0000043

EpA Region 5 Records Ctr.

227903

FINAL REPORT ON THE BENNETT'S

QUARRY DIOXIN SAMPLING

BLOOMINGTON, INDIANA

IND057393753

TDO#R5-8109-03I

March 25, 1986

ecology and environment, inc.Ill WEST JACKSON BLVD.. CHICAGO. ILLINOIS 60804. TEL. 312-463-9415

Imtmmiond Spccalira in ttw Envitoomtrn

M E M O R A N D U M

DATE: March 18, 1986

TO: File

FROM: C. F. Bieze, Jr.

SUBJECT: Indiana/TDD R5-8109-03I

Bloomington/Bennett's Quarry-Dioxin Sampling

In accordance with the elements presented 1n Technical Directive

Document (TDD) R5-8109-03I, Ecology and Environment (ElE) Region V

FIT personnel conducted sampling activities at the Bennett Quarry in

Bloomlngton, Indiana. The primary objective of the work was to

obtain representative soil samples to be analyzed for dioxins and

dlbensofurans. Soil borings with subsurface sampling and surfldal

soil sampling techniques were utilized to achieve the sampling

objectives. Soil borings were performed by a subcontracted soil

drilling/engineering firm. Field work was coordinated with similar

sampling tasks at the Lemon Lane and Meal's Landfill site, both also

in the Bloomington area (Figure 1). A separate letter report has

been prepared for activities at the latter sites.

Operations at the Bennett Quarry began on October 30, 1984 with the

collection of two surfidal soil samples (E 13 and E 14) fro*

off-site points east/northeast of the former fill area (Figure 2). A

background sample (E 12) was collected from a nearby city park for

baseline data comparison. Sampling locations were selected after

consultation with Mr. Walter Nied, U.S. EPA site project manager.

Samples were collected in accordance with established U.S. EPA dioxin

sampling protocol, utilizing pre-assembled sampling kits and

disposable stainless steel Implements. Samples were bottled, sealed,

and sent to U.S. Testing Company, Inc. to be analyzed for dioxins and

0I" furans. U.S. EPA cha1n-of-custody procedures were followed

throughout all phases of sample handling. Sample analyses and QA/QC! data are presented 1n Appendix A.I

Subsurface soil Investigative work took place on November 7, 1984. A• vehicular mounted drill rig was utilized to advance hollow stem, augers to the upper surface of the bedrock. Sampling procedures; formulated in conjunction with W. Nied and Dr. Richard Powell

(consultant/expert witness to U.S. EPA) were as follows: (1); continuous soil sampling with a split-spoon sampler; (2) close

^ scrutiny of each sample, with segregation of any visible ash layers) and/or burned materials; (3) mixing of segregated ash/burned material

to form a composite sample - remaining portions of the original soil• sample(s) were discarded.

The original scope of work called for a single soil boring with ash<_>' layer sampling at the site. The location of the boring, as selected

by Dr. Powell, was in the northeast portion of the site, at a pointapproximately 70 feet northeast of previously installed boring, B-9(Figure 2). The new boring (DF-1) was installed, but was quickly

•

i terminated by contact with the bedrock surface at 4.5 feet. Acomposite soil sample (E25) was collected from the three split-spoon

** samples taken from the borehole. No ash layers or burned material' were observed in any of the samples. The boring position was thent offset to a point approximately 25-30 feet northeast of 89 andI redrilled. This boring (DF-1A) was terminated at 6.5 feet, again due. to auger refusal on bedrock. Auger cuttings from the boreholei contained evidence of likely PCB contaminated refuse, including:

pieces of capacitors, capacitor binding,insulation (i.e., yellow andI silver "paper"), pieces of brown ceramic insulators, and oil. No

split samples could be retrieved below 4.0 feet due to the debris•• encountered. Logs for borings DF-1 and DF-1A are attached in

Appendix B.

SAMPLE ANALYSES RESULTS

Results of analyses for dioxins in the three on-site samples and the

background sample are presented 1n the table below. No furans were

detected 1n any of the samples.

Sample Description Tetra Penta Hexa Hepta Octa

1339E-12 Background Surface Soil N.D.1339E-13 Surface Soil 0.2J1339E-14 Surface Soil N.D.1339E-25 Subsurface Soil (Composite) N.D.

N.D.

N.D.

N.D.

N.D.

N.D

N.D.

N.D.

N.D.

N.D.

0.04

N.D.

0.3

0.3

1.3

1.5

3.3

J - Indicates estimated value

Results show that three separate dioxin isomers are present in thesoils at the Bennett Quarry site. As expected, the higher chlorinatedisomers, in particular the octa form, are most prevalent. Note thatthe octa isomer was also detected in the background sample from thepark. TCDD (tetra Isomer) was detected in one surface soil sample, butflagged as an estimated concentration due to a QC protocol.

83J:4F

V'I

limMi^m

UNITED STATTS E N V I R O N M E N T Ai PFO11C1O'.1 ASENCYr£G1DSV DECEIVED MA.; o 3

n .

n. Revle* ef Region V CLP Datafor E*view en

/ _/IP

. Curtis Ross. Director (5SCRL)C«ntr*l Regional laboratory

Data Vier:

Ke htvc rtvie^ed the tfeta for the

'' SITE KV'I:1

S?O Triffick

CI.P

ho. ofXj C B S C Ho.

^ £PA Deta S«t Ko.

hrj .for Review:

fir.dinjs." o A.

. L

D*l» are acceptable for w«.Dtta ere acceptable for use wUh qu»TUk»t1ons noted abo^.Dita fcrc ore* iff^»iry - psndfn; v e r i f k a t l o n ^ Contractor Laboratory.

are unacceptfible.

cc: Dr. Al f red Kaeberer/J&an Fisi/Gery t'srd, EPA Support ServicesRoss K. F.obeson. EKSL-Lis VegasDon Trees. CLP/Siirfle Kdnagerent Off ics

rev > TO

APPENDIX A

SAMPLE ANALYSES RESULTS

Illecology and environment, inc.Ill WEST JACKSON BLVD.. CHICAGO. ILLINOIS 60604. TEL. 312-663 9416

! . Intirnationil Sp*ei»lii» In th» Environmentt

Date Received for Review: 3-3-8(r> Date Review Completed: 3-4-8(=>

TO:

: FROM: Suzanne Kozlowskl

I SUBJECT: AJcaVs L.F. , Lc^^c^ Li*^, 6*^n*Jt Ou^-rv

*** Sample Description: Case I 5A-S /33^ 2k /o^, Soil

Project Data Status: (?>„

FIT Data Review Findings:

Addi t ional Consents:

Book No.

Page No.

-

fir-

l»lt Wild 11*1(1 ICIIIM CWTMI, INC.

[»» Mi DIU

M.I

irrwi milt (•»»*»* n,

tf in M

nc/m «tmicn

tn,II

nm oinm nnni-tiiinr iiimr on

n:i[ 01inn-otDI1(.gt-HIjm ainm ii

iinr «iI11K-IOiiM-iiinn i?inn- n

iini-Huin-14 »nnt-iiurn-itiivu-ii

iiw-iiinr i»IJVM-?IHW-7Murn n

[II '1 (MMMil CM Mr

11/11/1110/71/1111/71/1110/11/1110/11/1)

10/71/1111/71(1111/21/01IO/71/I)H/J1/I)

10/71/1110/21/1111/71/1110/71(1110/71/11

14/71/1110/71/0111/21/1114/71/11II/11/I)

10/71/1111/71/1110/71/1114/71/1) C/C11/71(11

M mwyMl IIIVMI!

ll.lll.lll.lll.lll.l

ll.lll.lll.lll.lll.l

ll.lll.lll.lll.l10.1

ll.lll.lll.lll.lll.l

1.111.1ll.lll.lIt.}

MAI. H II Mir UK 171/171 117/111 **l. 1ICM 111 111 lit 170- 11} III MmMI

i.*j* irt n/04/11 DID .11 .it i.ii 111 1111 mi i nut mm i7i7ii'n .1 111 II/I//M HID .11 .M i.ii 11 -mi/ 7i4ii i (tun IMUI mmn .1 ict n/04/11 HID .M .77 I.N 111 flitf in? i )m mm nun 1*1*11 : •n .11 id II/I//DI HIM .11 .11 •I.M /.Mm /«)> «7 in in i mm mill » miM II ID ll/ll/tt IMl .M .11 1.11 0''!' 11 III 111)41 1MIM )IIO«t.- ,

II .1 Ift 11/14/11 Dill .11 .It l.ll III 1 1 1141 111141 7>tl)1 HUH 'Kl -. .t ICt ll/tl/l) IMM .11 .7) l.ll III 11141 1 1 11711 1*1*11 77*71)(jV) ICt 11/14/11 71lll .>! .1) l.ll III Itlll ItWI 11141 114*1 1(10*1 }|)«U '

ii .in it* ii/ii/n HIM .u .» i.ii 111 uti loti i r«)i D1411 umtHI .In ICt II/IVH 11141 .11 .11 l.ll III 111) 1 I 11411 II1I1I 1/1114*

in .1 ui 1101/11 iiii: .11 .ii i.ii 111 iitti i i mil UDii 1*1111 ' jHO .1 1C) 11/47/11 70-I1 .11 .It l.ll 1| 111/ I HI .11111 /5»)1 tllllH .1 If* ll/tl/11 Oll71 .41 .11 |.|| (I) f Illl 1)111 1111*1 1*1117 l«»tft'.M .] Ifk ll/OI/ll Itill .01 ,tl 1.17 11 III |7lltl 144U7 )|irt( T) 1C* 11/14/11 (till .11 .It l.ll III 17111 17111 Hill 111111 trtir) I30IW

III JOfli '" II/0//I1 IliM .N .11 l.ll III I 1 imi| 7*1MI 171111 701701 'li\Oy/Vir* 11/01/11 lli*l .11 .11 l.ll 111 - 71141 Itlll JUII 1)7111 71/111 UIMt

II .7. II* 11/04/11 IMl .11 .11 1.11 1| | UN | i;i1t| HI5I7 IIMMn . 1C* ll/ll/l) Hil) .N .11 l.ll III III Hill] 1111(7 (15)11 . i•1 . ICt ll/tl/11 Hill .M .11 I.M III I |7ltl 17141 nil/} (7111! tMICl

in . irt n/or/ii 7H14 .11 .11 i.ii in i KID ;HJI unu UIDI OMIINI . if. n/«//r. i»iM .10 .11 I.H HI tit 1*111 i77»i itin'II . ^ II* ll/IVr. (till .11 .11 I.H 11 Ultl H4KM 1 IIU14I 1141(111 (1I7J-* &ii . 47W ii/41/ii HIM .11 .» t.it i iii ]fl»n Hum mint fM . itt u/i)/n iiiii .u .it i.ii in 11*74 i i ie»i5i nun 111*01

C/C- C«rlitpiM • l>l|tn|f • TiilMI • N<ll>» Illl

< In i»«lrM<lll»

I

Ji-

Mill Mint i i . . . ITTIT h 111/171 mi W irrcll 1V/177 Ml W VIC

1/1 ih , - /

-o

M.I

nr»i*it

•i Hiii «•*•*•» n, mi

CM.WKI cr III-N

tentin* HI it

l|rml ««. M.

» ffi. 101 MM m suMowit

UK IK/111 111/])*. ««. I «C't

(•IKUIII riW Htl W NICM1• ••n*mt«t*>«t«v«t«r««i ••••••••••

in n» J7i- . in

UJII-JJ

IHH-'fliim-n

MlMl

It/M/ll10/71/1)

ll.lll.lll.l

I,0:,1

1.1ii.iii.iii.i

MHI

MNI•I

"1HI

wMl

.1

.1

.1

.1.1

.1

.11

.1!

.1

Kt1C)1C)U)1C)

1C)1C)1C!IC4

II/II'I)u/ii/n<inr/»

llfO'SI)

ii'iifiiIUI//I1it/ir/iiiifi*/i)

lllM1IH1Hi 11111!}Mill

Dill1M1III 111*1*1

1.10I.Ml.llI.MI.M

l.ll•.MI.MI.M

.11

.11.11.11n

ii110111

i.it1.71I.M1.11«.1»

x?»°<<?iI.M g,I.M V1.11

illn

IM1111

>c „W III

I0«

11

lit

III

1 *niI 111)I IIPII

III)I1»

1 1)0171. 41IU1 I11H

1*J)»IIU*

HillIM11

IITJ't

141111

mowintii157111111 nHIM

110*1111101}j;0]»»»»}1«

linn

ixirMill .

11*211 • -

C/C> Ci'keiik/Crllttt| • fcriftnl Hint

• Kill** l»l'«ll|H1

lll\l (l ink>ot it if (

lull

iCorrtctrl Iir ceilriltliM ki Illltt Kill ".II •' •/! 121 tittriclt4.

It ))«/ni OUI Of 5'fCIt tt'/ui oui K snc(I SAW it MWIMS «tl|IIO«H

'•it

UNITED STATIS ENVIRONMENTAL PROTECTS* AGENCYREGION V

:t few cf Region V CLP D*tadeceived for Review en s

'1 tls RCJS. Dirtctor (5SCRL)Regional Laboratory

I have reviewed the data for the following

.&!, A^» . SXD Case Ho.»o. of

^A Data S«t Wo._^l_£^£ _ Stales;. ^^ fiurisr*

XI Me.

0 Traf f ic ho.. f - r- - hrs. fi

LP Laboratory. £S • - /^ZZvr* _ for Revte*: /O

ire our findings.

Q /<.

TO

Data are acceptable for ute. .'Dita are acceptable for use «Hh qualincattc-rs noted alcv*.D*ta &re preliminary - pending verification by Contractor laboratoryData are

CC: Dr. Alfred Kaeberer/Joan Fist/Gary Uard, EPA Support ServicssRoss K. Robeson. D*.SL-l»s VegasDon Trees, CLP/Si^lt Ktnagersnt Offics

x- >.^DIOXIN>IBOhCf« DATA PCFORT FORM

TCT^A, PEN1A t> HEX A

• •• v • > - . -

.;'.'; • . LABi United Bt«t*« T««Ung Co., Inc.

•ij .': j CA6G NO I GAB 13396

1 . '?• -:•;. BATCH/SHIPMENT NO. I

Ruport 0»t«i 0*c«*b«r 26, 1983

CnluMil CP 6IL-68

:;t: r •!-;. ' ' '. ;• SAMPLE

'.•'; ;';.',-':..v!i / 1339E-OI-N; '••'.£ •'•:•".-•;.:; i339e-O2•-•. l-i'.vVf i'.» '. ~t 1 339E-02-N

''.- •.''.*':')••'•,!"''< 1339E-03

'":,•-.;:'. '' '•'•, ':•'! 1339E-04D».'•.•;•••• ;..;''• -it 1339E-03".'.; i •;;.!'•/;.[; 1339E-06• ; '•»' :.!>•'">' •',:'• 1339E-O7•/I' IX-':;.'-. v' 1339E-OB'••.•I.'';", i1 '••'"• 1339E-O9;.'.'..'::./;.'!: 1339E-IO|> «<:• t .i :i'r. " 1339E-1 1• •'.ijJ.j: .v'k .V | 1339E— 12'••;': •.. -.' !.'; i !'•>' • ; [T339E- 1 3)"»: ':'.'.>"' •*<" • 1 1339E- 1 4.;'•; &'• '-«'.'»';• 13J9E-1S'•." ' '"•' '••", , 1339E-I6V V':':: i; '/•:.'•• I339E-I7'."•:V«'i-!' V'lV;'-.! »339E->8•»)*'•"•;' "'i''- /.'* ' ' 1339E— 19-:: 'i

:i'>;:i ;iX''j« 1339E-20•i'l:--- '"'• V V"'.!'' 1339t-20-R' V ..'•• .V •;•'•. ,'i ' i 1 33VE-2 1j ;{"*•". "'j :-t •/'.: 1339E-2IOi'j-, ! !.'•• '• !';•'' I33VE-221-,' /.•'• ;.'>:','.'! 1339E-23' ' K'V >:.Vi'-i • 1 339E-24"/ /"•••- "V''; C»3^9E-231('.:.'5i.'<V." r.|. *:?V I339E-26

'jiV'-'j-i''.''/!;'-;.' RD1

ss i RB3**"*." *• •"* *•• i i' *• * * *

»"1 "••.*.'• rt* *"•••*

320

0468922

O479424

O

O000O0O00

277600000O0000O0O0O0000

322

0430970

0397232

0o00000•o'o00

37360000O0O00O00o00o000

TOTAL

334

O136639

O203328

0o00o0oo00ooooo

33733OO0OOO

200192OOO0O00

AREAS

334

. O248640

0303816

OoOo00ooooo0oo0

58408OoO --

• 0O0

• 338732O00

.' 0o00

I f , t

1

TOTAL IBOriER O.A68

390

. 079633

029874

0000o000oo000o000

.- . . oo

': 0O0oo

. 000000

392 332 334

043243

023040

0000000000oo0oo00O00000o000000

1471103030683343631777024319032832182G64342V9739160692K'94221430941733687363936193234467267917332331234333238087247IIO4369132622O4

1303610011364301916392430861O992O1328196991747309190011160003220340371907

17020664290441367622464238363034396434 4 MOO333324276213I67*/301799Q4198834934376686963112968384067OO20I44669349331260040643033O76O38

194223C.O2113140244002284', 37142144I897r.48742760628234^53193992268399731609

AL10UOT WT. (go)

10. 1IO.O10.110.210. 1IO. 110. 110. 1IO.O10. 110. 110. 110. 110. 110. 110. 1IO.OIO.O X)10. 1 m

.10.1 k1

' 7-° rn10.0 li!10. i *C10.1 rn10.2 O10. 1 ~r10.1 S10.0 ;:?IO.O oIO.O3.0 tO10.0 --,10.0 £310.0 ««

V 4f+«/

TC7RA

MO(X rPNTTGjT* riRir

NDNDNDNDNDNDNONDNDMp

.2 ^ND —NOND .NONDNDNDNDNDNONONDNDNONONDNDND

r,r-rw

(PPBI

PENTA

1 -"/ vJLM

)ND_<&ANONDNONONONONONONONDNDNONONO

JtfU

NDNONONDNO

J O-N

no"'NDNDNONO140ND

«""

• m - ~+

IICXA

N ND*\>&.y

— » 5iP O--T;DIIDUKtintinnnnoNOtlGtiDtiptlD~toIII;"

l'f

i nr,tIDIII)|j;j

tonr,

f/itS nr\f. // fj;)

'» III)nr.n:;n:rr.n:ND

**S*H(L

.- ^ • • • ' _ : • • . •

( - ',-.) (

'.•{'&''''•:'••'•'• LAB| United Bt«t«* l«tlng Co., Ine.

':'{" -':,-;.' CASE NOi BAB 1339E

DIOX|H>I6OHER DATA REFORI FORMICPTH I. OCTA ISOHFR8

BATCM/BMIPMENT NO. 1

Report D«t«l DoQcobar 2*, 1983

ColumnI OB-3

TOTAL AREAS TOTAL IBQHER CLASS

lV£ 6AHFLE

JM/.'I 1339E-01<'•;.«; 1339E-02'f\lXf 1339E-03..:iV,' 1339E-04-•. 'JV 13H9E-03 . '*'•••'.. I339K-O*.t':'/7 I339E-07'.•'•'•;• ' I339E-OB->/i 1339C-09'"•'f- ' IJ7W-10'.•I- I339II-IO-N'**';' 13J9I"— I !••)'•.,.' J319E-12',-jft [I3.WE-13-

l;j?:V I339E-I31

,J;-!- ' I339E-I*. .'-•'.'1 . . I339G-17-,V! J33-7E-JH-ky;)l 1339E-19'ijr1,."' .' I339E-2O •' !l.jIM : I319E-2O--0' if* I339F— 21tjif4 M ' '

/•fill ' 1 339E—22 ''*','?• ' 133*C~25«.... .

'•V' Ll'33"'C~23 " 'i'i|>. I319H-2* '.V.C' 'nni. .• v.' .• * 1 ^ j

424

0o

8332032*

0o

13143IA4440104

O224496

OO

327OO00O00O0

DA930O

•• • o7360

0I- . • O

42*

OO

3I4O

**120O

112421 26<l*721*

0loion

' 00

2397OO0OOO0O .

*73*0 ,o • .o ••'

7O2O .O

. 0 ,

i

4 as

193200

3940336BI*6990

4367*07264'Jl'J'lt*H40?0

01 7A9r,14414497O

21172'/A in

123420OO00O

31420 '00

1*2300

: . .0

.

4*O

211680

4301**OQS*

70014747293*332233767941

0lonoo159735320

233131016714030 •

000. '0

• 0 ."0 •

293B . '0 ...00 i

17130 .0

': O

. • • i l

472 Al

3K.4B730*

44374949B9

401441729733533IO4433094

*3*43309A41204S23J2301472076B19*4010*737026032320

329Q1427 •004

4*3013420 '.B0O2

197101*909002R

12912 . ..»

.IQUOr MT. <qi

10.1

10.1

10. I10. 110.1to.o10. 110. 110. 110. 1IO.O

10. 1ffl.l10. 1IO.OIO.O

10. 110.1

7.0,IO.O10. 110.1

10.210.1

IO.OIO.O

IO.O3.0

IO.O

• ) HEPCA

NOtjD

<^q^T3(* o!oTRfliIIP21o

^ O'. <j^ ^7lO

•NllJl- 5^ <

III!

\w

Ml»(>

MilNl)Nl)Nl)MONl)

JilX.CjTjj£^

Nl)Nnfan

<CuT^MilNl)

OC

<ZLNO

<t 3cS£\A. I

^^/^^^

c^Tuc^.*ijsr

f^i.a!^^^^^T_0*17:cjuif~ * . *.f • •' '

NONONONONOtjB —

dl?;

NO ~

N0»,

olz;MO1(0

TA

>

)sssS5>>>a

T7X*lE i>_y]^» *

mrnS

°»

V.

• LABi United St*t«« T»tlng Co., Inc./

.'. CAfiE NOi SAB I339E

BATCH/SHIPMENT NO.I

LFURANJISOHER DATA REPORT FOKHTRA, PENTA t. HE IIA JSOhEAS 1

Report D«t«i Oocn«b«r 24, 1983

Columni CP BIL-BB

TOTAL AREAS TOTAL IBOHER CLASS (PPB)

:.'•?'• . SAMPLE* * '*•- •

•*?•'/'*' Vij '1339E-01

:&'; 1339E-01-M'•'••• i 1339E-02; ;••:- 1339E-02-N

. :..;;•/. 1339E-03•: -.vV'i; 1339E-04•! .V»'»t 1339E-04O

• '..Vvt'.- I339E-O3•': ' °:'v. M- 1 339E-06?.!'".?.'•:•' 1339E-07••.j*''..i-' 1339E-OBii-'/.-i'VJ 1339E-09','*:'.', 1339E-10'i|V*'» ! t339E-llI'-"''.'-*'1 J339E-12' •' i-'-*;': V'V| jl 339E - 1 3

'V>''!v'i* t339E-13 ••.•'.«'{•;'•••.! ' i I339E-16'/;'-'••' V.i "' • I339E-17•*. .'•: '.') * 1339E-IBi'l'...j';Lji 1339E-19'.:'\« W i • 1339E-20!:i->, Ur I ' 1339E-20-R:,*.'•&;•: \i 1339E-21'-' '''•'•' j'l'-<' 1339E-210 ''••' i'hff'i'i* 1339E-22

"'it '.'•••' VvV.r' 1339E-24

'; ''»•' i. vi '" i 3J9E-26,'f'(''*'l'i '•"'•'•j- fthi•"•'•,' V«j'."''j hb2

''••'. i-'ii"-: ''** *•' •* ••! • /J * '

/.:•'•' .'fa'.H ' ' .

•-.'••"""*'•*: '

* • •*•.*'

304

0383328

0204236

00

• o00000000000

92692000

S374710476440

O00

' o0

• oo0o0

306

07B6703

O213424

00000000000000

118138000

47232306IO032

O000O00000

338

O277613

099476

000O0000

• 0000000O00

220128• 29028

0 .000000000

340

O442148

0141490

0O00000O0000O0000o

332287 •41697

0 :• 0000

. 0O

.' 000

"

374

t

0124748

04B40B

O00O000OO000O000o •0o -..o •o :0o0000000

374 332 334

097249

O39449

00000O0O00O00000OO000000oo0oo0

1471103030683343631777024319012B32I8286454279739I6B692139422143094173360736393619323446726791738.233 123433323BOB7247110436913262204

1303610011364301916392430Q6

. 10992O132819699174 73O91900111600(13220340873907

1702066429044156762246423BS63B34396434400033332422621316793017990419BB349343766B696SI 1296B384067002014466934933126004064SOS3O76038

1942230021131402440022B49371421441897348742760628234233193992268399731609

ALIQUOT WT. <g*> TETRA

10.1 x 40- ^»o.o QL.B JJO. 1 NO .10.2 C3.3JC?10.10.to.10.to.to.to.to.to.10.10..10.10. <10. <10.10.7.10.10.10.10.10.10.

rJBNONONO

> NONONONONONONONONO^JQ£g7§je)NOi ;o NO> m t» —

O Cui*£y(T| Cll« *7 f)" 2 tlU '

m N0r-i ND

10.0 •" NO10.0 ZZ NO1O.O 5> NO3.O 3° NO10.0 O NO10.0 ,0 NO10.0 NO

CoCOCD

T ;, *.

PENTA

110 ^

Nfl — -^NONONONONONONONONONDNONDNDNONONONOijQ

<a>tNONDNDNONDNONONDNDNO

•

HE* A

fjB

s~V*~ji5 ^NONOnononoNONONOnono

nu JNOHONONONO

|> NOP NO

NONONONONONOjNONOHONO

*U,

V..

•;•'.': .'.. • '•': LAOI Unlt«d fit*t*»

^ - • i •

V •• •"•'•; •' '< CASE NOi BAB I339C. • :i-: .' • . .•

NO. i

DATA Mkf ilftf fUrtHIIEP1A li OCIA IbUHLKS

Co. , Inc.

Hoport D«tai D*cu*b«r 24,

Column DD-3

1*OS

Ms- \>. \ - ' : - . :^t;-•••;>•:;•;

:#:v£lvv;-...r, ••;•/;:•!'•-•:, .->T.4 *;.;r .-,"/,• •••••»•• •• •• • •••;:'-V-if''';^;-:;-:

. '..'. !j • ' ". '.'•;

•; BM»M.E

•

1339E-OI• ..'•••_' I'. .•••"•'• i '••..' 133VE-02' - ."» * .! v '•'-. •. ' • '% 1 339E -03I'./.'/.''-''. V.:-\ t/V I3SVE-04• :- ' >V ''«> •'•-; '' *:*4 » J39E-03.I-* V«-7ViV;:% : .••.'••» 1339E-04:. :AY.:'t *.?''• V/ilf. 1339E-07

: : -v,- .''•-;;. ;.'-::» i339£-oe.'.-;•:•'.. VSi-^ t;-. i 1339E-09

'.I Vf-:'£ ; • '' •''«' "3VE-IO•'•!•. j'-Vi'-t 'i ••--!» 1339E-10-N.1 -j. iV-h^K »»"£-»•v,, '- ..'. :«V;:-J 13J9E-12•ifv^^:u:::^r««9£-i3.??• !:;-i»f. : j :;;.• •: 1 13396-14•.WftlMtt!'--'! V4 I339E-13V--»j;^f;'|'1Vy>-^- I339E-I4 '!.\\$f:%'-i:'.'-.'''''!"''\- 15396-17>J;^|V1V^:.'J 1339E-1BW&V te* •^•'iSf. 1339E-19 :• • _• . i-i ;.!;•> •.'/'• .,V i.« -» 1 -JME-20?^5is»«'fi .,'/•»> -VI-va - i- te.^^ilv-'^'Vl--^rv^SA1^-*!^1 •:»*•*• -iT^- •".I! 5**-»5'•'f^'V'!«*'^.f-'-f\iMii/vS'i}/.?-;'-'I>l;vi«4-Tf'',v^.Vivj.fAi.-Vi.r.:'!, .'•sifcV-iii-f.in-f.^ti*f ew-yn*2*^1ki? v*^*Jv >*•»"** 'I'Xli-i.- v»/*t« *>ii ;••• M».*' £' i- * 1 • •••'4* • *»j« I:;->*:'. Vji, •!* ;.:-. ;^.«j..• *li""r*-: .-'i<. *••.»

>• ;• ?r .-.-> • *> <•.••; ' :.-,-w, »• • «•;*•].•;. .<^. »•:/».V:*'1|..'=:;«i*'-::!iM>.'• :%'•'*.- •f»*-''i M1—'*'

^^fe^J7' •<•.-V'.ri:M:. ' - ' - • -?^ • f,:. -.'. <;>; .•: • = »:;l-.V/?; ://.•'•'• -f, •'.:''i:-'«-'K'sV*"-''jl.ikV^ ••..?.'.•..•• •••••«**."

I I339E-20-01339E-2I-.1339E-22I339E-231339E-24 "

LJ339E-23133V6-24RBI

• i

'.

• .

.

••

TOTAL AREAS

4O8

0OO00O0

2102400

1218700\

. 00OO00

7208OO

2301O

. ... .. ' O' O

ooo

'"

^

4IO

0OOOOO0

1994700

21207O00o0o00

3784OO

— 2380o0

' 00

:' o•j • • o

•: •i

.'

'-

-

442

18220O00OO0

•4480

. O14904

0.: o

.'. .; . O

O- . • - . . - • o•••:.- 0

.":_.'. o• o

. . • 00

v -: o.' .-.-4324

•••. ,:• • 0- u- -o. '.•• .--'o

•-v>;-:; M": -'o• • r. .'.-..'." • • » . • " " * " " * ' * • .,..;>-.y,J,^..'. ' .

' : '• t • • ' "t*i* * •

•^'j'lif'r^-'

./•V\ • : . >;^••" •— ., .

" •

444

1711200OOO0

4804O0

13774;o0

• . O00

•: : . . ... 0••*":•:•.•. o

o• . 0

. .' o- : O— 4539,.'. .. O

• ;• --.•..o..• . ;^o'"': ,.;.o

. OO

• • -." .' ' * * ' .

k

. '" ' .'

\ •

.1

TOTAL I60.1ER CLA6Q <PPJ&> '

. 472 ALIQUOT WT. («•> HtPTA

314487&04

4437434989

4014417297S3S33104433094

434433094412843233238147207481944810473702483232832981427804

443O134208882

1971014989

' 302812912

" ' .•

10.110.110. 110. 110. I10.010,110. 110. 1IO. 1IO.OIO. 110.110. 1IO.O10.010. 110. 17.0

10.0IO. 110. 110.210. 110.0IO.OIO.O3.0

IO.O

NONONONONONO

Jtf>-c£r>NOlyt

(jCl.J)tnNONONONONONOMp

^p. )NOtyi

^0.2^tillNONONONONO

OCTA

cZZNONOHONONONO

^0?2)RUTMp

^[p^gONONONOTHOJNONONONONONOt j JJ^

(_ 1-63NONONONONOjNO

c

iS^QP

b. Rtlerencs to CAM Na(s):

Contract Laboratory ProgramREGIONAL/LABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call:

Laboratory Name:

Lab Contact:

Region:

Regional Contact:

Call Initiated By: Laboratory

In reference to data for the following sample numbeKs):

A- JI -, ** -7 v ~TS~ r\ n f- •

Summary of Questions/Issues Discussed:

~ cli ~ v /'-V-*-I/SV * .'*• f j J r S , >^.

Summary of Resolution:

Signature

Distribution: (1) Lab Copy, (2) Region Copy, (3) SMO Copy

States Teciins Company, Inc.rietals and Environmental Chemistry Division

HOCOKCN. NCW JCKSCV O7O90 «O1) 7M-24OO

November 26, 1985

USEPA Contract Lab ProgranSample Management OfficeP.O. Box 818Alexandria, VA 22313

Attn: Leslie BraunRE: SAS Number 1339E

Enclosed is the data for the 2,3,7-8.TCDD analysis of theabove-referenced SAS. Terra through Octa isoner class data willfollow.

You will note that sample "339-E-20 required clean-up andre-analysis, and that even after additional cleanup, many interferingpeaks were observed in the sample. Because of the presence of so•any interferences, unequivocal identification of internal standardand surrogate peaks was not possible. It should be noted that thesample as not a soil, but appeared to be oil.

If you have any questions, please do not hesitate to call.

Sincerely yours,

Allan M. TordiniAssistant Vice PresidentMetals &Environmental Chemistry Division

EPA-330

Enc: Report

MR K»O*T» AMD trrriw »»t re« TMI nckosm we of TNI cutxt TO VNOH tun »*t Aeoxnste. AND TNKT ANO TNC «»«c or TMC UNITCO STATCS TUTIMCSSAirr me oil ns itAL* o« IMICNIA. ARI MOT TO *( uiu IINDIR ANT CIICUMTANCCS IN AOVCKTISINC TO TKC CCNHAL PUSI.IC AND H»T NOT K usco MST OTMCII •AMNII1 WITHOUT OU* PRIOt VRITTU AfTMVAL. MM^LU NOT OUTMTU IN TUTIN6 A«C ICTAINCO A HAXIBUB Or TH1«TT DATS.

<_. — .• ^. •S»a1es Testing Company, Inc.Ittals and Environmental Chemistry Division

.MMAV«MUI-«K«N. wtw jcftscv orojo ooi) ?«2.24Oo (2i2) *«

USEPA Contract Lab ProgramSample Management Office300 North Lee StreetAlexandria, VA 22314

Attention: Maka Crogard

Reference: SAS 1339E

Maka:

December 26, 1985

Enclosed please find the deliverables for the total tetrathrough octa dioxin and furaa isomer class portion, of theabove-referenced SAS.

All samples vere extracted and cleaned up using CLP 2,3,7,8-TCDDprocedures with the following exceptions:

1. In addition to TCDD Spiking Solution II, all samplesvere spiked vith 100 ul of a solution containing 0.4ug/nl 13C-OCDD.

2. All samples vere concentrated to a final volume of lOul.

Once extracted, samples vere analyzed for total tetra, penta andhexa dioxias and furans on a CP SIL-88 capillary column.Samples for total hepta and octa dioxins and furans vereanalyzed on a DB-5 capillary column.

i The following masses vere monitored for each constituent:

f Constituent Masses Monitored

Tetra Dioxins 320/322, Tetra Furans . 304/306I Penta Dioxins ' 354/356

Penta Furans 338/340Rexa Dioxins 390/392

f Hexa Furans 374/376i C13-Tetra Dioxin 332/334

(Internal Std)r

Hepta Dioxins 424/426Hepta Furans 408/410Octa Dioxin 458/460Octa Furan 442/444C13-0cta Dioxin 472

(Internal Std)

"" "•«• KKVT* AIM ICTTtn MC W TMC tlClMIVt M( OT Tut CUIMT TO WMOII TNIT AMI APMUltO. AND THH AND TMt •*•! OF TMI UHITTO »ATU TBTHCIA. Alt MOT TO tl MtO UHOtl ANT CIKCUNSTANCU IN ABVCITISINC TO TMI 6CNCKAL PU»tlC AKO NAT NOT (( USU UT. IHC. 0* IT* HAL* Oft IWI«»IA. Alt MOT TO tl MtO UHOtl ANT CIKCUNSTANCU IN ABVCITISINC TO TMI 6CNCKAL PU»tlC AKO NAT NOT ((

ANT OTHCB MAMlU •ITNOWT •«• f«IOt WUTTtM A/PMVAL. AANfLU NAT BUTROTIS IN TUTINA AM 11TAINCO A BUINUN Of THIin BAtl.

* u.mtMr of a, $0$ Group (SociMt Gwwnto «• Suntiltenra)

ed Slales TesJJng Company, Inc.

Response factors for tetra through hexa classes were calculatedrelative to the known response factor of 2,3,7,8-TCDD, based ona five point calibration. A mixed standard of knownconcentrations of one isomer from each class was analyzed. Theassumption was made that the response factor for the tetraisooer in the mixture (1,2,3,4-TCDD) was the same as that for2,3,7,8-TCDD. The responses of the other compounds in themixture were then evaluated relative to the response of the1,2,3,4-TCDD, and a response factor for each compound wascalculated. For example, if the response factor for2,3,7,8-TCDD were known to be 1.00 (based on the five pointcalibration), the total 320+322 area in the mixed standard was100000 and the total 356+356 area (penta dioxin) was 80000, thenthe response factor for penta dioxin would be calculated asfollows:

(PCDD response)x(TCDD response factor)(TCDD response)

i

(80000)»(1.00)(100000) : 0.80 - penta dioxin RF

A mixed standard of known amounts of hepta and octa dioxins andfnrans and C13-OCDD was analyzed daily. Response factors werecalculated by comparing the response of the higher of the two

' masses monitored for each compound to the response of mass 472 v' (C13-OCDD). Response factors calculated from a mixed atandard //

analyzed on a given day were used for all samples run on that Iday.

A sample was considered positive if both of the masses monitoredwere present within two scans of each other and the ratio of thetwo nasses was within +. 202 of the ratio observed in the mixedstandard.

In Reference to Cue Nets):

Contract Laboratory ProgramREGIONAL/LABORATORY COMMUNICATION SYSTEM

Date of Call:

Laboratory Name:

Lab Contact:

Region:

Regional Contact:

Telephone Record Log

-^xJ- 3.O

i r ' i

i *1 Call Initiated By: Laboratory //^ Region

^ In reference to data for the following sample numbeKs):

Summary of Questions/Issues Discussed:

D. /

Summary of Resolution:

i // fl./i££./i.' ///.// ,r

/•/ A- /Y XT' /f

Signature

'. Distribution: "(1) Lab Copy, (2) Region Copy,' (3) SMO Copy"

Date*

STATES TESTING CO., IMC.

Cave Not SAS 1339E ~"CUflARn »* fifig

DIOXIN ft FURAN ISOMES SPIKE % RECOVERIESTetri. Pent a & Hexa I corners

—ISQHS3 12i5&=Si=NT»tra Dioxin 88%

Penta Dioxin 56%

Hexa Dioxin 48% 50%

T«tra Furan 76% 6£%

Penta Fur«n 56% 58%

Hexa Furan ' 4£% 52%

Hepta A Octa Icomerm

Hepta Dioxin

Hepta Furan £0%

Octa Dioxin 130%

Octa Furan^ 50%

RELATIVE % DIFFERENCE—DUPUIgATES

1 1339E-04 0%

! 1339E-21 0%

APPENDIX 8SOIL BORING LOGS

•« dlMrt /uT ffTEST BORING L06

IIC NUMB El

.Uk M*. t5 03 I

. t*rUtN«1

OvftA fttvf

•k«r J)F

•votlM

•J

t.« u.

D-.^C*^^U.

' ST- SHELBY TUBE

[ PA* POWER AUGER

1C* ROCK CORE

W W-WASH

•

1

; "'

1

*rii

ii!i»\

tijctTc,r

JV4S

* ^

HS"» HOLLOWSTEM^:

MA- HAND AUGER

SS * SPLIT SPOON~~

3-5^51*- /3oo

S«npU Daylti

0 - l'

^'-H'

M'.4*/

t~ i UcX*«

• Cflfn^V

SVMI («| (

>

DrlHli»t

«

^

5

r

D tl,

0 -ty'

M"*^ '

3'-V/

S^'-H1/

M./

GROUND WATER DATA

C1*«««l«i Tlaw D«»

WMtoOrlllbifl

Al E*4«f

Al 24 IMW*

•nd ROTH whs

C.U, T,M TOPSOIL*

B«^6,.T,duAV<^e 0U4/.J.C.

BteMi O..MI <RtO <..-r,CuAt L-rrxt o^««.

TV 4^XLL *CAV£U

«|Mu.0Mtt.l<f.u~«..«.Cu« T^ 0, c

i-UIU. 41*MC(_

U^.Ot««^*L^^tuHi,.««« 6«,«L

AvJAFt TUFHSAL,

«• norcit Incli

'.lit—, ALT < LnvfcTEST IORIHGLOC

IIC NUMBER

,•«**« PC U UctflM

OffM*

JT-SHfUY TUIE

PA* POWER AUGER

CgsyHOLLOW STi

HA "HAND AUGER

RC- ROCK CORE

: WASH

*

1

i

1

Ifi

1

I

1

Ifi

£±, $€•»>• 35T

r*«,* f

.

<~*» « SPLIT SPOONS

i-3-t-" •/**><

*MT

o- q'M'-fe'

6'- 6V

per 4 Inches

"

»

HS

^ r

r±?T.

O'-H'H'_ G'

I/ - L^- 'D D

4:>'

B**!M

At 24k*w«

H««u- .f T.p .f R.A

«4 RM.*h«

C.U, TTM TOPSOIL*

Nio S*wFLt 1«<t»/

Wt t,w« S-um S,,« PAHTV VJ^WI r^i.AV-.w.

VtuAo ^ S'«-»e ft. ftirev

AUGER. Rt3tC.T«ON*

IncK