KOLON HYDROCARBON RESINS

October 2008

History

1976. 2 Foundation of Kolon Chem. Co., Ltd.1976. 2 Foundation of Kolon Chem. Co., Ltd.1976. 3 Contract of Joint1976. 3 Contract of Joint--venture with Nippon Petrochemicals Co.,Ltd.venture with Nippon Petrochemicals Co.,Ltd.1977. 6 Completion of Aromatic Hydrocarbon Resins Plant in U1977. 6 Completion of Aromatic Hydrocarbon Resins Plant in Ulsanlsan

1990’s

1980’s

1970’s

1980. 1 Completion of Phenolic Resins Plant1980. 1 Completion of Phenolic Resins Plant1982.11 Completion of Coumarone1982.11 Completion of Coumarone--Indene Resins Plant in UlsanIndene Resins Plant in Ulsan1984.10 Completion of Production Facilities of Polyurethane Res1984.10 Completion of Production Facilities of Polyurethane Resinsins1984.12 Completion of Production Facilities of Alkyl Phenolic R1984.12 Completion of Production Facilities of Alkyl Phenolic Resinsesins1987.11 Completion of Super Absorbent Polymers Plant in Incheon1987.11 Completion of Super Absorbent Polymers Plant in Incheon1989. 5 Completion of Thermoplastic Polyurethane Resins Plant 1989. 5 Completion of Thermoplastic Polyurethane Resins Plant in Incheonin Incheon1989.10 Construction of Phenolic Resin Plant in Gimcheon1989.10 Construction of Phenolic Resin Plant in Gimcheon

1993. 7 Completion of Super Absorbent Polymers Plant in Gimche1993. 7 Completion of Super Absorbent Polymers Plant in Gimcheonon1993. 9 Completion of Aliphatic Hydrocarbon Resins Plant in Ul1993. 9 Completion of Aliphatic Hydrocarbon Resins Plant in Ulsansan1997. 1 Completion of Hydrogenated DCPD Resins Plant1997. 1 Completion of Hydrogenated DCPD Resins Plant

2000’s 2000. 3 Completion of DCPD2000. 3 Completion of DCPD--Phenol Resins Plant in GimcheonPhenol Resins Plant in Gimcheon2002. 2 Expansion Super Absorbent Polymer plant in Gimcheon2002. 2 Expansion Super Absorbent Polymer plant in Gimcheon2004. 2 Completion the construction of Kolon New Tackifying Res2004. 2 Completion the construction of Kolon New Tackifying Resin Plantin Plant2007. 6 Merge with 2007. 6 Merge with KolonKolon Industries Inc. and change its name to Industries Inc. and change its name to

KolonKolon Industries Chemical OrganizationIndustries Chemical Organization

Vision

World Top 3 HCR Manufacturer

Expansion of Production Capacity

Expansion of Production Capacity

Reinforcement ofGlobal Relationships

Reinforcement ofGlobal Relationships

Development ofEnvironment FriendlyHydrocarbon Resins

Development ofEnvironment FriendlyHydrocarbon Resins

The First Choice of Customers in the Chemical Specialties

ESHQ System

QualityISO 9001

QualityISO 9001

Safety & HealthOHSAS 18001KOSHA 18001

EnvironmentISO 14001

Kolon Industries is a member of KRCC(Korea Responsible Care Council)

Factory And R&D

Incheon Plant

Polyurethane ResinPVC Stabilizer

Hydrocarbon Resin

Ulsan Plant

Suzhou Plant

Phenolic Resins

Hydrocarbon Resin (KNT)

Yeosu Plant

R&D centerH/Q

SAPPhenolic Resin

Gimcheon Plant

HCRs Market & Kolon

Worldwide No. 4 HCR Supplier

‘World Class Product of Korea’ : Various Product Portfolio

Supplying 60 countires in the world

Brand & Capacity of HCRs

KOLON HYDROCARBON RESINS

Hydrocarbon Resin

LOW MOLECULAR WEIGHT

AMORPHOUS THERMOPLASTIC

Mw 300 - 3,000

0% CRYSTALLINITY

GLASSY POLYMER Tg > 30oC

Napha

H2H2

NCC

C2sC2s

C3sC3s

C4sC4s

RPGRPG

B.T.XExtractionB.T.XExtraction

BenzeneBenzene

TolueneToluene

XyleneXylene

C5 Stream

KOLON INDUSTRYHCRs PLANTs

C5 HCR

C9 HCR

H2 C5 HCR

Rubber compounding Rubber compounding

Hot Melt Road Marking Hot Melt Road Marking

Asphalt Compound.- Modified/Color Asphalt

Asphalt Compound.- Modified/Color Asphalt

Industrial Adhesives Industrial Adhesives

PSA Tapes- OPP, Cloth, PVC

PSA Tapes- OPP, Cloth, PVC

Hot Melt PSA for Hygiene Products

Hot Melt Adhesives- Packaging, Bookbinding..

Hot Melt Adhesives- Packaging, Bookbinding..

Miscellaneous Miscellaneous

H2 C5-C9 HCR

C9 Stream

Portfolio of Products

CI ResinsHIKOTACK®

C5/C9HIKOREZ®

H2-C5 ResinsSUKOREZ®

H2-C5/Cyclic/C9 ResinsSUKOREZ®

OthersHIKOTACK®

Modification

Ulsan Plant Yeosu Plant

C9/C5 ResinsHIKOTACK®

Hydrogenation

Slight Hydrogenation

Waterwhite Hydrogenation

H2-C5 ResinsSUKOREZ®

C9 AromaticRich

C9 ResinsHIKOTACK®

C5 Olefins, Cyclic Rich

CoumaroneIndene Rich

C5 ResinsHIKOREZ®

Kolon HCR Window

Application

ADHESIVES & SEALANTS RUBBER& TIRE

Non-Woven PSA

Packaging/Book-

binding

COATINGS & PAINT

INK &OTHERS

SUKOREZ® SU 100 / 400 SeriesSUKOREZSUKOREZ®® SU 100 / 400 SeriesSU 100 / 400 Series

RESINCOLOR

SUKOREZ® SU 200 SeriesSUKOREZSUKOREZ®® SU 200 SeriesSU 200 Series

HIKOREZ® H SeriesHIKOREZHIKOREZ®® H SeriesH Series

KOTACK® C Series KOTACKKOTACK®® C Series C Series

Hot Melt Solvent

HIKOREZ® A Series, C Series, R Series, T SeriesHIKOREZHIKOREZ®® A Series, C Series, R Series, T SeriesA Series, C Series, R Series, T Series

Water-White

Very LightColor

LightColor

Pale Yellow HIKOTACK® P Series, DP SeriesHIKOTACKHIKOTACK®® P Series, DP SeriesP Series, DP Series

Compatibility

Physical PropertyPhysical Property

- Differentiation according to softening point and aromatic contents- Typically Used with : EVA, SBS, SEBS, SIS, APP/APO

- Based on C5 cyclic rich feeds or C5 Cyclic with aromatic feeds- Hydrogenated to waterwhite or very light color

SUSU--9090

C5 / CyclicC5 / Cyclic /low Aromatic

C5 / Cyclic /High Aromatic

LowerMW

Higher MW

Feature

SUSU--100100SUSU--110110

Feature

SUSU--120120SUSU--130130 SUSU--200200

SUSU--210210SUSU--220220SUSU--230230

SUSU--400400SUSU--420420

Lower S.PSoft

Higher S.P

Hard

KNT Product

More Compatiblew/ SIS,SEBS,APP/APO

More Compatiblewith SBS, EVA

SUSU--490490

SUSU--100S100S

Kolon HCR Overview

SUKOREZ, WATER-WHITE RESINS

SU-90 SU-100 SU-110 SU-120 SU-130 SU-200 SU-210 SU-220 SU-230 SU-490 SU-400 SU-420

Specific Gravity ASTM D 71 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08

Softening Point ASTM E 28 oC 90 105 112 120 129 103 110 120 130 90 103 120

Color ASTM D 1544 APHA 20 20 20 30 30 80 80 80 80 30 30 30

Acid Value ASTM D 974 KOHmg/ g <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Heat Stability 200oC, 3hrs Ga.# <1 <1 <1 <1 <1 1.5 1.5 1.5 1.5 <1 <1 <1

Melt Viscosity Brookfield 140oC,cps 1200 5012 9450 15000 - - - - - - - -

Viscometer 160oC,cps 280 730 1330 4200 10400 450 1500 4700 13200 270 650 4500

180oC,cps 90 180 350 850 1500 150 340 810 1700 90 190 700

200oC,cps 40 75 125 215 215 - - - - - - -

EVA Com. 2:2:1 oC 65 65 65 65 95

1:1 45 95 110 160 44 46 115

Tg DSC oC 44 50 60 66 74 55 60 66 75 52 53 73

Flash Point ASTM D 92 oC >260 >270 >270 >270 >270 >270 >270 >270 >270 >270 >270 >270

M.W. G.P.C Mw 520 550 570 570 700 670 720 810 900 720 770 800

Physical Propert ies Test Method Unit

Physical PropertyPhysical Property

- Typically Used with : NR, BR, APP/APO, EVA, SIS, SBS, SEBS

- Differentiation according to molecular weight and modification degree

- Based on C5 cyclic rich feeds or C5 Cyclic with aromatic feeds

C5/Cylic C5/Cylic/Low Aromatic

C5/Cylic/High Aromatic Feature

LowerMW

HigherMW

Feature

H-2100H-2110H-2120H-2130H-2140

A-1100*A-1100S*R-1100*R-1100SC-1100A-1115

H-2300 H-2200

T-1095

T-1080T-1100

KNT Products

T-3100

* Acid Modified Grades

Higher Viscosity Mor Compatible

with BR, APP/APO

Lower Viscosity Mor Compatible

with SBS, EVA

Lower S.PSoft

Higher S.PHard

A-1100 A-1100S A-1115 C-1100 R-1100 R-1100S T-1080 T-1095 T-1100 T-3100

Specific Gravity ASTM D 71 0.98 0.98 0.98 0.98 0.98 0.98 0.99 0.99 0.99 1.02

Softening Point ASTM E 28 oC 100 100 112 100 100 100 87 95 100 100

Color ASTM D 1544 Ga.# 4 5 4 4 5 5 4 4 4 5

Acid Value ASTM D 974 KOHmg/ g 0.1 1.5 0.1 0.1 2.5 2.7 0.1 0.1 0.1 0.1

Bromine No. ASTM D 1158 Br.cg/ g 42 42 48 41 43 42 40 41 41 41

Heat Stability 200oC, 3hrs Ga.# 5 6 5 5 6 6 5 5 5 6

Melt Viscosity Brookfield 140oC,cps 5500 5500 7100 5800 6100 2800 3275 6000

Viscometer 160oC,cps 1100 1100 5250 1450 1200 1350 600 875 1300 900

180oC,cps 320 320 1280 430 320 410 200 235 400 270

200oC,cps 130 130 185 130 170 80 95 160

EVA Com. 2:2:1 oC 110 100 150 210 100 180 120 65 180 60

Tg DSC oC 48 48 62 48 48 48 37 44 49 50

Flash Point ASTM D 92 oC >270 >270 >270 >270 >270 >270 >265 >265 >270 >270

M.W. G.P.C Mw 1600 1600 3200 2800 1550 2300 2000 1500 2000 2000

Physical Properties Test Method UnitHIKOREZ, C5 RESINS

Kolon HCR Overview

Kolon HCR Overview

HIKOREZ, C5 RESINS

H-2100 H-2110 H-2120 H-2130 H-2200 H-2300

Specif ic Gravity ASTM D 71 1.08 1.08 1.08 1.08 1.08 1.08

Softening Point ASTM E 28 oC 103 110 120 130 100 100

Color ASTM D 1544 Ga.# 2 2 3 3 3 2

Acid Value ASTM D 974 KOHmg/ g 0.1 0.1 0.1 0.1 0.1 0.1

Heat Stability 200oC, 3hrs Ga.# 4 4 5 5 5 4

Melt Viscosity Brookfield 140oC,cps -

Viscometer 160oC,cps 550 1400 4700 13200 500 510

180oC,cps 160 330 810 1700 140 160

200oC,cps

EVA Com. 1:1 oC 45 65 95 140 47 46

Tg DSC oC 48 58 69 77 48 57

Flash Point ASTM D 92 oC >270 >270 >270 >270 >270 >270

M.W . G.P.C Mw 670 700 810 900 720 710

Physical Propert ies Test Method Unit

Physical PropertyPhysical Property

- Based on aromatic feeds and coumarone indene rich feeds

- Differentiation according to softening point and molecular weight and modification degree

- Typically used with : EVA, SBR, CR, Epoxy/Alkyd Resin

C9 Feeds C9 Feeds/Acid or Phenol

CoumaroneIndene feeds Feature

LowerMW

HigherMW

Feature

P-90(S)P-90HSP-110SP-120HP-120(S)P-120HSP-140P-150

DP-100 C-90C-120

P-120P

P-140MP-160

Lower S.PSoft

Higher S.PHard

(S) Means a light color

Kolon HCR Overview

HIKOTACK, C9 RESINS

DP-100 P-90 P-90S P-110S P-120P P-120 P-120S P-120HS P-140 P-150 P-160

Specif ic Gravity ASTM D 71 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08 1.08

Softening Point ASTM E 28 oC 98 98 98 111 118 120 120 128 145 153 160

Color ASTM D 1544 Ga.# 7 6 5.5 5 5 5 4 4 4 4 12

Acid Value ASTM D 974 KOHmg/ g <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 29.0

Bromine No. ASTM D 1158 Br.cg/ g 20.0 20.0 20.0 18.0 18.0 18.0 18.0 15.0 10.0 8.0 -

Heat Stability 200oC, 3hrs Ga.# 12 10 9 9 10 9 8 8 8 8 15

Melt Viscosity Brookfield 140oC,cps 800 830 830 11100 32500 32500 32500 135800 - - -

Viscometer 160oC,cps 210 225 225 1500 3125 3325 3325 10500 - - -

180oC,cps 65 70 70 360 600 635 635 1675 14000 35000 -

200oC,cps 25 30 30 110 175 185 185 360 2150 4750 18000

EVA Com. 2:2:1 oC 65 100 100 180 130 >220 >220 >220 >220 >220 >220

Tg DSC oC 50 50 50 61 67 70 70 79 95 102 112

Flash Point ASTM D 92 oC >250 >250 >250 >260 >270 >270 >270 >270 >270 >270 >270

M.W . G.P.C Mw 850 1000 1000 1400 1300 1600 1600 1800 2200 2400 3000

Physical Propert ies Test Method Unit

Analysis EquipmentAnalysis Equipment

Dispersion Kneader Hotmelt Gun

Solvent tape Pilot Hotmelt tape Pilot

Bar coater

Hotmelt Coater

Open/set time

Holding power

Basic Analysis