3.8; 18:0 – 1.6; 18:1 – 17.9; 18:2 – 72.9; 18:3 –

3.9 [2]

TAG, % mass of oil: 97.1 [1]

FAs of TAG

Composition (GLC, 15% Reoplex 400), %: 16:0 –

2.5; 16:1 – tr; 18:0 – 0.7; 18:1 – 18.6; 18:2 – 75.1;

18:3 – 3.1

Page 39: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Leonurus villosus Des. 427 Lamiaceae

Free FAs

Composition (GLC), %: 14:0 – 0.3; 16:0 – 6.2; 16:1

– tr; 18:0 – 2.0; 18:1 – 21.5; 18:2 – 65.3; 18:3 –

4.7 [1]

Free FAs of Tinctura Leonuri (GLC), %: 12:0 –

2.3; 14:0 – 3.0; 16:0 – 42.4; 16:1 – 3.1; 18:0 –

6.3; 18:1 – 6.0; 18:2 – 17.0; 18:3 – 18.7 [1]

References

1. S.D. Gusakova, G.A. Stepanenko, D.T. Asilbekova, Y.M.

Murdokhaev, Rast. Resursy 19(4), 444 (1983)

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Leonurus sibiricus L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 42.0

n40D : 1.4693

Iodine value (Wijs), % J2: 124; 121 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %:16:0 �4.9; 18:0� 1.8; 18:1� 24.0; 18:2� 50.0; 18:3�1.0; others (7) � 4.8

Allenic acid, %: 14.0

IR: 1960

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Leonurus turcestanicus

Family: Lamiaceae

Seed

Moisture, %: 5.2

Oil (petroleum ether, 40–50�C), % dry wt: 34.4

d204 : 0.9207

n40D : 1.4775

Acid value, mg KOH: 1.1

Iodine value (Kaufmann), % J2: 127.7

UV, IR

FAs

Iodine value, % J2: 128.5

Conjugated dienes, %: 1.23

UV, IR

Composition (GLC, 17% PEGS), %: 12:0 � 0.39;

16:0 – 4.49; 18:0 – 2.15; 18:1 – 30.45; 18:2 –

68.35; 20:1(11Z) – 1.25

TAG

Composition, %: SSS � 0.04; SSU + USS � 1.08;

USU � 6.83; SUS � 0.49; UUS + SUU � 12.46;

UUU � 79.10

References

1. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 8, 24 (1972)

Leonurus villosus Des.

Synonyms

L. quinquelobatus Gilib.

Family: Lamiaceae

Sterols, % dry wt: 0.04 [1]

Terpenoids

Phytol, % dry wt: 0.07 [1]

Seed

Oil, %: 25.4–30.2 [2]

d20: 0.4770

Iodine value, % J2: 125.1

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

Page 40: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 428 Lepechinia calycina Epl.

Lepechinia calycina Epl.

Family: Lamiaceae

Plant Material

Essential oil (Clevenger apparatus)Composition (GLC), %: 1,8-Сineole – 19.7; cam-

phor – 17.5; d-3-carene – 17.4; camphene – 7.8; a-pinene – 6.5; caryophyllene – 5.7; linalool – 2.6;

a-terpinene – 2.3; limonene – 2.3; b-pinene – 1.8;trans-nerolidol – 1.8; myrcene – 1.7; terpineol –

1.5; g-terpinene – 1.4; a-phellandrene – 1.0;

terpinolene – 0.9; piperitone – 0.8; d-cadinene –0.8; b-cymene – 0.7; terpinene-4-ol – 0.7; a-phellandrene – 0.6; menthone – 0.6; phenylethyl

butyrate – 0.6; trans-b-farnesene – 0.3; 10-epi-a-cadinol – 0.3; a-thujene – 0.2; isomenthone – 0.2;

a-gurjunene – 0.2; a-humulene – 0.2; bornyl ace-

tate – 0.1; geranyl acetate – 0.1; neoisopulegol –

tr; phenylethyl 2-methylbutyrate – tr

References

1. B.M. Lawrence, J.K. Morton, Phytochemistry 18, 1887 (1979)

Lepechinia spicata Willd.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

n40D : 1.4689

Iodine value (Wijs), % J2: 137; 141 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %:16:0 �9.2; 18:0 � 2.3; 18:1 – 15.0; 18:2 – 72.0; 18:3 –

1.6; others (3) – 0.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Leucas asper Link.

Family: Lamiaceae

Seed

Oil, %: 20.0 [1]

Iodine value, % J2:93.0

Seed and Pericarp

Ash, %: 6.7 [2]

Mass of 1,000, g: 7.0 [2]

Oil, % dry wt: 25.4 [2]

HBr uptake, as C18 acid, %: 1.4

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348

2. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Leucas cephalotes Spreng.

Family: Lamiaceae

Seed

Oil (petroleum ether, bp. 40–60�C) %: 28.5 [1]; 28 [2]

n20D : 1.4795 [1]

Iodine value, % J2 (Wij’s): 100 [1]

Saponification value, mg KOH: 160

NMR [2]

FAs

Composition (%, GLC): 16:0 – 13.0; 18:0 – 3.9;

18:1 – 41.6; 18:2 – 13.5; 18:2(5.6) – 28.0 (20%

LAC-2R 446)

16:0 – 15.0; 18:0 – 5.0; 18:1 – 46.0; 18:2 – 15.0;

18:2(5.6) – 19.0 (5% FFAP on Chromasorb P)

Methyl laballenate

IR [1]

NMR [1, 2]

References

1. S. Sarita, A.A. Ashfaque, S.M. Osman, Chem. Ind. (2), 67

(1978)

2. C. Shi-Chow, P.M. Elefson, J.M. MacTaggart, J. Agric Food

Chem. 27, 435 (1979)

Page 41: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lycopus europaeus L. 429 Lamiaceae

Leucas nutans Spreng.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.6

Oil (petroleum ether, 30–60�C), % dry wt: 43.0

n40D : 1.4654

Iodine value (Wijs), % J2: 91; 88 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

12.0; 18:0 – 5.7; 18:1 – 39.0; 18:2 – 23.0; 18:3 –

0.6; others – 3.4

Allenic acid (IR), %: 16.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Leucas zeylonica R. Br.

Family: Lamiaceae

Seed

Oil, %: 20.3

Iodine value, % J2:100.0

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Lycopus asper Greene

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.7

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4719

Iodine value (Wijs), % J2: 155.0

Saponification value, mg KOH: 168.0

FAs

Composition (20% Apiezon L), %: 18:1 � 49.0;

18:2 � 16.0; 18:3 � 30.0

HBr uptake, as C18 epoxy acid, %: 1.6

IR

References

1. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

Lycopus asper Greene.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.7

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4719

Iodine value (Wijs), % J2: 155; 185 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

3.5; 18:0 – 1.5; 18:1 – 16.0; 18:2 – 24.0; 18:3 –

50.0; others (5) – 5.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lycopus europaeus L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60�C), % dry wt: 33.0

n40D : 1.4700

Iodine value (Wijs), % J2: 131; 134 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.9; 18:0 – 1.8; 18:1 – 19.0; 18:2 – 59.0; 18:3 –

2.5; others (4) – 1.4

Page 42: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 430 Lycopus europeus L.

Allenic acid (IR), %: 11.0

IR: 1960

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Lycopus europeus L.

Family: Lamiaceae

Sterols, % dry wt: 0.05 [1]

Triterpenoic acids, % dry wt: Ursolic acid – 1.00 [1]

Terpenoids

Phytol, % dry wt: 0.03 [1]

Seed

Mass of 1,000, g: 0.15 [2]

Oil, % dry wt: 22.0 [2]

d20: 0.9330

Acid value, mg KOH: 8.60

Сolor: 3.0

FAs

Composition (GLC, FFAP), %: 16:0 � 4.5; 18:0 �2.4; 18:1 � 10.3; 18:2 � 29.4; 18:3 � 51.0;

others � 0.5 [2]

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

Lycopus exaltatus L.

Family: Lamiaceae

Sterols, % dry wt: 0.05

Triterpenoic acids, % dry wt: Ursolic acid � 1.19

Terpenoids

Phytol, % dry wt: 0.03

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

Lycopus lucidus Turcz.

Family: Lamiaceae

Herbal

Essential oil, % dry wt: 0.06

Leaf

Essential oil, % dry wt: 0.01

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 141

Lycopus uniflorus Michx.

Family: Lamiaceae

Leaves

TerpenoidsComposition, %: Сaryophyllene – 39.8;

a-humulene – 34.8; a-pinene – 5.6; linalool –

0.7; b-pinene – 0.5; limonene – 0.4l

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Majorana hortensis

Family: Lamiaceae

Seed

Ash, %: 5.2 [1]

Mass of 1,000, g: 1.5 [1]

Oil, % dry wt: 39.7 [1], 40.0 (petroleum ether, 30–

60�C) [2]n40D : 1.4753 [2]

Iodine value (Wijs), % J2: 199.0 [2]

Saponification value, mg KOH: 188.0 [2]

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Melissa officinalis L. 431 Lamiaceae

FAs

Composition (20% Apiezon L), %: Saturated� 5.0;

18:1 � 16.0; 18:2 � 20.0; 18:3 � 55.0 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, T.A.McGuire, J. Mallan, M.O. Bagby, I.A.Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

Majorana syriaca (L.) Rafin.

Synonyms

M. syriaca (L.) Feinbr.; Origanum maru L.; Origanumsyriacum L.

Family: Lamiaceae

Essential oil (steam distillation), % v/w: 0.9 (from

fresh plant material, Israel)

Composition of essential oil (GLC, 5% Carbowax

20 M and 6% OV 17; GC/MS, OV 1), %: a-Pinene � 2.3; camphene � 0.1; b-pinene �0.2; sabinene � tr; D3-carene � 0.1; myrcene �2.9; a-terpinene � 2.8; limonene � 0.4; 1;8-

cineole � 0.3; g-terpinene � 14.5; cymene �13.1; camphor � tr; linalool � 0.2; terpinene-4-

ol � 0.6; caryophyllene � 2.2; borneol � 0.7;

thymol � 41.1; carvacrol � 15.6

References

1. V. Ravid, E. Putievsky, Planta Med. 49, 248 (1983)

Marrubium alternidens

Family: Lamiaceae

Seed

Free FAs

Composition (GLC), %: 14:0 � 4.8; unidentified

1 � 2.0; 16:0 � 27.4; 16:1 � tr; 17:0 � 0.9;

18:0 � 5.7; 18:1 � 28.7; 18:2 � 18.6; 18:3 � tr;

20:0 � 0.9; 20:1 � 0.8; unidentified 2 � 10.2

References

1. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Marrubium vulgare

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil, % dry wt: 35.1

HBr uptake, as C18 acid, %: 0.3

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Melissa officinalis L.

Family: Lamiaceae

Aerial Part

Pigments

Composition, %: Chlorophyll a� 60.3; chlorophyll

b � 16.0; pheophytin a � 0.8; pheophytin b �0.3; pheophorbid a � 0.4; pheophorbid b � 0.3;

ethylchlorophyllide a� 1.9; ethylchlorophyllide

b� 0.8; chlorophyllide a� 12.0; chlorophyllide

b� 7.2; a-carotene � 4.5; b-carotene � 35.2; d-carotene� 0.6; 5,6-epoxy-lutein � 1.5; lutein�20.0; zeaxanthin � 2.5; violaxanthin � 9.2;

neoxanthin � 7.2; unidentified carotenoides �6.7 [1]

Carotenoids, 10�3%: 9.10 [1]

Chlorophylls, 10�3%: 109.3 [1]

Leaf

Essential oil, %: 0.06–0.375 [2]

Composition of essential oil (GC/MS, OV 101), %:

6-Methylhepten-2-ol � 2.2–8.6; citronellal �1.0–8.4; linalool � 0.5–2.7; neral – 19.6–36.1;

geranial� 25.3–47.5; geranyl acetate� 1.2–6.2;

b-caryophyllene-oxide � 0.5–9.0 and 62 com-

pounds as minor [2]

Seed

Mass of 1,000, g: 0.52 [3]

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Lamiaceae 432 Melittis melissophyllum L.

Oil, % dry wt: 39.0 [3]; 20.0–25.0 [4]

d20: 0.9370 [3]

Acid value, mg KOH: 2.72 [3]

Сolor: 2/2 [3]

Iodine value, % J2: 140.0–194.0 [4]

FAs

Composition (GLC, FFAP), %: 16:0 � 6.0; 18:0 �2.0; 18:1(9) � 4.0; 18:1(6) � 0.8; 18:2 � 36.4;

18:3 � 50.4 [3]

References

1. L.N. Pilipenko, L.B. Oleynik, V.V. Kozhukhar, Chem. Nat.

Comp. 33, 269 (1998)

2. G. Tittel, H. Wagner, R. Bos, Planta Med. 46, 91 (1982)

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

4. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Melittis melissophyllum L.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 125.9 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

6.1; 18:0 – 2.2; 18:1 – 51.2; 18:2 – 39.1; 18:3 – 1.4

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32 (1971)

Mentha aquatica L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), %: 25.0

n40D : 1.4750

Iodine value (Wijs), % J2: 184.0; 194.0 (cald)

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

5.7; 18:0 – 2.8; 18:1 – 11.0; 18:2 – 29.0; 18:3 –

51.0; and others – 0.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Mentha arvensis

Family: Lamiaceae

Seed and Pericarp

Ash, %: 8.9 [1]

Mass of 1,000, g: 0.1 [1, 2]

Oil, (petroleum ether, 30–60�C), % dry wt: 23.0 [1, 2]

n40D : 1.4752 [2]

Iodine value (Wijs), % J2: 199.0 [2]

Saponification value, mg KOH: 183.0 [2]

FAs

Composition (20% Apiezon L), %: Saturated� 9.0;

18:1 � 13.0; 18:2 � 16.0; 18:3 � 58.0 [2]

HBr uptake, as C18 epoxy, %: 1.6 [2]

IR [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

Mentha arvensis L.

Family: Lamiaceae

Essential oil, % dry wt: 0.16–0.37 [1]

[a]D: (�)2.44–(+)14.32� [1]d: 0.8570–0.9350 [1]

Ester value, mg KOH: 33.6 [1]

Ester value after acetylated, mg KOH: 134.0 [1]

Seed

Iodine value (Wijs), % J2: 199.0; 207.0 (cald) [2]

Page 45: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Mentha incana Willd. 433 Lamiaceae

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

5.2; 18:0 – 2.2; 18:1 – 9.5; 18:2 – 21.0; 18:3 –

62.0; others (1) – tr [2]

Use: The essential oil may be used in perfume and

food [1].

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 143 [in

Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Mentha asiatica

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.09 [1]

Oil (petroleum ether), %:22.2 [1]

d: 0.9245 [1]

n20D : 1.4827 [1]

Acid value, mg KOH: 2.4 [1]

Iodine value (Kaufmann), % J2: 202.3 [1]

Unsaponifables, %: 2.3 [1]

FAs

n20D : 1.4723 [1]

Iodine value (Kaufmann), % J2: 208.1; 203

(cald) [1]

Saponification value, mg KOH: 203.2 [1]

UV, IR [1]

Composition (GLC), %: 16:0 – 5.3; 18:0 – 1.6;

18:1 – 7.7; 18:2 – 29.8; 18:3 – 55.5; others (1)

– 0.1 [1]

TAG

Main components (Coleman), mole %: LeLeLe –

16.4; LLeLe – 15.2; OLeLe – 2.0; LeLLe – 11.9;

LeOLe – 5.9; PLeLe – 2.8; LLLe – 11.0; OLLe –

1.4; LOLe – 5.6; OLeL – 1.0; PLLe – 2.2; LLeL

– 3.5; POLe – 1.0; PLeL – 1.4; LePLe – 4.3; LLL

– 2.6; LOL – 1.3; PLL – 1.0; LPLe – 4.0 [2]

Composition, mole %: SSS – 0.01; SSU + USS –

0.68; SUS – 0.10; SUU – 9.86; USU – 5.72;

UUU – 83.63 [1]; SSS – 0.0; SSU + USS – 0.7;

USU – 10.1; SUS – 0.2; SUU + UUS – 9.2;

UUU – 79.8 [2]

FAs of TAG

Composition (GLC, 15% Reoplex 400), %: 16:0 –

5.7; 16:1(9) – tr; 18:0 – 1.6; 18:1(9) – 7.3; 18:2

(9,12) – 30.1; 18:3(9,12,15) – 56.3 [2]

12-Hydroxy-9Z,15Z-octadecadienoic acid [1]

MS [1]

Oxo acids

UV [1]

References

1. S.D. Gusakova, Kh.K. Kholmatov, A.U. Umarov, Chem. Nat.

Comp. 12, 134 (1976)

2. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Mentha dahurica Fisch.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.06–0.42

[a]D: 25.0–22.0�

d: 0.8651–0.8835

n40D : 1.4630–1.4685

Acid value, mg KOH: 0.66–1.0

Ester value, mg KOH: 10.27–23.32

Ester value after acetylated, mg KOH: 117.6–123.2

Stem

Essential oil, % dry wt: tr

Use: The essential oil may be used in food.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 142

Mentha incana Willd.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 218.7 (cald)

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Lamiaceae 434 Mentha longifolia (L.) Huds.

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.0; 18:0 – 1.2; 18:1 – 9.9; 18:2 – 33.2; 18:3 –

51.7

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Mentha longifolia (L.) Huds.

Family: Lamiaceae

Sterols, % dry wt: 0.05 [1]

Triterpenoic acids, % dry wt: Ursolic acid + oleanolic

acid - 0.74; uvaol, eritrodiol [1]

Terpenoids

Phytol, % dry wt: 0.04 [1]

Seed

Mass of 1,000, g: 0.01 [2]

Oil (petroleum ether, 30–60˚C), %: 28.0 [2]

n40D : 1.4752 [2]

Iodine value (Wijs), % J2: 197.0; 203.0 (cald) [2]

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

5.0; 18:0 – 2.1; 18:1 – 7.3; 18:2 – 30.0; 18:3 –

56.0; others (3) – 0.4 [2]

IR [2]

Seed

Oil (hexane) [3]

Iodine value, % J2: 207.4 (cald) [3]

FAs

Composition (GLC, 10% PEGA), mole %: 16:0 –

4.2; 18:0 – 1.4; 18:1 – 7.8; 18:2 – 31.6; 18:3 –

54.9 [3]

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Mentha piperita L.

Synonyms

M. officinalis Hull.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), %: 3.21 (from air-

dried plant material; Vojvodina, FR Yugoslavia, in

July, 2000, flowering stage) [1]

Composition (GC/MS, HP 5MS), %: a-Pinene –

0.12; sabinene – 0.20; b-pinene – 0.33; b-myrcene – 0.11; limonene – 0.10; 1.8-cineole –

0.8; 1-sabinene hydrate – 1.60; linalool – 0.31;

menthone – 8.93; isomenthone – 3.66; neo-

menthol – 2.11; menthol – 39.63; a-neo-isomenthol – 0.63; 1-a-terpineol – 3.0; pulegone– 1.59; piperitone – 0.88; bornyl acetate – 0.66;

methyl acetate – 10.44; isomethyl acetate – 0.64;

b-cubebene – 1.80; b-elemene – 2.48; (E)-

caryophyllene – 3.08; a-humulene – 0.46;

germacrene D – 0.25; epizonaren – 0.50; Z-b-farnesene – 0.54; spathulenol – 1.02; viridiflorol

– 1.11; t-muurolol – 0.21; 3-octanol – 0.05; total

– 87.24

Monoterpene hydrocarbons, %: 0.86

Oxygenated monoterpenes, %: 74.88

Sesquiterpene hydrocarbons, %: 9.11

Oxygenated sesquiterpenes, %: 2.34

Seed

Oil, %: 20.0 [2]

Iodine value, % J2: 194.0 [2]

Activity: Antibacterial activity of essential oil,

(20% and 50% solutions in n-hexane), millimeters,

including hole of 5 mm diameter: Escherichia coli –10.0–21.0 and 15.2–22.6, Salmonella enteritidis –

18.8 and 19.8, Salmonella typi – 28.0 and 20.8,

Shigella sonei – 42.0 and 47.4, Sarcina lutea – 15.8

and 16.0, Micrococcus flavus – 60.0 and 60.0, Staphy-

lococcus aureus – 20.0 and 39.8, Staphylococcus

epidermidis – 20.2 and 30.0, Bacillus subtilis – 18.6

and 22.2 [1]

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Mentha sp. 435 Lamiaceae

Antifungal activity, MIC and MFC, mL: Trichophytonmentagrophytes, Trichophyton rubrum,

Epidermophyton floccosum – 4 and 8, Trichophytontonsurans – both 8

DPPH-test: reached 50% of reduction with an IC50 of

2.53 mg/mL (BHT-2.45)

OH radical scavenging activity, %: 24.0

Use: Folium Menthae piperitae [3].

Oleum Menthae piperitae [3].

Tabulettae olei [3].

Tabulettae Pectusinum [3].

References

1. N. Mitica-Dukic, B. Bozin, M. Sokovic, B. Minajlovic,

M. Matavulj, Planta Med. 69, 413 (2003)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

3. M.D. Mashkovskii, Lekarstvennye sredstva (Meditsina,

Tashkent, 1988) 1, 346 [in Russian]

Mentha pulegiam L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), %: 27.0

n40D : 1.4754

Iodine value (Wijs), % J2: 193.0; 198.0 (cald)

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

6.4; 18:0 – 4.5; 18:1 – 6.5; 18:2 – 25.0; 18:3 –

57.0; others (5) – 0.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Mentha rotundifolia (L.) Huds.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.01

Oil (petroleum ether, 30–60�C), %: 25.0

n40D : 1.4750

Iodine value (Wijs), % J2: 193.0; 195.0 (cald)

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

6.3; 18:0 – 2.8; 18:1 – 8.5; 18:2 – 30.0; 18:3 –

52.0; others (5) – 0.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Mentha royleana L.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 210.8 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

3.6; 18:0 – 1.4; 18:1 – 6.7; 18:2 – 30.8; 18:3 – 57.5

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Mentha sp.

Family: Lamiaceae

Seed and Pericarp

Ash, %: 3.1 [1]

Mass of 1,000, g: 0.6 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 44.0%

[1, 2]

n40D : 1.4767 [2]

Iodine value (Wijs), % J2: 214.0 [2]

HBr, uptake, as C18 epoxy acid, %: 0.1 [2]

IR [2]

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Lamiaceae 436 Mentha spicata L.

FAs

Composition (GLC, 20% Apiezon L), %: Saturated

� 5.0; 18:1 � 9.0; 18:2 � 17.0; 18:3 � 64.0 [2]

References

1. F.R. Earle, Q. Jones, Econ.Bot. 16(4), 221 (1962)

2. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

Mentha spicata L.

Synonyms

M. crispa L.; M. viridis L., M

Family: Lamiaceae

Plant Material

Parts, %: Inflorescence – 8.7; leaves – 46.1; stem – 45.2

Inflorescence

Moisture and volatiles, % fresh wt: 75.3

Essential oil, % fresh wt: 0.08

Lipids, % fresh wt: 2.1

Lipids, % mg/g dry wt: 85.0

FAs, %: 61.8

Composition (GLC), %: 10:0 – 1.7; 12:0 – 6.3; 13:0

– 1.7; 14:0 – 1.4; 15:0 – tr; 16:0 – 16.7; 16:1 –

3.7; 17:0 – tr; 18:0 – 8.9; 18:1 – 7.3; 18:2 – 20.0;

18:3 – 32.3; 20:0 – tr

Leaf

Moisture and volatiles, % fresh wt: 74.8

Essential oil, % fresh wt: 0.24

Lipids, % fresh wt: 3.1

Lipids, % mg/g dry wt: 123.1

FAs, %: 61.8

Composition (GLC), %: 10:0 – 1.2; 12:0 – 9.3; 13:0

– 3.6; 14:0 – 1.7; 15:0 – 1.0; 16:0 – 17.5; 16:1 –

3.9; 17:0 – 0.8; 18:0 – 15.4; 18:1 – 4.8; 18:2 –

7.3; 18:3 – 29.5; 20:0 – 4.0

Stem

Moisture and volatiles, % fresh wt: 68.1

Lipids, % fresh wt: 0.6

Lipids, % mg/g dry wt: 18.8

FAs, %: 61.8

Composition (GLC), %: 10:0 – 4.6; 12:0 – 14.2;

13:0 – 7.8; 14:0 – 1.7; 15:0 – tr; 16:0 – 18.7; 16:1

– 2.1; 17:0 – tr; 18:0 – 15.4; 18:1 – 6.9; 18:2 –

9.7; 18:3 – 12.3; 20:0 – 6.6

References

1. T.V. Khomova, S.D. Gusakova, A. Nigmatullaev, Chem. Nat.

Comp. 33, 803 (1997)

Mentha sylvestris L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), %: 25.0

n40D : 1.4760

Iodine value (Wijs), % J2: 197.0; 200.0 (cald)

FAs

Composition (GLC; 20% LAC-2R 446), %: 16:0 –

5.4; 18:0 – 2.0; 18:1 – 8.0; 18:2 – 30.0; 18:3 –

54.0; others (8) – 1.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Mentha tomentosa D’Ury.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.04

Oil (petroleum ether, 30–60�C), %: 28.0

n40D : 1.4753

Iodine value (Wijs), % J2: 191.0; 197.0 (cald)

FAs

Composition (GLC; 20% LAC – 2R 446), %: 16:0 –

4.8; 18:0 – 2.7; 18:1 – 11.0; 18:2 – 29.0; 18:3 –

52.0; others (6) – 0.6

IR

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Monardella hypoleuca Gray Southern 437 Lamiaceae

References

1. J.M. Hageman, F.R. Earle, I.A.Wolff, A.S. Barclay, Lipids, 2,

371 (1967)

Micromeria benthami Webb. et Berth.

Family: Lamiaceae

Aerial Part

Betulinic acid

½a�20D : +3.50

M.p.

Micromeric acid

a�20D : +127

M.p.

References

1. J. Bermejo, J.L. Breton, G. De la Fuente, A.G. Gonzalez,

Tetrahedron Lett, 4649 (1967)

Monarda fistulosa

Family: Lamiaceae

Seed

Ash, %: 6.7 [1]

Mass of 1,000, g: 3.0 [1]

Oil, % dry wt: 31.8 [1]; 32.0 (petroleum ether, 30–

60�C) [2]n40D : 1.4756 [2]

Iodine value (Wijs), % J2: 210.0 [2]

Saponification value, mg KOH: 192.0 [2]

FAs

Composition (20% Apiezon L), %: 18:1 � 19.0;

18:2 � 18.0; 18:3 � 56.0 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, T.A. McGuire, J. Mallan, M.O. Bagby, I.A. Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

Monardalis sp.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.0

Oil, % dry wt: 26.8

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Monardella crispa Elmer

Family: Lamiaceae

Leaves and Stems

Essential oil (hydrodistillation)

Composition of essential oil (GLC, 3% SE 30 and

OV 17; GC/MS, WCOT), %: a-Pinene � 2.7; b-pinene � 0.5; camphene � 1.1; myrcene � 1.0;

a-phellandrene � 0.1; b-phellandrene � 0.2; a-thujene� tr; d-3-carene� 0.3; limonene� tr; b-caryophyllene � 0.4; caryophyllene isomer �0.2; trans-b-farnesene � 1.3; linalool � 0.2;

1;8-cineole � tr; citronellal � 0.5; isoborneol

� 2.0; piperitenone � 29.6; a-terpineol � 1.0;

pulegone � 57.0; piperitone � 0.6; carvacrol �tr; dihydrocarveol � tr; 4-terpineol � tr;

unknown alcohol � 1.0 (from air-dried plant

material, Santa Barbara Botanic Garden, USA)

References

1. B.D. Tanowitz, D.M. Smith, S.A. Junak, Phytochemistry 26,

2751 (1987)

Monardella hypoleuca Gray Southern

Family: Lamiaceae

Leaf

Terpenoids (solvent extraction, n-pentane–Et2O, 2:1,v/v; GLC, 3% SE 30 and 3% OV 17; GC/MS, HP

5840), %: Piperitone� 0.2; b-caryophyllene� 0.7;

Page 50: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 438 Monardella undulata Bentham var. undulata

piperitenone � 1.3; a-thujene � 3.4; 1,8-cineole �4.3; D-3-carene� 8.7; trans-b-farnesene� 76.0; b-pinene � tr; camphor � tr; isoborneol � tr; d-cadinene � tr; unidentified caryophyllene isomer

� tr (from fresh plant material, California)

References

1. B.D. Tanowitz, D.M. Smith, S.A. Junak, J. Nat. Prod. 47, 738

(1984)

Monardella undulata Bentham var.undulata

Family: Lamiaceae

Leaves and Stems

Essential oil (hydrodistillation)

Composition of essential oil (GLC, 3% SE 30 and

OV 17; GC/MS, WCOT), %: a-Pinene � 1.4; b-pinene � 0.6; camphene � 0.4; myrcene � 0.5;

a-phellandrene � tr; a-thujene � tr; d-3-carene� 1.3; g-terpinene � tr; limonene � tr; b-caryophyllene � 1.6; caryophyllene isomer �1.7; trans-b-farnesene � 2.2; linalool � tr; 1,8-

cineole� tr; isoborneol� tr; piperitenone� 4.8;

a-terpineol � 1.2; carveol � tr; pulegone � 0.5;

piperitone� tr; carvacrol� tr; dihydrocarveol�tr; 4-terpineol � tr; caryophyllene oxide � tr;

unknown alcohol � 1.7 (from air dried plant

material, Santa Barbara Botanic Garden, USA)

References

1. B.D. Tanowitz, D.M. Smith, S.A. Junak, Phytochemistry 26,

2751 (1987)

Monardella undulata var. frutescens

Family: Lamiaceae

Leaves and Stems

Essential oil (hydrodistillation)

Composition of essential oil (GLC, 3% SE 30 and

OV 17; GC/MS, WCOT), %: a-Pinene � 0.2; b-pinene � 0.7; camphene � tr; myrcene � 0.2;

b-phellandrene � tr; a-thujene � tr; d-3-carene� 1.5; limonene � tr; caryophyllene isomer �23.4; trans-b-farnesene � 15.4; linalool � 0.2;

1,8-cineole� tr; isoborneol� 0.5; a-terpineol�1.8; thymol � 0.3; pulegone � 54.5; piperitone

� 1.0; dihydrocarveol � tr (from air-dried plant

material, Santa Barbara Botanic Garden, USA)

References

1. B.D. Tanowitz, D.M. Smith, S.A. Junak, Phytochemistry 26,

2751 (1987)

Nepeta argolica ssp. dirphya (Boiss.) Stridand Kit Tan

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/w: 0.73 (endemic

in European Island)

Composition (GC/MS, HP 5MS), %: a-Thujene –

0.08; a-pinene – 0.59; sabinene – 0.63; 1-octen-3-ol – 0.17; b-pinene – 4.53; octanone-3 – 0.09;

myrcene-0.09; octanol-3 – 0.23; a-terpinene –

0.06; p-cymene – 0.45; 1;8-cineol – 5.88; g-terpinene – 0.14; cis-linalool oxide – 0.06; a-terpinolene – 0.13; linalool – 0.19; nonanal –

0.10; a-campholenal – 0.13; nopione – 0.23;

pinocarveol – 0.41; terpin-4-ol – 0.55; p-cymen-

8-ol – 0.11; a-terpineol – 0.62; myrtenal – 0.31;

myrtenol – 0.17; methyl 3-phenylpropionate –

0.24; ethyl 3-phenylpropionate – 0.16;

4aa,7a,7aa-nepetalactone – 58.05; b-bourbonene– 0.13; 4aa,7a,7ab-nepetalactone – 17.00;

dihydroisonepetalactone – 0.51; germacrene D –

0.18; d-cadinene – 0.68; a-bisabolol – 0.32; total –91.97

Activity: Inhibitory effects against Helicobacter

pylori, MICs, mg/mL: 32.0–256.0; MIC50 – 64.0;

MIC90 – 128.0 (ampicillin as standard – 0.15–0.6)

References

1. E. Kalpoutzakis, N. Aligiannis, A. Mentis, S. Mitaki,

C. Charvala, Planta Med. 67, 880 (2001)

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Nepeta cataria L. 439 Lamiaceae

Nepeta camphorate Boiss & Heldr. andBoiss.

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/w: 0.75 (at

flowering stage, jule 1999, endemic in Southern

Greece)

Composition (GC/MS, HP 5MS), %: a-Thujene –

0.11; a-pinene – 3.96; camphene – 0.08; 1-

Octen-3-ol – 0.09; b-pinene – 11.98; myrcene –

1.51; a-terpinene – 0.36; 1,8-cineol – 51.72; cis-b-ocimene – 0.67; cis-a-ocimene – 3.81; g-terpinene – 0.59; a-terpinolene – 0.26; linalool

– 0.44; a-campholenal – 0.14; nopione – 0.29;

pinocarveol – 1.15; trans-carveol – 0.35;

cuminal – 0.07; carvone – 0.07; terpinene-4-ol

– 1.76; a - terpineol – 5.87; myrtenal – 0.63;

myrtenol – 0.45; methyl 3-phenylpropionate –

0.30; ethyl 3-phenylpropionate – 0.16; a-copaene – 0.31; b-elemene – 0.08; a-gurjunene– 0.18; trans-b-caryophyllene – 0.20; trans-b –

farnesene – 0.20; germacrene D – 0.58;

bicyclogermacrene – 0.29; b-bisabolene – 0.19;

d-cadinene – 0.68; a-calacorene – 0.08;

germacrenol – 0.32; spathulenol – 0.27;

caryophyllene oxide – 0.47; guaiol – 0.15; total

– 93.22

Activity: Essential oil

Inhibitory effects, MICs, mg/mL: 64.0–512.0;

MIC50 – 128.0; MIC90 – 256.0

1,8-Cineol

Inhibitory effects against Helicobacter pylori,

MICs, mg/mL: 32.0–256.0; MIC50 – 64.0;

MIC90 – 128.0 (ampicillin 0.15–0.6)

4aa, 7aa-Nepetalactone 1

½a�20D : 2.5� (c 0.30 CHCl3)1H NMR

Inhibitory effects, MICs, mg/mL: >16.0–64.0;

MIC50 – 64.0; MIC90 – 128.0

4aa, 7a, 7aa-Nepetalactone½a�20D : 18.6 (c 0.25 CHCl3)1H NMR

Inhibitory effects, MICs, mg/mL: 32.0 – 256.0;

MIC50 – 64.0; MIC90 – 128.0

References

1. E. Kalpoutzakis, N. Aligiannis, A. Mentis, S. Mitaki,

C. Charvala, Planta Med. 67, 880 (2001)

Nepeta cataria

Family: Lamiaceae

Seed and Pericarp

Ash, %: 3.2 [1]

Mass of 1,000, g: 0.5 [1]

Oil, % dry wt: 21.2 [1]; 21.0 (petroleum ether, 30–

60�C) [2]n40D : 1.4754 [2]

Iodine value (Wijs), % J2: 201.0 [2]

Saponification value, mg KOH: 185.0 [2]

HBr, uptake, as C18 epoxy acid, %: 0.2 [2]

IR [2]

FAs

Composition (20% Apiezon L), %: Saturated� 8.0;

18:1 � 12.0; 18:2 � 18.0; 18:3 � 57.0 [2]

Seed

Oil, % dry wt: 24.7 [3]

TAG

FAs (GLC, 17% PEGS), %: 16:0 � 6.3; iso-17:0 –

tr; 18:0 � 0.7; 18:1 � 11.0; 18:2 � 24.5; 18:3 �57.5 [3]

Free FAs

Composition, %: 16:0 � 3.0; iso-17:0 – 0.3; 18:0 �0.5; 18:1 � 4.2; 18:2 � 25.6; 18:3 � 66.4 [3]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

3. T.V. Khomova, Autor’s Abstract of Candidate’s Dissertation

(Tashkent, 1985)

Nepeta cataria L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.27 (1); 0.11 (2) [1]

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Lamiaceae 440 Nepeta cataria L.

[a]D: (�)1.12–(�)2.49� (1); 11.4� (2) [1]d: 0.8810–0.8970 (1); 1.044 (2) [1]

n40D : 1.4740–1.4829 (1); 1.4891 (2)

Acid value, mg KOH: up to 28.8 (1); 63.02 (2) [1]

Ester value, mg KOH: up to 36.7 (1); 254.05 (2) [1]

Ester value after acetylated, mg KOH: 35.0–286.0

(1); 330.4 (2) [1]

Saponification value, mg KOH: 314.07 (2) [1]

Components, %: Citronellol – 25.0; geraniol – 17.0;

citral – 13.0; limonene + dipentene – 8.0; other

alcohols and sesquiterpene hydrocarbons (2) [1]

Inflorescence

Essential oil, % dry wt: 0.22 [1]

Leaf

Essential oil, % dry wt: 0.54 [1]

Seed

Mass of 1,000, g: 0.5 [2]

Oil, % dry wt: 21.0 (petroleum ether, 30–60�C) [2];24.8 (hexane) [3]

d: 0.9208 [3]

n40D : 1.4754 [1]; 1.4821[3]

Acid value, mg KOH: 3.3 [3]

Iodine value (Wijs), % J2: 201; 201 (cald) [1]; 212.3

[3]

Unsaponifables, %: 2.9 [3]

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

6.0; 18:0 – 2.0; 18:1 – 10; 18:2 – 20; 18:3 – 60;

others (3) – 1.3 [3]

Allenic acid (IR), %: 1.2 [2]

IR [2]

Lipids

Composition (TLC): Hydrogenes + Ester of sterols

+ methyl ethers of FAs – 2.2; TAGs – 85.0; di-2-

ethylhexylphtalate + free FAs + sterols + a,a’-DAGs + a,b-DAGs – 12.5; MAGs – 0.3; PhLs –

tr [3]

FAs of Methyl ethers

Composition (GLC; 15% Reoplex 400), %:

12:0 – 1.0; iso – 13:0 – 1.0; 14:0 – 1.1; 15:0 –

0.6; 16:0 – 22.3; iso – 17:0 – 0.9; 18:0 – 12.4;

18:1(9) – 23.9; 18:2(9;12) – 20.6; 18:3(9,12,15) –

16.2 [3]

TAG

Main components (Coleman), mol %: LeLLe –

24.5; LLLe – 8.6; PLLe – 6.6; OLLe – 3.6;

PLL – 1.2; LLL – 0.8; PLO – 0.6; StLLe – 0.6;

OLL – 0.6; PLP – 0.4; StLL – 0.2; OLO – 0.1;

LeLeLe – 14.9; LLeLe – 5.2; PLeLe – 4.0; OLeLe

– 2.2; PLeL – 0.8; LLeL – 0.5; StLeLe – 0.4;

OLeL – 0.4; PLeP – 0.3; PleO – 0.2; OLeO – 0.1;

LeOLe – 11.2; LOLe – 4.0; POLe – 3.0; OOLe –

1.6; POL – 0.6; OOL – 0.4; LOL – 0.4; POO –

0.2; StOLe – 0.2; POP – 0.2; OOO – 0.1; LePLe –

0.7; LPLe – 0.2; OPLe – 0.2; PPLe – 0.2 [3]

Composition, mol %: SSU – 0.2; SUS – 0.9; USU –

1.1; SUU – 18.6; UUU – 79.2 [3]

FAs of TAG

Composition (GLC; 15% Reoplex 400), %: 16:0 –

6.3; iso-17:0 – tr; 18:0 – 0.7; 18:1 – 11.0; 18:2 –

24.5; 18:3 – 57.5 [3]

Free FAs

Composition (GLC; 15% Reoplex 400), %: 16:0 –

3.0; iso-17:0 – 0.3; 18:0 – 0.5; 18:1 – 4.2; 18:2 –

25.6; 18:3 – 66.4 [3]

FAs of DAG

Composition (GLC; 15% Reoplex 400), %: 12:0 –

0.3; 14:0 – 0.5; 16:0 – 6.9; iso-17:0 – 1.0; 18:0 –2.4; 18:1 – 11.8; 18:2 – 19.4; 18:3 – 57.7 [3]

FAs of MAG

Composition (GLC; 15% Reoplex 400), %: 12:0 –

0.9; 16:0 – 9.8; iso-17:0 – 2.6; 18:0 – 3.2; 18:1 –

14.3; 18:2 – 22.5; 18:3 – 46.7 [3]

Sterols: b-Sitosterol [3]

Stem

Essential oil, % dry wt: 0.009 [1]

Use: The essential oil may be used in perfume and in

food as spice [1].

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 130 [in

Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. T.V. Khomova, S.D. Gusakova, A.U. Umarov, Chem. Nat.

Comp. 14, 139 (1978)

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Nepeta grandiflora 441 Lamiaceae

Nepeta congesta Fisch. and Mey.

Family: Lamiaceae

Mass of 1,000, g: 1.0

Oil (petroleum ether, 30–60�C), % dry wt: 17.0

n40D : 1.4766

Iodine value (Wijs), % J2: 202.0; 207.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.4; 18:0 – 1.6; 18:1 – 10.0; 18:2 – 19.0; 18:3 –

64.0; others (3) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta cyeanea Stev.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 18.6

Components of oil (TLC): Hydrocarbons, steryl

esters, TAG, free FAs, DAG, MAG, sterols,

chlorophylls

TAG

FAs (GLC), %: 16:0 � 4.5; 16:1 � 0.5; 18:0 � 1.5;

18:1 � 14.2; 18:2 � 14.8; 18:3 � 64.5

Free FAs

Composition (GLC), %: 16:0� 9.0; 16:1� 1.3; 18:0

� 2.4; 18:1 � 17.1; 18:2 � 18.9; 18:3 � 51.3

References

1. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Nepeta distants Raul

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 18.2

Components of oil (TLC): Hydrocarbons, steryl

esters, TAG, free FAs, sterols

TAG

FAs (GLC, 17% PEGS), %: 16:0 – 4.2; 16:1 � 0.8;

18:0 � 1.8; 18:1 � 11.7; 18:2 � 20.8; 18:3 �61.7

Free FAs

Composition (GLC), %: 16:0 � 16.3; 16:1 � 12.9;

18:0� 10.7; 18:1� 17.9; 18:2� 19.3; 18:3� 22.9

References

1. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Nepeta glomerulosa Boiss.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4753

Iodine value (Wijs), % J2: 195.0; 199.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.8; 18:0 – 7.7; 18:1 – 11.0; 18:2 – 17.0; 18:3 –

61.0; others (8) – 0.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta grandiflora

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 19.1

Components of oil (TLC): Hydrocarbons, steryl

esters, TAG, free FAs, DAG, MAG, sterols

TAG

FAs (GLC), %: 16:0 � 4.2; 16:1 � 0.4; 18:0 � 1.7;

18:1 � 14.6; 18:2 � 13.9; 18:3 � 65.2

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Lamiaceae 442 Nepeta grandiflora M.B.

Free FAs

Composition (GLC), %: 16:0 � 16.9; 16:1 � 4.1;

18:0� 11.0; 18:1� 45.1; 18:2� 15.7; 18:3� 7.2

References

1. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Nepeta grandiflora M.B.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 226.4 (cald.)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.4; 18:0 – 1.4; 18:1 – 8.5; 18:2 – 26.3; 18:3 – 59.4

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Nepeta involuczata (Bunge) Born

Family: Lamiaceae

Aerial Part

Essential oil (hydro distillation), % dry wt (w/w): 0.2

(air dried, Iran)

Composition (GC and GC/MS, DB 1), %: a-Thujene – 0.1; a-pinene – 4.9; sabinene – 6.7;

b-pinene – 12.2; myrcene – 1.4; a-terpinene –

0.6; 1,8-cineole – 23.1; (Z)-ocimene – 0.2; g-terpinene – 1.1; trans-sabinene hydrate – 0.2;

terpinolene – 0.6; linalool – 0.1; cis-verbenol –

0.1; a-campholenal – 0.6; trans-p-menth-2-en-1-

ol – 0.1; trans-pinane – 0.2; cis-limonene oxide –

0.1; trans-limonene oxide – 0.1; trans-

pinocarveol – 1.8; trans-verbenone – 0.8;

pinocarvone – 1.2; p-menth-1-en-8-ol – 1.3; 4-

terpineol – 1.9; a-terpineol – 3.3; myrtenol – 0.6;

trans-piperitol – 0.1; trans-carveol – 0.9;

carvone – 1.4; perilla aldehyde – 0.3; a-copaene– 0.6; b-bourbonene – 1.7; b-cedrene – 1.1; b-caryophyllene – 0.1; b-cubebene – 0.4; b-gurjunene – 0.4; b-lonone – 0.1; g-muurolene –

0.1; germacrene D – 15.1; bicyclogermacrene –

1.4; d-cadinene – 2.1; 2,3,3-trimethyl-2-(3-

methyl-1,3-butadienyl)-cyclohexanone – 1.5;

spathulenol – 2.3; caryophyllene oxide – 2.3; d-cadinol – 2.2; a-cedrol – 0.3; t-muurolol – 1.3

Monoterpene hydrocarbons – 27.8

Oxygenated monoterpenes – 38.3

Sesquiterpene hydrocarbons – 23.2

Oxygenated sesquiterpenes – 10.0

References

1. A. Sonboli, P. Salehi, L. Allahyari, Chem. Nat. Comp. 41, 562

(2005)

Nepeta italica L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.3

Oil (petroleum ether, 30–60�C), % dry wt: 22.0

n40D : 1.4757

Iodine value (Wijs), % J2: 196.0; 203.0 (cald)

FAs

Composition (GLC on 20% LAC – 2R 446), %:

16:0 – 4.9; 18:0 – 2.3; 18:1 – 10.0; 18:2 – 23.0;

18:3 – 59.0; others (6) – 0.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta latifolia L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60� C), % dry wt: 17.0

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Nepeta nepetella L. 443 Lamiaceae

n40D : 1.4756

Iodine value (Wijs), % J2: 196.0; 204.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.2; 18:0 – 1.6; 18:1 – 11.0; 18:2 – 20.0; 18:3 –

61.0; others (5) – 0.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta manchuriensis S. Moore

Family: Lamiaceae

Herbal

Essential oil, % dry wt: 0.17

Inflorescence

Essential oil, % dry wt: 2.52

Leaf

Essential oil, % dry wt: 0.77

Stem

Essential oil, % dry wt: 0.28

Use: The essential oil may be used in food as spice.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p.129 [in

Russian]

Nepeta micrantha Bge.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 237.7 (cald.)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

3.9; 18:0 – 1.4; 18:1 – 7.1; 18:2 – 18.9; 18:3 – 68.7

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Nepeta Mussinii Spreng.

Family: Lamiaceae

Seed and Pericarp

Ash, %: 8.0 [1]

Mass of 1,000, g: 8.0 [1]

Oil, % dry wt: 25.3 [1]

Seed

Oil (petroleum ether, 30–60�C), % dry wt: 25.0 [2]

n40D : 1.4749

Iodine value (Wijs), % J2: 200.0

Saponification value, mg KOH: 184.0

FAs

Composition (20% Apiezon L), %: Saturated� 6.0;

18:1 � 17.0; 18:2 � 18.0; 18:3 � 55.0 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, T.A. McGuire, J. Mallan, M.O. Bagby, I.A. Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

Nepeta nepetella L.

Family: Lamiaceae

Flowers and Leaves

Essential oil (steam distillation), % dry wt: 1.24 (from

dried plant material; Aosta Valley, Valnontey, Italy,

1700 mts a.s.l.) [1]

Compounds (HPLC pre-separation; GLC, HTS-OV

1, GC/MS OV-1), %: 2-Methylmethylbutanoate

– tr; menth-1-(7)-ene – tr; 2-methyl pentanol – tr;

trans-3-hexenal – tr; ethyl valerate – tr; 1,3,5,7

cyclooctatriene – tr; b-pinene – tr; methyl

hexanoate – tr; methyl-2-hexanoate – tr; benzal-

dehyde – tr; propyl isovalerate – tr; octen-3-ol –

0.5; phenylacetaldehyde – tr; p-cymene – tr;

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Lamiaceae 444 Nepeta nuda

ocimene – 0.4; acetophenone – tr; butyl valerate

– tr; car-3-ene – 1.6; matatabiether – tr; terpinen-

4-ol – tr; geranial – tr; linalool – tr; penthyl

valerate – tr; 1,3-dimethyl-2-acetylcyclo-pent-

2-ene – tr; methyl salicylate – tr; a-terpineol –tr; 3-oxobicyclo(4,3,0)-nonen-2-one – tr;

unidentified – tr; hexenyl valerate – tr;

phenylethyl valerate – tr; phenylethyl acetate –

tr; unidentified – tr; nepetalactone – 76.5;

epinepetalactone – 0.6; geranyl acetate – 0.9;

dihydronepetalactone – 1.6; cis-caryophyllene

– 0.4; trans-b-caryophyllene – 7.0; humulene –

tr; b-ionone – tr; trans-b-farnesene – 2.8;

neonepetalactone – 0.4; sesquiterpenoid – tr;

geranyl propionate – tr; sesquiterpene hydrocar-

bon – 2.4; dehydronepetalactone – tr; sesquiter-

pene alcohol – tr [1]

Seed

Mass of 1,000, g: 0.4 [2]

Oil (petroleum ether, 30–60˚C), % dry wt: 27.0 [2]

n40D : 1.4754 [2]

Iodine value (Wijs), % J2: 194.0; 198.0 (cald) [2]

FAs

Composition (GLC, 20% LAC − 2R 446), %: 16:0 –

6.6; 18:0 – 2.8; 18:1 – 10.0; 18:2 – 22.0; 18:3 –

58.0; others (6) – 0.7 [2]

IR [2]

References

1. C. Bicchi, M. Mashaly, P. Sandra, Planta Med. 50, 96 (1984)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta nuda

Synonyms

Nepeta pannonica L.

Family: Lamiaceae

Aerial Part

Seedlings grown in the greenhouses of the Botanical

Garden of the University of Gent, Belgium; Seeds

obtained from the Botanical Gardens of FRG [1].

Essential oil, %: 0.03–0.3 (air dried) [1]

Composition (by treatment with steam distillation

for 3 h, followed by exhaustive extraction of the

steam distillate with CH2Cl2; GLC, OV-1, GC/

MS, SE 30) %: a-Pinene – tr – 0.7; camphene –

tr; sabinene – 0.1 – 0.3; b-pinene – 0.5–2.9; 3-

octanone – tr – 0.2; myrcene – tr – 0.7; p-cymene –

tr – 0.1; 1,8-cineole (+ limonene) – 11.2–38.0;

cis-b-ocimene – tr – 0.7; trans-b-ocimene – tr –

3.8;g-terpinene– tr; cis-sabinenehydrate–0.1–0.7;linalool – tr; trans-sabinene hydrate – tr – 0.2;

d-terpineol – tr – 0.7; terpinen-4-ol – tr – 0.4;

2-methyl-2,3-dihydroindole+a-terpineol – tr –

5.3; 4ab; 7a 7aa-nepetalactone – tr – 18.4; 4aa,7a,7aa-nepetalactone – 0.9-–6.0; 4aa,7a,7ab-nepetalactone – 6.7–76.6; 4ab,7a,7ab-nepetalactone – 1.6–4.5; a-copaene – 0.6–1.8;

b-bourbonene – 0.7–4.5; b-elemene – 0.2–0.9;

n-tetradecane – tr – 0.1; b-caryophyllene – 0.4 –2.4; g-muurolene – 0.1–0.7; unidentified sesqui-

terpene – tr – 0.6; b-farnesene – 0.4–2.4;

alloaromadendrene(?) – tr – 0.3; dehydronepe-

telactone – tr – 0.2; germacrene – 0.2 – 23.0; a-elemene – tr – 0.9; a-farnesene – tr – 0.3; b-bisabolene – tr – 1.6; d-cadinene – 0.3 – 1.7;

caryophyllene oxide – 0.4 – 2.4 [1]

Seedlings grown in the greenhouses of the

Botanical Garden of the University of Gent,

Belgium; Seeds are wild origin from Armenia,

USSR [1]

Essential oil [1]Composition (by treatment with steam for 3 h,

followed by exhaustive extraction of the steam

distillate with CH2Cl2; GLC, OV-1, GC/MS, SE

30) %: a-Pinene – tr; sabinene – tr; b-pinene –

0.1–0.5; 3-octanone – 0.1–0.3; myrcene – tr –

0.7; p-cymene – tr; 1,8-cineole (+limonene) –

1.8–6.7; cis-b-ocimene – tr, trans-b-ocimene –

tr – 0.3; trans-sabinene hydrate – tr; d-terpineol –tr; 2-methyl – 2,3-dihydroindole + a – terpineol –tr – 0.6; 4ab, 7a,7aa-nepetalactone – tr – 3.9;

4aa,7a,7aa-nepetalactone – 4.8–7.1; 4aa,7a,7ab-nepetalactone – 22.6–74.4; 4ab,7a,7ab-nepetalactone – 1.4–54.8; a-copaene – 0.4–2.5;

b-bourbonene 0.8 – 2.7; b-elemene – tr – 0.2; n-

tetradecane – tr; b-caryophyllene – 1.3–2.7; g-muurolene – tr – 0.3; unidentified sesquiterpene –

tr – 0.2; b-farnesene – 0.6–0.7; alloaromadendrene

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Nepeta pannonica L. 445 Lamiaceae

(?) – tr – 0.2; dehydronepetelactone – tr;

germacrene – 0.4–4.6; a-farnesene – tr; b-bisabolene – tr; d-cadinene – 0.1–1.0;

caryophyllene oxide – 0.6–6.4 [1]

4ab,7a,7aa-NepetalactoneMS [1]

Seed

Oil, %: 20.34 [2]

n20D : 1.4834 [2]

Iodine value, % J2: 192.0 [2]

References

1. H.L. De Pooter, B. Nicolai, L.F. De Buyck, P. Goetghebeur,

N.M. Schamp, Phytochemistry 26, 2311 (1987)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 444 [in

Russian]

Nepeta nuda L. var. albiflora B.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.5

Oil (petroleum ether, 30–60�C), % dry wt: 23.0

n40D : 1.4752

Iodine value (Wijs), % J2: 197.0; 203.0 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

5.3; 18:0 – 2.5; 18:1 – 11.0; 18:2 – 18.0; 18:3 –

62.0; others (7) – 1.1

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta oxyodonta Boiss.

Family: Lamiaceae

Aerial part

Essential oil (hydro distillation), % dry wt: 0.2 (w/w)

(air dried, Iran)

Composition (GC/MS, HP 5MS), %: trans-2-

hexenal – 0.4; a-thujene – 0.2; a-pinene – 3.2;

sabinene – 1.6; b-pinene – 1.4; myrcene – 0.2; 2-

octanol – 0.1; a-terpinene – 0.1; p-cymene – 0.1;

limonene – 0.1; 1,8-cineole – 3.3; trans-b-ocimene – 0.1; g-terpinene – 0.2; cis-sabinene

hydrate – 0.1; terpinolene – 0.1; linalool – 0.3;

nonanal – 0.2; p-menth – 2-en-1-ol – 0.1; a-campholene aldehyde – 0.1; cis-verbenol – 0.2;

trans-verbenol – 0.2; terpinen-4-ol – 0.5; a-terpineol – 0.3; myrtenol – 0.3; decanal – 0.1;

bicycloelemene – 0.2; a-copaene – 1.6; b-bourbonene – 8.1; b-elemene – 1.3; (Z)-caryophyllene – 0.1; a-gurjunene – 0.2; (E)-

caryophyllene – 12.6; b-gurjunene – 1.1; cis-a-bergamoten – 0.2; cis-b-farnesene – 0.6; a-humulene – 0.9; allo-aromadendrene – 1.9;

germacrene D – 7.4; b-lonone – 0.3; cis-b-guaiene – 0.2; bicyclogermacrene – 1.7; a-muurolene – 0.5; (E;E)-a-farnesene – 0.1; g-cadinene – 0.4; d-cadinene – 0.6; b-sesquiphellandrene – 0.6; cadina – 1;4-diene –

0.1; a-cadinene – 0.2; ledol – 0.4; germacrene D-

4-ol – 6.8; spathulenol – 8.5; caryophyllene

oxide – 5.3; viridiflor–1.6; cedrol – 0.9;

humulene epoxide II – 1.3; t-cadinol – 5.6; b-eudesmol – 1.8; a-cadinol – 7.3

References

1. S.E. Sajjadi, B. Eskandari, Chem. Nat. Comp. 42, 141

(2005)

Nepeta pannonica L.

Family: Lamiaceae

Terpenoids

Phytol, % dry wt: 0.05 [1]

Sterols, % dry wt: 0.03 [1]

Triterpenoic acids, % dry wt: Ursolic acid – 0.50 [1]

Seed

Mass of 1,000, g: 0.4 [2]

Oil, % dry wt: 22.0 (petroleum ether, 30–60˚C) [2];

24.6 (hexane) [3]

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Lamiaceae 446 Nepeta russini Spreng.

n40D : 1.4754 [2]

Iodine value (Wijs), % J2: 197.0; 199.0 (cald) [2]

FAs

Composition (GLC, 20% LAC – 2R 446), %: 16:0 –

5.0; 18:0 – 2.0; 18:1 – 11.0; 18:2 – 22.0; 18:3 –

58.0; others (10) – 2.7 [2]

IR [2]

FAs

Composition (GLC, 15% Reoplex 400), %: 16:0 –

3.0; 16:1(9) – 0.3; 18:0 – 0.6; 18:1(9) – 5.5; 18:2

(9,12) – 18.8; 18:3(9,12,15) – 71.8 [3]

TAG

Main components (Coleman), mole %: LeLeLe –

33.9; LLeLe – 12.2; OLeLe – 0.4; LeLLe – 18.7;

LeOLe – 10.8; PLeLe – 0.4; LLLe – 6.6; OLLe –

0.4; LOLe – 3.8; OOLe – 0.2; OLeL – 0; PLLe –

0.4; LLeL – 1.1; POLe – 0.2; PLeL – 0.2; PLeO –

0; OLeO – 0.4; LePLe – 6.0; LLL – 0.7; LOL –

0.3; PPLe – 0.1

Compositions, mole %: SSU + USS – 0.1; USU –

6.2; SUS – 0.2;UUS+SUU– 1.6;UUU– 91.9 [3]

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. resursy (in Rus-

sian), 12(2), 247 (1976)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Nepeta russini Spreng.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4760

Iodine value (Wijs), % J2: 200.0; 206.0 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

4.7; 18:0 – 2.2; 18:1 – 9.2; 18:2 – 21.0; 18:3 –

61.0; others (7) – 1.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta sp.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 17.5

Components (TLC): Hydrocarbons, steryl esters,

TAG, free FAs, DAG, MAG, sterols

TAG

FAs (GLC), %: 16:0 � 3.2; 16:1 � 0.3; 18:0 � 1.6;

18:1 � 13.8; 18:2 � 18.7; 18:3 � 62.4

Free FAs

Composition (GLC), %: 16:0 � 3.4; 16:1 � 2.3;

18:0� 2.5; 18:1� 7.4; 18:2� 17.4; 18:3� 67.0

References

1. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Nepeta spicata Benth.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.4

Oil (petroleum ether, 30–60�C), % dry wt: 41.0

n40D : 1.4757

Iodine value (Wijs), % J2: 202.0; 206.0 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

5.0; 18:0 – 3.2; 18:1 – 11.0; 18:2 – 17.0; 18:3 –

64.0; others (2) – 0.1

Allenic acid (IR), %: 15.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta sulphurea C. Koch.

Family: Lamiaceae

Seed

Oil (hexane)

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Ocimum basilicum L. 447 Lamiaceae

Iodine value, % J2: 223.1 (cald)

FAs

Composition (GLC, 10%PEGA), mol%: 16:0 – 5.1;

18:0 – 1.3; 18:1 – 10.1; 18:2 – 24.0; 18:3 – 58.8

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32 (1971)

Nepeta timolea Boiss.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60�C), % dry wt: 29.0

n40D : 1.4761

Iodine value (Wijs), % J2: 200.0; 206.0 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

5.3; 18:0 – 3.0; 18:1 – 8.5; 18:2 – 18.0; 18:3 –

64.0; others (6) – 1.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta tuberosa L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.5

Oil (petroleum ether, 30–60�C), % dry wt: 19.0

n40D : 1.4764

Iodine value (Wijs), % J2: 202.0; 206.0 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

5.6; 18:0 – 2.1; 18:1 – 8.7; 18:2 – 13.0; 18:3 –

68.0; others – 3.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Nepeta ucrainica L.

Family: Lamiaceae

Seed

Oil, %: 25.0

Iodine value, % J2: 189.2

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 444 [in

Russian]

Ocimum americanum L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.9

Oil (petroleum ether, 30–60�C), % dry wt: 18.0

n40D : 1.4753

Iodine value (Wijs), % J2: 186.0; 194.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.2; 18:0 – 3.1; 18:1 – 15.0; 18:2 – 17.0; 18:3 –

58.0; others (6) – 0.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ocimum basilicum L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 1.65 [1]

Oil, % dry wt: 21.2 [1]; 24.0 [2] (petroleum ether, 30–

60˚C); 11.6 – 19.0 [3]; 24.2 (hexane) [4]

Сolor: dresden yellow 64/1 [1]

d20: 0.9141 [1]

n40D : 1.4742 [2]; 1.4770 [3]

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Lamiaceae 448 Ocimum canum Sims.

Acid value, mg KOH: 7.53 [1]

Iodine value, % J2: 191.0 [2]; 93.8–179.8 [3]

Saponification value, mg KOH: 188.0 [2]; 194.5 [3]

FAs

Composition (GLC), %: 16:0 – 8.1; 18:0 – 2.8; 18:1

(9) – 7.9; 18:1(6) – 0.7; 18:2 – 20.0; 18:3 – 59.3

(FFAP) [1]; Saturated – 8.0; 18:1 – 15.0; 18:2 –

22.0; 18:3 – 50.0 (20% Apiezon L) [5]

TAG

Main components (Coleman), %: LeLeLe – 24.9;

LLeLe – 9.7; OLeLe – 5.7; LeLLe – 15.1;

LeOLe – 6.2; PLeLe – 7.0; LLLe – 5.8; OLLe

– 3.4; LOLe – 2.4; OOLe – 1.4; OLeL – 1.0;

PLLe – 4.6; LLeL – 0.9; POLe – 2.0; PLeO – 1.0;

LePLe – 1.1; PLL – 1.0; POO & others – 5.2 [4]

Composition, %: SSS – 0.0; SSU + USS – 0.2; USU

– 2.0; SUS – 0.9; UUS + SUU – 17.4; UUU –

79.5 [4]

FAs (GLC, 15%Reoplex 400), %: 16:0 – 6.3; 16:1 – tr;18:0 – 1.3; 18:1 – 9.6; 18:2(9, 12) – 19.4; 18:3 –

63.4 [4]

Seed and Pericarp

Ash, %: 7.2 [6]

Mass of 1,000, g: 1.3 [6]

Oil, % dry wt: 24.2 [6]

References

1. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Pol. 44(3), 161

(1998)

2. F.R. Earle, T.A. McGuire, J. Mallan, M.O. Bagby, I.A. Wolff,

J. Amer. Oil Chem. Soc. 37, 48 (1960)

3. N.I. Sharapov, Oil Plants and the Process of Oil Formation(ASUSSR Press,Moskwa-Leningrad, 1959), 351 [in Russian]

4. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

5. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Amer.

Oil Chem. Soc. 37, 440 (1960)

6. F.R. Earle, Q Jones, Econ. Bot. 16(4), 221 (1962)

Ocimum canum Sims.

Family: Lamiaceae

Aerial Part

Essential oil (cold acetone, steam distillation), % of the

weight of the fresh plant: 0.5–0.7 (Somalia) [1]

Composition of essential oil (Carbowax 1000), %:

a-Pinene � 2.0; camphene-2.0; b-pinene � 0.2;

sabinene � tr; a-phellandrene � 0.4; myrcene �2.0; limonene � 13.0; b-phellandrene or b-terpinene � 0.2; 1,8-cineol � 0.4; g-terpinene� 3.0; p-cymene � 1.0; terpinolene � 1.0;

diacetonalcohol (artifact) � 1.0; 1- octen-3-ol

� 2.0; trans-sabinene hydrate � 0.2; camphor

� 60; cis-sabinene hydrate� 0.2; caryophyllene

� 2.0; b-elemene� 0.3; alcohol C10H18O� 0.2;

terpinen-4-ol � 0.6; humulene � 0.1; borneol �0.3; b-selinene � 3.0; a-selinene � 3.0;

isoborneol � 1.0; hydrocarbon C15H24 � 0.1;

hydrocarbon C15H24 � 0.1; myrtenol � 0.4

Seed

Oil, %: 10.0

Iodine value, % J2: 127.0

References

1. С.C. Xaasan, A.D. Cabdulraxmaan, S. Passannanti, F. Piozzi,

J.P. Schmid, J. Nat. Prod. 44, 752 (1981)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

Ocimum gratissimum L.

Family: Lamiaceae

Leaf

Essential oil (hydrodistillation), % fresh wt: 0.5 (from

fresh plant material) [1]

Composition of essential oil (GC/MS, HP 5 and

Carbowax 20 M), %: a-Thujene � 4.1; a-pinene� 5.3; camphene � 0.1; sabinene � 0.3; b-pinene � 0.9; myrcene � 3.4; a-phellandrene� 0.5; d-3-carene � 2.1; a-terpinene � 2.9; p-cymene� 1.6; b-phellandrene� 21.1; limonene

� 11.4; 1,8-cineole � 1.3; (Z)-b-ocimene� 0.2;

(E)-b-ocimene � 0.2; g-terpinene � 21.9;

sabinene hydrate � 0.9; terpineolene � 1.6; lin-

alool � 0.4; terpinen-4-ol � 1.4; a-terpineol �0.4; thymol � 11.2; d-elemene � tr; a-copaene� 0.4; b� elemene� tr; b-caryophyllene� 2.1;

alloaromadendrene � 0.1; germacrene-D � tr;

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Ocimum kilimandscharicum (R. Br.) Guerke 449 Lamiaceae

a-selinene� 0.8; g-muurolene� 0.3; g-cadinene� 0.5; T-cadinol � 0.1; a-cadinol � 0.1; total �97.9 [1]

Activity: Antimalarial activity (in vivo), at concen-

trations of 200, 300, and 500 mg/kg of mouse per day,

%: The essential oil produced the activity with the

respective percentage of suspression of parasitemia

(Plasmodium berghei): 62.1, 81.7, and 86.6 [1].

Leaves and Flowers

Essential oil, % (vol/wt, from fresh plant material):

0.40 (Sample A, growing Rwanda); 0.65 (Sample

B, cultivated in Butare, Rwanda from seeds of

plants grown in Cameroon) [2]

Composition of essential oil (GC/MS, Durabond-

DB 1), %: trans-Hex-2-enal � 0.1; a-thujene �3.0; a-pinene � 1.0; camphene � 0.1; oct-1-en-

3-ol� 0.3; 3-octanone� 0.1; sabinene� 0.5; b-pinene � 0.4; myrcene-3.1; a-phellandrene-0.3;D3-carene-0.2; a-terpinene � 3.0; p-cymene �5.8; 1,8-cineole � 0.3; limonene � 0.9; cis-b-ocimene � 1.8; trans-b-ocimene � 0.3; g-terpinene � 22.9; trans-sabinene hydrate � 0.4;

a-p-dimethylstyrene � 0.9; terpinolene � 0.1;

linalool � 0.2; cis-sabinene hydrate � 0.1;

trans-p-menth-2-en-1-ol � tr; terpinen-4-ol �1.1; a-terpineol � 0.1; thymol � 46.7; carvacrol

� 0.6; eugenol � 0.3; methyl cinnamate � tr;

methyleugenol � tr; a-copaene � 0.4; b-elemene � 0.1; b-caryophyllene � 2.0; trans-

b-farnesene � tr; a-numulene � 0.2; trans-methylisoeugenol � 0.1; germacrene D � 0.1;

b-selinene � 0.9; a-farnesene � tr; b-bisabolene� tr; g-cadinene � 0.2; d–cadinene � 0.3; b-caryophyllene � 0.3; total � 99.2 (A)

trans-Hex-2-enal � 0.2; a-thujene � 3.4; a-pinene� 1.1; camphene � 0.1; oct-1-en-3-ol � 0.3; 3-

octanone� 0.1; sabinene� 0.5; b-pinene� 0.4;

myrcene� 3.3; a-phellandrene� 0.1; D3-carene

� 0.2; a-terpinene � 1.0; p-cymene � 18.3; 1,8-

cineole� 3.5; limonene� 1.0; cis- b-ocimene�3.4; trans- b-ocimene � 0.2; g-terpinene � 3.4;

trans-sabinene hydrate � 1.5; a-p-dimethylstyrene � 1.0; terpinolene � 0.1; linal-

ool � 0.3; cis-sabinene hydrate � 0.4; trans-p-

menth-2-en-1-ol � 0.1; d–terpineol � 0.1;

terpinen-4-ol � 1.2; a-terpineol � 0.1; thymol

� 35.4; carvacrol� 0.8; eugenol� 10.7; methyl

cinnamate � 0.1; methyleugenol � 0.1; a-copaene � 0.4; b-elemene � 0.1; b-caryophyllene � 1.2; trans-b-farnesene � 0.1;

a-numulene � 0.2; trans-methylisoeugenol �0.2; germacrene D � tr; b-selinene � 1.5; a-farnesene� 0.1; b-bisabolene � 0.1; g-cadinene� 0.1; d–cadinene� 0.4; b-caryophyllene� 1.3;

total � 98.1 (B) [2]

Seed

Oil, %: 26.0 [3]

Iodine value, % J2: 144.0 [3]

References

1. F. Tchoumbougnang, P.H. Amvam Zollo, E. Dagne,

Y. Mekonnen, Planta Med. 71, 20 (2005)

2. L. Ntezurubanza, J.J.C. Scheffer, A.B. Svendsen, Planta Med.

53, 421 (1987)

3. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Ocimum graveolens R. Br.

Family: Lamiaceae

Seed

Oil, %:18.6

n20D : 1.4805

Iodine value, % J2: 157.4

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Ocimum kilimandscharicum (R. Br.)Guerke

Family: Lamiaceae

Flowers and Leaves

Essential oil, % vol/wt (fresh): 0.4–0.5 9 (from fresh

plant material, Rwanda, Central Africa)

Page 62: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 450 Ocimum sanctum L.

Composition (GLC, CP-Wax 57 cb and CP-Sil 5 cb;

GC/MS, CP-Sil 5 cb), %: a-Pinene � 2.8; a-fenchene � tr; camphene � tr; b-pinene � 5.2;

sabinene � 0.9; myrcene � 0.4; a-phellandrene� tr; a-terpinene � 0.1; limonene � 12.8; b-phellandrene � tr; 1,8-cineole � 62.2; cis-b-ocimene � tr; g-terpinene � 0.5; p-cymene �0.1; terpinolene � 0.1; 3-octanol � tr; myrcene

epoxide � 0.6; 1-octen-3-ol � 0.5; trans-

sabinene hydrate � 0.8; linalool + sesquiterpene

hydrocarbon 1 � 0.1; cis-sabinene hydrate �0.1; trans-p-menth-2-en-1-ol � 0.3; terpinene-

4-ol � 1.1; cis-p-menth-2-en-1-ol � 0.1; a-terpineol � 0.2; d–terpineol + sesquiterpene

hydrocarbon 2 � 4.2; carvone � 0.2; cis-

anethole + citronellol � 0.1; trans-carveol �0.3; cis-carveol � tr

Monoterpene hydrocarbons, %: 23.0

Oxygen-containing components, %: 71.0

Sesquiterpene hydrocarbons, %: 6.0

Seed

Oil, %: 12.5–16.2 [2]

n40D : 1.4667–1.4852

Iodine value, % J2: 192.6–195.6

References

1. L. Ntezurubanza, J.J.C. Scheffer, A. Looman, A.B. Svendsen,

Planta Med. 50, 385 (1984)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

Ocimum sanctum L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 16.0 [1]

n40D : 1.4748

Iodine value (Wijs), % J2: 192.0; 196.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.9; 18:0 � 2.6; 18:1 � 7.5; 18:2� 29.0; 18:3�54.0; others (6) � 0.7 [1]

IR

Seed

Oil, % dry wt: 17.8 [2]

n30D : 1.4789

Saponification value, mg KOH: 181.6

Iodine value, % J2: 173.0

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

Ocimum selloi Benth.

Family: Lamiaceae

Seed and Pericarp

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4731

Iodine value (Wijs), % J2: 178.0; 184.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.3; 18:0� 2.9; 18:1� 12.0; 18:2� 33.0; 18:3�44.0; others (3) � 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ocimum viride Willd.

Family: Lamiaceae

Seed

Oil, %: 9.7

n25D : 1.4808

Saponification value, mg KOH: 192.2

Iodine value, % J2: 168.9

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 351 [in

Russian]

Page 63: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Origanum x dolichosiphon P. H. Davis 451 Lamiaceae

Origanum compactum Benth.

Family: Lamiaceae

Aerial Part

Extract (acetone) [1]

Components (CC), g (from 1.0 kg aerial part):

Essential oil � 6.0; oleanolic + ursolic acids �3.0; betulin � 0.09; betulinic acid � 0.07;

b-amyrin � 0.06; 21a-hydroxy-oleanolicacid � 0.02; 21-hydroxy-ursolic acid and

others

Leaf

Lipids, % dry wt: 9.72 [2]

NL, %: 81.0

Components: Steryl esters, TAG, free FA, sterols,

free fatty alcohols, triterpenoic acids, compo-

nents of essential oil

PL, %: 19.0

Components, %: GL � 90.0; PhL � 10.0

GL

Components: MGDG, DGDG

FAs (GLC), %: 16:0 � 36.6–50.6; 18:1 � 18.1–

29.1; 18:2 � 17.7–31.6

PhL

Components: PhL, PhC, PhE, PhG, PhS, PhI, PhAFAs: 16:0; 18:1; 18:2

SL, %: 27.4

Cerebrosides, %: 25.1

Essential oil

Main component: Carvacrol [2]

Leaves and Flowers

Essential oil (steam distillation), %: 3.3 [3]

Components, %: Thymol� up to� 4.2; carvacrol�57.0–71.0; p-cymene – tr � 25.4 (5 samples);

thymol � 28.0–43.4; carvacrol � 3.8–25.1

(3 samples)

Phenols, %: 47.0–70.0

Activity: Spasmolytic activity of thymol and carva-

crol [4].

Antagonistic effect of thymol and carvacrol [5].

Use: As a spasmlytic drug for the gastrointestinal

tract (in Morocco) [1].

References

1. J. Bellakhdar, S. Passannanti, M. Paternostro, F. Piozzi, Planta

Med. 54, 94 (1988)

2. C.O. Van Den Broucke, J.A. Lemli, Planta Med. 38, 264

(1980)

3. K. Revinthi-Moraiti, M.E. Komaitis, G. Evangelatos, V.V.

Kapoulas, Food Chem. 16(1), 15 (1985)

4. C.O. Van Den Broucke, J.A. Lemli, Planta Med. 38, 317

(1980)

5. C.O. Van Den Broucke, J.A. Lemli, Planta Med. 40, 188

(1982)

Origanum x dolichosiphon P. H. Davis

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.04 (from

air dried plant material, Turkey)

Composition of essential oil (GC/MS, Innowax

FSC), %: Decane � 0.01; a-pinene � 1.8; a-thujene � 0.2; camphene � 0.1; b-pinene �0.8; sabinene � 0.9; isoamyl acetate � 0.1; d-carene� 0.3; myrcene � 1.2; a-terpinene � 0.3;

limonene � 6.4; 1,8-cineole � 2.3; b-phellandrene � 0.4; (Z)-b-ocimene � 0.1; g-terpinene� 1.9; (E)-b-ocimene� 0.2; p-cymene

� 4.1; terpinolene � 0.1; 3-octanyl acetate �0.2; 1-octenyl acetate � 0.01; 3-octanol � 0.01;

tetradecane� 0.1; a-fenchone� 0.01; a-thujone� 0.02; b-thujone � 0.02; a;p-dimethylstyrene

� 0.03; menthone � 0.1; bicycloelemene � 0.6;

a-copaene � 0.4; decanal � 0.03; a-bourbonene� 0.1; b-bourbonene� 2.1; a-gurjunene� 0.02;

(E)-2-nonenal � 0.01; b-cubebene � 0.1; linal-

ool� 0.5; linalyl acetate� 0.8; bornyl acetate�0.03; b-elemene � 0.4; b-caryophyllene � 13.0;

menthol � 0.02; allo-aromadendrene� 0.3; (Z)-

b-farnesene � 0.1; (E)-b-farnesene � 0.01;

gurjunene � 0.1; a-humulene � 0.8;

heptadecane � 0.2; a-terpineol � 0.3; ledene �0.2; a-terpinyl acetate � 0.1; germacrene D �10.8; bicyclogermacrene � 19.9; d-cadinene �0.4; g-cadinene � 0.1; (E)-b-bisabolene � 0.02;

cuminaldehyde � 0.1; (E;E)-2;4-decadienol �0.1; b-damascone � 0.1; (E)-b-damascone �0.1; cis-calemene � 0.1; p-cymen-8-ol � 0.02;

(E)-geranyl acetone � 0.2; epicubebol � 0.03;

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Lamiaceae 452 Origanum kopetdaghense Boriss.

tetradecanal � 0.1; a-calacorene � 0.02;

palustrol � 0.04; cubebol � 0.03; (E)-b-lonone� 0.1; isocaryophyllene oxide � 0.2;

caryophyllene oxide � 3.5; perilla alcohol �0.1; norbourbonene � 0.2; (E)-nerolidol � 0.2;

10-epi-elemol � 0.1; germacrene D-4-ol � 0.3;

globulol � 0.7; viridiflor � 0.3; hexahydro-

farnesyl acetone � 0.3; spathulenol � 4.9; 3,4-

dimethyl-5-penthylidene-2(5H)-furanone � 0.2;

nonanoic acid� 0.4; thymol� 0.7; t-muurolol�0.1; carvacrol � 2.9; trans-a-bergamotol � 0.8;

a–cadinol � 0.3; decanoic acid � 0.3; tricosane

� 0.1; caryophylla-2(12),6(13)-dien-5a–ol(¼caryophylladienol-II) � 0.1; caryophylla-

2(12),6-dien-5a–ol (¼caryophylladienol-I) �0.1; farnesylacetone � 0.2; caryophylla-

2(12),6-dien-5b–ol (¼caryophylladienol-II) �0.3; pentacosane � 0.6; phytol � 0.3; others –

3.3; total – 92.0

Monoterpene hydrocarbons, %: 12.4

Oxygenated monoterpenes, %: 14.8

Sesquiterpene hydrocarbons, %: 49.3

Oxygenated sesquiterpenes, %: 12.1

References

1. N. Tabanca, F. Demirci, T. Ozek, G. Tumen, K.H.C. Baser,

Chem. Nat. Comp. 37(3), 238 (2001)

Origanum kopetdaghense Boriss.

Family: Lamiaceae

Essential oils, % dry wt: 0.38–0.40

References

1. Rastitel’nye resursy SSSR (Nauka, St. Petersburg, 1991), 6, 61

[in Russian]

Origanum majarona L.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.40

Oil, %: 37.5

d20: 0.9369

Acid value, mg KOH: 3.57

Color: Primrose yellow 2/2

FAs

Composition (GLC, FFAP), %: 16:0 � 8.7; 18:0 �2.2; 18:1(9) � 8.1; 18:1(6) � 0.9; 18:2 � 24.4;

18:3 � 59.6

References

1. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

Origanum onites L.

Family: Lamiaceae

Aerial Part

Lipids (chloroform-methanol, 2:1, v/v), % dry wt:

4.68

Unsaponifables, %: 0.85

FAs

Composition (GC/MS, Innowax FSC), %: 12:0� tr;

14:0 � 0.1; 15:0 � tr; 16:0 � 23.3; 16:1 (9Z) +

16:1 (7Z) � 1.3; 16:1 (3E) � 0.7; 17:0 � 1.5;

18:0 � 4.1; 18:1 � 8.2; 18:2 � 13.5; 19:0 � tr;

18:3 � 44.5; 20:0 � 2.2; 22:0 � 0.6

NL, mg/g dry aerial part: 2.44

Components: Hydrocarbons, carotenes, esters of

alkanols and sterols, TAG, free FAs, alkanols,

pigments, triterpenols, sterols, components of

essential oils

FAs (GC/MS) %: 12:0 � tr; 14:0 � 3.4; 15:0 � tr;

16:0� 33.6; 16:1 (9Z) + 16:1 (7Z)� 1.0; 18:0�1.6; 18:1 � 10.3; 18:2 � 14.7; 18:3 � 35.4

GL, mg/g dry aerial part: 2.11

FAs (GC/MS), %: 12:0 � tr; 14:0 � 0.6; 16:0 �21.7; 16:1 � 0.7; 18:0 � 4.8; 18:1� 9.8; 18:2�13.3; 18:3 � 49.1

PhL, mg/g dry aerial part: 0.13

FAs (GC/MS), %: 12:0� tr; 14:0� tr; 16:0� 31.7;

16:1 (7Z) � 0.2; 16:1 (9Z) � 0.3; 16:1 (3E) �9.4; 17:0 � 0.9; 18:0 � 5.9; 18:1 � 6.5;

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Origanum tytthanthum L. 453 Lamiaceae

18:2� 12.1; 19:0� 0.1; 18:3� 30.5; 20:0� 1.1;

22:0 � 1.3

Hydrocarbons (GC/MS), %: С23 � 1.0; С25 � 1.9;

С26 � 0.8; С27 � 11.7; С28 � 4.1; С29 � 55.1;

С31 � 25.4; С33 � tr

Sterols (GC/MS), %: b-Sitosterol � 83.2;

campesterol � 7.4; stigmasterol � 7.1; choles-

terol � 2.3

Pigments, mg/g dry aerial part: 1.033

Components, mg/g dry aerial part: Chlorophyll a –

0.520; chlorophyll b – 0.220; pheophytin a –

0.003; pheophytin b – 0.140; carotenoids –

0.150

Essential oils (hydrodistillation), mL %: 1.8

Composition (GC/MS, Innowax FSC, Wiley GC/

MS Library and TBAM Library of Essential

oil), %: a-Pinene � 0.11; a-thuyene � 0.03;

camphene � 0.05; b-pinene � 0.11; d-3-carene� 0.02; myrcene � 0.58; a-terpinene � 0.55;

limonene � 0.15; 1,8-cineole � 0.13; a-phellandrene � 0.10; g-terpinene � 2.20; p-

cymene � 4.18; terpinolene � 0.12; 3-octanol

� 0.06; a;p-dimethyl styrene � 0.03; 1-octen-3-

ol � 0.37; trans-sabinene hydrate � 0.14; a-campholene aldehyde � 0.04; camphor � 0.02;

linalool � 1.74; cis-sabinene hydrate � 0.14;

trans-menth-2-en-1-оl � 0.10; terpinen-4-оl �1.57; b-caryophyllene � 0.85; cis-dihydrocarvone � 0.04; aromadendrene �0.09; cis-p-menth 2-en-1-оl � 0.07; trans-

pinocarveol � 0.07; b-humulene � 0.06; a-terpineol � 0.32; borneol � 1.69; carvenone �0.28; b-bisabolene � 0.70; cis-piperitone oxide

� 0.31; carvone � 0.30; d-cadinene � 0.06;

myrtenol � 0.06; trans-carveol � 0.07; p-

cymen-8-оl � 0.19; 4-isoprophyl

salicylaldehyde � 0.23; piperitenone � 0.83;

caryophyllene oxide � 0.77; salvial-4(14)-en-

1-one � 0.04; globulol � 0.03; cumin alcohol

� 0.10; spathulenol � 0.47; cis-p-mentha-4-en-

1;2-diol � 0.23; isothymol (2-isopropyl-4-

methyl phenol) � 0.08; eugenol � 0.06; thymol

� 5.97; isocarvacrol � 0.06; carvacrol � 71.22;

caryopylladienol II (caryopylla-2(12);6(13)-

dien-5-a-ol) � 0.06; caryopyllenol II

(caryopylla-2(12);6-dien-5-b-ol) � 0.15; total

� 98.00

Use: Herbal tea.

References

1. N. Azcan, M. Kara, D.T. Asilbekova, T. Ozek, K.H.C. Baser,

Chem. Nat. Comp. 36, 132 (2000)

Origanum tytthanthum L.

Family: Lamiaceae

Triterpenoic acids, %: 0.7 [1]

Components: Oleanolic acid, ursolic acid [1, 2]

Essential oils, %: 0.4 � 1.15 [1]; 1.15 (at flowering

stage) [2]

n20D : 1.5195

d2020: 0.9506

½a�20D : �38.8�

Components: Thymol, carvacrol, a-thuyene, a-pinene, b-pinene, camphene, sabinene, myrcene,

a-terpinene, d-limonene, 1,8-cineol, n-octyl

alcohol, linalyl acetate, linalool, bourbonene, b-elemene, terpinen-4-ol, caryophyllene, a-humulene, borneol, a-terpineol [1]

Composition (GLC, 15% PEGA), %: Thymol �49.6; carvacrol � 19.8 and others [2]

Neutral components (7% PEGS), %: a-Thujene �0.1; a-pinene� 1.58; camphene � 0.3; b-pinene� 0.3; sabinene � 1.56; myrcene � 0.3; a-terpinene � 0.32; limonene � 7.1; 1,8-cineole

� 10.3; n-octanol � 0.2; linalyl acetate � 0.3;

linalool � 1.22; bourbonene � 0.2; elemene �0.2; terpineol � 40.8; caryophyllene � 3.0; a-humulene � 0.1; borneol � 2.0; a-terpineol �0.1 [2]

Phenols, %: 70.0 [2]

n20D : 1.5195 [2]

IR [2]

Aerial Part

Moisture, %: 8.0 [3]

Lipids (chloroform-methanol, 2:1, v/v), % dry wt: 4.4

[3]

Composition of lipids (CC), %: Hydrocarbons +

carotenes � 23.6; esters of FAs with alkanols

and cyclic alcohols + TAG + essential oils� 9.7;

free FAs � 12.3; alkanols + pigments � 3.0; GL

+ pigments � 48.8; PhL � 1.8 [3]

FAs

Composition (GC/MS, Innowax FSC), %: 9:0 �0.1; 10:0 � 0.1; 12:0 � 0.2; 14:0 � 2.0;

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Lamiaceae 454 Origanum tytthanthum L.

15:0 � 0.4; 16:0 � 38.6; 16:1 (9Z) � 0.6; 16:1

(3E)� 0.8; iso-17:0� tr; 17:0� 0.4; 18:0� 7.3;

18:1 � 18.0; 18:2 � 12.7; isomer of 18:2 � tr;

18:3 � 18.8; 20:0 � tr; 22:0 � tr

Esters of alkanols and cyclic alcohols

FAs (GLC, 15% Reoplex 400), %: 12:0� 0.7; 14:0

� 2.7; 15:0 � 0.9; 16:0� 43.3; 17:0� 0.9; 18:0

� 7.5; 18:1 � 12.6; 18:2� 8.6; 18:3� 2.2; 20:0

� 11.6; 22:0 � 9.0Free FAs

Composition (GC/MS), %: 9:0 � 0.1; 10:0 � tr;

12:0� 0.2; 14:0� 1.6; 15:0 � 0.6; 16:0 � 39.5;

16:1(9Z) � 0.5; iso-17:0 � 0.5; 17:0 � 0.6; 18:0

� 8.7; 18:1 � 28.5; 18:2 � 12.2; isomer 18:2 �0.4; 18:3 � 6.1; 20:0 � 0.5; 22:0 � tr

GL

FAs (GLC), %: 14:0 � 1.9; 15:0 � tr; 16:0 � 26.7;

17:0 � tr; 18:0 � 0.6; 18:1 � 26.3; 18:2 � 17.3;

18:3 � 21.4

PhL

FAs (GLC), %: 14:0 � 1.3; 15:0 � tr; 16:0 � 45.6;

16:1 (9Z) + 16:1 (3E) � 4.3; 18:0 � 4.6; 18:1 �12.6; 18:2 � 14.9; 18:3 � 16.7

Alkanols and sterols (GLC, HP-5), %: С14 � 0.4;

С16� 0.2;С18� 0.1;С20� 0.3;С22� 2.0;С24

� 0.1; С26 � 91.7; С28 � 1.0; С30 � 1.6; b-sitosterol � 1.0; others (6) � 1.6

Pigments, mg % dry aerial part: b-Carotene � 1.3;

xantophylles � 4.7; chlorophyll a � 21.0; chlo-

rophyll b � 3.2; pheophytin a + pheophytin b �3.2 [3]

Unsaponifables, % total lipids: 33.0 [3]

Sterols: b-Sitosterol [1]Triterpenoic acids

Components, %: Ursolic acid � 0.7; oleanolic acid

+ bungeolic acid [1]

Essential oils: 1.2 mL % [3]; 1.09 dry wt [4]; 2.20–

2.50% absolute dry wt [5]; 0.17–3.0 [1]

d184 : 0.9410–0.9670 [5]

n18D : 1.5010–1.5148 [5]

Composition of essential oil, %: a-Pinene� 0.27; a-thuyene � 0.23; camphene � 0.05; b-pinene �0.05; d-3-carene � 0.04; myrcene + a-phellandrene � 0.77; a-terpinene � 1.45; limo-

nene � 0.17; b-phellandrene � 0.12; (E)-2-

hexenal � 0.06; (Z)-b-ocimene � 0.11; g-terpinene � 9.50; (E)-b-ocimene � 0.01; 5-

methyl-3-heptanone � 0.16; p-cymene � 5.90;

terpinolene� 0.11; 6-methyl-3-heptanol� 0.04;

1-octen-3-ol � 1.57; trans-sabinene hydrate �0.41; linalool � 0.05; cis-sabinene hydrate �0.23; trans-p-menth-2-en-1-ol � 0.04; trans-b-bergamoten � 0.09; b-caryophyllene � 1.10;

terpinen-4-оl � 0.99; methyl carvacrol � 0.20;

cis-dihydrocarvone � 0.07; a-humulene � 0.07;

a-terpineol� 0.20; borneol� 0.42; b-bisabolene� 2.65; carvone� 0.21; b-sesquiphellandrene�0.05; p-cymen-8-ol � 0.10; thymyl acetate �0.05; caryophyllene oxide � 0.31; hexahydro-

farnesylacetone � 0.07; thymol � 27.18; carva-

crol � 42.76 [4]

Flower

Essential oils, %: 3.5 [1]

Components, %: a-Thujone, a-pinene, camphene,

1-octen-3-ol, myrcene, a-phellandrene, n-

cymol, limonene, g-terpinene, menthol, thymol

methyl ether, carvacrol methyl ether, thymol,

carvacrol, thymol acetate, caryophyllene,

gurjunene, humulene, b-bisabolene

Fruit

Essential oil, % absolute dry wt: 2.73 [5]

d184 : 0.9682

n18D : 1.5148

Leaf

Essential oils, %: 0.25–2.7 [1]

Seed

Mass of 1,000, g: 0.07 [6]

Oil (petroleum ether), %: 26.7 [6]

d20: 0.9553

n20D : 1.4869

Acid value, mg KOH: 5.3

Color: Green-yellow

Hehner value, %: 95.6

Iodine value (Kauffmann), % J2: 196.6

Saponification value, mg KOH: 201.7

Unsaponifables, %: 3.8

FAs

n20D : 1.4869

Iodine value, % J2: 206.5 (Kauffmann); 209 (cald)

Saponification value, mg KOH: 201.3

Composition (GLC, 17% PEGS), %: 14:0 � 0.2;

16:0� 5.7; 18:0� 1.8; 18:1 � 8.0; 18:2 � 20.0;

18:3 � 64.3

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Origanum vulgare L. 455 Lamiaceae

TAG

Main components, mol %: LeLeLe � 24.9; LLeLe

� 9.7; OLeLe � 5.7; LeLLe � 15.1; LeOLe �6.2; PLeLe � 7.0; LLLe � 5.8; OLLe � 3.4;

PLeL � 0.6; PLeO � 1.0; OLeO � 0.3; OLL �0.6; OOL � 0.2; LePLe � 1.1; LLL � 0.6; POL

� 0.2; LOL� 0.2; PLO� 0.4; PLL� 1.0; OLO

� 0.1; PLeP � 0.9; OOO � 0;1 PPLe � 0.2;

OPLe � 0; LPLe � 0.2; POO � 0.2 [7]

Composition, %: SSU + USS � 0.2; USU � 0.6;

SUS� 1.4; UUS + SUU� 20.8; UUU� 77.0 [8]

FAs (GLC, 17% PEGS), %: 16:0 � 6.4; 16:1 � tr;

18:0� 1.8; 18:1� 7.8; 18:2� 19.8; 18:3� 64.2

Stem

Essential oils, %: 0.26 [1]

References

1. Rastitel’nye resursy SSSR (Nauka, St. Petersburg, 1991), 6, 61

[in Russian]

2. L.A. El’tchibekov, G.K. Nikonov, Chem. Nat. Comp. 22, 232

(1986)

3. D.T. Asilbekova, A.I. Glushenkova, N. Azcan, T. Ozek,

K.H.C. Baser, Chem. Nat. Comp. 36, 124 (2000)

4. K.H.C. Baser, B. Demircakmak, K.R. Nuriddinov, A.M.

Nigmatullaev, K.N. Aripov, J. Essent. Oil Res. 9, 611 (1997)

5. Y.M. Nuraliev, N.M. Safarov, M.K. Kurbanov, K.S.

Dzhuraev, S.M. Davlatkadamov, Rast. Resursy 22, 337

(1986) [in Russian]

6. S.D. Gusakova, K.K. Kholmatov, A.U. Umarov, Chem. Nat.

Comp. 12, 134 (1976)

7. T.V. Khomova (unpublished)

8. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Origanum virens Hoffmanns and Link

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt (v/w): 4.5

(from air-dried plant material at flowering stage,

Portugal)

Composition of essential oil (GC and GC/MS, SPB

1 and Supelco Wax 10), %: a-Thujene � 1.8; a-pinene � 0.9; camphene � 0.3; oct-1-en-3-ol �0.3; sabinene � 0.2; b-pinene � 0.2; myrcene �2.3; a-phellandrene � 0.3; D3-carene � 0.1;

a-terpinene � 1.8; p-cymene � 4.5; limonene

� 0.2; b-phellandrene � 0.2; Z-b-ocimene �0.2; E-b-ocimene � 0.2; g-terpinene � 9.9; cis-sabinene hydrate � 0.4; terpinolene � 0.1; lin-

alool� 1.1; cis-p-menth-2-en-1-ol� tr; trans-p-

menth-2-en-1-ol� tr; borneol� 0.1; terpinen-4-

ol� 0.7; a-terpineol� 0.4; thymyl methyl oxide

� 0.1; carvacryl methyl oxide � 0.5; thymol �2.0; carvacrol � 68.1; b-bourbonene � tr; E-

caryophyllene � 1.2; a-humulene � 0.2; g-muurolene � tr; valencene � tr; d-cadinene �0.1; caryophyllene oxide� 0.1; others–0.3; total

� 98.5

Monoterpene hydrocarbons, %: 23.2

Oxygenated monoterpenes, %: 73.4

Sesquiterpene hydrocarbons, %: 1.5

Oxygenated sesquiterpenes, %: 0.1

Activity: Antifungal activity of essential oils against

Candida albicans ATCC 10231, C. albicans H37,

C. albicans MI, C. tropicalis ATCC 13803, C.

tropicalis H 18, C. glabrata H 16, C. glabrata H 30,

C. krusei H 9, C. guillermondii MAT 23, C.parapsilosis ATCC 90018, MIC and MLC, mL/mL:

0.16 � 0.32, Fluconazole as standard <1–64 (MIC);

Concentrations lower than MIC values strongly pre-

vent germ tuber formation.

Carvacrol: MIC � 0.08–0.16; MLC � 0.16–0.32

b-Cymene: MIC � 0.08-0.63; MLC � 0.08–0.63

g-Terpinene: MIC � 1.25–20.0; MLC � 2.5–20.0

References

1. L.R. Salqueiro, C. Cavaleiro, E. Pinto, C. Pina-Vaz,

A.G. Rodriques, A. Palmeria, C. Tavares, S. Costa-de-

Oliveira, M.J. Goncalves, J. Martinez-de-Oliveira, Planta

Med. 69, 871 (2003)

Origanum vulgare L.

Family: Lamiaceae

Herbal

Essential oil, % dry wt: 1.2

[a]D: (–) 3.12–(–) 39.70�

d: 0.8688–0.9347

n40D : 1.4825–1.4949

Acid value, mg KOH: 1.42

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Lamiaceae 456 Origanum vulgare L. (S.O.)

Ester value, mg KOH: 7.35–13.06

Ester value after acetylated, mg KOH: 54.88–

114.68

Components, %: Thymol up to 50 and carvacrol,

phenols – 44.0; bi and three cyclic sesquiterpenes

– 12.5; free alcohols – 15.4 and geraniol up to 5.0

Use: The essential oil may be used in perfume and

food.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p.133 [in

Russian]

Origanum vulgare L. (S.O.)

Family: Lamiaceae

Sterols, % dry wt: 0.03 [1]

Triterpenoic acids, % dry wt: Ursolic acid � 1.20 [1]

Terpenoids

Phytol, % dry wt: 0.06 [1]

Essential oils, %: 0.01–2.17 [2]

Components of essential oil, %: a-Pinene, b-pinene,myrcene, selinene, camphene, a-thuyene,sabinene, ocimene, limonene, a-terpinene, b-caryophyllene, origanene, borneol, 1,8-cineol,

n-cymol, linalool, menthon, octanon-3, 6-

methylgepten-5-one-2, carvon, undekanon-2,

octanol-3, 1-octen-3-ol, a-terpineol, linallyl ace-tate, geraniol, hexenal, carvacrol, cumin alde-

hyde, camphor, thymol, thymil acetate [2]

Aerial Part

Steroids: 0.03 [2]

Triterpenoic acids, %: Ursolic acid � 1.2 [2]

Terpenoids

Phytol, %: 0.06 [2]

Essential oils, %: 0.1 � 1.5 [2]

Components, %: Thymol, linalool, terpineol, cam-

phor, linalyl acetate [2]

Flowers

Essential oils, %: 0.63–0.7 [2]

Leaves

Essential oils, %: 0.12–0.32 [2]

Triterpenoic acids, %: Ursolic acid � 0.31; oleanolic

acid [2]

Seed

Mass of 1,000, g: 1.1 [3]; 0.1 [4]

Oil, % dry wt: 27.1 [3]; 35.0 (petroleum ether, 30–

60�C) [4]; 10.1–29.2 [2]

d20: 0.9249 [3]

n40D : 1.4772 [4]

Acid value, mg KOH: 2.94 [3]

Сolor: 763.0 [3]

Iodine value, J2: 197.8–243.3 [3–5]

Saponification value, mg KOH: 194.9 [4]

FAs

Composition (GLC), %: 14:0 � 1.9; 16:0 � 3.1;

18:0� 1.0; 18:2� 4.9; 18:2� 21.8; 18:3� 45.8

� 69.7 [2]

16:0 � 6.9; 18:0 � 1.2; 18:1(9) � 4.6; 18:1(6) �0.9; 18:2� 22.7; 18:3� 65.6 (mol %, FFAP) [3]

16:0 � 4.5; 18:0 � 1.9; 18:1 � 5.4; 18:2 � 22.0;

18:3 � 66.0; others (2) � 0.2 (20% LAC-2R

446) [4]

16:0 � 3.1; 18:0 � 1.0; 18:1 � 4.5; 18:2 � 21.8;

18:3 � 69.7 (10% PEGA) [6]

TAG, %: 98.1 [6]

FAs (GLC, 15% Reoplex 400): 14:0 � 0.6; 16:0 �3.6; 16:1 � 1.0; 18:0 � 2.7; 18:1 � 7.5; 18:2 �19.2; 18:3 � 62.7; others � 2.7

Free FAs

Composition (GLC), %: 14:0 � 1.9; 15:0 � 1.8;

16:0� 3.1; 16:1� 2.1; 18:0 � 4.9; 18:1 � 11.3;

18:2 � 22.5; 18:3 � 45.8; others � 6.6 [6]

Stem

Essential oils, %: 0.08–0.11 [2]

Use: The officinal remedy “HerbaOrogani vulgaris” of

the aerial part Origanum vulgare used as antiseptic [8].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(20),

247 (1976) [in Russian]

2. Rastitel’nye resursy SSSR (Nauka, St. Petersburg, 1991), 6, 59

[in Russian]

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

4. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

5. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Page 69: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Perilla frutescens L. 457 Lamiaceae

6. S.D. Gusakova, G.A. Stepanenko, D.T. Asilbekova, Y.M.

Murdokhaev, Rast. Resursy 19(4), 444 (1983) [in Russian]

7. G.V. Novitzkaya, V. Krishtopa, Rast. Resursy 7(1), 32 (1971)

8. M.D. Mashkovskii, Lekarstvennye Sredstva (Meditsina,

Tashkent, 1988) 1, 1988, p. 684 [in Russian]

Origanum vulgare ssp. virens

Family: Lamiaceae

Leaves

Essential oil (from fresh leaves, hydrodistillation)

Composition of essential oil (GLC, 5% phenyl

methylpolysiloxane), %: Nonane � tr; a-pinene� tr; camphene� 0.20; sabinene� tr; octen-3-ol

� 0.37; 3-octanone � 0.27; myrcene � 3.37; 3-

octanol � 0.28; a-terpinene � tr; limonene �0.48; (Z)-b-ocimene � 3.70; (E)-b-ocimene �6.57; g-terpinene � tr; terpinolene � tr; linalool

� 16.36; unidentified 1 � 9.59; borneol � tr; 4-

terpineol� tr; a-terpineol� 9.20; linalyl acetate

� tr; isobornyl acetate � tr; unidentified 2 �1.30; d-elemene � 12.85; neryl acetate � tr; a-copaene� tr; geranyl acetate� tr; b-bourbonene� tr; b- elemene � 0.35; b-caryophyllene �11.07; unidentified 3 � 2.64; a-humulene �1.32; germacrene-D � 0.98; germacrene-B �6.58; a-farnesene � tr; d-cadinene � 0.34; (E)-g-bisabolene � tr; ledol � tr; 4-b-hydroxygermacra-1(10);5-diene � 0.70;

spathulenol � 0.46; caryophyllene oxide +

globulol � 0.94; tau-cadinol � tr; tau-muurolol

� tr; a-cadinol � 0.37; tricosane � tr;

tetracosane � tr; pentacosane � 0.97;

hexacosane � tr; heptacosane � 0.89; squalene

� 0.52; nonacosane � 0.97

References

1. M.S. Alves-Pereira, M. Fernandes-Ferreira, Phytochemistry

48, 795 (1998)

Otostegia limbata (Benth.) Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.5

Oil (petroleum ether, 30–60�C), % dry wt: 43.0

n40D : 1.4652

Iodine value (Wijs), % J2: 88.0; 84.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �11.0; 18:0 � 4.8; 18:1� 53.0; 18:2� 14.0; 18:3

� 0.36; others (5) � 1.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Panzeria lanata (L.) Bunge

Synonyms

Ballota lanata L.; Panzeria argyracea Kuprian.

Family: Lamiaceae

Essential oil, % dry wt: 0.02–0.03

Aerial Part

Essential oil, % dry wt: 0.02

Activity: Ethanol extracts have sedative, hypoten-

sive, and diuretic properties.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

62 [in Russian]

Perilla frutescens L.

Family: Lamiaceae

Seed and Pericarp

Ash, %: 4.3 [1]

Mass of 1,000, g: 2.8 [2]

Oil, (petroleum ether, 30–60�C), % dry wt: 42.0 [1, 2]

n40D : 1.4734 [2]

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Lamiaceae 458 Perilla nankinensis (Lour.) Decne.

Iodine value (Wijs), % J2: 189.0 [2]

Saponification value, mg KOH: 185.0 [2]

FAs

Composition (20% Apiezon L), %: Saturated� 9.0;

18:1 � 21.0; 18:2 � 11.0; 18:3 � 55.0 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, T.A.McGuire, J. Mallan, M.O. Bagby, I.A.Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

Perilla nankinensis (Lour.) Decne.

Synonyms

Ocimum crispum Thunberg

Family: Lamiaceae

Essential oil, % dry wt: 0.19 [1]

Seed

Oil, % dry wt: 27.0 [1]; 35.8–38.0 [2]

d1515: 0.9370–0.9390 [2]

n15D : 1.4826–1.4856 [2]

n20D : 1.4830–1.4841 [2]

n25D : 1.4800–1.4820 [2]

n40D : 1.4735–1.4785 [2]

Iodine value, % J2: 185.0–08.0 [2]

Saponification value, mg KOH: 188.0–197.0 [2]

Activity: Ether and ethanol extracts have

antibacterial property [1].

Use: Cultivated in Europe as ornamental plant [1].

The essential oil is of economical importance in the

perfume industry [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

63 [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Perilla ocymoides L.

Family: Lamiaceae

Seed

Oil, % dry wt: 32.0 � 40.0–50.0 [1]; 40.8 (petroleum

ether, 40–60�С) [2]; 26.0 [3]

d1515: 0.9306–0.9390 [1]

n40D : 1.4753–1.4880 [1]

Iodine value, % J2: 42.5 [1]; 182.8 [3]; 193.0

(Gardnes); 208.8 (Wijs) [2]

Saponification value, mg KOH: 189.6–192.8 [1];

192.9 [3]

Unsaponifiables, %: 0.9

Composition (CC), %: Triterpenols – 27.0;

4-monomethylsterols � 12.0; sterols � 39.0;

less polar compounds (hydrocarbons, etc.) �22.0

IR, MS, 1H NMR

TAG

Components (GLC, 3% OV 17), %: C48 � tr; C50�2.4; C52 � 27.9; C54 � 69.7 [2]

FAs

Composition (GLC), %: 16:0 � 8.9; 16:1 � 6.0;

18:0 � 1.6; 18:1 � 11.5; 18:2 � 17.5; 18:3 �60.5 [2]

Hydrocarbons (GLC, 3%OV 17), %: C15� 0.8; C19�0.3; C20 � 0.3; C21 � 15.4; C22 � 9.9; C23 � 3.8;

C24 � 6.8; C25 � 4.6; C26 � 2.9; C27 � 6.5; C28 �4.9; C29 � 11.9; C30 � 2.9; C31 � 22.1; C32 � 4.0;

C33 � 0.8 [2]

Sterols

Components (GLC, 1.5%OV 17), %: Cholesterol�1.0; brassicasterol � tr; campesterol � 28.0;

stigmasterol � 9.0; b-sitosterol � 49.0; D5-

avenasterol � 11.0; D7- stigmastenol � 2.0; D7-

avenasterol – tr [3]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

2. A. Bhati, M. Benbouzid, R.J. Hamilton, P.A. Sewell, Chem.

Ind. 70 (1986)

3. T.M. Jeoung, T. Itoh, T. Tamura, T. Matsumoto, Lipids 9, 921

(1974)

Page 71: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Perovskia angustifolia Kudr. 459 Lamiaceae

Perovskia abrotanoides Kar.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.94 –3.6 [1]

Composition of the essential oil, %: a-Pinene �2.8–6.2; camphene � 4.5–7.5; b-pinene � 0.8–

3.2; sabinene � tr � 0.6; d-3-carene � 10.0–

14.5; myrcene � 0.5–2.1; a-terpinene � tr �0.5; limonene � 0.9–2.3; b-phellandrene �0.0–0.5; 1,8-cineole � 6.5–11.0; g-terpinene �0.2–2.5; p-cymene � 0.9–2.3; b-thujone � tr �2.4; linalool� 0.1–2.0; linalylacetete� tr� 1.5;

camphor� 27.0–36.0; bornyl acetate� tr� 2.0;

terpinen-4-ol � 1.5–3.1; borneol � tr � 0.5; a-terpineol � tr � 1.0; a-cububene � tr � 0.5;

copaene � 0.3–0.8; b-cububene � 0.8–1.1;

b-caryophyllene � 2.7–4.1; alloaromadendrene

� 0.2–0.8; humulene� 2.4–3.3; a-muurolene �0.3–1.5; g-cadinene � tr � 0.5; calaminene–

0.2–0.5; vetivenene – 0.5–0.7; a-calacorene –

tr � 0.4; atlantone � 0.5–1.1; ledol � tr � 0.5;

palustrol � 3.5–6.5; viridiflorol � 0.4–1.2; a-celenenol – 0.4–1.3; b- celenenol � 2.3–3.1; a-betulenol � tr � 0.8; b-betulenol � tr � 0.2

(from four different localities in Kyrgyzystan)

[2]

1,8-Cineol – 31.5; a-pinene� 13.7; myrcene� 9.5;

germacrene � 8.0; limonene – 7.4 and others

[3]

Activity: Extracts of essential oil have antibacterial

property [1].

Use: As fodder grass [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

63 [in Russian]

2. A.D. Dembitski, Izv. Akad. Nauk Kaz, SSR, Ser. Khim. 4, 4

(1984)

3. K.H.C. Baser, T. Ozek, B. Demirchakmak, B.Y. Abduganiev,

K.R. Nuriddinov, K.N. Aripov, A.S. Doriev, C.S. Karataeva,

Chem. Nat. Comp. 33, 296 (1997)

Perovskia angustifolia Kudr.

Synonyms

Perovskia kudrjaschevii Pjat.

Family: Lamiaceae

Composition of the essential oil, %: a-Pinene� 13.2;

camphene � 4.5; b-pinene � 5.0; sabinene � tr;

d-3-carene � 1.8; myrcene � 5.8; a-terpinene �0.6; limonene � 3.1; b-phellandrene � tr; 1,8-

cineole � 23.5; g-terpinene � 2.4; p-cymene �4.1; b-thujone � tr; linalool � 4.2; linalylacetete

� 0.9; camphor �4.0; bornyl acetate � 0.4;

terpinen-4-ol � 1.8; borneol � 2.3; a-terpineol �2.8; b-cububene � 0.3; b-caryophyllene � 6.1;

alloaromadendrene � 1.5; humulene �4.5;

a-muurolene � tr; atlantone �0.2; ledol �20.0;

palustrol � 0.6; viridiflorol � 1.5; a-betulenol �0.5; b- betulenol � 0.2 (sample collected alone in

river Aflotun of Kyrgyzstan) [1]

a-Pinene� 15.5–14.8; camphene� 3.4–2.8;b-pinene� 5.4–6.0; sabinene � 0.0 – tr; d-3-carene � 4.5–

3.2; myrcene � 4.1–3.5; a-terpinene � 0.2–0.2;

limonene � 1.7–3.0; b-phellandrene � tr – tr;

1,8-cineole � 22.4–21.0; g-terpinene � 1.2–1.5;

p-cymene� 2.7–3.0; b-thujone� 0.9–1.5; linalool

� 6.5–10.1; linalylacetete � 2.3–3.5; camphor

�2.6–1.3; bornyl acetate � 0.6–1.5; terpinen-4-ol

� 1.5–1.2; borneol � 1.5–0.5; a-terpineol � 2.8–

3.2; b-cububene � 0.2–0.2; b-caryophyllene �6.5–6.0; alloaromadendrene � 1.2–2.0; humulene

� 4.7–3.2; a-muurolene � 0.5–0.2; atlantone �0.3 – tr; ledol � 0.9–2.0; palustrol � 0.2 – 0.8;

viridiflorol � 2.0–2.2; a-betulenol � 0.3–0.5;

b-betulenol � 0.2–0.5 (samples collected from

two different localities in Chimgan mountains of

Uzbekistan) [1]

Aerial Part

Essential oil, % dry wt: 0.115–0.62 [2]

Leaf

Essential oil (hydrodistillation), % dry wt: 1.1 (A);

0.82 (B); 0.75 (C; from three different localities A,

B, and C in the Arslonbob mountains of Kyrgyzstan

in October 1994) [3]

Composition of the essential oil (GC/MS, Innowax

FSC, Wiley GC/MS Library &TBAM Library),

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Lamiaceae 460 Perovskia scrophulariaefolia Bgl.

%: Tricyclene� 0.27, 0.0, 0.25; a-pinene� 11.3,

7.25, 14.7; a-thujene� 0.15, 0.0, 0.29; camphene

� 6.82, 2.54, 6.37; b-pinene � 3.60, 1.65, 4.55;

sabinene � 0.05, 0.0, 0.12; d-3-carene � 0.0,

1.36, 0.40; myrcene � 4.04, 0.30, 2.54;

a-phellandrene � 0.0, 0.30, 0.0; a-terpinene �0.18, 0.0, 0.28; limonene � 2.33, 3.57, 1.94; 1,8-

cineole � 24.9, 12.0, 27.5; b-phellandrene �0.30, 0.39, 1.03; g-terpinene � 0.38, 0.16, 0.62;

5-methyl-3-heptanone� 0.0, 0.0, 0.07; p-cymene

� 2.18, 1.61, 2.86; terpinolene � 0.06, 0.0, 0.10;

a-thujone � 0.12, 0.0, 0.0; 1-octen-3-ol � 0,08,

0.0, 0.18; trans-sabinene hydrate� 0.01, 0.0, 008;

a-campholene aldehyde� 0.07, 0.0, 0.0; camphor

� 4.51, 6.47, 4.31; linalool� 0.52, 0.48, 0.32; cis-

sabinen hydrate� 0.05, 0.0, 0.08; trans-p-menth-

2-en-1-ol � 0.0, 0.0, 0.06; pinocarvone � 0.12,

0.27, 0.0; bornyl acetate � 8.72, 1.22, 4.47;

b-caryophyllene � 3.17, 6.50, 3.17; terpinen-4-

ol � 0.20, 0.01, 0.0; alloaromadendrene � 0.12,

0.0, 0.16; 2-methyl-6-methylene-3,7-octadien-2-

ol � 0.22, 0.0, 0.0; myrtenal � 0.01, 0.0, 0.0;

aromadendrene � 2.14, 1.77, 2.85; trans-

pinocarveol � 0.32, 0.64, 0.14; d-terpineol �0.68, 0.57, 0.65; a-humulene � 2.27, 5.24, 2.10;

trans-verbenol – 0.09, 0.15, 0.0; g-muurolene –

0.0, 0.12, 0.0; a-terpineol-1.95, 2.13, 2.11;

a-terpinyl acetate � 0.30, 0.0, 0.0; borneol �3.20, 3.04, 3.20; carvone � 0.0, 0.12, 0.0; d-cadinene � 0.0, 0.01, 0.07; myrtenol � 0.14,

0.17, 0.0; p-cymen-8-ol � 0.05, 0.0, 0.0; trans-jasmone � 0.07, 0.0, 0.0; cis-jasmone � 0.06,

0.13, 0.0; caryophyllene oxide � 2.22, 5.92,

1.67; methyl euqenol � 0.0, 0.01, 0.0; humulene

epoxide � 21.88, 4.76, 0.0; elemenal � 0.09,

0.22, 0.0; spathulenol � 0.08, 0.0, 0.0; euqenol

� 0.17, 0.88, 0.11; carvacrol – 0.06, 0.0, 0.0;

caryophylladienol � 0.14, 0.50, 0.0;

caryophyllenol I� 1.38, 4.32, 0.0; caryophyllenol

II� 0.78, 2.28, 0.51; epi-13-manool� 3.81, 12.6,

4.01 (from A, B, C, respectably) [3]

Activity: Leaf extract has antihelmintic activity [3].

An ointment prepared from extract exhibited

antibacterial activity [3].

Use: Plant extract is used for skin diseases, stomach

disorders, and as diuretic [3].

Leaf extract is used as an antihelmintic agent [2].

References

1. A.D. Dembitski, Izv. Akad. Nauk Kaz, SSR, Ser. Khim. 4, 4

(1984)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

63 [in Russian]

3. K.H.C. Baser, T. Ozek, B. Demirchakmak, B.Y. Abduganiev,

K.R. Nuriddinov, K.N. Aripov, A.S. Doriev, C.S. Karataeva,

Chem. Nat. Comp. 33, 296 (1997)

Perovskia scrophulariaefolia Bgl.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.54 [1]; 0.2–0.21 [2]

Composition of the essential oil (GC/MS. Innowax

FSC, Wiley GC/MS Library &TBAM Library),

%: a-Pinene� 1.43; a-thujene�0.10; camphene

� 1.25; b-pinene � 1.41; sabinene � 0.09; d-3-carene � 1.22; myrcene � 0.18; limonene �2.79; 1,8-cineole � 11.0; p-cymene � 5.71; a-p-dimethylstyrene � 0.01; a-cububene � 0.19;

trans-sabinenehydrate �0.15; a-copaene �0.69; camphor �9.0; carvone � 0.12;

geranylacetete � 1.49; d-cadinene � 0.22; g-cadinene � 1.32; selina-3,7(11)-dien � 0.29;

myrtenol � 0.32; trans-carveol � 0.16;

calaminene � 0.43; m-cymen-8-ol � 0.24; p-cymen-8-ol � 0.32; a-calacorene I � 0.14;

piperitenone � 0.97; cubebol �0.08; cis-

jasmone �0.14; a-calacorene II �0.07; a-jurjunene � 0.30; linalool � 0.54; cis-

sabinenehydrate � 0.07; linalylacetate � 0.27;

pinacarvone � 0.09; bornyl acetate � 7.82; b-caryophyllene � 0.72; terpinen-4-ol� 0.54; cis-

p-mentha-2,8-dien-1-ol � 0.11; myrthenal �0.11; aromadendrene � 0.29; trans-pinocarveol� 0.29; d-terpineol � 0.48; a-humulene � 1.8;

cryptone � 0.44; g-muurolene � 0.48; a-terpinylacetete � 4.56; borneol � 2.81; thujol

� 0.3; a-muurolene� 0.79; a� selinene� 0.16;

isocaryophyllene oxide� 1.75;� caryophyllene

oxide � 9.98; humulene epoxide I � 0.54;

humulene epoxide II � 7.85; elemenal � 0.45;

1-epicubenol � 0.10; viridiflorol � 0.57; cumin

alcohol 0.13; cis-p-menth-3en-1,2-diol � 0.09;

T-cadinol � 0.42; T-muurolol � 0.20; a-bisabolol � 0.91; carvacrol � 0.15; a-eudesmol

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Phlomus austra – anatolica Hub. Mur. 461 Lamiaceae

� 0.22; a-cadinol � 0.77; caryophylladienol

0.84; calacorene alcohol I � 0.26; calacorene

alcohol II � 0.22; caryophyllenol II � 0.62;

epi-13- manool � 2.57 (from Uzbekistan) [1]

a-Pinene � 7.5–12.1; camphene � 3.7–6.2; b-pinene � 0.8–4.3; sabinene � tr � 0.3; d-3-carene � 3.9–6.5; myrcene � 0.5–1.0; a-terpinene � 0.3–0.6; limonene � 0.8–1.4; b-phellandrene � tr � 0.2; 1,8-cineole � 15.5–

18.5; g-terpinene � 3.5–4.5; p-cymene � 3.0–

4.3; b-thujone � tr � 0.3; linalool � 3.0–7.2;

linalylacetete � 2.4–8.4; camphor � tr � 1.5;

bornyl acetate � tr � 0.6; terpinen-4-ol � tr �0.9; borneol� 0.7–3.4; a-terpineol� tr� 0.5; b-caryophyllene � 7.3–12.5; alloaromadendrene

� 2.6–6.2; humulene � 5.1–7.7; atlantone �0.1–0.3; ledol � 2.5–4.0; palustrol � 0.0–0.8;

viridiflorol � 0.0–0.1; a-betulenol � 3.8–6.7; b-betulenol � 0.2–1.0 (from four different locali-

ties in Kyrgyzstan) [3]

Activity: Extracts of essential oil have antibacterial

property [2].

Use: The essential oil is of importance in the perfume

industry [1].

References

1. K.R. Nuriddinov, K.K. Khodzimatov, K.N. Aripov, T. Ozek,

B. Demirchakmak, K.H.C. Baser, Chem. Nat. Comp. 33, 290

(1997)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

63 [in Russian]

3. A.D. Dembitski, Izv. Akad. Nauk Kaz, SSR, Ser. Khim. 4, 4

(1984)

Phlomus alpina Pall.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 142.0 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �3.1; 18:0� 0.5; 18:1� 43.7; 18:2� 51.0; 18:3�1.7

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971) [in Russian]

Phlomus armeniaca Willd.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 7.7

Oil (petroleum ether, 30–60� C), % dry wt: 26.0

n40D : 1.4650

Iodine value (Wijs), % J2: 95.0; 95.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.1; 18:0� 0.9; 18:1� 68.0; 18:2� 16.0; 18:3�0.7; others (6) � 1.2

Allenic acid, %: 8.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Phlomus austra – anatolica Hub. Mur.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 6.4

Oil (petroleum ether, 30–60� C), % dry wt: 14.0

n40D : 1.4662

Iodine value (Wijs), % J2: 85.0; 82.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.0; 18:0 � 1.9; 18:1 � 61.0; 18:2� 7.4; 18:3�0.3; others (6) � 2.0

Allenic acid, %: 20.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

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Lamiaceae 462 Phlomus caucasica Rech. fil.

Phlomus caucasica Rech. fil.

Synonyms

Ph. orientalis auct.

Family: Lamiaceae

Essential oil, % dry wt: 0.1–0.2

Use: Ornamental plant.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

65 [in Russian]

Phlomus crinita Cav.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 11.0

Oil (petroleum ether, 30–60�C), % dry wt: 24.0

n40D : 1.4646

Iodine value (Wijs), % J2: 88.0; 82.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.7; 18:0 � 1.7; 18:1 � 64.0; 18:2

� 10.0; 18:3 � 0.1; others (10) � 4.3

Allenic acid, %: 12.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Phlomus fruticosa L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 10.0 [1]

Oil (petroleum ether, 30–60� C), % dry wt: 18.0 [1]

n40D :1.4646 [1]

Iodine value (Wijs), % J2: 114.4 (cald) [2]

FAs

Composition: 16:0 � 7.3; 18:0 � 2.4; 18:1 � 68.0;

18:2 � 8.5; 18:3 � 0.8; others (7) � 1.2 (%,

GLC, 20% LAC-2R 446) [1]

16:0 � 14.7; 18:0 � 2.2; 18:1 � 59.5; 18:2 � 29.9;

18:3 � 0.8 (mol %, GLC, 10% PEGA) [2]

Allenic acid, %: 12.0 [1]

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971) [in Russian]

Phlomus herba-venti L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 10.0

Oil (petroleum ether, 30–60� C), % dry wt: 30.0

n40D : 1.4658

Iodine value (Wijs), % J2: 104.0; 105.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.8; 18:0� 1.4; 18:1� 58.0; 18:2� 28.0; 18:3�0.8; others (4) � 1.9

Allenic acid, %: 5.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Phlomus iberica (Vis.). Adyl

Synonyms

Eremostachys iberica Vis.

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Phlomus lycia D. Don. 463 Lamiaceae

Family: Lamiaceae

Flower

Essential oil, % dry wt: 0.012

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

67 [in Russian]

Phlomus laciniata (Bunge) Adyl.

Synonyms

Eremostachys laciniata (L.) Bunge

Family: Lamiaceae

Seed

Oil, % dry wt: 16.3–30.23

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, 67

Phlomus lanata L.

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/ wt: 0.35

Composition of essential oil (GLC, Supelcowax 10;GC/MS, HP-5 MS), %: a-Thujene� tr; a-pinene� 25.41; sabinene � 0.65; b-pinene � 1.74; b-myrcene � 1.58; a-phellandrene � 1.27; a-terpinene � 0.87; p-cymene � tr; limonene �15.67; (Z)-b-ocimene � 2.89; benzene acetalde-

hyde � tr; (E)-b-ocimene � 2.07; g-terpinene �0.42; a-terpinolene � 1.32; linalool � 0.78;

nonanal � 1.03; a-campholenal � tr; terpin-4-

ol � tr; a-terpineol � 0.24; decanal � 0.26;

geraniol � tr; carvacrol � 3.26; cyclosativene

� 0.34; a-copaene � 1.26; isocomene � 4.91;

b-cubebene � tr; b-elemene � tr; (E)-

caryophyllene � 8.76; b-gurjunene � tr; a-himachalene � 1.80; a-humulene � tr;

dehydroaromadendrene � 3.18; 9-epi-(E)-

caryophyllene � tr; g-muurolene � 4.53; (E)-b-ionone� 0.33; cis- b-guaiene� 0.49; valencene

� tr; d-cadinene � 1.51; a-calacorene � tr; (E)-nerolidol � 0.68; caryophyllene oxide � 2.86;

humulene epoxide II � 0.35; tetradecanal � tr;

hexadecanal � 0.77; 6,10,14-trimethyl-2-

pentadecanone � 0.94; hexadecanoic acid �0.85; 3,7,11,15 � tetramethyl-2-hexadecen-1-ol

� 3.54; tricosane � 0.20; total � 96.85

½a�25D : –3.4� (CH2Cl2, C 0.6)

Activity: Essential oil

Bacteriostatic activity, MIC mg/mL:

Staphyllococcus aureus, S. epidermidis,Enterobactera cloacae >20; Klebsiella

pneumoniae � 8.0; Pseudomonas aeruginosa �6.5; Candida albicans, C. tropicalis, Torulopisglabrata � 4.65–4.95; Escherichia coli � 3.0

a-PineneBacteriostatic activity, MIC mg/mL:

Staphyllococcus aureus � 7.5; S. epidermidis

� 9.5; Pseudomonas aeruginosa � 6.0;

Enterobacter cloacae � 15.0; Klebsiella

pneumoniae � 8.0; Candida albicans � 4.0; C.

tropicalis � 4.0; Torulopis glabrata � 2.0;

Escherichia coli � 2.0

References

1. M. Couladis, A. Tanimanidis, O. Tzakou, I.B. Chinou, C.

Harvala, Planta Med. 66, 670 (2000)

Phlomus lycia D. Don.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 6.0

Oil (petroleum ether, 30–60�C), % dry wt: 18.0

n40D : 1.4646

Iodine value (Wijs), % J2: 84.0; 82.0 (cald)

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Lamiaceae 464 Phlomus Maximoviczii Rgl.

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.3; 18:0 � 1.6; 18:1 � 70.0; 18:2� 6.5; 18:3�0.1; others (6) � 1.3

Allenic acid, %: 13.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Position

of TAG 16:0 18:0 18:1 18:2(9,12) 18:2(5,6) 18:3

Sn-1 3.8 1.0 33.9 59.0 59.0 2.3

Sn-2 0.6 – 25.9 72.0 – 1.5

Sn-3 3.1 0.8 50.3 41.8 41.8 4.0

Phlomus Maximoviczii Rgl.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 149.1 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �5.4; 18:0� 1.3; 18:1� 26.9; 18:2� 62.1; 18:3�2.4

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32 (1971)

Phlomus oreophilla Kar. et. Kir.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 17.6 [1]

IR

UV

FAs

Composition (GLC, 17% EGS), %: 14:0 � tr; 16:0

� 3.4; 16:1(9) � 0.6; 18:0 � 1.4; 18:1 � 35.1;

18:2(9,12) + 18:2(5,6) � 56.5; 18:3 � 3.0

Composition of oil (CC): Hydrocarbons + caro-

tenes � 1.1; TAG � 91.1; free FAs � 0.6;

epoxy-TAG + oxo-TAG � 2.1; hydroxy-TAG

� 0.4; triterpenols + sterols � 2.6; GL � 0.6 [1]

TAG

Main components (Coleman), mol %: LabLLab �1.0; OLLab � 6.5; LLLab � 6.3; OOLab � 2.4;

LOLa � 2.4; POO � 1.0; POL � 1.0; LOO �8.4; LOL� 4.0; OOO� 4.4; PLO� 2.3; PLL�2.2; OLO � 12.8; OLL � 24.5; OLLe � 1.2;

LOLe � 1.0; OOLe � 1.0; LeOP � 1.0; LLL �11.7; LLLe � 1.0; StLO + StLL � 1.1 [2]

Composition, %: SSU + USS � 0.0; SUS � 1.5(2);

SUU � 2.6(7); UUS � 3.9(9); USU � 0.6 (4);

UUU � 91.4 (21) [3]

FAs (GLC), %: 14:0 � tr; 16:0 � 2.5; 16:1 � 0.3;

18:0 � 0.6; 18:1 � 36.4; 18:2(5.6) � 7.1;

18:2(9,12) � 50.5; 18:3(9,12,15) � 2.6 [3]

The Positional Distributions of FAs in TAG (stereo

specific analysis), mol %: [3]

Epoxy-TAG + oxo-TAG

Usual FAs of Epoxy-TAG + Оxo-TAG (GLC), %:

14:0 � tr; 16:0 � 5.3; 16:1(9) � tr; 18:0 � 1.2;

18:1 � 27.9; 18:2 � 60.0; 18:3 � 5.6 [1]

Epoxy-FAs + oxo-FAs

Composition (GLC), %: Epoxy-18:0 � 27.1, 9,10-

epoxy� 18:1 - 53.3; epoxy-18:2� 4.0; oxo-18:1

� 15.6 [1]

Cis-9,10-Epoxy-18:0

Cis-9,10-Epoxy-18:2 (12)

Cis-12,13-Epoxy-18:1 (9)

Cis-15,16-Epoxy-18:2 (9,2)

Oxo-18:0

9-Oxo-18:1(12)

Free FAs

Composition (GLC), %: 14:0 � tr; 16:0 � 4.8;

16:1(9) � tr; 18:0 � 1.2; 18:1(9) � 30.8;

18:2(9,12) � 44.4; 18:2(5,6) � 15.2; 18:3 �3.6 [1]

Hydroxy TAG

Usual FAs of Hydroxy-TAG (GLC), %: 14:0 � tr;

16:0 � 4.4; 16:1(9) � 0.3; 18:0 � 1.3; 18:1 �33.0; 18:2 � 57.0 18:3 � 4.0 [1]

Page 77: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Phlomus regelii M. Pop. 465 Lamiaceae

Hydroxy FAs

Components: 12-Hydroxy-18:1(9), 9-hydroxy-

18:1(12), 13-hydroxy-18:2(9,11), 9-hydroxy-

18:2(10,12) [1,2]

Sterylglycosides [1]

Hydrocarbons

Composition (CLC, 5% SE 30), %: Saturated C17�C22 � tr; C23 � 0.5; C24 � 0.4; C25 � 2.6; C26 �1.2; C27 � 10.2; C28 � 3.6; C29 � 32.6; C30 �6.6; C31 � 33.8; C32 � 3.0; C33 � 5.5 [2]

a-Carotene

UV [1]

Sterols

Components: b-Sitosterol, stigmasterol,

camphesterol [2]

References

1. D.T. Asilbekova, S.D. Gusakova, A.U. Umarov, Chem. Nat.

Comp. 56, 525 (1983)

2. D.T. Asilbekova (unpublished)

3. T.V. Khomova, D.T. Asilbekova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 19, 266 (1983)

Phlomus ostrowskiana (Rgl.) Adyl.

Family: Lamiaceae

Aerial Part

Extract (chloroform) [1]

Components: FAs, ursolic acid, b-sitosterol, hydro-carbons (C31) [2]

Free FAs

Components (CC, MS), %: 20:0–32:0 [1]

Hydrocarbons

Components, %: Saturated C29 – C32, C33 (main) [1]

b-Sitosterol [1]

Ursolic acid (CC, UV, IR, MS) [1]

Chlorophyll [1]

References

1. K.K. Kholmatov, I.A. Kharlamov, K.I. Alimov, M.T.

Ikramov, Chem. Nat. Comp. 19, 761 (1983)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

68 [in Russian]

Phlomus pungens Willd.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.06 [1]

Carotene [1]

Sterols, % dry wt: 0.03 [2]

Terpenoids

Phytol, % dry wt: 0.09 [2]

Activity: Extract has tonic, diuretic, and

antituberculosis effects [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

65 [in Russian]

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

Phlomus purpurea L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.4

Oil (petroleum ether, 30–60�C), % dry wt: 21.0

n40D : 1.4647

Iodine value (Wijs), % J2: 82.0; 81.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.6; 18:0 � 3.4; 18:1 � 66.0; 18:2� 6.8; 18:3�tr; others (7) � 1.1

Allenic acid, %: 15.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Phlomus regelii M. Pop.

Family: Lamiaceae

Seed

Oil (hexane), %: 12.0 [1]

IR

UV

Page 78: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 466 Phlomus rigida Labill.

FAs

Composition (GLC, 17% EGS), %: 14:0 � tr; 16:0

� 4.0; 16:1(9) � 0.4; 18:0 � 0.6; 18:1 � 69.2;

18:2(9;12) + 18:2(5;6) � 25.8; 18:3 � tr

Composition of oil (CC): Hydrocarbons + caro-

tenes � 0.3; TAG � 92.4; free FAs � 2.4;

hydroxy-TAG � 1.9; triterpenols + sterols �2.9; GL � 0.1

TAG

Main components (Coleman), mol%: POLab� 1.7;

OOLab � 15.5; LabOLab � 1.8; LabOL � 2.8;

OLLab � 1.2; PLabO � 1.1; OLabO � 5.2;

OLabLab � 2.3; OLabLab � 2.3; OLabL �1.8; POO � 7.4; POL � 1.3; StOO � 1.0;

OOO � 33.9; OOL � 12.3; OOLe � 1.0; LOL

� 1.1; LLO � 1.0; OLO � 2.5; others � 5.1 [2]

Composition, %: SSU + USS � 0.1(2); SUU �14.1(9); UUS � 0.4(6); USU � 0.8(4); UUU �84.6(15) [2]

FAs (GLC, 17%EGS),%: 14:0� tr; 16:0� 4.6; 16:1

� tr; 18:0 � 0.6; 18:1 � 70.5; 18:2(5.6) � 13.9;

18:2(9,12)� 9.8; 18:3� 0.6; others (1)� 2.7 [3]

The Positional Distributions of FAs in TAG (stereo

specific analysis), mol % [2]

Position

of TAG 16:0 18:0

18:1

+

16:1 18:2(5,6) 18:2(9,12) 18:3

Sn-1 12.7 1.6 63.5 20.7 20.7 1.5

Sn-2 0.9 – 78.7 4.8 15.3 0.3

Sn-3 0.2 0.2 69.3 30.3 30.3 –

Free FAs

Composition (GLC, 17% EGS), %: 14:0� tr; 16:0�5.8; 16:1(9) � 0.6; 18:0 � 2.0; 18:1(9) � 43.7;

18:2(5;6)� 22.3; 18:2(9,12)� 21.9; 18:3� 3.7 [1]

Hydroxy-TAG

Usual FAs of Hydroxy-TAG (GLC, 17% EGS), %:

14:0 � 0.5; 16:0 � 5.7; 16:1(9) � 0.9; 18:0 �1.5; 18:1 � 50.8; 18:2 � 39.5; 18:3 � 1.1 [1]

Hydroxy FAs

Components: 12-Hydroxy-18:1(9), 9-hydroxy-

18:1(12), 13-hydroxy-18:2(9,11), 9-hydroxy-

18:2(10,12) [1, 2]

Hydrocarbons

Composition (CLC, 5% SE 30), %: Saturated C17 -

C20 � tr; C21 � 0.5; C22 � tr; C23 � 4.3; C24 �

2.0; C25 � 10.7; C26 � 1.9; C27 � 13.6; C28 �10.3; C29 � 23.8; C30 � 2.4; C31 � 24.5; C32 �1.4; C33 � 4.6 [2]

b-Carotene

UV [1]

Sterols

Components: b-Sitosterol, stigmasterol,

camphesterol [2]

References

1. D.T. Asilbekova, S.D. Gusakova, A.U. Umarov, Chem. Nat.

Comp. 56, 525 (1983)

2. D.T. Asilbekova (unpublished)

3. T.V. Khomova, D.T. Asilbekova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 266 (1983)

Phlomus rigida Labill.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 15.0

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

n40D :1.4657

Iodine value (Wijs), % J2: 92.0; 89.0 (cald)

FAs (GLC, 20% LAC-2R 446), %: 16:0–7.4; 18:0–

1.5; 18:1–62.0; 18:2–14.0; 18:3–0.5; others

(8) � 2.3

Allenic acid, %: 12.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Phlomus salicifolia Rgl.

Family: Lamiaceae

Oil (hexane), %: 12.0 [1]

TAG

Main components (Coleman), mol %: LLL � 1.7;

OLL � 11.2; PLL � 1.8; OLO � 18.1; PLO �3.2; PLP� 0.1; LOL� 3.0; OOL� 20.0 POL�1.8; OOO � 32.6; POO � 5.6; others � 1.8 [1]

Page 79: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Physostegia virginiana (L.) Benth. 467 Lamiaceae

Composition, %: SSU + USS � 0.2; SUS � 0.4;

USU � 1.2; UUS + SUU � 11.6; UUU � 86.6

FAs (GLC, 17% EGS), %: 16:0 � 4.6; 16:1(9) �0.6; 18:0 � tr; 18:1 � 68.3; 18:2(9,12) +

18:2(5,6) � 26.4; 18:3 � 0.1

Free FAs

Composition (GLC), %: 14:0 � 4.9; 16:0 � 5.0;

16:1� tr; 17:0� tr; 18:0� tr; 18:1� 61.1; 18:2

� 29.0; 18:3 � tr; 20:0 � tr [2]

References

1. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

2. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Phlomus speciosa (Rup.) Adyl.(Eremostachys speciosa (Rup.))

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.75 [1]

Activity: Tincture has hypotensive effect.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

68 [in Russian]

Phlomus tuberosa L.

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.08 [1]

Seed

Oil, % dry wt: 19.3–27.5 [1–3]

Iodine value, % J2: 36.5 [2]; 157.0 (cald) [1]

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �1.7; 18:0� 0.2; 18:1� 30.7; 18:2� 66.3; 18:3�1.2 [3]

Activity: Extract has antibacterial and antifungal

properties [1].

Use: As spice [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

68 [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971) [in Russian]

Physostegia viorginiana

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.6

Oil, % dry wt: 35.2

HBr uptake, as C18 acid, %: 0.2

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Physostegia virginiana (L.) Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.6

Oil (petroleum ether, 30–60� C), % dry wt: 35.0

n40D : 1.4706

Iodine value (Wijs), % J2: 146.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �3.9; 18:0� 2.0; 18:1� 29.0; 18:2� 31.0; 18:3�22.0; others (3) � 0.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 80: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Position of

TAG 16:0 18:0 18:1 18:2(9,12) 18:2(5,6) 18:3

Sn-1 6.2 tr 7.3 19.8 4.7 62.0

Sn-2 – – 6.3 25.8 2.2 65.7

Sn-3 0.7 Tr 1.1 5.1 8.1 85.0

Position

of TAG 16:0 18:0 18:1 18:2(9,12) 18:2(5,6) 18:3

Sn-1 11.4 tr 16.0 25.0 2.8 44.8

Sn-2 0.9 – 19.1 33.6 1.3 45.1

Sn-3 0.3 Tr 4.2 22.1 3.1 70.3

Lamiaceae 468 Plectranthus glaucocalyx Maxim.

Plectranthus glaucocalyx Maxim.

Family: Lamiaceae

Seed

Oil (petrol ether), %: 24.6 (Sample 1, wild plant from

Russian); 10.5 (Sample 2, introduced in Uzbekistan

plant) [1]

FAs

Composition (GLC, 17% EGS), %: 14:0 � tr; 16:0

� 3.0; 18:0 � 1.6; 18:1 � 6.9; 18:2(9,12) +

18:2(5,6) � 24.7; 18:3 � 63.8 (1)

14:0 � tr; 16:0 � 4.3; 18:0 � 1.3; 18:1 � 14.8;

18:2(9,12) + 18:2(5,6) � 30.5; 18:3 � 49.1 (2)

Composition of oil (CC): Hydrocarbons � 1.0;

steryl esters � 1.0; methyl ether of FAs �0.2; unidentified � 0.3; TAG � 88.4; free

FAs � 1.8; esters of triterpenioc acids �0.7; DAG � 0.9; MAG � 0.8; sterols �2.0; chlorophyll’s + unidentified components

� 2.9 (1)

Hydrocarbons � 0.9; steryl esters � 1.2; methyl

ether of FAs � 0.3; unidentified � 0.2; TAG �85.3; free FAs � 2.5; ester of triterpenioc

acids � 1.3; DAG � 1.6; sterols � 2.6;

MAG � 1.2; chlorophyll’s + unidentified com-

ponents � 2.9 (2)

Steryl esters

FAs (GLC), %: 12:0 � 1.2; 14:0 � 1.4; 15:0–0.5;

16:0� 18.7; 18:0� 6.5; 18:1� 9.3; 18:2(9,12) +

18:2(5,6)� 30.9; 18:3� 12.7; 20:0� 13.5; 22:0

� 0.8; unidentified � 4.5 (1)

12:0� 1.0; 14:0� 0.6; 15:0� tr; 16:0� 34.8; 18:0

� 7.6; 18:1� 7.2; 18:2(9,12) + 18:2(5,6)� 25.8;

18:3� 13.2; 20:0� 6.0; 22:0� 0.6; unidentified

� 3.2 (2)

Methyl ethers of FAs

Composition (GLC), %: 12:0 � 4.0; 13:0 � 3.4;

14:0 � 7.2; 15:0 � 4.6; 16:0 �14.4; 17:0 � 5.8;

18:0 � 2.1; 18:1 � 19.5; 18:2(9,12) + 18:2(5,6)

� 13.4; 18:3 � 5.6; 20:0 � 5.7; 22:0 � 5.6;

unidentified � 8.7 (1)

12:0� 2.6; 13:0� tr; 14:0� 2.1; 15:0� tr; 16:0�12.7; 17:0 � 0.4; 18:0 � 5.7; 18:1 � 19.9;

18:2(9,12) + 18:2(5,6) � 26.5; 18:3 � 11.6;

20:0 � 5.0; 22:0 �6.2; unidentified � 7.3 (2)

TAG

FAs (GLC), %: 12:0� tr; 13:0� tr; 14:0� tr; 15:0

� tr; 16:0 � 2.1; 18:0 � tr; 18:1 � 5.0;

18:2(9,12) � 17.0; 18:2(5,6) � 5.0; 18:3 �70.9; 20:0 � tr; 22:0 � tr (1)

12:0� tr; 13:0� tr; 14:0� tr; 15:0� tr; 16:0� 3.9;

18:0 � tr; 18:1 � 13.3; 18:2(9,12) � 27.1;

18:2(5,6) � 2.3; 18:3 � 53.4; 20:0 � tr; 22:0 �tr (2)

The Positional Distributions of FAs in TAG of sample 1(stereo specific analysis), mol %: [2]

The Positional Distributions of FAs in TAG of sample 2

(stereo specific analysis), mole %: [2]

Free FAs

Composition (GLC), %: 12:0 � 0.2; 13:0 � tr; 14:0

� 0.5; 15:0� 0.1; 16:0� 12.4; 17:0� tr; 18:0�4.2; 18:1� 12.4; 18:2(9,12)� 23.8; 18:2(5,6)�6.1; 18:3 � 40.0; 20:0 � 0.3; 22:0 � tr (1)

12:0 � tr; 13:0 � tr; 14:0 � tr 15:0 � tr; 16:0 �10.6; 17:0 � tr; 18:0 � 3.6; 18:1 � 21.2;

18:2(9,12) � 30.0; 18:2(5,6) � 3.9; 18:3 �30.7; 20:0 � tr (2)

DAG

FAs (GLC), %: 12:0 � tr; 13:0 � tr; 14:0 � 0.1;

16:0 � 4.9; 17:0 � tr; 18:0 � 2.5; 18:1 � 7.9;

18:2(9,12)� 33.7; 18:2(5,6)� 5.5; 18:3� 45.4;

20:0 � tr (1)

12:0 � tr; 13:0 � tr; 14:0 � 0.1; 15:0 � tr; 16:0 �7.5; 17:0 � tr; 18:0 � 2.6; 18:1 � 19.5;

18:2(9,12) � 34.0; 18:2(5,6) � 2.4; 18:3 �33.9; 20:0 � tr (2)

MAG

FAs (GLC), %: 12:0 � tr; 13:0 � tr; 14:0 � 0.4;

15:0 � tr; 16:0 � 10.9; 17:0 � tr; 18:0 � 3.2;

18:1� 15.7; 18:2(9,12)� 29.1; 18:2(5,6)� 3.4;

18:3 � 37.3; 20:0 � tr (1)

Page 81: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Pogostemon parviflorus Benth. 469 Lamiaceae

12:0 � tr; 13:0 � tr; 14:0 � 0.4; 15:0 � tr; 16:0 �

12.3; 18:0� 4.1; 18:1� 21.7; 18:2(9,12)� 30.7;

18:2(5,6) � 1.3; 18:3 � 29.5; 20:0 � tr (2)

References

1. T.V. Khomova, S.D. Gusakova, Y.M. Murdakhaev,

A.U. Umarov, Chem. Nat. Comp. 20, 27 (1984)

Plectranthus inflexus Vahl. et Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8 [1]

Oil (petroleum ether), %: 39.0

n40D : 1.4754

Iodine value, % J2: 201.0; 204.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �4.5; 18:0� 2.1; 18:1� 10.0; 18:2� 25.0; 18:3�58.0; others (1) � 0.1

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids

2(5), 371 (1967)

Plectranthus rugosus Wall.

Family: Lamiaceae

Leaf

Extract (8 kg fresh leaves, after soxhletting with

pet ether were extracted with hot MeOH for 48 h,

CC) [1]

(20S)-3a-Hydroxy-18a,19a-urs-12-en-30b-oic acid

(plectranthoic acid A), C30H48O3

½a�25D : +59� (c 0.1, MeOH) [1]

M.p. [1]

IR, 1H-NMR MS [1]

(14 S)-3a-Hydroxy-18a,19a-urs-12-en-27a-oic acid

(plectranthoic acid B), C30H48O3

[aD]: +62� (c 0.12, MeOH [1]

M.p [1]

IR, 1H-NMR, MS [1]

Fresh foliage and terminal branchlets

Essential oil, (steam distillation) %: 0.05 [2]

Composition (GC-MS, analytical GLC on FFAP-

FS-WCOT), %: a-Pinene – 3.1; camphene –

0.03; b-pinene – 0.1; sabinene – 0.2; 3-carene –

0.7; myrcene – 2.1; a-phellandrene – 4.6; a-terpinene –.04; limonene – 2.4; b-phellandrene– 2.3; cis- b-ocimene – 0.2; g-terpinene – 0.2;

trans-b-ocimene – 1.0; p-cymene – 2.1;

terpinolene – 1.0; thujone + 1-nonene-3-ol –

0.7; a-copaene – 0.3; b-bourbonene – 0.3; b-cubebene – 0.4; linalool – 0.9; caryophyllene –

22;0; terpinene-4-ol – 0.7; humulene – 1.6; g-muurolene – 1.4; germacrene D – 7.5; piperitone

epoxide – 0.8; a-muurolene – 1.0;

bicyclogermacrene – 0.8; d-cadinene – 2.8; g-cadinene –1.1; a-curcumene – 0.2; C15H26O –

1.1; C15H26O – 0.7; caryophyllene oxide – 3.1;

aromatic ester C15H26O2 – 1.2; C15H26O – 2.9;

sesquiterpene alcohol C15H26O – 1.4; T-cadinol

+ aromatic alcohol C10H14O – 1.2; sesquiterpene

alcohol C15H26O – 1.7; torreyol – 1.3; C15H26O

–1.0; a-cadinol – 3.1; sesquiterpene alcohol

C15H26O – 0.6 [2]

IR, 1H NMR, 13C NMR [2]

References

1. T.K. Razdan, V. Kachroo, S. Harkar, G.L. Koul, Tetrahedron

38, 991 (1982)

2. P. Weyerstahl, V.K. Kaul, N. Meier, M. Weirauch,

H. Marschall, Planta Med. 48(2), 99 (1983)

Pogostemon parviflorus Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.2

Oil (petroleum ether, 30–60�C), % dry wt: 36.0

n40D : 1.4685

Iodine value (Wijs), % J2: 130.0; 143.0 (cald)

Page 82: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 470 Prasium majus L.

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �8.5; 18:0� 3.3; 18:1� 11.0; 18:2� 76.0; 18:3�1.0; others (3) � 0.7

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Prasium majus L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 7.2

Oil (petroleum ether, 30–60� C), % dry wt: 15.0

n40D : 1.4642

Iodine value (Wijs), % J2: 108.0; 107.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �6.1; 18:0� 4.1; 18:1� 48.0; 18:2� 35.0; 18:3�0.2; others (4) � 0.9

Allenic acid, %: 6.2

IR

Prunella asiatica Nak.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60� C), % dry wt: 20.0

n40D : 1.4754

Iodine value (Wijs), % J2: 194.0; 200.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �5.7; 18:0� 2.3; 18:1� 13.0; 18:2� 19.0; 18:3�59.0; others (4) � 0.7

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Prunella grandiflora (L.) Jacq.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 229.1 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �5.0; 18:0 � 1.6; 18:1 � 8.4; 18:2� 21.2; 18:3�63.8

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971)

Prunella vulgaris L.

Synonyms

Brunella vulgaris Moench.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.9 [1]

Oil (petroleum ether, 30–60� C), % dry wt: 19.0 [1];

16.0 [2]

n40D : 1.4752

Iodine value (Wijs), % J2: 189.0; 196.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �7.7; 18:0� 2.1; 18:1� 14.0; 18:2� 16.0; 18:3�60.0; others (2) � 0.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Page 83: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Pycnanthemum virginianum L. 471 Lamiaceae

Prunella vulgaris L.var. larceolata (B)

Family: Lamiaceae

Seed and Pericarp

Ash, %: 3.1

Mass of 1,000, g: 1.8 [1, 2]

Oil, % dry wt: 22.4 [1]; 28.0 (petroleum ether, 30–

60� C) [2]HBr uptake, as C18 acid, %: 0.1

n40D : 1.4740 [2]

Iodine value (Wijs), % J2: 193.0; 194.0

(cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 �8.4; 18:0� 2.1; 18:1� 13.0; 18:2� 17.0; 18:3�59.0; others (1) � 0.7

IR

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16, N4, 221 (1962)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Prunella vulgaris var. lilacina Nakai.

Family: Lamiaceae

Leaves and Stems

Sterols: a-Spinasterol and stigmast-7-enol [1]

M.p. [1]

[a]D20:+3.0o [1]

Triterpenoic acids: Ursolic acid and oleanolic acid [1]

Root

Triterpenoic acids (GLC): Ursolic acid and oleanolic

acid and others [2]

Betulinic acid [2]

M.p. [2]

[a]D20: +4.0o (CHCl3, C 0.5)

References

1. H. Kojima, H. Ogura, Phytochemistry 25, 729 (1986)

2. H. Kojima, H. Tominaga, Sh. Sato, H. Ogura, Phytochemistry

26, 1107 (1987)

Pycnanthemum muticum Pers.

Family: Lamiaceae

Seed and Pericarp

Ash, %: 4.8 [1]

Mass of 1,000, g: 0.4 [1]

Oil, % dry wt: 35.0 [1]; 34.8 (petroleum ether, 30–60�

C) [2]

n40D : 1.4775 [2]; 1.4772 [3]

HBr, uptake, as C18 epoxy acid, %: 0.2 [2]

Iodine value (Wijs), % J2: 215.0 [2]; 209; 212

(cald) [3]

FAs

Saponification value, mg KOH: 184.0 [2]

IR [2, 3]

FAs

Composition (GLC), %: 18:1 � 19.0; 18:2 � 14.0;

18:3 � 68.0; conjugated 18:3 � 0.1 (20%

Apiezon L) [2]

16:0 � 2.9; 18:0 � 2.8; 18:1 � 9.2; 18:2 � 19.0;

18:3 � 65.0; others (6) � 1.2, (20% LAC-2R

446) [3]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

3. J.M. Hageman, F.R. Earle, I.A.Wolff, A.S. Barclay, Lipids, 2,

371 (1967)

Pycnanthemum virginianum L.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 206.5 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 �4.4; 18:0 � 1.9; 18:1 � 8.4; 18:2� 28.2; 18:3�57.1

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971)

Page 84: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 472 Pycnanthemum virginianum (L.) Durand and Jackson

Pycnanthemum virginianum (L.) Durandand Jackson

Family: Lamiaceae

Leaves

Terpenoids

Composition, %: Isomenthone – 77.7; pulegone –

14.5; limonene – 1.8; menthone – 0.7; a-pinene –0.5; b-pinene – 0.5; myrcene – 0.5; 1-octen-3-ol

– 0.3; 1.8-cineol – 0.2; camphene – 0.1; sabinene

– 0.1

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Rosmarinus officinalis

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 12.0

n40D : 1.4681

Iodine value (Wijs), % J2: 130; 136.5 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.9; 18:0 – 3.8; 18:1 – 20.0; 18:2 – 64.0; 18:3 –

2.1; others (6) – 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia acetabulosa L. var. simplicifoliaBoiss.

Family: Lamiaceae

Seed

Mass of 1,000, g: 6.0

Oil (petroleum ether, 30–60�C), % dry wt: 18.0

n40D : 1.4686

Iodine value, % J2: 132.0; 138.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.1; 18:0 – 1.5; 18:1 – 19.0; 18:2 – 67.0; 18:3 –

1.3; others (6) – 0.5

Allenic acid, %: 2.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia adenostachya Juz.

Family: Lamiaceae

Inflorescence

Essential oil, %: 0.1

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

72 [in Russian]

Salvia aegyptiaca L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 22.0 [1]

n40D : 1.4746 [1]

Iodine value, % J2: 190.0; 194.0 (cald) [1]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.0; 18:0 – 3.5; 18:1 – 11.0; 18:2 – 21.0; 18:3 –

57.0; others (2) – 0.2 [1]

IR

Seed

Oil (hexane), %: 17.7 [2]

Page 85: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia aethiopis L. 473 Lamiaceae

TAG

Main components (by Coleman): LeLeLe – 17.5;

LLeLe – 8.4; OLeLe – 17.8; LeLLe – 5.3;

LeOLe – 3.9; PLeLe – 4.6; LLLe – 2.6; OLLe

– 5.4; LOLe – 1.8; OOLe – 4.2; OLeL – 4.4;

PLLe – 1.4; LLeL – 1.0; POLe – 1.0; PLeL – 1.2;

PLeO – 2.4; OLeO – 4.6; OLL – 1.4; OOL – 1.0;

LePLe – 1.3; PLO – 1.0; OLO – 1.4; OOO – 1.0;

OPLe – 1.4; LPLe – 1.0; others – 1.8 [2]

Сomposition, %: SSU +USS – 0.6; USU – 4.1; SUS

– 0.5; UUS + SUU – 12.6; UUU – 82.2 [2]

FAs of TAG

Composition (GLC, 17% PEGS), %: 16:0 – 6.2;

16:1(9) – 0.2; 18:0 – tr; 18:1(9) – 22.7;

18:2(9,12) – 14.8; 18:3(9,12,15) – 56.1 [2]

References

1. J.M. Hageman, F.R. Earle, I.A.Wolff, A. S. Barclay, Lipids 2,

371 (1967)

2. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Salvia aethiopis L.

Family: Lamiaceae

Sterols, % dry wt: 0.05 [1]

Terpenoids

Phytol, % dry wt: 0.09 [1]

Aerial Part

Essential oil, %: 0.12 – 0.14 [2]

Components: Essential oil, phytol, steroids [3]

Composition (GLC, 15% Carbowax 20): a-Pinene –0.2; b-pinene – 0.5; cineole – 0.1; thujone – 1.1;linalool – 1.7; borneol – 4.6; linalyl acetate – 1.3;

bornyl acetate – 21.8; and others [3]

Inflorescence

Essential oil, %: 0.28 [3]

Components: a-Pinene, b-pinene, limonene, bor-

neol, caryophyllene, camphor [3]

Leaf

Essential oil, %: 0.16 [3]

Components: a-Pinene, b-pinene, limonene, bor-

neol, caryophyllene, camphor [3]

Seed

Oil, % dry wt: 25.3 (chloroform) [4]; 7.2 [5]; 23.0 –

27.8 (hexane) [3, 6, 7]

d1515: 0.9340 [7]

d25: 0.9358 [7]

n25: 1.4838-1.4860 [7]

Iodine value, % J2: 153.26 [4]; 169 – 208.7 [7]

Saponification value, mg KOH: 195.4 [7]

FAs

Composition, %: 14:0 – 0.12; 16:0 - 8.25; 16:1 -

1.53; 18:0 - 6.00; 18:1 – 28.90; 18:2 – 18.80;

18:3 – 36.21 [4]; 13:0 – tr; 14:0 – tr; 16:0 - 10.5;

16:1(7Z) – tr; 16:1(9Z) – 0.1; 18:0 – 3.0; 18:1 –

8.4; 18:2 – 73.4; 18:3 – 2.9; 20:1(11Z) – 1.2; 22:0

- tr; total - 99.5 (GC/MS, SGE BPx70) [5]; 14:0 –

tr; 16:0 – 9.0; 16:1 – 0.6; 18:0 – 1.9; 18:1 – 16.7;

18:2 – 13.7; 18:3 – 58.1, other (1) – tr (GLC,

20% PEGS) [6];

Seed and Pericarp

Mass of 1,000, g: 2.2 [8]

Oil (petroleum ether, 30–60˚C), % dry wt: 22.0 [8]

n40D : 1.4747 [8]

Iodine value, % J2: 186.0; 192.0 (cald) [8]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.8; 18:0 – 2.4; 18:1 – 20.0; 18:2 – 12.0; 18:3 –

58.0; others (6) – 1.0 [8]

IR [8]

Stem

Essential oil, %: 0.28 [3]

Components: a-Pinene, b-pinene, limonene, bor-

neol, caryophyllene, camphor [3]

Activity: Antimicrobial activity of oil, MIC, mg/ml:

Staphylococus aureus ATCC 6538 and Escherichiacoli ATCC 8379 – 2.2; Mycobacterium stegmatis and

Candida albicans ATCC 10231 – 1.1 [5]. Antimicro-

bial activity of 18:1 and 18:2, MIC, mg/ml:Staphylococus aureus – 2.2; Escherichia coli and Can-

dida albicans – not active [5]

18:0 did not show activity against Staphylococusaureus, Escherichia coli, and Candida albicans [5]

Use: Essential oil may be use in perfume [3]

Page 86: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 474 Salvia albimaculata Hedge and Hub. – Mor.

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. R. Ivanic, K. Savin, Planta Med. 30, 26 (1976)

3. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, p. 72 in Russian

4. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

5. T. Kilic, T. Dirmenci, F. Satil, G. Bilsel, T. Kocagoz, M.

Altun, A.C. Goren, Chem. Nat. Comp. 41, 168 (2005)

6. A.V. Patudin, I.U Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

7. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

8. J.M. Hageman, F. R. Earle, I. A. Wolff, A. S. Barclay, Lipids,

2, 371 (1967)

Salvia albimaculata Hedge and Hub. –Mor.

Family: Lamiaceae

Seed

Oil (hexane), %: 3.2

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.5;

15:0 – 0.1; 16:0 – 9.7; 16:1(7Z) – 0.2; 16:1(9Z) –

0.2; 17:0 – 0.1; 18:0 – 2.4; 18:1(9Z) – 16.1;

18:1(11Z) – 0.9; 18:2 – 37.2; 18:3 – 1.8; 20:0 –

0.4; 20:1 – 0.3; 22:0 – 0.1

References

1. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia amplexicaulis Lam.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.9

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4738

Iodine value, % J2: 181.0; 185.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.2; 18:0 – 3.2; 18:1 – 11.0; 18:2 – 36.0; 18:3 –

44.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia apiana

Family: Lamiaceae

Seed and Pericarp

Ash, %: 3.8

Mass of 1,000, g: 1.2

Oil, % dry wt: 6.9

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Salvia apiana Jeps.

Family: Lamiaceae

Seed

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 6.9

n40D : 1.4733

Iodine value, % J2: 160.0; 168.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.1; 18:0 – 3.4; 18:1 – 21.0; 18:2 – 31.0; 18:3 –

36.0; others (8) – 1.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 87: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia bicolor Desf 475 Lamiaceae

Salvia argentea L.

Family: Lamiaceae

Aerial Part

Acetone extract (from dried 250 g plant material), g:

17.0 [1]

Triterpenoids (CC), mg: Oleanolic acid – 7.0; ursolic

acid – 40; and four new ursine and two oleanene

triterpenoids – sum 450 mg [1]

Seed

Oil (hexane), %: 24.7 [2]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – tr; 16:0

– 8.5; 16:1 – 0.8; 18:0 – 2.6; 18:1 – 20.6; 18:2 –

16.5; 18:3 – 50.4; others (2) – 0.6 [2]

References

1. M. Bruno, G. Savona, J.A. Hueso-Rodriguez, C. Pascual,

B. Rodriguez, Phytochemistry 26, 497 (1987)

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

Salvia austriaca Jacq.

Family: Lamiaceae

Sterols, % dry wt: 0.07 [1]

Terpenoids

Phytol, % dry wt: 0.07 [1]

Aerial Part

Essential oil, %: 0.03 [1]

Components: Thujone, borneol, camphor,

caryophyllene [2]

Flower

Essential oil, %: 0.03 [1]

Components: a-Pinene, b-pinene, borneol,

caryophyllene [2]

Seed

Oil (hexane), %: 28.1 [2, 3]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – 0.7;

16:0 – 6.4; 16:1 – 1.1; 18:0 – 2.7; 18:1 – 10.4;

18:2 – 30.3; 18:3 – 48.4; others-(1) – tr [3]

Use: Essential oil of flowers may be used in perfume

[1].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

73 [in Russian]

3. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia bellotaeflora Benth.

Family: Lamiaceae

Aerial part

Petroleum ether extract (30–60�, from 1,200 g plant

material), %: 1.32

Components, mg: 3-Epioleanolic acid C30H48O3 –

887; oleanolic acid C30H48O3 – 343; sitosterol

C29H56O – 310

References

1. X.A. Dominguez, F.H. Gonzalez, Phytochemistry 11, 2641

(1972)

Salvia bicolor Desf

Family: Lamiaceae

Seed

Mass of 1,000, g: 7.0

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4666

Iodine value, %: 119.0; 123.0 (cald)

FAs

Page 88: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 476 Salvia brachyantha (Bordz.) Pobed.

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

14.0; 18:0 – 2.6; 18:1 – 25.0; 18:2 – 55.0; 18:3 –

2.1; others (7) – 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia brachyantha (Bordz.) Pobed.

Family: Lamiaceae

Seed

Mass of 1,000, g: 0.9

Oil (petroleum ether, 30–60�C), % dry wt: 22.0

n40D : 1.4733

Iodine value, % J2: 176.0; 182.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.1; 16:1 – 1.8; 18:0 – 14.0; 18:1 – 29.0; 18:2 –

45.0; 18:3 – 45.0; others (4) – 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia bracteata Russ.

Family: Lamiaceae

Seed

Mass of 1,000, g: 10.0 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 6.9 [1]

n40D : 1.4683 [1]

Iodine value, % J2: 132.0; 134.0 (cald) [1]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.1; 18:0 – 3.4; 18:1 – 21.0; 18:2 – 31.0; 18:3 –

36.0; others (8) – 1.0 [1]

IR

Seed

Oil (hexane), %: 8.7 [2]

FAs

Composition (GC/MS, SGE BPx70), %: 13:0 – 0.1;

14:0 – 0.4; 3-hydroxy-14:0 – 0.7; 16:0 – 8.2;

16:1(7Z) – tr; 16:1(9Z) – 0.1; 18:0 – 2.9; 18:1 –

15.4; 18:2 – 64.3; 18:3 – 3.8; 20:1(11) – 1.1; 22:0 –

tr; total – 97.1 [2]

Activity: Antimicrobial activity of oil, MIC, mg/mL:

Staphylococus aureus ATCC 6538 – 1.1; Escherichia

coli ATCC 8379 – 0.5; Mycobacterium stegmatis andCandida albicans ATCC 10231 – 1.1 [2]

Antimicrobial activity of FAs

18:1 and 18:2, MIC, mg/mL: Staphylococus aureus– 2.2; Escherichia coli and Candida albicans –

not active [2]

18:0: Did not show activity against Staphylococusaureus, Escherichia coli and Candida albicans

[2]

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. T. Kilic, T. Dirmenci, F. Satil, G. Bilsel, T. Koсagoz,M. Altun, A. C. Goren, Chem. Nat. Comp. 41, 223 (2005)

Salvia breviflora Moc and Sesse

Family: Lamiaceae

Aerial Part

Oleanolic acid

Ursolic acid

References

1. G. Cuevas, O. Collera, F. Garcia, J. Cardenas, E. Maldonado,

A. Ortega, Phytochemistry 26(7), 2019 (1987)

Salvia candidissima Vahl.

Family: Lamiaceae

Essential oil

Composition (GLC, 10% Carbowax): a-Pinene –

22.6; camphene – 1.7; b-pinene – 34.4; myrcene

Page 89: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia carduacea Benth. 477 Lamiaceae

– 1.8; a-phellandrene – 3.6; a-terpinene – 0.2;

limonene – 1.5; 1,8-cineole – 8.4; g- terpinene –tr; r-cymene – 2.0; a-thujone – 0.5; b-thujone –tr; camphor – 0.6; linalool – 0.2; linalyl acetate –

1.1; bornyl acetate – 3.5; borneol – 3.1;

isoborneol – 2.2; terpinen-4-ol – 1.5; b-caryophyllene – 4.2; a-humulene – 0.5; a-terpinyl acetate – tr; geranyl acetate – 2.0; gera-

niol – 2.6 (from Anatolia, Turkey) [1]

Seed

Oil (hexane), %: 5.6 [2]

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.3;

16:0 – 21.0; 18:0 – 4.5; 18:1(9Z) – 21.1;

18:1(11Z) – 1.0; 18:2 – 19.2; 18:3 – 20.9 [2]

References

1. A. Bayrak, A. Akgul, Phytochemistry 26(3), 846 (1987)

2. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia candidissima ssp. candidissima

Family: Lamiaceae

Seed

Oil (hexane), %: 0.6

FAs

Composition (GC/MS, ISGEBPx70), %: 14:0 – 0.4,

15:0 – 0.2, 16:0 – 20.8, 16:1(7Z) – tr, 16:1(9Z) –0.1, 18:0 – 5.7, 18:1 – 20.4, 18:2 – 20.8, 18:3 –

18.5, 20:1(11) – tr, 22:0 – tr, total – 91.5

Activity: Antimicrobial activity of oil, MIC, mg/mL:

Mycobacterium stegmatis – 0.25; Staphylococus

aureus ATCC 6538, Escherichia coli – ATCC 8379

and Candida albicans ATCC 10231 – not active.

References

1. T. Kilic, T. Dirmenci, F. Satil, G. Bilsel, T. Kosagoz,

M. Altun, A.C. Goren, Chem. Nat. Comp. 41, 168 (2005)

Salvia canescens C.A. Mey.

Family: Lamiaceae

Seed

Oil (hexane), %: 26.1 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – tr; 16:0

– 7.6; 16:1 – 0.9; 18:0 – 2.4; 18:1 – 7.8; 18:2 –

43.3; 18:3 – 38.0; others (1) – tr [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

73 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

Salvia cardiophylla Benth.

Family: Lamiaceae

Aerial part

Triterpenoids, %: b-Amyrin – 0.21; a mixture of

ursolic and oleanolic acids – 0.14 [1]

References

1. A.G. Gonzalez, J.R. Aerrera, J.G. Luis, A.G. Ravelo, E.A.

Ferro, Phytochemistry 27(5), 1540 (1988)

Salvia carduacea Benth.

Family: Lamiaceae

Seed

Mass of 1,000, g: 2.2

Oil (petroleum ether, 30–60�C), % dry wt: 30.040D : 1.4698

Iodine value, % J2: 148.0; 149.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.3; 18:0 – 2.8; 18:1 – 34.0; 18:2 – 19.0; 18:3 –

32.0; others (7) – 2.2

IR

Page 90: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 478 Salvia cedronella Boiss.

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia cedronella Boiss.

Family: Lamiaceae

Seed

Oil (hexane), %: 3.0

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.4;

15:0 – 0.2; 16:0 – 15.7; 16:1(7Z) – 0.3; 16:1(9Z)– 1.0; 17:0 – 0.2; 18:0 – 3.3; 18:1(9Z) – 20.5;

18:1(11Z) – 1.2; 18:2 – 49.2; 18:3 – 1.8; 20:0 –

0.6; 20:1 – 0.4; 22:0 – 0.7

References

1. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia ceratophylla L.

Family: Lamiaceae

Essential oil

Components: Limonene, borneol, camphor,

thujone, cineole [1]

Flower

Essential oil [1]

Seed

Oil (hexane), %: 19.3 [2]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – 0.4;

16:0 – 11.0; 16:1 – 0.8; 18:0 – 2.3; 18:1 – 16.6;

18:2 – 25.8; 18:3 – 43.1; others (1) – tr [2]

Seed and Pericarp

Mass of 1,000, g: 9.6 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 19.0 [3]

n40D : 1.4740 [3]

Iodine value, % J2: 179.0; 185.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.0; 18:0 – 1.6; 18:1 – 14.0; 18:2 – 36.0; 18:3 –

42.0; others (1) – 1.0 [3]

IR [3]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

73 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia cilicica Boiss and Kotschy.

Family: Lamiaceae

Root

Acetone extract

Triterpenoic acids (CC): Oleanolic acid, ursolic acid

Activity: The triterpenoic acids were found to be

potently active against amastigote (IC50 values of 7–

120 nM) and moderately active against promastigote

stages (IC50 values of 51–137 nM) of the donovani and

Leishmania major.

References

1. N. Tan, M. Kaloga, O.A. Radtke, A.F. Kideren, S. Oksuz,

A. Ulubelen, H. Kolodziej, Phytochemistry 61, 881 (2002)

Salvia coccinea

Family: Lamiaceae

Dehydrouvaol (3b,28-(OH)2; D12, 20(30))

References

1. K.S Mukherjee, P.K Ghosh, J. Indian Chem. Soc. 55, 850

(1978)

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Salvia cryptantha Montbr. and Aucher ex Bentham 479 Lamiaceae

Salvia columbaria Benth.

Family: Lamiaceae

Seed

Oil (hexane), %: 33.9 [1]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – 0.1;

16:0 – 6.0; 16:1 – 0.5; 18:0 – 2.0; 18:1 – 11.8;

18:2 – 20.2; 18:3 – 59.3; others (3) – 0.1 [1]

Seed and Pericarp

Mass of 1,000, g: 0.59 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 32.0 [2]

n40D : 1.4758 [2]

Iodine value (Wijs), % J2: 202.0; 208.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.8; 18:0 – 2.8; 18:1 – 8.9; 18:2 – 17.0; 18:3 –

65.0; others (4) – 0.6 [2]

IR [2]

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia columbariae

Family: Lamiaceae

Seed and Pericarp

Ash, %: 5.6 [1]

Mass of 1,000, g: 0.7 [1]

Oil, % dry wt: 34.4 [1]

Seed

Oil, % dry wt: 34.0 (petroleum ether, 30–60� C) [2]n40D : 1.4748 [2]

Iodine value (Wijs), % J2: 198.0 [2]

Saponification value, mg KOH: 188.0 [2]

FAs

Composition (20% Apiezon L), %: Saturated� 5.0;

18:1 � 18.0; 18:2 � 16.0; 18:3 � 56.0 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, T.A. McGuire, J. Mallan, M.O. Bagby, I.A. Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

Salvia cryptanthaMontbr. and Aucher exBentham

Family: Lamiaceae

Essential oil

Composition (GLC, 10% Carbowax): a-Pinene –

5.8; camphene – 2.8; myrcene – 3.2; a-phellandrene – 2.9; limonene – 1.4; 1,8-cineole

– 10.4; g- terpinene – tr; terpinolene – 0.8; a-thujone – 0.6; b- thujone – 0.3; camphor – 17.5;

linalool – 4.0; linalyl acetate – 5.1; isobornyl

acetate – 2.1; bornyl acetate – 3.1; borneol –

24.8; isoborneol – 3.4; terpinen-4-ol – tr; b-caryophyllene – 4.2; a-terpinyl acetate – 3.3;

geranyl acetate – 0.5; geraniol – tr (from

Gumushane, Turkey) [1]

Seed

Oil (hexane), %: 4.7 (from Turkey) [2]

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.2;

15:0 – 0.2; 16:0 – 11.8; 16:1(7Z) – 0.2; 16:1(9Z)

– 0.1; 17:0 – 0.2; 18:0 – 2.8; 18:1(9Z) – 14.0;

18:1(11Z) – 1.0; 18:2 – 61.1; 18:3 – 1.5; 20:0 –

0.9; 20:1 – 0.6; 22:0 – 0.5 [2]

Seed and Pericarp

Mass of 1,000, g: 6.1 [3]

Oil (petroleum ether, 30–60� C), % dry wt: 11.0 [3]

n40D : 1.4649 [3]

Iodine value, % J2: 135.0; 142.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.4; 18:0 – 2.3; 18:1 – 20.0; 18:2 – 71.0; 18:3 –

0.7; others (6) – 0.7 [3]

IR [3]

References

1. A. Bayrak, A. Akgul, Phytochemistry 26(3), 846 (1987)

Page 92: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 480 Salvia deserta Schang.

2. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia deserta Schang.

Synonyms

S. nemorosa auct.p. p.

Family: Lamiaceae

Inflorescence

Essential oil, %: 0.002 [1]

Leaf

Essential oil, %: 0.02 [1]

Seed

Oil (hexane), %: 23.0 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.8;

16:0 – 7.5; 16:1 – 1.6; 18:0 – 2.8; 18:1 – 13.6;

18:2 – 24.9; 18:3 – 47.4; others (5) – 1.4 [2]

Activity: Essential oil has antimycotic activity [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

73 [in Russian]

2. A.V. Patudin, I.U Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

Salvia dracocephaloides Boiss.

Family: Lamiaceae

Seed

Oil (hexane), %: 16.4

FAs

Composition (GLC, 20% DEGS), %: 16:0 – 8.2;

18:0 – 2.4; 18:1 – 25.0; 18:2 – 61.0; 18:3 – 1.8;

others (4) – 1.4

References

1. A.V. Patudin, I.U Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

Salvia dumetorum Andrz.

Family: Lamiaceae

Aerial Part and Inflorescences

Essential oil, %: 0.01 [1]

Seed

Oil, %: 32.0 [2]

d: 0.9303 [2]

n25: 1.4803 [2]

Saponification value, mg KOH: 192.98 [2]

Iodine value, % J2: 173.5 – 174.4 [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, p. 74 [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

Salvia euphratica Montbr. et Anch.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 34.0

Oil (petroleum ether, 30–60�C), % dry wt: 21.0

n40D : 1.4687

Iodine value (Wijs), % J2: 138.0; 140.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.8; 18:0 – 2.0; 18:1 – 21.0; 18:2 – 67.0; 18:3 –

1.6; others (5) – 0.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

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Salvia fruticosa Miller. 481 Lamiaceae

Salvia farinacea Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 17.0

n40D : 1.4726

Iodine value, % J2: 184.0; 186.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.6; 18:0 – 2.6; 18:1 – 17.0; 18:2 – 22.0; 18:3 –

51.0; others (1) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia fominii Grossh.

Family: Lamiaceae

Seed

Oil (hexane), %: 31.0 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.4;

16:0 – 6.5; 16:1 – 0.5; 18:0 – 2.4; 18:1 – 19.4;

18:2 – 34.1; 18:3 – 36.7; others (1) – tr [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

74 [in Russian]

2. A. V. Patudin, I. U. Yusupova, D. A. Voloshina, Rast. resursy(in Russian), 12, 272 (1976)

Salvia forskahlei L.

Family: Lamiaceae

Seed

Oil (hexane), %: 2.7

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.3;

15:0 – 0.2; 16:0 – 13.7; 16:1(7Z) – 0.3; 16:1(9Z)

– 0.2; 17:0 – 0.2; 18:0 – 3.3; 18:1(9Z) – 9.6;

18:1(11Z) – 1.5; 18:2 – 60.8; 18:3 – 2.6; 20:0 –

0.6; 20:1 – 0.3; 22:0 – 0.3

References

1. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia fruticosa

Family: Lamiaceae

Essential oil

Composition (GLC, 10% Carbowax): a-Pinene –

3.2; camphene – 0.7; b-pinene – 4.3; myrcene –

3.1; a-terpinene – 0.4; limonene – tr; 1.8-cineole

– 55.5; g- terpinene – 1.7; terpinolene – 0.9; a-thujone – 2.0; b- thujone – 2.0; camphor – 8.4;

linalool – 1.6; linalyl acetate – 0.5; bornyl ace-

tate – 1.7; borneol – 4.6; terpinen-4-ol – 1.1; b-caryophyllene – 5.2; a-humulene – 0.3; a-terpinyl acetate – 1.1 (Mugla, Turkey).

References

1. A. Bayrak, A. Akgul, Phytochemistry 26, 846 (1987)

Salvia fruticosa Miller.

Synonyms

Salvia fruticosa Boiss., Salvia triloba L. fil.

Family: Lamiaceae

Essential oil

Composition (GLC, 10% Carbowax): a-Pinene –

3.2; camphene – 0.7; b-pinene – 4.3; myrcene –

3.1; a-terpinene – 0.4; limonene – tr; 1,8-cineole

– 55.5; g-terpinene – 1.7; terpinolene – 0.9; a-thujone – 2.0; b-thujone – 2.0; camphor – 8.4;

linalool – 1.6; linalyl acetate – 0.5; bornyl ace-

tate – 1.7; borneol – 4.6; terpinen-4-ol – 1.1; b-caryophyllene – 5.2; a-humulene – 0.3; a-terpinyl acetate – 1.1 (from Mugla, Turkey) [1]

Page 94: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 482 Salvia garedji Troitzk.

Seed

Oil (hexane), %: 11.0 [2]

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.2;

15:0 – tr; 16:0 – 12.1; 16:1(9Z) – 0.2; 17:0 – 0.1;

18:0 – 5.1; 18:1(9Z) – 31.0; 18:1(11Z) – 1.1; 18:2

– 47.6; 18:3 – 0.6; 20:0 – 0.2; 20:1 – 0.7; 22:0 –

0.2 [2]

Seed and Pericarp

Mass of 1,000, g: 7.3 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 23.0 [3]

n40D : 1.4667 [3]

Iodine value, % J2: 124.0; 126.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.2; 18:0 – 5.2; 18:1 – 25.0; 18:2 – 59.0; 18:3 –

0.8; others (4)– 0.6 [3]

IR [3]

Activity: Antioxidant activity [4].

References

1. A. Bayrak, A. Akgul, Phytochemistry 26(3), 846 (1987)

2. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

4. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

74 [in Russian]

Salvia garedji Troitzk.

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.17–0.29

Components: 1,8-Cineole, octan-3-ol, menthone,

isomenthone, camphor, b-bourbonene, linalool,linalylacetate, terpinen-4-ol, humulene,

isobornylpropionate, terpinylacetate, borneol,

a-terpineol, isobornylbutyrate, isobornyl-

valeriate, a-curcumene, sitronellol, geraniol

Use: Essential oil may be used in perfume.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

74 [in Russian]

Salvia glabricaulis Pobed.

Family: Lamiaceae

Seed

Oil, %: 21.6

FAs: 18:1(5,6); 20:1(11)

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

74 [in Russian]

Salvia glutinosa L.

Family: Lamiaceae

Triterpenoids: b-Amyrin, 11a-hydroxyamyrin and

others [1]

Flower

Hydrocarbons: C29 [1]

Triterpenoids: a-Amyrin, ursolic acid [1]

Fruit

Oil, %: 27.52 [1]

Sterols: Cholesterol, campesterol, stigmasterol, sitos-

terol, avenasterol [1]

Herb

Essential oil, %: 0.06–0.08 [2]

Composition (GLC, 15% Carbowax 20): a-Pinene –0.2; cineole – 1.7; thujone – 0.4; linalool – 4.2;

borneol – 0.3; linalyl acetate –2.4; bornyl acetate

– 11.7; and others [2]

Inflorescence

Essential oilComponents: Thujone, borneol, linalool,

caryophyllene [1]

Seed

Oil (hexane), %: 40.8 [3]

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Salvia hians Royle ex Benth. 483 Lamiaceae

FAs

Composition (GLC, 20% PEGS), %: 14:0 – tr, 16:0

– 5.1, 16:1 – 0.4, 18:0 – 2.9, 18:1 – 15.2, 18:2 –

42.0, 18:3 – 34.0 [3]

Seed and Pericarp

Mass of 1,000, g: 4.0 [4]

Oil (petroleum ether, 30–60�C), % dry wt: 39.0 [4]

n40D : 1.4730 [4]

Iodine value, % J2: 176.0; 178.0 (cald) [4]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.2; 18:0 – 2.6; 18:1 – 15.0; 18:2 – 39.0; 18:3 –

37.0; others (5) – 1.1 [4]

IR [4]

Use: Essential oil may be used in perfume [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

75 [in Russian]

2. R. Ivanic, K. Savin, Planta Med. 30, 26 (1976)

3. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

4. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia grandiflora Ettling.

Family: Lamiaceae

Aerial Part

Triterpenoids

Components: Oleanolic, ursolic, maslinic (2a, 3b-dihydroxyolean-12-en-28-oic), epimaslinic (2a,3a-dihydroxyolean-12-en-28-oic) acids [1]

Seed and Pericarp

Mass of 1,000, g: 6.0 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 16.0 [2]

n40D : 1.4677 [2]

Iodine value, % J2: 124.0; 126.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

11.0; 18:0 – 2.6; 18:1 – 26.0; 18:2 – 58.0; 18:3 –

0.7; others (6) – 1.2 [2]

IR [2]

Seed

Oil, %: 13.0 [3]

Iodine value, % J2:106.4 [3]

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

3. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349

Salvia halophila Hedge.

Family: Lamiaceae

Seed

Oil (hexane), %: 20.8

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.1;

15:0 – tr; 16:0 – 7.4; 16:1(7Z) – 0.1; 16:1(9Z) –0.1; 17:0 – 0.1; 18:0 – 4.2; 18:1(9Z) – 23.5;

18:1(11Z) – 1.2; 18:2 – 31.4; 18:3 – 30.7; 20:0

– 0.1; 20:1 – 0.6; 22:0 – tr

References

1. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia hians Royle ex Benth.

Family: Lamiaceae

Seed

Oil (hexane), %: 24.0 [1]; 27.2 [2]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – 0.1;

16:0 – 7.9; 16:1 – 0.4; 18:0 – 2.4; 18:1 – 16.5;

18:2 – 39.3; 18:3 – 34.3; others (2) – tr [2]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

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Lamiaceae 484 Salvia hispanica L.

Salvia hispanica L.

Family: Lamiaceae

Seed

Oil, %: 28.0–36.0 [1]; 24.4 [2]

d1515: 0.9340 [1]

d25: 0.9358 [1]

n25: 1.4838–1.4860 [1]

Saponification value, mg KOH/g: 192.9–194.8 [1]

Iodine value, % J2: 194.8–196.0 [1]; 232.9 (cald) [3]

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 7.6; 16:1 –

0.4; 18:0 – 1.4; 18:1 – 6.4; 18:2 – 19.7; 18:3 –

64.5; others (1) – tr (20% PEGS) [2],

16:0 – 6.1; 18:0 – 1.4; 18:1 – 5.3; 18:2 – 20.3; 18:3 –

66.8 (10% PEGA) [3]

Seed and Pericarp

Mass of 1,000, g: 0.4 [4]

Oil (petroleum ether, 30–60�C), % dry wt: 29.0 [4]

n40D : 1.4753 [4]

Iodine value, % J2: 196.0; 201.0 (cald) [4]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.1; 18:0 – 3.3; 18:1 – 6.8; 18:2 – 24.0; 18:3 –

59.0; others (3) – 0.2 [4]

IR [4]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

3. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7, 32

(1971) [in Russian]

4. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967) [in Russian]

Salvia horminum (L.) Batt.

Family: Lamiaceae

Aerial part

Sterols: Sitosterol [1]

Triterpenoic acids: Oleanolic, ursolic and micrometric

acids [1, 2]

Herbage

Triterpenols: Lupeol, lup-(20)29-ene-2a, 3b-diol andolean-(13)18-ene-2b,3b-diol [3]IR, MS, NMR [3]

Essential oil

Components: Linalool, camphor, cineole [4]

Triterpenoids: Micrometric, ursolic, oleanolic acids,

lupeol and others [4]

Seed

Oil (hexane), %: 24.7 [4, 5]; 45.2 [6]

Iodine value, % J2:140.5 [6]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – 0.3;

16:0 – 9.6; 16:1 – 0.4; 18:0 – 2.8; 18:1 – 18.9;

18:2 – 29.4; 18:3 – 38.6; others-(6) – 1.1 [5]

Seed and Pericarp

Mass of 1,000, g: 2.7 [7]

Oil (petroleum ether, 30–60�C), % dry wt: 24.0 [7]

n40D : 1.4725 [7]

Iodine value, % J2: 173.0; 172.0 (cald) [7]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.0; 18:0 – 2.6; 18:1 – 19.0; 18:2 – 27.0; 18:3 –

41.0; others (6) – 1.1 [7]

IR [3]

References

1. A. Ulubelen, C.H. Brieskorn, Phytochemistry 14, 1450 (1975)

2. A. Ulubelen, C.H. Brieskorn, Phytochemistry 14, 820 (1975)

3. A. Ulubelen, C.H. Brieskorn, N. Ozdemir, Phytochemistry 16,

790 (1977)

4. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

75 [in Russian]

5. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

6. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

7. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia hydrangea DC ex Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.1

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Salvia karabachensis Pobed. 485 Lamiaceae

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

n40D : 1.4672

Iodine value, % J2: 122.0; 123.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

10.0; 18:0 – 2.4; 18:1 – 32.0; 18:2 – 51.0; 18:3 –

0.9; others (6) – 0.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia hypargeia Fisch. and Mey.

Family: Lamiaceae

Seed

Oil (hexane), %: 2.0

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.1;

15:0 – tr; 16:0 – 9.0; 16:1(7Z) – tr; 16:1(9Z) –

0.1; 17:0 – 0.1; 18:0 – 3.7; 18:1(9Z) – 20.9;

18:1(11Z) – 0.9; 18:2 – 43.7; 18:3 – 19.3; 20:0

– 0.1; 20:1 – 0.5; 22:0 – 0.1

References

1. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia japonica Tnub.

Family: Lamiaceae

Seed

Oil, % dry wt: 37.3

Iodine value, % J2: 172.43

Composition (GLC), %: 14:0 � 0.80; 16:0 � 7.20;

16:1 � 0.65; 18:0 � 3.74; 18:1 � 19.15; 18:2 �29.57; 18:3 � 39.60

References

1. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

Salvia judiaca Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60� C), % dry wt: 20.0

n40D : 1.4754

Iodine value, % J2: 192.0; 195.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.0; 18:0 – 2.8; 18:1 – 7.7; 18:2 – 30.3; 18:3 –

52.0; others (3) – 1.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia jurisicii Kosanin.

Family: Lamiaceae

Seed

Oil (hexane), %: 27.8

FAs

Composition (GLC, 20% DEGS), %: 14:0 – tr; 16:0

– 5.8; 16:1 – 0.4; 18:0 – 2.0; 18:1 – 8.1; 18:2 –

27.0; 18:3 – 56.4; others (2) – 0.3

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia karabachensis Pobed.

Family: Lamiaceae

Seed

Oil (hexane), %: 22.4

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.9;

16:0 – 8.5; 16:1 – 2.1; 18:0 – 3.7; 18:1 – 14.0;

18:2 – 26.7; 18:3 – 42.9; others (5) – 1.2

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Lamiaceae 486 Salvia kopetdaghensis Kudr.

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia kopetdaghensis Kudr.

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.15

Components: Cineole – 63.0%, a-pinene, b-pinene,limonene, p-cimole, terpinolene, linalool

Use: Essential oil may be used in perfume and

cosmetics.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

75 [in Russian]

Salvia Kuznetzovii Sosn.

Family: Lamiaceae

Seed

Oil (hexane), %: 20.1 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.9;

16:0 – 8.4; 16:1 – 1.5; 18:0 – 3.5; 18:1 – 13.6;

18:2 – 23.7; 18:3 – 45.3; others (6) – 3.1 [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

75 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia lanata

Family: Lamiaceae

Aerial Parts and Roots

Petrol extracts (60–80�)

Horminone, g (from 1 kg air dried plant material):

0.4 [1]

[a]D: 130�

Desacylhorminone, g (from 1 kg air dried plant mate-

rial): 0.38 g [1]

[a]D: 130� (CHCl3)7a-Acetoxy-royleanone, g (from 1kg air dried plant

material): 0.42 [1]

[a]D25: –20� (CHCl3)

3-Epi-ursolic acid, g (from 1 kg air dried plant mate-

rial): 0.35 [2]

[a]D: +98� (CHCl3)

References

1. K.S. Mukherjii, P.K. Ghosh, S. Badruddoza, Phytochemistry

20, 1441 (1981)

2. K.S. Mukherjii, M.K. Bhattacharya, P.K. Ghosh, Phytochem-

istry 21, 2416 (1982)

Salvia lanigera Poir.

Family: Lamiaceae

Leaf

Petrol extract (from 1 kg air-dried plant material), g:

20.0 [1]

Methanol extract (after petrol extract), g: 150 [1]

Triterpenoic acids: Oleanolic and ursolic acids [1]

Seed and Pericarp

Mass of 1,000, g: 1.0 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 23.0 [2]

n40D : 1.4735 [2]

Iodine value, % J2: 182.0; 184.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.7; 18:0 – 2.0; 18:1 – 16.0; 18:2 – 21.0; 18:3 –

51.0; others (6) – 1.4 [2]

IR [2]

References

1. H.M.G. Al-Hazimi, G.A. Miana, M.S.N. Deep, Phytochemis-

try 26, 1091 (1987)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Page 99: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia lavandulifolia Vahl ssp. oxyodon 487 Lamiaceae

Salvia lavandulaefolia Vahl.

Synonyms

S. hispanica

Family: Lamiaceae

Aerial Part

Triterpenoic acids: Oleanolic and ursolic acids (1:1)

[1]

Seed and Pericarp

Mass of 1,000, g: 3.0 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 21.0 [2]

n40D : 1.4685 [2]

Iodine value (Wijs), % J2: 137.0; 141.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.9; 18:0 – 2.2; 18:1 – 18.0; 18:2 – 69.0; 18:3 –

2.1; others (5) – 0.9 [2]

IR [2]

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia lavandulifolia Vahl ssp. oxyodon

Family: Lamiaceae

Flowers

Essential oil (steam distillation from fresh flowers), %

v/w: 1.5

Components (throughout its complete vegetative

variations, GC on Carbowax 20 M, GC/MS),

%: a-Pinene – 4.1; camphene – 6.7; b-pinene +D3-carene – 4.3; myrcene – 2.8; limonene – 4.0;

1,8-cineole – 23.4; p-cymene – 1.0; unidentified

1 – tr; unidentified 2 – tr; terpinolene – tr; a-thujone+ b-thujone – 1.0; camphor – 38.9;

terpinen-4-ol – 1.4; unidentified 3 – tr;

unidentified 4 – tr; unidentified 5 – tr; borneol –

8.5; a-terpineol – 0.8; thujyl alcohol isomer –

1.3; a-ionone – 1.0 (March 23);

a-Pinene – 7.4; camphene – 4.9; b-pinene + D3-

carene – 8.2; myrcene – 4.4; limonene – 3.9;

1,8-cineole – 31.6; p-cymene – 1.2; unidentified

1 – tr; unidentified 2 – tr; terpinolene – tr; a-thujone + b-thujone – 1.3; camphor – 16.0;

terpinen-4-ol – 2.7; unidentified 3 – tr;

unidentified 4 – tr; unidentified 5 – tr; borneol –

12.6; a-terpineol – 1.0; thujyl alcohol isomer –

2.2; a-ionone – 1.2 (April 24);

a-Pinene – 8.8; camphene – 7.6; b-pinene + D3-

carene – 7.6; myrcene – 5.6; limonene – 4.2;

1;8-cineole – 14.0; p-cymene – 1.8; unidentified

1 – tr; unidentified 2 – tr; terpinolene – 0.6; a-thujone + b-thujone – 1.4; camphor – 25.9;

terpinen-4-ol – 2.8; unidentified 3 – tr;

unidentified 4-tr; unidentified 5 – tr; borneol –

16.2; a-terpineol – tr; thujyl alcohol isomer – tr;

a-ionone – 1.4 (May 23);

a-Pinene – 9.0; camphene – 6.8; b-pinene + D3-

carene – 4.8; myrcene – 6.1; limonene – 5.5;

1;8-cineole – 10.8; p-cymene – 1.4; unidentified

1 – tr; unidentified 2 – tr; terpinolene – tr; a-thujone + b thujone – 0.9; camphor – 24.9;

terpinen-4-ol – 1.5; unidentified 3 – tr;

unidentified 4 – tr; unidentified 5 – tr; borneol –

23.8; a-terpineol – 1.5; thujyl alcohol isomer –

1.5; a-ionone – 0.9 (June 26);

a-Pinene – 8.2; camphene – 7.7; b-pinene + D3-

carene – 7.7; myrcene – 7.0; limonene – 5.2; 1;8-

cineole – 23.8; p-cymene – 1.0; unidentified 1 – tr;

unidentified 2 – tr; terpinolene – tr; a-thujone + bthujone – 1.1; camphor – 35.3; terpinen-4-ol – tr;

unidentified 3 – tr; unidentified 4 – tr; unidentified

5 – tr; borneol – tr; a-terpineol – 1.5; thujyl alcoholisomer – tr; a-ionone – tr (July 29);

a-Pinene – 7.8–10.6; camphene – 8.8–11.9; b-pinene + D3-carene – 5.7–7.4; myrcene – 3.8–

6.2; limonene – 3.6–4.9; 1,8-cineole – 14.0–

20.3; p-cymene – 0.6–1.7; unidentified 1 – tr;

unidentified 2 – tr; terpinolene – tr – 0.7; a-thujone+ b-thujone – 0.9–1.5; camphor – 28.7–

35.4; terpinen 4-ol – 0.8–1.7; unidentified 3 – tr;

unidentified 4 – tr; unidentified 5 – tr – 0.8;

borneol – 8.0–10.6; a-terpineol – tr – 1.3; thujyl

alcohol isomer – tr – 1.8; a-ionone – tr – 1.2 (4

September-11 January);

Page 100: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 488 Salvia leucantha

a-Pinene – 9.3; camphene – 9.4; b-pinene + D3-

carene – 8.9; myrcene – 4.2; limonene – 3.2;

1;8-cineole – 20.7; p-cymene – 0.6; unidentified

1 – tr; unidentified 2 – tr; terpinolene – tr; a-thujone + b-thujone – 0.7; camphor – 29.1;

terpinen-4-ol – 1.4; unidentified 3 – tr;

unidentified 4 – tr; unidentified 5 – tr; borneol –

9.3; a-terpineol – 0.7; thujyl alcohol isomer –

1.2; a-ionone – 0.9 (February 12)

Activity: Spasmolytic activity of essential oil, ED50

according to mount of harvest, mg/mL: 33.2 � 3.4

(March), 41.8 � 1.1 (April), 14.0 � 2.5 (May), 36.5

� 4.0 (June), 62.9 � 4.4 (July), 27.5 � 7.4 – 34.0 �3.5 (September–January), 54.2 � 3.0 (February)

References

1. M.E. Crespo, J. Jimenez, C. Navarro, A. Zarzuelo, Planta

Med. 5, 367 (1986)

Salvia leucantha

Family: Lamiaceae

3-Epierythrodiol (3a,28-(OH)2; D12)

References

1. M.C. Das, S.B. Mahato, Phytochemistry 22(5), 1071 (1983)

Salvia lilacinocoerulea Nevski

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.12

Components, %,: Cyneol – 63.0; a-pinene, b-pinene, limonene, p-cumole, terpinolene,

linalool

Use: Essential oil may be used in perfume and

cosmetics.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p.75 [in Russian]

Salvia limbata C.A. Mey.

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.08 [1]

Triterpenoic acids: Ursolic acid [1]

Seed

Oil (hexane), %: 29.7 [2]

FAs

Composition (GLC, 20% PEGS), %: 14:0 – tr; 16:0

– 6.0; 16:1 – 0.7; 18:0 – 2.6; 18:1 – 16.3; 18:2 –

31.7; 18:3 – 42.7

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

75 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia longipedicellata

Family: Lamiaceae

Essential oil

Composition, %: Nonanal – 0.3; bornyl acetate –

0.6; a-copaene – 8.1; b-elemene – 4.4; b-caryophyllene – 37.0; aristolene – 0.8; a-humulene – 9.7; germacrene-D – 13.4;

bicyclogermacrene – 3.4; g-cadinene – 3.2;

endo-1-bourbonanol – 2.2; caryophyllene oxide

– 1.2; a-cadinol – 0.3; hexahydrofarneysl ace-

tone – 0.6; sclareoloxide – 2.5; cembrene – 9.2;

total – 95.8

References

1. H. Ozer, H. Kilic, O. Baris, A. Adiguzel, M. Gulluce, Chem.

Nat. Comp. 43, 230 (2007)

Salvia longispicata Mart. et Gal.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.2

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Salvia malaica Hornm. 489 Lamiaceae

Oil (petroleum ether, 30–60�C), % dry wt: 19.0

n40D : 1.4745

Iodine value (Wijs), % J2: 188.0; 189.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.1; 18:0 – 4.9; 18:1 – 8.7; 18:2 – 26.0; 18:3 –

52.0; others (7) – 1.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia lyrata L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 23.0

n40D : 1.4589

Iodine value (Wijs), % J2: 133.0; 138.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.6; 18:0 – 3.5; 18:1 – 17.0; 18:2 – 70.0; 18:3 –

1.0; others (4) – 0.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia macilenta Boiss.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % (w/w) dry wt: 0.2

Composition (GC/MS, HP 5MS), %: a-Pinene –

60.0; camphene – 1.2; b-pinene – 1.3; myrcene

– 0.3; a-terpinene – 0.3; p-cymene – 0.6; limo-

nene – 1.6; g-terpinene – 1.0; terpinolene – 0.2;

linalool – 0.3; camphor – 0.6; borneol – 1.3; 4-

terpineol – 0.5; a-terpineol – 0.3; trans-anethol –0.1; thymol – 5.2; bornyl acetate – 2.2; a-copaene– 0.6; b-caryophyllene – 4.1; 9-epi-(E)-

caryophyllene – 0.2; allo-aromadendrene – 0.6;

z-D-dihydro-apofarnesene – 0.7; b-bisabolene –

1.2; g-cadinene – 0.2; d-cadinene – 1.1; b –

eudesmol – 1.6; a-eudesmol – 0.7; total – 92.4

Monoterpene hydrocarbons – 66.5

Oxygenated monoterpenes – 10.5

Sesquiterpene hydrocarbons – 9.0

Oxygenated sesquiterpenes – 13.4

References

1. A. Sonboli, A.R. Farhari, F. Sefidkon, Chem. Nat. Comp. 41,

136 (2005)

Salvia macrosiphon Boiss.

Family: Lamiaceae

Essential oil, %: 0.2

Components: (–) Hexanol, (–) linalool,

isovalerianic acid

Inflorescence

Essential oil, %: 0.059

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

76 [in Russian]

Salvia malaica Hornm.

Family: Lamiaceae

Seed

Oil, %: 24.0

References

1. N.I. Sharapov,Oil Plants and the Process of oil formation (ASUSSR Press, Moskwa-Leningrad, 1959) p. 349 [in Russian]

Page 102: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 490 Salvia menthaefolia Tenore

Salvia menthaefolia Tenore

Family: Lamiaceae

Aerial Part

Triterpenoid acids: Oleanoic, ursolic and micromeric

(3b-hydroxy-ursa-12,20(30)-dien-28-oic) acids

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

Salvia mexicana L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.4

Oil (petroleum ether, 30–60�C), % dry wt: 14.0

n40D : 1.4740

Iodine value (Wijs), % J2: 187.0; 192.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.9; 18:0 – 3.9; 18:1 – 11.0; 18:2 – 26.0; 18:3 –

52.0; others (6) – 0.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia modesta Boiss.

Synonyms

S. brachyantha (Bordz.) Pobed.

Family: Lamiaceae

Seed

Oil, %: 22.0

FAs: 16:0; 16:1; 18:0; 18:1; 18:2; 18:3

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

76 [in Russian]

Salvia moldavica Klok.

Family: Lamiaceae

Seed

Oil (hexane), %: 26.4

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 1.3;

16:0 – 9.5; 16:1 – 2.5; 18:0 – 3.5; 18:1 – 11.2;

18:2 – 30.0; 18:3 – 36.6; others (6) – 5.1

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia montbretii Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 10.0

Oil (petroleum ether, 30–60�C), % dry wt: 21.0

n40D : 1.4703

Iodine value (Wijs), % J2: 153.0; 159.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.5; 18:0 – 2.7; 18:1 – 14.0; 18:2 – 5.0; 18:3 –

20.0; others (6) – 0.8

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia moorcraftiana Wall. Ex Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 3.3

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Salvia nemorosa L. 491 Lamiaceae

Oil (petroleum ether, 30–60�C), % dry wt: 27.0

n40D : 1.4705

Iodine value (Wijs), % J2: 154.0; 159.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.6; 18:0 – 3.4; 18:1 – 27.0; 18:2 – 23.0; 18:3 –

36.0; others (3) – 0.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia multicaulis Vahl.

Family: Lamiaceae

Seed

Oil (hexane), %: 18.0

FAs

Composition (GLC, 20% DEGS), %: 16:0 – 9.1;

18:0 – 1.5; 18:1 – 19.0; 18:2 – 67.0; 18:3 – 1.3;

others (6) – 0.5

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Salvia nemorosa L.

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.14 [1]; 0.08 – 0.14 [2]

Components: a-Thujene, a-pinene, b-pinene,myrcene, a-terpinene, g-terpinene, p-cymole,

limonene, cis-ocimene, trans-ocimene,

terpinolene, borneol, camphene, caryophyllene

[1]

Composition (GLC, 15% Carbowax 20): a-Pinene –3.4; b-pinene – 25.6; cineole – 0.5; thujone – 0.7;linalool – 1.8; borneol – 0.5; linalyl acetate – 0.5;

bornyl acetate – 26.6; and others [2]

Sterols, % dry wt: 0.08 [3]

Terpenoids

Phytol, % dry wt: 0.05 [3]

Flower

Essential oil, %:0.20–0.34 [2]

Fruit

Oil, %: 17.0 [1]

FAs: 14:0, 16:0, 16:1, 18:0, 18:1, 18:2, 18:3 [1]

Inflorescence

Essential oil, %: 0.18 [1]

Components: Thujene, pinene, myrcene, terpinene,

p-cymole, limonene, ocimene-1, ocimene-2,

terpinolene, borneol, caryophyllene, camphene

[1]

Leaf

Essential oil

Components, %: Caryophyllene – 38.8; sabinene –

12.3; b-pinene – 8.4; germacrene D – 6.2; a-pinene – 5.4; caryophyllene oxide – 4.3;

bicyclogermacrene – 3.1; cis-ocimene – 2.7;

trans-ocimene – 2.2; a-humulene – 1.6;

terpinen-4-ol – 0.5 [1, 4]

Seed

Oil (hexane), %: 19.0–29.8 [1, 5–7]

Iodine value, % J2: 141.0–166.1 [6, 7]

Saponification value, mg KOH: 193.0 [6]

FAs

Composition (GLC), %: 14:0 – 0.4; 16:0 – 6.6; 16:1

– 0.6; 18:0 – 3.4; 18:1 – 13.0; 18:2 – 34.2; 18:3 –

40.5; others (6) – 1.3 (20% PEGS) [5]; 14:0 –

0.16; 16:0 – 8.04; 16:1 – 0.99; 18:0 – 2.73; 18:1 –

21.48; 18:2 – 31.26; 18:3 – 35.33 [7]

Seed and Pericarp

Mass of 1,000, g: 1.1 [8]

Oil (petroleum ether, 30–60˚C), % dry wt: 27.0 [8]

n40D : 1.4750 [8]

Iodine value (Wijs), % J2: 193.0, 199.0 (cald) [6]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.8; 18:0 – 1.9; 18:1 – 9.2; 18:2 – 30.0; 18:3 –

53.0; others (5)– 0.8 [8]

IR [8]

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Lamiaceae 492 Salvia nilotica Jacq.

Use: Essential oil may be used in perfume and cos-

metic [1]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991),

6, p. 77 [in Russian]

2. R. Ivanic, K. Savin, Planta Med. 30, 26 (1976)

3. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

4. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, LS.

Gill, Phytochemistry 11, 2636 (1972)

5. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. resursy

12, 272 (1976) [in Russian]

6. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 349 [in

Russian]

7. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

8. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia nilotica Jacq.

Family: Lamiaceae

Seed

Oil

FAs

Composition (Ag+-TLC, GLC, 5% LAC-2-R 446),

%: 12:0 – tr; 13:0 – tr; 14:0 – tr; 15:0 – tr; 16:0 –

8.2; 16:1 – 0.1; 17:0 – 0.1; iso 17:0 – 0.1; 17:1

(8) – 0.1; 17:2 (8,11) – 0.1; 17:3 (8,11,14) – 0.4;

18:0 – 4.5; 18:1 – 10.1; 18:2 – 35.8; 18:3 – 28.7;

20:0 – 1.0; unidentified – 0.3; a-hydroxy-18:1 –

0.6; a-hydroxy-18:2 – 4.3; a-hydroxy – 18:3 – 5.6a-Hydroxy-acids (GLC, MS, NMR, ORD), %: a-

Hydroxy-18:1 – 0.6; a-hydroxy-18:2 – 4.2; a-hydroxy-18:3 – 5.4

a-Hydroxylinolenate

½a�25589: –3.25�; [a]550: �3.75�; [a]500: �6.07�;[a]450: �7.75�; [a]400: �12.9� (c. 0.0016 g/mL

in methanol)

a-Hydroxylinolenate ½a�25589: � 5.89�; [a]550: �9.23�; [a]500: � 12.9�; [a]450: � 17.0�; [a]400:�24.3� (c. 0.0016 g/mL in chloroform)

a-Hydroxylinolenate ½a�25589: � 6.9�; [a]550: � 8.4�;[a]500: � 11.85�; [a]450: � 15.6�; [a]400: �23.0�

(c. 0.0016 g/mL in chloroform)

References

1. M.B. Bohannon, R. Kleiman, Lipids 10, 703 (1975)

Salvia nutans L.

Family: Lamiaceae

Essential oil: Borneol, caryophyllene [1]

Aerial Part

Sterols, % dry wt: 0.06 [2]

Terpenoids

Phytol, % dry wt: 0.09 [2]

Inflorescence

Essential oil, %: 0.014 [1]

Seed

Oil (hexane), %: 30.1 [1, 3]

Iodine value, % J2: 226.8 (cald) [4]

FAs

Composition (GLC): 14:0 – tr; 16:0 – 4.8; 16:1 – tr;

18:0 – 1.7; 18:1 – 10.2; 18:2 – 29.3; 18:3 – 54.0;

others (2) – tr (20% PEGS, %) [3]

16:0 – 4.5; 18:0 – 2.0; 18:1 – 9.2; 18:2 – 22.2; 18:3 –

62.1(GLC, 10% PEGA, mol %) [4]

Use: Essential oil may be used in perfume and cos-

metics [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p.77 [in Russian]

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

3. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

4. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Salvia officinalis L.

Family: Lamiaceae

Aerial Part

Essential oil

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Salvia officinalis L. 493 Lamiaceae

Composition (GC/MS), %: Tricyclene – 0.1; a-

pinene – 2.7; camphene – 3.4, sabinene - tr; b-pinene – 8.0; myrcene – 0.5; a-terpinene – 0.2;

(E)-ocimene – 1.3; g-terpinene – 0.3;

terpineolene – 0.1; 1,8-cineole – 16.8; trans-sabinene hydrate – 0.3; linalool – tr; a-thujone– 12.8; b-thujone – 1.1; a-campholenal – 1.1;

сamphor – 7.1; borneol – 8.4; 4-terpineol – 0.4;

a-terpineol – 0.2; myrtenol – 0.1; isobornyl ace-

tate – 0.2; b-caryophyllene – 10.5; (E)-a-bergamoten – 0.1; a-humulene – 8.2; g-gurjunene– 0.1; g-muurolene – tr; germacrene-D – tr; g-elemene – 0.1; g-cadinene – tr; d-cadinene – tr;

caryophyllene oxide – 0.5; globulol – 10.4;

citronellyl propionate – 0.6; b-eudesmol – tr;

manool – 2.6; total – 98.2 (vegetative) [1]

Tricyclene – 0.2; a-pinene – 3.1; camphene – 2.5;

sabinene – tr; b-pinene – 12.3; myrcene – 0.6; a-terpinene – 0.1; p-cymene – tr; (E)-ocimene –

1.0; g-terpinene – 0.2; terpineolene – tr; 1,8-

cineole – 19.3; trans-sabinene hydrate – 0.3;

linalool – 0.1; a-thujone – 13.2; b-thujone –

2.7; camphor – 2.1; borneol – 6.9; 4-terpineol –

0.4; a-terpineol – 0.1; myrtenol – 0.1; isobornyl

acetate – 0.1; a-cubebene – 0.1; a-ylangene – tr;a-copaene – 0.1; b-bourbonene – tr; b-caryophyllene – 10.6; b-cedrene – 0.1; (E)-a-bergamoten – 0.1; a-humulene – 9.2; g-gurjunene – 0.1; g-muurolene – 0.3;

germacrene-D – 0.1; g-elemene – 0.1; g-cadinene – 0.1; d-cadinene – 0.4; caryophyllene

oxide – 0.3; globulol – 8.1; citronellyl propionate

– 0.4; (Z)-a-santalyl acetate – tr; manool – 2.2;

total – 97.6 (floral budding) [1]

Tricyclene – 0.3; a-pinene – 4.6; camphene – 4.7;

sabinene – tr; b-pinene – 16.4; myrcene – 0.7; a-terpinene – tr; p-cymene – tr; (E)-ocimene – 0.9;

g-terpinene – 0.2; terpineolene – tr; 1,8-cineole –22.3; trans-sabinene hydrate – 0.4; linalool –

0.1; a-thujone – 9.1; b-thujone – 2.1; camphor

– 1.6; borneol – 11.0; 4-terpineol – 0.8; a-terpin-eol – 0.1; myrtenol – tr; isobornyl acetate – 0.2;

a-cubebene – 0.1; a-ylangene – tr; a-copaene –

0.1; b-bourbonene – tr; b-caryophyllene – 4.9; b-cedrene – 0.1; (E)-a-bergamoten – tr; a-humulene – 8.7; g-gurjunene – tr; g-muurolene

– 0.4; germacrene-D – 0.1; g-elemene – 0.1; g-cadinene – 0.2; d-cadinene – 0.4; caryophyllene

oxide – tr; globulol – 6.4; citronellyl propionate

– 0.3; (Z)-a-santalyl acetate – tr; manool-1.4;

total - 98.7 (flowering) [1]

Tricyclene – 0.2; a-pinene – 3.3; camphene – 4.0;

sabinene – tr; b-pinene – 10.5; myrcene – 0.5; p-cymene – tr; (E)-ocimene – 0.6; g-terpinene –

0.1; terpineolene – 0.1; 1;8-cineole – 19.5; trans-sabinene hydrate – tr; linalool – tr; a-thujone –

9.5; b-thujone – 1.1; camphor – 2.8; borneol –

14.6; 4-terpineol – 1.3; a-terpineol – 0.2;

isobornyl acetate – 0.3; a-cubebene – tr; a-copaene – tr; b-bourbonene – tr; b-caryophyllene– 3.6; b-cedrene – tr; (E)-a-bergamoten – 0.1; a-humulene – 12.1; g-muurolene – 0.2;

germacrene-D – tr; g-elemene – 0.1; g-cadinene– 0.1; d-cadinene – 0.2; globulol – 10.0;

citronellyl propionate – 0.1; b-eudesmol – tr;

(Z)-a-santalyl acetate – tr; manool-2.1; total –

97.2 (fruiting set-Immature) [1]

Tricyclene – 0.3; a-pinene – 3.5; camphene – 1.6;

sabinene – 0.3; b-pinene – 7.1; myrcene – tr; a-terpinene – 0.2; p-cymene – 0.2; g-terpinene –

0.5; terpineolene – 0.2; 1;8-cineole – 15.3; linal-

ool – 0.3; a-thujone – 25.1; b-thujone – 5.0;

camphor – 6.3; borneol – 3.5; 4-terpineol – 0.6;

a-terpineol – 0.2; isobornyl acetate – 0.6; a-cubebene – 0.1; a-ylangene – tr; a-copaene –

0.2; b-bourbonene – 0.1; b-caryophyllene –

7.3; b-cedrene – 0.2; (E)-a-bergamoten – 0.6;

a-humulene – 11.6; g-gurjunene – tr; g-muurolene – 0.4; germacrene-D – tr; g-elemene

– 0.5; g-cadinene – 0.2; d-cadinene – 0.5; a-calacorene – 0.1; spathulenol – 0.1;

caryophyllene oxide – 0.5; globulol – 2.6;

citronellyl propionate – 0.6; (Z)-a-santalyl ace-tate – 0.1; manool – 1.8; total – 98.3 (ripen) [1]

Composition (GLC, 10% Carbowax): a-Pinene –

3.5; camphene – 4.7; b–pinene – 1.8; myrcene

– 0.8; a-terpinene – 0.1; limonene – 1.4; 1.8-

cineole – 5.0; g- terpinene – 0.4; p-cymene –

1.1; a-thujone – 20.6; b- thujone – 15.1; camphor

– 22.9; linalool – 1.1; linalyl acetate – 1.0; bornyl

acetate – 2.6; borneol – 7.9; b-caryophyllene –

4.1; a-humulene – 2.1; a- terpinyl acetate – 0.9

(Plant does not occur wild in Turkey. It was

cultivated in Izmir) [2]

a-Pinene – 3.8; cineole – 10.7; thujone – 57.6; linal-ool – 0.3; borneol – 9.5; linalyl acetate – 0.7;

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Lamiaceae 494 Salvia pachystachya Trautv.

bornyl acetate – 1.2; and others (GLC, 15%

Carbowax 20) [3]

Leaves

Alkanes: C12–C35 [4]

Pristane, C19H40 [4]

IR, MS

Sterols, % dry wt: 0.001 [4]

Components, %: b-Sitosterol – 76.0; stigmasterol –

24.0

Triterpenols, % dry wt: a-Amyrin – 0.18; b-amyrin –

0.1 [4]1H NMR

Triterpenoic acids, g %: 2a-Hydroxy-3-oxo-olean-12-en-28-oic – 0.00012; 3a-hydroxyolean-12-en-28-oic (3-epi-oleanolic) – 0.00014; 19a-hydroxyursolic (pomolic) - 0.00024; 2a-3a-dihydroolean-12-en-28-oic - 0.00011; 2a, 3b-dihydroolean-12-en-28-oic (crataegolic) -

0.00032; 2a, 3b-dihydroxyurs-12-en-28-oic(hydroxyursolic) - 0.0001 [4]

IR, MS, 1H NMR

Seed

Mass of 1,000, g: 8.69 [5]

Oil; % dry wt: 14.7 [5]; 25.6 [6]; 42.0 (chloroform) [7];

21.1 [8]

d20: 0.9373 [5]

Acid value, mg KOH: 1.89 [5]

Сolor: 603.0 [5]

Iodine value, % J2: 190.3 [6]

FAs (GLC,), %: 16:0 – 6.6; 18:0 – 2.2; 18:1(9) – 9.6;

18:1(6) – 0.9; 18:2 – 78.4; 18:3 – 1.5 (FFAP)[5]

Composition (GLC), %: 14:0 – 0.2; 16:0 – 7.6; 16:1

– 0.9; 18:0 – 2.2; 18:1 – 18.4; 18:2 – 67.2; 18:3 –

3.5; others – tr. (20% DEGS) [8]

Seed and Pericarp

Mass of 1,000, g: 8.6 [9]

Oil (petroleum ether, 30–60˚C), % dry wt: 25.0 [9]

n40D : 1.4696 [9]

Iodine value (Wijs), % J2: 143.0; 146.0 (cald) [9]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.2; 18:0 – 2.4; 18:1 – 13.0; 18:2 – 76.0; 18:3 –

0.9; others (4) – 0.5 [9]

IR [9]

References

1. M.H. Mirjalili, P. Salehi, A. Sonboli, M. Mohammadi Vala,

Chem. Nat. Comp. 42, 16 (2006)

2. A. Bayrak, A. Akgul, Phytochemistry 26(3), 846 (1987)

3. R. Ivanic, K. Savin, Planta Med. 30, 26 (1976)

4. C.H. Brieskorn, Z. Kapadia, Planta Med. 38, 86 (1980)

5. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Pol. 44(3), 161

(1998)

6. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

7. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

8. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

9. J. M. Hageman, F. R. Earle, I. A. Wolff, A. S. Barclay, Lipids

2, 371 (1967)

Salvia pachystachya Trautv.

Family: Lamiaceae

Essential oil, %: 0.15 [1]

Seed and Pericarp

Mass of 1,000, g: 0.2 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 33.0 [2]

n40D : 1.4750 [2]

Iodine value (Wijs), % J2: 190.0; 196.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.1; 18:0 – 3.2; 18:1 – 11.0; 18:2 – 21.0; 18:3 –

57.0; others (6) – 1.3 [2]

IR [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

77 [in Russian]

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia palaestina Bentham.

Family: Lamiaceae

Leaf

Benzene extract

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Salvia potentillifolia (Boiss. et Heldr.) ex Bentham 495 Lamiaceae

Triterpenoids, mg: Ursolic acid – 30.0; vergatic acid –

10.0; sclareol – 500.0; crataegolic acid – 20.0;

lupane-3b,11a,20-triol – 15.0

Sitosteryl 3b-glucoside, mg: 50.0

Activity: Sclareol showed high antibacterial activity

against standard test strains Staphylococcus aureus, S.epidermis, Escherichia coli, Proteus vulgaris, and

Pseudomonas aeruginosa.

References

1. A. Ulubelen, M.Miski, C. Jonansson, E. Lee, T.J. Mabry, S.A.

Matlin, Phytochemistry 24(6), 1386 (1985)

Salvia phlomoides

Family: Lamiaceae

Aerial Part

Acetone extract

Components, mg (from 585 g air dried plant mate-

rial): Lupeol – 170.0; lup-20(29)-ene-2a,3b-diol– 1,200.0; 3b-acetoxy-lupane-11a,20-diol –

380.0; 3-keto-lupane-11a,20-diol – 290.0;

lupane-3 b,11a,20-triol – 630.0

References

1. M.C. Garcia-Alvarez, G. Savona, B. Rodriguez, Phytochem-

istry 20, 481 (1981)

Salvia pinnata L.

Family: Lamiaceae

Leaf

Benzene extract (in Soxhlet)

Components, mg: Vergatic acid (3b-hydroxy-1-oxo-olean-12-ene-28-oic) – 20.0; oleanoic acid

– 80.0; lupeol – 25.0; lup-20(29)-ene-3b,11a-diol– 45.0; olean–13(18)-ene-2a,3b,11a-triol – 75.0

References

1. A. Ulubelen, G. Topcu, Phytochemistry 23, 133 (1984)

Salvia plebeia R. Br.

Family: Lamiaceae

Seed

Moisture, %: 7.0 [1]

Oil, %: 23.0 [1]; 15.0 [2]

n30D : 1.4854 [1]

Iodine value, % J2: 160.0 [1]; 131.0 [2]

Saponification value, mg KOH: 180.0 [1]; 195.0 [2]

FAs

Composition (GLC, DEGS), %: 14:0 – 3.1; 16:0 –

7.8; 18:0 – 3.3; 18:1 – 13.4; 18:2 – 43.9; 18:3 –

28.5 [1]

Seed and Pericarp

Mass of 1,000, g: 8.6 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 21.0 [3]

n40D : 1.4758 [3]

Iodine value (Wijs), % J2: 159.0; 163.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.0; 18:0 – 2.9; 18:1 – 13.0; 18:2 – 37.0; 18:3 –

33.0; others (5) – 5.2 [3]

IR [3]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

2. S.Q. Hasan, I. Ahmad, M.R.K. Sherwani, A.A. Ansari, S.M.

Osman, Fette, Seifen, Anstrichmittel 82(5), 204 (1980)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia potentillifolia (Boiss. et Heldr.) exBentham

Family: Lamiaceae

Root

Acetone extract

Sitosteryl 3b-glucoside, g (from 400 g plant material):

0.10

Triterpenols, g (from 400 g plant material): Lupeol –

0.15; b-amyrin, lupane-3b-11a, 20-triol

Page 108: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 496 Salvia pratensis L.

Sterols: b-SitosterolTriterpeoic acids: Oleanolic, crataegolic, and vergatic

acids

References

1. A. Ulubelen, E. Tuzlaci, Planta Med. 53, 578 (1987)

Salvia pratensis L.

Family: Lamiaceae

Aerial Part

Sterols, % dry wt: 0.03 [1]

Terpenoids

Phytol, % dry wt: 0.04 [1]

Inflorescence

Essential oil, %: 0.013 [2]

Leaf

Organic acids, %: 1.3–3.4 [2]

Seed

Oil, %: 19.0 [2]

Seed and Pericarp

Mass of 1,000, g: 1.1 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 19.0 [3]

n40D : 1.4748 [3]

Iodine value (Wijs), % J2: 185.0; 194.0 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.9; 18:0 – 2.6; 18:1 – 9.3; 18:2 – 31.0; 18:3 –

50.0; others (4) – 0.6 [3]

IR [3]

Activity: Essential oil has antimycotic activity [2].

Use: Essential oil may be used in perfume [2].

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

78 [in Russian]

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia reflexa Hornem.

Family: Lamiaceae

Seed

Oil (hexane), %: 24.7 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – tr; 16:0

– 4.1; 16:1 – 0.2; 18:0 – 1.9; 18:1 – 9.7; 18:2 –

20.3; 18:3 – 63.7; others (2) – 0.11 [2]

Seed and Pericarp

Mass of 1,000, g: 1.4 [3, 4]

Oil (petroleum ether, 30–60˚C), % dry wt: 23.0 [3, 4]

n40D : 1.4760 [4]

Iodine value (Wijs), % J2: 199.0; 202.0 (cald) [4]

HBr uptake, as C18 acid, %: 0.1 [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.6; 18:0 – 3.0; 18:1 – 11.0; 18:2 – 16.0; 18:3 –

63.0; others (2) – tr [4]

IR [4]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 83 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) in Russian

3. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

4. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia reglal Cav.

Family: Lamiaceae

Aerial Part

Triterpenoic acids: Oleanolic acid

Sterols: b-SitosterolM.p.

References

1. M. Hernandez, B. Esquivel, J Cardenas, L. Rodriguez-Hahn,

T.P. Ramamoorthy, Phytochemistry 26, 3297 (1987)

Page 109: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia rosaefolia Smith. 497 Lamiaceae

Salvia ringens Sibth.et Smich.

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), %: 0.89 (at flowering

stage in June, Sample 1; 1997); 1.70 (Sample 2;

1998) [1]

Composition (GC and GC/MS, DB 5 and

Supelcowax 10), %: Tricyclene – tr; a-pinene –10.64; a-thujene – tr; camphene – 3.59; b-pinene– 4.34; myrcene – 3.68; a-phellandrene – tr; a-terpinene – tr; p-cymene – 2.81; limonene – tr;

1,8-cineole – 50.74; benzene acetaldehyde – tr;

g-terpinene – 0.13; cis-sabinene hydrate – tr;

linalool – 0.95; a-thujone – tr; endo-fenchol –

tr; cis-p-menth-2-en-1-ol – tr; a-campholenal –

tr; trans-sabinol – tr; camphor – 1.77; borneol –

3.52; terpin-4-ol – 1.04; a-terpineol – 0.38;

bornyl acetate – 6.54; trans-sabinyl acetate – tr

thymol – tr; carvacrol – tr; piperitenone – tr; a-copaene – 0.44; 1,7-di-epi-a-cedrene – tr; a-gurjunene – tr; a-cedrene – tr; b-caryophyllene –1.08; trans-a-bergamoten – 0.38; a-humulene –

1.71; (E)-b-farnesene – tr; b-acoradiene – tr; a-muurolene – tr; b-bisabolene – 0.41; g-cadinene –0.45; b-curcumene – tr; d-cadinene – 1.14; a-calacorene – tr; cis-sesquisabinene hydrate – tr;

germacrene D-ol - tr; caryophyllene oxide – 0.43;

humulene epoxide II – 0.5; 1-epi-cubenol – tr; a-acorenol – tr; epi-a-cadinol – tr; b-eudesmol – tr;

a-cadinol – tr; b-bisabolol – 0.59; cadalene – tr;

a-bisabolol – tr; total – 99.82 (Sample 1) [1]

d25: 0.88 (1) [1]

n25D : 1.47 (1) [1]

½a�25D : 4.25 (in CHCl3, C ¼ 2.27 (1) [1]

Tricyclene – tr; a-pinene – 12.85; camphene – 3.99;

b-pinene – 5.64; myrcene – 4.96); a-phellandrene – tr; a-terpinene – tr; p-cymene –

tr; 1,8-cineole – 46.42; cis-sabinene hydrate – tr;

a-terpinolene – tr; p-cymenene – tr; trans-sabinene hydrate – tr; linalool – 0.66; a-thujone– tr; endo-fenchol – tr; b-thujone – tr; a-campholenal – tr; camphor–1.57; menthone –

tr; borneol – 2.83; terpin-4-ol – 0.78; p-cymen-

8-ol – tr; a-terpineol – 0.23; cis-piperitol – tr;

trans-carveol – tr; bornyl acetate – 4.53; thymol

– tr; carvacrol – tr; a-cubebene – tr; neryl acetate– tr; a-copaene – 0.43; 1,7-di-epi-a-cedrene – tr;

a-gurjunene – 0.37; a-cedrene – tr; b-caryophyllene – 0.86; trans-a-bergamoten –

0.28; a-humulene – 2.11; b-acoradiene – 0.15;

a-muurolene – 0.25; b-bisabolene – 0.34; g-cadinene – 0.94; b-curcumene – tr; cis-calamene

– tr; d-cadinene – 2.09; a-calacorene – 0.26;

trans-sesquisabinene hydrate – 0.34;

caryophyllene oxide – tr; gleenol – tr; guaiol –

0.37; humulene epoxide II – 0.49; 1-epi-cubenol

– 0.28; a-acorenol – 0.44; epi-a-cadinol – 0.84;

a-muurolol – tr; b-eudesmol – tr; a-cadinol-0.66;b-bisabolol – 01.13; a-bisabolol – 0.23; total –

99.86 (Sample 2) [1]

Activity: Antimicrobical activity, MICmg/mL: 2.75–

3.75; Escherichia coli, Enterobacter cloacae,Klebsiclla pneumoniae, Pseudomonas aerugonosa),

0.75 against Candila albicans, C. vaginalis, Toree

lopsis glabrata [1]

Seed and Pericarp

Mass of 1,000, g: 4.7 [2]

Oil (petroleum ether, 30–60�C), % dry wt: 13.0 [2]

n40D : 1.4688 [2]

Iodine value (Wijs), % J2: 131.0; 134.0 (cald) [2]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.5; 18:0 – 2.4; 18:1 – 21.0; 18:2 – 65.0; 18:3 –

0.8; others (9) – 2.5 [2]

IR

References

1. O. Tzakou, D. Pitarokili, I.B. Chinou, C. Harvala, Planta Med.

67, 81 (2001)

2. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia rosaefolia Smith.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.4

Oil (petroleum ether, 30–60�C), % dry wt: 20.0

n40D : 1.4685

Iodine value (Wijs), % J2: 136.0; 139.0 (cald)

Page 110: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 498 Salvia rugosa Dryond ex Ait.

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.9; 18:0 – 2.4; 18:1 – 21.0; 18:2 – 68.0; 18:3 –

1.0; others (3) – 0.8

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia rugosa Dryond ex Ait.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.4

Oil (petroleum ether, 30–60�C), % dry wt: 28.0

n40D : 1.4716

Iodine value (Wijs), % J2: 165.0; 172.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.2; 18:0 – 3.6; 18:1 – 17.0; 18:2 – 32.0; 18:3 –

39.0; others (4) – 0.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia sanomensis Greene.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.0

Oil (petroleum ether, 30–60�C), % dry wt: 21.0

n40D : 1.4718

Iodine value (Wijs), % J2: 162.0; 168.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.4; 18:0 – 2.7; 18:1 – 21.0; 18:2 – 37.0; 18:3 –

32.0; others (7) – 1.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia sarawschanica Regel et Schmalth.

Family: Lamiaceae

Essential oil, %: 0.1–0.14

Components: Cineole, a-pinene, b-pinene, limo-

nene, p-cymole, terpinolene, linalool

Root

Essential oil, %: 0.15

Components: Cineole – 63.0%, a-pinene, b-pinene,limonene, p-cumole, terpinolene, linalool

Use: Essential oil may be used in perfume.

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

78 [in Russian]

Salvia scabiosifolia Lam.

Family: Lamiaceae

Seed

Oil (hexane), %: 17.0

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.4;

16:0 – 7.5; 16:1 – 1.6; 18:0 – 2.3; 18:1 – 13.7;

18:2 – 72.5; 18:3 – 2.0; others (1) – tr

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Page 111: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia sclarea L. 499 Lamiaceae

Salvia schamalhausenii Regel.

Family: Lamiaceae

Seed

Oil, %: 33.5

FAs: 16:0; 16:1; 18:0; 18:1; 18:2; 18:3

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 78 [in Russian]

Salvia sclarea L.

Family: Lamiaceae

Seed

Oil, % dry wt: 33.5

References

1. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

Salvia sclarea L.

Family: Lamiaceae

Essential oil

Composition, %: Myrcene – 8.4; limonene – 1.7;

(Z)-b-ocimene – 5.7; terpinolene – 1.03; linalool

– 24.5; a-terpineol – 9.8; geraniol – 1.2; linalyl

acetate – 20.9; neryl acetate – 3.6; a-copaene –

1.1; geranyl acetate – 6.3; b-caryophyllene – 3.0;germacrene D – 0.9; d-cadinene – 1.1;

spathulenol – 2.0; caryophyllene oxide – 5.3;

sclareol – 1.8 [1]

Aerial Part

Essential oil, %: 0.15–0.22 [2]

Components: a-Thujene, a-pinene, b-pinene,myrcene, b-ocimene, limonene, camphene, cin-

eole, linalyl acetate, linalool, caryophyllene,

cadinene [2]

Inflorescence

Essential oil

Components: Myrcene, linalool, a-terpineol,linalylacetate, nerol, geraniol, carvacrol,

nerylacetate, geranylacetate, copaene,

caryophyllene [2]

Flower

Essential oil, %: 0.24–1.1 [2]

Fruit

Oil, %: 19.2–27.4 [2]

Sterols: Cholesterol, campesterol, stigmasterol,

avenasterol, sitosterol [2]

Leaf

Essential oil, %: 0.03–0.12 [2]

Components: Sclareol, carotene, tocopherols [2]

Seed

Mass of 1,000, g: 3.0 [3]

Oil, % dry wt: 20.0 [3]; 27.5–31.0 [2]; 29.0–31.0 [4]

d20: 0.9293 [4]

d12: 0.9300–0.9308 (USSR) [4]

d15: 0.9327 (Italy) [4]

n15D : 1.4829 (Italy) [4]

n20D : 1.4714–1.4766 (USSR) [4]

Acid value, mg KOH: 1.11 [4]

Color: 602/2 [3]

Iodine value, % J2: 141.0 (Italy) [4]; 169.0–174.0

(USSR) [4]

Saponification value, mg KOH: 191.0–193.0 [4]

FAs

Composition (GLC, FFAP, 30 m � 0.2 mm), %:

16:0 – 6.8; 18:0 – 2.8; 18:1(9) – 16.1; 18:1(6) –

1.1; 18:2 – 17.8; 18:3 – 54.7 [3]

Seed and Pericarp

Mass of 1,000, g: 3.0 [5]

Oil, %: 27.5–34.6 [5-8]; 21.5 [9]; 4.0 (cultivated in

Turkey; hexane, Soxhlet) [10]

d204 : 0.9513 [6]; 0.9267 [7]

n40D : 1.4729 [5]

n20D : 1.4820 [6]

n18D : 1.4811 [7]

Eo20: 8 [6]; 6.22 [7]

Acid value, mg KOH: 3.1 [6]

Аcetic value, mg KOH: 34.56 [7]

Page 112: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 500 Salvia sclarea L.

Hehner value, %: 94.52 [7]

Iodine value, % J2: 185 (Wijs); 189 (cald) [5]; 179

[6]; 178.63 [7]

Saponification value, mg KOH: 193 [6] ; 186.62 [7]

Unsaponifables, %: 0.902 [7]

IR [5]

FAs

Iodine value, % J2: 181.94 [7]

Neutralization value, mg KOH: 195.22 [7]

Composition (GLC), %: 16:0 – 6.9; 18:0 – 2.5; 18:1

– 18.0; 18:2 – 17.0; 18:3 – 54.0; others (4) – 0.7

(20% LAC-2R 446) [5]

10:0 – 0.92; 16:0 – 7.05; 18:0 – 2.82; 18:1 – 21.71;

18:2 – 16.82; 18:3 – 50.66; 20:0; 22:0; 24:0; 26:0

– tr [7]

14:0 – tr; 16:0 – 6.4; 16:1 – 0.3; 18:0 – 2.0; 18:1 –

13.6; 18:2 – 20.6; 18:3 – 57.1; others (2) – tr

(20% DECS) [8]

14:0 – 0.2; 15:0 – 0.1; 16:0 – 11.3; 16:1(7Z) – 0.2;

16:1(9Z) – 0.1; 17:0 – 0.2; 18:0 – 4.9; 18:1(9Z) –

19.4; 18:1(11Z) – 1.4; 18:2 – 18.1; 18:3 – 38.6;

20:0 – 0.5; 20:1 – 0.7; 22:0 – 0.6 (GC/MS, HP-

Innowax) [10]

TAG

Main components, mol %: LeLeLe – 15.6; LLeLe –

8.2; OLeLe – 9.8; LeLLe – 6.1; LeOLe – 8.2;

PLeLe – 6.2; LLLe – 3.2; OLLe – 3.8; LOLe –

4.4; OOLe – 5.2; OLeL – 2.6; PLLe – 2.8; LLeL

– 1.1; POLe – 3.8; PLeL – 1.8; PLeO – 2.2;

OLeO – 1.5; OLL – 1.0; OOL – 1.4; LLL – 3.2;

POO – 1.2; LePLe – 1.0; others – 5.8 (wild

plant); LeLeLe – 21.4; LLeLe – 8.4; OLeLe –

7.8; LeLLe – 10.3; LeOLe – 10.6; PLeLe – 5.4;

LLLe – 4.2; OLLe – 4.0; LOLe – 4.2; OOLe –

3.8; OLeL – 1.6; PLLe – 2.8; POLe – 3.0; PLeL –

1.2; PLeO – 1.0; LePLe – 1.4; others – 8.2

(cultivated plant) [9]

Compositions, mol %: SSS – 0.06; SSU + USS –

0.71; SUS – 2.10; USU – 2.14; UUS +

SUU – 24.38; UUU – 70.58 (wild plant);

SSU+SSU – 0.2; USU – 2.3; SUS – 0.7;

UUS+SUU – 16.0; UUU – 80.8 (cultivated

plant) [9]FAs of TAG

Composition of (GLC, 17% PEGS), %: 16:0 – 7.2;

16:1(9) – tr; 18:0 – 2.0; 18:1(9) – 20.5;

18:2(9,12) – 16.4; 18:3(9,12,15) – 53.9 (wild

plant); 16:0 – 5.8; 16:1(9) – tr; 18:0 – 1.2;

18:1(9) – 16.0; 18:2(9,12) – 16.6; 18:3(9,12,15)

– 60.4 (cultivated plant) [9]

a-Carotene [7]

Chlorophyll b [7]

Sterols [7]

Activity: Antimicrobial activity of essential oil

(in vitro), 100% inhibition at ppm: Rhizoctonia solani– at 800 (fungi-static); Botrytis cinera – at 1,600

(fungi-static) and at 3,200 (fungicidal); Fusariumoxysporum and Alternaria solani – at 3,200 (fungicidal

and fungistatic); MIC, mg/mL: Fusarium oxysporum –

1,800; Botrytis cinera – 950; Rhizoctonia solani – 700;Alternaria solani – 1,900 [1]

MFC, mg/mL: Fusarium oxysporum and Botrytis

cinera – 3,000; Rhizoctonia solani – 1,450;

Alternaria solani – >3,200 [1]

Linalool, MIC, mg/mL: Fusarium oxysporum – 800;

Botrytis cinera – 300; Rhizoctonia solani – 200;

Alternaria solani – 1,000 [1]

MFC, mg/mL: Fusarium oxysporum – 2,800; Botry-

tis cinera and Rhizoctonia solani – 2,400;

Alternaria solani – 3,200 [1]

Linalyl acetate, MIC, mg/mL: Fusarium oxysporum,

Botrytis cinera, Rhizoctonia solani and Alternariasolani – >4,000 [1]

References

1. D. Fraternale, L. Giamperi, A. Bucchini, D. Ricci, F.

Epifano, S. Genovase, M. Curini, Chem. Nat. Comp. 41,

604 (2005)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

79 [in Russian]

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica

44(3), 161 (1998)

4. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350

5. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids

2(5), 371 (1967)

6. L.M. Dranowskaya, Maslo-Ji’rovaya promischlennost (11),

33 (1961)

7. S.D. Gusakova, A.U. Umarov, A.L. Markman, Chem. Nat.

Comp. 4, 250 (1968)

8. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12(2), 272 (1976)

9. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

10. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Page 113: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Salvia splendens (L.) Ker-Gawl. 501 Lamiaceae

Salvia sp.

Family: Lamiaceae

Seed

Oil (hexane), %: 17.1

TAG

Main components, mol %: LeLeLe – 14.8; LLeLe –

6.6; OLeLe – 9.0; LeLLe – 6.7; LeOLe – 13.4;

PLeLe – 3.4; LLLe – 3.0; OLLe – 4.0; LOLe –

6.2; OOLe – 8.0; OLeL – 2.0; PLLe – 1.6; POLe

– 3.0; PLeO – 1.0; OLeO – 1.4; OLL – 1.0; OOL

– 1.8; LePLe – 1.2; OOO – 1.2; OPLe – 1.2;

LPLe – 1.0; POO – 1.0; others – 5.5

FAs from TAG

Composition (GLC; 17% PEGS), %: 16:0 – 6.4;

16:1(9) – tr; 18:0 – tr; 18:1(9) – 24.3;

18:2(9;12) – 15.3; 18:3(9,12,15) – 54.0

Compositions: SSU + USS – 0.8; USU – 4.7; SUS –

0.5; UUS + SUU – 12.4; UUU – 81.6

References

1. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Salvia speciosa Presl.

Family: Lamiaceae

Seed

Oil, %: 20.0

Saponification value, mg KOH: 196.1

Iodine value, % J2: 160.0–162.0

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Salvia spinosa L.

Family: Lamiaceae

Essential oil, %: 0.03–0.6 [1]

Aerial Part

Essential oil, %: 0.19–0.6 [1]

Seed

Oil, %: 29.8 [1]; 20.0 [2]; 27.0 [3]

d15: 0.9298 [2]

n15D : 1.4799 [2]

Iodine value, % J2: 59.0 [2]

Saponification value, mg KOH: 193.0 [2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.9;

16:0 – 10.4; 16:1 – 1.6; 18:0 – 3.0; 18:1 – 16.9;

18:2 – 19.9; 18:3 – 45.6; others (6) – 1.7 [3]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

80 [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

3. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12 (272) (1976) [in Russian]

Salvia splendens (L.) Ker-Gawl.

Family: Lamiaceae

Aerial part

Triterpenoic acids: Ursolic (main) and oleanoic acids

[1]

Seed

Oil, %: 21.0–32.0 [2]; 29.2 [3]; 26.5 [4]

n20D : 1.4810 [2]

Iodine value, % J2: 137.0–164.5 [2]

Saponification value, mg KOH: 184.1 [2]

FAs

Composition (GLC, 20% DECS), %: 14:0 – tr; 16:0

– 7.3; 16:1 – 0.6; 18:0 – 2.9; 18:1 – 12.3; 18:2 –

39.4; 18:3 – 37.0; others (1) – 0.5 [3]

TAG

Main components, mol %: LeLeLe – 4.9; LLeLe –

11.6; OLeLe – 3.6; LeLLe – 5.0; LeOLe – 1.4;

PLeLe – 3.6; LLLe – 12.0; OLLe – 3.8; LOLe –

3.4; OOLe – 1.0; OLeL – 4.4; PLLe – 3.8; LLeL

– 7.0; POLe – 1.0; PLL – 4.4; others – 3.1 [4]

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Lamiaceae 502 Salvia splendens Ker. – Gawl.

Compositions, mol %: SSU +USS – 0.4; USU – 1.3;

SUS – 1.2; UUS + SUU – 21.8; UUU – 75.3 [4]

FAs from TAG

Composition (GLC; 17% PEGS), %: 16:0 – 6.4;

16:1(9) – tr; 18:0 – 2.3; 18:1(9) – 12.7;

18:2(9,12) – 41.5; 18:3(9,12,15) – 36.7 [4]

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

3. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12(2), 272 (1976)

4. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Salvia splendens Ker. – Gawl.

Family: Lamiaceae

Seed

Oil, % dry wt: 31.0

References

1. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

Salvia stenophylla Burch

Family: Lamiaceae

Essential oil (steam distillation), %: 0.5–0.6

Composition (GC, Carbowax 20 M and PPG; GC-

MS, IR, 1H NMR, 13C NMR): a-Pinene – 2.6;

camphene – 2.45; b-pinene – 0.38; a-phellandrene – 14.9; b-myrcene; a-terpinene;and 1;8-cineole – 8.01; limonene – 7.44; g-terpinene – 0.41; monoterpene – 1.43; linalool

– 0.015; oxygenated monoterpene – 0.41; cam-

phor and isoborneol – 2.96; borneol – 0.46;

b-caryophyllene and bergamoten – 2.40;

a-humulene and trans-b-farnesene – 2.12;

b-humulene – 1.18; a-bisabolene – 0.60;

d-cadinene – 0.24; b-bisabolene – 0.14;

nerolidol (E) – 1.94; oxygenated sesquiterpene

1–1.20; (+) a-bisabolol – 40.99; oxygenated ses-quiterpene 2 – 0.81; a-sinensal (R) – 0.39;

a-sinensal (S) – 0.62; sesquiterpene alcool –

1.12; manool – 3.89; total – 99.00 (The High

Weld of the Orange Republic of South Africa)

References

1. C. Jequer, G. Nicollier, R. Tabacchi, J. Garnero, Phytochem-

istry 19(3), 461 (1980)

Salvia stepposa Schost.

Family: Lamiaceae

Seed

Oil (hexane), %: 29.8

FAs

Composition (GLC, 20% DECS), %: 14:0 – 1.3;

16:0 – 7.8; 16:1 – 1.3; 18:0 – 4.1; 18:1 – 13.6;

18:2 – 25.7; 18:3 – 42.1; others (6) – 4.1

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12(2), 272 (1976) [in Russian]

Salvia suffruticosa Montbr. et Auch.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 15.0

Oil (petroleum ether, 30–60�C), % dry wt: 40.0 [1]

n40D : 1.4679

Iodine value (Wijs), % J2: 132.0; 137.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.4; 18:0 – 1.7; 18:1 – 21.0; 18:2 – 67.0; 18:3 –

0.7; others (5) – 0.9

IR

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Salvia tesquicola Klok. 503 Lamiaceae

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia sylvestris L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.0

Oil (petroleum ether, 30–60�C), % dry wt: 27.0

n40D : 1.

Iodine value (Wijs), % J2: 192.0; 198.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.2; 18:0 – 2.3; 18:1 – 14.0; 18:2 – 24.0; 18:3 –

55.0; others-(3) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia syriaca L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4

Oil (petroleum ether, 30–60�C), % dry wt: 12.0 [1]

n40D : 1.4735

Iodine value (Wijs), % J2: 174.0; 182.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.0; 18:0 – 2.2; 18:1 – 17.0; 18:2 – 31.0; 18:3 –

43.0; others (7) – 1.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia tchihatcheffii (Fisch. etMey.) Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 4.5 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 22.0 [1]

n40D : 1.4705

Iodine value (Wijs), % J2: 150.0; 151.0 (cald) [1]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.8; 18:0 – 1.6; 18:1 – 13.0; 18:2 – 79.0; 18:3 –

2.0; others (3) – 0.2 [1]

IR [1]

Seed

Oil (hexane), %: 3.9 [2]

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.4;

16:0 – 14.8; 17:0 – 0.2; 18:0 – 5.2; 18:1(9Z) –

22.7; 18:1(11Z) – 0.7; 18:2 – 44.2; 18:3 – 1.5;

20:0 – 0.5 [2]

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

Salvia tesquicola Klok.

Family: Lamiaceae

Seed

Oil, % dry wt: 40.0

References

1. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

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Lamiaceae 504 Salvia tesquicola Klok. et Pobed.

Salvia tesquicola Klok. et Pobed.

Family: Lamiaceae

Seed

Oil (hexane), %: 28.2 [1]; 40.0 [2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.5;

16:0 – 6.3; 16:1 – 1.3; 18:0 – 2.3; 18:1 – 11.2;

18:2 – 24.1; 18:3 – 54.3; others – tr [1]

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

80 [in Russian]

Salvia texana (Sheele) Toir.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.0

Oil (petroleum ether, 30–60�C), % dry wt: 16.0 [1]

n40D : 1.4690

Iodine value (Wijs), % J2: 140.0; 141.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

11.0; 18:0 – 2.9; 18:1 – 8.9; 18:2 – 76.0; 18:3 –

12.0; others (2) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia tiliifolia Vahl.

Family: Lamiaceae

Seed

Oil (hexane), %: 29.8

FAs

Composition (GLC, 20% DEGS), %: 14:0 – tr; 16:0

– 6.6; 16:1 – 0.4; 18:0 – 2.5; 18:1 – 6.8; 18:2 –

21.4; 18:3 – 62.3; others (1) – tr

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976)

Salvia tomentosa Mill.

Family: Lamiaceae

Essential oil

Composition (GLC, 10% Carbowax): a-Pinene –

11.4; camphene – 1.8; b-pinene – 19.2; myrcene

– 0.7; a-phellandrene – 3.0; limonene – 0.8; 1.8-

cineole – 15.0; g- terpinene – 0.7; a-thujone –

0.1; b-thujone – 0.2; camphor – 1.2; linalool –

1.6; linalyl acetate – 6.2; isobornyl acetate – 0.4;

bornyl acetate – 7.8; borneol – 3.2; terpinen-4-ol

– 5.1; b-caryophyllene – 4.9; a-humulene – 5.9;

a- terpinyl acetate – 3.1; geranyl acetate – 2.3;

geraniol – 2.0 (from Kars, Turkey) [1]

Triterpenoids: b-Amyrin, uvaol [2]

Aerial Part

Triterpenoids: Methyl oleate, methyl ursolate, methyl

maslinate [2]

Seed

Oil (hexane), %: 4.6 [3]

FAs

Composition (GC/MS, HP-Innowax), %: 14:0 – 0.3;

15:0 – 0.1; 16:0 – 20.9; 16:1(7Z) – 0.2; 16:1(9Z)

– 0.2; 17:0 – 0.1; 18:0 – 4.9; 18:1(9Z) – 3.9;

18:1(11Z) – 1.0; 18:2 – 41.0; 18:3 – 2.7; 20:0 –

0.7; 20:1 – 0.8; 22:0 – 0.5 [3]

References

1. A. Bayrak, A. Akgul, Phytochemistry 26(3), 846 (1987)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

81 [in Russian]

3. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 186 (2004)

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Salvia verbenaca L. 505 Lamiaceae

Salvia turcomanica Pobed.

Family: Lamiaceae

Seed

Oil, %: 22.3

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

81 [in Russian]

Salvia valentina Vahl.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.0

Oil (petroleum ether, 30–60�C), % dry wt: 14.0

n40D : 1.4732

Iodine value (Wijs), % J2: 176.0; 182.0 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.4; 18:0 – 2.9; 18:1 – 12.0; 18:2 – 31.0; 18:3 –

45.0; others (3) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia verbascifolia Beib.(S. karabachensis Pobed.)

Family: Lamiaceae

Seed

Oil (hexane), %: 26.9 [1] 22.4–26.9 [2]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – tr; 16:0

– 6.3; 16:1 – 0.4; 18:0 – 2.3; 18:1 – 12.6; 18:2 –

28.7; 18:3 – 49.7; others (2) – tr [1, 2]

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

81 [in Russian]

Salvia verbenaca L.

Family: Lamiaceae

Essential oilComponents: a-Pinene, 1,8-cineol, camphor, bor-

neol, terpineol, a-thujene, b-thujene,caryophyllene

Triterpenoids: Ursolic acid, b-sitosterol [1]

Seed

Oil, %: 26.8 (hexane) [2]; 20.0 [3]; 30.0 [4]

n20D : 1.4813 [3]

Iodine value, % J2: 178.28 [3]; 166.07 [4]

FAs

Composition (GLC, 20% DEGS), %: 14:0 – 0.3;

16:0 – 9.2; 16:1 – 1.0; 18:0 – 2.8; 18:1 – 16.4;

18:2 – 25.1; 18:3 – 44.7; others (5) – 0.5 [2]

16:0 – 9.5; 18:0 – 3.42; 18:1 – 22.08; 18:2 – 26.93;

18:3 – 37.99 [3]

Seed and Pericarp

Mass of 1,000, g: 0.6 [5]

Oil (petroleum ether, 30–60), % dry wt: 18.0 [5]

n40D : 1.4736 [5]

Iodine value (Wijs), % J2: 177.0; 180.0 (cald) [5]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

11; 18:0 − 2.1; 18:1 − 14.0; 18:2 − 25.0; 18:3 −48.0; others (4) − 0.5 [5]

IR [5]

Activity: Essential oil has antimycotic activity [1]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6, p.

82 [in Russian]

2. A.V. Patudin, I.U Yusupova, D.A. Voloshina, Rast. Resursy,

12, 272 (1976) [in Russian]

3. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

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Lamiaceae 506 Salvia verticillata L.

4. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

5. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Salvia verticillata L.

Family: Lamiaceae

Steroids: b-Sitosterol, 3-b-D-glycosid sterols [1]

Triterpenoids: Ursolic, oleanoic, cratalgaloic,

virgatoic and betulinic, acids [1]

Aerial Part

Essential oil, %: 0.07–0.10 [1]; 0.05–0.08 [2]

Composition (GLC, 15% Carbowax 20): a-Pinene –1.0; b-pinene – 1.6; cineole – 1.7; thujone – 0.6;linalool – 1.5; borneol – 0.8; linalyl acetate – 0.7;

bornyl acetate – 24.6; and others [1]

Steroids, %: 0.05 [2, 3]

Triterpenoids, %: Ursolic acid – 0.45 [2, 3]

Flower

Essential oil, %: 0.16–0.22 [1]

Fruit

Oil, %: 21.32 [2]

Sterols: Cholesterol, campesterol, stigmasterol,

avenasterol, sitosterol [2]

Seed

Oil (hexane), %: 30.1 [4]; 30.5–33.8 [5]; 23.0 [6]

Iodine value, % J2: 169.9–175.7 [5]; 201.1 (cald.)

[7]

FAs

Composition (GLC), %: 14:0 – 0.2; 16:0 – 6.8; 16:1

– 0.6; 18:0 – 2.0; 18:1 – 16.6; 18:2 – 27.0; 18:3 –

46.6 (20% DEGS [4]

16:0 – 4.1; 18:0 – 1.2; 18:1 – 7.7; 18:2 – 38.7; 18:3 –

48.3 (10% PEGA) [7]

References

1. R. Ivanic; K. Savin, Planta Med. 30, 26 (1976)

2. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

p. 82 [in Russian]

3. D.P. Popa, L. A. Saley, T.M. Orghiyan, Rast. resursy 12, 247

(1976) [in Russian]

4. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

5. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

6. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR (10), 43 (1973)

7. G.V. Novitzkaya, I.U. Yusupova, D.A. Voloshina, Rast.

Resursy 7, 32 (1971) [in Russian]

Salvia virgata Jacq.

Family: Lamiaceae

Seed

Oil, % dry wt: 23.0

Iodine value, % J2: 156.05

Composition (GLC), %: 14:0 � tr; 16:0 � 10.85;

16:1 � tr; 18:0 � 4.19; 18:1 � 22.45; 18:2 �31.35; 18:3 � 31.14

References

1. N. Ramazanova, M. Ganieva, K. Khodzhimatov, Dokl. Akad.

Nauk Uzb. SSR, (10), 43 (1973)

Salvia virgata Jacq.

Family: Lamiaceae

Seed

Oil (hexane), %: 21.3 [1]; 25.1 [2]; 20.9 (in Soxhlet)

[3]

FAs

Composition (GLC, 20% DECS), %: 14:0 – 0.3;

16:0 – 8.3; 16:1 – 0.5; 18:0 – 2.7; 18:1 – 16.7;

18:2 – 29.3; 18:3 – 42.2; others (1) – tr [1]

Composition (GC/MS, HP-Innowax), % 14:0 – 0.1;

15:0 – 0.1; 16:0 – 13.6; 16:1(7Z) – 0.1; 16:1(9Z)

– 0.2; 17:0 – 0.1; 18:0 – 5.8; 18:1(9Z) – 23.6;

18:1(11Z) – 1.4; 18:2 – 44.5; 18:3 – 0.4; 20:0 –

0.3; 20:1 – 0.8; 22:0 – 0.1 [3]

TAG

Main components, mol %: LeLeLe – 19.3; LLeLe –

15.6; OLeLe – 7.2; LeLLe – 8.8; LeOLe – 3.3;

PLeLe – 6.2; LLLe – 7.2; OLLe – 3.2; LOLe –

2.8; OOLe – 1.2; OLeL – 3.0; PLLe – 3.2; LLeL

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Satureja calamintha 507 Lamiaceae

– 3.2; POLe – 1.2; PLeL – 2.8; PLeO – 1.4; OLL

– 1.4; LLL – 1.5; PLL – 1.4; others – 5.0 [2]

Composition, mol %: USU – 0.7; SUS – 0.9; UUS +

SUU – 18.4; UUU – 80.0 [2]

FAs from TAG

Composition (GLC; 17% PEGS), %: 16:0 – 5.5;

16:1(9) – tr; 18:0 – 1.6; 18:1(9) – 10.6;

18:2(9,12) – 24.5; 18:3(9,12,15) – 57.8 [2]

References

1. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12(2), 272 (1976)

2. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

3. N. Azcan, A. Ertan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 40, 218 (2004)

Salvia viridis L.

Family: Lamiaceae

Seed

Oil (hexane), %: 24.0 [1, 2]

FAs

Composition (GLC, 20% DEGS), %: 16:0 – 9.0;

18:0 – 2.6; 18:1 – 19.0; 18:2 – 27.0; 18:3 –

41.0; others (1) – 1.1 [2]

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

82 [in Russian]

2. A.V. Patudin, I.U. Yusupova, D.A. Voloshina, Rast. Resursy

12, 272 (1976) [in Russian]

Satureja boissieri Hausskn. ex Boiss.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 2.1 (from

plant collected in August 2000, Turkey)

Composition of essential oil (GC/MS, CPSil 5 CB),

%: a-Thujene � 1.4; a-pinene � 1.0; camphene

� 0.1; 1-octen-3-ol � 0.2; b-pinene � 0.2;

myrcene � 2.8; a-phellandrene � 0.4; D3-carene

� 0.1; a-terpinene � 4.6; p-cymene � 14.5; b-phellandrene + limonene� 0.9; (Z)-b-ocimene�tr; g-terpinene � 26.4; (E)-b-ocimene � 0.1;

trans-sabinene hydrate � 0.2; methyl benzoate

� tr; trans-linalool oxide + cumenene � 0.1;

terpinolene + trans-p-menth-2-en-8-dien-1-ol �0.2; linalool � 1.3; trans-p-menth-2-en-1-ol �tr; borneol � 0.1; 1;8-menthadien-4-ol + p-

cymen-8-ol + terpinen-4-ol � 0.8; a-terpineol �tr; methyl carvacrol � 0.2; isothymol � 0.1; thy-

mol + isocarvacrol � 0.3; carvacrol � 40.8;

carvacryl acetate � 0.2; b-caryophyllene � 0.8;

aromadendrene� tr; a-humulene� tr; alloaroma-

dendrene � tr; ledene � 0.2; d-cadinene � tr;

spathulenol � 0.2; caryophyllene oxide � 0.1;

viridiflorol � tr; hexadecanoic acid � tr

Use: It is known as “Catali” and as herbal tea in the

regions where it grows.

References

1. M. Kurkcuoglu, G. Tumen, K.H.C. Baser, Chem. Nat. Comp.

37, 329 (2001)

Satureja calamintha

Family: Lamiaceae

Leaf

Components: Campesterol, stigmasterol, sitosterol,

calaminthadiol (3,4-seco-4(23),12-ursadien-3,28-

diol), iso-calaminthadiol (3,4 seco-4 (23), 12-

ursadien-1,28-diol) [1]

Calaminthadiol

[a]D: +87 (CHCl3, c, 1.5) [1]

IR, 1H NMR, MS [1]

Epiursolic acid [2]

References

1. G. Romeo, P. Giannetto, M.C. Aversa, Phytochemistry 19,

437 (1980)

2. P. Giannetto, G. Romeo, M.C. Aversa, Phytochemistry 18,

1203 (1979)

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Lamiaceae 508 Satureja coreana (Levl) Nakai

Satureja coreana (Levl) Nakai

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.1

Oil (petroleum ether, 30–60�C), % dry wt: 26.0

n40D : 1.4757

Iodine value (Wijs), % J2: 197; 200 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.7; 18:0 – 2.7; 18:1 – 9.0; 18:2 – 28.0; 18:3 –

54.0; others (6) – 0.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Satureja glabella (Michx.) Briquet

Family: Lamiaceae

Leaves

Terpenoids

Composition, %: Isomenthone – 70.4; pulegone –

15.5; isomenthol – 4.1; menthone – 2.8;

neoisomenthol – 2.6; 3-octanol – 0.7; b-pinene– 0.5; limonene – 0.5; a-pinene – 0.4; neo men-

thol – 0.3; germacrene D – 0.3

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Satureja graeca

Family: Lamiaceae

Leaf

Components: Ursolic, oleanolic, and 3-epiursolic

acids, calaminthadiol (3,4-seco-4 (23),12-

ursadien-3,28-diol [1] iso-Calaminthadiol (3,4

seco-4 (23), 12-ursadien-1,28-diol) [2]

References

1. P. Giannetto, G. Romeo, M.C. Aversa, Phytochemistry 18,

1203 (1979)

2. G. Romeo, P. Giannetto, M.C. Aversa, Phytochemistry 19,

437 (1980)

Satureja hortensis L.

Family: Lamiaceae

Essential oil, % dry wt: 1.10–4.67 (ontogenetic devel-

opment) [1]

Seed and Pericarp

Ash, %: 5.7 [2]

Mass of 1,000, g: 0.7 [2]

Oil, % dry wt: 41.3 [2]

Seed

Mass of 1,000, g: 0.54 [3]

Oil, % dry wt: 39.0 [3]; 42.0 (petroleum ether, 30–

60�C) [4]d20: 0.9268 [3]

n40D : 1.4765 [4]

Acid value, mg KOH: 3.23 [3]

Сolor: 0862.2 [3]

Iodine value (Wijs), % J2: 214.0 [4]

Saponification value, mg KOH: 184.0 [4]

FAs

Composition (GLC), %: 16:0 � 7.9; 18:0 � 3.0;

18:1(9) � 8.0; 18:1(6) � 0.6; 18:2 � 20.2; 18:3

� 60.2 [3]

Saturated � 4.0; 18:1 � 12.0; 18:2 � 18.0; 18:3 �62.0 (20% Apiezon L) [4]

References

1. W. Czabajska, B. Iernas, E. Maciolowska-Ludowicz,

K. Kazmierczak, Herba Polonica 22, 45 (1976)

2. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

3. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

4. F.R. Earle, T.A.McGuire, J. Mallan, M.O. Bagby, I.A.Wolff,

J. Am. Oil Chem. Soc. 37, 48 (1960)

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Satureja parnassica subsp. parnassica Heldr. Sart. ex Boiss. 509 Lamiaceae

Satureja hortensis L.

Synonyms

S. laxiflora C. Koch

Family: Lamiaceae

Aerial Part

Essential oil, %: 0.1–3.2 [1]

Components: Carvacrol – 12.8–52.5; thymol – 0.2–

18.4; n-cymol – 6.8–35.8; a-pinene – 0.6–1.5;

b-pinene – 0.2–0.9; myrcene – 1.0–2.3;

a-terpinene – 1.4–3.5; g-terpinene – 6.3–32.3;

terpineol – 0.1–3.4; b-caryophyllene – 0.5–3.2;

a-thujene -0.4–1.9 and others [1]

Leaf

Triterpenoic acid: Ursolic – 0.4% [1]

Seed

Mass of 1,000, g: 0.54 [2]

Oil, % dry wt: 39.0 [2]

Сolor: Fern green 0862/2 [2]

d20: 0.9268 [2]

Acid value, mg KOH: 3.23 [2]

FAs

Composition (GLC, FFAP, 30 m � 0.2 mm), %:

16:0 – 7.9; 18:0 – 3.0; 18:1(9) – 8.0; 18:1(6) -

0.6; 18:2 – 20.2; 18:3 – 60.2 [2]

16:0 + 18:0 – 4.0; 18:1 – 12.0; 18:2 – 18.0; 18:3 –

62.0 [1]

Seed and Pericarp

Mass of 1,000, g: 0.6 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 39.0 [3]

n40D : 1.4765 [3]

Iodine value (Wijs), % J2: 207; 212 (cald) [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.3; 18:0 – 1.7; 18:1 – 7.6; 18:2 – 20.0; 18:3 –

65.0; others (5) – 1.4 [3]

IR [3]

Stem

Triterpenoic acid: Ursolic – 0.17% [1]

Activity: Essential oil has antibacterial, antimycotic,

and antifungal activities [1].

Use: Leaves are used as kitchen spice [1].

References

1. Rastitel’nye Resursy SSSR (Nauka, St. Petersburg, 1991), 6,

83 [in Russian]

2. J. Kozlowski, I. Dedio, M. Krzyzaniak, Herba Polonica 44(3),

161 (1998)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Satureja montana L.

Family: Lamiaceae

Seed

Oil, %: 25.6

Iodine value, % J2: 70.4

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 350 [in

Russian]

Satureja parnassica subsp. parnassicaHeldr. Sart. ex Boiss.

Family: Lamiaceae

Leaves

Essential oil (steam distillation), %: 0.56 (from the

mountain of Parnassos, vegetative stage)

Composition of essential oil (GC/MS; HPSMS); %:

Tricyclene� 0.49; a-thujene� 0.73; a-pinene�3.16; camphene� 1.96; b-pinene� 1.08; octen-

3-ol � tr; myrcene � 4.41; 3-octanol � tr; a-terpinene � tr; p-cymene � 15.30; limonene �1.0; 1.8-cineole� 0.94; (Z)-b-ocimene� tr; (E)-

b-ocimene � 0.23; g-terpinene � 1.70; cis-sabinene hydrate � 3.53; terpinolene � 0.06; p-

cymenene � tr; linalool � 12.85; camphor �0.59; isoborneol � 1.45; borneol � 2.79;

terpin-4-ol � 1.88; a-terpineol � 0.65; cis-

dihydrocarvone � tr; nerol � tr; neral � tr;

thymol � 8.50; carvacrol � 1;59; a-elangene �tr; b-bourbonene � tr; (Z)-caryophyllene � tr;

(E)-caryophyllene � 7.13; a-trans-bergamoten

� tr; aromadendrene � tr; a-humulene � tr;

Page 122: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 510 Satureja thymbra L.

g-muurolene � tr; germacrene � tr;

bicyclogermacrene � 0.81; a- muurolene � tr;

b-bisabolene � 3.36; g-cadinene � tr; d-cadinene � 0.66; a-cadinene � tr; a-calacorene� tr; spathulenol � tr; caryophyllene oxide �16.34; humulene epoxide II� 0.61; caryophylla-

4(14),8(15)-dien-5a-ol � tr; caryophylla-

4(14),8(15)-dien-5b-ol � 1.29; epi-a-cadinol �tr; epi-a-muurolol � tr; 14-hydroxy-9-epi-(E)-

caryophyllene � 2.09; total � 99.35

Monoterpene hydrocarbons, %: 19.40

Oxygenated monoterpenes, %: 31.80

Sesquiterpene hydrocarbons, %: 27.82

Oxygenated sesquiterpenes, %: 20.33

Activity: Antibacterial activity, MIC mg/mL: Essen-

tial oils � 0.5–1.0; (E)-caryophyllene � 1.0–2.0;

caryophyllene oxide � 1.0–2.0; carvacrol � 0.5–1.0;

streptomycin (as standard) � 0.1–0.5

Inhibitory effect on Helicobacter pylori in vitro, MIC

mg/mL: Essential oil � 250; carvacrol � 67.5; ampi-

cillin-(as standard) � 1.0

Leaves and Flowers

Essential oil (steam distillation), % dry wt: 0.44 (from

the mountain of Parnassos, flowering stage)

Composition of essential oil (GC/MS, HPSMS), %:

Tricyclene� tr; a-thujene� tr; a-pinene� 0.58;

camphene � tr; b-pinene � tr; octen-3-ol � tr;

myrcene � 3.43; 3-octanol � tr; a-terpinene �tr; p-cymene � 12.96; limonene � 0.56; 1.8-

cineole � 0.37; (Z)-b-ocimene � 0.39; (E)-b-ocimene � tr; g-terpinene � 0.90; cis-sabinene

hydrate � 0.58; terpinolene � tr; p-cymenene �tr; linalool � 2.56; nonanal � tr; 1,3.8-p-

menthatriene � tr; camphor � tr; borneol �0.58; terpin-4-ol � 0.44; a-terpineol � tr; cis-dihydrocarvone � tr; nerol � tr; neral � tr;

thymol � 7.45; carvacrol � 20.40; a-ylangene� tr; b-bourbonene� tr; (Z)-caryophyllene� tr;

(E)-caryophyllene� 20.85; b–gurjunene� tr; a-trans-bergamoten � tr; aromadendrene � tr; a-humulene� 0.79; g-muurolene� tr; germacrene

� tr; bicyclogermacrene � tr; a-muurolene � tr;

b-bisabolene � 5.52; g-cadinene � tr; d-cadinene � tr; spathulenol � 17.18;

caryophyllene oxide � 1.70; humulene epoxide

II � tr; caryophylla-4(14),8(15)-dien-5a-ol � tr;

caryophylla-4(14),8(15)-dien-5b-ol � 1.94; epi-

a-cadinol� tr; epi-a-muurolol� tr; 14-hydroxy-

9-epi-(E)-caryophyllene� 1.33; lanceol � 0.26;

total � 98.59

Monoterpene hydrocarbons, %: 33.64

Oxygenated monoterpenes, %: 31.24

Sesquiterpene hydrocarbons, %: 11.30

Oxygenated sesquterpenes, %: 22.41

Activity: Antibacterial activity, MIC mg/mL: Essen-

tial oils � 0.5–1.0; (E)-caryophyllene � 1.0–2.0;

caryophyllene oxide � 1.0–2.0; carvacrol � 0.5–1.0;

streptomycin (as standard) � 0.1–0.5.

Inhibitory effect on Helicobacter pylori in vitro, MIC

mg/mL: Essential oil � 250; carvacrol � 67.5; ampi-

cillin (as standard) � 1.0

References

1. G. Willuhn, S. May, I. Merfort, Planta Med. 69, 282 (2003)

Satureja thymbra L.

Family: Lamiaceae

Essential oil (steam distillation), % v/wt: 1.0 (from

fresh plant material, Israel)

Satureja thymbra L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60�C), % dry wt: 18.0

n40D : 1.4745

Iodine value (Wijs), % J2: 185; 188 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.3; 18:0 – 2.2; 18:1 – 18.0; 18:2 – 26.0; 18:3 –

49.0; others (4) – 0.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

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Scutellaria baicalensis Georgi. 511 Lamiaceae

Satureja vulgaris (L.) Fritch.

Family: Lamiaceae

Leaves

Terpenoids

Composition, %: Germacrene D – 51.8;

caryophyllene – 21.2

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Schizonepeta multifida (L.) Briq.

Synonyms

Nepeta lavandulacea L.

Family: Lamiaceae

Seed

Oil, %: 20.0

Iodine value, % J2: 185.0–187.0

References

1. N. I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 348 [in

Russian]

Scutellaria albida L.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 155.2 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

4.6; 18:0 –1.5; 18:1 – 23.6; 18:2 – 69.3; 18:3 – 0.9

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Scutellaria albida L. ssp. albida

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/dry wt:

< 0.01(from Mt. Pilion, Greek mainland, July 1997)

½L�20D : �22.2� (pentane, C 0.23)

Composition of essential oil (GC/MS, HP-5MS),%:

trans-2-Hexenal� 1.65; cis-3-hexen-1-ol� 0.83;

octen-3-ol � 2.92; octanal � 2.59; d-3-carene �0.85; benzene acetaldehyde � 0.42; g-terpinene� 2.24; octanol � 0.35; linalool � 52.63;

nonanal � 6.73; terpinen-4-ol � 6.63; a-terpin-eol � 4.13; trans-geraniol � 1.82; trans-

nerolidol � 9.03; cis-3-hexenyl benzoate �2.85; total � 95.67

Monoterpene hydrocarbons, %: 3.09

Oxygenated monoterpenes, %: 65.21

Oxygenated sesquiterpenes, %: 9.03

Activity: Antimicrobial activity of the essential oil, as

the diameter of the inhibition zone in mm:

Staphylococcus aureus � 10.0; Bacillus subtilis �11.0;Escherichia coli� 11.0;Pseudomonas aeruginosa

� 8.0; Saccharomyces cerevisiae � 12.0� 13.0.

Linalool, as the diameter of the inhibition zone in mm:

Staphylococcus aureus � 9.0; Bacillus subtilis � 8.0;

Escherichia coli � 20.0; Pseudomonas aeruginosa �4.0; Saccharomyces cerevisiae � 4.0.

References

1. H. D. Skaltsa, D. M. Lazari, A. S. Mavromati, E. A. Tiligada,

T. A. Constantinidis, Planta Med. 66, 672 (2000)

Scutellaria baicalensis Georgi.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 163.4 (cald)

FAs

Composition (GLC, 10% PEGA), mol %:

16:0 – 5.0; 18:0 – 1.6; 18:1 – 15.4; 18:2 – 76.3;

18:3 – 1.8

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Lamiaceae 512 Scutellaria columnae All.

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Scutellaria columnae All.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.6

Oil (petroleum ether, 30–60�C), % dry wt: 38.0

n40D : 1.4670

Iodine value (Wijs), % J2: 119; 123 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.8; 18:0 – 2.7; 18:1 – 33.0; 18:2 – 54.0; 18:3 –

0.1; others (5) – 2.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Scutellaria condensata Rech.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

Iodine value (Wijs), % J2: 115 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.1; 18:0 – 3.3; 18:1 – 42.0; 18:2 – 44.0; 18:3 –

0.6; others (5) – 0.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Scutellaria drummondi Benth.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.5

Oil (petroleum ether, 30–60�C), % dry wt: 33.0

n40D : 1.4656

Iodine value (Wijs), % J2: 102; 100 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.5; 18:0 – 2.4; 18:1 – 6.2; 18:2 – 27.0; others

(5) – 2.7

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Scutellaria galericulata L.

Family: Lamiaceae

Leaf

TerpenoidsComposition, %: Caryophyllene – 29.4; trans-b-

farnesene – 17.0; menthone – 10.4; 1-octen-3-

ol – 8.0; b-cubebene – 3.3; a-humulene – 2.6;

germacrene D – 2.2; limonene – 2.1

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Scutellaria multicaulis Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.5

Oil (petroleum ether, 30–60�C), % dry wt: 42.0

n40D : 1.4688

Iodine value (Wijs), % J2: 130; 132 (cald)

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Sideritis arguta Boiss Ex Heldr. 513 Lamiaceae

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.0; 18:0 – 3.1; 18:1 – 29.0; 18:2 – 61.0; 18:3 –

0.5; others (8) – 1.1

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Scutellaria parvula Michx.

Family: Lamiaceae

Leaf

Terpenoids

Composition, %: a-Bisabolol – 20.6, trans-a-bergamoten – 13.4, b-bisabololene – 6.0,

caryophyllene – 5.2, a-terpineol – 4.0, d-cadinene – 4.0, cis-a-bisabololene – 3.5,

a- cadinol – 3.0, trans-b-farnesene – 2.6,

caryophyllene oxide – 2.2, a-humulene – 2.1

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Sideritis albiflora Hub.-Mor.

Family: Lamiaceae

Aerial Part

Essential oil (hydro distillation), % dry wt: 0.02

(endemic inTurkey)

Main component (GC/MS, Innowax FSC), %: b-caryophyllene – 35.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis amasiaca Bornm.

Family: Lamiaceae

Aerial Part

Essential oil (hydro distillation), % dry wt: 0.02–0.15

(endemic in Turkey)

Main components, %: b-Pinene – 9.0–28.0; a-pinene – 4.0–11.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis arborescens Salzm

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % of the dry wt: ca

0.1 – 0.2 (dried at flowering, Spain)

Composition (GC/MS), %: a-Pinene – 0.1; b-pinene– tr; sabinene – 0.2; myrcene – 0.9; a-phellandrene – 0.4; limonene – 0.9; b-phellandrene – 0.8; 1,8-cineole – 4.5; g-terpinene– 1.9; p-cymene – 5.2; terpinolene – 0.3;

fenchone – 3.0; 1-octen-3-ol – 3.2; fenchyl ace-

tate – 0.8; pinocarvone – 1.0; 1-octanol – 1.3;

4-terpineol – 8.4; caryophyllene – 19.7; achillenole

– 2.1; 3(4)-carene-3-ol – 2.2; a-terpineol – 3.9;

a-terpenyl acetate – 0.7; phellandren-8-ol – 3.0;

p-cymen-8-ol – 0.2; p-menthen-4-ol – 2.2; X1 –

3.0; b-ionone – 19.6; nerolidol – 0.3; a-betulenal –2.1; thymol – 1.8; X2 – 1.6

References

1. C. Mateo, J. Calderon, J. Sanr, Phytochemistry 27, 151 (1988)

Sideritis arguta Boiss Ex Heldr.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.07–0.1

Main components, %: b-Caryophyllene – 10.0–20.0;b-phellandrene – 23.0; germacrene D – 14.0

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Lamiaceae 514 Sideritis argyrea P. H. Davis

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis argyrea P. H. Davis

Family: Lamiaceae

Aerial Part

Essential oil, % dry wt: 0.1–0.45 (endemic Turkey) [1]

Main components, %: b-Pinene – 7.0–20.0;

a-pinene – 3.0–14.0; epicubebol – 10.0–16.0 [1]b-Pinene – 24.0; a-pinene – 17.0; limonene – 18.0 [2]

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

2. N. Ezer, R. Vila, S. Canigueral, T. Adzet, Phytochemistry 41,

203 (1996)

Sideritis armeniaca Bornm.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.16–0.5

Main components, %: b-Pinene – 39.0–45.0;

a-pinene – 17.0–24.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis athoa Papanikolau Ex Kokkini

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.16–0.25

Main components, %: Myrcene – 19.0–39.0; b-pinene – 7.0–12.0; a-pinene – 4.0–7.0; ar-

curcumene – 7.0–12.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis athoa papanikolaou Kokkini.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 25.0

FAs

Composition (% GC/MS, Innowax): 12:0 � tr; 14:0

� tr; 15:0 � tr; 16:0 � 6.0; 16:1(7Z) � 0.1;

16:1(9Z) � 0.1; 17:0 � 0.1; 18:0 � 2.8; 18:1(9Z)

� 25.4; 18:1(9E)� 1.2; 18:2� 57.6; 18:1(6-yn)�4.5; 18:3� 1.3; 20:0� 0.2; 20:1� 0.5

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis bilgerana P. H. Davis.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.26

Main components (GC/MS, Innowax FSC), %:

b-Pinene – 34.0; a-pinene – 17.0;

b-Pinene – 0.51; a-pinene – 30.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004); M. Ozcan, J.C. Chalchat, A. Akgul,

Food Chem. 75, 459 (2001)

Sideritis brevibracteata P. H. Davis.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.06

Main components, %: b-Caryophyllene – 20.0;

naphthalene – 18.0

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Sideritis cilicica Boiss. and Ball. 515 Lamiaceae

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis brevidens P. H. Davis.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.5–0.7

Main components, %: b-Pinene – 14.0–22.0;

a-pinene – 8.0–16.0; epicubebol – 12.0–13.0

References

1. N. Kirimer, K.H.C. Baser, B. Demirci, H. Duman, Chem. Nat.

Comp. 40, 19 (2004)

Sideritis caesarea Duman.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 35.4

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�tr; 12:0� tr; 14:0 � 0.1; 15:0� 0.1; 16:0 � 6.6;

16:1(7Z)� 0.2; 16:1(9Z)� 0.1; 17:0� 0.1; 18:0

� 2.4; 18:1(9Z) � 18.5; 18:1(9E) � 0.9; 18:2 �55.0; 18:1(6-yn) � 12.9; 18:3� 1.6; 20:0 � 0.1;

20:1 � 0.5; 24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis cilicica Boiss. and Ball.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.55

Composition of essential oil (GC/MS, HP Innowax

FSC), %: Tricyclene � 0.1; a-pinene � 31.9;

a-thujene � tr; camphene � 0.3; b-pinene �48.4; sabinene� 1.7; d-3-carene� 0.1; myrcene

� 1.3; p-mentha � 1.7; (8)-diene

(¼pseudolimonene � tr; limonene � 2.4; b-phellandrene � 5.2; (E)-2-hexenal � tr; g-terpinene � tr; (E)-b-ocimene � tr; p-cymene

� 0.1; 2-methylbutyl-2-methylbutyrate � tr;

terpinolene � tr; 2-methylbutyl-isovalerate �0.1; 3-octanol � 0.1; nonanal � 0.1; 1-octen-3-

ol � 0.2; a-cubebene � tr; trans-sabinene

hydrate-0.1, a-copaene-0.1, (E,E)-2,4-

heptadienal-tr; b-bourbonene � 0.1; a-gurjunene � 0.1; linalool � 0.4; trans-p-menth-

2-en-1-ol � tr; linalyl acetate � tr; pinocarvone

� 0.1; bornyl acetate � 0.5; b-caryophyllene �0.4; myrtenal � 0.1; bornyl isobutyrate � tr;

trans-pinocarvyl acetate � tr; cis-verbenol � tr;

trans-pinocarveol� 0.3; (Z)-b-farnesene� tr; d-terpineol � tr; a-humulene � tr; trans-verbenol� 0.4; a-terpineol � 0.2; a-terpinyl acetate � tr;

borneol-tr; germacrene D � 0.1; bicyclosesqui-

phellandrene � tr; p-mentha-1.5-dien-8-ol � tr;

a-muurolene � tr; bicyclogermacrene � 0.2;

naphthalene � 0.1; d-cadinene � 0.2; (E)-a-bisabolene � tr; cadina-1,4-diene(¼cubenene)

� 0.1; myrtenol � 0.2; isobutyl benzoate � tr;

(E)-b-damascenone� tr; trans-carveol� tr; cis-

calamenene� 0.1; (E)-geranyl acetone� tr; epi-

cubebol � 0.1; 2-methylbutyl benzoate-tr, 3-

methylbutyl benzoate � tr; cubebol � 0.3;

caryophyllene oxide � 0.1; (E)-nerolidol � tr;

germacrene D 4-ol� tr; 1-epi-cubenol� tr; hexyl

benzoate � tr; viridiflor � tr; hexahydrofarnesyl

acetone-0.1, spathulenol-0.2, (Z)-3-hexenyl ben-zoate-tr, 3,4-dimethyl-5-penthylidene-2(5H)-

furanone � tr; eugenol � tr; t-muurolol � 1.0;

a-cadinol� 0.1; caryophylla-2(12),6(13)-dien-5a� ol (¼caryophylladienol II)� tr; kaur-15-ene�tr; hexadecanoic acid � 0.3

Activity: Antimicrobial activity, MIC, mg/mL:

Escherichia coli (NRRL B-3008)� 0.5; MRSA (Clin-

ical isolate) � 0.5; Enterobacter aerogenes (NRRL B-

3567)� 0.5; Salmonella typhimurium (NRRL B-4420)

� 0.25; Bacillus cereus (NRRL B-3711) � 0.125;

Staphylococcus epidermidis (ATCC 12228) � 0.125;

Candida albicans (clinical isolate) � 0.03; Standarts:

Chloramphenicol � 0.003 � 0.062; ketocona zole �0.03.

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Lamiaceae 516 Sideritis condensata Boiss. and Heldr. Apud Benth.

References

1. G. Iscan, M. Kirimer, M. Kurkcuoglu, K.H. Baser, Chem. Nat.

Comp. 41, 679 (2005)

Sideritis condensata Boiss. and Heldr.Apud Benth.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 19.5

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�tr; 12:0 � 0.1; 14:0 – tr, 15:0 � 0.1; 16:0 � 6.9;

16:1(7Z)� 0.2; 16:1(9Z)� 0.1; 17:0� 0.1; 18:0

� 3.8; 18:1(9Z) � 19.6; 18:1(9E) � 0.8; 18:2 �56.2; 18:1(6-yn) � 8.1; 18:3 � 1.1; 20:0 � 0.1;

20:1 � 0.4; 24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis congesta P. H. Davis Hub. – Mor.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 29.6

FAs

Composition (% GC/MS, Innowax): 8:0 � tr;

12:0 � tr; 14:0 � tr; 15:0 � tr; 16:0 � tr;

16:1(7Z) � 0.1; 16:1(9Z) � 0.1; 17:0 � 0.1;

18:0 � 3.1; 18:1(9Z) � 25.9; 18:1(9E) � 1.1;

18:2 � 53.8; 18:1(6-yn) � 6.1; 18:3 � 1.3; 20:0

� 0.1; 20:1 � 0.5; 22:0 � tr; 24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis dichotoma Huter.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 20.0

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�0.1; 12:0 � 0.1; 14:0 � 0.2; 15:0 � 0.1; 16:0 �7.1; 16:1(7Z) � 0.3; 16:1(9Z) � 0.1; 17:0 � 0.1;

18:0 � 2.5; 18:1(9Z) � 22.4; 18:1(9E) �0.8;

18:2 � 57.0; 18:1(6-yn) � 7.3; 18:3 � 1.4;

20:0 � tr; 20:1 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis erythrantha Boiss. var.cedretorum

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 20.0

FAs

Composition (% GC/MS, Innowax): 8:0� 0.1; 12:0

� tr; 14:0 � 0.1; 15:0 � 0.1; 16:0 � 8.7;

16:1(7Z) � 0.1; 16:1(9Z) � tr; 17:0 � 0.1; 18:0

– tr–3.6; 18:1(9Z) tr–21.6; 18:1(9E) � 0.8; 18:2

� 54.2; 18:1(6-yn) � 8.6; 18:3 � 1.4; 20:0 �0.1; 20:1 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis germanicopolitana subsp.germanicopolitana

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 27.0

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Sideritis niveotomentosa Hub.-Mor. 517 Lamiaceae

FAs

Composition (% GC/MS, Innowax): 9:0 � tr; 12:0

� tr; 14:0 � 0.1; 15:0 � tr; 16:0 � 5.1; 16:1(9Z)

� tr; 17:0 � 0.1; 18:0 � 2.3; 18:1(9Z) � 19.4;

18:1(9E) � 0.9; 18:2 � 64.0; 18:1(6-yn) � 5.9;

18:3 � 0.8; 20:0 � 0.1; 20:1 � 0.5

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis lanata L.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 25.0

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�tr; 12:0 � tr; 14:0 � 0.1; 15:0 � tr; 16:0 � 8.2;

16:1(7Z)� 0.1; 16:1(9Z)� 0.1; 17:0� 0.1; 18:0

� 3.2; 18:1(9Z) � 22.9; 18:1(9E) � 0.8; 18:2 �49.7; 18:1(6-yn) � 11.5; 18:3� 1.3; 20:0 � 0.2;

20:1 � 0.2; 22:0 � 0.1; 24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis libanotica Labill. ssp. violascens

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 36.3

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�tr; 12:0 � tr; 14:0 � tr�0.1; 15:0 � tr; 16:0 �8.0; 16:1(7Z) � 0.1; 16:1(9Z) � 0.1; 17:0 � 0.1;

18:0 � 2.5; 18:1(9Z) � 21.3; 18:1(9E) � 1.3;

18:2 � 53.6; 18:1(6-yn) � 9.1; 18:3 � 1.6; 20:0

� 0.1; 20:1 � 0.7; 22:0 – 0.1; 24:0 – tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis lycia Boiss. and Helder.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 18.0

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�0.2; 12:0 � 2.6; 14:0 � 0.7; 15:0 � 0.1; 16:0 �9.4; 16:1(7Z) � 0.2; 16:1(9Z) � 0.3; 16:2(9,12)

� tr; 17:0 � 0.1; 18:0 � 4.9; 18:1(9Z) – 20.3,

18:1(9E) � 1.0; 18:2 � 48.9; 18:1(6-yn) � 8.4;

18:3 � 1.0; 20:0 � 0.2; 20:1 � 0.3; 22:0 � 0.1;

24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis montana L.

Family: Lamiaceae

Sterols, % dry wt: 0.03

Terpenoids

Phytol, % dry wt: 0.04

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

Sideritis niveotomentosa Hub.-Mor.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 28.0

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Lamiaceae 518 Sideritis perfoliata L.

FAs

Composition (% GC/MS, Innowax): 8:0 � tr; 12:0

� tr; 14:0 � 0.1; 15:0 � tr; 16:0 � 6.9; 16:1(7Z)

� 0.1; 16:1(9Z) � 0.1; 16:2(9,12) � tr; 17:0 �0.1; 18:0 � 3.3; 18:1(9Z) � 24.8; 18:1(9E) �1.1; 18:2 � 52.6; 18:1(6-yn) � 7.6; 18:3 � 1.2;

20:0 � 0.1; 20:1 � 0.6; 24:0 � 0.1

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis perfoliata L.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 25.6

FAs

Composition (% GC/MS, Innowax): 8:0 � tr; 12:0

� tr; 14:0 � 0.1; 15:0 � tr; 16:0 � 7.0; 16:1(7Z)

� 0.1; 16:1(9Z) � 0.1; 17:0 � 0.1; 18:0 � 4.0;

18:1(9Z) � 24.5; 18:1(9E) � 1.2; 18:2 � 56.1;

18:1(6-yn)� 5.3; 18:3� 0.9; 20:0� 0.1; 20:1�0.3; 22:0 � tr; 24:0 � tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis phrygia Bornm.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 5.6

FAs

Composition (% GC/MS, Innowax): 8:0� tr; 9:0�tr; 12:0 � tr; 14:0 � 0.1; 15:0 � tr; 16:0 � 5.7;

16:1(7Z)� 0.1; 16:1(9Z)� 0.1; 17:0� 0.1; 18:0

� 3.0; 18:1(9Z) � 25.0; 18:1(9E) � 0.9; 18:2 �52.9; 18:1(6-yn) � 7.0; 18:3 � 1.3; 20:0 � 0.2;

20:1 � 0.6; 22:0 � 0.2; 24:0 � 0.2

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Sideritis pisidica Boiss. and Helder.

Family: Lamiaceae

Seed

Oil (hexane), % dry wt: 9.0

FAs

Composition (% GC/MS, Innowax): 12:0 � 24:0 �tr; 14:0 � 0.2; 15:0 � 0.2; 16:0 � 8.9; 16:1(7Z)

� tr; 16:1(9Z) � tr; 17:0 � 0.1; 18:0 � 2.4;

18:1(9Z) � 12.3; 18:1(9E) � 0.8; 18:2 � 45.4;

18:1(6-yn) � 26.8; 18:3 � 2.0; 20:0 � 0.1; 20:1

� tr

References

1. A. Ertan, N. Azcan, B. Demirci, K.H.C. Baser, Chem. Nat.

Comp. 37, 301 (2001)

Stachiopsis sp.

Family: Lamiaceae

Seed

Oil (hexane), %: 11.4 [1]

TAG

Main components (Colemann), mol %: LLeL – 0.2;

OLeL – 0.6; OLeO – 0.6; LLLe – 0.2; OLLe –

0.4; LLL – 3.1; OLL – 12.0; PLL – 0.8; OLO –

11.6; PLO – 1.6; PLP – 0.1; LOLe – 0.4; OOLe –

0.6; LOL – 7.1; OOL – 27.4; POL – 1.8; OOO –

26.7; POO – 3.4; LPL – 0.2; OPL – 0.6; OPO –

0.6; POP – 0.1[1]

Composition, mol %: SSU + USS – 0.0; USU – 1.4;

SUS – 0; UUS + SUU – 7.6; UUU – 90.8 [1]

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Stachys betoniciflora 519 Lamiaceae

FAs from TAG

Composition (GLC; 17% PEGS) %: 16:0 – 3.2;

16:1(9) – 0.4; 18:0 – tr; 18:1(9) – 64.0;

18:2(9;12) + 18:2(5;6) – 31.4; 18:3 – 1.0 [1]

Free FAs

Composition (GLC), %: 14:0 – 0.3; 16:0 – 12.3;

16:1 – tr; 17:0 – tr; 18:0 – 4.5; 18:1 – 52.2; 18:2 –

28.7; 18:3 – 0.4 [2]

References

1. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

2. G.A. Stepanenko, T.V. Khomova, S.D. Gusakova, A.U.

Umarov, Chem. Nat. Comp. 17, 326 (1981)

Stachys aleurites Boiss. and Heldr.

Family: Lamiaceae

Aerial Part

Essential oil (hydro distillation), % dry wt: 0.15

Composition (GC/MS, FFAP), %: (Z)-b-Caryophyllene – 31.60; a-humulene – 5.00;

germacrene D – 2.85; caryophyllene dioxide –

22.12; carvacrol – 5.0

References

1. G. Ozkan, R.S. Gokturk, O. Unal, S. Celik, Chem. Nat. Comp.

42, 141 (2006)

Stachys annua L.

Family: Lamiaceae

Seed

Oil, %: 26.79–36.69

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Stachys arvensis L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 38.0

n40D : 1.4693

Iodine value (Wijs), % J2: 130; 126 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

5.8; 18:0 – 3.3; 18:1 – 20; 18:2 – 52; 18:3 – 3.2;

others (4) – 3.0

Allenic acid (IR), %: 12.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys betoniciflora

Family: Lamiaceae

Seed

Oil (petroleum ether), % abs. dry wt: 24.1

d20: 0.9232

n20D : 1.4764

E: 14.29

Acid value, mg KOH: 6.69

Acetic value, mg KOH: 235.48

Content of hydroxyl group, %: 9.67

Hehner’s value, %: 94.94

Iodine value, % J2: 139.20

Saponification value, mg KOH: 1.8851

Unsaponifiables, %: 1.46

Phosphatides, %: 1.12

FAs

Iodine value, % J2: 143.0

Neutralization value, mg KOH: 214.15

Thiocyanogen value, %: 89.36

Composition (GLC, 17% PEGS), %: 9:0 � 0.17;

10:0 � 0.59; 12:0 � 0.46; 14:0 � 0.24; 16:0 �1.21; 16:1 � 0.91; 17:0 � 0.29; 18:1 � 25.96;

18:2 � 68.44; 18:3 � 1.73

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Lamiaceae 520 Stachys betoniciflora Rupr.

b-Carotene

Chlorophyll a

Alkane: n-C27

References

1. A.S. Akramova, S.D. Gusakova, A.U. Umarov, Chem. Nat.

Comp. 4, 217 (1968)

Stachys betoniciflora Rupr.

Family: Lamiaceae

Seed

Oil (hexane), %: 26.5

TAG

Main components (Colemamm), mol %: LLeLe –

1.4; OLeL – 0.4; OLeO – 0.1; OLLe – 0.4; LLLe

– 1.4; LLL – 32.3; OLL – 21.2; PLL – 2.2; OLO

– 3.5; PLO – 0.6; LOLe – 0.8; OOLe – 0.2; LOL

– 19.1; OOL – 12.6; POL – 1.2; OOO – 2.1; POO

– 0.4; LPL – 0.4; OPL – 0.2

Compositions, mol %: SSU +USS – 0.0; USU – 0.6;

SUS – 0.0; UUS + SUU – 4.5; UUU – 94.8

FAs from TAG

Composition (GLC, 17% PEGS), %: 16:0 – 1.3;

16:1(9) – tr; 18:0 – 0.5; 18:1(9) – 28.0;

18:2(9;12) + 18:2(5;6) – 68.8; 18:3 – 1.4

References

1. T.V. Panekina, S.D. Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Stachys cretica L. subsp. mersinaea

Family: Lamiaceae

Aerial part

Essential oil (hydro distillation), % dry wt: 0.15

Composition (GC/MS, FFAP), %: b-Bourbonene –1.05; (Z)-b-caryophyllene – 4.84; germacrene

D – 2.14; caryophyllene dioxide – 3.97;

humulene oxide – 1.36; a-сurcumene – 34.10;

tetradecanol – 6.27

References

1. G. Ozkan, R.S. Gokturk, O. Unal, S. Celik, Chem. Nat. Comp.

42, 141 (2006)

Stachys cretica Sibth and Sm.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 3.6

Oil (petroleum ether, 30–60�C), % dry wt: 29.0

n40D : 1.4688

Iodine value (Wijs), % J2: 135; 131 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

4.8; 18:0 – 2.1; 18:1 – 29; 18:2 – 59; 18:3 – 0.1;

others (4) – 1.3

Allenic acid (IR), %: 3.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys germanica L.

Family: Lamiaceae

Terpenoids

Components, %: b-Pinene – 15.5; a-pinene – 8.4;

cis-ocimene – 8.1; trans-b-farnesene – 7.0;

1.8-cineol – 6.0; germacrene D – 5.4; limonene

– 2.2; sabinene – 1.8; p-cymene – 1.6; myrcene –

0.9; a-terpineol – 0.7 (Guelph, Ontario) [1]

Page 133: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Stachys iberica Bieb. subsp. stenostachya (Boiss). Rech. fil. 521 Lamiaceae

Phytol, % dry wt: 0.04 [2]

Sterols, % dry wt: 0.06 [2]

Seed and Pericarp

Mass of 1,000, g: 1.3 [3]

Oil (petroleum ether, 30–60�C), % dry wt: 30.0 [3]

n40D : 1.4698 [3]

Iodine value (Wijs), % J2: 140; 140 (cald) [3]

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

4.2; 18:0 – 2.0; 18:1 – 19.0; 18:2 – 68.0; 18:3 –

0.8; others (4) – 0.4 [3]

Allenic acid (IR), %: 4.7 [3]

IR

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys hirta L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60�C), % dry wt: 32.0

n40D : 1.4681

Iodine value (Wijs), % J2: 124; 126 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

6.5; 18:0 – 3.0; 18:1 – 21; 18:2 – 55.0; 18:3 – 1.5;

others (6) – 1.6

Allenic acid (IR), %: 11.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys iberica Bieb. subsp. stenostachya(Boiss). Rech. fil.

Family: Lamiaceae

Aerial Part

Essential oil (hydro distillation), %: 0.08 (Turkey)

Composition (GC/MS, HP-Innowax FSC), %: a-Pinene – 0.02; b-pinene – 0.01; myrcene –

0.48; limonene – 0.15; 1,8-cineole – 0.02; (Z)-

b-ocimene – 0.64; g-terpinene – 0.01; (E)-b-ocimene – 0.56; p-cymene – 0.02; terpinolene –

0.13; tridecane – 0.02; hexanol – 0.04; 3-octanol

– 0.02; nonanal – 0.24; (E)-2-octenal – 0.02;

trans-linalool oxide (furanoid) – 0.03; 1-octen-

3-ol – 0.60; cis-linalool oxide (furanoid) – 0.04;

nerol oxide – 0.03; decanal – 0.03; b-bourbonene– 0.06; linalool – 18.86; linalyl acetate – 42.16;

nonyl acetate – 0.02; b-elemene – 0.06; terpinen-

4 – ol – 0.04; p-menth-1-en-9-ol – 0.03;

alloaromadendrene – 0.04; nonanol – 0.04; (Z)-

b-farnesene – 0.05; neral – 0.02; a-terpineol –5.27; a-terpinyl acetate – 0.10; germacrene D –

0.67; neryl acetate – 4.17; geranial – 0.09; b-bisabolene – 0.08; a-cadinene – 0.08; geranyl

acetate – 8.17; d-cadinene – 0.31; g-cadinene –

0.14; nerol – 1.53; (E)-b-damascenone – 0.16;

geraniol – 4.30; (E)-geranyl acetone – 0.07;

aplotaxene – 0.23; epi-cubebol – 0.03; (Z)-3-hexenyl nonanoate – 0.01; (E)- b-lonone –

0.09; 3,7-dimethyl-1,5-octadiene-3,7-diol –

0.04; caratol – 0.23; germacrene D-4-ol – 0.27;

b-oplopenone – 0.12; elemol – 0.09; viridiflorol

– 0.34; hexahydrofarnesyl acetone – 0.52;

tetradecanol – 0.14; T-cadinol – 0.17; thymol –

0.05; T-muurolol – 0.27; a-bisabolol – 0.13;

carvacrol – 0.18; a-eudesmol – 0.04; a-cadinol– 0.64; tricosane – 0.13; hexadecanol – 0.18;

pentacosane – 0.16; phytol – 0.86; heptacosane

– 0.43; nonacosane – 0.01; hexadecanoic acid –

1.01; total – 96.0

References

1. A. Kaya, B. Demirci, K.H.C. Baser, Chem. Nat. Comp. 37,

325 (2001)

Page 134: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 522 Stachys inflata Benth.

Stachys inflata Benth.

Family: Lamiaceae

Seed

Oil, %: 27.7 [1]

Iodine value, % J2:138.7

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 327 [in

Russian]

Stachys ionica

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/dry wt: 0.36–

0.38 (from air-dried plant material; Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): a-Thujene – 0.1; (+)a-pinene – tr –

0.4; sabinene – tr – 0.2; 1-octen-3-ol – 0.1; (+)b-pinene – 0.1; 3-octanol – tr – 0.1; octanal – tr; p-cymene – tr – 0.1; (+)limonene – 0.6–1.2; 1,8-

cineole – tr – 0.1; cis-ocimene – 0.1; phenylace-

taldehyde – tr; trans-ocimene – tr – 0.7; g-terpinene – tr; n-octanol – 0.3; terpinolene – tr;

trans-sabinene hydrate – tr; (+)-b – linalol – tr –

0.4; n-nonanal – tr – 0.3; (+)-a-terpineol – 0.2;

decanal – tr; (E)-2-decenal – tr; dec-9-en-1-ol –

0.1; n-decanol – tr; carvacrol – tr – 0.3; (2E,4E)-

2.4 – decadienal – tr; a-cubebene – 0.1; eugenol

– 0.1; cyclosativene – tr – 0.1; a-copaene – 0.3 –0.4; b-cubebene – 0.1; b-elemene – 0.2; g-gurjunene – 0.4; (+)(E)- caryophyllene – 0.3–

1.1; calarene – 0.1; a-humulene – 0.3;

allomadendrene – 1.2; g-muurolene – 0.4–0.7;

epi-bicyclo-sesquiphellandrene – 0.3–0.4; b-selinene – 0.3; valencene – 2.4–2.5; trans-b-guaiene – 1.3; b-himachalene – 0.7; a-muurolene – 1.4–2.0; cuparene – 0.1; (E,E)-a-farnesene – tr – 0.1; g-cadinene – 1.6–2.3; 7-epi-a-selinene – 1.5–1.6; d-cadinene – 4.7–6.3;

cadina-1.4-diene – 0.6; a-cadinene – 0.5–2.8; a-calacorene – tr – 0.1; selina-3,7-diene – 0.2–1.7;

elemol – 1.2–5.5; (E)-nerolidol – 14.3–14.9;

spathulenol – 7.2–8.0; viridiflorol – 0.5; epi-globulol – 1.8–3.6; 1-epi-cubenol – 0.1–1.0;

g-eudesmol 0.9 – 1.1; T-cadinol – 0.9 – 4.6;

epi-a-muurolol¼T-muurolol – 4.4; torreyol –

0.9 – 7.9; b-eudesmol – 0.5 – 1.5; a-eudesmol –

0.3; a-cadinol – 8.8–13.1; veleranone – 0.5–1.0;

heptadecene – 0.1; (E,E)-farnesol – 1.0–8.0; (E,

Z))-farnesol – 2.5; a-sinensal – 2.1–10.5;

sclarene – 6.0–7.0; manoyl oxide – 1.2–2.0; 13-

epi-manoyl oxide – 0.3–0.4; abietatriene – 0.1;

sclareol – tr – 0.1; total – 86.0–92.6

Monoterpenes, %: 0.6–2.7

Oxygenated monoterpenes, %: tr – 1.1

Sesquiterpene hydrocarbons, %: 15.9–21.5

Oxygenated sesquiterpenes, %: 55.4–60.1

Alcohols, %: tr – 0.5

Aldehydes, %: tr – 0.3

Diterpenoids, %: 8.6

Aromatics, %: 0.1

Alkanes and alkenes, %: 0.1

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235 (2001)

Stachys lanata

Family: Lamiaceae

Seed

Oil (petroleum ether, 30–60�C), % dry wt: 31.9

n40D : 1.4679

Iodine value (Wijs), % J2: 142.0

Saponification value, mg KOH: 189.0

FAs

Composition (20% Apiezon L), %: Saturated� 5.1;

18:1 � 24.0; 18:2 � 65.0; 18:3 � 0.6

References

1. F.R. Earle, E.H. Melvin, L.H. Mason, C.H. Van Etten, I.A.

Wolff, J. Am. Oil Chem. Soc. 36, 304 (1959)

Page 135: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Stachys pinardii Boiss. 523 Lamiaceae

Stachys lanata Jacq.

Family: Lamiaceae

Seed

Oil, %: 19.0–26.0 [1]

Iodine value, % J2:123.0–129.0

References

1. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Stachys melanii Petrov.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.8

Oil (petroleum ether, 30–60�C), % dry wt: 32.0

n40D : 1.4701

Iodine value (Wijs), % J2: 139; 140 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

2.0 – 18:0 – 0.4; 18:1 – 28.0; 18:2 – 54.0; 18:3 –

8.2; others (5) – 0.9

Allenic acid

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys olymrica Poir.

Family: Lamiaceae

Seed and Pericarp

Ash, %: 7.0

Mass of 1,000, g: 2.1

Oil, % dry wt: 31.9

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Stachys palustris L.

Family: Lamiaceae

Sterols, % dry wt: 0.07 [1]

Terpenoids

Phytol, % dry wt: 0.09 [1]

Seed

Oil, %: 38.0–44.0 [2]

Iodine value, % J2:134.1 [2]

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976) [in Russian]

2. N.I. Sharapov, Oil Plants and the Process of Oil Formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 347 [in

Russian]

Stachys pinardii Boiss.

Family: Lamiaceae

Aerial Part

Essential oil (hydrodistillation), % dry wt: 0.15

(endemic, Turkey)

Composition (GC/MS, FFAP), %: b-Bourbonene –0.65; alloaromadendrene – 2.05; a-humulene –

8.65; a-cubebene – 0.83; germacrene D – 6.04;

g-cadinene – 2.00; d-cadinene – 1.37;

caryophyllene oxide – 3.26; a-bisabolene –

3.01; caryophyllene dioxide – 22.15; humulene

oxide – 7.66; cedrandiol – 25.26; b-eudesmol –

1.24

References

1. G. Ozkan, R.S. Gokturk, O. Unal, S. Celik, Chem. Nat. Comp.

42, 141 (2006)

Page 136: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 524 Stachys recta L.

Stachys recta L.

Family: Lamiaceae

Sterols, % dry wt: 0.07

Terpenoids

Phytol, % dry wt: 0.08

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

Stachys schtschegleevii Sosn.

Family: Lamiaceae

Leaf

Essential oil (hydrodistillation), % dry wt: 0.2 (w/w)

(from air dried plant material, Iran)

Composition (GC, CP-Sil 5 CB, GC/MS, Rtx

1FSC), %: Tricyclene – 0.8; a-pinene – 36.4;

oct-1-en-3-ol – 0.4; sabinene – 0.4; b-pinene –

4.7; myrcene – 1.4; a-phellandrene – 0.6; d-3-carene – 1.1; a-terpinene – 0.1; p-cymene – 0.1;

limonene – 8.2; (Z)-b-ocimene – 0.6; g-terpinene– 0.4; terpinolene – 0.4; linalool – 0.5; menthone

– 0.1; a-terpineol – tr; pulegone – 0.5; piperitone– 6.2; thymol – 0.1; eugenol – 0.5; d-elemene –

0.1; farnesyl acetate – tr; a-copaene – 0.6; b-elemene – 0.7; b-cedrene – tr; b-caryophyllene– 0.1; b-gurjunene – tr; aromadendrene – 0.1; g-gurjunene – tr; g-curcumene – tr; isoitalicene –

1.3; germacrene D – 18.6; elemol – 1.4;

spathulenol – 1.1; b-eudesmol – 6.2; 4b-

hydroxygermacra-1(10),5-diene – 0.1; a-cadinol– 1.4; a-eudesmol – 1.1; total identified – 98.7

Activity: Antimicrobial activity of oil, inhibition

zone, mm: Enterococcus faecalis – 10.0; Staphylococ-cus aureus – 15.0; S. epidermidis – 12.0; Escherichia

coli – 8.0; Klebsiella pneumoniae – not active; Pseu-

domonas aeruginosa – in active.

a-Pinene: Enterococcus faecalis – in active; Staphy-

lococcus aureus – 7.0,;Staphylococcus epidermidis –

in active; Escherichia coli – 10.0; Klebsiellapneumoniae - in active; Pseudomonas aeruginosa –

in active.

Limonene: Enterococcus faecalis – 8.0; Staphylococ-cus aureus – 10.0; Staphylococcus epidermidis – in

active; Escherichia coli – 11.0; Klebsiella pneumoniae– in active; Pseudomonas aeruginosa – in active.

Ampicillin as standard: Enterococcus faecalis – 11.0;

Staphylococcus aureus – 13.0; Staphylococcusepidermidis – 12.0; Escherichia coli – 12.0; Klebsiella

pneumoniae – 12.0; Pseudomonas aeruginosa – 9.7

(Tested at a concentration of 15 m/disk).

References

1. A. Sonboli, P. Saehi, S.N. Ebrahimi, Chem. Nat. Comp. 41,

171 (2005)

Stachys spruneri

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation, % v/dry wt: 0.29–0.31

(from air-dried plant material; Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): a-Thujene – tr-3.3, (+) a-pinene –

0.2 – 8.0, camphene – tr – 0.1; sabinene – 0.3–

4.1; 1-octen-3-ol – 0.1–2.4; (+) b-pinene – tr –

1.3; b-myrcene – 0.1–0.7; 3-octanol – tr – 0.2; a-phellandrene – tr – 0.2; d-3-carene – 0.1; a-terpinene – 0.1–1.3; p-cymene – tr – 0.3; (+)-

limonene – 1.4–17.3; 1,8-cineole – 0.3; cis-

ocimene – 0.1–0.4; phenylacetaldehyde – 0.1;

trans-ocimene – tr – 1.3; g-terpinene – 0.3–2.3;

cis-sabinene hydrate – 0.1–1.5; n-octanol – tr –

0.2; terpinolene – 0.2–1.0; trans-sabinenehydrate – 0.1-0.5; (+)-b-linalol – 0.1-0.5; (-)-b-linalol – 0.1-0.4; n-nonanal – 0.1 – 0.5; trans-

thujone – tr; cis-p-2-menthen-1-ol – 0.1 – 0.4; a-campholenal – tr; allo-ocimene – 0.1; trans-

pinocarveol – tr; (+)-terpinen-4-ol – 1.5-3.3;

(-)-terpinen-4-ol – 0.5; p-cymen-8-ol – 0.1; (+)-

a-terpineol – 0.1–0.2; (-)-a-terpineol – 0.1–0.2;

methyl salicylate – tr – 0.1; cis-piperitol – 0.1;

decanal – tr – 0.1; b-cyclocitral – tr – 0.1; cis-carveol – tr; neral – tr; carvone – tr; (+)-linalyl

acetate – 0.1; (E)-2-decenal – tr – 0.2; dec-9-en-

1-ol – 0.2; geranial – tr; bornyl acetate – tr;

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Stachys swainsonii ssp. Ardolica (Boiss.) Phitos 525 Lamiaceae

(2E,4E)-2.4-decadienal – 0.1-0.2; iso-

dihydrocarvyl acetate – tr; trans-carvyl acetate– tr – 0.1; d-elemene – 0.8; a-terpinyl acetate –

0.7–1.4; eugenol – 0.5; (E)-2-undecenal – 0.1;

cis-carvyl acetate – 0.2; cyclosativene – 0.4–1.1;a-copaene – 2.5–4.7; b-bourbonene – 0.5-1.0; b-cubebene – 0.1; b-elemene – 1.2–5.1; cyperene –

tr; (Z)- caryophyllene – 0.1–0.6; dodecanal – tr –

0.3; g-cedrene – 0.1; g-gurjunene – 0.1–0.5;

(-)(E)- caryophyllene – 1.0; (+)(E)-caryophyllene – 8.5–15.0; calarene – 0.1-0.2; a-trans-bergamoten – tr – 1.1; aromadendrene – tr

– 1.0; a-humulene – 0.8–2.1; (E)-b-farnesene –

1.0–1.7; allomadendrene – 0.1-0.3; g-selinene0.1 – 1.0; g-muurolene – 0.4–0.5; epi-

bicyclo – sesquiphellandrene – 0.4–2.2;

cermacrene D – 0.2; (E)-b-ionone – 0.3; b-selinene – 0.3–1.0; cis-b-gualene – 1.5; a-selinene – 3.5–11.0; bicyclogermacrene – 4.5;

trans-b-guaiene – 0.3; a-muurolene – 0.3–1.2;

eremophilene – 1.6; germacrene A – 0.5–1.0; (E,

E)-a-farnesene – 0.2–0.4; g-cadinene – 0.7–1.6;

7-epi-a-selinene – 1.0; d-cadinene – 4.2–5.8;

cadina-1.4 – diene – 0.1–0.4; a-cadinene – tr –

0.2; a-calacorene – 0.1–0.2; elemol – 0.6; ledol –

0.4; caryophyllene alcohol – 0.6; (Z)-hexenyl

benzoate – 0.1–0.3; spathulenol – 3.9–7.4; b-copaen-4-a-ol – 0.7; (-)-caryophyllene oxide –

0.3–0.6; (+)-caryophyllene oxide – 1.2–3.0;

viridiflorol – 0.1–2.9; a-cedrol – 0.4-1.8; epi-

globulol – 0.7; T-cadinol – 0.7–1.0; epi-a-muurolol¼T-muurolol – 0.5–2.9; torreyol –

0.2–0.8; a-eudesmol – 1.2; a-cadinol – 0.2–3.5;

cadalene – 0.2–1.6; (Z)-nerolidol acetate – 0.8–

2.7; tetradecanol – 0.7; (Z)-a-santalol – 0.1; (Z;

E)-farnesol – 0.1; benzyl benzoate – 0.1–0.2;

tetradecanoic acid – 0.2; isopropyl myristate –

tr – 0.1; 6,10,14-trimethyl pentadecan-2-one –

0.2–0.6; hexadecanol – 0.1–0.2;

sandaracopimara – 8(14),15-diene – 0.9–5.8;

hexadecanoic acid – 0.1–0.8; isokaurene – 1.0;

manoyl oxide – 0.4–0.5; 13-epi- manoyl oxide –

1.6; abietatriene – 1.3–7.6; abietatdiene – 1.3;

dehydroabietal – 0.1–3.2, abieta-7,13-diene-3-

one – 1.3; trans-ferriginol – tr – 1.0; 4-epi-

dehydroabietol – 0.4–2.1; total – 85.1–94.4

Monoterpenes, %: 2.1–6.8

Oxygenated monoterpenes, %: 2.1–6.8

Sesquiterpene hydrocarbons, %: 37.7–40.0

Oxygenated sesquiterpenes, %: 5.5–16.0

Diterpenoids, %: 1.3–20.0

Aromatics, %: 0.1–0.5

Alkanes and alkenes, alcohols %: 0.1–3.1

Aldechydes, %: 0.5–1.3

Ketones, %: 0.1–0.6

Miscellaneous terpenoids, %: 0.3–3.5

FAs and aliphatic esters, %: 0.1–1.0

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235 (2001)

Stachys swainsonii ssp. Ardolica (Boiss.)Phitos

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/dry wt: 0.21–0.26

(from air-dried plant material; Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): a-Thujene – tr – 2.5, (+) a-pinene –

tr – 2.2, benzaldehyde – tr; sabinene – tr – 1.4; 1-

octen-3-ol – 0.2–2.1; (+) b-pinene – tr – 0.5; 6-

methyl-5-hepten-2-one – tr; b-myrcene – 0.11–

1.1; 3-octanol – 0.2; octanal – 0.1–0.5; a-phellandrene – 0.2; d-3-carene – 0.4; a-terpinene– tr – 0.1; p-cymene – 0.1–0.3; (+)-limonene –

0.5–4.0; b-phellandrene – 0.6; 1,8-cineole – 0.2–0.5; cis-ocimene – 0.1–4.1; phenylacetaldehyde

– 0.1; trans-ocimene – 0.2–1.0; g-terpinene –

0.2-0.9; cis-sabinene hydrate – 0.3–0.5;

n-octanol – 0.1–0.6; terpinolene – 0.4–3.1; 2-

nonanone - tr; trans-sabinene hydrate – 0.2;

(+)-b-linalol – 0.9–8.2; n-nonanal – 0.8–8.5;

p-mentha-1,3,8-triene – 0.1; trans-thujone – tr;

cis-p-2-menthen-1-ol – 0.1–0.3; a-campholenal

– 0.1; trans-pinocarveol – 0.2; trans-2-menthen-

1-ol – 0.1; camphor – tr.; 2,6-nonadienal – 0.1;

2–nonenal – 0.1-0.3; nonanol – 0.1; (+)-terpinen-

4-ol – 1.6–3.6; p-cymen-8-ol – 0.1; (+)-a-terpineol – 0.6–1.6; (-)-a-terpineol – 0.5–0.9;

methyl salicylate – 0.2; myrtenal – 0.3; myrtenol

– 0.1–0.5; decanal – 0.2; b-cyclocitral – 0.2–0.5;

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Lamiaceae 526 Stachys swainsonnii ssp. Melangavica D. Persson

carvone – 0.1; (+)-linalyl acetate – 2.5–5.1; (E)-2-

decenal – 0.2–2.5; n-decanol – tr; bornyl acetate –0.1; (2E,4E)-2.4-decadienal – 0.1; trans-

pinocarvyl acetate – 0.1; tridecane – 1.5; carvacrol

– 0.2–1.4; undecanal – 0.2; (2E,4E)-2.4-decadienal – 0.3; a-cubebene – 0.6–1.9; a-terpinylacetate – 0.6; 2-phenyl ethyl propanoate – 0.1;

eugenol – tr.; (E)-2-undecenal – 0.5–3.1;

cyclosativene – 1.7; a-copaene – 1.3–4.4; geranyl

acetate – 1.1–2.2; b-bourbonene – 1.6; b-cubebene– 0.3–0.4;b-elemene – 0.9–2.4; (Z)- caryophyllene

– 0.1–0.2; g-gurjunene – 0.2–0.4; (+) (E)-

caryophyllene – 7.8–16.3; calarene – 0.5; a-trans-bergamoten – tr – 0.2; aromadendrene – 0.2; g-neo-clovene – 0.1; a-humulene – 0.9–1.5; (E)-b –

farnesene – 1.1-2.6; allomadendrene – 0.3–0.7; b-acoradiene – 0.1; g-muurolene – 1.8–7.4; ar-

curcumene – 0.8–1.8; (E)-b-ionone – 0.7; b-selinene – 6.1; viridiflorene – 5.8; a-selinene –

4.1; bicyclogermacrene – 3.2; a-muurolene – 0.6;

eremophilene – 0.2; germacrene A – 0.4; (E,E)-a-farnesene – 0.2–1.5; a-dehydro-himachalene – 0.5;

g-cadinene – 0.3–0.8; d-cadinene – 1.3–6.5;

cadina-1.4-diene – 0.1; b-cerdanoxide – 0.3; a-calacorene – 0.1; elemol – tr – 0.3; (E)-nerolidol –0.4–0.7; ledol – 0.2; caryophyllene alcohol – 0.2;

(Z)-hexenyl benzoate – 0.1–0.3; spathulenol – 1.3–

4.4; (-)-caryophylleneoxide– tr; (+)-caryophyllene

oxide – 2.6–7.1; viridiflorol – 0.3; a-cedrol – 0.5–1.8; epi-a-muurolol¼t-muurolol – 1.1; torreyol –

1.6–1.7; a–cadinol – 0.8–1.5; tetradecanol – 0.3–

0.6; heptadecane – 0.1; pentadecanal – 0.1–0.3;

benzyl benzoate – 0.7; isopropyl myristate – 0.2;

6;10;14-trimethyl pentadecan-2-one – 0.5 – 0.7;

hexadecanol – 0.2; (E;E)-farnesyl acetone – 0.2;

methyl hexadecanoate – tr.; cembrene – 0.2;

pimaradiene – 0.3; neocembrene – 0.2;

sandaracopimara – 8(14);15-diene – 0.2;

hexadecanoic acid – 0.1 – 1.1; manoyl oxide –

0.4–0.5; 13-epi-manoyl oxide – 0.2-0.8; 13-epi-

manoyl oxide – 1.3–1.6; cembra-2,7,11-trien-4-ol

–2.6; abietatriene–1.4–3.4; octadecanol–0.2–1.0;

trans-phytol – 0.1–0.5; dehydroabietal – 0.2–0.5;

trans-ferriginol – 0.5; 4-epi-dehydroabietol – 0.1–

0.2; neoabietic acid – 0.2; total – 76.9.1–94.9

Monoterpenes, %: 3.0 – 22.6

Oxygenated monoterpenes, %: 6.1–15.6

Sesquiterpene hydrocarbons, %: 35.0–44.6

Oxygenated sesquiterpenes, %: 9.3–11.7

Diterpenoids, %: 2.9–7.5

Aromatics, %: 0.1–1.1

Terpene esters, %: 0.8–7.3

Alkanes and alkenes, %: 0.1–1.5

Alcohols, %: 1.4–4.2

Aldechydes, %: 1.5-–15.9

Ketones, %: 0.1–0.8

Miscellaneous terpenoids, %: 0.1–0.5

FAs and aliphatic esters, %: 0.2–1.3

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235 (2001)

Stachys swainsonnii ssp. MelangavicaD. Persson

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/dry wt: 0.23–

0.24 (from air-dried plant material, Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): (E)-2-Hexenal – 0.1-0.5; heptanal –

tr. – 0.1; a-thujene – 1.5–2.3; (E) heptenal – tr.;

(+) a-pinene – 1.1–2.7; camphene – tr; sabinene

– 1.4–1.5; 1-octen-3-ol – 0.5–1.9; (+) b-pinene –0.1–1.9; b-myrcene – 0.5–0.6; 3-octanol – tr –

0.1; a-phellandrene – 0.3–0.4; d-3-carene – 0.1;

a-terpinene – 0.3–0.4; p-cymene – tr – 0.3; (+)-

limonene – 0.4–4.4; cis-ocimene – tr; phenylace-

taldehyde – tr; trans-ocimene – tr – 1.0; cis-

sabinene hydrate – 0.2–1.5; n-octanol – 0.1–

0.3; terpinolene – tr – 1.7; trans-sabinene

hydrate – 0.2–0.4; (+)-b-linalol – 0.1–0.3; n-

nonanal – 0.2–0.6; trans-thujone – tr; cis-p-2-menthen-1-ol – 0.1–0.3; 3-acetoxy octane – tr;

a-campholenal – tr; camphor – tr; 2,6-

nonadienal – tr. – 0.1; 2-nonenal – tr – 0.2;

nonanol – tr; (+)-terpinen-4-ol – 0.2–3.5; (+)-a-terpineol – tr – 0.3; methyl salicylate – tr; cis-

piperitol – 0.1; decanal – 0.1–0.2; b-cyclocitral –0.1; (+) linalyl acetate – tr; (E)-2-decenal – 0.1;

geranial – tr; n-decanol – tr; bornyl acetate – tr;

carvacrol – 0.1; undecenal – tr – 0.1; (2E,4E)-2.4-decadienal – tr – 0.1; iso-dihydrocarvyl ace-

tate – 0.2; 0.1; a-cubebene – 0.3 – 0.7; a-terpinyl

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Stachys swainsonnii ssp. scyronica (Boiss) Phitos and Damboldt 527 Lamiaceae

acetate – 0.2; eugenol – tr – 0.1; (E)-2-undecenal –

0.2; cyclosativene – 1.5; a-copaene – 1.3 – 4.4; b-bourbonene – tr – 1.0; b-cubebene – 0.5 – 1.4; b-elemene – 0.7–18.8; dodecanal – 0.3; g-gurjunene– 1.0; g-cis-bergamoten – 0.1; (+)(E)-caryophyllene – 4.8–7.3; calarene – 0.1–0.5;

aromadendrene – 0.2–0.5; a-humulene – 0.7–

0.8; allomadendrene – 0.5–1.0; g-selinene – 0.5–

1.5; g-muurolene – 1.1–1.3; epi-bicyclo-

sesquiphellandrene – 1.2-2.0; germacrene D –

5.4; (E)-b-ionone – 0.2; b-selinene – 0.6–1.8;

viridiflorene – 4.6–10.6; bicyclogermacrene –

4.7–5.0; a-muurolene – 0.7–1.1; eremophilene –

0.2–8.1; (E,E)-a-farnesene – 0.3–4.2; g-cadinene– 1.6-2.9; d-cadinene – 3.7–13.7; cadina-1.4-

diene – 0.1–0.5; a-cadinene – tr – 0.3; a-calacorene – 0.3; (E)-nerolidol – 0.2; (Z)-hexenyl

benzoate – 0.2; germacrene – D-4-ol – 3.4;

spathulenol – 1.4–6.2; (+)-caryophyllene oxide –

1.0–2.6; viridiflorol – 0.2; epi-a-muurolol ¼ t-

muurolol – 1.5–3.5; torreyol – 0.3–0.5; b-eudesmol – 0.2–3.1; a-eudesmol – 5.4; a–cadinol– 0.1; b-bisabolol – 0.5; cadalene – 4.0;

heptadecene – 0.1; pentadecanal – 0.1; benzyl

benzoate – 0.2–0.4; isopropyl myristate – 0.1;

6,10,14-trimethyl pentadecan-2-one – 0.2–1.3;

hexadecanol – tr; (E,E)-farnesyl acetate – tr –

0.1; (E)-phytol – tr; hexadecanoic acid – 0.1–

1.1; manoyl oxide – 0.5–0.9; 13-epi-manoyl

oxide – 0.2–0.7; abietatriene – 0.4–1.0;

octadecanol – 0.1–1.6; dehydroabietal – 0.2–0.5;

4-epi-dehydroabietol – 0.2–0.3; total – 82.3–92.1

Monoterpenes, %: 0.8–17.5

Oxygenated monoterpenes, %: 0.6–4.4

Sesquiterpene hydrocarbons, %: 50.2–60.7

Oxygenated sesquiterpenes, %: 8.7–13.4

Terpene esters, %: tr – 0.3

Diterpenoids, %: 1.4–2.3

Aromatics, %: tr – 0.4

Alcohols, %: 1.3–2.4

Aldehydes, %: 0.5–2.0

Ketones, %: 0.2–1.4

Miscellaneous terpenoids, %: tr

FAs and aliphatic esters, %: tr – 0.6

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235 (2001)

Stachys swainsonnii ssp. scyronica (Boiss)Phitos and Damboldt

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/dry wt: 0.21

(from air-dried plant material; Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): a-Thujene – 0.7–1.9; (+) a-pinene –

0.3–1.0; camphene – tr; sabinene – 0.7–1.3; 1-

octen-3-ol – 1.7–2.1; (+) b-pinene – 0.2–0.3; b-myrcene – 0.4–0.5; 3-octanol – 0.2; a-phellandrene – 0.2–0.3; d-3-carene – 0.1; a-terpinene – 0.2–0.5; p-cymene – tr – 0.3; (+)-

limonene – 1.4; b-phellandrene – 1.4; 1.8-

cineole – 0.3; cis-ocimene – tr – 0.4; phenylace-

taldehyde – tr – 0.1; trans-ocimene – tr – 0.1; g-terpinene – 0.8–1.1; cis-sabinene hydrate – 0.6–

1.4; n-octanol – tr – 0.2; terpinolene – 0.2–0.3;

trans-sabinene hydrate – 0.3–0.5; (+)-b-linalol –tr – 0.2; n-nonanal – tr – 0.5; trans-thujone – tr;

cis-p-2-menthen-1-ol – tr – 0.3; 3-acetoxy octane

– tr; a-campholenal – tr; trans-p-2-methen-1-ol –

0.1; borneol – tr – 0.1; nonanol – 1.8–3.2; (+)-a-terpineol – 0.4; methyl salicylate – tr; cis-piperitol – tr – 0.1; decanal – 0.1; trans-carveol

– 0.1–0.2; neral – tr; carvone – tr; (E)-2-decenal

– tr – 0.1; dec-9-en-1-ol – 0.2; geranial – tr; n-decanol - tr; bornyl acetate – tr; (2E;4E)-2.4-

decadienal – tr; carvacrol – 0.1; undecanal – tr

– 0.1; (2E,4E)-2.4-decadienal – tr – 0.1; a-terpinyl acetate – tr – 0.7; eugenol – tr – 0.1;

cyclosativene – tr – 1.1; a-copaene – 0.8-4.6; b-cubebene – 0.4; b-elemene – 5.0–8.4; dodecanal

– 0.3; g-gurjunene – 0.5; (+)-(E)- caryophyllene

– 1.1-8.4; calarene – 0.1; a-trans-bergamoten –

1.1; aromadendrene – tr; a-humulene – 0.5–1.1;

(E)-b-farnesene – 1.6; allomadendrene – 0.2–

1.2; g-muurolene – 0.7–0.9; epi-bicyclo-

sesquiphellandrene – 0.4–2.0; b-selinene – 0.6–

0.7; cis-b-guaiene – 3.4; viridiflorene – 7.3;

bicyclogermacrene – 1.9; a-muurolene – 1.9–

2.3; eremophilene – 1.6–2.8; (E;E)-a-farnesene– tr – 1.2; g-cadinene – 2.8; 7-epi-a-selinene –

1.4; d-cadinene – 5.7–8.5; cadina-1.4-diene –

0.2–0.7; a-cadinene – 0.3–0.5; (E)-nerolidol –0.3–0.4; spathulenol – tr – 2.6; (-)-caryophyllene

oxide – tr; (+)-caryophyllene oxide – 2.4–16.3;

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Lamiaceae 528 Stachys swainsonii ssp. swainsonii

globulol – 0.6–1.8; viridiflorol – 0.2–0.5; a-cedrol – 1.8; 1-epi-cubenol – 1.0; epi-a-muurolol¼t-muurolol – 2.1-7.4; torreyol – 0.2–

1.1; a–cadinol – 1.0–9.9; tetradecanol – 2.7;

benzyl benzoate – 0.2–0.3; isopropyl myristate

– 0.1; 6;10;14-trimethyl pentadecan-2-one –

0.1–0.6; hexadecanol – 0.1; (E,E)-farnesyl ace-tone – tr; selarene – 5.7; hexadecanoic acid – 0.5;

manoyl oxide – 0.1–0.5; abietatriene – 0.2–2.4;

octadecanol – 0.2–0.5; trans-phytol – 0.6; ethyl

octadecanoate – 0.7; sclareol – tr – 0.1;

dehydroabietal – 0.1–1.4; 4-epi-dehydroabietol

– 0.1–0.7; total – 88.4–94.3

Monoterpenes, %: 7.7–9.5

Oxygenated monoterpenes, %: 2.3–4.9

Sesquiterpene hydrocarbons, %: 40.9–43.1

Oxygenated sesquiterpenes, %: 14.1–36.0

Diterpenoids, %: 0.4–10.7

Aromatics, %: tr – 0.1

Terpene esters, %: 0.3–0.9

Alcohols, %: 2.3–5.8

Aldechydes, %: 0.2–1.0

Ketones, %: 0.2–0.5

Miscellaneous terpenoids, %: 0.6

FAs and aliphatic esters, %: tr – 1.2

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235–244 (2001)

Stachys swainsonii ssp. swainsonii

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation), % v/drywt: 0.16–0.20

(from air-dried plant material; Greece)

Composition (GC/MS, HP-5 MS, HP-Innowax

Cydex B): Hexanal – tr; (E)-2-hexenal – tr –

0.7; (Z)-3- hexenol – tr; heptanal – tr; a-thujene– 0.6; (+) a-pinene – 1.8; camphene – tr;

sabinene – tr – 0.5; 1-octen-3-ol – 0.5–4.3; (+)

b-pinene – 0.1–1.7; 3-octanone – tr; b-myrcene –

tr; 3-octanol – tr; a-phellandrene – tr – 0.2;

a-terpinene – tr; p-cymene – tr – 0.2; (+)-

limonene – 0.2–0.9; b-phellandrene – 0.2; 1.8-

cineole – tr – 0.2; cis-ocimene – 0.8–4.7;

phenylacetaldehyde – tr – 0.1; trans-ocimene –

0.1–0.6; g-terpinene – 0.1–0.3; cis-sabinenehydrate – 0.1-0.5; n-octanol – tr – 0.1;

terpinolene – tr; (+)-b-linalol – 0.2–0.4; n-nonanal – 0.1–0.2; p-mentha-1,3,8-triene – tr;

a-campholenal – tr; allo-ocimene – tr – 0.1;

trans-pinocarveol – tr – 0.1; 2,6-nonadienal –

tr; 2-nonenal – tr; borneol – tr; (+)-terpinen-4-

ol – 0.2–2.1; (-)-terpinen-4-ol – 0.2; cymen-8-ol

– tr; (+)-a-terpineol – tr – 0.3; methyl salicylate –

tr; myrtenal – tr; myrtenol – tr; decanal – 0.1;

trans-carveol – 0.1 – 0.2; b-cyclocitral – 0.1–0.2;myrthenyl acetate – 0.2; pulegone – tr; neral – tr.;

carvone – tr; (E)-2-decenal – tr – 0.1; geranial –

tr; n-decanol – tr; bornyl acetate – tr; (2E,4E)-

2.4-decadienal – 0.1–0.2; thymol – tr; trans-pinocarvyl acetate – 0.1; tridecane – 0.1;

undecanal – tr – 0.3; cis-pinocarvyl acetate – tr;

(2E,4E)-2.4-decadienal – tr; trans-carvyl acetate– tr; d-elemene – 0.1–0.2; a-cubebene – tr – 0.2;a-terpinyl acetate – tr; eugenol – tr – 0.1.;

cyclosativene – tr – 0.6; a-ylangene – tr;

undecanol – 0.4; a-copaene – 0.6-2.8; b-bourbonene – 0.4; b-cubebene – 0.3; b-elemene

– 0.3 – 2.2; b-longipinene – tr – 0.1; (Z)-caryophyllene – 0.1; dodecanal – 1.0–3.4; g-cedrene – tr; g-gurjunene – tr – 0.4; (+)-(E)-

caryophyllene – 7.8–12.8; cis-thujopsene – tr;

calarene – tr – 0.2; a-trans-bergamoten – tr –

0.6; aromadendrene – 0.2; g-guaiene – 0.1; a-humulene – 0.9–1.4; (E)-b-farnesene – 0.1 – 0.2;allomadendrene – 0.1–0.4; b-acoradiene – tr –

0.2; g-selinene – 0.1–0.3; g-muurolene – tr – 0.4;

epi-bicyclo-sesquiphellandrene – 2.6–5.6; ar-

curcumene – 0.7–3.6; (E)-b-ionone – 0.2–0.5;

1-pentadecene – 0.2; viridiflorene – 3.7–4.7; a-selinene – 0.2–5.4; bicyclogermacrene – 0.9; a-muurolene – 0.3–0.4; eremophilene – 0.2–0.8;

cuparene – 0.1; (E,E)-a-farnesene – 0.6–1.2; g-cadinene – 0.3–1.0; d-cadinene – 0.7–3.6;

cadina-1.4-diene – tr – 0.2; a-cadinene – tr –

0.1; a-calacorene – 0.2; elemol – 0.2; (E)-

nerolidol – tr – 0.5; dodecanoic acid – 0.1; (Z)-hexenyl benzoate – 0.3–0.5; n-tridecanol – 0.2;

spathulenol – 6.3–7.8; (-)-caryophyllene oxide

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Stachys viticina Boiss. 529 Lamiaceae

– tr – 3.4; (+)-caryophyllene oxide – 6.5–15.5;

viridiflorol – 8.9–11.4; epi-a-muurolol¼T-

muurolol – 0.5–1.1; torreyol – 0.2; b-eudesmol

– 0.2–0.4; b-eudesmol – 0.5–0.8; a–cadinol –0.2–0.7; b-bisabolol – 0.6; (Z)-a-santalol – 0.2;

heptadecane – 0.2; pentadecanal – tr – 0.3; (Z,E)-

farnesol – 0.1–2.9; benzyl benzoate – 0.7–1.1; 1-

octadecene – 0.1; (Z,E)–farnesyl acetate – 1.1-

4.0; 6,10,14-trimethyl pentadecan-2-one – 0.6–

0.9; hexadecanol – 0.3; iso-pimar-9(11),15-

diene – 0.2–0.8; (E,E)-farnesyl acetone – 0.2;

methyl hexadecanoate – tr; cembrene – 0.2;

hexadecanoic acid – 1.6–5.9; manoyl oxide –

0.7–7.7; 13-epi- manoyl oxide – 0.9; abietatriene

– 1.4–2.1; octadecanol – 0.9–1.4; methyl

octadecanoate – 0.2; (Z)-9-octadecanoic acid –

2.8; octadecanoic acid – 0.3–0.5; tricosane – 0.2–

0.3; neoabietic acid – 0.3–0.4; total – 83.6–89.9

Monoterpenes, %: 1.6–11.4

Oxygenated monoterpenes, %: 0.9–3.1

Sesquiterpene hydrocarbons, %: 23.8–33.7

Oxygenated sesquiterpenes, %: 25.0–27.5

Diterpenoids, %: 3.7–10.9

Aromatics, %: 1.0–1.6

Terpene esters, %: 1.1–4.1

Alkanes and alkenes, %: 0.4–1.1

Alcohols, %: 2.1–5.8

Aldehydes, %: 1.6–4.1

Ketones, %: tr – 1.1

FAs and aliphatic esters, %: 0.3–9.6

References

1. H.D. Skaltsa, A. Mavrommati, T. Constantinidis, Phytochem-

istry 57, 235–244 (2001)

Stachys sylvatica L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 22.0 [1]

n40D : 1.4696 [1]

Iodine value (Wijs), % J2: 128; 132 (cald) [1]; 151.5

[2]

FAs

Composition (GLC), %: 16:0 – 6.3; 18:0 – 2.8; 18:1

– 23; 18:2 – 52; 18:3 – 6.6; others (5) – 2.4 (20%

LAC – 2R 446 [1]

16:0 – 3.9; 18:0 – 1.5; 18:1 – 22.3; 18:2 – 65.1; 18:3

– 7.2 (mol %, 10% PEGA) [2]

Allenic acid (IR), %: 6.2 [1]

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32 (1971)

Stachys thirkei C. Koch.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.5

Oil (petroleum ether, 30–60�C), % dry wt: 29.0

n40D : 1.4692

Iodine value (Wijs), % J2: 137; 138 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

4.2; 18:0 – 3.3; 18:1 – 20; 18:2 – 67; 18:3 – 0.4;

others (3) – 1.2

Allenic acid (IR), %: 4.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Stachys viticina Boiss.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.3

Oil (petroleum ether, 30–60�C), % dry wt: 31.0

n40D : 1.4682

Iodine value (Wijs), % J2: 126; 127 (cald)

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Lamiaceae 530 Tetradea corulteria

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.8; 18:0 – 3.1; 18:1 – 27.0; 18:2 – 57.0; 18:3 –

0.4; others (4) – 1.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Tetradea corulteria

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 5.4

Oil, % dry wt: 8.4

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Tetradea corulteria Gray.

Family: Lamiaceae

Seed and Pericarp

Oil (petroleum ether, 30–60�C)Iodine value (Wijs), % J2: 110; 109 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

9.2; 18:0 – 3.5; 18:1(9) – 48.0; 18:2(9;12) – 32.0;

18:3(9;12;15) – 3.9; others (10) – 3.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium almeriense C.E. Hubb & Sandw.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.6

Oil (petroleum ether, 30–60�C), % dry wt: 13.0

n40D : 1.4737

Iodine value (Wijs), % J2: 176; 176 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.0; 18:0 – 2.6; 18:1(9) – 14.0; 18:2(9;12) – 37.0;

18:3(9,12,15) – 23.0; others (6) – 17.0

trans-FAs (IR, methyl esters), %: 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium canadensis L.

Family: Lamiaceae

Plant Material

Terpenoids

Composition, %: Germacrene D – 2.7;

caryophyllene – 13.6; d-cadinene – 13.0; a-humulene – 10.2; linalool – 6.0; copaene – 2.2;

1-octen-3-ol – 0.7

References

1. B.M. Lawrence, J.W. Hogg, S.J. Terhune, J.K. Morton, L.S.

Gill, Phytochemistry 11, 2636 (1972)

Teucrium capitalum L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

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Teucrium depressum Small. 531 Lamiaceae

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

n40D : 1.4732

Iodine value (Wijs), % J2: 175; 173 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.1; 18:0 – 2.7; 18:1(9) – 14.0; 18:2(9;12) – 34.0;

18:3(9;12;15) – 25.0; others (7) – 16.0

trans-FAs (IR, methyl esters), %: 3.8

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium chamaedrus L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4

Oil (petroleum ether, 30–60�C), % dry wt: 10.0

n40D : 1.4753

Iodine value (Wijs), % J2: 176, 172 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.6; 18:0 – 2.9; 18:1(9) – 20.0; 18:2(9,12) – 32.0;

18:3(9,12,15) – 33.0; others (4) – 5.7

trans-FAs (IR, methyl esters), %: 1.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium creticum L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 3.0

Oil (petroleum ether, 30–60�C), % dry wt: 23.4

n40D : 1.4700

Iodine value (Wijs), % J2: 142; 143 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.7; 18:0 – 1.8; 18:1 – 30.0; 18:2 – 43.0; 18:3 –

0.4; others (3) – 18.0

trans-Unsaturated FAs (IR, methyl esters), %: 5.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium cubense Jacq. ssp. Laevigatum

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.7

Oil (petroleum ether, 30–60�C), % dry wt: 15.0

n40D : 1.4704

Iodine value (Wijs), % J2: 140; 142 (cald)

FAs

Composition (GLC, 20% LAC-2R 446); %: 16:0 –

7.8; 18:0 – 4.0; 18:1 – 26.0; 18:2 – 45.0; 18:3 –

1.0; others (6) – 7.0

trans-Unsaturated FAs (IR, methyl esters), %:5.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium depressum Small.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4707

Iodine value (Wijs), % J2: 138; 139 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.9; 18:0 – 4.3; 18:1 – 22.0; 18:2 – 52.0; 18:3 –

0.8; others (8) – 13.0

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Lamiaceae 532 Teucrium expansum

trans-Unsaturated FAs (Ag+-TLC), %: 5.3

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium expansum

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.9

Oil (petroleum ether, 30–60�C), % dry wt: 16.0

n40D : 1.4740

Iodine value (Wijs), % J2: 178; 171 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.3; 18:0 – 2.3; 18:1 – 16.0; 18:2 – 32.0; 18:3 –

29.0; others (8) – 16.0

trans-Unsaturated FAs (Ag+-TLC), %: 3.6

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium flavum L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.6

Oil (petroleum ether, 30–60�C), % dry wt: 11.0

n40D : 1.4733

Iodine value (Wijs), % J2: 166; 165 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.9; 18:0 – 3.0; 18:1 – 22.0; 18:2 – 27.0; 18:3 –

34.0; others (7) – 7.0

trans-Unsaturated FAs (Ag+-TLC), %: 2.5

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium fruticans L.

Family: Lamiaceae

Aerial Part

Terpenoic acids: Ursolic and oleanoic (3:1)

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

Teucrium gnaphalodes Vahl.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 2.6

Oil (petroleum ether, 30–60�C), % dry wt: 13.0

n40D : 1.4737

Iodine value (Wijs), % J2: 177; 179 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.6; 18:0 – 1.8; 18:1 – 16.0; 18:2 – 34.0; 18:3 –

30.0; others (5) – 13.0

trans-Unsaturated FAs (Ag+-TLC), %: 3.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

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Teucrium pseudochamaepitus L. 533 Lamiaceae

Teucrium jailae Juz.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 190.3 (cald)

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 – 4.8;

18:0 – 1.8; 18:1 – 16.6; 18:2 – 45.2; 18:3 – 31.6

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Teucrium marum L.

Family: Lamiaceae

Aerial Part

Terpenoic acids: Ursolic, oleanoic, and micrometric

(small)

References

1. S. Passannanti, M. Paternostro, F. Piozzi, Phytochemistry 22,

1044 (1983)

Teucrium nuchense C. Koch.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 190.7 (cald)

FAs

Composition (GLC, 10%PEGA), mol%: 16:0 – 6.8;

18:0 – 2.2; 18:1 – 17.2; 18:2 – 36.7; 18:3 – 37.1

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Teucrium polium L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.4 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 11.0 [1]

n40D : 1.4726 [1]

Iodine value (Wijs), % J2: 172; 167 (cald) [1]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.7; 18:0 – 2.7; 18:1 – 18.0; 18:2 – 35.0; 18:3 –

21.0; others (6) – 16.0 [1]

trans-Unsaturated FAs (Ag+-TLC), %: 4.5 [1]

IR [1]

Plant Material

Terpenoids

Phytol, % dry wt: 0.07 [2]

Sterols, % dry wt: 0.09 [2]

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

Teucrium pseudochamaepitus L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 7.5

Oil (petroleum ether, 30–60�C), % dry wt: 10.0

n40D : 1.4684

Iodine value (Wijs), % J2: 125; 124 (cald)

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Lamiaceae 534 Teucrium scordioides Schreb.

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

8.8; 18:0 – 4.0; 18:1 – 37.0; 18:2 – 41.0; 18:3 –

0.6; others (5) – 8.7

trans-Unsaturated FAs (Ag+-TLC), %: 2.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium scordioides Schreb.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.4

Oil (petroleum ether, 30–60�C), % dry wt: 19.0

n40D : 1.4727

Iodine value (Wijs), % J2: 169; 165 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.3; 18:0 – 3.3; 18:1 – 14.0; 18:2 – 50.0; 18:3 –

24.0; others (5) – 2.8

trans-Unsaturated FAs (Ag+-TLC), %: 2.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Teucrium scorodonia L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.4

Oil (petroleum ether, 30–60�C), % dry wt: 13.0

n40D : 1.4746

Iodine value (Wijs), % J2: 186; 178 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

6.1; 18:0 – 3.5; 18:1 – 18.0; 18:2 – 27.0; 18:3 –

39.0; others (3) – 6.8

trans-Unsaturated FAs (Ag+-TLC), %: 2.9

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Thymbra spicata L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 3.4

Oil (petroleum ether, 30–60�C), % dry wt: 6.4

n40D : 1.4740

Iodine value (Wijs), % J2: 186; 193 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.2; 18:0 – 2.5; 18:1 – 12.0; 18:2 – 22.0; 18:3 –

55.0; others (3) – 0.9

Allenic acid

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Thymus argaeus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), % dry wt: 0.8–1.3

Main components (GС, Thermon-600 T, GC/MS),

%: Linalyl acetate – 45.0–66.0; linalool – 10.0–

15.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

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Thymus chaubardii B. & H&B. 535 Lamiaceae

Thymus atticus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1 (1);

0.6 (2)

Main components (GС, Thermon-600 T, GC/MS),

%: Caryophyllene oxide + terpinen-4-ol (1); thy-

mol – 38.0; p-cymene – 10.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus bornmuelleri

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.7

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 45.0; p-cymene – 13.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus cariensis

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.2–0.4

Main components (GС, Thermon-600 T, GC/MS),

%: Borneol – 13.0–19.0; 1,8-cineole – 10.0–

13.0; a-pinene – 12.0; camphor – 8.0–9.0;

a-pinene – 17.0; 1,8-cineole – 10.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus chankoanus Klok.

Synonyms

Thymus mandschuricus Ronn.

Family: Lamiaceae

Inflorescence

Essential oil, % dry wt: 1.1

Leaf

Essential oil, % dry wt: 0.8

Use: The essential oil may be used in perfume, med-

icine, and food.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 139 [in

Russian]

Thymus chaubardii B. & H&B.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.3

Oil, %: 38 (petroleum ether, 30–60�C, in the Butt

apparatus)

n40D : 1.4823

Iodine value (Wijs), % J2: 191; 188 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

5.3; 18:0 – 2.8; 18:1 – 13; 18:2 – 17; 18:3 – 56;

others (6) – 6.2

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

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Lamiaceae 536 Thymus cilicicus

Thymus cilicicus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.5

Main components (GС, Thermon-600 T, GC/MS),

%: a-Pinene – 17.0; 1,8-cineole – 10.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus comptus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.8 (1);

1.0 (2)

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 36.0 (1); thymol – 50.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus dimorphus Klok. Et Shost.(Hybrid of Th. marschallianus Willd andTh. calcareous Klok et Shost)

Family: Lamiaceae

Essential oil (hydro distillation), %: 2.0

Composition (GC/MS, HP 20M and SE 30), %:

Carpic acid methyl ester – 0.1; b-phellandrene– 0.1; a-thujene – 0.2; a-pinene – 2.0; camphene

– 0.8; sabinene – 1.6; b-myrcene – 8.5; mono-

terpene – 1.3; 1-phellandrene – 0.2; 1,8-cineole –

6.5; limonene – 6.5; cis- b – ocimene – 0.3;

trans-b-ocimene – 2.2; g-terpinene – 1.1;

trans-sabinene hydrate – 0.1; dimethyl-sturene

– 0.1?; a-terpinolene – 0.2; trans-ocimene – 0.2;

camphor – 0.9; cyclo-hexa-1,4-diene; 3,4-

ethenyl; 1,2-dimethyl – 0.3; endo-borneol –

1.0; 4-erpineol – 1.0; 1-a-terpineol – 0.5; carveol– 0.01; terpinen-?-ol-0.01; thymol methyl esters

– 0.1; carvacrol – 11.7; thymol – 1.1; a-cubebene– 0.1; a-ylangene – 0.2; sesquiterpene – 0.6; b-bourbonene – 1.0; b-elemene – 0.6; a-gurjunene– 0.2; trans-caryophyllene – 3.5; epi-bicyclo –

sesquiphellandrene – 0.5; b-gurjunene – 0.1;

alloaromadendrene – 0.4; sesquiterpene – 0.4;

cyclo-iso-longipholene – 1.5?; b-guajen – 2.5;

sesquiterpenol ester – 0.2; b-farnesene – 0.5; d-cadinene – 4.9; g-cadinene – 1.5; b-cubebene –

0.6; g-elemene – 2.2; a-muurolene – 1.5; ?-

cadinene – 0.3; g-muurolene – 3.1; ?-cadinene

– 4.4; a-cubebene – 0.4; g-muurolene – 1.8; a-humulene – 1.0; dihydroaromadendrene – 0.3;

nerolidol – 4.1; p-menth-3-en-9-ol – 0.4;

sesquiterpenol – 0.5; sesquiterpenol – 0.4;

torreol – 0.3; sesquiterpen-?-ol – 0.4; d-cadinene– 0.9; terpen-?-ol – 2.0; terpen-?-O-CO-R – 0.3;

sesquiterpen-?-ol – 2.4; a-guajen – 0.4; a-costol– 0.2; terpen-O-CO-R – 0.2; sesquiterpen-?-ol –

2.9; sesquiterpen (di-Rr) – 0.5; 9;10-dihydro-iso-

longifolen-?-ol – 0.2; terpinen-?-ol – 0.2; burden

– 0.03; sesquiterpen-?-ol – 0.1; sesquiterpen-?-ol

– 0.1; cis- a-copaene-8-ol – 0.3; 9-aristolene-1-

ol –0.2; sesquiterpen-?-ol – 0.2

References

1. A.B. Prikhod’ko, N.A. Klyuev, S.V. Volkovich, T.I. Emefs,

V.V. Petrenko, E.V. Dolya, Chem. Nat. Comp. 35, 46

(1999)

Thymus eigii

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.2–1.8

Main components (GС, Thermon-600 T, GC/MS),

%: Carvacrol - 30.0–65.0

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Thymus kotschyanus var. kotschyanus 537 Lamiaceae

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus haussknechtii

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.05–0.5

Main components (GС, Thermon-600 T, GC/MS),

%: Linalool – 5.0–20.0; caryophyllene oxide –

7.0–12.0; borneol – 10.0–11.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus Komarovii Serg.

Family: Lamiaceae

Inflorescence

Essential oil, % dry wt: 0.41

Leaf

Essential oil, % dry wt: 0.48

Use: The aerial part may be used in food, and the

essential oil may be used in perfume.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 141 [in

Russian]

Thymus kotschyanus var. eriophorus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.9

Main components (GС, Thermon-600 T, GC/MS),

%: Carvacrol – 28.0; thymol – 18.0; p-cymene –

15.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus kotschyanus var. glabrescens

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.5 (1); 1.9

(2)

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 45.0; p-cymene – 18.0 (1); carva-

crol – 53.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus kotschyanus var. kotschyanus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.9

Main components (GС, Thermon-600 T, GC/MS),

%: Carvacrol – 60.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

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Lamiaceae 538 Thymus leucostomus var. argillaceus

Thymus leucostomus var. argillaceus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.6–1.0

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 16.0–35.0; carvacrol – 15.0–26.0;

borneol – 12.0–24.0; p-cymene – 11.0–145.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus leucostomus var. leucostomus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.5

Main components (GС, Thermon-600 T, GC/MS),

%: Carvacrol – 22.0; p-cymene – 18.0; thymol –

14.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus longicaulis ssp. longicaulis var.longicaulis

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.7 (1); 0.8

(2); 0.3 (3)

Main components (GС, Thermon-600 T, GC/MS),

%: a-Terpinyl acetate – 82.0 (1); geraniol – 69.0;geranyl acetate – 16.0 (2); thymol – 53.0 – 57.0

(1); thymol – 26.0; p-cymene – 48.0 (3)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus longicaulis ssp. longicaulis var.subisophyllus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1–2.1

(1); 1.3–1.7 (2)

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 21.0–57.0 (1); thymol – 26.0; car-

vacrol – 26.0; g – terpinene – 14 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus magnus

Family: Lamiaceae

Flowers and Leaves (1:1)

Essential oil (steam distillation)

Composition of essential oil (GC/MS, HP 1 and HP

Innowax): a-Thujene � 1.5; a-pinene � 3.5;

camphene � 2.3; sabinene � 1.1; b-pinene �0.9; myrcene � 1.2; a-phellandrene � 0.3;

d-carene � 0.8; a-terpinene � 1.8; p-cymene �5.5; limonene � 0.9; cis-ocimene � 0.5;

g-terpinene � 9.9; sabinene hydrate � 0.9; 1-

octen-3-ol � 1.6; terpinolene � 0.7; linalool �tr; camphor � 5.0; borneol � 3.8; terpinen-4-ol

� 1.6; 4-allylanisol � tr; carvone � 0.5; thymol

� 39.8; carvacrol � 3.6; thymol acetate � 1.4;

b-caryophyllene � 4.7; a-humulene � 0.6;

b-farnesene � 0.9; germacrene D � 0.2;

b-bisabolene � 2.8; b-sesquiphellandrene �0.5; a-bisabolene � 0.3; total – 99.3

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Thymus praecox ssp. arcticus (E. Durand) Jalas 539 Lamiaceae

Activity: Antifungal activities of essential oil, MICs

and MFCs, mg/mL: 0.19–0.39 and 0.19–0.78

(Aspergillus niger, A. flavus, Candida albicans, C.

utilis, Cryptococcus neoformans, Trichosporonmucoides, Trichophyton rubrum, Blastoschyzomyces

capitatus).

Thymol, MICs and MFCs, mg/mL: 0.04–0.39 and

0.19–0.78

Carvacrol, MICs and MFCs, mg/mL: 0.04–0.39 and

0.09–6.25

p-Cymene, MICs andMFCs, mg/mL: 0.39�> 6.25 and

0.39–> 6.25

g-Terpinene, MICs and MFCs, mg/mL: 0.19–> 6.25

and 0.39–>6.25

References

1. S. Shin, J.H. Kim, Planta Med. 70, 1090 (2004)

Thymus marschallianus Willd.

Family: Lamiaceae

Plant Material

Terpenoids

Phytol, % dry wt: 0.03

Sterols, % dry wt: 0.07

Triterpenoic acids, % dry wt: ursolic acid – 1.15

References

1. D.P. Popa, L.A. Saley, T.M. Orghiyan, Rast. Resursy 12(2),

247 (1976)

Thymus pectinatus var. pectinatus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.2

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 13.0–35.0; p-cymene – 11.0–33.0;

borneol – 10.0–18.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus praecox ssp. arcticus (E. Durand)Jalas

Family: Lamiaceae

Herb

Essential oil (at flowering stage, from Iceland) [1]

Composition (GC), %: 1,8-Cineole – 0.46; n-octen-

1-ol-3-acetate – 0.95; n-octen-1–3-ol – 0.73;

trans-sabinene hydrate – 1.19; menthone

+fenchylacetate – 0.05; iso-menthone – 0.37;

b-bourbonene – 0.12; camphor – 0.18; cis-

sabinene hydrate – 0.03; linalylacetate – 69.43;

bornyl acetate – 0.23; a-bergamoten – 0.01;

b-elemene – 0.01; b-caryophyllene – 3.58;

a-cubebene – 0.26; a-humulene – 0.15;

b-cubebene – 0.26; borneol – 0.51; germacrene

D – 1.30; b-bisabolene – 3.16; sesquiterpene –

0.06; a-farnesene – 0.21; g-cadinene – 1.14;

b-sesquiphellandrene – 0.87; caryophyllene

oxide – 0.19; nerolidol – 0.73; sesquiterpe-

nalcohol – 0.02; cubenol – 0.44; elemol – 1.42;

hedycaryol – 7.00; T-cadinol – 3.54; a-cadinol –0.34 (Norway); 1,8-cineole – 0.28; n-octen-1-ol-

3-acetate – 1.68; n-octen-1–3-ol – 0.70; trans-

sabinene hydrate – 0.07; menthone

+fenchylacetate – 0.05; iso-menthone – 0.05;

b-bourbonene – 0.19; camphor – 0.15; cis-

sabinene hydrate – 0.03; linalylacetate – 70.28;

bornyl acetate – 0.06; a-bergamoten – 0.02;

b-elemene – 0.03; b-caryophyllene – 4.36;

terpinen-4-ol – 0.05; a-cubebene – 0.12; a-humulene – 0.11; b-cubebene – 0.12; a-terpinylacetate – 0.03; borneol – 0.05; germacrene D –

2.67; b-bisabolene – 2.11; sesquiterpene – 0.11;

a-farnesene – 0.45; g-cadinene – 0.21;

b-sesquiphellandrene – 1.24; caryophyllene

oxide – 0.46; nerolidol – 2.99; sesquiterpe-

nalcohol – 0.16; cubenol – 0.13; elemol – 1.00;

hedycaryol – 6.98; T-cadinol – 0.94; a-cadinol –0.27 [1]

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Lamiaceae 540 Thymus praecox ssp. grossheimii var. grossheimii

Plant Material

Essential oil (steam distillation) (from Iceland) [2]

Composition (GC, WG 11), %: a-Pinene – 0.05;

unidentified 1 – 0.19; camphene – 0.08; b-pinene– 0.04; sabinene – 0.02; myrcene – 1.49;

a-terpinene – 0.02; limonene – 0.29; b-phellandrene – 0.05; 1,8-cineole – 0.28; cis-ocimene – 0.65; unidentified 2 – 0.04; trans-

ocimene – 1.40; unidentified 3 – 0.03; p-cymene

– 0.03; terpinolene – 0.32; n-octen-1-yl-3-acetate – 1.68; unidentified 4 – 0.04; n-octen-1-

ol-3 – 0.70; trans-sabinene hydrate – 0.07;

a-fenchylacetate – 0.04; menthone – 0.04;

iso-menthone – 0.05; b-bourbonene – 0.19; cam-

phor – 0.15; linalool – 24.73; cis-sabinene

hydrate – 0.03; linalyl acetate – 25.83; bornyl

acetate – 0.06; a-bergamoten – 0.02; b-elemene

– 0.03; b-caryophyllene – 4.36; terpinen-4-ol – 00.05; a-cubebene – 0.12; a-humulene – 0.11; b-cubebene – 0.10; a-terpineol – 5.96; a-terpinylacetate – 0.03; borneol – 0.05; germacrene D –

2.67; neryl acetate-1.00; b – bisabolene – 2.11;

sesquiterpene-KW – 0.11; E,E-a-farnesene –

0.45; geranyl acetate – 3.30; g-cadinene – 0.21;

b-sesquiphellandrene – 1.24; nerol – 1.25; gera-

niol – 3.41; unidentified 5 – 0.06; caryophyllen

epoxide – 0.46; nerolidol – 2.99; sesquiterpe-

nalcohol – 0.16; cubenol – 0.13; 7-

hydroxygermacren – tr; elemol – 1.00;

hedycaryool – 6.98; T-cadinol – 0.94; a-cadinol– 0.27; others – 1.88 [2]

Nerolidol

IR, MS, 1H NMR [2]

T-Cadinol

IR, MS, 1H NMR [2]

7-Hydroxygermacrene

IR, MS, 1H NMR [2]

Hedycaryol

IR, MS, 1H NMR [2]

Elemol

IR [2]

References

1. E. Stahl-Biskup, Planta Med. 48, 36 (1986)

2. E. Stahl, Planta Med. 50, 157 (1984)

Thymus praecox ssp. grossheimii var.grossheimii

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.3 (1); 0.7

(2)

Main components (GС, Thermon-600 T, GC/MS),

%: Carvacrol – 19.0; p-cymene – 10.0 (1);

thymol – 25.0; p-cymene – 23.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus praecox ssp. skorpilii var. laniger

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1 (1);

0.8 (2)

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 18.0; carvacrol + eudesmol – 13.0

(1); thymol – 41.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus praecox ssp. skorpilii var.skorpilii

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.5

Main components (GС, Thermon-600 T, GC/MS),

%: a-terpineol + a-terpinylacetate – 25.0; gera-

niol – 24.0

Page 153: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Thymus satureioides 541 Lamiaceae

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus pseudopulegioides

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.6

Main components (GС, Thermon-600 T, GC/MS),

%: Linalool – 26.0; a-terpinyl acetate – 15.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus pulvinatus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.4–0.9

Main components (GС, Thermon-600 T, GC/MS),

%: Borneol – 29.0–31.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus revolutus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.3

Main components (GС, Thermon-600 T, GC/MS),

%: p-cymene – borneol – 29.0–31.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus roegneri

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.0

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 54.0; p-cymene – 17.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus saravshanicus Klok.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 227.5 (cald)

FAs

Composition (GLC, 10%PEGA), mol%: 16:0 – 4.2,

18:0 – 1.7, 18:1 – 10.3, 18:2 – 21.0, 18:3 – 62.8

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]

Thymus satureioides

Family: Lamiaceae

Aerial Part

Essential oil (steam distillation in a modified

Clevenger apparatus), % dry wt: 1.1–1.3

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Lamiaceae 542 Thymus serpyllum L.

Composition (CC; GLC, Carbowax 20M), %:

Tricyclene – 0.19; a-pinene – 3.27; camphene –

5.43; b-pinene – 0.44; myrcene – 0.33; a-terpinene – 0.28; limonene – 0.51; 1;8-cineole

– 0.16; g-terpinene – 1.70; b-cymene – 2.96;

trans-4-thujanol – 0.14; linalool – 3.43; camphor

– 2.65; bornyl acetate – 1.71; carvacrol methyl

ether – 1.43; 1-terpinen-4 – ol-4.81; b-caryophyllene – 6.44; a-terpineol – 12.24; bor-

neol – 26.22; thymol – 19.23; carvacrol – 4.25.

References

1. J.D. Miquel, H.M.J. Richard, F.G. Sandret, J. Agric. Food

Chem. 24, 833 (1976)

Thymus serpyllum L.

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.0 [1]

Components, %: Thymol – 0.1–1.0

Triterpenoic acids: Ursolic and oleanolic [1]

Activity: Thymol from essential oil is antiseptic [1].

Use: Essential oil is used in perfume [1].

Herba Serpylli [2].

Extractum Serpylli fleeidum [2].

Pertussinum [2].

References

1. I.A. Gubanov, K.V. Kiselyeva, V.S. Novikov, Dikorastushyepoleznye rasteniya (Moscow University Press, Moscow,

1987), p. 82 [in Russian]

2. M.D. Mashkovskii, Lekarstvennye sredstva (Meditsina, Tash-

kent, 1988), 1 [in Russian]

Thymus sibthorpii

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.8–1.7

(1); 1.8 (2); 1.5 (3)

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 24.0–50.0; p-cymene – 17.0–18.0

(1); carvacrol – 39.0; p-cymene – 17.0 (2); car-

vacrol – 40.0; p-cymene – 22.0; thymol –

16.0 (3)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus sipyleus ssp. Rosulans

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.9 (1); 0.5

(2); 0.2 (3)

Main components (GС, Thermon-600 T; GC/MS);

%: Thymol – 68.0 (1); thymol – 17.0; carvacrol –

12.0; thymol – 39.0; thymol – 20.0 (2); 1,8-

cineole – 20.0 (3)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus sipyleus ssp. sipyleus var.sipyleus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1; 0.2

(1); 0.3 (2)

Main components (GС, Thermon-600 T, GC/MS),

%: Geranial – 26.0; neral – 14.0; geranial – 29.0;

neral – 21 (1); linalool – 22.0; geranial – 8.0;

neral – 3.0 (2)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

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Thymus ussuriensis Klok. 543 Lamiaceae

Thymus spicata L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 3.4

Oil, % dry wt: 6.4 (petroleum ether, 30–60�C, in the

Butt apparatus)

n40D : 1.4740

Iodine value (Wijs), % J2: 186; 193 (cald)

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

7.2; 18:0 – 2.5; 18:1 – 12.0; 18:2 – 22.0; 18:3 –

55.0; others (3) – 0.9

Hydroxy acid (IR)

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Thymus striatus var. interruptus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1 (1); 0.4

(2); 1.3 (3)

Main components (GС, Thermon-600 T, GC/MS),

%: b-caryophyllene + terpinen-4-ol – 27.0 (1);

p-cymene – 15.0; 1,8-cineole – 13.0; thymol –

11.0 (2); thymol – 36.0 (3)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus syriacus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.7

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 50.0; carvacrol – 16.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus thracicus var. longidens

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 1.2–1.3

Main components (GС, Thermon-600 T, GC/MS),

%: Geraniol – 16.0–47.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus transcaucasicus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.1

Main components (GС, Thermon-600 T, GC/MS),

%: Germacrene D, + b-caryophyllene – 18.0

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus ussuriensis Klok.

Synonyms

Thymus amurensis Klok.

Family: Lamiaceae

Inflorescence

Essential oil (hydro distillation), % dry wt: 0.96–1.4

Page 156: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 544 Thymus villosus subsp. lusitancus

Leaf

Essential oil (hydro distillation), % dry wt: 0.87

Use: The essential oil may be used in perfume, med-

icine, and food.

References

1. N.I. Suprunov, P.G. Gorov, Y.A. Pankov, Efirno-maslichnyerasteniya Dalnogo Vostoka (Novosibirsk, 1972), p. 140 [in

Russian]

Thymus villosus subsp. lusitancus

Family: Lamiaceae

Leaf

Essential oil (from samples A – Toledo: Los Yebenes,

Sierra del Rebollarejo, 30S VJ26, 11/6, Velasco

Negueruela; B – Caceres: Hospital del Obispo,

Sierra de Guadalupe, Velasco Negueruela; C –

Ciudad Real: Piedrabuena, Sierra del Rio Frio

Velasco Negueruela. The plant were collected at

flowering stage)

Composition of essential oil (GLC, 5% OV 1 and

10% Carbowas 20), %: b-Myrcene � 0.18; lin-

alool � 1.41; citronellal � 1.66; a-phellandrene� 0.34; a-terpinene � tr; a-limonene � tr; 1,8-

cineole � 1.86; g-terpinene � 0.08; 1-terpinen-

4-ol � 2.24; a-terpineol � 0.36; a-thujene �0.21; a-pinene � 1.36; camphene � 7.64; b-pinene � 0.46; sabinene � tr; camphor �36.97; borneol � 15.59; bornyl acetate � tr; p-

cymene � 1.76; thymol � 3.23; unidentified 1�2.71; b-caryophyllene� 0.43; humulene� 0.62;

nerolidol � 2.95; unidentified 2 � 17.9 (A)

Monoterpenes, %: 78.06

Sesquiterpenes, %: 21.94

b-Myrcene – 0.41; linalool – 12.83; citronellal –

0.74; linalyl acetate � 7.81; a-phellandrene �0.03; a-terpinene � tr; a-limonene – tr; 1,8-

cineole – 14.74; g-terpinene – 0.12; 1-terpinen-

4-ol – 2.25; a-terpineol – 2.66; a-thujene – 0.19;a-pinene – 3.48; camphene – 4.41; b-pinene –

1.03; sabinene – tr; camphor – 25.65; borneol –

8.78; bornyl acetate – tr; p-cymene – 1.41;

thymol � 0.80; unidentified 1 – 1.78; b-

caryophyllene – tr; humulene – tr; cadiol –

4.36; unidentified 2 – 6.52 (B)

Monoterpenes, %: 89.12

Sesquiterpenes, %: 10.88

b-Myrcene – 2.57; linalool � 18.24; citronellal –

0.32; linalyl acetate – 0.48; a-phellandrene –

0.26; a-terpinene – tr; a-limonene – tr; 1,8-

cineole – 13.81; g-terpinene – 1.14; b-terpineol– 0.54; 1-terpinen-4-ol – 1.84; a-terpineol –

7.11; a-thujene – 0.24; a-pinene – 5.52; cam-

phene – 5.75; b-pinene – 2.32; sabinene – tr;

camphor – 14.18; borneol – 4.37; bornyl acetate

– 0.44; p-cymene – 0.44; thymol – 1.94;

unidentified 1 – 1.71; b-caryophyllene – 0.93;

humulene – 0.11; cadiol – 7.96; unidentified 2 –

7.78 (C)

Monoterpenes, %: 83.22

Sesquiterpenes, %: 16.78

References

1. M.J. Perez Alonso, A.V. Negueruela, Phytochemistry 23, 581

(1984)

Thymus vulgaris

Family: Lamiaceae

Plant material

Essential oil (hydro distillation), %: dry wt: 1.0

Main components (GС, Thermon-600 T, GC/MS),

%: Thymol – 36.0; p-cymene – 30.0

2-Methyl-6-methylene—2,7-octadienol (Z) [2]

Seed

Mass of 1,000, g: 0.6 [3]

Oil, %: 37.0 (petroleum ether, 30–60�C, in the Butt

apparatus) [3]

n40D : 1.4783 [3]

Iodine value (Wijs), % J2: 204 [3]

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

1.6; 18:0 – 1.8; 18:1 – 7.0; 18:2 – 14.0; 18:3 –

54.0; others (7) – 21.0 [3]

Hydroxy acid (IR) [3]

2-Hydroxy-18:3 (9,12,15) [4]

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Ziziphora clinopodioides Lam. 545 Lamiaceae

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

2. R. Granger, J. Passer, J.P. Girard, Phytochemistry, 11, 2301

(1972)

3. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

4. P. Pohl, H. Wagner, Fette, Seifen, Anstrichmittel 74(9), 541

(1972)

Thymus zygioides var. lycaonicus

Family: Lamiaceae

Plant Material

Essential oil (hydro distillation), %: dry wt: 0.9 (1), 1.1

(2), 1.1 (3), 1.1 (4), 0.2 (5)

Main components (GС, Thermon-600 T, GC/MS);

%: Thymol – 45.0; b-bisabolene – 11.0 (1);

thymol – 58.0; p-cymene – 11.0 (2); thymol –

50.0 (3); carvacrol – 62.0 (4); geraniol – 77.0 (5)

References

1. G. Tumen, N. Kirimer, K.H.C. Baser, Chem. Nat. Comp. 31,

42 (1995)

Thymus zygis L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.2

Oil, %: 30.0 (petroleum ether, 30–60�C, in the Butt

apparatus)

n40D : 1.4783

Iodine value (Wijs), % J2: 206.0

FAs

Composition (GLC, 20% LAC-2R 446), %: 16:0 –

4.6; 18:0 – 2.4; 18:1 – 2.6; 18:2 – 14.0; 18:3 –

56.0; others (7) – 14.0

Hydroxy acid (IR)

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Widemannia orientalis F. & M.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 1.2

Oil (petroleum ether, 30–60�C), % dry wt: 26

n40D : 1.4706

Iodine value (Wijs), % J2: 142; 135 (cald)

FAs

Composition (GLC, 20% LAC - 2R 446), %: 16:0 –

5.1; 18:0 – 2.5; 18:1 – 23.0; 18:2 – 50.0; 18:3 –

8.7; others (6) – 2.4

Allenic acid (IR), %: 7.0

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ziziphora capitata L.

Family: Lamiaceae

Mass of 1,000, g: 0.4

Oil (petroleum ether, 30–60�C), % dry wt: 34

n40D : 1.4768

Iodine value (Wijs), % J2: 209; 216 (cald)

FAs

Composition (GLC 20% LAC-2R 446), %: 16:0 –

5.9; 18:0 – 2.1; 18:1 – 6.5; 18:2 – 14; 18:3 – 71;

others (2) – 0.4

IR

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

Ziziphora clinopodioides Lam.

Family: Lamiaceae

Seed

Oil (hexane)

Iodine value, % J2: 240.6 (cald)

Page 158: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Thymus serpyllum L.

Lamiaceae 546 Ziziphora pedicellata Pazij et Vved.

FAs

Composition (GLC, 10% PEGA), mol %: 16:0 –

3.1; 18:0 – 1.2; 18:1 – 7.4; 18:2 – 17.8; 18:3 – 70.5

References

1. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971)

Ziziphora pedicellata Pazij et Vved.

Family: Lamiaceae

Aerial Part

Mass, %: Inflorescence – 27.5; leaves – 28.2; stems –

44.3

Moisture and volatiles, % fresh wt: 9.5

Extract of lipids, mg/g: 3.0 (fresh wt); 33.0 (dry wt)

Chlorophyll a, mg % abs. dry wt: 0.084 (from dried

plant material)

Chlorophyll b, mg % abs. dry wt: 0.075 (from dried

plant material)

Carotenoids, mg % abs. dry wt: 0.0326 (from dried

plant material)

Essential oil, % fresh wt: 2.02 (from fresh plant mate-

rial); 1.6 (from dried plant material)

FAs, %: 37.9

Composition (GLC), %: 10:0 – 3.3; 12:0 – 14.2;

13:0 – 2.3; 14:0 – 1.8; 15:0 – tr; 16:0 – 17.2; 16:1

– 2.2; 17:0 – tr; 18:0 – 3.2; 18:1 – 5.1; 18:2 –

16.5; 18:3 – 29.5; 20:0 – 4.7

Unsaponifiables, %: 23.8

Inflorescence

Moisture and volatiles, % fresh wt: 30.2

Extract of lipids, mg/g: 3.4 (fresh wt); 48.7 (dry wt)

Chlorophyll a, mg % abs. dry wt: 0.329 (from fresh

plant material)

Chlorophyll b, mg % abs. dry wt: 0.164 (from fresh

plant material)

Carotenoids, mg % abs. dry wt: 0.039 (from fresh

plant material)

Lipid composition (TLC): Hydrogen’s, esters of ste-

rols and triterpenols, esters of fatty alkanols, TAGs,

free FAs, tocopherols, sterols, triterpenols, fatty

alkanols

FAs, %: 46.3

Composition (GLC), %: 10:0 – 3.4; 12:0 – 9.9; 13:0

– 6.8; 14:0 – 2.2; 15:0 – tr; 16:0 – 17.2; 16:1 –

6.9; 17:0 – tr; 18:0 – 10.0; 18:1 – 7.4; 18:2 – 9.8;

18:3 – 22.9; 20:0 – 3.5

Unsaponifiables, %: 12.6

Leaf

Moisture and volatiles, % fresh wt: 36.1

Extract of lipids, mg/g: 5.3 (fresh wt); 82.9 (dry wt)

Chlorophyll a, mg % abs. dry wt: 0.562 (from fresh

plant material)

Chlorophyll b, mg % abs. dry wt: 0.287 (from fresh

plant material)

Carotenoids, mg % abs. dry wt: 0.049(from fresh

plant material)

Lipid composition (TLC): Hydrogen’s, esters

of sterols and triterpenols, esters of fatty

alkanols, TAGs, free FAs, tocopherols, sterols,

triterpenols, fatty alkanols

FAs, %: 44.9

Composition (GLC), %: 10:0 – 2.4; 12:0 – 8.8; 13:0

– 3.1; 14:0 – 2.0; 15:0 – tr; 16:0 – 14.2; 16:1 –

4.2; 17:0 – tr; 18:0 – 12.3; 18:1 – 8.1; 18:2 – 6.7;

18:3 – 32.0; 20:0 – 6.2

Unsaponifiables, %: 7.0

Stem

Moisture and volatiles, % fresh wt: 7.6

Extract of lipids, mg/g: 1.4 (fresh wt); 15.2 (dry wt)

Chlorophyll a, mg % abs. dry wt: 0.107 (from fresh

plant material)

Chlorophyll b, mg % abs. dry wt: 0.063 (from fresh

plant material)

Carotenoids, mg % abs. dry wt: 0.011 (from fresh

plant material)

Lipid composition (TLC): Hydrogen’s, esters of

sterols and triterpenols, esters of fatty alkanols,

TAGs, free FAs, sterols, triterpenols, and fatty

alkanols

FAs, %: 35.8

Composition (GLC), %: 10:0 – 1.9; 12:0 – 12.5;

13:0 – 2.7; 14:0 – 1.5; 15:0 – 0.6; 16:0 – 26.2;

16:1 – 7.6; 17:0 – tr; 18:0 – 10.1; 18:1 – 4.7; 18:2

– 14.6; 18:3 – 12.2; 20:0 – 5.2

Unsaponifiables, %: 15.6

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Ziziphora tenuior L. 547 Lamiaceae

References

1. S.D. Gusakova, T.V. Khomova, Chem. Nat. Comp. 33, 633

(1997)

Ziziphora pedicillata

Family: Lamiaceae

Seed

Oil (hexane), %: 17.6 [1]

d20: 0.9288 [1]

n20D : 1.4831 [1]

Acid value, mg KOH: 8.9 [1]

Iodine value (Wijs), % J2: 192.6 [1]

Saponification value, mg KOH: 194.3 [1]

Unsaponifiables, %: 1.9 [1]

FAs

n20D : 1.4815 [1]

Iodine value (Wijs), % J2: 220.1 [1]

UV, IR

Composition (GLC, 17% PEGS), %: 16:0 – 5.7;

18:0 – 1.2; 18:1 – 9.3; 18:2 – 16.2; 18:3 – 67.6 [1]

TAG

Main components: LeLeLe – 30.7; LLeLe – 11.2;

OLeLe – 5.8; LeLLe – 11.1; LeOLe – 6.9; PLeLe

– 8.6; LLLe – 4.0; OLLe – 2.0; LOLe – 2.6;

OOLe – 1.4; OLeL – 1.0; PLLe – 3.4; LLeL –

1.0; POLe – 2.2; PLeL – 1.6; PLeO – 1.0; others

(14) – 4.3 [2]

Composition, %: SSS – 0.01; SSU + USS – 0.10; USU –

0.49; UUS + SUU – 19.98; UUU – 80.42 [3]

FAs (GLC, 17% PEGS), %: 16:0 – 6.1; 16:1(9) – tr;

18:0–1.2; 18:1 – 9.1; 18:2 – 16.1; 18:3 – 67.5; others

(13) – 5.5 [2]

Hydrocarbons (MS): C28 [1]

a-Carotene [1]UV

b Carotene [1]

UV

References

1. S.D. Gusakova, A.U. Umarov, Chem. Nat. Comp. 340 (1975)

2. T. V Panekina, S.D Gusakova, E.M. Zalewskaya, A.U.

Umarov, Chem. Nat. Comp. 15, 538 (1979)

Ziziphora tenuior L.

Family: Lamiaceae

Seed and Pericarp

Mass of 1,000, g: 0.4 [1]

Oil (petroleum ether, 30–60�C), % dry wt: 32.0 [1]

n40D : 1.4756 [1]

Iodine value (Wijs), % J2: 207; 215 (cald) [1]; 249.4

(cald) [2]

FAs

Composition (GLC 20% LAC - 2R 446), %: 16:0 –

5.2; 18:0 – 2.0; 18:1 – 7.0; 18:2 – 14.0; 18:3 –

70.0; others (5) – 1.3

IR [1]

Seed

Oil (hexane) [2]

FAs

Composition (GLC, 10% PEGA), mol %: 160 – 3.7;

18:0 – 0.9; 18:1 – 5.3; 18:2 – 11.9; 18:3 – 778.2

References

1. J.M. Hageman, F.R. Earle, I.A. Wolff, A.S. Barclay, Lipids 2,

371 (1967)

2. G.V. Novitzkaya, V.I. Krishtopa, Rast. Resursy 7(1), 32

(1971) [in Russian]