Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R....

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Rosaceae Juss. Agrimonia asiatica Juz. (A. eupatoria L., subsp. asiatica (Juz.) Skalicky, A. eupatoria subsp. asiatica (Juz.) Scho ¨ nkeck-Temesy) Family: Rosaceae Juss. Branch Ursolic acid, %: 0.38 [1] Fruit Ursolic acid, %: 0.02 [1] Leaf Ursolic acid, %: 0.13 [1] Root Ursolic acid, %: 0.17 [1] Root-Stock Ursolic acid, %: 0.34 [1] Seed Mass of 1,000, g: 32 [2] Oil (petrol), % on dry wt: 11.26 [2] n 20 D : 1.4788 [2] Acid value, mg KOH: 3.58 [2] Iodine value, % J 2 : 165.92 [2] Saponification value, mg KOH: 184.84 [2] Unsaponifiables, %: 3.4 [2] FAs Iodine value, % J 2 : 177.70 [2] Mean mol. wt: 280.01 [2] Neutralization value, mg KOH/g: 200.35 [2] Composition of FAs (GLC, 15% PEGS), %: 16:0 – 6.74; 18:0 – 2.84; 18:1 – 21.83; 18:2 – 33.58; 18:3 – 35.01 [2] (GLC), %: 16:0 + 18:0 – 7.0; 18:1 – 20.0; 18:2 – 69.0; 18:3 – 4.0 [3] References 1. А.Y. Ibragimov, R.L. Khazanovich, Chem. Nat. Comp. 8(3), 394 (1972) 2. E.I. Gigienova, Е.I. Кiryushina, А.U. Umarov, Chem. Nat. Comp. 13(4), 411 (1977) 3. Rukovodstvo po metodam issledovaniya, tekhnologicheskomu kontrolyu i uchetu proizvodstva v maslozhirovoi promyshlennosti, L. (1969) [in Russian] Agrimonia eupatoria L. Family: Rosaceae Juss. Leaf Triterpenoic acids Components: Ursolic, hydroxyursolic Seed FAs: 16:0; 18:2; 18:3 Underground Part Components: Hydrocarbons, ceryl alcohol, ceryl palmitate, ceryl stearate, butyric acid, 16:0-, 18:0 – FAs A.I. Glushenkova (ed.), Lipids, Lipophilic Components and Essential Oils from Plant Sources, DOI 10.1007/978-0-85729-323-7, # Springer-Verlag 2012

Transcript of Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R....

Page 1: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss.

Agrimonia asiatica Juz. (A. eupatoria L.,subsp. asiatica (Juz.) Skalicky, A.eupatoria subsp. asiatica (Juz.)Schonkeck-Temesy)

Family: Rosaceae Juss.

Branch

Ursolic acid, %: 0.38 [1]

Fruit

Ursolic acid, %: 0.02 [1]

Leaf

Ursolic acid, %: 0.13 [1]

Root

Ursolic acid, %: 0.17 [1]

Root-Stock

Ursolic acid, %: 0.34 [1]

Seed

Mass of 1,000, g: 32 [2]

Oil (petrol), % on dry wt: 11.26 [2]

n20D : 1.4788 [2]

Acid value, mg KOH: 3.58 [2]

Iodine value, % J2: 165.92 [2]

Saponification value, mg KOH: 184.84 [2]

Unsaponifiables, %: 3.4 [2]

FAs

Iodine value, % J2: 177.70 [2]

Mean mol. wt: 280.01 [2]

A.I. Glushenkova (ed.), Lipids, Lipophilic Components and EssentialDOI 10.1007/978-0-85729-323-7, # Springer-Verlag 2012

Neutralization value, mg KOH/g: 200.35 [2]

Composition of FAs (GLC, 15% PEGS), %: 16:0 –

6.74; 18:0 – 2.84; 18:1 – 21.83; 18:2 – 33.58;

18:3 – 35.01 [2]

(GLC), %: 16:0 + 18:0 – 7.0; 18:1 – 20.0; 18:2 –

69.0; 18:3 – 4.0 [3]

References

1. А.Y. Ibragimov, R.L. Khazanovich, Chem. Nat. Comp. 8(3),

394 (1972)

2. E.I. Gigienova, Е.I. Кiryushina, А.U. Umarov, Chem. Nat.

Comp. 13(4), 411 (1977)

3. Rukovodstvo po metodam issledovaniya, tekhnologicheskomukontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, L. (1969) [in Russian]

Agrimonia eupatoria L.

Family: Rosaceae Juss.

Leaf

Triterpenoic acids

Components: Ursolic, hydroxyursolic

Seed

FAs: 16:0; 18:2; 18:3

Underground Part

Components: Hydrocarbons, ceryl alcohol, ceryl

palmitate, ceryl stearate, butyric acid, 16:0-,

18:0 – FAs

Oils from Plant Sources,

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Rosaceae Juss. 702 Agrimonia pilosa Ledeb.

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae

(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Agrimonia pilosa Ledeb.

Family: Rosaceae Juss.

Whole Plant

Triterpenoic acids

Components: 1b,2a,3b,19a-tetrahydroxyurs-12-en-28-oic, 1b,2b,3b,19a-tetrahydroxy-urs-12-en-28-oic [1]

Activity: Antitumor activity of the extracts from the

roots [2].

References

1. I. Kouno, N. Baba, Y. Ohni, N. Kawano, Phytochemistry

27(1), 297 (1988)

2. K. Miyamoto, R. Koshiura, Y. Ikeya, H. Taguchi, Chem.

Pharm. Bull. 33, 3977 (1985)

Agrimonia procera Wallr. (A. odorataauct.)

Family: Rosaceae Juss.

Leaf

Essential oilComponent: Mentol

References

1. F. Gizycki, Pharmazie 4(10), 463 (1949)

Alchemilla alpina L.

Family: Rosaceae Juss.

Aerial Part

Components: Aliphatic hydrocarbons, glycerides,

lecithin

PhL

FAs: 18:1; 18:2

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Alchemilla caucasica Bus.

Family: Rosaceae Juss.

Leaf

Carotenoids

Components: Violaxanthin, lutein

References

1. N.V. Bazhanova, А.G. Gevorkyan, Dokl. АN Аrm. SSR

50(2), 111 (1970) [in Russian]

Alchemilla xanthochlora Rothm.(A. vulgaris auct.)

Family: Rosaceae Juss.

Aerial Part

Hydrocarbons

Component: n-Dotriacontane

TAG

FAs: 16:0; 18:0

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae,izd. (“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Amelanchier canadensis L.

Family: Rosaceae Juss.

Fruit

Unsaponifiables, mg/100 g: 60

Sterols, mg/100 g: 6

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Amygdalus communis L. 703 Rosaceae Juss.

References

1. L.I. Vigorov, Rastit. Resursy VIII(4), 557 (1972) [in Russian]

Amelanchier ovalis Medik. (A.rotundifolia (Lam.) Dumcours.,A. vulgarisMoench, Crataegus rotundifolia Lam.)

Family: Rosaceae Juss.

Leaf, Bud, and Sprout

Essential oilComponents: Cyan substances

References

1. А.А. Grossgeim, Rastitel’nye resursy Kavkaza(1946) [in Russian]

Amygdalus bucharica Korsh.

Family: Rosaceae Juss.

Coat of Seed

Lipids, % on dry wt: 0.51 [1]

Kernel of Seed

Oil, % on dry wt: 40.9–53.0 [1, 2]

Seed

Mass of 1,000, g: 500 [3]

Oil, % on abs. dry wt: 50.1 [3]; on dry wt, %: 27.72 [1]

d: 0.9142 [1]

n: 1.4680 [1]

Absolute viscosity, sp: 74.73 [1]

Hehner value, %: 5.13 [1]

Iodine value, % J2: 99.5 [1]; 103.35 [2]

Phospholipids, %: 1.1 [4]

Saponification value, mg KOH/g: 193.0 [1]

Thiocyanogen value, % J2: 81.02 [1]

Unsaponifiables, %: 0.13 [1]

FAs

Iodine value, % I2: 103.85 [1]

Mean mol. wt: 264.5 [1]

Neutralization value, mg KОН/g: 212.17 [1]

Thiocyanogen value, % J2: 84.21 [1]

Saturated FAs

Content (Bertram), %: 6.39 [1]

Mean mol. wt: 273.6 [1]

Neutralization value, mg KOH/g: 205.09 [1]

Unsaturated FAsContent, %: 91.8 [1]

Composition of FAs (GLC, 15% PEGS), %: 10:0 –

0.3; 16:0 – 5.5; 18:0 – 0.6; 18:1 – 67.9; 18:2 –

24.3; 18:3–1.4 [1]

Unsaturated FAs (GLC, 10% PEGS), %: 18:2 –

31.3; 18:1– 60.5 [3]

TAG

Composition, %: SSS – 0.20; SSU – 1.1; SUU –

16.8; UUU – 81.9 [1]

Tocopherols

Content, mg%: 30.7 [3]

Composition, mg%: a-Tocopherol – 6.5;

g-tocopherol – 24.2 [3]

Activity: Fatty oil – Purge [5]

References

1. G.А. Stepanenko,А.U. Umarov,А.L.Маrkman, Chem. Nat.

Comp. 6(4), 410 (1970)

2. M.G. Pakhomova, Mindali Uzbekistana (izd. AN Uzb. SSR,

Tashkent, 1961), 233 s [in Russian]

3. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

4. K.S. Mukhamedova, R.R. Akbarov, S.Т. Akramov, Chem.

Nat. Comp. 14(3), 330 (1978)

5. Е.I. Кiryushina, In: Rasprostranenie i prirodnye zapasypoleznykh rastenii Uzbekistana (Таshkent, 1974), vyp. 1,

220 [in Russian]

Amygdalus communis L. (A. dulcis Mill.,Prunus amygdalus Stokes, P. dulcis (Mill.)D.A. Webb)

Family: Rosaceae Juss.

Coat of Seed

Lipids, % on dry wt: 0.55 [1]

FAs (GLC), %: 14:0 – tr; 16:0 – 5.9–6.1; 16:1 – 0.4–

1.0; 17:0 – tr; 17:1 – tr; 18:0 – 1.2–1.8; 18:1 –

63.8–72.8; 18:2 – 18.9–28.1; 18:3 – tr; 20:0 – tr;

20:1 – tr [2]

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Rosaceae Juss. 704 Amygdalus communis L.

External layer

FAs of lipids (GLC), %: 16:0 – 7.36; 18:0 – 1.32;

18:1 – 73.49; 18:2 – 17.54 [2]

Inner layer

FAs of lipids (GLC), %: 16:0 – 5.78; 18:0 – 1.65;

18:1 – 76.44; 18:2 – 15.86 [2]

Fruit

Moisture, %: 4.0 [3]

Oil, % on dry wt: 10.55–24.67 [4]

Unsaponifiables

Content, mg% on fresh wt: 240–260 [5]

Sterols

Content, mg/100 g on fresh wt: 25–27 [5]

Kernel of Seed

Oil, % on dry wt: 45.9–61.7 [1, 4, 6–8]

Seed

Essential oil

Content, %: 0.5–0.8 [9, 10]

[a]D: +0�90 [9]d15: 1.045–1.070 [9, 10]

n20D : 1.5320–1.5440 [9]

Composition, %: Cyanogen acid, benzaldehyde –

96–98; benzaldehyde cyanohydrin [9]

Mass of 1,000, g: 80–150 [12]; 194.1–519.6 [6]

Oil, % on dry wt: 12.7–35.3 [1, 6]; on abs. dry wt, %:

50.0–57.4 [10, 11]

d: 0.9141 [1]; d15: 0.914–0.921 [4, 12]

n: 1.4650 [1]; n40D : 1.4617–1.4636 [6]; n20D : 1.468–

1.4713 [4, 12]

Acetic value, mg KOH: 6–10 [12]

Acid value, mg KOH: 0.75 [4]

Ester value, mg KOH: 189.7–190.2 [4]

Hehner value, %: 94.0–96.5 [12]

Iodine value, % J2: 93–106 [1, 4, 12]

Polenske value, mL KOH: 2.6 [12]

Reichert-Meissl value, mL KOH: 0.2–0.8 [4, 12]

Saponification value, mg KOH/g: 183–195.4

[1, 4, 12]

Thiocyanogen value, % J2: 83.61 [1]; 81–85 [12]

Viscosity, E30, sp: 47.8 [12]

Unsaponifiables, %: 0.45–0.7 [6, 12]

FAs

Iodine value, % J2: 105.03 [1]; 90.1–97.6 [6]

Mean mol. wt: 266.04 [1]

Neutralization value, mg KОН/g: 210.5 [1]

Thiocyanogen value, % J2: – 84.0 [1]

Saturated FAs (Bertram), %: 6.0–9.20 [1, 12]

Mean mol. wt of saturated acids: 272.1 [1]

Neutralization value, mg KOH/g: 206.2 [6]

Unsaturated FAs, % 87.3–91.5 [5]; 94–97 [12]

Composition of FAs (GLC), %: 11:0 – 1.41; 14:0 –

tr – 1.2; 16:0 – 3.0–9.8; 16:1 – 0.4–1.9; 17:0 –

0.1; 17:1 – 0.1; 18:0 – 0.4–4.0; 18:1 – 21.0–84.0;

18:2 – 11.9–49.0; 18:3 – 1.7–2.3; 20:0 – tr [1, 2,

6, 8, 11, 12]

TAG

Composition, %: SSS – 0.70; SSU – 2.3; SUU –

22.6; UUU – 74.4 [1]; OPO – 17, OLO –52;

OOO – 31 [12]

Tocopherols and tocotrienols

Content, mg% of oil: 26.2–28.8 [11]

Composition, mg/100 g on fresh wt: a-Tocopherol –26.44; a-tocotrienol – 0.24; b-tocopherol – 0.17;g-tocopherol – 0.76; g-tocotrienol– 0.02; d-tocopherol – 0.02 [3]

(PC), mg%: a-tocopherol – 24.8–26.9; g-tocopherol– 1.1–1.9 [11]

Activity: Fatty oil – light purge [13]. It has sedative

and analgetic properties [2].

Use: The oil is a base of complex liniment for treat-

ment of piles [2]; solvent for some medicinal

preparates [13].

References

1. Т.Y. Leshchuk, Agrotekhnika osnovnykh efiro-maslichnykhkul’tur (1948) [in Russian]

2. M.I. Goryaev, N.A. Evdakova, Spravochnik pogazozhidkostnoi khromatografii organicheskikh kislot(“Nauka” Kaz. SSR, Alma-Ata, 1977), pp. 104–382 [in

Russian]

3. A.P. Gammerman, G.N. Kadaev, A.A. Yatsenko-

Khmelevskii, Lekarstvennye rasteniya (Vysshaya shkola,

Moscow, 1983), 399 s [in Russian]

4. N. Boldyrev, N. Boldyrev, Masloboino-zhirovoe delo (6),

310 (1936) [in Russian]

5. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969) [in Russian]

6. G.А. Stepanenko, А.U. Umarov, А.L. Markman, Chem.

Nat. Comp. 6(4), 410 (1970)

7. L.I. Vigorov, Rastit. Resursy VIII(4), 557 (1972) [in

Russian]

Page 5: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Amygdalus nana L. (Prunus tenella Rehd.) 705 Rosaceae Juss.

8. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,

ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae,pod red. P.D. Sokolova (“Nauka”, Leningrad, 1987),

pp. 19–101 [in Russian]

9. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen,

P. Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

10. Efirnye masla, pod red. G.V. Pigulevskogo

(Pishchepromizdat, Мoskwa-Leningrad, 1938) [in Russian]

11. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4) 675 (1977) [in Russian]

12. M. Mehran, M. Filsoof, J. Am. Oil Chem. Soc. 51(10), 433

(1974)

13. Lekarstvennye rasteniya: rasteniya-tseliteli, pod red. А.F.

Gammerman, 2 izd. (Мoscow, (1976), 389 s [in Russian]

Amygdalus fenzliana (Fritsch) Lypski(Prunus fenzliana Fritsch)

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 300

Oil, % on abs. dry wt: 54.6

Unsaturated FAs (GLC, 10% PEGS), %: 18:1 –

70.7; 18:2 – 23.7

Tocopherols

Content, mg%: 25.8

Composition of tocopherols, mg%: a-Tocopherol –2.5; g-tocopherol – 23.3

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

Amygdalus ledebouriana Schlecht.

Family: Rosaceae Juss.

Kernel of Fruit

Essential oil

References

1. М.I. Goryaev, Efirnye masla flory SSSR, izd. (АN Каz. SSR,Alma-Аtа, 1952) [in Russian]

Amygdalus nana L. (Prunus tenella Rehd.)

Leaf

Lipids, % on dry wt: 5.0 [1]

Seed

Essential oil

Components: Benzaldehyde, cyanogen acid [2]

Mass of 1,000, g: 300 [3]

Oil, % on abs. dry wt: kernel 49.79–52.8 [1, 3, 4];

whole pip 16.94–18.37 [5]

d15: 0.9154 [5]

n20D : 1.4714 [5]

Acid value, mg KOH: 0.38 [5]

Ester value, mg KOH: 189.9 [5]

Iodine value, % J2: 94–97 [1]; 104.6 [5]

Reichert-Meissl value, mL KOH: 0.34 [5]

Saponification value, mg KOH: 190.3 [5]

Unsaturated FAs

Content, %: 96.2 [3]

Composition (GLC, 10% PEGS), %: 18:1 – 70.7;

18:2 – 25.5 [3]

Tocopherols

Content, mg% on oil: 20.5 [3]

Composition, mg%: a-Tocopherol – 16.6;

g-tocopherol – 3.9 [3]

Activity: The essential oil act as sedative and analgetic

remedy by heart and pulmonary diseases [6]; the

ether extracts of seeds have antibacterial activity [7].

Use: The fatty oil is used in cosmetology, perfumery

[8].

References

1. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala, Izd. (“Nauka”, Moscow, 1976),

263 s [in Russian]

2. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1938), 550 s [in Russian]

3. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

4. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri Izd. (AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

5. N. Boldyrev, N. Boldyrev, Masloboino-zhirovoe Delo (6),

310 (1936) [in Russian]

6. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 6: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 706 Amygdalus pedunculata Pall.

7. А.S. Bondarenko, B.E. Aizenman, M.O. Shvaiger, Т.P.Mandrik, А.N. Bredikhina, In: Fitontsidy v narodnomkhozyaistve (Kiev, 1964), pp. 170–179 [in Russian]

8. S.S. Stankov, Dikorastushchie maslichnye rasteniya SSSRi ikh СССР prakticheskoe ispol’zovanie, М. (1944), 78 s [in

Russian]

Amygdalus pedunculata Pall.

Family: Rosaceae Juss.

Seed

Oil

Use: The oil – for smearing wounds and myositis treat-

ment, outwardly – for skin slurring, inward – laxative.

References

1. T. Khaidav, Т.А. Меn’shikova, Lekarstvennye rasteniyav mongol’skoi meditsine (Ulan-Bator, 1978), 192 s [in

Russian]

Amygdalus persica L.

Family: Rosaceae Juss.

Fruit

Cutine

Composition of monomers (GLC/MS, 3% OV-1),

%: Hexadecan-1-ol – 0.47; octadecan-1-ol –

1.42; octadecen-1-ol – tr; eicosan-1-ol – tr;

hexadecane-1,16-diol – 0.91; docosan-1-ol – tr;

octadecane-1,18-diol – 3.20; octadecene-1,18-

diol – 3.69; hexadecanetriol – 32.97;

octadecane-1,9,18-triol – 25.95; octadecene-

1,9,18-triol – 13.62; octadecane-1,9,10,18-tetraol

– 14.66; octadecene-1,9,10,18–tetraol – 3.10 [1]

Seed

Oil

FAs (GLC), %: 14:0 – tr; 15:0 – tr; 16:0 – 5.9–12.3;

16:1 – 0.3–1.1; 17:0 – tr – 0.9; 17:1 – 0.1; 18:0 –

1.2–2.8; 18:1 – 44.6–77.0; 18:2 – 13.7–41.2;

18:3 – tr – 0.1; 20:0 – tr – 0.1; 20:4 – 0.1; 22:0

– tr [2]

References

1. T.J. Walton, P.E. Kolattukudy, Biochemistry 11(10), 1885

(1972)

2. M.I. Goryaev, N.A. Evdakova, Spravochnik pogazozhidkostnoi khromatografii organicheskikh kislot(“Nauka”Kaz. SSR,Alma-Ata, 1977), pp. 104–382 [inRussian]

Amygdalus petunnikowii Tamamsch.

Family: Rosaceae Juss.

Coat of Seed

Lipids, % on dry wt: 0.4 [1]

Kernel of Seed

Oil, % on dry wt: 45.35 [1]; % on abs. dry wt: 58.4 [1]

Seed

Essential oil

T.b.: 172–174�C/720 mm [2]

d2020: 1.0394 [2]

nD: 1.5424 [2]

Mass of 1,000, g: 300 [1]

Oil, % on dry wt: 24.84 [3]

d: 0.9120 [3]

nD: 1.4675 [3]

Absolute viscosity, sp: 75.01 [3]

Hehner value: 95.17 [3]

Iodine value, % J2: 95.9 [3]

Saponification value, mg KОН/g: 191.01 [3]

Thiocyanogen value, % J2: 80.9 [3]

Unsaponifiables, %: 0.51 [3]

FAs

Iodine value, % J2: 101.01 [3]

Mean mol. wt: 263.6 [3]

Neutralization value, mg KOH/g: 212.91 [3]

Thiocyanogen value, % J2: 83.75 [3]

Saturated FAs (Bertram), %: 4.35 [3]

Neutralization value, mg KOH/g: 207.6 [3]

Mean mol. wt of saturated acids: 275.0 [3]

Composition of FAs (GLC, 15% PEGS), %: 10:0 –

0.1; 16:0 – 3.6; 18:0 – 0.7; 18:1 – 66.4–75.0;

18:2 – 20.0–27.3; 18:3–1.9 [3, 4]

(GLC, 10% PEGS), %: 18:2 – 20.4; 18:1 – 75.3 [1]

TAG

Composition, %: SSS – 0.08; SSU – 0.53; SUU –

11.8; UUU – 87.59 [3]

Page 7: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Amygdalus spinosissima Bunge 707 Rosaceae Juss.

Tocopherols

Content, mg%: 21.3 [1]

Composition of tocopherols, mg%: a-Tocopherol –19.1; g-tocopherol – 2.2 [1]

PhL

Content, %: 0.7 [5]

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsovв, Rastit. Resursy13(4), 675 (1977) [in Russian]

2. М.I. Goryaev, Efirnye masla flory SSSR izd. (АN Каz. SSR,Аlma-Аtа, 1952) [in Russian]

3. G.А. Stepanenko,А.U. Umarov,А.L.Маrkman, Chem. Nat.

Comp. 6(4), 410 (1970)

4. М.G. Pakhomova, Мindali Uzbekistana (Таshkent, 1961),233 s [in Russian]

5. K.S. Mukhamedova, R.R. Akbarov, S.Т. Akramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Amygdalus saviczii Pachom.

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 48.4

References

1. M.G. Pakhomova, Mindali Uzbekistana (izd. AN Uzb. SSR,

Tashkent, 1961), 233 s

Amygdalus scoparia Spach

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 100

Oil, % on abs. dry wt: 43.6

FAs (GLC, 10% PEGS), %: 18:2–21.6; 18:1–65.9

Tocopherols

Content, mg%: 39.7

Composition of tocopherols, mg%: a-Tocopherol –37.5; g-tocopherol – 2.2

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

Amygdalus sp.

Family: Rosaceae Juss.

Seed

Oil (methylene chloride), % on dry wt: 38 [1]

Iodine value, % J2: 100.3 [1]

Saponification value, mg KOH: 190.1 [1]

Unsaponifiables

Content, %: 0.9 [1]

Composition of unsaponifiables, %: Less polar

compounds (hydrocarbons, etc.) – 52; triterpene

alcohols (4,4-dimethylsterols) – 4; 4-

methylsterols (4-monomethylsterols) – 4; sterols

(4-desmethylsterols) – 40 [1]

4,4-Dimethylsterols

Composition (GLC: 1.5% OV-17, 1.5% QF-1), %:

Lanostenol – tr; cycloartanol – 5; cycloartenol –

9; 24-methylenecycloartanol – 83 [2]

4-Monomethylsterols

Composition (GLC: 1.5% OV-17, 1.5% QF-1), %:

31-Norlanosterol – 1; obtusifoliol – 17; 31-

norcycloartenol – tr; gramisterol – 30;

citrostadienol – 44 [2]

Sterols

Composition (PTLC, Ag+/TLC, GLC, 1.5%OV-17,

GLC-MS), %: Sterols: cholesterol – tr;

campesterol – 4; stigmasterol – 3; b-sitosterol –77; D5-avenasterol – 12; D7-stigmastenol – 2;

D7-avenasterol – 2 [1]

References

1. T.M. Jeong, T. Itoh, T. Tamura, T. Matsumoto, Lipids 9(11),

921 (1974)

2. T.M. Jeong, T. Itoh, T. Tamura, T. Marsumoto, Lipids 10(10),

634 (1975)

Amygdalus spinosissima Bunge

Family: Rosaceae Juss.

Coat of Seed

Lipids, % on dry wt: 0.64 [1]

Kernel of Seed

Essential oil [2]

Oil, % on dry wt: 45.07–62.0 [1, 3]

Page 8: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 708 Amygdalus turcomanica Lincz. (A. brachuica auct.)

Seed

Mass of 1,000, g: 200 [4]

Oil, % on dry wt: 27.55 [1]; on abs. dry wt: 49.3 [4]

d: 0.9153 [1]

nD: 1.4723 [1]

Absolute viscosity, sp: 74.91 [1]

Hehner value, %: 95.47 [1]

Iodine value, % J2: 97.6 [1]

Saponification value, mg KOH/g: 194.49 [1]

Thiocyanogen value, % J2: 81.6 [1]

Unsaponifiables, %: 0.25 [1]

FAs

Iodine value, % J2: 100.0 [1]

Mean mol. wt: 266.0 [1]

Neutralization value, mg KOH/g: 211.4 [1]

Thiocyanogen value, % J2: 83.1 [1]

Saturated FAs (Bertram), %: 10.02 [1]

Mean mol. wt: 278.6 [1]

Neutralization value, mg KOH/g: 202.0 [1]

Unsaturated FAs, %: 91.7 [4]

Composition of FAs (GLC, 15% PEGS), %: 11:0 –

1.0; 16:0 – 6.9; 18:0 – 2.1; 18:1 – 66.3; 18:2 –

21.6; 18:3 – 2.1 [1]

(GLC, 10% PEGS), %: 18:1–64.8; 18:2–26.9 [4]

TAG

Composition of TAG, %: SSS – 1.0; SSU – 2.7;

SUU – 24.0; UUU – 72.3 [1]

Tocopherols

Content, mg%: 25.8 [4]

Composition of tocopherols (PC), mg%: a-Tocopherol – tr; g-tocopherol – 25.8 [4]

Activity: Fatty oil equals the oil from A. communis bypharmacological activity [5].

References

1. G.А. Stepanenko,А.U. Umarov,А.L.Маrkman, Chem. Nat.

Comp. 6(4), 410 (1970)

2. М.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Аlma-Аtа, 1952) [in Russian]

3. M.G. Pakhomova, Mindali Uzbekistana (izd. AN Uzb. SSR,

Tashkent, 1961), 233 s [in Russian]

4. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

5. Е.I. Кiryushina, In: Rasprostranenie i prirodnye zapasypoleznykh rastenii Uzbekistana (Таshkent, 1974), vyp. 1,

220 [in Russian]

Amygdalus turcomanica Lincz.(A. brachuica auct.)

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 52.64

References

1. М.S. Shalyt, Dikorastushchie poleznye rasteniya TurkmenkoiSSR (Мoscow, 1951), 222 s [in Russian]

Amygdalus vavilovii M. Pop.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 700

Oil, % on abs. dry wt: 52.1

Unsaturated FAs, %: 89.7

Composition of FAs (GLC, 10% PEGS), %: 18:1 –

70.8; 18:2 – 18.9

Tocopherols

Content, mg%: 36.9

Composition of tocopherols (PC), mg%: a-Tocopherol – 16.0; g-tocopherol – 20.9

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

Aphanes arvensis L. (Alchemilla arvensis(L.) Scop.).

Family: Rosaceae Juss.

Seed

Oil

nD: 1.4706–1.4720

Acid value, mg KOH: 1.8

Iodine value, % J2: 80–94

Saponification value, mg KOH/g: 184.6–192.2

Page 9: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Armeniaca vulgaris Lam. (Prunus armeniaca L.) 709 Rosaceae Juss.

References

1. R. Normakhmatov, Т. Khudaishukurov, Маslo-zhirovayapromyshlennost’ (12), 13 (1973) [in Russian]

Armeniaca mandshurica (Maxim.)Skvorts. (Prunus manshurica Kochne,Prunus armeniaca L. var. manshirocaKoehne.)

Family: Rosaceae Juss.

Seed

Essential oilContent (after fermentation), %: 0.6–1.6 [1]

Oil, % on dry wt: 52.44 [2]

References

1. B.N. Rutovckii, EfirnyeMasla (Moskwa-Leningrad, 1932) [in

Russian]

2. Y.V. Branke, Dikorastushchie plody i yagody Dal’nevos-tochnogo kraya (Vladivostok, 1935), 71 s [in Russian]

Armeniaca sibirica (L.) Lam. (Prunussibirica L.)

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 35–48 [1]

Iodine value, % J2: 85–89 [1]

Use: Fatty oil is used for eye drops production for

conjunctivitis treatment [2].

References

1. V.N. Voroshilov, Poiski novogo lekarstvennogo syr’ya(Мoscow, 1941), 255 s [in Russian]

2. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Armeniaca vulgaris Lam. (Prunusarmeniaca L.)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: Carotene, lycopene [1]

Kernel

Moisture, %: 5.56 [2]

Oil, % on dry wt: 40.39 [2]

d15: 0.915–0.921 [3]; d36: 0.9204 [2]

n20D : 1.470–1.476 [3]; n36D : 1.46375 [2]

Acetic value, mg KOH: 4.2 [3]

Acid value, mg KOH: 7.85 [2]

Hehner value, %: 93.0–97.2 [3]

Iodine value, % J2: 90–112 [2, 3]

Polenske value, mL KOH: 0–0.6 [3]

Reichert-Meissl value, mL KOH: 0.1–0.4 [3]

Saponification equiv., mg KOH: 292.2 [2]

Saponification value, mg KOH/g: 178–198 [2, 3]

Saturated acids, %: 2–8 [3]

Thiocyanogen value, % J2: 77–79.2 [3]

Unsaponifiables, %: 0.4–1.38 [2, 3]

Unsaturated acids, %: 97 [3]

FAs (GLC), %: 14:0 – tr – 2.69; 16:0 – 2.1–4.5;

18:0 – 1.0–1.2; 18:1 – 60–79; 18:2 – 18–32;

20:0 – 0.5 [2–4]

Unsaponifiables

Main component: b-Sitosterol [3]

Seed

Essential oilComponent: Benzaldehyde [2]

Oil

FAs (GLC), %: 14:0 – 2.69; 16:0 – 4.4; 18:0 – 1.12;

20:0 – 0.5; 18:1 – 68.4–74.0; 18:3 – 21.0–21.7

[1, 5, 6]

Sterols

Components: D24-Cholesterol (0.91%), sitosterol,

estron, a-estradiol [7]

Use: Fatty oil – solvent for some oils and base of

liniment [8], source of “apricot milk” [9].

Page 10: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 710 Aronia melanocarpa (Michx.) Elliot

References

1. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

2. D.R. Dhingra, U.K. Shukla, Proc. Ann. Convention Oil

Technol. Assoc. India 3(2) (1947); Chem. Abstr. 45 N 8273

(1951)

3. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969)

4. M.Y. Haggag, M.S. Hifnawy, Bull. Fac. Pharm., Cairo Univ.

13(1), 175 (1974); Chem. Abstr. 86, N 40213d (1977)

5. M.I. Goryaev, N.A. Evdakova, Spravochnik pogazozhidkostnoi khromatografii organicheskikh kislot(“Nauka” Kaz. SSR, Alma-Ata, 1977), pp. 104–382 [in

Russian]

6. R.М. Мirzakarimov, А.К. Таdzhiev, N.U. Rizaev, А.U.

Маkhmudov, Uzb. Khim. Zhurn. (5), 68 (1972) [in Russian]

7. O. Awad, Phytochemistry 13(3), 678 (1974)

8. G.К. Shreter, Lekarstvennye rasteniya i rastitel’noe syr’e,vklyuchennye v otechestvennye farmakopei (Мoscow, 1972),

119 s [in Russian]

9. Аtlas lekarstvennykh rastenii SSSR (Мoscow, 1962), 704 s

[in Russian]

Aronia melanocarpa (Michx.) Elliot

Family: Rosaceae Juss.

Fruit

Unsaponifiables, mg/100 g: 44 [1]

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLe – 2.0; LeLeP – 0.5; LLL + LeLO –

48.8; LeLP + LeLeO – 1.0; LLO + LeOO –

26.0; LLP + LeLS + LeOP – 9.0; LOO – 6.7;

LLS + LOP + LeOS – 5.5; LPP + LePS – 0.1;

ОOO – 0.2; LOS + ОOP – 0.2; LPS + ОPP – tr;

ОOS – tr [2]

References

1. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

2. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Cerasus avium (L.) Moench(Prunus avium L.)

Family: Rosaceae Juss.

Seed

Essential oil

Content, %: 1.0 [1]

Oil

FAs: a-Eleostearic – 7.0–13.5; 18:2–2.2 [2, 3]

Use: The oil is used in perfumery and liqueur

industry [1].

References

1. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1947), 550 s [in Russian]

2. J.A. Funes, P. Cattaneo, Ann. Assoc. quim. Argent. 66, N 5,

239 (1978); Chem. Abstr. 93(5), 41530m (1980)

3. A. Popov, Izv. Inst. Obshueva Neorg. Khim., Org. Khim.

Bulg. Akad. Nauk 9, 175 (1962); Chem. Abstr. 59, N 5495

(1963)

Cerasus erythrocarpa Nevski(C. bifrons auct., p.p.)

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 51.08

n420: 0.9140

Absolute viscosity, sp: 0.8443

Acid value, mg KOH: 0.31

Hehner value, %: 94.42

Iodine value, % J2: 96.15

Saponification value, mg KOH/g: 187.9

Thiocyanogen value, % J2: 76.40

Unsaponifiables, %: 0.31

FAs

Iodine value, % J2: 95.47

Mean mol. wt: 280

Neutralization value, mg KOH: 200

Thiocyanogen value, % J2: 82.86

Composition of FAs (GLC, 15% PEGS), %: 16:0 –

4.36; 16:1 – 1.36; 17:0 – tr; 18:0 – 1.21; 18:1 –

73.56; 18:2–19.51

Page 11: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Cerasus vulgaris Mill. 711 Rosaceae Juss.

TAG

Composition, %: SUU – 0.32; UUS – 11.08; SSU –

0.12; SUU – 2.52; UUU – 86.03

References

1. А.U. Umarov, М. Мirzabaeva, Chem. Nat. Comp. 6(6), 764

(1970)

Cerasus fruticosa Pall. (Prunuschamaecerasus Jacq., P. fruticosa Pall.)

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg%: 0.37–0.55 [1]

Seed

Oil, % on dry wt: 37.3 [2]

FAs (GLC), %: 16:0 – 5.6; 18:0 – 1.16; 18:1 – 29.2;

18:2 – 60.5; 18:3 – 0.53; a-eleostearic acid [18:3(9,11,13)] – 3.5 [2]

References

1. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (“Nauka”, Moscow, 1976), 263 s

[in Russian]

2. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Cerasus mahaleb (L.) Mill.

Family: Rosaceae Juss.

Seed

Oil

PhL

Content, %: 1.1

References

1. K.S. Мukhamedova, R.R. Аkbarov, S.Т. Аkramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Cerasus vulgaris Mill.

Family: Rosaceae Juss.

Kernel of Fruit

Essential oil

Content, %:0.3 [1]

Pollen

Oil

TAG

FAs (GLC), %: 10:0 – tr; 12:0 – 1.72; 14:0 – 0.74;

14:1 – 1.09; 15:0 – tr; iso-16:0 – 0.47; 16:0 –

11.66; 16:1 – 0.16; 16:2 – 0.11; 17:0 – 0.12; 17:1

– 0.22; 17:2 – 0.46; 18:0 – 3.03; 18:1 – 10.19;

18:2 – 30.02; 18:3 – 37.91; 19:0 – 0.56; 20:0 –

0.52; 21:0 – 0.40 [2]

Seed

Oil, % on dry wt: 30.68 [3]

n420: 0.9210 [3]

Acid value, mg KOH: 0.39 [3]

Hehner value, %: 95.0 [3]

Iodine value, % J2: 129.67 [3]

Saponification value, mg KOH/g: 179.3 [3]

Thiocyanogen value, % J2: 78.57 [3]

Unsaponifiables, %: 0.39 [3]

FAs

Iodine value, % J2: 131.96 [3]

Mean mol. wt: 277 [3]

Neutralization value, mg KOH: 202 [3]

Thiocyanogen value, % J2: 72.26 [3]

Composition of FAs (GLC, 15% PEGS), %: 10:0 –

1.58; 12:0 – 0.25; 14:0 – 0.2–0.9; 16:0 – 4.3–8.83;

16:1 – tr; 17:0 – 2.92; 18:0 – tr – 2.9; 18:1 – 43.74–

60.8; 18:2 – 30.6–42.0; 18:3 – 3.0; 20:0 – 1.0 [3, 4]

TAG

Composition, %: SSS – 0.29; SUU – 36.08; UUS –

8.09; SSU – 2.26; SUU – 23.79; UUU – 62.49 [3]

References

1. Flora SSSR, X (АN SSSR, Мoskwa-Leningrad, 1941) [in

Russian]

2. V.А. Bandyukova, G.I. Deineko, D.K. Shapiro, Chem. Nat.

Comp. 18(2), 227 (1982)

3. А.U. Umarov, М. Мirzabaeva, Chem. Nat. Comp. 6(6), 764

(1970)

4. M.I. Goryaev, N.A. Evdakova, Spravochnik po gazozhidkostnoikhromatografii organicheskikh kislot (“Nauka”, Kaz. SSR,

Alma-Ata, 1977), pp. 104–382 [in Russian]

Page 12: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 712 Chaenomeles japonica Lindl.

Chaenomeles japonica Lindl.

Family: Rosaceae Juss.

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLeО – 1.3; LeLeP – 0.3; LLL +

LeLO – 17.6; LeLP + LeLe – 1.2; LLO +

LeOO – 28.4; LLP + LeLS + LeOP – 9.4;

LOO – 19.3; LLS + LOP + LeOS – 10.9;

LPP + LePS – 1.2; ОOO – 5.9; LOS + ОOP –

3.9; LPS + ОPP – 0.3; ОOS – 0.4 [1]

PhL

Content, %: 0.5 [2]

References

1. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

2. K.S. Мukhamedova, R.R. Аkbarov, S.Т. Аkramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Coluria geoides (Pall.) Ledeb.

Family: Rosaceae Juss.

Root and Rhizome

Essential oilContent, %: 0.4–1.8 [1–3]

d20: 1.0640–1.0690 [3]

nD: 1.5380–1.5400 [3]

Composition, %: eugenol – 93–98 [1–3]

Use: Essential oil is used in stomatology [2].

References

1. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (Izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

2. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

3. M.I. Goryaev, N.A. Evdakova, Spravochnik po gazozhidkostnoikhromatografii organicheskikh kislot (“Nauka” Kaz. SSR,

Alma-Ata, 1977), pp. 104–382 [in Russian]

Comarum palustre L. (Potentilla palustris(L.) Scop.)

Family: Rosaceae Juss.

Aerial Part

Essential oil

Content, %: 0.03–0.06

Leaf

Carotene

Content, mg%: 18

Seed

Essential oil

Content, %: 0.68

Components: a-Pinene, terpineol, citronellal, methyl

heptenone, iso-valeric and iso-butyric acids

References

1. A.Ph. Gammerman, G.N. Kadaev, A.A. Yatsenko-

Khmelevskii, Lekarstvennye rasteniya (Vysshaya shkola,

Moscow, 1983), 399 s [in Russian]

Cotoneaster melanocarpa Lodd.

Family: Rosaceae Juss.

Fruit

Carotene, mg% on dry wt: 2.8

References

1. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (“Nauka”, Moscow, 1976), 263 s

[in Russian]

Cotoneaster microphylla Wall.

Family: Rosaceae Juss.

Aerial Part

Essential oil

Components: Benzaldehyde, cyanogen acid

Page 13: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Crataegus chlorosarca Maxim. 713 Rosaceae Juss.

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Crataegus almaatensis Pojark.(C. dshungarica Zab.)

Family: Rosaceae Juss.

Bark, Bud, Fruit

Carotene

References

1. Rasrirel’nye resursy SSSR. Tsvetkovye rasteniya, ikh sostav,ispol’zpvanie. Semeistva Hydrangeaceae-Haloragaceae, podred. P.D. Sokolova (“Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Crataegus altaica (Loud.) Lange

Family: Rosaceae Juss.

Bark

Oil [1]

Flower

Essential oil, %: 0.1–0.16 [1, 2]

Fruit

Carotene [3]

References

1. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1947), 550 s [in Russian]

2. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (Izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

3. V.P. Petrova, Ukr. Botan. Zhurn. 29(2), 144 (1972) [in

Ukrainian]

Crataegus atrofusca Stev. ex Fisch. etMey.

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus caucasica C. Koch

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % of fresh wt: 0.09

References

1. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

Crataegus ceratocarpa Kossych

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus chlorosarca Maxim.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg%: 6.42 (on fresh wt); 19.28 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Page 14: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 714 Crataegus curvisepala Lindm. (C. kyrtostyla auct., C. oxyacantha auct.)

Crataegus curvisepala Lindm.(C. kyrtostyla auct., C. oxyacantha auct.)

Family: Rosaceae Juss.

Flower

Essential oil

Content, %: 0.15 [1]

Fruit

Carotenoids

Content, % of fresh wt: 0.98 [2]

Triterpenoic acids

Components: Oleanolic acid, ursolic acid [3]

References

1. V.N. Voroshilov, Poiski novogo lekarstvennogo rastitel’nogosyr’ya (Мoscow, 1941), 255 s [in Russian]

2. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

3. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus dahurica Koehne ex Schneid.

Family: Rosaceae Juss.

Bark, Bud

Carotene [1]

Flower

Sterols [2]

Triterpenoic acids [2]

Fruit

Sterols [2]

Triterpenoic acids [2]

Leaf

Sterols [2]

Triterpenoic acids [2]

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

2. V.I. Bykov, In: Voprosy farmatsii na Dal’nem Vostoke (Kha-barovsk, 1973), vyp. 1, 80 [in Russian]

Crataegus densiflora Sarg.

Family: Rosaceae Juss.

Fruit

Carotene, mg%: 0.75 (on fresh wt); 2.33 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus dipyrena Pojark.

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus intricata Lge

Family: Rosaceae Juss.

Fruit

Carotene, mg%: 1.40 (on fresh wt); 3.92 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus macrosperma Ashe

Family: Rosaceae Juss.

Fruit

Carotene, mg%: 2.0 (on fresh wt); 5.47 (on dry wt)

Page 15: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Crataegus monogyna Jacq. 715 Rosaceae Juss.

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus maximowiczii Schneid.

Family: Rosaceae Juss.

Bark, Bud

Carotene [1]

Flower

Triterpenoic acids [2]

Fruit

Triterpenoic acids [2]

Leaf

Triterpenoic acids [2]

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

2. V.I. Bykov, In: Voprosy farmatsii na Dal’nem Vostoke (Kha-barovsk, 1973), vyp. 1, 80 [in Russian]

Crataegus microphylla C. Koch(C. lagenaria Fisch. et Mey.)

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus mollis (Torr. & A. Gray)

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 9.0 [1, 2]

Oil, % on dry wt: 31.0–31.3 [1, 2]

n40D : 1.4676 [1]

Iodine value, % J2: 128 [1]

Saponification value, mg KOH/g: 183 [1]

FAs

Diene as C18-acid, %: nonconjugated – 50; conju-

gated – 1.0 [1]

Epoxy acids C18 (HBr), %: 2.5 [1]

Monoene as 18:1, %: 38 [1]

Saturated, %: 6 [1]

Triene as C18-acid, %: conjugated – 0.1 [1]

References

1. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37(9), 440 (1960)

2. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Crataegus monogyna Jacq.

Family: Rosaceae Juss.

Bark, Bud

Carotene [1]

Flower

Carotene [1]

Fruit

Lipids

Components: n-Triacontane, 1-nonacosanol, b-sitosterol, ursolic acid, crataegolic acid, caffeic

and oleanolic acids [2]

Carotenoids

Content, mg/g: 0.20 [3]

Composition, %: Phytofluene – tr; a-carotene – 0.5;

b-carotene – 20.8; cryptoxanthin – 7.8; 5,6:5060-diepoxy-b-carotene – 14.5; violaxanthin – 52.5 [3]

Leaf

Triterpenoic acids

Components: Oleanolic acid, ursolic acid [4]

Carotene [1]

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Page 16: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 716 Crataegus orientalis Pall. ex Bieb.

2. A. Ulubelen, S. Kartin, Istanbul €univ. Eczacilik. Fak. Mecm.

7(2), 67 (1971); Chem. Abstr. 77, N 72595k (1972)

3. L.R.G. Valadon, A.M. Sellens, R.S. Mummery, Ann. Bot.

39(162), 785 (1975)

4. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus orientalis Pall. ex Bieb.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % on fresh wt: 0.93 [1]

Triterpenoic acids

Components: Oleanolic acid, ursolic acid [2]

References

1. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

2. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus pentagyna Waldst. et Kit.

Family: Rosaceae Juss.

Fruit

Essential oil [1]

Carotenoids

Content, % of fresh wt: 0.13 [2]

Component: Carotene [3]

Content of carotene, mg%, 1.83 (on fresh wt); 5.05

(on dry wt) [3]

Triterpenoic acids

Components: Oleanolic acid, ursolic acid [4]

References

1. D.Y. Guseinov, Farmakol. i toksikol. 26(4), 435 (1963) [in

Russian]

2. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

3. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

4. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus pinnatifida Bunge

Family: Rosaceae Juss.

Bark, Bud

Carotene [1]

Flower

Triterpenoic acids [2]

Fruit

Carotene [1]

Content, mg%, 1.17 (on freshwt); 2.63 (ondrywt) [3]

Triterpenoic acids [2]

Leaf

Triterpenoic acids [2]

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

2. V.I. Bykov, In: Voprosy farmatsii na Dal’nem Vostoke(Khabarovsk, 1973), vyp. 1, 80 (in Russian)

3. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus pojarkovae Kossych

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus rivularis Nutt

Family: Rosaceae Juss.

Fruit

Carotene, mg%: 18.20 (on fresh wt); 67.91 (on dry wt)

Page 17: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Crataegus sphaenohylla Pojark. 717 Rosaceae Juss.

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus rotundifolia Moench.

Family: Rosaceae Juss.

Fruit

Carotene, mg%: 1.07 (on fresh wt); 3.59 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus sanguinea Pall.

Family: Rosaceae Juss.

Flower

Essential oil [1]

Fruit

Carotenoids

Content, mg% on fresh wt: 5.8 [2]

Component: carotene [3, 4]

Content of carotene, mg%: on fresh wt 0.25–0.5 [4];

on dry wt 5.8–30 mg [3]

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLeО – 0.7; LeLeP – tr; LLL +

LeLO – 29.3; LeLP + LeLe – 1.1; LLO +

LeOO – 27.0; LLP + LeLS + LeOP – 9.0;

LOO – 15.2; LLS + LOP + LeOS – 7.5; LPP +

LePS – 0.5; ОOO – 6.1; LOS + ОOP – 2.7;

LPS + ОPP – 0.5; ОOS – 0.5 [5]

References

1. Е.А. Romanovskaya, Vest. sel.-khoz. naukiКаzakhstana (5),113 (1978) [in Russian]

2. Dikorastushchie i introdutsiruemye poleznye rasteniyav Bashkirii, vyp. 1 (АN SSSR, Bashkirskii philial, institute

biologii, Ufa, 1961) [in Russian]

3. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (izd. “Nauka”, Moscow, 1976),

263 s [in Russian]

4. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

5. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Crataegus songarica C. Koch

Family: Rosaceae Juss.

Fruit

Carotene

References

1. V.P. Petrova, Ukr. Botan. Zhurn. 29(2), 144 (1972) [in

Ukrainian]

Crataegus sorbifolia Lge

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg%: 4.18 (on fresh wt); 12.86 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus sphaenohylla Pojark.

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Page 18: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 718 Crataegus stankovii Kossych

Crataegus stankovii Kossych

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus stevenii Pojark.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg%: 0.90 (on fresh wt); 2.00 (on dry wt)

[1]

Triterpenoic acids

Components: Oleanolic acid, ursolic acid [2]

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

2. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus submollis Sarg.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg%: 22.0 (on fresh wt); 74.0 (on dry wt)

References

1. E.Z. Babareka, Vestsi AN Bel. SSR, ser. biyal. navuk (4), 42

(1964) [in Byelorussian]

Crataegus taurica Pojark.

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus tournefortii Griseb.(C. schraderiana Ledeb.)

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Components: Oleanolic acid, ursolic acid

References

1. L.R. Shcherbanivskii, V.М. Коsikh, Ukr. Botan. Zhurn.

27(6), 763 (1970) [in Ukrainian]

Crataegus turkestanica Pojark.

Family: Rosaceae Juss.

Pericarp

PhL

Content, % on dry wt: 0.21

Composition, %: PhI – 10.3; PhC – 60.1; PhG – tr;

PhS – 1.7; PhE – 23.8

FAs of total PhL (GLC, 15% PEGS), %: 14:0 – 0.2;

16:0 – 40.7; 16:1 – 1.4; 18:0 – 2.0; 18:1 – 4.8;

18:2 – 36.3; 18:3–6.3

PhC

FAs total (GLC, 15% PEGS), %: 14:0 – 0.4; 16:0 –

86.7; 16:1 – 0.3; 18:1 – 4.9; 18:2 – 40.5; 18:3 – 6.9

sn-1-position (GLC, 15% PEGS), %: 14:0 – 0.4;

16:0 – 86.7; 16:1 – 0.6; 18:1 – 7.5; 18:2 – 3.7

Page 19: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Cydonia oblonga Mill. (C. vulgaris Pers.) 719 Rosaceae Juss.

sn-2-position (GLC, 15% PEGS), %: 14:0 – 0.4;

16:0 – 4.5; 16:1 – 0.6; 18:1 – 2.3; 18:2 – 77.3;

18:3 – 13.8

PhE

FAs total (GLC, 15% PEGS), %: 12:0 – 0.1; 14:0 –

0.1; 16:0 – 53.8; 18:0 – 1.6; 18:1 – 1.9; 18:2 –

34.5; 18:3 – 3.3

sn-1-position (GLC, 15% PEGS), %: 16:0 – 75.9;

18:0 – 2.6; 18:1 – 2.9; 18:2 – 14.9

sn-2-position (GLC, 15% PEGS), %: 12:0 – 0.2;

14:0 – 0.2; 16:0 – 31.7; 18:0 – 0.6; 18:1 – 0.9;

18:2 – 54.1; 18:3 – 6.6

PhI

FAs total (GLC, 15% PEGS), %: 12:0 – 0.3; 14:0 –

0.5; 16:0 – 61.7; 16:1 – 1.4; 16:2 – 1.1; 18:0 – tr;

18:1 – 2.1; 18:2 – 14.9; 18:3 – 7.4

sn-1-position (GLC, 15% PEGS), %: 16:0 – 100;

16:1 – tr; 18:0 – tr

sn-2-position (GLC, 15% PEGS), %: 12:0 – 0.6;

14:0 – 1.0; 16:0 – 34.2; 16:1 – 2.8; 16:2 – 2.2;

18:1 – 4.2; 18:2 – 29.8; 18:3 – 14.8

References

1. P.Y. Gazizov, А.I. Glushenkova, Chem. Nat. Comp. 31(4),

465 (1995)

Cydonia oblonga Mill. (C. vulgaris Pers.)

Family: Rosaceae

Fruit

Essential oil

Content, % on fresh wt: 0.0076 [1]

Lipids (benzene)

Acid part

FAs (GLC): 16:0; 18:1; 18:2 [1]

Neutral part

Components: Paraffins C23, C25, C27 and C29, b-sitosterol, saringosterol, uvaol, ursolic acid (10

mg%) [1]

Ethyl esters

FAs: 6:0; 8:0; 10:0; 12:0 [2]

Fruit and Leaf

Lipids (petrol ether)

Ursolic acid, %: 1.5 [3]

Lipids (chloroform)

Ursolic acid, %: 1 [3]

Leaf

Essential oil

Content, % on dry wt: 4.48; on abs. dry wt: 4.63 [4]

Moisture, %: 8.24 [4]

Lipids

Content, % on air-dry wt: 1.18; on abs. dry wt: 1.28

[4]

Vitamin E

Content, mg% on air-dry wt: 108.5; on abs. dry wt:

118.2 [4]

Peel of Fruit

Essential oil [5, 6]

Headspace sampling, by the method of Yabumoto

Composition (GLC/MS, capillary column DB-

WAX), %: Acetaldehyde – tr; ethyl acetate –

22.83; ethanol – 12.02; ethyl propionate – 29.23;

ethyl isobutyrate – 9.6; isobutyl acetate – 0.95; 2-

butanol – 0.31; ethyl butyrate – 5.38; ethyl 2-

methylbutyrate – 1.71; butyl acetate – 0.40;

isobutyl propionate – 0.50; isobutyl isobutyrate –

0.76; ethyl 3-butenoate – tr; 2-methyl-1-propanol

– 8.43; isoamyl acetate – 0.34; ethyl pentanoate –

0.15; butyl isobutyrate – 0.06; isobutyl butyrate –

tr; ethyl 2-butenoate – 1.11; butanol – 0.21; lim-

onene – 0.23; butyl butyrate – tr; (E)-2-hexenal –

0.58; ethyl hexanoate – 1.91; amyl alcohol – tr;

hexyl acetate – 0.68; ethyl 3-hexenoate – tr; (Z)-3-

hexenyl acetate – 0.58; (E)-2-hexenyl acetate –

0.08; hexanol – 0.80; (Z)-3-hexenol – 0.47; (E)-2-hexenol – 0.19; ethyl octanoate – tr; acetic acid –

tr [5]

Simultaneous distillation and extraction (SDE), bya modified method of Likens and Nickerson

Composition (GLC/MS, capillary column DB-

WAX), %: Acetone – tr; ethyl acetate – 4.7;

ethyl propionate – 0.18; diacetyl – tr; ethyl buty-

rate – 0.22; ethyl 2-methylbutyrate – tr; hexanal

– 0.44; 2-methyl-1-propanol – 1.73; butanol –

0.39; ethyl 2-methyl-2-propionate – 0.33;

heptanal – tr; isoamyl alcohol – 0.78; (E)-2-

hexenal – 0.20; ethyl hexanoate – 1.43;

amyl alcohol – tr; hexyl acetate – 1.01; acetoin –

0.84; (Z)-3-hexenyl acetate – 0.28; (E)-2-hexenyl

Page 20: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 720 Dasiphora fruticosa (L.) Rydb.

acetate + ethyl heptanoate – 0.81; hexyl

isobutyrate – 0.79; isobutyl hexanoate – tr;

hexanol – 5.58; (Z)-3-hexenol – 2.95; (E)-2-

hexenol – 1.93; hexyl butyrate – 0.69; (E)-2-

octenal – tr; hexyl 2-methylbutyrate – tr; ethyl

octanoate – 6.37; furfural – 1.22; (Z)-3-hexenyl

butyrate – tr; ethyl (E)-6-octenoate – 0.65; ethyl

(Z)-6-octenoate – 1.45; (E)- or (Z)-theaspirane –

tr; benzaldehyde – 0.65; ethyl 3-hydroxybutyrate

– 1.19; propyl octanoate – tr; (E)- or (Z)-theaspirane – 0.40; ethyl nonanoate – tr; isobutyl

octanoate – 3.02; isobutyric acid – tr; ethyl (E)-6-

nonenoate – tr; ethyl (Z)-6-nonenoate – 0.48;

butyl octanoate – tr; ethyl decanoate – 3.08;

ethyl (E)-4-decenoate – 5.62; ethyl (Z)-4-

decenoate – 4.96; trans-a-farnesene – 5.92; ethyl

dodecanoate + unknown – 13.65; ethyl (E)-

dodecanoate – 3.26; b-ionone – 0.73; eugenyl

methyl ether – 1.65; ethyl tetradecanoate – tr;

ethyl (E)-9-tetradecenate – tr; capric acid – tr;

ethyl (Z)-9-tetradecenate – 1.79; g-decalactone –tr; 2,7-dimethyl-4-hydroxy-5 (E); 7-octadienoicacid lactone (stereoisomers) – 1.82; eugenol –

0.79; 2,7-dimethyl-4-hydroxy-5 (E), 7-

octadienoic acid lactone (stereoisomers) – 1.95;

anisyl propionate – 0.28; 1,2,3-trimethyl-5-(2-

propenyl)benzene – tr; ethyl hexadecanoate – tr;

g-dodecalactone – tr [5]In addition: Linalool, citral, a-terpineol, D3-carene,

trans-b-farnesene, dodecane, methanol, 1-

propanol, 3-methylbutanol, 2-methylbutanol, 2-

methyl-2-buten-1-оl, 1-octanol, 2-

phenylethanol, benzyl alcohol, 3-methylbutanal,

2-methylbutanal,2-methyl-2-butenal (tiglinicalde-

hyde), 5-methylfurfurol, 2-butanone, 2-heptanone,

2-methyl-2-hepten-6-one, 2-octanone, 5-

nonanone, 2-nonanone, 2-decanone, 2-

pentadecanone, diethyl ether, 3-methyl-

butylformiate, ethyl crotonate, ethyl-3-

methylbutyrate, 3-methylbutylacetate, methyl

hexanoate, ethylcinnamoate, ethyl-2-methyl-2-

butenoate, ethyl-3-hexanoate, propyl-2-methyl-2-

butenoate, ethyl-2-hexenoate, ethylheptanoate, 3-

methylbutyl-3-methylbutyrate, heptylacetate, 2-

methylbutyl-3-methylbutyrate, methyloctanoate,

2-methylpropylhexanoate, ethylbenzoate, 3-

methylbutylbenzoate, propylacetate, g-caprolactone [6]

Seed

Oil, % on abs. dry wt: 15.0–29.3 [7–9]

d204 : 0.9236 [7]

n20D : 1.4728 [7]

Iodine value, % J2: 120 [7]; 107.6 [9]

Unsaponifiables, %: 0.94 [7]

FAs (GLC, PEGS), %: 16:0 – 5.5; 18:0 – 0.8; 18:1 –

39.2; 18:2 – 54.5; 18:3 – tr [7]

Use: Essential oil is used in liqueur and lemonade

production [10].

References

1. H. Shibata, S. Maejima, S. Shimizu, Agric. Biol. Chem.

42(8), 1589 (1978)

2. Shimizu S., Yoshihara S., Agric. Biol. Chem. 41, 1525

(1977)

3. А.М. Аliev, I.S. Movsumov, Chem. Nat. Comp. 12(3), 352

(1976)

4. R.K. Aliev, P.A. Yuzbashinskaya, A.I. Ismailov, A.K.

Rakhimova, Izv. АN Azer. SSR, ser. biol. i med. nauk (6),

117 (1961) [in Russian]

5. K. Umano, A. Shoji, Y. Hagi, T. Shibamoto, J. Agric. Food

Chem. 34(4), 593 (1986)

6. Z. Schreyen. P. Dirinck, P. Sandra, N. Schamp, J.

Agric. Food Chem. 27(4), 872 (1979)

7. D.А. Rakhimov, Е.S. Kondratenko, K. Ubaev, А.U.

Umarov, Chem. Nat. Comp. 19(2), 226 (1983)

8. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti 5 (Leningrad, 1969) [in Russian]

9. E. Bures, J. Satek, Cas. lek. cesk. (8), 187 (1928); Chem.

Abstr. 23, N 3364 (1929)

10. М.I. Goryaev, Efirnye masla flory SSSR (izd. АN Kazakh.

SSR, Аlma-Аta, 1952) [in Russian]

Dasiphora fruticosa (L.) Rydb.

Family: Rosaceae Juss.

Leaf

Carotene

Content, mg%: 17.5

References

1. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

Page 21: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Filipendula denudata (J. et C. Presl) Fritsch 721 Rosaceae Juss.

Dryas octopetala L.

Family: Rosaceae Juss.

Seed

Oil (petrol), % on dry wt: 7.0

FAs (GLC, 15% DEGS on Chromosorb W AW

DMCS), %: 16:0 – 5.7; 16:1 – tr; 18:0 – 2.8;

18:1 – 19.9; 18:2 – 57.0; 18:3 – 11.1; other – 3.4

References

1. C.M. Scrimgeour, Lipids 11(12), 877 (1976)

Eriobotria japonica Lind.

Family: Rosaceae Juss.

Seed

Essential oil

Content, %: 0.016

Component: Cyanogen acid

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Exochorda racemosa (L.) Rehd.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 6.0 [1]

Oil, % on dry wt: 27.7 [1]

Epicuticular wax

Content, %: 30.1 [2]

Secondary alcohols

Composition, C27-7-ol – 0.1; C27-8-ol – 0.4; C27-9-

ol – 0.4; C27-10-ol – 0.2; C28-8-ol – tr; C28-9-ol –

0.2; C28-10-ol – 0.1; C29-9-ol – 2.3; C29-10-ol –

93.0; C29-11-ol – 1.0; C30 – 0.4; C31-9-ol – tr;

C31-10-ol – 1.0; C31-11-ol – 0.9 [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

2. P.J. Holloway, C.E. Jeffree, E.A. Baker, Phytochemistry

15(11), 1768 (1976)

Filipendula angustifolia (Turcz.) Maxim.(Spiraea lobata b-angustifolia Turcz.; S.digitata glabra Ldb.; S. argunensis Ldb.)

Family: Rosaceae Juss.

Whole Plant

Essential oil

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Filipendula camtschatica (Pall.) Maxim.(Spiraea camtschatica Pall.)

Family: Rosaceae Juss.

Whole Plant

Essential oil

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1932),

578 s [in Russian]

Filipendula denudata (J. et C. Presl)Fritsch

Family: Rosaceae Juss.

Flower

Essential oil

Components (GLC, 10% PEGA on Chromosorb

W): Benzaldehyde, ethylbenzoate, salicylic

aldehyde, methyl salicylate, benzyl alcohol,

heliotropin, vanilin

Page 22: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 722 Filipendula hexapetala Gilib.

References

1. N.А. Saiphullina, I.S. Коzhina, Rastit. Resursy XI(4), 542

(1975) [in Russian]

Filipendula hexapetala Gilib.

Family: Rosaceae Juss.

Aerial Part

Lipids

Content, % on dry wt: 4.1

References

1. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (izd. “Nauka”, Moscow, 1976),

263 s [in Russian]

Filipendula palmate (Pall.) Maxim.(Spiraea palmate Pall.; S. digitata Willd.,Ulmaria palmate Focke.)

Family: Rosaceae Juss.

Whole Plant

Essential oil

Content, %: 1.25

References

1. М.I. Goryaev, Efirnye masla flory SSSR (izd. АN Kazakh.

SSR, Аlma-Аta, 1952) [in Russian]

Filipendula stepposa Juz.

Family: Rosaceae Juss.

Flower

Essential oil

Content, %: 0.2

Components (GLC, 10% PEGA on Chromosorb

W): Benzaldehyde, ethylbenzoate, salicylic

aldehyde, methylsalicylate, benzyl alcohol,

heliotropin, vanilin

References

1. N.А. Saiphullina, I.S. Коzhina, Rastit. Resursy XI(4), 542

(1975) [in Russian]

Filipendula ulmaria (L.) Maxim. (Spiraeaulmaria L., S. glauca Schal., Ulmariapentapetala Gilib., Ulmaria palustrisMoench.)

Family: Rosaceae Juss.

Aerial Part

Lipids

Content, %: 3.2–3.4 [1]

Flower

Essential oil

Content, % on dry wt: 0.06–0.2 [2–4]

Components (GLC, 10% PEGA on Chromosorb

W): Benzaldehyde, ethylbenzoate, methyl salic-

ylate, benzyl alcohol, heliotropin, vanillin [2]

(GC/MS), %: Salicylaldehyde – 74.8; phenethyl

alcohol – 2.8; benzyl alcohol – 2.1;

4-methoxybenzaldehyde – 2.0; methyl salicylate

– 1.3 [5]

(Capillar column, SE-30, Carbowax), %: Hexanal,

2-hexenal, salicylaldehyde – 36; limonene, lin-

alool – 2.7; nonanal, 2-amylfuran, menthon,

menthol, methyl salicylate – 19; a-terpineol –1.3; carvon, piperiton, p-anisaldehyde, geraniol –

1.4; trans-anethol – 2.2; carvacral, thymol,

benzaldehyde, b-ionone – 1.8; dibutyl/

diisobutylphtalate [6]

Inflorescence

Essential oilContent, %: 0.2 [7, 8]

Composition (GLC, Reoplex-400, PEGS), %:

Salicylic aldehyde – 70; methyl salicylate,

geliotropin, vanillin, benzaldehyde, ethyl benzo-

ate, phenylethylphenyl acetate, benzyl alcohol,

5-hydroxymethylfurfural [7, 8]

Leaf with Branch

Essential oil, %: 0.1 [4]

Pollen

Triterpenoic acids [9]

Carotenoids [9]

Page 23: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Fragaria sp. 723 Rosaceae Juss.

Root

Essential oil, %: 0.06 [3, 4]

Component: Salicylaldehyde [3], methyl salicylate

[4]

Seed

Oil, % on dry wt: 14.0 [9]

FAs: 18:1; 18:2; 18:3 [9]

References

1. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (izd. “Nauka”, Moscow, 1976),

263 s [in Russian]

2. N.А. Saiphullina, I.S. Коzhina, Rastit. Resursy XI(4), 542

(1975) [in Russian]

3. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1938), 550 s [in Russian]

4. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

5. A. Lindeman, P. Jounela-Eriksson, M. Lounasmaa,

Lebensmitt.-Wiss. Technol. 15(5), 286 (1982); Chem. Abstr.

98, N 3664d (1983)

6. M.G. Valle, G.M. Nano, S. Tira, Planta Med. 54(2), 181 (1988)

7. S.А. Коzhin, Y.G. Silina, Rastit. Resursy 7, vyp. 4, 567

(1971) [in Russian]

8. О.D. Barnaulovв, А.V. Kumkov, N.А. Khalikova, I.S.

Kozhina, B.А. Shukhobodskii, Rastit. Resursy 13(4), 661

(1977) [in Russian]

9. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Filipendula vulgaris Moench (F.hexapetala Gilib.)

Family: Rosaceae Juss.

Leaf

Essential oil

Component: Salicylaldehyde [1]

Pollen

Triterpenoic acids [2]

Carotene [2]

References

1. A.Ph. Gammerman, G.N. Kadaev, A.A. Yatsenko-

Khmelevskii, Lekarstvennye rasteniya (Vysshaya shkola,

Moscow, 1983), 399 s [in Russian]

2. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Fragaria ananassa Duch.

Family: Rosaceae Juss.

Fruit

Moisture, %: 89.6 [1]

Unsaponifiables, mg/100 g on fresh wt: 20 [2]

Tocopherols and tocotrienols

Content, ppm on fresh wt: 2.2 [3]

Composition, mg/100 g on fresh wt: a-Tocopherol –0.56; b-tocopherol – tr; g-tocopherol – 0.15; d-tocopherol – tr [1]

Carotenoids

Composition (HPLC), mg/100 g on fresh wt: b-Carotene – 8.9–39; lutein – 31–42; lycopene 1.5 [4]

References

1. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen, P.

Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

2. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

3. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

4. M.I. Heinonen, V. Ollilainen, E.K. Linkola, P.T. Varo, P.E.

Koivistoinen, J. Agric. Food Chem. 37(3), 655 (1989)

Fragaria sp.

Family: Rosaceae Juss.

Fruit

Lipids (diethyl ether with 10% MeOH)

Organic acids

Components (GC/MS, Carbowax 20M): Propionic,

butyric, isobutyric, 2-methylbutyric, valeric,

isovaleric, hexanoic, isohexanoic, heptanoic,

isoheptanoic, octanoic, nonanoic, decanoic,

undecanoic, dodecanoic, palmitic, 2-methyl-

2-butenoic, methylbutenedioic, 2-methyl-cis-3-pentenoic, 2-methyl-trans-3-pentenoic, 2-

methyl-2-pentenoic, 2-hexenoic, 2-octenoic,

3-nonenoic, 3-hydroxyhexanoic,

3-hydroxyoctanoic, phenylacetic,

phenylpropionic, benzoic, 4-methylbenzoic,

cinnamic, furoic, succinic, glutaric

References

1. C.J. Mussinan, J.P. Walradt, J. Agric. Food. Chem. 23(3),

482–484 (1975)

Page 24: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 724 Fragaria vesca L.

Fragaria vesca L.

Family: Rosaceae Juss.

Fruit

Essential oil

Composition (combined GC-MS), mg/kg: acids:

Acetic acid – 0.45–1.5; propanoic acid, 2-

methylpropanoic acid – tr – 0.20; butanoic acid

– 0.45–0.65; 2-methylbutanoic acid – tr – 0.80;

hexanoic acid – 0.85–1.2; octanoic acid, decanoic

acid, dodecanoic acid, tetradecanoic acid – tr –

0.40; hexadecanoic acid – tr – 2.1; trans-cinnamic

acid – tr – 0.50; alcohols: ethanol, 3-methyl-2-

butanol – tr – 0.05; 3-methyl-1-butanol,

1-pentanol – tr – 0.05; 3-penten-1-ol – tr – 0.05;

1-hexanol – 0.20–0.50; trans-2-hexen-1-ol – 0.1–0.65, cis-3-hexen-1-ol – tr – 0.05; 2-ethyl-1-

hexanol; 1-heptanol – tr – 0.05; 2-heptanol –

0.05–0.10; 6-methyl-5-hepten-2-ol, 1-octanol –

tr – 0.05; 2-nonanol – tr – 0.15; 1-decanol, 2-

undecanol, 2-tridecanol, 2-pentadecanol – tr –

0.30; linalool – tr – 0.15; a-terpineol, citronellol,methanol, benzyl alcohol – tr – 0.45; 2-

phenylethanol, 3-phenylpropanol, trans-cinnamyl

alcohol; carbonyl compounds: hexanal, 2-hexenal– tr – 0.05; 2-heptanone – 0.15–0.30; 2-nonanone

– tr – 0.15; 2-undecanone, 2-tridecanone, 2-

pentadecanone – tr – 0.45; acetoin – tr – 0.05;

benzaldehyde, verbenone, vanillin; esters: butyl

formate – tr – 0.10; hexyl formate – tr – 0.05; ethyl

acetate – 0.05–0.10; butyl acetate, 3-methyl-2-

butenyl acetate – tr – 0.05; hexyl acetate – tr –

0.10; trans-2-hexenyl acetate – tr – 0.05; cis-3-

hexenyl acetate, octyl acetate – tr – 0.05; decyl

acetate – tr – 0.05; ethylacetoacetate, benzyl ace-

tate, carveyl acetate – tr – 0.05; methyl butanoate

– 0.20–0.50; ethyl butanoate – 0.15–0.30; hexyl

butanoate, decyl butanoate, ethyl crotonate,

methyl hexanoate, ethyl hexanoate – tr – 0.15;

methyl decanoate, methyl dodecanoate, methyl

salicylate, methyl nicotinate, methyl cinnamate,

methyl anthranilate, methyl N-formylan-

thranilate; miscellaneous: diethyl ether, pentane,dichloromethane, chloroform, dodecane,

tetradecane, pentadecane, styrene,

phenylacetylene, linalool oxide (five-membered),

linalool oxide (six-membered), g-hexalactone,g-heptalactone, d-hexalactone, g-octalactone, d-octalactone, 2,5-dimethyl-4-methoxy-3(2H)-

furanone – 0.20–1.7; 2-methoxy-4-vinylphenol,

4-vinylphenol – tr – 0.05; eugenol – tr – 0.25 [1, 2]

Components (GC/MS): Hydrocarbons: 1,1-

Diethoxyethane, 1,1-diethoxypropane, 1,1-

diethoxypentane, 1,1-diethoxyoctane, 1,1-

methoxybutoxyethen, 1,1-ethoxypropoxyethane,

1,1-ethoxybutoxyethane, 1,1-methoxybu-

toxyethane, 1,1-diethoxybutane, 2-hydroxy-3-

methylbutane, 1,1-ethoxybutoxyethane, 1,1-

methoxypentoxyethane, 1,1-methoxypen-

toxyethane, 1,1-diethoxypentane, 1,1-ethoxypen-

toxyethane, 1,1-methoxyhexoxyethane, 1,1-

diethoxyhexane, 1,1-ethoxyhexoxyethane, 1,1-

ethoxyhex-3-ethoxyethane, 1,1-di-n-

hexoxyethane, 1,1-dihexenoxyethane; alcohols:

2-methyl-1-butanol, 2-methylbutane-2-ol, n-buta-nol, 2-pentanol; esters:methyl a-methylbutanoate,

isoamyl formate, amyl formate, ethyl n-butyrate,

ethyl a-methylbutanoate, ethyl isovalerate, 2-hexyl

acetate, isoamyl acetate, methyl n-hexanoate, ethyl

n-hexanoate, isopropyl hexanoate, ethyl

heptanoate, hexenyl acetate, butyl hexanoate,

methyl octanoate, n-butyl n-hexanoate, n-hexyl n-

butyrate, pentyl hexanoate, pentyl hexanoate,

pentenyl hexanoate, ethyl benzoate, n-hexyl n-hexanoate, cis-3-hexen-1-yl-caproate, ethyl n-

decanoate, trans-3-hexen-1-yl caproate, 2-hexen-

1-yl caproate, pentyl octanoate, b-phenylethyl ace-tate, hexyl octanoate, ethyl dodecanoate, hexenyl

octanoate, cis-ethyl cinnamate, trans-methyl

cinnamate, trans ethyl cinnamate, ethyl octanoate,

butyl a-methylbutyrate;miscellaneous: furfurol, 2-

acetylfuran, benzaldehyde, methylfurfurol,

acetophenone, naphthalene, 2-methylnaphthalene,

1-methylnaphthalene [2, 3];

In addition: Hydrocarbons: Terpine, isopentane,

dimethoxymethane, dimethoxy-1,1-ethan,

methoxy-1-ethoxy-1-ethan, methyl a-methylbutyrate, ethyl a-methylbutyrate,

methylpentane, n-hexane, methylcyclopentane,

2-methyl-1-penten, cyclohexane; acids: formyl

acid, capronic acid, benzoic acid, salicylic acid;

alcohols: methanol, n-propanol, butanol-1, buta-nol-2, isobutanol, pentanol-2, hexen-2-ol-trans,

Page 25: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Fragaria virginiana Mill. 725 Rosaceae Juss.

ethyl-2-hexanol, borneol, p-hydroxyphenyl-2-

ethanol; esters: methylacetate, ethyl propionate,

methylisovaleriate, methylbutyrate, methyl

isobutyrate, ethyl isobutyrate, ethyl valerate,

ethyl caproate, ethyl salicylate, propyl acetate,

ethyl propionate, methyl butyrate, isopropyl-

butyrate, methyl caproate, ethyl caproate,

hexen-2-yl-trans butyrate; carbonyl compounds:

acetaldehyde, acetone, methyl-3-butanone-2,

crotonal, propanal, penten-2-al, cis-hexen-3-al,pentanone-2, heptanone; miscellaneous: acro-

lein, benzol, 2,5-dimethyl-4-methoxy-3-methyl-

naphthalene, g-decalactone [4–6]Composition of acids, %: Formyl – 1.5; acetyl – 2.2;

propionic – 1.1; n-butyric – 1.1; isobutyric – 8.1;

(+)-a-methylbutyric – 40; caproic – 40 [7]

Neutral lipids

Content, %: 15 [8]

FAs (GLC), %: 16:0 – 3.9; 16:1 – 0.2; 18:0 – 1.8;

18:1 – 17.8; 18:2 – 37.8; 18:3 – 37.7; 20:1 – 0.8 [8]

PhL

FAs (GLC), %: 16:0 – 10.4; 18:0 – 3.6; 18:1 – 19.1;

18:2 – 48.0; 18:3 – 17.8 [8]

GL

FAs (GLC), %: 16:0 – 15.2; 18:0 – 1.5; 18:1 – 23.0;

18:2 – 38.8; 18:3 – 19.8 [8]

Juice of Fruit

Essential oilContent, %: 4.2 [8]

Lipids

Content, %: 0.75 [8]

Acids, %: Capronic – 0.15; valerianic – 0.08; n-

butanoic + iso-butanoic – 0.052; acetic – 0.012 [8]

Esters

Content, %: 0.94 [8]

Components: Ethyl n-capronate, n-hexyl acetate,

trans-hexen-2-ol-1, his acetate [8]

Leaf

Essential oil [9]

Seed

Oil, % on dry wt: 16.0–19.0 [10, 11]

Iodine value, % J2: 192.0 [11]

FAs

Components: 16:0; 16:1; 18:0; 18:1; 18:2 [8]

Triterpenes, %: 5.9 [12]

References

1. T. Pyysalo, E. Honkanen, T. Hirvi, J. Agric. Food Chem.

27(1), 19 (1979)

2. P. Dirinck, L. Schreyen, N. Schamp, J. Agric. Food Chem.

25, 759 (1977)

3. W.H. McFadden, R. Teranishi, I. Course, D.R. Black, T.R.

Mon, J. Chromatogr. 18(1), 10 (1965)

4. M. Winter, B. Willhalm, Helv. Chim. Acta 47, 1215 (1964)

5. W.H. McFadden, R. Teranishi, I. Course, D.R. Black, T.R.

Mon, J. Chromatogr. 18(1), 10 (1965)

6. R. Teranishi, J.W. Corse, W.H. McFadden, D.R. Black, A.I.

Morgan, J. Food Sci. 28(4), 478 (1963)

7. B. Willhalm, E. Palluy, M. Winter, Helv. Chim. Acta 49, 65

(1966)

8. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–

101 [in Russian]

9. S.S. Stankov, Dikorastushchie poleznye rasteniya SSSR, 2izd., М. (1951), 316 s [in Russian]

10. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

11. А.А. Grossgeim, Rastitel’nye bogatstva Kavkaza, 2 izd.,

М., 1952, 631 s [in Russian]

12. A. Pourrat, Bull. Soc. Bot. France 112(7–8), 351 (1965)

Fragaria virginiana Mill.

Family: Rosaceae Juss.

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – 4.4; LeLeL –

12.0; LeLL + LeLeО – 20.9 (3:1); LeLeP – 1.8;

LLL + LeLO – 21.7 (2:3); LeLP + LeLe – 5.0;

LLO + LeOO – 13.8; LLP + LeLS + LeOP –

6.5; LOO – 5.1; LLS + LOP + LeOS – 4.7;

LPP + LePS – 0.3; ОOO – 2.0; LOS + ОOP –

1.3; LPS + ОPP – 0.7; ОOS – tr

References

1. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Page 26: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 726 Fragaria viridis Duch. (F. collina Ehrh.)

Fragaria viridis Duch. (F. collina Ehrh.)

Family: Rosaceae Juss.

Fruit

Essential oil

Leaf

Essential oil

References

1. S.S. Stankov,Dikorastushchie poleznye rasteniya SSSR, 2 izd.(Мoscow, 1951), 316 s [in Russian]

Geum aleppicum Jacq. (G. strictum (Ait.)Clausen)

Family: Rosaceae Juss.

Root with Rhizome

Essential oil

Content, %: 0.4

References

1. N.I. Suprunov, P.G. Gorovoi, Y.A. Pankov, Efirno-maslichnye rasteniya Dal’nego Vostoka (“Nauka”, Novosi-

birsk, 1972), 187 s [in Russian]

Geum chiloense Balb. (G. quellyon)

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 1.4 [1, 2]

Oil, % on dry wt: 24–24.4 [1, 2]

n40D : 1.4720 [1]

Iodine value, % J2: 162 [1]

Saponification value, mg KOH/g: 186 [1]

FAs

Diene as C18-acid, %: nonconjugated – 26 [1]

Epoxy acids C18 (HBr), %: 0.3 [1]

Monoene as 18:1, %: 37 [1]

Saturated, %: 3 [1]

Triene as C18-acid, %: nonconjugated – 30 [1]

References

1. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37(9), 440 (1960)

2. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Geum japonicum Thunb.

Family: Rosaceae Juss.

Whole Plant

Lipids (methanol)

Triterpenoic acids

Components (CC): 2a-Hydroxyoleanolic acid, 2a-hydroxyursolic acid, 2a,19a-dihydroxyursolic acid

References

1. S. Shigenaga, I. Kouno, N. Kawano, Phytochemistry 24(1),

115 (1985)

Geum macrophyllum Willd. var.sachalinensis (Koidz.) Hara ¼ G. fanriei

Family: Rosaceae Juss.

Root

Essential oilContent, %: 1.2 [1, 2]

References

1. R.К. Аliev, N.D. Аliev, А.K. Rakhimova, Dokl. АN Аzer.

SSR 17(6), 519 (1961) [in Russian]

2. V.N. Voroshilov, Poiski novogo lekarstvennogo rastitel’nogosyr’ya (Мoscow, 1941), 255 s [in Russian]

Geum montanum L.

Family: Rosaceae Juss.

Root

Essential oilContent, cc/100 g on dry wt: 0.2–0.35; on fresh wt:

0.04–0.08

Component (TLC): Eugenol

Page 27: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Hulthemia berberifolia (Pall.) Dumort. 727 Rosaceae Juss.

References

1. A. Krupinska, Ann. Pharm. (Poznan) 8, 93 (1970); Chem.

Abstr. 74, N 102954j (1971)

Geum rivale L. subsp. urbanum (L.) A. etD. Love ¼ G. urbanum

Family: Rosaceae Juss.

Leaf

Carotene

Content, mg% on fresh wt: 13.7 [1, 2]

Rhizome

Essential oilComponents: Eugenol, gein [3]

Oil (fatty) [4]

Root

Essential oil

Content, %: 0.1 [5]

Component: Eugenol [5]

References

1. А.А. Grossgeim, Rastitel’nye bogatstsva Kavkaza, 2 izd.

(Мoscow, 1952), 631 s [in Russian]

2. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (izd. “Nauka”, Moscow, 1976),

263 s [in Russian]

3. A. Krupinska, Ann. Pharm. 8(93) (1970); Chem. Abstr. 74,

N 102954 (1971)

4. R.К. Аliev, N.D. Аliev, А.Kh. Rakhimova, Dokl. АN Аzer.

SSR 17(6), 519 (1961) [in Russian]

5. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1938), 550 s [in Russian]

Geum urbanum L. (Geum rivale L., subsp.urbanum (L.) A. et D. Love,G.caryophyllatum Pers.,G. ibericum Bess.,Caryophyllata urbana Scop., C. officinalisScop.)

Family: Rosaceae Juss.

Leaf

Carotene [1, 2]

Rhizome

Essential oil

Content, %: 0.2 [3, 4]

Components: Eugenol, gein [5]

Root

Essential oil

Content, %: 0.022–0.4 [6, 7]

Content, cc/100 g on dry wt: 0.52–0.65; on fresh wt:

0.14–0.23 [8]; % on dry wt: 0.022–0.1 [9]

[a]20 10 [8]

d20: 1.041 [8]; d13.5: 1.0370 [9]; d13,5: 1.087 [7]

n20D : 1.525 [8]

Component (TLC): Eugenol [8, 9]

Use: Is used as spice and in liqueur and brewing

trade [7].

References

1. А.А. Grossgeim, Rastitel’nye bogatstsva Kavkaza, 2 izd.

(Мoscow, 1952), 631 s [in Russian]

2. G.G. Bosse, Vitaminonosnye rasteniya SSSR i ikh pishchevoeispol’zovanie (Мoscow, 1943), 105 s [in Russian]

3. R.К. Аliev, N.D. Аliev, А.K. Rakhimova, Dokl. АN Аzer.

SSR 17(6), 519 (1961) [in Russian]

4. E.V. Kucherov, G.K. Baikov, I.B. Gufranova, Poleznyerasteniya Yuzhnogo Urala (Izd. “Nauka”, Moscow, 1976),

263 s [in Russian]

5. C. Wehmer, Die Pflanzenstoffe, Bd. 1–2, Jena (1929), Bd. 1,640 s

6. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

7. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

8. A. Krupinska, Ann. Pharm. (Poznan) 8, 93 (1970); Chem.

Abstr. 74, N 102954j (1971)

9. B.N. Rutovskii, Efirnye Masla (Moskwa-Leningrad, 1931),

578 s [in Russian]

Hulthemia berberifolia (Pall.) Dumort.(H. persica persica (Michx. ex Juss.)Bornm.)

Family: Rosaceae Juss.

Flower

Essential oil

Page 28: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 728 Laurocerasus officinalis M. Roem.

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Laurocerasus officinalis M. Roem.

Family: Rosaceae Juss.

Leaf

Essential oil

[a]D: (�0�460)–(+ 0�300) [1]d: 1.046–1.067 [1]

nD: 1.5400–1.5470 [1]

Acid value, mg KOH: 1.6–10.8 [1]

Components: Benzaldehyde, benzyl alcohol, cyan-

ogens acid [1]

Oil

Sterols (total)

Content, %: 0.001–0.02 [2]

Free sterols

Composition, %: b-Sitosterol – 70.6; stigmasterol –

2.1; cholesterol – 10.1 [2]

Ethers of sterols

Composition, %: b-Sitosterol – 99.8 [2]

SG

Composition of sterols, %: b-Sitosterol – 22;

campesterol – 34.1; cholesterol – 35.5 [2]

Triterpenoids

Content, %: 2.7 [3]

Ursolic acid

Content, %: 1.0 [3]

Leaf with Young Branch

Essential oil

Content, %: 0.5 [1]

Components: Benzaldehyde, benzyl alcohol, cyan-

ogen acid [1]

Seed

Essential oil

Content, %: 1.0 [1]

d: 1.012 [1]

Composition, %: Benzaldehyde – 98; benzyl alco-

hol, benzaldehyde cyanohydrin, cyanogen acid –

0.4–0.8 [1]

Oil

FAs: 18:1; 18:2 [4]

Use: The oil is used in soap, food, and pharmaceutical

industry [5].

References

1. М.I. Goryaev, Efirnye masla flory SSSR (Аlma-Аta, 1952),

378 s [in Russian]

2. L.S. Tushishvili, N.Е. Zambakhidze, N.А. Kekelidze, Chem.

Nat. Comp. 13(5), 594 (1977)

3. J. Le Men, H. Pourrat, Ann. Pharm. franc. 13, 169 (1955);

Chem. Abstr. 49, N 11959 (1955)

4. R. Hegnauer, Chemotaxonomie der Pflanzen: Bd. 1–6

(Birkh€auser, Basel, Stuttgart, 1969), Bd. 5, 506 s; 1966, Bd.

4, 551 s; 1973, Bd. 6, 882 s.

5. Т.Y. Leshchuk, Аgrotekhnika osnovnykh efiro-maslichnykhkultur (1948) [in Russian]

Malus domestica Borkh.

Family: Rosaceae Juss.

Pollen

Oil

TAG

FAs (GLC), %: 10:0 – tr; 12:0 – 1.14; 14:0 – 0.86;

14:1 – tr; 15:0 – 0.20; iso-16:0 – tr; 16:0 – 33.83;

16:1 – 0.33; 16:2 – tr; 17:0 – 0.21; 17:1 – 0.18;

17:2 – tr; 18:0 – 3.67; 18:1 – 13.39; 18:2 – 10.59;

18:3 – 32.38; 19:0 – 0.47; 20:0 – 0.63; 21:0 –

1.91 [1]

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLeО – 0.5; LeLeP – tr; LLL +

LeLO – 16.7; LeLP + LeLe – 0.9; LLO +

LeOO – 27.0; LLP + LeLS + LeOP – 9.0;

LOO – 19.2; LLS + LOP + LeOS – 10.7;

LPP + LePS – 1.6; ОOO – 7.2; LOS + ОOP –

4.2; LPS + ОPP – 0.8; ОOS – 2.1 [2]

References

1. V.А. Bandyukova, G.I. Deineko, D.К. Shapiro, Chem. Nat.

Comp. 18(2), 227 (1982)

2. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Page 29: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Malus sp. 729 Rosaceae Juss.

Malus pumila Mill.

Family: Rosaceae Juss.

Fruit

Cutine

Composition of monomers (treatment with LiAlH4)

(GLC/MS, 3% OV-1 on Gas Chrom-Q), %:

Hexadecan-1-ol – 0.29; octadecan-1-ol – 1.38;

octadecen-1-ol – tr; eicosan-1-ol – tr;

hexadecane-1,16-diol – 6.62; octadecane-1,18-

diol – 2.51; octadecene-1,18-diol – 7.30;

hexadecanetriol – 23.11; octadecane-1,9,18-

triol – 13.11; octadecene-1,9,18-triol – 14.63;

octadecane-1,9,10,18-tetraol – 24.88;

octadecene-1,9,10,18–tetraol – 6.05 [1]

Peel of Fruit

Carotenoids

Free carotenoids

Composition (CC, TLC), ng/g on fresh wt: b-Carotene – 110; lutein – 230; violaxanthin –

330; neoxanthin – 20 [2]

Monoester

Composition of carotenoids (CC, TLC), ng/g on

fresh wt: Violaxanthin – 1,480; neoxanthin –

420 [2]

Composition of esters (HPLC), %:

Violaxanthin: Laurate – 14.5; myristate – 5.2; oleate

– 17.0; palmitate – 43.6; stearate – 14.7

Neoxanthin: Laurate – 12.9;myristate – 5.2; oleate +

palmitate – 55.8; stearate – 12.0 [2]

Diesters

Composition (CC, TLC), ng/g on fresh wt: Lutein –330; violaxanthin – 5,140; neoxanthin – 2010 [2]

Composition of diesters (HPLC), %:

Lutein: Caproate – 10.6; laurate – 15.6; myristate –

15.3; palmitate – 4.9; stearate – 1.4

Violaxanthin: Myristate – 8.4; palmitate – 15.4;

stearate – 5.7

Neoxanthin: Myristate – 11.6; stearate – 7.4 [2]

References

1. T.J. Walton, P.E. Kolattukudy, Biochemistry 11(10), 1885

(1972)

2. M. Knee, Phytochemistry 27(4), 1005 (1988)

Malus sieversii (Ledeb.) M. Roem.(M. anisophylla Sumn., M. heterophyllaSumn. non valide publ., M. hissaricaKudr., M. jarmolenkoi Sumn., M.juzepczukii Vass. non valide publ., M.kirghisorum Al. Theod. et Fed., M.kudrjaschevii Sumn., M. linczevskiiPoljak., M. niedzwetzkyana Dieck, M.persicifolta (M. Pop.) Sumn., M. pumilaMill. var persicifolia M. Pop., M.schischkinii Poljak., M. sieversii subsp.hissarica (Kudr.) Likhonos, M. sieversiisubsp. kirghisorum (Al. Theod et Fed.)Likhonos, M. sieversii subsp.turkmenorum (Juz. et M. Pop.) Likhonos,M. sylvestrisMill. subsp. sieversii (Ledeb.)Soo, M. tienschanica Sumn., M.turkmenorum Juz. et M. Pop.)

Family: Rosaceae Juss.

Fruit

Cutine

Components of monomers: 18-hydroxyoctadeca-

9,12-dienoic acid, 10,16-dihydroxyhexadecanoic

acid, 9,10-epoxy-18-hydroxyoctadec-12-enoic

acid, 9,10-epoxy-18-hydroxyoctadecanoic acid,

9,10,18-trihydroxyoctadecanoic acid

References

1. P.J. Holloway, Phytochemistry 12(12), 2913 (1973)

Malus sp.

Family: Rosaceae Juss.

Fruit

Essential oilComponents: Acetone, diethyl ether, n-pentane,

dichloromethane, 2-methylpentane, 2-

methylpropanol, 2-methylpentane, n-hexane,chloroform, ethyl acetate, methylcyclopentane, 2-

methylpropan-1-ol, benzene, tetrachloromethane,

cyclohexane, 1-butanol, 1-propylacetate,

methylcyclohexane, 3-methylbutan-1-ol, toluene,

2-methyl-1-propyl acetate, 1-butylacetate,

Page 30: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 730 Malus sylvestris Mill. (M. praecox (Pall.) Borkh.)

ethylbenzene, m- and p-xylene, 3-methyl-1-butyl

acetate, o-xylene, 1-butylpropionate, 1-

pentylacetate, a-pinene, 1-butylbutyrate, 1-hexylacetate, 1-hexyl butyrate, estragol [1]

In addition (GLC, DC-705 on Celit 545): Acetalde-hyde, methyl octanoate, ethyl octanoate, metha-

nol, methylethylketone, ethanol, isopropanol,

hexyl propionate methyl propyl ketone,

butyl octanoate, isoamyl octanoate, amyl

octanoate, ethyl capronate, propyl capronate,

2-methyl-1-butanol, methylhexylketone, hexyl

octanoate [2]

Moisture, %: 87.5 [3]

Tocopherols and tocotrienols

Content, mg/100 g on fresh wt: a-Tocopherol –

0.24 [3]

Carotenoids

Composition (HPLC), mg/100 g on fresh wt: b-Carotene – 12–39; lutein – 42–48 [4]

Cutin

18-Oxo-9,10-epoxystearic acid [5]

Seed Endosperm

TAG

FAs

Composition (GLC, 10% DEGS), %: 16:0 – 10.2;

18:0 – 2.0; 18:1 – 26.7; 18:2 – 61.1 [6]

Sn-1-position (GLC, 10% DEGS), %: 16:0 –

22.2; 18:0 – 5.7; 18:1 – 33.9; 18:2 – 38.2 [6]

Sn-2-position (GLC, 10%DEGS), %: 16:0 – 0.4;

18:0 – 0.1; 18:1 – 21.6; 18:2 – 77.9 [6]

Sn-3-position (GLC, 10%DEGS), %: 16:0 – 8.0;

18:0 – 0.2; 18:1 – 24.6; 18:2 – 67.2 [6]

Composition of TAG, mol %: DDD – 16.3; DDM –

42.6; DDS – 21.1; DMM – 11.8; DMS – 3.4;

MMM–0.9;DSS – 1.1;MMS–1.8;MSS–1.0 [6]

References

1. P. Dirinck, L. Schreym, N. Schamp, J. Agric. Food Chem.

25(4), 759 (1977)

2. A. Pribela, Biologia 20(3), 173 (1965)

3. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen, P.

Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

4. M.I. Heinonen, V. Ollilainen, E.K. Linkola, P.T. Varo, P.E.

Koivistoinen, J. Agric. Food Chem. 37(3), 655 (1989)

5. P.E. Kolattukudy, Lipids 8(2), 90 (1973)

6. M.P. Velcheva, V.N. Dimov, G.P. Dimitrov, M.S. Dodova-

Anghelova, I. Am. Oil Chem. Soc. 56(6), 648 (1979)

Malus sylvestris Mill. (M. praecox (Pall.)Borkh.)

Family: Rosaceae Juss.

Flower

Essential oil

Content (steam distillation), %: 0.3; (pentane

extract), %: 0.1 [1]

Composition (GC-FID and GC-FTIR-MS (Fourier

transform infrared spectroscopy), % of peaks

area: Hydrocarbons: 3-carene – 1.23–4.20; p-

cymene – 1.83–3.17; n-decane – tr – 2.71;

dodecane – tr – 1.89; hexadecane – tr – 3.48, a-cumulene – 2.31 – 3.12, limonene – 4.31 – 6.13;

myrcene – 0.42–1.03; perillene – tr – 1.19; a-pinene – 0.40–4.15; terpinolene – 1.18–4.33;

alcohols/phenols/ethers: benzyl alcohol – 1.92–

8.13; borneol – 0.78–1.27; cinnamic alcohol –

0.17–2.13; eugenol – 1.12–4.11; geraniol –

2.22–4.11; hexanol – 0.13–1.33; 3-hexen-1-ol –

0.47–4.14; linalool – 0.83–2.03; menthol – 1.00–

2.39; 2-phenylethyl alcohol – 1.09–3.17; thymol

– 0.39–1.21; vanillin – tr – 3.27; aldehydes/

ketones: benzaldehyde – 1.71–13.35;

cinnamaldehyde – 4.13–5.11; (E)-citral – 1.47–

3.00; (Z)-citral – 2.00–7.39; decanal – 0.72–

1.88; b-ionone – 0.61–2.01; acids/esters: benzylacetate – 0.91–3.17; bornyl acetate – 1.08–6.12;

butyl acetate – 1.01–3.17; cyclohexyl acetate – tr

– 2.24; geranyl acetate – 0.91–2.63; 3-hexen-1-

yl-acetate – 0.78–0.92; hexyl acetate – 1.39–

2.11; methyl butyrate – 0.31–4.11; palmitic

acid – 1.29–8.33; linoleic acid – 1.17–3.47;

1,5-pentadiyl acetate – tr – 1.17; 2-phenylethyl

acetate – 2.29–3.18 [1]

Fruit

Carotenoids [2]

Seed

Oil (hexane)

FAs (GLC, Silar 5 CP):16:0 – 6.71; 16:1 – 0.09;

17:0 – 0.08; 17:1 – 0.05; 18:0 – 1.69; 18:1 –

28.17; 18:2 – 60.41; 18:3 – 0.47; 20:0 – 1.13;

20:1 – 0.47; 22:0 – 0.22; 22:1 – 0.03 [2]

Isomers 16:1 (Ag+/PТLC, Ozonolise), %: n-7 –

55.6; n-9 – 44.4 [3]

Page 31: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

+

Orthurus kokanicus (Regel et Schmalh.) Juz. 731 Rosaceae Juss.

Isomers 18:1 (Ag /PТLC, оzonolize), %: n-7 – 1.1;

n-9 – 98.9 [3]

Isomers 20:1 (Ag+/PТLC, оzonolize), %: n-9 – 100

[3]

References

1. G. Buchbauer, L. Jirovetz, M. Wasicky, A. Nikiforov, J.

Agric. Food Chem. 41(1), 116 (1993)

2. К.К. Gutmanis, In: Rasteniya, ispol’zuemye v narodnomkhozyaistve (Riga, 1968), 13 [in Russian]

3. A. Seher, U.Gundlach, Fette, Seifen,Anstrich. 84(9), 342 (1982)

Mespilus germanica L.

Family: Rosaceae Juss.

Aerial Part

Ursolic acid [1]

Leaf

Triterpenes

Content, %: 2.1 [2]

Ursolic acid

Content, %: 0.7 [2]

Seed

Oil, %: 10.0 [3]

References

1. L.Y. Ivanovskaya, А.А. Ryabinin, L.P. Barabanova, Zhurn.

Obshch. Khim. 33, vyp. 10, 3446 (1963) [in Russian]

2. J. Le Men, H. Purrat, Ann. Pharm. franc. 13, 169 (1955);

Chem. Abstr. 49, N 11959 (1955)

3. R. Hegnauer, Chemotaxonomie der Pflanzen, Bd. 1–6 (Basel;Stuttgart, 1969), Bd. 5, 506 s; 1966, Bd. 4, 551 s; 1973, Bd. 6,

882 s

Mespilus japonica Thunb. (Eriobotryajaponica Lindl., Photinia japonicaFr. Et Sav.)

Family: Rosaceae Juss.

Flower

Essential oil

d: 0.9998

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Orthurus heterocarpus (Boiss.) Juz.(Geum heterocarpum Boiss.)

Family: Rosaceae Juss.

Underground Part

Essential oil

Content, %: 0.35 [1]

Composition, %: Eugenol – 83.5; glycoside of euge-

nol (gein) – 0.97 [1]

Use: Essential oil is used as substitute of oil cloves in

stomatology and for receiving cementing properties

preparation [2, 3].

References

1. Z.K. Khabibov, Dokl. АN UzSSR (7), 42 (1960) [in Russian]

2. Z.K. Khabibov, Тr. Таshk. Farmats. Inst. 3, 162 (1962)

[in Russian]

3. K.K. Khalmatov, F.G. Akhmedova, Тr. Таshk. Farmats. Inst.

3, 60 (1962) [in Russian]

Orthurus kokanicus (Regel et Schmalh.)Juz. (Geum kokanicus Regel et Schmalh.)

Family: Rosaceae Juss.

Root and Rhizome

Essential oil

Content, %: 0.22–0.42 [1]

a½ �20D : (�1.40)–(�1.50) [1]

d2020: 1.0450–1.0508 [1]

n20D : 1.5265–1.5278 [1]

Acid value, mg KOH: 28.50–28.76 [1]

Eugenol

Content, % on abs. dry wt: 0.19–0.34; % on oil:

80.05–84.13 [1]

Aldehydes and ketones

Content, %: 17.00–19.55 [1]

Gein

Content, %: 0.56–1.17 [1–3]

Use: Essential oil substitutes oil cloves in

stomatology [1].

Page 32: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 732 Padellus mahaleb

References

1. Z.K. Khabibov, Dokl. АN UzSSR (7), 42 (1960) [in Russian]

2. I.P. Tsukervanik, А.G. Avanesova, Тr. Inst. Khim. АN

UzSSR vyp. 1, 53 (Таshkent, 1948) [in Russian]

3. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Padellus mahaleb (L.) Vass. (Cerasusmahaleb (L.) Mill., Padus mahaleb (L.)Borkh, Prunus mahaleb L.)

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 33–36 [1, 2]

FAs, %: 18:1 – 44.8; 18:2 – 13.3; a-eleostearic – 27–45[1, 2]

Sitosterol [3]

PhL

Content, %: 1.1 [4]

References

1. J.A. Funes, P. Cattaneo, Ann. Assoc. quim. Argent. 66, N 5,

239 (1978); Chem. Abstr. 93(5), 41530m (1980)

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

3. M. El-Dakhakhy, M.B.E. Fayez, Planta Med. 10(4), 455

(1962)

4. K.S. Mukhamedova, R.R. Akbarov, S.Т. Akramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Padus avium Mill. (P. racemosa (Lam)Gilib., Prunus padus L.)

Family: Rosaceae Juss.

Bud

Essential oil

Content, %: 0.26 [1]

Flower

Nonacosane [2]

Lupeol [2]

Sitosterol [2]

Leaf

Essential oil

Content, %: 0.03–0.05 [1]

Carotene [1]

Seed

Oil [3]

Use: Oil of fruits has bactericidal action (goldish

staphylococcus, hemolytic streptococcus, typhus,

paratyphoid, dysentery bacillus, colon bacillus, and

some anaerobic bacteria) [3].

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

2. Z. Kowalewski, H. Grabarczyk, Diss. Pharm. et Pharmacol.

PAN 20(2), 211 (1968)

3. A.I. Shapiro, O.K. Filippova, Zh. Mikrobiol., Epidemiol.,

Immunobiol. (10), 26 (1947) [in Russian]

Padus maackii (Rupr.) Kom. (Prunusmaackii Rupr.)

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Padus racemosa (Lam.) Gilib.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, mg% on dry wt: tr – 5.8 [1]

Leaf

Essential oilComponent: Prunasin [2]

Page 33: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Persica mira (Koehne) Kov. et Kost. 733 Rosaceae Juss.

References

1. Dikorastushchie i introdutsiruemye poleznye rasteniyav Bashkirii, vyp. 1 (АN SSSR, Bashkirskii philial, institute

biologii, Ufa, 1961) [in Russian]

2. А.А. Grossgeim, Rastitel’nye resursy Kavkaza (Мoskwa-

Leningrad, 1946) [in Russian]

Padus virginiana (L.) Mill. (Prunus serotinaEhrh., P. virginianaMill., P. rubtaMill.)

Family: Rosaceae Juss.

Bark

Essential oil

Content, %: 0.2

d15: 1.045–1.050

Components: Benzaldehyde, cyanogen acid

Leaf

Essential oil

Content, %: 1.0

d: 1.0532

Component: Cyanogen acid – 0.27%

Seed

Essential oil

Components: Benzaldehyde, cyanogen acid

References

1. N.А. Shugam, L.О. Shnaidman, Izv. Vuzov. Pishch. Tekhnol.

(1), 52 (1967) [in Russian]

Pentaphylloides fruticosa (L.) O. Schwars(Dasyphora fruticosa (L.) Rydb., Potentillafruticosa L.)

Family: Rosaceae Juss.

Aerial Part

Carotene [1]

Leaf

Triterpenoids

Content, %: 2.0 [2]

Ursolic acid

Content, %: 0.7 [2]

References

1. A. Johnston, L.M. Bezeau, Can. J. Plant Sci. 42(1), 105 (1962)

2. J. Le Men, H. Pourrat, Ann. Pharm. franc. 13, 169 (1955);

Chem. Abstr. 49, N 11959 (1955)

Persica davidiana Carr.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 400

Oil, % on abs. dry wt: 51.9

Unsaturated FAs, %: 91.9

Composition of FAs (GLC, 10% PEGS), %: 18:1 –

61.2; 18:2 – 30.7

Tocopherols

Content, mg%: 34.6

Composition of tocopherols (PC), mg%: a-Tocopherol – 25.0; g-tocopherol – 9.8

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

Persica mira (Koehne) Kov. et Kost.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 300

Oil, % on abs. dry wt: 41.2

Unsaturated FAs, %: 90.9

Composition of FAs (GLC, 10% PEGS), %: 18:1 –

69.2; 18:2 – 21.7

Tocopherols

Content, mg%: 41.3

Composition of tocopherols (PC), mg%: a-Tocopherol – 19.0; g-tocopherol – 22.3

References

1. А.А. Rikhter, G.I. Nilov, V.I. Kriventsov, Rastit. Resursy

13(4), 675 (1977) [in Russian]

Page 34: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 734 Persica sp.

Persica sp.

Family: Rosaceae Juss.

Fruit

Essential oil

Components (GC): Ethyl acetate, 1-nonene, 1-

decene, isoamyl acetate, pentyl acetate, limo-

nene, hexyl acetate, cis-3-hexenyl acetate,

trans-2-hexenyl acetate, nonanal, naphthalene,

furfural, 3-nonen-2-one, benzaldehyde, linalool,

monoterpene, carvomenthenol, a-terpineol, g-hexalactone, g-heptalactone, geraniol, g-octalactone, g-nonalactone, g-decalactone,tricosane, g-dodecalactone [1]

In addition (GLC/MS): Hexanal, (E)-2-hexenal,

hexanol, (E)-2-hexenol, xylene, benzaldehyde,benzyl alcohol, benzolthiazole, 1-methylnaph-

thalene, 2-pentylfuran, (E,E)-2,4-decadienal,

methyleugenol, 6-pentyl-a-pyrone,dihydroionone, b-ionone, d-decalactone, a-bergamoten, 2,6-dichloro-4-nitroaniline,

dibutyl phthalate, palmitic acid, methyl 3-

methyloxyoctadecanoate, C21H44, C23H48, bis

(ethylhexyl)phthalate, C25H52 [2]

(GLC, 20% Apiezon L or 10% DEGS): 1,2-

dihydro-1,1,6-trimethylnaphthalene; 1,2,3,4-

tetrahydro-1,1,6-trimethylnaphthalene (ionene)

and two C14H22 hydrocarbons; trans-3-hexen-1-ol, nonanal, methyl salicylate, eugenol [3]

Moisture, %: 88.8 [4]

Carotenoids

Composition (HPLC), mg/100 g on fresh wt: a-Carotene – tr; b-carotene – 86–100;

cryptoxanthin – 51–82; lutein – 14–28 [5]

Tocopherols

Composition, mg/100 g on fresh wt: a-Tocopherol –0.96; b-tocopherol – tr; g-tocopherol – 0.05 [4]

Leaf

Essential oil

Composition (capillary GC, DB-1), %: Hexanal – tr;

(E)-2-hexenal – tr; (Z)-3-hexenol – tr; benzalde-

hyde –>95; benzyl alcohol – tr; ethyl benzoate –

tr; (Z)-3-hexenyl butyrate – tr; methyl salicylate

– tr; ethyl salicylate – tr; benzoic acid – 1.2;

eugenol – tr; (Z)-3-hexenyl benzoate – tr;

benzyl salicylate – tr; palmitic acid – tr; ethyl

palmitate – tr; isopropyl palmitate – tr; C21H44 –

tr; C23H48 – tr; C25H52 – tr [6]

References

1. M.D. Spencer, R.M. Pangborn, W.G. Jennings, J. Agric. Food

Chem. 26(3), 725 (1978)

2. R.J. Horvat, G.W. Chapman, Jr. J.A. Robertson, F.I. Meredith,

R. Scorza, A.M. Callahan, P. Morgens, J. Agric. Food Chem.

38(1), 234 (1990)

3. T.R. Kemp, L.P. Stoltz, L.V. Packett, Phytochemistry 10(2),

478 (1971)

4. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen, P.

Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

5. M.I. Heinonen, V. Ollilainen, E.K. Linkola, P.T. Varo, P.E.

Koivistoinen, J. Agric. Food Chem. 37(3), 655 (1989)

6. R.J. Horvat, G.W. Chapman, J. Agric. Food Chem. 38(7),

1442 (1990)

Persica vulgaris Mill. (Amygdalus persicaL.; Prunus persica Stokes.)

Family: Rosaceae Juss.

Kernel

Oil

d15: 0.914–0.925 [1]

n20: 1.471–1.473 [1]

Acetic value, mg KOH: 0.7–1.0 [1]

Hehner value, %: 94–95 [1]

Iodine value, % J2: 74–123 [1]

Polenske value, mL KOH: 1.6 [1]

Reichert-Meissl value, mL KOH: 1.0–1.5 [1]

Saponification value, mg KOH/g: 163–196 [1]

Thiocyanogen value, % J2: 78–81 [1]

Unsaponifiables, %: 0.3–1.5 [1]

Viscosity, E20, sp: 72.8 [1]

FAS

Saturated, %: 12.0 [1]

Unsaturated, %: 88 [1]

Composition of FAs (GLC), %: 14:0 – 1.0; 16:0 – 3–

15; 18:1 – 73.3–85.0; 18:2 – 16.4 [1]

Pulp of Fruit

Essential oil

Content, %: 0.00074–0.00082 [2]

Components: Acetaldehyde, furfurol, methyl

anthranilate, cadinene, paraffin, methanol,

Page 35: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Potentilla argentea L. 735 Rosaceae Juss.

linalool, formic acid, acetic acid, valeric acid,

capric acid and their esters [2]

References

1. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969) [in Russian]

2. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Physocarpus opulifolius (L.) Maxim.(Spiraea opulifolia L., Neilla opulifoliaBenth., Opulaster opulifolius O. Kuntze)

Family: Rosaceae Juss.

Whole Plant

Essential oil

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Potentilla anserina L.

Family: Rosaceae Juss.

Aerial Part

Essential oilContent, %: 0.28 [1]

Lipids

Content, %: 2.0 [1]

FAs: 14:0; 16:0; 18:1; 18:2; 18:3; 20:0; 26:0 [1]

Carotenoids

Components: a-Carotene, b-carotene [2]Sterols

Component: b-Sitosterol [2, 3]n-Nonacosane [3]

Ceryl alcohol [3]

Flower

Carotene [3]

Stem

Aliphatic hydrocarbons [3]

References

1. H.W. Youngken, E.B. Fischer Am. J. Pharm. 114, 372 (1942);

Chem. Abstr. 37, N 499 (1943)

2. N.F. Goncharov, А.G. Коtov, Chem. Nat. Comp. 27(6), 752

(1991)

3. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Potentilla arenaria Borkh.

Family: Rosaceae Juss.

Whole Plant

Pigments

Composition, mg/g on dry wt: a- + b-Carotene –

0.336; chlorophyll a – 1.286; chlorophyll b –

0.850; xanthophylls –1.033

References

1. G. Fekete, Z. Tuba, I. Precsenyi, Acta Botan. Acad. Sci. Hung.

26(3–4), 289 (1980)

Potentilla argentea L.

Family: Rosaceae Juss.

Aerial Part

Essential oilContent, %: 0.24 [1]

Carotenoids

Components: a-Carotene, b-carotene [2]Sterols

Component: b-Sitosterol [2]

Flower

b-Carotene [3]

References

1. H.W. Youngken, E.B. Fischer, Am. J. Pharm. 114, 372

(1942); Chem. Abstr. 37, N 499 (1943)

2. N.F. Goncharov, А.G. Коtov, Chem. Nat. Comp. 27(6), 752

(1991)

3. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 36: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 736 Potentilla asiatica (Th. Wolf) Juz.

Potentilla asiatica (Th. Wolf) Juz.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 0.35 [1]

Oil, % on dry wt: 21.74 [1]

n20D : 1.4848 [1]

Acid value, mg KOH: 1.97 [1]

Iodine value, % J2: 212.43

Saponification, mg KOH/g: 185.88 [1]

Unsaponifiables; %: 1.5 [1]

FAs

Iodine value, % J2: 214.41 [1]

Mean mol. wt: 280.20 [1]

Neutralization value, mg KOH: 200.22 [1]

Composition of FAs (GLC, PEGS), %: 16:0 – 4.51;

18:0 – 1.81; 20:0 – tr; 18:1 – 10.3; 18:2 – 24.39;

18:3 – 58.99 [1]

PhL

Content, %: 0.4 [2]

References

1. E.I. Gigienova, Е.I. Kiryushina, А.U. Umarov, Chem. Nat.

Comp. 13(4), 411 (1977)

2. K.S. Мukhamedova, R.R. Akbarov, S.Т. Akramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Potentilla callieri (Th. Wolf) Juz. (P.taurica Willd. s.l.)

Family: Rosaceae Juss.

Fruit

Oil, % on dry wt: 7.54

References

1. А.I. Barbarich, О.М. Dubovik, D.V. Strelko, Zhirooliiniroslini Ukrainy Кiiv (1973), 132 p. (in Ukrainian)

Potentilla desertorum Bunge

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 0.18

Oil, % on dry wt: 21.08

n20D : 1.4822

Acid value, mg KOH: 3.01

Iodine value, % J2: 194.55

Saponification value, mg KOH/g: 183.44

Unsaponifiables, %: 2.04

FAs

Iodine value, % J2: 205.29

Mean mol. wt: 281.94

Neutralization value, mg KOH/g: 198.98

Composition of FAs (GLC, PEGS), %: 16:0 – 4.45;

18:0 – 2.55; 20:0 – tr; 18:1 – 15.97; 18:2 – 21.48;

18:3 – 55.55

References

1. E.I. Gigienova, Е.I. Kiryushina, А.U. Umarov, Chem. Nat.

Comp. 13(4), 411 (1977)

Potentilla erecta (L.) Raeusch. (P.tormentilla Neck., P. silvestris Neck.)

Family: Rosaceae Juss.

Aerial Part

Carotenoids

Components: a-Carotene, b-carotene [1]Sterols

Component: b-Sitosterol [1]

Rhizome

Essential oil [2]Triterpenoids

Content, %: 6.0 [3]

Root

Essential oil

Components: Cyneol, alpinine, galangine [4]CO2-extract

Content, % on abs. dry wt: 4.7 [2]

Composition of extract, %: Essential oil – 26; fatty

oil – 11.2; saponifiables – 59.2; unsaponifiables

– 40.8 [2]

Lipids (chloroform-methanol)

Content, % on dry wt: 9.1 [5]

Oil (hexane), % on dry wt: 1.3 [5]

d204 : 0.9900 [2]

Page 37: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Potentilla orientalis Juz. 737 Rosaceae Juss.

n20D : 1.5036 [2]

Acid value, mg KOH: 50.0 [2]

Ether value mg КОН/g: 290.0 [2]

FAs (GLC), %: 12:0 – 0.4; 15:0 – 11.5; 16:0 – 21.3;

16:1 – 7.0; 18:0 – 8.0; 18:1 – 30.0; 18:2 – 10.4;

18:3 – 11.4 [2]

(GLC, Chromaton N-AW-DMCS with 15%

Reoplex-400), %: 14:0 – 0.5; 16:0 – 16.5; 16:1

– 3.8; 18:0 – 3.3; 18:1 – 9.5; 18:2 – 44.1; 18:3 –

22.3 [5]

TAG

Content, % from oil: 96.9% [5]

FAs of TAG (GLC, Chromaton N-AW-DMCSwith

15% Reoplex-400), %: 14:0 – 0.9; 16:0 – 17.6;

16:1 – 8.4; 18:0 – 2.6; 18:1 – 21.1; 18:2 – 43.9;

18:3 – 5.5 [5]

Seed

Lipids (chloroform-methanol)

Content, % on dry wt: 0.16 [5]

Oil (hexane), % on dry wt: 11.3 [5]

TAG

Content, %: 96.2 [5]

FAs of TAG (GLC, Chromaton N-AW-DMCSwith

15% Reoplex-400), %: 14:0 – tr; 16:0 – 4.0; 18:0

– 1.7; 18:1 – 11.8; 18:2 – 32.6; 18:3 – 49.9 [5]

Composition (HPLC), %: LeLeLe – 34.6; LeLeL –

21.2; LeLL + LeLeO – 15.7 (2:3); LeLeP – 6.3;

LLL + LeLO – 7.1 (1:4); LeLP + LeLe – 5.9;

LLO + LeOO – 3.0 (1:1); LLP + LeLS + LeOP –

4.1; LOO – 0.7; LLS + LOP + LeOS – 0.9; LPP +

LePS – tr;ОOO – 0.2; LOS +ОOP – 0.1; LPS +

ОPP – 0.1; ОOS – tr [6]

FFA (GLC, Chromaton N-AW-DMCS with 15%

Reoplex-400), %: 14:0 – 0.4; 15:0 – 2.8; 16:0 –

12.1; 16:1 – 3.2; 18:0 – 2.5; 18:1 – 10.7; 18:2 –

26.9; 18:3 – 41.4 [5]

References

1. N.F. Goncharov, А.G. Коtov, Chem. Nat. Comp. 27(6), 752

(1991)

2. G.I. Kas’yanov, E.А. Shaftan, Е.S. Кlimova, Chem. Nat.

Comp. 13(1), 94 (1977)

3. A. Pourrat, Bull. Soc. Bot. France 112(7–8), 351 (1965)

4. А.А. Grossgeim, Rastitel’nye resursy Kavkaza (Мoskwa-

Leningrad, 1946) [in Russian]

5. S.D. Gusakova, G.А. Stepanenko, D.Т. Asilbekova, Y.М.

Мurdakhaev, Rastit. Resursy 19(4), 444 (1983) [in Russian]

6. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Potentilla fruticosa L.

Family: Rosaceae Juss.

Aerial Part

Oil, %: 3.53–4.43 [1]

Carotene, mg/kg: 6.03–40.6 [1]

Sterols

Components: b-Sitosterol, stigmasterol,

campesterol [2]

Leaf

Triterpene

Content, %: 2.0 [3]

Components: Epi-ursolic acid, 2a-hydroxyursolicacid, ursolic acid (0.7%), tormentoic acid

(2a,19a-dihydroxyursolic) [3, 4]

References

1. A. Johnston, L.M. Bezeau, Can. J. Plant Sci. 42(1), 105 (1962)

2. Т.V. Ganenko, А.L. Veteshchagin, А.А. Semenov, Chem.

Nat. Comp. 27(2), 246 (1991)

3. J. Le Men, H. Purrat, Ann. Pharm. Franc. 13, 169 (1955);

Chem. Abstr. 49, 11959 (1955)

4. Т.V. Ganenko, А.А. Semenova, Chem. Nat. Comp. 25(6),

727 (1989)

Potentilla norvegica L.

Family: Rosaceae Juss.

Aerial Part

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Potentilla orientalis Juz.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 0.37

Page 38: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 738 Potentilla pedata Nestl. (P. transcaspia Th. Wolf)

Oil, % on dry wt: 17.18

n20D : 1.4814

Acid value, mg KOH: 2.89

Iodine value, % J2: 187.49

Saponification value, mg KOH/g: 182.13

Unsaponifiables, %: 2.89

FAs

Iodine value, % J2: 199.45

Mean mol. wt: 282.10

Neutralization value, mg KOH/g: 198.87

Composition of FAs (GLC, PEGS), %: 16:0 – 4.37;

18:0 – 0.94; 20:0 – tr; 18:1 – 19.49; 18:2 – 26.14;

18:3–49.06

References

1. E.I. Gigienova, Е.I. Kiryushina, А.U. Umarov, Chem. Nat.

Comp. 13(4), 411 (1977)

Potentilla pedata Nestl. (P. transcaspiaTh. Wolf)

Family: Rosaceae Juss.

Seed

Oil (ether), % on abs. dry wt: 26.24

d20: 0.9347

n20D : 1.4839

Acetic value, mg KOH: 21.17

Acid value, mg KOH: 1.50

Hehner value, %: 94.83

Hydroxyl, content, %: 0.65

Iodine value, % J2: 197.22

Polenske value, mL KOH: 0.44

Phosphatides, %: 0.29

Saponification value, mg KOH: 191.33

Thiocyanogen value, % J2: 114.47

Tocopherols, mg%: 34.69

Unsaponifiables, %: 1.15

Viscosity (Engler), E20: 5.44

FAs

Iodine value, % J2: 207.70

Hexabromic value, %: 49.65

Mean mol. wt: 281.53

Neutralization value, mg KOH: 199.30

Saturated value (Bertram), %: 5.09

Mean mol. wt of saturated acids: 320.36

Thiocyanogen value, % J2: 124.92

Composition of FAs (PC): Saturated acids – 4.82–

5.09; 18:1 – 15.65–16.54; 18:2 – 16.26–17.19;

18:3 – 51.14–54.06

TAG

Composition of TAG, %: SSS – 0.01; SUU – 13.75;

SSU – 0.74; UUU – 85.5

Pigments

Components: b-Carotene, chlorophyll b

References

1. I.P. Nazarova, А.I. Glushenkova, А.L. Маrkman, Uzb.

Khim. Zhurn. (3), 36 (1966) [in Russian]

Potentilla recta L. (P. hirta auct.)

Family: Rosaceae Juss.

Fruit

Oil, %: 11.16 [1]

Leaf

Ursolic acid [2]

References

1. А.I. Barbarich, О.М. Dubovik, D.V. Strelko, Zhirooliiniroslini Ukrainy, Кiiv (1973), 132 p. [in Ukrainian]

2. J. Le Men, H. Pourrat, Ann. Pharm. franc. 13, 169 (1955);

Chem. Abstr. 49, N 11959 (1955)

Potentilla reptans L.

Family: Rosaceae Juss.

Flower

Carotenoids

Components: b-Carotene, 5,6-monoepoxyde of a-carotene, 5,6:50,60-diepoxide of a-carotene,5,6:50,60-diepoxide b-carotene, cryptoxanthin,

epoxide of cryptoxanthin, mutatochrome, lutein,

trans-epoxide of lutein, cis-epoxide of lutein,

flavoxanthin, auroxanthin

Page 39: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Poterium polygamum Waldst. et Kit. (Sanguisorba muricata (Spach) Gremli) 739 Rosaceae Juss.

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

Potentilla tanacetifoliaWilld. ex Schlecht.

Family: Rosaceae Juss.

Aerial Part

Essential oil

Content, %: 0.3

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Potentilla tormentilla Neck.

Family: Rosaceae Juss.

Whole Plant

Triterpenes

Content, %: 6.0

References

1. A. Pourrat, Bull. Soc. Bot. France 112(7–8), 351 (1965)

Potentilla transcaspia Th. Wolf.(= P. pedata)

Family: Rosaceae Juss.

Seed

Oil (ether), % on abs. dry wt: 26.24

d20: 0.9347

n20D : 1.4839

Acetic value, mg KOH: 21.17

Acid value, mg KOH: 1.50

Hehner value, %: 94.83

Hydroxyl, content, %: 0.65

Iodine value, % J2: 197.22

Polenske value, mL KOH: 0.44

Phosphatides, %: 0.29

Saponification value, mg KOH: 191.33

Thiocyanogen value, % J2: 114.47

Tocopherols, mg%: 34.69

Unsaponifiables, %: 1.15

Viscosity (Engler), E20: 5.44

FAs

Iodine value, % J2: 207.70

Hexabromic value, %: 49.65

Mean mol. wt: 281.53

Neutralization value, mg KOH: 199.30

Saturated value (Bertram), %: 5.09

Mean mol. wt of saturated acids: 320.36

Thiocyanogen value, % J2: 124.92

Composition of FAs (PC): saturated acids – 4.82–

5.09; 18:1 – 15.65–16.54; 18:2 – 16.26–17.19;

18:3 – 51.14–54.06

TAG

Composition of TAG, %: SSS – 0.01; SUU – 13.75;

SSU – 0.74; UUU – 85.5

Pigments

Components: b-Carotene, chlorophyll b

References

1. I.P. Nazarova, А.I. Glushenkova, А.L. Маrkman, Uzb.

Khim. Zhurn. (3), 36 (1966) [in Russian]

Poterium polygamum Waldst. et Kit.(Sanguisorba muricata (Spach) Gremli)

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 5.99 [1]

Oil, % on dry wt: 17.73 [1]; on abs. dry wt: 20.12 [2]

d204 : 0.9272 [2]

n20D : 1.4807–1.4812 [1, 2]

Absolute viscosity by 20�C, puaz: 0.3982 [2]

Acetic value, mg KOH: 26.92 [2]

Acid value, mg KOH: 2.74 [1]

Hehner value, %: 94.89–95.27 [2]

Page 40: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 740 Poterium sanguisorba L. (Sanguisorba minor Scop.)

Iodine value, % J2: 181.29 [1]; 164.02–166.59 [2]

Phosphatides, % 0.053 [2]

Polenske value, mL KOH: 0.61–1.06 [2]

Reichert-Meissl value, mL KOH: 1.07–1.14 [2]

Saponification value, mg KOH/g: 182.94 [1];

190.89–191.98 [2]

Saponification value with calculation of

unsaponifiables, mg KOH/g: 193.7–194.6 [2]

Thiocyanogen value, % J2: 101.77–102.2 [2]

Viscosity on Engler, E�: 5.66 [2]

Unsaponifiables, %: 1.16–1.49 [1, 2]

FAs

Hexabromide value, %: 38.37 [2]

Iodine value, % J2: 184.36 [1]; 175.32 [2]

Mean mol. wt: 282.16 [1]; 274.80 [2]

Neutralization value, mg KOH/g: 198.83 [1];

204.18 [2]

Thiocyanogen value, % J2: 106.27 [2]

Saturated acids (Bertram), %: 9.45 [2]

Iodine value, % J2: 2.68 [2]

Neutralization value, mg KOH/g: 200.85 [2]

Mean mol. wt: 279.36 [2]

Composition of FAs (GLC, PEGS), %: 16:0 – 7.66;

18:0 – 2.52; 18:1 – 16.48; 18:2 – 34.86; 18:3 –

38.48; 20:0 – tr; 22:0 – tr [1]

(PC, UV), %: 16:0 – 2.5; 18:0 – 11.24; 18:1 – 18.99;

18:2 – 20.98; 18:3 – 39.30 [2]

TAG

Composition of TAG, %: SSS – 0.142; SSP – 0.095;

SPP – 0.021; PPP – 0.002; SSO – 0.720; SSL –

1.108; SSLe – 1.491; SPO – 0.320; SPL – 0.471;

SPLe – 0.663; PPO – 0.036; PPL – 0.052; PPLe –

0.074; SOO – 1.216; SLL – 2.630; SLeLe – 5.219;

SOL – 3.577; SOLe – 5.035; SLLe – 7.405; POO–

0.270; PLL – 0.585; PLeLe – 1.161; POL – 0.796;

POLe – 1.121; PLLe – 1.648; OOO – 0.685; OOL

– 3.022; OOLe – 4.256; OLL – 4.444; OLLe –

12.502; OLeLe – 8.812; LLL – 2.179; LLLe –

9.200; LLeLe – 12.960, LeLeLe – 6.082 [2]

Tocopherols

Content, mg%: 0.195 [2]

PhL

Content, %: 0.2 [3]

References

1. E.I. Gigienova, Е.I. Kiryushina, А.U. Umarov, Chem. Nat.

Comp. 13(4), 411 (1977)

2. B.М. Baram, А.L. Маrkman, Uzb. Khim. Zhurn. (4), 47

(1963) [in Russian]

3. K.S. Мukhamedova, R.R. Akbarov, S.Т. Akramov, Chem.

Nat. Comp. 14(3), 330 (1978)

Poterium sanguisorba L. (Sanguisorbaminor Scop.)

Family: Rosaceae Juss.

Aerial Part

Essential oil [1]

Leaf

Carotene [2, 3]

Triterpenes, %: 5.5 [4]

Seed

Oil, %: 17.7–20.3 [5, 6]

n40D : 1.4713 [6]

Iodine value, % J2: 167 [6]

Saponification value, mg KOH/g: 187 [6]

FAs

Triene, as 18:3, %: nonconjugated – 29 [6]

Diene, as 18:2, %: nonconjugated – 38 [6]

Monoene, as 18:1, %: 19 [6]

Saturated, %: 8.8 [6]

Composition (GLC, Silar 5 CP), %: 16:0 – 6.03;

16:1 – 0.13; 17:0 – 0.08; 17:1 – 0.05; 18:0 – 2.89;

18:1 – 13.16; 18:2 – 36.88; 18:3 – 38.20; 20:0 –

0.43; 20:1 – 0.64; 22:0 – 0.28; 22:1 – 0.10 [7]

16:1

Composition of isomers (Ag+-PТLC), %: n-7 –

62.6; n-9 – 37.4 [7]

18:1

Composition of isomers (Ag+-PТLC), %: n-5 – 0.4;

n-7 – 2.8; n-9 – 96.8 [7]

20:1

Composition of isomers (Ag+-PТLC), %: n-7–

65.6; n-9 – 14.1; n-11 – 20.3 [7]

References

1. E.F. Heeger, Pharm. Ind. 7, 370 (1940); Chem. Abstr. 37,

N 1563 (1943)

2. L. Grlic, Acta Pharm. Jugosl. 4, 115 (1954); Chem. Abstr. 49,

N 5594 (1955)

Page 41: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Prunus armeniaca L. 741 Rosaceae Juss.

3. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikh

khimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

4. A. Pourrat, Bull. Soc. Bot. France 112(7–8), 351 (1965)

5. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

6. F.R. Earle, E.H. Melvin, L.H. Mason, C.H. van Etten, I.A.

Wolff, J. Am. Oil Chem. Soc. 36(7), 304 (1959)

7. A. Seher, U. Gundlach, Fette, Seifen, Anstrich. 84(9), 342

(1982)

Prunus amygdalus Boill.

Family: Rosaceae Juss.

Kernel

Oil, % on dry wt: 42.5

n25D : 1.4681

Iodine value, % J2: 93.8

Saponification value, mg KOH/g: 198.7

FAs

Content, %: 0.2

Composition (GLC), %: 16:0 – 5.35; 16:1 – 0.38;

18:0 – 1.12; 18:1 – 78.70, 18:2 – 14.45

References

1. C. Galoppini, G. Lotti, Olearia 16, 164–167 (1962); Chem.

Abstr. 61, N 11023 (1964)

Prunus armeniaca L.

Family: Rosaceae Juss.

Fruit

Essential oil (from fresh material)

Components (GC/MS, GLC, BD-1): (Ether elu-

tion): Hydrocarbons: (E, Z)-1,3,5-Undecatriene,

dodecane, tridecane, pentadecane; esters: ethylpropanoate, methyl butanoate, ethyl 2-

methylpropanoate, methyl 2-methylbutanoate,

ethyl butanoate, propyl propanoate, butyl ace-

tate, 2-propyl butanoate, ethyl 2-

methylbutanoate, propyl butanoate, ethyl

pentanoate, butyl propanoate, pentyl acetate, 2-

methylpropyl 2-methylpropanoate, methyl

hexanoate, propyl 2-methylbutanoate, butyl 2-

methylpropanoate, 2-methylpropyl butanoate, 2-

methylbutyl propanoate, butyl butanoate, ethyl

hexanoate, 2-methylpropyl 2-methylbutanoate,

hexyl acetate, 2-methylbutyl 2-

methylpropanoate, butyl 2-methylbutanoate,

butyl 3-methylbutanoate, pentyl 2-

methylpropanoate, 3-methylbutyl butanoate, 2-

methylbutyl butanoate, pentyl butanoate, propyl

hexanoate, ethyl heptanoate, hexyl propanoate, 2-

methylbutyl 2-methylbutanoate, methyl

octanoate, pentyl 2-methylbutanoate, hexyl 2-

methylpropanoate, 2-methylpropyl hexanoate, 2-

methylbutyl pentanoate, ethyl (E)-4-octenoate,

(Z)-3-hexenyl butanoate, butyl hexanoate, hexyl

butanoate, ethyl octanoate, (Z)-3-hexenyl 2-

methylbutanoate, hexyl 2-methylbutanoate, (E)-

2-hexenyl acetate, 3-methylbutyl hexanoate, 2-

methylbutyl hexanoate, pentyl hexanoate, propyl

octanoate, 2-methylpropyl octanoate, ethyl (Z)-4-

decenate, hexyl hexanoate, butyl octanoate,

ethyl decanoate, hexyl benzoate, hexyl octanoate,

butyl decanoate, ethyl dodecanoate, ethyl

hexadecanoate; alcohols: butanol, 2-

methylbutanol, hexanol, 3-hexanol, 2-hexanol,

(Z)-3-hexenol, (E)-2-hexenol, a-terpineol; car-

bonyl compounds: hexanal, (E)-2-hexenal, 2-

hexanone, hexadecanal, (E)-2-nonenal, (E,E)-2,4-decadienal, tetradecanal, benzaldehyde,

phenylacetaldehyde, (Z)-2-heptenal, 6-methyl-5-

hepten-2-one, 3-nonen-2-one, 2,2,6-trimethylcy-

clohexanone; miscellaneous: limonene, (E)-b-ocimene, linalool, nerol, geraniol, geranylacetone,

b-cyclocitral, 3,4-didehydro-b-ionol, dihydro-b-ionone, epoxy-b-ionone, b-ionone, g-decalactone,d-decalactone, g-octalactone, dihydroacti-

nidiolide, g-dodecalactone [1]In addition: Terpene hydrocarbons, terpene alco-

hols, lactones [2, 3]; camphene, g-terpinene, g-butyrolactone [4]; damascenone, rose oxide,

nerol oxide [5]

Composition of esters, %: Butyl butanoate – 29.66;

butyl hexanoate – 24.54; hexyl butanoate –

11.78; ethyl hexanoate – 4.70; hexyl hexanoate

– 4.12; hexyl 2-methyl-butanoate – 3.50; butyl 2-

methylbutanoate – 2.76; ethyl butanoate –

2.00; pentyl butanoate – 1.45; butyl propanoate

– 1.30 [1]

Page 42: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 742 Prunus armieca

Kernel

Essential oil

Content (fermentation), %: 0.6–1.6 [6]

Seed

Essential oilComponent: Benzaldehyde (main) [7]

Moisture, %: 5.56 [7]

Oil, % on dry wt: 40.39 [7]

d36: 0.9204 [7]

n36D : 1.46375 [7]

Acid value, mg KOH: 7.85 [7]

Iodine value, % J2: 99.35 [7]

Saponification value, mg KOH/g: 192.0 [7]

Saponification equivalent: 292.2 [7]

Unsaponifiables, %: 1.38 [7]

FAs (GLC), %: 14:0 – 2.69; 16:0 – 4.40; 18:0 – 1.12;

18:1 – 68.42; 18:2 – 21.69; 20:0 – 0.50 [7, 8]

d24-cholesterol, % on dry wt: 0.91 [9]

b-Sitosterol [8]

References

1. G.R. Takeoka, R.A. Flath, T.R. Mon, R. Teranishi, M.

Guentert, J. Agric. Food Chem. 38(2), 471 (1990)

2. C.S. Tang,W.G. Jennings, J. Agric. Food Chem. 15, 24 (1967)

3. C.S. Tang, W.G. Jennings, J. Agric. Food Chem. 16, 252

(1968)

4. F. Rodriguez, S. Seck, J. Crouzet, Lebensm. Wiss. Technol.

13, 152 (1980)

5. G. Chairote, F. Rodriguez, J. Crouzet, J. Food Sci. 46(1898),

1906 (1981)

6. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

7. D.R. Dhingra, U.K. Shukla, Proc. Ann. Convention Oil

Technol. Assoc. India 3(2) (1947); Chem. Abstr. 45, N 8273

(1951)

8. M.Y. Haggag, M.S. Hifnawy, Bull. Fac. Pharm., Cairo Univ.

13(1), 175 (1974); Chem. Abstr. 86, N 40213d (1977)

9. O. Awad, Phytochemistry 13(3), 678 (1974)

Prunus armieca

Family: Rosaceae Juss.

Fruit

Essential oil

Components (GLC, Carbowax 20M): Myrcene,

limonene, p-cymene, terpinolene, trans-2-

hexenol, acetic acid, cis-epoxydihydrolinalool,

trans-epoxydihydrolinalool, linalool,

2-methylbutyric acid, a-terpineol, geranial, gera-niol, g-octalactone, g-decalactone

References

1. C.S. Tang,W.G. Jennings, J. Agric. FoodChem. 16, 252 (1968)

Prunus avium L.

Family: Rosaceae Juss.

Fruit

Lipids, % on fresh wt: 0.1–0.3 [1, 2]; mg/100 g on

fresh wt: 123 [1]

Lipid phosphorus, %: 2.1 [1]

FAs (GLC, 25% DEGS-2% phosphoric acid): 14:0

– 0.7; 16:0 – 19.7; 16:1 – 0.4; 17:0 – 0.4; 17:1 –

0.2; 18:0 – 6.7; 18:1 – 33.5; 18:2 – 19.0; 18:3 –

18.4; 20:0 – 0.9 [1]

Composition of lipids (CC), %: NL – 31.2; GL –

23.5; PhL – 45.3 [1]

NL

Components: Wax esters, sterol esters, free sterols,

triterpene acids [1]

FAs (GLC, 25% DEGS-2% phosphoric acid): 14:0

– 1.8; 16:0 – 26.4; 16:1 – 0.7; 17:0 – 0.4; 17:1 –

0.3; 18:0 – 8.1; 18:1 – 30.5; 18:2 – 15.2; 18:3 –

15.2; 20:0 – 1.3 [1]

Ester fraction, mg/100 mg total lipid: 11.8 [1]

Sterols, mg/100 mg total lipid: 1.2 [1]

Composition (GLC, 3% OV-101), %: Sitosterol –

95; campesterol – 5 [1]

Free sterol, mg/100 mg total lipid: 6.6 [1]

Composition (GLC, 3% OV-101), %: Sitosterol –

95; campesterol – 5 [1]

Triterpenoic acids, mg/100 mg total lipid: 12.5 [1]

Components: Oleanolic and ursolic acids (1:6.7) [1]

GL

FAs (GLC, 25% DEGS-2% phosphoric acid): 14:0

– 0.9; 16:0 – 17.2; 16:1 – 0.4; 17:0 – 0.4; 17:1 –

0.3; 18:0 – 6.9; 18:1 – 29.3; 18:2 – 15.8; 18:3 –

28.1; 20:0 – 0.7 [1]

Acyl-SG, mg sugar/100 mg total lipid: 2.6 [1]

Component of sterols (GLC, 3% OV-101): Sitos-

terol over 95% [1]

MGDG, mg sugar/100 mg total lipid: 0.4 [1]

DGDG, mg sugar/100 mg total lipid: 1.62 [1]

Page 43: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Prunus cerasus L. 743 Rosaceae Juss.

PhL

FAs (GLC, 25% DEGS-2% phosphoric acid): 14:0

– 0.6; 16:0 – 18.8; 16:1 – 0.2; 17:0 – 0.3; 17:1 –

0.2; 18:0 – 6.3; 18:1 – 35.2; 18:2 – 20.8; 18:3 –

16.5; 20:0 – 1.1 [1]

Composition of PhL, %: PhC + PhE – 80.0; PhG,

diPhG, PhS, PhI [1]

PhC, mg phosphor/100 mg total lipid: 1.16 [1]

PhE, mg phosphor/100 mg total lipid: 0.48 [1]

a-TocopherolContent, ppm on fresh wt: 1.3 [3]

Kernel

Oil (petroleum ether), % on dry wt: 28.3–37.9 [2]

Leaf

Ursolic acid [4]

Sitosterol [4]

Seed

Oil (petroleum ether), % on dry wt: 3.4–5.8 [2]

n40D : 1.4692–1.4721 [2]

Iodine value, % J2: 123.1–127.8 [2]

Saponification value, mg KOH/g: 188.2–191.5 [2]

Unsaponifiables, %: 0.77–1.19 [2]

FAs (GLC, 20%DEGS), %: 14:0– tr; 16:0–6.7–9.9;

18:0 – 0.9–4.2; 20:0 – 0.3–1.1; 16:1 – 0.3–0.7;

18:1 – 38.6–53.2; 18:2 – 33.9–51.9; 18:3 –

0.2–0.8 [2]

Eleostearic acid, %: 7–10 [5]; 13.5 [6]

18:2 – 2.2 [6]

Tocopherols

Content, mg%: 8–20 [5]

Sterols

Composition, %: Sitosterol – 87–94; D5-avenasterol

– 2.1–6.5; campesterol – 2.5–4.9; cholesterol – tr

– 0.6 [5]

References

1. D.G. Bishop, N.L. Wade, Phytochemistry 16(1), 67 (1977)

2. F. Farrohi, M. Mehran, J. Am. Oil Chem. Soc. 52(12), 520

(1975)

3. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

4. S.A. Siddiqui, A.B. Sen, J. Indian Chem. Soc. 46, 755 (1969)

5. J.A. Funes, P. Cattaneo, Ann. Assoc. quim. Argent. 66, N 5,

239 (1978); Chem. Abstr. 93(5), 41530m (1980)

6. A. Popov, Izv. Inst. ObshchaNeorg. Khim., Org.Khim. Bulgar.

Akad. Nauk 9, 175 (1962); Chem. Abstr. 59, N 5495 (1963)

Prunus cerasus L.

Family: Rosaceae Juss.

Fruit

Lipids (petroleum ether), % on fresh wt: 0.51–0.59 [1]

Kernel

Oil (petroleum ether), % on dry wt: 20.5–33.2 [1]

d15: 0.921–0.929 [2]

n20D : 1.472–1.474 [2]

Acetic value, mg KOH: 12.0 [2]

Hehner value %: 94.5–96.0 [2]

Iodine value, % J2: 93–122 [2]

Polenske value, mL KOH: 0.3 [2]

Reichert-Meissl value, mL KOH: 0.3–0.4 [2]

Saponification value, mg KOH/g: 186–195 [2]

Saturated acids, %: 8–9 [2]

Thiocyanogen value, % J2: 87.3 [2]

Unsaturated acids, %: 91–92 [2]

Unsaponifiables, %: 1.0 [2]

FAs (GLC), %: 14:0 – 0.2; 16:0 – 4.3; 18:0 – 2.9;

20:0 – 1.0; 18:1 – 47–50; 18:2 – 40–42 [2]

TAG

Component (HPLC, the mobile phase CH3CN/H2O,

4:1, v/v): 1,3-di[(Z)-9-octadecenoyl]-2-[(Z,Z)-9,12-octadecadienoyl]glycerol [3]

FAs (GLC), %: 18:1 – 63.6; 18:2 – 31.5 [3]

%: eleostearic 18:3(9,11,13) – 7.5; 18:2 – 3.0 [4]

Seed

Oil (petroleum ether), % on dry wt: 5.8–7.7 [1]

Eleostearic acid, %: 14 [5]

Tocopherol, mg%: 8–20 [5]

Sterols

Composition, %: Sitosterol – 87–94; D5-avenasterol

– 2.1–6.5; campesterol – 2.5–4.9; cholesterol – tr

– 0.6 [5]

References

1. F. Farrohi,M.Mehran, J.Am.Oil Chem. Soc.52(12), 520 (1975)

2. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969) [in Russian]

3. A. Chandra,M.G.Nair, J. Agric. FoodChem. 41(6), 879 (1993)

4. A. Popov, Izv. Inst. ObshchaNeorg. Khim., Org.Khim. Bulgar.

Akad. Nauk 9, 175 (1962); Chem. Abstr. 59, N 5495 (1963)

5. J.A. Funes, P. Cattaneo, Ann. Assoc. quim. Argent. 66, N 5,

239 (1978); Chem. Abstr. 93(5), 41530m (1980)

Page 44: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 744 Prunus divaricata Ledeb. (P. caspica Koval. et Ekim., P. cerasifera auct., p.p.)

Prunus divaricata Ledeb. (P. caspicaKoval. et Ekim., P. cerasifera auct., p.p.)

Family: Rosaceae Juss.

Coat of Fruit

Essential oil

Seed

Oil

FAs: 18:1; 18:2

Use: The oil can be used in perfumery for medical

soap grade production, in food industry – for making

canned fish.

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Prunus domestica L.

Family: Rosaceae Juss.

Fruit

Essential oil

Composition, GLC: o-Xylene – 5; p-xylene – 5.45;

styrene – 14; nonanal – 49.5; hexane-2,5-dione –

5.9; benzaldehyde – 1.8; naphthalene – 16 [1]

Lipids

Epicuticular wax

Alkanes

Content, % of wax: 20.1 [1]

Composition, %: C21–C31; C27 – 4.3; C29 – 86.0; C31

– 2.9 [1]

Alkyl esters

Content, %: 8.2 [1]

Composition, %: C34–C50; C40 – 45.3; C42 – 20.5;

C44 – 18.5 [1]

Esterified primary alcohols

Composition of alcohols, %: C18–C30; C22 – 4.9;

C24 – 64.8; C26 – 16.5; C28 – 3.9 [1]

Esterified FAs, %: 12:0–32:0; 16:0 – 15.1; 18:0 –

16; 20:0 – 10.7; 22:0 – 5.1; 24:0 – 12.8 [1]

Ketones

Content, %: 1.0 [1]

Composition, %: C29-10-one – 100.0 [1]

Aldehydes

Content, %: 1.1 [1]

Secondary alcohols

Content, %: 48.3 [1]

Composition, %: C27–C31; C27-7-ol – 0.1; 8-ol – 0.8;

9-ol – 0.5; 10-ol – 0.3; C28 – 0.5; C29-9-ol – 2.9;

10-ol – 92.7; 11-ol – 1.0; C30 – 0.6; C31 – 0.6 [1, 2]

Primary alcohols

Content, %: 3.0 [1]

Composition, %: C18–C30; C24 – 53.3, C26 – 24.1,

C28 – 9.6 [1]

FAs

Content, %: 0.5 [1]

Composition, %: 16:0–36:0; 16:0 – 6.0; 24:0 – 14.5;

26:0 – 10.8; 28:0 – 16.9; 30:0 – 14.5, 34 – 21.7 [1]

Triterpenoic acids

Content, %: 5.4 [1]

Composition, %: Oleanolic, ursolic – 1.0 [1]

Kernel

Oil

d15: 0.915–0.920 [3]

n20D : 1.470–1.472 [3]

Hehner value, %: 95–97 [3]

Iodine value, % J2: 91–105 [3]

Polenske value, mL KOH: 0.7 [3]

Reichert-Meissl value, mL KOH: 0.2–0.8 [3]

Saponification value, mg KOH/g: 185.8–198 [3]

Saturated acids, %: 6–8 [3]

Thiocyanogen value, % J2: 80.4 [3]

Unsaturated acids, %: 92–94 [3]

Unsaponifiables, %: 0.5–0.6 [3]

Viscosity E20, sp: 72.8 [3]

FAs (GLC), %: 16:0 – 4.5–4.9; 18:0 – 1.0–1.4;

16:1 – 0.5–0.8; 18:1 – 69–72; 18:2 – 19–25 [3]

Seed

Essential oil

Content, %: 0.3–0.5 [4]

Component: Main benzaldehyde [4]

References

1. H.M. Ismail, G.A. Brown, O.G. Tucknott, P.J. Holloway, A.

A. Williams, Phytochemistry 16(6), 769 (1977)

2. P.J. Holloway, C.E. Jeffree, E.A. Baker, Phytochemistry

15(11), 1768 (1976)

Page 45: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Prunus mahaleb L. 745 Rosaceae Juss.

3. Rukovodstvo po metodam issledovaniya, tekhnokhimi-

cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969) [in Russian]

4. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952,) p. 249 [in Russian]

Prunus instititia L.

Family: Rosaceae Juss.

Fruit

a-Tocopherol

Content, ppm on dry wt: 40.0; on fresh wt – 7.0

References

1. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

Prunus laurocerasus L.

Family: Rosaceae Juss.

Leaf

Essential oil

Content (fermentation), %: 0.05–0.5 [1, 2]

[a]D: (�0�460)– (+0�300) [1]; (+0�120)–(�0�460) [2]d15: 1.046–1.067 [1, 2]

n20D : 1.5390–1.5430 [1, 2]

Acid value, mg KOH: 1.6–10.8 [1]

Composition, %: Benzaldehyde – 98.0; benzyl alco-

hol, benzaldehyde cyanohydrin, cyanogen acid –

0.4–4.1 [1, 2]

Lipids

Triterpene (total)

Content, %: 2.7 [3]

Ursolic acid

Content, %: 1.0 [3]

Seed

Essential oil

Content (fermentation), %: 1.0 [1]

d: 1.012 [1]

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

2. Efirnye masla, pod red. G.V. Pigulevskogo

(Pishchepromizdat, Мoskwa-Leningrad, 1938) [in Russian]

3. J. Le Men, H. Purrat, Ann. Pharm. Franc. 13, 169 (1955);

Chem. Abstr. 49, 11959 (1955)

Prunus lusitanica L.

Family: Rosaceae Juss.

Leaf

Triterpenes

Components: Ursolic acid, 2a,3a-dihydroxyurs-12-en-28-oic acid, ursol aldehyde, friedelin

References

1. H.W.A. Biessels, A.C. van der Kerk-van Hoof, J.J. Kettenes-

van den Bosch, C.A. Salemink, Phytochemistry 13(1), 203

(1974)

Prunus mahaleb L.

Family: Rosaceae Juss.

Kernel

Oil, % on dry wt: 27–36 [1]

Unsaponifiables, %: 0.5–1.62 [1]

b-Sitosterol [1]

Choline, %: 0.08–0.1 [2]

Seed

Eleostearic acid

Content, % on FAs: 43.0 [3]

Tocopherols

Content, mg%: 8–20 [3]

Sterols

Composition, %: Sitosterol–87–94;D5-avenasterol–

2.1–6.5; campesterol – 2.5–4.9; cholesterol – tr –

0.6

References

1. M. El-Dakhakhny, M.B.E. Fayez, Planta Med. 10(4), 455

(1962)

2. M. El-Dakhakhny, Planta Med. 13(1), 23 (1965)

3. J.A. Funes, P. Cattaneo, Ann. Assoc. quim. Argent. 66, N 5,

239 (1978); Chem. Abstr. 93(5), 41530m (1980)

Page 46: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 746 Prunus nepalensis L.

Prunus nepalensis L.

Family: Rosaceae Juss.

Leaf

Triterpenes

Friedelin

References

1. H.W.A. Biessels, A.C. van der Kerk-van Hoof, J.J. Kettenes-

van den Bosch, C.A. Salemink, Phytochemistry 13(1), 203

(1974)

Prunus padus L.

Family: Rosaceae Juss.

Flower

Lipids

Content (chloroform), %: 0.1

Composition (CC), %: Nonacosane – 22.8; b-sitosterol – 30.6; lupeol – 20.3

References

1. Z. Kowalewski, H. Grabarczyk, Dissert. Pharmaceut.

Pharmacol. XX(2), 211 (1968)

Prunus persica (L.) Batsch. (¼ Persicavulgaris)

Family: Rosaceae Juss.

Leaf

Lipids

Content (hexane), %: 1.3 [1]

Components (CC): Hentriacontane,

hentriacontanol, b-sitosterol, ursolic acid [1]

Cutine

Composition of oxy-FAs, %: Dioxy-16:0 – 74.0;

9,10-epoxy-18-oxy-18:0 – 6.5–32.0; 9,10,18-

trioxy-18:0 – 5–25 [2]

Kernel

Essential oil (fermentation),

Content, %: 0.7 [3]

Pulp of Fruit

Essential oil

Content, %: 0.0007–0.00082 [3]

Components: Paraffin, formic, acetic, valeric and

caprilic ethers of linalool, acetaldehyde,

furfurol [3]

Seed

Oil (petroleum ether), %: 13.8 [4]

d30: 0.9024 [4]

n22D : 1.4655 [4]

Acid value, mg KOH: 4.46 [4]

Hehner value, %: 90.3 [4]

Iodine value (Hanus), % J2: 89.2 [4]

Polenske value, mL KOH: 8.6 [4]

Reichert-Meissl value, mL KOH: 1.4 [4]

Saponification value, mg KOH/g: 200.4 [4]

Unsaponifiables, %: 2.2 [4]

FAs

Iodine value, % J2: 70.4 [4]

Mean mol. wt: 274.8 [4]

Liquid FAs, %: 66.6 [4]

Iodine value, % J2: 92.1 [4]

Mean mol. wt: 275.7 [4]

Solid FAs, %: 33.4 [4]

Iodine value, % J2: 46.2 [4]

Mean mol. wt: 273.4 [4]

Composition of FAs (oxidation, polarographie), %:

14:0 – 6.54; 16:0 – 6.18; 18:0 – 5.59; 20:0 – 2.48;

18:1 – 72.94; 18:2 – 6.29 [4]

(GLC), %: 14:0 – 1.0; 16:0 – 3.0; 18:0 – 11; 18:1 –

73.3–85.0; 18:2 – 16.2 [5]

References

1. S.A. Siddiqui, A.B. Sen, J. Indian Chem. Soc. 46(8), 755 (1969)

2. T.J. Walton, P.E. Kolattukudy, Biochemistry 11(10), 1885

(1972)

3. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

4. D.R. Gupta, S.K. Garg, Fette, Seifen, Anstrich. 70(7), 488

(1968)

5. M.I. Goryaev, N.A. Evdakova, Spravochnik po gazo-zhidkostnoi khromatografii organicheskikh kislot (izd.

“Nauka” Kaz. SSR, Alma-Ata, 1977) [in Russian]

Page 47: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Prunus sphaerocarpa SW 747 Rosaceae Juss.

Prunus salicina Lindl.

Family: Rosaceae Juss.

Fruit

Essential oil

Components (GLC/MS, 5% Igepal CO-880): Acet-

aldehyde,methanol, ethanol, ethyl ether (solvent),

1-propanol, ethyl acetate, chloroform, 2-methyl-

3-buten-2-ol, 2-methyl-1-propanol, 1-butanol, 1-

penten-3-ol, 1-propyl acetate, 1,1-

diethoxyethane, 3-hydroxy-2-butanone, 3-

methyl-1-butanol, 2-methyl-1-butanol, 2-methyl-

1-propyl acetate, diethyl carbonate, 1-pentanol,

ethyl butyrate, 1-butyl acetate, 2-methyl-2-

pentenal, 3-methyl-1-butyl acetate, 2-methyl-1-

butyl acetate, trans-3-hexen-1-ol, cis-3-hexen-1-

ol, 1-hexanol, trans-2-hexen-1-ol, 1-pentyl ace-

tate, benzaldehyde, 1-heptanol, 1-butyl butyrate,

ethyl hexanoate, cis-3-hexenyl acetate, 1-hexyl

acetate, g-hexalactone, 1-octanol, 1-heptyl ace-tate, linalool, benzyl, alcohol, benzyl acetate, 2-

phenylethanol, ethyl octanoate, a-terpineol, ethylphenylacetate, g-octalactone, 1-methylnaphtha-

lene, g-nonalactone, ethyl decanoate, biphenyl,ethyl anisate, g-decalactone, butylated

hydroxytoluene

References

1. R.R. Forrey, R.A. Flath, J. Agric. Food Chem. 22(3), 496

(1974)

Prunus serotina Ehrh.

Family: Rosaceae Juss.

Leaf

Essential oil

Content (fermentation), %: 1.0 [1]

d: 1.0532 [1]

Component: Cyanogen acid (0.27%) [1]

Lipids

Triterpenoic acids

Components: Ursolic acid, 2a,3a-dihydroxyurs-12-en-28-oic acid [2]

Ursolic aldehyde [2]

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

2. H.W.A. Biessels, A.C. van der Kerk-van Hoof, J.J. Kettenes-

van den Bosch, C.A. Salemink, Phytochemistry 13(1), 203

(1974)

Prunus sp.

Family: Rosaceae Juss.

Fruit

Essential oil

Composition (capillary GC, DB-1), %: Hexanal –

1.0; (E)-2-hexenal – 10.3; (Z)-3-hexenol – tr,

benzaldehyde – 64.0; benzyl alcohol – tr; ethyl

benzoate – tr; benzoic acid – tr; benzyl salicylate

– tr; palmitic acid – tr; ethyl palmitate – tr;

isopropyl palmitate – tr; C21H44 – 1.6; C23H48 –

1.7; C25H52 – tr [1]

Lipids

Moisture, %: 86.2 [2]

Tocopherols and tocotrienols

Composition (HPLC), mg/100 g on fresh wt: a-Tocopherol – 0.85; a-tocotrienol – tr; b-tocopherol – 0.01; g-tocopherol – 0.08 [2]

Carotenoids

Composition (HPLC), mg/100 g on fresh wt: a-Carotene – tr – 31; b-carotene – 140–430; lutein –120–240 [3]

References

1. R.J. Horvat, G.W. Chapman, J. Agric. Food Chem. 38(7),

1442 (1990)

2. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen, P.

Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

3. M.I. Heinonen, V. Ollilainen, E.K. Linkola, P.T. Varo, P.E.

Koivistoinen, J. Agric. Food Chem. 37(3), 655 (1989)

Prunus sphaerocarpa SW

Family: Rosaceae Juss.

Bark

Essential oil

Page 48: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 748 Prunus spinosa L. (P. stepposa Korov)

Content (fermentation), %: 0.046

d: 1.0409

Component: Benzaldehyde

Leaf

Essential oilContent, %: 0.001–0.085

Component: Cyanogen acid

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Prunus spinosa L. (P. stepposa Korov)

Family: Rosaceae Juss.

Coat of Fruit

Essential oil [1]

Fruit

Neutral lipids (methanol)

Component: Nonacosane, nonacosanol-10, b-sitosterol [2–4]

Carotene [5]

Vitamin E [5]

Seed

Oil, % on dry wt: 12.44–42.01 [5, 6]

FAs, %: 14:0 – 1.8–3.8; 16:0 – 4.96–9.9; 16:1 – 0.9–

1.0; 18:0 – 0.80–1.25; 18:1 – 66.47–67.41; 18:2 –

25.45–26.63; eleostearic 18:3(9,11,13) [5]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. U. Kaminska-Thiel, R.S. Ludwiczak, Rocz. Chem. 41(2), 409

(1967)

3. U. Kaminska-Thiel, R.S. Ludwiczak, Rocz. Chem. 44(2), 291

(1970)

4. U. Kaminska-Thiel, R.S. Ludwiczak, Rocz. Chem. 44(1), 103

(1970)

5. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

6. А.I. Barbarich, О.М. Dubovik, D.V. Strelko, Zhirooliiniroslini Ukrainy, Кiiv (1973), 132 p. [in Ukrainian]

Prunus virginiana Mill.

Family: Rosaceae Juss.

Bark

Essential oilContent (fermentation), %: 0.2

d: 1.045–1.050

Components: Benzaldehyde, cyanogen acid

Reference

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Pygeum acuminatum Coleb.

Family: Rosaceae Juss.

Bark of Stem

Lipids (hexane)

Triterpenoids

Components (IR, NMR, MS): Acuminatic acid

(2a,3a,19a-trihydroxyurs-12-en-28-oic acid);

friedelin, epifriedelinol, lupeol, betulinic acid,

ursolic acid, 2a-hydroxyursolic acid, 2a,3a-dihydroxyurs-12-en-28-oic acid,b-sitosterol [1, 2]

References

1. R.S. Chandel, R.P. Rastogi, Indian J. Chem. 15B, 914 (1977)

2. M.C. Das, S.B. Mahato, Phytochemistry 22(5), 1071 (1983)

Pyracantha coccinea M. Roem.(Cotoneaster pyracantha (L.) Spach,Crataegus pyracantha Medil.)

Family: Rosaceae Juss.

Aerial Part

Triterpenoic acids

Component: Morolic (3-hydroxyolean-18-en-28-oic)

acid

Content, % on plant wt: 0.008 [1]

Branch

Тriterpenoic acidsComponent: Moroloic acid (0.08%) [1]

Page 49: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Pyrus communis L. 749 Rosaceae Juss.

Fruit

Carotenoids

Components (TLC): a-,b- and g-Carotenes, lycopine,flavoxanthin, epoxide of xanthophyll [2]

Seeds + Pericarp

Mass of 1,000, g: 2.0 [3]

Oil, % on dry wt: 6.6 [3]

References

1. А.А. Ryabinin, V.N. Belous, Zhurn. Obshch. Khimii 33, vyp.

10, 3447 (1963) [in Russian]

2. P. Karrer, J. Rutschmann, Helv. Chim. Acta 28(7), 1528

(1945)

3. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Pyrus arbutifolia (L.) L. f.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 3.0

Oil, % on dry wt: 10.4

References

1. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Pyrus communis L.

Family: Rosaceae Juss.

Bark

Triterpenoides

Composition, %: Friedelin – 0.5; epifriedeline –

0.1 [1]

Sterols

b–Sitosterol, %: 0.04 [1]

Flower

Triterpenoides

Components (CC): Ursolic acid, oleanolic acid, a-amyrin, neoolenadiene [2]

Sterols

Component (GC/MS): b-Sitosterol [2]

Fruit

a-Tocopherol

Content, ppm on dry wt: 30.0; on fresh wt: 5.0 [3]

Flesh of Fruit

Lipids

Content, mg/kg: 1587–2674 [4]

FAs (GLC), %: 9:0 – 0.1; 10:0 – 0.1–0.2; 12:0 – 0.1–

0.2; 13:0–0.1; 14:0–0.2–0.3; 14:1– tr–0.1; 15:0–

0.1–0.4;16:0–11.7–14.8;16:1–0.1–0.6;16:2–0–

tr; 17:0 –0.1–0.3; 18:0 –4.3–6.0; 18:1–17.5–27.4;

18:2 – 22.8–36.0; 18:3 – 0.4–1.1; 20:1 – 5.6–12.5;

20:2 – 0–21.9; 20:3 – 0–14.7 [4]

NL

Content, mg/kg: 514.2–812.9 (30.4–39.4%) [4]

Composition, %: Hydrocarbons – 0.8–1.4; ethers of

sterols – 1.0–1.1; ethers of FAs – 3.6–3.8;ТАG –

0.9–1.3; tocopherols – 0.1; FFA – 0.2–0.4; fatty

alcohols – 3.0–3.6; DАG – 8.2–8.6; sterols – 8.3–

16.7; pigments (chlorophylls, carotenoids) –

0.05–0.3;МАG – 2.6–3.8 [4]

GL

Content, mg/kg: 625.3–751.4 (28.1–39.4%) [4]

Composition, %: acyl-MGDG – 0.9–1.1; ESG –

1.3–1.7; MGDG – 7.2–11.8; SG – 3.4–6.5; cere-

brosides – 2.5; ceramide oligosides – 3.5–4.7;

DGDG – 4.0–6.9; ceramide phosphate inositol

oligosides – 2.3–2.5; SQDG – 2.2–2.5 [4]

PhL

Content, mg/kg: 447.5–1109.7 (21.2–41.5%) [4]

Composition, %: di-PhG– 0–2.9; PhA– 0–1.3; PhE –

7.5–14.7; PhG – 6.8–12.4; PhC – 4.7–5.2; PhS –

0.8–2.2; PhI – 0.5–1.4; lyso-PhE – 0.3–1.0; lyso-PhC – 0.1–0.9 [4]

Chlorophylls

Content, mg/kg: 0.3–1.4 [4]

Composition, %: chlorophyll a – 50.7–61.8; chlo-

rophyll b – 15.1–18.4; chlorophyllide a – 13.3–

23.2; chlorophyllide b – 6.5–11.0 [4]

Carotenoids

Content, mg/kg: 0.1–0.2 [4]

Composition, %: Phytoene – 2.0–2.9; phytofluene –

2.3–3.1; a-carotene – 5.0–6.1; b-carotene –

16.6–38.1; hydroxy-a-carotene – 0.4–0.9;

cryptoxanthin – 1.1–2.8; lutein – 30.6–38.2; zea-

xanthin – 1.6–3.0; lutein-monoepoxide – 3.5–

4.9; mutatoxanthin – 1.1–3.7; violaxanthin –

4.9–6.5; luteoxanthin – 0–1.5; neoxanthin –

4.0–5.2 [4]

Page 50: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 750 Pyrus domestica Medic.

a-Tocopherol

Content, ppm on dry wt: 5.0; on fresh wt: <1.0 [3]

Skin of Fruit

Lipids

Content, mg/kg: 6850–9980 [4]

FAs (GLC), %: 9:0 – tr – 0.1; 10:0 – 0.1; 12:0 – 0.2–

0.3; 13:0 – 0.2; 14:0 – 0.1–0.3; 14:1 – tr–0.2;

15:0 – 0.2–0.3; 16:0 – 7.1–12.5; 16:1 – tr – 0.2;

16:2 – 0.2–0.7; 17:0 – 0.2; 18:0 – 1.1–2.9; 18:1 –

3.7–12.1; 18:2 – 19.0–29.5; 18:3 – 0.4–2.3;

20:1 – 0 – tr; 20:2 – 3.5–8.0; 20:3 – 35.1–59.1 [4]

NL

Content, mg/kg: 4110–5469 (54.8–60.0%) [4]

Composition of NL, %: Hydrocarbons – 4.8–5.0;

ethers of sterols – 2.4–3.6; ethers of FAs – 8.4–

9.0; ТАG – 1.4–1.8; tocopherols – 0.1–0.3; FFA

– 2.9–3.1; fatty alcohols – 4.3–4.5; DАG – 6.4–

6.9; sterols – 9.8–10.7; pigments (chlorophylls,

carotenoids) – 0.1–0.7; МАG – 11.3–17.3 [4]

GL

Content, mg/kg: 1753.6–2455.0 (24.6–25.6%) [4]

Composition, %: Acyl-MGDG – 3.9–4.7; ESG –

2.7–3.3; MGDG – 4.2–4.8; SG – 1.8–2.7; cere-

brosides – 1.4–2.1; ceramidoligosides – 3.6–4.1;

DGDG – 2.3–2.9; ceramidophosphateinosito-

ligosides – 1.1–1.7; SQDG – 1.2–1.7 [4]

PhL

Content, mg/kg: 986.4–2056.0 (14.4–20.6%) [4]

Composition, %: di-PhG – 0–0.5; PhA – 0–0.3;

PhE – 5.7–9.0; PhG – 4.2–5.6; PhC – 2.4–4.6;

PhS – 0.5–0.6; PhI – 0.4; lyso-PhE – 0.2–0.3;

lyso-PhC – 0.1–0.2 [4]

Chlorophylls

Content, mg/kg: 4.9–17.7 [4]

Composition, %: Chlorophyll a – 65.6–70.1; chlo-

rophyll b – 19.4–29.9; chlorophyllide a – tr –

10.4; chlorophyllide b – tr – 4.1 [4]

Carotenoids

Content, mg/kg: 0.7–19.2 [4]

Composition, %: Phytoene – 0.5–0.9; phytofluene –

1.1–1.7; a-carotene – 4.8–7.2; b-carotene – 7.7–

11.5; hydroxy-a-carotene – 4.5–6.0;

cryptoxanthin – 0.7–2.0; lutein – 47.1–56.0; zea-

xanthin – 3.8–6.4; lutein-monoepoxide – 2.4–

2.7; mutatoxanthin – tr – 1.7; violaxanthin –

7.8–9.0; luteoxanthin – 0–2.4; neoxanthin –

5.4–6.7 [4]

Cutine

Composition of monomers (GLC/MS, 3% OV-1 on

Gas Chrom-Q), %: Hexadecan-1-ol – 0.25;

octadecan-1-ol – 0.35; octadecen-1-ol – tr;

eicosan-1-ol – tr; hexadecane-1,16-diol – 2.74;

docosan-1-ol – tr; octadecane-1,18-diol – 3.34;

octadecene-1,18-diol – 9.42; hexadecanetriol –

44.76; octadecane-1,9,18-triol – 6.50;

octadecene-1,9,18-triol – 24.94; octadecane-

1,9,10,18-tetraol – 4.95; octadecene-1,9,10,18–

tetraol – 2.74 [5]

Triterpenoic acids

Component: Pomolic acid (2.18%) [6]

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLeО – 0.4; LeLeP – tr; LLL +

LeLО – 20.3; LeLP + LeLe – 0.8; LLО +

LeOO – 27.6; LLP + LeLS + LeОP –2.3;

LOO – 18.5; LLS + LOP + LeОS – 11.3;

LPP + LePS – 1.2; ОOO – 11.2; LОS + ОOP –

4.5; LPS + ОPP – 0.1; ОOS – 1.8 [7]

References

1. D. Chakravarti, N. Chakravarti, S. Samanta, J. Indian Chem.

Soc. 41(12), 859 (1964)

2. I. Rychlinska, J. Gudej, Herba Polon. XLVIII(4), 198 (2002)

3. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

4. А.А. Kolesnik, V.N. Golubov, E.B. Farzaliev, Chem. Nat.

Comp. 25(2), 148 (1989)

5. T.J. Walton, P.E. Kolattukudy, Biochemistry 11(10), 1885

(1972)

6. C.H. Brieskorn, H.P. S€uss, Tetrahedron Lett. (16), 1515

(1972)

7. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Pyrus domestica Medic.

Family: Rosaceae Juss.

Pollen

TAG

FAs (GLC), %: 10:0 – 0.15; 12:0 – 0.84; 14:0 –

2.07; 14:1 – 0.76; 15:0 – 0.13; izo-16:0 – 1.39;

Page 51: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Pyrus sp. 751 Rosaceae Juss.

16:0 – 25.05; 16:1 – 0.25; 16:2 – 0.27; 17:0 –

0.59; 17:1 – 0.27; 17:2 – 0.45; 18:0 – 4.14; 18:1 –

14.32; 18:2 – 32.86; 18:3 – 11.96; 19:0 – 0.50;

20:0 – 0.94; 21:0 – 1.50

References

1. V.А. Bandyukova, G.I. Deineko, D.К. Shapiro, Chem. Nat.

Comp. 18(2), 227 (1982)

Pyrus lanata D. Don.

Family: Rosaceae Juss.

Bark

Lipids (petrol ether)

Components (CC): b-Sitosterol, hexacosanol

C28H56O2, friedelin

Leaf

Lipids (petrol ether)

Components (CC): Myricyl alcohol, C30H62O, b-sitosterol, C29H50O, friedelin, C30H50O

References

1. N.N. Chakravarti, S.K. Moitra, A.N. Ganguly, R.N. Adhya,

Phytochemistry 10(6), 1403 (1971)

Pyrus malus L. (Malus domestica Borkh.)

Family: Rosaceae Juss.

Coat of Fruit

Essential oil

Content, %: 0.0022–0.0043 [1]

Fruit

Essential oil

Content, %: 0.0007 [1]

Components: Triacontane, furfurol, acetaldehyde,

methanol, ethanol, amylic alcohol, geraniol,

myristyl alcohol-carbinol, malol, formic acid,

acetic acid, capronoic acid, caprinoic acid and

their ethers [1]

Lipids

a-TocopherolContent, ppm on dry wt: 50.0; on fresh wt: 5.0 [2]

Flesh of Fruit

a-Tocopherol

Content, ppm on dry wt: 18.0; on fresh wt: 2.0 [2]

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

2. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

Pyrus pashia Buch. & Ham.

Family: Rosaceae Juss.

Stem

Lipids (benzene)

Components: Hentriacontanol, b-sitosterol,friedelin, a-amyrin, arborinol C30H50O

References

1. D.S. Bhakuni, N.C. Gupta, S. Satish, S.C. Sharma, Y.N.

Shukla, J.S. Tandon, Phytochemistry 10(9), 2247 (1971)

Pyrus sp.

Family: Rosaceae Juss.

Fruit

Essential oilComponents: (GLC, DC-705 on Celit 545): Acetal-

dehyde, acetone, octane ethylate, methanol,

methylethylketone, ethanol, isopropanol,

methylpropylketone, octane butanoate, n-

propanol, isoamyl octanoate, amyl octanoate,

methylamylketone, isopentanol

References

1. A. Pribela, Biologia 20(3), 173 (1965)

Page 52: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 752 Rosa achburensis Chrshan

Rosa achburensis Chrshan

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Т.F. Коchkareva, Е.P. Тrofimova, Izv. АN Таdzh. SSR,otdel. biol. nauk (1), 17 (1967) [in Russian]

Rosa acicularis Lindl. (R. sichotealinensisKolesn., R. gmelini Bge., R. baicalensisTurcz., R. carelica Fr., R. korsakoviensisLevl.)

Family: Rosaceae Juss.

Fruit

Mass of 1,000, g: 350–420 [1]

Carotenoids

Content, mg% on abs. dry wt: 24.7–49.9 [1]

Petal

Essential oil

Content, % on fresh wt: 0.04 [2, 3]

Seed

Oil, % on dry wt: 8.0–10.0 [3]

Use: The essential oil is used in perfumery and soap

industry [2].

The fatty oil of seeds – outwardly by chaps, bedsores,

trophic ulcers of shank, dermatosis, by burns [4, 5],

radiation injury of skin [6]. The clysters – by

nonspecific colitis [7].

References

1. G.P. Shnyakina, E.P. Маlygina, Rastit. Resursy 11, vyp. 3,

390 (1975) [in Russian]

2. N.I. Suprunov, P.G. Gorovoi, Yu.A. Pankov, Efirno-maslichnye rasteniya Dal’nego Vostoka (Izd. “Nauka”, Novo-sibirsk, 1972), 187 s [in Russian]

3. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1938), 550 s [in Russian]

4. А.F. Gammerman, I.I. Grom, Dikorastushchie lekarstvennyerasteniya SSSR (Мoscow, 1976), 286 s [in Russian]

5. D.А. Murav’eva, Farmakognoziya (Мoscow, 1978), 656 s [in

Russian]

6. V.G. Minaeva, Lekarstvennye rasteniya Sibiri (Novosibirsk,1970), 272 s [in Russian]

7. Lekarstvennye preparaty, razreshennye k primeneniyu v SSSR(Мoscow, 1979), 351 s [in Russian]

Rosa agrestis Savi

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: Carotene, lycopene

References

1. F.C. Jacoby, F. Wokes, Biochem. J. 38(3), 279 (1944)

Rosa alba L.

Family: Rosaceae Juss.

Flower

Essential oil

Content, % (distillation): 0.03 [1]; (petroleum

ether): 0.08 [2]; 0.005–0.01 [3]

[a]: (�2�540)–(3�500) [1]; (�2�350)–(�3�500) [4]d: 0.852–0.869 [1]; d30 0.8526–0.8696 [4]

n25D : 1.4587–1.4622 [1, 4]

Acid value, mg KOH: 2.2 [1, 4]

Ether value, mg KOH: 11.1 [1]; 9.9 [4]

Ether value after acetylation, mg KOH: 222.4 [1];

213.9 [4]

Composition, %: total alcohols – 73 [1]

References

1. B.N. Rutovskii, Efirnye masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

2. Biokhimija kul’turnykh rastenii, t. 6, pod red. N.N.

Ivanova, Sel’khozgiz (Мoskwa-Leningrad, 1938), 228 s [in

Russian]

Page 53: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa americana Waitz 753 Rosaceae Juss.

3. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikh

khimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

4. Efirnye masla, pod red. G.V. Pigulevskogo

(Pishchepromizdat, Мoskwa-Leningrad, 1938) [in Russian]

Rosa alberti Regel

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg% on abs. dry wt (colorimetry): 30.0

[1, 2]

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rosa alexeenkoi Crep.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg% on abs. dry wt (colorimetry): 9.0

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rosa amblyotis C.A. Mey.

Family: Rosaceae Juss.

Fruit

Mass of 1,000, g: 200–320 [1]

Carotenoids

Content, mg% on abs. dry wt: 4.4–17.2 [1]; on dry

wt: 44.0 [2]

References

1. G.P. Shnyakina, E.P. Malygina, Rastit. Resursy 11, vyp. 3,

390 (1975) [in Russian]

2. I.N. Kushchinskaya, L.O. Shnaidman, Med. promyshlennost’

SSSR (4), 38 (1964) [in Russian]

Rosa americana Waitz

Family: Rosaceae Juss.

Flower

Wax

Hydrocarbons

Content, % on wax: 63.9; % on absolute: 31.2 [1]

Composition, % (Ag+-CC): paraffins –65.0; olefins –

10.4 [1]

Branched-chain hydrocarbons, %: 0.8 [1]

Paraffins

Composition (GLC, 2% SE-30), %: C19 – 1.0; C20 –

0.5; C21 – 5.2; C22 – 0.8; C23 – 9.7; C24 – 1.4; C25

– 16.7; C26 – 1.4; C27 – 43.7; C28 – 1.3; C29 –

10.8; C31 – 4.4; C33 – 3.1 [1]

Olefins

Composition (GLC, 2% SE-30), %: C19 – 4.6; C20 –

0.3; C21 – 1.8; C22 – 0.4; C23 – 7.5; C24 – 2.2; C25

– 17.0; C26 – 2.5; C27 – 35.1; C28 – 1.8; C29 –

15.9; C31 – 6.8; C33 – 4.0 [1]

Aldehydes

Content (CC, TLC), %: 2.24 [2]

Composition (GLC, 1.5% SE-30 on Chromosorb

W), %: C15 – 1.3; C16 – 6.7; C17 – 0.4; iso-C18 –

3.7; C18 – 12.3; C19 – 0.5; C20 – 10.7; C21 – 3.2;

C22 – 19.8; C23 – 5.3; C24 – 11.7; C25 – 4.0; C26 –

7.4; C27 – 1.6; C28 – 11.3 [2]

Primary alcohols

Composition, %: C18 – 0.1; C19 – 0.5; C20 – 1.8; C21 –

3.1; C22 – 10.4; C23 – 3.9; C24 – 12.8; C25 – 3.6;

C26 – 16.9; C27 – 5.7; C28 – 32.7; C29 + b-amyrin –

2.0; C30 – 4.0; a-amyrin – 2.5 [3]

Sterols

Composition, %: b-Sitosterol – 91; cholesterol,

campesterol [3]

Page 54: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 754 Rosa beggeriana Schrenk (R. lehmanniana Bge.)

References

1. B. Stoianova-Ivanova, K. Mladenova, Compt. Rend Acad.

Bulg. Sci. (Dokl. Bolg. АN) 27(9), 1239 (1974)

2. K. Mladenova, B. Stoianova-Ivanova, Compt. Rend. Acad.

Bulg. Sci. (Dokl. Bolg. АN) 28(3), 335 (1975)

3. K. Mladenova, B. Stoianova-Ivanova, Phytochemistry 16(2),

269 (1977)

Rosa beggeriana Schrenk(R. lehmanniana Bge.)

Family: Rosaceae Juss.

Flower

Essential oil [1]

Fruit

Carotene

Content, mg% on abs. dry wt (colorimetry): 42.0 [2]

Vitamin E [3]

Seed

Oil [4]

Use: The fatty oil is used by burns and dermatitis [4].

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

3. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

4. D.A. Muraveva, Farmakognoziya (Мoscow, 1978), 656 s

[in Russian]

Rosa bellicose Nevski

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa bungeana Boiss. et Buhse

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa buschiana Chrshan.

Family: Rosaceae Juss.

Seed

Oil

Content, % on dry wt: 13.37 [1]

b-Carotene

Content (colorimetry), mg%: on dry wt 8.20; %:

13.37 [2]

Vitamin E

Content, mg%: 204 [2]

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

2. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Rosa caesia Smith (R. coriifolia Fries)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: b-Carotene [1–3], lycopene [3]

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, ser. biol. nauk (3), 23

(1978) [in Russian]

2. I.R. Riekstinsh, E.A. Rubine, S.M. Ozola, L.K. Baranova, Izv.

AN Latv. SSR (9), 33 (1975) [in Russian]

3. F.C. Jacoby, F. Wokes, Biochem. J. 38(3), 279 (1944)

Page 55: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa canina L. 755 Rosaceae Juss.

Rosa canina L.

Family: Rosaceae Juss.

Flower

Essential oil [1]

Wax

Content, % on fresh wt: 0.24 [2]

Acid part, % on wax: 5.0 [2]

Neutral part, % on wax: 95.0 [2]

Composition of neutral wax, %: Aldehydes – 6.22;

aliphatic hydrocarbons – 23.89; aliphatic alco-

hols – 10.21; sterols – 2.4 [3]

Free FAs (total) (GLC, 10%DEGS on Chromosorb

W), %: 12:0 – 0.2; 14:0 – 1.7; 15:0 –0.7; 16:0 –

66.5; 16:1 – 3.7; 18:0 – 11.7; 18:1 – 8.3; 20:0 –

0.6; 22:0 – 0.6; 24:0 – 0.5 [2]

Ester-bound FA (total) (GLC, 10% DEGS on

Chromosorb W), %: 12:0 – 0.7; 14:0 – 3.4;

15:0 – 0.8; 16:0 – 53.6; 16:1 – 3.6; 17:0 – 2.8;

18:0 – 11.2; 18:1 – 4.2; 20:0 – 2.5; 22:0 – 3.1;

24:0 – 1.5 [2]

Alcohols of ester (total): C14, C22, C24, 1-octadecanol,

b-sitosterol [2]Esters, fraction I

FAs (GLC, 10% DEGS on Chromosorb W), %:

11:0 – 0.3; 12:0 – 0.1; 13:0 – 0.1; 14:0 – 0.4;

15:0 – 0.3; 16:0 – 0.9; 16:1 – 4.0; 18:0 – 0.8;

18:1 – 0.1; 19:0 – 1.1; 20:0 – 3.3; 21:0 – 9.9;

22:0 – 9.9; 23:0 – 5.0; 24:0 – 38.4; 25:0 – 1.7;

26:0 – 24.5 [2]

Alcohols (GLC, 3% OV-17 on Gas-chrom P), %:

C16:1 – 0.4; C18 – 0.5; C19 – 0.1; C20 – 12.0; C21 –

1.2; C22 – 45.3; C23 – 1.0; C24 – 18.2; C25 – 0.8;

C26 – 10.7; C27 – 0.4; C28 – 6.6; C29 – 1.0; C30 –

2.7 [2]

Esters, fraction II

FAs (GLC, 10% DEGS on Chromosorb W), %:

14:0 – 6.2; 15:0 – 5.7; 16:0 – 21.5; 18:0 – 13.9;

18:1 – 48.2 [2]

Alcohols (GLC, 3% OV-17 on Gas-chrom P), %:

C12 – 1.2; C14 – 12.6; C15 – 1.6; C16 – 3.0; C18 –

0.7; C19 – 2.2; C20 – 11.8; C21 – 2.0; C22 – 40.5;

C23 – 2.5; C24 – 12.5; C25 – 1.0; C26 – 5.9; C28 –

2.6 [2]

Hydrocarbons

n-Paraffins (IR, GLC, 2.5% SE-30 on Chromosorb

W), %: C19 – 0.8; C20 – 0.5; C21 – 6.0; C22 – 0.03;

C23 – 13.8; C24 – 1.8; C25 – 10.4; C26 – 1.6;

C27 – 25.2; C28 – 2.1; C29 – 16.2; C30 – 0.8; C31

– 13.5; C32 – 0.3; C33 – 3.0 [3, 4]

Olefins (Ag+/TLC, IR, GLC, 2.5% SE-30 on

Chromosorb W), %: C19 – 1.1; C20 – tr; C21 –

1.1; C22 – tr; C23 – 3.0; C24 – 1.5; C25 – 5.6; C26 –

1.8; C27 – 14.1; C28 – 4.1; C29 – 31.3; C30 – 2.5;

C31 – 22.7; C32 – 1.0; C33 – 10.6 [3]

Dienes (Ag+/TLC, IR, GLC, 2.5% SE-30 on

Chromosorb W), %: C22 – 1.8; C23 – 3.1; C24 –

11.3; C25 – 5.6; C26 – 7.2; C27 – 11.3; C28 – 6.7;

C29 – 4.4; C30 – 8.2; C31 – 2.8; C32 – 8.9; C33 –

1.8; C34 – 3.4 [3]

Aldehydes (IR, GLC, 2.5% SE-30), %: C14 – 7.4;

C16 – 2.6; C17 – 0.4; C18 – 1.1; C20 – 7.2; C21 – 1.5;

C22 – 16.8; C23 – 2.3; C24 – 14.5; C25 – 1.8; C26 –

10.7; C27 – 1.5; C28 – 17.7; C29 – 0.9; C30 – 13.4 [3]

Primary alcohols (GLC, 3% OV-17), %: C20 – 0.3;

C21 – 0.5; C22 – 7.8; C23 – 1.0; C24 – 15.8; C25 –

1.2; C26 – 24.0; C27 – 1.7; C28 – 26.0; C29 – 2.2;

C30 – 14.6; C31 – 0.8; C32 – 4.0 [3]

Secondary alcohols (GLC, 3% OV-17), %: C14 –

0.1; C15 – 0.1; C16 – 0.1; C17 – 0.8; C18 – 0.1;

C19 – 2.5; C20 – 0.2; C21 – 0.6; C25 – 0.6; C26 – 0.7;

C27 – 0.1; C28 – 0.2; C29 – 2.3; C30 – 1.4; C31 –

87.1; C32 – 1.0; C33 – 2.0 [3]

Triterpenoic acids

Sterols

Composition, (GLC, 3% OV-17), %: b-Sitosterol –88.7; stigmasterol – 1.5; campesterol – 3.7; cho-

lesterol – 1.4 [3]

Fruit

Oil, % on dry wt: 4.4–4.9 [5]; on abs. dry wt: 4.6 [6]

nD 1.481 [6]

Acid value, mg KOH: 7.05–9.1 [5]; 4.8 [6]

Lipids

Composition, %: NL – 7.3; GL – 83.6; PhL – 9.1 [6]

NL

FAs (GLC, PEGS), %: 10:0 – 0.3; 12:0 – 0.2; 14:0 –

0.2; 16:0 – 4.4; 16:1 – 0.5; 18:0 – 2.8; 18:1 –

22.6; 18:2 – 48.9; 18:3 – 18.8; 20:0 – 1.3 [6]

GL

FAs (GLC, PEGS), %: 12:0 – 0.7; 14:0 – 0.6; 16:0 –

11.8; 16:1 – 0.8; 18:0 – 4.1; 18:1 – 19.2; 18:2 –

31.9; 18:3 – 30.9 [6]

PhL

FAs (GLC, PEGS), %: 12:0 – 1.0; 14:0 – 0.7; 16:0 –

31.5; 16:1 – 1.7; 18:0 – 8.5; 18:1 – 24.2; 18:2 –

24.9; 18:3 – 7.5 [6]

Page 56: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 756 Rosa canina L.

(GLC), %: 16:0 – 2.5; 18:0 – 2.0; 18:1 – 15.0; 18:2 –

62.0; 18:3 – 18.5; 20:0 – 1.0 [3]

Carotenoids

Content, mg/g on abs. dry wt: 32.0 [7]; mg/g on

fresh wt: 0.47 [8]; mg%: 362.5–838 [5, 6]

Carotene

Content, mg/100 g: 22.5–40.5 [9]; mg% on abs. dry

wt: 14.0 [10]

Composition of carotenoids, % (CC, TLC, UV):

Phytofluene – 1.1; a-carotene – tr; b-carotene –

16.8; x-carotene and b-zeacarotene – 0.3; g-carotene – 15.0; lycopene – 39.1; cryptoxanthin –

12.0; 5,6:monoepoxy-a-carotene – 2.9; 5,6:

monoepoxy-b-carotene – 3.2; rubixanthin – 0.8;

violaxanthin – 1.0; zeaxanthin – 0.6;

anteraxanthin – 2.8; lycoxanthin – 0.7 [8]

In addition: cis-Rubixanthin, cis-lycopene, cis-g-carotene [11]

Triterpenoic alcohols [3]

Sterols

Components: b-Sitosterol, stigmasterol,

campesterol, b-sitosteryl oleate [3]Vitamin Е [12]

Pollen

Essential oil

Components (GC/MS, Superox FA): Terpenoids:

6-methyl-5-hepten-2-one, geranyl acetone; ali-phatics: pentadecane, tetradecanal, hexadecanal;

aromatics: methyleugenol, b-phenylethyl acetate[13]

Pulp

Lipids

Content (hexane), % on dry wt: 0.8–1.1; (chloro-

form-methanol): 5.5–6.7 [5]

Carotenoids, mg%: 2613–3933 [5]

Carotene, % on dry wt: 0.01–0.07 [14]

Unsaponifiables, mg/100 g: 26.0 [15]

Root

Triterpenes

Content, %: 5.2 [16]

Seed

Moisture, %: 6.62 [17]; 8.37 []

Oil (hexane), % on dry wt: 8.0–8.9 [5]

Acid value, mg KOH: 2.2–2.8 [5]

FAs, %: Saturated – 24.0; 18:1 – 50.2; unsaturated –

75.0 [17]

(GLC, 17% PEGS), %: 14:0 – 0.5–2.0; 16:0 – 6.8–

7.8; 16:1 – 0.3–1.0; 18:0 – 0.6–2.8; 18:1 – 16.8–

20.0; 18:2 – 32.5–41.0; 18:3 – 23.7–34.9; 20:0 –

0.7–4.5; 22:0 – 0.6–4.4 [5]

(GLC, capillary column, 5% phenyl methyl sili-

cone), %: 16:0 – 3.87; 18:0 – 3.65; 18:1(9) –

21.96; 18:2 – 51.18; 18:3 (a-linolenic) – 18.13;

20:0 – 0.56; 20:1(11) – 0.58 [18]

Carotenoids

Content, mg%: 4.0 [17]; 2.5–5.0 [5]

Tocopherols

Content, mg%: 232.0

PhL

Content, %: 0.2 [19]

Lipids (chloroform-methanol)

Content, %: 0.9–1.4 [5]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

1952), p. 249 [in Russian]

2. B. Stoyanova-Ivanova, Y. Angelova, Compt. Rend. Acad.

Bulg. Sci. 32(6), 771 (1979)

3. B. Stoyanova-Ivanova, I. Iochkova, K. Meadenova, R.

Daskolov, Compt. Rend. Acad. Bulg. Sci. 32(11), 1503

(1979)

4. M. Streibl, A. Buckova, J. Tomko, Chem. Zvest. 29(5), 709

(1975)

5. N.T. Ulchenko, A.I. Glushenkova, Y.M. Murdakhaev,

Chem. Nat. Comp. 31(5), 565 (1995)

6. N.T. Ulchenko, Kh.S. Mukhamedova, A.I. Glushenkova,

A.A. Nabiev, Chem. Nat. Comp. 31(6), 672 (1995)

7. M.V. Sivtsev, I.V. Abramovich, Rastit. Resursy 15(2), 230

(1979) [in Russian]

8. L.R.G. Valadon, A.M. Sellens, R.S. Mummery, Ann. Bot.

39(162), 785 (1975)

9. B.D. Alekseev, Rastit. Resursy 17(4), 557 (1981) [in Russian]

10. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

11. G. Toth, J. Szabolcs, Acta Chim. Acad. Sci. Hung. 64(4), 393

(1970)

12. B.D. Alekseev, Rastit. Resursy 7, vyp. 4, 557 (1981) [in

Russian]

13. H.E.M. Dobson, J. Bergstrom, G. Bergstrom, I. Groth, Phy-

tochemistry 26(12), 3171 (1987)

14. Т.F. Kochkareva,Е.P. Trofimova, Izv.АN Tadzh. SSR, otd.

biol. nauk (1), 17 (1967) [in Russian]

15. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

16. A. Pourrat, Bull. Soc. Botan. France 112(7–8), 351 (1965)

17. L. Stepanov, T. Khadzhiiski, T. Palaveeva, Maslo-Sapunena

Prom. 19(2), 38 (1983); Chem. Abstr. 100, N 32228e (1984)

18. S. Ercisli, E. Orhan, A. Esitken, Chem. Nat. Comp.

(2006) (unpublished)

19. K.S. Mukhamedova, S.T. Akramov, Chem. Nat. Comp.

13(4), 505 (1977)

Page 57: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa cinnamomea L. 757 Rosaceae Juss.

Rosa cardina

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 27

Oil, % on dry wt: 14.3

References

1. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Rosa centifolia L.

Family: Rosaceae Juss.

Bud

Essential oil

Content (distillation), % on dry wt: 0.03 [1]

a½ �25D : 0� [1]d15: 0.8628 [1]

n25D : 1.4627 [1]

Acid value, mg KOH: 19.6 [1]

Ether value, mg KOH: 35.07 [1]

Ether value after formil., mg KOH: 68.74 [1]

Content (petroleum ether + distillation), %: 1.05 [1]

a½ �20D : +0�200 [1]d15: 0.8666 [1]

n20D : 1.4637 [1]

Acid value, mg KOH: 16.8–18.2 [1]

Ether value, mg KOH: 39.2–64.4 [1]

Ether value after acetylation: 129.6 [1]

Ether value after formil., mg KOH: 105.21 [1]

Calyx, Stamen, Pistil

(Without petals)

Essential oilContent, %: 0.005 [2]

[a]: –41� [2]d15: 0.8704 [2]

Acid value, mg KOH: 6.12 [2]

Ester value, mg KOH: 22.4 [2]

Composition, %: Stearoptene – 51.13; total alcohols

– 13.99; citronellole – 13.56 [2]

Flower

Essential oil

Content (petroleum ether), %: 0.11–0.19 [3]; (dis-

tillation), %: 0.007–0.012 [2]; 0.016–0.02 [4]

[a]D: �3� [2]; (�0�230)–(�0�520) [4]d15: 0.8790 [2]; d30: 0.845–0.855 [4]

n: 1.4571–1.4614 [4]

Acid value, mg KOH: 0–4.3 [4]

Acetic value, mg KOH: 4.5–10.4 [4]

Composition, %: Total alcohols – 88.55; citronellol –

22.4 [2]; total alcohols – 54–60.4; stearoptene –

26–42; citronellol – 13–17; phenylethyl alcohol –

9 [4]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. Efirnye masla, pod red. G.V. Pigulevskogo

(Pishchepromizdat, Мoskwa-Leningrad, 1938) [in Russian]

3. Biokhimija kul’turnykh rastenii, t. 6, pod red. N.N. Ivanova

(Sel’khozgiz, Мoskwa-Leningrad, 1938), 228 s [in Russian]

4. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Rosa cinnamomea L.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, mg% on dry wt: 5.5–43.3 [1, 2]

Components (CC, TLC, UV): Phytofluene, a-, b-, z-carotene, poly-cis-lycopene A, B and C, lyco-

pene, cryptoxanthin, rubixanthin, taraxanthin [2]

Composition, %: Lycopenes – 53.2; oxygen

containing carotenoids – 41.3 [2]

Carotene (colorimetry), mg% on abs. dry wt: 29 [3]

Seed

TAG

Composition (HPLC), %: LeLeLe – 2.0; LeLeL –

8.1; LeLL + LeLeО – 19.8; LeLeP – 1.3; LLL +

LeLO – 25.3 (5:2); LeLP + LeLe – 3.9; LLO +

LeOO – 17.7 (5:1); LLP + LeLS + LeOP – 6.5;

LOO – 7.4; LLS + LOP + LeOS – 4.6; LPP +

LePS – tr;ОOO – 1.8; LOS +ОOP – 1.2; LPS +

ОPP – 0.3; ОOS – tr [4]

Page 58: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 758 Rosa corymbifera Borkh. (R. dumetorum Thuill.)

References

1. Dikorastushchie i introdutsiruemye poleznye rasteniyav Bashkirii, vyp. 1 (АN SSSR, Bashkirskii philial, institute

biologii, 1961) [in Russian]

2. I.N. Kushchinskaya, L.O. Shnaidman, Med. promyshlennost’

SSSR (4), 38 (1964) [in Russian]

3. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

4. V.I. Deineka, L.А. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Rosa corymbifera Borkh. (R. dumetorumThuill.)

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg/100 g: 24.0–36.5 [1]; (colorimetry) mg%

on abs. dry wt: 11.0 [2]

Carotenoids

Components (CC, TLC, UV): b-, g-Carotene, lyco-pene, rubixanthin [3]

Seed

Oil, % on dry wt: 8.42 [4]

b-Carotene (colorimetry), mg% on dry wt: 10.0; %:

8.42 [4]

Vitamin E, mg%: 185.0 [4]

References

1. B.D.Аlekseev, Rastit. Resursy 17(4), 557 (1981) [in Russian]

2. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

3. I.N. Kushchinskaya, L.O. Shnaidman, Med. promyshlennost’

SSSR (4), 38 (1964) [in Russian]

4. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Rosa damascena Mill. (R. damascena f.Trigintipetala)

Family: Rosaceae Juss.

Bud

Concrete

Hydrocarbons

n-Paraffins

Composition (molecular sieve, GLC, 3% SE-30),

%: C17 – 0.4; C18 – 0.2; C19 – 13.9; C20 – 1.7;

C21 – 12.2; C22 – 0.9; C23 – 12.3; C24 – 1.0; C25 –

8.7; C26 – 0.8; C27 – 21.6; C28 – 1.2; C29 – 12.8;

C30 – tr; C31 – 12.3; C33 – tr [1]

n-Olefins (molecular sieve, GLC, 3% SE-30), %:

C19 – 3.3; C20 – 0.4; C21 – 3.4; C22 – 0.7; C23 –

8.8;C24–1.4;C25–11.2;C26–2.3;C27–21.5;C28–

3.7; C29 – 33.5; C30 – 0.8; C31 – 7.6; C33 – 1.4 [1]

Wax

Ketones

Composition (GLC), %: C27 – 1.7; C28 – 0.6; C29 –

7.6; C30 – 1.2; C31 – 83.1; C32 – 3.0 [2]

Calyx

Essential oil

Content, %: 0.008 [3]

d30: 0.8754 [3]

n27: 1.4810 [3]

Acid value, mg KOH: 0.93 [3]

Ether value, mg KOH: 18.18 [3]

Flower

Essential oil

Content (steam distillation), %: 0.02–0.34 [4–6];

0.0087–0.037 [3]; (petroleum ether), %: 0.22–

0.25 [4]

[a]: (�0.2�)–(�8�) [7]; (�1�)–(�4.06�) [6]d15: 0.849–0.862 [6]; d2020: 0.8257–0.8334 [7]; d:

0.8257–0.889 [3, 8]

d30: (steam distillation) 0.822–0.880 [4, 6]; (petro-

leum ether) 0.9502–0.9750 [4]

n25: (steam distillation) 1.4520–1.4660 [6, 7]; n27:

1.4525–1.4590 [7]; nD: 1.4069–1.467 [3]; n30:

(petroleum ether) 1.4846–1.5160 [4]; 0.004–

0.105 [6]

Acid value (petroleum ether), mg KOH: 7.6–8.4

[4]; 0.21–5.70 [3]; (steam distillation): 0.15–

0.21 [7]; 0.5–3 [6]

Ester value (steam distillation): 4.50–22.06 [3, 4, 6];

22.06–23.9 [7] (petroleum ether) 22.4–26.9 [4]

Ester value after acetylation (steam distillation):

197.00–233.33 [4, 6]; 114.3–129.5 [7]; 31.80–

255.90 [3]; (petroleum ether) 227.73–236.3 [4]

Iodine value, % J2: 0.92–17.2 [4]

Saponification value, mg KOH: 3.14–16.50 [3]

Composition (steam distillation), %: Phenylethanol –

63.7; citronellole + geraniol – 22.1; geraniol +

Page 59: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa damascena Mill. (R. damascena f. Trigintipetala) 759 Rosaceae Juss.

nerole – 13.7; eugenol + eugenolacetate – tr [4];

(petroleum ether), %: stearoptenes – 12.4–85.5;

geraniol – 19.6–35.3; citronellol – 14.3–58.6

[4, 7]; phenylethanol – 1–7; geraniol – 30.0–87.4;

citronellol –5.81–37.0; nerol –10–15; isomenton–

2–4; ethanol – 2–4; benzaldehyde – 1.0–1.5;

methyleugenol – 1.0; eugenol – 1.0–1.5; citral –

0.5–1.0; valeric aldehyde – tr; salicylic aldehyde –

tr; linalool, farnezol, nonalaldehyde [3, 5, 6]

Concrete

Content, % of fresh wt: 0.35–0.36 [9]

Hydrocarbons

n-Paraffins

Composition (molecular sieve, GLC, 3% SE-30),

%: C17 – 0.6; C18 – tr; C19 – 18.4; C20 – 2.2;

C21 – 17.3; C22 – 0.8; C23 – 12.6; C24 – 0.6; C25 –

6.8; C26 – 0.7; C27 – 18.9; C28 – 1.1; C29 – 11.3;

C30 – tr; C31 – 8.8 [1]

n-Olefins (molecular sieve, GLC, 3% SE-30), %:

C19 – 3.0; C20 – 0.3; C21 – 3.2; C22 – 0.4; C23 –

6.0; C24 – 1.3; C25 – 9.6; C26 – 1.9; C27 – 24.5;

C28 – 3.7; C29 – 34.8; C30 – 0.8; C31 – 8.5; C33 –

2.1 [1]

Alkadienes (GLC, IR, UV), %: C11 – 1.2; C12 – 3.2;

C13 – 4.5; C14 – 4.5; C15 – 3.1; C16 – 4.6; C17 –

3.1; C18 – 1.1; C19 – 14.2; C20 – 2.9; C21 – 6.9;

C22 – 0.7; C23 – 4.7; C24 – 1.0; C25 – 60; C26 –

1.3; C27 – 8.2; C28 – 2.3; C29 – 9.3; C30 – 1.1; C31 –

2.8; C33 – 0.8 [10]

g-Diols

Content, % on wax: 7.0 [11]

Lactones of g-hydroxy acids

Components (MS,M+,%): C22 – 0.1; C23 – 0.2; C24 –

3.0; C25 – 2.0; C26 – 6.0; C27 – 0.3; C28 – 0.2 [12]

Absolute

Content, % of concrete: 46.87–53.90 [9]

Wax

Content, % of concrete: 38.44–53.13 [9]

Composition of wax (TLC), %: Hydrocarbons –

48.6–57.1; esters I – 7.1–9.3; carbonyl com-

pounds – 2.0–7.4; esters II – 2.4–3.1; secondary

alcohols – 3.4–8.1; primary alcohols and other

polar comp. – 12.5–19.0 [9]

Hydrocarbons

Alkanes

Composition (GLC), %: C17 – 0.6; C19 – 10.4–18.4;

C20 – 1.4–2.2; C21 – 14.4–17.3; C22 – 0.6–0.8;

C23 – 11.3–12.6; C24 – 0.6–0.8; C25 – 6.8–8.5;

C26 – 0.7–1.4; C27 – 18.9–29.7; C28 – 1.1–2.7;

C29 – 10.2–11.3; C31 – 7.1–8.8; C33 – 1.5 [9]

Alkenes

Composition (GLC), %: C19 – 1.3–3.0, C20 – 0.3,

C21 – 2.4–3.2, C22 – 0.4, C23 – 6.0–6.8, C24 –

0.9–1.3, C25 – 8.8–9.6, C26 – 1.8–1.9, C27 –

24.5–36.7, C28 – 2.7–3.7, C29 – 24.5–34.8, C30

– 0.8–0.9, C31 – 8.5–8.7, C33 – 2.1–4.5 [9]

Alkadienes

Composition (GLC), %: C12 – 3.2; C13 – 4.5; C14 –

4.5; C15 – 3.1; C16 – 4.6; C17 – 3.1; C18 – 1.1; C19 –

14.2; C20 – 2.9; C21 – 6.9; C22 – 0.7; C23 –

4.7; C24 – 1.0; C25 – 6.0; C26 – 1.3; C27 – 8.2;

C28–2.3;C29–9.3;C30–1.1;C31–2.8;C33–0.8[9]

Ketones

Composition (GLC), %: C17 – 0.4; C18 – 0.2; C19 –

3.4; C20 – 1.0; C21 – 2.9; C22 – 1.0; C23 – 2.3; C24

– 1.2; C25 – 2.4; C26 – 2.2; C27 – 1.9–6.8; C28 –

2.8–3.0; C29 – 7.4–8.3; C30 – 1.6–2.8; C31 –

55.5–79.8; C32 – 2.6–3.4; C33 – 3.2; C34 – 1.2;

C35 – 0.8 [2, 9]

Aldehydes

Composition (GLC), %: C20 – 0.3; C21 – 1.0–2.7;

C22 – 1.1–10.0; C23 – 3.6–26.1; C24 – 4.5–22.2;

C25 – 1.5–9.2; C26 – 4.1–5.7; C27 – 3.1; C28 –

10.2–28.8; C29 – 3.4; C30 – 10.0–30.7; C31 – 0.7;

C32 – 4.0–12.1 [9]

Secondary alcohols

Composition (GLC), %: C15 – 0.1; C16 – 0.4; C17 –

1.0; C18 – 0.8; C19 – 1.8; C20 – 1.2; C21 – 2.2;

C22 – 3.9; C23 – 4.0; C24 – 4.9; C25 – 4.6; C26 –

4.9; C27 – 0.5–5.2; C28 – 4.7; C29 – 2.4–5.2; C30 –

0.9–3.4; C31 – 50.0–94.3; C32 – 0.3–0.5; C33 –

1.4–1.8 [9]

Primary alcohols

Composition (GLC), %: C16 – 0.4; C17 – 0.3; C18 –

0.4; C19 – 0.5; C20 – 3.4–3.9; C21 – 0.9–2.1; C22 –

12.8–20.9; C23 – 1.3–1.4; C24 – 13.1–18.7; C25 –

1.1–1.2; C26 – 12.5–15.9; C27 – 1.5–1.9; C28 –

17.7–24.4; C29 – 1.4–1.5; C30 – 5.5–9.5; b-amyrin – 2.3–3.4; a-amyrin – 9.2–11.1 [9]

Free acids

Composition (GLC), %: 12:0 – 0.3–2.7; 13:0 – 0.6;

14:0 – 0.9–1.1; 15:0 – 0.8; 16:0 – 23.5–28.1;

17:0 – 0.6–0.8; 18:0 – 9.8–10.4; 18:1 – 1.7–2.6;

18:2 – 12.2–21.1; 18:3 – 12.4–14.1; 19:0 – 0.7;

20:0 – 2.4–11.5; 21:0 – 0.2–0.6; 22:0 – 2.4–5.9;

23:0 – 0.3–0.7; 24:0 – 1.1–2.1; 26:0 – 0.3 [9]

Page 60: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 760 Rosa davurica Pall.

Flower with Calyx

Essential oil

Content, %: 0.032 [3]

d30: 0.8334 [3]

n27: 1.4590–1.4624 [3]

Acid value, mg KOH: 0.65 [3]

Ether value, mg KOH: 23.90 [3]

Composition, %: Total alcohols – 39.27; citronellol –

12.30; stearoptene – 29.1 [3]

Petal

Essential oil

Content, %: 0.036 [3]

d30: 0.8257–0.8439 [3]

n27: 1.4524–1.4565 [3]

Acid value, mg KOH: 0.21 [3]

Ether value, mg KOH: 22.06 [3]

Composition, %: Total alcohols – 34.28; citronellol –

14.30; stearoptene – 50.0 [3]

Use: Attar of roses is used in perfumery, soap indus-

try, food industry, pharmaceutical, medical, and other

sectors of the national economy [8].

References

1. K. Mladenova, B. Stoianova-Ivanova, Compt. Rend. Acad.

Bulgar. Sci. (Dokl. Bolg. AN) 26(7), 901 (1973)

2. B. Stoianova-Ivanova, K.Mladonova, S. Popov, Phytochem-

istry 10(6), 1391 (1971)

3. V.P Nilova, Biokhimija kul’turnykh rastenii, t. 6, pod red. N.N. Ivanova (Sel’khozgiz, Мoskwa-Leningrad, 1938), 228 s.

[in Russian]

4. К.А. Guseva, Маsloboino-zhirovaya promyshlennost’ (8),24 (1956) [in Russian]

5. Y. Nuraliev, Lekarstvennye rasteniya (“Maorif”, Dushanbe,

1989), 283 s [in Russian]

6. B.N. Rutovskii, Efirnye masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

7. Efirnye masla, pod red. G.V. Pigulevskogo

(Pishchepromizdat, Мoskwa-Leningrad, 1938) [in Russian]

8. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

9. K. Mladenova, Y.A. Yochkova, B. Stoianova-Ivanova, Phy-

tochemistry 22(4), 943 (1983)

10. B. Stoianova-Ivanova, K. Mladenova, I. Malova, Phyto-

chemistry 10(10), 2525 (1971)

11. B. Stoianova-Ivanova, P. Hadjieva, J. Tamas, Phytochemis-

try 13(8), 1523 (1974)

12. P. Hadjieva, B. Stoianova-Ivanova, B. Danieli, Chem. Phys.

Lipids 12(1), 60 (1974)

Rosa davurica Pall.

Family: Rosaceae Juss.

Flower

Essential oil

Content, %: 0.05–0.06 [1]

Fruit

Mass of 1,000, g: 320–520 [2]

Carotenoids

Content, mg% on abs. dry wt: 10.0–46.2 [2]

Seed

Oil [3]

Use: Fatty oil is used outwardly by burn, trophic

ulcer, and dermatitis [4], radiation injury of skin [3].

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. G.P. Shnyakina, E.P. Malygina, Rastit. Resursy 11, vyp. 3,

390 (1975) [in Russian]

3. D.A. Muraveva, Farmakognoziya (Moscow, 1978), 656 s [in

Russian]

4. A.F. Gammerman, I.I. Grom, Dikorastushchie lekarstvennyerasteniya SSSR (Moscow, 1976), 286 s [in Russian]

Rosa dumalis Bechst. (R. afzeliana Friesex Liljebl., R. vosagiaca Desportes)

Family: Rosaceae Juss.

Fruit

Carotene [1]

Seed

Oil, % on dry wt: 7.84 [2]

FAs (GLC, capillary column, 5% phenyl methyl

silicone), %: 16:0 – 4.20; 18:0 – 2.82; 18:1(9) –

38.08; 18:2 – 49.39; 20:0 – 0.55; 20:1(11) – 0.39;

21:0 – 0.18 [2]

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

2. S. Ercisli, E. Orhan, A. Esitken, Chem. Nat. Comp.

(2006) (unpubl.)

Page 61: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa foetida Herrm. (Rosa lutea Mill., R. fedorovii Sumn. ex Chrschan.) 761 Rosaceae Juss.

Rosa eglanteria L.

Family: Rosaceae Juss.

Leaf

Essential oil

(Steam distillation, fresh leaves):

a½ �20D : �5�

d20: 0.924–0.933

n20D : 1.5105

Acid value, mg KOH: 23.2

Ether value, mg KOH: 35.3

Ether value after acetylation, mg KOH: 67.3

Saponification value, mg KOH: 58.5

(petroleum ether extraction):

a½ �20D : +34.9�

d20: 0.840–0.880

n25D : 1.5145

Acid value, mg KOH: 13.8

Ether value, mg KOH: 35.3

Ether value after acetylation, mg KOH: 65.4

Saponification value, mg KOH: 173.3

References

1. T. Krzaczek, J. Chybowski, Acta Polon. Pharm. XXX(3), 325

(1973)

Rosa elasmacantha Trautv.

Family: Rosaceae Juss.

Fruit

Carotene

References

1. G.G. Gadzhieva, Izv. AN AzSSR, ser. biol. nauk (3), 23

(1978) [in Russian]

Rosa elliptica Tausch

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa fedtschenkoana Regel

Family: Rosaceae Juss.

Pulp of Fruit

Carotene [1]

Seed

Oil [2]

Use: The fatty oil is used by burn, dermatitis, radia-

tion injury of skin [2].

References

1. Т.F. Kochkareva, Е.P. Trofimova, Izv. АN Tadzh. SSR, otd-

nie biol. nauk (1), 17 (1967) [in Russian]

2. D.A. Muraveva, Farmakognoziya (Moscow, 1978), 656 s

[in Russian]

Rosa floribunda Stev.

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 6.0

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rosa foetida Herrm. (Rosa lutea Mill.,R. fedorovii Sumn. ex Chrschan.)

Family: Rosaceae Juss.

Flower

Essential oil

Page 62: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 762 Rosa gallica L.

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Rosa gallica L.

Family: Rosaceae Juss.

Flower

Essential oilContent (steam distillation), %: 0.008 [1]; (petro-

leum ether extraction), %: 0.12 [2]

d3015: 0.8440 [1]

Composition, %: Citronellol – 30.0; geraniol – 26.0;

aliphatic hydrocarbons – 9.0 [3]

Wax

FAs (GLC, PEGS), %: 12:0 – 1.0; 13:0 – tr; 14:0 –

1.0; 15:0 – tr; 16:0 – 16.3; 16:1 – tr; 17:0 – tr;

18:0 – 28.2; 18:1 – 1.0; 18:2 – 5.0; 19:0 – tr; 20:0

– 29.1; 21:0 – tr; 22:0 – 8.4; 24:0 – tr [4]

Composition, %: Hydrocarbons – 42.4; complex

ethers of FAs with alkanols and cyclic alcohols

– 21.6; second alcohols, carbonyl components

(aldehydes and ketones) – 6.3; primary alcohols

– 4.0; free acids – 3.3; acetate of triterpenoic acid

– 0.1; triterpenols – 2.5; sterols – 5.5 [4]

Alkanes

Composition (GLC, SE-30), %: С17 – 0.5; С18 –

0.2;С19 – 20.4;С20 – 2.9;С21 – 21.5;С22 – 0.5;

С23 – 11.5;С24 – 1.0;С25 – 9.0;С26 – 1.1;С27 –

19.1; С28 – 0.7; С29 – 4.3; С30 – 0.4; С31 – 4.0;

С32 – tr; С33 – 0.5; С34 – tr; С35 – tr [4]

Alkenes

Composition (GLC, SE-30), %: С19Н40 – tr;

С21Н41 – tr; С23Н48 – 1.0; С25Н52 – 0.3;

С27Н56 – 0.7; С29Н60 – 0.6; С31Н64 – 0.3 [4]

Complex ethers

FAs of complex ethers (GLC, PEGS), %: 12:0 –

0.4; 13:0 – 0.7; 14:0 – 0.7; 15:0 – tr; 16:0 – 11.0;

17:0 – 0.5; 18:0 – 29.8; 18:1 – 1.4; 18:2 – 3.3;

19:0 – tr; 20:0 – 31.6; 21:0 – 0.5; 22:0 – 20.1;

24:0 – tr [4]

Alcohols of complex ethers (TLC), %: Aliphatic –

69; cyclic – 31 [4]

(GLC, MS), %:С18 saturated and monoenic – 18.4;

С19 saturated and monoenic – tr; С20 saturated

and monoenic – 40.4; С21 saturated and

monoenic – tr; С22 saturated and monoenic –

28.9; С23 saturated and monoenic – tr; С24 sat-

urated and monoenic – 8.7; С26 saturated – 3.6;

С28 saturated – tr; С30 saturated – tr; С32 satu-

rated – tr [4]

FFA (GLC, PEGS), %: 12:0 – 1.3; 13:0 – tr; 14:0 –

2.8; 15:0 – tr; 16:0 – 11.5; 16:1 – tr; 17:0 – 0.2;

18:0 – 25.8; 18:1 – 3.5; 18:2 – 1.8; 19:0 – tr; 20:0

– 31.4; 21:0 – 0.2; 22:0 – 17.5; 24:0 – 4.0 [4]

Free alcohols (GLC, MS), %: С16Н33ОН – 2.3;

С17Н35ОН – 0.4;С18 saturated and monoenic –

6.1; С19 saturated and monoenic – 1.7; С20 sat-

urated and monoenic – 17.5; С21 saturated and

monoenic – 2.6; С22 saturated and monoenic –

21.6; С23 saturated and monoenic – 2.6; С24

saturated and monoenic – 20.1; С25Н51ОН –

4.3; С26Н53ОН – 17.5; С26Н51ОН – 3.3;

С28Н57ОН – tr; С30Н61ОН – tr; С32Н65ОН –

tr [4]

Second alkanols

Components (MS): С25–33Н51–67ОН [4]

Sterols

Components: Cholesterol, campesterol, stigmas-

terol, b-sitosterol [4]

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 24 [5]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. Biokhimija kul’turnykh rastenii, t. 6, pod red. N.N.

Ivanova (Sel’khozgiz, Мoskwa-Leningrad, 1938), 228 s [in

Russian]

3. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

4. D.T. Asilbekova, S.D. Gusakova, A.I. Glushenkova, Chem.

Nat. Comp. 35(3), 295 (1999)

5. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Page 63: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa imperial 763 Rosaceae Juss.

Rosa glutinosa auct.

Family: Rosaceae Juss.

Flower

Essential oil

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Rosa huntica Chrshan.

Family: Rosaceae Juss.

Pulp of Fruit

Carotene

Content, % on dry wt: 0.04–0.06

References

1. Т.F. Kochkareva, Е.P. Trofimova, Izv. АN Tadzh. SSR, otd-

nie biol. nauk (1), 17 (1967) [in Russian]

Rosa iberica Stev. ex. Bieb.

Family: Rosaceae Juss.

Flower

Essential oil [1]

Fruit

Carotene

Content, mg/100 g: 24.8–36.0 [2]

Seed

Oil (ether)

b-Carotene

Content (colorimetry), mg% on dry wt: 16.20; %:

7.95 [3]

Vitamin E

Content, mg% on oil: 180.0 [3]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. B.D. Alekseev, Rastit. Resursy 17(4), 557 (1981) [in Russian]

3. V.A. Bunakov, Biol. nauki (2), p. 144 (1960) [in Russian]

Rosa iliensis Chrshan

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 2.0

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rosa imperial

Family: Rosaceae Juss.

Flower

Absolute

Content, %: 43.0 [1]

Wax, %: 57.1 [1]

Hydrocarbons

Composition (Ag+/CC), %: Paraffins – 42.3; olefins

– 11.2; branched-chain – 0.3 [1]

Paraffins

Composition (GLC, 2% SE-30), %: C19 – 0.7; C20 –

0.4; C21 – 3.1; C22 – 0.5; C23 – 14.1; C24 – 1.4;

C25 – 20.1; C26 – 1.4; C27 – 38.9; C28 – 1.3; C29 –

9.3; C31 – 6.6; C33 – 2.2 [1]

Olefins

Composition (GLC, 2% SE-30), %: C21 – 1.0; C22 –

0.7; C23 – 7.7; C24 – 1.8; C25 – 17.0; C26 – 2.5;

C27 – 33.9; C28 – 1.6; C29 – 15.3; C30 – tr; C31 –

10.6; C33 – 7.9 [1]

Primary alcohols

Composition, (GLC), %: C19 – 0.2; C20 – 0.9; C21 –

1.7; C22 – 2.1; C23 – 2.6; C24 – 20.8; C25 – 3.8;

C26 – 25.1; C27 – 4.1; C28 – 31.7; C29+b-amyrin

– 1.1; C30 – 2.1; a-amyrin – 3.8 [2]

Page 64: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 764 Rosa kokanica (Regel) Regel ex Juz.

Sterols

Composition (GLC), %: b-Sitosterol – 91.0; choles-terol, campesterol [2]

Aldehydes

Content (CC, TLC), %: 2.27 [3]

Composition (GLC, 1.5% SE-30), %: C16 – 2.0; C17

– 0.4; iso-C18 – 1.1; C18 – 4.3; C19 – 2.2; C20 –

10.3; C21 – 9.7; C22 – 30.1; C23 – 7.6; C24 – 15.5;

C25 – 2.4; C26 – 7.1; C27 – 1.1; C28 – 6.2 [3]

References

1. B. Stoianova-Ivanova, K. Mladenova, Compt. Rend. Acad.

Bulg. Sci. (Dokl. Bolgar. AN) 27(9), 1239 (1974)

2. K. Mladenova, B. Stoianova-Ivanova, Phytochemistry 16(2),

269 (1977)

3. K. Mladenova, B. Stoianova-Ivanova, Compt. Rend. Acad.

Bulg. Sci. (Dokl. Bolgar. AN) 28(3), 335 (1975)

Rosa kokanica (Regel) Regel ex Juz.

Family: Rosaceae Juss.

Fruit

b-CaroteneVitamin E

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rosa laevigata Michx.

Family: Rosaceae Juss.

Aerial Part

Lipids (acetone)

Triterpenoic acids (CC, 13C NMR): Ursolic,

oleanolic, 2a-hydroxyursolic, 2a-methoxyursolic,

tormentic, 11a-hydroxy tormentic, euscaphic

References

1. J.-M. Fang, K.-C. Wang, Y-S. Cheng, Phytochemistry 30(10),

3383 (1991)

Rosa laxa Retz.

Family: Rosaceae Juss.

Fruit

Carotenoids [1]

Carotene

Content, mg%: 5–6 [2]

References

1. V.G. Khrzhanovskii, V.G. Klyazkina, A.I. Shreter, Dokl.

Mosk. sel.-khoz. akad. im. K.A. Timiryazeva (187), 143

(1972) [in Russian]

2. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

Rosa lehmanniana Bunge (R. laceransBoiss. et Buhse)

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rosa majalis Herrm. (R. cinnamomea L.)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: a-, b-Carotene, lycopene,

phytofluene, poly-cis-lycopenes А, В and С,

cryptoxanthin, rubixanthin, taraxanthin [1]

Pulp of Fruit

Carotenoids

Content, mg/100 g: 2.0–19.8 [2]

Page 65: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa micramtha Smith (R. floribunda Stev. ex Bess.) 765 Rosaceae Juss.

Seed

Oil [3]

Tocopherols

Components: a-, d-tocopherols [4]

Use: The oil of fruits is used for prophylaxis and

atherosclerosis treatment, stomach ulcer, trophic

ulcer, gynecological disorders [4].

The oil of seeds – for nonspecific ulcerative colitis

treatment, dermatosis; outwardly – by trophic ulcer

of shank, bedsores, chaps of mammilla, grazes [5].

References

1. I.N. Kushchinskaya, L.O. Shnaidman, Med. Prom. SSSR (4),

38 (1964) [in Russian]

2. T.S. Shirko, A.F. Radyuk, Rastit. Resursy 272, 59 (1991) [in

Russian]

3. Lekarstvennye rasteniya dikorastushchie, pod red. A.F.

Gammerman, I.D. Yurkevicha, 4 izd., Minsk (1968), 390

s [in Russian]

4. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

5. M.D. Mashkovskii, Lekarstvennye Sredstva, v 2 ch., 7 izd.

(Moscow, 1972), ch. 1, 430 s., ch. 2, 647 s., 10 izd., M., 1985,

ch. 1, 624 s., ch. 2, 575 s

Rosa mandenovae Gadzhieva

Family: Rosaceae Juss.

Fruit

Carotene

Vitamin E

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa maracandica Bunge

Family: Rosaceae Juss.

Pulp of Fruit

Carotene

Content, % on dry wt: 0.01

References

1. Т.F. Kochkareva, Е.P. Trofimova, Izv. АN Tadzh. SSR, otd-

nie biol. nauk (1), 17 (1967) [in Russian]

Rosa marschalliana Sosn.

Family: Rosaceae Juss.

Fruit

Carotene

References

1. B.D. Alekseev, Rastit. Resursy 7, vyp. 4, 557 (1981) [in

Russian]

Rosa maximowicziana Regel

Family: Rosaceae Juss.

Fruit

Mass of 1,000, g: 220

Carotenoids

Content, mg% on abs. dry wt: 7.6

References

1. G.P. Shnyakina, E.P. Malygina, Rastit. Resursy 11, vyp. 3,

390 (1975) [in Russian]

Rosa micramtha Smith (R. floribundaStev. ex Bess.)

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 66: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 766 Rosa mollis Smith (R. ruprechtii Boiss.)

Rosa mollis Smith (R. ruprechtii Boiss.)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: Carotene, lucopene [1]Vitamin Е [2]

Seed

Oil, % on dry wt: 10.94 [3]

References

1. F.C. Jacoby, F. Wokes, Biochem. J. 38(3), 279 (1944)

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

3. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Rosa nanothamnus Bouleng.

Family: Rosaceae Juss.

Pulp of Fruit

Carotene

Content, % on dry wt: 0.08

References

1. Т.F. Kochkareva, Е.P. Trofimova, Izv. АN Tadzh. SSR, otd-

nie biol. nauk (1), 17 (1967) [in Russian]

Rosa nisami Sosn.

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 18 [1]

Pulp of Fruit

Lipids, % on dry wt: 5.9 [2]

Triterpenoic acids

Component: ursolic acid [2]

Seed

Oil (ether), % on dry wt: 5.8 [2]

d204 : 0.9122 [2]

n20D : 1.4786 [2]

Acid value, mg KOH: 5.45 [2]

Ether value, mg KOH: 191.65 [2]

Saponification value, mg KOH: 187.1 [2]

b-Carotene

Content (colorimetry), mg% on dry wt: 7.90; %:

10.17 [3]

Vitamin E

Content, mg% on oil: 132.0 [3]

FFA

Content, %: 2.7 [2]

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

2. V.B. Kuliev, N.V. Gusarova, Chem. Nat. Comp. 20(4), 513

(1984)

3. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Rosa oxyodon Boiss.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg/100 g: 46–48 [1]

Seed

Oil (ether), % on dry wt: 9.8 [2]

b-Carotene

Content (colorimetry), mg% on dry wt: 15.20; %

9.82 [2]

Vitamin E

Content, mg% on oil: 204 [2]

References

1. B.D. Alekseev, Rastit. Resursy 17(4), 557 (1981) [in Russian]

2. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Page 67: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa rugosa Thunb. 767 Rosaceae Juss.

Rosa pisiformis (H. Christ.) Sosn.

Family: Rosaceae Juss.

Seed

Oil, % on dry wt: 7.60

FAs (GLC, capillary column, 5% phenyl methyl

silicone), %: 16:0 – 4.07; 17:0 – 0.46; 18:0 –

4.10; 18:1(9) – 40.89; 18:2 – 46.31; 20:0 – 0.47;

20:1(11) – 0.46

References

1. S. Ercisli, E. Orhan, A. Esitken, Chem. Nat. Comp.

(2006) (unpublished)

Rosa platyacantha Schrenk

Family: Rosaceae Juss.

Pulp of Fruit

Carotene

Content, mg%: 11.0

Seed

Oil (ether), % on dry wt: 4.5

References

1. T.N. Bikbulatova, K.D. Beisekova, Chem. Nat. Comp. 15(3),

372 (1979)

Rosa pulverulentha Bieb. (R. glutinosaauct.)

Family: Rosaceae Juss.

Fruit

Essential oilCarotene [1]

Seed

Oil, % on dry wt: 8.13 [2]

FAs (GLC, capillary column, 5% phenyl methyl

silicone), %: 16:0 – 3.50; 17:0 – 0.75; 18:0 –

4.31; 18:2 – 54.03; 18:3 (a-linolenic) – 34.38 [2]

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

2. S. Ercisli, E. Orhan, A. Esitken, Chem. Nat. Comp.

(2006) (unpublished)

Rosa rubiginosa L. (R. eglanteria L.)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: b-, g-Carotene, lycopene,

rubixanthin, zeaxanthin, cis-rubixanthin, cis-

lycopene, anteraxanthin, xanthophyll,

violaxanthin, taraxanthin [1–4]

Leaf

Essential oilContent, %: 0.55 [5]

Seed

Oil, % on dry wt: 6.6 [6]

FAs: 14:0; 16:0; 18:0; 18:1; 18:2; 18:3 [6]

References

1. N. Arpin, S. Liaaen-Jensen, Phytochemistry 8(1), 185 (1969)

2. I.N. Kushchinskaya, L.O. Shnaidman, Med. prom. SSSR (4),

38 (1964) [in Russian]

3. F.C. Jacoby, F. Wokes, Biochem. J. 38 (3), 279 (1944)

4. G. Toth, J. Szabolcs, Acta Chim. Acad. Sci. Hung. 64(4), 393

(1970)

5. T. Krzaczek, J. Chybowski, Acta pol. Pharm. 30(3), 325

(1973)

6. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa rugosa Thunb.

Family: Rosaceae Juss.

Flower

Essential oilContent (Кlevend.), % on abs. dry wt: 0.11–0.23 [1]

Composition (GLC, 15% DEGS on Chromosorb

W), %: Linalool – 4.47–7.56; citronellyl

Page 68: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 768 Rosa rugosa Thunb.

formate – 1.34–1.73; geranyl formiate – 8.88–

18.73; citronellol – tr – 3.04; geranyl acetate –

4.28–7.74; geraniol – 5.76–16.12; phenylethanol

– 31.44–33.31 [1]

(GC/MS, Superox FA): Terpenoids: trans-b-ocimene – x; 6-methyl-5-hepten-2-one, geranial,

3-methyl-1-butanol – xx; citronellol – xxx; nerol

– xxx; geraniol – xxx; neryl acetate; aliphatics:

pentadecane – x; 2-tridecanone – x; 1-pentanol –

xx; 1-hexanol – x; 3-hexenol – x; acetic acid,

hexyl acetate – x; 3-hexenyl acetate – xx; aro-

matics: benzyl alcohol – xxx; b-phenylethanol –xxx; methyleugenol – xxx; eugenol – xx; b-phenylethyl acetate (x – �4%; xx – >4%;

�20%; xxx – >20%) [2]

Fruit

Essential oil

Components: a-Pinene, b-myrcene, azulene, geraniol,

(–)-linalool, nerolidol, n-heptyl alcohol, benzyl

alcohol, 2-phenylethanol, eugenol, isoeugenol, cit-

ral, n-undecylaldehyde, benzaldehyde, benzoic

acid, phenylacetic acid, linalyl acetate, mentone [3]

Mass of 1,000, g: 820–880 [4]

Carotenoids

Content, mg% on abs. dry wt: 9.0–10.4 [5]

Components (TLC, UV): a-, b-, g-Carotene, lyco-pene, rubixanthin, phytoxanthin [6]

Kernel

Oil

d15: 0.925–0.929 [7]

n20: 1.474–1.482 [7]

Hehner value, %: 94.5–95.0 [7]

Hydroxyl value, mg KOH: 4.5–4.7 [7]

Iodine value, % J2: 155–187 [7]

Polenske value, mL KOH: 0.3–0.4 [7]

Reichert-Meissl value, mL KOH: 0.3–1.5 [7]

Saponification value, mg KOH: 186–192 [7]

Saturated acids (Bertram), %: 5.0–5.5 [7]

Unsaponifiables, %: 1.0–2.6 [7]

Unsaturated acids, %: 94.5–95.0 [7]

FAs (GLC), %: 16:0 – 3.5–4.0; 18:0 – 1.5–24.8;

18:1 – 8–26; 18:2 – 45.2–55.0; 18:3 – 14–34 [7]

Petal

Essential oilContent, %: 0.25–0.38 [8]

Components: Phenylethyl alcohol (86.3%), linal-

ool, citronellol, geraniol, nerol, benzyl alcohol,

nonyl alcohol, heptyl alcohol, phenylethyl ace-

tate, benzyl formate, nonyl aldehyde, benzalde-

hyde, nonalactone, eugenol, phenylacetic acid,

benzoic acid [8]

Pollen

Essential oil

Composition (GC/MS, Superox FA): Terpenoids:

6-methyl-5-hepten-2-one – xx; geranyl acetone

– xxx; neral – xx; geranial – xxx; nerol, geraniol

– xx; citronellyl acetate – xx; neryl acetate – xx;

geranyl acetate – xxx; aliphatics: pentadecane –xx; 2-undecanone – xxx; 2-tridecanone – xxx; 2-

pentadecanone – xx; tetradecanal – xxx;

hexadecanal – x; acetic acid, tetradecyl acetate

– xxx; hexadecyl acetate; aromatics: b-phenylethanol – xxx; methyleugenol – xxx;

eugenol – xx; b-phenylethyl acetate – xx (x –

�4%; xx – >4%; �20%; xxx – >20%) [2]

Pollenkitt

Essential oilComposition (GC/MS, Superox FA): terpenoids:

geranyl acetone – x; geranial – x; citronellyl

acetate – x; geranyl acetate – x; aliphatics:pentadecane – x; 2-tridecanone – xx;

tetradecanol – xx; tetradecyl acetate – xxx;

hexadecyl acetate – xxx; aromatics:methyleugenol – x; b-phenylethyl acetate – x (x

– �4%; xx – >4%; �20%, xxx – >20%) [2]

Pulp of Fruit

Carotenoids

Content, mg/100 g: 2.0–19.4 [9]

Unsaponifiables

Content, mg/100 g: 29 [10]

Choline

Content, mg%: 65.0 [10]

Seed

Oil, % on dry wt: 13.5–14.3 [4]

n20D :1.4705 [4]

Acid value, mg KOH: 2.6 [4]

Iodine value, % J2: 164.3 [4]

Saponification value, mg KOH: 181.8 [4]

Phosphatides, %: 3.8 [4]

Unsaponifiables, %: 1.4 [4]

Page 69: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa sp. 769 Rosaceae Juss.

FAs (PC), %: 16:0 – 17.6; 18:1 – 5.2; 18:2 – 44.5;

18:3 – 32.0 [4]

Carotenoids

Components: a-, b-Carotene, cryptoxanthin,

taraxanthin, rubixanthin, lycopene, lutein,

phytofluene, poly-cis-lycopenes А, В, С [3]

Use: Essential oil of petals – in perfumery and soap

industry [8].

References

1. S.G. Sakov, G.G. Senchenko, I.S. Kozhina, Rastit. Resursy

18(3), 388 (1982) [in Russian]

2. H.E.M. Dobson, J. Bergstrom, G. Bergstrom, I. Groth, Phy-

tochemistry 26(12), 3171 (1987)

3. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–

101 [in Russian]

4. A. Rutkowski, J. Batura, A. Kopczynska, Oleagineux 20(6),

383 (1965)

5. G.P. Shnyakina, E.P. Malygina, Rastit. Resursy 11, vyp. 3,

390 (1975) [in Russian]

6. I.N. Kushchinskaya, L.O. Shnaidman, Med. prom. SSSR (4),

38 (1964) [in Russian]

7. Rukovodstvo po metodam issledovaniya, tekhnokhimi-cheskomu kontrolyu i uchetu proizvodstva v maslozhirovoipromyshlennosti, t. 5, L. (1969) [in Russian]

8. N.I. Suprunov, P.G. Gorovoi, Y.A. Pankov, Efirno-maslichnye rasteniya Dal’nego Vostoka (Izd. “Nauka”,

Novosibirsk, 1972), 187 s [in Russian]

9. T.S. Shirko, A.F. Radyuk, Rastit. Resursy 27(2), 59

(1991) [in Russian]

10. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

Rosa ruprechtii Boiss.

Family: Rosaceae Juss.

Seed

Oil (ether)

b-CaroteneContent (colorimetry), mg% on dry wt: 14.20; %:

10.94

Vitamin E

Content, mg% on oil: 197.0

References

1. V.A. Bunakov, Biol. nauki (2), 144 (1960) [in Russian]

Rosa sachokiana P. Jarosch.

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae(izd. “Nauka”, Leningrad, 1987, 19–101 (in Russian)

Rosa schrenkiana Crep.

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursySSSR.Tsvetkovye rasteniya, ikh khimicheskiisostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd.“Nauka”, Leningrad, 1987), pp. 19–101 [in Russian]

Rosa sosnovskyana Tamamsch.

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 28

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rosa sp.

Family: Rosaceae Juss.

Flower

Essential oil

Page 70: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

30

Rosaceae Juss. 770 Rosa sp.

d4 : 0.870–0.871 [1]

n30D : 1.4640–1.4658 [1]

Composition, %: Stearoptene – 5–23.0;

phenylethanol – 40–50; citronellol – 27.5–35;

geraniol – 5; eugenol – 2–3; aldehydes – tr [2]

Composition (GLC), %: Free monoterpene alcohols

– 66.5–67.5 (geraniol, linalool, nerol);

phenylethanol – 1.7–3.9; ethanol,

dinitrobenzoate of nonyl alcohol, methanol; car-

bonyl compounds (citral, citronellal) – 1.6–2.0;

aldehydes (nonyl aldehyde) – 0.25; benzalde-

hyde – 1.5; acetaldehyde, propionaldehyde,

valeraldehyde, salicylaldehyde, phenylace-

taldehyde, aromatic compounds (eugenol,

eugenolmethylether), hydrocarbons

(heptadecane, nonadecane, eicosane,

heneicosane, eicosen-10 [1, 3]

(GLC, Carbowax 1500), %: Ethanol – 0.5–1.3;

nonyl aldehyde – 0.2–0.3; citronellal – 0.3–0.4;

linalool – 1.3–1.5; citronellylacetate – 2.1–2.5;

citral – 1.4–1.7; geranylacetate – 1.1–1.2; citro-

nellol – 40.5–44.5; nerol – 1.8–6.3; geraniol –

18.2–19.8; phenylethyl alcohol – 1.7–3.9; euge-

nol – 0.1–0.4; eugenolmethylether – 0.5–0.7;

pentadecane – 0.4–0.7; hexadecane – 0.4–0.6;

heptadecane – 1.4–1.6; octadecane – 0.6–1.5;

nonadecane – 3.7–9.3; eicosane – 1.5–2.8;

heneicosane – 3.0–3.2; docosane – 0.8–1.7;

tricosane – 0.5–0.8; tetracosane – 0.2–0.3 [1]

Wax

Acid value, mg KOH: 1.8–5.7 [4]

Ether value, mg KOH: 25–80 [4]

Composition, %: Hydrocarbons – 60; oxygen

containing compounds – 40 (myricyl

alcohol, ceryl alcohol, complex ethers of

capronic, caprylic, phenylacetic, ceratic, stearic

acids with terpenoic, isoceryl and myricyl

alcohols [4]

Fruit

Moisture, %: 79.7 [5]

Tocopherols

Composition (HPLC), mg/100 g on fresh wt: a-Tocopherol – 4.14; b-tocopherol – 0.14; g-tocopherol – 0.10; d-tocopherol – tr [5]

CO2-extract

Content, % on dry wt: 4.0 [6]

n20D : 1.4775 [6]

Acid value, mg KOH: 24.5 [6]

Ether value, mg KOH: 157.7 [6]

Lipids

Content, % on extract: 65 [6]

FAs (GLC), %: 16:0 – 6.7; 18:0 – 7.2; 18:1 – 40.4;

18:2 – 18.8; 18:3 – 26.9 [6]

Carotenoids

Content, mg%: 78.8 [6]

Component: Carotene only [6]

Wax, %: 2.0 [6]

Vitamin E, mg%: 1523 [6]

Vitamin F, %: 33.8 [6]

Chladone-extract

Content, % on dry wt: 6.2 [6]

n20D : 1.4780 [6]

Acid value, mg KOH: 7.4 [6]

Ether value, mg KOH: 178.5 [6]

Lipids

Content, % on extract: 67 [6]

Carotenoids

Content, mg%: 535 [6]

Composition, mg%: Carotene – 496; lycopene –

5.75; oxygen containing carotenoids – 30 [6]

Wax, %: 2.0 [6]

Seed

Oil (petrol ether)

TAG (6 fractions)

FAs of fr. I (GLC, EGS), %: 16:0 + 18:0 – 2.0; 18:1

– 1.0; 18:2 – 3.0; 18:3 – 94.0 [7]

FAs of fr. II: 18:1 – 2.0; 18:2 – 31.0; 18:3 – 67.0 [7]

FAs of fr. III: 16:0 + 18:0 – 11.0; 18:1 – 18.0; 18:2 –

8.0; 18:3 – 63.0 [7]

FAs of fr. IV: 16:0 + 18:0 – 1.0; 18:1 – 2.0; 18:2 –

61.0; 18:3 – 36.0 [7]

FAs of fr. V: 16:0 + 18:0 – 9.0; 18:1 – 20.0; 18:2 –

37.0; 18:3 – 34.0 [7]

FAs of fr. VI: 16:0 + 18:0 – 9.0; 18:1 – 18.0; 18:2 –

68.0; 18:3 –5.0 [7]

Activity: Oil of fruits has bactericidal action (goldish

staphylococcus, hemolytic streptococcus, typhus,

paratyphoid, dysentery bacillus, colon bacillus and

some anaerobic bacteria) [8].

Use: The oil is used instead of beeswax in cosmetol-

ogy [4].

Page 71: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosa villosa L. (R. pomifera Herrm.) 771 Rosaceae Juss.

References

1. S. Juvonen, Planta Med. 12(4), 488 (1964)

2. Efiromaslichnye kul’tury, pod red. А.А. Khotina, G.Т.Shulgina (Sel’khozizdat, Moscow, 1963), p. 332 [in Russian]

3. К.А. Timanovich, Maslo-zhirovaya promyshlennost’ (1), 32(1968) [in Russian]

4. N.F. Novotel’nova, Z.I. Fedulova, B.M. Berkengeim, S.D.

Kustova, Maslo-zhirovaya promyshlennost’ (5), 30

(1966) [in Russian]

5. V. Piironen, E.-L. Syv€aoja, P. Varo, K. Salminen, P.

Koivistoinen, J. Agric. Food Chem. 34(4), 742 (1986)

6. E.A. Shaftan, N.S. Mikhailova, N.F. Dyuban’kova, N.D.

Gol’berg, L.N. Fefelova, Rastit. Resursy 14(2), 208

(1978) [in Russian]

7. F.D. Gunstone, F.B. Padley, J. Am. Oil Chem. Soc. 42(11),

957 (1965)

8. A.I. Shapiro, O.K. Filippova, Zh. Mikrobiol., Epidemiol.,

Immunobiol. (10), 26 (1947) [in Russian]

Rosa spinosissima L.

Family: Rosaceae Juss.

Fruit

Carotene

Content, mg/100 g: 35.5–36.8 [1]

Lycopene [2]

Pulp of Fruit

Oil, % on dry wt: 11.6 [3]

Seed

Oil (ether), % on dry wt: 9.1 [3]

Acid value, mg KOH: 9.9 [3]

Saponification value, mg KOH: 97.1 [3]

Ether value, mg KOH: 87.2 [3]

References

1. B.D. Alekseev, Rastit. Resursy 17(4), 557 (1981) [in Russian]

2. F.C. Jacoby, F. Wokes, Biochem. J. 38(3), 279 (1944)

3. T.I. Plekhanova, V.А. Bandyukova, F.K. Bairamkulova,

Chem. Nat. Comp. 14(3), 334 (1978)

Rosa tomentosa Smith.

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 18

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rosa turkestanica Regel

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rosa villosa L. (R. pomifera Herrm.)

Family: Rosaceae Juss.

Fruit

Carotenoids

Components: (15Z)-Phytoene, (15Z)-phytofluene,

all-(Е)-phytofluene, x-carotene, mono-(Z)- x-carotene, (6R)-E,C-carotene, mono-(Z)- E,C-

carotene, b,C-carotene, mono-(Z)-b,C-caro-

tene, neurosporene, mono-(Z)-neurosporene,

lycopene, (Z)-lycopenes, b,b-carotene,mono-(Z)-b,b-carotene, b-cryptoxanthin, (Z)-b-cryptoxanthin, rubixanthin, (50Z)-rubixanthin,(90Z)-rubixanthin, (130Z)-rubixanthin, (13Z)-rubixanthin, (50Z),130Z)- or (50Z,13Z)-rubixanthin, lutein, zeaxanthin, (13Z)-zeaxan-

thin, mono-(Z)-zeaxanthin, (8R)-mutatoxanthin,

(8S)-mutatoxanthin, neoxanthin, (80R)-neochrom, (80S)-neochrom, tetrahydroxy-

carotenoid, tetrahydroxyepoxycarotenoid [1]

Seed

Oil, % on dry wt: 7.79 [2]

FAs (GLC, capillary column, 5% phenyl methyl

silicone), %: 16:0 – 3.14; 17:0 – 0.70; 18:0 –

5.18; 18:2 – 49.93; 18:3 (a-linolenic) – 32.94 [2]

Page 72: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 772 Rosa virgo

References

1. E. M€arki-Fischer, U. Marti, R. Buchecker, C.H. Eugster,

Helv. Chim. Acta 66(2), 494 (1983)

2. S. Ercisli, E. Orhan, A. Esitken, Chem. Nat. Comp.

(2006) (unpublished)

Rosa virgo

Family: Rosaceae Juss.

Flower

Absolute

Content, %: 49.1 [1]

Wax

Content, %: 34.5 [1]

Hydrocarbons

Composition (Ag+/CC), %: Paraffins – 44.1; olefins

– 7.8 [1]

Branched-chain hydrocarbons

Content, %: 0.4 [1]

Paraffins

Composition (GLC, 2% SE-30), %: C19 – 1.0; C20 –

0.5; C21 – 10.5; C22 – 0.7; C23 – 11.2; C24 – 1.2;

C25 – 12.2; C26 – 1.5; C27 – 33.3; C28 – 2.8; C29 –

15.0; C30 – 1.1; C31 – 6.0; C32 – 0.7; C33 – 2.2 [1]

Olefins

Composition (GLC, 2% SE-30), %: C19 – 5.1; C20 –

0.6; C21 – 3.7; C22 – 0.6; C23 – 6.8; C24 – 1.1; C25

– 10.6; C26 – 2.1; C27 – 26.6; C28 – 3.7; C29 –

22.3; C30 – 1.1; C31 – 9.6; C32 – 1.1; C33 – 4.8 [1]

Primary alcohols

Free alcohols

Composition (GLC), %: C16 – tr; C18 – tr; C20 – 4.2;

C21 – 3.5; C22 – 17.5; C23 – 5.4; C24 – 12.1; C25 –

2.9; C26 – 8.6; C27 – 3.1; C28 – 20.3; C29 + b-amyrin – 4.9; C30 – 2.7; a-amyrin – 14.1 [2]

Ester-bound alcohols

Composition (GLC), %: C16 – 1.4; C17 – 0.3; C18 –

11.0; C19 – 0.7; C20 – 20.2; C21 – 2.9; C22 – 17.8;

C23 – 1.5; C24:1 – 2.5; C24 – 11.7; C25 – 0.9; C26 –

6.8; C27 – 0.7; C28:1 – 0.8; C28 – 7.0; C29+b-amyrin – 6.4; C30 – 2.5; a-amyrin – 5.0 [2]

Secondary alcohols

Composition (GLC), %: C25 – 1.7 (4-ol – 32; 5-ol –

39; 6-ol – 29); C26 – 1.6 (4-ol – 29; 5-ol – 60; 6-ol

– 11); C27 – 37.7 (4-ol – 26; 5-ol – 50; 6-ol – 24);

C28 – 4.3 (4-ol – 26; 5-ol – 52; 6-ol – 22); C29 – 28.6

(4-ol – 23; 5-ol – 54; 6-ol – 23); C30 – 0.9 (4-ol –

32; 5-ol – 50; 6-ol – 18); C31 – 16.0 (4-ol – 36; 5-ol

– 50; 6-ol – 14); C32 – 1.4 (4-ol – 37; 5-ol – 48; 6-ol

– 15); C33 – 7.7 (4-ol – 31; 5-ol – 50; 6-ol – 20) [2]

Sterols

Composition (GLC), %: b-Sitosterol – 91; choles-

terol, campesterol [2]

Aldehydes

Content, %: 3.03 [3]

Composition (GLC, 1.5%SE-30 onChromosorbW),

%: 14 – tr; 15 – tr; 16 – 3.4; 17 – 0.2; 18 – 6.3; 19 –

0.6; 20 – 3.5; 21 – 4.1; 22 – 21.0; 23 – 8.3; 24 –

28.7; 25 – 4.0; 26 – 9.9; 27 – 2.2; 28 – 8.0 [3]

References

1. B. Stoianova-Ivanova, K. Mladenova, Compt. Rend. Acad.

Bulgar Sci. (Dokl. Bolgar. AN) 27(9), 1239 (1974)

2. K. Mladenova, B. Stoianova-Ivanova, Phytochemistry 16(2),

269 (1977)

3. K. Mladenova, B. Stoianova-Ivanova, Compt. Rend. Acad.

Bulgar Sci. (Dokl. Bolgar. AN) 28(3), 335 (1975)

Rosa webbiana Wall. ex Royle

Family: Rosaceae Juss.

Fruit

Carotene

Seed

Oil, % on dry wt: 4

FAs: 16:0; 18:1; 18:2; 18:3

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rosa woodsii L.

Family: Rosaceae Juss.

Aerial Part

Dry matter, %: 94.25

Page 73: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rubus arcticus L. 773 Rosaceae Juss.

Lipids, %: 3.10

Carotene

Content, mg/kg: 34.35

References

1. A. Johnston, L.M. Bezeau, Can. J. Plant Sci. 42(1), 105 (1962)

Rosa zakatalensis Gadzh.

Family: Rosaceae Juss.

Fruit

Carotene

Content (colorimetry), mg% on abs. dry wt: 22

References

1. G.G. Gadzhieva, Izv. AN Azer. SSR, Biol. nauki (3), 23

(1978) [in Russian]

Rubus anatolicus (Focke) Focke exHausskn. (R. turcomanicus Freyn., R.sanguineus auct.)

Family: Rosaceae Juss.

Root

Essential oil

Content, % on dry wt: 0.44

References

1. R.K. Aliev, R.A. Abdullaev, A.Kh. Rakhimova, Izv. AN

Azer. SSR, ser. biol. i med. nauk (8), 117 (1961) [in Russian]

Rubus arcticus L.

Family: Rosaceae Juss.

Fruit

Essential oil

Components: Hydrocarbons: n-Pentane, chloro-

form; organic acids: acetic acid, n-butanoicacid, propionic acid, 2-methylpropionic acid, 3-

methylbutanoic acid, 3-methyl-2-butenoic acid,

3-methyl-3-butenoic acid, n-hexanoic acid;

ethers: diethyl ether, ethylacetate, 2-methyl-2-

butenylacetate, 3-methyl-2-butenylacetate, cis-3-hexenylacetate, 2-phenylethylacetate, ethyl

nicotiniate, dimethyl phthalate, diethyl phthal-

ate, ethy lformate, methyl ether of pyruvic acid,

methyleugenol, ethylbenzoate, diethyl ether of

succinic acid; lactones: g-lactone of butyric

acid, E-lactone of caproic acid; aldehydes andketones: acetaldehyde, tiglic aldehyde, formal-

dehyde, n-butanal, 2-butenal, propanal,

propenal, n-pentanal, pentenal, hexenal,

nonanal, benzaldehyde, methylbutanal, 2-

methylpropanal, furfurol, acetone, 2-heptanone,

2-butanone, 6-methyl-5-hepten-2-one, b-dihydroionone, b-tetrahydroionone, diacetyl,

acetoin, acetoin acetate; alcohols: methanol,

ethanol, n-pentanol, 1-propanol, diacetonic alco-hol (2-methyl-2-hydroxy-4-pentanone), 1-buta-

nol, 2-heptanol, 1-hexanol, 3-methyl-1-butanol,

trans-3-penten-1-ol, cis-3-hexen-1-ol, trans-3-hexen-1-ol, 3-methyl-2-buten-1-ol, 2-

phenylethanol, benzyl alcohol, phenol, a-terpin-eol, nerol, geraniol, guaiacol, eugenol, linalool,

2-vinyl-2,6,6-trimethyl-5-

hydroxytetrahydropyran (oxide of linalool), (+)-

(2R,5S)-cis-2-vinyl-2-methyl-5-(10-hydroxy-10-methylethyl)-tetrahydrofuran (cis-oxide of lin-

alool), (–)-(2R,5S)-trans-2-vinyl-2-methyl-5-

(10-hydroxy-10-methylethyl)-tetrahydrofuran

(trans-oxide of linalool); heterocyclic compo-

nents: mezifuran (2,5-dimethyl-4-metoxy-2,3-

dihydro-3-furanone), hydroxymezifuran [1–4]

References

1. H. Kallio, J. Food. Sci. 41(3), 556 (1976)

2. H. Kallio, J. Food Sci. 41(3), 563 (1976)

3. T. Pyysalo, M. Suihko, E. Honkanen, Lebensmitt.-Wiss.

+ Technol. 10(1), 36 (1977); Chem. Abstr. 87, N 20798 (1977)

4. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 74: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 774 Rubus buschii Grossh. ex Sinjkova

Rubus buschii Grossh. ex Sinjkova

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % on fresh wt: 0.09 [1]

Leaf

Carotene [2]

Vitamin Е [2]

References

1. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rubus caesius L. (R. turkestanicus (Regel)Pavl.)

Family: Rosaceae Juss.

Fruit

Lipids

Content, % on fresh wt: 1.26–1.32 [1]

b-Carotene [2]Vitamin E [2]

Pulp of Fruit

Oil, % on dry wt: 13.5 [1]

FAs (GLC), %: 15:0 – 0.5; 16:0 – 7.61; 18:1 – 20.3;

18:2 – 65.6; 18:3 – 3.23 [1]

References

1. E.N. Novruzov, L.A. Shamsi-zade, Rastit. Resursy 19, vyp. 3,

366 (1983) [in Russian]

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Rubus caucasicus Focke

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % on fresh wt: 0.06

References

1. E.N. Novruzov, Rastit. Resursy, 24(1), 48 (1988) [in Russian]

Rubus chamaemorus L.

Family: Rosaceae Juss.

Fruit

Essential oilComponents: Hydrocarbons: Heptane, toluene, о-,

m- and p-xylene, styrene, naphthalene; alcohols:

methanol, ethanol, 2-butanol, 2-methyl-1-

propanol, 2-methyl-1-butanol, 1-pentanol, 2-

pentanol, 2-heptanol, 3-penten-1-ol, 3-methyl-2-

buten-1-ol, 1-hexanol, trans-2-hexen-1-ol, trans-3-hexen-1-ol, cis-3-hexen-1-ol, 1-octen-3-ol,

trans-2-octen-1-ol; ethers: ethylacetate,

butylformate, methylhexanoate, ethylhexanoate;

aldehydes and ketones: acetaldehyde, hexanal,

acetone, diacetyl, acetoin, 2-pentanone, 2-

heptanone, 6-methyl-5-hepten-2-one; aromaticcomponents: benzyl alcohol, 1-phenylethanol, 2-

phenylethanol, 3-phenylpropanol, cis- and trans-cinnamic alcohol, phenol, 4-ethylphenol, о-methoxyphenol, 4-vinylphenol, 2-methoxy-5-

vinylphenol, 4-allylphenol, eugenol, 2,6-di-

tret-butyl-4-methylphenol, 4-methoxyace-

tophenon, methylbenzoate, ethylbenzoate,

benzylbenzoate, benzylacetate, 2-phenylethyl-

formate, methylcinnamate, dimethylphthalate,

dibutylphthalate, benzaldehyde, acetophenone, 4-

methoxybenzaldehyde, cinnamic aldehyde, vanil-

lin, 4-allylphenol, methylvanillate,

acethovanillone, butylhydroxyanisole, methyl-3-

hydroxybenzoate, 3-hydroxyacetophenone,

methyl-4-hydroxybenzoate, 4-hydroxyace-

tophenone, 2-phenylphenol; terpenes: a-fenchene,

Page 75: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rubus idaeus L. (R. sericeus Gilib.) 775 Rosaceae Juss.

geraniol, linalool, linalylacetate, a-terpineol,isopinocamphon, cis- and trans-oxide of linalool;heterocyclic compounds: furfurol, 5-

hydroxymethylfurfurol, 5-methylfurfurol, g-caprolactone, coumarin, 3,5-dihydro-2-methyl-

4Н-pyran-4-one; organic acids: acetic, propionic,

2-methylpropionic, butanoic, 2-methylbutanoic,

pentanoic, hexanoic, octanoic, 2-methylictanoic,

benzoic, cis-cinnamic, trans-cinnamic, p-

hydroxycinnamic (p-coumaric), 3-hydroxy-4-

methoxycinnamic, 3-phenylpropionic, nonanoic,

decanoic, dodecanoic, tetradecanoic,

hexadecanoic acids [1, 2]

Carotenoids

Component: Rubixanthin [3]

Pulp of Fruit

Unsaponifiables

Content, mg/100 g: 52.0 [4]

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

2. Pyysalo T., Suihko M., Honkanen E., Lebemsm.-Wiss.

Technol. 10(1), 369 (1977); Chem. Abstr. 87, N 207798r

(1977)

3. W. Karrer, Konstitution und Vorkommen der organischenPflanzenstoffe (Basel, Stuttgart, 1958), 1207 s

4. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

Rubus chingii Hu

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Component (UV, MS, 1H, 13C NMR): 2,19a-dihydroxy-3-oxo-urs-1,12-dien-28-oic acid

(fupenzic acid)

References

1. M. Hattori, K.-P. Kuo, Y.-Z. Shu, S. Tezuka, T. Kikuchi, T.

Namba, Phytochemistry 27(12), 3975 (1988)

Rubus crataegifolius Bunge

Family: Rosaceae Juss.

Root

Triterpenoic acid

Component: Ursolic acid

Sterols

Components: b-Sitosterol, stigmasterol,

campesterol, cholestanol

References

1. C.K. Moon, C.K. Yoo, Seoul Taehakkyo Saongyak Yonguso

Opjukjip 15(86) (1976); Chem. Abstr. 88, N 47503 (1978)

Rubus fruticosus L.

Family: Rosaceae Juss.

Fruit

Triterpenoic acids

Component: 3b, 17a-dihydroxy-D12–28-oic acid

(rubitic acid) [1]

a-Tocopherol

Content, ppm on dry wt: 210; on fresh wt: – 35 [2]

References

1. M.C. Das, S.B. Mahato, Phytochemistry 22(5), 1071 (1983)

2. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

Rubus idaeus L. (R. sericeus Gilib.)

Family: Rosaceae Juss.

Fruit

Essential oil[a]: +2.8� [1]d: 0.8830 [1]

Ether value, mg KOH: 193 [1]

Ether value after acetylation, mg KOH: 215 [1]

Components: Hydrocarbons: a-Pinene, a-phellandrene, limonene, a-terpinolene,

Page 76: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 776 Rubus idaeus L. (R. sericeus Gilib.)

sabinene, trans-caryophyllene, humulene, a-elemene; alcohols: ethanol, 2-methylpropanol,

2-methylbutan-1-ol, 1-pentanol, 3-methyl-2-

buten-1-ol, 1-hexanol, trans-3-hexen-1-ol, cis-

3-hexen-1-ol, trans-2-hexen-1-ol, linalool, linal-ool oxide, terpinen-4-ol, a-terpineol, cis-sabinol,nerol, geraniol, mentanol; ethers: ethylacetate,3-methyl-2-buten-1-ylacetate, 3-methyl-2-

buten-1-ylformiate, cis-3-hexen-1-ylacetate,

cis-3-hexen-1-ylformiate, ethyl-5-hydroxyox-

yoctanoate, ethyl-5-hydroxydecanoate; alde-

hydes and ketones: hexanal, trans-2-hexenal, 6-

methyl-5-hepten-2-one, acetoin, piperitone, a-and b-ionone; aromatic compounds: xylol, p-

cymene, benzaldehyde, benzylacetate, benzylic

alcohol, 2-phenylethanol, 2-methoxy-4-

vinylphenol, 2-methoxy-5-vinylphenol, 3,4-

dimethoxybenzaldehyde, eugenol, 4-

vinylphenol, trans-cinnamic alcohol, benzoic

acid, vanillin, gingerone, 4-(4-hydroxyphenyl)

butan-2-one; heterocyclic compounds: 2,5-

dimethyl-4-methoxy-3(2Н)-furanone, 5-methyl-

4-hydroxy-3(2Н)-furanone, 2,5-dimethyl-4-

hydroxy-3(2Н)-furanone, g- and d-hexalactones,g- and d-octalactones, d-decalactone, d-dodecalactone; organic acids: acetic, propionic,

butanoic, 2-methylbutanoic, 3-methyl-2-

butenoic, 3-methyl-3-butenoic, hexanoic,

octanoic, decanoic, tetradecanoic, hexadecanoic

[2]

Tocopherols

Components: a-, g- and d-tocopherols [2]a-Tocopherol

Content, ppm on fresh wt: 3.0 [3]

Carotenoids

Content, % on fresh wt: 0.05 [4]

Component: Carotene [2]Sterols

Component: Phytosterol (0.7%) [5]

Leaf

Carotene [6]

Vitamin Е [6]

Aliphatic hydrocarbons [2]

Pollen

Triterpenoic acids [2]

b-Carotene [2]

FAs: 4:0; 16:0; 16:1; 18:0; 18:2; 18:3; 20:0; 21:0;

22:0 [2]

TAG

FAs (GLC), %: 10:0 – tr; 12:0 – 2.22; 14:0 – 0.30;

14:1 – tr; 15:0 – 0.14; iso-16:0 – 0.59; 16:0 –

2.51; 16:1 – 0.31; 16:2 – 0.14; 17:0 – 0.15;

17:1 – tr; 17:2 – tr; 18:0 – 5.12; 18:1 – 3.16;

18:2 – 6.31; 18:3 – 52.19; 19:0 – tr; 20:0 – 0.17;

21:0 – 0.28 [7]

Pulp of Fruit

Sterols

Content, mg/100 g on fresh wt: 23 [8]

Unsaponifiables, mg/100 g: 40–72 [8]

Seed

Oil, % on dry wt: 21.3 [2]

Iodine value, mg KOH: 174.8 [2]

FAs: 4:0; 16:0; 16:1; 18:0; 18:2; 18:3; 20:0; 21:0;

22:0 [2]

TAG

Composition (HPLC), %: LeLeLe – 3.9; LeLeL –

10.6; LeLL + LeLeО – 25.3; LeLeP – 0.8; LLL +

LeLO – 21.1; LeLP + LeLe – 4.0; LLO + LeOO

– 14.0; LLP + ЛLeLS + LeOP –6.2; LOO – 5.3;

LLS+LOP + LeOS – 5.2; LPP + LePS – tr; OOO

– 2.1; LOS + OOP – 0.6; LPS + OPP – 0.4; OOS

– tr [9]

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1932)

[in Russian]

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

3. V.H. Booth, M.P. Bradford, Brit. J. Nutr. 17(4), 575 (1963)

4. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in

Russian]

5. Atlas lekarstvennykh rastenii SSSR (Мoscow, 1962), 704 s [in

Russian]

6. S. Ya. Zolotnitskaya, Lekarstvennye resursy floryArmenii: в 2 t. (Erevan, 1958), t. 1, 609 s., 1965, t. 2, 371 s

[in Russian]

7. V.A. Bandyukova, G.I. Deineko, D.K. Shapiro, Chem. Nat.

Comp. 18(2), 227 (1982)

8. L.I. Vigorov, Rastit. ResursyVIII(4), 557 (1972) [in Russian]

9. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Page 77: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Sanguisorba officinalis L. 777 Rosaceae Juss.

Rubus sanguineus Friv. (R. Sanctus auct.Plur. Non Schreb.)

Family: Rosaceae Juss.

Root

Essential oilContent, % on dry wt: 0.32; on abs. dry wt: 0.44

Lipids

Moisture, %: 14.66

Content of lipids, % on dry wt: 5.3; on abs. dry wt:

6.2

Vitamin E

Content, mg on dry wt: 160.0; on abs. dry wt: 192.3

References

1. R.K. Aliev, R.A. Abdullaev, A.Kh. Rakhimova, Izv. AN

Azer. SSR, ser. boil. i med. nauk (8), 117 (1961) [in Russian]

Rubus saxatilis L.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % on fresh wt: 0.08 [1]

Pulp of Fruit

Unsaponifiables

Content, mg/100 g: 70 [2]

References

1. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

2. L.I. Vigorov, Rastit. Resursy 8(4), 557 (1972) [in Russian]

Sanguisorba minor Scop.

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 8.9–13.7 [1]

Oil, % on dry wt: 17.7–20.3 [1, 2]

n40D : 1.4713 [2]

Iodine value, % J2: 167 [2]

Saponification value, mg KOH/g: 187 [2]

FAs

Triene, as 18:3, %: nonconjugated – 29 [2]

Diene, as 18:2, %: nonconjugated – 38 [2]

Monoene, as 18:1, %: 19 [2]

Saturated, %: 8.8 [2]

Composition (GLC, Silar 5 CP), %: 16:0 – 6.03;

16:1 – 0.13; 17:0 – 0.08; 17:1 – 0.05; 18:0 – 2.89;

18:1 – 13.16; 18:2 – 36.88; 18:3 – 38.20; 20:0 –

0.43; 20:1 – 0.64; 22:0 – 0.28; 22:1 – 0.10 [3]

16:1

Composition of isomers (Ag+-PТLC), %: n-7 –

62.6; n-9 – 37.4 [3]

18:1

Composition of isomers (Ag+-PТLC), %: n-5 – 0.4;

n-7 – 2.8; n-9 – 96.8 [3]

20:1

Composition of isomers (Ag+-PТLC), %: n-7–

65.6; n-9 – 14.1; n-11 – 20.3 [3]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

2. F.R. Earle, E.H. Melvin, L.H. Mason, C.H. van Etten, I.A.

Wolff, J. Am. Oil Chem. Soc. 36(7), 304 (1959)

3. A. Seher, U. Gundlach, Fette, Seifen, Anstrich. 84(9), 342

(1982)

Sanguisorba officinalis L.

Family: Rosaceae Juss.

Leaf

Triterpenoic acids

Components: Ursolic acid (0.6%), hydroxyursolic

acid [1]

Root

Essential oilContent, %: 1.5–1.8 [2, 3]

Sterols

Components: Sitosterol, stigmasterol [1]

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 78: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Rosaceae Juss. 778 Sibiraea altaiensis (Laxm.)

2. R. Hegnauer, Chemotaxonomie der Pflanzen, Bd. 1–6 (Basel;Stuttgart, 1969), Bd. 5, 506 s; 1966, Bd. 4, 551 s; 1973, Bd. 6,

882 s

3. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri ( izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

Sibiraea altaiensis (Laxm.) Schneid.(S. laevigata (L.) Maxim., Spiraealaevigata L., S. altaica Pall.,Spiraea altaiensis Laxm.; Sibiricalaevigata Maxim.)

Family: Rosaceae Juss.

Leaf

Essential oil [1]Triterpenoic acids

Component: Ursolic acid [2]

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931)

578 s [in Russian]

2. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

Sorbaria sorbifolia (L.) A. Br.(Spiraea sorbifolia L. S. pinnataMoench.; Basilima sorbifolia Raf.;Schizonotus sorbifolius Lindl.; Sorbariastellipila C.K. Schn., Sorbaria assurgenshort. et C. K. Schn.)

Family: Rosaceae Juss.

Root

Essential oil (fermentation)

Components: Methyl salicylate, salicylic aldehyde

References

1. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Sorbus americana Marsh. (Pyrusamericana)

Family: Rosaceae Juss.

Seed

Mass of 1,000, g: 3.8

Oil, % on dry wt: 23.9

References

1. F.R. Earle, Q. Jones, Econ. Bot. 15(4), 221 (1962)

Sorbus aucuparia L. (S. boissieri Schneid.)

Family: Rosaceae Juss.

Bark

Triterpenoids

Components: Ceryl alcohol, b-sitosterol, betulin,lupenol, 23-hydroxybetulin, 20, 30-dihydro-23-

hydroxybetulin, 23-hydroxyallobetulin [1]

Branch

Ursolic acid [2]

Flower

Triterpenoid

Components: a-Amyrin, ursolic acid [3, 4]

Sterols

Component: b-Sitosterol [3, 4]Aliphatic hydrocarbons: n-Octacosane, tricosanol [4]

Fruit

Essential oil

[a]: +40.8� [5]d14: 1.0680 [5]

Component: Lactone of oxyhydrosorbic acid [5]

Carotenoids

Content, mg% on fresh wt: 15.4–18.0; mg% on dry

wt: 27.1–53.9 [6–8]; mg% on abs. dry wt: 16.3

[9]; mg/g: 0.31–1.13 [10, 11]

Composition, %: b-Carotene –29.6, cryptoxanthin +b-carotene monoepoxide – 70 [6]; phytofluene –

0.9, a-carotene – 0.5–1.6, b-carotene – 29.3–

30.6, cis-cryptoxanthin – 32.3–36.3, trans-

cryptoxanthin – 17.8, 5,6:monoepoxy-a-carotene

Page 79: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Sorbus domestica L. (Pyrus sorbus Gaertn.) 779 Rosaceae Juss.

– 28.9, 5,6:monoepoxy-b-carotene – 0.8–2.4,

violaxanthin – 0.6, lutein – 1.9, zeaxanthin – 1.7,

mutatochrome – 6.9, aurochrome – 5.7 [10–12]

mg%: a-carotene – 6.2, neo-b-carotene – 3.3, b-carotene – 3.84, polycopene – 1.4, x-carotene –

1.6 [9]

Carotene

Content, mg% on fresh wt: 5.37–18.0 [12–14]; mg

% on dry wt: 13.5–30.6 [12]; 2.6–8.0 [15]

Triterpenoids

Content, %: 1.84 [16]

Triterpenoic acids

Content, % of triterpenoids: 28.0 [16]; % on dry

fruit: 1.58–1.91

Components: Ursolic acid, oleanolic acid [16, 17]

Tocopherols

Content, mg%: 4.41 [7]

PhL

Content, mg%: 70.4 [7]

Components: PhC, PhE [7]

Leaf

Ursolic acid [2]

Pulp of Fruit

Unsaponifiables, mg/100 g: 46 [18]

Seed

Oil

TAG

Composition (HPLC), %: LeLeLe – tr; LeLeL – tr;

LeLL + LeLeO – 2.4; LeLeP – 0.1; LLL +

LeLO – 37.3; LeLP + LeLe – 1.9; LLO +

LeOO – 24.0; LLP + LeLS + LeOP –13.0;

LOO – 9.8; LLS+LOP + LeOS – 7.8; LPP +

LePS – tr; OOO – 2.2; LOS + OOP – 1.1;

LPS + OPP – tr; OOS – 0.1 [19]

References

1. W. Lawrie, J. McLean, G.R. Taylor, J. Chem. Soc. 4303

(1960)

2. A.G. Shavva, L.G. Matyukhina, I.A. Saltykova, Chem. Nat.

Comp. 5(5), 372 (1969)

3. M. Krolikowska, J. Kamecki, Rocz. Chem. 39(12), 1937

(1965)

4. M. Krolikowska, J. Kamecki, Rocz. Chem. 47(7), 1375

(1973)

5. B.N. Rutovskii, Efirnye Masla (Мoskwa-Leningrad, 1932),

578 s [in Russian]

6. B.G. Savinov, L.D. Protsenko, Ukr. Khim. Zhurn. 20, vyp. 4,

399 (1954) [in Russian]

7. L.O. Shnaidman, I.N. Kushchinskaya, M.K.Mitel’man, A.Z.

Efimov, I.V. Klement’eva, Z.P. Alekseeva, Rastit. Resursy

7, vyp. 1, 68 (1971) [in Russian]

8. A.F. Gammerman, I.I. Grom,Dikorastushchie lekarstvennyerasteniya SSSR (Moscow, 1976), 110 s [in Russian]

9. S.A. Deren’ko, Chem. Nat. Comp. 14(4), 454 (1978)

10. L.R.G. Valadon, A.M. Sellens, R.S. Mummery, Ann. Bot.

39(162), 785 (1975)

11. L.R.G. Valadon, R.S. Mummery, Ann. Bot. 36(146), 471

(1972)

12. A. Shmuk, A. Zamyslov, Dokl. VASKhNIL (4–5), 7

(1945) [in Russian]

13. A.Ph. Gammerman, G.N. Kadaev, A.A. Yatsenko-

Khmelevskii, Lekarstvennye rasteniya (Vysshaya shkola,

Moscow, 1983), 399 s [in Russian]

14. D.K. Shapiro, S.N. Bichevaya, N.I. Mantsivodo, I.L.

Rabinovich, Z.I. Kachanovskaya, L.I. Gontaryuk, Rastit.

Resursy III(2), 188 (1967) [in Russian]

15. Dikorastushchie i introdutsiruemye poleznye rasteniyav Bashkirii vyp. 1 (AN SSSR, Bashkirskii filial, institute

biologii, Ufa, 1961) [in Russian]

16. S.A. Deren’ko, N.I. Suprunov, Khim. Prirod. Soedin. (1),

128 (1980) [in Russian]

17. S.A. Deren’ko, N.I. Suprunov, Chem. Nat. Comp. 15(3), 363

(1979)

18. L.I. Vigorov, Rastit. Resursy VIII(4), 557 (1972) [in

Russian]

19. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40(3), 293

(2004)

Sorbus caucasica Zinserl.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, % on dry wt: 3.30

References

1. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

Sorbus domestica L. (Pyrus sorbusGaertn.)

Family: Rosaceae Juss.

Fruit

Carotene

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Rosaceae Juss. 780 Sorbus intermedia (Ehrh.) Pers. (S. scandica (L.) Hedl.)

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

Sorbus intermedia (Ehrh.) Pers.(S. scandica (L.) Hedl.)

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, 1987), pp. 19–101 [in Russian]

Sorbus pohuashanensis Hedl.

Family: Rosaceae Juss.

Fruit

Carotenoids

Content, mg/g: 2.12

Composition, %: Phytofluene – tr; a-carotene – 5.5;b-carotene – 54.4; x-carotene and d-carotene –

4.7; cryptoxanthin – 21.3; 5;6:monoepoxy-a-carotene – 1.5; 5;6-monoepoxy-b-carotene –

0.8; mutatochrome – 3.2; violaxanthin – 0.2;

lutein – 0.3; zeaxanthin – 2.2

References

1. L.R.G. Valadon, A.M. Sellens, R.S. Mummery, Ann. Bot.

39(162), 785 (1975)

Sorbus sambucifolia (Cham. et Schlecht.)M. Roem.

Family: Rosaceae Juss.

Fruit

Carotene

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Sorbus sibirica Hedl. (S. aucuparia L. ssp.sibirica Kryl.; Pyrus aucuparia Bge.)

Family: Rosaceae Juss.

Fruit

Essential oil [1]

Carotene

Content, mg% on dry wt: 20.0 [2]

Seed

Oil, % on dry wt: 22.0

References

1. N.V. Pavlov, Rastitel’noe syr’e Kazakhstana. Rasteniya: ikhveshchestva i ispol’zovanie, otv. red. akad. V.L. Komarov

(izd. AN SSSR,Moskwa-Leningrad, 1938), 550 s [in Russian]

2. V.I. Vereshchagin, K.A. Sobolevskaya, A.I. Yakubova,

Poleznye rasteniya Zapadnoi Sibiri (Izd. AN SSSR,

Мoskwa-Leningrad, 1959), 347 s [in Russian]

Sorbus tianschanica Rupr.

Family: Rosaceae Juss.

Seed

Oil

Use: Fatty oil is offered for paratyphoid treatment.

References

1. Rastitel’nye resursy SSSR. Tsvetkovye rasteniya, ikhkhimicheskii sostav, ispol’zovanie. Sem. Hydrangeaceae-Haloragaceae (izd. “Nauka”, Leningrad, 1987), pp. 19–101

[in Russian]

Page 81: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,

Spiraea ulmaria L. 781 Rosaceae Juss.

Sorbus torminalis (L.) Crantz

Family: Rosaceae Juss.

Branch and Leaf

Triterpenoic acids

Component: Ursolic acid [1]

Fruit

Carotenoids

Content, % on fresh wt: 2.80 [2]

References

1. L.Y. Ivanovskaya, A.A. Ryabinin, L.P. Barabanova, Zhurn.

Obshch. Khimii 33, vyp. 10, 3446 (1963) [in Russian]

2. E.N. Novruzov, Rastit. Resursy 24(1), 48 (1988) [in Russian]

Spiraea hypericifolia L. (S. ambigua Pall.;S. crenata Pall. (non L.); S. acutifoliaWilld.; S. obovata Grossh.)

Family: Rosaceae Juss.

Aerial Part

Essential oil

Components: Salicylic acid, salicylic aldehyde [1]

Leaf

Carotenoids

Content, mg/100 g on fresh wt: 184–201; on dry wt:

409–445 [2]

Chlorophyllic pigments

Content, mg/100 g on fresh wt: Chlorophyll a –

199–227; chlorophyll b – 66–86; on dry wt: chlo-

rophyll a – 440–505; chlorophyll b 145–190 [2]

References

1. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

2. E.N. Ketskhoveli, M.A. Saradzheva, Izv. AN Gruz. SSR, ser.

biol. 4(2), 138 (1978) [in Russian]

Spiraea salicifolia L.

Family: Rosaceae Juss.

Flower

Lipids (petroleum ether)

Wax

Components: Hydrocarbon C29H60, alcohol

C28H58O [1]

Root

Essential oil [2]

References

1. E. Steinegger, P. Carparis, Pharm. Acta Helv. 20, 154 (1945);

Chem. Abstr. 42, N 4578 (1948)

2. M.I. Goryaev, Efirnye masla flory SSSR (izd. AN Kaz. SSR,

Alma-Ata, 1952), p. 249 [in Russian]

Spiraea ulmaria L.

Family: Rosaceae Juss.

Flower

Essential oilContent, % on dry wt: 0.2

Components: Salicylic acid, salicyl aldehyde,

methyl salicylate, vanillin, heliotropin

References

1. B.N. Rutowskii, Efirnye Masla (Мoskwa-Leningrad, 1931),

578 s [in Russian]

Page 82: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Rosa acicularis Lindl. (R. sichotealinensis Kolesn., R. gmelini Bge., R. baicalensis Turcz., R. carelica Fr.,