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LARGE FORMAT DUAL-BAND QUANTUM WELL INFRAREDPHOTODETECTOR FOCAL PLANE ARRAYS
A THESIS SUBMITTED TOTHE GRADUATE SCHOOL OF NATURAL AND APPLIED SCIENCES
OFMIDDLE EAST TECHNICAL UNIVERSITY
BY
YETKİN ARSLAN
IN PARTIAL FULFILLMENT OF THE REQUIREMENTSFOR
THE DEGREE OF MASTER OF SCIENCEIN
ELECTRICAL AND ELECTRONICS ENGINEERING
SEPTEMBER 2009
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Approval of the thesis:
LARGE FORMAT DUAL-BAND QUANTUM WELL INFRARED
PHOTODETECTOR FOCAL PLANE ARRAYS
submitted by YETKİN ARSLAN in partial fulfillment of the requirements for thedegree of Master of Science in Electrical and Electronics Engineering Department,Middle East Technical University by,
Prof. Dr. Canan ÖzgenDean, Graduate School of Natural and Applied Sciences
Prof. Dr. İsmet ErkmenHead of Department, Electrical and Electronics Engineering
Prof. Dr. Cengiz BeşikçiSupervisor, Electrical and Electronics Engineering Dept., METU
Examining Committee Members:
Prof. Dr. Tayfun AkınElectrical and Electronics Engineering Dept., METU
Prof. Dr. Cengiz BeşikçiElectrical and Electronics Engineering Dept., METU
Prof. Dr. Nevzat G. GençerElectrical and Electronics Engineering Dept., METU
Asst. Prof. Dr. Haluk KülahElectrical and Electronics Engineering Dept., METU
Prof. Dr. Raşit TuranPhysics Dept., METU
Date: 11.09.2009
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I hereby declare that all information in this document has been obtained andpresented in accordance with academic rules and ethical conduct. I also declarethat, as required by these rules and conduct, I have fully cited and referenced allmaterial and results that are not original to this work.
Name, Last Name: YETKİN ARSLAN
Signature :
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ABSTRACT
LARGE FORMAT DUAL-BAND QUANTUM WELL INFRAREDPHOTODETECTOR FOCAL PLANE ARRAYS
Arslan, YetkinM.S., Department of Electrical and Electronics Engineering
Supervisor : Prof. Dr. Cengiz Beşikçi
September 2009, 76 pages
Quantum Well Infrared Photodetectors (QWIPs) are strong competitors to other de-
tector technologies for future third generation thermal imagers. QWIPs have inherent
advantages of mature III-V material system and well settled fabrication technology,
as well as narrow band photo-response which is an important property facilitating the
development of dual-band imagers with low crosstalk. This thesis focuses on the de-
velopment of long/mid wavelength dual band QWIP focal plane arrays (FPAs) based
on the AlGaAs/GaAs material system.
Apart from traditional single band QWIPs, the dual-band operation is achieved by
proper design of a bias tunable quantum well structure which has two responsiv-
ity peaks at 4.8 and 8.4 µm for midwave infrared (MWIR) and longwave infrared
(LWIR) atmospheric windows, respectively. The fabricated large format (640x512)
FPA has MWIR and LWIR cut-off wavelengths of 5.1 and 8.9 µm, and it provides
noise equivalent temperature differences (NETDs) of ∼ 20 and 32 mK (f/1.5 at 65 K)in these bands, respectively.
The employed bias tuning approach for the dual-band operation requires the same
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fabrication steps established for single band QWIP FPAs, which is an important ad-
vantage of the selected method resulting in high-yield, high-uniformity and low-cost.
Results are encouraging for fabrication of low cost, large format, and high perfor-
mance dual band FPAs, making QWIP a stronger candidate in the competition for
third generation thermal imagers.
Keywords: Quantum-well infrared photodetectors, MWIR / LWIR, Dual-Band ther-
mal imaging,
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ÖZ
GENİŞ FORMATLI ÇİFT BANTLI KUANTUM KUYULU KIZILÖTESİ ODAKDÜZLEM DİZİNLERİ
Arslan, YetkinYüksek Lisans, Elektrik Elektronik Mühendislig̃i Bölümü
Tez Yöneticisi : Prof. Dr. Cengiz Beşikçi
Eylül 2009, 76 sayfa
Kuantum Kuyulu kızılötesi fotodedektörler (KKKF) gelecek üçüncü nesil termal gö-
rüntüleme sistemlerinde yer almak için dig̃er dedektör teknolojileri arasında kuvvetli
adaylardandır. AlGaAs/GaAs KKKFler, olgunlaşmış bir malzeme sistemiyle üretilme,
gelişmiş ve oturmuş üretim teknolojisine sahip olmak gibi avantajlarının yanında çift
bantlı çalışan dedektörler için önemli bir nokta olan dar bantlı tepki özellig̃ine de
sahiptir. Bu tez çalışması AlGaAs/GaAs malzeme sistemi üzerinde, uzun ve orta
dalgaboyu kızılötesi bantlarında çalışan çift bantlı KKKF odak düzlem dizinlerinin
(ODD) geliştirilmesine odaklanmıştır.
Tek bantlı KKKFlerden farklı olarak, çift bantlı çalışma, orta dalgaboyu kızılötesi
(ODK) atmosferik penceresinde 4.8 µm, uzun dalgaboyu kızılötesi (UDK) atmos-
ferik penceresinde ise 8.4 µm tepe duyarlılık dalgaboyu göstermek üzere özel tasar-
lanan kuantum kuyularının eg̃imleme gerilimlerinin anahtarlanması prensibiyle elde
edilmiştir. Üretilen geniş formatlı (640x512) ODD, ODK ve UDK pencerelerinde
sırasıyla 5.1 µm ve 8.9 µm üst kesim dalgaboyuna sahip olup, bu bantlarda sırasıyla
20 mK ve 32 mK (f/1.5, 65K) gürültü eşdeg̃er sıcaklık farkı göstermiştir.
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Çift bantlı çalışma için uygulanan eg̃ilim gerilimi anahtarlanması yaklaşımı stan-
dart tek bantlı KKKF ODD ile aynı üretim sürecine tabi olup, bu sayede yüksek
üretim verimi, yüksek düzgünlük ve düşük maliyet avantajlarına sahiptir. Elde edilen
sonuçlar düşük maliyetli, geniş formatlı ve yüksek performanslı çift bantlı KKKF
ODD üretimi açısından ümit verici olup, KKKFleri dig̃er teknolojilere kıyasla üçüncü
nesil görüntüleme sistemlerinde bir adım öne çıkarmaktadır.
Anahtar Kelimeler: Kuantum kuyulu kızılötesi fotodedektörler, MWIR / LWIR, Çift
bantlı termal görüntüleme
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To my family
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ACKNOWLEDGMENTS
First, I would like to thank my advisor Prof. Dr. Cengiz Beşikci for his enlightening
guidance and providing me the possibility to work in such a sophisticated facility.
I would like to thank Prof.Dr. Raşit Turan, Prof. Dr. Nevzat Gençer and Asst. Prof.
Dr. Haluk Külah for being on my thesis committee.
I would like to thank Prof. Dr. Tayfun Akın for being on my thesis committee and
sharing his laboratories with us.
I would like to thank Dr. Oray Orkun Cellek , Dr. Selçuk Özer and Mr. Ümid
Tümkaya and Mr. Burak Aşıcı for sharing with me their knowledge, their invaluable
comments and opinions as well as their friendship.
I would like to express my gratitude to Mr. Süleyman Umut Eker and Mr. Melih
Kaldırım for all the talks, all the jokes and all the sleepless growth nights. Your
invaluable friendly support kept me going, thank you for every moment that we have
spent throughout this research.
I would like to thank to Mr. Emre Onuk, Mr. Alp Tolungüç, Mr. and Mrs. Ag̃aog̃lu
for their friendships and help in all the laboratory.
I would like to thank to Mr. Özgür Şen for his unbelievable efforts to keep the labo-
ratory working.
Last but the best, I want to express my deep love and gratitude to my family and
Irmak, for being always with me.
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TABLE OF CONTENTS
ABSTRACT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv
ÖZ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vi
DEDICATON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
ACKNOWLEDGMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix
TABLE OF CONTENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . x
LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xii
LIST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xiii
CHAPTERS
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Infrared Radiation and Thermal Imaging . . . . . . . . . . . 2
1.2 Infrared Detectors . . . . . . . . . . . . . . . . . . . . . . . 7
1.3 Figure of Merits of Infrared Detectors and Imaging Systems . 10
1.4 Scope and Objective of This Work . . . . . . . . . . . . . . 14
2 Dual-Band Detection with QWIPs and Design Approach . . . . . . . 16
2.1 Advantages of Dual/Multi-Band Detection . . . . . . . . . . 16
2.2 State-of-The-Art Dual-Band Detectors . . . . . . . . . . . . 18
2.3 Advantages of QWIPs for Dual/Multi-Band Detection . . . . 22
2.4 QWIP Basics . . . . . . . . . . . . . . . . . . . . . . . . . . 23
2.4.1 Theory of Operation . . . . . . . . . . . . . . . . 23
2.4.2 Material Systems for QWIPs . . . . . . . . . . . . 30
2.5 Design Approach . . . . . . . . . . . . . . . . . . . . . . . 34
2.5.1 Selection of Dual-Band Operation Type . . . . . . 34
2.5.2 Operation of Voltage Tunable Detector Structure . 40
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2.5.3 Design Targets . . . . . . . . . . . . . . . . . . . 42
2.5.4 Design . . . . . . . . . . . . . . . . . . . . . . . . 44
3 Implementation and Characterization of GaAs Based MWIR/LWIRDual-Band QWIP FPAs . . . . . . . . . . . . . . . . . . . . . . . . . 47
3.1 Final Design . . . . . . . . . . . . . . . . . . . . . . . . . . 47
3.2 Growth of the Device Epilayer Structure . . . . . . . . . . . 48
3.2.1 Molecular Beam Epitaxy Basics . . . . . . . . . . 48
3.2.2 Optimization of Growth Parameters and DopingCalibration . . . . . . . . . . . . . . . . . . . . . 50
3.2.3 X-ray Diffraction Characterization . . . . . . . . . 51
3.3 FPA Fabrication . . . . . . . . . . . . . . . . . . . . . . . . 53
3.4 Pixel and FPA Level Characterization and Discussions . . . . 58
3.4.1 Pixel Level Characterization . . . . . . . . . . . . 58
3.4.2 FPA Characterization . . . . . . . . . . . . . . . . 63
4 CONCLUSION AND FURTHER WORK . . . . . . . . . . . . . . . 71
REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
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LIST OF TABLES
TABLES
Table 2.1 Mature III-V material systems used for QWIP fabrication. . . . . . . 31
Table 2.2 Specifications of the ISC9803 ROIC. . . . . . . . . . . . . . . . . . 43
Table 3.1 Comparison of the dual-band focal plane arrays. . . . . . . . . . . . 70
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LIST OF FIGURES
FIGURES
Figure 1.1 Spectral photon exitance of blackbody at various temperatures . . 4
Figure 1.2 Atmospheric transmission . . . . . . . . . . . . . . . . . . . . . . 5
Figure 1.3 Band structure of type II strained superlattices . . . . . . . . . . . 10
Figure 2.1 Pixel architecture for TLHJ type dual-band detectors . . . . . . . . 19
Figure 2.2 Pixel architecture with multiple electrical contact. . . . . . . . . . 20
Figure 2.3 Multiple contact pixel architecture by CEA/LETI. . . . . . . . . . 20
Figure 2.4 Layer diagram of the four-band QWIP device structure. . . . . . . 21
Figure 2.5 An image recorded with the four-band detector. . . . . . . . . . . . 22
Figure 2.6 Typical QWIP diagram. . . . . . . . . . . . . . . . . . . . . . . . 24
Figure 2.7 Typical band diagram of the QWIP. . . . . . . . . . . . . . . . . . 24
Figure 2.8 Al mole fraction dependence of energy states AlGaAs/GaAs . . . 25
Figure 2.9 Typical spectral responses of different QWIP types. . . . . . . . . 26
Figure 2.10 Illustration of the effect of diffraction grating. . . . . . . . . . . . . 27
Figure 2.11 Corrugated pixel structure . . . . . . . . . . . . . . . . . . . . . . 27
Figure 2.12 Illustration of the capture and emission mechanisms in QWIPs . . 28
Figure 2.13 Temperature dependence of the detectivity of the QWIPs. . . . . . 30
Figure 2.14 Dependence of the NETD on detector bias . . . . . . . . . . . . . 32
Figure 2.15 Thermal image recorded with the 640x512 InP/InGaAs FPA. . . . . 33
Figure 2.16 Responsivity spectrum of AlInAs/InGaAs/InP QWIPs. . . . . . . . 34
Figure 2.17 Multi-contact pixel schemes for co-registered dual-band operation . 35
Figure 2.18 Illustration of space sharing pixel placement . . . . . . . . . . . . 36
Figure 2.19 Dual-band detector structure employing one contact per pixel. . . . 37
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Figure 2.20 Band diagram of a voltage-tunable two-color detector . . . . . . . 37
Figure 2.21 Responsivity spectra of a MWIR/LWIR detector . . . . . . . . . . 38
Figure 2.22 Voltage tunable MWIR/MWIR spectral response . . . . . . . . . . 39
Figure 2.23 Characteristic I-V curve of standard AlGaAs/GaAs QWIP. . . . . . 41
Figure 2.24 Operation points of the series connected QWIP stacks. . . . . . . . 41
Figure 2.25 Simplified unit cell schematic of the ISC9803. . . . . . . . . . . . 44
Figure 2.26 Generic layer structure for voltage-tunable QWIP structure. . . . . 45
Figure 3.1 Final dual-band QWIP epilayer structure. . . . . . . . . . . . . . . 48
Figure 3.2 Riber Epineat III-V MBE Reactor utilized in this work. . . . . . . . 49
Figure 3.3 Rocking curve of the detector epilayer structure. . . . . . . . . . . 52
Figure 3.4 Illustration of fabrication steps of detector hybrid . . . . . . . . . . 54
Figure 3.5 FC-150 flip-chip aligner/bonder. . . . . . . . . . . . . . . . . . . . 56
Figure 3.6 Transmission of the wide-band AR coating. . . . . . . . . . . . . . 57
Figure 3.7 Pictures of the FPA after polishing and AR coating. . . . . . . . . . 57
Figure 3.8 Dark current and photo current characteristic of a single pixel. . . . 59
Figure 3.9 Responsivity and detectivity measurement setup diagram. . . . . . 60
Figure 3.10 Absolute spectral responsivity of test pixels. . . . . . . . . . . . . 61
Figure 3.11 Bias sharing between dual-band detector stacks. . . . . . . . . . . 63
Figure 3.12 NETD histogram of the dual-band QWIP in LWIR mode. . . . . . 64
Figure 3.13 Outdoor images taken with the MWIR/LWIR dual-band sensor. . . 66
Figure 3.14 Thermal images of a man holding a 8-12 µm band-pass filter. . . . 67
Figure 3.15 Outdoor images in two bands and image fusion. . . . . . . . . . . 68
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CHAPTER 1
Introduction
Infrared (IR) radiation was unknown to mankind until Sir Frederick William Her-
schel’s experiments with thermometers and a simple glass prism, 200 years ago. What
he called ”calorific rays” at that time kept being an important field of interest to re-
searchers all around the world.
Today’s infrared detectors started their evolution in the form of thermal detectors in
1820’s by August Ludwig Friedrich Wilhelm Seebeck with the main purpose being
simple temperature measurement. Advancements like construction of thermopiles by
Leopoldo Nobili followed, and Samuel Pierpont Langley’s bolometer employing a
Wheatstone bridge was able to detect the radiation emitted by a cow from quarter
miles away in late 1890’s [1].
Even though photoconductivity of Selenium was well known since 1897 after W.Smith,
first synthesized photon detectors have their origin in the work of T.W. Case where
he made a systematic search for ”light-active substances” in 1917 [2, 3]. Some of to-
day’s major infrared materials’ appearances are InSb in mid 1950’s, HgCdTe in early
1960’s and AlGaAs/GaAs quantum well infrared detectors in late 1980’s.
Its development well driven by military applications in years, infrared detection tech-
nology has evolved from first generation single element (or 1-D arrays) scanning
configurations to second generation 2-D detector arrays in late 1970’s owing to the
establishment of reproducible bulk growth techniques. Recently, in mid 1990’s, with
improved fabrication techniques, focal plane arrays (FPAs) appeared with improved
capabilities like very large number of pixels, decreased pixel pitch and multi-band
spectral operation. Although its definition is not well established, these talented de-
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tectors are accepted to constitute the third generation of infrared systems. [4]
Latest efforts in the development of third generation infrared systems are toward
higher resolution, higher sensitivity and multi-band operation at lower cost. At the
low cost end of performance-cost dilemma, quantum well infrared photodetectors
(QWIPs) based on the fairly mature GaAs material system display big potential.
QWIPs are also inherently advantageous as a multi-band detector alternative as they
have narrow band spectral response by their nature. Mainly influenced by these two
facts, in this thesis work, longwavelength / midwavelength dual-band QWIPs employ-
ing bias tuning approach are designed, implemented, and their FPA level performance
is assessed after fabrication of very large format (640x512) FPAs.
This chapter focuses on the fundamentals of infrared radiation and infrared detectors
including the present status of detector technology. The second chapter presents the
design criteria and approach adopted in this work, as well as the basics of QWIPs.
The third chapter is devoted to demonstration of the dual-band FPA, characterization,
results and discussion. Finally, fourth chapter includes the conclusions that can be
drawn from this work and further work.
1.1 Infrared Radiation and Thermal Imaging
Infrared radiation is an electromagnetic radiation, and its location in the electromag-
netic spectrum starts from high side of the visible part at 700-800 nm and ends at the
low side of terahertz radiation which is at 100 µm. Spanning roughly two orders of
magnitude in wavelength, subdivisions and their nomenclatures are varying for dif-
ferent application fields. Commonly used names in infrared sensor related studies are
as follows [5]
• Near infrared (NIR): 0.7 to 1.0 µm.• Short-wave infrared (SWIR): 1.0 to 3.0 µm.• Mid-wave infrared (MWIR): 3 to 5 µm.• Long-wave Infrared (LWIR): 8 to 12, or 7 to 14 µm.• Very-long wave infrared (VLWIR): 12 to 30 µm.• Far infrared (FIR) : 30 to 100 µm.
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The above division is mainly based on the atmospheric transmission related issues
which will be discussed later.
As an electromagnetic wave, infrared radiation obeys all Maxwell’s equations. From
a practical point of view, infrared radiation is subject to some extra rules dictated by
its interaction with matter, its sources and environment. Unlike the human vision,
NIR and partly SWIR systems, which are concerned with the reflected light from
objects, passive infrared (thermal) imaging senses the radiation emitted by the object
itself. This emitted radiation by each object with a temperature above absolute zero
is described by Planck’s law of radiation. Planck’s law relates the spectral exitance
of a blackbody to its temperature where a blackbody is defined as an idealized object
which absorbs all the radiation falling on it without any reflection or transmission.
Planck’s law is given as
Mp(λ,T ) =2πhc2
λ51
ehc/λkT − 1 (1.1)
where Mp(λ,T ) is the spectral radiant exitance in Watt/cm2µm, c is speed of light, h is
the Planck constant, k is the Boltzmann constant, and T is the object temperature. It is
also possible to express spectral exitance in terms of number of photons/cm2 emitted
in unit time per wavelength interval. Spectral photon exitance is plotted in Fig. 1.1
for various blackbody temperatures.
There are several important observations that can be extracted by investigating the
spectral photon exitance distribution. The first observation is that most of the energy
radiated from near room temperature objects is in the IR region with a peak around
10 µm. Dependence of the peak wavelength of the blackbody radiation to object
temperature is explained by Wien’s displacement law as follows
λmax =2897.7µmK
T. (1.2)
Another observation is that the change in the exitance with varying wavelength is
higher in the MWIR (3-5 µm) region than that in LWIR (8-12 µm) region, resulting
in a higher imaging contrast in the MWIR band. Even though there is less power in
this window, higher contrast may be useful in some cases.
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Figure 1.1: Spectral photon exitance of blackbody at various temperatures
In reality, the blackbody assumption of Planck’s law is seldom valid. Instead, real-
life objects exhibit reflection and transmission properties resulting in deviations from
the blackbody assumption. In order to characterize this behavior, emissivity (ε) of
a material is defined to be the ratio of the total energy emitted by a material to the
total energy radiated from a perfect blackbody at the same temperature. Emissivity of
a material shows wavelength and view angle dependence. However, for engineering
purposes it is common to consider the emissivity of a surface to be wavelength and
angle independent at least for a certain wavelength range. This is known as greybody
assumption.
After the infrared radiation is emitted by matter, it is also important to examine its
propagation through the transmission medium which is generally air. Infrared ra-
diation is subject to different events that could affect its propagation. These events
include the absorption by atmospheric gases, scattering by aerosols and reflections.
Absorption of the atmospheric gases is the most significant mechanism, and it is
greatly varying with atmospheric conditions. Absorbing gases include H2O, CO2,
CH4, N2O, O3, NH3, etc. For low attitude horizontal paths, H2O and CO2 are the
dominant absorbing gases. Sample atmospheric transmission is given in Figure 1.2.
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For passive thermal imaging systems there are two important spectral regions, MWIR
and LWIR where the atmosphere is transparent. However, H2O absorption isolating
these two windows is strongly dependent on the water vapor content of the air which
is very different from place to place and time to time.
Figure 1.2: Atmospheric transmission and absorbing molecules, measured at sea leveland through 1800 m horizontal path [6].
Scattering is the next important factor in atmospheric propagation. It is due to in-
teraction of photons with atmospheric molecules and aerial particles like fog, dust
and droplets. Rate of scattering of photons by particles smaller than wavelength is
inversely proportional to wavelength. However scattering rate becomes wavelength
independent as particle size becomes much larger than radiation wavelength. Con-
sequently, infrared imaging becomes more advantageous over visible imaging when
only the scattering mechanisms are considered.
Taking these mechanisms into account, a more sophisticated model can be constructed.
In this model the amount of radiation falling on a detector due to a distant emitting
target is expressed as
I = F(r) ·∫
λ
[τa(λ, r){εtM(λ, Tt) + ρlM(λ,Tae)} + [1 − τa(λ, r)]M(λ, Ta)] dλ (1.3)
In the above equation,
• F(r) is a geometric factor depending on target’s projected area and distance,• τa is the atmospheric transmission factor as a function of wavelength and target
distance,
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• εt is the emissivity of the target,
• M(λ, Tt) is the spectral exitance,
• ρl is the reflectivity of the target,
• M(λ, Tae) is the spectral exitance of background,
• 1 − τa is the emissivity of the atmosphere (emissivity+transmissivity=1 whenreflection is ignored),
• M(λ, Ta) is the temperature dependent exitance of the atmosphere,
• Ta is the temperature of air,
• Tt is the temperature of target,
• Tae is the temperature of background.
This model also accounts for the reflections of background from target and the emis-
sion of the atmosphere itself. Such artifacts should be considered when designing an
imaging system.
Thermal imaging systems basically consist of an input optics stage, detector stage,
and electronics. Optic stage is responsible from construction of the image on the
detector, and it is specially designed to work in a selected spectral window. Passive
imaging systems usually cover 3-5 µm, 8-12 µm or directly 3-12 µm windows. With
the help of cold shield, optical stage determines the optical power falling on the unit
area of the detector or field of view of the system. The detector converts incoming
radiation power into electrical signal. Detectors operate at near room temperature or
at cryogenic temperatures. In both cases, detectors are vacuum sealed for maximum
isolation from environmental conditions. In the hybrid technology, the detector is
coupled to a readout integrated circuit (ROIC). There also exist monolithic technolo-
gies where the readout circuitry and the detectors are fabricated on the same chip.
ROIC is responsible from driving the detector array, reading the output from each
detector and multiplexing output to the first stage of electronics. Typically, external
electronics exist in two stages in an imaging system. The front stage is usually located
near the detector-ROIC hybrid. This stage drives the ROIC and preamplifies output
to the back stage. Back stage electronics constructs the image and streams the data to
the user in desired protocol and form.
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Operation principles for the various types of detectors, figures of merit and present
detector technologies are investigated in further detail in the next section.
1.2 Infrared Detectors
It is possible to build an infrared detector by exploiting many physical phenomena.
Some of these are thermoelectric effect (thermocouples), change in the electrical con-
ductivity with temperature (bolometers), gas expansion (Golay cell), pyroelectricity,
intrinsic absorption, impurity absorption, and intersubband transitions. In some of
these effects, incoming photons are absorbed into heat, and the resulting temperature
change is detected by monitoring some physical properties of the detector material.
Detectors based on this principle are called thermal detectors. On the other side, in
some of the listed phenomena, photons are interacting with electrons causing some
change in the electronic state of the material, and an electrical signal is output as the
indicator of the infrared radiation. These types of detectors are called photon detec-
tors.
Thermal detectors are wide band detectors in the sense that detector response is given
to all wavelengths. Operating region of thermal detectors is dictated by optics. Ther-
mal detectors do not require cryogenic cooling, but thermoelectric coolers are used
for temperature stabilization. Currently microbolometers are the detectors of choice
for applications fitting into specifications of thermal detectors. Microbolometers’s
theory of operation is based on monitoring of the thermally induced change in the
electrical resistance of the active material. Advantages of microbolometers over pho-
ton detectors covering similar spectral range can be listed as follows
• Small and lightweight imager structure
• Low power consumption
• Immediate video output after power on
• Very long mean time between failure (MTBF)
• Low cost.
Main disadvantages of thermal detectors can be given as follows
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• Low sensitivity
• High speed imaging is not possible due to large response time
• Dual/multi-band operation can not be implemented at detector level
• Difficulties in decreasing the pixel size for very high resolution.
Performance limits for microbolometers arise from structural properties of the pixels
and active material’s physical properties. Roughly, sensitivity of a microbolometer is
limited by thermal conductance, and the response time is dictated by the heat capacity
over thermal conductance ratio for a single pixel [7].
In photon detectors, not like thermal detector where photons are absorbed into heat,
absorption of photons occurs through excitation of electrons from one energy state to
another one. Cryogenic cooling requirement of photon detectors arises from the fact
that, thermal excitations must be suppressed for photo-excitations to stay dominant.
Excited electrons are collected with the help of an electric field to create detector
signal. Photon detectors are further divided into two subgroups according to the gen-
eration of this electric field. In the first group, called photovoltaic detectors, built in
electric field, as in a p-n junction, is employed to collect excited charge carriers. In
the second group, an external bias potential is applied to collect excited carriers, and
this type of photon detectors are called photoconductive detectors.
Excitations of charge carriers in a photon detector can be between bands, subbands or
minibands. Today, most commonly used technologies for fabrication of infrared pho-
ton detectors utilize low bandgap materials like HgCdTe and InSb or QWIP structures
of the AlGaAs/GaAs material system. Type II strained superlattice of InAs/InGaSb
material system is also showing great advancement. These technologies are briefly
discussed below.
InSb is a binary compound which has band to band transition energy corresponding
to a wavelength in the MWIR region. InSb is a mature technology, and InSb pho-
todiodes have been available since late 1950’s [8]. Main drawback of the InSb is
impossibility of wavelength tuning since it is a binary compound. InSb is preferred
especially in astronomy and megapixel size FPA applications. High quality InSb
FPAs are demonstrated and commercialized by several manufacturers [9, 10].
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HgxCd1−xTe is a very important infrared material and has been studied extensively
over many years. Since it is a ternary compound, its bandgap can be tailored to cover
the 1-20 µm spectral range. Its high quantum efficiency together with the possibility
of tuning responsivity spectrum make HgCdTe currently the first choice of technol-
ogy where performance is the primary requirement. Main problems with the HgCdTe
technology are production cost, unavailability of high quality lattice matched sub-
strates, nonuniformity (especially in LWIR band) and difficulties in epitaxial growth.
In order to overcome these closely correlated difficulties, there is significant amount
of research on high quality growth of HgCdTe on alternative substrates like Si, Ge
and GaAs. Currently HgCdTe arrays with megapixel (1280x720) size and dual-band
operation (MWIR/LWIR) ability have been demonstrated [11].
Type II strained superlattice technology (SLS) progressed very quickly in the last cou-
ple of years and nowadays offers the high quantum efficiency of low bandgap detec-
tors combined with mature fabrication methods of III-V compound semiconductors.
Type II SLSs consist of stacked InAs/(In)GaSb layers. In this structure, bottom of the
conduction band of InAs goes below of the top of the valence band of (In)GaSb as in
Figure 1.3. In this broken gap structure, minibands are formed due to overlapping of
wave functions. Spacing of these bands are controlled with thickness of layers over a
wide range. The fact that SLS is the only material that can theoretically outperform
HgCdTe attracted researchers, and breakthrough advancements have been made in
this material over the past few years. Main obstacles in front of the performance of
the SLSs were surface passivation for LWIR detectors, low quantum efficiency, and
high leakage. With the recent advancements, passivation quality is greatly increased
with SiO2 coating, and good quality, high quantum efficiency layers are demonstrated
[12]. Currently MWIR/MWIR dual color mid-format SLS FPAs are in production
for European military aircrafts by AIM in Germany. SLSs are also considered as a
future solution in VLWIR imaging area where HgCdTe has very serious uniformity
problems.
Quantum well infrared photodetectors constitute an important share of the current
detector market. QWIP’s theory of operation bases on the intersubband excitations
of electrons by photons. These subbands are created by 1-D confinement in the con-
duction band of alternating AlGaAs/GaAs layers. Relying on mature GaAs material
9
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system, QWIPs are relatively low cost photon detectors with high yield, good uni-
formity and stability. Main drawback of the QWIPs is the low quantum efficiency
of the structure. Integration time should be increased to keep the sensitivity at ac-
ceptable level, and therefore, very high speed imaging is not feasible. With proper
selection of material system, spectral response of QWIPs covers the entire infrared
region, and photoresponse is narrow band type unlike low bandgap photon detectors.
This property of narrow band type response is an advantage for multi band imaging
decreasing spectral cross talk and facilitating spectral tuning. QWIP technology has
reached megapixel size with dual-band ability [13]. QWIPs are investigated in further
detail in the next chapter.
Figure 1.3: Band structure of type II strained superlattices [14].
1.3 Figure of Merits of Infrared Detectors and Imaging Systems
In order to assess the performance of an IR detector or imaging system one needs
quantitative measures. In this section, fundamental figures of merit for an IR detector
and imaging system are presented. Main performance parameters for an IR detector
can be listed as follows
• Responsivity
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• Noise level
• Detectivity.There are also parameters that are defined at system level, and commonly used ones
can be given as follows
• Noise equivalent temperature difference (NETD)
• Minimum resolvable temperature difference (MRTD)
• Modulation transfer function (MTF).
Responsivity:
Responsivity is the magnitude of the response of the detector to unit radiation power.
It provides information on gain, linearity, dynamic range, and saturation level of the
detector. Responsivity is a measure of the transfer function between the input signal
photon power or flux and the detector signal output
< = outputsignalinput f lux
=iphotoφ
. (1.4)
Output signal is expressed in volts or amperes, and input signal is expressed in ei-
ther watts or photons/sec. Responsivity can be defined as a function of wavelength in
which case it is called spectral responsivity. Responsivity can be also defined inde-
pendent of wavelength and detector’s spectral response, assuming that response is flat
all over the blackbody spectrum at a specific temperature. This interpretation is called
blackbody responsivity, and it is used in conjunction with a blackbody temperature. It
is possible to switch from blackbody responsivity to spectral responsivity with a mul-
tiplicative factor called peak factor, which is the ratio of the integrated normalized
blackbody spectrum to detector’s integrated response spectrum.
For photon detectors, responsivity is commonly defined in units of ampere/watts and
is expressed as follows
< = qηg λhc. (1.5)
In this equation, η is the quantum efficiency meaning how many electrons are excited
per incoming photon. Symbol ’g’ is the photoconductive gain meaning how many
electrons are collected at the external circuit for a single excited electron in the de-
tector. For photovoltaic detectors g is close to unity. Photoconductive detectors have
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variable gain values, and g is expressed as the ratio of the average drift distance to
total device length.
Noise:
Noise level in the system determines the system performance. Most pronounced noise
sources for IR detectors are generation-recombination (g-r) noise, shot noise, photon
noise, 1/f noise, and thermal noise.
Even though it is not well understood yet, 1/f noise is thought to arise from material
instabilities. For GaAs QWIPs, it is shown experimentally that 1/f noise seldom limits
detector performance and thermal noise, which is inherent to all resistive devices, has
a negligible contribution [15].
Shot noise is statistical noise and arises from random arrival rates of the electrons in
the device. It is expressed as follows
i2n = 2qIdevice∆ f (1.6)
where Idevice is the device current, ∆f is the bandwidth, and q is the unit charge.
Dominant noise mechanisms in QWIPs are photo- and dark current originated g-r
noise. Randomness of the generation and the recombination events creates the noise
called g-r noise. The g-r noise is expressed as
i2n = 4qgnoise(Iphoto + Idark)∆ f . (1.7)
In this equation gnoise is the noise gain, and under normal operation it is taken to
be equal to photoconductive gain [16]. Iphoto + Idark are the two components of the
current flowing through the device. Idark is the current which is unavoidably flowing
through the detector even without any illumination. Dark current is dominated by
thermal activation of electrons and is minimized by lowering the detector temperature.
The condition where Iphoto � Idark is called background limited performance (BLIP)condition, and it defines the operation temperature of the detector.
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Detectivity:
Although responsivity, by itself, gives how much signal is generated by the detector
to incoming irradiance, it gives no indication of minimum amount of radiant flux that
can be detected. Detection of small amount of irradiance is inhibited by the noise
level of the detector. A convenient descriptor for minimum detectable signal is the
noise equivalent power (NEP) which is the required radiant flux to give signal output
equal to detector noise [17]. NEP is expresssed as
NEP =inoise< . (1.8)
However, NEP is a situation specific descriptor and does not allow direct comparison
of different detectors. For this purpose, the noise term in the NEP definition is nor-
malized to detector area and measurement bandwidth, and the inverse of the result is
defined as specific detectivity (D∗) as
D∗ =
√A∆ f
inoise< [cm√Hz/Watt] (1.9)
In order to study the theoretical detectivity limit for photoconductive detector, con-
sider the incoming radiant power given as follows
φ = φpAhcλ
(1.10)
where φp is the photon flux similar to that expressed in Eqn. 1.3, and A is the detector
area. Also consider the signal generated by the detector which is expressed as follows
iphoto = qηgphotoAφp (1.11)
Employing Eqn. 1.10, 1.11, 1.7 and Eqn. 2.13 and making the assumptions of
Iphoto � Idark and gphoto ∼ gnoise yield the ultimate performance of the photocon-ductive detectors as
D∗BLIP =λ
2hc
√η
φp. (1.12)
Noise Equivalent Temperature Difference:
NETD is the target-to-background temperature difference that produces a signal equal
to rms background noise. Since the change in the photon exitance with temperature
will be different at different temperatures, NETD values are also specified with a
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background temperature. Smaller NETD values indicate better thermal sensitivity.
NETD is a measure of the thermal sensitivity of the whole imaging system and ig-
nores spatial resolution [17]. Its analytical expression is given as follows
NET D =(4 f 2 + 1)
√∆ f√
A∫λ
D∗(λ)dMp(λ,T )dT dλ[Kelvin]. (1.13)
In this equation f is the f-number of the optics which describes the field-of-view of the
optical aperture. This equation is valid under detector limited performance situations.
Under BLIP condition, NETD will depend on the f-number linearly because D∗(λ)
will also exhibit linear f-number dependence. Taking nonuniformity of the array as
an additional noise component, NETD for a system may also be uniformity limited
[18].
Minimum Resolvable Temperature Difference:
MRTD is subjective measure of both spatial resolution and thermal sensitivity. MRTD
measurement encompasses all the components of the system including the user itself.
Its measurement includes an ensemble of observers looking to a standardized 4-bar
pattern with an aspect ratio of 7:1. Observers determine the minimum temperature
difference required to resolve 4-bar pattern from the background. Analytically MRTD
is directly proportional to NETD and inversely proportional to MTF. MRTD is also
affected by parameters like equivalent integration time of human eye [17, 19].
Modulation Transfer Function:
MTF characterizes spatial resolution and image quality by means of spatial frequency
response of an imaging system. It has complex measurement routines, and it is a
function of detector pitch, pixel to pixel crosstalk, fill factor, quality of optics, etc.
MRTD measurement is preferred over MTF alone because MRTD does not regard for
a noise level.
1.4 Scope and Objective of This Work
The third generation concept brings the requirements of improved reconnaissance per-
formance, dual-band capability, and reduced cost to the IR photon sensors. Main mo-
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tivation in this work is to develop and demonstrate a dual-band large format quantum
well infrared photodetector focal plane array in order to satisfy these requirements.
The dual-band capability of the detector is obtained by using the voltage tuning of
the spectral response principle. Even though there are several methods to adjust the
spectral response of the detector by changing the bias voltage, the mechanism used
in this work is not well investigated in the literature. Therefore this work has an im-
portant contribution to the literature in the sense that it demonstrates the application
of its principles, especially at the final product level. An important advantage of the
voltage-tuning principle employed in this work is that it is fully compatible with the
present single band detector technology, therefore time and effort to put this technol-
ogy on the market is drastically reduced.
In the first phase of the work, detector structure is designed and the proper opera-
tion of the design is justified. Complete fabrication and the characterization of the
designed detector structure were performed in the second phase of the work. Next
chapter discusses the dual-band imaging with QWIPs and describes the design phase
carried out in this work.
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CHAPTER 2
Dual-Band Detection with QWIPs and Design Approach
In this chapter of the thesis, first the requirement for dual-band imaging is justified
by listing the advantages and exemplifying the important applications. Following this
justification, present status of the dual-band detector technology is presented with
examples from the literature. Thirdly, necessary background is given to understand
the basics of operation and fabrication of QWIPs. Finally design process is described
in details including auxiliary studies and investigations.
2.1 Advantages of Dual/Multi-Band Detection
Dual/multi-band imaging (sometimes called hyperspectral imaging) provides plenty
of benefits and reveals new potential applications. Improved reconnaissance perfor-
mance is the main factor calling for simultaneous imaging in different bands or differ-
ent spectral regions in the same band. Advantages provided by hyperspectral imaging
and some of potential applications are discussed in this section.
MWIR band is well known for its high maritime performance and its immunity to the
degradations caused by water vapor. Also MWIR band is preferred in narrow field-of-
view applications due to its lower diffraction limit. However, when a scene contains
hot sources or reflections from hot sources, imaging quality in the MWIR band is
greatly degraded by saturation of the readout circuit capacitors. On the other side,
LWIR band is advantageous when the background radiation is too low for MWIR
imaging or the detection range is degraded by atmospheric scattering. LWIR band is
also insensitive to stray light effects and saturation by hot sources due to its high dy-
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namic range. In a dual/multi-band imaging system, these inherent advantages of each
band are combined in a single system. Therefore optimum imaging quality is ensured
under many scenarios and circumstances where performance of a single band detec-
tor is not sufficient [20]. Improved image quality and reconnaissance performance
are especially desirable for early warning systems. Utilization of dual/multi-band de-
tectors will decrease false alarm rates, and reaction time will be shortened compared
to a single band system.
Imaging in more than one band allows new interpretations to emissivity and black-
body characteristics. Considering the emissivity specific features of a scene, target
recognition and disclosure of camouflaged targets can be described by algorithms
thus automated. On the other side, long-range accurate temperature measurement
is possible by discarding the emissivity changes. Accurate long-range temperature
measurements are useful for a number of important applications. As an example, in
battlefield and emergence situations, such as those requiring triage, vital physiolog-
ical parameters, such as skin temperature, must be measured when direct contact is
not possible [1, 21].
Another advantage of the hyperspectral imaging is that it allows the detection of spe-
cific emissions by spectral comparison. Specific emissions in a certain spectral region
can be caused by combustion, explosions, lasers or other emitters. These sources can
be differentiated from blackbody radiation by checking their counter part in another
band. Such a differential operation yields very high prediction accuracy.
MWIR and LWIR signature of rocket vehicles and their plumes are of great interest
for detection, recognition and interception. Rocket plumes present a large MWIR
signal that can be detected and tracked at hundreds of kilometers away. However, for
interception it is necessary to image the hardbody of the missile which radiates mostly
in the LWIR band. LWIR signature of the plume is stronger than that of hardbody
but it is weaker than plume’s MWIR signature. Therefore, it is advantageous for an
interceptor to have imaging ability in both MWIR and LWIR regions [22].
With various additional potential applications not mentioned here, dual-band imaging
is an active research area and significant amount of research is in progress for low cost
and more talented dual-band detector arrays.
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2.2 State-of-The-Art Dual-Band Detectors
Currently different research groups are working on various infrared materials to im-
plement dual-band detector arrays. Even though each detector technology has its
own advantages and shortcomings, general trend is toward megapixel size arrays with
highly customized ROICs.
In the year 2006, Raytheon Vision Systems (RVS) has developed and demonstrated
the first 1280 x 720 pixel dual-band MWIR/LWIR FPAs under the U.S. Army’s Dual-
Band FPA Manufacturing program. These dual-band detector arrays are based upon a
mercury-cadmium-telluride (HgCdTe) n-p-n triple-layer heterojunction (TLHJ) back-
to-back diode detector structure. The ”bottom” n-type absorbing layer has a shorter
cutoff (MWIR) than the ”top” n-type absorbing layer (LWIR). Detector arrays are
fabricated by etching mesa structures in the TLHJ and extending beyond the bottom
p-n (MWIR) junction. Only a single indium bump per pixel is then required for ROIC
interconnections. The cross section of the stack diode structure is shown in Figure 2.1.
This stacked structure permits either of the two p-n junctions within each detector
element to be reverse-biased by applying the appropriate voltage to the mesa top
contact. By alternating between two pre-determined bias voltage values, the photo-
response of the diode stack can be switched between MWIR and LWIR bands. The
bias switching is either performed on an alternating frame basis or many times within
a single frame period. The 1280 x 720 detector arrays have LWIR cut-off wavelengths
longer than 10.5 µm at 78 K. These FPAs have demonstrated high-sensitivity at 78
K with MWIR NETD values less than 20 mK and LWIR NETD values less than 30
mK with f/3.5 aperture. Pixel operability greater than 99.9% has been achieved in the
MWIR band and greater than 98% in the LWIR band.
Jet Propulsion Laboratory (JPL) demonstrated a megapixel (1024x1024) dual-band
QWIP FPA based on the standard AlGaAs/InGaAs/GaAs material system [13]. Full
width at half maximum (FWHM) of the MWIR part covers 4.4-5.1 µm and that of the
LWIR detector covers 7.8-8.8 µm. The FPA was fabricated with co-registered pixels
with two indium bumps per pixel approach. MWIR part consists of coupled-quantum
wells to broaden the spectral response. At 90 K FPA temperature, MWIR stack is
under BLIP condition with f/2.5 optics up to -1 V bias and exhibits a peak detectivity
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of 4x1011 cmHz1/2/Watt. LWIR stack is BLIP at 72 K temperature with -1 V bias
and f/2.5 aperture. Peak detectivity for LWIR stack is 1x1011 cmHz1/2/Watt at 70 K
FPA temperature. They report NETD values of 27 and 40 mK at 70 K FPA tempera-
ture with f/2 optics for MWIR and LWIR band, respectively. Main problem with the
approach is the complexity of the fabrication procedure (thirteen layer photolithog-
raphy) which results in low operability. Operability of the reported FPA is around
90 % according to 3σ definition for both bands, and low operability is explained by
discontinuities of the metal lines.
Figure 2.1: Pixel architecture for TLHJ type dual-band detectors. Band 1 is designedto respond to MWIR radiation and Band 2 is designed to respond to LWIR radiation[11].
These two demonstrations by RVS and JPL represent the latest published results in
the dual-band FPA field. There are other mid- and large-format FPAs previously
reported by several groups. Lockheed Martin demonstrated 256 x 256 pixel dual-
band FPAs with 40 µm pitch size featuring three indium bumps per pixel [23]. The
reported MWIR/LWIR FPA shows detection in two separate bands peaked at 5.1 µm
and 8.5 µm. The pixel operability of the FPA is larger than 97%, NETD is better than
35 mK (T = 65 K, f/2 optics, 295 K background, and 100 Hz frame rate), and the
uncorrected uniformity (sigma/mean) is smaller than 4% for both colors. The pixel
reading scheme of the FPA is illustrated in Figure 2.2. They have also demonstrated
FPAs in MWIR/MWIR and LWIR/LWIR configurations with the same approach.
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Figure 2.2: Pixel architecture with multiple electrical contact. The responses fromred QWIP and blue QWIP are integrated into different capacitors [23].
CEA/LETI achieved the dual-band imaging capability with multiple contact pixel
architecture using HgCdTe detector technology [24]. The epilayer structure of the
reported detector consists of a p-type MWIR HgCdTe layer grown on top of a LWIR
one. These two layers are isolated by a layer with larger bandgap (SWIR). The fab-
rication starts with the etching of the holes in order to reach the buried LWIR region.
Two photodiodes are then formed by n-type ion implantation (Figure 2.3). The re-
maining p-type layers are connected together as the detector common node (Figure
2.3). The reported FPA has cut-off wavelengths of 4.8 and 9.7 µm in the MWIR
and LWIR bands, respectively. The fabricated FPA is hybridized to a custom ROIC
designed for this structure, and characterized at 77 K detector temperature with f/2
optics. NETD values of 12 mK and 25 mK are reported with operabilities of 99.1 %
and 95.1 % in MWIR and LWIR bands, respectively.
Figure 2.3: Multiple contact pixel architecture by CEA/LETI. Two photodiodes areformed in different p-type regions by ion implantation (right), p-type regions are con-nected together as the detector common node (left) [24].
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A different approach to achieve multi-band capability is demonstrated by Gunapala
et.al [25]. In this approach, the pixels responsive in different bands are spatially
separated on the same array. A four-band device structure is achieved by the growth
of multi-stack QWIP structures separated by heavily doped n+ contact layers on a
GaAs substrate. Device parameters of each QWIP stack are designed to respond in
different wavelength bands. The schematic of the device structure is shown in Figure
2.4. Four separate detector bands are defined by a deep trench etch process, and the
unwanted spectral bands are eliminated by a detector short circuiting process. The
unwanted top detectors are electrically shorted by gold coated etched gratings. The
unwanted bottom QWIP stacks are electrically shorted at the end of each detector
pixel row. The FPA is hybridized to a standard CMOS multiplexer. The spectral
response of the four stacks are reported to be between 4-5.5, 8.5-10, 10-12, and 13.5-
15 µm. The NETDs are 21.4, 45.2, 13.5, and 44.6 mK (at 40 K) in these bands,
respectively. An example image recorded with the four-band detector is shown in
Figure 2.5.
Figure 2.4: Layer diagram of the four-band QWIP device structure. Each pixel rep-resent a 640 x 128 pixel area of the four-band focal plane array [25].
21
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Figure 2.5: An image recorded with the four-band detector [25].
2.3 Advantages of QWIPs for Dual/Multi-Band Detection
Different methods are present in the literature in order to implement dual-band ca-
pability in different detector technologies. Advantages and disadvantages of these
methods and technologies should be mentioned before investigating the advantages
of QWIPs over them.
QWIPs are mostly challenged by low bandgap infrared materials. Cut-off wavelength
is the only adjustable parameter for the spectral response of a low bandgap material,
and material is sensitive to all the wavelengths below this limit. It is too difficult to
isolate the spectral regions in a dual-band detector with a low bandgap semiconductor
because the material with higher cut-off wavelength tends to cover all the response
from the material with lower cut-off. In the triple layer heterojunction type dual-band
detection, spectral regions are separated by exploiting the high absorption quantum
efficiency of the material. The layer with higher cut-off wavelength is placed first
on the path of illumination, and behaves as a filter for the layer with lower cut-off
by absorbing all the photons above its bandgap energy. However, spectral isolation
with this approach is limited, and it is very difficult to create spectral gaps if not
impossible. At this point, QWIPs are clearly very advantageous since the cut-on
and cut-off wavelengths can be adjusted independently for each stack, and precise
22
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tailoring of the spectral response is very easy.
HgCdTe, which is one of the most popular detector materials, still suffers from ma-
terial instabilities and lack of high quality large area substrates after decades of its
discovery. These facts increase the cost of the HgCdTe based detectors by decreasing
yield and production volume. Lattice matched 7x7 cm2 CdZnTe substrates are pro-
nounced as state of the art substrate sizes [11]. On the other side, GaAs based QWIP
technology is very mature and well proven. Fabrication methods are well investigated
in the literature, and high quality large substrates are widely available at affordable
prices. Resulting high volume production capability with low cost and high yield
makes QWIPs very favorable as an infrared detector solution.
Thermal imaging performance of the QWIPs is shown to be more than satisfactory
at moderate frame rates, and dual-band imaging capability can be easily integrated
into the present technology without compromising any of the advantages of the sin-
gle band QWIPs. Therefore, QWIPs are very promising as a solution to dual-band
imaging requirements of the new generation systems with low cost at the sensor level.
2.4 QWIP Basics
Design of QWIP structures requires the knowledge on the key performance parame-
ters which will be presented in this section.
2.4.1 Theory of Operation
Theory of operation of QWIPs is briefly introduced in section 1.2. QWIP structures
consists of alternating layers of a large bandgap barrier material and low bandgap well
material. This well-barrier stack is placed between two highly doped contact layers
as shown in Figure 2.6. Discontinuities in the conduction band and valence band of
the structure produce a well shaped confinement in one dimension. This confinement
leads to quantization of the energy levels and discrete energy states are formed. The
band diagram of a typical QWIP structure is shown in Figure 2.7.
Incoming radiation is detected by the interaction of the quantized electrons with the
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photons. Photoexcited electrons form the photocurrent flowing through the device.
Under dark conditions, excitations are mostly due to thermionic emission which con-
stitutes the device dark current. Schrödinger equation with proper boundary condi-
tions should be solved to find the energy levels. Energy levels are determined by the
width and depth of the well and the effective mass of the electron in the well material.
Width of the well is controlled with the thickness of the well material, and depth of
the well is dependent on the band discontinuity which is controlled with the composi-
tions of well and barrier materials. Transitions between ground state and first excited
state are of interest for regular QWIP operation. Change of energy levels and corre-
sponding peak absorption wavelength with well width are depicted in Figure 2.8 for
different compositions of AlxGa1−xAs/GaAs material system.
Figure 2.6: Typical QWIP structure [26].
Figure 2.7: Typical band diagram of the QWIP [26].
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Figure 2.8: Dependence of energy states [left] and peak absorption wavelength [right]on well width for different Al mole fraction [27].
QWIPs are classified according to the position of the first excited energy state. QWIPs
in which the first excited energy state is below the edge of the barrier are called bound-
to-bound QWIPs. First excited state can be located at the edge of the barrier, then it
is called a bound-to-quasibound QWIP. In these two cases, excited electron needs
to tunnel through the tip of the barrier where high electric field is required to force
excited electrons to tunnel. QWIPs in which the first excited state is above the edge of
the barrier are called bound-to-continuum QWIPs, and small electric field is required
only to collect the electrons excited to continuum. As the excited state moves into
continuum, detector responsivity becomes less dependent on bias voltage, and the
spectral response becomes wider. The typical spectral responses of different QWIP
types are shown in Figure 2.9. Transition rate from ground states to excited states
can be found via Fermi’s Golden Rule. Using the transition rate, theoretical quantum
efficiency is estimated as follows [15, 18]
η =q2hS in2θ
Cosθn2D f δ(E2 − E1 − ~ω). (2.1)
In this equation, n2D is two dimensional electron density in the well, θ is the angle
of incidence, and f is the oscillator strength. Dependence of quantum efficiency on
the angle of incidence predicts no response to normal incidence. The quantum effi-
ciency is maximized if the radiation is perpendicular to growth direction which is not
practically possible.
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Figure 2.9: Typical spectral responses of different QWIP types.
In practice, QWIPs show non-zero response to normal incident radiation, and this is
explained by auxiliary mechanisms and imperfections. Light coupling schemes are
utilized to increase the quantum efficiency of QWIPs which is in the range of 5-10%.
Implementing grating structures on top of the pixel is a common method to increase
light coupling of QWIPs as shown in Figure 2.10. Incoming radiation is diffracted by
the grating structure creating a component parallel to the quantum wells. Diffraction
gratings are applicable at the FPA level and commonly employed. Another method to
increase light coupling efficiency in QWIPs is the corrugated pixel structure. In this
method, FPA pixels are structured so that incoming photons are reflected from walls
and propagate parallel to the active region. Illustration of the structure is depicted in
Figure 2.11.
As reflected by Eqn.2.1, quantum efficiency of the device is increased with the well
doping density. However, dark current in the device also increases with increasing
doping density. Another mechanism determining the dark current level in the device
is the transition type. Dark current density is increased as the excited level is moved
into continuum. Therefore, the position of the excited state determines both the dark-
and photo-current at a specific bias. As shown in Figure 2.9, αp∆λ/λpeak
NDis almost
constant where αp is the peak absorption coefficient, and ∆λ is the full width at half
maximum of the responsivity spectrum.
26
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Figure 2.10: Illustration of the effect of diffraction grating on the incoming radiation[26].
Figure 2.11: Corrugated pixel structure [28].
Capture and emission processes in QWIPs are illustrated in Figure 2.12. Capture
probability (pc) in a QWIP is defined as the probability of an electron to be captured
by a well while it is flowing through the device.
If the device current is dominated by photocurrent (Ip), the current captured by each
well (pcIp) must be equal to the current emitted (Iem). The emitted current is expressed
as
Iem = qφηsingle well = pcIp (2.2)
where φ is the number of photons falling on the detector in one second, and ηsinglewell
is the quantum efficiency of a single well.
27
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Figure 2.12: Illustration of the capture and emission mechanisms in QWIPs [26].
The total photocurrent expression generated by unit area of the detector is given as
Ip = qφηgphoto (2.3)
where η is the quantum efficiency of the overall structure, and gphoto is the photocon-
ductive gain. Therefore, the gain of a QWIP is expressed as
g =1pc
ηsingle well
η. (2.4)
It is known that quantum efficiency of a single well is very low (∼ 1%), thus it isconvenient to assume η � ηsingle wellN, where N is the total number of wells [18].
Therefore, the gain expression reduces to
gphoto =1
N pc. (2.5)
Photoconductive gain is also given by [18]
gphoto =τLτt
=τLυdri f t
τtυdri f t=
Ldri f tLdevice
(2.6)
where τL is the lifetime of the photoexcited carriers, τt is the transit time of the carriers
through the QWIP structure, υdri f t is the drift velocity of the carriers, Ldri f t is the drift
distance of the excited carriers, and Ldevice is the length of the quantum well stack.
More intuitively, this expression states that the gain of the device is equal to the ratio
of the total number of excited electrons to the number of electrons collected at the
contacts.
28
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The Johnson noise and 1/f noise are not dominant in QWIPs under typical operating
conditions. The G-R noise is generally the dominant noise source in QWIPs, and
this noise arises from fluctuations in the device current due to both dark- and photo-
current generation mechanisms. Total G-R noise in a QWIP is therefore expressed
as
in =√
4qgnoise(qnthermalυdri f tAd + qφηgphoto)∆ f (2.7)
where nthermal is the thermally excited electron density, and the products qφηgphoto and
qnthermalυdri f tAd represent the photocurrent and the dark current flowing through the
device, respectively.
Under dark current limited conditions caused by low illumination level or high detec-
tor temperature, expression of detector noise is reduced to
in =√
4q2gnoisenthermalυdri f tAd∆ f . (2.8)
Detectivity of the QWIP is therefore expressed by using Eqns. 1.5, 1.9 and 2.8 as
D∗dark =η
2hc/λ
√τL
nthermalLdevice. (2.9)
The temperature dependence of the detectivity of the QWIP is given in Figure 2.13.
The detectivity increases with decreasing detector temperature until the BLIP tem-
perature is reached. This increase in the detectivity is due to the suppression of
the thermionic emission with decreasing temperature. After the BLIP temperature
is reached, detectivity is background limited and does not considerably depend on
detector temperature. Under this (BLIP) condition the detectivity is given as
D∗BLIP =λ
2hc
√η
φp. (2.10)
The above equation shows that the BLIP detectivity is independent of the device gain.
However, it depends considerably on the quantum efficiency of the detector.
29
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Figure 2.13: Temperature dependence of the detectivity of the QWIPs [26].
2.4.2 Material Systems for QWIPs
The major advantage of the QWIP technology is its low cost due to the relatively
mature III-V semiconductor technologies utilized in the fabrication of focal plane
arrays. While the III-V semiconductor famility offers a wide range of heterostructure
systems suitable for QWIP fabrication, the low cost nature of the technology can
only be preserved if the device is based on mature III-V semiconductor systems such
as AlGaAs/GaAs or InP/InGaAs(P). Table 2.1 lists the alternatives offered by these
material systems for different applications.
Material systems on InP provides certain advantages for single and dual-band QWIPs.
While the InP/InGaAs and InP/InGaAsP systems provide higher responsivity than
their GaAs based counterparts in the LWIR band, AlInAs/InGaAs system provides
a lattice matched solution in the MWIR band [29]. Higher responsivity of the InP
based QWIPs is a result of the larger gain offered by this material system. This larger
gain arises from the higher drift distance of the photoexcited electrons which was
shown by detailed ensemble Monte Carlo simulations to be due to longer lifetime of
the photoexcited carriers [30].
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Table 2.1: Mature III-V material systems used for QWIP fabrication. Eg1 and Eg2are the bandgaps of the materials and ∆Ec is conduction band discontinuity of theresulting heterostructure.
Material System Eg1 (eV) Eg2 (eV) ∆Ec Comments
AlxGa1−xAs/GaAs Variable 1.43 Variable Used for LWIR QWIPs∆Ec is insufficient forMWIR QWIPswith acceptable x
AlxGa1−xAs/InyGa1−yAs Variable Variable Variable Used for MWIR QWIPsInP/In0.53Ga0.47As 1.35 0.75 0.25 Used for LWIR QWIPs
High
-
NETDs of the FPA are as low as 14 and 40 mK with integration times as short as 1.8
ms and 250 µs (f/1.5, 65 K). Without field of view correction, the uncorrected DC
signal and NETD nonuniformities of the FPA are 5.5% and 15%, respectively [34].
Figure 2.14 shows the NETD of the FPA calculated using the measurements on the
test detectors which are identical to the FPA pixels. The integration times shown at
each bias voltage correspond to half-filled ROIC capacitors (1.1x107 electron capac-
ity). A thermal image recorded with an integration time of 500 µs is shown in Figure
2.15 displaying the successful operation of the FPA with very short integration times.
Figure 2.14: Dependence of the NETD on detector bias [34].
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Figure 2.15: Thermal image recorded with the 640x512 InP/InGaAs FPA at 65 Kdetector temperature with an integration time of 500 µs and f/2 optics [34].
In the MWIR band, we have shown that cut-off wavelength of AlInAs/InGaAs QWIPs
on InP substrates can be adjusted very flexibly from 4.15 µm to 5.1 µm by changing
only the well width without deviating from the lattice matched composition [35].
Figure 2.16 shows the normalized responsivity spectrum of various InAlAs/InGaAs
MWIR QWIPs with well widths ranging from 22 to 30 Å. We have demonstrated
the performance of the AlInAs/InGaAs material system in the MWIR band at the
FPA level. A large format (640x512) FPA was fabricated using an epilayer structure
consisting of thirty 23 Å thick, Si doped (ND = 4 x 1018 cm−3) In0.53Ga0.47As quan-
tum wells sandwiched between 300 Å thick Al0.52In0.48As barriers. The FPA yielded
excellent sensitivity with an NETD as low as 22 mK (τint = 20 ms) and a BLIP tem-
perature as high as 115 K with f/1.5 aperture and 300 K background [29].
33
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Figure 2.16: Responsivity spectrum of AlInAs/InGaAs/InP QWIPs with differentwell widths [29].
2.5 Design Approach
Our design process of a MWIR/LWIR dual-band QWIP FPA is started with the selec-
tion of the virtually most feasible approach for the fabrication of large format dual-
band detector arrays. The detector epilayer structure is designed based on the theoret-
ical expectations and experimental observations. Once the measurements on the test
detectors reflected acceptable performance, large format FPAs were fabricated with
the optimized epilayer structure.
2.5.1 Selection of Dual-Band Operation Type
In order to implement dual-band sensing capability on a single detector array, there
are mainly three schemes implemented in the literature. The first approach is to em-
ploy a multi-contact pixel geometry [13, 23, 24, 36]. In this method, two independent
active regions are grown one on the top of other, and these active regions are driven
by two or three electrical contacts. The main advantage of this method is that it
34
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provides temporal and spatial coherence at the same time. However, fabrication of
such a structure deviates from the standard single contact process, and it is greatly
complicated. Furthermore, placing at least two In bumps on each pixel practically es-
tablishes a lower limit for the pitch size making it impossible to obtain high resolution
with an acceptable FPA size. Pixel structure with two and three electrical contacts are
illustrated in Figure 2.17.
Figure 2.17: Multi-contact pixel schemes for co-registered dual-band operation. (a)Fully isolated pixels with three electrical contacts. (b) Mid-contact layer is shortedto ground contact layer as the detector common. Passivation layer exists betweendetector stacks [13].
The second approach is to employ space shared pixel placement [37]. In this ap-
proach, two independent active regions are grown. One stack of each pixel is deacti-
vated either by removing (etching) the stack or short circuiting both ends of the stack.
Pixels are placed in the form of a checkerboard or line by line. This approach is not
preferred because spatial coherence is crucial in most of the applications. Addition-
ally, operating conditions (detector bias, integration time and well capacity) can not
be optimal for both bands at the same time, unless a special ROIC is used. Further-
more, fill factor of the FPA is greatly degraded. A sample pixel placement for space
sharing dual-band operation approach is illustrated in Figure 2.18. Demonstration of
implementation of this approach has been limited in the literature.
35
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Figure 2.18: Space sharing pixel placement. Pixels are placed in lines or as in acheckerboard [38].
The third approach is to obtain dual-band operation by tuning of the spectral response
of the detector with the applied detector bias [11, 39, 40, 41]. In this method, detector
structure is specially designed so that the peak responsivity wavelength shifts from
one band to the other with the changing detector bias. The detector structure used
in this approach is illustrated in Figure 2.19. The main advantage of bias tuning
scheme is the utilization of the same fabrication process with single band detectors.
Consequently, production is simple, yield is high, cost is low, and detector pitch can
be decreased freely to keep the resolution diffraction limited. The main issue with
this approach is the lack of temporal coherence. Pixels can be operated in one band
at a time. In order to obtain the scene in two bands simultaneously, the detector
bias is continuously switched in consecutive frames during imaging. Therefore, there
exists one frame delay between the frames of the same band. This reading scheme
is problematic only at rapidly changing scenes. The time delay between the frames
of each band can be reduced by decreasing the integration time of the other band.
However, it should be noted that the detector’s sensitivity is sacrificed in this case.
Noting the need for low cost dual-band sensors in affordable third generation thermal
imagers, this approach is selected in this work because of its fabrication simplicity,
smaller array size, high resolution and standard ROIC advantage.
36
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Figure 2.19: Dual-band operation employing one contact per pixel. Two active re-gions exist in each pixel and they are activated with the applied bias.
Several methods are demonstrated in the literature to obtain dual-band voltage tun-
able spectral response. Choi et.al. demonstrated a 256x256 voltage tunable AlGaAs/
InGaAs/GaAs MWIR/LWIR QWIP FPA with NETD performances of 27 mK (τint =
33 ms) in the MWIR band and 90 mK (τint = 2 ms) in the LWIR band for f/2.44 optics
and 50 K FPA temperature [40]. Spectral tuning mechanism was based on photocur-
rent asymmetry in a double-supperlattice quantum well structure. In this structure,
two quantum well stacks with thin barriers are separated by a graded barrier in the
middle as shown in Figure 2.20.
Figure 2.20: Band diagram of a voltage-tunable two-color detector. The numeralswithout units are either energies in milli-electron volts or thicknesses in angstroms.The Al and In molar ratios are denoted by x and y, respectively [40].
37
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There is no voltage drop on the stacks because of the sequential tunneling through
ground minibands, and the resistance of the structure is determined by the middle
contact. When a bias is applied to the structure, the electron injection into the barrier
is controlled by the photoexcitation from one of the stacks only. Therefore spectral
response of the overall structure is switched from one stack to the other by switching
the bias polarity as shown in Figure 2.21. However, the main drawback of the struc-
ture is the large thermally assisted tunneling which results in high dark current and
low operating temperature. Currently, this fundamental problem exists as a limitation
to reach a feasible operating temperature with this approach.
Figure 2.21: Responsivity spectra under various bias voltages [40].
Zhang et.al. also published promising results on voltage tuning of spectral response
[42]. They reported the single pixel characterization of a combined photovoltaic (PV)
and photoconductive (PC) QWIP structure. PV stack (MWIR) consists of AlGaAs/
AlAs/GaAs double barrier quantum wells, and PC stack (LWIR) consists of standard
bound-to-continuum AlGaAs/GaAs quantum wells. At zero external bias, responsiv-
ity of the PV stack is close to saturation, and PC stack does not contribute to response,
since there is no electric field to collect excited carriers. At positive bias, PC stack
starts to show its response, but response of the PV stack is decreased because of the
reduced drift distance of excited electrons [42]. Authors have no published work on
the FPA level characterization of this detector structure.
38
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We reported a MWIR/MWIR dual-color QWIP FPA in which voltage-tunable spectral
response has been achieved through series connection of two eight-well stacks of
AlGaAs/InGaAs epilayers grown by molecular beam epitaxy on GaAs substrate [39].
The peak responsivity wavelength of the detectors is shifted from 4.1 µm (color 1)
to 4.7 µm (color 2) as the bias is increased from -1 V to -3.5 V as shown in Figure
2.22. The operability of the FPA is ∼99.5%, and NETDs of ∼ 60 and 30 mK (f/1.5)are achieved in color modes 1 and 2, respectively. The voltage-tunable shift in the
responsivity spectrum is attributed to two different QWIPs acting in series with each
other. The distribution of the applied bias voltage between the two QWIPs (based on
relative resistances) and their relative responsivities determine the spectral response
of the structure [43].
Figure 2.22: Voltage tunable MWIR/MWIR spectral response reported by Kaldirimet.al [39].
In this thesis work, we adopted a similar approach which exploits the saturation of
the responsivity and dark current limited operation in QWIPs based on the AlGaAs/
InGaAs/GaAs material system. This approach will be detailed in the following sec-
tion.
39
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2.5.2 Operation of Voltage Tunable Detector Structure
If a multi quantum well stack sensitive in the MWIR atmospheric window is con-
nected in series with a LWIR sensitive stack, the spectral response of the resultant
structure depends on the distribution of the applied bias voltage between these stacks
and the relative responsivities of the stacks. On the other hand, the division of the bias
voltage between the two stacks depends on the individual stack resistances. Under
dark current limited conditions, the stack resistances do not considerably depend on
the photocurrents flowing through them. Similarly, under background limited condi-
tions, stack currents do not depend considerably on the detector bias after the respon-
sivity is saturated. Therefore, if the structure is designed properly to switch significant
portion of the total bias voltage from one stack to the other under two different bias
voltages, the desired spectral response can be achieved.
In order to explain the concept in further details, consider the characteristic I-V be-
havior of the standard AlGaAs/GaAs QWIPs under illumination, as illustrated in Fig-
ure 2.23. In region I, current increases strongly with increasing bias. Under BLIP
conditions, this increase in the total current is mostly due to the increase in the pho-
tocurrent which is indeed a result of increase in the responsivity. When biased in this
region, dynamic resistance of the detector is relatively small. In region II, dynamic
resistance increases due to saturation of the responsivity. When the responsivity of
the stack is saturated and the dark current is negligible with respect to the photocur-
rent (BLIP condition), dependence of the total detector current on the applied bias
voltage is decreased. However, due to the high responsivity, detector current is very
sensitive to the incoming radiation power. In Region III, dark current dominates over
photocurrent and BLIP condition is no longer valid. Detector behavior is vanished
unless extreme illumination is encountered.
In our approach, dual-band capability is achieved by sequential growth of specially
designed one color detectors separated by a conducting layer. It is experimentally
shown that this behavior of stacked devices corresponds to individual devices simply
connected in series [43].
40
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Figure 2.23: Characteristic I-V curve of standard AlGaAs/GaAs QWIP.
In our stack design, we have adjusted the dc and dynamical resistances for both of
the stacks such that, under low bias LWIR stack operates in region I and MWIR stack
operates in region II. The total detector current is mostly controlled by the stack which
has the larger dynamical resistance. At low bias, MWIR stack controls the detector
current, and a response in the MWIR band is observed from the overall structure.
When the bias is increased, MWIR stack is forced to enter the dark current dominated
regime, and the photoresponse of the LWIR part is almost saturated. In other words,
dynamical resistance of the MWIR stack is decreased when it moves from region II
to region III, and the dynamical resistance of the LWIR stack is increased by moving
from region I to region II. Therefore, control of the detector current is not at MWIR
stack, and overall detector response is LWIR dominated. The corresponding operating
points under low and high biases are illustrated in Figure 2.24.
Figure 2.24: Operation points of the series connected QWIP stacks in MWIR andLWIR modes.
41
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2.5.3 Design Targets
In this section design targets which we have determined prior to design are described
with justifications. Design targets include the spectral characteristics of the detector
structure, spectral switching requirement, thermal imaging performance and feasible
operation conditions.
The spectral response of each stack should be properly designed to cover the neces-
sary portions of the corresponding atmospheric windows. It is beneficial to extend
the cut-off wavelength of the MWIR part toward 5.0 µm as much as possible due
to significant increase of photon flux from room temperature objects. Cut-on wave-
length should be selected taking into account scattered background from sun, stray
light sources and hot sources. Absorption/emission band of CO2 should be also taken
into account. In our design we targeted a peak response wavelength above 4.5 µm
(upper end of the CO2 absorption region) and a cut-off wavelength around 5 µm. In
the design of the spectral response of the LWIR part, there is an important trade-off
between long range performance and operation temperature. Long range performance
in the LWIR band improves significantly by increasing the cut-off wavelength above
9.0 µm, especially under water vapor rich conditions. However, background limited
performance is reached at lower detector temperatures as the cut-off wavelength is
extended. This arises from the fact that the thermionic emission is stronger from
shallower wells. In our design, we targeted a cut-off wavelength around 9 µm. Ac-
ceptable limit for the operation temperature in our case is 65 K. Close cycle stirling
coolers can reach this temperature with reasonable power consumption and lifetime.
There exists an important restriction that the switching of the spectral response should
be achieved within the applicable bias limit of a standard ROIC. In this work, com-
mercially available ISC9803 ROIC from Indigo/FLIR Systems is used. Specifications
of this ROIC are given in the Table 2.2.
42
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Table 2.2: Specifications of the ISC9803 ROIC.
ISC9803Array Size 640x512Array Pitch 25 µmInput Circuit Direct InjectionInput Polarity p-on-nElectron Well Capacity 11.2 Me−
Input Noise at Lowest Gain 550 e−
Gain 2 bits (x1, x1.3, x2, x4)Integration Type SnapshotIntegration Modes Integrate-While-Read
Integrate-Then-ReadNumber of Outputs Selectable 1,2 or 4Maximum Power Consumption 180 mW
The ISC9803 uses a direct injection input circuit as shown in Figure 2.25. Detector is
connected between the common node (Vdetcom) and the unit cell input by hybridiza-
tion. Detector current flows through the input gate transistor and charges up the inte-
gration capacitor. The voltage on the integration capacitor is sampled and multiplexed
to the column amplifier. The column amplifiers provide sample/hold, amplification,
and skimming functions. The signal from the column amplifiers are multiplexed to
the output buffers through output multiplexer [44].
The maximum allowed bias that can be applied to the detector by changing the Vdetcom
voltage is 3.5 V. Therefore, the dominant response should switch from one stack to the
other with adequate responsivity within the bias range of 0-3.5 V. Furthermore, the
spectral modes should be separated with minimum crosstalk. Crosstalk mechanisms
are investigated in further detail in the next chapter when discussing the experimental
results.
43
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Figure 2.25: Simplified unit cell schematic of the ISC9803 [44].
2.5.4 Design
Overview of the voltage-tunable dual-band QWIP structure and design variables are
shown in Figure 2.26. The AlGaAs/InGaAs/GaAs system is the standard material
system used in MWIR QWIPs. Spectral response is determined by the width of the
well and band discontinuity. In the design of the MWIR stack, reported results in the
literature are investigated. In order to achieve the required band discontinuity, the Al
mole fraction in the barriers and the In mole fraction in the wells are selected as x
= 0.35 and y = 0.2, respectively. Our target sp