LEVENOL® - Kao Chemicals Eu...ANIONIC 50% NON IONIC 35% Coconut Soap 15% LAS/LES 60/40 Market...

KAO Chemicals Europe

Surfactants for Consumer Applications

October 2013

GREEN INGREDIENT TO FORMULATE

SUSTAINABLE HOME CARE PRODUCTS

LEVENOL®

2

• EU Trends in Home care

• LEVENOL® range

• LEVENOL®F-200• Benefits in formulation

• Summary

Content

EU Trends in Home Care

Towards a sustainable and eco-friendly cleaning …

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… saving time, energy, water and money.

Source: Mintel Executive summaries 2012-2013.

EffectivenessEco-friendly

productsConvenient

formatsEconomic

lines

4

LEVENOL® range

From nature...

to surface active agents

Based on Ethoxylated Glycerine Ester Derivatives

LEVENOL® are green multifunctional non ionic surfactants

CH2O(-CH2-CH2-O)x- R’I CHO (-CH2-CH2-O)y- R’I CH2O(-CH2-CH2-O)z- R’

x+y+z = EO number

R’: H or R-CO

R: coconut chain

Product Concentration

(100% Act)

Vegetal Origin

Eco-toxicological Profile:NON LABELLED Product

ToxicologicalProfile:NON LABELLED ProductCarbon & Water Food Print Reduction

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LEVENOL® range: Product Profile

6

LEVENOL® range

LEVENOL®C-421 Glycereth-2 Cocoate



LEVENOL®F-200 Glycereth-7 Cocoate

Outstandinghydrotropic properties and ECO-toxicological profile

Did-list nr 44 Registered in Bra Miljöval Suitable for ECOLABEL formulas

Liquid Product

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Benefits in Formulation

Product Properties

Hydrotropic Ability

Non Labelled Material

Energy saving

Easy to Handel

even at low T

Formulation Aid in Concentrated HDLD

Solvent reduction or

avoidance

Formulas with better Eco-toxicological profile

Advantage to prepare non labelled

and ECOLABEL formulations

LEVENOL® F-200

Easy to handle, even at low temperature

Pumpable below 0ºC - COLD Processible

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DROPPING POINT

CLEAR POINT

-100ºC

10 20 30 40-5ºC

Dropping point

Clear point

LEVENOL®F-200

22ºC

Dropping point

C1315-7EO

35ºC

Clear point

T (ºC)

LEVENOL®F-200: Product Handling

LEVENOL®F-200: Hydrotropic ability

Formulation benefits in liquid Laundry detergentsGood compatibility with other formula ingredients

x3 concentrated HDLD

Reduction or avoidance of solvents

Market products 8 – 15% solvents

Liquid Tablets

Glycerine as solvent

Market products 20 - 25% solvents - PG present

Avoidance of glycols

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ANIONIC 50%

NON IONIC 35%

Coconut Soap 15%

LAS/LES 60/40

Market products:

8 – 15% solvents

L.F-200 C1315-7EO

10

0% PG 0% PG 8% PG

Solvent Free

Clear Turbid paste Clear

With std NI, clear formulas need hydrotrope addition

Formula characteristics

Other: builders, enzymes,

optical brighteners…

pH 8.0 – 8.5

45% active matter

Usage in x3 concentrated HDLD

Non solvent required to obtain clear formulations

Formula appearance


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Surfactant effect Enzyme activity

Mean value: E101, E104, E125, E141/2, wfk10D, wfk10TE, wfk20D

Mean value: E112, E116, E117, E123, E160, E164, E165

Cleaning efficacy at 20ºC

% Soil

removal

Wash conditionsMIELE Softtronic

W5722Sint/mix, 800 rpm

2kg ballast Mkt 1 Mkt 2 KAO

Usage in x3 concentrated HDLD

Competitive performance at COLD wash temperature

Dosage

35ml / wash

0

20

40

60

80

Market 1 Market 2 KAO Mkt 1 Mkt 2 KAO0

20

40

60

80

Market 1 Market 2 KAO


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Glycerine Glycerine Propylene Glycol

Clear Turbid paste Turbid

anionic LAS

anionic SLES

Clear Phase separation Clear

Formula appearance

Glycol free

L.F-200 C1315-7EO

With std NI, clear formulas need glycol addition

Usage in Liquid Tablets

Non glycols required to obtain clear formulations

ANIONIC 28% 31%

NON IONIC 42% 54%

Coconut Soap 30% 15%

Formula characteristics

Other: builders, enzymes,

optical brighteners…

pH 8.0 – 8.5

60 - 65% act. matter

18–23% Solvent

<10% Water


LAS SLES

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Mkt 1 Mkt 2 KAO KAOLAS LES

Mkt 1 Mkt 2 KAO KAOLAS LES

Usage in Liquid Tablets

Competitive performance at COLD wash temperature

Surfactant effect Enzyme activity

Mean value: E101, E104, E125, E141/2, wfk10D, wfk10TE, wfk20D

Mean value: E112, E116, E117, E123, E160, E164, E165

Cleaning efficacy at 20ºC

% Soil

removal

Wash conditionsMIELE Softtronic

W5722Sint/mix, 800 rpm

2kg ballast

Dosage

35ml / wash

0

20

40

60

80

Market 1 Market 2 KAO LAS KAO LES

0

20

40

60

80

Market 1 Market 2 KAO LAS KAO LES



Formulation example: neutral pH APC - ECOLABEL

Criterion 1 -Toxicity to aquatic organisms

CDV Critical dilution volumeDF Degradation factorTFchronic Toxicity factor

based on chronic toxicity on aquatic organisms

0,00

0,04

0,08

0,12

0,16

DF TF chronic

C911-9EO LEVENOL F-200Non ionic contribution

140,00

0,04

0,08

0,12

0,16

DF TF chronic

C911-9EO LEVENOL F-200

0,00

0,04

0,08

0,12

0,16

DF TF chronic


LEVENOL®F-200: Non labelled product


Formulation example: neutral pH APC - ECOLABEL

Criterion 1 -Toxicity to aquatic organisms

CDV Critical dilution volumeDF Degradation factorTFchronic Toxicity factor

based on chronic toxicity on aquatic organisms

LEVENOL®F-200: Non labelled product

CDV chronic

150,00

0,04

0,08

0,12

0,16

DF TF chronic


0,00

0,04

0,08

0,12

0,16

DF TF chronic


Product as it is

Diluted in water (12g/L)

Classification limit

52000 L

18000 L

Product as it is


0

20.000

40.000

60.000

product as it is product diluted in

water (12g/L)

0,00

0,04

0,08

0,12

0,16

DF TF chronic


0,00

0,04

0,08

0,12

0,16

DF TF chronic


Product as it is


Classification limit

52000 L

18000 L

Product as it is


0

20.000

40.000

60.000

product as it is product diluted in

water (12g/L)

Summary

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Green ingredient Vegetable origin 100% concentrated Non labelled product

Product handling

Easy to handle, even at low temperature COLD Processible

Hydrotropic ability Reduction or avoidance of solvents in

concentrated HDLD Avoidance of glycols in liquid tablets

Good Eco-toxicological profile

Suitable for non labelled and ECOLABEL formulations

LEVENOL® range

LEVENOL®

F-200

Thank you

very much

for your

attention

GREEN INGREDIENT TO FORMULATE

SUSTAINABLE HOME CARE PRODUCTS

LEVENOL®

LEVENOL® - Kao Chemicals Eu...ANIONIC 50% NON IONIC 35% Coconut Soap 15% LAS/LES 60/40 Market...

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