Light Emitting Device(uday).pptx
Transcript of Light Emitting Device(uday).pptx
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Light Emitting Devices
Assignment:
Semiconductor Device modeling and stimulation
1
Submitted by:
Uday Kumar Rai
ECE Deptt.
ME-modular 2014
Roll no.- 141633
Submitted to:
Dr. S B L SACHAN
Professor &Head
ECE Deptt.
NITTTR-CHANDIGARH
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CONTENTS1. PHOTOLUMINESCENCE AND ELECTROLUMINESCENCE
1.1 BASIC TRANSISTION
1.2 LUMINESCENCE EFFICIENCY
2. MATERIALS FOR OPTOELECTRONIC DEVICE
3. LIGHT EMITTING DIODE(LED)
3.1 GENERATION OF LIGHT3.2 LED EXTERNAL QUANTUM EFFICIENCY
3.3 LED DEVICE
3.4 APPLICATIONS
4. LASER DIODES
4.1 STIMULATED EMMISSION AND POPULATION
INVERSION
4.2 OPTICAL CAVITY
4.3 APPLICATIONS
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Photoluminescence and Electroluminescence
When excess electron and holes recombine, it result
in emission of photon known as luminescence.
Photoluminescence: Photon emission from recombination
process when excess electron and holes are created by photon
absorption, is called photoluminescence.
Electroluminescence: Photon emission when the excitation of
excess carrier is a result of an electric current caused by an applied
field.
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Basic transitions
Once electrons-holespair are formed, there
are several possible
process by which the
electrons and holescan recombine.
Fig 1
(a)_ Basic interband transition(b)_Possible recombination process
involving impurity or defect states
(c)_ Auger recombination process
4Fig_1 Basic transitions in a semiconductor
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The recombination shown in fig 1(a) indicate that theemission of a photon is not necessarily at a single, discrete
energy, but can occur over a range of energies.
The spontaneous emission rate is given as :-
I(v)v2(hv-Eg)1/2exp[-(hv-Eg)/kT]
Where ,
Eg=bandgap energy
h = planks constant(6.625x10-34J-s
k = Boltzmansconstant(1.38x10-23J/K
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Basic transitions
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Light emission
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In certain semiconductors, excited electrons can
relax by emitting light instead of producing heat.
These semiconductors are used in the construction
of light emitting diode and pn junction laser diode.
In these device electrical energy, in the form of acurrent , is converted directly into photon energy.
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Luminescent Efficiency
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All recombination are not radiactive. An efficient is one in which radiactive transistion predominate .
For all process quantum efficiency is the ratio of radiactive
recombination rate to the total recombination rate. Given by
nq= Rr/R
where,
nq= quantum efficiencyRr= radiactive recombination rate.
R = total recombination rate
Since recombination rate is inversly proportional to life time,
the quantum efficiency in term of lifetime is given by,nq= nr/(nr+ r)
where,
nr= nonradiactive lifetime
r = radiactive lifetime
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Luminescent Efficiency
The interband recombination rate of electrons and holeswill be directly proportional to the number of electronavailable and directly proportional to the number ofavailable energy state(holes). Given by
Rr= Bnp
Where,Rr= band to band recombination rate
B = constant of proportionality
The emission of photons from direct bandgap materials
encounter reabsorption of the emitted photons. Possible solution to reabsorption is to use hetrojuction
devices
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Material for optoelectronic devices
Important direct bandgap semiconductor material for optical
devices are GaAsand AlxGa1-xAs. In AlxGa1-xAs the ratio of aluminum can be varied to achieve
specific characteristics as shown in fig_2
Fig_2 Bandgap energy of AlxGa1-xAs
as a function of the mole fraction 9
Fig_ 2 shows bandgap energyas the function of mole
fraction between Al and Ga.
Direct bandgap materials for
0
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Material for optoelectronic devices
Another compound semiconductor for optical device is
GaAs1-xPx
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Fig_3 (a)Bandgap energy of AlxGa1-xPxas a function of the
mole fraction x (b) E Vs k diagram fo AlxGa1-xPxfor various x
Fig_3 shows
bandgap energy as
a function of mole
fraction x
Direct bandgap
materials for
xx0.45
Indirect bandgap
materials for x>0.45
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LED
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When a light-emitting diode is
forward biased, electronsare ableto recombine with holeswithin
the device, releasing energy in the
form of photons.
This effect is called
electroluminescenceand the color
of the light (corresponding to the
energy of the photon) is
determined by the energy gapof
the semiconductor.
Light Emitting diode
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http://en.wikipedia.org/wiki/Electronshttp://en.wikipedia.org/wiki/Electron_holehttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Energy_gaphttp://en.wikipedia.org/wiki/Energy_gaphttp://en.wikipedia.org/wiki/Electroluminescencehttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Electron_holehttp://en.wikipedia.org/wiki/Electrons -
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UV AlGaNBlue GaN, InGaNRed, green GaPRed, yellow GaAsP
IR- GaAs
Light Emitting diode
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Light Emitting diode
Application of forward voltage across pn junction result diode
current flow.
This flow of current can produce photons and a light output in
the junction diode, which is known as LED.
LED may have a relatively wide wavelength bandwidth of
between 30-40 nm.
This emission spectrum is narrow.
Particular color light will be visible if output is in the visible
range14
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Color
Wavelength
(nm)
Voltage (V) Semiconductor Material
Infrared < 760 V < 1.9 Gallium arsenide(GaAs) Aluminium gallium arsenide(AlGaAs)
Red 610 < < 760 1.63 < V < 2.03 Aluminium gallium arsenide(AlGaAs) Gallium arsenide phosphide(GaAsP)
Aluminium gallium indium phosphide(AlGaInP) Gallium(III) phosphide(GaP)
Orange 590 < < 610 2.03 < V < 2.10 Gallium arsenide phosphide(GaAsP) Aluminium gallium indium phosphide
(AlGaInP)Gallium(III) phosphide(GaP)
Yellow 570 < < 590 2.10 < V < 2.18 Gallium arsenide phosphide(GaAsP) Aluminium gallium indium phosphide
(AlGaInP) Gallium(III) phosphide(GaP)
Green 500 < < 570 1.9 < V < 4.0 Indium gallium nitride(InGaN) / Gallium(III) nitride(GaN) Gallium(III)
phosphide(GaP)Aluminium gallium indium phosphide(AlGaInP) Aluminium
gallium phosphide(AlGaP)
Blue 450 < < 500 2.48 < V < 3.7 Zinc selenide(ZnSe), Indium gallium nitride(InGaN), Silicon carbide(SiC) as
substrate, Silicon(Si)
Violet 400 < < 450 2.76 < V < 4.0 Indium gallium nitride(InGaN)
Purple multiple types 2.48 < V < 3.7 Dual blue/red LEDs,blue with red phosphor,or white with purple plastic
Ultra-
violet
< 400 3.1 < V < 4.4 diamond(235 nm), Boron nitride(215 nm) , Aluminium nitride(AlN) (210 nm)
Aluminium gallium nitride(AlGaN) (AlGaInN) (to 210 nm)
White Broad
spectrum
V = 3.5 Blue/UV diode with yellow phosphor
Light Emitting diode
http://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Infraredhttp://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Delta_(letter)http://en.wikipedia.org/wiki/Gallium_arsenidehttp://en.wikipedia.org/wiki/Aluminium_gallium_arsenidehttp://en.wikipedia.org/wiki/Redhttp://en.wikipedia.org/wiki/Aluminium_gallium_arsenidehttp://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Orange_(colour)http://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Yellowhttp://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Greenhttp://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Gallium(III)_nitridehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_phosphidehttp://en.wikipedia.org/wiki/Bluehttp://en.wikipedia.org/wiki/Zinc_selenidehttp://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Silicon_carbidehttp://en.wikipedia.org/wiki/Siliconhttp://en.wikipedia.org/wiki/Violet_(color)http://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Purplehttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Diamondhttp://en.wikipedia.org/wiki/Boron_nitridehttp://en.wikipedia.org/wiki/Aluminium_nitridehttp://en.wikipedia.org/wiki/Aluminium_gallium_nitridehttp://en.wikipedia.org/wiki/Aluminium_gallium_nitridehttp://en.wikipedia.org/wiki/Aluminium_nitridehttp://en.wikipedia.org/wiki/Boron_nitridehttp://en.wikipedia.org/wiki/Diamondhttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Ultraviolethttp://en.wikipedia.org/wiki/Purplehttp://en.wikipedia.org/wiki/Purplehttp://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Violet_(color)http://en.wikipedia.org/wiki/Violet_(color)http://en.wikipedia.org/wiki/Siliconhttp://en.wikipedia.org/wiki/Silicon_carbidehttp://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Zinc_selenidehttp://en.wikipedia.org/wiki/Bluehttp://en.wikipedia.org/wiki/Bluehttp://en.wikipedia.org/wiki/Aluminium_gallium_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Gallium(III)_nitridehttp://en.wikipedia.org/wiki/Indium_gallium_nitridehttp://en.wikipedia.org/wiki/Greenhttp://en.wikipedia.org/wiki/Greenhttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Yellowhttp://en.wikipedia.org/wiki/Yellowhttp://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Orange_(colour)http://en.wikipedia.org/wiki/Orange_(colour)http://en.wikipedia.org/wiki/Gallium(III)_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_indium_phosphidehttp://en.wikipedia.org/wiki/Gallium_arsenide_phosphidehttp://en.wikipedia.org/wiki/Aluminium_gallium_arsenidehttp://en.wikipedia.org/wiki/Redhttp://en.wikipedia.org/wiki/Redhttp://en.wikipedia.org/wiki/Aluminium_gallium_arsenidehttp://en.wikipedia.org/wiki/Gallium_arsenidehttp://en.wikipedia.org/wiki/Delta_(letter)http://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Infraredhttp://en.wikipedia.org/wiki/Infraredhttp://en.wikipedia.org/wiki/Wavelength -
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Light Spectrum
Red, green and blue LEDs
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Generation of Light
E=c/v = hc/E = 1.24/E m
When voltage applied across pn junction, electron and holes areinjected across the space charge region where they become
excess minority carriers
Excess minority carrier diffuse into neutral semiconductor regionwhere they recombine with majority carrier
If this recombine process is direct band to band process, photons
are emitted
In GaAs, electroluminescence originates primarily on p side of the
junction as the efficiency of electron injection is higher than that
for hole injection
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Led external quantum efficiency
Photons can be emitted in any direction.
Emitted photon energy must be hvEg.
Emitted photons can be reabsorbed within the semiconductor
material.
The majority of photons will be actually emitted away from
the surface and reabsorbed in the semiconductor.
18Fig_4 Schematic of photon emission at the pn junction of an LED
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Led external quantum efficiency
Photons must be emitted from the semiconductor to air ie,
transmitted across the dielectric surface as shown in fig_5.
19
The parameter n2is is the index ofrefraction for the semiconductor
and n1is the index of refraction forair.
The reflection coefficient is givenas
= [(n2-n1)/(n2+n1)]2
This effect is known as Fresnel loss
Fig_5 Schematic of incident, reflected and
transmitted photon at a dielectric interface
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Led external quantum efficiency
Photons incident on the semiconductor-air interface at an
angle are reflected as shown in fig_6.
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If the photons are incident on
the interface at an angle
greater than the critical angle
c, the photon experience
total internal reflection.
The critical angle is determined
from Snells law and is given by
c=sin-1(n1/n2)
Fig_6 Schematic showing refraction and total internal
reflection at the critical angle at a dielectric interface
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Led external quantum efficiency
fig_7(a) shows the external quantum efficiency plotted as a
function of p type doping concentration. Fig_7(b) shows the external quantum efficiency as a function
of junction depth below the surface
Both fig. shows that the external quantum efficiency is in therange of 1 to 3 percent.
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Fig_7(a) External quantum efficiency of a GaP LED versus acceptor doping
(b) External quantum efficiency of a GaAs LED versus junction depth
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Led Devices
Direct bandgap material(GaAs)has a bandgap energy Eg=1.42eVand =0.873m as shown in
fig_8
The output of GaAs LED is not inthe visible range.
For visible output, the
wavelength of the signal shouldbe in the range of 0.40.72mand bandgap energy
1.7-3.1eV(approx.)
22
The wavelength of the output of an LED is determined by
the bandgap energy.
Fig_8 GaAs diode emission spectra at T=295K and T=77K
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GaAs1-xPxis a direct bandgap material for 0 x0..45 as
shown in fig_9
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Led Devices
Fig_9(a)Bandgap energy of GaAs1-xPxas a function of
the mole fraction x
At x=0.40, the bandgap
energy is approximatelyEg=1.9eV which would
produce an optical
output in the red range
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The brightness of GaAs1-xPxdiode can be varied for
different value of x (mole fraction)
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Led Devices
Fig_10 shows thebrightness of GaAs1-xPxdiode for different value
of x
The peak brightnessoccurs at red color.
GaAs0.6P0.4monolithic
array has beenfabricated for numericand alphanumericdisplay.
Fig_10 brightness of GaAsPdiode versus wavelength
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when the mole fraction x of GaAsP is greater than 0.45, the material
change to an indirect bandgap semiconductor so that the quantumefficiency is greatly reduced.
GaAlxAs1-xcan be used in a hetrojuction structure to form an LED.
Fig_11(a) shows the structure of GaAlAs hetrojunction LED.
Electron are injected from wide bandgap N- GaAl0.7As0.3to the narrow
bandgap p- GaAl0.7As0.3
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Led Devices
Fig_11(a)cross section of GaAlAshetrojunction LED
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Fig_11(b) shows the thermal equilibrium energy-band
diagram of a GaAlAs hetrojunction LED
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Led Devices
The minority carrierelectrons in the pmaterial can recombine
radiatively. Since Egp< EgN, photons
are emitted throughwide bandgap Nmaterial with no
absorption.
The wide bandgap Nmaterial act as anoptical window.
Fig_11(b) thermal equilibrium energy-band
diagram of GaAlAs hetrojunction LED
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Never connect an LED directly to a battery or a power supply!It will be destroyed almost instantly because too much current
will pass through and burn it out.
LEDs must have a resistor in series to limit the current to a safe
value, for quick testing purposes a 1kresistor is suitable for most
LEDs if your supply voltage is 12V or less.
Remember to connect the LED the correct way!
Testing of LED
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The most popular type of tri-color LED has a red and agreen LED combined in one package with three leads.
They are called tri-color because mixed red and green
light appears to be yellow.
The diagram shows the organization of a tri-color LED.
Note the different lengths of the three leads.
The central lead (k) is the common cathode for both
LEDs, the outer leads (a1 and a2) are the anodes to theLEDs allowing each one to be lit separately, or both
together to give the third color.
Tri-color LED
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An LED must have a resistor connected in series to
limit the current through the LED. The resistorvalue, R is given by:
R = (VS - VL) / I
Calculating an LED resistor value
VS = supply voltageVL = LED voltage (usually 2V, but 4V for blue and white LEDs)
I = LED current (e.g. 20mA), this must be less than the maximum permitted
If the calculated value is not available, choose the nearest standard resistor value
which is greater,to limit the current. Even greater resistor value will increase the
battery life but this will make the LED less bright.
For example
If the supply voltage VS = 9V, and you have a red LED (VL = 2V), requiring a current
I = 20mA = 0.020A,
R = (9V - 2V) / 0.02A = 350, so choose 390 (the nearest greater standard value).29
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If you wish to have several LEDs on at thesame time, connect them in series.
This prolongs battery life by lighting several
LEDs with the same current as just one LED.
The power supply must have sufficient
voltage to provide about 2V for each LED (4V
for blue and white) plus at least another 2V
for the resistor.
To work out a value for the resistor you must
add up all the LED voltages and use this for
VL.
Connecting LEDs in series
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LED displays are packages of many LEDs arranged in a pattern, the
most familiar pattern being the 7-segment displays for showing
numbers (digits 0-9).
LED Displays It is a common anode display sinceall anodes are joined together and
go to the positive supply.
The cathodes are connected
individually to resistors limiting the
current through each diode to a safe
value.
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Wireless telemedicine
The PillCam is a swallow
diagnostic device, taking
high-quality, high-speed
photos as it passes through
the esophagus.
PillCam transmits 14
pictures/sec. to a receiver
worn by the patient.
This enables diagnosis of
throat disease and related
ailments.
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PN JUNCTION-LASER DIODE
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Laser diode
Laser stand for Light Amplification by StimulatedEmission of Radiation.
Laser diode produces a coherent spectral output with a
bandwidth of wavelength less than 0.1nm.
Laser diode are the modified LED in its structure and
operating condition
There are many different type of laser, one of them are pn
junction laser diode.
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Fig_12 shows the different process of stimulatedemission and population inversion
35
Stimulated Emission and population Inversion
Induced absorption: when an
incident photon is absorbed and
an electron is elevated from E1to
E2
Spontaneous emission: theelectron spontaneously make the
transition back to the lower
energy level with a photon being
emitted. Stimulated emission : there is an
incident photon at a time when
an electron is in the higher
energy state.
Fig_12(a) induced absorption
(b) spontaneous emission
(c) stimulated emission
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In thermal equilibrium, the electron distribution in a
semiconductor is determine by the Fermi-dirac statistics. If
the Boltzmann approximation applies, then we can write
N2/N1= exp[-(E2-E1)/kT]
where
N1=electron concentration in energy level E1
N2=electron concentration in energy level E2
E2>E1
In thermal equilibrium
N2
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In thermal equilibrium (N2N1. this is called population
inversion.
We cannot achieve lasing action at thermal equilibrium.
37
Stimulated Emission and population Inversion
l d d l
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Fig_13 shows the two energy levels with a light wave atan intensity Iv, propagating in the z direction.
The change in intensity of z direction can be written as:-
dlv/dz (3 photons emitted/cm33 photons absorbed/cm3)
or
dlv/dz=N2Wi.hv- N1Wi.hv
38
Stimulated Emission and population Inversion
where
Wi= induced transition
probability The equation assume no
loss mechenism and neglects
the spontaneous transition Fig_13 light propagation in z directionthrough a matrial with two energy levels
l d d l
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We have
dlv/dz=N
2W
i.hv- N
1Wi.hv --------------(1)
which can be written as,
dlv/dz =(v)Iv -------------------------(2)
where,
(v)Iv (N2-N1) is the amplification factorFrom equation (2),
Iv= Iv(0)e(v)z -------------------------------(3)
Amplification occurs when,
(v)>0 and
Absorption occurs when,
(v)
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we can achieve population inversion and lasing in a
forward-biased pn hetrojunction diode, if both sides of thejunction are degenerately doped.
40
Stimulated Emission and population Inversion
Fig_14(a) shows theenergy band diagram of
a degenerately dopedpn junction in thermalequilibrium.
The Fermi level is in the
conduction band in then region and the Fermilevel is in the valenceband in the p region.
Fig_14(a) degenerateely doped pn
junction at zero biased
S i l d E i i d l i I i
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Fig_14(b) shows the energy bands of the pn junction when aforward bias is applied with photon emission.
41
Stimulated Emission and population Inversion
The gain factor in a pn hetrojunction
diode is given by:-
(v) {1-exp[(hv-(Efn-EFp))/kT]}--(4)
in order for, (v)>1 we must have
hv
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Optical cavity help to achieve the coherent emission output
by causing buildup of the optical intensity from positive feedback.
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Optical cavity
Fig_15 shows the optical cavityfabricated by cleaving a galliumarsenide crystal along the (110)plane
The optical wave propagatesthrough the junction in the zdirection, bouncing back and forthbetween the end mirror.
Only partial optical wave is
transmitted out of the junction. For resonance, the length of the
cavity must be an integral numberof half wavelength
N(/2)=L Fig_15 a pn junction laser diode withcleaved(110) planes forming the Fabry-
Perot cavity
Stimulated Emission and population Inversion
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There can be many resonant mode in the cavity, fig_16 showsdifferent resonant mode
43
Stimulated Emission and population Inversion
Fig_16(a) shows resonant mode
as a function of wavelength
Fig_16(a) resonant mode cavity with length L (b) spontaneous curve (c) actual emission modes
Fig_16(b) shows spontaneous emissionwhen forward bias current is applied
Spontaneous emission is relativelybroadband and is superimposed on thepossible lasing mode
Fig_16(c) shows lasing mode which canoccurs at several specific wavelength.
Lasing will initiate when spontaneousemission gain become more than theoptical losses
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Radar/Laser Detectors
A radar/laser detector is a combination of a radar detector,
which senses radar in the air, and a laser detector, which looksfor laser beams directed at your car.
A laser beam is a very focused
beam of light that does not
separate out from its beampath.
Fortunately, there is a lot of
dust and fine particles in the air,
which causes the laser beam to
separate enough that the
beams can be seen by a proper
detector.