Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

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Page 1: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae

Atropa belladonna L.

Family: Solanaceae

Seed

Oil, %: 30.0 [1]; 39.6 [2]

d15: 0.9250–0.9256 [1]

n25D : 1.4726 [1]; 14755 [2]oE20: 8.02 [2]

Acid value, mg KOH: 1.13 [2]

Iodine value, % J2: 145.0 [1]; 142.80 [2]

Saponification value, mg KOH: 191.2 [1];

182.93 [2]

FAs

Composition (GLC), %: 6:0 – 0.34; 14:0–0.2; 16:0 –

5.25; 16:1 – tr; 18:0 – 3.70; 18:1 – 13.31; 18:2 –

86.46; 18:3 – 0.5

References

1. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

2. V.S. Dolya, E.N. Shkurupy, N.S. Fursa, Chem. Nat. Comp. 9,

578 (1973)

Atropa caucasica Kreyer.

Family: Solanaceae

Seed

Oil, % dry wt: 34.0

Iodine value, % J2: 127.0

A.I. Glushenkova (ed.), Lipids, Lipophilic Components and EssentDOI 10.1007/978-0-85729-323-7, # Springer Science+Business M

References

1. N.I. Sharapov,Oil Plants and the Process of Oil formation (ASUSSR Press, Moskwa-Leningrad, 1959), p. 352 [in Russian]

Capsicum annuum L.

Family: Solanaceae

Fruit

Moisture, %: 89.9 [1]

Parts, %: Pulp – 84.2; pestil – 6.7; seed – 9.1

(fresh wt) [1]

Pericarp – 57.8; seed – 7.0; stem with calyces – 33.9

(sweet red pepper); pericarp – 6.8; seed – 25.4; stem

with calyces – 1.7% (hot red pepper) [2]

Dry matter, %: 10.72 (sweet red pepper) [3]

Oil (petroleum ether), % dry wt: 12.9 (sweet red pep-

per), 15.6 (hot red pepper) [2]

FAs

Composition (GLC; 15% EGS); %: 8:0 – tr – 0.1;

10:0 – tr; 12:0 – 0.2–0.5; 14:0 – 1.1–1.3; 14:1 –

tr; 15:0 – tr; 16:0 – 10.8–11.9; 16:1 – 0.3–0.5;

17:0 – tr; 18:0 – 2.2–2.4; 18:1 – 8.1–8.3; 18:2 –

71.2–73.0; 18:3 + 20:0 – 3.0–4.3 (sweet red

pepper); 8:0 – tr; 10:0 – tr; 12:0 – 0.3; 14:0 –

0.7–1.1; 14:1 – tr; 16:0 – 10.8–11.5; 16:1 – 0.2–

0.3; 17:0 – tr; 18:0 – 2.0–2.1; 18:1 – 7.0–8.2;

18:2 – 74.5–75.8; 18:3 + 20:0 – 1.9–2.5 (hot red

pepper) [2]

Carotenoids, 10–3% fresh wt: 4.80 [3]

Composition, %: a-Carotene – 1.8; b-carotene –

12.5; 5;6-epoxy-lutein – 4.0; lutein – 53.2; b –

cryptoxanthin – 0.9; violaxanthin – 8.2;

ial Oils from Plant Sources,edia, LLC 2012

Page 2: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 874 Capsicum annuum L.

neoxanthin – 10.3; unidentified carotenoids –

9.1 [3]

Chlorophylls, 10–3% fresh wt: 67.80 [3]

Composition, %: Chlorophyll a – 61.3; сhlorophyllb – 24.9; pheophytin a – 0.8; pheophytin b – 0.3;

chlorophyllid a – 8.5; chlorophyllid b – 4.2

Fruit Wall

Dry matter, %: 12.4 [4]

Oil (petroleum ether), % dry wt: 0.17% [4]

FAs

Composition, %: 12:0 – 1.4; 12:1 – 0.1; 14:0 – 3.9;

14:1 – 0.2; 16:0 – 13.8; 16:1 – 1.4; 16:2 – 0.2;

17:0 – 0.2; 18:0 – 4.7; 18:1 – 5.2; 18:2 – 45.5;

18:3 – 21.9; 20:0 – tr; 20:4 – 0.6; 20:5 – 0.2; 22:0

– 0.3; others – 0.4

Pericarp

FAs

Composition (GLC, 15% EGS), %: 8:0 – tr; 10:0 –

tr; 12:0 – tr; 14:0 – 0.1 – tr; 15:0 – tr; 16:0 – 9.3–

10.3; 16:1 – 0.2–0.3; 17:0 – tr; 18:0 – 1.7–2.2;

18:1 – 8.1–8.5; 18:2 – 79.0–79.8; 18:3 + 20:0 –

0.1 – tr (sweet red pepper): 8:0 – tr; 10:0 – tr –

0.1; 12:0 – 1.5–2.5; 14:0 – 4.4–6.2; 14:1 – tr; 15:0

– tr; 16:0 – 16.0–16.3; 16:1 – 0.9; 17:0 – tr – 0.1;

18:0 – 2.9–3.7; 18:1 – 7.8–9.5; 18:2 – 48.4–50.3;

18:3 + 20:0 – 13.9–14.4 (hot red pepper) [2]

Pestil

Lipids, % dry wt: 0.89 (sweet red pepper, chloroform-

methanol) [1]

FAs

Composition (GLC, 15% EGS), %: 12:0 – 0.3; 14:0

– 1.0; 15:0 – tr; 16:0 – 27.4; 16:1 – 0.4; 17:0 –

0.5; 17:1 – tr; 18:0 – 1.4; 18:1 – 7.9; 18:2 – 51.8;

18:3 – 8.5; 20:0 – 0.8

Carotenoids, mg% of lipids: 56.8

Placenta

Dry matter, %: 11.4 [4]

Oil (petroleum ether), % dry wt: 0.18 [4]

FAs

Composition, %: 12:0 – 1.0; 12:1 – 0.2; 14:0 – 2.7;

14:1 – 0.3; 16:0 – 15.6; 16:1 – 1.3; 16:2 – 0.2;

17:0 – 0.4; 18:0 – 6.9; 18:1 – 9.6; 18:2 – 40.4;

18:3 – 18.7; 20:0 – tr; 20:4 – 0.9; 20:5 – 0.3; 22:0

– 0.2; others – 1.2

Pulp

Lipids, % dry wt: 1.75 (sweet pepper, chloroform-

methanol) [1], 4.1 (hot red pepper, benzine) [5]

FAs

Composition (GLC, 15% EGS), %: 12:0 – 2.7; 14:0

– 3.3; 15:0 – tr; 16:0 – 33.3; 16:1 – 1.2; 17:0 –

0.7; 17:1 – tr; 18:0 – 4.1; 18:1 – 11.3; 18:2 – 33.2;

18:3 – 8.4; 20:0 – 1.8; unidentified – tr (sweet red

pepper) [1]; 14:0 – 7.7; 16:0 – 18.3; 16:1 – 1.0;

17:0 – 0.6; 18:0 – 4.1; 18:1 – 13.3; 18:2 – 45.0;

18:3 – 10.0 (hot red pepper) [5]

Composition of lipids

Surface lipids, %: 3.8 [1]

NL, %: 78.76 [1]

GL, %: 14.34 [1]

PhL %: 3.10 [1]

Composition of NL (CC), %: Hydrogenes + carot-

enoids – 0.36–8.2; esters of FAs with alkanols

and cyclic alcohols – 10.86; TAG – 55.8; tocoph-

erols – 0.14; free FAs – 14.28; alkanols – 6.16;

triterphenols + monomethylsterols + sterols –

3.84; DAG + MAG – 0.44

FAs

Composition (GLC, 15% EGS), %: 12:0 – 0.2; 14:0

– 2.6; 15:0 – 0.5; 16:0 – 26.7; 16:1 – 1.0; 17:0 –

0.3; 17:1 – 0.2; 18:0 – 11.9; 18:1 – 19.7; 18:2 –

34.0; 18:3 – 2.3; 20:0 – 0.2; unidentified – 0.4 [1]

TAG, mg %: 72.8 [6]

Main components (Coleman), mol %: PLL – 12.6;

OLL – 9.4; LLL – 8.4; PLO – 8.2; PLP – 5.3;

StLL – 5.0; PLS – 4.5; LLLe – 4.4 [6]

GL, mg/g dry wt: 2.45 [1]

FAs (GLC, 15% EGS), %: 12:0 – 0.4; 14:0 – 1.9;

15:0 – 0.4; 16:0 – 25.2; 16:1 – 0.7; 17:0 – 0.8;

17:1 – 0.8; 18:0 – 0.7; 18:1 – 7.2; 18:2 – 19.3;

18:3 – 42.1; 20:0 – 0.5

Composition (CC), %: ESG – 22.5; MGDG – 40.8;

SG – 13.7; DGDG – 20.0; SQDG – 3.0;

unidentified – tr (sweet red pepper) [7]

ESG

FAs (GLC, 15%Reoplex 400, DB 1), %: 12:0 – 0.6;

14:0 – 2.3; 15:0 – tr; 16:0 – 29.4; 16:1 – tr; 17:0 – tr;

18:0 – 1.3; 18:1 – 6.6; 18:2 – 38.4; 18:3 – 21.4 [7]

MGDG

FAs (GLC), %: 12:0 – 0.6; 14:0 – 0.7; 15:0 – tr; 16:0

– 19.2; 16:1 – 0.7; 18:0 – 0.5; 18:1 – 4.6; 18:2 –

13.2; 18:3 – 60.7; 20:0 – 0.7 [7]

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Capsicum annuum L. 875 Solanaceae

DGDG

FAs (GLC), %: 12:0 – 0.7; 14:0 – 1.2; 15:0 – tr; 16:0

– 22.2; 16:1 – 0.5; 17:0 – tr; 18:0 – 0.5; 18:1 –

4.3; 18:2 – 21.5; 18:3 – 49.1 [7]

PhL, mg/g dry wt: 0.53 [1]

Components (CC), %: PhC, PhE, PhI, PhG (main

components), PhA and two N-acyl-PhLFAs (GLC, 15% EGS), %: 12:0 – 6.6; 14:0 – 1.8;

15:0 – tr; 16:0 – 42.7; 16:1 – tr; 17:0 – tr; 18:0 –

1.7; 18:1 – 18.6; 18:2 – 19.3; 18:3 – 9.3; 20:0 – tr

Unsaponifiables

Components, %: Isoprenes – 19.0; triterpenols –

30.0; sterols – 38.0 [5]

Carotenoids, mg %: 875.8 [5]

Pigments: Capsanthin, capsorubin, and their esters [5]

Components: Carotenes, lutein, violaxanthin

neoxanthin, chlorophyll a and b (Large green

cultivar at immature and mature stages) [9]

Carotenes, cryptoxanthin, unidentified 1,

capsanthin, zeaxanthin, cryptocapsin,

mutatoxanthin, unidentified 2, capsorubin,

capsanthin isomer, violaxanthin, anteraxanthin,

luteoxanthin a and b, neoxanthin, capsorubin

isomer, capsanthin isomer (Large green cultivar

at half and fully ripened stages) [9]

Carotenes, hydroxyl-a-carotene, cryptoxanthin,

cryptoxanthin-5,6-epoxide and cryptoxanthin-

5,6-diepoxide, mutatoxanthin, unidentified 1,

lutein, violaxanthin, anteraxanthin,

luteoxanthin, unidentified 2, auroxanthin,

neoxanthin, unidentified 3, chlorophyll a and

b (Golden Californian Wonder cultivar at half

and fully ripened stages) [9]

b-Carotene, neurosporene, lutein, zeaxanthin, chlo-rophyll b, pheophytin a, pheophytin b (mature

green fruit), b-carotene, lutein, capsanthin,

capsanthin monododecanoate, capsanthin

monohexadecanoate, capsanthin monolinoleate,

capsanthin ester 4, capsorubin, capsorubin ester

1, capsorubin ester 2, zeaxanthin, zeaxanthin

ester 1 (mature red fruit) [10]

Carotenoids, mg/g dry wt: b-Carotene – 54.9; b-crypthoxanthin – 20.8 (as free and monoester);

lutein – 79.9; violaxanthin – 33.8; neoxanthin –

39.1; total – 228.5 (fully green) [8]

b-Carotene – 271.8; b-crypthoxanthin – 217.0 (as

free and monoester); cryptocapsin – 90.0;

zeaxanthin – 54.7 (as monoester); anteraxanthin

– 162.4 (as diester); violaxanthin – 125.3;

capsanthin – 587.7 (as free; monoester and dies-

ter); capsanthin-5,6-epoxide – 30.0 (as diester);

capsorubin – 181.7 (as diester); neoxanthin –

35.3; total – 1755.9 (mature red) [8]

Composition%: b-Carotene – 24.0; b-cyptoxantine(free and monoester) – 9.1; lutein – 34.9;

violaxanthin – 14.8; neoxanthin – 17.1 (fully

green) [8]

b-Carotene – 15.4; b-cryptoxanthin (free and

monoester) – 12.3; cryptocapsin – 5.1; zeaxan-

thin monoester – 3.1; anteraxanthin diester –

9.2; violaxanthin – 7.1; capsanthin (free; mono-

ester; diester) – 33.3; capsanthin-5,6-epoxide

diester – 1.7; capsorubin diester – 10.3,

neoxanthin – 2.0 (mature red) [8]

Xanthophylls

Composition, %: b-Crypthoxanthin – 12.0; lutein –

45.9; violaxanthin – 19.5; neoxanthin – 22.4 (all

as free – 99.8 in the fully green) [8]

Cryptocapsin – 6.1; violaxanthin – 8.5; capsanthin –

2.9; neoxanthin – 2.4 (all as free – 19.9); b-crypthoxanthin – 14.6; zeaxanthin – 3.7;

capsanthin – 7.6 (all as monoester – 25.9);

anteraxanthin – 11.0; capsanthin-5,6-epoxide

– 2.1; capsanthin – 28.8; capsorubin – 12.2 (all

as diester – 54.1 in the mature red) [8]

Oxygenated carotenoids

Components: Zeaxanthin; carotenoid 3,6-epoxide

(heteroxanthin), tetrol karpoxanthin,

anteraxanthin, capsanthin, via violaxanthin

capsanthin 5,6-epoxide, capsorubin, capsanthin

3,6-epoxide, capsochrome 5,6-epoxide (pods of

red paprika) [11]

TLC [5, 9, 10]

UV [5, 8, 11]

HPLC [10]1H NMR [11]

Capsanthin 5,6-epoxide

M.p.[11]

[a]D: + 9.4o (C6H6) [11]

Capsanthin 3,6-epoxide

UV [11]

[a]D: + 3.2o (C6H6) [11]

Tocopherols, mg/% of lipids: 127.0, a, b + g and d-Isomers [1]

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Solanaceae 876 Capsicum annuum L.

Seed

Dry matter, %: 53.2 [4]

Moisture, %: 9.4–12.4 [12]

Mass of 1,000, g: 4.85–5.09 [12]

Oil, %: 2.65–5.12 (hexane, fresh wt) [12]; 7.89–9.10

[5]; 18.0–26.0 (dry wt) [4, 13, 14]

d20: 0.9228–0.9290 [13]

n20D : 1.4750 [13]

n21D : 1.4776 [13]

Saponification value, mg KOH: 171.1 [13]; 189.5

[14]

Iodine value, % J2: 84.5–134.4 [13]; 138.2 [14]

Unsaponifiables, %: 1.8 [14]

FAs

Composition (GLC, 15% ECS), %: 8:0 – tr; 10:0 –

tr; 12:0 – tr; 14:0 – tr – 0.1; 15:0 – tr; 16:0 – 9.3–

10.3; 16:1 – 0.2–0.3; 17:0 – tr; 18:0 – 1.7–2.2;

18:1 – 8.1–8.5; 18:2 – 79.1–79.8; 18:3 + 20:0 – tr

– 0.1 (sweet red pepper) [2]

8:0 – tr; 12:0 – tr; 14:0 – tr; 15:0 – tr; 16:0 – 9.9; 16:1

– 0.2; 17:0 – tr; 18:0 – 2.1–2.3; 18:1 – 8.0–8.4;

18:2 – 79.1–79.4; 18:3 + 20:0 – tr – 0.1 (hot red

pepper) [2]

14:0 – 0.2; 16:0 – 11.3; 16:1 – 0.5; 16:2 – 0.2; 17:0 –

0.1; 18:0 – 4.4; 18:1 – 14.8; 18:2 – 67.4; 18:3 –

0.2; 20:0 – 0.5; 22:0 – 0.2 [4]

Low molecular weight acids (6:0–13:0) – 2.2; 14:0 –

0.4; 16:0 – 12.6; 16:1 – 1.7; 16:2 – 0.9; 18:0 –

8.8; 18:1 – 19.4; 18:2 – 54.0 (hot red pepper) [12]

Composition of Oil (CC), %: Hydrogenes with carot-

enoids – 0.9; esters of FAs with alkanols and cyclic

alcohols – 1.5; TAG – 87.2; free FAs + tocopherols

– 4.5; triterpenols – 1.2; sterols + DAG – 3.2; MAG

+ unidentified – 1.2 [12]

Esters of alkanols and cyclic alcohols

FAs (GLC), %: Low molecular weight acids C6 –

C13 – 9.0; 14:0 – 1.6; 16:0 – 15.5; 16:1 – 2.3; 16:2

– 1.6; 17:0 – 0.8; 18:0 – 9.5; 18:1 – 23.2; 18:2 –

33.4; 18:3 – 3.1 [12]

Free FAs

Composition (GLC), %: Low molecular weight

acids (6:0–13:0) – 3.5; 14:0 – 1.0; 16:0 – 21.2;

16:1 – 3.2; 16:2 – 2.5; 17:0 – 1.3; 18:0 – 5.7; 18:1

– 17.2; 18:2 – 38.1; 18:3 – 4.8; 20:0 – 1.5 [12]

TAG

Composition (HPLC), mole %: LeLL – 0.9; LLL +

LeLO – 44.5; LeLeP – 1.0; LLO – 11.8; LLP –

24.0; LOO – 2.7; LLS + LOP – 9.5; LPP – 1.1;

OOO – 0.6; LOSt + OOP – 1.7; LPSt + OPP –

1.2; OOSt – 0.2; others – 0.8 (sweet pepper) [15]

LeLL – 0.3; LLL + LeLO – 48.6; LeLeP – 0.2; LLO

– 10.9; LLP – 28.0; LOO – 1.8; LLSt + LOP –

7.7; LPP – 1.2; OOO – 0.1; LOSt + OOP – 0.2;

LPSt + OPP – 0.2; OOSt – 0.1; others – 0.7 (hot

pepper) [15]

FAs (GLC, 15% ECS), %: 14:0 – tr; 16:0 – 12.6;

18:0 – 5.5; 18:1 – 12.3; 18:2 – 69.6 [12]

GL

Composition (CC), %: ESG – 17.8; MGDG – 7.2;

SG – 61.1; DGDG – 3.9; unidentified – 10.0 [7]

ESG

FAs (GLC, 15% Reorlex 400, DB 1), %: 9:0 – tr;

10:0 – tr; 12:0 – 1.8; 13:0 – 1.8; 14:0 – 6.1; 15:0 –

2.3; 16:0 – 43. – tr; 17:0 – 1.3; 17:1 – tr; 18:0 –

11.1; 18:1 – 7.2; 18:2 – 24.2; 20.0 – 1.2 [7]

MGDG

FAs (GLC), %: 9:0 – 0.2; 10:0 – 0.3; 12:0 – 0.3;

13:0 – 0.3; 14:0 – 7.1; 15:0 – 0.7; 16:0 – 27.2;

16:1 – 1.1; 17:0 – 0.7; 17:1 – 0.7; 18:0 – 6.8; 18:1

– 17.2; 18:2 – 36.8; 18:3 – tr; 20:0 – 0.6 [7]

DGDG

FAs (GLC), %: 9:0 – tr; 10:0 – tr; 12:0 – 0.9;

13:0 – 0.5; 14:0 – 5.6; 15:0 – 1.8; 16:0 – 36.2;

16:1 – 1.4; 17:0 – 1.8; 17:1 – 1.7; 18:0 – 11.9;

18:1 – 7.6; 18:2 – 27.1; 20:0 – 2.5 [7]

Lipids (chloroform-methanol), %: 2.65; 3.33 (seeds

from green fruits); 5.12; 6.43 (seeds from green-

red ripe fruits); 6.33–7.06 (stored seeds, fresh wt)

[16]; 15.0 (dry wt) [1]

FAs

Composition, (GLC, Silar 5CP)%: 16:0 – 12.13;

16:1 – 0.20; 17:0 – 0.23; 17:1 – 0.32; 18:0 –

1.77; 18:1 – 7.82; 18:2 – 75.82; 18:3 – 0.40;

20:0 – 0.22; 20:1 (11) – 0.28; 20:1 (13) – tr [17]

Isomers of 16:1, %: 16:1 (9) – 86.3; 16:1 (7) – 13.7

Isomers of 18:1, %: 18:1 (9) – 91.0; 18:1 (11) – 9.0

10:0 – 0.23; 11:0 – 0.14; 12:0 – 0.06; 13:0 – 0.13;

14:0 – tr; 16:0 – 12.40; 18:0 – 0.20; 18:1 – 5.97;

18:2 – 79.98; others (2) – 0.24; 0.56 (from seed

of mature fruits) [16]

10:0 – 0.03; 11:0 – 0.03; 12:0 – 0.03; 13:0 – 0.03;

14:0 – 0.43; 14:1 – 0.08; 15:0 – 0.12; 16:0 –

22.56; 18:0 – 0.61; 18:1 – 6.04; 18:2 – 70.04

(from seed of green fruits) [16]

Composition of lipids (CC), %: Hydrocarbons +

esters of FAs with sterols – 1.5; TAG – 87.8; free

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Capsicum annuum L. 877 Solanaceae

FAs + tocopherols – 3.8; triterpenols + sterols – 2.9;

DAG – 0.5; MAG – tr; GL – 1.2; Phl – 2.3 [18]

Free lipids (hexane), % dry wt: 13.5 [18]

Composition of free lipids (CC), %: Hydrocarbons

+ esters of FAs with sterols – 1.7; TAG – 94.5;

free FAs + tocopherols – 0.7; triterpenols + ste-

rols – 3.1; DAG – tr [18]

FAs (GLC, 17% EGS), %: 9:0 – 0.2; 10:0 – 0.2; 12:0 –

0.2; 13:0 – tr; 14:0 – 0.3; 15:0 – tr; 16:0 – 11.7; 16:1

– 0.5; 17:0 – 0.1; 18:0 – 3.3; 18:1 – 14.5; 18:2 –

68.5; 18:3 – tr; 20:0 – 0.3; 22:0 – tr

Bound lipids (chloroform-methanol), % dry wt: 1.5

[18]

Composition of bound lipids (CC), %: Hydrocar-

bons + esters of FAs with sterols – tr; TAG –

27.0; free FAs + tocopherols – 31.5.8;

triterpenols + sterols – 1.5; DAG – 5.2; MAG –

tr; GL – 11.9; Phl – 22.9 [18]

FAs (GLC, 17% EGS), %: 9:0 – tr; 10:0 – 0.1; 12:0

– 0.3; 13:0 – 0.2; 14:0 – 0.3; 15:0 – tr; 16:0 –

19.7; 16:1 – 0.9; 17:0 – tr; 17:1 – tr; 18:0 – 2.6;

18:1 – 19.4; 18:2 – 55.6; 18:3 – tr; 20:0 – 0.9

Free FAs

Composition (GLC), %: 9:0 – tr; 10:0 – tr; 12:0 – tr;

14:0 – 1.5; 15:0 – 0.8; 16:0 – 32.8; 16:1 – 1.9;

17:0 – 5.1; 17:1 – tr; 18:0 – 12.2; 18:1 – 26.2;

18:2 – 13.5; 20:0 – 2.8; 22:0 – 2.5; 24:0 – 0.7 [18]

DAG

FAs (GLC), %: 9:0 – 0.3; 10:0 – 0.7; 12:0 – 0.4;

13:0 – 0.1; 14:0 – 0.5; 15:0 – 0.1; 16:0 – 15.1;

16:1 – 0.8; 17:0 – tr; 17:1 – tr; 18:0 – 2.5; 18:1 –

13.3; 18:2 – 65.7; 18:3 – tr; 20:0 – 0.5 [18]

GL

FAs (GLC), %: 9:0 – tr; 10:0 – tr; 12:0 – 1.2;

13:0 – 1.6; 14:0 – 6.2; 15:0 – 1.8; 16:0 – 38.2;

16:1 – 0.5; 17:0 – 1.2; 17:1 – 0.4; 18:0 – 10.1;

18:1 – 9.8; 18:2 – 27.9; 20:0 – 1.1 [18]

Phl

FAs (GLC), %: 9:0 – tr; 10:0 – tr; 12:0 – 0.2; 14:0 –

0.3; 15:0 – tr; 16:0 – 20.6; 16:1 – 0.8; 17:0 – 0.4;

17:1 – 0.2; 18:0 – 6.2; 18:1 – 10.8; 18:2 – 60.3;

18:3 – tr; 20:0 – 0.2 [18]

Unsaponifiables

Composition (GLC), %: Triterpenols – 46.0; 4-

monomethylsterols – 6.0; sterols – 31.0; less

polar compounds (hydrocarbons, etc.) – 17.0 [14]

Alkanols C30 – 5.6; C32 – 1.42; C34 – 4.12;

unidentified C34 – 0.85; cholesterol – 1.50;

campesterol – 2.91; stigmasterol – 17.95; b-sitosterol – 40.25; D5-avenasterol – 0.90; D7-

stigmastenol – 23.45; D7-avenasterol – 1.05

(from seed of mature fruits) [16]

Alkanols C30 – 4.77; C32 – 0.48; unidentified C34 –

1.00; unidentified C34 – 2.43; cholesterol – 1.23;

campesterol – 10.85; stigmasterol – 1.50; b-sitosterol – 74.24; D5-avenasterol – 1.57; D7-

stigmastenol – 1.43; D7-avenasterol – 0.50

(from seed of green fruits) [16]

Alkanols C30 – 5.05 – 5.36; C32 – 0.25–0.45;

unidentified C34 – 1.21–1.74; unidentified C34 –

1.68–1.98; cholesterol – 0.79–1.92; campesterol

– 2.09–2.41; stigmasterol – 13.13–13.96; b-sitosterol – 39.98–41.54; D5-avenasterol –

0.66–0.82; D7-stigmastenol – 30.09–31.96; D7-

avenasterol – 1.36–1.79 (from stored seeds) [16]

Carotenoids, mg %: 3.8 [5]

Carotenoids, mg/ % of lipids: 300.3 [1]; 1062 [2]

Tocopherols, mg/ % of lipids: 57.7, a, b + g and

d-isomers [1]

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 3.0–20.0; lanosterol – tr –

14.0; methylenelanost-8-en-3b-ol – tr – 1.0;

cycloartanol – 14.0–26.0; cycloartenol – 33.0–

50.0; 24-methylenecycloartanol – 2.0–4.0;

lupeol – tr – 16.0; b-amyrin – tr – 20.0; others

– 1.0–6.0; daturaolone and daturadiol [19, 20]

IR, MS, 1H NMR [19, 20]

4a-Methylsterols

Composition (Ag+-PLC, GLC), %: 31-

Norlanostenol + 4a-methyl zymostenol – 26.0;

lophenol – 30.0; obtusifoliol – 8.0; 31-

norcycloartenol – 3.0; gramisterol – 7.0;

citrostadienol – 10.0; unidentified – 4.0; others

– 12.0 (Korea) [19]

31-Norcycloartanol – 4.0; 31-norcycloartenol – 3.0;

cycloeucalenol – 3.0; 31-norlanost-8-enol –

13.0; 31-norlanosterol – 9.0; obtusifoliol – 6.0;

31-norlanost-9(11)-enol – 5.0; 24-methyl-31-

norlanost-9(11)-enol – tr; 4a-methylcholest-8-

enol – 7.0; lophenol – 23.0; 24-methyllophenol

– tr; 24-ethyllophenol – tr – 2.0; gramisterol –

5.0; citrostadienol – 1.0; 4a,24-dimethyl-

cholesta-7,24-dienol – tr; 4a-methyl-24-

ethylcholesta-7,24-dienol – 1.0; others – 7.0

(California chili) [21]

Page 6: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 878 Capsicum annuum L. var angulosum Mill.

31-Norcycloartanol – 3.0; 31-norcycloartenol – 9.0;

cycloeucalenol – 1.0; 31-norlanost-8-enol – 7.0;

31-norlanosterol – 9.0; obtusifoliol – 3.0; 31-

norlanost-9(11)-enol – 15.0; 24-methyl-31-

norlanost-9(11)-enol – tr; 4a-methylcholest-8-

enol – 4.0; lophenol – 3.0; 24-methyllophenol –

tr; 24-ethyllophenol – tr; gramisterol – 5.0;

citrostadienol – 5.0; 4a,24-dimethylcholesta-

7,24-dienol – tr; 4a-methyl-24-ethylcholesta-

7,24-dienol – 1.0; others – 8.0 (Takanotsume

tougarashi) [21]

IR, 1H NMR [19, 20]

IR, MS, 1H NMR [21]

Sterols

Composition (GLC, 1.5% OV 17), %: Cholesterol –

9.0; brassicasterol – 1.0; campesterol + 24-

methylenecholesterol – 17.0; stigmasterol –

13.0; b-sitosterol – 45.0; D5-avenasterol – 14.0;

D7-stigmastenol – 1.0; D7-avenasterol – tr [14]

IR, MS, 1H NMR [14]

Stem and Calyces

Oil

FAs

Composition (GLC, 15% EGS), %: 8:0 – tr; 10:0 –

tr; 12:0 – 0.7–1.1; 14:0 – 2.3–3.0; 15:0 – 0.1–0.2;

16:0 – 14.4–15.6; 16:1 – 0.4–0.8; 17:0 – 0.3–0.8;

18:0 – 3.04.3–4.8; 18:1 – 3.9–4.7; 18:2 – 51.3–

60.1; 18:3 + 20:0 – 12.3–17.7; 20:0 – 1.0;

unidentified (2) – 0.5, 0.2 (sweet red pepper) [2]

8:0 – tr; 10:0 – tr; 12:0 – 1.1; 14:0 – 3.3; 15:0 – 0.2;

16:0 – 15.3; 16:1 – 0.6; 17:0 – 0.4; 18:0 – 3.9;

18:1 – 5.2; 18:2 – 55.4; 18:3 + 20:0 – 14.3; 20:0 –

1.0 unidentified (2) – 0.1; 0.2 (hot red pepper) [2]

Use: Food-stuff as sweet and hot peppers [1, 5, 13].

Remedies “Fructus Capsici,” “Tinctura Capsici,”

“Linimentum Capsici ammoniatum,” “Linimentum

Capsici camphoratum” [22].

References

1. D.T. Asilbekova Chem. Nat. Comp. 39, 442 (2003)

2. G.C. Tsatsaronis, A.H. Kehayoglou, J. Am. Oil Chem.

Soc. 48, 365 (1971)

3. L.N. Pilipenko, L.B. Oleinik, V.V. Kozhukhar, Chem. Nat.

Comp. 34, 269 (1998)

4. J.E. Marion, A.H. Dempsey, J. Am. Oil Chem. Soc. 41, 548

(1964)

5. N.P. Bekker, N.T. Ul’chenko, A.I. Glushenkova, Chem. Nat.

Comp. 38, 466 (2002)

6. D.T. Asilbekova, in abs: YII Molod’yezhnaya nauchnaya

shkola-konferentsiya po organicheskoy khimii

(Ekaterinburg, 2004), p. 208 [in Russian]

7. D.T. Asilbekova, Chem. Nat. Comp. 40, 115 (2004)

8. B. Camara, R. Moneger, Phytochemistry 17, 91 (1978)

9. K.A. Buckle, F.M.M. Rahman, J. Chromatogr. 171, 385 (1979)

10. P. Biacs, H.G. Daood, A. Pavisa, F. Hajdu, J. Agric. Food.

Chem. 37, 350 (1989)

11. K.E.B. Parkes, G. Pattenden, M. Baranyai, P. Molnar, J.

Szabolcs, G. Toth, Tetrahedron Lett. 27, 2535 (1986)

12. N.P. Bekker, N.T. Ul’chenko, A.I. Glushenkova, Chem. Nat.

Comp. 37, 131 (2001)

13. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 351 [in

Russian]

14. T.M. Jeoung, T. Itoh, T. Tamura, T. Matsumoto, Lipids

9(11), 921 (1974)

15. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

16. R.S. Farag, A.M. Youssef, A.A. Radwan, A.H. Kheraba, A.I.

Ismail, Fette, Seifen, Anstrichmittel 366 (1982)

17. Von A. Seher, U. Gundlach, Fette, Seifen, Anstrichmittel

84(9), 342 (1982)

18. D.T. Asilbekova, Chem. Nat. Comp. 39, 528 (2003)

19. T.M. Jeoung, T. Itoh, T. Tamura, T. Matsumoto, Lipids 10,

634 (1975)

20. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

21. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

22. M.D. Mashkovsky, Lekarstvennye sredstva, vol 1

(Meditsina, Tashkent, 1988), p. 684 [in Russian]

Capsicum annuum L. var angulosum Mill.

Family: Solanaceae

Seed

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 10.0; lanosterol – tr;

methylenelanost-8-en-3b-ol – tr; cycloartanol –

21.0; cycloartenol – 33.0; 24-

methylenecycloartanol – 3.0; lupeol – 7.0; b-amyrin – 20.0; others – 6.0 [1]

IR, MS, 1H NMR [1]

4a-Methylsterols

Composition (Ag+-PLC, GLC), %: 31-

Norcycloartanol – 5.0; 31-norcycloartenol – 1.0;

cycloeucalenol – 3.0; 31-norlanost-8-enol – 14.0;

31-norlanosterol – 2.0; obtusifoliol – 5.0;

31-norlanost-9(11)-enol – 3.0; 24-methyl-31-

norlanost-9(11)-enol – tr; 4a-methylcholest-8-enol

– 8.0; lophenol – 28.0; 24-methyllophenol – tr;

Page 7: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Capsicum frutescens 879 Solanaceae

24-ethyllophenol – 1.0; gramisterol – 4.0;

citrostadienol – 15.0; 4a;24-dimethylcholesta-

7;24-dienol – tr; 4a-methyl-24-ethylcholesta-7;24-

dienol – 1.0; others – 10.0 [2]1H NMR [2]

References

1. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

2. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Capsicum annuum L. var cerasiforme Irish

Family: Solanaceae

Seed

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 20.0; lanosterol – 14.0;

methylenelanost-8-en-3b-ol – 1.0; cycloartanol –14.0; cycloartenol – 47.0; 24-methylenecy-

cloartanol – 2.0; lupeol – tr; b-amyrin – tr;

others – 2.0 [1]

IR, MS, 1H NMR [1]

4a-Methylsterols

Composition (Ag+-PLC, GLC), %: 31-

Norcycloartanol – 9.0; 31-norcycloartenol –

2.0; cycloeucalenol – 2.0; 31-norlanost-8-enol –

21.0; 31-norlanosterol – 3.0; obtusifoliol – 6.0;

31-norlanost-9(11)-enol – 2.0; 24-methyl-31-

norlanost-9(11)-enol – tr; 4a-methylcholest-8-

enol – 10.0; lophenol – 23.0; 24-methyllophenol

– tr; 24-ethyllophenol – tr; gramisterol – 4.0;

citrostadienol – 10.0; 4a,24-dimethylcholesta-

7,24-dienol – tr; 4a-methyl-24-ethylcholesta-

7,24-dienol – tr; others – 8.0 [2]1H NMR [2]

References

1. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

2. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Capsicum annuum L. var fasciculatumIrish

Family: Solanaceae

Seed

Triterpenols

Composition (Ag+-PLC, GLC on 3% OV 17), %:

Lanost-8-en-3b-ol – 4.0; lanosterol – tr;

methylenelanost-8-en-3b-ol – tr; cycloartanol –

26.0; cycloartenol – 49; 24-

methylenecycloartanol – 3.0; lupeol – 15.0; b-amyrin – 2.0; others – 1.0 [1]

IR, MS, 1H NMR [1]

4a-Methylsterols

Composition (Ag+-PLC, GLC), %: 31-

Norcycloartanol – 2.0; 31-norcycloartenol – tr;

cycloeucalenol – 1.0; 31-norlanost-8-enol – 4.0;

31-norlanosterol – tr; obtusifoliol – tr; 31-

norlanost-9(11)-enol – 19.0; 24-methyl-31-

norlanost-9(11)-enol – tr; 4a-methylcholest-8-

enol – tr; lophenol – 46.0; 24-methyllophenol –

tr; 24-ethyllophenol – tr; gramisterol – 10.0;

citrostadienol – 11.0; 4a;24-dimethylcholesta-

7;24-dienol – tr; 4a-methyl-24-ethylcholesta-

7.24-dienol – tr; others – 7.0 [2]1H NMR [2]

References

1. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

2. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Capsicum frutescens

Family: Solanaceae

Seed

Ash, %: 4.6

Mass of 1,000, g: 5.0–5.8

Oil, % dry wt: 17.5–26.1

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Page 8: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 880 Cestrum parquii L. Herit.

Cestrum parquii L. Herit.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.10

Free sterols, % of total: 37.0

Components: Sitosterol, stigmasterol, campesterol,

cholesterol

Sterols from esters, % of total: 17.0

Components: Cholesterol, sitosterol, campesterol,

stigmasterol

Sterols from sterylglycosides, % of total: 16.0

Components: Sitosterol, campesterol, stigmasterol,

cholesterol

Sterols from acylated sterylglycosides, % of total:

30.0

Components: Sitosterol, stigmasterol, campesterol,

cholesterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Chamaesaracha coronopus

Family: Solanaceae

Seed

Mass of 1,000, g: 0.04

Oil, % dry wt: 20.3

References

1. F. R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Datura alba Wecs.

Family: Solanaceae

Seed

Oil, % dry wt: 19.0

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 23.9; 16:1 –

2.8;18:0 – 2.0; 18:1 – 25.5; 18:2 – 43.3; 18:3 – tr

References

1. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 177 [in Russian]

Datura arborea L.

Family: Solanaceae

Leaves

Sterols, % dry wt: 0.14

Free sterols, % of total: 65.0

Components: Stigmasterol, sitosterol, campesterol,

cholesterol

Sterols from esters, % of total: 9.0

Components: Sitosterol, campesterol, stigmasterol,

cholesterol

Sterols from sterylglycosides, % of total: 11.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total:

15.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Datura inermis Jacq.

Family: Solanaceae

Seed

Oil, % dry wt: 17.5

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 13.1; 16:1

– tr; 16:2 – tr; 18:0 – 0.6; 18:1 – 30.8; 18:2 –

55.0; 18:3 – tr

Page 9: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Datura meteloides DC. 881 Solanaceae

References

1. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 117 [in Russian]

Datura innoxia Mill.

Family: Solanaceae

Seed

Oil, % dry wt: 22.0

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 11.6; 16:1

– tr; 16:2 – tr; 18:0 – 0.5; 18:1 – 25.2; 18:2 –

61.7; 18:3 – tr

References

1. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 552 [in Russian]

Datura metel L.

Synonyms

Datura albaNees; D. fastuosa L. var. alba Hook

Family: Solanaceae

Seed

Ash, %: 4.5 (1), 5.6 (2) [1]

Mass of 1,000, g: 11.2 (1) [1]; 14.1 [1–3]

Oil % dry wt: 17.2–19.0 [1–3]; 12.0 [4]

d28: 0.9255 [4]

n28D : 1.4730 [4]

n40D : 1.4662 [2]; 1.4658 [3]

Iodine value,% J2: 109.0 [2]; 110 (Wij’s) [3]; 84.6 [4]

Saponification value, mg KOH: 188 [2]; 179 [3];

189.0 [4]

HBr uptake, as C18 epoxy acid, %: 0.3 [2, 3]

UR [3]

FAs

Composition, %: Saturated – 6.0; 18:1–59.0; 18:2–

30.0; 18:3–0.5 (GLC, 20% LAC-2R 446) [2]

Saturated – 16.0, 18:1–39.0; 18:2–40.0; 18:3–1.0

(GLC, 14% Resoflex 446 and 20% Apiezon L)

[3]

4a-Methylsterols

Composition (Ag+-PLC-PLC, GLC, OV 17 SCOT,

GC/MS, 2% OV 17), %: 31-Norcycloartanol –

tr; 31-norcycloartenol – tr; cycloeucalenol – 4.0;

31-norlanost-8-enol – 1.0; 31-norlanosterol –

2.0; obtusifoliol – 73.0; 4a-14a,24-trimethyl-

cholesta-8.24-dienol – tr, 31-norlanost-9(11)-

enol – 2.0; methylcholest-8-enol – 2.0; lophenol

– 3.0; 24-methyllophenol – tr; 24-ethyllophenol

– tr; gramisterol – tr; citrostadienol – 3.0; 4a-methyl-24-ethylcholesta-7,24-dienol – tr; others

– 10.0 [5]1H NMR [5]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. F.R. Earle, I.A. Wolff, C.A. Glass, J. Am. Oil Chem. Soc. 39,

381 (1962)

3. F.R. Earle, C.A. Glass, G.C. Geisinger, I.A. Wolff, J. Am. Oil

Chem. Soc. 37, 440 (1960)

4. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 351 [in

Russian]

5. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Datura meteloides DC.

Family: Solanaceae

Seed

Ash, %: 4.5 [1]

Mass of 1,000, g: 6.4 [1]

Oil, % dry wt: 21.8 [1]; 21.0 [2]

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 12.3; 16:1

– tr; 16:2 – tr; 18:0 – 1.1; 18:1 – 18.9; 18:2 – 67.6

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 117 [in Russian]

Page 10: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 882 Datura quercifolia H.B. et K.

Datura quercifolia H.B. et K.

Family: Solanaceae

Seed

Ash, %: 2.7 [1]

Mass of 1,000, g: 4.6 [1]

Oil, % dry wt: 16.1 [1], 17.5 [2]

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 10.6; 16:1

– tr; 16:2 – tr; 18:0 – 0.2; 18:1 – 32.8; 18:2 –

54.0; 18:3 – tr [2]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 117 [in Russian]

Datura sanguinea Riz. et Pav.

Family: Solanaceae

Seed

Oil, % dry wt: 18.0

FAs

Composition (GLC), %: 14:0 – tr; 16:0 – 12.3; 16:1

– tr; 16:2 – tr; 18:0 – 0.9; 18:1 – 20.1; 18:2 – 65.4

References

1. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 552 [in Russian]

Datura stramonium L.

Family: Solanaceae

Seed

Ash, %: 2.7 (1, 2) [1]

Mass of 1,000, g: 6.5 (1); 7.8 (2) [1]

Oil, % dry wt: 25.8 (1); 22.8 (2) [1]; 16.7–25.0 [2–4]

d15: 0.9130–0.9170 [2]

d20D : 0.9600 [3]

n20D : 1.4748 [3]oE20: 8.95 [3]

Acid value, mg KOH: 4.40 [3]

Iodine value, % J2: 113.0–126.0 [2]; 130.46 [3]

Saponification value, mg KOH: 186.0–202.0 [2];

182.93 [3]

FAs

Composition (GLC), %: 6:0 – tr; 8:0 – tr; 14:0 –

0.13; 16:0 – 10.88; 16:1 – 0.46; 18:0 – 2.17; 18:1

– 27.01; 18:2 – 58.39; 18:3 – 0.76; others – 0.2

[3, 4]

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 2.0; lanosterol – tr;

methylenelanost-8-en-3b-ol – tr; cycloartanol –

tr; cycloartenol – 34.0; 24-methylenecycartanol

– 7.0; lupeol – 2.0; b-amyrin – 53.0; others – 2.0

[5]

IR, MS, 1H NMR [5]

4a-Methylsterols

Composition (Ag+-PLC, GLC, OV 17 SCOT, GC/

MS on 2% OV 17), %: 31-Norcycloartanol – tr;

31-norcycloartenol – 6.0; cycloeucalenol – 9.0;

31-norlanost-8-enol – tr; 31-norlanosterol – 2.0;

obtusifoliol – 13.0; 31-norlanost-9(11)-enol –

1.0; 4a-methylcholest-8-enol – 1.0; lophenol –

6.0; 24-methyllophenol – tr; 24-ethyllophenol –

tr; gramisterol – 43.0; citrostadienol – 13.0;

methyl-24-ethylcholesta-7;24-dienol – tr; others

– 6.0 [6]1H NMR [6]

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

2. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

3. V.S. Dolya, E.N. Shkurupy, N.S. Fursa, Chem. Nat. Comp. 9,

578 (1973)

4. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 117 [in Russian]

5. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

6. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Page 11: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Hyoscyamus muticus 883 Solanaceae

Datura sp.

Family: Solanaceae

Seed

Ash, %: 2.7

Mass of 1,000, g: 9.6

Oil, % dry wt: 22.3

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Duboisia myoporoides R.Br.

Family: Solanaceae

Leaves and Stems

Extract (hexane)

Components: Hentriacontanyl tetratriacontanoate,

6-methyldotriacontane, 3-hydroxydotriacontan-

28-one, 4-pentatriacontanone [1]

Dotriacontanol, tetratriacontanoic acid, 8-

hydroxydotriacontan-30-one, betulinic acid,

ursolic acid (30 mg) [2]

References

1. Y.N. Shukla, R.S. Thakur, Phytochemistry 23, 799 (1984)

2. Y.N. Shukla, R.S. Thakur, Phytochemistry 23, 1516 (1984)

Fabiana imbricata Ruiz and Pavon.

Family: SolanaceaeExtract (percolation with EtOH), kg (from 40 kg the

dried ground tops): 5.0–6.0

A dark residue (partitioned between HCL (1%) and

CHCI3), kg: 1.7

FAs, g (from 100 g a dark residue): 1.90

Components (GLC, OV-17, GC/MS): 22:0, 24:0,

26:0, 28:0, 30:0 22:0 with smaller amounts of

23:0, 25:0, 27:0, 29:0

M.p., IR

Alkanes, mg (from 100 g a dark residue): 800

Components(GLC OV-17, GC/MS): n – C23, n –

C25, n – C27, n – C29 with smaller amounts of n –C24, n – C26, n – C28, n – C31

M.p., IR

References

1. J.E. Knapp, N.R. Farnsworth, M. Theiner, Jr. P.L. Schiff,

Phytochemistry 11, 3091 (1972)

Hyoscyamus albus L.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.12

Free sterols, % of total: 57.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from esters, % of total: 9.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from sterylglycosides, % of total: 15.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol*

Sterols from acylated sterylglycosides, % of total:

19.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Hyoscyamus muticus

Family: Solanaceae

Leaves and Stems

Components (from 2.0 kg dried mass), mg:

Tritriacontane – 2,500; 15-hydroxyheneicosanoic

acid – 100; sitosterol – 200; tritriacontan-3-one – 8.0;

Page 12: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 884 Hyoscyamus niger L.

pentatriacontan-3-one – 10.0; 3-hydroxytetra-

triacontan-3-one – 5.0

IR, MS

References

1. A. Goswami, Y.N. Shukla, R.S. Thakur, Phytochemistry 20,

1315 (1981)

Hyoscyamus niger L.

Family: Solanaceae

Seed

Oil, %: 30.0–35.3 [1]

d15: 0.9390

d20: 0.9294

n15D : 1.4788

n40D : 1.4702

Iodine value, % J2: 129.5–143.0

Saponification value, mg KOH: 170.8–190.3

FAs

Composition (GLC, 15% PEGS), %: 18:1 – 24.2;

18:2 – 64.1; others – 2.7 [2]

References

1. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

2. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 117 [in Russian]

Lycium barbarum L.

Synonyms

L. halimifolium Mill

Family: Solanaceae

Fruit

Essential Oil (hydrodistillation), % dry wt: 0.09

Composition (GC/MS, HP-Innowax FSC), %: Limo-

nene – 0.2; 1-octen-3-ol – 0.4; (E)-2-nonenal – 0.9;

linalool – 0.2; b-elemene – 5.4; safranal – 0.4;

methyl salicylate – 1.1; (E)-geranylacetone – 1.8;

(E)-b-ionone – 0.5; 2-pentadecanone – 1.3;

heneicosane – 0.2; ethyl hexadecanoate – 4.0;

selin-11-en-4a-ol – 0.3; farnesylacetone – 0.5;

dodecanoic acid – 1.5; ethyl linoleate – 2.5; ethyl

linolenate – 0.9; myristic acid – 4.2; nonacosane –

1.1;hexadecanoicacid–47.5; linoleicacid–9.1[1]

Leaf

Sterols, % dry wt: 0.20 [2]

Free sterols, % of total: 73.0

Components: Sitosterol, isofucosterol, campesterol,

stigmasterol

Sterols from esters, % of total: 18.0

Components: Sitosterol, isofucosterol, cholesterol,

campesterol

Sterols from sterylglycosides, % of total: 7.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total: 2.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

Seed

Oil, %: 40.0 [3]

Iodine value, % J2: 138.8

References

1. A. Altintas, M. Kirimer, K.H.C. Baser, B. Demirci, Chem.

Nat. Comp. 42, 24 (2006)

2. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

3. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

Lycium chinense Mill.

Family: Solanaceae

Seed

Triterpenols

Composition (Ag+ – PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – tr; lanosterol – tr;

Page 13: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Lycopersicon esculentum Mill. 885 Solanaceae

methylenelanost-8-en-3b-ol – tr; cycloartanol –

13.0; cycloartenol – 49.0; 24-methylenecy-

cartanol – 38.0; lupeol – tr; b-amyrin – tr [1]

IR, MS, 1H NMR [1]

4a-Methylsterols

Composition (Ag+-PLC, GLC, OV 17 SCOT, GC/

MS on 2% OV 17), %: 31-Norcycloartanol – tr;

31-norcycloartenol – 6.0; cycloeucalenol – 8.0;

31-norlanost-8-enol – 1.0; 31-norlanosterol –

1.0; obtusifoliol – 6.0; 31-norlanost-9(11)-enol

– 2.0; 4a-methylcholest-8-enol – tr; lophenol –

9.0; 24-methyllophenol – tr; 24-ethyllophenol –

2.0; gramisterol – 44.0; citrostadienol – 18.0; 4a-methyl-24-ethylcholesta-7,24-dienol – tr; others

– 3.0 [2]1H NMR [2]

References

1. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

2. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Lycium ruthenicum

Family: Solanaceae

Fruit

Essential Oil (hydrodistillation), % dry wt: 0.07

Composition (GC/MS, HP-Innowax FSC), %:

Hexadecane – 0.8; (E;E)-2;4-decadienal – 0.8;

(E)-geranylacetone – 1.1; heneicosane – 0.9;

hexahydrofarnesylacetone – 2.7; docosane –

1.5; methyl hexadecanoate – 4.5; ethyl

hexadecanoate – 5.8; tricosane – 2.5;

farnesylacetone – 4.6; tetracosane – 3.9; methyl

linoleate – 5.6; ethyl linoleate – 10.0;

hexacosane – 7.0; phytol – 3.0; heptacosane –

14.3; octacosane – 5.2; nonacosane – 6.2

References

1. A. Altintas, M. Kirimer, K.H. Baser, B. Demirci, Chem. Nat.

Comp. 42, 24 (2006)

Lycium turcomanicum Turez ex Miers.

Family: Solanaceae

Fruit

FAs

Composition (GLC, 17% PEGS), %: 12:0 – 0.9;

14:0 – 6.4; 15:0 – 0.9; 16:0 – 28.3; 16:1 – 14.2;

18:0 – 0.6; 18:1 – 10.5; 18:2 – 34.0; 18:3 – 3.1;

20:0 – 1.1

Seed

FAs

Composition (GLC, 17% PEGS), %: 14:0 – 0.4;

15:0 – tr; 16:0 – 10.5; 16:1 – 0.8; 18:0 – 2.8;

18:1 – 14.6; 18:2 – 66.9; 18:3 – 4.0

References

1. M. Aslanov, M.E. Mamedova, Chem. Nat. Comp. 22, 796

(1986)

Lycopersicon esculentum Mill.

Synonyms

Solanum lycopersicum L.

Family: Solanaceae

Fruit

Lipids (chloroform-methanol, as FA methyl esters),

mg/100 g fresh wt: 44.6–45.6 [1]

GL, mg/100 g fresh wt: 16.3–17.63 (as glucose and

galactose)

PhL, mg/100 g fresh wt: 1.8–1.87 (as phosphorus)

Carotene epoxides

Components (acetone, TLC, CC): Phytoene epox-

ide, z-carotene epoxide, lycopene-1,2-epoxide,

lycopene-5,6-epoxide, mutatochrome, apo-6-

lycopenal, apo-8-lycopenal, lycoxanthin, and

two phyto fluene epoxides (1,2-epoxy-

1,2,7,8,70,80,110,120-octahydro-C,C-carotene and

1,2-epoxy-1,2,7,8,11,12, 70,80-octahydro-C,

C-carotene) [2]

UV, MS [2]

Sterols, mg/100 g fresh wt: 9.14–9.42 [1]

Page 14: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 886 Lycopersicon esculentum Mill.

Flesh

Pigments

Components, nmol/g dry wt: Phytofluene – up to

219.0; lycophyll and lycoxanthin – up to 30.0;

lycopene – up to 2,530.0; b-carotene – 67.0–

209.0; lutein – 32.0–130.0; epoxy lutein – up to

16.0; violaxanthin and auroxanthin – 15.0–73.0;

neoxanthin – up to 27.0; chlorophyll a – up to –

1,455.0; chlorophyll b – up to 296.0; total –

350.0 – 3,021.0 (during growth and repining)

Composition, %: Phytofluene – up to 10.7;

lycophyll and lycoxanthin – up to 2.7; lycopene

– up to 82.9; b-carotene – 3.6–45.1; lutein – 1.1–12.6; epoxy lutein – up to 4.6; violaxanthin and

auroxanthin – 0.9–8.6; neoxanthin – up to 1.8;

chlorophyll a – up to 77.4; chlorophyll b – up to

22.9; total – 99.8–100 [3]

Pulp

Pigments

Components, nmol/g dry wt: Lycophyll and

lycoxanthin – up to 25.0; lycopene – up to

233.0; b-carotene – 67.0–236.0; lutein –

34.0–132.0; epoxy lutein – up to 13.0;

violaxanthin – 21.0–53.0; violaxanthin and

auroxanthin – 15.0–64.0; neoxanthin – 4.0–

36.0; chlorophyll a – tr – 1,455.0; chlorophyll

b – tr – 355.0; total – 290.0–1887.0 (during

growth and repining) [3]

Composition, %: Lycophyll and lycoxanthin – up to

4.4; lycopene – up to 40.9; b-carotene – 3.5–

48.3; lutein – 4.6–36.9; epoxy lutein – up to

4.5; violaxanthin – 1.5–2.8; violaxanthin and

auroxanthin – 1.3–9.3; neoxanthin – 0.3–3.1;

chlorophyll a – tr – 77.1; chlorophyll b – tr –

27.9; total – 99.8–100 [3]

Parenchymatous Tissue

Tocopherols, mg/g fresh wt: a – 0.5; g – 0.32 (whole

tissue) [4]

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 5.0; 18:0 – 3.0; 18:1 – 9.0; 18:2 – 16.0;

18:3 – 6.0; hydroxyl-18:1 – 45.0; hydroxyl-18:2

– 16.0 [5]

Leaf

FAs, % in total lipids: 16:3 (7Z,10Z,13Z) – 13.8 [6]

TAG

FAs (GLC, PE 800) %: 16:0 – 15.1; 16:1(7) +

16:1(9) – tr; 16:2(7,10) – 0.1; 16:3(7,10,13) –

1.6; 18:0 – 6.2; 18:1 – 10.4; 18:2 – 29.6; 18:3 –

37.0; total o – 3 FAs – 38.6 [6]

DAG

FAs, (GLC) %: 16:0 – 44.6; 16:1(7) + 16:1(9) – 0.1;

16:2(7,10) – 0.2; 16:3(7,10,13) – 22.7; 18:0 –

1.8; 18:1 – 1.6; 18:2 – 6.8; 18:3 – 22.2; totalo -3

FAs – 44.9 [6]

MGDG

FAs (GLC), %:16:0 – 2.4; 16:1(7) + 16:1(9) – 0.3;

16:2(7,10) – 0.7; 16:3(7,10,13) – 32.4; 18:0 –

0.3; 18:1 – 0.6; 18:2 – 4.4; 18:3 – 58.9; totalo – 3

FAs – 91.3 [6]

DGDG

FAs (GLC) %: 16:0 – 9.8; 16:1(7) + 16:1(9) – 0.2;

16:2(7,10) – 0.2; 16:3(7,10,13) – 3.3; 18:0 – 1.6;

18:1 – 2.4; 18:2 – 7.1; 18:3 – 75.4; totalo -3 FAs

– 78.7 [6]

PL

FAs (GLC) %: 16:0 – 21.8; 16:1(7) +1 6:1(9) – 0.5;

16:1(3E) – 3.4; 16:2(7,10) – 0.1; 16:3(7,10,13) –1.5; 18:0 – 1.8; 18:1 – 4.1; 18:2 – 34.0; 18:3 –

32.8; total o -3 FAs – 34.3 [6]

Sterols, % dry wt: 0.16 [7]

Free sterols, % of total: 10.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterol from esters, % of total: 8.0

Components: Sitosterol, cholesterol, campesterol,

24 – methylenecholesterol

Sterol from sterylglycosides, % of total: 26.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total:

56.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol (the sterols are listed in order of

decreasing concentration)

Pigments

Components, nmol/g dry wt: b-Carotene – 760.0;

lutein – 705.0; violaxanthin – 90.0; flavoxanthin

– 30.0; neoxanthin – 44.0; chlorophyll a –

11,109.0; chlorophyll b – 5,587.0; total –

19,917.0 (during growth and repining) [3]

Page 15: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Lycopersicon esculentum Mill. 887 Solanaceae

Composition, %: b-Carotene – 5.3; lutein – 4.9;

violaxanthin – 0.6; flavoxanthin – 0.2;

neoxanthin – 0.8; chlorophyll a – 61.8; chloro-

phyll b – 26.8; total – 99.9

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.53 (from chill-

sensitive leaves) [8]

Composition (GLC, 15% EGSS-X), %: 16:0 – 17.1;

16:1 – 6.1; 16:2 – tr; 18:0 – 1.5; 18:1 – 6.1; 18:2 –

9.7; 18:3 – 60.0

Seed

Oil, %: 18.0 [9]; 25.0–30.0 [10–12]

d1515 : 0.9184–0.930 [9, 11, 13, 14]

d25: 0.9184–0.9195 [9]

n25D : 1.4715–1.4794 [9, 11–14]

n40D : 1.4678 [9]

Hehner’s value, %: 96.0–96.5 [13, 14]

Iodine value of Oil, % J2: 109–125 [9, 11–14]

Saponification value, mg KOH: 171.0–197.0 [9,

11–14]

Unsaponifables, %: 0.8–1.4 [12]; 1.74–1.88 [11,

13]

Phosphatides, %: 0.886 [11]

FAs

Composition (GLC), %: 12:0 – 0.98; 13:0 – 0.19;

14:0 – 0.36 – 1.03; 15:0 – 0.36; 16:0 – 9.50 –

13.99; 16:1 – 0.96; 18:0 – 5.01 – 5.83; 18:1 –

31.7 – 22.77; 18:2 – 35.0 – 62.0; 18:3 – 0.8 – 2.5;

20:0 – tr – 2.5 [11–14]

16:0 – 16.26; 16:1 – 0.54; 17:0 – 0.26; 17:1 – 0.64;

18:0 – 5.13; 18:1 – 21.05; 18:2 – 52.06; 18:3 –

1.89; 20:0 – 0.40; 20:1 (11) – 0.29 (Silar 5CP)

[15]

Isomers of 16:1, %: 16:1 (9) – 73.6; 16:1 (7) – 15.9;

16:1 (11) – 10.5

Isomers of 18:1%: 18:1 (9) – 96.2; 18:1 (11) – 3.7;

18:1 (13) – 0.1

Isomers of 20:1, %: 20:1 (11) – 62.9; 20:1 (13) –

37.1

Carotenoids, %: 0.94 [11]

Tocopherols, mg %: 112–150 [11–13]

Composition of oil (CC), %: Hydrocarbons – 0.1–0.3;

b-carotene – tr; acylsterols – tr – 0.4; lycopene – tr;acetyltriterpenols with lycopene – tr; TAG with

lycopene – 80.7–90.9; tocopherols – tr; epoxy-

TAG – tr – 0.8; free FAs – 2.3–12.1; chlorophyll

a – tr; triterpenols – tr – 0.5; DAG with pheophytin

a – 4.3–6.3; free sterols – tr – 0.2; chlorophyll b with

pheophytin b – tr; MAG – 0.2–0.3; unidentified – tr

– 0.8 [10]

TAG

Main components (stereospecific analysis), %:

LPL – 1.2; OOO – 1.3; LOL – 6.6; PLP – 2.0;

OLO – 3.1; LLL – 15.2; PPL – 1.6; POO – 2.1;

POL – 8.2; OOL – 4.8; PLO – 5.1; PLL – 18.9;

OLL – 11.5; LOO – 1.7; OLP – 1.2; LLP – 1.6;

LLO – 3.9 [10]

Composition of TAG (HPLC), mol %: LeLL – 2.5;

LLL + LeLO – 23.6; LeLeP – 1.6; LLO – 17.5;

LLP – 18.7; LOO – 6.9; LLSt + LOP – 15.8; LPP

– 3.9; OOO – 1.7; LOSt + OOP – 3.3; LPSt +

OPP – 2.9; OOSt – 0.7; others – 0.9 [16]

SSS – 0.71; SSU – 3.56; SUS – 7.22; SUU – 36.88;

USU – 4.56; UUU – 47.07 [14]1H NMR [10]

Epoxy-TAG [10]

Usual epoxy-FAs (GLC, 17% PEGS); mol %: 12:0

– 2.3; 13:0 – 1.0; 14:0 – 1.4; 16:0 – 14.2; 16:1 –

2.3; 18:0 – 7.3; 18:1 – 22.3; 18:2 – 46.4; 18:3 –

2.8

Epoxy-FAs (TLC, GLC, 5% SE 30), %: trans-

Epoxy-18:0 – 5.9, cis-epoxy-18:0 – 16.7, 9,10-

epoxy-18:1(12Z) – 39.0, unidentified acids 1 –

15.9, unidentified acid 2 – 10.2, unidentified acid

3 – 8.4, unidentified acid 4 – 3.9

Free FAs

Composition (GLC), %: 14:0 – 0.1; 16:0 – 16.5;

16:1 – 0.6; 17:0 – 0.3; 18:0 – 5.6; 18:1 – 20.0;

18:2 – 55.3; 18:3 – 1.6 [10]

DAG1H NMR [10]

FAs (GLC, 17% PEGS), mol %: 12:0 – 0.8; 13:0 – 0.4;

14:0 – 0.4 16:0 – 9.5; 16:1 – 0.5; 18:0 – 2.5; 18:1 –

17.5; 18:2 – 67.7; 18:3 – 1.3 [10]

MAG1H NMR [10]

FAs (GLC, 17% PEGS), mol %: 10:0 – 1.4; 12:0 – 1.0;

14:0 – 0.6 16:0 – 12.9; 16:1 – 0.9; 17:0 – 0.9; 18:0 –

3.8; 18:1 – 21.9; 18:2 – 55.4; 18:3 – 1.2 [10]

Hydrocarbons:C29 – C33 [10]

MS [10]

Triterpenols

Components: a-and b-Amyrins (MS) [10]

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 5.0; lanosterol – tr;

Page 16: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 888 Lycopersicon hirsutum

methylenelanost-8-en-3b-ol – tr; cycloartanol –

55.0; cycloartenol – 38.0; 24-

methylenecycartanol – 1.0; lupeol – tr; b-amyrin

– tr; others – 1.0 [17]

IR, MS, 1H MR [10]

4a-Methylsterols

Composition (Ag+-PLC, GLC, OV 17 SCOT, GC/

MS, 2% OV 17), %: 31-norcycloartanol – 2.0;

31-norcycloartenol – 2.0; cycloeucalenol – 2.0;

31-norlanost-8-enol – 4.0; 31-norlanosterol –

8.0; obtusifoliol – 2.0; 31-norlanost-9(11)-enol

– tr; 4a-methylcholest-8-enol – 1.0; lophenol –

44.0; 24-methyllophenol – tr; 24-ethyllophenol –

tr; gramisterol – 8.0; citrostadienol – 23.0; 24-

ethylcholesta-7,24 – dienol – tr; others – 4.0 [18]1H PMR [18]

Sterols

Components (MS): b-Sitosterol (main),

campesterol and sterols with a molecular weight

of 386 and 412 [10]

Use: Food-stuffs [10–12].

References

1. M.J. Fishwick, A.J. Wright, Phytochemistry 16, 1507 (1977)

2. A. Ben-Aziz, G. Britton, T.W. Goodwin, Phytochemistry 12,

2759 (1973)

3. D.L. Martin, J. Quennemet, R. Moneger, Phytochemistry 14,

2357 (1975)

4. R.T. Newton, J.F. Pennock, Phytochemistry 10, 2323 (1971)

5. A. Koiwai, T. Matsuzaki, Phytochemistry, 27, 2827 (1988)

6. G.R. Jamieson, E.H. Reid, Phytochemistry, 10, 1837 (1971)

7. I.R. Duperon, M. Thiersault, P. Duperon, Phytochemistry

23, 743 (1984)

8. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28,

1813 (1989)

9. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

10. N.T. Ul’chenko, E.I. Gigienova, A.U. Umarov, Chem. Nat.

Comp. 19, 262 (1983)

11. V.D. Gioshvili, L.A. Tsulukidze, Masloboyno-jirovayapromyshlennost (1), 6 (1958) [in Russian]

12. A.D. Popov, I.D. Mitsev, Masloboyno-jirovayapromyshlennost, 35 (1965) [in Russian]

13. V.P. Rzhekhin, A.F. Sergeev (eds.), Handbook on Methodsof Investigation, Technical and Chemical Control, andAccounting of Production in the Oils and Fats Industry,vol. 5, Book 1 (VNIIZh (All-Union Scientific Research Insti-

tute of Oils and Fats), Leningrad, 1969), p. 11 [in Russian]

14. A.U. Umarov, A. L. Markman, N.T. Kisapova, Maslo-jirovaya promyshlennost 12 (1971) [in Russian]

15. Von A. Seher, U. Gundlach, Fette, Seifen, Anstrichmittel

84(9), 342 (1982)

16. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

17. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

18. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Lycopersicon hirsutum

Family: Solanaceae

Leaf

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.53 (from chill-

sensitive leaves), 0.42 (from chill-tolerant

leaves)

Composition (GLC, 15% EGSS-X), %: 16:0 – 16.1;

16:1 – 4.6; 16:2 – 2.5; 18:0 – 6.4; 18:1 – 6.1; 18:2

– 17.0; 18:3 – 47.1 (chill-sensitive)

16:0 – 8.8; 16:1 – 4.1; 16:2 – 4.9; 18:0 – 39.5; 18:1 –

7.5; 18:2 – 8.8; 18:3 – 26.3 (chill-tolerant)

References

1. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28, 1813

(1989)

Lycopersicon pennellii

Family: Solanaceae

Leaf

Trichomes

NL, %: 12.0

PL, %: 8.0

GL

Composition (HPLC, m-Bondapak C18)/ %: a-andb-Anomer of compound 1 – 16.0; a-and b-anomers of 2 and 3 – 25.0; b-anomer of 4 – 7.0;

a-and b anomer of 4 and 5 – 22.0; a-anomer of 5

– 8.0; b-anomer of 6 and 7 – 3.0; a-and b anomer

of 6 and 7, and 8 and 9 – 11.0; a-anomer of 8 and

9 – 4.0

IR, 1H NMR

Page 17: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Mandragora turcomanica Mizger. 889 Solanaceae

FAs

Composition (GC/MS, Silar 10C), %: 2-

Methylpropanoic – 41.4 � 3.3; 2-

methylbutanoic – 4.5 � 2.1; 3-methylbutanoic

– 4.1 � 0.7; 8-methylnonanoic – 31.6 � 2.3; n-decanoic – 10.4 � 1.2; 8-methyldecanoic – 1.2

� 0.3; 10-methylundecanoic – 0.8 � 0.1; n-modecanoic – 3.4 � 0.2

References

1. A. Burke, G. Goldsby, J.B. Mudd, Phytochemistry 26, 2567

(1987)

Lycopersicon peruvianum

Family: Solanaceae

Leaf

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.27 (from chill-

tolerant leaves)

Composition (GLC, 15% EGSS-X), %: 16:0 – 11.5;

16:1 – 3.5; 16:2 – tr; 18:0 – 5.0; 18:1 – 5.3; 18:2 –

29.1; 18:3 – 45.6

References

1. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28, 1813

(1989)

Mandragora turcomanica Mizger.

Family: Solanaceae

Fruit Flesh

Lipids, mg/g dry wt: 19.95 [1]

NL, mg/g dry wt: 18.30

GL, mg/g dry wt: 0.98

PhL, mg/g dry wt: 0.67

Composition of lipids, %: Hydrocarbons – 1.4; esters

of alkanols and sterols with FAs + methyl esters –

3.5; TAG – 64.5; alkanols – 1.9; free FAs – 10.5;

DAG – 2.8; sterols – 3.6; MAG – 3.6; steryl

glycoside esters – 0.1; MGDG – 1.5; steryl glyco-

sides – 2.5; DGDG – 0.3; PhL (PhE, PhC, PhI, PhA)

– 3.3

Esters of alkanols, triterpenols and sterols

[MS] [1]

FAs (GLC, 15% Reoplex 400), %: 12:0 – 1.5; 14:0 –

4.0; 15:0 – 1.8; 16:0 – 38.2; 16:1 – 4.5; 17:0 – 1.6;

18:0 – 18.5; 18:1 – 11.1; 18:2 – 7.1; 18:3 – tr; 20:0 –

10.5; 22:0 – 1.2 [1]

Alcohols

Composition (GLC, 5% SE-30), %: Alkanols C20 –

4.5; C22 – 9.6; C23 – 4.8; C24 – 20.4; C25 – 7.3;

C26 – 14.8; C27 – 2.0; C28 – 5.1; C30 – 0.1;

cholesterol and unidentified component – 2.8;

campesterol and lophenol – 13.2; stigmasterol –

0.1; b-sitosterol – 10.8; cycloartanol – 4.5 [1]

TAG

Main components (Coleman), mol %: OLL – 11.8;

LLL – 7.2; PLL – 9.1; OLO – 4.8; PLO – 7.4;

StLO – 2.7; StLO – 2.2; PLP – 2.9; StLP – 1.7;

OOL – 10.1; LOL – 6.2; POL – 7.8; OOO – 4.3;

POO – 6.4; StOL – 2.3; StOO – 1.9; StOP – 1.4

[2]

Composition, %: UUU – 47.7; SUU + UUS – 41.6;

USU – 0.8; SUS – 9.2; SSU + USS – 0.6; SSS –

0.1 [2]

FAs (GLC, 15% Reoplex 400), %: 12:0 – tr; 14:0 –

tr; 16:0 – 15.2; 16:1 – 0.6; 18:0 – 4.7; 18:1 – 35.7;

18:2 – 42.5; 18:3 – 1.3; 20:0 – tr [1]

Free FAs

Composition (GLC, 15% Reoplex 400), %: 12:0 –

tr; 14:0 – 0.6; 15:0 – 0.4; 16:0 – 23.4; 16:1 – 0.4;

17:0 – 1.5; 18:0 – 5.0; 18:1 – 27.1; 18:2 – 32.1;

18:3 – tr; 20:0 – 9.5 [1]

MGDG

FAs (GLC, 15% Reoplex 400), %: 14:0 – 0.5; 15:0

– tr; 16:0 – 37.7; 16:1 – 3.3; 17:0 – tr; 18:0 – 6.0;

18:1 – 21.2; 18:2 – 22.4; 18:3 – 8.9 [1]

DGDG

FAs (GLC, 15% Reoplex 400), %: 14:0 – 1.7; 15:0

– tr; 16:0 – 41.4; 16:1 – 5.7; 17:0 – tr; 18:0 – 9.9;

18:1 – 18.3; 18:2 – 19.2; 18:3 – 3.8 [1]

PhL

FAs (GLC, 15% Reoplex 400), %: 12:0 – tr; 14:0 –

2.0; 15:0 – tr; 16:0 – 37.2; 16:1 – 0.9; 17:0 – tr;

18:0 – 6.9; 18:1 – 44.3; 18:2 – 7.3; 18:3 – 1.4 [1]

Triterpenols

Components (MS): Cycloartanol, cycloartenol [1]

Page 18: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 890 Mandragora turcomanica Mizger.

4-a-Methylsterols

Components (MS): Lophenol [1]

Sterols

Components (TLC, MS): b-Sitosterol, stigmasterol,

campesterol, cholesterol [1]

Leaf

Lipids, mg/g dry wt: 46.0 (at flowering) [3]

Components of lipids (CC), %: NL – 43.8; GL –

46.2; PhL – 10.0

NL, mg/g dry wt: 20.15

FAs

Composition (GLC, 15% Reoplex 400), %: 14:0 –

1.7; 15:0 – 0.1; 16:0 – 33.5; 16:1 (9) – tr; 18:0 –

3.1; 18:1 – 6.0; 18:2 – 25.3; 18:3 – 30.3; 20:0 – tr

GL, mg/g dry wt: 21.25

FAs

Composition (GLC, 15% Reoplex 400), %: 12:0 –

0.1; 14:0 – 0.1; 15:0 – tr; 16:0 – 8.1; 16:1 (9) –

0.5; 16:3 (7Z; 10Z; 13Z) – 9.4; 18:0 – tr; 18:1 –

0.2; 18:2 – 3.5; 18:3 – 78.1

Hexadeca (7Z, 10Z, 13Z)-trienoic acid [3]

Ag+-TLC, MS

PhL, mg/g dry wt: 4.60

FAs

Composition (GLC, 15% Reoplex 400), %: 14:0 –

0.1; 15:0 – 0.1; 16:0 – 33.7; 16:1 (3E) – tr; 17:0 –

tr; 18:0 – 3.5; 18:1 – 6.0; 18:2 – 30.7; 18:3 – 25.9

Components of NL (TLC): Hydrocarbons, esters of

sterols and triterpenols with FAs, TAG, free

FAs, sterols, monomethylsterols, triterpenols,

MAG and DAG

GL

Composition (TLC), %: MGDG – 52.0; DGDG,

steryl glycosides, and SQDG – 48.0

PhL

Components (TLC), %: PhG, PhE, PhC, PhI, (main)

PhA (tr)

Pigments, % in lipids: Carotenes – 0.3; xanthophylls –

0.4; chlorophylls and pheophytenes – 5.9 [3]

Carotenes

Components (UV): a and b-Carotenes [3]Xanthophylls

Components (UV): Lutein (main) [3]

4-a-Methylsterols

Components (MS): Lophenol [3]

Seed

Lipids, mg/g dry wt: 221.02 [1]

NL, mg/g dry wt: 210.90

GL, mg/g dry wt: 3.25

PhL, mg/g dry wt: 6.87

Composition of lipids, %: Hydrocarbons – 0.2;

esters of alkanols and sterols with FAs + methyl

esters – 3.0; TAG – 85.5; alkanols – 2.0; free FAs

– 1.3; DAG – 1.9; sterols – 1.4; MAG – 0.5;

steryl glycoside esters – 0.2; MGDG – 0.1; steryl

glycosides – 1.4; DGDG – 0.1; PhL (PhE, PhC,

PhI, PhA) – 3.1

TAG

Main components (by Coleman), mol %: OLL –

28.0; LLL – 25.1; PLL – 10.0; OLO – 7.8; PLO

– 5.5; StLO – 2.4; StLO – 1.4; PLP – 1.0; OOL –

5.7; LOL – 5.1; POL – 2.0; OOO – 1.6; POO –

1.1 [2];

Composition, %: UUU – 74.8; SUU + UUS – 23.3;

USU – 0.4; SUS – 1.7 [2]

FAs (GLC, 15% Reoplex 400), %: 14:0 – tr; 16:0 –

6.8; 16:1 – 0.5; 18:0 – 1.8; 18:1 – 26.4; 18:2 –

64.5; 18:3 – tr; 20:0 – tr [1]

Free FAs

Composition (GLC, 15% Reoplex 400), %: 14:0 –

tr; 16:0 – 6.9; 16:1 – 0.3; 18:0 – 0.8; 18:1 – 17.6;

18:2 – 74.4 [1]

ESG

FAs (GLC), %: 14:0 – 0.7; 16:0 – 50.2; 16:1 – 3.7;

18:0 – 8.0; 18:1 – 22.7; 18:2 – 14.7; 18:3 – tr [1]

PhL

FAs (GLC), %: 14:0 – 0.8; 16:0 – 31.4; 16:1 – 0.6;

18:0 – 3.3; 18:1 – 25.8; 18:2 – 38.1; 18:3 – tr [1]

Tuberous Root

Lipids, mg/g dry wt: 36.0 [4]

NL, mg/g dry wt: 23.32

GL, mg/g dry wt: 10.10

PhL, mg/g dry wt: 2.58

Composition of lipids (CC), %: Hydrocarbons – 5.4;

esters of alkanols triterpenols and sterols – 3.9;

TAG – 20.7; oxo-TAG 0.1, free FAs – 8.9; high

molecular alcohols – 13.5; hydroxy TAG – 0.1;

1,2(1,3)-DAG – 0.6; triterpenols, methyl sterols

and sterols – 10.1; MAG – 1.4; sterylglycoside

esters – 5.7; MGDG – 11.9; sterylglycosides – 4.1;

DGDG – 6.4; PhL – 7.2

Esters of alkanols, triterpenols and sterols with FAs

Composition, %: Saturated (C38-52 – H76-104 O2) and

unsaturated (C42H82O2, C44H86O2, – C46H90-

88O2 and C48H94-92O2) wax esters esters of

Page 19: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicandra physalodes (L.) Gaerth. 891 Solanaceae

b-sitosterol, stigmasterol, campesterol, choles-

terol, lophenol, a and b-amyrin, cycloartenol

and 24-methylenecycloartenol [4]

FAs(GLC), %: 14:0 – 1.3; 16:0 – 35.6; 16:1 – 3.3;

17:0 – tr; 18:0 – 7.2; 18:1 – 37.6; 18:2 – 4.4; 20:0

– 5.7; 21:0 – 1.9; 22:0 – 3.0

TAG

MS [5]

Main components (Coleman), %: LOO – 20.5; LOL

– 17.8; LOP – 8.0; LOLe – 6.0; LOSt – 4.2;

LOPo + LPoO – 1.4; OLA – 1.3; OOO – 6.2;

OOP – 3.8; OOLe – 2.0; OOSt – 1.9; LeOP – 1.4;

POP – 1.4; POSt – 1.0; OLL – 2.1; LLL – 1.8;

OStL – 1.5; LStL – 1.2; OPL – 2.6; LPL – 2.2;

LPP – 1.2; LPLe – 1.0; [5]

Composition, %: SUU + SUU – 24.6; USU – 10.3;

SUS – 3.0; SSS – 2.4; UUU – 59.7 [5]

FAs (GLC, 15% Reoplex 400), mol %: 14:0 – 0.2;

15:0 – 0.4; 16:0 – 9.3; 16:1 – 0.9; 17:0 – 0.5; 17:1

– 0.2; 18:0 – 4.4; 18:1 – 43.7; 18:2 – 33.8; 18:3 –

5.5; 19:0 – tr; 20:0 – 1.1; 20:1 – tr [5]

Free FAs

Composition (GLC, 15% Reoplex 400), %: 14:0 –

0.4; 15:0 – 0.2; 16:0 – 46.2; 16:1 – 1.8; 17:0 –

1.7; 17:1 – 0.9; 18:0 – 8.8; 19:0 – tr; 18:1 – 16.2;

18:2 – 19.3; 18:3 – 3.1; 20:0 – 1.4 [4]

DAG

FAs (GLC), %: 14:0 – 1.0; 15:0 – tr; 16:0 – 28.3;

16:1 – 1.8; 17:0 – 0.3; 17:1 – 0.7; 18:0 – 10.6;

18:1 – 35.1; 18:2 – 20.0; 18:3 – 1.2; 20:0 – 1.0 [4]

MAG

FAs (GLC), %: 14:0 – 1.0; 15:0 – 0.9; 16:0 – 23.4;

16:1 – 1.8; 17:0 – 0.4; 17:1 – 1.4; 18:0 – 10.2;

18:1 – 33.6; 18:2 – 22.7; 18:3 – 4.6; 20:0 – tr [4]

ESG

FAs (GLC), %: 14:0 – 1.4; 15:0 – 2.1; 16:0 – 44.0;

16:1 – 3.9; 17:0 – tr; 17:1 – 0.8; 18:0 – 5.5; 18:1 –

32.3; 18:2 – 4.5; 18:3 – tr; 20:0 – 5.5 [4]

MGDG

FAs (GLC), %: 14:0 – 1.3; 15:0 – tr; 16:0 – 32.1;

16:1 – 3.7; 17:0 – tr; 17:1 – 2.7; 18:0 – 11.8; 18:1

– 12.0; 18:2 – 31.6; 18:3 – 4.8; 20:0 – tr [4]

DGDG

FAs (GLC), %: 14:0 – 2.9; 15:0 – tr; 16:0 –

37.8; 16:1 – 2.3; 17:0 – 1.2; 17:1 – 2.7;

18:0 – 8.9; 18:1 – 12.9; 18:2 – 27.8; 18:3 – 3.5;

20:0 – tr [4]

PhL

Components (TLC): PhE, PhC, PhI, PhA [4]

FAs (GLC), %: 14:0 – 0.4; 15:0 – tr; 16:0 – 26.3;

16:1 – tr; 17:0 – tr; 18:0 – 4.8; 18:1 – 19.7; 18:2 –

46.9; 18:3 – 1.9

Hydrocarbons

Components (TLC, UV,MS):Monoenic, dienic and

trienic C21-C33 and only odd saturated C27-C33

hydrogenes, and alkylbenzenes

Alkanols

Components (MS): C20-C30 (as free and esters with

FAs) [4]

Free sterols

Composition (GLC, 5% SE-30, Ag+-TLC), %:

Cholesterol – 4.3; campesterol and lophenol –

9.7; stigmasterol and cycloartanol – 13.5;

b-sitosterol – 15.5; b-amyrin + gramisterol – 6.2;

cycloartenol – 25.8; 25-methylenecycloartanol –

15.5; citrostadienol – 9.5 [4]

References

1. D.T. Asilbekova, A.I. Glushenkova, Chem. Nat. Comp. 34,

664 (1998)

2. D.T. Asilbekova, A.I. Glushenkova, Chem. Nat. Comp. 35,

291 (1999)

3. D.T. Asilbekova, H.R. Nuriddinov, A.M. Nigmatullaev, E.T.

Akhmedov, Past. Resursy (2), 61 (2004) [in Russian]

4. D.T. Asilbekova, C.D. Gusakova, Y.M. Murdakhaev, A.I.

Glushenkova, Chem. Nat. Comp. 30, 566 (1994)

5. C.D. Gusakova, D.T. Asilbekova, Chem. Nat. Comp. 33, 441

(1997)

Nicandra physalodes (L.) Gaerth.

Family: Solanaceae

Leaf

Sterols % dry wt: 0.11 [1]

Free sterols, % of total: 54.0

Components: Sitosterol, campesterol, stigmasterol,

cholesterol

Sterols from esters, % of total: 15.0

Components: Campesterol, sitosterol, cholesterol,

stigmasterol

Sterols from sterylglycosides, % of total: 22.0

Components: Sitosterol, campesterol, Cholesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total: 9.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

Page 20: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 892 Nicotiana acuminatum

Seed

Oil, %: 21.0–24.0 [2]

Acid value, mg KOH: 1.8

Iodine value, % J2: 127.0–138.0

Saponification value, mg KOH: 187.5

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

2. N. I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

Nicotiana acuminatum

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 1.0; 18:0 – tr; 18:1 – 13.0; 18:2 – 6.0;

18:3 – 3.0; hydroxy-18:1 – 46.0; hydroxyl-18:2 –

31.0 [1]

Leaf

FAs, mg/g dry wt: 34.8 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.2; 16:1

– 6.8; 16:3 – 4.2; 18:0 – 2.5; 18:1 – 1.1; 18:2 –

13.5; 18:3 – 56.7

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30–anteiso-C33 [3]

Main compounds: n-C29, anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 353.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.7; 18:0

– 1.4; 18:1 – 13.3; 18:2 – 76.7; 18:3 – 0.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana affinis

Family: Solanaceae

Seed

Ash, %: 4.0

Mass of 1,000, g: 0.1

Oil, % dry wt: 39.2

HBr uptake, as C18 acid, % 4.8

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Nicotiana africana

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 29.4 [1]

Composition (GLC, 5% BDS), %: 16:0 – 17.5; 16:1

– 7.0; 16:3 – 5.1; 18:0 – 2.1; 18:1 – 3.7; 18:2 –

11.1; 18:3 – 53.5

Alkanes (GC): n-C27 – n-C33 iso-C29 - iso-C33,

anteiso-C30 – anteiso-C33 [2]

Main compounds: n-C29, n-C31, anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 285.0 [1]

Composition (GLC, 5%DEGS), %: 16:0 – 7.1; 18:0

– 2.7; 18:1 – 20.9; 18:2 – 64.6; 18:3 – 4.7

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

2. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana alata

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 17.0; 18:2 – 35.0;

Page 21: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana attenuata 893 Solanaceae

18:3 – 6.0; hydroxy-18:1 – 13.0; hydroxy-18:2 –

25.0 [1]

Leaf

FAs, mg/g dry wt: 33.7 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.4; 16:1

– 6.1; 16:3 – 5.2; 18:0 – 3.0; 18:1 – 1.0; 18:2 –

12.2; 18:3 – 57.1

Alkanes (GC):): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C31, iso-C31, anteiso-C32

(>10%)

Seed

FAs, mg/g dry wt: 303.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 6.8; 18:0

– 4.0; 18:1 – 9.9; 18:2 – 76.9; 18:3 – 2.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana amplexicaulis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 29.0; 18:2 – 5.0; 18:3 –

7.0; hydroxy-18:1 – 49.0; hydroxy-18:2 – 7.0 [1]

Leaf

FAs, mg/g dry wt: 27.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.8; 16:1

– 6.3; 16:3 – 4.4; 18:0 – 3.0; 18:1 – 1.7; 18:2 –

5.0; 18:3 – 62.8

Seed

FAs, mg/g dry wt: 316.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.8; 18:0

– 3.5; 18:1 – 19.5; 18:2 – 44.6; 18:3 – 22.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana arentsii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 + 18:1 – 26.0; 18:2 – 15.0; 18:3 – 2.0;

hydroxy-18:1 – 36.0; hydroxy-18:2 – 20.0 [1]

Leaf

FAs, mg/g dry wt: 41.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.3; 16:1

– 6.0; 16:3 – 4.1; 18:0 – 2.2; 18:1 – 2.7; 18:2 –

11.8; 18:3 – 58.9

Seed

FAs, mg/g dry wt: 287.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.0; 18:0

– 2.1; 18:1 – 11.7; 18:2 – 76.2; 18:3 – 1.0

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana attenuata

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 + 18:1 – 22.0; 18:2 – 8.0; 18:3 – 4.0;

hydroxy-18:1 – 50.0; hydroxy-18:2 – 14.0 [1]

Page 22: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 894 Nicotiana benavidesii

Leaf

FAs, mg/g dry wt: 31.5 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.9; 16:1

– 6.3; 16:3 – 5.0; 18:0 – 2.7; 18:1 – 1.1; 18:2 –

13.7; 18:3 – 56.3

Seed

FAs, mg/g dry wt: 404.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.1; 18:0

– 1.9; 18:1 – 14.3; 18:2 – 76.2; 18:3 – 0.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana benavidesii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – 1.0; 18:1 – 18.0; 18:2 – 6.0; 18:3 –

2.0; hydroxy-18:1 – 49.0; hydroxy-18:2 –

21.0 [1]

Leaf

FAs, mg/g dry wt: 27.5 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.3; 16:1

– 5.9; 16:3 – 4.1; 18:0 – 2.0; 18:1 – 1.9; 18:2 –

8.5; 18:3 – 60.3

Seed

FAs, mg/g dry wt: 322.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.6; 18:0

– 2.7; 18:1 – 13.5; 18:2 – 75.3; 18:3 – 0.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana benthamiana

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 44.1

Composition (GLC, 5% BDS), %: 16:0 – 16.4; 16:1

– 6.8; 16:3 – 4.9; 18:0 – 2.8; 18:1 – 2.8; 18:2 –

5.7; 18:3 – 60.6

Seed

FAs, mg/g dry wt: 393.0

Composition (GLC, 5% DEGS), %: 16:0 – 12.2;

18:0 – 2.6; 18:1 – 17.5; 18:2 – 66.1; 18:3 – 1.6

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana bigelovii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 26.0; 18:2 – 5.0; 18:3 – 2.0;

hydroxy-18:1 – 54.0; hydroxy-18:2 – 12.0 [1]

Leaf

FAs, mg/g dry wt: 35.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.4; 16:1

– 6.0; 16:3 – 4.8; 18:0 – 1.8; 18:1 – 2.0; 18:2 –

11.4; 18:3 – 58.6

Seed

FAs, mg/g dry wt: 381.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.2; 18:0

– 1.7; 18:1 – 12.6; 18:2 – 76.9; 18:3 – 0.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Page 23: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana cordifolia 895 Solanaceae

Nicotiana bonariensis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 1.0; 18:0 – tr; 18:1 – 15.0; 18:2 – 20.0;

18:3 – 2.0; hydroxy-18:1 – 28.0; hydroxy-18:2 –

34.0 [1]

Leaf

FAs, mg/g dry wt: 30.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.5; 16:1

– 4.3; 16:3 – 5.6; 18:0 – 2.6; 18:1 – 0.7; 18:2 –

11.7; 18:3 – 59.6

Seed

FAs, mg/g dry wt: 287.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.1; 18:0

– 3.4; 18:1 – 9.6; 18:2 – 76.9; 18:3 – 2.0

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana cavicola

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – 1.0; 18:1 – 21.0; 18:2 – 5.0; 18:3 –

6.0; hydroxy-18:1 – 54.0; hydroxy-18:2 – 10.0 [1]

Leaf

FAs, mg/g dry wt: 44.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.8; 16:1

– 5.8; 16:3 – 7.7; 18:0 – 3.8; 18:1 – 1.3; 18:2 –

9.0; 18:3 – 56.6

Seed

FAs, mg/g dry wt: 316.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.9; 18:0

– 2.8; 18:1 – 19.2; 18:2 – 58.4; 18:3 – 10.7

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana clevelandii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 6.0; 18:0 – 1.0; 18:1 – 20.0; 18:2 – 11.0; 18:3 –

10.0; hydroxy-18:1 – 42.0; hydroxy-18:2 – 10.0 [1]

Leaf

FAs, mg/g dry wt: 33.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.5; 16:1

– 7.3; 16:3 – 5.8; 18:0 – 3.0; 18:1 – 1.2; 18:2 –

13.0; 18:3 – 52.2

Seed

FAs, mg/g dry wt: 349.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.9; 18:0

– 3.1; 18:1 – 12.3; 18:2 – 73.8; 18:3 – 0.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana cordifolia

Family: Solanaceae

Seed

FAs, mg/g dry wt: 352.0

Composition (GLC, 5%DEGS), %: 16:0 – 8.2; 18:0

– 2.2; 18:1 – 15.1; 18:2 – 73.4; 18:3 – 1.1

Page 24: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 896 Nicotiana corymbosa

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry, 22, 1409 (1983)

Nicotiana corymbosa

Family: Solanaceae

Flower

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 14.0; 18:2 – 7.0; 18:3 –

5.0; hydroxy-18:1 – 49.0; hydroxy-18:2 –

22.0 [1]

Leaf

FAs, mg/g dry wt: 28.7 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.5; 16:1

– 2.2; 16:3 – 4.6; 18:0 – 1.7; 18:1 – 1.5; 18:2 –

14.1; 18:3 – 60.4

Seed

FAs, mg/g dry wt: 356.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.6; 18:0

– 1.6; 18:1 – 14.7; 18:2 – 72.7; 18:3 – 1.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana debneyi

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 4.0; 18:0 – 1.0; 18:1 – 22.0; 18:2 – 10.0;

18:3 – 5.0; hydroxy-18:1 – 43.0; hydroxy-18:2 –

15.0 [1]

Leaf

FAs, mg/g dry wt: 41.2 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.0; 16:1

– 7.0; 16:3 – 5.2; 18:0 – 3.0; 18:1 – 1.0; 18:2 –

8.7; 18:3 – 58.1

Seed

FAs, mg/g dry wt: 315.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.8; 18:0

– 3.1; 18:1 – 14.0; 18:2 – 59.1; 18:3 – 14.0

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C31, n-C33,iso-C31, anteiso-C32

(>10%)

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry, 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana excelsior

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 28.0; 18:2 – 4.0; 18:3 –

2.0; hydroxy-18:1 – 58.0; hydroxy-18:2 – 7.0 [1]

Leaf

FAs, mg/g dry wt: 30.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.5; 16:1

– 7.3; 16:3 – 7.1; 18:0 – 3.5; 18:1 – 1.4; 18:2 –

6.3; 18:3 – 56.9

Seed

FAs, mg/g dry wt: 328.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.9; 18:0

– 3.0; 18:1 – 18.5; 18:2 – 44.5; 18:3 – 24.1

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Page 25: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana glauca 897 Solanaceae

Nicotiana exigua

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 5.0; 18:0 – 1.0; 18:1 – 18.0; 18:2 – 4.0; 18:3 –

7.0; hydroxy-18:1 – 57.0; hydroxy-18:2 – 8.0 [1]

Leaf

FAs, mg/g dry wt: 22.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.7; 16:1

– 6.7; 16:3 – 7.7; 18:0 – 1.9; 18:1 – 1.7; 18:2 –

11.4; 18:3 – 54.9

Seed

FAs, mg/g dry wt: 320.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.4; 18:0

– 3.1; 18:1 – 15.8; 18:2 – 45.0; 18:3 – 26.7

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana forgetiana

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 18.0; 18:2 – 26.0; 18:3 –

2.0; hydroxy-18:1 – 23.0; hydroxy-18:2 – 30.0 [1]

Leaf

FAs, mg/g dry wt: 26.5 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.6; 16:1

– 5.8; 16:3 – 4.5; 18:0 – 2.9; 18:1 – 2.0; 18:2 –

11.8; 18:3 – 57.4

Seed

FAs, mg/g dry wt: 323.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 6.7;

18:0 – 3.4; 18:1 – 10.7; 18:2 – 77.0; 18:3 – 2.2

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana fragrance

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 4.0; 18:0 – 1.0; 18:1 – 18.0; 18:2 – 6.0; 18:3 –

4.0; hydroxy-18:1 – 58.0; hydroxy-18:2 – 9.0 [1]

Leaf

FAs, mg/g dry wt: 28.4 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.4; 16:1

– 7.1; 16:3 – 5.9; 18:0 – 2.5; 18:1 – 1.8; 18:2 –

10.6; 18:3 – 55.7

Seed

FAs, mg/g dry wt: 259.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.0;

18:0 – 3.8; 18:1 – 11.7; 18:2 – 57.8; 18:3 – 16.7

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana glauca

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 26.0; 18:2 – 9.0;

18:3 – 3.0; hydroxy-18:1 – 45.0; hydroxy-18:2 –

13.0 [1]

Page 26: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 898 Nicotiana glutinosa

Leaf

FAs, mg/g dry wt: 42.8 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.8; 16:1

– 6.8; 16:3 – 7.4; 18:0 – 1.7; 18:1 – 1.8; 18:2 –

17.3; 18:3 – 50.2

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C31 (>10%)

Seed

FAs, mg/g dry wt: 362.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.8;

18:0 – 2.3; 18:1 – 14.5; 18:2 – 70.0; 18:3 – 2.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana glutinosa

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 5.0; 18:0 – 2.0; 18:1 – 16.0; 18:2 – 9.0; 18:3 –

9.0; hydroxy-18:1 – 45.0; hydroxy-18:2 – 14.0 [1]

Leaf

FAs, mg/g dry wt: 32.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.1; 16:1

– 7.4; 16:3 – 6.3; 18:0 – 1.8; 18:1 – 0.9; 18:2 –

8.9; 18:3 – 58.6

Seed

FAs, mg/g dry wt: 328.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.5;

18:0 – 2.7; 18:1 – 16.2; 18:2 – 70.2; 18:3 – 0.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana goodspeedii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1); %: 16:0

– 2.0; 18:0 + 18:1– 10.0; 18:2 – 2.0; 18:3 – 3.0;

hydroxy-18:1 – 76.0; hydroxy-18:2 – 7.0 [1]

Leaf

FAs, mg/g dry wt: 35.6 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.6; 16:1

– 4.5; 16:3 – 2.6; 18:0 – 4.3; 18:1 – 2.1; 18:2 –

18.8; 18:3 – 50.1

Seed

FAs, mg/g dry wt: 298.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.1;

18:0 – 3.3; 18:1 – 20.0; 18:2 – 33.3; 18:3 – 33.3

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana gossei

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 16.0; 18:2 – 2.0; 18:3 –

2.0; hydroxy-18:1 – 71.0; hydroxy-18:2 – 8.0 [1]

Leaf

FAs, mg/g dry wt: 31.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 18.5; 16:1

– 4.8; 16:3 – 4.2; 18:0 – 3.6; 18:1 – 1.6; 18:2 –

10.2; 18:3 – 57.1

Seed

FAs, mg/g dry wt: 334.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.5; 18:0

– 3.2; 18:1 – 21.2; 18:2 – 44.0; 18:3 – 22.1

Page 27: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana kawakamii 899 Solanaceae

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana hesperis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 7.0; 18:0 – 1.0; 18:1 – 14.0; 18:2 – 7.0;

18:3 – 11.0; hydroxy-18:1 – 46.0; hydroxy-18:2 –

14.0 [1]

Leaf

FAs, mg/g dry wt: 35.7 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.7; 16:1

– 5.8; 16:3 – 4.3; 18:0 – 3.2; 18:1 – 1.7; 18:2 –

12.2; 18:3 – 56.1

Seed

FAs, mg/g dry wt: 287.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.5;

18:0 – 2.5; 18:1 – 17.0; 18:2 – 51.5; 18:3 – 18.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana ingulba

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – tr; 18:1 – 11.0; 18:2 – 2.0; 18:3 –

4.0; hydroxy-18:1 – 74.0; hydroxy-18:2 – 7.0 [1]

Leaves

FAs, mg/g dry wt: 31.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 18.2; 16:1

– 6.3; 16:3 – 4.3; 18:0 – 3.3; 18:1 – 1.3; 18:2 –

7.7; 18:3 – 58.9

Seed

FAs, mg/g dry wt: 268.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 –

11.4; 18:0 – 2.5; 18:1 – 13.9; 18:2 – 62.7;

18:3 – 9.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana kawakamii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 4.0; 18:0 – 1.0; 18:1 – 35.0; 18:2 – 11.0;

18:3 – 5.0; hydroxy-18:1 – 33.0; hydroxy-18:2 –

11.0 [1]

Leaves

FAs, mg/g dry wt: 43.5 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.0; 16:1

– 7.1; 16:3 – 5.5; 18:0 – 2.4; 18:1 – 1.7; 18:2 –

11.6; 18:3 – 55.7

Seed

FAs, mg/g dry wt: 355.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.7; 18:0

– 2.0; 18:1 – 13.9; 18:2 – 74.9; 18:3 – 0.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Page 28: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 900 Nicotiana knightiana

Nicotiana knightiana

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 38.8 [1]

Composition (GLC, 5% BDS), %: 16:0 – 16.1; 16:1

– 6.9; 16:3 – 6.5; 18:0 – 2.4; 18:1 – 2.8; 18:2 –

8.4; 18:3 – 56.9

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [2]

Main compounds: n-C31, n-C33, iso-C29, iso-C31,

anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 307.0 [1]

Composition (GLC, 5%DEGS), %: 16:0 – 9.7; 18:0

– 2.4; 18:1 – 13.1; 18:2 – 73.9; 18:3 – 0.9

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

2. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana langsdorffii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 19.0; 18:2 – 27.0; 18:3 –

6.0; hydroxy-18:1 – 10.0; hydroxy-18:2 – 25.5

[1]

Leaf

FAs, mg/g dry wt: 35.2 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.2; 16:1

– 6.4; 16:3 – 5.6; 18:0 – 2.8; 18:1 – 0.8; 18:2 –

10.1; 18:3 – 59.1

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C31, n-C33, iso-C31, iso-C33

(>10%)

Seed

FAs, mg/g dry wt: 293.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.1; 18:0

– 2.8; 18:1 – 11.6; 18:2 – 75.7; 18:3 – 1.8

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana linearis

Family: Solanaceae

Seed

FAs, mg/g dry wt: 391.0

Composition (GLC, 5%DEGS), %: 16:0 – 7.9; 18:0

– 1.7; 18:1 – 15.7; 18:2 – 74.1; 18:3 – 0.6

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana longiflora

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 28.7 [1]

Composition (GLC, 5% BDS), %: 16:0 – 17.2; 16:1

– 4.4; 16:3 – 6.3; 18:0 – 3.3; 18:1 – 1.6; 18:2 –

13.4; 18:3 – 53.8

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [2]

Main compounds: n-C29, n-C31, n-C33, iso-C31

(>10%)

Seed

FAs, mg/g dry wt: 359.0 [1]

Composition (GLC, 5% DEGS), %: 16:0 – 8.5;

18:0 – 3.0; 18:1 – 11.4; 18:2 – 75.0; 18:3 – 2.1

Page 29: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana nesophila 901 Solanaceae

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

2. V. Koiwai, U. Brummer, C. Paulsen, F. Seehofer, Phytochem-

istry 22, 133 (1983)

Nicotiana maritima

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 4.0; 18:0 – tr; 18:1 – 20.0; 18:2 – 4.0; 18:3 –

5.0; hydroxy-18:1 – 59.0; hydroxy-18:2 – 8.0 [1]

Leaves

FAs, mg/g dry wt: 31.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 18.0; 16:1

– 5.4; 16:3 – 4.1; 18:0 – 3.8; 18:1 – 1.6; 18:2 –

9.7; 18:3 – 57.4

Seed

FAs, mg/g dry wt: 312.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.1; 18:0

– 2.6; 18:1 – 18.8; 18:2 – 31.1; 18:3 – 38.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana megalosiphon

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 21.0; 18:2 – 3.0; 18:3 –

4.0; hydroxy-18:1 – 64.0; hydroxy-18:2 – 5.0 [1]

Leaf

FAs, mg/g dry wt: 31.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 18.6; 16:1

– 5.8; 16:3 – 3.6; 18:0 – 3.2; 18:1 – 1.5; 18:2 –

10.2; 18:3 – 57.1

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33;

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C29, n-C31, n-C33, iso-C31,

anteiso-C30, anteiso-C32 (>10%)

Seed

FAs, mg/g dry wt: 330.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.4;

18:0 – 2.5; 18:1 – 14.4; 18:2 – 64.8; 18:3 – 7.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana miersii

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 33.5

Composition (GLC, 5% BDS), %: 16:0 – 14.8; 16:1

– 6.7; 16:3 – 5.6; 18:0 – 2.2; 18:1 – 1.0; 18:2 –

14.1; 18:3 – 55.6

Seed

FAs, mg/g dry wt: 361.0

Composition (GLC, 5%DEGS), %: 16:0 – 9.9; 18:0

– 1.9; 18:1 – 11.4; 18:2 – 76.0; 18:3 – 0.8

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana nesophila

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 4.0; 18:0 – 1.0; 18:1 – 7.0; 18:2 – 5.0;

Page 30: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 902 Nicotiana noctiflora

18:3 – 5.0; hydroxy-18:1 – 64.0; hydroxy-18:2 –

14.0 [1]

Seed

FAs, mg/g dry wt: 305.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 –

10.0; 18:0 – 4.6; 18:1 – 10.3; 18:2 – 70.2;

18:3 – 4.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana noctiflora

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 40.5

Composition (GLC, 5% BDS), %: 16:0 – 16.4; 16:1

– 5.7; 16:3 – 6.2; 18:0 – 2.9; 18:1 – 1.7; 18:2 –

13.1; 18:3 – 54.0

Seed

FAs, mg/g dry wt: 361.0

Composition (GLC, 5%DEGS), %: 16:0 – 8.2; 18:0

– 3.0; 18:1 – 20.0; 18:2 – 45.4; 18:3 – 23.4

Steryl esters, % total FAs: 7.4 (as FAs)

FAs(GLC, 5% DEGS), %: 16:0 – 1.0; 18:0 – 0.3;

18:1 – 1.2; 18:2 – 3.6; 18:3 – 1.3

TAG, % total FAs: 72.5 (as FAs)

FAs(GLC), %: 16:0 – 6.2; 18:0 – 2.0; 18:1 – 14.0;

18:2 – 32.8; 18:3 – 17.5

DAG, % total FAs: 8.2 (as FAs)

FAs(GLC), %: 16:0 – 1.1; 18:0 – 0.8; 18:1 – 1.4;

18:2 – 3.4; 18:3 – 1.5

PL, % total FAs: 11.9 (as FAs)

FAs(GLC), %: 16:0 – 2.7; 18:0 – 0.8; 18:1 – 1.9;

18:2 – 4.7; 18:3 – 1.8

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana nudicaulis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 25.0; 18:2 – 12.0;

18:3 – 5.0; hydroxy-18:1 – 39.0; hydroxy-18:2 –

15.0 [1]

Leaves

FAs, mg/g dry wt: 35.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.0; 16:1

– 7.2; 16:3 – 7.2; 18:0 – 2.2; 18:1 – 1.2; 18:2 –

12.7; 18:3 – 52.5

Seed

FAs, mg/g dry wt: 321.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.9; 18:0

– 2.9; 18:1 – 12.9; 18:2 – 71.3; 18:3 – 5.0

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana occidentalis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 4.0; 18:0 – 1.0; 18:1 – 23.0; 18:2 – 6.0;

18:3 – 8.0; hydroxy-18:1 – 49.0; hydroxy-18:2 –

10.0 [1]

Leaves

FAs, mg/g dry wt: 29.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.6; 16:1

– 5.3; 16:3 – 4.7; 18:0 – 2.9; 18:1 – 1.7; 18:2 –

12.2; 18:3 – 55.6

Page 31: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana pauciflora 903 Solanaceae

Seed

FAs, mg/g dry wt: 339.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 11.0;

18:0 – 2.3; 18:1 – 16.9; 18:2 – 64.7; 18:3 – 2.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana otophora

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – 1.0; 18:1 – 41.0; 18:2 – 5.0; 18:3 –

4.0; hydroxy-18:1 – 41.0; hydroxy-18:2 – 5.0 [1]

Leaves

FAs, mg/g dry wt: 36.4 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.8; 16:1

– 2.7; 16:3 – 5.2; 18:0 – 2.6; 18:1 – 1.3; 18:2 –

10.0; 18:3 – 63.4

Seed

FAs, mg/g dry wt: 304.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.6;

18:0 – 1.7; 18:1 – 12.5; 18:2 – 74.6; 18:3 – 0.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana paniculata

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 2.0; 18:0 – 1.0; 18:1 – 46.0; 18:2 – 10.0;

18:3 – 3.0; hydroxy-18:1 – 30.0; hydroxy-18:2 –

8.0 [1]

Leaf

FAs, mg/g dry wt: 35.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.1; 16:1

– 7.0; 16:3 – 6.0; 18:0 – 2.7; 18:1 – 2.8; 18:2 –

8.0; 18:3 – 56.4

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C31, iso-C29, iso-C31, and

anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 316.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.2;

18:0 – 2.7; 18:1 – 15.6; 18:2 – 70.3; 18:3 – 1.2

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana pauciflora

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FA

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 17.0; 18:2 – 6.0; 18:3 – 2.0;

hydroxy-18:1 – 50.0; hydroxy-18:2 – 24.0 [1]

Leaf

FAs, mg/g dry wt: 30.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.0; 16:1

– 4.6; 16:3 – 3.1; 18:0 – 2.2; 18:1 – 1.3; 18:2 –

17.1; 18:3 – 57.7

Seed

FAs, mg/g dry wt: 366.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.5; 18:0

– 1.5; 18:1 – 14.3; 18:2 – 74.7; 18:3 – 1.0

Page 32: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 904 Nicotiana petunioides

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana petunioides

Family: Solanaceae

Seed

FAs, mg/g dry wt: 396.0

Composition (GLC, 5%DEGS), %: 16:0 – 8.6; 18:0

– 2.6; 18:1 – 17.4; 18:2 – 70.3; 18:3 – 1.1

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana plumbaginifolia

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 10.0; 18:2 – 9.0;

18:3 – 3.0; hydroxy-18:1 – 51.0; hydroxy-18:2 –

23.0 [1]

Leaves

FAs, mg/g dry wt: 38.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.4; 16:1

– 6.6; 16:3 – 6.7; 18:0 – 2.3; 18:1 – 2.4; 18:2 –

15.2; 18:3 – 51.4

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30, anteiso-C33 [3]

Main compounds: -n-C29, C31 (>10%)

Seed

FAs, mg/g dry wt: 319.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.8; 18:0

– 3.4; 18:1 – 11.2; 18:2 – 73.1; 18:3 – 2.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana raimondii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – 1.0; 18:1 – 27.0; 18:2 – 6.0; 18:3 –

2.0; hydroxy-18:1 – 49.0; hydroxy-18:2 – 13.0

[1]

Leaf

FAs, mg/g dry wt: 35.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.0; 16:1

– 7.0; 16:3 – 5.8; 18:0 – 2.4; 18:1 – 2.1; 18:2 –

10.2; 18:3 – 57.5

Seed

FAs, mg/g dry wt: 352.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.5; 18:0

– 2.0; 18:1 – 15.3; 18:2 – 72.1; 18:3 – 1.1

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana repanda

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 4.0; 18:0 – 1.0; 18:1 – 6.0; 18:2 – 5.0;

Page 33: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana rustica L. 905 Solanaceae

18:3 – 5.0; hydroxy-18:1 – 72.0; hydroxy-18:2 –

7.0 [1]

Leaf

FAs, mg/g dry wt: 41.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.7; 16:1

– 6.4; 16:3 – 4.2; 18:0 – 2.7; 18:1 – 0.8; 18:2 –

15.1; 18:3 – 54.1

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C29, n-C31, iso-C29, anteiso-

C30 (>10%)

Seed

FAs, mg/g dry wt: 371.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.1; 18:0

– 4.7; 18:1 – 11.4; 18:2 – 72.9; 18:3 – 3.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana rosulata

Family: Solanaceae

Flowers

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 13.0; 18:2 – 3.0; 18:3 –

4.0; hydroxy-18:1 – 68.0; hydroxy-18:2 – 9.0 [1]

Leaf

FAs, mg/g dry wt: 29.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.9; 16:1

– 5.5; 16:3 – 4.6; 18:0 – 3.4; 18:1 – 1.3; 18:2 –

7.3; 18:3 – 60.0

Seed

FAs, mg/g dry wt: 291.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.4;

18:0 – 3.2; 18:1 – 20.3; 18:2 – 39.7; 18:3 – 26.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana rotundifolia

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 42.1

Composition (GLC, 5% BDS), %: 16:0 – 16.3; 16:1

– 6.3; 16:3 – 5.4; 18:0 – 2.4; 18:1 – 1.6; 18:2 –

10.3; 18:3 – 57.7

Seed

FAs, mg/g dry wt: 352.0

Composition (GLC, 5%DEGS), %: 16:0 – 9.6; 18:0

– 2.2; 18:1 – 22.8; 18:2 – 29.2; 18:3 – 36.2

Steryl esters, % total FAs: 3.8 (as FAs)

FAs(GLC), %: 16:0 – 1.1; 18:0 – 0.1; 18:1 – 0.5;

18:2 – 1.3; 18:3 – 0.8

TAG, % total FAs: 87.6 (as FAs)

FAs(GLC, 5% DEGS), %: 16:0 – 8.1; 18:0 – 1.6;

18:1 – 18.3; 18:2 – 29.4; 18:3 – 30.2

DAG, % total FAs: 3.7 (as FAs)

FAs(GLC), %: 16:0 – 0.7; 18:0 – 0.2; 18:1 – 1.0;

18:2 – 1.2; 18:3 – 0.6

PL, % total FAs: 4.9 (as FAs)

FAs(GLC), %: 16:0 – 2.5; 18:0 – 0.4; 18:1 – 0.9;

18:2 – 0.8; 18:3 – 0.3

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana rustica L.

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 27.0; 18:2 – 24.0;

Page 34: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 906 Nicotiana sanderae

18:3 – 5.0; hydroxy-18:1 – 19.0; hydroxy-18:2 –

21.0 [1]

Leaf

FAs, mg/g dry wt: 34.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.8; 16:1

– 6.8; 16:3 – 4.6; 18:0 – 2.2; 18:1 – 1.5; 18:2 –

8.6; 18:3 – 59.5

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C29, n-C31, iso-C29, anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 324.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.0; 18:0

– 3.5; 18:1 – 12.6; 18:2 – 73.8; 18:3 – 1.1

Seed

Oil, %: 40.0–46.0 [4], 37.3 (petroleum ether) [5]

Iodine value, % J2: 139.0–151.6 [4]; 141.1 (Wij’s)

[5]

Saponification value, mg KOH: 191.2 [4]; 294 [5]

Polenske value: 0.3 [5]

Unsaponifables, %: 2.1 [5]

Reichert value: 2.9 [5]

FAs

Iodine value, % J2 (Wij’s): 141.1 [5]

Saponification value, mg KOH: 278.3 [5]

Composition (%, GLC; 10% DEGS): 16:0 – 8.4;

18:0 – 3.8; 18:1 – 15.7; 18:2 – 71.2; 18:3 – 0.8;

20:0 – 0.1 [5]

TAG

Main components (Coleman), mole %: SSL – 1.0;

SLS – 3.3; LSL – 1.7; SOO – 1.0; SOL – 5.2;

SLO – 4.2; SLL – 20.9; OOL – 3.4; LOL – 8.4;

OLO – 1.4; OLL – 13.8; LLL – 33.4; others –

2.2 [5]

FAs, mol %: 16:0 – 10.2; 18:0 – 4.8; 18:1 – 15.4;

18:2 – 68.8; 18:3 – 0.8 [5]

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

4. N.I. Sharapov,Oil Plants and the Process of Oil formation (ASUSSR Press, Мoskwa-Leningrad, 1959), p. 352 [in Russian]

5. A. Sengupta, U.K. Mazumder, J. Am. Oil Chem. Soc. 53, 680

(1976)

Nicotiana sanderae

Family: Solanaceae

Leaf

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33

Main compounds: n-C33, iso-C31, anteiso-C32

(>10%)

References

1. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana setchellii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – tr; 18:1 – 51.0; 18:2 – 13.0; 18:3 –

6.0; hydroxy-18:1 – 20.0; hydroxy-18:2 – 8.0 [1]

Leaf

FAs, mg/g dry wt: 33.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.7; 16:1

– 6.1; 16:3 – 4.9; 18:0 – 2.6; 18:1 – 1.5; 18:2 –

9.3; 18:3 – 59.9

Seed

FAs, mg/g dry wt: 361.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.8; 18:0

– 1.8; 18:1 – 12.9; 18:2 – 76.9; 18:3 – 0.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Page 35: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana spegazzini 907 Solanaceae

Nicotiana simulans

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – 1.0; 18:1 – 9.0; 18:2 – 2.0; 18:3 –

4.0; hydroxy-18:1 – 74.0; hydroxy-18:2 – 8.0 [1]

Leaf

FAs, mg/g dry wt: 27.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.9; 16:1

– 5.7; 16:3 – 4.0; 18:0 – 3.8; 18:1 – 1.4; 18:2 –

10.9; 18:3 – 56.3

Seed

FAs, mg/g dry wt: 317.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.9;

18:0 – 3.1; 18:1 – 17.8; 18:2 – 65.1; 18:3 – 3.1

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana solanifolia

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – 1.0; 18:1 – 56.0; 18:2 – 16.0; 18:3 –

3.0; hydroxy-18:1 – 14.0; hydroxy-18:2 – 8.0 [1]

Leaf

FAs, mg/g dry wt: 33.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.6; 16:1

– 6.8; 16:3 – 6.9; 18:0 – 2.7; 18:1 – 3.9; 18:2 –

10.9; 18:3 – 53.2

Seed

FAs, mg/g dry wt: 327.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.6; 18:0

– 2.7; 18:1 – 16.9; 18:2 – 71.0; 18:3 – 0.9

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana sp.

Family: Solanaceae

Seed

TAG

Composition (HPLC), mol %: LeLL – 2.2; LLL +

LeLO – 38.6; LeLeP – 1.0; LLO – 16.3; LLP –

17.6; LOO – 5.3; LLSt + LOP – 11.4; LPP – 2.1;

OOO – 0.8; LOSt + OOP – 1.9; LPSt + OPP –

1.3; OOSt – 0.3; others – 1.2

References

1. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

Nicotiana spegazzini

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 2.0; 18:0 – tr; 18:1 – 12.0; 18:2 – 8.0; 18:3 –

3.0; hydroxy-18:1 – 51.0; hydroxy-18:2 – 24.0

[1]

Seed

FAs, mg/g dry wt: 405.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.3; 18:0

– 1.8; 18:1 – 16.6; 18:2 – 73.7; 18:3 – 0.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Page 36: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 908 Nicotiana stocktonii

Nicotiana stocktonii

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 5.0; 18:0 – tr; 18:1 – 11.0; 18:2

– 5.0; 18:3 – 8.0; hydroxy-18:1 – 64.0; hydroxy-

18:2 – 7.0 [1]

Leaf

FAs, mg/g dry wt: 29.5 [2]

Composition (GLC, 5% BDS), %: 16:0 – 18.3; 16:1

– 3.9; 16:3 – 3.6; 18:0 – 2.4; 18:1 – 2.4; 18:2 –

15.4; 18:3 – 54.0

Seed

FAs, mg/g dry wt: 390.0 [2]

Composition (GLC, 5% DEGS), %: 16:0 – 10.3;

18:0 – 3.4; 18:1 – 11.4; 18:2 – 69.4; 18:3 – 5.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana suaveolens

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 20.0; 18:2 – 4.0; 18:3 – 2.0;

hydroxy-18:1 – 63.0; hydroxy-18:2 – 10.0 [1]

Leaves

FAs, mg/g dry wt: 29.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.1; 16:1

– 6.1; 16:3 – 4.9; 18:0 – 2.4; 18:1 – 1.4; 18:2 –

8.6; 18:3 – 59.5

Seed

FAs, mg/g dry wt: 377.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.3; 18:0

– 2.8; 18:1 – 16.5; 18:2 – 41.1; 18:3 – 31.3

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana sylvestris

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – tr; 18:1 – 42.0; 18:2 – 12.0; 18:3 –

2.0; hydroxy-18:1 – 32.0; hydroxy-18:2 – 9.0 [1]

Leaf

FAs, mg/g dry wt: 42.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.8; 16:1

– 6.3; 16:3 – 6.1; 18:0 – 3.0; 18:1 – 2.1; 18:2 –

10.6; 18:3 – 57.1

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [3]

Main compounds: n-C33, n-C33 (>10%)

Seed

FAs, mg/g dry wt: 348.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.3; 18:0

– 2.5; 18:1 – 10.3; 18:2 – 74.5; 18:3 – 3.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. V. Koiwai, U. Brummer, C. Paulsen, F. Seehofer, Phytochem-

istry 22, 133 (1983)

Nicotiana tabacum L.

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 3.0; 18:0 – 1.0; 18:1 – 26.0; 18:2 – 9.0;

Page 37: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana tabacum L. 909 Solanaceae

18:3 – 3.0; hydroxy-18:1 – 45.0; hydroxy-18:2 –

13.0 [1]

TAG (chloroform-methanol), mg/mg lipid: 282 (as

FAs) [1]

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 1.0; 18:0 – tr; 18:1 – 34.0; 18:2

– 6.0; 18:3 – 1.0; hydroxy-18:1 – 42.0; hydroxy-

18:2 – 16.0

DAG(chloroform-methanol), mg/mg lipid: 139 (as

FAs) [1]

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 1.0; 18:0 – tr; 18:1 – 27.0; 18:2

– 4.0; 18:3 – tr; hydroxy-18:1 – 50.0; hydroxy-

18:2 – 18.0

PL(chloroform-methanol), mg/mg lipid: 127 (as

FAs) [1]

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 5.0; 18:0 – 1.0; 18:1 – 19.0;

18:2 – 11.0; 18:3 – 8.0; hydroxy-18:1 – 42.0;

hydroxy-18:2 – 14.0

Leaf

FAs, mg/g dry wt: 36.1 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14

2; 16:1 – 3.2; 16:3 – 4.2; 18:0 – 1.8; 18:1 – 2.6; 18:2

– 12.0; 18:3 – 62.0

Extract (hexane), % dry wt: 9.95 [3]

FAs of extract, mg of FAs/g: 14:0 – 149.6 � 6.9;

anteiso-15:0 – 25.2 � 1.1; 15:0 (iso 15:0

included in quantization of major peak) – 51.5

� 2.1; 15:1 – 184.2 � 6.9; 16:0 – 1737 � 32.6;

iso 17:0 – 98 � 3.8; 17:0 – 95 � 9.2; iso 18:0 –

48 � 4.9; 18:0 – 321 � 11.1; 18:1 – 570 � 12.3;

18:2 (19:0) – 1150 � 20.9; 20:0 – 127.7 � 13.3;

18:3 (21:0) – 1515 � 84.9; 22:0 – 65.5 � 5.5;

23:0 – 36.1 � 2.1; 24:0 – 46.9 � 6.2; 25:0 – 9.8

� 1.1; 26:0 – 34.3 � 2.9; 27:0 – 12.9 � 3.5;

28:0 – 93.8� 8.8; 29:0 – 20� 5.6; 30:0 – 48.3�4.1; 31:0 – 17.9 � 3.5; 32:0 – 64 � 6.3

Alkanes

Components (GC): n-C27 – C33, iso-C29 – C33,

anteiso-C30 – C33, n-C31 >10% (main com-

pounds) [4]

Epicuticular alkanes

Components: C27 – 7.31; C29 – 6.45; C31 – 26.23;

C33 – 8.55; iso-C29 – 2.13; iso- C31 – 16.85; iso-C33 – 5.73; anteiso-C28- – 1.18; anteiso-C30 –

9.55; anteiso-C32 – 16.02; anteiso-C34 – tr (from

the main stalks) [5]

C27 – 8.08; C29 – 5.43; C31 – 19.31; C33 – 22.88; iso-

C29 – 1.38; iso-C31 – 10.90; iso-C33 – tr; anteiso-C28 – 2.53; anteiso-C30 – 9.67; anteiso-C32 –

19.83; anteiso-C34 – tr (from sucker (axillary

buds) [5]

Polyisoprenoid alcohols consisting of 9 isoprene units

with all trans configuration [6]

Sterols: 0.11% dry wt [7]; 1.68–1.91 mg/g [8]

Free sterols, % of total: 50.0 [7]

Sterols from esters, % of total: 34.0 [7]

Sterols from sterylglycosides, % of total: 10.0, [7]

Sterols from acylated sterylglycosides, % of total:

6.0 [7]

Components (GLC), mg/g: Sitosterol – 0.72–0.75;

stigmasterol – 0.50–0.75; campesterol – 0.26–

0.27; cholesterol – 0.16–0.17 [8]

Composition (GLC, 5% OV-101), %: Sitosterol –

37.8–44.4; stigmasterol – 30.0–39.4;

campesterol – 13.9–16.2; cholesterol – 9.4–9.5

[8]

Free sterols: 1.03–1.23 mg/g [8]

Composition %: Sitosterol – 33.7–36.9; stigmas-

terol – 36.6–44.1; campesterol – 12.2–15.7; cho-

lesterol – 10.0–11.9 [7, 8]

Steryl esters, mg/g: 0.23–0.30 [8]

Composition of sterols, %: Sitosterol – 46.6–49.0;

stigmasterol – 16.6–23.6; campesterol – 15.8–

20.3; cholesterol – 13.6–14.1 [7, 8]

Steryl glycosides, mg/g: 0.29–0.31 [8]

Composition of sterols, %: Sitosterol – 46.7–52.3;

stigmasterol – 27.5–36.0; campesterol – 12.2–

14.0; cholesterol – 5.1–6.2 [7, 8]

Acylated steryl glycosides, mg/g: 0.04–0.09 [8]

Composition of sterols, %: Sitosterol – 39.5–44.9;

stigmasterol – 22.9–28.4; campesterol – 15.6–

18.2; cholesterol – 15.4–16.6 [7, 8]

Seed

Oil, % dry wt: 33.0–38.0 [9]; 43.2 (petrol ether) [10]

d15: 0.9232 [9]

d20: 0.9231 [10]

d3030 : 0.9130 (Philippines) [9]

n20: 1.4758 [10]

n30D : 1.4714 [9]

Hehner’s value, %: 93.47 [10]

Iodine value, % J2: 135.8 (Philippines); 118.6

(Europe) [9]; 143.82 [10]

Saponification value, mg KOH: 190.8 (Philip-

pines); 109.0 (Europe) [9]; 193.56 [10]

Page 38: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 910 Nicotiana tabacum L.

Unsaponifiables, %: 1.24 [10]; 1.38 [11]

FAs, mg/g dry wt: 360.0 [4], 352 (in immature seeds at

37 days after flowering) [12]

Composition (GLC),%: 16:0 – 9.6; 18:0 – 2.8; 18:1 –

12.1; 18:2 – 74.1; 18:3 – 1.4 (5%DEGS) [2]; 16:0

– 6.1; 18:1 – 7.2; 18:2 – 85.2 (17% PEGS) [10]

Saturated – 12.8 – 19.5; 18:1 – 9.3–19.3; 18:2 –

64.7–72.6; 18:3 – 1.1–2.0 (15 species from

India) [13]

Components of Oil (TLC): Hydrocarbons, TAG, free

FAs, sterols, DAG, MAG [10]

TAG: 339 mg/g dry seeds (as FAs) [13]; 89.0% of

oil [11]

Main components, %: LeLL – 2.0; LLL – 33.0–

35.0; LLO – 17.0–22.0; LLSt – 22.0–23.0;

LOO – 4.0–5.0; LOSt – 4.0–9.0; OOO – 3.0;

LStSt – 3.0–7.0; OOSt – 3.0; OStSt – 1.0 [11]

Composition, %: SSU – 4.0–7.0; SUU – 32.0–33.0;

UUU – 62.0–63.0 [11]

FAs(GLC), %: 16:0 – 9.2; 18:0 – 2.6; 18:1 – 11.8;

18:2 – 75.3; 18:3 – 1.1 (5% DEGS) [13]

16:0 – 9.8; 16:1 – 1.0; 18:0 – 3.8; 18:1 – 13.5; 18:2 –

70.6; 18:3 – 1.3 (mol %) [11]

Steryl esters, mg/g dry seeds: 2.92 (as FAs) [13]

FAs (GLC, 5% DEGS), %: 16:0 – 16.8; 18:0 – 6.1;

18:1 – 10.0; 18:2 – 65.3; 18:3 – 1.8

Free FAs, mg/g dry seeds 0.85 [13]

Composition (GLC, 5% DEGS), %: 16:0 – 38.3;

18:0 – 14.0; 18:1 – 14.4; 18:2 – 32.2; 18:3 – 1.1

DAG, mg/g dry seeds: 5.51 (as FAs) [13]

FAs (GLC, 5% DEGS), %: 16:0 – 15.5; 18:0 – 5.7;

18:1 – 16.6; 18:2 – 61.7; 18:3 – 0.5

PhG, mg/g dry seeds: 0.41 (as FAs) [13]

FAs (GLC), %: 16:0 – 51.8; 18:0 – 13.9; 18:1 –

15.8; 18:2 – 16.1; 18:3 – 2.4

PhC, mg/g dry seeds: 1.89 (as FAs) [13]

FAs (GLC), %: 16:0 – 18.4; 18:0 – 5.8; 18:1 – 18.0;

18:2 – 56.8; 18:3 – 1.0

PhE, mg/g dry seeds: 0.54 (as FAs) [13]

FAs (GLC), %: 16:0 – 32.4; 18:0 – 7.8; 18:1 – 13.9;

18:2 – 45.0; 18:3 – 0.9

PhI, mg/g dry seeds: 0.84 (as FAs) [13]

FAs (GLC), %: 16:0 – 38.1; 18:0 – 10.1; 18:1 –

12.6; 18:2 – 37.1; 18:3 – 2.1

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – tr; cycloartanol – 4.0;

cycloartenol – 87.0; 24-methylenecycartanol –

5.0; b-amyrin – tr; others – 4.0 [14]

IR, MS, 1H MR [14]

4a-Methylsterols

Composition (Ag+-PLC, GLC on OV 17 SCOT,

GC/MS on 2% OV 17), %: 31-Norcycloartanol

– tr; 31-norcycloartenol – 2.0; cycloeucalenol –

6.0; 31-norlanost-8-enol – 1.0; 31-norlanosterol

– 4.0; obtusifoliol – 1.0; 31-norlanost-9(11)-enol

– tr; 4a-methylcholest-8-enol – 1.0; lophenol –

14.0; 24-methyllophenol – 1.0; 24-ethyllophenol

– 1.0; gramisterol – 5.0; citrostadienol – 60.0; 4a-methyl-24-ethylcholesta-7,24-dienol – 1.0; others

– 3.0 [15]1H MR [14]

Use: As tobacco.

Tobacco

Lipids (chloroform; chloroform-acetone, 1:1; acetone;

methanol), % dry wt: 3.65–12.38 (Barley tobacco);

13.90–14.49 (Flue-cured tobacco) [16]

NL, %: 75.0 (Barley); 50.0 (Flue-cured tobacco)

PhL

Composition, %: DPhG – 7.0–9.0; PhE – 14.4–15.1;

PhG – 6.8–9.4; PhC – 10.3–12.3; unidentified –

5.8–6.7; PhI – 16.0–19.8; PhA – 12.6–14.8; ori-

gin – 20.2–22.1 (Barley) [16]

DPhG – 6.6–7.7; PhE – 19.8–21.6; PhG – 10.5–

11.4; PhC – 12.0–12.8; unidentified – 6.8–7.5;

PhI – 6.8–7.7; PhA – 13.5–14.9; origin – 19.1–

21.350.0 (Flue-cured tobacco) [16]

GL

Components, %: MGDG – 22.3–27.4; DGDG –

40.6–58.9; unidentified – 16.6–33.2 (Barley) [16]

MGDG – 62.5–70.1; DGDG – 30.1–34.1;

unidentified – 1.8–5.1 (Flue-cured tobacco) [16]

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

3. J.J. Ellington, P.F. Schlotzhauer, A.I. Schepartz, J. Indian

Chem. Soc. 55, 572 (1978)

4. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

5. R.E. Wilkinson, M.J. Kasperbauer, Phytochemistry 2439

(1972)

Page 39: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Nicotiana trigonophylla 911 Solanaceae

6. J.W. Rip, C.A. Rupar, K. Ravi, K.K. Carroll, Prog. Lipid

Res. 24, 269 (1985)

7. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

8. C. Grunwald, Phytochemistry 14, 79 (1975)

9. I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352

[in Russian]

10. A.U. Umarov, M.Kh. Khasanov, Kh.N. Teshabaeva, Chem.

Nat. Comp. 26, 706 (1990)

11. F.D. Gunstone, M. Ilyas Qureshi, J. Am. Oil Chem. Soc. 42,

961 (1965)

12. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 21, 305 (1982)

13. S.R. Chakrabarty, M.M. Chakrabarty, J. Indian Chem. Soc.,

IND. News Ed. 20, 17 (1957)

14. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 17, 1723

(1977)

15. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

16. M.K. Wassef, J.W. Hendrix, J. Agric Food Chem. 23(4), 688

(1975)

Nicotiana tomentosa

Family: Solanaceae

Leaf

FAs, mg/g dry wt: 21.2 [1]

Composition (GLC, 5% BDS), %: 16:0 – 17.2; 16:1

– 4.9; 16:3 – 3.8; 18:0 – 3.6; 18:1 – 2.0; 18:2 –

10.7; 18:3 – 57.8

Alkanes (GC): n-C27 – n-C33, iso-C29 – iso-C33,

anteiso-C30 – anteiso-C33 [2]

Main compounds: n-C31, anteiso-C30 (>10%)

Seed

FAs, mg/g dry wt: 284.0 [1]

Composition (GLC, 5%DEGS), %: 16:0 – 7.2; 18:0

– 2.0; 18:1 – 11.2; 18:2 – 79.1; 18:3 – 0.5

References

1. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

2. V. Heemann, U. Brummer, C. Paulsen, F. Seehofer, Phyto-

chemistry 22, 133 (1983)

Nicotiana tomentosiformis

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 4.0; 18:0 – 2.0; 18:1 – 20.0; 18:2 – 7.0;

18:3 – 3.0; hydroxy-18:1 – 52.0; hydroxy-

18:2 – 12.0 [1]

Leaf

FAs, mg/g dry wt: 40.9 [2]

Composition (GLC, 5% BDS), %: 16:0 – 14.9; 16:1

– 4.4; 16:3 – 5.0; 18:0 – 2.8; 18:1 – 1.9; 18:2 –

10.7; 18:3 – 60.3

Seed

FAs, mg/g dry wt: 308.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.1; 18:0

– 1.9; 18:1 – 14.1; 18:2 – 76.3; 18:3 – 0.6

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana trigonophylla

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 42.0; 18:2 – 2.0; 18:3 –

4.0; hydroxy-18:1 – 49.0; hydroxy-18:2 – 2.0 [1]

Leaf

FAs, mg/g dry wt: 36.3 [2]

Composition (GLC, 5% BDS), %: 16:0 – 17.3; 16:1

– 4.7; 16:3 – 4.4; 18:0 – 2.4; 18:1 – 2.6; 18:2 –

11.1; 18:3 – 57.5

Page 40: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 912 Nicotiana umbratica

Seed

FAs, mg/g dry wt: 288.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.9; 18:0

– 2.8; 18:1 – 13.6; 18:2 – 74.3; 18:3 – 0.4

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana umbratica

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 1.0; 18:0 – tr; 18:1 – 13.0;

18:2 – 2.0; 18:3 – 2.0; hydroxy-18:1 – 72.0;

hydroxy-18:2 – 10.0 [1]

Leaf

FAs, mg/g dry wt: 27.8 [2]

Composition (GLC, 5% BDS), %: 16:0 – 16.4; 16:1

– 5.4; 16:3 – 5.2; 18:0 – 4.1; 18:1 – 2.0; 18:2 –

8.1; 18:3 – 58.8

Seed

FAs, mg/g dry wt: 333.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.1; 18:0

– 3.0; 18:1 – 16.1; 18:2 – 67.6; 18:3 – 4.2

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana undulata

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs (GC/MS, 5% BDS and

OV 1), %: 16:0 – 3.0; 18:0 – 1.0; 18:1 – 23.0;

18:2 – 7.0; 18:3 – 3.0; hydroxy-18:1 – 53.0;

hydroxy-18:2 – 10.0 [1]

Leaf

FAs, mg/g dry wt: 41.0 [2]

Composition (GLC, 5% BDS), %: 16:0 – 13.5; 16:1

– 5.3; 16:3 – 4.5; 18:0 – 2.6; 18:1 – 4.0; 18:2 –

12.0; 18:3 – 58.1

Seed

FAs, mg/g dry wt: 295.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 8.3; 18:0

– 2.3; 18:1 – 12.3; 18:2 – 75.9; 18:3 – 1.2

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana velutina

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0, 18:0 – tr, 18:1 – 32.0, 18:2 – 5.0, 18:3 – 6.0,

hydroxy-18:1 – 49.0, hydroxy-18:2 – 6.0 [1]

Seed

FAs, mg/g dry wt: 285.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 9.7; 18:0

– 3.0; 18:1 – 15.1; 18:2 – 47.0; 18:3 – 25.2

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Nicotiana wigandioides

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %:

16:0 – 2.0; 18:0 – 1.0; 18:1 – 24.0; 18:2 – 19.0;

Page 41: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Physalis alkekengi L. 913 Solanaceae

18:3 – 2.0; hydroxy-18:1 – 26.0; hydroxy-18:2 –

26.0 [1]

Leaf

FAs, mg/g dry wt: 29.6 [2]

Composition (GLC, 5% BDS), %: 16:0 – 15.8; 16:1

– 6.6; 16:3 – 3.8; 18:0 – 2.0; 18:1 – 2.4; 18:2 –

12.7; 18:3 – 56.7

Seed

FAs, mg/g dry wt: 304.0 [2]

Composition (GLC, 5%DEGS), %: 16:0 – 7.9; 18:0

– 2.8; 18:1 – 10.9; 18:2 – 76.9; 18:3 – 1.5

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. A. Koiwai, F. Suzuki, T. Matsuzaki, N. Kawashima, Phyto-

chemistry 22, 1409 (1983)

Petunia hybrida

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 1.0; 18:2 – 1.0; 18:3 – 1.0;

hydroxy-18:1 – 72.0; hydroxy-18:2 – 24.0 [1]

Leaf

Surface lipids: 2,3,4-O-Tri-acyl-a-D-glycopyranosyl-1-O-malonyl-4-O-acyl-6-O-acetyl-b-D-fructofuranoside, 2,3,4-O-tri-acyl-a-D-glycopyranosyl-4-O-acyl-6-O-acetyl-b-D-fructofuranoside and 2,3,4-O-tetra-acyl-a-D-glycopyranosyl-b-D-fructofuranoside [2]FAs: Both unbranched and branched C2-C8

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. I. Ohya, Y. Shinozaki, T. Tobita, H. Takahashi, T. Matsuzaki,

Phytochemistry 41, 787 (1996)

Physalis aequata Jacq.

Synonyms

Ph. ixocarpa Brct. ex Haraem

Family: Solanaceae

Seed

Oil, %: 35.6

Iodine value, % J2: 137.0

References

1. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 352 [in

Russian]

Physalis alkekengi L.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.17 [1]

Free sterols, % of total: 44.0

Components: Sitosterol, campesterol, stigmasterol,

cholesterol

Sterols from esters, % of total: 50.0

Components: Isofucosterol, sitosterol, campesterol,

stigmasterol

Sterols from sterylglycosides, % t of total: 3.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total:

3.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

Seed

Oil, %: 23.7–32.1 [2]

Iodine value, % J2: 126.0–137.0

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Page 42: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 914 Physalis alkekengi L. var. francheti Hort.

2. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 352 [in

Russian]

Physalis alkekengi L. var. francheti Hort.

Family: Solanaceae

Seed

Triterpenols

Composition (Ag+-PLC, GLC, 3% OV 17), %:

Lanost-8-en-3b-ol – 24.0; lanosterol – tr;

methylenelanost-8-en-3b-ol – 3.0; cycloartanol

– 35.0; cycloartenol – 27.0; 24-

methylenecycartanol – 11.0 [1]

IR, MS, 1H NMR [1]

4a-Methylsterols

Composition (Ag+-PLC, GLC, OV 17 SCOT; GC/

MS, 2% OV 17), %: 31-Norcycloartanol – 1.0;

31-norcycloartenol – 4.0; cycloeucalenol – 8.0;

31-norlanost-8-enol – 7.0; 31-norlanosterol –

2.0; obtusifoliol – 14.0; 31-norlanost-9(11)-

enol – tr; 4a-methylcholest-8-enol – 5.0;

lophenol – 7.0; 24-methyllophenol – tr; 24-

ethyllophenol – 3.0; gramisterol – 36.0;

citrostadienol – 8.0; 24- ethylcholesta-7,24-

dienol – tr; others – 5.0 [2]1H NMR [2]

References

1. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

2. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Physalis ixocarpa L.

Family: Solanaceae

Seed

TAG

Composition (HPLC), mol %: LeLL – 0.4; LLL +

LeLO – 47.2; LeLeP – 0.2; LLO – 16.9; LLP –

19.6; LOO – 4.5; LLSt + LOP – 8.0; LPP – 0.6;

OOO – 0.3; LOSt + OOP – 0.8; LPSt + OPP –

0.5; OOSt – 0.1; others – 0.9

References

1. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

Physalis minima

Family: Solanaceae

Seed

Ash, %: 2.1

Side, mm: 3.5 � 2.6 � 1.1

Moisture, %: 5.6

Mass of 1,000, g: 10.0

Oil (hexane), %: 4.0

d30: 0.9176

n40D : 1.4679

Acidic value, mg KOH: 0.7

Iodine value (Wijs), % J2: 122.5

Saponification value, mg KOH: 189.0

Unsaponifables, %: 0.8

FAs

Composition (GLC), %: 16:0 – 10.5; 16:1 – 0.1;

18:0 – 8.6; 18:1 – 17.3; 18:2 – 61.4

Epoxy-FAs: 0.6

Hydroxy-FAs: 1.5

References

1. T.Ch. Rao, G. Lakshminarayana, N.B.L. Prasad, S.J.M. Rao,

G. Azeemoddin, D.A. Ramayya, S.D.T. Rao, J. Am. Oil

Chem. Soc. 61, 1472 (1984)

Physalis peruviana L.

Family: Solanaceae

Fruit

Oil (petrol ether), % air dry wt: 7.3 [1]

d204 : 0.9235

n20: 1.4462

Acid value, mg KOH: 4.2

Iodine value, % J2: 88.2

Unsaponifiables, %: 2.6

Page 43: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Salpichroa origanifolia Lmk. 915 Solanaceae

FAs

Composition (GLC, 17% EGS), %: 16:0 – 15.7;

16:1 – 14.4; 18:0 – 1.6; 18:1 – 14.3; 18:2 –

51.5; 18:3 – 1.4; 20:0 – 1.1

Carotenoids, mg %: 189.2

Tocopherols, mg %: 158.4

Sterols, %: 1.92

Seed

Oil, % dry wt: 18.0 (petrol ether) [1]; 6.3 [2]

d204 : 0.9264 [1]

n20D : 1.4481 [1]

Acid value, mg KOH: 2.9 [1]

Iodine value, % J2: 116.3 [1]; 120.5 [2]

Saponification value, mg KOH: 177.6 [2]

Unsaponifiables, %: 2.1 [1]

FAs

Composition (GLC, 17% EGS), %: 16:0 – 8.2; 16:1

– 1.1; 18:0 – 3.1; 18:1 – 20.2; 18:2 – 65.1; 18:3 –

2.3; 20:0 – tr [1]

Carotenoids, mg %: 16.1 [1]

Tocopherols, mg %: 152.3 [1]

Sterols, %: 0.91 [1]

References

1. S.M. Aslanov, M.E. Mamedova, S.A. Bairamova, Chem. Nat.

Comp. 31, 410 (1995)

2. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Moskwa-Leningrad, 1959), p. 352 [in

Russian]

Physalis pubescens L.

Family: Solanaceae

Seed

TAG

Composition (HPLC), mol %: LeLL – 0.5; LLL +

LeLO – 45.5; LeLeP – 0.4; LLO – 16.3; LLP –

21.1; LOO – 3.1; LLSt + LOP – 9.8; LPP – 1.2;

OOO – 0.5; LOSt + OOP – 1.2; LPSt + OPP –

0.2; OOSt – 0.1; others – 0.1

References

1. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

Physalis viscosa

Family: Solanaceae

Flowers and Steams

Acylated sucrose ester physaloside A

Activity: Antimicrobial activity, LC50, mM: Staphy-lococcus aureus – 52.0; Streptococcus pneumoniae –

53.0; Klebsiella pneumoniae and Pseudomonas

aeruginosa > 413

References

1. S.P.B. Ovenden, J. Yu, J. Bernays, S.S. Wan, L.J.

Christophidis, G. Sberna, R.M. Tait, H.G. Wildman, D.

Lebeller, J. Lowther, N.G. Walsh, B.M. Meurer-Grimes, J.

Nat. Prod. 68, 282 (2005)

Physalis sp.

Family: Solanaceae

Seed

Mass of 1,000, g: 0.4 (Sample 1); 0.8 (Sample 2)

Oil, % dry wt: 17.6 (1); 19.1 (2)

HBr uptake, as C18 acid: 0.2 (2)

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Salpichroa origanifolia Lmk.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.20

Free sterols, % of total: 65.0

Components: Isofucosterol, campesterol, sitosterol,

cholesterol

Sterols from esters, % of total: 33.0

Components: Isofucosterol, sitosterol, campesterol,

cholesterol

Sterols from sterylglycosides, % of total: 1.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol

Page 44: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 916 Salpiglossis sinuata

Sterols from acylated sterylglycosides, % of

total: 1.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Salpiglossis sinuata

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 1.0; 18:0 – tr; 18:1 – 26.0; 18:2 – 15.0; 18:3 –

2.0; hydroxy-18:1 – 36.0; hydroxy-18:2 – 20.0

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

Schizanthus pinnatus Ruiz-Pavone.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.19

Free sterols, % of total: 70.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol

Sterols from esters, % of total: 16.0

Components: Sitosterol, campesterol, isofucosterol,

cholesterol

Sterols from sterylglycosides, % of total: 6.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total:

8.0

Components: Sitosterol, campesterol, cholesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Solanum ajanhuirii

Family: Solanaceae

Leaf

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.36 (chill-tolerant)

Composition (GLC, 15% EGSS-X), %: 16:0 – 9.5;

16:1 – 2.6; 18:0 – 0.8; 18:1 – 16.2; 18:2 – 8.3;

18:3 – 63.1

References

1. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28, 1813

(1989)

Solanum arundo Crit.

Family: Solanaceae

Seed

Oil

Iodine value, % J2: 134.0

Saponification value, mg KOH: 193.5

References

1. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

Solanum carolinense L.

Family: Solanaceae

Seed

Mass of 1,000, g: 0.6

Oil, % dry wt: 21.4

Page 45: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanum dulcamara L. 917 Solanaceae

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Solanum chaucha

Family: Solanaceae

Leaf

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.39 (chill-tolerant)

Composition (GLC, 15% EGSS-X), %: 16:0 – 13.4;

16:1 – 5.5; 18:0 – 3.5; 18:1 – 12.8; 18:2 – 10.8;

18:3 – 50.8; 20:0 – 0.2–2.7

References

1. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28, 1813

(1989)

Solanum dulcamara L.

Family: Solanaceae

Fruit

Sterols, mg/100 g: 43–86 [1]

Composition (CLC, SE 52), %: Cholesterol – 14.0–

15.0; brassicasterol – 6.0–7.0; campesterol –

7.0–8.0; 24-methylenecholesterol – l.0; stigmas-

terol – 9.0–10.0; sitosterol – 55.0; isofucosterol –

6.0

Free sterols, % of total: 58.1

Sterols from steryl esters, % of total: 7.0

Sterols from steryl glycosides, % of total: 18.5

Sterols from acylated steryl glycosides, % of

total: 16.4

Leaf

Extract (petrol ether), % dry wt: 3.3 [2]

Sum esters of sterols and triterpenols

FAs(GLC, 2.5% EGS), %: 12:0 – 1.0; 13:0 – tr;

14:0 – 2.0; 15:0 – 1.0; 16:0 – 24.0; 16:1 – 2.0;

16:2 – 1.0; 16:3 – 5.0; 17:0 – tr; 18:0 – 9.0; 18:1 –

14.0; 18:1 – 13.0; 18:2 – 20.0; 19:0 – tr;

20:0 – 9.0

Triterpenyl esters

Triterpenols(GLC, 2.5% SE 52), %: Lophenol – 6.0;

24-methylenelophenol – 2.0; 24-ethylidenlophenol

– 5.0; cycloeucalenol – 6.0; cycloartenol – 75.0; 24-

methylenecycloartanol – 6.0

Sterylesters

Sterols (GLC, 2.5% SE 52), %: Cholesterol – 41.0;

brassicasterol – 5.0; campesterol – 3.0; 24-

methylenecholesterol – 1.0; stigmasterol – 4.0; b-sitosterol – 41.0; isofucosterol – 5.0

Unsaponifables, % dry wt: 0.6 [2]

Alkanols

Components (GLC, 2.5% SE 52), %:С16 – 0.3;С18

– 90.0; С19 – tr; C20 – 0.8; C21 – 0.1; C22 – 1.6;

C23 – 0.1; C24 – 0.3; C25 – 0.1; C26 – 0.2; C27 –

0.1; C28 – 0.4; C29 – 0.2; sum of unidentified –

5.8

Triterpenols

Components (GLC, 2.5% SE 52), %: Lophenol –

1.0; 24-methylenlophenol – 2.0; 24-

ethylidenlophenol – 4.0; obtusifoliol – 9.0;

cycloeucalenol – 16.0; cycloartenol – 57.0; 24-

methylenecycloartanol – 11.0

Sterols: 44–112 mg/100 g [1]; 0.12% dry wt [3]

Composition (GLC, 2.5% SE 52), %: Cholesterol –

34.0; brassicasterol – 3.0; campesterol – 6.0; 24-

methylenecholesterol – 1.0; stigmasterol – 24.0;

b-sitosterol – 29.0; isofucosterol – 3.0 [2]

Cholesterol – 21.0–25.0; brassicasterol – 4.0–6.0;

campesterol – 10.0–12.0; 24-methylenecho-

lesterol – l.0; stigmasterol – 13.0–18.0; sitosterol

– 34.0–40.0; isofucosterol – 4.0–5.0 [1]

Forms, %: Free sterols – 42.4; as steryl esters – 2.0;

as steryl glycosides – 26.3; as acylated glyco-

sides – 29.3 [1]

Free sterols, % of total: 28.0 [3]

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterols from esters, % of total: 7.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from sterylglycosides, % of total: 27.0 [3]

Components: Sitosterol, stigmasterol, cholesterol

brassicasterol

Sterols from acylated sterylglycosides, % of total:

38.0S [3]

Components: Sitosterol, stigmasterol, cholesterol,

campesterol (the sterols are listed in order of

decreasing concentration)

Page 46: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 918 Solanum ferox L.

Root

Sterols, mg/100 g: 65.0 – 73.0 [1]

Composition (CLC, SE 52), %: Cholesterol – 15.0–

18.0; brassicasterol – 4.0–5.0; campesterol –

6.0–7.0; 24-methylenecholesterol – l.0; stigmas-

terol – 13.0–14.0; sitosterol – 51.0–53.0;

isofucosterol – 6.0

Free sterols, % of total: 74.8

Sterols from steryl esters, % of total: 9.0

Sterols from steryl glycosides, % of total: 10.2

Sterols from acylated steryl glycosides, % of

total: 6.0

Seed

Oil (petrol ether), %: 28.1 [4]

FAs

Composition (GLC, 3% OV-17), %: 14:0 – tr; 16:0

– 5.4; 16:1 – tr; 17:0 – tr; 18:0 – 1.3; 18:1 – 12.2;

18:2 – 79.2; 18:3 – 1.7 [4]

Free FAs

Composition (GLC, 3% OV-17), %: 12:0 – tr;

14:0 – 0.3; 16:0 – 49.3; 16:1 – 0.2; 17:0 –

4.4; 18:0 – 12.2; 18:1 – 28.7; 18:2 – 3.4; 18:3 –

1.5 [4]

Triterpenols

Composition (TLC, GLC, GC/MS, 3% OV-17), %:

24-Dihydrolanosterol – 5.0; cycloartenol – 68.0;

lanosterol < 1.0; 24-methylenelanost-8-en-3b-ol < 1.0; lupeol or isomer < 1.0; 24-

methylenecycloartanol < 1.0

4a-Methylsterols

Composition (TLC, GLC, GC/MS, 3% OV-17), %:

31-Norlanost-8-en-3b-ol – 21.0; lophenol –

44.0; 31-norlanosterol – 19.0; 31-

norcycloartenol – 7.0; citrostadienol – 2.0;

obtusifoliol < 1.0; cycloeucalenol-< 1.0;

gramisterol < 1.0; unidentified (5) < 1.0 – 4.0

Sterols

Composition (TLC, GLC, GC/MS, 3% OV-17), %:

Cholesterol – 20.0; campesterol – 13.0; stigmas-

terol – 12.0; b-sitosterol – 4.0; isofucosterol <

1.0; 24-methylenecholesterol – 1.0

Stem

Sterols, mg/100 g: 62.0–75.0 [1]

Composition (CLC, SE 52), %: Cholesterol – 18.0–

23.0; brassicasterol – 5.0–12.0; campesterol –

7.0–9.0; 24-methylenecholesterol – l.0;

stigmasterol – 12.0–18.0; sitosterol – 40.0–

47.0; isofucosterol – 4.0–5.0

Free sterols, % of total: 44.3

Sterols from steryl esters, % of total: 2.5

Sterols from steryl glycosides, % of total: 12.9

Sterols from acylated steryl glycosides, % of

total: 40.3

References

1. G. Koiwai, J. Kostens, Phytochemistry 14, 2055 (1975)

2. G. Willuhn, J. Kostens, Planta Med. 25(2), 115 (1974)

3. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

4. G. Willuhn, S. May, I. Merfort, Planta Med. 46, 99 (1982)

Solanum ferox L.

Family: Solanaceae

Seed

FAs (GLC), %: 16:0 – 12.15; 18:0 – 9.96; 18:1 –

39.83; 18:2 – 38.96

References

1. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma Ata, 1977), p. 324 [in Russian]

Solanum indicum L.

Family: SolanaceaeOil

Iodine value, % J2: 121.5

Saponification value, mg KOH: 177.6

References

1. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

Page 47: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanum melongena L. 919 Solanaceae

Solanum khasianum C.B. Clarke & SenGupta

Family: Solanaceae

Cotyledon

FAs

Composition (% GLC, 10% PEGA): 12:0 – tr; 14:0

– 0.5; 14:1 – 0.3; 16:0 – 21.2; 16:1(9) – 1.8; 18:0

– 6.2; 18 [1]

Seed

Oil (petroleum ether), %: 14.5 [2]

d: 0.941

n27: 1.4725

Iodine value, % J2: 181.1

Saponification value, mg KOH: 199.4

FAs

Composition (GLC, 25% Resoflex, 3% O-

phosphoric acid coated on Chromatosorb “P”),

%: 12:0 + unidentified – 2.7; 14:0 – 0.2; 16:0 –

14.2; 16:1 – 0.9; 18:0 – 4.4; 18:1 – 15.0; 18:2 –

62.6; 18:1 – 14.4; 18:2 – 55.6; 18:3 – tr

References

1. B. Koiwai, S. Manday, D.R. Gadgil, J. Am. Oil Chem.

Soc. 63, 541 (1986)

2. P. Parimoo, R.N. Baruah, J. Am. Oil Chem. Soc. 52, 357

(1975)

Solanum marginatum

Family: Solanaceae

Seed

FAs

Composition (GLC, Silar 5CP), %: 16:0 – 10.77;

16:1 – 0.40; 17:0 – 0.10; 17:1 – 0.09; 18:0 – 3.52;

18:1 – 15.77; 18:2 – 66.95; 18:3 – 1.69; 20:0 –

0.16; 20:1(11) – 0.06

Isomers of 16:1, %: 16:1(9) – 95.0; 16:1(7) – 5.0;

16:1(11) – tr

Isomers of 18:1, %: 18:1(9) – 93.9; 18:1(11) – 6.0;

18:1(13) – 0.1

References

1. Von A. Seher, U. Gundlach, Fette, Seifen, Anstrichmittel

84(9), 342 (1982)

Solanum melongena L.

Family: Solanaceae

Flower

Stigma

Usual and v-hydroxy-FAs

Composition (GC/MS, 5% BDS and OV 1), %: 16:0

– 3.0; 18:0 – 1.0; 18:1 – 3.0; 18:2 – 5.0; 18:3 –

2.0; hydroxy-18:1 – 77.0; hydroxy-18:2 – 9.0 [1]

Leaf

Sterols, % dry wt: 0.19 [2]

Free sterols, % of total: 22.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterols from esters, % of total: 11.0

Components: Sitosterol, stigmasterol, cholesterol,

isofucosterol

Sterols from sterylglycosides, % of total: 22.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterols from acylated sterylglycosides, % of

total: 45.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol (the sterols are listed in order of

decreasing concentration) [2]

Cotyledon

FAs

Composition (% GLC, 10% PEGA): 12:0 – tr; 14:0

– 1.4; 16:0 – 35.1; 16:1 – 2.1; 18:0 – 3.5; 18:1 –

39.4; 18:2 – 18.5; 18:3 – tr [3]

Seed

FAs

Composition (GLC), %: 14:0 – tr; 14:0 – 0.1; 14:0 –

tr; 16:0 – 8.8; 16:1 – 0.2; 17:0 – tr; 18:0 – 3.4;

18:1 – 18.1; 18:2 – 67.7; 18:3 – 1.4 [4]

TAG

Composition (HPLC), mole %: LeLL – 1.5; LLL +

LeLO – 33.6; LeLeP – 1.4; LLO – 16.9; LLP –

17.2; LOO – 7.1; LLSt + LOP – 13.2; LPP – 1.4;

Page 48: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 920 Solanum nigrum L.

OOO – 0.8; LOSt + OOP – 3.9; LPS +OPP – 1.8;

OOSt – 0.1; others – 1.1 [5]

Triterpenols

Composition (Ag+-PLC, GLC on 3% OV 17), %:

Lanost-8-en-3b-ol – 15.0; lanosterol – tr;

methylenelanost-8-en-3b-ol – tr; cycloartanol –

69.0; cycloartenol – 7.0; 24-

methylenecycartanol – tr.0; lupeol – tr; b-amyrin

– tr; others – 9.0 [6]

IR, MS, 1H NMR [6]

4a-Methylsterols

Composition (Ag+-PLC, GLC, OV 17 SCOT: GC/

MS, 2%OV 17), %: 31-Norcycloartanol – tr; 31-

norcycloartenol – tr; cycloeucalenol – tr; 31-

norlanost-8-enol – 2.0; 31-norlanosterol – 1.0;

obtusifoliol – tr; 31-norlanost-9(11)-enol – tr;

4a-methylcholest-8-enol – 1.0; lophenol – 13.0;

24-methyllophenol – 4.0; 24-ethyllophenol –

65.0; gramisterol – 3.0; citrostadienol – 8.0; 4a-methyl-24-ethylcholesta-7,24-dienol – 1.0,

others – 2.0 [7]1H NMR [7]

Use: Food-stuffs [4].

References

1. A. Koiwai, T. Matsuzaki, Phytochemistry 27, 2827 (1988)

2. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

3. B. Pandey, S. Manday, D.R. Gadgil, J. Amer. Oil Chem.

Soc. 63, 541 (1986)

4. M.I. Goryaev, N.A. Evdakova, Spravochnik pogasozhidkostnoi khromatographii organicheskikh kislot(Nauka, Alma ata, 1977), p. 224 [in Russian]

5. V.I. Deineka, L.A. Deineka, Chem. Nat. Comp. 40, 184 (2004)

6. T. Itoh, T. Tamura, T. Matsumoto, Phytochemistry 16, 1723

(1977)

7. T. Itoh, T. Ishii, T. Tamura, T. Matsumoto, Phytochemistry

17, 971 (1978)

Solanum nigrum L.

Family: Solanaceae

Cotyledon

FAs

Composition (GLC, 10), % PEGA): 14:0 – tr; 14:0 –

0.7; 16:0 – 12.4; 18:0 – 2.5; 18:1 – 20.5; 18:2 –

60.4; 18:3 – 3.4 [1]

Leaf

Sterols, % dry wt: 0.15 [2]

Free sterols, % of total: 38.0

Components: Sitosterol, isofucosterol, cholesterol,campesterol

Sterols from esters, % of total: 3.0

Components: Sitosterol, cholesterol, isofucosterol,campesterol

Sterols from sterylglycosides, % of total: 9.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol

Sterols from acylated sterylglycosides, % of total:

50.0

Components: Sitosterol, cholesterol, campesterol,

stigmasterol (the sterols are listed in order of

decreasing concentration)

Seed

Ash, %: 4.6 [3]

Mass of 1,000, g: 0.6 [3]

Oil % dry wt: 27.2 [3]

HBr uptake, as C18 acid, %: 0.1 [3]

Iodine value, % J2: 123.2 [4]

Saponification value, mg KOH: 193.5 [4]

TAG

Composition (HPLC), mol %: LeLL – 1.2; LLL +

LeLO – 35.6; LeLeP – 1.2; LLO – 14.7; LLP –

19.3; LOO – 3.8; LLSt + LOP – 14.2; LPP – 1.6;

OOO – 0.4; LOSt + OOP – 4.2; LPS +OPP – 2.6;

OOS – 0.2; others – 1.0 [5]

References

1. B. Pandey, S. Manday, D.R. Gadgil, J. Am. Oil Chem.

Soc. 63, 541 (1986)

2. R. Koiwai, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

3. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

4. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 352 [in

Russian]

5. V.I. Deineka, L. A. Deineka, Chem. Nat. Comp. 40, 184

(2004)

Solanum noctiflorus

Family: Solanaceae

Seed

Ash, %: 4.6

Page 49: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanum toralapanum 921 Solanaceae

Mass of 1,000, g: 0.8

Oil, % dry wt: 25.3

References

1. F.R. Earle, Q. Jones, Econ. Bot. 16(4), 221 (1962)

Solanum nodiflorum Jacq.

Family: Solanaceae

Seed

Mass of 1,000, g: 0.8

Oil (petroleum ether, 30–60�C), % dry wt: 25.0

n40D : 1.4688

Saponification value, mg KOH: 180.0

FAs

Composition (GLC on 20% LAC-2R 446), %:

Saturated – 10.0; 18:1 – 20.0; 18:2 – 65.0; 18:3

– 0.8

IR

References

1. F.R. Earle, I.A. Wolff, C.A. Glass, J. Am. Oil Chem. Soc. 39,

381 (1962)

Solanum persicum Willd.

Family: SolanaceaeOil, % fresh wt: 1.6–2.2

d20D : 0.9282

n20D : 1.4558

Acid value, mg KOH: 1.28

Saponification value, mg KOH: 188.8

Iodine value, % J2: 115.3

Unsaponifiables, %: 1.24

Carotenoids mg/100 g: 74.2–82.5

Components: a-Carotene, b-carotene, xanthene,

lycopene, cis-lycopene

References

1. E.N. Novruzov, Rast. Resursy 19, 89 (1983) [in Russian]

Solanum pseudocapsicum L.

Family: Solanaceae

Leaf

Sterols, % dry wt: 0.18

Free sterols, % of total: 25.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterols from esters, % of total: 8.0

Components: Sitosterol campesterol, cholesterol,

stigmasterol

Sterols from sterylglycosides, % of total: 28.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol

Sterols from acylated sterylglycosides,% of total: 39.0

Components: Sitosterol, stigmasterol, cholesterol,

campesterol (the sterols are listed in order of

decreasing concentration)

References

1. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

Solanum sisymbriifolium Lamk.

Family: Solanaceae

Cotyledon

FAs

Composition (GLC, 10% PEGA), %: 12:0 – tr; 14:0

– 1.5; 14:1 – 1.0; 16:0 – 33.8; 16:1 – 2.2; 18:0 –

5.0; 18:1 – 42.1; 18:2 – 14.5; 18:3 – tr

References

1. B. Pandey, S. Manday, D.R. Gadgil, J. Am. Oil Chem.

Soc. 63, 541 (1986)

Solanum toralapanum

Family: Solanaceae

Leaf

Chloroplasts

Free FAs, mmol/mg chloroplasts: 0.39 (chill-sensitive)

Page 50: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.

Solanaceae 922 Solanum torvum

Composition (GLC, 15% EGSS-X), %: 16:0 – 18.6;

16:1 – 5.4; 18:0 – 3.2; 18:1 – 13.5; 18:2 – 11.7;

18:3 – 44.2; 20:0 – 3.9

References

1. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28, 7

(1989)

Solanum torvum

Family: Solanaceae

Leaf

Components, mg (from 5.5 kg dried material):

Octacosanyl triacontanoate – 35.0; tetratria-

contanoic acid – 100.0; 2,3,4-trimethyltriacontane

– 10.0; 5-triacontanol – 350.0; 3-tritriacontanone –

500.0; hexatriacontanone – 20.0; sitosterol; stig-

masterol; campesterol – 900.0

M.p., IR, MS, 1H NMR

References

1. U. Mahmood, Y.N. Shukla, R.S. Thakur, Phytochemistry 22,

167 (1983)

Solanum trilobatum L.

Family: Solanaceae

Cotyledon

FAs

Composition (GLC, 10% PEGA), %: 14:0 – 0.5;

16:0 – 15.6; 16:1 – 1.4; 18:0 – 3.9; 18:1 – 22.5;

18:2 – 54.6; 20:0 – 1.2; 22:0 – 0.3

References

1. B. Pandey, S. Manday, D.R. Gadgil, J. Am. Oil Chem.

Soc. 63, 541 (1986)

Solanum tuberosum L.

Family: Solanaceae

Leaf

Lipids

FAs, % in total lipids: 16:3 (7Z,10Z,13Z) – 11.6 [1]

NL(TLC) [2]

FAs (GLC, 15% PEGA), %: 10:2 – 2.06; 11:2 –

0.28; 12:0 – 0.74; 12:1 – 0.85; 12:2 – 1.09; 13:0 –

5.02; 13:1 – 6.42; 13:2 – 4.51; 14:0 – 6.33; 14:1 –

7.80; 14:2 – 1.07; 14:3 – 1.07; 15:0 – 0.55; 15:1 –

3.70; 15:2 – 4.46; 15:3 – 3.23; 16:0 – 13.68; 16:1

– 3.38; 16:2 – 1.54; 16:3 – 5.72; 18:0 – 2.18; 18:1

– 4.01; 18:2 – 9.07; 18:3 – 3.27; 20:0 – 0.40; 20:1

– 3.01; 20:2 – 4.55

GL + PhL(TLC) [2]

FAs (GLC, 15% PEGA), %: 14:0 – tr; 15:1 – tr;

16:0 – 14.8; 16:1 – 1.8; 16:2 – 0.2; 16:3 – 8.7;

18:0 – 0.6; 18:1 – 1.4; 18:2 – 23.0; 18:3 – 49.5;

20:0 – tr [2]

GL(TLC) [2]

MGDG

FAs (GLC, 15% PEGA), %: 13:0 – 0.1; 13:1 – 0.1;

14:0 – 0.1; 15:1 – 0.2; 16:0 – 2.8; 16:1(3) +

16:1(9) – 0.4; 16:2 – 0.3; 16:3(7;10.13) – 25.4;

18:0 – 1.1; 18:1 – 1.0; 18:2 – 1.6; 18:3 – 66.9 [2]

DGDG

FAs (GLC, 15% PEGA), %: 13:1 – 0.1; 14:0 – 0.1;

16:0 – 10.9; 16:1(3) + 16:1(9) – 0.3; 16:2 – 0.3;

16:3(7;10;13) – 2.1; 18:0 – 2.0; 18:1 – 1.2; 18:2 –

2.6; 18:3 – 80.4 [2]

PhL (TLC) [2]

FAs (GLC, 15% PEGA), %: 12:0 – 0.03; 12:1 –

0.02; 12:2 – 0.01; 13:0 – 0.02; 13:1 – 0.02; 13:2 –

0.02; 14:0 – 0.18; 14:2 – 0.05; 14:3 – 0.01; 15:0 –

0.12; 15:1 – 0.62; 16:0 – 14.46; 16:1 – 7.90; 16:2

– 0.43; 16:3 – 1.64; 18:0 – 2.37; 18:1 – 5.84; 18:2

– 39.47; 18:3 – 25.86; 20:0 – 0.78; 20:1 – 0.14

[2]

PhG

FAs (GLC, 15% PEGA), %: 14:1 – 0.1; 15:0 – 0.2;

15:1 – 0.3; 16:0 – 25.8; 16:1(3) + 16:1(9) – 34.4;

16:2 – 0.5; 16:3(3) + 16:1(9) – 0.6; 18:0 – 2.2;

18:1 – 2.8; 18:2 – 16.2; 18:3 – 17.0 [2]

PhC

FAs (GLC, 15% PEGA), %: 14:1 – 0.1; 15:0 – 0.1;

15:1 – 0.1; 16:0 – 29.8; 16:1(3) + 16:1(9) – 0.8;

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Solanum tuberosum L. 923 Solanaceae

16:2 – 0.2; 16:3(7;10;13) – 0.5; 18:0 – 2.0; 18:1 –

1.3; 18:2 – 30.4; 18:3 – 34.7 [2]

PhE

FAs (GLC, 15% PEGA), %: 14:0 – 0.1; 16:0 – 26.0;

16:1(3) + 16:1(9) – 0.2; 18:0 – 3.1; 18:1 – 2.6;

18:2 – 44.9; 18:3 – 23.1 [2]

PhI

FAs (GLC, 15% PEGA), %: 16:0 – 45.6; 16:1(3) +

16:1(9) – 0.8; 16:2 – 0.3; 16:3(7;10;13) (7;10;13)

– 0.2; 18:0 – 6.4; 18:1 – 3.9; 18:2 – 17.0; 18:3 –

25.8 [2]

DPhG

FAs (GLC, 15% PEGA), %: 14:0 – 1.1; 14:2 – 1.0;

15:0 – 0.3; 15:1 – 1.4; 16:0 – 24.2; 16:1(3) +

16:1(9) – 3.0; 18:0 – 15.0; 18:1 – 14.7; 18:2 –

22.1; 18:3 – 17.2 [2]

PhA

FAs (GLC, 15% PEGA), %: 14:1 – 0.6; 15:0 – 0.4;

15:1 – 0.7; 16:0 – 39.9; 16:1(3) + 16:1(9) – 3.7;

16:2 – 0.4; 16:3(7;10;13) – 0.6; 18:0 – 14.5; 18:1

– 16.5; 18:2 – 16.5; 18:3 – 6.2 [2]

SL

FAs (GLC, 15% PEGA), %: 14:0 – 0.1; 16:0 – 44.8;

16:1(3) + 16:1(9) – 1.0; 16:2 – 0.3; 16:3(7;10;13)

– 0.7; 18:0 – 2.1; 18:1 – 1.6; 18:2 – 6.7; 18:3 –

42.7 [2]

3,7,11,15,19-Penthamethyl-2-cis-6-trans-eicosadien-

1-ol

n20D : 1.4780 [3]

CC, IR, MS, 1NMR [3]

Sterols, % dry wt: 0.20 [4]

Free sterols, % of total: 12.0

Components: Sitosterol, isofucosterol, stigmasterol,

cholesterol

Sterol from esters, % of total: 13.0

Components: Sitosterol, cholesterol, stigmasterol,

24- methylenecholesterol

Sterol from sterylglycosides, % of total: 27.0

Components: Sitosterol, cholesterol, stigmasterol,

24-methylenecholesterol

Sterols from acylated sterylglycosides, % of total:

48.0

Components: Sitosterol, stigmasterol, cholesterol,

isofucosterol (the sterols are listed in order of

decreasing concentration)

Chloroplast

Free FAs, mmol/mg chloroplasts: 0.34 (from chill-

sensitive leaves) [5]

Composition (GLC, 15% EGSS-X), %: 16:0 – 5.7;

16:1 – 1.1; 18:0 – 1.0; 18:1 – 19.0; 18:2 – 7.9;

18:3 – 63.4; 20:0 – 1.6

Tuber

Lipids: 62.7 – 70.1 mg/100 g fresh wt (chloroform-

methanol; as FAs) [6]; 0.10 – 0.11 fresh wt; 0.4 –

0.6 dry wt (acyl containing lipids) [7]

FAs, % (GLC), %: Low molecular acids – up to

5.0; 16:0 – 14.0–25.1; 18:0 – 2.0–5.5; 18:1 –

0.3–3.5; 18:2 – 37.0–62.9; 18:3 – 10.9–38.7

[6, 8]

GL, mg/100 g fresh wt: 13.74–14.87 (as glucose and

galactose) [6]

PhL, mg/100 g fresh wt: 2.23–2.26 (as phosphorus) [6]

Sterols, mg/100 g fresh wt: 4.20–4.29 [6]

Suberin (enzymatically, chloroform-methanol; TLC,

GLC) [9]

MS [9]

Composition of the suberin (from the cork layers of

young tubers)

Total monomers, %: 1-Alkanols C18 - C32 – 11.1;

alkanoic acids C16 - C32 – 8.2; a,o-alkanedioicacids C16 - C32 – 32.7; o-hydroxyalkanoic acidsC16 - C32 – 31.7; dihydroxyhexadecanoic acid –

tr; 9,10-epoxy-18-hydroxyoctadecanoic acid –

0.5; 9,10,18-trihydroxyoctadecanoic acids – tr;

9,10-epoxyoctadecane-1,18-dioic acid – tr; 9,10-

dihydroxyoctadecanedioic acid – 1.5 [10]

FAs, (GLC), %, 16:0 – 4.2; 18:1 – 6.95; 20:0 – 3.47;

22:0 – 14.20; 24:0 – 26.95; 26:0 – 26.08; 28:0 –

31.73 (5% OV 101) [9]; 16:0 – 1.4; 18:0 – 1.2;

20:0 – 1.7; 22:0 – 9.6; 24:0 – 20.1; 26:0 – 29.2;

28:0 – 31.1; 30:0 – 5.7; 32:0 – tr (SE-30; OV-17)

[10]

v-Hydroxy-FAs (GLC), %: Hydroxy-16:0 – 0.59;

hydroxy-18:1 – 95.48; hydroxy-22:0 – 1.10;

hydroxy-24:0 – 1.70; hydroxy-26:0 – 0.81;

hydroxy-28:0 – 0.29 (5% OV 101) [9]

Hydroxy-16:0 – 0.7; hydroxy-18:0 – 5.0;

hydroxy-18:1 – 76.6; hydroxy-20:0 – 0.2;

hydroxy-22:0 – 4.3; hydroxy-24:0 – 6.2;

hydroxy-26:0 – 4.8; hydroxy-28:0 – 2.2 (SE 30,

OV 17) [10]

a,v-Alkanedioic acid (GLC), %: 16:0 – 4.3; 18:1 –

95.6 (5% OV 101) [9]

16:0 – 1.2; 18:0 – 0.2; 18:1 – 98.2; 20:0 – tr; 22:0 – 0.1;

24:0 – 0.2; 26:0 – 0.1 (SE 30 and OV 17) [10]

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Solanaceae 924 Solanum xanthocarpum Schard et Wendl.

Aliphatic constituents

Composition (TLC, GLC), %: 18-Hydroxyoctadec-

9,18-dioic acids – major; alkanols – 6.0; FAs –

8.0; o-hydroxy FAs – 16.0; dicarboxylic acids –24.0 [9]

MS [9]

Alkanols

Components (GLC), %: Saturated C16 – 3.12; C20 –

9.79; C22 – 26.46; C24 – 12.91; C26 – 18.12; C28 –

24.58; monoenic C18 – 4.79 (5% OV 101) [9]

C18 – 4.1; C20 – 1.4; C22 – 40.0; C24 – 18.1; C26 –

13.4; C28 – 23.0 (SE 30, OV 17) [10]

Plasmalemma

Lipids

NL and sterols, %: 48.0 [11]

Galactolipids, %: 21.0 [11]

PhL, %: 31.0 [11]

Components, %: PhC – 38.0; PhE – 47.0; PhI – 15.0;

PhC – 32.0; PhE – 46.0; DPhG – 3.0; PhI – 19.0;

PhA – tr [11]

FAs (GLC), %: 16:0 – 27.8; 18:0 – 8.4; 18:1 – 4.3;

18:2 – 40.0; 18:3 – 8.5

16:0 – 28.5; 18:0 – 7.5; 18:1 – 4.5; 18:2 – 41.0; 18:3

– 17.5 [11]

Microsomes

Lipids

NL, %: 36.5 [11]

Galactolipids, %: 16.0 [11]

PhL, %: 47.0 [11]

Composition, %: PhC – 44.8; PhE – 32.5; PhI –

16.0; DPhG – 1.0; PhA – 3.5; PhS – 1.0; PhG –

1.0 [11]

FAs(GLC), %: 16:0 – 31.0; 18:0 – 7.0; 18:1 – 0.5;

18:2 – 49.5; 18:3 – 12.0 [11]

Mitochondria

Lipids

FAs

Composition, %: 16:0 – 14.7; 18:0 – 2.7; 18:1 – 1.4;

18:2 – 63.5; 18:3 – 16.9 (whole organelles) [11]

16:0 – 24.0; 18:0 – 3.5; 18:1 – 1.8; 18:2 – 58.0; 18:3

– 12.7 (outer membrane) [11]

16:0 – 12.5; 18:0 – 2.3; 18:1 – 0.8; 18:2 – 67.4; 18:3

– 16.8 (inner membrane) [11]

PhL

Composition, %: PhC – 43.0; PhE – 30.0; DPhG –

8.0; PhA – 5.0; PhI – 7.0; PhS – 3.0; PhG – 3.0

(whole organelles) [11]

PhC – 27.0; PhE – 29.0; DPhG – 19.5; PhI, PhS, and

PhG – 24.5 (inner membranes) [11]

PhC – 52.6; PhE – 25.0; DPhG – 12.1; PhI, PhS, and

PhG – 10.3 [11]

Peroxisomes

Lipids

FAs

Composition, %: 14:0 – 2.0; 16:0 – 22.0; 18:0 – 2.1;

18:1 – 4.3; 18:2 – 56.0; 18:3 – 13.3 [11]

PhL

Composition, %: PhC – 61.0; PhE – 19.6; PhI – 4.3;

PhG – 15.1 [11]

Sterols, % total lipids: 4.6 [11]

Steryl glycosides, %: 1.0 [11]

Acylated steryl glycosides, %: 3.6 [11]

Use: Food-stuffs (as potato) [4].

References

1. G.R. Jamieson, E.H. Reid, Phytochemistry 10, 1837 (1971)

2. V.S. Rodionov, L.S. Zakharova, Biokhimiya 44(9), 1706

(1979) [in Russian]

3. M. Toyoda, M. Asahina, H. Fukawa, Tetrahedron Lett. (5),

4879 (1969)

4. R. Duperon, M. Thiersault, P. Duperon, Phytochemistry 23,

743 (1984)

5. J. Gemel, V. Saczynska, Z. Kaniuga, Phytochemistry 28,

1813 (1989)

6. M.J. Fishwick, A.J. Wright, Phytochemistry 16, 1507 (1977)

7. V.D. Tsydendambaev, A.G. Vereshchagin, Appl. Biochem.

Microbiol. 16(6), 824 (1980) [in Russian]

8. T. Galliard, Phytochemistry 11, 1899 (1972)

9. P.E. Kolattukudy, V.P. Agrawal, Lipids 9, 682 (1974)

10. P.J. Holloway, Phytochemistry 22, 495 (1983)

11. P. Mazliak, Glyco- and phospholipids of biomembranes in

higner plants, in Lipids and Lipid Polymers in HigherPlants, ed. by M. Tevini, H.K. Lichtenthaler (Springer-

Verlag, Berlin, Heidelberg, New York, 1977), pp. 48, 171

Solanum xanthocarpum Schard et Wendl.

Family: Solanaceae

Fruit

Triterpenols: Cycloartanol, cycloartenol [1]

Sterols: Sitosterol, stigmasterol, campesterol, choles-

terol [1]

Sterylglucosides: Sitosterylglucoside, stigmasteryl-

glucoside [1]

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Solanum xanthocarpum Schard et Wendl. 925 Solanaceae

Seed

Oil, %: 19.3 [2]

d27: 0.9240 [2]

Iodine value, % J2: 124.3 [2]

Saponification value, mg KOH: 182.5 [2]

References

1. G. Koiwai, J. Beisler, Y. Sato, Phytochemistry 12, 397 (1973)

2. N.I. Sharapov, Oil Plants and the Process of Oil formation(AS USSR Press, Мoskwa-Leningrad, 1959), p. 351 [in

Russian]

Page 54: Lipids, Lipophilic Components and Essential Oils from Plant Sources || Physalis peruviana L.